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qp_plugins_scemama/devel/qmcchem/qmc_e_curve.irp.f

116 lines
3.1 KiB
Fortran

program e_curve
use bitmasks
implicit none
integer :: i,j,k, nab, m, l
double precision :: norm
integer, allocatable :: iorder(:)
double precision , allocatable :: norm_sort(:)
PROVIDE mo_two_e_integrals_in_map mo_one_e_integrals
if (.not.read_wf) then
stop 'Please set read_wf to true'
endif
PROVIDE psi_bilinear_matrix_values nuclear_repulsion
if (.True.) then
print *, ''
print *, 'Energy: ', psi_energy(1)+nuclear_repulsion
endif
print *, ''
print *, '=============================='
print *, 'Energies at different cut-offs'
print *, '=============================='
print *, ''
print *, '=============================================================================='
print '(A8,2X,A8,A8,A8,2X,A12,2X,A10,2X,A12)', 'Thresh.', 'Ndet', 'Na', 'Nb', 'Cost', 'Norm', 'E'
print *, '=============================================================================='
double precision :: thresh
integer(bit_kind), allocatable :: det_i(:,:), det_j(:,:)
integer :: na, nb
nab = n_det_alpha_unique+n_det_beta_unique
allocate ( norm_sort(0:nab), iorder(0:nab) )
thresh = 1.d-8
do while (N_det > 1)
nab = n_det_alpha_unique+n_det_beta_unique
norm_sort(0) = 0.d0
iorder(0) = 0
do i=1,n_det_alpha_unique
norm_sort(i) = det_alpha_norm(i)
iorder(i) = i
enddo
do i=1,n_det_beta_unique
norm_sort(i+n_det_alpha_unique) = det_beta_norm(i)
iorder(i+n_det_alpha_unique) = -i
enddo
call dsort(norm_sort(1),iorder(1),nab)
na = n_det_alpha_unique
nb = n_det_beta_unique
do j=1,nab
i = iorder(j)
if ((i<0).and.(nb>1)) then
nb -= 1
do k=1,n_det
if (psi_bilinear_matrix_columns(k) == -i) then
psi_bilinear_matrix_values(k,1) = 0.d0
endif
enddo
else if ((i>0).and.(na>1)) then
na -= 1
do k=1,n_det
if (psi_bilinear_matrix_rows(k) == i) then
psi_bilinear_matrix_values(k,1) = 0.d0
endif
enddo
endif
if (thresh < norm_sort(j)) then
exit
endif
enddo
do k=1,N_states
psi_coef(1:N_det,k) = psi_bilinear_matrix_values(1:N_det,k)
call dset_order(psi_coef(1,k),psi_bilinear_matrix_order_reverse,N_det)
enddo
TOUCH psi_det psi_coef
psi_det = psi_det_sorted
psi_coef = psi_coef_sorted
do m=1,n_det
if (psi_coef_sorted(m,1) == 0.d0) exit
enddo
N_det = m-1
TOUCH psi_det psi_coef N_det
! Avoid providing psi_energy
if (.True.) then
double precision :: cost0, cost
cost0 = elec_alpha_num**3 + elec_beta_num**3
cost = (na-1) * elec_alpha_num**2 + &
(nb-1) * elec_beta_num**2 + &
elec_alpha_num**3 + elec_beta_num**3
cost = cost/cost0
double precision :: u_dot_u
norm = dsqrt(u_dot_u(psi_coef(1,1),N_det))
print '(E9.1,2X,I8,I8,I8,2X,F10.2,2X,F10.8,2X,F15.10)', thresh, N_det, &
na, nb, cost, norm, psi_energy(1) + nuclear_repulsion
thresh = thresh * dsqrt(10.d0)
endif
enddo
print *, '=========================================================='
deallocate (iorder, norm_sort)
end