srDFT_G2/G09/C2/C_vqz.out
2019-04-01 22:35:49 +02:00

2500 lines
156 KiB
Plaintext

Entering Gaussian System, Link 0=g09
Input=C_vqz.inp
Output=C_vqz.out
Initial command:
/share/apps/gaussian/g09d01/nehalem/g09/l1.exe "/mnt/beegfs/tmpdir/42372/Gau-42537.inp" -scrdir="/mnt/beegfs/tmpdir/42372/"
Entering Link 1 = /share/apps/gaussian/g09d01/nehalem/g09/l1.exe PID= 42538.
Copyright (c) 1988,1990,1992,1993,1995,1998,2003,2009,2013,
Gaussian, Inc. All Rights Reserved.
This is part of the Gaussian(R) 09 program. It is based on
the Gaussian(R) 03 system (copyright 2003, Gaussian, Inc.),
the Gaussian(R) 98 system (copyright 1998, Gaussian, Inc.),
the Gaussian(R) 94 system (copyright 1995, Gaussian, Inc.),
the Gaussian 92(TM) system (copyright 1992, Gaussian, Inc.),
the Gaussian 90(TM) system (copyright 1990, Gaussian, Inc.),
the Gaussian 88(TM) system (copyright 1988, Gaussian, Inc.),
the Gaussian 86(TM) system (copyright 1986, Carnegie Mellon
University), and the Gaussian 82(TM) system (copyright 1983,
Carnegie Mellon University). Gaussian is a federally registered
trademark of Gaussian, Inc.
This software contains proprietary and confidential information,
including trade secrets, belonging to Gaussian, Inc.
This software is provided under written license and may be
used, copied, transmitted, or stored only in accord with that
written license.
The following legend is applicable only to US Government
contracts under FAR:
RESTRICTED RIGHTS LEGEND
Use, reproduction and disclosure by the US Government is
subject to restrictions as set forth in subparagraphs (a)
and (c) of the Commercial Computer Software - Restricted
Rights clause in FAR 52.227-19.
Gaussian, Inc.
340 Quinnipiac St., Bldg. 40, Wallingford CT 06492
---------------------------------------------------------------
Warning -- This program may not be used in any manner that
competes with the business of Gaussian, Inc. or will provide
assistance to any competitor of Gaussian, Inc. The licensee
of this program is prohibited from giving any competitor of
Gaussian, Inc. access to this program. By using this program,
the user acknowledges that Gaussian, Inc. is engaged in the
business of creating and licensing software in the field of
computational chemistry and represents and warrants to the
licensee that it is not a competitor of Gaussian, Inc. and that
it will not use this program in any manner prohibited above.
---------------------------------------------------------------
Cite this work as:
Gaussian 09, Revision D.01,
M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria,
M. A. Robb, J. R. Cheeseman, G. Scalmani, V. Barone, B. Mennucci,
G. A. Petersson, H. Nakatsuji, M. Caricato, X. Li, H. P. Hratchian,
A. F. Izmaylov, J. Bloino, G. Zheng, J. L. Sonnenberg, M. Hada,
M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima,
Y. Honda, O. Kitao, H. Nakai, T. Vreven, J. A. Montgomery, Jr.,
J. E. Peralta, F. Ogliaro, M. Bearpark, J. J. Heyd, E. Brothers,
K. N. Kudin, V. N. Staroverov, T. Keith, R. Kobayashi, J. Normand,
K. Raghavachari, A. Rendell, J. C. Burant, S. S. Iyengar, J. Tomasi,
M. Cossi, N. Rega, J. M. Millam, M. Klene, J. E. Knox, J. B. Cross,
V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann,
O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski,
R. L. Martin, K. Morokuma, V. G. Zakrzewski, G. A. Voth,
P. Salvador, J. J. Dannenberg, S. Dapprich, A. D. Daniels,
O. Farkas, J. B. Foresman, J. V. Ortiz, J. Cioslowski,
and D. J. Fox, Gaussian, Inc., Wallingford CT, 2013.
******************************************
Gaussian 09: ES64L-G09RevD.01 24-Apr-2013
1-Apr-2019
******************************************
-------------------------------------
#p ROCCSD(T) cc-pVQZ pop=full gfprint
-------------------------------------
1/38=1/1;
2/12=2,17=6,18=5,40=1/2;
3/5=16,6=2,11=2,16=1,24=100,25=1,30=1,116=101/1,2,3;
4//1;
5/5=2,38=5/2;
8/5=-1,6=4,9=120000,10=1/1,4;
9/5=7,14=2/13;
6/7=3/1;
99/5=1,9=1/99;
Leave Link 1 at Mon Apr 1 18:12:15 2019, MaxMem= 0 cpu: 0.0
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l101.exe)
--
G2
--
Symbolic Z-matrix:
Charge = 0 Multiplicity = 3
C
NAtoms= 1 NQM= 1 NQMF= 0 NMMI= 0 NMMIF= 0
NMic= 0 NMicF= 0.
Isotopes and Nuclear Properties:
(Nuclear quadrupole moments (NQMom) in fm**2, nuclear magnetic moments (NMagM)
in nuclear magnetons)
Atom 1
IAtWgt= 12
AtmWgt= 12.0000000
NucSpn= 0
AtZEff= 0.0000000
NQMom= 0.0000000
NMagM= 0.0000000
AtZNuc= 6.0000000
Leave Link 101 at Mon Apr 1 18:12:15 2019, MaxMem= 33554432 cpu: 0.2
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l202.exe)
Input orientation:
---------------------------------------------------------------------
Center Atomic Atomic Coordinates (Angstroms)
Number Number Type X Y Z
---------------------------------------------------------------------
1 6 0 0.000000 0.000000 0.000000
---------------------------------------------------------------------
Stoichiometry C(3)
Framework group OH[O(C)]
Deg. of freedom 0
Full point group OH NOp 48
Largest Abelian subgroup D2H NOp 8
Largest concise Abelian subgroup C1 NOp 1
Standard orientation:
---------------------------------------------------------------------
Center Atomic Atomic Coordinates (Angstroms)
Number Number Type X Y Z
---------------------------------------------------------------------
1 6 0 0.000000 0.000000 0.000000
---------------------------------------------------------------------
Leave Link 202 at Mon Apr 1 18:12:15 2019, MaxMem= 33554432 cpu: 0.0
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l301.exe)
Standard basis: CC-pVQZ (5D, 7F)
Ernie: Thresh= 0.10000D-02 Tol= 0.10000D-05 Strict=F.
Ernie: 3 primitive shells out of 33 were deleted.
AO basis set (Overlap normalization):
Atom C1 Shell 1 S 8 bf 1 - 1 0.000000000000 0.000000000000 0.000000000000
0.3398000000D+05 0.1468124114D-03
0.5089000000D+04 0.1116460016D-02
0.1157000000D+04 0.5890887108D-02
0.3266000000D+03 0.2421725547D-01
0.1061000000D+03 0.8317163879D-01
0.3811000000D+02 0.2205684777D+00
0.1475000000D+02 0.4287314969D+00
0.6035000000D+01 0.3643614225D+00
Atom C1 Shell 2 S 7 bf 2 - 2 0.000000000000 0.000000000000 0.000000000000
0.5089000000D+04 -0.1002265364D-04
0.3266000000D+03 -0.4365894368D-03
0.1061000000D+03 -0.1932312730D-02
0.3811000000D+02 -0.2148394772D-01
0.1475000000D+02 -0.9030916566D-01
0.6035000000D+01 -0.4187915117D+00
0.2530000000D+01 -0.5318019058D+00
Atom C1 Shell 3 S 1 bf 3 - 3 0.000000000000 0.000000000000 0.000000000000
0.7355000000D+00 0.1000000000D+01
Atom C1 Shell 4 S 1 bf 4 - 4 0.000000000000 0.000000000000 0.000000000000
0.2905000000D+00 0.1000000000D+01
Atom C1 Shell 5 S 1 bf 5 - 5 0.000000000000 0.000000000000 0.000000000000
0.1111000000D+00 0.1000000000D+01
Atom C1 Shell 6 P 3 bf 6 - 8 0.000000000000 0.000000000000 0.000000000000
0.3451000000D+02 0.3168785521D-01
0.7915000000D+01 0.2128943073D+00
0.2368000000D+01 0.8395867520D+00
Atom C1 Shell 7 P 1 bf 9 - 11 0.000000000000 0.000000000000 0.000000000000
0.8132000000D+00 0.1000000000D+01
Atom C1 Shell 8 P 1 bf 12 - 14 0.000000000000 0.000000000000 0.000000000000
0.2890000000D+00 0.1000000000D+01
Atom C1 Shell 9 P 1 bf 15 - 17 0.000000000000 0.000000000000 0.000000000000
0.1007000000D+00 0.1000000000D+01
Atom C1 Shell 10 D 1 bf 18 - 22 0.000000000000 0.000000000000 0.000000000000
0.1848000000D+01 0.1000000000D+01
Atom C1 Shell 11 D 1 bf 23 - 27 0.000000000000 0.000000000000 0.000000000000
0.6490000000D+00 0.1000000000D+01
Atom C1 Shell 12 D 1 bf 28 - 32 0.000000000000 0.000000000000 0.000000000000
0.2280000000D+00 0.1000000000D+01
Atom C1 Shell 13 F 1 bf 33 - 39 0.000000000000 0.000000000000 0.000000000000
0.1419000000D+01 0.1000000000D+01
Atom C1 Shell 14 F 1 bf 40 - 46 0.000000000000 0.000000000000 0.000000000000
0.4850000000D+00 0.1000000000D+01
Atom C1 Shell 15 G 1 bf 47 - 55 0.000000000000 0.000000000000 0.000000000000
0.1011000000D+01 0.1000000000D+01
There are 20 symmetry adapted cartesian basis functions of AG symmetry.
There are 6 symmetry adapted cartesian basis functions of B1G symmetry.
There are 6 symmetry adapted cartesian basis functions of B2G symmetry.
There are 6 symmetry adapted cartesian basis functions of B3G symmetry.
There are 2 symmetry adapted cartesian basis functions of AU symmetry.
There are 10 symmetry adapted cartesian basis functions of B1U symmetry.
There are 10 symmetry adapted cartesian basis functions of B2U symmetry.
There are 10 symmetry adapted cartesian basis functions of B3U symmetry.
There are 14 symmetry adapted basis functions of AG symmetry.
There are 5 symmetry adapted basis functions of B1G symmetry.
There are 5 symmetry adapted basis functions of B2G symmetry.
There are 5 symmetry adapted basis functions of B3G symmetry.
There are 2 symmetry adapted basis functions of AU symmetry.
There are 8 symmetry adapted basis functions of B1U symmetry.
There are 8 symmetry adapted basis functions of B2U symmetry.
There are 8 symmetry adapted basis functions of B3U symmetry.
55 basis functions, 89 primitive gaussians, 70 cartesian basis functions
4 alpha electrons 2 beta electrons
nuclear repulsion energy 0.0000000000 Hartrees.
IExCor= 0 DFT=F Ex=HF Corr=None ExCW=0 ScaHFX= 1.000000
ScaDFX= 1.000000 1.000000 1.000000 1.000000 ScalE2= 1.000000 1.000000
IRadAn= 0 IRanWt= -1 IRanGd= 0 ICorTp=0 IEmpDi= 4
NAtoms= 1 NActive= 1 NUniq= 1 SFac= 1.00D+00 NAtFMM= 60 NAOKFM=F Big=F
Integral buffers will be 131072 words long.
Raffenetti 2 integral format.
Two-electron integral symmetry is turned on.
Leave Link 301 at Mon Apr 1 18:12:16 2019, MaxMem= 33554432 cpu: 0.1
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l302.exe)
NPDir=0 NMtPBC= 1 NCelOv= 1 NCel= 1 NClECP= 1 NCelD= 1
NCelK= 1 NCelE2= 1 NClLst= 1 CellRange= 0.0.
One-electron integrals computed using PRISM.
NBasis= 55 RedAO= T EigKep= 7.11D-02 NBF= 14 5 5 5 2 8 8 8
NBsUse= 55 1.00D-06 EigRej= -1.00D+00 NBFU= 14 5 5 5 2 8 8 8
Leave Link 302 at Mon Apr 1 18:12:16 2019, MaxMem= 33554432 cpu: 0.3
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l303.exe)
DipDrv: MaxL=1.
Leave Link 303 at Mon Apr 1 18:12:16 2019, MaxMem= 33554432 cpu: 0.1
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l401.exe)
ExpMin= 1.01D-01 ExpMax= 3.40D+04 ExpMxC= 3.27D+02 IAcc=1 IRadAn= 1 AccDes= 0.00D+00
Harris functional with IExCor= 205 and IRadAn= 1 diagonalized for initial guess.
HarFok: IExCor= 205 AccDes= 0.00D+00 IRadAn= 1 IDoV= 1 UseB2=F ITyADJ=14
ICtDFT= 3500011 ScaDFX= 1.000000 1.000000 1.000000 1.000000
FoFCou: FMM=F IPFlag= 0 FMFlag= 100000 FMFlg1= 0
NFxFlg= 0 DoJE=T BraDBF=F KetDBF=T FulRan=T
wScrn= 0.000000 ICntrl= 500 IOpCl= 0 I1Cent= 200000004 NGrid= 0
NMat0= 1 NMatS0= 1 NMatT0= 0 NMatD0= 1 NMtDS0= 0 NMtDT0= 0
Petite list used in FoFCou.
Harris En= -37.5365422630026
JPrj=0 DoOrth=F DoCkMO=F.
Initial guess orbital symmetries:
Occupied (A1G) (A1G) (T1U) (T1U)
Virtual (T1U) (A1G) (T1U) (T1U) (T1U) (EG) (EG) (T2G)
(T2G) (T2G) (T1U) (T1U) (T1U) (A1G) (T1U) (T1U)
(T1U) (A2U) (T2U) (T2U) (T2U) (EG) (EG) (T2G)
(T2G) (T2G) (A1G) (EG) (EG) (?A) (?A) (?A) (?A)
(?A) (?A) (T1U) (T1U) (T1U) (EG) (EG) (T2G) (T2G)
(T2G) (T1U) (T1U) (T1U) (A2U) (T2U) (T2U) (T2U)
(A1G)
Leave Link 401 at Mon Apr 1 18:12:16 2019, MaxMem= 33554432 cpu: 0.3
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l502.exe)
Restricted open shell SCF:
Using DIIS extrapolation, IDIIS= 1040.
Integral symmetry usage will be decided dynamically.
Keep R1 and R2 ints in memory in symmetry-blocked form, NReq=5758472.
IVT= 34895 IEndB= 34895 NGot= 33554432 MDV= 33204941
LenX= 33204941 LenY= 33199600
Requested convergence on RMS density matrix=1.00D-08 within 128 cycles.
Requested convergence on MAX density matrix=1.00D-06.
Requested convergence on energy=1.00D-06.
No special actions if energy rises.
FoFCou: FMM=F IPFlag= 0 FMFlag= 0 FMFlg1= 0
NFxFlg= 0 DoJE=F BraDBF=F KetDBF=F FulRan=T
wScrn= 0.000000 ICntrl= 600 IOpCl= 0 I1Cent= 0 NGrid= 0
NMat0= 1 NMatS0= 1540 NMatT0= 0 NMatD0= 1 NMtDS0= 0 NMtDT0= 0
Petite list used in FoFCou.
Cycle 1 Pass 1 IDiag 1:
Density matrix breaks symmetry, PCut= 1.00D-04
Density has only Abelian symmetry.
E= -37.6776254829626
DIIS: error= 5.99D-02 at cycle 1 NSaved= 1.
NSaved= 1 IEnMin= 1 EnMin= -37.6776254829626 IErMin= 1 ErrMin= 5.99D-02
ErrMax= 5.99D-02 0.00D+00 EMaxC= 1.00D-01 BMatC= 5.24D-02 BMatP= 5.24D-02
IDIUse=3 WtCom= 4.01D-01 WtEn= 5.99D-01
Coeff-Com: 0.100D+01
Coeff-En: 0.100D+01
Coeff: 0.100D+01
Gap= 0.144 Goal= None Shift= 0.000
GapD= 0.144 DampG=1.000 DampE=0.500 DampFc=0.5000 IDamp=-1.
Damping current iteration by 5.00D-01
RMSDP=2.16D-03 MaxDP=5.61D-02 OVMax= 7.92D-02
Cycle 2 Pass 1 IDiag 1:
Density matrix breaks symmetry, PCut= 1.00D-07
Density has only Abelian symmetry.
E= -37.6821231007372 Delta-E= -0.004497617775 Rises=F Damp=T
DIIS: error= 3.13D-02 at cycle 2 NSaved= 2.
NSaved= 2 IEnMin= 2 EnMin= -37.6821231007372 IErMin= 2 ErrMin= 3.13D-02
ErrMax= 3.13D-02 0.00D+00 EMaxC= 1.00D-01 BMatC= 1.33D-02 BMatP= 5.24D-02
IDIUse=3 WtCom= 6.87D-01 WtEn= 3.13D-01
Coeff-Com: -0.851D+00 0.185D+01
Coeff-En: 0.000D+00 0.100D+01
Coeff: -0.584D+00 0.158D+01
Gap= 0.119 Goal= None Shift= 0.000
RMSDP=9.69D-04 MaxDP=2.80D-02 DE=-4.50D-03 OVMax= 6.87D-02
Cycle 3 Pass 1 IDiag 1:
Density matrix breaks symmetry, PCut= 1.00D-07
Density has only Abelian symmetry.
E= -37.6855082611197 Delta-E= -0.003385160383 Rises=F Damp=F
DIIS: error= 9.50D-03 at cycle 3 NSaved= 3.
NSaved= 3 IEnMin= 3 EnMin= -37.6855082611197 IErMin= 3 ErrMin= 9.50D-03
ErrMax= 9.50D-03 0.00D+00 EMaxC= 1.00D-01 BMatC= 1.69D-03 BMatP= 1.33D-02
IDIUse=3 WtCom= 9.05D-01 WtEn= 9.50D-02
Coeff-Com: -0.448D+00 0.837D+00 0.610D+00
Coeff-En: 0.000D+00 0.000D+00 0.100D+01
Coeff: -0.405D+00 0.758D+00 0.647D+00
Gap= 0.122 Goal= None Shift= 0.000
RMSDP=9.17D-04 MaxDP=2.66D-02 DE=-3.39D-03 OVMax= 3.32D-02
Cycle 4 Pass 1 IDiag 1:
Density matrix breaks symmetry, PCut= 1.00D-07
Density has only Abelian symmetry.
E= -37.6880013251916 Delta-E= -0.002493064072 Rises=F Damp=F
DIIS: error= 3.49D-03 at cycle 4 NSaved= 4.
NSaved= 4 IEnMin= 4 EnMin= -37.6880013251916 IErMin= 4 ErrMin= 3.49D-03
ErrMax= 3.49D-03 0.00D+00 EMaxC= 1.00D-01 BMatC= 1.61D-04 BMatP= 1.69D-03
IDIUse=3 WtCom= 9.65D-01 WtEn= 3.49D-02
Coeff-Com: -0.356D+00 0.668D+00 0.404D+00 0.284D+00
Coeff-En: 0.000D+00 0.000D+00 0.000D+00 0.100D+01
Coeff: -0.344D+00 0.645D+00 0.390D+00 0.309D+00
Gap= 0.123 Goal= None Shift= 0.000
RMSDP=4.59D-05 MaxDP=1.29D-03 DE=-2.49D-03 OVMax= 1.39D-03
Cycle 5 Pass 1 IDiag 1:
Density matrix breaks symmetry, PCut= 1.00D-07
Density has only Abelian symmetry.
E= -37.6880496109507 Delta-E= -0.000048285759 Rises=F Damp=F
DIIS: error= 3.04D-03 at cycle 5 NSaved= 5.
NSaved= 5 IEnMin= 5 EnMin= -37.6880496109507 IErMin= 5 ErrMin= 3.04D-03
ErrMax= 3.04D-03 0.00D+00 EMaxC= 1.00D-01 BMatC= 1.34D-04 BMatP= 1.61D-04
IDIUse=3 WtCom= 9.70D-01 WtEn= 3.04D-02
Coeff-Com: -0.144D+00 0.273D+00 0.680D-02-0.272D+01 0.358D+01
Coeff-En: 0.000D+00 0.000D+00 0.000D+00 0.000D+00 0.100D+01
Coeff: -0.139D+00 0.265D+00 0.659D-02-0.263D+01 0.350D+01
Gap= 0.124 Goal= None Shift= 0.000
RMSDP=2.52D-04 MaxDP=7.31D-03 DE=-4.83D-05 OVMax= 9.15D-03
Cycle 6 Pass 1 IDiag 1:
Density matrix breaks symmetry, PCut= 1.00D-07
Density has only Abelian symmetry.
E= -37.6882580882016 Delta-E= -0.000208477251 Rises=F Damp=F
DIIS: error= 1.21D-03 at cycle 6 NSaved= 6.
NSaved= 6 IEnMin= 6 EnMin= -37.6882580882016 IErMin= 6 ErrMin= 1.21D-03
ErrMax= 1.21D-03 0.00D+00 EMaxC= 1.00D-01 BMatC= 2.15D-05 BMatP= 1.34D-04
IDIUse=3 WtCom= 9.88D-01 WtEn= 1.21D-02
Coeff-Com: -0.627D-02 0.125D-01 0.143D-01-0.676D-01-0.610D+00 0.166D+01
Coeff-En: 0.000D+00 0.000D+00 0.000D+00 0.000D+00 0.000D+00 0.100D+01
Coeff: -0.619D-02 0.123D-01 0.141D-01-0.667D-01-0.603D+00 0.165D+01
Gap= 0.125 Goal= None Shift= 0.000
RMSDP=1.63D-04 MaxDP=4.75D-03 DE=-2.08D-04 OVMax= 5.91D-03
Cycle 7 Pass 1 IDiag 1:
Density matrix breaks symmetry, PCut= 1.00D-07
Density has only Abelian symmetry.
E= -37.6882981489897 Delta-E= -0.000040060788 Rises=F Damp=F
DIIS: error= 4.89D-05 at cycle 7 NSaved= 7.
NSaved= 7 IEnMin= 7 EnMin= -37.6882981489897 IErMin= 7 ErrMin= 4.89D-05
ErrMax= 4.89D-05 0.00D+00 EMaxC= 1.00D-01 BMatC= 3.43D-08 BMatP= 2.15D-05
IDIUse=1 WtCom= 1.00D+00 WtEn= 0.00D+00
Coeff-Com: 0.876D-03-0.175D-02 0.718D-03 0.204D-01 0.150D-01-0.153D+00
Coeff-Com: 0.112D+01
Coeff: 0.876D-03-0.175D-02 0.718D-03 0.204D-01 0.150D-01-0.153D+00
Coeff: 0.112D+01
Gap= 0.125 Goal= None Shift= 0.000
RMSDP=7.80D-06 MaxDP=2.21D-04 DE=-4.01D-05 OVMax= 2.85D-04
Cycle 8 Pass 1 IDiag 1:
Density matrix breaks symmetry, PCut= 1.00D-07
Density has only Abelian symmetry.
E= -37.6882982117086 Delta-E= -0.000000062719 Rises=F Damp=F
DIIS: error= 7.54D-06 at cycle 8 NSaved= 8.
NSaved= 8 IEnMin= 8 EnMin= -37.6882982117086 IErMin= 8 ErrMin= 7.54D-06
ErrMax= 7.54D-06 0.00D+00 EMaxC= 1.00D-01 BMatC= 8.72D-10 BMatP= 3.43D-08
IDIUse=1 WtCom= 1.00D+00 WtEn= 0.00D+00
Coeff-Com: -0.207D-03 0.394D-03-0.592D-05-0.492D-02 0.786D-02 0.334D-02
Coeff-Com: -0.196D-01 0.101D+01
Coeff: -0.207D-03 0.394D-03-0.592D-05-0.492D-02 0.786D-02 0.334D-02
Coeff: -0.196D-01 0.101D+01
Gap= 0.125 Goal= None Shift= 0.000
RMSDP=1.33D-06 MaxDP=3.87D-05 DE=-6.27D-08 OVMax= 4.86D-05
Cycle 9 Pass 1 IDiag 1:
Density matrix breaks symmetry, PCut= 1.00D-07
Density has only Abelian symmetry.
E= -37.6882982132322 Delta-E= -0.000000001524 Rises=F Damp=F
DIIS: error= 1.86D-06 at cycle 9 NSaved= 9.
NSaved= 9 IEnMin= 9 EnMin= -37.6882982132322 IErMin= 9 ErrMin= 1.86D-06
ErrMax= 1.86D-06 0.00D+00 EMaxC= 1.00D-01 BMatC= 5.12D-11 BMatP= 8.72D-10
IDIUse=1 WtCom= 1.00D+00 WtEn= 0.00D+00
Coeff-Com: 0.623D-06-0.582D-06-0.203D-04 0.215D-03-0.474D-03-0.225D-02
Coeff-Com: -0.217D-02-0.196D+00 0.120D+01
Coeff: 0.623D-06-0.582D-06-0.203D-04 0.215D-03-0.474D-03-0.225D-02
Coeff: -0.217D-02-0.196D+00 0.120D+01
Gap= 0.125 Goal= None Shift= 0.000
RMSDP=2.66D-07 MaxDP=7.80D-06 DE=-1.52D-09 OVMax= 9.60D-06
Cycle 10 Pass 1 IDiag 1:
Density matrix breaks symmetry, PCut= 1.00D-07
Density has only Abelian symmetry.
E= -37.6882982133279 Delta-E= -0.000000000096 Rises=F Damp=F
DIIS: error= 1.75D-08 at cycle 10 NSaved= 10.
NSaved=10 IEnMin=10 EnMin= -37.6882982133279 IErMin=10 ErrMin= 1.75D-08
ErrMax= 1.75D-08 0.00D+00 EMaxC= 1.00D-01 BMatC= 4.83D-15 BMatP= 5.12D-11
IDIUse=1 WtCom= 1.00D+00 WtEn= 0.00D+00
Coeff-Com: -0.445D-06 0.971D-06-0.204D-05-0.117D-04-0.449D-04 0.250D-03
Coeff-Com: -0.226D-02 0.388D-02 0.291D-01 0.969D+00
Coeff: -0.445D-06 0.971D-06-0.204D-05-0.117D-04-0.449D-04 0.250D-03
Coeff: -0.226D-02 0.388D-02 0.291D-01 0.969D+00
Gap= 0.125 Goal= None Shift= 0.000
RMSDP=3.29D-09 MaxDP=1.02D-07 DE=-9.56D-11 OVMax= 1.09D-07
Density matrix breaks symmetry, PCut= 1.00D-07
Density has only Abelian symmetry.
SCF Done: E(ROHF) = -37.6882982133 A.U. after 10 cycles
NFock= 10 Conv=0.33D-08 -V/T= 2.0000
<Sx>= 0.0000 <Sy>= 0.0000 <Sz>= 1.0000 <S**2>= 2.0000 S= 1.0000
<L.S>= 0.000000000000E+00
KE= 3.768825252205D+01 PE=-8.813651313079D+01 EE= 1.275996239542D+01
Annihilation of the first spin contaminant:
S**2 before annihilation 2.0000, after 2.0000
Leave Link 502 at Mon Apr 1 18:12:19 2019, MaxMem= 33554432 cpu: 1.8
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l801.exe)
Windowed orbitals will be sorted by symmetry type.
Density matrix breaks symmetry, PCut= 1.00D-07
Density has only Abelian symmetry.
GenMOA: NOpAll= 48 NOp2=8 NOpUse= 8 JSym2X=1
FoFJK: IHMeth= 1 ICntrl= 0 DoSepK=F KAlg= 0 I1Cent= 0 FoldK=F
IRaf= 0 NMat= 1 IRICut= 1 DoRegI=T DoRafI=F ISym2E= 1.
FoFCou: FMM=F IPFlag= 0 FMFlag= 100000 FMFlg1= 0
NFxFlg= 0 DoJE=F BraDBF=F KetDBF=F FulRan=T
wScrn= 0.000000 ICntrl= 0 IOpCl= 1 I1Cent= 0 NGrid= 0
NMat0= 1 NMatS0= 1 NMatT0= 0 NMatD0= 1 NMtDS0= 0 NMtDT0= 0
Petite list used in FoFCou.
<Sx>= 0.0000 <Sy>= 0.0000 <Sz>= 1.0000 <S**2>= 2.0000 S= 1.0000
ExpMin= 1.01D-01 ExpMax= 3.40D+04 ExpMxC= 3.27D+02 IAcc=3 IRadAn= 5 AccDes= 0.00D+00
HarFok: IExCor= 205 AccDes= 0.00D+00 IRadAn= 5 IDoV=-2 UseB2=F ITyADJ=14
ICtDFT= 12500011 ScaDFX= 1.000000 1.000000 1.000000 1.000000
Largest valence mixing into a core orbital is 1.88D-04
Largest core mixing into a valence orbital is 4.32D-05
Largest valence mixing into a core orbital is 2.69D-04
Largest core mixing into a valence orbital is 1.24D-04
Range of M.O.s used for correlation: 2 55
NBasis= 55 NAE= 4 NBE= 2 NFC= 1 NFV= 0
NROrb= 54 NOA= 3 NOB= 1 NVA= 51 NVB= 53
Singles contribution to E2= -0.3245511131D-02
Leave Link 801 at Mon Apr 1 18:12:20 2019, MaxMem= 33554432 cpu: 1.2
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l804.exe)
Open-shell transformation, MDV= 33554432 ITran=4 ISComp=2.
Semi-Direct transformation.
ModeAB= 2 MOrb= 3 LenV= 33219256
LASXX= 28395 LTotXX= 28395 LenRXX= 28395
LTotAB= 30607 MaxLAS= 402570 LenRXY= 402570
NonZer= 443394 LenScr= 1310720 LnRSAI= 0
LnScr1= 0 LExtra= 0 Total= 1741685
MaxDsk= -1 SrtSym= F ITran= 4
DoSDTr: NPSUse= 1
JobTyp=1 Pass 1: I= 1 to 3.
(rs|ai) integrals will be sorted in core.
Complete sort for first half transformation.
First half transformation complete.
Complete sort for second half transformation.
Second half transformation complete.
ModeAB= 2 MOrb= 1 LenV= 33219256
LASXX= 9814 LTotXX= 9814 LenRXX= 134190
LTotAB= 9514 MaxLAS= 134190 LenRXY= 9514
NonZer= 147798 LenScr= 720896 LnRSAI= 0
LnScr1= 0 LExtra= 0 Total= 864600
MaxDsk= -1 SrtSym= F ITran= 4
DoSDTr: NPSUse= 1
JobTyp=2 Pass 1: I= 1 to 1.
(rs|ai) integrals will be sorted in core.
Complete sort for first half transformation.
First half transformation complete.
Complete sort for second half transformation.
Second half transformation complete.
Spin components of T(2) and E(2):
alpha-alpha T2 = 0.4441681328D-02 E2= -0.1372146477D-01
alpha-beta T2 = 0.2217566732D-01 E2= -0.6009787087D-01
beta-beta T2 = 0.0000000000D+00 E2= 0.0000000000D+00
ANorm= 0.1014237958D+01
E2 = -0.7706484677D-01 EUMP2 = -0.37765363060100D+02
(S**2,0)= 0.20000D+01 (S**2,1)= 0.20000D+01
E(PUHF)= -0.37688298213D+02 E(PMP2)= -0.37765363060D+02
Leave Link 804 at Mon Apr 1 18:12:24 2019, MaxMem= 33554432 cpu: 3.9
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l913.exe)
CIDS: MDV= 33554432.
Frozen-core window: NFC= 1 NFV= 0.
IFCWin=0 IBDFC=1 NFBD= 0 0 NFCmp= 0 0 NFFFC= 0 0
Using original routines for 1st iteration, S=T.
Using DD4UQ or CC4UQ for 2nd and later iterations.
Keep R2 and R3 ints in memory in symmetry-blocked form, NReq=5706150.
FoFCou: FMM=F IPFlag= 0 FMFlag= 0 FMFlg1= 0
NFxFlg= 0 DoJE=F BraDBF=F KetDBF=F FulRan=T
wScrn= 0.000000 ICntrl= 600 IOpCl= 0 I1Cent= 0 NGrid= 0
NMat0= 1 NMatS0= 1540 NMatT0= 0 NMatD0= 1 NMtDS0= 0 NMtDT0= 0
Petite list used in FoFCou.
CCSD(T)
=======
Iterations= 50 Convergence= 0.100D-06
Iteration Nr. 1
**********************
DD1Dir will call FoFMem 1 times, MxPair= 10
NAB= 3 NAA= 3 NBB= 0.
DD1Dir will call FoFMem 1 times, MxPair= 10
NAB= 3 NAA= 3 NBB= 0.
MP4(R+Q)= 0.15998655D-01
Maximum subspace dimension= 5
Norm of the A-vectors is 1.1454286D-02 conv= 1.00D-05.
RLE energy= -0.0752884037
E3= -0.14215771D-01 EROMP3= -0.37779578831D+02
E4(SDQ)= -0.30556302D-02 ROMP4(SDQ)= -0.37782634461D+02
VARIATIONAL ENERGIES WITH THE FIRST-ORDER WAVEFUNCTION:
DE(Corr)= -0.75244057E-01 E(Corr)= -37.763542271
NORM(A)= 0.10134099D+01
Iteration Nr. 2
**********************
DD1Dir will call FoFMem 1 times, MxPair= 10
NAB= 3 NAA= 3 NBB= 0.
Norm of the A-vectors is 9.6938894D-02 conv= 1.00D-05.
RLE energy= -0.0766006633
DE(Corr)= -0.89067092E-01 E(CORR)= -37.777365305 Delta=-1.38D-02
NORM(A)= 0.10140402D+01
Iteration Nr. 3
**********************
DD1Dir will call FoFMem 1 times, MxPair= 10
NAB= 3 NAA= 3 NBB= 0.
Norm of the A-vectors is 9.0951752D-02 conv= 1.00D-05.
RLE energy= -0.0896220438
DE(Corr)= -0.89446390E-01 E(CORR)= -37.777744603 Delta=-3.79D-04
NORM(A)= 0.10220954D+01
Iteration Nr. 4
**********************
DD1Dir will call FoFMem 1 times, MxPair= 10
NAB= 3 NAA= 3 NBB= 0.
Norm of the A-vectors is 2.9840225D-02 conv= 1.00D-05.
RLE energy= -0.0971526833
DE(Corr)= -0.93590361E-01 E(CORR)= -37.781888574 Delta=-4.14D-03
NORM(A)= 0.10285195D+01
Iteration Nr. 5
**********************
DD1Dir will call FoFMem 1 times, MxPair= 10
NAB= 3 NAA= 3 NBB= 0.
Norm of the A-vectors is 7.5443225D-03 conv= 1.00D-05.
RLE energy= -0.0986143714
DE(Corr)= -0.96149062E-01 E(CORR)= -37.784447275 Delta=-2.56D-03
NORM(A)= 0.10298596D+01
Iteration Nr. 6
**********************
DD1Dir will call FoFMem 1 times, MxPair= 10
NAB= 3 NAA= 3 NBB= 0.
Norm of the A-vectors is 1.4147298D-02 conv= 1.00D-05.
RLE energy= -0.0956549880
DE(Corr)= -0.96618124E-01 E(CORR)= -37.784916337 Delta=-4.69D-04
NORM(A)= 0.10272516D+01
Iteration Nr. 7
**********************
DD1Dir will call FoFMem 1 times, MxPair= 10
NAB= 3 NAA= 3 NBB= 0.
Norm of the A-vectors is 2.5104753D-04 conv= 1.00D-05.
RLE energy= -0.0957202520
DE(Corr)= -0.95686217E-01 E(CORR)= -37.783984431 Delta= 9.32D-04
NORM(A)= 0.10273175D+01
Iteration Nr. 8
**********************
DD1Dir will call FoFMem 1 times, MxPair= 10
NAB= 3 NAA= 3 NBB= 0.
Norm of the A-vectors is 8.6841017D-05 conv= 1.00D-05.
RLE energy= -0.0957031287
DE(Corr)= -0.95709732E-01 E(CORR)= -37.784007945 Delta=-2.35D-05
NORM(A)= 0.10273012D+01
Iteration Nr. 9
**********************
DD1Dir will call FoFMem 1 times, MxPair= 10
NAB= 3 NAA= 3 NBB= 0.
Norm of the A-vectors is 7.9466036D-06 conv= 1.00D-05.
RLE energy= -0.0957040538
DE(Corr)= -0.95703772E-01 E(CORR)= -37.784001985 Delta= 5.96D-06
NORM(A)= 0.10273020D+01
Iteration Nr. 10
**********************
DD1Dir will call FoFMem 1 times, MxPair= 10
NAB= 3 NAA= 3 NBB= 0.
Norm of the A-vectors is 1.8229338D-06 conv= 1.00D-05.
RLE energy= -0.0957040158
DE(Corr)= -0.95704030E-01 E(CORR)= -37.784002244 Delta=-2.59D-07
NORM(A)= 0.10273020D+01
Iteration Nr. 11
**********************
DD1Dir will call FoFMem 1 times, MxPair= 10
NAB= 3 NAA= 3 NBB= 0.
Norm of the A-vectors is 4.5079228D-07 conv= 1.00D-05.
RLE energy= -0.0957040398
DE(Corr)= -0.95704027E-01 E(CORR)= -37.784002241 Delta= 2.99D-09
NORM(A)= 0.10273020D+01
CI/CC converged in 11 iterations to DelEn= 2.99D-09 Conv= 1.00D-07 ErrA1= 4.51D-07 Conv= 1.00D-05
Dominant configurations:
***********************
Spin Case I J A B Value
ABAB 2 2 5 3 -0.103542D+00
Largest amplitude= 1.04D-01
Time for triples= 4.92 seconds.
T4(CCSD)= -0.24288527D-02
T5(CCSD)= -0.16611508D-04
CCSD(T)= -0.37786447705D+02
Discarding MO integrals.
Leave Link 913 at Mon Apr 1 18:12:47 2019, MaxMem= 33554432 cpu: 8.1
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l601.exe)
Copying SCF densities to generalized density rwf, IOpCl= 0 IROHF=1.
**********************************************************************
Population analysis using the SCF density.
**********************************************************************
Orbital symmetries:
Occupied (A1G) (A1G) (?A) (?A)
Virtual (?A) (T2G) (?A) (?A) (?A) (T2G) (T2G) (T2G) (T2G)
(T2G) (?A) (?A) (?A) (?A) (?A) (?A) (A2U) (?A)
(?A) (?A) (?B) (?B) (?C) (?C) (?C) (?B) (?B) (?C)
(?C) (?C) (?B) (?C) (?C) (?C) (?B) (?D) (?D) (?D)
(?D) (?D) (?D) (?D) (A2U) (?D) (?D) (EG) (T2G)
(T2G) (EG) (T2G) (A1G)
Unable to determine electronic state: an orbital has unidentified symmetry.
Alpha occ. eigenvalues -- -11.34711 -0.82046 -0.43321 -0.43321
Alpha virt. eigenvalues -- 0.02347 0.31393 0.32067 0.32067 0.37356
Alpha virt. eigenvalues -- 0.60603 0.60603 0.61467 0.61467 0.61791
Alpha virt. eigenvalues -- 1.48574 1.48574 1.52127 1.88309 1.88506
Alpha virt. eigenvalues -- 1.88506 1.89113 1.89113 1.90150 1.90150
Alpha virt. eigenvalues -- 1.91739 2.05797 2.05797 2.06629 2.06629
Alpha virt. eigenvalues -- 2.06973 5.07412 5.07673 5.07673 5.08459
Alpha virt. eigenvalues -- 5.08459 5.09771 5.09771 5.11616 5.11616
Alpha virt. eigenvalues -- 5.72090 5.72090 5.72265 6.20743 6.21096
Alpha virt. eigenvalues -- 6.21096 6.22165 6.22165 6.23977 6.23977
Alpha virt. eigenvalues -- 6.25623 6.25956 6.25956 6.26981 6.26981
Alpha virt. eigenvalues -- 20.16556
Molecular Orbital Coefficients:
1 2 3 4 5
(A1G)--O (A1G)--O O O V
Eigenvalues -- -11.34711 -0.82046 -0.43321 -0.43321 0.02347
1 1 C 1S 0.62700 -0.13278 0.00000 0.00000 0.00000
2 2S -0.40831 0.22163 0.00000 0.00000 0.00000
3 3S 0.01569 0.27384 0.00000 0.00000 0.00000
4 4S -0.00353 0.58655 0.00000 0.00000 0.00000
5 5S 0.00076 0.28535 0.00000 0.00000 0.00000
6 6PX 0.00000 0.00000 0.00000 0.00000 0.11030
7 6PY 0.00000 0.00000 0.00000 0.16971 0.00000
8 6PZ 0.00000 0.00000 0.16971 0.00000 0.00000
9 7PX 0.00000 0.00000 0.00000 0.00000 0.24625
10 7PY 0.00000 0.00000 0.00000 0.34212 0.00000
11 7PZ 0.00000 0.00000 0.34212 0.00000 0.00000
12 8PX 0.00000 0.00000 0.00000 0.00000 0.25264
13 8PY 0.00000 0.00000 0.00000 0.46386 0.00000
14 8PZ 0.00000 0.00000 0.46386 0.00000 0.00000
15 9PX 0.00000 0.00000 0.00000 0.00000 0.62358
16 9PY 0.00000 0.00000 0.00000 0.25007 0.00000
17 9PZ 0.00000 0.00000 0.25007 0.00000 0.00000
18 10D 0 -0.00006 0.00060 0.00000 0.00000 0.00000
19 10D+1 0.00000 0.00000 0.00000 0.00000 0.00000
20 10D-1 0.00000 0.00000 0.00000 0.00000 0.00000
21 10D+2 0.00010 -0.00105 0.00000 0.00000 0.00000
22 10D-2 0.00000 0.00000 0.00000 0.00000 0.00000
23 11D 0 0.00027 -0.00033 0.00000 0.00000 0.00000
24 11D+1 0.00000 0.00000 0.00000 0.00000 0.00000
25 11D-1 0.00000 0.00000 0.00000 0.00000 0.00000
26 11D+2 -0.00046 0.00058 0.00000 0.00000 0.00000
27 11D-2 0.00000 0.00000 0.00000 0.00000 0.00000
28 12D 0 -0.00001 0.00258 0.00000 0.00000 0.00000
29 12D+1 0.00000 0.00000 0.00000 0.00000 0.00000
30 12D-1 0.00000 0.00000 0.00000 0.00000 0.00000
31 12D+2 0.00002 -0.00447 0.00000 0.00000 0.00000
32 12D-2 0.00000 0.00000 0.00000 0.00000 0.00000
33 13F 0 0.00000 0.00000 -0.00001 0.00000 0.00000
34 13F+1 0.00000 0.00000 0.00000 0.00000 -0.00031
35 13F-1 0.00000 0.00000 0.00000 -0.00001 0.00000
36 13F+2 0.00000 0.00000 0.00002 0.00000 0.00000
37 13F-2 0.00000 0.00000 0.00000 0.00000 0.00000
38 13F+3 0.00000 0.00000 0.00000 0.00000 0.00040
39 13F-3 0.00000 0.00000 0.00000 0.00002 0.00000
40 14F 0 0.00000 0.00000 -0.00002 0.00000 0.00000
41 14F+1 0.00000 0.00000 0.00000 0.00000 -0.00292
42 14F-1 0.00000 0.00000 0.00000 -0.00001 0.00000
43 14F+2 0.00000 0.00000 0.00002 0.00000 0.00000
44 14F-2 0.00000 0.00000 0.00000 0.00000 0.00000
45 14F+3 0.00000 0.00000 0.00000 0.00000 0.00377
46 14F-3 0.00000 0.00000 0.00000 0.00003 0.00000
47 15G 0 0.00000 -0.00001 0.00000 0.00000 0.00000
48 15G+1 0.00000 0.00000 0.00000 0.00000 0.00000
49 15G-1 0.00000 0.00000 0.00000 0.00000 0.00000
50 15G+2 0.00000 0.00001 0.00000 0.00000 0.00000
51 15G-2 0.00000 0.00000 0.00000 0.00000 0.00000
52 15G+3 0.00000 0.00000 0.00000 0.00000 0.00000
53 15G-3 0.00000 0.00000 0.00000 0.00000 0.00000
54 15G+4 0.00000 -0.00001 0.00000 0.00000 0.00000
55 15G-4 0.00000 0.00000 0.00000 0.00000 0.00000
6 7 8 9 10
(T2G)--V V V V (T2G)--V
Eigenvalues -- 0.31393 0.32067 0.32067 0.37356 0.60603
1 1 C 1S -0.08382 0.00000 0.00000 0.00000 -0.00227
2 2S 0.08899 0.00000 0.00000 0.00000 0.00049
3 3S -0.22483 0.00000 0.00000 0.00000 -0.01743
4 4S 2.03117 0.00000 0.00000 0.00000 0.06968
5 5S -2.01403 0.00000 0.00000 0.00000 -0.05544
6 6PX 0.00000 0.00000 0.00000 -0.15570 0.00000
7 6PY 0.00000 -0.12159 0.00000 0.00000 0.00000
8 6PZ 0.00000 0.00000 -0.12159 0.00000 0.00000
9 7PX 0.00000 0.00000 0.00000 -0.11648 0.00000
10 7PY 0.00000 -0.05948 0.00000 0.00000 0.00000
11 7PZ 0.00000 0.00000 -0.05948 0.00000 0.00000
12 8PX 0.00000 0.00000 0.00000 -1.07017 0.00000
13 8PY 0.00000 -0.90030 0.00000 0.00000 0.00000
14 8PZ 0.00000 0.00000 -0.90030 0.00000 0.00000
15 9PX 0.00000 0.00000 0.00000 1.25185 0.00000
16 9PY 0.00000 1.36709 0.00000 0.00000 0.00000
17 9PZ 0.00000 0.00000 1.36709 0.00000 0.00000
18 10D 0 0.00113 0.00000 0.00000 0.00000 -0.02772
19 10D+1 0.00000 0.00000 0.00000 0.00000 0.00000
20 10D-1 0.00000 0.00000 0.00000 0.00000 0.00000
21 10D+2 -0.00195 0.00000 0.00000 0.00000 0.04801
22 10D-2 0.00000 0.00000 0.00000 0.00000 0.00000
23 11D 0 -0.00486 0.00000 0.00000 0.00000 0.07360
24 11D+1 0.00000 0.00000 0.00000 0.00000 0.00000
25 11D-1 0.00000 0.00000 0.00000 0.00000 0.00000
26 11D+2 0.00842 0.00000 0.00000 0.00000 -0.12748
27 11D-2 0.00000 0.00000 0.00000 0.00000 0.00000
28 12D 0 0.01531 0.00000 0.00000 0.00000 -0.53909
29 12D+1 0.00000 0.00000 0.00000 0.00000 0.00000
30 12D-1 0.00000 0.00000 0.00000 0.00000 0.00000
31 12D+2 -0.02651 0.00000 0.00000 0.00000 0.93373
32 12D-2 0.00000 0.00000 0.00000 0.00000 0.00000
33 13F 0 0.00000 0.00000 0.00087 0.00000 0.00000
34 13F+1 0.00000 0.00000 0.00000 0.00116 0.00000
35 13F-1 0.00000 0.00036 0.00000 0.00000 0.00000
36 13F+2 0.00000 0.00000 -0.00112 0.00000 0.00000
37 13F-2 0.00000 0.00000 0.00000 0.00000 0.00000
38 13F+3 0.00000 0.00000 0.00000 -0.00150 0.00000
39 13F-3 0.00000 -0.00138 0.00000 0.00000 0.00000
40 14F 0 0.00000 0.00000 -0.00023 0.00000 0.00000
41 14F+1 0.00000 0.00000 0.00000 0.00103 0.00000
42 14F-1 0.00000 -0.00009 0.00000 0.00000 0.00000
43 14F+2 0.00000 0.00000 0.00029 0.00000 0.00000
44 14F-2 0.00000 0.00000 0.00000 0.00000 0.00000
45 14F+3 0.00000 0.00000 0.00000 -0.00133 0.00000
46 14F-3 0.00000 0.00036 0.00000 0.00000 0.00000
47 15G 0 -0.00002 0.00000 0.00000 0.00000 0.00099
48 15G+1 0.00000 0.00000 0.00000 0.00000 0.00000
49 15G-1 0.00000 0.00000 0.00000 0.00000 0.00000
50 15G+2 0.00002 0.00000 0.00000 0.00000 -0.00148
51 15G-2 0.00000 0.00000 0.00000 0.00000 0.00000
52 15G+3 0.00000 0.00000 0.00000 0.00000 0.00000
53 15G-3 0.00000 0.00000 0.00000 0.00000 0.00000
54 15G+4 -0.00003 0.00000 0.00000 0.00000 0.00195
55 15G-4 0.00000 0.00000 0.00000 0.00000 0.00000
11 12 13 14 15
(T2G)--V (T2G)--V (T2G)--V (T2G)--V V
Eigenvalues -- 0.60603 0.61467 0.61467 0.61791 1.48574
1 1 C 1S 0.00000 0.00000 0.00000 0.00000 0.00000
2 2S 0.00000 0.00000 0.00000 0.00000 0.00000
3 3S 0.00000 0.00000 0.00000 0.00000 0.00000
4 4S 0.00000 0.00000 0.00000 0.00000 0.00000
5 5S 0.00000 0.00000 0.00000 0.00000 0.00000
6 6PX 0.00000 0.00000 0.00000 0.00000 0.00000
7 6PY 0.00000 0.00000 0.00000 0.00000 0.00000
8 6PZ 0.00000 0.00000 0.00000 0.00000 -0.18228
9 7PX 0.00000 0.00000 0.00000 0.00000 0.00000
10 7PY 0.00000 0.00000 0.00000 0.00000 0.00000
11 7PZ 0.00000 0.00000 0.00000 0.00000 -1.30084
12 8PX 0.00000 0.00000 0.00000 0.00000 0.00000
13 8PY 0.00000 0.00000 0.00000 0.00000 0.00000
14 8PZ 0.00000 0.00000 0.00000 0.00000 1.89111
15 9PX 0.00000 0.00000 0.00000 0.00000 0.00000
16 9PY 0.00000 0.00000 0.00000 0.00000 0.00000
17 9PZ 0.00000 0.00000 0.00000 0.00000 -0.77731
18 10D 0 0.00000 0.00000 0.00000 0.04931 0.00000
19 10D+1 0.05587 0.00000 0.00000 0.00000 0.00000
20 10D-1 0.00000 0.00000 0.05694 0.00000 0.00000
21 10D+2 0.00000 0.00000 0.00000 0.02847 0.00000
22 10D-2 0.00000 0.05587 0.00000 0.00000 0.00000
23 11D 0 0.00000 0.00000 0.00000 -0.11945 0.00000
24 11D+1 -0.14502 0.00000 0.00000 0.00000 0.00000
25 11D-1 0.00000 0.00000 -0.13793 0.00000 0.00000
26 11D+2 0.00000 0.00000 0.00000 -0.06897 0.00000
27 11D-2 0.00000 -0.14502 0.00000 0.00000 0.00000
28 12D 0 0.00000 0.00000 0.00000 0.92918 0.00000
29 12D+1 1.07720 0.00000 0.00000 0.00000 0.00000
30 12D-1 0.00000 0.00000 1.07293 0.00000 0.00000
31 12D+2 0.00000 0.00000 0.00000 0.53646 0.00000
32 12D-2 0.00000 1.07720 0.00000 0.00000 0.00000
33 13F 0 0.00000 0.00000 0.00000 0.00000 0.00392
34 13F+1 0.00000 0.00000 0.00000 0.00000 0.00000
35 13F-1 0.00000 0.00000 0.00000 0.00000 0.00000
36 13F+2 0.00000 0.00000 0.00000 0.00000 -0.00507
37 13F-2 0.00000 0.00000 0.00000 0.00000 0.00000
38 13F+3 0.00000 0.00000 0.00000 0.00000 0.00000
39 13F-3 0.00000 0.00000 0.00000 0.00000 0.00000
40 14F 0 0.00000 0.00000 0.00000 0.00000 -0.01805
41 14F+1 0.00000 0.00000 0.00000 0.00000 0.00000
42 14F-1 0.00000 0.00000 0.00000 0.00000 0.00000
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51 15G-2 0.00000 -0.00086 0.00000 0.00000 0.00000
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V V V V V
Eigenvalues -- 1.48574 1.52127 1.88309 1.88506 1.88506
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13 8PY 1.89111 0.00000 0.00000 -0.05047 0.00000
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43 14F+2 0.00000 0.00000 0.00000 0.00000 0.83592
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(A2U)--V V V V V
Eigenvalues -- 1.89113 1.89113 1.90150 1.90150 1.91739
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4 4S 0.00000 0.00000 0.00000 0.00000 3.57195
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36 13F+2 0.00000 0.00000 0.00000 -0.07109 0.00000
37 13F-2 -0.11622 0.00000 0.00000 0.00000 0.00000
38 13F+3 0.00000 -0.07117 0.00000 0.00000 0.00000
39 13F-3 0.00000 0.00000 -0.02902 0.00000 0.00000
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42 14F-1 0.00000 0.00000 1.02411 0.00000 0.00000
43 14F+2 0.00000 0.00000 0.00000 0.64770 0.00000
44 14F-2 1.05775 0.00000 0.00000 0.00000 0.00000
45 14F+3 0.00000 0.64774 0.00000 0.00000 0.00000
46 14F-3 0.00000 0.00000 0.26442 0.00000 0.00000
47 15G 0 0.00000 0.00000 0.00000 0.00000 0.00012
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51 15G-2 0.00000 0.00000 0.00000 0.00000 0.00000
52 15G+3 0.00000 0.00000 0.00000 0.00000 0.00000
53 15G-3 0.00000 0.00000 0.00000 0.00000 0.00000
54 15G+4 0.00000 0.00000 0.00000 0.00000 0.00024
55 15G-4 0.00000 0.00000 0.00000 0.00000 0.00000
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V V V V V
Eigenvalues -- 2.05797 2.05797 2.06629 2.06629 2.06973
1 1 C 1S -0.00435 0.00000 0.00000 0.00000 0.00000
2 2S 0.02405 0.00000 0.00000 0.00000 0.00000
3 3S 0.12510 0.00000 0.00000 0.00000 0.00000
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5 5S 0.06368 0.00000 0.00000 0.00000 0.00000
6 6PX 0.00000 0.00000 0.00000 0.00000 0.00000
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13 8PY 0.00000 0.00000 0.00000 0.00000 0.00000
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21 10D+2 -0.06417 0.00000 0.00000 0.00000 -0.03541
22 10D-2 0.00000 0.00000 -0.07351 0.00000 0.00000
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24 11D+1 0.00000 1.34742 0.00000 0.00000 0.00000
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26 11D+2 1.16618 0.00000 0.00000 0.00000 0.67295
27 11D-2 0.00000 0.00000 1.34742 0.00000 0.00000
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31 12D+2 -0.65578 0.00000 0.00000 0.00000 -0.38292
32 12D-2 0.00000 0.00000 -0.76006 0.00000 0.00000
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35 13F-1 0.00000 0.00000 0.00000 0.00000 0.00000
36 13F+2 0.00000 0.00000 0.00000 0.00000 0.00000
37 13F-2 0.00000 0.00000 0.00000 0.00000 0.00000
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39 13F-3 0.00000 0.00000 0.00000 0.00000 0.00000
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50 15G+2 -0.00476 0.00000 0.00000 0.00000 0.00274
51 15G-2 0.00000 0.00000 -0.00275 0.00000 0.00000
52 15G+3 0.00000 0.00514 0.00000 0.00000 0.00000
53 15G-3 0.00000 0.00000 0.00000 0.00512 0.00000
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55 15G-4 0.00000 0.00000 0.00727 0.00000 0.00000
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V V V V V
Eigenvalues -- 5.07412 5.07673 5.07673 5.08459 5.08459
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2 2S -0.00001 0.00000 0.00000 0.00000 0.00000
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4 4S 0.00003 0.00000 0.00000 0.00000 0.00000
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6 6PX 0.00000 0.00000 0.00000 0.00000 0.00000
7 6PY 0.00000 0.00000 0.00000 0.00000 0.00000
8 6PZ 0.00000 0.00000 0.00000 0.00000 0.00000
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11 7PZ 0.00000 0.00000 0.00000 0.00000 0.00000
12 8PX 0.00000 0.00000 0.00000 0.00000 0.00000
13 8PY 0.00000 0.00000 0.00000 0.00000 0.00000
14 8PZ 0.00000 0.00000 0.00000 0.00000 0.00000
15 9PX 0.00000 0.00000 0.00000 0.00000 0.00000
16 9PY 0.00000 0.00000 0.00000 0.00000 0.00000
17 9PZ 0.00000 0.00000 0.00000 0.00000 0.00000
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20 10D-1 0.00000 0.00000 0.00000 -0.00245 0.00000
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22 10D-2 0.00000 -0.00341 0.00000 0.00000 0.00000
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26 11D+2 -0.00672 0.00000 0.00000 0.00000 -0.00247
27 11D-2 0.00000 -0.00706 0.00000 0.00000 0.00000
28 12D 0 -0.00121 0.00000 0.00000 0.00000 0.00135
29 12D+1 0.00000 0.00000 -0.00221 0.00000 0.00000
30 12D-1 0.00000 0.00000 0.00000 0.00156 0.00000
31 12D+2 0.00210 0.00000 0.00000 0.00000 0.00078
32 12D-2 0.00000 0.00221 0.00000 0.00000 0.00000
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35 13F-1 0.00000 0.00000 0.00000 0.00000 0.00000
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37 13F-2 0.00000 0.00000 0.00000 0.00000 0.00000
38 13F+3 0.00000 0.00000 0.00000 0.00000 0.00000
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45 14F+3 0.00000 0.00000 0.00000 0.00000 0.00000
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50 15G+2 -0.55899 0.00000 0.00000 0.00000 0.49999
51 15G-2 0.00000 -0.35354 0.00000 0.00000 0.00000
52 15G+3 0.00000 0.00000 -0.66141 0.00000 0.00000
53 15G-3 0.00000 0.00000 0.00000 0.93540 0.00000
54 15G+4 0.73948 0.00000 0.00000 0.00000 0.66143
55 15G-4 0.00000 0.93538 0.00000 0.00000 0.00000
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V V V V V
Eigenvalues -- 5.09771 5.09771 5.11616 5.11616 5.72090
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6 6PX 0.00000 0.00000 0.00000 0.00000 -1.43703
7 6PY 0.00000 0.00000 0.00000 0.00000 0.00000
8 6PZ 0.00000 0.00000 0.00000 0.00000 0.00000
9 7PX 0.00000 0.00000 0.00000 0.00000 1.78516
10 7PY 0.00000 0.00000 0.00000 0.00000 0.00000
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13 8PY 0.00000 0.00000 0.00000 0.00000 0.00000
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16 9PY 0.00000 0.00000 0.00000 0.00000 0.00000
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51 15G-2 0.93541 0.00000 0.00000 0.00000 0.00000
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V V V V V
Eigenvalues -- 5.72090 5.72265 6.20743 6.21096 6.21096
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13 8PY -1.09915 0.00000 0.00000 0.02964 0.00000
14 8PZ 0.00000 -1.09915 0.00000 0.00000 0.02964
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V (A2U)--V V V (EG)--V
Eigenvalues -- 6.22165 6.22165 6.23977 6.23977 6.25623
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(T2G)--V (T2G)--V (EG)--V (T2G)--V (A1G)--V
Eigenvalues -- 6.25956 6.25956 6.26981 6.26981 20.16556
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Alpha Density Matrix:
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51 52 53 54 55
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53 15G-3 0.00000 0.00000 0.00000
54 15G+4 0.00000 0.00000 0.00000 0.00000
55 15G-4 0.00000 0.00000 0.00000 0.00000 0.00000
Full Mulliken population analysis:
1 2 3 4 5
1 1 C 1S 0.82152
2 2S 0.47593 0.43167
3 3S -0.01780 -0.06948 0.15047
4 4S -0.02879 -0.09993 0.27467 0.68811
5 5S -0.00674 -0.02519 0.08674 0.28327 0.16285
6 6PX 0.00000 0.00000 0.00000 0.00000 0.00000
7 6PY 0.00000 0.00000 0.00000 0.00000 0.00000
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10 7PY 0.00000 0.00000 0.00000 0.00000 0.00000
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13 8PY 0.00000 0.00000 0.00000 0.00000 0.00000
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6 7 8 9 10
6 6PX 0.00000
7 6PY 0.00000 0.02880
8 6PZ 0.00000 0.00000 0.02880
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10 7PY 0.00000 0.03793 0.00000 0.00000 0.11705
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13 8PY 0.00000 0.02164 0.00000 0.00000 0.11518
14 8PZ 0.00000 0.00000 0.02164 0.00000 0.00000
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11 7PZ 0.11705
12 8PX 0.00000 0.00000
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55 15G-4 0.00000 0.00000 0.00000 0.00000 0.00000
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16 9PY 0.06254
17 9PZ 0.00000 0.06254
18 10D 0 0.00000 0.00000 0.00000
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53 15G-3 0.00000 0.00000 0.00000 0.00000 0.00000
54 15G+4 0.00000 0.00000 0.00000 0.00000 0.00000
55 15G-4 0.00000 0.00000 0.00000 0.00000 0.00000
21 22 23 24 25
21 10D+2 0.00000
22 10D-2 0.00000 0.00000
23 11D 0 0.00000 0.00000 0.00000
24 11D+1 0.00000 0.00000 0.00000 0.00000
25 11D-1 0.00000 0.00000 0.00000 0.00000 0.00000
26 11D+2 0.00000 0.00000 0.00000 0.00000 0.00000
27 11D-2 0.00000 0.00000 0.00000 0.00000 0.00000
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54 15G+4 0.00000 0.00000 0.00000 0.00000 0.00000
55 15G-4 0.00000 0.00000 0.00000 0.00000 0.00000
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26 11D+2 0.00000
27 11D-2 0.00000 0.00000
28 12D 0 0.00000 0.00000 0.00001
29 12D+1 0.00000 0.00000 0.00000 0.00000
30 12D-1 0.00000 0.00000 0.00000 0.00000 0.00000
31 12D+2 0.00000 0.00000 0.00000 0.00000 0.00000
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33 13F 0 0.00000 0.00000 0.00000 0.00000 0.00000
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36 13F+2 0.00000 0.00000 0.00000 0.00000 0.00000
37 13F-2 0.00000 0.00000 0.00000 0.00000 0.00000
38 13F+3 0.00000 0.00000 0.00000 0.00000 0.00000
39 13F-3 0.00000 0.00000 0.00000 0.00000 0.00000
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41 14F+1 0.00000 0.00000 0.00000 0.00000 0.00000
42 14F-1 0.00000 0.00000 0.00000 0.00000 0.00000
43 14F+2 0.00000 0.00000 0.00000 0.00000 0.00000
44 14F-2 0.00000 0.00000 0.00000 0.00000 0.00000
45 14F+3 0.00000 0.00000 0.00000 0.00000 0.00000
46 14F-3 0.00000 0.00000 0.00000 0.00000 0.00000
47 15G 0 0.00000 0.00000 0.00000 0.00000 0.00000
48 15G+1 0.00000 0.00000 0.00000 0.00000 0.00000
49 15G-1 0.00000 0.00000 0.00000 0.00000 0.00000
50 15G+2 0.00000 0.00000 0.00000 0.00000 0.00000
51 15G-2 0.00000 0.00000 0.00000 0.00000 0.00000
52 15G+3 0.00000 0.00000 0.00000 0.00000 0.00000
53 15G-3 0.00000 0.00000 0.00000 0.00000 0.00000
54 15G+4 0.00000 0.00000 0.00000 0.00000 0.00000
55 15G-4 0.00000 0.00000 0.00000 0.00000 0.00000
31 32 33 34 35
31 12D+2 0.00004
32 12D-2 0.00000 0.00000
33 13F 0 0.00000 0.00000 0.00000
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38 13F+3 0.00000 0.00000 0.00000 0.00000 0.00000
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40 14F 0 0.00000 0.00000 0.00000 0.00000 0.00000
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55 15G-4 0.00000 0.00000 0.00000 0.00000 0.00000
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36 13F+2 0.00000
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46 14F-3 0.00000 0.00000 0.00000 0.00000 0.00000
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51 15G-2 0.00000 0.00000 0.00000 0.00000 0.00000
52 15G+3 0.00000 0.00000 0.00000 0.00000 0.00000
53 15G-3 0.00000 0.00000 0.00000 0.00000 0.00000
54 15G+4 0.00000 0.00000 0.00000 0.00000 0.00000
55 15G-4 0.00000 0.00000 0.00000 0.00000 0.00000
41 42 43 44 45
41 14F+1 0.00000
42 14F-1 0.00000 0.00000
43 14F+2 0.00000 0.00000 0.00000
44 14F-2 0.00000 0.00000 0.00000 0.00000
45 14F+3 0.00000 0.00000 0.00000 0.00000 0.00000
46 14F-3 0.00000 0.00000 0.00000 0.00000 0.00000
47 15G 0 0.00000 0.00000 0.00000 0.00000 0.00000
48 15G+1 0.00000 0.00000 0.00000 0.00000 0.00000
49 15G-1 0.00000 0.00000 0.00000 0.00000 0.00000
50 15G+2 0.00000 0.00000 0.00000 0.00000 0.00000
51 15G-2 0.00000 0.00000 0.00000 0.00000 0.00000
52 15G+3 0.00000 0.00000 0.00000 0.00000 0.00000
53 15G-3 0.00000 0.00000 0.00000 0.00000 0.00000
54 15G+4 0.00000 0.00000 0.00000 0.00000 0.00000
55 15G-4 0.00000 0.00000 0.00000 0.00000 0.00000
46 47 48 49 50
46 14F-3 0.00000
47 15G 0 0.00000 0.00000
48 15G+1 0.00000 0.00000 0.00000
49 15G-1 0.00000 0.00000 0.00000 0.00000
50 15G+2 0.00000 0.00000 0.00000 0.00000 0.00000
51 15G-2 0.00000 0.00000 0.00000 0.00000 0.00000
52 15G+3 0.00000 0.00000 0.00000 0.00000 0.00000
53 15G-3 0.00000 0.00000 0.00000 0.00000 0.00000
54 15G+4 0.00000 0.00000 0.00000 0.00000 0.00000
55 15G-4 0.00000 0.00000 0.00000 0.00000 0.00000
51 52 53 54 55
51 15G-2 0.00000
52 15G+3 0.00000 0.00000
53 15G-3 0.00000 0.00000 0.00000
54 15G+4 0.00000 0.00000 0.00000 0.00000
55 15G-4 0.00000 0.00000 0.00000 0.00000 0.00000
Gross orbital populations:
Total Alpha Beta Spin
1 1 C 1S 1.24411 0.62206 0.62206 0.00000
2 2S 0.71299 0.35650 0.35650 0.00000
3 3S 0.42460 0.21230 0.21230 0.00000
4 4S 1.11732 0.55866 0.55866 0.00000
5 5S 0.50093 0.25046 0.25046 0.00000
6 6PX 0.00000 0.00000 0.00000 0.00000
7 6PY 0.09210 0.09210 0.00000 0.09210
8 6PZ 0.09210 0.09210 0.00000 0.09210
9 7PX 0.00000 0.00000 0.00000 0.00000
10 7PY 0.29671 0.29671 0.00000 0.29671
11 7PZ 0.29671 0.29671 0.00000 0.29671
12 8PX 0.00000 0.00000 0.00000 0.00000
13 8PY 0.43518 0.43518 0.00000 0.43518
14 8PZ 0.43518 0.43518 0.00000 0.43518
15 9PX 0.00000 0.00000 0.00000 0.00000
16 9PY 0.17601 0.17601 0.00000 0.17601
17 9PZ 0.17601 0.17601 0.00000 0.17601
18 10D 0 0.00000 0.00000 0.00000 0.00000
19 10D+1 0.00000 0.00000 0.00000 0.00000
20 10D-1 0.00000 0.00000 0.00000 0.00000
21 10D+2 0.00000 0.00000 0.00000 0.00000
22 10D-2 0.00000 0.00000 0.00000 0.00000
23 11D 0 0.00000 0.00000 0.00000 0.00000
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25 11D-1 0.00000 0.00000 0.00000 0.00000
26 11D+2 0.00000 0.00000 0.00000 0.00000
27 11D-2 0.00000 0.00000 0.00000 0.00000
28 12D 0 0.00001 0.00001 0.00001 0.00000
29 12D+1 0.00000 0.00000 0.00000 0.00000
30 12D-1 0.00000 0.00000 0.00000 0.00000
31 12D+2 0.00004 0.00002 0.00002 0.00000
32 12D-2 0.00000 0.00000 0.00000 0.00000
33 13F 0 0.00000 0.00000 0.00000 0.00000
34 13F+1 0.00000 0.00000 0.00000 0.00000
35 13F-1 0.00000 0.00000 0.00000 0.00000
36 13F+2 0.00000 0.00000 0.00000 0.00000
37 13F-2 0.00000 0.00000 0.00000 0.00000
38 13F+3 0.00000 0.00000 0.00000 0.00000
39 13F-3 0.00000 0.00000 0.00000 0.00000
40 14F 0 0.00000 0.00000 0.00000 0.00000
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44 14F-2 0.00000 0.00000 0.00000 0.00000
45 14F+3 0.00000 0.00000 0.00000 0.00000
46 14F-3 0.00000 0.00000 0.00000 0.00000
47 15G 0 0.00000 0.00000 0.00000 0.00000
48 15G+1 0.00000 0.00000 0.00000 0.00000
49 15G-1 0.00000 0.00000 0.00000 0.00000
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51 15G-2 0.00000 0.00000 0.00000 0.00000
52 15G+3 0.00000 0.00000 0.00000 0.00000
53 15G-3 0.00000 0.00000 0.00000 0.00000
54 15G+4 0.00000 0.00000 0.00000 0.00000
55 15G-4 0.00000 0.00000 0.00000 0.00000
Condensed to atoms (all electrons):
1
1 C 6.000000
Atomic-Atomic Spin Densities.
1
1 C 2.000000
Mulliken charges and spin densities:
1 2
1 C 0.000000 2.000000
Sum of Mulliken charges = 0.00000 2.00000
Mulliken charges and spin densities with hydrogens summed into heavy atoms:
1 2
1 C 0.000000 2.000000
Electronic spatial extent (au): <R**2>= 13.7698
Charge= 0.0000 electrons
Dipole moment (field-independent basis, Debye):
X= 0.0000 Y= 0.0000 Z= 0.0000 Tot= 0.0000
Quadrupole moment (field-independent basis, Debye-Ang):
XX= -4.8006 YY= -6.8601 ZZ= -6.8601
XY= 0.0000 XZ= 0.0000 YZ= 0.0000
Traceless Quadrupole moment (field-independent basis, Debye-Ang):
XX= 1.3730 YY= -0.6865 ZZ= -0.6865
XY= 0.0000 XZ= 0.0000 YZ= 0.0000
Octapole moment (field-independent basis, Debye-Ang**2):
XXX= 0.0000 YYY= 0.0000 ZZZ= 0.0000 XYY= 0.0000
XXY= 0.0000 XXZ= 0.0000 XZZ= 0.0000 YZZ= 0.0000
YYZ= 0.0000 XYZ= 0.0000
Hexadecapole moment (field-independent basis, Debye-Ang**3):
XXXX= -4.6947 YYYY= -8.8538 ZZZZ= -8.8538 XXXY= 0.0000
XXXZ= 0.0000 YYYX= 0.0000 YYYZ= 0.0000 ZZZX= 0.0000
ZZZY= 0.0000 XXYY= -2.2581 XXZZ= -2.2581 YYZZ= -2.9513
XXYZ= 0.0000 YYXZ= 0.0000 ZZXY= 0.0000
N-N= 0.000000000000D+00 E-N=-8.813651291997D+01 KE= 3.768825252205D+01
Symmetry AG KE= 3.518137762150D+01
Symmetry B1G KE= 3.038420325985D-37
Symmetry B2G KE= 3.038420325985D-37
Symmetry B3G KE= 9.642959639086D-54
Symmetry AU KE= 7.728189777535D-41
Symmetry B1U KE= 1.253437450273D+00
Symmetry B2U KE= 1.253437450273D+00
Symmetry B3U KE= 4.699637926849D-33
Orbital energies and kinetic energies (alpha):
1 2
1 (A1G)--O -11.347111 16.058236
2 (A1G)--O -0.820456 1.532453
3 O -0.433207 1.253437
4 O -0.433207 1.253437
5 V 0.023466 0.718407
6 (T2G)--V 0.313926 0.834382
7 V 0.320672 0.669791
8 V 0.320672 0.669791
9 V 0.373560 1.043985
10 (T2G)--V 0.606031 0.758471
11 (T2G)--V 0.606031 0.759266
12 (T2G)--V 0.614667 0.759266
13 (T2G)--V 0.614667 0.761993
14 (T2G)--V 0.617908 0.761993
15 V 1.485737 2.839627
16 V 1.485737 2.839627
17 V 1.521268 2.969396
18 V 1.883090 2.098058
19 V 1.885061 2.098079
20 V 1.885061 2.098079
21 (A2U)--V 1.891130 2.097581
22 V 1.891130 2.097581
23 V 1.901503 2.097618
24 V 1.901503 2.097618
25 V 1.917388 4.621953
26 V 2.057973 2.703125
27 V 2.057973 2.700390
28 V 2.066290 2.700390
29 V 2.066290 2.700477
30 V 2.069732 2.700477
31 V 5.074121 5.560325
32 V 5.076735 5.560355
33 V 5.076735 5.560355
34 V 5.084589 5.560429
35 V 5.084589 5.560429
36 V 5.097714 5.560500
37 V 5.097714 5.560500
38 V 5.116160 5.560500
39 V 5.116160 5.560500
40 V 5.720902 10.775354
41 V 5.720902 10.744779
42 V 5.722650 10.744779
43 V 6.207425 7.313581
44 V 6.210959 7.313069
45 V 6.210959 7.313069
46 V 6.221650 7.311534
47 (A2U)--V 6.221650 7.311534
48 V 6.239775 7.311496
49 V 6.239775 7.311496
50 (EG)--V 6.256234 8.284559
51 (T2G)--V 6.259563 8.283683
52 (T2G)--V 6.259563 8.283683
53 (EG)--V 6.269813 8.280796
54 (T2G)--V 6.269813 8.280796
55 (A1G)--V 20.165559 50.172857
Total kinetic energy from orbitals= 4.019512742259D+01
Isotropic Fermi Contact Couplings
Atom a.u. MegaHertz Gauss 10(-4) cm-1
1 C(13) 0.00000 0.00000 0.00000 0.00000
--------------------------------------------------------
Center ---- Spin Dipole Couplings ----
3XX-RR 3YY-RR 3ZZ-RR
--------------------------------------------------------
1 Atom -1.341794 0.670897 0.670897
--------------------------------------------------------
XY XZ YZ
--------------------------------------------------------
1 Atom 0.000000 0.000000 0.000000
--------------------------------------------------------
---------------------------------------------------------------------------------
Anisotropic Spin Dipole Couplings in Principal Axis System
---------------------------------------------------------------------------------
Atom a.u. MegaHertz Gauss 10(-4) cm-1 Axes
Baa -1.3418 -180.056 -64.248 -60.060 1.0000 0.0000 0.0000
1 C(13) Bbb 0.6709 90.028 32.124 30.030 0.0000 1.0000 0.0000
Bcc 0.6709 90.028 32.124 30.030 0.0000 0.0000 1.0000
---------------------------------------------------------------------------------
No NMR shielding tensors so no spin-rotation constants.
Leave Link 601 at Mon Apr 1 18:12:48 2019, MaxMem= 33554432 cpu: 0.5
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l9999.exe)
1\1\GINC-COMPUTE-40-0\SP\ROCCSD(T)-FC\CC-pVQZ\C1(3)\LOOS\01-Apr-2019\0
\\#p ROCCSD(T) cc-pVQZ pop=full gfprint\\G2\\0,3\C\\Version=ES64L-G09R
evD.01\HF=-37.6882982\MP2=-37.7653631\MP3=-37.7795788\PUHF=-37.6882982
\PMP2-0=-37.7653631\MP4SDQ=-37.7826345\CCSD=-37.7840022\CCSD(T)=-37.78
64477\RMSD=3.287e-09\PG=OH [O(C1)]\\@
THE ONLY TROUBLE WITH A SURE THING IS THE UNCERTAINTY.
-- FROM A TEABAG (BELONGING TO W.H.?)
Job cpu time: 0 days 0 hours 0 minutes 16.8 seconds.
File lengths (MBytes): RWF= 56 Int= 0 D2E= 0 Chk= 1 Scr= 1
Normal termination of Gaussian 09 at Mon Apr 1 18:12:48 2019.