srDFT_G2/G09/C2/C2_vtz.out
2019-04-01 22:35:49 +02:00

2855 lines
180 KiB
Plaintext

Entering Gaussian System, Link 0=g09
Input=C2_vtz.inp
Output=C2_vtz.out
Initial command:
/share/apps/gaussian/g09d01/nehalem/g09/l1.exe "/mnt/beegfs/tmpdir/42372/Gau-42446.inp" -scrdir="/mnt/beegfs/tmpdir/42372/"
Entering Link 1 = /share/apps/gaussian/g09d01/nehalem/g09/l1.exe PID= 42447.
Copyright (c) 1988,1990,1992,1993,1995,1998,2003,2009,2013,
Gaussian, Inc. All Rights Reserved.
This is part of the Gaussian(R) 09 program. It is based on
the Gaussian(R) 03 system (copyright 2003, Gaussian, Inc.),
the Gaussian(R) 98 system (copyright 1998, Gaussian, Inc.),
the Gaussian(R) 94 system (copyright 1995, Gaussian, Inc.),
the Gaussian 92(TM) system (copyright 1992, Gaussian, Inc.),
the Gaussian 90(TM) system (copyright 1990, Gaussian, Inc.),
the Gaussian 88(TM) system (copyright 1988, Gaussian, Inc.),
the Gaussian 86(TM) system (copyright 1986, Carnegie Mellon
University), and the Gaussian 82(TM) system (copyright 1983,
Carnegie Mellon University). Gaussian is a federally registered
trademark of Gaussian, Inc.
This software contains proprietary and confidential information,
including trade secrets, belonging to Gaussian, Inc.
This software is provided under written license and may be
used, copied, transmitted, or stored only in accord with that
written license.
The following legend is applicable only to US Government
contracts under FAR:
RESTRICTED RIGHTS LEGEND
Use, reproduction and disclosure by the US Government is
subject to restrictions as set forth in subparagraphs (a)
and (c) of the Commercial Computer Software - Restricted
Rights clause in FAR 52.227-19.
Gaussian, Inc.
340 Quinnipiac St., Bldg. 40, Wallingford CT 06492
---------------------------------------------------------------
Warning -- This program may not be used in any manner that
competes with the business of Gaussian, Inc. or will provide
assistance to any competitor of Gaussian, Inc. The licensee
of this program is prohibited from giving any competitor of
Gaussian, Inc. access to this program. By using this program,
the user acknowledges that Gaussian, Inc. is engaged in the
business of creating and licensing software in the field of
computational chemistry and represents and warrants to the
licensee that it is not a competitor of Gaussian, Inc. and that
it will not use this program in any manner prohibited above.
---------------------------------------------------------------
Cite this work as:
Gaussian 09, Revision D.01,
M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria,
M. A. Robb, J. R. Cheeseman, G. Scalmani, V. Barone, B. Mennucci,
G. A. Petersson, H. Nakatsuji, M. Caricato, X. Li, H. P. Hratchian,
A. F. Izmaylov, J. Bloino, G. Zheng, J. L. Sonnenberg, M. Hada,
M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima,
Y. Honda, O. Kitao, H. Nakai, T. Vreven, J. A. Montgomery, Jr.,
J. E. Peralta, F. Ogliaro, M. Bearpark, J. J. Heyd, E. Brothers,
K. N. Kudin, V. N. Staroverov, T. Keith, R. Kobayashi, J. Normand,
K. Raghavachari, A. Rendell, J. C. Burant, S. S. Iyengar, J. Tomasi,
M. Cossi, N. Rega, J. M. Millam, M. Klene, J. E. Knox, J. B. Cross,
V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann,
O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski,
R. L. Martin, K. Morokuma, V. G. Zakrzewski, G. A. Voth,
P. Salvador, J. J. Dannenberg, S. Dapprich, A. D. Daniels,
O. Farkas, J. B. Foresman, J. V. Ortiz, J. Cioslowski,
and D. J. Fox, Gaussian, Inc., Wallingford CT, 2013.
******************************************
Gaussian 09: ES64L-G09RevD.01 24-Apr-2013
1-Apr-2019
******************************************
-------------------------------------
#p ROCCSD(T) cc-pVTZ pop=full gfprint
-------------------------------------
1/38=1/1;
2/12=2,17=6,18=5,40=1/2;
3/5=16,6=1,11=2,16=1,24=100,25=1,30=1,116=101/1,2,3;
4//1;
5/5=2,38=5/2;
8/5=-1,6=4,9=120000,10=1/1,4;
9/5=7,14=2/13;
6/7=3/1;
99/5=1,9=1/99;
Leave Link 1 at Mon Apr 1 17:59:33 2019, MaxMem= 0 cpu: 0.1
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l101.exe)
--
G2
--
Symbolic Z-matrix:
Charge = 0 Multiplicity = 1
C
C 1 CC
Variables:
CC 1.2425
NAtoms= 2 NQM= 2 NQMF= 0 NMMI= 0 NMMIF= 0
NMic= 0 NMicF= 0.
Isotopes and Nuclear Properties:
(Nuclear quadrupole moments (NQMom) in fm**2, nuclear magnetic moments (NMagM)
in nuclear magnetons)
Atom 1 2
IAtWgt= 12 12
AtmWgt= 12.0000000 12.0000000
NucSpn= 0 0
AtZEff= 0.0000000 0.0000000
NQMom= 0.0000000 0.0000000
NMagM= 0.0000000 0.0000000
AtZNuc= 6.0000000 6.0000000
Leave Link 101 at Mon Apr 1 17:59:34 2019, MaxMem= 33554432 cpu: 0.2
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l202.exe)
Input orientation:
---------------------------------------------------------------------
Center Atomic Atomic Coordinates (Angstroms)
Number Number Type X Y Z
---------------------------------------------------------------------
1 6 0 0.000000 0.000000 0.000000
2 6 0 0.000000 0.000000 1.242500
---------------------------------------------------------------------
Stoichiometry C2
Framework group D*H[C*(C.C)]
Deg. of freedom 1
Full point group D*H NOp 8
Largest Abelian subgroup D2H NOp 8
Largest concise Abelian subgroup C2 NOp 2
Standard orientation:
---------------------------------------------------------------------
Center Atomic Atomic Coordinates (Angstroms)
Number Number Type X Y Z
---------------------------------------------------------------------
1 6 0 0.000000 0.000000 0.621250
2 6 0 0.000000 0.000000 -0.621250
---------------------------------------------------------------------
Rotational constants (GHZ): 0.0000000 54.5598479 54.5598479
Leave Link 202 at Mon Apr 1 17:59:34 2019, MaxMem= 33554432 cpu: 0.0
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l301.exe)
Standard basis: CC-pVTZ (5D, 7F)
Ernie: Thresh= 0.10000D-02 Tol= 0.10000D-05 Strict=F.
Ernie: 6 primitive shells out of 52 were deleted.
AO basis set (Overlap normalization):
Atom C1 Shell 1 S 7 bf 1 - 1 0.000000000000 0.000000000000 1.173992360055
0.8236000000D+04 0.5419783203D-03
0.1235000000D+04 0.4192873817D-02
0.2808000000D+03 0.2152216205D-01
0.7927000000D+02 0.8353432195D-01
0.2559000000D+02 0.2395828457D+00
0.8997000000D+01 0.4428528419D+00
0.3319000000D+01 0.3517995618D+00
Atom C1 Shell 2 S 6 bf 2 - 2 0.000000000000 0.000000000000 1.173992360055
0.2808000000D+03 -0.5949224937D-04
0.7927000000D+02 -0.1148158310D-02
0.2559000000D+02 -0.1001913745D-01
0.8997000000D+01 -0.6121949230D-01
0.3319000000D+01 -0.1732698541D+00
0.3643000000D+00 0.1072915192D+01
Atom C1 Shell 3 S 1 bf 3 - 3 0.000000000000 0.000000000000 1.173992360055
0.9059000000D+00 0.1000000000D+01
Atom C1 Shell 4 S 1 bf 4 - 4 0.000000000000 0.000000000000 1.173992360055
0.1285000000D+00 0.1000000000D+01
Atom C1 Shell 5 P 3 bf 5 - 7 0.000000000000 0.000000000000 1.173992360055
0.1871000000D+02 0.3942638716D-01
0.4133000000D+01 0.2440889849D+00
0.1200000000D+01 0.8154920089D+00
Atom C1 Shell 6 P 1 bf 8 - 10 0.000000000000 0.000000000000 1.173992360055
0.3827000000D+00 0.1000000000D+01
Atom C1 Shell 7 P 1 bf 11 - 13 0.000000000000 0.000000000000 1.173992360055
0.1209000000D+00 0.1000000000D+01
Atom C1 Shell 8 D 1 bf 14 - 18 0.000000000000 0.000000000000 1.173992360055
0.1097000000D+01 0.1000000000D+01
Atom C1 Shell 9 D 1 bf 19 - 23 0.000000000000 0.000000000000 1.173992360055
0.3180000000D+00 0.1000000000D+01
Atom C1 Shell 10 F 1 bf 24 - 30 0.000000000000 0.000000000000 1.173992360055
0.7610000000D+00 0.1000000000D+01
Atom C2 Shell 11 S 7 bf 31 - 31 0.000000000000 0.000000000000 -1.173992360055
0.8236000000D+04 0.5419783203D-03
0.1235000000D+04 0.4192873817D-02
0.2808000000D+03 0.2152216205D-01
0.7927000000D+02 0.8353432195D-01
0.2559000000D+02 0.2395828457D+00
0.8997000000D+01 0.4428528419D+00
0.3319000000D+01 0.3517995618D+00
Atom C2 Shell 12 S 6 bf 32 - 32 0.000000000000 0.000000000000 -1.173992360055
0.2808000000D+03 -0.5949224937D-04
0.7927000000D+02 -0.1148158310D-02
0.2559000000D+02 -0.1001913745D-01
0.8997000000D+01 -0.6121949230D-01
0.3319000000D+01 -0.1732698541D+00
0.3643000000D+00 0.1072915192D+01
Atom C2 Shell 13 S 1 bf 33 - 33 0.000000000000 0.000000000000 -1.173992360055
0.9059000000D+00 0.1000000000D+01
Atom C2 Shell 14 S 1 bf 34 - 34 0.000000000000 0.000000000000 -1.173992360055
0.1285000000D+00 0.1000000000D+01
Atom C2 Shell 15 P 3 bf 35 - 37 0.000000000000 0.000000000000 -1.173992360055
0.1871000000D+02 0.3942638716D-01
0.4133000000D+01 0.2440889849D+00
0.1200000000D+01 0.8154920089D+00
Atom C2 Shell 16 P 1 bf 38 - 40 0.000000000000 0.000000000000 -1.173992360055
0.3827000000D+00 0.1000000000D+01
Atom C2 Shell 17 P 1 bf 41 - 43 0.000000000000 0.000000000000 -1.173992360055
0.1209000000D+00 0.1000000000D+01
Atom C2 Shell 18 D 1 bf 44 - 48 0.000000000000 0.000000000000 -1.173992360055
0.1097000000D+01 0.1000000000D+01
Atom C2 Shell 19 D 1 bf 49 - 53 0.000000000000 0.000000000000 -1.173992360055
0.3180000000D+00 0.1000000000D+01
Atom C2 Shell 20 F 1 bf 54 - 60 0.000000000000 0.000000000000 -1.173992360055
0.7610000000D+00 0.1000000000D+01
There are 16 symmetry adapted cartesian basis functions of AG symmetry.
There are 3 symmetry adapted cartesian basis functions of B1G symmetry.
There are 8 symmetry adapted cartesian basis functions of B2G symmetry.
There are 8 symmetry adapted cartesian basis functions of B3G symmetry.
There are 3 symmetry adapted cartesian basis functions of AU symmetry.
There are 16 symmetry adapted cartesian basis functions of B1U symmetry.
There are 8 symmetry adapted cartesian basis functions of B2U symmetry.
There are 8 symmetry adapted cartesian basis functions of B3U symmetry.
There are 13 symmetry adapted basis functions of AG symmetry.
There are 3 symmetry adapted basis functions of B1G symmetry.
There are 7 symmetry adapted basis functions of B2G symmetry.
There are 7 symmetry adapted basis functions of B3G symmetry.
There are 3 symmetry adapted basis functions of AU symmetry.
There are 13 symmetry adapted basis functions of B1U symmetry.
There are 7 symmetry adapted basis functions of B2U symmetry.
There are 7 symmetry adapted basis functions of B3U symmetry.
60 basis functions, 104 primitive gaussians, 70 cartesian basis functions
6 alpha electrons 6 beta electrons
nuclear repulsion energy 15.3322973917 Hartrees.
IExCor= 0 DFT=F Ex=HF Corr=None ExCW=0 ScaHFX= 1.000000
ScaDFX= 1.000000 1.000000 1.000000 1.000000 ScalE2= 1.000000 1.000000
IRadAn= 0 IRanWt= -1 IRanGd= 0 ICorTp=0 IEmpDi= 4
NAtoms= 2 NActive= 2 NUniq= 1 SFac= 4.00D+00 NAtFMM= 60 NAOKFM=F Big=F
Integral buffers will be 131072 words long.
Raffenetti 2 integral format.
Two-electron integral symmetry is turned on.
Leave Link 301 at Mon Apr 1 17:59:34 2019, MaxMem= 33554432 cpu: 0.1
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l302.exe)
NPDir=0 NMtPBC= 1 NCelOv= 1 NCel= 1 NClECP= 1 NCelD= 1
NCelK= 1 NCelE2= 1 NClLst= 1 CellRange= 0.0.
One-electron integrals computed using PRISM.
One-electron integral symmetry used in STVInt
NBasis= 60 RedAO= T EigKep= 1.32D-03 NBF= 13 3 7 7 3 13 7 7
NBsUse= 60 1.00D-06 EigRej= -1.00D+00 NBFU= 13 3 7 7 3 13 7 7
Leave Link 302 at Mon Apr 1 17:59:34 2019, MaxMem= 33554432 cpu: 0.2
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l303.exe)
DipDrv: MaxL=1.
Leave Link 303 at Mon Apr 1 17:59:34 2019, MaxMem= 33554432 cpu: 0.1
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l401.exe)
ExpMin= 1.21D-01 ExpMax= 8.24D+03 ExpMxC= 2.81D+02 IAcc=1 IRadAn= 1 AccDes= 0.00D+00
Harris functional with IExCor= 205 and IRadAn= 1 diagonalized for initial guess.
HarFok: IExCor= 205 AccDes= 0.00D+00 IRadAn= 1 IDoV= 1 UseB2=F ITyADJ=14
ICtDFT= 3500011 ScaDFX= 1.000000 1.000000 1.000000 1.000000
FoFCou: FMM=F IPFlag= 0 FMFlag= 100000 FMFlg1= 0
NFxFlg= 0 DoJE=T BraDBF=F KetDBF=T FulRan=T
wScrn= 0.000000 ICntrl= 500 IOpCl= 0 I1Cent= 200000004 NGrid= 0
NMat0= 1 NMatS0= 1 NMatT0= 0 NMatD0= 1 NMtDS0= 0 NMtDT0= 0
Petite list used in FoFCou.
Harris En= -75.4684657843150
JPrj=0 DoOrth=F DoCkMO=F.
Initial guess orbital symmetries:
Occupied (SGG) (SGU) (SGG) (SGU) (PIU) (PIU)
Virtual (SGG) (PIG) (PIG) (SGU) (PIU) (PIU) (SGG) (SGG)
(PIG) (PIG) (SGU) (DLTG) (DLTG) (SGU) (PIU) (PIU)
(DLTU) (DLTU) (PIG) (PIG) (SGG) (SGU) (PIU) (PIU)
(SGG) (PIG) (PIG) (SGU) (DLTG) (DLTG) (PIU) (PIU)
(PHIU) (PHIU) (SGG) (PHIG) (PHIG) (DLTG) (DLTG)
(PIG) (PIG) (DLTU) (DLTU) (SGU) (PIU) (PIU) (DLTU)
(DLTU) (SGG) (SGU) (PIG) (PIG) (SGG) (SGU)
The electronic state of the initial guess is 1-SGG.
Leave Link 401 at Mon Apr 1 17:59:34 2019, MaxMem= 33554432 cpu: 0.2
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l502.exe)
Restricted open shell SCF:
Using DIIS extrapolation, IDIIS= 1040.
Integral symmetry usage will be decided dynamically.
Keep R1 and R2 ints in memory in symmetry-blocked form, NReq=3680183.
IVT= 34402 IEndB= 34402 NGot= 33554432 MDV= 33078773
LenX= 33078773 LenY= 33073432
Requested convergence on RMS density matrix=1.00D-08 within 128 cycles.
Requested convergence on MAX density matrix=1.00D-06.
Requested convergence on energy=1.00D-06.
No special actions if energy rises.
FoFCou: FMM=F IPFlag= 0 FMFlag= 0 FMFlg1= 0
NFxFlg= 0 DoJE=F BraDBF=F KetDBF=F FulRan=T
wScrn= 0.000000 ICntrl= 600 IOpCl= 0 I1Cent= 0 NGrid= 0
NMat0= 1 NMatS0= 1830 NMatT0= 0 NMatD0= 1 NMtDS0= 0 NMtDT0= 0
Petite list used in FoFCou.
Cycle 1 Pass 1 IDiag 1:
E= -75.3242210591186
DIIS: error= 4.91D-02 at cycle 1 NSaved= 1.
NSaved= 1 IEnMin= 1 EnMin= -75.3242210591186 IErMin= 1 ErrMin= 4.91D-02
ErrMax= 4.91D-02 0.00D+00 EMaxC= 1.00D-01 BMatC= 1.25D-01 BMatP= 1.25D-01
IDIUse=3 WtCom= 5.09D-01 WtEn= 4.91D-01
Coeff-Com: 0.100D+01
Coeff-En: 0.100D+01
Coeff: 0.100D+01
Gap= 0.312 Goal= None Shift= 0.000
GapD= 0.312 DampG=1.000 DampE=0.500 DampFc=0.5000 IDamp=-1.
Damping current iteration by 5.00D-01
RMSDP=3.20D-03 MaxDP=3.19D-02 OVMax= 1.31D-01
Cycle 2 Pass 1 IDiag 1:
E= -75.3611386841229 Delta-E= -0.036917625004 Rises=F Damp=T
DIIS: error= 2.73D-02 at cycle 2 NSaved= 2.
NSaved= 2 IEnMin= 2 EnMin= -75.3611386841229 IErMin= 2 ErrMin= 2.73D-02
ErrMax= 2.73D-02 0.00D+00 EMaxC= 1.00D-01 BMatC= 3.18D-02 BMatP= 1.25D-01
IDIUse=3 WtCom= 7.27D-01 WtEn= 2.73D-01
Coeff-Com: -0.869D+00 0.187D+01
Coeff-En: 0.000D+00 0.100D+01
Coeff: -0.632D+00 0.163D+01
Gap= 0.335 Goal= None Shift= 0.000
RMSDP=1.34D-03 MaxDP=1.80D-02 DE=-3.69D-02 OVMax= 2.36D-02
Cycle 3 Pass 1 IDiag 1:
E= -75.4003146734364 Delta-E= -0.039175989313 Rises=F Damp=F
DIIS: error= 7.25D-03 at cycle 3 NSaved= 3.
NSaved= 3 IEnMin= 3 EnMin= -75.4003146734364 IErMin= 3 ErrMin= 7.25D-03
ErrMax= 7.25D-03 0.00D+00 EMaxC= 1.00D-01 BMatC= 4.08D-04 BMatP= 3.18D-02
IDIUse=3 WtCom= 9.27D-01 WtEn= 7.25D-02
Coeff-Com: 0.964D-01-0.243D+00 0.115D+01
Coeff-En: 0.000D+00 0.000D+00 0.100D+01
Coeff: 0.894D-01-0.226D+00 0.114D+01
Gap= 0.341 Goal= None Shift= 0.000
RMSDP=2.90D-04 MaxDP=5.75D-03 DE=-3.92D-02 OVMax= 1.88D-02
Cycle 4 Pass 1 IDiag 1:
E= -75.4013080456350 Delta-E= -0.000993372199 Rises=F Damp=F
DIIS: error= 2.17D-03 at cycle 4 NSaved= 4.
NSaved= 4 IEnMin= 4 EnMin= -75.4013080456350 IErMin= 4 ErrMin= 2.17D-03
ErrMax= 2.17D-03 0.00D+00 EMaxC= 1.00D-01 BMatC= 5.59D-05 BMatP= 4.08D-04
IDIUse=3 WtCom= 9.78D-01 WtEn= 2.17D-02
Coeff-Com: 0.445D-01-0.685D-01-0.492D+00 0.152D+01
Coeff-En: 0.000D+00 0.000D+00 0.000D+00 0.100D+01
Coeff: 0.435D-01-0.670D-01-0.481D+00 0.150D+01
Gap= 0.345 Goal= None Shift= 0.000
RMSDP=2.05D-04 MaxDP=2.86D-03 DE=-9.93D-04 OVMax= 8.96D-03
Cycle 5 Pass 1 IDiag 1:
E= -75.4014462491238 Delta-E= -0.000138203489 Rises=F Damp=F
DIIS: error= 5.71D-05 at cycle 5 NSaved= 5.
NSaved= 5 IEnMin= 5 EnMin= -75.4014462491238 IErMin= 5 ErrMin= 5.71D-05
ErrMax= 5.71D-05 0.00D+00 EMaxC= 1.00D-01 BMatC= 1.08D-07 BMatP= 5.59D-05
IDIUse=1 WtCom= 1.00D+00 WtEn= 0.00D+00
Coeff-Com: -0.532D-02 0.814D-02 0.688D-01-0.236D+00 0.116D+01
Coeff: -0.532D-02 0.814D-02 0.688D-01-0.236D+00 0.116D+01
Gap= 0.346 Goal= None Shift= 0.000
RMSDP=2.18D-05 MaxDP=4.48D-04 DE=-1.38D-04 OVMax= 2.81D-04
Cycle 6 Pass 1 IDiag 1:
E= -75.4014464537439 Delta-E= -0.000000204620 Rises=F Damp=F
DIIS: error= 9.62D-06 at cycle 6 NSaved= 6.
NSaved= 6 IEnMin= 6 EnMin= -75.4014464537439 IErMin= 6 ErrMin= 9.62D-06
ErrMax= 9.62D-06 0.00D+00 EMaxC= 1.00D-01 BMatC= 1.44D-09 BMatP= 1.08D-07
IDIUse=1 WtCom= 1.00D+00 WtEn= 0.00D+00
Coeff-Com: 0.163D-03-0.132D-03-0.642D-02 0.222D-01-0.215D+00 0.120D+01
Coeff: 0.163D-03-0.132D-03-0.642D-02 0.222D-01-0.215D+00 0.120D+01
Gap= 0.346 Goal= None Shift= 0.000
RMSDP=2.32D-06 MaxDP=5.11D-05 DE=-2.05D-07 OVMax= 2.60D-05
Cycle 7 Pass 1 IDiag 1:
E= -75.4014464566014 Delta-E= -0.000000002857 Rises=F Damp=F
DIIS: error= 1.21D-06 at cycle 7 NSaved= 7.
NSaved= 7 IEnMin= 7 EnMin= -75.4014464566014 IErMin= 7 ErrMin= 1.21D-06
ErrMax= 1.21D-06 0.00D+00 EMaxC= 1.00D-01 BMatC= 2.28D-11 BMatP= 1.44D-09
IDIUse=1 WtCom= 1.00D+00 WtEn= 0.00D+00
Coeff-Com: -0.280D-04 0.226D-04 0.964D-03-0.331D-02 0.386D-01-0.289D+00
Coeff-Com: 0.125D+01
Coeff: -0.280D-04 0.226D-04 0.964D-03-0.331D-02 0.386D-01-0.289D+00
Coeff: 0.125D+01
Gap= 0.346 Goal= None Shift= 0.000
RMSDP=3.21D-07 MaxDP=5.28D-06 DE=-2.86D-09 OVMax= 4.72D-06
Cycle 8 Pass 1 IDiag 1:
E= -75.4014464566583 Delta-E= -0.000000000057 Rises=F Damp=F
DIIS: error= 1.07D-07 at cycle 8 NSaved= 8.
NSaved= 8 IEnMin= 8 EnMin= -75.4014464566583 IErMin= 8 ErrMin= 1.07D-07
ErrMax= 1.07D-07 0.00D+00 EMaxC= 1.00D-01 BMatC= 2.71D-13 BMatP= 2.28D-11
IDIUse=1 WtCom= 1.00D+00 WtEn= 0.00D+00
Coeff-Com: 0.369D-05-0.255D-05-0.116D-03 0.385D-03-0.521D-02 0.445D-01
Coeff-Com: -0.282D+00 0.124D+01
Coeff: 0.369D-05-0.255D-05-0.116D-03 0.385D-03-0.521D-02 0.445D-01
Coeff: -0.282D+00 0.124D+01
Gap= 0.346 Goal= None Shift= 0.000
RMSDP=1.04D-07 MaxDP=1.96D-06 DE=-5.69D-11 OVMax= 6.70D-07
Cycle 9 Pass 1 IDiag 1:
E= -75.4014464566591 Delta-E= -0.000000000001 Rises=F Damp=F
DIIS: error= 9.17D-09 at cycle 9 NSaved= 9.
NSaved= 9 IEnMin= 9 EnMin= -75.4014464566591 IErMin= 9 ErrMin= 9.17D-09
ErrMax= 9.17D-09 0.00D+00 EMaxC= 1.00D-01 BMatC= 1.62D-15 BMatP= 2.71D-13
IDIUse=1 WtCom= 1.00D+00 WtEn= 0.00D+00
Coeff-Com: 0.657D-06-0.130D-05-0.158D-05 0.942D-05 0.113D-03-0.178D-02
Coeff-Com: 0.194D-01-0.138D+00 0.112D+01
Coeff: 0.657D-06-0.130D-05-0.158D-05 0.942D-05 0.113D-03-0.178D-02
Coeff: 0.194D-01-0.138D+00 0.112D+01
Gap= 0.346 Goal= None Shift= 0.000
RMSDP=7.80D-09 MaxDP=1.53D-07 DE=-8.24D-13 OVMax= 3.00D-08
SCF Done: E(ROHF) = -75.4014464567 A.U. after 9 cycles
NFock= 9 Conv=0.78D-08 -V/T= 2.0000
<Sx>= 0.0000 <Sy>= 0.0000 <Sz>= 0.0000 <S**2>= 0.0000 S= 0.0000
<L.S>= 0.000000000000E+00
KE= 7.540426753541D+01 PE=-2.064544707387D+02 EE= 4.031645935488D+01
Annihilation of the first spin contaminant:
S**2 before annihilation 0.0000, after 0.0000
Leave Link 502 at Mon Apr 1 17:59:35 2019, MaxMem= 33554432 cpu: 0.6
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l801.exe)
Windowed orbitals will be sorted by symmetry type.
GenMOA: NOpAll= 8 NOp2=8 NOpUse= 8 JSym2X=1
FoFJK: IHMeth= 1 ICntrl= 0 DoSepK=F KAlg= 0 I1Cent= 0 FoldK=F
IRaf= 0 NMat= 1 IRICut= 1 DoRegI=T DoRafI=F ISym2E= 1.
FoFCou: FMM=F IPFlag= 0 FMFlag= 100000 FMFlg1= 0
NFxFlg= 0 DoJE=F BraDBF=F KetDBF=F FulRan=T
wScrn= 0.000000 ICntrl= 0 IOpCl= 1 I1Cent= 0 NGrid= 0
NMat0= 1 NMatS0= 1 NMatT0= 0 NMatD0= 1 NMtDS0= 0 NMtDT0= 0
Petite list used in FoFCou.
<Sx>= 0.0000 <Sy>= 0.0000 <Sz>= 0.0000 <S**2>= 0.0000 S= 0.0000
ExpMin= 1.21D-01 ExpMax= 8.24D+03 ExpMxC= 2.81D+02 IAcc=3 IRadAn= 5 AccDes= 0.00D+00
HarFok: IExCor= 205 AccDes= 0.00D+00 IRadAn= 5 IDoV=-2 UseB2=F ITyADJ=14
ICtDFT= 12500011 ScaDFX= 1.000000 1.000000 1.000000 1.000000
Largest valence mixing into a core orbital is 2.48D-04
Largest core mixing into a valence orbital is 6.07D-05
Largest valence mixing into a core orbital is 2.48D-04
Largest core mixing into a valence orbital is 6.07D-05
Range of M.O.s used for correlation: 3 60
NBasis= 60 NAE= 6 NBE= 6 NFC= 2 NFV= 0
NROrb= 58 NOA= 4 NOB= 4 NVA= 54 NVB= 54
**** Warning!!: The largest alpha MO coefficient is 0.10377371D+02
**** Warning!!: The largest beta MO coefficient is 0.10377371D+02
Singles contribution to E2= -0.5615684412D-17
Leave Link 801 at Mon Apr 1 17:59:36 2019, MaxMem= 33554432 cpu: 0.5
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l804.exe)
Open-shell transformation, MDV= 33554432 ITran=4 ISComp=2.
Semi-Direct transformation.
ModeAB= 4 MOrb= 4 LenV= 33264237
LASXX= 46823 LTotXX= 46823 LenRXX= 96900
LTotAB= 50077 MaxLAS= 331296 LenRXY= 0
NonZer= 143723 LenScr= 720896 LnRSAI= 331296
LnScr1= 917504 LExtra= 0 Total= 2066596
MaxDsk= -1 SrtSym= T ITran= 4
DoSDTr: NPSUse= 1
JobTyp=1 Pass 1: I= 1 to 4.
(rs|ai) integrals will be sorted in core.
Complete sort for first half transformation.
First half transformation complete.
Complete sort for second half transformation.
Second half transformation complete.
ModeAB= 4 MOrb= 4 LenV= 33264237
LASXX= 46823 LTotXX= 46823 LenRXX= 90190
LTotAB= 43367 MaxLAS= 331296 LenRXY= 0
NonZer= 137013 LenScr= 720896 LnRSAI= 331296
LnScr1= 917504 LExtra= 0 Total= 2059886
MaxDsk= -1 SrtSym= T ITran= 4
DoSDTr: NPSUse= 1
JobTyp=2 Pass 1: I= 1 to 4.
(rs|ai) integrals will be sorted in core.
Complete sort for first half transformation.
First half transformation complete.
Complete sort for second half transformation.
Second half transformation complete.
Spin components of T(2) and E(2):
alpha-alpha T2 = 0.2552566829D-01 E2= -0.4385732778D-01
alpha-beta T2 = 0.1582076071D+00 E2= -0.2673988818D+00
beta-beta T2 = 0.2552566829D-01 E2= -0.4385732778D-01
ANorm= 0.1099663105D+01
E2 = -0.3551135374D+00 EUMP2 = -0.75756559994032D+02
(S**2,0)= 0.00000D+00 (S**2,1)= 0.00000D+00
E(PUHF)= -0.75401446457D+02 E(PMP2)= -0.75756559994D+02
Leave Link 804 at Mon Apr 1 17:59:37 2019, MaxMem= 33554432 cpu: 0.9
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l913.exe)
CIDS: MDV= 33554432.
Frozen-core window: NFC= 2 NFV= 0.
IFCWin=0 IBDFC=1 NFBD= 0 0 NFCmp= 0 0 NFFFC= 0 0
Using original routines for 1st iteration, S=T.
Using DD4UQ or CC4UQ for 2nd and later iterations.
Keep R2 and R3 ints in memory in symmetry-blocked form, NReq=3623783.
FoFCou: FMM=F IPFlag= 0 FMFlag= 0 FMFlg1= 0
NFxFlg= 0 DoJE=F BraDBF=F KetDBF=F FulRan=T
wScrn= 0.000000 ICntrl= 600 IOpCl= 0 I1Cent= 0 NGrid= 0
NMat0= 1 NMatS0= 1830 NMatT0= 0 NMatD0= 1 NMtDS0= 0 NMtDT0= 0
Petite list used in FoFCou.
CCSD(T)
=======
Iterations= 50 Convergence= 0.100D-06
Iteration Nr. 1
**********************
DD1Dir will call FoFMem 1 times, MxPair= 44
NAB= 16 NAA= 6 NBB= 6.
DD1Dir will call FoFMem 1 times, MxPair= 44
NAB= 16 NAA= 6 NBB= 6.
MP4(R+Q)= -0.22442030D-01
Maximum subspace dimension= 5
Norm of the A-vectors is 1.2474300D-01 conv= 1.00D-05.
RLE energy= -0.3408570526
E3= 0.37294798D-01 EROMP3= -0.75719265196D+02
E4(SDQ)= -0.34975601D-01 ROMP4(SDQ)= -0.75754240798D+02
VARIATIONAL ENERGIES WITH THE FIRST-ORDER WAVEFUNCTION:
DE(Corr)= -0.34026077 E(Corr)= -75.741707226
NORM(A)= 0.10902754D+01
Iteration Nr. 2
**********************
DD1Dir will call FoFMem 1 times, MxPair= 44
NAB= 16 NAA= 6 NBB= 6.
Norm of the A-vectors is 6.7584139D-01 conv= 1.00D-05.
RLE energy= -0.3334522957
DE(Corr)= -0.30328268 E(CORR)= -75.704729134 Delta= 3.70D-02
NORM(A)= 0.10857900D+01
Iteration Nr. 3
**********************
DD1Dir will call FoFMem 1 times, MxPair= 44
NAB= 16 NAA= 6 NBB= 6.
Norm of the A-vectors is 5.3044884D-01 conv= 1.00D-05.
RLE energy= -0.3378643298
DE(Corr)= -0.31096551 E(CORR)= -75.712411965 Delta=-7.68D-03
NORM(A)= 0.10917342D+01
Iteration Nr. 4
**********************
DD1Dir will call FoFMem 1 times, MxPair= 44
NAB= 16 NAA= 6 NBB= 6.
Norm of the A-vectors is 3.8775862D-01 conv= 1.00D-05.
RLE energy= -0.3451043124
DE(Corr)= -0.31952772 E(CORR)= -75.720974179 Delta=-8.56D-03
NORM(A)= 0.11460461D+01
Iteration Nr. 5
**********************
DD1Dir will call FoFMem 1 times, MxPair= 44
NAB= 16 NAA= 6 NBB= 6.
Norm of the A-vectors is 1.8894522D-01 conv= 1.00D-05.
RLE energy= -0.3495516250
DE(Corr)= -0.35816379 E(CORR)= -75.759610251 Delta=-3.86D-02
NORM(A)= 0.11326925D+01
Iteration Nr. 6
**********************
DD1Dir will call FoFMem 1 times, MxPair= 44
NAB= 16 NAA= 6 NBB= 6.
Norm of the A-vectors is 8.6890467D-02 conv= 1.00D-05.
RLE energy= -0.3472148732
DE(Corr)= -0.34243773 E(CORR)= -75.743884184 Delta= 1.57D-02
NORM(A)= 0.11379539D+01
Iteration Nr. 7
**********************
DD1Dir will call FoFMem 1 times, MxPair= 44
NAB= 16 NAA= 6 NBB= 6.
Norm of the A-vectors is 8.4849417D-03 conv= 1.00D-05.
RLE energy= -0.3480713190
DE(Corr)= -0.34800458 E(CORR)= -75.749451033 Delta=-5.57D-03
NORM(A)= 0.11397718D+01
Iteration Nr. 8
**********************
DD1Dir will call FoFMem 1 times, MxPair= 44
NAB= 16 NAA= 6 NBB= 6.
Norm of the A-vectors is 2.0111885D-03 conv= 1.00D-05.
RLE energy= -0.3481187395
DE(Corr)= -0.34812652 E(CORR)= -75.749572973 Delta=-1.22D-04
NORM(A)= 0.11397482D+01
Iteration Nr. 9
**********************
DD1Dir will call FoFMem 1 times, MxPair= 44
NAB= 16 NAA= 6 NBB= 6.
Norm of the A-vectors is 1.2341640D-03 conv= 1.00D-05.
RLE energy= -0.3480906124
DE(Corr)= -0.34808328 E(CORR)= -75.749529742 Delta= 4.32D-05
NORM(A)= 0.11397121D+01
Iteration Nr. 10
**********************
DD1Dir will call FoFMem 1 times, MxPair= 44
NAB= 16 NAA= 6 NBB= 6.
Norm of the A-vectors is 5.5612110D-04 conv= 1.00D-05.
RLE energy= -0.3481018347
DE(Corr)= -0.34809865 E(CORR)= -75.749545108 Delta=-1.54D-05
NORM(A)= 0.11397209D+01
Iteration Nr. 11
**********************
DD1Dir will call FoFMem 1 times, MxPair= 44
NAB= 16 NAA= 6 NBB= 6.
Norm of the A-vectors is 2.2207618D-04 conv= 1.00D-05.
RLE energy= -0.3481062481
DE(Corr)= -0.34809868 E(CORR)= -75.749545134 Delta=-2.63D-08
NORM(A)= 0.11397400D+01
Iteration Nr. 12
**********************
DD1Dir will call FoFMem 1 times, MxPair= 44
NAB= 16 NAA= 6 NBB= 6.
Norm of the A-vectors is 6.6899514D-05 conv= 1.00D-05.
RLE energy= -0.3481039158
DE(Corr)= -0.34810390 E(CORR)= -75.749550352 Delta=-5.22D-06
NORM(A)= 0.11397388D+01
Iteration Nr. 13
**********************
DD1Dir will call FoFMem 1 times, MxPair= 44
NAB= 16 NAA= 6 NBB= 6.
Norm of the A-vectors is 2.4726504D-05 conv= 1.00D-05.
RLE energy= -0.3481052428
DE(Corr)= -0.34810478 E(CORR)= -75.749551237 Delta=-8.85D-07
NORM(A)= 0.11397388D+01
Iteration Nr. 14
**********************
DD1Dir will call FoFMem 1 times, MxPair= 44
NAB= 16 NAA= 6 NBB= 6.
Norm of the A-vectors is 1.2045154D-05 conv= 1.00D-05.
RLE energy= -0.3481038611
DE(Corr)= -0.34810407 E(CORR)= -75.749550526 Delta= 7.11D-07
NORM(A)= 0.11397368D+01
Iteration Nr. 15
**********************
DD1Dir will call FoFMem 1 times, MxPair= 44
NAB= 16 NAA= 6 NBB= 6.
Norm of the A-vectors is 4.2714489D-06 conv= 1.00D-05.
RLE energy= -0.3481040376
DE(Corr)= -0.34810413 E(CORR)= -75.749550586 Delta=-5.99D-08
NORM(A)= 0.11397363D+01
CI/CC converged in 15 iterations to DelEn=-5.99D-08 Conv= 1.00D-07 ErrA1= 4.27D-06 Conv= 1.00D-05
Dominant configurations:
***********************
Spin Case I J A B Value
ABAB 4 4 7 7 -0.291796D+00
Largest amplitude= 2.92D-01
Time for triples= 214.43 seconds.
T4(CCSD)= -0.37880196D-01
T5(CCSD)= 0.43613349D-02
CCSD(T)= -0.75783069447D+02
Discarding MO integrals.
Leave Link 913 at Mon Apr 1 18:09:41 2019, MaxMem= 33554432 cpu: 222.8
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l601.exe)
Copying SCF densities to generalized density rwf, IOpCl= 0 IROHF=1.
**********************************************************************
Population analysis using the SCF density.
**********************************************************************
Orbital symmetries:
Occupied (SGG) (SGU) (SGG) (SGU) (PIU) (PIU)
Virtual (SGG) (PIG) (PIG) (SGU) (SGG) (PIU) (PIU) (SGG)
(PIG) (PIG) (SGU) (DLTG) (DLTG) (SGU) (PIU) (PIU)
(DLTU) (DLTU) (PIG) (PIG) (SGG) (SGU) (PIU) (PIU)
(SGG) (PIG) (PIG) (SGU) (DLTG) (DLTG) (PHIU) (PHIU)
(PIU) (PIU) (SGG) (PHIG) (PHIG) (DLTG) (DLTG)
(PIG) (PIG) (DLTU) (DLTU) (SGU) (PIU) (PIU) (DLTU)
(DLTU) (SGG) (SGU) (PIG) (PIG) (SGG) (SGU)
The electronic state is 1-SGG.
Alpha occ. eigenvalues -- -11.35967 -11.35737 -1.06072 -0.51670 -0.45709
Alpha occ. eigenvalues -- -0.45709
Alpha virt. eigenvalues -- -0.11154 0.15207 0.15207 0.27269 0.40517
Alpha virt. eigenvalues -- 0.41497 0.41497 0.51351 0.54118 0.54118
Alpha virt. eigenvalues -- 0.71202 0.75124 0.75124 0.85215 0.96934
Alpha virt. eigenvalues -- 0.96934 1.07262 1.07262 1.33325 1.33325
Alpha virt. eigenvalues -- 1.34360 1.69055 2.25875 2.25875 2.37537
Alpha virt. eigenvalues -- 2.54340 2.54340 2.63802 2.72385 2.72385
Alpha virt. eigenvalues -- 2.79575 2.79575 2.81277 2.81277 3.05408
Alpha virt. eigenvalues -- 3.18786 3.18786 3.26427 3.26427 3.27922
Alpha virt. eigenvalues -- 3.27922 3.34942 3.34942 3.59122 3.77963
Alpha virt. eigenvalues -- 3.77963 3.83523 3.83523 3.96132 4.38695
Alpha virt. eigenvalues -- 4.96853 4.96853 5.25976 13.25376
Molecular Orbital Coefficients:
1 2 3 4 5
(SGG)--O (SGU)--O (SGG)--O (SGU)--O (PIU)--O
Eigenvalues -- -11.35967 -11.35737 -1.06072 -0.51670 -0.45709
1 1 C 1S 0.69239 0.69292 -0.16041 -0.13378 0.00000
2 2S -0.00538 -0.00510 0.36114 0.36520 0.00000
3 3S 0.02810 0.02817 0.08943 0.09369 0.00000
4 4S 0.00161 0.01016 0.11144 0.30402 0.00000
5 5PX 0.00000 0.00000 0.00000 0.00000 0.00000
6 5PY 0.00000 0.00000 0.00000 0.00000 0.23107
7 5PZ 0.00012 0.00003 -0.10141 0.09954 0.00000
8 6PX 0.00000 0.00000 0.00000 0.00000 0.00000
9 6PY 0.00000 0.00000 0.00000 0.00000 0.30659
10 6PZ -0.00061 -0.00239 -0.09204 0.14789 0.00000
11 7PX 0.00000 0.00000 0.00000 0.00000 0.00000
12 7PY 0.00000 0.00000 0.00000 0.00000 0.17077
13 7PZ -0.00007 -0.00315 -0.00832 0.09349 0.00000
14 8D 0 0.00011 0.00058 0.01671 -0.00350 0.00000
15 8D+1 0.00000 0.00000 0.00000 0.00000 0.00000
16 8D-1 0.00000 0.00000 0.00000 0.00000 -0.02018
17 8D+2 0.00000 0.00000 0.00000 0.00000 0.00000
18 8D-2 0.00000 0.00000 0.00000 0.00000 0.00000
19 9D 0 0.00002 0.00088 0.00985 -0.00870 0.00000
20 9D+1 0.00000 0.00000 0.00000 0.00000 0.00000
21 9D-1 0.00000 0.00000 0.00000 0.00000 -0.02627
22 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
23 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
24 10F 0 -0.00011 -0.00036 -0.00672 0.00171 0.00000
25 10F+1 0.00000 0.00000 0.00000 0.00000 0.00000
26 10F-1 0.00000 0.00000 0.00000 0.00000 0.01027
27 10F+2 0.00000 0.00000 0.00000 0.00000 0.00000
28 10F-2 0.00000 0.00000 0.00000 0.00000 0.00000
29 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
30 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
31 2 C 1S 0.69239 -0.69292 -0.16041 0.13378 0.00000
32 2S -0.00538 0.00510 0.36114 -0.36520 0.00000
33 3S 0.02810 -0.02817 0.08943 -0.09369 0.00000
34 4S 0.00161 -0.01016 0.11144 -0.30402 0.00000
35 5PX 0.00000 0.00000 0.00000 0.00000 0.00000
36 5PY 0.00000 0.00000 0.00000 0.00000 0.23107
37 5PZ -0.00012 0.00003 0.10141 0.09954 0.00000
38 6PX 0.00000 0.00000 0.00000 0.00000 0.00000
39 6PY 0.00000 0.00000 0.00000 0.00000 0.30659
40 6PZ 0.00061 -0.00239 0.09204 0.14789 0.00000
41 7PX 0.00000 0.00000 0.00000 0.00000 0.00000
42 7PY 0.00000 0.00000 0.00000 0.00000 0.17077
43 7PZ 0.00007 -0.00315 0.00832 0.09349 0.00000
44 8D 0 0.00011 -0.00058 0.01671 0.00350 0.00000
45 8D+1 0.00000 0.00000 0.00000 0.00000 0.00000
46 8D-1 0.00000 0.00000 0.00000 0.00000 0.02018
47 8D+2 0.00000 0.00000 0.00000 0.00000 0.00000
48 8D-2 0.00000 0.00000 0.00000 0.00000 0.00000
49 9D 0 0.00002 -0.00088 0.00985 0.00870 0.00000
50 9D+1 0.00000 0.00000 0.00000 0.00000 0.00000
51 9D-1 0.00000 0.00000 0.00000 0.00000 0.02627
52 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
53 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
54 10F 0 0.00011 -0.00036 0.00672 0.00171 0.00000
55 10F+1 0.00000 0.00000 0.00000 0.00000 0.00000
56 10F-1 0.00000 0.00000 0.00000 0.00000 0.01027
57 10F+2 0.00000 0.00000 0.00000 0.00000 0.00000
58 10F-2 0.00000 0.00000 0.00000 0.00000 0.00000
59 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
6 7 8 9 10
(PIU)--O (SGG)--V (PIG)--V (PIG)--V (SGU)--V
Eigenvalues -- -0.45709 -0.11154 0.15207 0.15207 0.27269
1 1 C 1S 0.00000 -0.02417 0.00000 0.00000 -0.04820
2 2S 0.00000 0.04981 0.00000 0.00000 0.27077
3 3S 0.00000 0.01536 0.00000 0.00000 0.06029
4 4S 0.00000 0.34194 0.00000 0.00000 7.61093
5 5PX 0.23107 0.00000 0.00000 0.20930 0.00000
6 5PY 0.00000 0.00000 0.20930 0.00000 0.00000
7 5PZ 0.00000 0.23608 0.00000 0.00000 0.03541
8 6PX 0.30659 0.00000 0.00000 0.26297 0.00000
9 6PY 0.00000 0.00000 0.26297 0.00000 0.00000
10 6PZ 0.00000 0.27780 0.00000 0.00000 -0.36994
11 7PX 0.17077 0.00000 0.00000 0.84803 0.00000
12 7PY 0.00000 0.00000 0.84803 0.00000 0.00000
13 7PZ 0.00000 0.27155 0.00000 0.00000 -3.84147
14 8D 0 0.00000 -0.01034 0.00000 0.00000 -0.01180
15 8D+1 -0.02018 0.00000 0.00000 0.01810 0.00000
16 8D-1 0.00000 0.00000 0.01810 0.00000 0.00000
17 8D+2 0.00000 0.00000 0.00000 0.00000 0.00000
18 8D-2 0.00000 0.00000 0.00000 0.00000 0.00000
19 9D 0 0.00000 -0.00436 0.00000 0.00000 0.33998
20 9D+1 -0.02627 0.00000 0.00000 -0.00444 0.00000
21 9D-1 0.00000 0.00000 -0.00444 0.00000 0.00000
22 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
23 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
24 10F 0 0.00000 0.00760 0.00000 0.00000 -0.02354
25 10F+1 0.01027 0.00000 0.00000 0.00598 0.00000
26 10F-1 0.00000 0.00000 0.00598 0.00000 0.00000
27 10F+2 0.00000 0.00000 0.00000 0.00000 0.00000
28 10F-2 0.00000 0.00000 0.00000 0.00000 0.00000
29 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
30 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
31 2 C 1S 0.00000 -0.02417 0.00000 0.00000 0.04820
32 2S 0.00000 0.04981 0.00000 0.00000 -0.27077
33 3S 0.00000 0.01536 0.00000 0.00000 -0.06029
34 4S 0.00000 0.34194 0.00000 0.00000 -7.61093
35 5PX 0.23107 0.00000 0.00000 -0.20930 0.00000
36 5PY 0.00000 0.00000 -0.20930 0.00000 0.00000
37 5PZ 0.00000 -0.23608 0.00000 0.00000 0.03541
38 6PX 0.30659 0.00000 0.00000 -0.26297 0.00000
39 6PY 0.00000 0.00000 -0.26297 0.00000 0.00000
40 6PZ 0.00000 -0.27780 0.00000 0.00000 -0.36994
41 7PX 0.17077 0.00000 0.00000 -0.84803 0.00000
42 7PY 0.00000 0.00000 -0.84803 0.00000 0.00000
43 7PZ 0.00000 -0.27155 0.00000 0.00000 -3.84147
44 8D 0 0.00000 -0.01034 0.00000 0.00000 0.01180
45 8D+1 0.02018 0.00000 0.00000 0.01810 0.00000
46 8D-1 0.00000 0.00000 0.01810 0.00000 0.00000
47 8D+2 0.00000 0.00000 0.00000 0.00000 0.00000
48 8D-2 0.00000 0.00000 0.00000 0.00000 0.00000
49 9D 0 0.00000 -0.00436 0.00000 0.00000 -0.33998
50 9D+1 0.02627 0.00000 0.00000 -0.00444 0.00000
51 9D-1 0.00000 0.00000 -0.00444 0.00000 0.00000
52 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
53 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
54 10F 0 0.00000 -0.00760 0.00000 0.00000 -0.02354
55 10F+1 0.01027 0.00000 0.00000 -0.00598 0.00000
56 10F-1 0.00000 0.00000 -0.00598 0.00000 0.00000
57 10F+2 0.00000 0.00000 0.00000 0.00000 0.00000
58 10F-2 0.00000 0.00000 0.00000 0.00000 0.00000
59 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
11 12 13 14 15
(SGG)--V (PIU)--V (PIU)--V (SGG)--V (PIG)--V
Eigenvalues -- 0.40517 0.41497 0.41497 0.51351 0.54118
1 1 C 1S 0.03032 0.00000 0.00000 0.02122 0.00000
2 2S 0.02532 0.00000 0.00000 -0.84245 0.00000
3 3S 0.06181 0.00000 0.00000 -0.14470 0.00000
4 4S 0.30693 0.00000 0.00000 0.85787 0.00000
5 5PX 0.00000 0.00000 -0.13095 0.00000 0.00000
6 5PY 0.00000 -0.13095 0.00000 0.00000 -0.21780
7 5PZ -0.14987 0.00000 0.00000 -0.03944 0.00000
8 6PX 0.00000 0.00000 -0.51853 0.00000 0.00000
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32 2S 0.02532 0.00000 0.00000 -0.84245 0.00000
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37 5PZ 0.14987 0.00000 0.00000 0.03944 0.00000
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39 6PY 0.00000 -0.51853 0.00000 0.00000 0.51949
40 6PZ 0.47531 0.00000 0.00000 0.13215 0.00000
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42 7PY 0.00000 0.70535 0.00000 0.00000 -1.60851
43 7PZ -1.30075 0.00000 0.00000 0.13648 0.00000
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(PIG)--V (SGU)--V (DLTG)-- (DLTG)-- (SGU)--V
Eigenvalues -- 0.54118 0.71202 0.75124 0.75124 0.85215
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43 7PZ 0.00000 -3.63656 0.00000 0.00000 -3.37210
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(PIU)--V (PIU)--V (DLTU)-- (DLTU)-- (PIG)--V
Eigenvalues -- 0.96934 0.96934 1.07262 1.07262 1.33325
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60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
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(PIG)--V (SGG)--V (SGU)--V (PIU)--V (PIU)--V
Eigenvalues -- 1.33325 1.34360 1.69055 2.25875 2.25875
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42 7PY 1.18380 0.00000 0.00000 -0.36610 0.00000
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60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
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(SGG)--V (PIG)--V (PIG)--V (SGU)--V (DLTG)--
Eigenvalues -- 2.37537 2.54340 2.54340 2.63802 2.72385
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(DLTG)-- (PHIU)-- (PHIU)-- (PIU)--V (PIU)--V
Eigenvalues -- 2.72385 2.79575 2.79575 2.81277 2.81277
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50 9D+1 0.00000 0.00000 0.00000 0.00000 0.38202
51 9D-1 0.00000 0.00000 0.00000 0.38202 0.00000
52 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
53 9D-2 0.21065 0.00000 0.00000 0.00000 0.00000
54 10F 0 0.00000 0.00000 0.00000 0.00000 0.00000
55 10F+1 0.00000 0.00000 0.00000 0.00000 -0.25676
56 10F-1 0.00000 0.00000 0.00000 -0.25676 0.00000
57 10F+2 0.00000 0.00000 0.00000 0.00000 0.00000
58 10F-2 -0.56867 0.00000 0.00000 0.00000 0.00000
59 10F+3 0.00000 0.66734 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.66734 0.00000 0.00000
41 42 43 44 45
(SGG)--V (PHIG)-- (PHIG)-- (DLTG)-- (DLTG)--
Eigenvalues -- 3.05408 3.18786 3.18786 3.26427 3.26427
1 1 C 1S -0.17766 0.00000 0.00000 0.00000 0.00000
2 2S -0.24495 0.00000 0.00000 0.00000 0.00000
3 3S 0.69634 0.00000 0.00000 0.00000 0.00000
4 4S 0.06208 0.00000 0.00000 0.00000 0.00000
5 5PX 0.00000 0.00000 0.00000 0.00000 0.00000
6 5PY 0.00000 0.00000 0.00000 0.00000 0.00000
7 5PZ 0.16060 0.00000 0.00000 0.00000 0.00000
8 6PX 0.00000 0.00000 0.00000 0.00000 0.00000
9 6PY 0.00000 0.00000 0.00000 0.00000 0.00000
10 6PZ -0.12858 0.00000 0.00000 0.00000 0.00000
11 7PX 0.00000 0.00000 0.00000 0.00000 0.00000
12 7PY 0.00000 0.00000 0.00000 0.00000 0.00000
13 7PZ 0.41433 0.00000 0.00000 0.00000 0.00000
14 8D 0 0.74206 0.00000 0.00000 0.00000 0.00000
15 8D+1 0.00000 0.00000 0.00000 0.00000 0.00000
16 8D-1 0.00000 0.00000 0.00000 0.00000 0.00000
17 8D+2 0.00000 0.00000 0.00000 0.00000 0.79045
18 8D-2 0.00000 0.00000 0.00000 0.79045 0.00000
19 9D 0 -0.72838 0.00000 0.00000 0.00000 0.00000
20 9D+1 0.00000 0.00000 0.00000 0.00000 0.00000
21 9D-1 0.00000 0.00000 0.00000 0.00000 0.00000
22 9D+2 0.00000 0.00000 0.00000 0.00000 -0.32806
23 9D-2 0.00000 0.00000 0.00000 -0.32806 0.00000
24 10F 0 0.15316 0.00000 0.00000 0.00000 0.00000
25 10F+1 0.00000 0.00000 0.00000 0.00000 0.00000
26 10F-1 0.00000 0.00000 0.00000 0.00000 0.00000
27 10F+2 0.00000 0.00000 0.00000 0.00000 0.22321
28 10F-2 0.00000 0.00000 0.00000 0.22321 0.00000
29 10F+3 0.00000 0.00000 0.75495 0.00000 0.00000
30 10F-3 0.00000 0.75495 0.00000 0.00000 0.00000
31 2 C 1S -0.17766 0.00000 0.00000 0.00000 0.00000
32 2S -0.24495 0.00000 0.00000 0.00000 0.00000
33 3S 0.69634 0.00000 0.00000 0.00000 0.00000
34 4S 0.06208 0.00000 0.00000 0.00000 0.00000
35 5PX 0.00000 0.00000 0.00000 0.00000 0.00000
36 5PY 0.00000 0.00000 0.00000 0.00000 0.00000
37 5PZ -0.16060 0.00000 0.00000 0.00000 0.00000
38 6PX 0.00000 0.00000 0.00000 0.00000 0.00000
39 6PY 0.00000 0.00000 0.00000 0.00000 0.00000
40 6PZ 0.12858 0.00000 0.00000 0.00000 0.00000
41 7PX 0.00000 0.00000 0.00000 0.00000 0.00000
42 7PY 0.00000 0.00000 0.00000 0.00000 0.00000
43 7PZ -0.41433 0.00000 0.00000 0.00000 0.00000
44 8D 0 0.74206 0.00000 0.00000 0.00000 0.00000
45 8D+1 0.00000 0.00000 0.00000 0.00000 0.00000
46 8D-1 0.00000 0.00000 0.00000 0.00000 0.00000
47 8D+2 0.00000 0.00000 0.00000 0.00000 0.79045
48 8D-2 0.00000 0.00000 0.00000 0.79045 0.00000
49 9D 0 -0.72838 0.00000 0.00000 0.00000 0.00000
50 9D+1 0.00000 0.00000 0.00000 0.00000 0.00000
51 9D-1 0.00000 0.00000 0.00000 0.00000 0.00000
52 9D+2 0.00000 0.00000 0.00000 0.00000 -0.32806
53 9D-2 0.00000 0.00000 0.00000 -0.32806 0.00000
54 10F 0 -0.15316 0.00000 0.00000 0.00000 0.00000
55 10F+1 0.00000 0.00000 0.00000 0.00000 0.00000
56 10F-1 0.00000 0.00000 0.00000 0.00000 0.00000
57 10F+2 0.00000 0.00000 0.00000 0.00000 -0.22321
58 10F-2 0.00000 0.00000 0.00000 -0.22321 0.00000
59 10F+3 0.00000 0.00000 -0.75495 0.00000 0.00000
60 10F-3 0.00000 -0.75495 0.00000 0.00000 0.00000
46 47 48 49 50
(PIG)--V (PIG)--V (DLTU)-- (DLTU)-- (SGU)--V
Eigenvalues -- 3.27922 3.27922 3.34942 3.34942 3.59122
1 1 C 1S 0.00000 0.00000 0.00000 0.00000 0.03865
2 2S 0.00000 0.00000 0.00000 0.00000 0.68007
3 3S 0.00000 0.00000 0.00000 0.00000 0.46147
4 4S 0.00000 0.00000 0.00000 0.00000 2.33075
5 5PX 0.00000 0.24186 0.00000 0.00000 0.00000
6 5PY 0.24186 0.00000 0.00000 0.00000 0.00000
7 5PZ 0.00000 0.00000 0.00000 0.00000 -0.24637
8 6PX 0.00000 -1.58464 0.00000 0.00000 0.00000
9 6PY -1.58464 0.00000 0.00000 0.00000 0.00000
10 6PZ 0.00000 0.00000 0.00000 0.00000 -0.89253
11 7PX 0.00000 -0.67142 0.00000 0.00000 0.00000
12 7PY -0.67142 0.00000 0.00000 0.00000 0.00000
13 7PZ 0.00000 0.00000 0.00000 0.00000 -0.94182
14 8D 0 0.00000 0.00000 0.00000 0.00000 -0.22492
15 8D+1 0.00000 -0.48059 0.00000 0.00000 0.00000
16 8D-1 -0.48059 0.00000 0.00000 0.00000 0.00000
17 8D+2 0.00000 0.00000 0.81025 0.00000 0.00000
18 8D-2 0.00000 0.00000 0.00000 0.81025 0.00000
19 9D 0 0.00000 0.00000 0.00000 0.00000 0.79484
20 9D+1 0.00000 1.75199 0.00000 0.00000 0.00000
21 9D-1 1.75199 0.00000 0.00000 0.00000 0.00000
22 9D+2 0.00000 0.00000 -0.64036 0.00000 0.00000
23 9D-2 0.00000 0.00000 0.00000 -0.64036 0.00000
24 10F 0 0.00000 0.00000 0.00000 0.00000 -0.85742
25 10F+1 0.00000 -0.83081 0.00000 0.00000 0.00000
26 10F-1 -0.83081 0.00000 0.00000 0.00000 0.00000
27 10F+2 0.00000 0.00000 0.28708 0.00000 0.00000
28 10F-2 0.00000 0.00000 0.00000 0.28708 0.00000
29 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
30 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
31 2 C 1S 0.00000 0.00000 0.00000 0.00000 -0.03865
32 2S 0.00000 0.00000 0.00000 0.00000 -0.68007
33 3S 0.00000 0.00000 0.00000 0.00000 -0.46147
34 4S 0.00000 0.00000 0.00000 0.00000 -2.33075
35 5PX 0.00000 -0.24186 0.00000 0.00000 0.00000
36 5PY -0.24186 0.00000 0.00000 0.00000 0.00000
37 5PZ 0.00000 0.00000 0.00000 0.00000 -0.24637
38 6PX 0.00000 1.58464 0.00000 0.00000 0.00000
39 6PY 1.58464 0.00000 0.00000 0.00000 0.00000
40 6PZ 0.00000 0.00000 0.00000 0.00000 -0.89253
41 7PX 0.00000 0.67142 0.00000 0.00000 0.00000
42 7PY 0.67142 0.00000 0.00000 0.00000 0.00000
43 7PZ 0.00000 0.00000 0.00000 0.00000 -0.94182
44 8D 0 0.00000 0.00000 0.00000 0.00000 0.22492
45 8D+1 0.00000 -0.48059 0.00000 0.00000 0.00000
46 8D-1 -0.48059 0.00000 0.00000 0.00000 0.00000
47 8D+2 0.00000 0.00000 -0.81025 0.00000 0.00000
48 8D-2 0.00000 0.00000 0.00000 -0.81025 0.00000
49 9D 0 0.00000 0.00000 0.00000 0.00000 -0.79484
50 9D+1 0.00000 1.75199 0.00000 0.00000 0.00000
51 9D-1 1.75199 0.00000 0.00000 0.00000 0.00000
52 9D+2 0.00000 0.00000 0.64036 0.00000 0.00000
53 9D-2 0.00000 0.00000 0.00000 0.64036 0.00000
54 10F 0 0.00000 0.00000 0.00000 0.00000 -0.85742
55 10F+1 0.00000 0.83081 0.00000 0.00000 0.00000
56 10F-1 0.83081 0.00000 0.00000 0.00000 0.00000
57 10F+2 0.00000 0.00000 0.28708 0.00000 0.00000
58 10F-2 0.00000 0.00000 0.00000 0.28708 0.00000
59 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
51 52 53 54 55
(PIU)--V (PIU)--V (DLTU)-- (DLTU)-- (SGG)--V
Eigenvalues -- 3.77963 3.77963 3.83523 3.83523 3.96132
1 1 C 1S 0.00000 0.00000 0.00000 0.00000 0.62727
2 2S 0.00000 0.00000 0.00000 0.00000 2.16139
3 3S 0.00000 0.00000 0.00000 0.00000 -0.49170
4 4S 0.00000 0.00000 0.00000 0.00000 -1.07750
5 5PX 0.00000 -0.19379 0.00000 0.00000 0.00000
6 5PY -0.19379 0.00000 0.00000 0.00000 0.00000
7 5PZ 0.00000 0.00000 0.00000 0.00000 -0.71502
8 6PX 0.00000 -0.12100 0.00000 0.00000 0.00000
9 6PY -0.12100 0.00000 0.00000 0.00000 0.00000
10 6PZ 0.00000 0.00000 0.00000 0.00000 0.65630
11 7PX 0.00000 0.04743 0.00000 0.00000 0.00000
12 7PY 0.04743 0.00000 0.00000 0.00000 0.00000
13 7PZ 0.00000 0.00000 0.00000 0.00000 0.68881
14 8D 0 0.00000 0.00000 0.00000 0.00000 0.36195
15 8D+1 0.00000 0.59095 0.00000 0.00000 0.00000
16 8D-1 0.59095 0.00000 0.00000 0.00000 0.00000
17 8D+2 0.00000 0.00000 0.00000 -0.27260 0.00000
18 8D-2 0.00000 0.00000 -0.27260 0.00000 0.00000
19 9D 0 0.00000 0.00000 0.00000 0.00000 -1.23348
20 9D+1 0.00000 -0.40014 0.00000 0.00000 0.00000
21 9D-1 -0.40014 0.00000 0.00000 0.00000 0.00000
22 9D+2 0.00000 0.00000 0.00000 -0.23922 0.00000
23 9D-2 0.00000 0.00000 -0.23922 0.00000 0.00000
24 10F 0 0.00000 0.00000 0.00000 0.00000 0.59066
25 10F+1 0.00000 0.67396 0.00000 0.00000 0.00000
26 10F-1 0.67396 0.00000 0.00000 0.00000 0.00000
27 10F+2 0.00000 0.00000 0.00000 0.96119 0.00000
28 10F-2 0.00000 0.00000 0.96119 0.00000 0.00000
29 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
30 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
31 2 C 1S 0.00000 0.00000 0.00000 0.00000 0.62727
32 2S 0.00000 0.00000 0.00000 0.00000 2.16139
33 3S 0.00000 0.00000 0.00000 0.00000 -0.49170
34 4S 0.00000 0.00000 0.00000 0.00000 -1.07750
35 5PX 0.00000 -0.19379 0.00000 0.00000 0.00000
36 5PY -0.19379 0.00000 0.00000 0.00000 0.00000
37 5PZ 0.00000 0.00000 0.00000 0.00000 0.71502
38 6PX 0.00000 -0.12100 0.00000 0.00000 0.00000
39 6PY -0.12100 0.00000 0.00000 0.00000 0.00000
40 6PZ 0.00000 0.00000 0.00000 0.00000 -0.65630
41 7PX 0.00000 0.04743 0.00000 0.00000 0.00000
42 7PY 0.04743 0.00000 0.00000 0.00000 0.00000
43 7PZ 0.00000 0.00000 0.00000 0.00000 -0.68881
44 8D 0 0.00000 0.00000 0.00000 0.00000 0.36195
45 8D+1 0.00000 -0.59095 0.00000 0.00000 0.00000
46 8D-1 -0.59095 0.00000 0.00000 0.00000 0.00000
47 8D+2 0.00000 0.00000 0.00000 0.27260 0.00000
48 8D-2 0.00000 0.00000 0.27260 0.00000 0.00000
49 9D 0 0.00000 0.00000 0.00000 0.00000 -1.23348
50 9D+1 0.00000 0.40014 0.00000 0.00000 0.00000
51 9D-1 0.40014 0.00000 0.00000 0.00000 0.00000
52 9D+2 0.00000 0.00000 0.00000 0.23922 0.00000
53 9D-2 0.00000 0.00000 0.23922 0.00000 0.00000
54 10F 0 0.00000 0.00000 0.00000 0.00000 -0.59066
55 10F+1 0.00000 0.67396 0.00000 0.00000 0.00000
56 10F-1 0.67396 0.00000 0.00000 0.00000 0.00000
57 10F+2 0.00000 0.00000 0.00000 0.96119 0.00000
58 10F-2 0.00000 0.00000 0.96119 0.00000 0.00000
59 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
56 57 58 59 60
(SGU)--V (PIG)--V (PIG)--V (SGG)--V (SGU)--V
Eigenvalues -- 4.38695 4.96853 4.96853 5.25976 13.25376
1 1 C 1S -0.25325 0.00000 0.00000 -0.56141 1.66285
2 2S -0.01673 0.00000 0.00000 -0.94576 8.44389
3 3S 0.72535 0.00000 0.00000 1.88841 -1.50008
4 4S -0.41487 0.00000 0.00000 0.11608 7.64911
5 5PX 0.00000 -0.20753 0.00000 0.00000 0.00000
6 5PY 0.00000 0.00000 -0.20753 0.00000 0.00000
7 5PZ -0.45259 0.00000 0.00000 -0.81945 0.22585
8 6PX 0.00000 1.90608 0.00000 0.00000 0.00000
9 6PY 0.00000 0.00000 1.90608 0.00000 0.00000
10 6PZ -0.42690 0.00000 0.00000 0.69066 -7.75868
11 7PX 0.00000 0.23593 0.00000 0.00000 0.00000
12 7PY 0.00000 0.00000 0.23593 0.00000 0.00000
13 7PZ 0.30072 0.00000 0.00000 0.14647 -2.80322
14 8D 0 1.07347 0.00000 0.00000 -0.02430 1.05576
15 8D+1 0.00000 -0.96381 0.00000 0.00000 0.00000
16 8D-1 0.00000 0.00000 -0.96381 0.00000 0.00000
17 8D+2 0.00000 0.00000 0.00000 0.00000 0.00000
18 8D-2 0.00000 0.00000 0.00000 0.00000 0.00000
19 9D 0 -0.21019 0.00000 0.00000 -0.65873 2.74511
20 9D+1 0.00000 -1.25743 0.00000 0.00000 0.00000
21 9D-1 0.00000 0.00000 -1.25743 0.00000 0.00000
22 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
23 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
24 10F 0 -0.48640 0.00000 0.00000 0.70276 -0.76380
25 10F+1 0.00000 1.25730 0.00000 0.00000 0.00000
26 10F-1 0.00000 0.00000 1.25730 0.00000 0.00000
27 10F+2 0.00000 0.00000 0.00000 0.00000 0.00000
28 10F-2 0.00000 0.00000 0.00000 0.00000 0.00000
29 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
30 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
31 2 C 1S 0.25325 0.00000 0.00000 -0.56141 -1.66285
32 2S 0.01673 0.00000 0.00000 -0.94576 -8.44389
33 3S -0.72535 0.00000 0.00000 1.88841 1.50008
34 4S 0.41487 0.00000 0.00000 0.11608 -7.64911
35 5PX 0.00000 0.20753 0.00000 0.00000 0.00000
36 5PY 0.00000 0.00000 0.20753 0.00000 0.00000
37 5PZ -0.45259 0.00000 0.00000 0.81945 0.22585
38 6PX 0.00000 -1.90608 0.00000 0.00000 0.00000
39 6PY 0.00000 0.00000 -1.90608 0.00000 0.00000
40 6PZ -0.42690 0.00000 0.00000 -0.69066 -7.75868
41 7PX 0.00000 -0.23593 0.00000 0.00000 0.00000
42 7PY 0.00000 0.00000 -0.23593 0.00000 0.00000
43 7PZ 0.30072 0.00000 0.00000 -0.14647 -2.80322
44 8D 0 -1.07347 0.00000 0.00000 -0.02430 -1.05576
45 8D+1 0.00000 -0.96381 0.00000 0.00000 0.00000
46 8D-1 0.00000 0.00000 -0.96381 0.00000 0.00000
47 8D+2 0.00000 0.00000 0.00000 0.00000 0.00000
48 8D-2 0.00000 0.00000 0.00000 0.00000 0.00000
49 9D 0 0.21019 0.00000 0.00000 -0.65873 -2.74511
50 9D+1 0.00000 -1.25743 0.00000 0.00000 0.00000
51 9D-1 0.00000 0.00000 -1.25743 0.00000 0.00000
52 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
53 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
54 10F 0 -0.48640 0.00000 0.00000 -0.70276 -0.76380
55 10F+1 0.00000 -1.25730 0.00000 0.00000 0.00000
56 10F-1 0.00000 0.00000 -1.25730 0.00000 0.00000
57 10F+2 0.00000 0.00000 0.00000 0.00000 0.00000
58 10F-2 0.00000 0.00000 0.00000 0.00000 0.00000
59 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
Alpha Density Matrix:
1 2 3 4 5
1 1 C 1S 1.00317
2 2S -0.11405 0.26384
3 3S 0.01210 0.06622 0.01836
4 4S -0.05040 0.15121 0.03878 0.10496
5 5PX 0.00000 0.00000 0.00000 0.00000 0.05339
6 5PY 0.00000 0.00000 0.00000 0.00000 0.00000
7 5PZ 0.00306 -0.00027 0.00026 0.01896 0.00000
8 6PX 0.00000 0.00000 0.00000 0.00000 0.07084
9 6PY 0.00000 0.00000 0.00000 0.00000 0.00000
10 6PZ -0.00710 0.02079 0.00554 0.03468 0.00000
11 7PX 0.00000 0.00000 0.00000 0.00000 0.03946
12 7PY 0.00000 0.00000 0.00000 0.00000 0.00000
13 7PZ -0.01341 0.03116 0.00792 0.02747 0.00000
14 8D 0 -0.00174 0.00475 0.00119 0.00080 0.00000
15 8D+1 0.00000 0.00000 0.00000 0.00000 -0.00466
16 8D-1 0.00000 0.00000 0.00000 0.00000 0.00000
17 8D+2 0.00000 0.00000 0.00000 0.00000 0.00000
18 8D-2 0.00000 0.00000 0.00000 0.00000 0.00000
19 9D 0 0.00021 0.00038 0.00009 -0.00154 0.00000
20 9D+1 0.00000 0.00000 0.00000 0.00000 -0.00607
21 9D-1 0.00000 0.00000 0.00000 0.00000 0.00000
22 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
23 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
24 10F 0 0.00052 -0.00180 -0.00045 -0.00023 0.00000
25 10F+1 0.00000 0.00000 0.00000 0.00000 0.00237
26 10F-1 0.00000 0.00000 0.00000 0.00000 0.00000
27 10F+2 0.00000 0.00000 0.00000 0.00000 0.00000
28 10F-2 0.00000 0.00000 0.00000 0.00000 0.00000
29 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
30 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
31 2 C 1S 0.00710 -0.00926 -0.00187 0.01687 0.00000
32 2S -0.00926 -0.00294 -0.00192 -0.07074 0.00000
33 3S -0.00187 -0.00192 -0.00078 -0.01876 0.00000
34 4S 0.01687 -0.07074 -0.01876 -0.08011 0.00000
35 5PX 0.00000 0.00000 0.00000 0.00000 0.05339
36 5PY 0.00000 0.00000 0.00000 0.00000 0.00000
37 5PZ -0.02964 0.07297 0.01839 0.04156 0.00000
38 6PX 0.00000 0.00000 0.00000 0.00000 0.07084
39 6PY 0.00000 0.00000 0.00000 0.00000 0.00000
40 6PZ -0.03578 0.08726 0.02204 0.05520 0.00000
41 7PX 0.00000 0.00000 0.00000 0.00000 0.03946
42 7PY 0.00000 0.00000 0.00000 0.00000 0.00000
43 7PZ -0.01597 0.03716 0.00942 0.02932 0.00000
44 8D 0 -0.00348 0.00732 0.00181 0.00292 0.00000
45 8D+1 0.00000 0.00000 0.00000 0.00000 0.00466
46 8D-1 0.00000 0.00000 0.00000 0.00000 0.00000
47 8D+2 0.00000 0.00000 0.00000 0.00000 0.00000
48 8D-2 0.00000 0.00000 0.00000 0.00000 0.00000
49 9D 0 -0.00334 0.00674 0.00167 0.00373 0.00000
50 9D+1 0.00000 0.00000 0.00000 0.00000 0.00607
51 9D-1 0.00000 0.00000 0.00000 0.00000 0.00000
52 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
53 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
54 10F 0 -0.00148 0.00305 0.00075 0.00126 0.00000
55 10F+1 0.00000 0.00000 0.00000 0.00000 0.00237
56 10F-1 0.00000 0.00000 0.00000 0.00000 0.00000
57 10F+2 0.00000 0.00000 0.00000 0.00000 0.00000
58 10F-2 0.00000 0.00000 0.00000 0.00000 0.00000
59 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
6 7 8 9 10
6 5PY 0.05339
7 5PZ 0.00000 0.02019
8 6PX 0.00000 0.00000 0.09400
9 6PY 0.07084 0.00000 0.00000 0.09400
10 6PZ 0.00000 0.02405 0.00000 0.00000 0.03035
11 7PX 0.00000 0.00000 0.05236 0.00000 0.00000
12 7PY 0.03946 0.00000 0.00000 0.05236 0.00000
13 7PZ 0.00000 0.01015 0.00000 0.00000 0.01460
14 8D 0 0.00000 -0.00204 0.00000 0.00000 -0.00206
15 8D+1 0.00000 0.00000 -0.00619 0.00000 0.00000
16 8D-1 -0.00466 0.00000 0.00000 -0.00619 0.00000
17 8D+2 0.00000 0.00000 0.00000 0.00000 0.00000
18 8D-2 0.00000 0.00000 0.00000 0.00000 0.00000
19 9D 0 0.00000 -0.00186 0.00000 0.00000 -0.00219
20 9D+1 0.00000 0.00000 -0.00805 0.00000 0.00000
21 9D-1 -0.00607 0.00000 0.00000 -0.00805 0.00000
22 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
23 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
24 10F 0 0.00000 0.00085 0.00000 0.00000 0.00087
25 10F+1 0.00000 0.00000 0.00315 0.00000 0.00000
26 10F-1 0.00237 0.00000 0.00000 0.00315 0.00000
27 10F+2 0.00000 0.00000 0.00000 0.00000 0.00000
28 10F-2 0.00000 0.00000 0.00000 0.00000 0.00000
29 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
30 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
31 2 C 1S 0.00000 0.02964 0.00000 0.00000 0.03578
32 2S 0.00000 -0.07297 0.00000 0.00000 -0.08726
33 3S 0.00000 -0.01839 0.00000 0.00000 -0.02204
34 4S 0.00000 -0.04156 0.00000 0.00000 -0.05520
35 5PX 0.00000 0.00000 0.07084 0.00000 0.00000
36 5PY 0.05339 0.00000 0.00000 0.07084 0.00000
37 5PZ 0.00000 -0.00038 0.00000 0.00000 0.00539
38 6PX 0.00000 0.00000 0.09400 0.00000 0.00000
39 6PY 0.07084 0.00000 0.00000 0.09400 0.00000
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1 1 C 1S 1.00317
2 2S -0.11405 0.26384
3 3S 0.01210 0.06622 0.01836
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34 4S 0.00000 0.00000 0.00000 0.00373 0.00000
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51 9D-1 -0.00053 0.00000 0.00000 0.00000 0.00000
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31 2 C 1S 0.00000 0.00000 0.00000 0.00148 0.00000
32 2S 0.00000 0.00000 0.00000 -0.00305 0.00000
33 3S 0.00000 0.00000 0.00000 -0.00075 0.00000
34 4S 0.00000 0.00000 0.00000 -0.00126 0.00000
35 5PX 0.00000 0.00000 0.00000 0.00000 0.00237
36 5PY -0.00607 0.00000 0.00000 0.00000 0.00000
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39 6PY -0.00805 0.00000 0.00000 0.00000 0.00000
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42 7PY -0.00449 0.00000 0.00000 0.00000 0.00000
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45 8D+1 0.00000 0.00000 0.00000 0.00000 0.00021
46 8D-1 -0.00053 0.00000 0.00000 0.00000 0.00000
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50 9D+1 0.00000 0.00000 0.00000 0.00000 0.00027
51 9D-1 -0.00069 0.00000 0.00000 0.00000 0.00000
52 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
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55 10F+1 0.00000 0.00000 0.00000 0.00000 0.00011
56 10F-1 -0.00027 0.00000 0.00000 0.00000 0.00000
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60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
26 27 28 29 30
26 10F-1 0.00011
27 10F+2 0.00000 0.00000
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32 2S 0.00000 0.00000 0.00000 0.00000 0.00000
33 3S 0.00000 0.00000 0.00000 0.00000 0.00000
34 4S 0.00000 0.00000 0.00000 0.00000 0.00000
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51 9D-1 0.00027 0.00000 0.00000 0.00000 0.00000
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31 32 33 34 35
31 2 C 1S 1.00317
32 2S -0.11405 0.26384
33 3S 0.01210 0.06622 0.01836
34 4S -0.05040 0.15121 0.03878 0.10496
35 5PX 0.00000 0.00000 0.00000 0.00000 0.05339
36 5PY 0.00000 0.00000 0.00000 0.00000 0.00000
37 5PZ -0.00306 0.00027 -0.00026 -0.01896 0.00000
38 6PX 0.00000 0.00000 0.00000 0.00000 0.07084
39 6PY 0.00000 0.00000 0.00000 0.00000 0.00000
40 6PZ 0.00710 -0.02079 -0.00554 -0.03468 0.00000
41 7PX 0.00000 0.00000 0.00000 0.00000 0.03946
42 7PY 0.00000 0.00000 0.00000 0.00000 0.00000
43 7PZ 0.01341 -0.03116 -0.00792 -0.02747 0.00000
44 8D 0 -0.00174 0.00475 0.00119 0.00080 0.00000
45 8D+1 0.00000 0.00000 0.00000 0.00000 0.00466
46 8D-1 0.00000 0.00000 0.00000 0.00000 0.00000
47 8D+2 0.00000 0.00000 0.00000 0.00000 0.00000
48 8D-2 0.00000 0.00000 0.00000 0.00000 0.00000
49 9D 0 0.00021 0.00038 0.00009 -0.00154 0.00000
50 9D+1 0.00000 0.00000 0.00000 0.00000 0.00607
51 9D-1 0.00000 0.00000 0.00000 0.00000 0.00000
52 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
53 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
54 10F 0 -0.00052 0.00180 0.00045 0.00023 0.00000
55 10F+1 0.00000 0.00000 0.00000 0.00000 0.00237
56 10F-1 0.00000 0.00000 0.00000 0.00000 0.00000
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60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
36 37 38 39 40
36 5PY 0.05339
37 5PZ 0.00000 0.02019
38 6PX 0.00000 0.00000 0.09400
39 6PY 0.07084 0.00000 0.00000 0.09400
40 6PZ 0.00000 0.02405 0.00000 0.00000 0.03035
41 7PX 0.00000 0.00000 0.05236 0.00000 0.00000
42 7PY 0.03946 0.00000 0.00000 0.05236 0.00000
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45 8D+1 0.00000 0.00000 0.00619 0.00000 0.00000
46 8D-1 0.00466 0.00000 0.00000 0.00619 0.00000
47 8D+2 0.00000 0.00000 0.00000 0.00000 0.00000
48 8D-2 0.00000 0.00000 0.00000 0.00000 0.00000
49 9D 0 0.00000 0.00186 0.00000 0.00000 0.00219
50 9D+1 0.00000 0.00000 0.00805 0.00000 0.00000
51 9D-1 0.00607 0.00000 0.00000 0.00805 0.00000
52 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
53 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
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60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
41 42 43 44 45
41 7PX 0.02916
42 7PY 0.00000 0.02916
43 7PZ 0.00000 0.00000 0.00882
44 8D 0 0.00000 0.00000 0.00047 0.00029
45 8D+1 0.00345 0.00000 0.00000 0.00000 0.00041
46 8D-1 0.00000 0.00345 0.00000 0.00000 0.00000
47 8D+2 0.00000 0.00000 0.00000 0.00000 0.00000
48 8D-2 0.00000 0.00000 0.00000 0.00000 0.00000
49 9D 0 0.00000 0.00000 0.00090 0.00020 0.00000
50 9D+1 0.00449 0.00000 0.00000 0.00000 0.00053
51 9D-1 0.00000 0.00449 0.00000 0.00000 0.00000
52 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
53 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
54 10F 0 0.00000 0.00000 0.00022 0.00012 0.00000
55 10F+1 0.00175 0.00000 0.00000 0.00000 0.00021
56 10F-1 0.00000 0.00175 0.00000 0.00000 0.00000
57 10F+2 0.00000 0.00000 0.00000 0.00000 0.00000
58 10F-2 0.00000 0.00000 0.00000 0.00000 0.00000
59 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
46 47 48 49 50
46 8D-1 0.00041
47 8D+2 0.00000 0.00000
48 8D-2 0.00000 0.00000 0.00000
49 9D 0 0.00000 0.00000 0.00000 0.00017
50 9D+1 0.00000 0.00000 0.00000 0.00000 0.00069
51 9D-1 0.00053 0.00000 0.00000 0.00000 0.00000
52 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
53 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
54 10F 0 0.00000 0.00000 0.00000 0.00008 0.00000
55 10F+1 0.00000 0.00000 0.00000 0.00000 0.00027
56 10F-1 0.00021 0.00000 0.00000 0.00000 0.00000
57 10F+2 0.00000 0.00000 0.00000 0.00000 0.00000
58 10F-2 0.00000 0.00000 0.00000 0.00000 0.00000
59 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
51 52 53 54 55
51 9D-1 0.00069
52 9D+2 0.00000 0.00000
53 9D-2 0.00000 0.00000 0.00000
54 10F 0 0.00000 0.00000 0.00000 0.00005
55 10F+1 0.00000 0.00000 0.00000 0.00000 0.00011
56 10F-1 0.00027 0.00000 0.00000 0.00000 0.00000
57 10F+2 0.00000 0.00000 0.00000 0.00000 0.00000
58 10F-2 0.00000 0.00000 0.00000 0.00000 0.00000
59 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
56 57 58 59 60
56 10F-1 0.00011
57 10F+2 0.00000 0.00000
58 10F-2 0.00000 0.00000 0.00000
59 10F+3 0.00000 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
Full Mulliken population analysis:
1 2 3 4 5
1 1 C 1S 2.00635
2 2S -0.02357 0.52769
3 3S 0.01251 0.10132 0.03672
4 4S -0.01487 0.25248 0.04156 0.20991
5 5PX 0.00000 0.00000 0.00000 0.00000 0.10678
6 5PY 0.00000 0.00000 0.00000 0.00000 0.00000
7 5PZ 0.00000 0.00000 0.00000 0.00000 0.00000
8 6PX 0.00000 0.00000 0.00000 0.00000 0.08665
9 6PY 0.00000 0.00000 0.00000 0.00000 0.00000
10 6PZ 0.00000 0.00000 0.00000 0.00000 0.00000
11 7PX 0.00000 0.00000 0.00000 0.00000 0.01751
12 7PY 0.00000 0.00000 0.00000 0.00000 0.00000
13 7PZ 0.00000 0.00000 0.00000 0.00000 0.00000
14 8D 0 0.00000 0.00000 0.00000 0.00000 0.00000
15 8D+1 0.00000 0.00000 0.00000 0.00000 0.00000
16 8D-1 0.00000 0.00000 0.00000 0.00000 0.00000
17 8D+2 0.00000 0.00000 0.00000 0.00000 0.00000
18 8D-2 0.00000 0.00000 0.00000 0.00000 0.00000
19 9D 0 0.00000 0.00000 0.00000 0.00000 0.00000
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22 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
23 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
24 10F 0 0.00000 0.00000 0.00000 0.00000 0.00000
25 10F+1 0.00000 0.00000 0.00000 0.00000 0.00000
26 10F-1 0.00000 0.00000 0.00000 0.00000 0.00000
27 10F+2 0.00000 0.00000 0.00000 0.00000 0.00000
28 10F-2 0.00000 0.00000 0.00000 0.00000 0.00000
29 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
30 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
31 2 C 1S 0.00000 -0.00092 -0.00003 0.00250 0.00000
32 2S -0.00092 -0.00229 -0.00084 -0.07056 0.00000
33 3S -0.00003 -0.00084 -0.00013 -0.01081 0.00000
34 4S 0.00250 -0.07056 -0.01081 -0.11243 0.00000
35 5PX 0.00000 0.00000 0.00000 0.00000 0.00276
36 5PY 0.00000 0.00000 0.00000 0.00000 0.00000
37 5PZ -0.00059 0.02685 0.00397 0.00869 0.00000
38 6PX 0.00000 0.00000 0.00000 0.00000 0.01703
39 6PY 0.00000 0.00000 0.00000 0.00000 0.00000
40 6PZ -0.00845 0.08806 0.01784 0.03833 0.00000
41 7PX 0.00000 0.00000 0.00000 0.00000 0.00953
42 7PY 0.00000 0.00000 0.00000 0.00000 0.00000
43 7PZ -0.00375 0.04486 0.00780 0.03497 0.00000
44 8D 0 -0.00026 0.00223 0.00067 0.00023 0.00000
45 8D+1 0.00000 0.00000 0.00000 0.00000 0.00087
46 8D-1 0.00000 0.00000 0.00000 0.00000 0.00000
47 8D+2 0.00000 0.00000 0.00000 0.00000 0.00000
48 8D-2 0.00000 0.00000 0.00000 0.00000 0.00000
49 9D 0 -0.00126 0.00571 0.00166 0.00130 0.00000
50 9D+1 0.00000 0.00000 0.00000 0.00000 0.00338
51 9D-1 0.00000 0.00000 0.00000 0.00000 0.00000
52 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
53 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
54 10F 0 -0.00042 0.00064 0.00044 0.00004 0.00000
55 10F+1 0.00000 0.00000 0.00000 0.00000 0.00122
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34 4S 0.00000 0.00000 0.00000 0.00130 0.00000
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21 9D-1 0.00138
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30 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
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33 3S 0.00000 0.00000 0.00000 0.00044 0.00000
34 4S 0.00000 0.00000 0.00000 0.00004 0.00000
35 5PX 0.00000 0.00000 0.00000 0.00000 0.00122
36 5PY 0.00338 0.00000 0.00000 0.00000 0.00000
37 5PZ 0.00000 0.00000 0.00000 0.00025 0.00000
38 6PX 0.00000 0.00000 0.00000 0.00000 0.00159
39 6PY 0.00885 0.00000 0.00000 0.00000 0.00000
40 6PZ 0.00000 0.00000 0.00000 -0.00001 0.00000
41 7PX 0.00000 0.00000 0.00000 0.00000 0.00015
42 7PY 0.00305 0.00000 0.00000 0.00000 0.00000
43 7PZ 0.00000 0.00000 0.00000 0.00001 0.00000
44 8D 0 0.00000 0.00000 0.00000 0.00002 0.00000
45 8D+1 0.00000 0.00000 0.00000 0.00000 0.00015
46 8D-1 0.00025 0.00000 0.00000 0.00000 0.00000
47 8D+2 0.00000 0.00000 0.00000 0.00000 0.00000
48 8D-2 0.00000 0.00000 0.00000 0.00000 0.00000
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50 9D+1 0.00000 0.00000 0.00000 0.00000 0.00004
51 9D-1 0.00043 0.00000 0.00000 0.00000 0.00000
52 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
53 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
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58 10F-2 0.00000 0.00000 0.00000 0.00000 0.00000
59 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
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26 10F-1 0.00021
27 10F+2 0.00000 0.00000
28 10F-2 0.00000 0.00000 0.00000
29 10F+3 0.00000 0.00000 0.00000 0.00000
30 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
31 2 C 1S 0.00000 0.00000 0.00000 0.00000 0.00000
32 2S 0.00000 0.00000 0.00000 0.00000 0.00000
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34 4S 0.00000 0.00000 0.00000 0.00000 0.00000
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59 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
31 32 33 34 35
31 2 C 1S 2.00635
32 2S -0.02357 0.52769
33 3S 0.01251 0.10132 0.03672
34 4S -0.01487 0.25248 0.04156 0.20991
35 5PX 0.00000 0.00000 0.00000 0.00000 0.10678
36 5PY 0.00000 0.00000 0.00000 0.00000 0.00000
37 5PZ 0.00000 0.00000 0.00000 0.00000 0.00000
38 6PX 0.00000 0.00000 0.00000 0.00000 0.08665
39 6PY 0.00000 0.00000 0.00000 0.00000 0.00000
40 6PZ 0.00000 0.00000 0.00000 0.00000 0.00000
41 7PX 0.00000 0.00000 0.00000 0.00000 0.01751
42 7PY 0.00000 0.00000 0.00000 0.00000 0.00000
43 7PZ 0.00000 0.00000 0.00000 0.00000 0.00000
44 8D 0 0.00000 0.00000 0.00000 0.00000 0.00000
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46 8D-1 0.00000 0.00000 0.00000 0.00000 0.00000
47 8D+2 0.00000 0.00000 0.00000 0.00000 0.00000
48 8D-2 0.00000 0.00000 0.00000 0.00000 0.00000
49 9D 0 0.00000 0.00000 0.00000 0.00000 0.00000
50 9D+1 0.00000 0.00000 0.00000 0.00000 0.00000
51 9D-1 0.00000 0.00000 0.00000 0.00000 0.00000
52 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
53 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
54 10F 0 0.00000 0.00000 0.00000 0.00000 0.00000
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56 10F-1 0.00000 0.00000 0.00000 0.00000 0.00000
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59 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
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36 5PY 0.10678
37 5PZ 0.00000 0.04038
38 6PX 0.00000 0.00000 0.18800
39 6PY 0.08665 0.00000 0.00000 0.18800
40 6PZ 0.00000 0.02942 0.00000 0.00000 0.06070
41 7PX 0.00000 0.00000 0.07063 0.00000 0.00000
42 7PY 0.01751 0.00000 0.00000 0.07063 0.00000
43 7PZ 0.00000 0.00450 0.00000 0.00000 0.01969
44 8D 0 0.00000 0.00000 0.00000 0.00000 0.00000
45 8D+1 0.00000 0.00000 0.00000 0.00000 0.00000
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60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
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41 7PX 0.05833
42 7PY 0.00000 0.05833
43 7PZ 0.00000 0.00000 0.01764
44 8D 0 0.00000 0.00000 0.00000 0.00058
45 8D+1 0.00000 0.00000 0.00000 0.00000 0.00081
46 8D-1 0.00000 0.00000 0.00000 0.00000 0.00000
47 8D+2 0.00000 0.00000 0.00000 0.00000 0.00000
48 8D-2 0.00000 0.00000 0.00000 0.00000 0.00000
49 9D 0 0.00000 0.00000 0.00000 0.00021 0.00000
50 9D+1 0.00000 0.00000 0.00000 0.00000 0.00056
51 9D-1 0.00000 0.00000 0.00000 0.00000 0.00000
52 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
53 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
54 10F 0 0.00000 0.00000 0.00000 0.00000 0.00000
55 10F+1 0.00000 0.00000 0.00000 0.00000 0.00000
56 10F-1 0.00000 0.00000 0.00000 0.00000 0.00000
57 10F+2 0.00000 0.00000 0.00000 0.00000 0.00000
58 10F-2 0.00000 0.00000 0.00000 0.00000 0.00000
59 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
46 47 48 49 50
46 8D-1 0.00081
47 8D+2 0.00000 0.00000
48 8D-2 0.00000 0.00000 0.00000
49 9D 0 0.00000 0.00000 0.00000 0.00035
50 9D+1 0.00000 0.00000 0.00000 0.00000 0.00138
51 9D-1 0.00056 0.00000 0.00000 0.00000 0.00000
52 9D+2 0.00000 0.00000 0.00000 0.00000 0.00000
53 9D-2 0.00000 0.00000 0.00000 0.00000 0.00000
54 10F 0 0.00000 0.00000 0.00000 0.00000 0.00000
55 10F+1 0.00000 0.00000 0.00000 0.00000 0.00000
56 10F-1 0.00000 0.00000 0.00000 0.00000 0.00000
57 10F+2 0.00000 0.00000 0.00000 0.00000 0.00000
58 10F-2 0.00000 0.00000 0.00000 0.00000 0.00000
59 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
51 52 53 54 55
51 9D-1 0.00138
52 9D+2 0.00000 0.00000
53 9D-2 0.00000 0.00000 0.00000
54 10F 0 0.00000 0.00000 0.00000 0.00010
55 10F+1 0.00000 0.00000 0.00000 0.00000 0.00021
56 10F-1 0.00000 0.00000 0.00000 0.00000 0.00000
57 10F+2 0.00000 0.00000 0.00000 0.00000 0.00000
58 10F-2 0.00000 0.00000 0.00000 0.00000 0.00000
59 10F+3 0.00000 0.00000 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
56 57 58 59 60
56 10F-1 0.00021
57 10F+2 0.00000 0.00000
58 10F-2 0.00000 0.00000 0.00000
59 10F+3 0.00000 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.00000 0.00000 0.00000
Gross orbital populations:
Total Alpha Beta Spin
1 1 C 1S 1.96723 0.98361 0.98361 0.00000
2 2S 0.95166 0.47583 0.47583 0.00000
3 3S 0.21268 0.10634 0.10634 0.00000
4 4S 0.38134 0.19067 0.19067 0.00000
5 5PX 0.24574 0.12287 0.12287 0.00000
6 5PY 0.24574 0.12287 0.12287 0.00000
7 5PZ 0.11092 0.05546 0.05546 0.00000
8 6PX 0.48313 0.24156 0.24156 0.00000
9 6PY 0.48313 0.24156 0.24156 0.00000
10 6PZ 0.23245 0.11622 0.11622 0.00000
11 7PX 0.24407 0.12203 0.12203 0.00000
12 7PY 0.24407 0.12203 0.12203 0.00000
13 7PZ 0.12959 0.06480 0.06480 0.00000
14 8D 0 0.00473 0.00236 0.00236 0.00000
15 8D+1 0.00572 0.00286 0.00286 0.00000
16 8D-1 0.00572 0.00286 0.00286 0.00000
17 8D+2 0.00000 0.00000 0.00000 0.00000
18 8D-2 0.00000 0.00000 0.00000 0.00000
19 9D 0 0.00831 0.00416 0.00416 0.00000
20 9D+1 0.01794 0.00897 0.00897 0.00000
21 9D-1 0.01794 0.00897 0.00897 0.00000
22 9D+2 0.00000 0.00000 0.00000 0.00000
23 9D-2 0.00000 0.00000 0.00000 0.00000
24 10F 0 0.00108 0.00054 0.00054 0.00000
25 10F+1 0.00340 0.00170 0.00170 0.00000
26 10F-1 0.00340 0.00170 0.00170 0.00000
27 10F+2 0.00000 0.00000 0.00000 0.00000
28 10F-2 0.00000 0.00000 0.00000 0.00000
29 10F+3 0.00000 0.00000 0.00000 0.00000
30 10F-3 0.00000 0.00000 0.00000 0.00000
31 2 C 1S 1.96723 0.98361 0.98361 0.00000
32 2S 0.95166 0.47583 0.47583 0.00000
33 3S 0.21268 0.10634 0.10634 0.00000
34 4S 0.38134 0.19067 0.19067 0.00000
35 5PX 0.24574 0.12287 0.12287 0.00000
36 5PY 0.24574 0.12287 0.12287 0.00000
37 5PZ 0.11092 0.05546 0.05546 0.00000
38 6PX 0.48313 0.24156 0.24156 0.00000
39 6PY 0.48313 0.24156 0.24156 0.00000
40 6PZ 0.23245 0.11622 0.11622 0.00000
41 7PX 0.24407 0.12203 0.12203 0.00000
42 7PY 0.24407 0.12203 0.12203 0.00000
43 7PZ 0.12959 0.06480 0.06480 0.00000
44 8D 0 0.00473 0.00236 0.00236 0.00000
45 8D+1 0.00572 0.00286 0.00286 0.00000
46 8D-1 0.00572 0.00286 0.00286 0.00000
47 8D+2 0.00000 0.00000 0.00000 0.00000
48 8D-2 0.00000 0.00000 0.00000 0.00000
49 9D 0 0.00831 0.00416 0.00416 0.00000
50 9D+1 0.01794 0.00897 0.00897 0.00000
51 9D-1 0.01794 0.00897 0.00897 0.00000
52 9D+2 0.00000 0.00000 0.00000 0.00000
53 9D-2 0.00000 0.00000 0.00000 0.00000
54 10F 0 0.00108 0.00054 0.00054 0.00000
55 10F+1 0.00340 0.00170 0.00170 0.00000
56 10F-1 0.00340 0.00170 0.00170 0.00000
57 10F+2 0.00000 0.00000 0.00000 0.00000
58 10F-2 0.00000 0.00000 0.00000 0.00000
59 10F+3 0.00000 0.00000 0.00000 0.00000
60 10F-3 0.00000 0.00000 0.00000 0.00000
Condensed to atoms (all electrons):
1 2
1 C 5.159389 0.840611
2 C 0.840611 5.159389
Atomic-Atomic Spin Densities.
1 2
1 C 0.000000 0.000000
2 C 0.000000 0.000000
Mulliken charges and spin densities:
1 2
1 C 0.000000 0.000000
2 C 0.000000 0.000000
Sum of Mulliken charges = 0.00000 0.00000
Mulliken charges and spin densities with hydrogens summed into heavy atoms:
1 2
1 C 0.000000 0.000000
2 C 0.000000 0.000000
Electronic spatial extent (au): <R**2>= 41.8067
Charge= 0.0000 electrons
Dipole moment (field-independent basis, Debye):
X= 0.0000 Y= 0.0000 Z= 0.0000 Tot= 0.0000
Quadrupole moment (field-independent basis, Debye-Ang):
XX= -12.5624 YY= -12.5624 ZZ= -8.8609
XY= 0.0000 XZ= 0.0000 YZ= 0.0000
Traceless Quadrupole moment (field-independent basis, Debye-Ang):
XX= -1.2338 YY= -1.2338 ZZ= 2.4677
XY= 0.0000 XZ= 0.0000 YZ= 0.0000
Octapole moment (field-independent basis, Debye-Ang**2):
XXX= 0.0000 YYY= 0.0000 ZZZ= 0.0000 XYY= 0.0000
XXY= 0.0000 XXZ= 0.0000 XZZ= 0.0000 YZZ= 0.0000
YYZ= 0.0000 XYZ= 0.0000
Hexadecapole moment (field-independent basis, Debye-Ang**3):
XXXX= -15.0315 YYYY= -15.0315 ZZZZ= -33.7237 XXXY= 0.0000
XXXZ= 0.0000 YYYX= 0.0000 YYYZ= 0.0000 ZZZX= 0.0000
ZZZY= 0.0000 XXYY= -5.0105 XXZZ= -8.6199 YYZZ= -8.6199
XXYZ= 0.0000 YYXZ= 0.0000 ZZXY= 0.0000
N-N= 1.533229739174D+01 E-N=-2.064544707995D+02 KE= 7.540426753541D+01
Symmetry AG KE= 3.568844857150D+01
Symmetry B1G KE= 3.543682392530D-34
Symmetry B2G KE= 3.880097713704D-31
Symmetry B3G KE=-8.771583596441D-20
Symmetry AU KE= 3.161918548221D-33
Symmetry B1U KE= 3.520388661222D+01
Symmetry B2U KE= 2.255966175841D+00
Symmetry B3U KE= 2.255966175841D+00
Orbital energies and kinetic energies (alpha):
1 2
1 (SGG)--O -11.359670 16.028606
2 (SGU)--O -11.357370 16.056551
3 (SGG)--O -1.060718 1.815618
4 (SGU)--O -0.516695 1.545393
5 (PIU)--O -0.457095 1.127983
6 (PIU)--O -0.457095 1.127983
7 (SGG)--V -0.111535 1.201665
8 (PIG)--V 0.152075 1.010274
9 (PIG)--V 0.152075 1.010274
10 (SGU)--V 0.272686 0.571684
11 (SGG)--V 0.405168 0.865903
12 (PIU)--V 0.414968 0.841953
13 (PIU)--V 0.414968 0.841953
14 (SGG)--V 0.513505 1.233885
15 (PIG)--V 0.541182 1.365981
16 (PIG)--V 0.541182 1.365981
17 (SGU)--V 0.712022 1.249058
18 (DLTG)--V 0.751245 1.021972
19 (DLTG)--V 0.751245 1.021972
20 (SGU)--V 0.852146 2.139757
21 (PIU)--V 0.969342 1.321173
22 (PIU)--V 0.969342 1.321173
23 (DLTU)--V 1.072623 1.286612
24 (DLTU)--V 1.072623 1.286612
25 (PIG)--V 1.333246 1.795867
26 (PIG)--V 1.333246 1.795867
27 (SGG)--V 1.343605 1.954211
28 (SGU)--V 1.690551 3.885464
29 (PIU)--V 2.258747 4.879009
30 (PIU)--V 2.258747 4.879009
31 (SGG)--V 2.375375 3.866149
32 (PIG)--V 2.543395 5.063236
33 (PIG)--V 2.543395 5.063236
34 (SGU)--V 2.638017 5.621136
35 (DLTG)--V 2.723852 3.325627
36 (DLTG)--V 2.723852 3.325627
37 (PHIU)--V 2.795747 3.249987
38 (PHIU)--V 2.795747 3.249987
39 (PIU)--V 2.812768 4.056583
40 (PIU)--V 2.812768 4.056583
41 (SGG)--V 3.054078 4.858976
42 (PHIG)--V 3.187864 3.647845
43 (PHIG)--V 3.187864 3.647845
44 (DLTG)--V 3.264271 4.357629
45 (DLTG)--V 3.264271 4.357629
46 (PIG)--V 3.279222 4.225215
47 (PIG)--V 3.279222 4.225215
48 (DLTU)--V 3.349421 4.463931
49 (DLTU)--V 3.349421 4.463931
50 (SGU)--V 3.591218 4.319961
51 (PIU)--V 3.779630 4.605413
52 (PIU)--V 3.779630 4.605413
53 (DLTU)--V 3.835229 4.428043
54 (DLTU)--V 3.835229 4.428043
55 (SGG)--V 3.961323 9.280481
56 (SGU)--V 4.386953 7.453291
57 (PIG)--V 4.968534 6.073685
58 (PIG)--V 4.968534 6.073685
59 (SGG)--V 5.259760 11.479782
60 (SGU)--V 13.253755 30.862832
Total kinetic energy from orbitals= 7.540426753541D+01
Isotropic Fermi Contact Couplings
Atom a.u. MegaHertz Gauss 10(-4) cm-1
1 C(13) 0.00000 0.00000 0.00000 0.00000
2 C(13) 0.00000 0.00000 0.00000 0.00000
--------------------------------------------------------
Center ---- Spin Dipole Couplings ----
3XX-RR 3YY-RR 3ZZ-RR
--------------------------------------------------------
1 Atom 0.000000 0.000000 0.000000
2 Atom 0.000000 0.000000 0.000000
--------------------------------------------------------
XY XZ YZ
--------------------------------------------------------
1 Atom 0.000000 0.000000 0.000000
2 Atom 0.000000 0.000000 0.000000
--------------------------------------------------------
---------------------------------------------------------------------------------
Anisotropic Spin Dipole Couplings in Principal Axis System
---------------------------------------------------------------------------------
Atom a.u. MegaHertz Gauss 10(-4) cm-1 Axes
Baa 0.0000 0.000 0.000 0.000 1.0000 0.0000 0.0000
1 C(13) Bbb 0.0000 0.000 0.000 0.000 0.0000 1.0000 0.0000
Bcc 0.0000 0.000 0.000 0.000 0.0000 0.0000 1.0000
Baa 0.0000 0.000 0.000 0.000 1.0000 0.0000 0.0000
2 C(13) Bbb 0.0000 0.000 0.000 0.000 0.0000 1.0000 0.0000
Bcc 0.0000 0.000 0.000 0.000 0.0000 0.0000 1.0000
---------------------------------------------------------------------------------
No NMR shielding tensors so no spin-rotation constants.
Leave Link 601 at Mon Apr 1 18:09:41 2019, MaxMem= 33554432 cpu: 0.2
(Enter /share/apps/gaussian/g09d01/nehalem/g09/l9999.exe)
1\1\GINC-COMPUTE-40-0\SP\ROCCSD(T)-FC\CC-pVTZ\C2\LOOS\01-Apr-2019\0\\#
p ROCCSD(T) cc-pVTZ pop=full gfprint\\G2\\0,1\C\C,1,1.2425\\Version=ES
64L-G09RevD.01\State=1-SGG\HF=-75.4014465\MP2=-75.75656\MP3=-75.719265
2\PUHF=-75.4014465\PMP2-0=-75.75656\MP4SDQ=-75.7542408\CCSD=-75.749550
6\CCSD(T)=-75.7830694\RMSD=7.799e-09\PG=D*H [C*(C1.C1)]\\@
ERWIN WITH HIS PSI CAN DO
CALCULATIONS QUITE A FEW.
BUT ONE THING HAS NOT BEEN SEEN
JUST WHAT DOES PSI REALLY MEAN.
-- WALTER HUCKEL, TRANS. BY FELIX BLOCH
Job cpu time: 0 days 0 hours 3 minutes 46.1 seconds.
File lengths (MBytes): RWF= 59 Int= 0 D2E= 0 Chk= 2 Scr= 1
Normal termination of Gaussian 09 at Mon Apr 1 18:09:41 2019.