112 lines
3.6 KiB
TeX
112 lines
3.6 KiB
TeX
\documentclass{standalone}
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%\usepackage[top=3cm,left=0cm,right=0cm,bottom=3cm]{geometry}
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\usepackage{mathtools,physics,bm,xcolor}
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\usepackage{tikz}
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% shadows only for title
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\usetikzlibrary{decorations.pathmorphing,shadows}
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\pagestyle{empty}
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\begin{document}
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% colors
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\definecolor{turquoise}{rgb}{0 0.41 0.41}
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\definecolor{rouge}{rgb}{0.79 0.0 0.1}
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\definecolor{vert}{rgb}{0.15 0.4 0.1}
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\definecolor{mauve}{rgb}{0.6 0.4 0.8}
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\definecolor{violet}{rgb}{0.58 0. 0.41}
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\definecolor{orange}{rgb}{0.8 0.4 0.2}
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\definecolor{bleu}{rgb}{0.39, 0.58, 0.93}
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\begin{center}
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\begin{tikzpicture}
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% styles
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\tikzstyle{elec} = [line width=2pt,draw=black!80]
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\tikzstyle{vib} = [thick,draw=black!30]
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\tikzstyle{trans} = [line width=2pt,->]
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\tikzstyle{transCI} = [trans,dashed,draw=vert]
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\tikzstyle{transCS} = [trans,dashed,draw=violet]
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\tikzstyle{relax} = [draw=orange,ultra thick,decorate,decoration=snake]
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\tikzstyle{rv} = [rotate=90,text=orange,pos=0.5,yshift=3mm]
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% fondamental
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\path[elec] (0,0) -- ++ (14,0)
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node[below,pos=0.5,yshift=-1mm] {\large Ground state $S_0$};
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\path[vib] (0,0.2) -- ++ (14,0);
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\path[vib] (0,0.4) -- ++ (13,0);
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\foreach \i in {1,2,...,30} {
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\path[vib] (0,0.4 + \i*0.2) -- ++ ({2 + 10*exp(-0.2*\i)},0);
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}
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% T1
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\path[elec] (11,4) -- ++ (3,0) node[anchor=south west] {\large $T_1$};
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\foreach \i in {1,2,...,6} {
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\path[vib] (11,4 + \i*0.2) -- ++ (3,0);
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}
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% S1
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\path[elec] (4,5) node[anchor=south east] {\large $S_1$} -- ++ (5,0);
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\foreach \i in {1,2,...,6} {
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\path[vib] (4,5 + \i*0.2) -- ++ (5,0);
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}
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\foreach \i in {1,2,...,12} {
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\path[vib] ({7.5 - 1*exp(-0.3*\i)},6.2+\i*0.2) -- (9,6.2+\i*0.2);
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}
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% S2
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\path[elec] (4,8) node[anchor=south east] {\large $S_2$} -- ++ (2,0);
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\foreach \i in {1,2,...,6} {
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\path[vib] (4,8 + \i*0.2) -- ++ (2,0);
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}
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% absorption
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\path[trans,draw=turquoise] (4.5,0) -- ++(0,9)
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node[rotate=90,pos=0.35,text=turquoise,yshift=-3mm] {\large Absorption};
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% fluo
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\path[trans,draw=rouge](7,5) -- ++(0,-4.4)
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node[rotate=90,pos=0.5,text=rouge,yshift=-3mm] {\large Fluorescence};
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% phosphorescence
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\path[trans,draw=mauve] (13,4) -- ++(0,-3.4)
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node[rotate=90,pos=0.5,text=mauve,yshift=-3mm] {\large Phosphorescence};
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% Conversion interne
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\path[transCI] (4,5) -- ++(-1.9,0) node[below,pos=0.5,text=vert] {\large IC};
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\path[transCI] (6,8) -- ++(1.3,0) node[above,pos=0.5,text=vert] {\large IC};
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% Croisement intersysteme
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\path[transCS] (9,5) -- ++(2,0) node[below,pos=0.5,text=violet] {\large ISC};
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\path[transCS] (11,4) -- ++(-2.5,0) node[below,pos=0.5,text=violet] {\large ISC};
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% relaxation vib
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\path[relax] (5.5,8.8) -- ++(0,-0.8) node[rv] {\textbf{VR}};
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\path[relax] (8,8) -- ++(0,-3) node[rv] {\textbf{VR}};
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\path[relax] (1,5) -- ++(0,-5) node[rv] {\textbf{VR}};
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\path[relax] (11.5,5) -- ++(0,-1) node[rv] {\textbf{VR}};
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\end{tikzpicture}
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\end{center}
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\begin{itemize}
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\item[] \tikz {\path[line width=2pt,->,dashed,draw=vert]
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(0,0) -- (1,0) node[above,pos=0.5,text=vert] {IC};} Internal Conversion,
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$S_i\,\longrightarrow\,S_j$ non radiative transition.
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\item[] \tikz {\path[line width=2pt,->,dashed,draw=violet]
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(0,0) -- (1,0) node[above,pos=0.5,text=violet] {ISC};} InterSystem Crossing,
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$S_i\,\longrightarrow\,T_j$ non radiative transition.
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\item[] \tikz {\path[line width=2pt,draw=orange,ultra thick,
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decorate,decoration=snake] (0,0) -- (1,0) node[above,pos=0.5,text=orange] {RV};}
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Vibrationnal Relaxation.
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\end{itemize}
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\end{document} |