Ec/output/CRCC/pyrazine.out

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219 KiB
Plaintext

----- GAMESS execution script 'rungms' -----
This job is running on host compute-1-5.local
under operating system Linux at Mon Jul 26 15:55:27 CEST 2021
SLURM has assigned the following compute nodes to this run:
compute-1-5
Available scratch disk space (Kbyte units) at beginning of the job is
Filesystem 1K-blocks Used Available Use% Mounted on
/dev/sda5 261896396 61468 248508288 1% /state/partition1
GAMESS temporary binary files will be written to /state/partition1/1174824
GAMESS supplementary output files will be written to /state/partition1/1174824
Copying input file pyrazine.inp to your run's scratch directory...
reading your own /home/scemama/.gmsrc
Distributed Data Interface kickoff program.
Initiating 1 compute processes on 1 nodes to run the following command:
/share/apps/common/gamess/gms14/gamess.00.x pyrazine
******************************************************
* GAMESS VERSION = 5 DEC 2014 (R1) *
* FROM IOWA STATE UNIVERSITY *
* M.W.SCHMIDT, K.K.BALDRIDGE, J.A.BOATZ, S.T.ELBERT, *
* M.S.GORDON, J.H.JENSEN, S.KOSEKI, N.MATSUNAGA, *
* K.A.NGUYEN, S.J.SU, T.L.WINDUS, *
* TOGETHER WITH M.DUPUIS, J.A.MONTGOMERY *
* J.COMPUT.CHEM. 14, 1347-1363(1993) *
**************** 64 BIT INTEL VERSION ****************
SINCE 1993, STUDENTS AND POSTDOCS WORKING AT IOWA STATE UNIVERSITY
AND ALSO IN THEIR VARIOUS JOBS AFTER LEAVING ISU HAVE MADE IMPORTANT
CONTRIBUTIONS TO THE CODE:
IVANA ADAMOVIC, CHRISTINE AIKENS, YURI ALEXEEV, POOJA ARORA,
ANDREY ASADCHEV, ROB BELL, PRADIPTA BANDYOPADHYAY, JONATHAN BENTZ,
BRETT BODE, KURT BRORSEN, CALEB CARLIN, GALINA CHABAN, WEI CHEN,
CHEOL HO CHOI, PAUL DAY, ALBERT DEFUSCO, NUWAN DESILVA, TIM DUDLEY,
DMITRI FEDOROV, GRAHAM FLETCHER, MARK FREITAG, KURT GLAESEMANN,
DAN KEMP, GRANT MERRILL, NORIYUKI MINEZAWA, JONATHAN MULLIN,
TAKESHI NAGATA, SEAN NEDD, HEATHER NETZLOFF, BOSILJKA NJEGIC, RYAN OLSON,
MIKE PAK, SPENCER PRUITT, LUKE ROSKOP, JIM SHOEMAKER, LYUDMILA SLIPCHENKO,
TONY SMITH, SAROM SOK, JIE SONG, TETSUYA TAKETSUGU, SIMON WEBB,
PENG XU, SOOHAENG YOO, FEDERICO ZAHARIEV
ADDITIONAL CODE HAS BEEN PROVIDED BY COLLABORATORS IN OTHER GROUPS:
IOWA STATE UNIVERSITY:
JOE IVANIC, AARON WEST, LAIMUTIS BYTAUTAS, KLAUS RUEDENBERG
UNIVERSITY OF TOKYO: KIMIHIKO HIRAO, TAKAHITO NAKAJIMA,
TAKAO TSUNEDA, MUNEAKI KAMIYA, SUSUMU YANAGISAWA,
KIYOSHI YAGI, MAHITO CHIBA, SEIKEN TOKURA, NAOAKI KAWAKAMI
UNIVERSITY OF AARHUS: FRANK JENSEN
UNIVERSITY OF IOWA: VISVALDAS KAIRYS, HUI LI
NATIONAL INST. OF STANDARDS AND TECHNOLOGY: WALT STEVENS, DAVID GARMER
UNIVERSITY OF PISA: BENEDETTA MENNUCCI, JACOPO TOMASI
UNIVERSITY OF MEMPHIS: HENRY KURTZ, PRAKASHAN KORAMBATH
UNIVERSITY OF ALBERTA: TOBY ZENG, MARIUSZ KLOBUKOWSKI
UNIVERSITY OF NEW ENGLAND: MARK SPACKMAN
MIE UNIVERSITY: HIROAKI UMEDA
NAT. INST. OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY: KAZUO KITAURA
MICHIGAN STATE UNIVERSITY:
KAROL KOWALSKI, MARTA WLOCH, JEFFREY GOUR, JESSE LUTZ,
WEI LI, PIOTR PIECUCH
UNIVERSITY OF SILESIA: MONIKA MUSIAL, STANISLAW KUCHARSKI
FACULTES UNIVERSITAIRES NOTRE-DAME DE LA PAIX:
OLIVIER QUINET, BENOIT CHAMPAGNE
UNIVERSITY OF CALIFORNIA - SANTA BARBARA: BERNARD KIRTMAN
INSTITUTE FOR MOLECULAR SCIENCE:
KAZUYA ISHIMURA, MICHIO KATOUDA, AND SHIGERU NAGASE
UNIVERSITY OF NOTRE DAME: ANNA POMOGAEVA, DAN CHIPMAN
KYUSHU UNIVERSITY:
HARUYUKI NAKANO,
FENG LONG GU, JACEK KORCHOWIEC, MARCIN MAKOWSKI, AND YURIKO AOKI,
HIROTOSHI MORI AND EISAKU MIYOSHI
PENNSYLVANIA STATE UNIVERSITY:
TZVETELIN IORDANOV, CHET SWALINA, JONATHAN SKONE,
SHARON HAMMES-SCHIFFER
WASEDA UNIVERSITY:
MASATO KOBAYASHI, TOMOKO AKAMA, TSUGUKI TOUMA,
TAKESHI YOSHIKAWA, YASUHIRO IKABATA, HIROMI NAKAI
NANJING UNIVERSITY: SHUHUA LI
UNIVERSITY OF NEBRASKA:
PEIFENG SU, DEJUN SI, NANDUN THELLAMUREGE, YALI WANG, HUI LI
UNIVERSITY OF ZURICH: ROBERTO PEVERATI, KIM BALDRIDGE
N. COPERNICUS UNIVERSITY AND JACKSON STATE UNIVERSITY:
MARIA BARYSZ
UNIVERSITY OF COPENHAGEN: CASPER STEINMANN
TOKYO INSTITUTE OF TECHNOLOGY: HIROYA NAKATA
NAGOYA UNIVERSITY: YOSHIO NISHIMOTO, STEPHAN IRLE
EXECUTION OF GAMESS BEGUN Mon Jul 26 15:55:28 2021
ECHO OF THE FIRST FEW INPUT CARDS -
INPUT CARD> $CONTRL
INPUT CARD> EXETYP=RUN COORD=UNIQUE UNITS=ANGS
INPUT CARD> RUNTYP=ENERGY SCFTYP=RHF CITYP=NONE CCTYP=CR-CC(Q)
INPUT CARD> MAXIT=100
INPUT CARD> ISPHER=1
INPUT CARD> MULT=1
INPUT CARD> ICHARG=0
INPUT CARD> MPLEVL=0
INPUT CARD> MAXIT=200
INPUT CARD> $END
INPUT CARD>
INPUT CARD> $SYSTEM
INPUT CARD> MEMORY=40000000
INPUT CARD> PARALL=.FALSE.
INPUT CARD> $END
INPUT CARD>
INPUT CARD> $GUESS
INPUT CARD> GUESS=HUCKEL
INPUT CARD> $END
INPUT CARD>
INPUT CARD> $SCF
INPUT CARD> SOSCF=.T.
INPUT CARD> DIIS=.F.
INPUT CARD> NOCONV=.F.
INPUT CARD> SHIFT=.T.
INPUT CARD> DAMP=.T.
INPUT CARD> RSTRCT=.F.
INPUT CARD> $END
INPUT CARD>
INPUT CARD> $BASIS
INPUT CARD> GBASIS=CCD
INPUT CARD> $END
INPUT CARD>
INPUT CARD> $DATA
INPUT CARD>title
INPUT CARD>C1 0
INPUT CARD>C 6.0 0.00000000 1.12814594 0.69592552
INPUT CARD>C 6.0 0.00000000 -1.12814594 0.69592552
INPUT CARD>C 6.0 0.00000000 1.12814594 -0.69592552
INPUT CARD>C 6.0 0.00000000 -1.12814594 -0.69592552
INPUT CARD>N 7.0 0.00000000 0.00000000 1.41089287
INPUT CARD>N 7.0 0.00000000 0.00000000 -1.41089287
INPUT CARD>H 1.0 0.00000000 2.05718388 1.24480592
INPUT CARD>H 1.0 0.00000000 -2.05718388 1.24480592
INPUT CARD>H 1.0 0.00000000 2.05718388 -1.24480592
INPUT CARD>H 1.0 0.00000000 -2.05718388 -1.24480592
INPUT CARD> $END
40000000 WORDS OF MEMORY AVAILABLE
BASIS OPTIONS
-------------
GBASIS=CCD IGAUSS= 0 POLAR=NONE
NDFUNC= 0 NFFUNC= 0 DIFFSP= F
NPFUNC= 0 DIFFS= F BASNAM=
RUN TITLE
---------
title
THE POINT GROUP OF THE MOLECULE IS C1
THE ORDER OF THE PRINCIPAL AXIS IS 0
ATOM ATOMIC COORDINATES (BOHR)
CHARGE X Y Z
C 6.0 0.0000000000 2.1318867008 1.3151085407
C 6.0 0.0000000000 -2.1318867008 1.3151085407
C 6.0 0.0000000000 2.1318867008 -1.3151085407
C 6.0 0.0000000000 -2.1318867008 -1.3151085407
N 7.0 0.0000000000 0.0000000000 2.6662009223
N 7.0 0.0000000000 0.0000000000 -2.6662009223
H 1.0 0.0000000000 3.8875138396 2.3523420967
H 1.0 0.0000000000 -3.8875138396 2.3523420967
H 1.0 0.0000000000 3.8875138396 -2.3523420967
H 1.0 0.0000000000 -3.8875138396 -2.3523420967
INTERNUCLEAR DISTANCES (ANGS.)
------------------------------
1 C 2 C 3 C 4 C 5 N
1 C 0.0000000 2.2562919 * 1.3918510 * 2.6510568 * 1.3356240 *
2 C 2.2562919 * 0.0000000 2.6510568 * 1.3918510 * 1.3356240 *
3 C 1.3918510 * 2.6510568 * 0.0000000 2.2562919 * 2.3898529 *
4 C 2.6510568 * 1.3918510 * 2.2562919 * 0.0000000 2.3898529 *
5 N 1.3356240 * 1.3356240 * 2.3898529 * 2.3898529 * 0.0000000
6 N 2.3898529 * 2.3898529 * 1.3356240 * 1.3356240 * 2.8217857 *
7 H 1.0790650 * 3.2322741 2.1516389 * 3.7299818 2.0638775 *
8 H 3.2322741 1.0790650 * 3.7299818 2.1516389 * 2.0638775 *
9 H 2.1516389 * 3.7299818 1.0790650 * 3.2322741 3.3592769
10 H 3.7299818 2.1516389 * 3.2322741 1.0790650 * 3.3592769
6 N 7 H 8 H 9 H 10 H
1 C 2.3898529 * 1.0790650 * 3.2322741 2.1516389 * 3.7299818
2 C 2.3898529 * 3.2322741 1.0790650 * 3.7299818 2.1516389 *
3 C 1.3356240 * 2.1516389 * 3.7299818 1.0790650 * 3.2322741
4 C 1.3356240 * 3.7299818 2.1516389 * 3.2322741 1.0790650 *
5 N 2.8217857 * 2.0638775 * 2.0638775 * 3.3592769 3.3592769
6 N 0.0000000 3.3592769 3.3592769 2.0638775 * 2.0638775 *
7 H 3.3592769 0.0000000 4.1143678 2.4896118 * 4.8089697
8 H 3.3592769 4.1143678 0.0000000 4.8089697 2.4896118 *
9 H 2.0638775 * 2.4896118 * 4.8089697 0.0000000 4.1143678
10 H 2.0638775 * 4.8089697 2.4896118 * 4.1143678 0.0000000
* ... LESS THAN 3.000
ATOMIC BASIS SET
----------------
THE CONTRACTED PRIMITIVE FUNCTIONS HAVE BEEN UNNORMALIZED
THE CONTRACTED BASIS FUNCTIONS ARE NOW NORMALIZED TO UNITY
SHELL TYPE PRIMITIVE EXPONENT CONTRACTION COEFFICIENT(S)
C
1 S 1 6665.0000000 0.000691583963
1 S 2 1000.0000000 0.005325796153
1 S 3 228.0000000 0.027060721042
1 S 4 64.7100000 0.101656846141
1 S 5 21.0600000 0.274574823617
1 S 6 7.4950000 0.448294318924
1 S 7 2.7970000 0.284902610715
1 S 8 0.5215000 0.015194859206
2 S 9 6665.0000000 -0.000293269653
2 S 10 1000.0000000 -0.002318035474
2 S 11 228.0000000 -0.011499786039
2 S 12 64.7100000 -0.046826727010
2 S 13 21.0600000 -0.128466168750
2 S 14 7.4950000 -0.301266272463
2 S 15 2.7970000 -0.255630702330
2 S 16 0.5215000 1.093793361012
3 S 17 0.1596000 1.000000000000
4 P 18 9.4390000 0.056979251590
4 P 19 2.0020000 0.313207211501
4 P 20 0.5456000 0.760376741738
5 P 21 0.1517000 1.000000000000
6 D 22 0.5500000 1.000000000000
C
7 S 23 6665.0000000 0.000691583963
7 S 24 1000.0000000 0.005325796153
7 S 25 228.0000000 0.027060721042
7 S 26 64.7100000 0.101656846141
7 S 27 21.0600000 0.274574823617
7 S 28 7.4950000 0.448294318924
7 S 29 2.7970000 0.284902610715
7 S 30 0.5215000 0.015194859206
8 S 31 6665.0000000 -0.000293269653
8 S 32 1000.0000000 -0.002318035474
8 S 33 228.0000000 -0.011499786039
8 S 34 64.7100000 -0.046826727010
8 S 35 21.0600000 -0.128466168750
8 S 36 7.4950000 -0.301266272463
8 S 37 2.7970000 -0.255630702330
8 S 38 0.5215000 1.093793361012
9 S 39 0.1596000 1.000000000000
10 P 40 9.4390000 0.056979251590
10 P 41 2.0020000 0.313207211501
10 P 42 0.5456000 0.760376741738
11 P 43 0.1517000 1.000000000000
12 D 44 0.5500000 1.000000000000
C
13 S 45 6665.0000000 0.000691583963
13 S 46 1000.0000000 0.005325796153
13 S 47 228.0000000 0.027060721042
13 S 48 64.7100000 0.101656846141
13 S 49 21.0600000 0.274574823617
13 S 50 7.4950000 0.448294318924
13 S 51 2.7970000 0.284902610715
13 S 52 0.5215000 0.015194859206
14 S 53 6665.0000000 -0.000293269653
14 S 54 1000.0000000 -0.002318035474
14 S 55 228.0000000 -0.011499786039
14 S 56 64.7100000 -0.046826727010
14 S 57 21.0600000 -0.128466168750
14 S 58 7.4950000 -0.301266272463
14 S 59 2.7970000 -0.255630702330
14 S 60 0.5215000 1.093793361012
15 S 61 0.1596000 1.000000000000
16 P 62 9.4390000 0.056979251590
16 P 63 2.0020000 0.313207211501
16 P 64 0.5456000 0.760376741738
17 P 65 0.1517000 1.000000000000
18 D 66 0.5500000 1.000000000000
C
19 S 67 6665.0000000 0.000691583963
19 S 68 1000.0000000 0.005325796153
19 S 69 228.0000000 0.027060721042
19 S 70 64.7100000 0.101656846141
19 S 71 21.0600000 0.274574823617
19 S 72 7.4950000 0.448294318924
19 S 73 2.7970000 0.284902610715
19 S 74 0.5215000 0.015194859206
20 S 75 6665.0000000 -0.000293269653
20 S 76 1000.0000000 -0.002318035474
20 S 77 228.0000000 -0.011499786039
20 S 78 64.7100000 -0.046826727010
20 S 79 21.0600000 -0.128466168750
20 S 80 7.4950000 -0.301266272463
20 S 81 2.7970000 -0.255630702330
20 S 82 0.5215000 1.093793361012
21 S 83 0.1596000 1.000000000000
22 P 84 9.4390000 0.056979251590
22 P 85 2.0020000 0.313207211501
22 P 86 0.5456000 0.760376741738
23 P 87 0.1517000 1.000000000000
24 D 88 0.5500000 1.000000000000
N
25 S 89 9046.0000000 0.000699617413
25 S 90 1357.0000000 0.005386054630
25 S 91 309.3000000 0.027391021189
25 S 92 87.7300000 0.103150591982
25 S 93 28.5600000 0.278570663317
25 S 94 10.2100000 0.448294849454
25 S 95 3.8380000 0.278085928395
25 S 96 0.7466000 0.015431561233
26 S 97 9046.0000000 -0.000304990096
26 S 98 1357.0000000 -0.002408026379
26 S 99 309.3000000 -0.011944448725
26 S 100 87.7300000 -0.048925992909
26 S 101 28.5600000 -0.134472724725
26 S 102 10.2100000 -0.315112577700
26 S 103 3.8380000 -0.242857832550
26 S 104 0.7466000 1.094382206854
27 S 105 0.2248000 1.000000000000
28 P 106 13.5500000 0.058905676772
28 P 107 2.9170000 0.320461106714
28 P 108 0.7973000 0.753042061792
29 P 109 0.2185000 1.000000000000
30 D 110 0.8170000 1.000000000000
N
31 S 111 9046.0000000 0.000699617413
31 S 112 1357.0000000 0.005386054630
31 S 113 309.3000000 0.027391021189
31 S 114 87.7300000 0.103150591982
31 S 115 28.5600000 0.278570663317
31 S 116 10.2100000 0.448294849454
31 S 117 3.8380000 0.278085928395
31 S 118 0.7466000 0.015431561233
32 S 119 9046.0000000 -0.000304990096
32 S 120 1357.0000000 -0.002408026379
32 S 121 309.3000000 -0.011944448725
32 S 122 87.7300000 -0.048925992909
32 S 123 28.5600000 -0.134472724725
32 S 124 10.2100000 -0.315112577700
32 S 125 3.8380000 -0.242857832550
32 S 126 0.7466000 1.094382206854
33 S 127 0.2248000 1.000000000000
34 P 128 13.5500000 0.058905676772
34 P 129 2.9170000 0.320461106714
34 P 130 0.7973000 0.753042061792
35 P 131 0.2185000 1.000000000000
36 D 132 0.8170000 1.000000000000
H
37 S 133 13.0100000 0.033498726390
37 S 134 1.9620000 0.234800801174
37 S 135 0.4446000 0.813682957883
38 S 136 0.1220000 1.000000000000
39 P 137 0.7270000 1.000000000000
H
40 S 138 13.0100000 0.033498726390
40 S 139 1.9620000 0.234800801174
40 S 140 0.4446000 0.813682957883
41 S 141 0.1220000 1.000000000000
42 P 142 0.7270000 1.000000000000
H
43 S 143 13.0100000 0.033498726390
43 S 144 1.9620000 0.234800801174
43 S 145 0.4446000 0.813682957883
44 S 146 0.1220000 1.000000000000
45 P 147 0.7270000 1.000000000000
H
46 S 148 13.0100000 0.033498726390
46 S 149 1.9620000 0.234800801174
46 S 150 0.4446000 0.813682957883
47 S 151 0.1220000 1.000000000000
48 P 152 0.7270000 1.000000000000
TOTAL NUMBER OF BASIS SET SHELLS = 48
NUMBER OF CARTESIAN GAUSSIAN BASIS FUNCTIONS = 110
NOTE: THIS RUN WILL RESTRICT THE MO VARIATION SPACE TO SPHERICAL HARMONICS.
THE NUMBER OF ORBITALS KEPT IN THE VARIATIONAL SPACE WILL BE PRINTED LATER.
NUMBER OF ELECTRONS = 42
CHARGE OF MOLECULE = 0
SPIN MULTIPLICITY = 1
NUMBER OF OCCUPIED ORBITALS (ALPHA) = 21
NUMBER OF OCCUPIED ORBITALS (BETA ) = 21
TOTAL NUMBER OF ATOMS = 10
THE NUCLEAR REPULSION ENERGY IS 209.0820594095
$CONTRL OPTIONS
---------------
SCFTYP=RHF RUNTYP=ENERGY EXETYP=RUN
MPLEVL= 0 CITYP =NONE CCTYP =CR-CC(Q) VBTYP =NONE
DFTTYP=NONE TDDFT =NONE
MULT = 1 ICHARG= 0 NZVAR = 0 COORD =UNIQUE
PP =NONE RELWFN=NONE LOCAL =NONE NUMGRD= F
ISPHER= 1 NOSYM = 0 MAXIT = 200 UNITS =ANGS
PLTORB= F MOLPLT= F AIMPAC= F FRIEND=
NPRINT= 7 IREST = 0 GEOM =INPUT
NORMF = 0 NORMP = 0 ITOL = 20 ICUT = 9
INTTYP=BEST GRDTYP=BEST QMTTOL= 1.0E-06
$SYSTEM OPTIONS
---------------
REPLICATED MEMORY= 40000000 WORDS (ON EVERY NODE).
DISTRIBUTED MEMDDI= 0 MILLION WORDS IN AGGREGATE,
MEMDDI DISTRIBUTED OVER 1 PROCESSORS IS 0 WORDS/PROCESSOR.
TOTAL MEMORY REQUESTED ON EACH PROCESSOR= 40000000 WORDS.
TIMLIM= 525600.00 MINUTES, OR 365.0 DAYS.
PARALL= F BALTYP= DLB KDIAG= 0 COREFL= F
MXSEQ2= 300 MXSEQ3= 150 mem10= 0
----------------
PROPERTIES INPUT
----------------
MOMENTS FIELD POTENTIAL DENSITY
IEMOM = 1 IEFLD = 0 IEPOT = 0 IEDEN = 0
WHERE =COMASS WHERE =NUCLEI WHERE =NUCLEI WHERE =NUCLEI
OUTPUT=BOTH OUTPUT=BOTH OUTPUT=BOTH OUTPUT=BOTH
IEMINT= 0 IEFINT= 0 IEDINT= 0
MORB = 0
EXTRAPOLATION IN EFFECT
DAMPING IN EFFECT
LEVEL SHIFTING IN EFFECT
SOSCF IN EFFECT
ORBITAL PRINTING OPTION: NPREO= 1 110 2 1
-------------------------------
INTEGRAL TRANSFORMATION OPTIONS
-------------------------------
NWORD = 0
CUTOFF = 1.0E-09 MPTRAN = 0
DIRTRF = F AOINTS =DUP
----------------------
INTEGRAL INPUT OPTIONS
----------------------
NOPK = 1 NORDER= 0 SCHWRZ= T
------------------------------------------
THE POINT GROUP IS C1 , NAXIS= 0, ORDER= 1
------------------------------------------
-- VARIATIONAL SPACE WILL BE RESTRICTED TO PURE SPHERICAL HARMONICS ONLY --
AFTER EXCLUDING CONTAMINANT COMBINATIONS FROM THE CARTESIAN GAUSSIAN BASIS
SET, THE NUMBER OF SPHERICAL HARMONICS KEPT IN THE VARIATION SPACE IS 104
DIMENSIONS OF THE SYMMETRY SUBSPACES ARE
A = 104
..... DONE SETTING UP THE RUN .....
STEP CPU TIME = 0.01 TOTAL CPU TIME = 0.0 ( 0.0 MIN)
TOTAL WALL CLOCK TIME= 0.1 SECONDS, CPU UTILIZATION IS 20.00%
********************
1 ELECTRON INTEGRALS
********************
...... END OF ONE-ELECTRON INTEGRALS ......
STEP CPU TIME = 0.01 TOTAL CPU TIME = 0.0 ( 0.0 MIN)
TOTAL WALL CLOCK TIME= 0.1 SECONDS, CPU UTILIZATION IS 22.22%
-------------
GUESS OPTIONS
-------------
GUESS =HUCKEL NORB = 0 NORDER= 0
MIX = F PRTMO = F PUNMO = F
TOLZ = 1.0E-08 TOLE = 1.0E-05
SYMDEN= F PURIFY= F
INITIAL GUESS ORBITALS GENERATED BY HUCKEL ROUTINE.
HUCKEL GUESS REQUIRES 100016 WORDS.
STATISTICS FOR GENERATION OF SYMMETRY ORBITAL -Q- MATRIX
NUMBER OF CARTESIAN ATOMIC ORBITALS= 110
NUMBER OF SPHERICAL CONTAMINANTS DROPPED= 6
NUMBER OF LINEARLY DEPENDENT MOS DROPPED= 0
TOTAL NUMBER OF MOS IN VARIATION SPACE= 104
SYMMETRIES FOR INITIAL GUESS ORBITALS FOLLOW. BOTH SET(S).
21 ORBITALS ARE OCCUPIED ( 6 CORE ORBITALS).
7=A 8=A 9=A 10=A 11=A 12=A 13=A
14=A 15=A 16=A 17=A 18=A 19=A 20=A
21=A 22=A 23=A 24=A 25=A 26=A 27=A
28=A 29=A 30=A 31=A
...... END OF INITIAL ORBITAL SELECTION ......
STEP CPU TIME = 0.01 TOTAL CPU TIME = 0.0 ( 0.0 MIN)
TOTAL WALL CLOCK TIME= 0.1 SECONDS, CPU UTILIZATION IS 25.00%
----------------------
AO INTEGRAL TECHNOLOGY
----------------------
S,P,L SHELL ROTATED AXIS INTEGRALS, REPROGRAMMED BY
KAZUYA ISHIMURA (IMS) AND JOSE SIERRA (SYNSTAR).
S,P,D,L SHELL ROTATED AXIS INTEGRALS PROGRAMMED BY
KAZUYA ISHIMURA (INSTITUTE FOR MOLECULAR SCIENCE).
S,P,D,F,G SHELL TO TOTAL QUARTET ANGULAR MOMENTUM SUM 5,
ERIC PROGRAM BY GRAHAM FLETCHER (ELORET AND NASA ADVANCED
SUPERCOMPUTING DIVISION, AMES RESEARCH CENTER).
S,P,D,F,G,L SHELL GENERAL RYS QUADRATURE PROGRAMMED BY
MICHEL DUPUIS (PACIFIC NORTHWEST NATIONAL LABORATORY).
--------------------
2 ELECTRON INTEGRALS
--------------------
THE -PK- OPTION IS OFF, THE INTEGRALS ARE NOT IN SUPERMATRIX FORM.
STORING 15000 INTEGRALS/RECORD ON DISK, USING 12 BYTES/INTEGRAL.
TWO ELECTRON INTEGRAL EVALUATION REQUIRES 91572 WORDS OF MEMORY.
SCHWARZ INEQUALITY OVERHEAD: 6105 INTEGRALS, T= 0.01
II,JST,KST,LST = 1 1 1 1 NREC = 1 INTLOC = 1
II,JST,KST,LST = 2 1 1 1 NREC = 1 INTLOC = 2
II,JST,KST,LST = 3 1 1 1 NREC = 1 INTLOC = 7
II,JST,KST,LST = 4 1 1 1 NREC = 1 INTLOC = 22
II,JST,KST,LST = 5 1 1 1 NREC = 1 INTLOC = 67
II,JST,KST,LST = 6 1 1 1 NREC = 1 INTLOC = 214
II,JST,KST,LST = 7 1 1 1 NREC = 1 INTLOC = 1189
II,JST,KST,LST = 8 1 1 1 NREC = 1 INTLOC = 1862
II,JST,KST,LST = 9 1 1 1 NREC = 1 INTLOC = 2707
II,JST,KST,LST = 10 1 1 1 NREC = 1 INTLOC = 3751
II,JST,KST,LST = 11 1 1 1 NREC = 1 INTLOC = 7128
II,JST,KST,LST = 12 1 1 1 NREC = 1 INTLOC =12125
II,JST,KST,LST = 13 1 1 1 NREC = 2 INTLOC =13688
II,JST,KST,LST = 14 1 1 1 NREC = 3 INTLOC = 6451
II,JST,KST,LST = 15 1 1 1 NREC = 4 INTLOC = 145
II,JST,KST,LST = 16 1 1 1 NREC = 4 INTLOC = 9749
II,JST,KST,LST = 17 1 1 1 NREC = 6 INTLOC =10523
II,JST,KST,LST = 18 1 1 1 NREC = 9 INTLOC = 3985
II,JST,KST,LST = 19 1 1 1 NREC = 16 INTLOC = 3019
II,JST,KST,LST = 20 1 1 1 NREC = 17 INTLOC =13818
II,JST,KST,LST = 21 1 1 1 NREC = 19 INTLOC =11766
II,JST,KST,LST = 22 1 1 1 NREC = 21 INTLOC =11651
II,JST,KST,LST = 23 1 1 1 NREC = 27 INTLOC =13588
II,JST,KST,LST = 24 1 1 1 NREC = 35 INTLOC = 1039
II,JST,KST,LST = 25 1 1 1 NREC = 52 INTLOC =12486
II,JST,KST,LST = 26 1 1 1 NREC = 56 INTLOC =14734
II,JST,KST,LST = 27 1 1 1 NREC = 61 INTLOC = 6254
II,JST,KST,LST = 28 1 1 1 NREC = 66 INTLOC = 1485
II,JST,KST,LST = 29 1 1 1 NREC = 80 INTLOC = 5728
II,JST,KST,LST = 30 1 1 1 NREC = 96 INTLOC =10515
II,JST,KST,LST = 31 1 1 1 NREC = 136 INTLOC = 780
II,JST,KST,LST = 32 1 1 1 NREC = 143 INTLOC = 9128
II,JST,KST,LST = 33 1 1 1 NREC = 151 INTLOC =13978
II,JST,KST,LST = 34 1 1 1 NREC = 160 INTLOC =10597
II,JST,KST,LST = 35 1 1 1 NREC = 186 INTLOC = 8976
II,JST,KST,LST = 36 1 1 1 NREC = 215 INTLOC =12707
II,JST,KST,LST = 37 1 1 1 NREC = 283 INTLOC = 2787
II,JST,KST,LST = 38 1 1 1 NREC = 296 INTLOC = 9438
II,JST,KST,LST = 39 1 1 1 NREC = 311 INTLOC = 386
II,JST,KST,LST = 40 1 1 1 NREC = 350 INTLOC = 2313
II,JST,KST,LST = 41 1 1 1 NREC = 365 INTLOC = 6741
II,JST,KST,LST = 42 1 1 1 NREC = 382 INTLOC = 4393
II,JST,KST,LST = 43 1 1 1 NREC = 425 INTLOC =10399
II,JST,KST,LST = 44 1 1 1 NREC = 443 INTLOC = 1106
II,JST,KST,LST = 45 1 1 1 NREC = 462 INTLOC = 8940
II,JST,KST,LST = 46 1 1 1 NREC = 512 INTLOC = 4568
II,JST,KST,LST = 47 1 1 1 NREC = 531 INTLOC =12474
II,JST,KST,LST = 48 1 1 1 NREC = 554 INTLOC = 4116
SCHWARZ INEQUALITY TEST SKIPPED 25967 INTEGRAL BLOCKS.
TOTAL NUMBER OF NONZERO TWO-ELECTRON INTEGRALS = 9118307
608 INTEGRAL RECORDS WERE STORED ON DISK FILE 8.
...... END OF TWO-ELECTRON INTEGRALS .....
STEP CPU TIME = 2.46 TOTAL CPU TIME = 2.5 ( 0.0 MIN)
TOTAL WALL CLOCK TIME= 2.6 SECONDS, CPU UTILIZATION IS 95.77%
--------------------------
RHF SCF CALCULATION
--------------------------
NUCLEAR ENERGY = 209.0820594095
MAXIT = 200 NPUNCH= 2
EXTRAP=T DAMP=T SHIFT=T RSTRCT=F DIIS=F DEM=F SOSCF=T
DENSITY MATRIX CONV= 1.00E-06
SOSCF WILL OPTIMIZE 1743 ORBITAL ROTATIONS, SOGTOL= 0.250
MEMORY REQUIRED FOR RHF ITERS= 123212 WORDS.
ITER EX DEM TOTAL ENERGY E CHANGE DENSITY CHANGE ORB. GRAD VIR. SHIFT DAMPING
1 0 0 -261.9511473089 -261.9511473089 0.197868088 0.000000000 0.000000000 1.000000000
---------------START SECOND ORDER SCF---------------
2 1 0 -262.6452424079 -0.6940950990 0.076381307 0.070009548 0.000000000 0.000000000
3 2 0 -262.6922485255 -0.0470061176 0.040417335 0.025856448 0.000000000 0.000000000
4 3 0 -262.7025959025 -0.0103473770 0.006870587 0.004676624 0.000000000 0.000000000
5 4 0 -262.7029501045 -0.0003542020 0.003127014 0.001957898 0.000000000 0.000000000
6 5 0 -262.7030093536 -0.0000592491 0.000528059 0.000226553 0.000000000 0.000000000
7 6 0 -262.7030107785 -0.0000014249 0.000210457 0.000105620 0.000000000 0.000000000
8 7 0 -262.7030109322 -0.0000001537 0.000054046 0.000028420 0.000000000 0.000000000
9 8 0 -262.7030109444 -0.0000000123 0.000018583 0.000007105 0.000000000 0.000000000
10 9 0 -262.7030109459 -0.0000000015 0.000004730 0.000001344 0.000000000 0.000000000
11 10 0 -262.7030109460 -0.0000000001 0.000001306 0.000000369 0.000000000 0.000000000
12 11 0 -262.7030109460 -0.0000000000 0.000000198 0.000000073 0.000000000 0.000000000
RHF HAS CONVERGED, NOW COMPUTING EXACT TOTAL FOCK MATRIX
FOR USE DURING THE COUPLED CLUSTER CALCULATION THAT FOLLOWS.
-----------------
DENSITY CONVERGED
-----------------
TIME TO FORM FOCK OPERATORS= 1.5 SECONDS ( 0.1 SEC/ITER)
TIME TO SOLVE SCF EQUATIONS= 0.0 SECONDS ( 0.0 SEC/ITER)
FINAL RHF ENERGY IS -262.7030109460 AFTER 12 ITERATIONS
------------
EIGENVECTORS
------------
1 2 3 4 5
-15.5951 -15.5951 -11.2871 -11.2871 -11.2859
A A A A A
1 C 1 S 0.000125 0.000048 0.500894 0.500806 0.501090
2 C 1 S 0.000139 -0.000030 0.002012 0.001872 0.002170
3 C 1 S 0.003901 0.001395 -0.001870 -0.001809 -0.001149
4 C 1 X 0.000000 0.000000 0.000000 0.000000 0.000000
5 C 1 Y -0.000039 0.000066 -0.000233 -0.000288 -0.000263
6 C 1 Z -0.000075 0.000083 0.000111 0.000265 0.000121
7 C 1 X 0.000000 0.000000 0.000000 0.000000 0.000000
8 C 1 Y -0.002733 -0.000805 0.000322 -0.000744 -0.002125
9 C 1 Z -0.000772 0.000143 0.000662 -0.000126 -0.000129
10 C 1 XX 0.000123 0.000075 -0.000146 -0.000278 -0.000675
11 C 1 YY -0.000229 -0.000100 0.000057 0.000269 0.000352
12 C 1 ZZ 0.000106 0.000026 0.000089 0.000009 0.000322
13 C 1 XY 0.000000 0.000000 0.000000 0.000000 0.000000
14 C 1 XZ 0.000000 0.000000 0.000000 0.000000 0.000000
15 C 1 YZ 0.000534 0.000291 -0.000048 -0.000086 -0.000105
16 C 2 S 0.000125 0.000048 -0.500894 0.500806 0.501090
17 C 2 S 0.000139 -0.000030 -0.002012 0.001872 0.002170
18 C 2 S 0.003901 0.001395 0.001870 -0.001809 -0.001149
19 C 2 X 0.000000 0.000000 0.000000 0.000000 0.000000
20 C 2 Y 0.000039 -0.000066 -0.000233 0.000288 0.000263
21 C 2 Z -0.000075 0.000083 -0.000111 0.000265 0.000121
22 C 2 X 0.000000 0.000000 0.000000 0.000000 0.000000
23 C 2 Y 0.002733 0.000805 0.000322 0.000744 0.002125
24 C 2 Z -0.000772 0.000143 -0.000662 -0.000126 -0.000129
25 C 2 XX 0.000123 0.000075 0.000146 -0.000278 -0.000675
26 C 2 YY -0.000229 -0.000100 -0.000057 0.000269 0.000352
27 C 2 ZZ 0.000106 0.000026 -0.000089 0.000009 0.000322
28 C 2 XY 0.000000 0.000000 0.000000 0.000000 0.000000
29 C 2 XZ 0.000000 0.000000 0.000000 0.000000 0.000000
30 C 2 YZ -0.000534 -0.000291 -0.000048 0.000086 0.000105
31 C 3 S -0.000125 0.000048 0.500894 0.500806 -0.501090
32 C 3 S -0.000139 -0.000030 0.002012 0.001872 -0.002170
33 C 3 S -0.003901 0.001395 -0.001870 -0.001809 0.001149
34 C 3 X 0.000000 0.000000 0.000000 0.000000 0.000000
35 C 3 Y 0.000039 0.000066 -0.000233 -0.000288 0.000263
36 C 3 Z -0.000075 -0.000083 -0.000111 -0.000265 0.000121
37 C 3 X 0.000000 0.000000 0.000000 0.000000 0.000000
38 C 3 Y 0.002733 -0.000805 0.000322 -0.000744 0.002125
39 C 3 Z -0.000772 -0.000143 -0.000662 0.000126 -0.000129
40 C 3 XX -0.000123 0.000075 -0.000146 -0.000278 0.000675
41 C 3 YY 0.000229 -0.000100 0.000057 0.000269 -0.000352
42 C 3 ZZ -0.000106 0.000026 0.000089 0.000009 -0.000322
43 C 3 XY 0.000000 0.000000 0.000000 0.000000 0.000000
44 C 3 XZ 0.000000 0.000000 0.000000 0.000000 0.000000
45 C 3 YZ 0.000534 -0.000291 0.000048 0.000086 -0.000105
46 C 4 S -0.000125 0.000048 -0.500894 0.500806 -0.501090
47 C 4 S -0.000139 -0.000030 -0.002012 0.001872 -0.002170
48 C 4 S -0.003901 0.001395 0.001870 -0.001809 0.001149
49 C 4 X 0.000000 0.000000 0.000000 0.000000 0.000000
50 C 4 Y -0.000039 -0.000066 -0.000233 0.000288 -0.000263
51 C 4 Z -0.000075 -0.000083 0.000111 -0.000265 0.000121
52 C 4 X 0.000000 0.000000 0.000000 0.000000 0.000000
53 C 4 Y -0.002733 0.000805 0.000322 0.000744 -0.002125
54 C 4 Z -0.000772 -0.000143 0.000662 0.000126 -0.000129
55 C 4 XX -0.000123 0.000075 0.000146 -0.000278 0.000675
56 C 4 YY 0.000229 -0.000100 -0.000057 0.000269 -0.000352
57 C 4 ZZ -0.000106 0.000026 -0.000089 0.000009 -0.000322
58 C 4 XY 0.000000 0.000000 0.000000 0.000000 0.000000
59 C 4 XZ 0.000000 0.000000 0.000000 0.000000 0.000000
60 C 4 YZ -0.000534 0.000291 0.000048 -0.000086 0.000105
61 N 5 S 0.708600 0.708299 0.000000 -0.000035 0.000146
62 N 5 S 0.002528 0.001959 0.000000 0.000469 0.000790
63 N 5 S -0.008288 -0.005562 0.000000 -0.001781 -0.004122
64 N 5 X 0.000000 0.000000 0.000000 0.000000 0.000000
65 N 5 Y 0.000000 0.000000 0.000141 0.000000 0.000000
66 N 5 Z -0.001595 -0.001505 0.000000 -0.000063 -0.000013
67 N 5 X 0.000000 0.000000 0.000000 0.000000 0.000000
68 N 5 Y 0.000000 0.000000 -0.001027 0.000000 0.000000
69 N 5 Z 0.002576 0.001765 0.000000 0.001062 0.001646
70 N 5 XX -0.000253 -0.000222 0.000000 0.000319 0.000430
71 N 5 YY 0.000222 0.000190 0.000000 -0.000248 -0.000315
72 N 5 ZZ 0.000031 0.000032 0.000000 -0.000071 -0.000115
73 N 5 XY 0.000000 0.000000 0.000000 0.000000 0.000000
74 N 5 XZ 0.000000 0.000000 0.000000 0.000000 0.000000
75 N 5 YZ 0.000000 0.000000 0.000074 0.000000 0.000000
76 N 6 S -0.708600 0.708299 0.000000 -0.000035 -0.000146
77 N 6 S -0.002528 0.001959 0.000000 0.000469 -0.000790
78 N 6 S 0.008288 -0.005562 0.000000 -0.001781 0.004122
79 N 6 X 0.000000 0.000000 0.000000 0.000000 0.000000
80 N 6 Y 0.000000 0.000000 0.000141 0.000000 0.000000
81 N 6 Z -0.001595 0.001505 0.000000 0.000063 -0.000013
82 N 6 X 0.000000 0.000000 0.000000 0.000000 0.000000
83 N 6 Y 0.000000 0.000000 -0.001027 0.000000 0.000000
84 N 6 Z 0.002576 -0.001765 0.000000 -0.001062 0.001646
85 N 6 XX 0.000253 -0.000222 0.000000 0.000319 -0.000430
86 N 6 YY -0.000222 0.000190 0.000000 -0.000248 0.000315
87 N 6 ZZ -0.000031 0.000032 0.000000 -0.000071 0.000115
88 N 6 XY 0.000000 0.000000 0.000000 0.000000 0.000000
89 N 6 XZ 0.000000 0.000000 0.000000 0.000000 0.000000
90 N 6 YZ 0.000000 0.000000 -0.000074 0.000000 0.000000
91 H 7 S -0.000016 -0.000132 -0.000292 -0.000116 -0.000088
92 H 7 S 0.000668 0.000157 0.000362 0.000938 0.001086
93 H 7 X 0.000000 0.000000 0.000000 0.000000 0.000000
94 H 7 Y 0.000193 0.000097 0.000164 0.000191 0.000329
95 H 7 Z -0.000068 -0.000057 -0.000005 0.000023 0.000163
96 H 8 S -0.000016 -0.000132 0.000292 -0.000116 -0.000088
97 H 8 S 0.000668 0.000157 -0.000362 0.000938 0.001086
98 H 8 X 0.000000 0.000000 0.000000 0.000000 0.000000
99 H 8 Y -0.000193 -0.000097 0.000164 -0.000191 -0.000329
100 H 8 Z -0.000068 -0.000057 0.000005 0.000023 0.000163
101 H 9 S 0.000016 -0.000132 -0.000292 -0.000116 0.000088
102 H 9 S -0.000668 0.000157 0.000362 0.000938 -0.001086
103 H 9 X 0.000000 0.000000 0.000000 0.000000 0.000000
104 H 9 Y -0.000193 0.000097 0.000164 0.000191 -0.000329
105 H 9 Z -0.000068 0.000057 0.000005 -0.000023 0.000163
106 H 10 S 0.000016 -0.000132 0.000292 -0.000116 0.000088
107 H 10 S -0.000668 0.000157 -0.000362 0.000938 -0.001086
108 H 10 X 0.000000 0.000000 0.000000 0.000000 0.000000
109 H 10 Y 0.000193 -0.000097 0.000164 -0.000191 0.000329
110 H 10 Z -0.000068 0.000057 -0.000005 -0.000023 0.000163
6 7 8 9 10
-11.2859 -1.3085 -1.2205 -1.0541 -0.9025
A A A A A
1 C 1 S -0.501265 -0.009465 0.008761 -0.013225 0.006482
2 C 1 S -0.002435 0.152558 -0.108789 0.219612 -0.142159
3 C 1 S 0.005578 0.057863 -0.043445 0.127432 -0.104544
4 C 1 X 0.000000 0.000000 0.000000 0.000000 0.000000
5 C 1 Y 0.000180 -0.077408 0.080728 -0.001722 -0.112951
6 C 1 Z -0.000108 -0.004467 -0.071197 -0.054522 0.157720
7 C 1 X 0.000000 0.000000 0.000000 0.000000 0.000000
8 C 1 Y 0.000199 -0.005553 0.001273 -0.012767 -0.028117
9 C 1 Z -0.003107 -0.006986 -0.005523 -0.032958 0.039402
10 C 1 XX 0.000514 -0.009562 0.006572 -0.008836 0.002588
11 C 1 YY -0.000196 0.007234 -0.016791 -0.005825 0.013041
12 C 1 ZZ -0.000318 0.002328 0.010219 0.014661 -0.015629
13 C 1 XY 0.000000 0.000000 0.000000 0.000000 0.000000
14 C 1 XZ 0.000000 0.000000 0.000000 0.000000 0.000000
15 C 1 YZ 0.000018 -0.008938 0.018137 -0.004824 -0.008013
16 C 2 S 0.501265 -0.009465 0.008761 0.013225 0.006482
17 C 2 S 0.002435 0.152558 -0.108789 -0.219612 -0.142159
18 C 2 S -0.005578 0.057863 -0.043445 -0.127432 -0.104544
19 C 2 X 0.000000 0.000000 0.000000 0.000000 0.000000
20 C 2 Y 0.000180 0.077408 -0.080728 -0.001722 0.112951
21 C 2 Z 0.000108 -0.004467 -0.071197 0.054522 0.157720
22 C 2 X 0.000000 0.000000 0.000000 0.000000 0.000000
23 C 2 Y 0.000199 0.005553 -0.001273 -0.012767 0.028117
24 C 2 Z 0.003107 -0.006986 -0.005523 0.032958 0.039402
25 C 2 XX -0.000514 -0.009562 0.006572 0.008836 0.002588
26 C 2 YY 0.000196 0.007234 -0.016791 0.005825 0.013041
27 C 2 ZZ 0.000318 0.002328 0.010219 -0.014661 -0.015629
28 C 2 XY 0.000000 0.000000 0.000000 0.000000 0.000000
29 C 2 XZ 0.000000 0.000000 0.000000 0.000000 0.000000
30 C 2 YZ 0.000018 0.008938 -0.018137 -0.004824 0.008013
31 C 3 S 0.501265 -0.009465 -0.008761 -0.013225 0.006482
32 C 3 S 0.002435 0.152558 0.108789 0.219612 -0.142159
33 C 3 S -0.005578 0.057863 0.043445 0.127432 -0.104544
34 C 3 X 0.000000 0.000000 0.000000 0.000000 0.000000
35 C 3 Y -0.000180 -0.077408 -0.080728 -0.001722 -0.112951
36 C 3 Z -0.000108 0.004467 -0.071197 0.054522 -0.157720
37 C 3 X 0.000000 0.000000 0.000000 0.000000 0.000000
38 C 3 Y -0.000199 -0.005553 -0.001273 -0.012767 -0.028117
39 C 3 Z -0.003107 0.006986 -0.005523 0.032958 -0.039402
40 C 3 XX -0.000514 -0.009562 -0.006572 -0.008836 0.002588
41 C 3 YY 0.000196 0.007234 0.016791 -0.005825 0.013041
42 C 3 ZZ 0.000318 0.002328 -0.010219 0.014661 -0.015629
43 C 3 XY 0.000000 0.000000 0.000000 0.000000 0.000000
44 C 3 XZ 0.000000 0.000000 0.000000 0.000000 0.000000
45 C 3 YZ 0.000018 0.008938 0.018137 0.004824 0.008013
46 C 4 S -0.501265 -0.009465 -0.008761 0.013225 0.006482
47 C 4 S -0.002435 0.152558 0.108789 -0.219612 -0.142159
48 C 4 S 0.005578 0.057863 0.043445 -0.127432 -0.104544
49 C 4 X 0.000000 0.000000 0.000000 0.000000 0.000000
50 C 4 Y -0.000180 0.077408 0.080728 -0.001722 0.112951
51 C 4 Z 0.000108 0.004467 -0.071197 -0.054522 -0.157720
52 C 4 X 0.000000 0.000000 0.000000 0.000000 0.000000
53 C 4 Y -0.000199 0.005553 0.001273 -0.012767 0.028117
54 C 4 Z 0.003107 0.006986 -0.005523 -0.032958 -0.039402
55 C 4 XX 0.000514 -0.009562 -0.006572 0.008836 0.002588
56 C 4 YY -0.000196 0.007234 0.016791 0.005825 0.013041
57 C 4 ZZ -0.000318 0.002328 -0.010219 -0.014661 -0.015629
58 C 4 XY 0.000000 0.000000 0.000000 0.000000 0.000000
59 C 4 XZ 0.000000 0.000000 0.000000 0.000000 0.000000
60 C 4 YZ 0.000018 -0.008938 -0.018137 0.004824 -0.008013
61 N 5 S 0.000000 -0.009589 0.012126 0.000000 -0.001038
62 N 5 S 0.000000 0.226901 -0.272264 0.000000 0.181903
63 N 5 S 0.000000 0.199698 -0.260735 0.000000 0.183694
64 N 5 X 0.000000 0.000000 0.000000 0.000000 0.000000
65 N 5 Y -0.000173 0.000000 0.000000 0.133465 0.000000
66 N 5 Z 0.000000 -0.084208 0.073729 0.000000 0.014401
67 N 5 X 0.000000 0.000000 0.000000 0.000000 0.000000
68 N 5 Y 0.001918 0.000000 0.000000 0.059205 0.000000
69 N 5 Z 0.000000 -0.031929 0.031775 0.000000 0.013492
70 N 5 XX 0.000000 -0.010081 0.009805 0.000000 -0.001112
71 N 5 YY 0.000000 0.006162 -0.008566 0.000000 0.005183
72 N 5 ZZ 0.000000 0.003919 -0.001239 0.000000 -0.004071
73 N 5 XY 0.000000 0.000000 0.000000 0.000000 0.000000
74 N 5 XZ 0.000000 0.000000 0.000000 0.000000 0.000000
75 N 5 YZ -0.000177 0.000000 0.000000 -0.018167 0.000000
76 N 6 S 0.000000 -0.009589 -0.012126 0.000000 -0.001038
77 N 6 S 0.000000 0.226901 0.272264 0.000000 0.181903
78 N 6 S 0.000000 0.199698 0.260735 0.000000 0.183694
79 N 6 X 0.000000 0.000000 0.000000 0.000000 0.000000
80 N 6 Y 0.000173 0.000000 0.000000 0.133465 0.000000
81 N 6 Z 0.000000 0.084208 0.073729 0.000000 -0.014401
82 N 6 X 0.000000 0.000000 0.000000 0.000000 0.000000
83 N 6 Y -0.001918 0.000000 0.000000 0.059205 0.000000
84 N 6 Z 0.000000 0.031929 0.031775 0.000000 -0.013492
85 N 6 XX 0.000000 -0.010081 -0.009805 0.000000 -0.001112
86 N 6 YY 0.000000 0.006162 0.008566 0.000000 0.005183
87 N 6 ZZ 0.000000 0.003919 0.001239 0.000000 -0.004071
88 N 6 XY 0.000000 0.000000 0.000000 0.000000 0.000000
89 N 6 XZ 0.000000 0.000000 0.000000 0.000000 0.000000
90 N 6 YZ -0.000177 0.000000 0.000000 0.018167 0.000000
91 H 7 S 0.000285 0.030790 -0.030455 0.090746 -0.086620
92 H 7 S -0.000040 -0.000575 0.000693 0.014838 -0.008114
93 H 7 X 0.000000 0.000000 0.000000 0.000000 0.000000
94 H 7 Y -0.000323 -0.006066 0.007351 -0.010419 0.007341
95 H 7 Z -0.000042 -0.001925 -0.000376 -0.008086 0.008912
96 H 8 S -0.000285 0.030790 -0.030455 -0.090746 -0.086620
97 H 8 S 0.000040 -0.000575 0.000693 -0.014838 -0.008114
98 H 8 X 0.000000 0.000000 0.000000 0.000000 0.000000
99 H 8 Y -0.000323 0.006066 -0.007351 -0.010419 -0.007341
100 H 8 Z 0.000042 -0.001925 -0.000376 0.008086 0.008912
101 H 9 S -0.000285 0.030790 0.030455 0.090746 -0.086620
102 H 9 S 0.000040 -0.000575 -0.000693 0.014838 -0.008114
103 H 9 X 0.000000 0.000000 0.000000 0.000000 0.000000
104 H 9 Y 0.000323 -0.006066 -0.007351 -0.010419 0.007341
105 H 9 Z -0.000042 0.001925 -0.000376 0.008086 -0.008912
106 H 10 S 0.000285 0.030790 0.030455 -0.090746 -0.086620
107 H 10 S -0.000040 -0.000575 -0.000693 -0.014838 -0.008114
108 H 10 X 0.000000 0.000000 0.000000 0.000000 0.000000
109 H 10 Y 0.000323 0.006066 0.007351 -0.010419 -0.007341
110 H 10 Z 0.000042 0.001925 -0.000376 -0.008086 -0.008912
11 12 13 14 15
-0.8878 -0.7263 -0.7020 -0.6765 -0.6089
A A A A A
1 C 1 S 0.008239 0.003446 0.001508 -0.003043 -0.003016
2 C 1 S -0.171825 -0.005247 -0.009846 0.107522 -0.042645
3 C 1 S -0.165892 -0.025911 -0.022788 0.099747 -0.043664
4 C 1 X 0.000000 0.000000 0.000000 0.000000 0.000000
5 C 1 Y 0.024881 -0.152359 -0.140265 0.172127 0.197663
6 C 1 Z -0.119359 -0.155665 0.235687 0.070556 0.175998
7 C 1 X 0.000000 0.000000 0.000000 0.000000 0.000000
8 C 1 Y 0.024329 -0.049723 -0.040656 0.061169 0.087719
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26 27 28 29 30
0.2424 0.2472 0.3307 0.3321 0.4341
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31 32 33 34 35
0.4591 0.4637 0.5786 0.6078 0.6327
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47 C 4 S 0.025050 0.075032 -0.052268 -0.080248 0.207208
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50 C 4 Y 0.055297 0.102402 -0.110386 -0.032061 0.038807
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36 37 38 39 40
0.6408 0.6551 0.7007 0.7031 0.7097
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1.1668 1.1829 1.1930 1.2576 1.2757
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1.3199 1.3797 1.3963 1.4130 1.4279
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1.5219 1.5836 1.6268 1.7427 1.8068
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2.2781 2.3475 2.4476 2.4707 2.5276
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72 N 5 ZZ 0.365489 0.000000 0.000000 0.000000 0.000000
73 N 5 XY 0.000000 0.800808 0.000000 0.000000 0.000000
74 N 5 XZ 0.000000 0.000000 0.694504 0.000000 0.000000
75 N 5 YZ 0.000000 0.000000 0.000000 -0.100671 0.359165
76 N 6 S 0.226988 0.000000 0.000000 0.000000 0.000000
77 N 6 S 0.437039 0.000000 0.000000 0.000000 0.000000
78 N 6 S -1.542627 0.000000 0.000000 0.000000 0.000000
79 N 6 X 0.000000 0.000000 0.036314 0.000000 0.000000
80 N 6 Y 0.000000 0.000000 0.000000 -0.101494 -0.467842
81 N 6 Z 0.014921 0.000000 0.000000 0.000000 0.000000
82 N 6 X 0.000000 0.000000 0.437328 0.000000 0.000000
83 N 6 Y 0.000000 0.000000 0.000000 0.047047 1.637156
84 N 6 Z -0.859256 0.000000 0.000000 0.000000 0.000000
85 N 6 XX 0.459760 0.000000 0.000000 0.000000 0.000000
86 N 6 YY -0.094271 0.000000 0.000000 0.000000 0.000000
87 N 6 ZZ -0.365489 0.000000 0.000000 0.000000 0.000000
88 N 6 XY 0.000000 0.800808 0.000000 0.000000 0.000000
89 N 6 XZ 0.000000 0.000000 0.694504 0.000000 0.000000
90 N 6 YZ 0.000000 0.000000 0.000000 0.100671 0.359165
91 H 7 S -0.403895 0.000000 0.000000 0.855859 0.307809
92 H 7 S -0.395775 0.000000 0.000000 0.382721 -0.063126
93 H 7 X 0.000000 0.057983 0.242873 0.000000 0.000000
94 H 7 Y 0.547649 0.000000 0.000000 -0.647711 -0.024950
95 H 7 Z 0.181962 0.000000 0.000000 -0.481595 -0.469833
96 H 8 S -0.403895 0.000000 0.000000 -0.855859 -0.307809
97 H 8 S -0.395775 0.000000 0.000000 -0.382721 0.063126
98 H 8 X 0.000000 -0.057983 0.242873 0.000000 0.000000
99 H 8 Y -0.547649 0.000000 0.000000 -0.647711 -0.024950
100 H 8 Z 0.181962 0.000000 0.000000 0.481595 0.469833
101 H 9 S 0.403895 0.000000 0.000000 0.855859 -0.307809
102 H 9 S 0.395775 0.000000 0.000000 0.382721 0.063126
103 H 9 X 0.000000 0.057983 -0.242873 0.000000 0.000000
104 H 9 Y -0.547649 0.000000 0.000000 -0.647711 0.024950
105 H 9 Z 0.181962 0.000000 0.000000 0.481595 -0.469833
106 H 10 S 0.403895 0.000000 0.000000 -0.855859 0.307809
107 H 10 S 0.395775 0.000000 0.000000 -0.382721 -0.063126
108 H 10 X 0.000000 -0.057983 -0.242873 0.000000 0.000000
109 H 10 Y 0.547649 0.000000 0.000000 -0.647711 0.024950
110 H 10 Z 0.181962 0.000000 0.000000 -0.481595 0.469833
96 97 98 99 100
2.8563 2.8771 2.8989 3.1315 3.1767
A A A A A
1 C 1 S 0.000000 -0.049986 -0.220234 -0.227744 0.059303
2 C 1 S 0.000000 0.009697 -0.517081 -0.501522 0.073460
3 C 1 S 0.000000 2.908938 -0.966071 -0.557015 -0.549486
4 C 1 X 0.015982 0.000000 0.000000 0.000000 0.000000
5 C 1 Y 0.000000 0.006862 -0.178013 0.486037 0.258716
6 C 1 Z 0.000000 0.346674 -0.330028 -0.088531 -0.348109
7 C 1 X -0.017638 0.000000 0.000000 0.000000 0.000000
8 C 1 Y 0.000000 -0.055573 0.102102 0.214829 0.236683
9 C 1 Z 0.000000 -0.945124 -0.153987 -0.390929 -0.166792
10 C 1 XX 0.000000 -0.463818 0.270081 0.008405 0.158361
11 C 1 YY 0.000000 0.698140 -0.400269 -0.255094 0.295622
12 C 1 ZZ 0.000000 -0.234322 0.130188 0.246689 -0.453983
13 C 1 XY -0.333115 0.000000 0.000000 0.000000 0.000000
14 C 1 XZ 0.489111 0.000000 0.000000 0.000000 0.000000
15 C 1 YZ 0.000000 -0.439504 -0.324123 0.254379 0.208076
16 C 2 S 0.000000 -0.049986 -0.220234 0.227744 0.059303
17 C 2 S 0.000000 0.009697 -0.517081 0.501522 0.073460
18 C 2 S 0.000000 2.908938 -0.966071 0.557015 -0.549486
19 C 2 X -0.015982 0.000000 0.000000 0.000000 0.000000
20 C 2 Y 0.000000 -0.006862 0.178013 0.486037 -0.258716
21 C 2 Z 0.000000 0.346674 -0.330028 0.088531 -0.348109
22 C 2 X 0.017638 0.000000 0.000000 0.000000 0.000000
23 C 2 Y 0.000000 0.055573 -0.102102 0.214829 -0.236683
24 C 2 Z 0.000000 -0.945124 -0.153987 0.390929 -0.166792
25 C 2 XX 0.000000 -0.463818 0.270081 -0.008405 0.158361
26 C 2 YY 0.000000 0.698140 -0.400269 0.255094 0.295622
27 C 2 ZZ 0.000000 -0.234322 0.130188 -0.246689 -0.453983
28 C 2 XY -0.333115 0.000000 0.000000 0.000000 0.000000
29 C 2 XZ -0.489111 0.000000 0.000000 0.000000 0.000000
30 C 2 YZ 0.000000 0.439504 0.324123 0.254379 -0.208076
31 C 3 S 0.000000 0.049986 -0.220234 -0.227744 0.059303
32 C 3 S 0.000000 -0.009697 -0.517081 -0.501522 0.073460
33 C 3 S 0.000000 -2.908938 -0.966071 -0.557015 -0.549486
34 C 3 X -0.015982 0.000000 0.000000 0.000000 0.000000
35 C 3 Y 0.000000 -0.006862 -0.178013 0.486037 0.258716
36 C 3 Z 0.000000 0.346674 0.330028 0.088531 0.348109
37 C 3 X 0.017638 0.000000 0.000000 0.000000 0.000000
38 C 3 Y 0.000000 0.055573 0.102102 0.214829 0.236683
39 C 3 Z 0.000000 -0.945124 0.153987 0.390929 0.166792
40 C 3 XX 0.000000 0.463818 0.270081 0.008405 0.158361
41 C 3 YY 0.000000 -0.698140 -0.400269 -0.255094 0.295622
42 C 3 ZZ 0.000000 0.234322 0.130188 0.246689 -0.453983
43 C 3 XY 0.333115 0.000000 0.000000 0.000000 0.000000
44 C 3 XZ 0.489111 0.000000 0.000000 0.000000 0.000000
45 C 3 YZ 0.000000 -0.439504 0.324123 -0.254379 -0.208076
46 C 4 S 0.000000 0.049986 -0.220234 0.227744 0.059303
47 C 4 S 0.000000 -0.009697 -0.517081 0.501522 0.073460
48 C 4 S 0.000000 -2.908938 -0.966071 0.557015 -0.549486
49 C 4 X 0.015982 0.000000 0.000000 0.000000 0.000000
50 C 4 Y 0.000000 0.006862 0.178013 0.486037 -0.258716
51 C 4 Z 0.000000 0.346674 0.330028 -0.088531 0.348109
52 C 4 X -0.017638 0.000000 0.000000 0.000000 0.000000
53 C 4 Y 0.000000 -0.055573 -0.102102 0.214829 -0.236683
54 C 4 Z 0.000000 -0.945124 0.153987 -0.390929 0.166792
55 C 4 XX 0.000000 0.463818 0.270081 -0.008405 0.158361
56 C 4 YY 0.000000 -0.698140 -0.400269 0.255094 0.295622
57 C 4 ZZ 0.000000 0.234322 0.130188 -0.246689 -0.453983
58 C 4 XY 0.333115 0.000000 0.000000 0.000000 0.000000
59 C 4 XZ -0.489111 0.000000 0.000000 0.000000 0.000000
60 C 4 YZ 0.000000 0.439504 -0.324123 -0.254379 0.208076
61 N 5 S 0.000000 -0.085650 -0.370171 0.000000 -0.192292
62 N 5 S 0.000000 -0.273375 -0.714858 0.000000 -0.339496
63 N 5 S 0.000000 -1.454336 1.966109 0.000000 1.520271
64 N 5 X 0.000000 0.000000 0.000000 0.000000 0.000000
65 N 5 Y 0.000000 0.000000 0.000000 0.136755 0.000000
66 N 5 Z 0.000000 0.341117 0.024064 0.000000 0.000110
67 N 5 X 0.000000 0.000000 0.000000 0.000000 0.000000
68 N 5 Y 0.000000 0.000000 0.000000 1.195239 0.000000
69 N 5 Z 0.000000 0.852415 -0.849976 0.000000 -0.172629
70 N 5 XX 0.000000 0.445186 -0.532080 0.000000 -0.314368
71 N 5 YY 0.000000 -0.245314 0.093342 0.000000 0.863456
72 N 5 ZZ 0.000000 -0.199872 0.438739 0.000000 -0.549088
73 N 5 XY -0.803822 0.000000 0.000000 0.000000 0.000000
74 N 5 XZ 0.000000 0.000000 0.000000 0.000000 0.000000
75 N 5 YZ 0.000000 0.000000 0.000000 -0.966498 0.000000
76 N 6 S 0.000000 0.085650 -0.370171 0.000000 -0.192292
77 N 6 S 0.000000 0.273375 -0.714858 0.000000 -0.339496
78 N 6 S 0.000000 1.454336 1.966109 0.000000 1.520271
79 N 6 X 0.000000 0.000000 0.000000 0.000000 0.000000
80 N 6 Y 0.000000 0.000000 0.000000 0.136755 0.000000
81 N 6 Z 0.000000 0.341117 -0.024064 0.000000 -0.000110
82 N 6 X 0.000000 0.000000 0.000000 0.000000 0.000000
83 N 6 Y 0.000000 0.000000 0.000000 1.195239 0.000000
84 N 6 Z 0.000000 0.852415 0.849976 0.000000 0.172629
85 N 6 XX 0.000000 -0.445186 -0.532080 0.000000 -0.314368
86 N 6 YY 0.000000 0.245314 0.093342 0.000000 0.863456
87 N 6 ZZ 0.000000 0.199872 0.438739 0.000000 -0.549088
88 N 6 XY 0.803822 0.000000 0.000000 0.000000 0.000000
89 N 6 XZ 0.000000 0.000000 0.000000 0.000000 0.000000
90 N 6 YZ 0.000000 0.000000 0.000000 0.966498 0.000000
91 H 7 S 0.000000 -0.435167 0.690023 -0.055638 -0.118072
92 H 7 S 0.000000 -0.167300 0.212243 -0.037945 0.022006
93 H 7 X 0.017973 0.000000 0.000000 0.000000 0.000000
94 H 7 Y 0.000000 0.107383 -0.521178 0.156440 -0.079450
95 H 7 Z 0.000000 0.526206 -0.331625 -0.046173 0.264130
96 H 8 S 0.000000 -0.435167 0.690023 0.055638 -0.118072
97 H 8 S 0.000000 -0.167300 0.212243 0.037945 0.022006
98 H 8 X -0.017973 0.000000 0.000000 0.000000 0.000000
99 H 8 Y 0.000000 -0.107383 0.521178 0.156440 0.079450
100 H 8 Z 0.000000 0.526206 -0.331625 0.046173 0.264130
101 H 9 S 0.000000 0.435167 0.690023 -0.055638 -0.118072
102 H 9 S 0.000000 0.167300 0.212243 -0.037945 0.022006
103 H 9 X -0.017973 0.000000 0.000000 0.000000 0.000000
104 H 9 Y 0.000000 -0.107383 -0.521178 0.156440 -0.079450
105 H 9 Z 0.000000 0.526206 0.331625 0.046173 -0.264130
106 H 10 S 0.000000 0.435167 0.690023 0.055638 -0.118072
107 H 10 S 0.000000 0.167300 0.212243 0.037945 0.022006
108 H 10 X 0.017973 0.000000 0.000000 0.000000 0.000000
109 H 10 Y 0.000000 0.107383 0.521178 0.156440 0.079450
110 H 10 Z 0.000000 0.526206 0.331625 -0.046173 -0.264130
101 102 103 104
3.2041 3.2360 3.3252 3.7733
A A A A
1 C 1 S -0.232438 0.010140 -0.021547 -0.041339
2 C 1 S -0.579857 -0.054341 -0.110706 -0.101709
3 C 1 S -2.314506 -1.360905 -1.237257 0.231293
4 C 1 X 0.000000 0.000000 0.000000 0.000000
5 C 1 Y 0.067756 0.233861 -0.400083 0.255395
6 C 1 Z -0.048393 -0.475762 -0.226363 0.202871
7 C 1 X 0.000000 0.000000 0.000000 0.000000
8 C 1 Y 0.909846 0.603294 -0.126178 0.445492
9 C 1 Z 0.279709 -0.167033 0.238869 -0.134858
10 C 1 XX 0.387455 0.216551 0.325643 0.005797
11 C 1 YY 0.089065 -0.665369 -0.360892 0.495761
12 C 1 ZZ -0.476520 0.448818 0.035249 -0.501558
13 C 1 XY 0.000000 0.000000 0.000000 0.000000
14 C 1 XZ 0.000000 0.000000 0.000000 0.000000
15 C 1 YZ -0.459028 0.327888 -1.128289 1.083783
16 C 2 S -0.232438 -0.010140 0.021547 -0.041339
17 C 2 S -0.579857 0.054341 0.110706 -0.101709
18 C 2 S -2.314506 1.360905 1.237257 0.231293
19 C 2 X 0.000000 0.000000 0.000000 0.000000
20 C 2 Y -0.067756 0.233861 -0.400083 -0.255395
21 C 2 Z -0.048393 0.475762 0.226363 0.202871
22 C 2 X 0.000000 0.000000 0.000000 0.000000
23 C 2 Y -0.909846 0.603294 -0.126178 -0.445492
24 C 2 Z 0.279709 0.167033 -0.238869 -0.134858
25 C 2 XX 0.387455 -0.216551 -0.325643 0.005797
26 C 2 YY 0.089065 0.665369 0.360892 0.495761
27 C 2 ZZ -0.476520 -0.448818 -0.035249 -0.501558
28 C 2 XY 0.000000 0.000000 0.000000 0.000000
29 C 2 XZ 0.000000 0.000000 0.000000 0.000000
30 C 2 YZ 0.459028 0.327888 -1.128289 -1.083783
31 C 3 S 0.232438 -0.010140 0.021547 0.041339
32 C 3 S 0.579857 0.054341 0.110706 0.101709
33 C 3 S 2.314506 1.360905 1.237257 -0.231293
34 C 3 X 0.000000 0.000000 0.000000 0.000000
35 C 3 Y -0.067756 -0.233861 0.400083 -0.255395
36 C 3 Z -0.048393 -0.475762 -0.226363 0.202871
37 C 3 X 0.000000 0.000000 0.000000 0.000000
38 C 3 Y -0.909846 -0.603294 0.126178 -0.445492
39 C 3 Z 0.279709 -0.167033 0.238869 -0.134858
40 C 3 XX -0.387455 -0.216551 -0.325643 -0.005797
41 C 3 YY -0.089065 0.665369 0.360892 -0.495761
42 C 3 ZZ 0.476520 -0.448818 -0.035249 0.501558
43 C 3 XY 0.000000 0.000000 0.000000 0.000000
44 C 3 XZ 0.000000 0.000000 0.000000 0.000000
45 C 3 YZ -0.459028 0.327888 -1.128289 1.083783
46 C 4 S 0.232438 0.010140 -0.021547 0.041339
47 C 4 S 0.579857 -0.054341 -0.110706 0.101709
48 C 4 S 2.314506 -1.360905 -1.237257 -0.231293
49 C 4 X 0.000000 0.000000 0.000000 0.000000
50 C 4 Y 0.067756 -0.233861 0.400083 0.255395
51 C 4 Z -0.048393 0.475762 0.226363 0.202871
52 C 4 X 0.000000 0.000000 0.000000 0.000000
53 C 4 Y 0.909846 -0.603294 0.126178 0.445492
54 C 4 Z 0.279709 0.167033 -0.238869 -0.134858
55 C 4 XX -0.387455 0.216551 0.325643 -0.005797
56 C 4 YY -0.089065 -0.665369 -0.360892 -0.495761
57 C 4 ZZ 0.476520 0.448818 0.035249 0.501558
58 C 4 XY 0.000000 0.000000 0.000000 0.000000
59 C 4 XZ 0.000000 0.000000 0.000000 0.000000
60 C 4 YZ 0.459028 0.327888 -1.128289 -1.083783
61 N 5 S -0.576423 0.000000 0.000000 0.116290
62 N 5 S -1.113260 0.000000 0.000000 0.281958
63 N 5 S 3.367165 0.000000 0.000000 0.803513
64 N 5 X 0.000000 0.000000 0.000000 0.000000
65 N 5 Y 0.000000 0.320792 -0.389271 0.000000
66 N 5 Z 0.127938 0.000000 0.000000 -0.072668
67 N 5 X 0.000000 0.000000 0.000000 0.000000
68 N 5 Y 0.000000 1.150578 -0.136108 0.000000
69 N 5 Z -1.001853 0.000000 0.000000 0.159444
70 N 5 XX -0.476813 0.000000 0.000000 -0.101633
71 N 5 YY 0.511420 0.000000 0.000000 0.876118
72 N 5 ZZ -0.034607 0.000000 0.000000 -0.774485
73 N 5 XY 0.000000 0.000000 0.000000 0.000000
74 N 5 XZ 0.000000 0.000000 0.000000 0.000000
75 N 5 YZ 0.000000 -0.950636 0.085459 0.000000
76 N 6 S 0.576423 0.000000 0.000000 -0.116290
77 N 6 S 1.113260 0.000000 0.000000 -0.281958
78 N 6 S -3.367165 0.000000 0.000000 -0.803513
79 N 6 X 0.000000 0.000000 0.000000 0.000000
80 N 6 Y 0.000000 -0.320792 0.389271 0.000000
81 N 6 Z 0.127938 0.000000 0.000000 -0.072668
82 N 6 X 0.000000 0.000000 0.000000 0.000000
83 N 6 Y 0.000000 -1.150578 0.136108 0.000000
84 N 6 Z -1.001853 0.000000 0.000000 0.159444
85 N 6 XX 0.476813 0.000000 0.000000 0.101633
86 N 6 YY -0.511420 0.000000 0.000000 -0.876118
87 N 6 ZZ 0.034607 0.000000 0.000000 0.774485
88 N 6 XY 0.000000 0.000000 0.000000 0.000000
89 N 6 XZ 0.000000 0.000000 0.000000 0.000000
90 N 6 YZ 0.000000 -0.950636 0.085459 0.000000
91 H 7 S 0.465378 0.184446 1.045899 -0.795941
92 H 7 S -0.020619 -0.000990 0.173903 -0.129260
93 H 7 X 0.000000 0.000000 0.000000 0.000000
94 H 7 Y -0.515706 0.021550 -0.694680 0.367501
95 H 7 Z 0.028209 -0.305436 -0.227694 0.244438
96 H 8 S 0.465378 -0.184446 -1.045899 -0.795941
97 H 8 S -0.020619 0.000990 -0.173903 -0.129260
98 H 8 X 0.000000 0.000000 0.000000 0.000000
99 H 8 Y 0.515706 0.021550 -0.694680 -0.367501
100 H 8 Z 0.028209 0.305436 0.227694 0.244438
101 H 9 S -0.465378 -0.184446 -1.045899 0.795941
102 H 9 S 0.020619 0.000990 -0.173903 0.129260
103 H 9 X 0.000000 0.000000 0.000000 0.000000
104 H 9 Y 0.515706 -0.021550 0.694680 -0.367501
105 H 9 Z 0.028209 -0.305436 -0.227694 0.244438
106 H 10 S -0.465378 0.184446 1.045899 0.795941
107 H 10 S 0.020619 -0.000990 0.173903 0.129260
108 H 10 X 0.000000 0.000000 0.000000 0.000000
109 H 10 Y -0.515706 -0.021550 0.694680 0.367501
110 H 10 Z 0.028209 0.305436 0.227694 0.244438
...... END OF RHF CALCULATION ......
STEP CPU TIME = 1.65 TOTAL CPU TIME = 4.1 ( 0.1 MIN)
TOTAL WALL CLOCK TIME= 4.4 SECONDS, CPU UTILIZATION IS 94.74%
----------------------------------------------------------------
PROPERTY VALUES FOR THE RHF SELF-CONSISTENT FIELD WAVEFUNCTION
----------------------------------------------------------------
---------------------------------------
MULLIKEN AND LOWDIN POPULATION ANALYSES
---------------------------------------
----- POPULATIONS IN EACH AO -----
MULLIKEN LOWDIN
1 C 1 S 2.00401 1.86996
2 C 1 S 0.67152 0.48707
3 C 1 S 0.39838 0.27110
4 C 1 X 0.52339 0.47398
5 C 1 Y 0.71868 0.63601
6 C 1 Z 0.74967 0.66259
7 C 1 X 0.41603 0.43860
8 C 1 Y 0.17752 0.31241
9 C 1 Z 0.13026 0.30442
10 C 1 XX 0.02997 0.08492
11 C 1 YY 0.01431 0.19946
12 C 1 ZZ 0.01242 0.20254
13 C 1 XY 0.01269 0.02220
14 C 1 XZ 0.03960 0.02855
15 C 1 YZ 0.00000 0.09119
16 C 2 S 2.00401 1.86996
17 C 2 S 0.67152 0.48707
18 C 2 S 0.39838 0.27110
19 C 2 X 0.52339 0.47398
20 C 2 Y 0.71868 0.63601
21 C 2 Z 0.74967 0.66259
22 C 2 X 0.41603 0.43860
23 C 2 Y 0.17752 0.31241
24 C 2 Z 0.13026 0.30442
25 C 2 XX 0.02997 0.08492
26 C 2 YY 0.01431 0.19946
27 C 2 ZZ 0.01242 0.20254
28 C 2 XY 0.01269 0.02220
29 C 2 XZ 0.03960 0.02855
30 C 2 YZ 0.00000 0.09119
31 C 3 S 2.00401 1.86996
32 C 3 S 0.67152 0.48707
33 C 3 S 0.39838 0.27110
34 C 3 X 0.52339 0.47398
35 C 3 Y 0.71868 0.63601
36 C 3 Z 0.74967 0.66259
37 C 3 X 0.41603 0.43860
38 C 3 Y 0.17752 0.31241
39 C 3 Z 0.13026 0.30442
40 C 3 XX 0.02997 0.08492
41 C 3 YY 0.01431 0.19946
42 C 3 ZZ 0.01242 0.20254
43 C 3 XY 0.01269 0.02220
44 C 3 XZ 0.03960 0.02855
45 C 3 YZ 0.00000 0.09119
46 C 4 S 2.00401 1.86996
47 C 4 S 0.67152 0.48707
48 C 4 S 0.39838 0.27110
49 C 4 X 0.52339 0.47398
50 C 4 Y 0.71868 0.63601
51 C 4 Z 0.74967 0.66259
52 C 4 X 0.41603 0.43860
53 C 4 Y 0.17752 0.31241
54 C 4 Z 0.13026 0.30442
55 C 4 XX 0.02997 0.08492
56 C 4 YY 0.01431 0.19946
57 C 4 ZZ 0.01242 0.20254
58 C 4 XY 0.01269 0.02220
59 C 4 XZ 0.03960 0.02855
60 C 4 YZ 0.00000 0.09119
61 N 5 S 2.00376 1.89364
62 N 5 S 0.78126 0.56638
63 N 5 S 0.77804 0.38904
64 N 5 X 0.56218 0.50942
65 N 5 Y 0.75056 0.66945
66 N 5 Z 0.96511 0.91574
67 N 5 X 0.48311 0.50583
68 N 5 Y 0.29619 0.38244
69 N 5 Z 0.62283 0.61119
70 N 5 XX 0.00572 0.14390
71 N 5 YY 0.00701 0.19223
72 N 5 ZZ 0.00788 0.16374
73 N 5 XY 0.00737 0.01732
74 N 5 XZ 0.02046 0.00742
75 N 5 YZ 0.00000 0.03744
76 N 6 S 2.00376 1.89364
77 N 6 S 0.78126 0.56638
78 N 6 S 0.77804 0.38904
79 N 6 X 0.56218 0.50942
80 N 6 Y 0.75056 0.66945
81 N 6 Z 0.96511 0.91574
82 N 6 X 0.48311 0.50583
83 N 6 Y 0.29619 0.38244
84 N 6 Z 0.62283 0.61119
85 N 6 XX 0.00572 0.14390
86 N 6 YY 0.00701 0.19223
87 N 6 ZZ 0.00788 0.16374
88 N 6 XY 0.00737 0.01732
89 N 6 XZ 0.02046 0.00742
90 N 6 YZ 0.00000 0.03744
91 H 7 S 0.76369 0.60293
92 H 7 S 0.16052 0.23798
93 H 7 X 0.00519 0.01667
94 H 7 Y 0.01753 0.03385
95 H 7 Z 0.00888 0.02097
96 H 8 S 0.76369 0.60293
97 H 8 S 0.16052 0.23798
98 H 8 X 0.00519 0.01667
99 H 8 Y 0.01753 0.03385
100 H 8 Z 0.00888 0.02097
101 H 9 S 0.76369 0.60293
102 H 9 S 0.16052 0.23798
103 H 9 X 0.00519 0.01667
104 H 9 Y 0.01753 0.03385
105 H 9 Z 0.00888 0.02097
106 H 10 S 0.76369 0.60293
107 H 10 S 0.16052 0.23798
108 H 10 X 0.00519 0.01667
109 H 10 Y 0.01753 0.03385
110 H 10 Z 0.00888 0.02097
----- MULLIKEN ATOMIC OVERLAP POPULATIONS -----
(OFF-DIAGONAL ELEMENTS NEED TO BE MULTIPLIED BY 2)
1 2 3 4 5
1 4.6291585
2 -0.1104523 4.6291585
3 0.5423651 -0.0251106 4.6291585
4 -0.0251106 0.5423651 -0.1104523 4.6291585
5 0.5340816 0.5340816 -0.0574253 -0.0574253 6.3853713
6 -0.0574253 -0.0574253 0.5340816 0.5340816 -0.0093354
7 0.4237315 0.0031480 -0.0411247 0.0000864 -0.0225272
8 0.0031480 0.4237315 0.0000864 -0.0411247 -0.0225272
9 -0.0411247 0.0000864 0.4237315 0.0031480 0.0035925
10 0.0000864 -0.0411247 0.0031480 0.4237315 0.0035925
6 7 8 9 10
6 6.3853713
7 0.0035925 0.5928323
8 0.0035925 -0.0002431 0.5928323
9 -0.0225272 -0.0037593 0.0000660 0.5928323
10 -0.0225272 0.0000660 -0.0037593 -0.0002431 0.5928323
TOTAL MULLIKEN AND LOWDIN ATOMIC POPULATIONS
ATOM MULL.POP. CHARGE LOW.POP. CHARGE
1 C 5.898458 0.101542 6.084998 -0.084998
2 C 5.898458 0.101542 6.084998 -0.084998
3 C 5.898458 0.101542 6.084998 -0.084998
4 C 5.898458 0.101542 6.084998 -0.084998
5 N 7.291479 -0.291479 7.005187 -0.005187
6 N 7.291479 -0.291479 7.005187 -0.005187
7 H 0.955802 0.044198 0.912409 0.087591
8 H 0.955802 0.044198 0.912409 0.087591
9 H 0.955802 0.044198 0.912409 0.087591
10 H 0.955802 0.044198 0.912409 0.087591
MULLIKEN SPHERICAL HARMONIC POPULATIONS
ATOM S P D F G H I TOTAL
1 C 3.07 2.72 0.11 0.00 0.00 0.00 0.00 5.90
2 C 3.07 2.72 0.11 0.00 0.00 0.00 0.00 5.90
3 C 3.07 2.72 0.11 0.00 0.00 0.00 0.00 5.90
4 C 3.07 2.72 0.11 0.00 0.00 0.00 0.00 5.90
5 N 3.56 3.68 0.05 0.00 0.00 0.00 0.00 7.29
6 N 3.56 3.68 0.05 0.00 0.00 0.00 0.00 7.29
7 H 0.92 0.03 0.00 0.00 0.00 0.00 0.00 0.96
8 H 0.92 0.03 0.00 0.00 0.00 0.00 0.00 0.96
9 H 0.92 0.03 0.00 0.00 0.00 0.00 0.00 0.96
10 H 0.92 0.03 0.00 0.00 0.00 0.00 0.00 0.96
-------------------------------
BOND ORDER AND VALENCE ANALYSIS BOND ORDER THRESHOLD=0.050
-------------------------------
BOND BOND BOND
ATOM PAIR DIST ORDER ATOM PAIR DIST ORDER ATOM PAIR DIST ORDER
1 3 1.392 1.415 1 4 2.651 0.100 1 5 1.336 1.497
1 7 1.079 0.986 2 3 2.651 0.100 2 4 1.392 1.415
2 5 1.336 1.497 2 8 1.079 0.986 3 6 1.336 1.497
3 9 1.079 0.986 4 6 1.336 1.497 4 10 1.079 0.986
5 6 2.822 0.076
TOTAL BONDED FREE
ATOM VALENCE VALENCE VALENCE
1 C 3.982 3.982 -0.000
2 C 3.982 3.982 0.000
3 C 3.982 3.982 -0.000
4 C 3.982 3.982 0.000
5 N 3.086 3.086 -0.000
6 N 3.086 3.086 -0.000
7 H 0.991 0.991 -0.000
8 H 0.991 0.991 -0.000
9 H 0.991 0.991 0.000
10 H 0.991 0.991 -0.000
---------------------
ELECTROSTATIC MOMENTS
---------------------
POINT 1 X Y Z (BOHR) CHARGE
0.000000 0.000000 0.000000 -0.00 (A.U.)
DX DY DZ /D/ (DEBYE)
0.000000 -0.000000 -0.000000 0.000000
...... END OF PROPERTY EVALUATION ......
STEP CPU TIME = 0.02 TOTAL CPU TIME = 4.2 ( 0.1 MIN)
TOTAL WALL CLOCK TIME= 4.4 SECONDS, CPU UTILIZATION IS 94.12%
---------------------------
COUPLED CLUSTER CALCULATION
---------------------------
CCTYP =CR-CC(Q)
TOTAL NUMBER OF MOS = 104
NUMBER OF OCCUPIED MOS = 21
NUMBER OF FROZEN CORE MOS = 6
NUMBER OF FROZEN VIRTUAL MOS = 0
MAXIMUM CC ITERATIONS = 30
MAXIMUM DIIS ITERATIONS = 5
CONVERGENCE CRITERION FOR CC = 7
AMPLITUDE ACCURACY THRESHOLD = 0.0E+00
--------------------------------------------
PARTIAL TWO ELECTRON INTEGRAL TRANSFORMATION
--------------------------------------------
NUMBER OF CORE MOLECULAR ORBITALS = 6
NUMBER OF OCCUPIED MOLECULAR ORBITALS = 104
TOTAL NUMBER OF MOLECULAR ORBITALS = 104
TOTAL NUMBER OF ATOMIC ORBITALS = 110
THRESHOLD FOR KEEPING TRANSFORMED 2E- INTEGRALS = 1.000E-09
AO INTEGRALS WILL BE READ IN FROM DISK...
EVALUATING THE FROZEN CORE ENERGY...
----- FROZEN CORE ENERGY = -321.9726354040
PLAN A: REQUIREMENTS FOR FULLY IN-MEMORY TRANSFORMATION:
# OF WORDS AVAILABLE = 40000000
# OF WORDS NEEDED = 65932622
PLAN B: REQUIREMENTS FOR THE SEGMENTED TRANSFORMATION:
MINIMUM= 792272 WORDS FOR 1 MOLECULAR ORBITAL PER PASS
MAXIMUM= 65932622 WORDS FOR ALL MOLECULAR ORBITALS IN 1 PASS
( 671550 EXTRA WORDS INCLUDES 1 EXTRA ORBITAL/PASS)
THIS RUN USES= 33026672 WORDS,
DISTRIBUTING 2 PASSES EACH CONTAINING 49 ORBITALS OVER 1 PROCESSORS.
CHOOSING SEGMENTED PARTIAL TRANSFORMATION...
PASS # 1 TOOK 2.84 SECONDS.
PASS # 2 TOOK 3.65 SECONDS.
TOTAL NUMBER OF TRANSFORMED 2E- INTEGRALS KEPT = 1528736
... END OF INTEGRAL TRANSFORMATION ...
STEP CPU TIME = 6.63 TOTAL CPU TIME = 10.8 ( 0.2 MIN)
TOTAL WALL CLOCK TIME= 11.1 SECONDS, CPU UTILIZATION IS 96.86%
-----------------------
COUPLED-CLUSTER PROGRAM
-----------------------
-------------------------------------------------------
P.PIECUCH, S.A.KUCHARSKI, M.WLOCH, K.KOWALSKI, M.MUSIAL
-------------------------------------------------------
*****************************************************************
THE FOLLOWING PAPERS SHOULD BE CITED WHEN USING COUPLED-CLUSTER
OPTIONS:
CCTYP = LCCD, CCD, CCSD, CCSD(T)
P. PIECUCH, S.A. KUCHARSKI, K. KOWALSKI, AND M. MUSIAL,
COMP. PHYS. COMMUN. 149, 71-96 (2002).
CCTYP = R-CC, CR-CC, CCSD(TQ), CR-CC(Q)
P. PIECUCH, S.A. KUCHARSKI, K. KOWALSKI, AND M. MUSIAL,
COMP. PHYS. COMMUN. 149, 71-96 (2002);
K. KOWALSKI AND P. PIECUCH, J. CHEM. PHYS. 113, 18-35 (2000);
K. KOWALSKI AND P. PIECUCH, J. CHEM. PHYS. 113, 5644-5652 (2000).
CCTYP = EOM-CCSD, CR-EOM
P. PIECUCH, S.A. KUCHARSKI, K. KOWALSKI, AND M. MUSIAL,
COMP. PHYS. COMMUN. 149, 71-96 (2002);
K. KOWALSKI AND P. PIECUCH, J. CHEM. PHYS. 120, 1715-1738 (2004);
M. WLOCH, J.R. GOUR, K. KOWALSKI, AND P. PIECUCH,
J. CHEM. PHYS. 122, 214107-1 - 214107-15 (2005).
CCTYP = CR-CCL
P. PIECUCH, S.A. KUCHARSKI, K. KOWALSKI, AND M. MUSIAL,
COMP. PHYS. COMMUN. 149, 71-96 (2002);
P. PIECUCH AND M. WLOCH, J. CHEM. PHYS. 123,
224105-1 - 224105-10 (2005).
CCTYP = CR-EOML
P. PIECUCH, S.A. KUCHARSKI, K. KOWALSKI, AND M. MUSIAL,
COMP. PHYS. COMMUN. 149, 71-96 (2002);
P. PIECUCH, J. R. GOUR, AND M. WLOCH,
INT. J. QUANTUM CHEM. 109, 3268-3304 (2009);
K. KOWALSKI AND P. PIECUCH,
J. CHEM. PHYS. 120, 1715-1738 (2004).
IN ADDITION, THE USE OF CCPRP=.TRUE. IN $CCINP AND/OR THE USE
OF CCPRPE=.TRUE. IN $EOMINP SHOULD REFERENCE
M. WLOCH, J.R. GOUR, K. KOWALSKI, AND P. PIECUCH,
J. CHEM. PHYS. 122, 214107-1 - 214107-15 (2005).
*****************************************************************
THE FOLLOWING CALCULATIONS WILL BE PERFORMED:
CCSD
CCSD[T]
CCSD(T)
R-CCSD[T]
R-CCSD(T)
CR-CCSD[T]
CR-CCSD(T)
THE FOLLOWING ENERGY WILL BE CONSIDERED THE HIGHEST LEVEL: CR-CC(Q)
THE AVAILABLE REPLICATED MEMORY IS 40000000 WORDS.
CONVERGENCE THRESHOLD: 1.0E-07
MAXIMUM NUMBER OF ITERATIONS: 30
MEMORY TO BE USED IN CC INTEGRAL SORTING IS 39483303 WORDS.
THE MINIMUM MEMORY TO ACCOMPLISH SORTING IS 9178592 WORDS.
1528736 NON-ZERO TRANSFORMED 2E- INTEGRALS WERE SORTED INTO FILE 72:
1138 [IJ|KL] TYPE, 20473 [AJ|KL] TYPE,
56142 [AB|IJ] TYPE, 103045 [IA|BJ] TYPE,
564375 [AB|CI] TYPE, 783563 [AB|CD] TYPE.
TRANSFORMED INTEGRAL FILE 9 WAS READ 4 TIMES.
....... DONE WITH CC INTEGRAL PREPARATION .......
STEP CPU TIME = 1.56 TOTAL CPU TIME = 12.4 ( 0.2 MIN)
TOTAL WALL CLOCK TIME= 12.7 SECONDS, CPU UTILIZATION IS 97.01%
MEMORY REQUIRED FOR THE CCSD ITERATIONS IS 15690291 WORDS.
ITER: 1 CCSD CORR. ENERGY: -0.8298968309 CONV.: 1.7240E-02
ITER: 2 CCSD CORR. ENERGY: -0.8508856781 CONV.: -1.0460E-02
ITER: 3 CCSD CORR. ENERGY: -0.8519223739 CONV.: -3.2848E-03
ITER: 4 CCSD CORR. ENERGY: -0.8541557325 CONV.: -1.9589E-02
ITER: 5 CCSD CORR. ENERGY: -0.8542555313 CONV.: -1.9295E-02
ITER: 6 CCSD CORR. ENERGY: -0.8557095376 CONV.: -1.5152E-02
ITER: 7 CCSD CORR. ENERGY: -0.8602468107 CONV.: -2.1066E-03
ITER: 8 CCSD CORR. ENERGY: -0.8610103444 CONV.: 4.4556E-04
ITER: 9 CCSD CORR. ENERGY: -0.8610191917 CONV.: 9.5850E-05
ITER: 10 CCSD CORR. ENERGY: -0.8610298957 CONV.: 4.8623E-05
ITER: 11 CCSD CORR. ENERGY: -0.8610275331 CONV.: 9.4390E-06
ITER: 12 CCSD CORR. ENERGY: -0.8610287350 CONV.: -3.4345E-06
ITER: 13 CCSD CORR. ENERGY: -0.8610284542 CONV.: 1.5055E-06
ITER: 14 CCSD CORR. ENERGY: -0.8610284742 CONV.: 5.6060E-07
ITER: 15 CCSD CORR. ENERGY: -0.8610284853 CONV.: 2.0704E-07
ITER: 16 CCSD CORR. ENERGY: -0.8610284855 CONV.: 7.6005E-08
ITER: 17 CCSD CORR. ENERGY: -0.8610284885 CONV.: 7.6005E-08
THE CCSD ITERATIONS HAVE CONVERGED
MBPT(2) CORRELATION ENERGY: -0.8346177006
CCSD CORRELATION ENERGY: -0.8610284885
T1 DIAGNOSTIC = 0.01113933
NORM OF THE T1 VECTOR= 0.06101265
NORM OF THE T2 VECTOR= 0.51534094
THE FIVE LARGEST T1 AMPLITUDES ARE:
T1 AMPLITUDE IS -0.024401 FOR I= 21 -> A= 39
T1 AMPLITUDE IS -0.018067 FOR I= 19 -> A= 56
T1 AMPLITUDE IS 0.017353 FOR I= 19 -> A= 41
T1 AMPLITUDE IS 0.014782 FOR I= 20 -> A= 24
T1 AMPLITUDE IS -0.014305 FOR I= 16 -> A= 37
THE FIVE LARGEST SPIN-UNIQUE T2 AMPLITUDES ARE:
T2 AMPLITUDE IS -0.093580 FOR I,J= 19 19 -> A,B= 22 22
T2 AMPLITUDE IS -0.092306 FOR I,J= 21 21 -> A,B= 23 23
T2 AMPLITUDE IS 0.051415 FOR I,J= 19 21 -> A,B= 23 22
T2 AMPLITUDE IS 0.043344 FOR I,J= 16 19 -> A,B= 22 28
T2 AMPLITUDE IS -0.041678 FOR I,J= 21 21 -> A,B= 22 22
PRINTED T2(I-ALPHA,J-BETA -> A-ALPHA,B-BETA) VALUES
EQUAL T2(J-ALPHA,I-BETA -> B-ALPHA,A-BETA) AMPLITUDES.
....... DONE WITH CC AMPLITUDE ITERATIONS .......
STEP CPU TIME = 63.68 TOTAL CPU TIME = 76.0 ( 1.3 MIN)
TOTAL WALL CLOCK TIME= 76.6 SECONDS, CPU UTILIZATION IS 99.20%
MEMORY REQUIRED FOR NONITERATIVE TRIPLES (T3WT2 ) IS 13103044 WORDS.
MEMORY REQUIRED FOR NONITERATIVE TRIPLES (INTQUA ) IS 10699862 WORDS.
MEMORY REQUIRED FOR NONITERATIVE TRIPLES (INTRIPL) IS 19276667 WORDS.
MEMORY REQUIRED FOR NONITERATIVE TRIPLES (INTRIP ) IS 10979987 WORDS.
THERE IS ENOUGH MEMORY TO RUN THE MORE EFFICIENT INTRIPL INSTEAD OF INTRIP.
MEMORY REQUIRED FOR NONITERATIVE TRIPLES (INTRIH ) IS 11260112 WORDS.
MEMORY USAGE BY WDEX: 10699862 NEEDED, 39999902 AVAILABLE
MEMORY USAGE BY INTQUAT2: 13799912 NEEDED, 39999902 AVAILABLE
MEMORY REQUIRED FOR NONITERATIVE TRIPLES (T3WT2N ) IS 13101799 WORDS.
MEMORY REQUIRED FOR NONITERATIVE TRIPLES (INTRIP ) IS 10978742 WORDS.
MEMORY REQUIRED FOR NONITERATIVE TRIPLES (INTRIH ) IS 11258867 WORDS.
MEMORY REQUIRED FOR NONITERATIVE TRIPLES (T3WT2N ) IS 13101799 WORDS.
MEMORY REQUIRED FOR NONITERATIVE TRIPLES (T3SQTOT) IS 3673082 WORDS.
MEMORY USAGE BY RANK1: 5221862 NEEDED, 39999902 AVAILABLE
MEMORY USAGE BY T2HPT2: 13950225 NEEDED, 39999902 AVAILABLE
MEMORY USAGE BY T2PPT2: 12400200 NEEDED, 39999902 AVAILABLE
MEMORY USAGE BY T2HHT3: 7860750 NEEDED, 39999902 AVAILABLE
MEMORY USAGE BY T2WWT3: 14799912 NEEDED, 39999902 AVAILABLE
MEMORY REQUIRED FOR COMPLETELY RENOR. QUADS.23250375 WORDS
SUMMARY OF RESULTS
REFERENCE ENERGY: -262.7030109460
MBPT(2) ENERGY: -263.5376286466 CORR.E= -0.8346177006
CCSD ENERGY: -263.5640394345 CORR.E= -0.8610284885
CCSD[T] ENERGY: -263.6034413070 CORR.E= -0.9004303611
CCSD(T) ENERGY: -263.6024317808 CORR.E= -0.8994208348
R-CCSD[T] ENERGY: -263.5934869966 CORR.E= -0.8904760506
R-CCSD(T) ENERGY: -263.5927036682 CORR.E= -0.8896927223
CR-CCSD[T] ENERGY: -263.5904282802 CORR.E= -0.8874173342
CR-CCSD(T) ENERGY: -263.5896914486 CORR.E= -0.8866805026
R-CCSD[T] DENOMINATOR 1.3380351295
R-CCSD(T) DENOMINATOR 1.3393815678
CCSD(TQ),B ENERGY: -263.6028552873 CORR.E= -0.8998443413
R1-CCSD(TQ),A ENERGY: -263.5920040986 CORR.E= -0.8889931526
R1-CCSD(TQ),B ENERGY: -263.5920165738 CORR.E= -0.8890056278
R2-CCSD(TQ),A ENERGY: -263.5925816541 CORR.E= -0.8895707081
R2-CCSD(TQ),B ENERGY: -263.5923704825 CORR.E= -0.8893595365
CR-CCSD(TQ),A ENERGY: -263.5925928754 CORR.E= -0.8895819294
CR-CCSD(TQ),B ENERGY: -263.5924198168 CORR.E= -0.8894088709
CCSD(TQ),A DENOMINATOR 1.3844844309
CCSD(TQ),B DENOMINATOR 1.3874132166
THE FOLLOWING METHOD AND ENERGY WILL BE CONSIDERED THE HIGHEST LEVEL RESULT:
COUPLED-CLUSTER ENERGY E( CR-CC(Q)) = -263.5924198168
..... DONE WITH CC NON-ITERATIVE TRIPLES CORRECTIONS .....
STEP CPU TIME = 1481.34 TOTAL CPU TIME = 1557.4 ( 26.0 MIN)
TOTAL WALL CLOCK TIME= 1560.8 SECONDS, CPU UTILIZATION IS 99.78%
39483401 WORDS OF DYNAMIC MEMORY USED
EXECUTION OF GAMESS TERMINATED NORMALLY Mon Jul 26 16:21:28 2021
DDI: 263640 bytes (0.3 MB / 0 MWords) used by master data server.
----------------------------------------
CPU timing information for all processes
========================================
0: 1488.628 + 68.753 = 1557.382
----------------------------------------
ddikick.x: exited gracefully.
----- accounting info -----
Files used on the master node compute-1-5.local were:
-rw-rw-r-- 1 scemama scemama 187227 Jul 26 15:55 /state/partition1/1174824/pyrazine.dat
-rw-rw-r-- 1 scemama scemama 1060 Jul 26 15:55 /state/partition1/1174824/pyrazine.F05
-rw-rw-r-- 1 scemama scemama 109449728 Jul 26 15:55 /state/partition1/1174824/pyrazine.F08
-rw-rw-r-- 1 scemama scemama 18400448 Jul 26 15:55 /state/partition1/1174824/pyrazine.F09
-rw-rw-r-- 1 scemama scemama 2290400 Jul 26 16:21 /state/partition1/1174824/pyrazine.F10
-rw-rw-r-- 1 scemama scemama 813600 Jul 26 16:11 /state/partition1/1174824/pyrazine.F41
-rw-rw-r-- 1 scemama scemama 55112 Jul 26 16:11 /state/partition1/1174824/pyrazine.F42
-rw-rw-r-- 1 scemama scemama 5580090000 Jul 26 16:20 /state/partition1/1174824/pyrazine.F43
-rw-rw-r-- 1 scemama scemama 100010400 Jul 26 16:11 /state/partition1/1174824/pyrazine.F61
-rw-rw-r-- 1 scemama scemama 3627008 Jul 26 15:56 /state/partition1/1174824/pyrazine.F70
-rw-rw-r-- 1 scemama scemama 124101600 Jul 26 15:56 /state/partition1/1174824/pyrazine.F71
-rw-rw-r-- 1 scemama scemama 1116128224 Jul 26 15:55 /state/partition1/1174824/pyrazine.F72
-rw-rw-r-- 1 scemama scemama 39840 Jul 26 15:57 /state/partition1/1174824/pyrazine.F73
-rw-rw-r-- 1 scemama scemama 86801400 Jul 26 15:57 /state/partition1/1174824/pyrazine.F74
-rw-rw-r-- 1 scemama scemama 6083813680 Jul 26 15:58 /state/partition1/1174824/pyrazine.F75
-rw-rw-r-- 1 scemama scemama 8964000 Jul 26 15:58 /state/partition1/1174824/pyrazine.F76
-rw-rw-r-- 1 scemama scemama 274457760 Jul 26 15:58 /state/partition1/1174824/pyrazine.F77
-rw-rw-r-- 1 scemama scemama 99201600 Jul 26 16:11 /state/partition1/1174824/pyrazine.F79
-rw-rw-r-- 1 scemama scemama 1215000 Jul 26 15:56 /state/partition1/1174824/pyrazine.F85
-rw-rw-r-- 1 scemama scemama 379666568 Jul 26 16:11 /state/partition1/1174824/pyrazine.F86