diff --git a/cyclopentadiene/cc-pvdz/cyclopentadiene.localized.nofci.out b/cyclopentadiene/cc-pvdz/cyclopentadiene.localized.nofci.out index 9cb0006..b41fd94 100644 --- a/cyclopentadiene/cc-pvdz/cyclopentadiene.localized.nofci.out +++ b/cyclopentadiene/cc-pvdz/cyclopentadiene.localized.nofci.out @@ -4224,3 +4224,260 @@ Iter Energy S^2 Residual 5 -193.4296116147 0.003974 0.237E-07 6 -193.4296117671 0.003975 0.765E-08 7 -193.4296118138 0.003975 0.264E-08 + 8 -193.4296118286 0.003976 0.775E-09 + 9 -193.4296118328 0.003976 0.220E-09 + 10 -193.4296118340 0.003976 0.571E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 44.587967 GB ] [ VIRT MEM : 69.797554 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 88964.188674 s ] [ CPU TIME: 6058573.292027 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 24.119354 GB ] [ VIRT MEM : 45.576344 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 88966.139211 s ] [ CPU TIME: 6058579.707929 s ] <<<<< .. + +* Energy of state 1 -193.4296118339588 +* S^2 of state 1 0.3975622262795956E-02 +* Saved determinants 20971520 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 23.090946 GB ] [ VIRT MEM : 41.725121 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 89244.006076 s ] [ CPU TIME: 6062054.912815 s ] <<<<< .. + +* Number of generators 20966343 + +.. >>>>> [ RES MEM : 23.090946 GB ] [ VIRT MEM : 41.725121 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 89244.051342 s ] [ CPU TIME: 6062058.164126 s ] <<<<< .. + +* Number of selectors 20966343 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -193.4296118339588 + +.. >>>>> [ RES MEM : 26.214996 GB ] [ VIRT MEM : 44.381382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 89262.120065 s ] [ CPU TIME: 6062799.317476 s ] <<<<< .. + +* Number of generators 20966343 + +.. >>>>> [ RES MEM : 26.214996 GB ] [ VIRT MEM : 44.381382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 89262.163527 s ] [ CPU TIME: 6062799.360775 s ] <<<<< .. + +* Number of selectors 20966343 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 21625706 +* Number of fragmented tasks 15852 +* Number of threads for PT2 72 +* Memory (Gb) 25.53274384740740 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.4963694357 0.190E-02 0.5035939248 0.0090863436 2692.5852 + 4 -193.4960841753 0.132E-02 0.5002411210 0.0090614589 3084.5728 + 5 -193.4960249660 0.106E-02 0.4995359545 0.0090564839 3566.0441 + 6 -193.4965300026 0.990E-03 0.5037564664 0.0091239237 3962.0861 + 7 -193.4964309918 0.842E-03 0.5034044052 0.0091031614 4272.6824 + 8 -193.4965471681 0.735E-03 0.5044536067 0.0091131200 4619.8861 + 9 -193.4963857018 0.669E-03 0.5030675807 0.0090953458 5211.7292 + 11 -193.4966977410 0.645E-03 0.5065475546 0.0091216924 5288.0573 + 12 -193.4966803626 0.598E-03 0.5072443831 0.0091105862 5639.5421 + 14 -193.4967637933 0.515E-03 0.5076037119 0.0091242751 5972.8051 + 15 -193.4966630909 0.490E-03 0.5065033031 0.0091167115 6092.5820 + 16 -193.4964572041 0.496E-03 0.5044850905 0.0090957245 6334.2452 + 18 -193.4965192028 0.449E-03 0.5048792129 0.0091053658 6617.5762 + 19 -193.4965608372 0.427E-03 0.5057760669 0.0091028882 6903.3901 + 20 -193.4966913298 0.423E-03 0.5068340765 0.0091185311 7238.8875 + 21 -193.4965902740 0.415E-03 0.5057343850 0.0091095541 7399.3191 + 24 -193.4965574550 0.382E-03 0.5058109753 0.0090993441 7492.3511 + 25 -193.4964619731 0.379E-03 0.5051082911 0.0090864994 7605.2548 + 26 -193.4967294372 0.432E-03 0.5071821459 0.0091227503 7693.5971 + 27 -193.4966536278 0.422E-03 0.5067364643 0.0091100390 8198.2150 + 28 -193.4966325239 0.407E-03 0.5066610097 0.0091056867 8393.1403 + 29 -193.4965506405 0.396E-03 0.5061560856 0.0090924541 8799.6722 + 30 -193.4965545248 0.382E-03 0.5063378026 0.0090907555 8812.4332 + 31 -193.4965736368 0.352E-03 0.5065076034 0.0090926077 8828.0941 + 32 -193.4964737551 0.355E-03 0.5056069718 0.0090808269 9378.6772 + 34 -193.4966093186 0.352E-03 0.5072049502 0.0090894841 9612.6218 + 35 -193.4966346903 0.343E-03 0.5074709266 0.0090915033 9847.8892 + 38 -193.4964052295 0.305E-03 0.5053504099 0.0090659547 10115.3261 + 41 -193.4963140530 0.294E-03 0.5045296689 0.0090554788 10371.0394 + 42 -193.4963538560 0.289E-03 0.5049192116 0.0090592091 10702.9002 + 43 -193.4963737943 0.283E-03 0.5049433422 0.0090639427 10858.1522 + 46 -193.4962251992 0.277E-03 0.5035738601 0.0090473584 11054.7646 + 47 -193.4962632463 0.268E-03 0.5037845708 0.0090545958 11392.8072 + 51 -193.4963227620 0.249E-03 0.5044681041 0.0090591089 11516.8901 + 52 -193.4963557054 0.246E-03 0.5047763531 0.0090629374 11800.2502 + 54 -193.4962798573 0.238E-03 0.5040098731 0.0090558860 11834.9962 + 55 -193.4962606311 0.234E-03 0.5038664810 0.0090532672 11886.2751 + 56 -193.4962589053 0.230E-03 0.5038424493 0.0090532768 12136.5910 + 60 -193.4961818818 0.220E-03 0.5031295996 0.0090443278 12274.3552 + 62 -193.4962298114 0.215E-03 0.5036602541 0.0090480768 12460.9198 + 63 -193.4962551924 0.213E-03 0.5038250239 0.0090520443 12535.3322 + 64 -193.4962966815 0.214E-03 0.5041867653 0.0090571544 12677.4082 + 65 -193.4962932272 0.210E-03 0.5042031145 0.0090560353 12712.2034 + 67 -193.4962516771 0.206E-03 0.5039204501 0.0090499126 12743.2311 + 69 -193.4962536678 0.204E-03 0.5038865892 0.0090508253 12835.3387 + 70 -193.4962303239 0.199E-03 0.5036269307 0.0090490310 12988.5651 + 71 -193.4962683396 0.200E-03 0.5040080827 0.0090529365 12999.0241 + 73 -193.4962279776 0.197E-03 0.5036557852 0.0090481552 13033.1193 + 74 -193.4962717159 0.199E-03 0.5040694852 0.0090529426 13163.9401 + 75 -193.4962854285 0.197E-03 0.5041936317 0.0090545030 13259.8581 + 76 -193.4962840064 0.194E-03 0.5041523226 0.0090547767 13262.7076 + 77 -193.4962886640 0.192E-03 0.5042112430 0.0090554968 13379.4561 + 78 -193.4962860173 0.189E-03 0.5042540573 0.0090541454 13482.2281 + 80 -193.4963358664 0.185E-03 0.5045704854 0.0090621769 13581.2321 + 81 -193.4963194321 0.184E-03 0.5044572129 0.0090597581 13618.0212 + 82 -193.4963630036 0.187E-03 0.5047660151 0.0090661870 13720.0790 + 83 -193.4963536248 0.185E-03 0.5046452368 0.0090658188 13743.6432 + 84 -193.4963585858 0.183E-03 0.5046530738 0.0090667901 13835.0861 + 85 -193.4963809244 0.182E-03 0.5049126178 0.0090683825 14051.0612 + 87 -193.4963758312 0.178E-03 0.5048309296 0.0090682739 14091.9471 + 88 -193.4963610020 0.177E-03 0.5047028251 0.0090662900 14109.9751 + 89 -193.4964112394 0.170E-03 0.5050666174 0.0090730279 14162.4146 + 90 -193.4964284135 0.169E-03 0.5052111261 0.0090749551 14193.9515 + 91 -193.4964156371 0.168E-03 0.5051040797 0.0090733876 14347.9541 + 93 -193.4964315259 0.166E-03 0.5052356120 0.0090755474 14494.3431 + 96 -193.4964687035 0.166E-03 0.5055263894 0.0090803393 14566.5253 + 97 -193.4964551616 0.165E-03 0.5053657235 0.0090792788 14684.2872 + 98 -193.4964501335 0.170E-03 0.5055218956 0.0090757179 14742.3471 + 100 -193.4964396766 0.168E-03 0.5054345610 0.0090743939 14775.4282 + 101 -193.4964597927 0.168E-03 0.5056626751 0.0090761670 14816.6145 + 102 -193.4964657333 0.166E-03 0.5057212152 0.0090768700 14818.8750 + 103 -193.4964698474 0.165E-03 0.5057941953 0.0090770483 14943.4842 + 104 -193.4964602125 0.164E-03 0.5057629031 0.0090753789 15033.8022 + 105 -193.4964491018 0.162E-03 0.5057040498 0.0090735163 15139.0711 + 106 -193.4964248141 0.163E-03 0.5054863800 0.0090705399 15153.1614 + 107 -193.4964120002 0.162E-03 0.5053512774 0.0090695490 15180.4701 + 108 -193.4964156949 0.160E-03 0.5053845528 0.0090697625 15191.1076 + 109 -193.4964084697 0.159E-03 0.5052799595 0.0090695341 15234.2631 + 110 -193.4963918221 0.157E-03 0.5051912804 0.0090665849 15341.9933 + 111 -193.4964048637 0.156E-03 0.5052998251 0.0090682229 15392.4352 + 112 -193.4963881384 0.156E-03 0.5051452439 0.0090663081 15405.7711 + 113 -193.4963972612 0.154E-03 0.5052310430 0.0090673512 15507.3411 + 114 -193.4964093631 0.154E-03 0.5053724146 0.0090682795 15584.3611 + 115 -193.4963896141 0.154E-03 0.5051745955 0.0090662518 15656.3233 + 117 -193.4963724017 0.152E-03 0.5050007823 0.0090646591 15680.8854 + 118 -193.4963632626 0.151E-03 0.5049217038 0.0090635578 15717.5582 + 119 -193.4963451762 0.150E-03 0.5047705727 0.0090613264 15768.0921 + 120 -193.4963504190 0.149E-03 0.5047792473 0.0090624879 15854.2671 + 121 -193.4963439881 0.148E-03 0.5046767659 0.0090623502 15883.7712 + 122 -193.4963465555 0.147E-03 0.5047067947 0.0090625361 15997.7437 + 123 -193.4963452531 0.146E-03 0.5046872572 0.0090623990 16043.3710 + 124 -193.4963847553 0.140E-03 0.5048850335 0.0090695473 16176.1951 + 125 -193.4963819018 0.139E-03 0.5048327513 0.0090695849 16300.9751 + 126 -193.4963920282 0.138E-03 0.5049533882 0.0090705467 16355.2883 + 127 -193.4963668031 0.139E-03 0.5046792366 0.0090685100 16363.6871 + 128 -193.4963553297 0.139E-03 0.5045502263 0.0090675805 16476.9781 + 129 -193.4963573212 0.137E-03 0.5045625713 0.0090678155 16500.9931 + 131 -193.4963538824 0.136E-03 0.5045494780 0.0090671767 16567.9211 + 132 -193.4963541107 0.135E-03 0.5045322803 0.0090673692 16602.6011 + 133 -193.4963451206 0.134E-03 0.5044501460 0.0090665095 16614.5849 + 134 -193.4963805598 0.128E-03 0.5047103717 0.0090716445 16698.3017 + 135 -193.4963875972 0.127E-03 0.5047660238 0.0090726060 16759.8704 + 136 -193.4963667249 0.128E-03 0.5045807411 0.0090701931 16769.8459 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 27.603535 GB ] [ VIRT MEM : 45.547760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 106113.287213 s ] [ CPU TIME: 7261543.534381 s ] <<<<< .. + +* Number of generators 20966343 + +.. >>>>> [ RES MEM : 27.603535 GB ] [ VIRT MEM : 45.547760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 106113.333775 s ] [ CPU TIME: 7261543.580446 s ] <<<<< .. + +* Number of selectors 20966343 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9037673260972987 + +Summary at N_det = 20971520 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.42961183 +# PT2 -0.06675489 0.00012760 +# rPT2 -0.06615485 0.00012646 +# +# E+PT2 -193.49636672 0.00012760 +# E+rPT2 -193.49576669 0.00012646 +# ============ ============================= + + N_det = 20971520 + N_states = 1 + + * State 1 + < S^2 > = 3.975622262795956E-003 + E = -193.429611833959 + Variance = 0.504580741100817 + PT norm = 9.523756163679550E-002 + PT2 = -6.675489091223681E-002 + rPT2 = -6.615485361239250E-002 + E+PT2 = -193.496366724871 +/- 1.276042550843628E-004 + E+rPT2 = -193.495766687571 +/- 1.264572632816179E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015661540 + Ven = -762.961022528721 + Vee = 219.393909637089 + Vecp = 0.000000000000000E+000 + T = 193.247485396133 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0678 -193.52629971 + -0.0686 -193.54040380 + -0.0696 -193.54494887 + -0.0702 -193.55333285 + -0.0728 -193.54959990 + -0.0768 -193.55079071 + -0.0839 -193.55050211 + =========== =================== + +* Number of unique beta determinants 3027048 +* Number of unique alpha determinants 3060083 + +.. >>>>> [ RES MEM : 33.496841 GB ] [ VIRT MEM : 53.174080 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123090.568709 s ] [ CPU TIME: 8416146.700372 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 41943040 +* Number of threads for diagonalization 72 +* Memory(Gb) 64.66508470475674 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.4296118344 0.003976 0.487E-03 + 2 -193.4335723434 0.004961 0.503E-04 diff --git a/cyclopentadiene/cc-pvdz/slurm-498044.out b/cyclopentadiene/cc-pvdz/slurm-498044.out index ef17e70..7389029 100644 --- a/cyclopentadiene/cc-pvdz/slurm-498044.out +++ b/cyclopentadiene/cc-pvdz/slurm-498044.out @@ -18861,3 +18861,4568 @@ Virtual orbitals after localization : Average : 5.0340364786; Median : 3.314179 20.34 % in 1919 seconds 20.72 % in 1930 seconds 21.48 % in 1957 seconds +21.86 % in 1973 seconds +22.24 % in 1991 seconds +22.43 % in 2006 seconds +23.19 % in 2016 seconds +23.57 % in 2034 seconds +23.76 % in 2044 seconds +24.33 % in 2057 seconds +24.71 % in 2077 seconds +24.90 % in 2089 seconds +25.67 % in 2103 seconds +26.05 % in 2122 seconds +26.24 % in 2132 seconds +26.81 % in 2144 seconds +27.19 % in 2164 seconds +27.95 % in 2184 seconds +28.33 % in 2204 seconds +28.52 % in 2215 seconds +29.28 % in 2230 seconds +29.85 % in 2251 seconds +30.04 % in 2268 seconds +30.23 % in 2279 seconds +30.42 % in 2289 seconds +30.61 % in 2301 seconds +30.80 % in 2312 seconds +31.56 % in 2322 seconds +32.51 % in 2339 seconds +32.89 % in 2356 seconds +33.08 % in 2366 seconds +33.27 % in 2377 seconds +33.84 % in 2387 seconds +34.60 % in 2401 seconds +34.98 % in 2421 seconds +35.74 % in 2437 seconds +36.12 % in 2453 seconds +36.31 % in 2467 seconds +36.50 % in 2479 seconds +37.45 % in 2490 seconds +37.83 % in 2502 seconds +38.02 % in 2512 seconds +38.21 % in 2524 seconds +38.97 % in 2536 seconds +39.35 % in 2550 seconds +39.73 % in 2570 seconds +40.49 % in 2581 seconds +41.06 % in 2597 seconds +41.44 % in 2618 seconds +42.40 % in 2628 seconds +42.78 % in 2646 seconds +43.35 % in 2665 seconds +43.92 % in 2678 seconds +44.30 % in 2690 seconds +44.49 % in 2703 seconds +44.68 % in 2719 seconds +44.87 % in 2730 seconds +45.06 % in 2742 seconds +46.01 % in 2753 seconds +46.77 % in 2763 seconds +47.15 % in 2780 seconds +47.72 % in 2794 seconds +48.10 % in 2815 seconds +48.86 % in 2825 seconds +49.43 % in 2838 seconds +49.62 % in 2848 seconds +50.19 % in 2858 seconds +50.57 % in 2876 seconds +50.76 % in 2888 seconds +51.52 % in 2898 seconds +52.28 % in 2913 seconds +52.66 % in 2926 seconds +52.85 % in 2940 seconds +53.04 % in 2952 seconds +53.80 % in 2962 seconds +54.56 % in 2973 seconds +55.13 % in 2986 seconds +55.51 % in 3006 seconds +55.70 % in 3017 seconds +56.65 % in 3027 seconds +57.22 % in 3039 seconds +57.60 % in 3059 seconds +57.79 % in 3069 seconds +58.75 % in 3079 seconds +59.32 % in 3093 seconds +59.70 % in 3110 seconds +59.89 % in 3123 seconds +60.08 % in 3134 seconds +61.03 % in 3145 seconds +61.79 % in 3156 seconds +62.36 % in 3166 seconds +62.74 % in 3184 seconds +62.93 % in 3205 seconds +63.12 % in 3226 seconds +63.50 % in 3249 seconds +63.88 % in 3263 seconds +64.07 % in 3275 seconds +64.26 % in 3294 seconds +64.45 % in 3310 seconds +65.21 % in 3320 seconds +65.97 % in 3331 seconds +66.73 % in 3342 seconds +67.49 % in 3353 seconds +68.25 % in 3364 seconds +69.01 % in 3376 seconds +69.39 % in 3390 seconds +69.77 % in 3410 seconds +70.53 % in 3421 seconds +71.29 % in 3431 seconds +71.67 % in 3442 seconds +71.86 % in 3453 seconds +72.05 % in 3465 seconds +72.81 % in 3476 seconds +73.57 % in 3486 seconds +73.95 % in 3496 seconds +74.33 % in 3512 seconds +74.52 % in 3522 seconds +74.90 % in 3532 seconds +75.86 % in 3542 seconds +76.62 % in 3556 seconds +76.81 % in 3567 seconds +77.57 % in 3579 seconds +77.95 % in 3597 seconds +78.71 % in 3612 seconds +79.09 % in 3631 seconds +79.47 % in 3642 seconds +80.42 % in 3653 seconds +81.18 % in 3666 seconds +81.37 % in 3676 seconds +81.75 % in 3693 seconds +82.70 % in 3703 seconds +83.46 % in 3713 seconds +83.65 % in 3727 seconds +84.22 % in 3737 seconds +84.60 % in 3750 seconds +84.98 % in 3771 seconds +85.93 % in 3782 seconds +86.69 % in 3793 seconds +87.26 % in 3816 seconds +87.64 % in 3833 seconds +88.02 % in 3852 seconds +88.21 % in 3866 seconds +88.78 % in 3876 seconds +89.73 % in 3886 seconds +90.49 % in 3896 seconds +91.25 % in 3907 seconds +92.02 % in 3922 seconds +92.21 % in 3933 seconds +92.97 % in 3943 seconds +93.35 % in 3957 seconds +93.54 % in 3968 seconds +93.73 % in 3980 seconds +94.68 % in 3991 seconds +95.44 % in 4002 seconds +95.82 % in 4013 seconds +96.20 % in 4031 seconds +97.15 % in 4043 seconds +97.72 % in 4056 seconds +98.10 % in 4077 seconds +98.86 % in 4087 seconds +99.62 % in 4097 seconds + 0.19 % in 18 seconds + 0.38 % in 35 seconds + 0.57 % in 51 seconds + 0.76 % in 64 seconds + 1.14 % in 86 seconds + 1.52 % in 104 seconds + 1.71 % in 119 seconds + 1.90 % in 129 seconds + 2.28 % in 149 seconds + 2.66 % in 174 seconds + 2.85 % in 187 seconds + 3.04 % in 200 seconds + 3.23 % in 211 seconds + 3.42 % in 221 seconds + 3.61 % in 234 seconds + 3.99 % in 252 seconds + 4.18 % in 266 seconds + 4.37 % in 281 seconds + 4.75 % in 301 seconds + 4.94 % in 314 seconds + 5.13 % in 324 seconds + 5.32 % in 338 seconds + 5.51 % in 351 seconds + 5.70 % in 364 seconds + 5.89 % in 376 seconds + 6.08 % in 389 seconds + 6.27 % in 403 seconds + 6.46 % in 416 seconds + 6.65 % in 429 seconds + 6.84 % in 444 seconds + 7.03 % in 459 seconds + 7.22 % in 519 seconds + 7.41 % in 588 seconds + 7.60 % in 656 seconds + 7.79 % in 726 seconds + 7.98 % in 794 seconds + 8.17 % in 864 seconds + 8.37 % in 935 seconds + 8.56 % in 1003 seconds + 8.75 % in 1072 seconds + 8.94 % in 1141 seconds + 9.13 % in 1207 seconds + 9.32 % in 1275 seconds + 9.51 % in 1345 seconds + 9.70 % in 1411 seconds + 9.89 % in 1438 seconds +10.27 % in 1457 seconds +10.65 % in 1473 seconds +10.84 % in 1486 seconds +11.22 % in 1506 seconds +11.41 % in 1517 seconds +11.79 % in 1532 seconds +11.98 % in 1546 seconds +12.36 % in 1561 seconds +12.74 % in 1578 seconds +12.93 % in 1591 seconds +13.31 % in 1603 seconds +13.69 % in 1621 seconds +13.88 % in 1631 seconds +14.07 % in 1644 seconds +14.64 % in 1663 seconds +14.83 % in 1673 seconds +15.21 % in 1687 seconds +15.40 % in 1700 seconds +15.59 % in 1713 seconds +16.35 % in 1729 seconds +16.54 % in 1749 seconds +16.92 % in 1767 seconds +17.30 % in 1781 seconds +17.49 % in 1793 seconds +17.87 % in 1812 seconds +18.06 % in 1826 seconds +18.25 % in 1840 seconds +19.20 % in 1857 seconds +19.39 % in 1869 seconds +19.77 % in 1886 seconds +20.15 % in 1904 seconds +20.34 % in 1917 seconds +20.72 % in 1928 seconds +21.48 % in 1954 seconds +21.86 % in 1971 seconds +22.24 % in 1988 seconds +22.43 % in 2002 seconds +23.19 % in 2012 seconds +23.57 % in 2031 seconds +23.76 % in 2041 seconds +24.33 % in 2054 seconds +24.71 % in 2074 seconds +24.90 % in 2085 seconds +25.67 % in 2101 seconds +26.05 % in 2119 seconds +26.43 % in 2130 seconds +27.00 % in 2149 seconds +27.19 % in 2161 seconds +27.95 % in 2180 seconds +28.33 % in 2201 seconds +28.71 % in 2212 seconds +29.28 % in 2225 seconds +29.85 % in 2248 seconds +30.04 % in 2264 seconds +30.23 % in 2276 seconds +30.42 % in 2287 seconds +30.61 % in 2298 seconds +30.80 % in 2311 seconds +31.75 % in 2322 seconds +32.51 % in 2338 seconds +32.89 % in 2355 seconds +33.08 % in 2365 seconds +33.27 % in 2377 seconds +33.84 % in 2387 seconds +34.60 % in 2402 seconds +34.98 % in 2422 seconds +35.74 % in 2438 seconds +35.93 % in 2448 seconds +36.31 % in 2467 seconds +36.50 % in 2479 seconds +37.45 % in 2489 seconds +37.83 % in 2500 seconds +38.02 % in 2510 seconds +38.21 % in 2525 seconds +38.97 % in 2537 seconds +39.35 % in 2551 seconds +39.73 % in 2572 seconds +40.49 % in 2583 seconds +41.06 % in 2599 seconds +41.44 % in 2620 seconds +42.40 % in 2631 seconds +42.59 % in 2641 seconds +42.97 % in 2651 seconds +43.35 % in 2667 seconds +43.92 % in 2680 seconds +44.30 % in 2692 seconds +44.49 % in 2705 seconds +44.68 % in 2721 seconds +44.87 % in 2731 seconds +45.06 % in 2742 seconds +46.01 % in 2753 seconds +46.77 % in 2763 seconds +47.15 % in 2779 seconds +47.72 % in 2793 seconds +48.10 % in 2813 seconds +48.86 % in 2823 seconds +49.43 % in 2837 seconds +49.81 % in 2848 seconds +50.38 % in 2863 seconds +50.57 % in 2874 seconds +50.76 % in 2886 seconds +51.52 % in 2896 seconds +52.28 % in 2912 seconds +52.66 % in 2925 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11211 seconds +43.90 % in 11234 seconds +44.00 % in 11246 seconds +44.10 % in 11258 seconds +44.19 % in 11268 seconds +44.38 % in 11297 seconds +44.48 % in 11331 seconds +44.57 % in 11367 seconds diff --git a/pyrazine/cc-pvdz/pyrazine.nofci.out b/pyrazine/cc-pvdz/pyrazine.nofci.out index d4cfe35..0006f57 100644 --- a/pyrazine/cc-pvdz/pyrazine.nofci.out +++ b/pyrazine/cc-pvdz/pyrazine.nofci.out @@ -4900,3 +4900,284 @@ Iter Energy S^2 Residual ========== ================= =========== =============== =============== ================= Samples Energy Stat. Err Variance Norm Seconds ========== ================= =========== =============== =============== ================= + 3 -263.5728946963 0.414E-02 0.7149091008 0.0211196490 6975.1119 + 4 -263.5735255444 0.284E-02 0.7188911660 0.0212402531 8605.6035 + 5 -263.5749416718 0.263E-02 0.7275540694 0.0215004316 10007.3149 + 6 -263.5746200714 0.214E-02 0.7263171611 0.0214258498 11538.8150 + 7 -263.5745599030 0.180E-02 0.7260022468 0.0214220312 12802.5844 + 8 -263.5737482990 0.176E-02 0.7191001079 0.0213451847 14328.5430 + 9 -263.5735478056 0.160E-02 0.7178039173 0.0213103735 15801.7358 + 10 -263.5738366831 0.145E-02 0.7204903202 0.0213340571 16222.9351 + 11 -263.5738954545 0.129E-02 0.7214322299 0.0213300532 16601.7851 + 12 -263.5736944353 0.119E-02 0.7216783670 0.0212595698 17794.2274 + 13 -263.5736705563 0.109E-02 0.7221769366 0.0212438329 18352.6296 + 14 -263.5738401439 0.103E-02 0.7230527712 0.0212795587 19599.4105 + 15 -263.5739428850 0.948E-03 0.7230448862 0.0213106093 20505.1435 + 16 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69934.6656 + 184 -263.5756654426 0.258E-03 0.7347336568 0.0215590026 69989.1705 + 185 -263.5757025035 0.259E-03 0.7349703959 0.0215649962 70064.2715 + 186 -263.5757039948 0.258E-03 0.7349576474 0.0215655422 70211.3815 + 187 -263.5756893711 0.257E-03 0.7348331200 0.0215640828 70221.8205 + 188 -263.5757069448 0.256E-03 0.7349017162 0.0215678705 70483.3976 + 189 -263.5756753959 0.252E-03 0.7348069338 0.0215603261 70530.0065 + 190 -263.5756761919 0.251E-03 0.7348606401 0.0215597063 70794.7407 + 191 -263.5757363251 0.256E-03 0.7351802928 0.0215714603 70940.1280 + 192 -263.5757380737 0.255E-03 0.7352544066 0.0215703240 71085.5965 + 193 -263.5757330091 0.254E-03 0.7352652487 0.0215684785 71301.6216 + 194 -263.5756994426 0.255E-03 0.7350644266 0.0215630188 71447.0718 + 195 -263.5756998508 0.253E-03 0.7350592883 0.0215636900 71609.0527 + 196 -263.5756803490 0.253E-03 0.7348975387 0.0215612270 71740.6513 + 198 -263.5757112786 0.251E-03 0.7351446180 0.0215648131 71946.7818 + 199 -263.5757179108 0.250E-03 0.7351761439 0.0215661710 71995.5297 + 201 -263.5757087596 0.248E-03 0.7351287214 0.0215641382 72214.4448 + 202 -263.5757181474 0.247E-03 0.7351957591 0.0215653862 72219.9680 + 203 -263.5757353304 0.247E-03 0.7351778340 0.0215715734 72423.9367 + 205 -263.5757621833 0.246E-03 0.7353455127 0.0215763326 72516.8746 + 206 -263.5757271878 0.247E-03 0.7350966031 0.0215713317 72581.0677 + 207 -263.5756979198 0.248E-03 0.7348924266 0.0215670258 72804.0986 + 208 -263.5757164428 0.247E-03 0.7349830056 0.0215704978 72846.5895 + 209 -263.5756997575 0.246E-03 0.7348273117 0.0215695780 72921.2865 + 210 -263.5756947823 0.245E-03 0.7347699112 0.0215692179 72952.0726 + 211 -263.5756805765 0.245E-03 0.7346827898 0.0215666843 73181.3978 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 56.167950 GB ] [ VIRT MEM : 61.988628 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 730941.715821 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 83833851 + +.. >>>>> [ RES MEM : 56.167950 GB ] [ VIRT MEM : 61.988628 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 730941.895042 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 83833851 +* Number of comb teeth 100 +* pt2_n_tasks_max 870 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8620095861217926 + +Summary at N_det = 83885877 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -263.45301184 +# PT2 -0.12264899 0.00024425 +# rPT2 -0.12006007 0.00023910 +# +# E+PT2 -263.57566083 0.00024425 +# E+rPT2 -263.57307191 0.00023910 +# ============ ============================= + + N_det = 83885877 + N_states = 1 + + * State 1 + < S^2 > = 1.241196770357880E-002 + E = -263.453011840889 + Variance = 0.734558927106780 + PT norm = 0.146845296610169 + PT2 = -0.122648993556116 + rPT2 = -0.120060073228205 + E+PT2 = -263.575660834445 +/- 2.442522918564238E-004 + E+rPT2 = -263.573071914117 +/- 2.390965241228987E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 209.082044377177 + Ven = -1032.17026075165 + Vee = 296.471026473254 + Vecp = 0.000000000000000E+000 + T = 263.164178060331 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1273 -263.59320573 + -0.1303 -263.60065432 + -0.1327 -263.59917906 + -0.1335 -263.60199443 + -0.1348 -263.60293424 + -0.1364 -263.60190167 + -0.1384 -263.60323313 + =========== =================== + +* Number of unique beta determinants 6991144 +* Number of unique alpha determinants 7068922 diff --git a/pyrazine/cc-pvdz/slurm-493750.out b/pyrazine/cc-pvdz/slurm-493750.out index 8d33421..c4341ab 100644 --- a/pyrazine/cc-pvdz/slurm-493750.out +++ b/pyrazine/cc-pvdz/slurm-493750.out @@ -34185,3 +34185,6339 @@ 0.11 % in 6929 seconds 0.11 % in 6939 seconds 0.11 % in 6949 seconds + 0.11 % in 6959 seconds + 0.11 % in 6969 seconds + 0.11 % in 6979 seconds + 0.11 % in 6989 seconds + 0.11 % in 6999 seconds + 0.11 % in 7009 seconds + 0.11 % in 7021 seconds + 0.11 % in 7031 seconds + 0.11 % in 7041 seconds + 0.11 % in 7052 seconds + 0.11 % in 7063 seconds + 0.11 % in 7073 seconds + 0.11 % in 7083 seconds + 0.11 % in 7093 seconds + 0.11 % in 7103 seconds + 0.11 % in 7113 seconds + 0.11 % in 7123 seconds + 0.11 % in 7133 seconds + 0.11 % in 7143 seconds + 0.11 % in 7153 seconds + 0.11 % in 7163 seconds + 0.11 % in 7173 seconds + 0.11 % in 7183 seconds + 0.11 % in 7193 seconds + 0.11 % in 7203 seconds + 0.11 % in 7214 seconds + 0.11 % in 7225 seconds + 0.11 % in 7235 seconds + 0.11 % in 7245 seconds + 0.11 % in 7256 seconds + 0.11 % in 7266 seconds + 0.11 % in 7276 seconds + 0.11 % in 7287 seconds + 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diff --git a/pyrrole/cc-pvdz/pyrrole.nofci.out b/pyrrole/cc-pvdz/pyrrole.nofci.out index e43fab9..691ad99 100644 --- a/pyrrole/cc-pvdz/pyrrole.nofci.out +++ b/pyrrole/cc-pvdz/pyrrole.nofci.out @@ -4734,3 +4734,5 @@ Iter Energy S^2 Residual 3 -209.4721265579 0.009562 0.229E-04 4 -209.4721630104 0.009674 0.931E-06 5 -209.4721661663 0.009680 0.235E-06 + 6 -209.4721666723 0.009682 0.371E-07 + 7 -209.4721667892 0.009681 0.657E-08 diff --git a/pyrrole/cc-pvdz/slurm-494951.out b/pyrrole/cc-pvdz/slurm-494951.out index 82e8382..9120661 100644 --- a/pyrrole/cc-pvdz/slurm-494951.out +++ b/pyrrole/cc-pvdz/slurm-494951.out @@ -25609,3 +25609,3036 @@ 8.86 % in 13331 seconds 8.91 % in 13368 seconds 8.96 % in 13410 seconds + 9.00 % in 13453 seconds + 9.05 % in 13498 seconds + 9.10 % in 13542 seconds + 9.15 % in 13589 seconds + 9.19 % in 13614 seconds + 9.29 % in 13630 seconds + 9.39 % in 13642 seconds + 9.48 % in 13653 seconds + 9.58 % in 13666 seconds + 9.67 % in 13677 seconds + 9.81 % in 13700 seconds + 9.86 % in 13726 seconds + 9.96 % in 13774 seconds +10.00 % in 13792 seconds +10.10 % in 13811 seconds +10.15 % in 13866 seconds +10.20 % in 13924 seconds +10.24 % in 13944 seconds +10.34 % in 13995 seconds +10.39 % in 14026 seconds +10.43 % in 14053 seconds +10.48 % in 14080 seconds +10.58 % in 14143 seconds +10.62 % in 14200 seconds +10.67 % in 14218 seconds +10.72 % in 14252 seconds +10.77 % in 14297 seconds +10.81 % in 14335 seconds +10.86 % in 14381 seconds +10.91 % in 14424 seconds +10.96 % in 14464 seconds +11.01 % in 14514 seconds +11.05 % in 14558 seconds +11.10 % in 14606 seconds +11.15 % in 14656 seconds +11.20 % in 14677 seconds +11.24 % in 14687 seconds +11.34 % in 14701 seconds +11.43 % in 14712 seconds +11.53 % in 14724 seconds +11.62 % in 14737 seconds +11.77 % in 14751 seconds +11.86 % in 14763 seconds +12.01 % in 14776 seconds +12.10 % in 14835 seconds +12.15 % in 14848 seconds +12.20 % in 14867 seconds +12.24 % in 14898 seconds +12.34 % in 14953 seconds 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+69.40 % in 30931 seconds +69.45 % in 30965 seconds +69.49 % in 30989 seconds diff --git a/tetrazine/cc-pvdz/tetrazine.nofci.out b/tetrazine/cc-pvdz/tetrazine.nofci.out index d73bc20..2a4b5a3 100644 --- a/tetrazine/cc-pvdz/tetrazine.nofci.out +++ b/tetrazine/cc-pvdz/tetrazine.nofci.out @@ -4509,3 +4509,299 @@ Iter Energy S^2 Residual 5 -295.4040138960 0.011923 0.112E-06 6 -295.4040141270 0.011913 0.223E-07 7 -295.4040142046 0.011901 0.451E-08 + 8 -295.4040142199 0.011898 0.944E-09 + 9 -295.4040142226 0.011895 0.172E-09 + 10 -295.4040142231 0.011894 0.302E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 65.140743 GB ] [ VIRT MEM : 83.739594 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 168818.628610 s ] [ CPU TIME: ************** s ] <<<<< .. + + +.. >>>>> [ RES MEM : 24.211128 GB ] [ VIRT MEM : 35.310375 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 168822.695794 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Energy of state 1 -295.4040142230919 +* S^2 of state 1 0.1189382627405114E-01 +* Saved determinants 41935197 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 22.867741 GB ] [ VIRT MEM : 27.682045 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 169366.168972 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 41892398 + +.. >>>>> [ RES MEM : 22.867741 GB ] [ VIRT MEM : 27.682045 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 169366.262726 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 41892398 +* Number of comb teeth 100 +* pt2_n_tasks_max 870 +* PT2 Energy denominator -295.4040142230919 + +.. >>>>> [ RES MEM : 30.207809 GB ] [ VIRT MEM : 35.024662 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 169406.391799 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 41892398 + +.. >>>>> [ RES MEM : 30.207809 GB ] [ VIRT MEM : 35.024662 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 169406.482545 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 41892398 +* Number of comb teeth 100 +* pt2_n_tasks_max 870 +* Number of tasks 42870849 +* Number of fragmented tasks 15872 +* Number of threads for PT2 72 +* Memory (Gb) 29.50943941421807 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -295.5388563645 0.501E-02 0.8378599708 0.0229753565 3810.8011 + 4 -295.5384430920 0.339E-02 0.8357420578 0.0228784175 4594.1711 + 5 -295.5387010976 0.248E-02 0.8375475896 0.0229100909 5338.4679 + 6 -295.5396568861 0.225E-02 0.8412721396 0.0231206393 6176.1977 + 7 -295.5393225784 0.193E-02 0.8409024878 0.0230205314 6794.3221 + 8 -295.5405022766 0.207E-02 0.8478372155 0.0232230896 7431.6792 + 9 -295.5400452850 0.183E-02 0.8447202854 0.0231616291 8154.1963 + 10 -295.5398051708 0.168E-02 0.8429264657 0.0231317168 8586.8297 + 11 -295.5391797152 0.164E-02 0.8385292920 0.0230381186 8622.2383 + 12 -295.5397592383 0.164E-02 0.8424288276 0.0231232774 9141.3794 + 13 -295.5396382448 0.151E-02 0.8412020833 0.0231154316 9524.8905 + 14 -295.5399676459 0.143E-02 0.8436022667 0.0231661385 9970.9002 + 15 -295.5403782696 0.140E-02 0.8461789843 0.0232364773 10472.8768 + 16 -295.5402827340 0.133E-02 0.8448367021 0.0232438438 10539.8088 + 17 -295.5403507640 0.125E-02 0.8450788741 0.0232589585 10614.9673 + 18 -295.5404091596 0.118E-02 0.8446921933 0.0232872398 11121.1015 + 19 -295.5405618563 0.109E-02 0.8467700956 0.0232839530 11745.4732 + 20 -295.5407537420 0.106E-02 0.8474985395 0.0233284268 12332.1871 + 21 -295.5406282036 0.101E-02 0.8465969223 0.0233120681 12528.5581 + 22 -295.5406331348 0.976E-03 0.8471524855 0.0232975145 12670.5144 + 23 -295.5406227576 0.932E-03 0.8469804650 0.0232989663 12973.8679 + 24 -295.5405499354 0.895E-03 0.8466939272 0.0232809269 13216.9181 + 25 -295.5408942467 0.916E-03 0.8489374910 0.0233373794 13346.9194 + 26 -295.5409073934 0.879E-03 0.8493216431 0.0233402661 13445.7828 + 27 -295.5407855801 0.855E-03 0.8480520228 0.0233298745 14015.4558 + 28 -295.5408343345 0.825E-03 0.8485875828 0.0233309632 14565.5524 + 29 -295.5407249666 0.803E-03 0.8480033965 0.0233063955 15047.9824 + 30 -295.5406292648 0.782E-03 0.8471264652 0.0232981370 15446.5867 + 31 -295.5406834941 0.747E-03 0.8476532200 0.0233025859 15575.5920 + 32 -295.5406369235 0.724E-03 0.8470542298 0.0233018948 16101.9521 + 33 -295.5407036550 0.705E-03 0.8475216657 0.0233100157 16362.6720 + 34 -295.5406455751 0.683E-03 0.8476882779 0.0232863120 16806.0166 + 35 -295.5407713169 0.675E-03 0.8485352648 0.0233050198 17042.7925 + 36 -295.5409881178 0.692E-03 0.8499135064 0.0233402203 17189.0960 + 37 -295.5409234882 0.688E-03 0.8494792698 0.0233299731 17299.3298 + 38 -295.5407847686 0.684E-03 0.8484687704 0.0233114046 17607.8624 + 40 -295.5406631338 0.657E-03 0.8473082597 0.0233016276 17928.6978 + 41 -295.5405408385 0.653E-03 0.8465265291 0.0232818316 18142.1331 + 42 -295.5406770168 0.636E-03 0.8473531864 0.0233044923 18524.2203 + 43 -295.5405826036 0.628E-03 0.8468954091 0.0232834663 18968.4392 + 44 -295.5408003941 0.651E-03 0.8483931066 0.0233163919 19157.2407 + 45 -295.5408377319 0.638E-03 0.8486326835 0.0233229209 19545.5386 + 47 -295.5404753082 0.645E-03 0.8468464477 0.0232510431 19746.9178 + 48 -295.5404197696 0.634E-03 0.8461083710 0.0232504182 20019.8208 + 49 -295.5403079825 0.636E-03 0.8452429593 0.0232363595 20064.5968 + 50 -295.5402936837 0.623E-03 0.8452414718 0.0232313948 20336.7249 + 51 -295.5401484093 0.628E-03 0.8442418476 0.0232087125 20556.9477 + 52 -295.5401133091 0.617E-03 0.8441003553 0.0232014517 20684.6036 + 53 -295.5401658610 0.607E-03 0.8446625357 0.0232041164 20865.0616 + 54 -295.5401652754 0.590E-03 0.8443055817 0.0232134032 20968.6952 + 55 -295.5401376475 0.580E-03 0.8443657511 0.0232031831 21171.7639 + 56 -295.5401872533 0.572E-03 0.8448344871 0.0232071385 21360.7031 + 58 -295.5402581053 0.554E-03 0.8452875354 0.0232203265 21524.2857 + 59 -295.5402574323 0.544E-03 0.8451986689 0.0232219965 21771.6371 + 61 -295.5402767945 0.526E-03 0.8452574787 0.0232257844 21782.0033 + 62 -295.5403434627 0.521E-03 0.8455915211 0.0232391917 22050.0127 + 63 -295.5403495809 0.513E-03 0.8457241652 0.0232391104 22126.6575 + 64 -295.5403416921 0.505E-03 0.8456824999 0.0232361340 22250.5741 + 65 -295.5404470773 0.508E-03 0.8463854730 0.0232532713 22327.8792 + 67 -295.5403588106 0.503E-03 0.8460361493 0.0232320132 22461.3224 + 68 -295.5403384512 0.496E-03 0.8458588019 0.0232291112 22569.7247 + 69 -295.5404119345 0.494E-03 0.8462569198 0.0232427757 22708.2424 + 70 -295.5403708032 0.488E-03 0.8460037999 0.0232355852 22875.9762 + 71 -295.5403991465 0.482E-03 0.8460605421 0.0232447506 22960.2473 + 72 -295.5403197538 0.482E-03 0.8455560502 0.0232325812 23090.5628 + 73 -295.5402110672 0.488E-03 0.8446459282 0.0232214626 23252.4914 + 74 -295.5400885371 0.497E-03 0.8437732720 0.0232034624 23356.0212 + 75 -295.5400829762 0.490E-03 0.8438207426 0.0232002097 23622.4315 + 76 -295.5400922682 0.484E-03 0.8441149301 0.0231959632 23708.9171 + 77 -295.5401273619 0.478E-03 0.8442395268 0.0232036865 23735.2450 + 78 -295.5401651752 0.474E-03 0.8444394143 0.0232108115 23897.9122 + 79 -295.5402101923 0.470E-03 0.8448410567 0.0232160628 24017.6693 + 80 -295.5402016546 0.464E-03 0.8448722373 0.0232128254 24184.2071 + 81 -295.5401834835 0.459E-03 0.8446810386 0.0232120490 24388.4409 + 83 -295.5401264260 0.450E-03 0.8442682705 0.0232029782 24521.8248 + 84 -295.5402128510 0.452E-03 0.8445317054 0.0232250559 24651.4559 + 85 -295.5402483892 0.448E-03 0.8447588538 0.0232305853 24729.3661 + 86 -295.5401854819 0.447E-03 0.8443341820 0.0232207793 24880.0295 + 87 -295.5402864374 0.454E-03 0.8450765288 0.0232350105 24979.4258 + 88 -295.5403316576 0.451E-03 0.8452576892 0.0232456728 25068.9231 + 89 -295.5402819111 0.448E-03 0.8448458388 0.0232390609 25277.3839 + 91 -295.5402742058 0.438E-03 0.8444154645 0.0232479159 25435.8215 + 92 -295.5402624700 0.433E-03 0.8443573391 0.0232453532 25663.7928 + 94 -295.5401886891 0.429E-03 0.8439233981 0.0232324316 25910.3332 + 97 -295.5402842948 0.424E-03 0.8444829156 0.0232471965 26016.9380 + 98 -295.5402488828 0.421E-03 0.8443085990 0.0232406879 26221.9544 + 100 -295.5401877689 0.410E-03 0.8439759213 0.0232289541 26388.1632 + 103 -295.5401514033 0.399E-03 0.8438255730 0.0232217622 26504.2211 + 104 -295.5401689661 0.395E-03 0.8439501476 0.0232243317 26723.6839 + 105 -295.5402012722 0.393E-03 0.8441584444 0.0232294716 26861.4376 + 106 -295.5401708273 0.390E-03 0.8440722261 0.0232220426 26947.8170 + 107 -295.5401507418 0.387E-03 0.8439800442 0.0232178161 27099.6131 + 109 -295.5401369948 0.380E-03 0.8438765538 0.0232159842 27199.7720 + 111 -295.5400886453 0.380E-03 0.8437781853 0.0232037073 27332.4072 + 112 -295.5401002641 0.377E-03 0.8438777341 0.0232047558 27486.2839 + 113 -295.5400597965 0.376E-03 0.8436580925 0.0231977858 27514.4591 + 114 -295.5400598856 0.372E-03 0.8436788654 0.0231971932 27651.4206 + 115 -295.5400404661 0.370E-03 0.8435588388 0.0231943023 27940.2747 + 118 -295.5399710966 0.365E-03 0.8432114916 0.0231816342 27983.1140 + 119 -295.5399543982 0.362E-03 0.8431367926 0.0231780641 28054.6700 + 120 -295.5399211723 0.361E-03 0.8430850427 0.0231688961 28118.9632 + 121 -295.5399481985 0.359E-03 0.8433288957 0.0231718312 28240.3821 + 122 -295.5399811846 0.360E-03 0.8436483934 0.0231756696 28399.2419 + 123 -295.5399867257 0.357E-03 0.8437064355 0.0231761679 28405.8269 + 124 -295.5399560409 0.355E-03 0.8434688304 0.0231719403 28574.0341 + 125 -295.5399181572 0.355E-03 0.8432484795 0.0231654510 28681.7250 + 126 -295.5399555232 0.354E-03 0.8433964585 0.0231733443 28768.5383 + 127 -295.5399461383 0.351E-03 0.8433716305 0.0231707094 28826.3724 + 128 -295.5399658836 0.349E-03 0.8434361115 0.0231754661 28952.2413 + 129 -295.5399534403 0.346E-03 0.8433953682 0.0231727594 28997.3431 + 131 -295.5399936258 0.346E-03 0.8438093538 0.0231744317 29104.4797 + 132 -295.5400062071 0.343E-03 0.8438521897 0.0231775328 29116.2995 + 133 -295.5399583586 0.344E-03 0.8435234961 0.0231701830 29143.4873 + 134 -295.5399612007 0.342E-03 0.8434821565 0.0231722823 29232.5360 + 135 -295.5399763568 0.339E-03 0.8435549471 0.0231751648 29240.9131 + 136 -295.5400231638 0.340E-03 0.8438378452 0.0231829269 29327.5271 + 137 -295.5400397470 0.338E-03 0.8439111339 0.0231863267 29490.4849 + 138 -295.5399955580 0.339E-03 0.8436476966 0.0231786112 29573.9475 + 139 -295.5399998606 0.337E-03 0.8436064910 0.0231807432 29609.0100 + 141 -295.5399963535 0.332E-03 0.8435941173 0.0231788576 29699.2394 + 142 -295.5400305161 0.332E-03 0.8437026473 0.0231868034 29803.3681 + 143 -295.5400108567 0.330E-03 0.8435781339 0.0231841685 29898.2411 + 144 -295.5400052411 0.328E-03 0.8435030262 0.0231839601 29969.0450 + 145 -295.5399850664 0.326E-03 0.8434638428 0.0231785960 30037.0881 + 146 -295.5399450584 0.326E-03 0.8431562656 0.0231736852 30082.1624 + 147 -295.5399697136 0.324E-03 0.8433169474 0.0231781260 30230.3974 + 148 -295.5399698667 0.322E-03 0.8432610314 0.0231793974 30304.8217 + 149 -295.5399644298 0.320E-03 0.8432120324 0.0231789130 30375.4153 + 150 -295.5399316573 0.319E-03 0.8430147668 0.0231736282 30387.5983 + 151 -295.5399440215 0.318E-03 0.8430850698 0.0231757584 30483.3642 + 152 -295.5399526592 0.316E-03 0.8432040656 0.0231757936 30625.7961 + 153 -295.5399758425 0.314E-03 0.8434031017 0.0231785935 30737.0155 + 154 -295.5399846978 0.310E-03 0.8434018158 0.0231812695 30801.1606 + 155 -295.5399706020 0.308E-03 0.8433103450 0.0231787034 30957.2851 + 156 -295.5399744067 0.306E-03 0.8432996918 0.0231795913 31000.6933 + 157 -295.5399892040 0.304E-03 0.8434078633 0.0231816283 31110.3616 + 158 -295.5400130409 0.303E-03 0.8434961985 0.0231871271 31142.3952 + 159 -295.5399890536 0.302E-03 0.8433483545 0.0231829534 31243.7541 + 160 -295.5399717854 0.301E-03 0.8433175989 0.0231783899 31341.7261 + 161 -295.5399569126 0.299E-03 0.8432253599 0.0231756087 31365.2192 + 162 -295.5400030126 0.301E-03 0.8435258686 0.0231833270 31400.4646 + 163 -295.5399836099 0.300E-03 0.8433980067 0.0231803509 31520.4852 + 165 -295.5400178623 0.292E-03 0.8437080683 0.0231831697 31637.8383 + 167 -295.5400332018 0.289E-03 0.8437749190 0.0231868438 31699.8198 + 168 -295.5400390881 0.287E-03 0.8438033983 0.0231884423 31780.6351 + 169 -295.5400024508 0.288E-03 0.8435587467 0.0231826248 31895.9781 + 170 -295.5400152094 0.287E-03 0.8436650791 0.0231840201 32035.3040 + 171 -295.5400232610 0.285E-03 0.8437036776 0.0231855588 32112.0817 + 172 -295.5400615944 0.286E-03 0.8439078192 0.0231925930 32321.6580 + 174 -295.5401062560 0.290E-03 0.8440954857 0.0232027114 32334.0063 + 175 -295.5400966552 0.288E-03 0.8440594439 0.0232004430 32466.1559 + 176 -295.5400938351 0.286E-03 0.8440382157 0.0231997865 32526.8741 + 177 -295.5400878120 0.285E-03 0.8440229007 0.0231981330 32580.4852 + 179 -295.5400922513 0.282E-03 0.8440120007 0.0231992761 32596.0410 + 180 -295.5400819750 0.280E-03 0.8439053232 0.0231984725 32638.5845 + 181 -295.5400945410 0.279E-03 0.8439807814 0.0232001693 32745.2459 + 182 -295.5400827286 0.276E-03 0.8437073546 0.0232023816 32849.8437 + 184 -295.5401080704 0.273E-03 0.8437966628 0.0232081094 32872.6099 + 185 -295.5400918328 0.272E-03 0.8436996819 0.0232056666 32934.6021 + 186 -295.5400717777 0.272E-03 0.8436198653 0.0232013350 32958.6031 + 187 -295.5400679599 0.270E-03 0.8436791110 0.0231989324 33071.3645 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 30.228531 GB ] [ VIRT MEM : 35.328064 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 202635.995998 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 41892398 + +.. >>>>> [ RES MEM : 30.228531 GB ] [ VIRT MEM : 35.328064 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 202636.083175 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 41892398 +* Number of comb teeth 100 +* pt2_n_tasks_max 870 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8556630446210793 + +Summary at N_det = 41935197 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -295.40401422 +# PT2 -0.13605374 0.00027010 +# rPT2 -0.13296900 0.00026397 +# +# E+PT2 -295.54006796 0.00027010 +# E+rPT2 -295.53698322 0.00026397 +# ============ ============================= + + N_det = 41935197 + N_states = 1 + + * State 1 + < S^2 > = 1.189382627405114E-002 + E = -295.404014223092 + Variance = 0.843679111018692 + PT norm = 0.152311957550764 + PT2 = -0.136053736761586 + rPT2 = -0.132968997964783 + E+PT2 = -295.540067959854 +/- 2.700984967121723E-004 + E+rPT2 = -295.536983221057 +/- 2.639745685379245E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 212.857674810953 + Ven = -1115.69133949083 + Vee = 312.390518744463 + Vecp = 0.000000000000000E+000 + T = 295.039131712326 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1358 -295.61314127 + -0.1380 -295.58728280 + -0.1393 -295.58200922 + -0.1413 -295.56583885 + -0.1419 -295.56916436 + -0.1455 -295.56308171 + -0.1498 -295.56886075 + =========== =================== + +* Number of unique beta determinants 5136993 +* Number of unique alpha determinants 5227036 diff --git a/thiophene/cc-pvdz/slurm-496706.out b/thiophene/cc-pvdz/slurm-496706.out index a245b4a..64722b6 100644 --- a/thiophene/cc-pvdz/slurm-496706.out +++ b/thiophene/cc-pvdz/slurm-496706.out @@ -17518,3 +17518,4031 @@ 1.14 % in 19303 seconds 1.14 % in 19313 seconds 1.15 % in 19323 seconds + 1.15 % in 19333 seconds + 1.15 % in 19343 seconds + 1.15 % in 19353 seconds + 1.15 % in 19363 seconds + 1.15 % in 19373 seconds + 1.15 % in 19383 seconds + 1.15 % in 19393 seconds + 1.15 % in 19403 seconds + 1.15 % in 19414 seconds + 1.15 % in 19424 seconds + 1.15 % in 19434 seconds + 1.15 % in 19444 seconds + 1.16 % in 19454 seconds + 1.16 % in 19467 seconds + 1.16 % in 19477 seconds + 1.16 % in 19487 seconds + 1.16 % in 19497 seconds + 1.16 % in 19507 seconds + 1.16 % in 19517 seconds + 1.16 % in 19527 seconds + 1.16 % in 19537 seconds + 1.16 % in 19547 seconds + 1.16 % in 19557 seconds + 1.16 % in 19567 seconds + 1.16 % in 19577 seconds + 1.16 % in 19588 seconds + 1.17 % in 19598 seconds + 1.17 % in 19608 seconds + 1.17 % in 19619 seconds + 1.17 % in 19630 seconds + 1.17 % in 19640 seconds + 1.17 % in 19650 seconds + 1.17 % in 19660 seconds + 1.17 % in 19670 seconds + 1.17 % in 19680 seconds + 1.17 % in 19690 seconds + 1.17 % in 19700 seconds + 1.17 % in 19710 seconds + 1.17 % in 19720 seconds + 1.18 % in 19731 seconds + 1.18 % in 19772 seconds + 1.18 % in 19790 seconds + 1.18 % in 19800 seconds + 1.18 % in 19813 seconds + 1.18 % in 19823 seconds + 1.18 % in 19833 seconds + 1.18 % in 19843 seconds + 1.18 % in 19853 seconds + 1.18 % in 19863 seconds + 1.18 % in 19873 seconds + 1.18 % in 19883 seconds + 1.18 % in 19893 seconds + 1.18 % in 19903 seconds + 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seconds + 2.48 % in 1928 seconds + 2.53 % in 1971 seconds + 2.58 % in 2011 seconds + 2.62 % in 2050 seconds + 2.67 % in 2085 seconds + 2.72 % in 2124 seconds + 2.77 % in 2162 seconds + 2.81 % in 2199 seconds + 2.86 % in 2233 seconds + 2.91 % in 2267 seconds + 2.96 % in 2303 seconds + 3.01 % in 2339 seconds diff --git a/thiophene/cc-pvdz/thiophene.nofci.out b/thiophene/cc-pvdz/thiophene.nofci.out index 5e1763e..87535f1 100644 --- a/thiophene/cc-pvdz/thiophene.nofci.out +++ b/thiophene/cc-pvdz/thiophene.nofci.out @@ -4628,3 +4628,200 @@ Iter Energy S^2 Residual 30 -552.0278659010 0.450E-03 0.5060516521 0.0204125685 18287.9223 31 -552.0277435295 0.453E-03 0.5051964575 0.0203986987 18420.7487 32 -552.0276986080 0.440E-03 0.5049238387 0.0203901460 19025.5460 + 33 -552.0277355284 0.435E-03 0.5051277795 0.0203963608 19283.8708 + 34 -552.0276955220 0.424E-03 0.5049141381 0.0203883805 19900.0973 + 35 -552.0277749653 0.419E-03 0.5053961876 0.0203997973 20072.9446 + 36 -552.0276967408 0.409E-03 0.5051515770 0.0203777642 20283.6081 + 37 -552.0277633332 0.404E-03 0.5056693882 0.0203886138 20524.6740 + 38 -552.0277635792 0.393E-03 0.5054927188 0.0203950328 20766.4732 + 40 -552.0277464625 0.379E-03 0.5053608336 0.0203930584 20960.2061 + 41 -552.0279385908 0.400E-03 0.5064578526 0.0204250900 21510.9499 + 42 -552.0279162903 0.391E-03 0.5064200493 0.0204185099 22046.1263 + 43 -552.0278777014 0.383E-03 0.5061343393 0.0204126282 22512.0740 + 44 -552.0277833109 0.386E-03 0.5055494367 0.0203973575 22761.5682 + 45 -552.0277489319 0.371E-03 0.5053143167 0.0203939821 22817.6772 + 46 -552.0277801997 0.364E-03 0.5053641751 0.0204068608 23016.2049 + 47 -552.0277818421 0.356E-03 0.5052837357 0.0204114082 23427.5322 + 48 -552.0277347638 0.347E-03 0.5050737885 0.0203986546 23658.1113 + 49 -552.0277307602 0.340E-03 0.5051434600 0.0203951433 23747.9837 + 50 -552.0277472023 0.334E-03 0.5051771343 0.0203993826 24083.2172 + 51 -552.0278930970 0.351E-03 0.5059615595 0.0204259979 24459.1489 + 52 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0.263E-03 0.5084355496 0.0204950273 29295.7890 + 87 -552.0283397440 0.261E-03 0.5086051269 0.0204992960 29550.6099 + 88 -552.0283044655 0.261E-03 0.5084825874 0.0204906785 29642.1229 + 89 -552.0282844724 0.259E-03 0.5083593067 0.0204869663 29654.8357 + 90 -552.0283063470 0.257E-03 0.5085584561 0.0204888388 29845.9190 + 91 -552.0282428239 0.262E-03 0.5082568992 0.0204753593 29979.3830 + 92 -552.0282576361 0.258E-03 0.5084023511 0.0204755917 30139.7812 + 93 -552.0282662338 0.255E-03 0.5084474558 0.0204773449 30272.0170 + 94 -552.0282423435 0.253E-03 0.5083107434 0.0204733238 30462.5624 + 95 -552.0281938748 0.255E-03 0.5080916345 0.0204627135 30472.6089 + 96 -552.0281734464 0.253E-03 0.5079960340 0.0204588529 30514.3885 + 97 -552.0281929096 0.252E-03 0.5081368351 0.0204614684 30672.8079 + 98 -552.0282002520 0.249E-03 0.5081772739 0.0204626544 30901.2330 + 100 -552.0282128935 0.246E-03 0.5081881299 0.0204662988 30939.6612 + 101 -552.0282011547 0.244E-03 0.5081385226 0.0204635623 31147.2047 + 103 -552.0282386414 0.245E-03 0.5083744038 0.0204692245 31210.9861 + 104 -552.0282251031 0.243E-03 0.5082625614 0.0204676031 31428.6569 + 105 -552.0282285537 0.240E-03 0.5083077491 0.0204670521 31652.7302 + 106 -552.0282474608 0.239E-03 0.5083815061 0.0204714960 31674.7750 + 107 -552.0282142323 0.239E-03 0.5081174741 0.0204679586 31891.2377 + 109 -552.0282237502 0.235E-03 0.5082335170 0.0204675657 32045.9102 + 111 -552.0281772545 0.234E-03 0.5079636464 0.0204592371 32123.5422 + 112 -552.0281574735 0.233E-03 0.5078771487 0.0204546371 32417.0673 + 114 -552.0281600293 0.229E-03 0.5077901573 0.0204583948 32509.7793 + 115 -552.0281810960 0.228E-03 0.5079062293 0.0204622827 32686.0532 + 116 -552.0281737499 0.226E-03 0.5078883851 0.0204600738 32758.9794 + 118 -552.0281724710 0.223E-03 0.5079526938 0.0204571738 32762.3079 + 119 -552.0281776769 0.221E-03 0.5079591143 0.0204583531 32875.1813 + 120 -552.0282037057 0.221E-03 0.5081297548 0.0204620550 33020.2592 + 121 -552.0281924917 0.219E-03 0.5080983257 0.0204590341 33144.4479 + 122 -552.0281809000 0.218E-03 0.5080481052 0.0204562026 33184.3141 + 123 -552.0281824592 0.216E-03 0.5079550091 0.0204600386 33373.2575 + 124 -552.0281744231 0.214E-03 0.5078803592 0.0204594185 33499.2851 + 125 -552.0281717397 0.212E-03 0.5078534965 0.0204592693 33610.4620 + 126 -552.0281812852 0.211E-03 0.5078805598 0.0204616862 33768.4021 + 127 -552.0281772422 0.209E-03 0.5078776610 0.0204603794 33791.2901 + 128 -552.0281714214 0.208E-03 0.5077908996 0.0204613522 33915.5046 + 129 -552.0281743021 0.206E-03 0.5078288486 0.0204608204 33947.9755 + 131 -552.0281928051 0.204E-03 0.5078863924 0.0204655253 34068.0091 + 132 -552.0282141218 0.203E-03 0.5079875845 0.0204699529 34090.8523 + 133 -552.0281934988 0.203E-03 0.5078295807 0.0204674741 34156.8852 + 134 -552.0281917259 0.202E-03 0.5079064017 0.0204639764 34243.7167 + 135 -552.0281543308 0.204E-03 0.5076994091 0.0204568712 34262.4513 + 136 -552.0281277390 0.204E-03 0.5075493595 0.0204519819 34390.8396 + 137 -552.0281281660 0.202E-03 0.5075377787 0.0204521486 34539.6791 + 138 -552.0281166932 0.201E-03 0.5074457551 0.0204510973 34607.6399 + 139 -552.0281246211 0.200E-03 0.5074531607 0.0204537545 34689.4404 + 141 -552.0281681417 0.200E-03 0.5076537319 0.0204628403 34748.6885 + 142 -552.0281425615 0.195E-03 0.5075156014 0.0204580214 34815.9432 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 29.887245 GB ] [ VIRT MEM : 35.620293 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 201125.019111 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 41894212 + +.. >>>>> [ RES MEM : 29.887245 GB ] [ VIRT MEM : 35.620293 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 201125.112261 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 41894212 +* Number of comb teeth 100 +* pt2_n_tasks_max 950 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8618957178131542 + +Summary at N_det = 41938486 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -551.92876634 +# PT2 -0.09937622 0.00019471 +# rPT2 -0.09738394 0.00019081 +# +# E+PT2 -552.02814256 0.00019471 +# E+rPT2 -552.02615028 0.00019081 +# ============ ============================= + + N_det = 41938486 + N_states = 1 + + * State 1 + < S^2 > = 1.012003300073003E-002 + E = -551.928766343548 + Variance = 0.507515601372279 + PT norm = 0.143031539935135 + PT2 = -9.937621795551042E-002 + rPT2 = -9.738393532111565E-002 + E+PT2 = -552.028142561504 +/- 1.947125813574325E-004 + E+rPT2 = -552.026150278869 +/- 1.908090066137221E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 202.700650943125 + Ven = -1710.59196589553 + Vee = 404.113036937942 + Vecp = 0.000000000000000E+000 + T = 551.849511670918 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0996 -552.06532709 + -0.1019 -552.03903086 + -0.1029 -552.04084469 + -0.1042 -552.03972229 + -0.1054 -552.03803748 + -0.1076 -552.03971145 + -0.1121 -552.04121878 + =========== =================== + +* Number of unique beta determinants 4264523 +* Number of unique alpha determinants 4286302 + +.. >>>>> [ RES MEM : 44.342007 GB ] [ VIRT MEM : 57.028294 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 237243.453934 s ] [ CPU TIME: ************** s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 83777822 +* Number of threads for diagonalization 72 +* Memory(Gb) 123.7689538262784 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -551.9285033167 0.010324 0.151E-02 diff --git a/triazine/cc-pvdz/slurm-496708.out b/triazine/cc-pvdz/slurm-496708.out index 1f10c15..8248f14 100644 --- a/triazine/cc-pvdz/slurm-496708.out +++ b/triazine/cc-pvdz/slurm-496708.out @@ -14356,3 +14356,5774 @@ 77.71 % in 8477 seconds 77.90 % in 8500 seconds 78.00 % in 8517 seconds +78.10 % in 8536 seconds +78.29 % in 8548 seconds +78.67 % in 8559 seconds +79.05 % in 8572 seconds +79.43 % in 8584 seconds +79.71 % in 8594 seconds +80.00 % in 8604 seconds +80.19 % in 8624 seconds +80.29 % in 8638 seconds +80.38 % in 8656 seconds +80.48 % in 8666 seconds +80.86 % in 8678 seconds +81.24 % in 8689 seconds +81.62 % in 8701 seconds +81.90 % in 8711 seconds +82.10 % in 8723 seconds +82.19 % in 8738 seconds +82.29 % in 8756 seconds +82.38 % in 8771 seconds +82.67 % in 8781 seconds +83.05 % in 8792 seconds +83.43 % in 8803 seconds +83.81 % in 8816 seconds +84.10 % in 8833 seconds +84.19 % in 8850 seconds +84.29 % in 8868 seconds +84.57 % in 8878 seconds +84.95 % in 8889 seconds +85.33 % in 8901 seconds +85.62 % in 8918 seconds +85.71 % in 8936 seconds +85.81 % in 8954 seconds +86.00 % in 8966 seconds +86.38 % in 8977 seconds +86.76 % in 8989 seconds +87.05 % in 9000 seconds +87.24 % in 9015 seconds +87.33 % in 9032 seconds +87.43 % in 9050 seconds +87.81 % in 9062 seconds +88.19 % in 9073 seconds +88.57 % in 9085 seconds +88.86 % in 9096 seconds +88.95 % in 9108 seconds +89.05 % in 9124 seconds +89.14 % in 9144 seconds +89.43 % in 9156 seconds +89.81 % in 9167 seconds +90.19 % in 9178 seconds +90.48 % in 9188 seconds +90.76 % in 9213 seconds +90.86 % in 9232 seconds +91.05 % in 9243 seconds +91.43 % in 9254 seconds +91.81 % in 9266 seconds +92.10 % in 9277 seconds +92.19 % in 9289 seconds +92.29 % in 9306 seconds +92.38 % in 9320 seconds +92.76 % in 9331 seconds +93.14 % in 9343 seconds +93.52 % in 9356 seconds +93.81 % in 9372 seconds +93.90 % in 9391 seconds +94.00 % in 9407 seconds +94.38 % in 9418 seconds +94.76 % in 9430 seconds +95.14 % in 9443 seconds +95.43 % in 9462 seconds +95.52 % in 9481 seconds +95.62 % in 9493 seconds +96.00 % in 9504 seconds +96.38 % in 9515 seconds +96.76 % in 9528 seconds +96.95 % in 9547 seconds +97.05 % in 9566 seconds +97.24 % in 9577 seconds +97.62 % in 9589 seconds +98.00 % in 9601 seconds +98.29 % in 9613 seconds +98.48 % in 9632 seconds +98.57 % in 9650 seconds +98.86 % in 9662 seconds +99.24 % in 9674 seconds +99.62 % in 9687 seconds + 0.10 % in 30 seconds + 0.19 % in 49 seconds + 0.29 % in 68 seconds + 0.38 % in 90 seconds + 0.48 % in 107 seconds + 0.57 % in 125 seconds + 0.67 % in 145 seconds + 0.76 % in 162 seconds + 0.86 % in 180 seconds + 0.95 % in 199 seconds + 1.05 % in 216 seconds + 1.14 % in 235 seconds + 1.24 % in 253 seconds + 1.33 % in 271 seconds + 1.43 % in 289 seconds + 1.52 % in 308 seconds + 1.62 % in 326 seconds + 1.71 % in 347 seconds + 1.81 % in 365 seconds + 1.90 % in 383 seconds + 2.00 % in 402 seconds + 2.10 % in 421 seconds + 2.19 % in 440 seconds + 2.29 % in 459 seconds + 2.38 % in 477 seconds + 2.48 % in 494 seconds + 2.57 % in 512 seconds + 2.67 % in 529 seconds + 2.76 % in 546 seconds + 2.86 % in 643 seconds + 2.95 % in 766 seconds + 3.05 % in 890 seconds + 3.14 % in 1014 seconds + 3.24 % in 1136 seconds + 3.33 % in 1259 seconds + 3.43 % in 1386 seconds + 3.52 % in 1511 seconds + 3.62 % in 1634 seconds + 3.71 % in 1758 seconds + 3.81 % in 1879 seconds + 3.90 % in 2005 seconds + 4.00 % in 2130 seconds + 4.10 % in 2254 seconds + 4.19 % in 2381 seconds + 4.29 % in 2495 seconds + 4.38 % in 2515 seconds + 4.48 % in 2525 seconds + 4.76 % in 2553 seconds + 4.86 % in 2587 seconds + 4.95 % in 2621 seconds + 5.05 % in 2651 seconds + 5.33 % in 2681 seconds + 5.43 % in 2713 seconds + 5.52 % in 2723 seconds + 5.71 % in 2754 seconds + 5.81 % in 2775 seconds + 5.90 % in 2791 seconds + 6.00 % in 2807 seconds + 6.10 % in 2827 seconds + 6.19 % in 2846 seconds + 6.29 % in 2872 seconds + 6.38 % in 2894 seconds + 6.48 % in 2915 seconds + 6.76 % in 2927 seconds + 6.86 % in 2960 seconds + 6.95 % in 2984 seconds + 7.24 % in 2995 seconds + 7.33 % in 3020 seconds + 7.43 % in 3052 seconds + 7.52 % in 3085 seconds + 7.62 % in 3095 seconds + 7.81 % in 3123 seconds + 7.90 % in 3149 seconds + 8.00 % in 3161 seconds + 8.10 % in 3175 seconds + 8.19 % in 3192 seconds + 8.29 % in 3212 seconds + 8.38 % in 3232 seconds + 8.48 % in 3257 seconds + 8.57 % in 3280 seconds + 8.67 % in 3291 seconds + 8.86 % in 3306 seconds + 9.14 % in 3318 seconds + 9.33 % in 3331 seconds + 9.43 % in 3361 seconds + 9.52 % in 3382 seconds + 9.81 % in 3418 seconds + 9.90 % in 3444 seconds +10.10 % in 3460 seconds +10.19 % in 3486 seconds +10.29 % in 3497 seconds +10.38 % in 3510 seconds +10.48 % in 3527 seconds +10.57 % in 3546 seconds +10.67 % in 3567 seconds +10.76 % in 3590 seconds +10.86 % in 3604 seconds +11.14 % in 3617 seconds +11.43 % in 3632 seconds +11.62 % in 3650 seconds +11.81 % in 3676 seconds +11.90 % in 3694 seconds +12.10 % in 3725 seconds +12.29 % in 3756 seconds +12.38 % in 3766 seconds +12.48 % in 3793 seconds +12.57 % in 3811 seconds +12.67 % in 3830 seconds +12.76 % in 3852 seconds +12.86 % in 3872 seconds +12.95 % in 3893 seconds +13.05 % in 3914 seconds +13.33 % in 3925 seconds +13.62 % in 3935 seconds +14.00 % in 3946 seconds +14.19 % in 3961 seconds +14.38 % in 3979 seconds +14.57 % in 4012 seconds +14.76 % in 4038 seconds +14.86 % in 4053 seconds +14.95 % in 4066 seconds +15.05 % in 4088 seconds +15.14 % in 4104 seconds +15.24 % in 4119 seconds +15.33 % in 4138 seconds +15.43 % in 4158 seconds +15.52 % in 4180 seconds +15.62 % in 4201 seconds +15.71 % in 4222 seconds +15.81 % in 4232 seconds +16.10 % in 4242 seconds +16.38 % in 4252 seconds +16.76 % in 4264 seconds +17.14 % in 4280 seconds +17.24 % in 4290 seconds +17.33 % in 4301 seconds +17.43 % in 4312 seconds +17.62 % in 4338 seconds +17.81 % in 4369 seconds +18.00 % in 4394 seconds +18.10 % in 4404 seconds +18.19 % in 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1.47 % in 29094 seconds + 1.47 % in 29106 seconds + 1.47 % in 29116 seconds + 1.47 % in 29135 seconds + 1.47 % in 29148 seconds + 1.47 % in 29158 seconds + 1.47 % in 29168 seconds + 1.47 % in 29179 seconds + 1.47 % in 29190 seconds + 1.47 % in 29200 seconds diff --git a/triazine/cc-pvdz/triazine.nofci.out b/triazine/cc-pvdz/triazine.nofci.out index 20201c3..a701012 100644 --- a/triazine/cc-pvdz/triazine.nofci.out +++ b/triazine/cc-pvdz/triazine.nofci.out @@ -4515,3 +4515,106 @@ Iter Energy S^2 Residual ===== ================ =========== =========== 1 -279.4611289504 0.007358 0.868E-03 2 -279.4654248306 0.008829 0.563E-04 + 3 -279.4655189681 0.008897 0.115E-04 + 4 -279.4655348014 0.008952 0.379E-06 + 5 -279.4655361967 0.008955 0.860E-07 + 6 -279.4655363897 0.008955 0.183E-07 + 7 -279.4655364423 0.008955 0.306E-08 + 8 -279.4655364521 0.008956 0.426E-09 + 9 -279.4655364534 0.008957 0.728E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 63.808632 GB ] [ VIRT MEM : 82.751930 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 186572.143897 s ] [ CPU TIME: ************** s ] <<<<< .. + + +.. >>>>> [ RES MEM : 24.746132 GB ] [ VIRT MEM : 34.311970 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 186575.831842 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Energy of state 1 -279.4655364533515 +* S^2 of state 1 0.8956684648933150E-02 +* Saved determinants 41943040 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 23.430683 GB ] [ VIRT MEM : 27.820000 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 187113.080427 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 41911738 + +.. >>>>> [ RES MEM : 23.430683 GB ] [ VIRT MEM : 27.820000 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 187113.171131 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 41911738 +* Number of comb teeth 100 +* pt2_n_tasks_max 870 +* PT2 Energy denominator -279.4655364533515 + +.. >>>>> [ RES MEM : 30.931313 GB ] [ VIRT MEM : 35.324245 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 187146.881403 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 41911738 + +.. >>>>> [ RES MEM : 30.931313 GB ] [ VIRT MEM : 35.324245 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 187146.968545 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 41911738 +* Number of comb teeth 100 +* pt2_n_tasks_max 870 +* Number of tasks 43372901 +* Number of fragmented tasks 24942 +* Number of threads for PT2 72 +* Memory (Gb) 33.08328482232988 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -279.6026442936 0.275E-02 0.8331037420 0.0238024037 4115.1391 + 4 -279.6020450444 0.196E-02 0.8293166294 0.0237144047 5119.6217 + 5 -279.6017811765 0.134E-02 0.8274214683 0.0236752538 6047.4825 + 6 -279.6017988805 0.108E-02 0.8274051132 0.0236760763 6999.2776 + 7 -279.6018191653 0.903E-03 0.8280713883 0.0236638451 7928.9955 + 8 -279.6020231041 0.768E-03 0.8287205081 0.0237031244 8852.2122 + 9 -279.6019505886 0.678E-03 0.8268603184 0.0237252467 9779.2779 + 10 -279.6023797234 0.748E-03 0.8287554549 0.0238179501 9995.6238 + 11 -279.6016454802 0.101E-02 0.8240563900 0.0236920018 10345.3368 + 12 -279.6015280639 0.919E-03 0.8231378642 0.0236722746 11112.5597 + 13 -279.6020574313 0.100E-02 0.8274628502 0.0237357382 11631.0104 + 14 -279.6020979290 0.927E-03 0.8272531380 0.0237533745 12403.6003 + 15 -279.6018217071 0.906E-03 0.8259481089 0.0236940211 13160.1852 + 16 -279.6018774534 0.856E-03 0.8258519467 0.0237141834 13316.2715 + 17 -279.6016183925 0.845E-03 0.8244683874 0.0236663020 13534.4710 + 18 -279.6016404437 0.796E-03 0.8248784680 0.0236713260 14187.7794 + 19 -279.6016309328 0.753E-03 0.8254904327 0.0236495947 14959.0894 + 20 -279.6015597390 0.701E-03 0.8259188709 0.0236130712 15793.5056 + 21 -279.6014235185 0.681E-03 0.8248943463 0.0236009372 16194.4527 + 22 -279.6014083680 0.649E-03 0.8245786309 0.0236056190 16566.2191 + 23 -279.6016222737 0.656E-03 0.8263507282 0.0236311336 16894.2423 + 24 -279.6014255801 0.659E-03 0.8249470364 0.0236043338 17504.3801 + 25 -279.6017193763 0.698E-03 0.8266507567 0.0236544295 17775.3324 + 26 -279.6017577067 0.661E-03 0.8272556749 0.0236523093 17944.7746 + 27 -279.6015721709 0.663E-03 0.8258943068 0.0236281956 18713.5167 + 28 -279.6015885073 0.639E-03 0.8259078608 0.0236332466 19686.5362 + 29 -279.6018366537 0.665E-03 0.8276442026 0.0236655145 20241.1481 + 30 -279.6021054995 0.698E-03 0.8292670821 0.0237116026 20986.2476 + 31 -279.6020875530 0.666E-03 0.8293257702 0.0237021762 21183.1326 + 32 -279.6022194304 0.658E-03 0.8301416279 0.0237273998 22224.5006 + 34 -279.6021223820 0.635E-03 0.8295170690 0.0237095231 22919.2620 + 35 -279.6023119683 0.646E-03 0.8305729945 0.0237442274 23276.2354 + 36 -279.6021784510 0.642E-03 0.8298124023 0.0237217126 23573.9613 + 37 -279.6022333632 0.626E-03 0.8301619082 0.0237307798 23835.1566 + 38 -279.6023169488 0.615E-03 0.8305498649 0.0237477743 24111.7519 + 39 -279.6024298825 0.624E-03 0.8311410986 0.0237702499 24305.5099 + 40 -279.6025752668 0.625E-03 0.8320048393 0.0237957176 24558.9553 + 41 -279.6026500209 0.614E-03 0.8326644980 0.0238043633 25138.1443 + 42 -279.6025970512 0.599E-03 0.8326521517 0.0237892325 25868.8263 + 43 -279.6024250505 0.610E-03 0.8314376720 0.0237653558 26519.7237 + 44 -279.6024155715 0.596E-03 0.8313707085 0.0237637393 26607.7307 + 45 -279.6023962002 0.583E-03 0.8311010311 0.0237652478 26871.2727 + 46 -279.6024291951 0.574E-03 0.8313644631 0.0237723030 27121.1396 + 47 -279.6023938671 0.563E-03 0.8309926480 0.0237717897 27823.6343 + 49 -279.6025369194 0.551E-03 0.8319996992 0.0237924308 28135.2334 + 50 -279.6025042057 0.545E-03 0.8318195592 0.0237851472 28548.8913 + 51 -279.6025874162 0.540E-03 0.8325535407 0.0237938795 28937.3144