diff --git a/cyclopentadiene/cc-pvdz/cyclopentadiene.nofci.out b/cyclopentadiene/cc-pvdz/cyclopentadiene.nofci.out index 7b3678a..812eb73 100644 --- a/cyclopentadiene/cc-pvdz/cyclopentadiene.nofci.out +++ b/cyclopentadiene/cc-pvdz/cyclopentadiene.nofci.out @@ -4275,3 +4275,588 @@ Iter Energy S^2 Residual 5 -193.4249097242 0.010599 0.431E-07 6 -193.4249098274 0.010568 0.124E-07 7 -193.4249098653 0.010547 0.418E-08 + 8 -193.4249098738 0.010543 0.771E-09 + 9 -193.4249098758 0.010542 0.131E-09 + 10 -193.4249098761 0.010543 0.204E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 35.164505 GB ] [ VIRT MEM : 45.918667 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 53916.706238 s ] [ CPU TIME: 3754692.817958 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 14.695953 GB ] [ VIRT MEM : 21.697456 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 53918.692584 s ] [ CPU TIME: 3754700.226620 s ] <<<<< .. + +* Energy of state 1 -193.4249098761376 +* S^2 of state 1 0.1054280912104339E-01 +* Saved determinants 20971520 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 14.245102 GB ] [ VIRT MEM : 18.348869 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 54192.178790 s ] [ CPU TIME: 3758320.068512 s ] <<<<< .. + +* Number of generators 20959243 + +.. >>>>> [ RES MEM : 14.245102 GB ] [ VIRT MEM : 18.348869 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 54192.224567 s ] [ CPU TIME: 3758323.356021 s ] <<<<< .. + +* Number of selectors 20959243 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -193.4249098761376 + +.. >>>>> [ RES MEM : 17.841476 GB ] [ VIRT MEM : 21.946369 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 54211.222256 s ] [ CPU TIME: 3759227.884072 s ] <<<<< .. + +* Number of generators 20959243 + +.. >>>>> [ RES MEM : 17.841476 GB ] [ VIRT MEM : 21.946369 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 54211.265972 s ] [ CPU TIME: 3759227.927623 s ] <<<<< .. + +* Number of selectors 20959243 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 21890985 +* Number of fragmented tasks 19462 +* Number of threads for PT2 72 +* Memory (Gb) 25.53255155909806 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.5259521300 0.120E-02 0.5486887532 0.0194862139 1768.5257 + 4 -193.5265716713 0.105E-02 0.5504312321 0.0196487490 2197.0455 + 5 -193.5264692784 0.898E-03 0.5499591319 0.0196232885 2647.9418 + 6 -193.5255930966 0.117E-02 0.5447823877 0.0194703588 3044.6357 + 7 -193.5260410895 0.109E-02 0.5461086655 0.0195974541 3268.3312 + 8 -193.5259036185 0.908E-03 0.5460925332 0.0195411251 3699.5499 + 9 -193.5265475930 0.103E-02 0.5500917494 0.0196524975 4133.8196 + 10 -193.5266568846 0.921E-03 0.5507960579 0.0196739809 4253.0202 + 11 -193.5268156415 0.846E-03 0.5512804541 0.0197137635 4473.5189 + 12 -193.5268924634 0.775E-03 0.5522985682 0.0197018421 4609.7929 + 13 -193.5264046366 0.804E-03 0.5499054905 0.0196047423 4979.1014 + 14 -193.5260101114 0.845E-03 0.5475556963 0.0195368134 5157.9959 + 15 -193.5262352800 0.818E-03 0.5489623707 0.0195786058 5499.5540 + 16 -193.5265867145 0.844E-03 0.5508644558 0.0196473665 5533.3653 + 17 -193.5264387420 0.798E-03 0.5499430720 0.0196255241 5589.3617 + 18 -193.5261558712 0.804E-03 0.5482270163 0.0195831337 5922.2457 + 19 -193.5260341872 0.775E-03 0.5476437869 0.0195552741 6250.0683 + 20 -193.5263911710 0.819E-03 0.5497143078 0.0196210258 6522.6117 + 21 -193.5261131659 0.828E-03 0.5479227450 0.0195787278 6567.4330 + 22 -193.5259337876 0.768E-03 0.5470001323 0.0195438211 7057.3318 + 23 -193.5257348437 0.760E-03 0.5457530170 0.0195115883 7076.4111 + 24 -193.5255797099 0.744E-03 0.5445190509 0.0194942320 7240.5869 + 25 -193.5256803530 0.721E-03 0.5451610198 0.0195139183 7390.0703 + 27 -193.5258903367 0.651E-03 0.5462745250 0.0195548534 7709.1098 + 28 -193.5258168701 0.631E-03 0.5458395278 0.0195406230 7974.6781 + 29 -193.5258816952 0.612E-03 0.5460942673 0.0195554727 8230.0530 + 30 -193.5258808769 0.591E-03 0.5463278817 0.0195464926 8597.8839 + 32 -193.5259337341 0.556E-03 0.5467786553 0.0195537020 8996.0959 + 33 -193.5259826205 0.539E-03 0.5470611839 0.0195610912 9087.2664 + 34 -193.5258468743 0.541E-03 0.5462712414 0.0195383821 9360.4734 + 35 -193.5258865051 0.526E-03 0.5465122059 0.0195441580 9551.4079 + 37 -193.5258836881 0.494E-03 0.5467541826 0.0195343147 9661.8428 + 38 -193.5259010938 0.481E-03 0.5467993240 0.0195381980 9769.9589 + 39 -193.5258638493 0.470E-03 0.5465996898 0.0195315354 9957.7617 + 40 -193.5259043686 0.460E-03 0.5469778558 0.0195340655 10145.9879 + 41 -193.5257495405 0.463E-03 0.5461112488 0.0195051313 10315.9007 + 42 -193.5258082877 0.455E-03 0.5464850913 0.0195150504 10502.2745 + 43 -193.5258805705 0.450E-03 0.5468777266 0.0195270746 10837.4252 + 45 -193.5258650547 0.437E-03 0.5469557154 0.0195206228 11096.8710 + 47 -193.5256833584 0.442E-03 0.5461090878 0.0194836193 11272.0578 + 48 -193.5257693923 0.441E-03 0.5467687434 0.0194937375 11403.3332 + 49 -193.5257725116 0.432E-03 0.5467626439 0.0194940883 11500.8721 + 50 -193.5258345462 0.428E-03 0.5471305576 0.0195036078 11669.3088 + 51 -193.5258830296 0.422E-03 0.5474144233 0.0195120705 11824.4876 + 53 -193.5260337047 0.423E-03 0.5482404700 0.0195410308 12054.5301 + 54 -193.5260820438 0.418E-03 0.5485940784 0.0195477877 12100.6908 + 55 -193.5260531215 0.411E-03 0.5483666523 0.0195451062 12122.4698 + 56 -193.5260731825 0.404E-03 0.5484787335 0.0195486078 12231.6939 + 58 -193.5259005838 0.395E-03 0.5473723419 0.0195222096 12395.6359 + 59 -193.5258337733 0.394E-03 0.5468943195 0.0195130968 12449.1880 + 61 -193.5259026993 0.389E-03 0.5473577229 0.0195232102 12608.2329 + 63 -193.5259603527 0.384E-03 0.5477926037 0.0195311075 12769.2169 + 64 -193.5259733560 0.378E-03 0.5478226861 0.0195337828 12771.1489 + 65 -193.5259379170 0.364E-03 0.5476961125 0.0195246901 12942.6859 + 67 -193.5259457905 0.354E-03 0.5478251818 0.0195230750 12951.1539 + 68 -193.5259055454 0.351E-03 0.5476364444 0.0195147818 13012.4958 + 69 -193.5259150895 0.346E-03 0.5477403496 0.0195145044 13107.4431 + 70 -193.5259652336 0.344E-03 0.5480037605 0.0195242175 13315.6904 + 71 -193.5258886741 0.345E-03 0.5475138792 0.0195124444 13352.0229 + 72 -193.5258686868 0.341E-03 0.5473539185 0.0195107362 13380.6639 + 74 -193.5258134356 0.334E-03 0.5469160130 0.0195042896 13710.7939 + 76 -193.5257865497 0.326E-03 0.5467388002 0.0194994695 13800.7928 + 77 -193.5257364565 0.322E-03 0.5465134438 0.0194880240 13920.8727 + 79 -193.5257675386 0.315E-03 0.5467187579 0.0194925085 14018.0599 + 80 -193.5257800977 0.311E-03 0.5467802895 0.0194944750 14184.5737 + 81 -193.5258031883 0.308E-03 0.5469343740 0.0194980214 14293.5880 + 82 -193.5258101973 0.305E-03 0.5469959669 0.0194982408 14373.0104 + 85 -193.5256961462 0.295E-03 0.5463859286 0.0194758811 14409.0218 + 86 -193.5256855245 0.292E-03 0.5462966447 0.0194745715 14641.3369 + 88 -193.5256765765 0.285E-03 0.5463068143 0.0194713392 14775.0518 + 89 -193.5256755121 0.282E-03 0.5463246200 0.0194711563 14908.1648 + 91 -193.5256339579 0.278E-03 0.5460854467 0.0194639802 14978.8759 + 92 -193.5256371567 0.275E-03 0.5462026423 0.0194618235 14980.1742 + 93 -193.5256268906 0.274E-03 0.5461190197 0.0194606850 15049.4079 + 94 -193.5256020901 0.272E-03 0.5459591487 0.0194568439 15205.7749 + 95 -193.5256101784 0.269E-03 0.5459788556 0.0194590166 15218.5398 + 97 -193.5256558659 0.266E-03 0.5461877741 0.0194692738 15545.2998 + 100 -193.5256675444 0.262E-03 0.5462798387 0.0194699994 15642.8768 + 103 -193.5255986856 0.260E-03 0.5459754931 0.0194552125 15743.9333 + 104 -193.5255914792 0.258E-03 0.5459204549 0.0194543801 15749.4419 + 105 -193.5255712971 0.256E-03 0.5458100138 0.0194505325 15865.5720 + 106 -193.5255814086 0.254E-03 0.5458634385 0.0194522676 15972.8553 + 107 -193.5255553380 0.253E-03 0.5457121532 0.0194479645 16028.3658 + 109 -193.5255311222 0.246E-03 0.5454599335 0.0194472664 16121.3579 + 112 -193.5255172206 0.240E-03 0.5454210911 0.0194434069 16236.6268 + 113 -193.5255243931 0.238E-03 0.5454913429 0.0194438836 16256.7358 + 114 -193.5255055925 0.236E-03 0.5453401486 0.0194415924 16450.7989 + 116 -193.5254756017 0.234E-03 0.5451719675 0.0194361642 16486.5348 + 117 -193.5254932879 0.232E-03 0.5452789318 0.0194390937 16530.3148 + 118 -193.5254859497 0.230E-03 0.5452979623 0.0194361028 16626.3419 + 120 -193.5254907120 0.230E-03 0.5452453476 0.0194390023 16834.1819 + 123 -193.5255248121 0.226E-03 0.5454909466 0.0194439119 16887.8968 + 124 -193.5255391312 0.225E-03 0.5456423981 0.0194448688 17011.0720 + 125 -193.5255262848 0.223E-03 0.5455776886 0.0194423306 17132.3568 + 126 -193.5255292125 0.221E-03 0.5456258758 0.0194421039 17373.3449 + 129 -193.5254893197 0.219E-03 0.5454323399 0.0194338969 17558.1501 + 132 -193.5255572841 0.213E-03 0.5459037631 0.0194421163 17633.1290 + 133 -193.5255334845 0.213E-03 0.5457668469 0.0194380269 17638.5786 + 134 -193.5255288852 0.212E-03 0.5458176716 0.0194351376 17646.1058 + 135 -193.5255177098 0.210E-03 0.5457779831 0.0194325808 17710.7220 + 137 -193.5254834876 0.209E-03 0.5455473440 0.0194272213 17792.4734 + 138 -193.5254854443 0.207E-03 0.5455365490 0.0194281825 17855.4867 + 139 -193.5255094246 0.207E-03 0.5457077054 0.0194314993 18127.5379 + 143 -193.5254352854 0.202E-03 0.5452519563 0.0194180252 18151.6758 + 144 -193.5254199032 0.201E-03 0.5451728048 0.0194148232 18164.7258 + 145 -193.5254264780 0.200E-03 0.5452190223 0.0194156067 18204.7900 + 146 -193.5254477799 0.200E-03 0.5453318680 0.0194199317 18262.0032 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 19.365097 GB ] [ VIRT MEM : 23.681385 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 72554.776610 s ] [ CPU TIME: 5065840.208218 s ] <<<<< .. + +* Number of generators 20959243 + +.. >>>>> [ RES MEM : 19.365097 GB ] [ VIRT MEM : 23.681385 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 72554.820419 s ] [ CPU TIME: 5065840.251864 s ] <<<<< .. + +* Number of selectors 20959243 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8621072422320069 + +Summary at N_det = 20971520 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.42490988 +# PT2 -0.10053790 0.00019976 +# rPT2 -0.09862266 0.00019596 +# +# E+PT2 -193.52544778 0.00019976 +# E+rPT2 -193.52353253 0.00019596 +# ============ ============================= + + N_det = 20971520 + N_states = 1 + + * State 1 + < S^2 > = 1.054280912104339E-002 + E = -193.424909876138 + Variance = 0.545331868013677 + PT norm = 0.139355415194792 + PT2 = -0.100537903743664 + rPT2 = -9.862265844817736E-002 + E+PT2 = -193.525447779881 +/- 1.997633514156506E-004 + E+rPT2 = -193.523532534586 +/- 1.959578630897259E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -762.980911250773 + Vee = 219.429272882040 + Vecp = 0.000000000000000E+000 + T = 193.236712616431 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1005 -193.53867476 + -0.1020 -193.53170513 + -0.1030 -193.53636138 + -0.1043 -193.53397583 + -0.1064 -193.54013119 + -0.1115 -193.54372081 + -0.1224 -193.54610901 + =========== =================== + +* Number of unique beta determinants 2655307 +* Number of unique alpha determinants 2697422 + +.. >>>>> [ RES MEM : 25.141449 GB ] [ VIRT MEM : 34.040554 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 80888.694701 s ] [ CPU TIME: 5634909.849516 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 41943037 +* Number of threads for diagonalization 72 +* Memory(Gb) 63.59372384473681 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.4249098764 0.010543 0.773E-03 + 2 -193.4284651060 0.011808 0.502E-04 + 3 -193.4285372046 0.011870 0.103E-04 + 4 -193.4285493815 0.011888 0.298E-06 + 5 -193.4285504636 0.011868 0.108E-06 + 6 -193.4285506921 0.011842 0.300E-07 + 7 -193.4285507941 0.011814 0.108E-07 + 8 -193.4285508186 0.011808 0.162E-08 + 9 -193.4285508228 0.011808 0.252E-09 + 10 -193.4285508235 0.011809 0.357E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 65.744747 GB ] [ VIRT MEM : 82.128513 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 163463.977510 s ] [ CPU TIME: ************** s ] <<<<< .. + + +.. >>>>> [ RES MEM : 24.807507 GB ] [ VIRT MEM : 33.690018 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 163467.994533 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Energy of state 1 -193.4285508234690 +* S^2 of state 1 0.1180893728642071E-01 +* Saved determinants 41943037 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 23.730713 GB ] [ VIRT MEM : 28.006802 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 164019.242355 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 41911940 + +.. >>>>> [ RES MEM : 23.730713 GB ] [ VIRT MEM : 28.006802 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 164019.333281 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 41911940 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -193.4285508234690 + +.. >>>>> [ RES MEM : 31.075512 GB ] [ VIRT MEM : 35.354301 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 164055.766213 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 41911940 + +.. >>>>> [ RES MEM : 31.075512 GB ] [ VIRT MEM : 35.354301 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 164055.852816 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 41911940 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 42844420 +* Number of fragmented tasks 19646 +* Number of threads for PT2 72 +* Memory (Gb) 27.66251030489802 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.5263054825 0.211E-02 0.5327689001 0.0188100639 2959.0890 + 4 -193.5272579796 0.176E-02 0.5379697488 0.0189903218 3712.0472 + 5 -193.5261232951 0.193E-02 0.5320124141 0.0187647220 4369.0377 + 6 -193.5270043448 0.181E-02 0.5369607737 0.0189288500 5125.1894 + 7 -193.5277461510 0.170E-02 0.5404349080 0.0190804282 5711.2374 + 8 -193.5276938830 0.148E-02 0.5407667206 0.0190619319 6385.8404 + 9 -193.5279987489 0.134E-02 0.5423135004 0.0191217737 7103.7925 + 10 -193.5278697258 0.120E-02 0.5407985912 0.0191205481 7512.4751 + 11 -193.5275272024 0.114E-02 0.5389457187 0.0190591879 7616.1468 + 12 -193.5268985128 0.122E-02 0.5356551319 0.0189397293 8209.8592 + 13 -193.5267065732 0.109E-02 0.5353179168 0.0188767211 8495.6454 + 14 -193.5269139203 0.103E-02 0.5358677129 0.0189291074 9063.5617 + 15 -193.5269067945 0.960E-03 0.5356663935 0.0189312850 9570.5571 + 16 -193.5266337014 0.939E-03 0.5339928094 0.0188869540 9657.7824 + 17 -193.5267197334 0.876E-03 0.5344452753 0.0189037538 9808.8821 + 18 -193.5270491877 0.890E-03 0.5369244480 0.0189494440 10220.4867 + 19 -193.5270119010 0.842E-03 0.5365101672 0.0189483929 10866.7380 + 20 -193.5270028972 0.801E-03 0.5366224691 0.0189423788 11467.9423 + 21 -193.5271658219 0.779E-03 0.5380799611 0.0189604179 11690.1962 + 22 -193.5271488354 0.742E-03 0.5376785891 0.0189669890 11890.0204 + 23 -193.5274487374 0.798E-03 0.5392105871 0.0190259561 12180.5583 + 24 -193.5272044925 0.802E-03 0.5379556679 0.0189757811 12531.7502 + 25 -193.5272086682 0.769E-03 0.5379624203 0.0189782533 12683.1709 + 26 -193.5272732024 0.741E-03 0.5381383024 0.0189955879 12808.9241 + 27 -193.5272779825 0.713E-03 0.5381906766 0.0189947442 13373.3197 + 28 -193.5274333409 0.705E-03 0.5389063558 0.0190275674 13978.0943 + 29 -193.5272350685 0.662E-03 0.5381919943 0.0189744460 14529.8577 + 30 -193.5271747703 0.642E-03 0.5378921804 0.0189624095 14997.4293 + 31 -193.5271149813 0.624E-03 0.5374585643 0.0189537816 15197.6205 + 32 -193.5270288347 0.610E-03 0.5369319344 0.0189382955 15670.6880 + 33 -193.5270197299 0.591E-03 0.5367931862 0.0189378801 16097.1503 + 34 -193.5269362196 0.564E-03 0.5362102239 0.0189291173 16521.9109 + 35 -193.5271350849 0.583E-03 0.5372383487 0.0189663522 16907.5044 + 36 -193.5270280220 0.577E-03 0.5367843246 0.0189423930 16981.8399 + 37 -193.5270721021 0.556E-03 0.5370665391 0.0189490354 17365.4485 + 39 -193.5272478785 0.545E-03 0.5381953296 0.0189750269 17531.8413 + 40 -193.5271471035 0.540E-03 0.5373914099 0.0189630644 17762.7503 + 41 -193.5271217505 0.527E-03 0.5372940896 0.0189568420 18200.7120 + 42 -193.5270357542 0.516E-03 0.5371229067 0.0189287357 18596.5445 + 43 -193.5269402476 0.513E-03 0.5364941173 0.0189141629 19084.0799 + 44 -193.5268537822 0.509E-03 0.5358953763 0.0189015446 19329.4485 + 45 -193.5268550040 0.497E-03 0.5358537296 0.0189034386 19367.8053 + 46 -193.5267472588 0.477E-03 0.5353141333 0.0188811813 19668.5885 + 47 -193.5266750097 0.472E-03 0.5348645263 0.0188706816 19944.0073 + 48 -193.5266326323 0.464E-03 0.5345568736 0.0188644058 20216.9448 + 49 -193.5265333687 0.454E-03 0.5341630799 0.0188412941 20271.6243 + 50 -193.5265246829 0.445E-03 0.5342432510 0.0188371145 20583.5322 + 51 -193.5265041523 0.437E-03 0.5340196880 0.0188361404 20794.5583 + 52 -193.5265418402 0.430E-03 0.5342333122 0.0188430135 21151.7404 + 54 -193.5264374398 0.421E-03 0.5336287670 0.0188250526 21355.4004 + 55 -193.5264216333 0.413E-03 0.5336185126 0.0188199150 21557.2094 + 56 -193.5263447243 0.413E-03 0.5332236844 0.0188054866 21734.9344 + 58 -193.5262852650 0.409E-03 0.5328407606 0.0187954639 21904.2684 + 59 -193.5263097623 0.408E-03 0.5329412752 0.0188002091 22060.0282 + 61 -193.5263915438 0.402E-03 0.5335173342 0.0188115692 22180.4819 + 62 -193.5264186962 0.397E-03 0.5335813756 0.0188189483 22423.1085 + 63 -193.5264693888 0.394E-03 0.5337614500 0.0188313555 22818.3233 + 64 -193.5264857967 0.388E-03 0.5337716673 0.0188361764 22831.0066 + 65 -193.5264467294 0.384E-03 0.5334771030 0.0188320901 22887.2814 + 67 -193.5263911359 0.376E-03 0.5331072671 0.0188244121 23139.7953 + 68 -193.5263649637 0.371E-03 0.5330947428 0.0188151988 23250.2201 + 69 -193.5263374884 0.367E-03 0.5329133707 0.0188109775 23289.3643 + 70 -193.5263629199 0.362E-03 0.5331101318 0.0188147456 23488.8385 + 71 -193.5263368334 0.366E-03 0.5329715183 0.0188106280 23653.7873 + 72 -193.5263402073 0.360E-03 0.5328735057 0.0188142540 23795.4302 + 74 -193.5263605181 0.358E-03 0.5331005570 0.0188136853 24131.4836 + 75 -193.5263415224 0.354E-03 0.5330559550 0.0188082331 24347.2483 + 76 -193.5263750983 0.351E-03 0.5333018263 0.0188126832 24449.1133 + 77 -193.5264444392 0.353E-03 0.5336441783 0.0188271609 24602.7132 + 78 -193.5263927099 0.345E-03 0.5332318309 0.0188228871 24847.1710 + 79 -193.5263874757 0.340E-03 0.5331566043 0.0188231225 25023.8083 + 80 -193.5263564127 0.337E-03 0.5329922301 0.0188167028 25179.1015 + 81 -193.5263924975 0.335E-03 0.5331967908 0.0188233805 25401.3453 + 82 -193.5263617665 0.332E-03 0.5330570128 0.0188167178 25441.3283 + 83 -193.5263349950 0.329E-03 0.5329318527 0.0188109875 25582.1833 + 84 -193.5263772585 0.325E-03 0.5332617827 0.0188143419 25679.5704 + 85 -193.5263475440 0.322E-03 0.5330304766 0.0188107895 25730.3738 + 86 -193.5263419772 0.319E-03 0.5330511212 0.0188086932 25996.3023 + 87 -193.5263765320 0.317E-03 0.5332617929 0.0188145464 26234.9532 + 88 -193.5263614895 0.314E-03 0.5331622373 0.0188122960 26352.8868 + 90 -193.5264512258 0.320E-03 0.5337232723 0.0188270306 26530.2295 + 91 -193.5264056090 0.320E-03 0.5334148540 0.0188206094 26709.1634 + 92 -193.5264426132 0.318E-03 0.5336092468 0.0188272790 26823.0444 + 93 -193.5264541844 0.313E-03 0.5336425688 0.0188296759 26973.8873 + 94 -193.5264240626 0.311E-03 0.5334993353 0.0188233866 27213.9963 + 95 -193.5263943227 0.310E-03 0.5333395983 0.0188176312 27404.7654 + 97 -193.5263817156 0.306E-03 0.5333378855 0.0188130931 27548.0996 + 98 -193.5263524367 0.305E-03 0.5331183164 0.0188092483 27865.9559 + 101 -193.5264133622 0.297E-03 0.5335417831 0.0188176231 28021.4715 + 103 -193.5263521829 0.294E-03 0.5331821102 0.0188066542 28072.6502 + 104 -193.5263036757 0.295E-03 0.5328635861 0.0187992914 28314.3263 + 105 -193.5263503264 0.296E-03 0.5331698357 0.0188066122 28515.7904 + 106 -193.5263453463 0.293E-03 0.5332210368 0.0188036223 28623.4184 + 107 -193.5262976385 0.295E-03 0.5329490265 0.0187956950 28783.7783 + 110 -193.5262875239 0.286E-03 0.5329685807 0.0187922950 28824.1913 + 111 -193.5263291837 0.287E-03 0.5332372248 0.0187989699 28965.9684 + 112 -193.5263197941 0.284E-03 0.5332159501 0.0187963312 29212.1876 + 113 -193.5263238671 0.282E-03 0.5332099499 0.0187978458 29297.7763 + 114 -193.5263356702 0.280E-03 0.5332279503 0.0188013211 29446.8206 + 115 -193.5263814346 0.281E-03 0.5334718269 0.0188100575 29596.2433 + 116 -193.5263905055 0.279E-03 0.5335550765 0.0188108243 29619.7661 + 117 -193.5264271484 0.279E-03 0.5337876502 0.0188164496 29747.4962 + 119 -193.5264115254 0.275E-03 0.5337122238 0.0188130224 29903.4775 + 120 -193.5263884388 0.273E-03 0.5335627707 0.0188096293 29985.9617 + 121 -193.5264012952 0.271E-03 0.5336072847 0.0188126949 30233.6023 + 123 -193.5264130859 0.266E-03 0.5336571669 0.0188166363 30404.9156 + 124 -193.5264340091 0.265E-03 0.5337808032 0.0188205893 30592.9881 + 125 -193.5264395078 0.263E-03 0.5338134611 0.0188215953 30780.4154 + 126 -193.5264282082 0.261E-03 0.5337306764 0.0188204502 30990.3116 + 127 -193.5264486474 0.260E-03 0.5338369724 0.0188243776 31108.2883 + 128 -193.5264396826 0.258E-03 0.5337510474 0.0188237626 31209.0985 + 129 -193.5264050161 0.258E-03 0.5335738132 0.0188167549 31529.7344 + 132 -193.5263969045 0.249E-03 0.5335687540 0.0188143760 31697.4515 + 135 -193.5263569566 0.245E-03 0.5333045652 0.0188089872 31769.1943 + 136 -193.5263031432 0.249E-03 0.5329615306 0.0188004855 31932.4893 + 137 -193.5263028373 0.248E-03 0.5329600172 0.0188003437 32109.0782 + 138 -193.5262939563 0.246E-03 0.5329265418 0.0187982066 32276.0302 + 139 -193.5263019377 0.240E-03 0.5329672698 0.0187992683 32437.0820 + 140 -193.5263475592 0.243E-03 0.5332755926 0.0188062612 32570.2203 + 143 -193.5263562294 0.238E-03 0.5332955672 0.0188084341 32633.2777 + 144 -193.5263657325 0.236E-03 0.5333379831 0.0188106296 32784.1054 + 146 -193.5264074503 0.235E-03 0.5336019624 0.0188173750 32855.5483 + 147 -193.5264267520 0.234E-03 0.5336836747 0.0188218128 33011.4813 + 148 -193.5264339119 0.229E-03 0.5337414441 0.0188223415 33089.9343 + 149 -193.5264371568 0.227E-03 0.5337728948 0.0188226585 33176.1920 + 150 -193.5264563387 0.227E-03 0.5338765798 0.0188262814 33200.4745 + 151 -193.5264485847 0.225E-03 0.5338158631 0.0188253459 33301.3463 + 152 -193.5264451849 0.224E-03 0.5338675185 0.0188231058 33447.7813 + 153 -193.5264254318 0.223E-03 0.5337576357 0.0188194134 33571.5543 + 154 -193.5264126538 0.222E-03 0.5336885377 0.0188173867 33683.0574 + 155 -193.5263744783 0.219E-03 0.5334514278 0.0188109679 33880.0113 + 156 -193.5263757538 0.218E-03 0.5334410956 0.0188116270 33977.7073 + 157 -193.5263559454 0.218E-03 0.5333472007 0.0188073859 34056.3174 + 158 -193.5263712866 0.217E-03 0.5334931157 0.0188085202 34125.8694 + 159 -193.5263763066 0.215E-03 0.5334733889 0.0188106554 34235.2155 + 160 -193.5263778930 0.214E-03 0.5335058132 0.0188100195 34338.9287 + 161 -193.5264056381 0.214E-03 0.5336771361 0.0188145156 34353.9098 + 162 -193.5263856699 0.214E-03 0.5335593850 0.0188110626 34473.1503 + 163 -193.5263879494 0.213E-03 0.5335615619 0.0188117369 34592.5279 + 165 -193.5264366338 0.213E-03 0.5338439865 0.0188206534 34758.1073 + 167 -193.5264457003 0.210E-03 0.5338473221 0.0188237812 34793.5262 + 168 -193.5264444541 0.208E-03 0.5338582986 0.0188233362 34897.4914 + 169 -193.5264936958 0.213E-03 0.5341483462 0.0188320464 35036.8803 + 170 -193.5265065423 0.212E-03 0.5341952981 0.0188350612 35175.6244 + 171 -193.5265054467 0.211E-03 0.5341972650 0.0188346123 35275.8400 + 172 -193.5265106708 0.210E-03 0.5342017501 0.0188362076 35392.5109 + 173 -193.5264977932 0.209E-03 0.5341373279 0.0188336824 35424.0514 + 174 -193.5264910709 0.208E-03 0.5340967158 0.0188328015 35560.5836 + 175 -193.5264958370 0.207E-03 0.5341499709 0.0188329532 35688.4673 + 176 -193.5264827863 0.206E-03 0.5340702479 0.0188305755 35768.1972 + 177 -193.5264695860 0.205E-03 0.5339744626 0.0188287330 35870.5952 + 179 -193.5264602450 0.203E-03 0.5339533607 0.0188261292 35905.0167 + 180 -193.5264616870 0.202E-03 0.5339689128 0.0188262663 35987.7137 + 181 -193.5264446257 0.201E-03 0.5338765436 0.0188229023 36143.5908 + 182 -193.5264176285 0.198E-03 0.5336891996 0.0188188328 36258.5853 + 184 -193.5264451634 0.197E-03 0.5338672012 0.0188230551 36262.4273 + 186 -193.5264364298 0.195E-03 0.5337969405 0.0188219572 36344.2754 + 187 -193.5264228389 0.194E-03 0.5337624747 0.0188185328 36457.8358 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 31.099121 GB ] [ VIRT MEM : 35.808483 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 200676.371758 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 41911940 + +.. >>>>> [ RES MEM : 31.099121 GB ] [ VIRT MEM : 35.808483 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 200676.463145 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 41911940 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8658873901060481 + +Summary at N_det = 41943037 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.42855082 +# PT2 -0.09787202 0.00019420 +# rPT2 -0.09606423 0.00019062 +# +# E+PT2 -193.52642284 0.00019420 +# E+rPT2 -193.52461505 0.00019062 +# ============ ============================= + + N_det = 41943037 + N_states = 1 + + * State 1 + < S^2 > = 1.180893728642071E-002 + E = -193.428550823469 + Variance = 0.533762474703520 + PT norm = 0.137180657647228 + PT2 = -9.787201542547216E-002 + rPT2 = -9.606422760426996E-002 + E+PT2 = -193.526422838895 +/- 1.942046543930616E-004 + E+rPT2 = -193.524615051073 +/- 1.906175124760761E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -762.981782151069 + Vee = 219.420171071215 + Vecp = 0.000000000000000E+000 + T = 193.243044380220 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0986 -193.56526149 + -0.1005 -193.55473849 + -0.1020 -193.54676297 + -0.1030 -193.54621931 + -0.1043 -193.54282515 + -0.1064 -193.54438230 + -0.1115 -193.54526934 + =========== =================== + +* Number of unique beta determinants 3846295 +* Number of unique alpha determinants 3891399 + +.. >>>>> [ RES MEM : 45.338257 GB ] [ VIRT MEM : 56.260654 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 234848.880325 s ] [ CPU TIME: ************** s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 83886073 +* Number of threads for diagonalization 72 +* Memory(Gb) 122.7459119111300 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.4285508236 0.011809 0.160E-02 + 2 -193.4359119716 0.013952 0.186E-03 + 3 -193.4361094787 0.014004 0.237E-04 + 4 -193.4361456156 0.013978 0.103E-05 + 5 -193.4361492958 0.013872 0.344E-06 + 6 -193.4361500772 0.013792 0.786E-07 + 7 -193.4361503080 0.013735 0.233E-07 + 8 -193.4361503607 0.013719 0.449E-08 + 9 -193.4361503718 0.013713 0.819E-09 diff --git a/cyclopentadiene/cc-pvdz/slurm-486827.out b/cyclopentadiene/cc-pvdz/slurm-486827.out index 945d8e6..6301733 100644 --- a/cyclopentadiene/cc-pvdz/slurm-486827.out +++ b/cyclopentadiene/cc-pvdz/slurm-486827.out @@ -8248,3 +8248,22885 @@ 2.85 % in 312 seconds 3.04 % in 360 seconds 3.23 % in 410 seconds + 3.42 % in 459 seconds + 3.99 % in 473 seconds + 4.18 % in 488 seconds + 4.37 % in 501 seconds + 4.75 % in 512 seconds + 4.94 % in 526 seconds + 5.32 % in 539 seconds + 5.51 % in 549 seconds + 5.70 % in 559 seconds + 6.27 % in 578 seconds + 6.46 % in 592 seconds + 6.84 % in 607 seconds + 7.22 % in 621 seconds + 7.41 % in 631 seconds + 7.79 % in 642 seconds + 8.37 % in 658 seconds + 8.75 % in 671 seconds + 9.13 % in 688 seconds + 9.51 % in 698 seconds +10.27 % in 712 seconds +10.65 % in 726 seconds +11.03 % in 742 seconds +11.41 % in 755 seconds +12.36 % in 768 seconds +12.74 % in 781 seconds +13.12 % in 794 seconds +13.50 % in 808 seconds +14.64 % in 822 seconds +15.02 % in 833 seconds +15.40 % in 846 seconds +15.78 % in 862 seconds +17.11 % in 874 seconds +17.49 % in 886 seconds +17.87 % in 900 seconds +18.25 % in 917 seconds +19.77 % in 930 seconds +20.15 % in 941 seconds +20.53 % in 958 seconds +21.48 % in 968 seconds +22.05 % in 979 seconds +22.43 % in 991 seconds +22.81 % in 1008 seconds +23.76 % in 1018 seconds +24.71 % in 1029 seconds +25.10 % in 1041 seconds +25.48 % in 1057 seconds +26.24 % in 1067 seconds +27.38 % in 1077 seconds +27.76 % in 1089 seconds +28.14 % in 1106 seconds +28.71 % in 1116 seconds +30.23 % in 1129 seconds +30.61 % in 1141 seconds +30.99 % in 1157 seconds +31.75 % in 1167 seconds +33.08 % in 1177 seconds +33.46 % in 1189 seconds +33.84 % in 1206 seconds +34.60 % in 1216 seconds +35.93 % in 1226 seconds +36.31 % in 1238 seconds +36.69 % in 1252 seconds +38.40 % in 1263 seconds +38.78 % in 1274 seconds +39.16 % in 1286 seconds +40.68 % in 1296 seconds +41.06 % in 1310 seconds +41.63 % in 1320 seconds +43.16 % in 1332 seconds +43.54 % in 1346 seconds +44.30 % in 1356 seconds +45.63 % in 1366 seconds +46.01 % in 1379 seconds +46.58 % in 1389 seconds +48.10 % in 1400 seconds +48.48 % in 1411 seconds +48.86 % in 1422 seconds +50.57 % in 1433 seconds +51.14 % in 1449 seconds +52.09 % in 1459 seconds +53.23 % in 1471 seconds +53.61 % in 1485 seconds +55.32 % in 1496 seconds +55.89 % in 1509 seconds +56.46 % in 1519 seconds +57.98 % in 1529 seconds +58.56 % in 1546 seconds +59.89 % in 1556 seconds +60.84 % in 1571 seconds +61.79 % in 1581 seconds +63.12 % in 1596 seconds +63.50 % in 1607 seconds +65.21 % in 1617 seconds +65.59 % in 1632 seconds +67.11 % in 1642 seconds +67.68 % in 1657 seconds +69.20 % in 1668 seconds +69.77 % in 1678 seconds +70.53 % in 1688 seconds +71.67 % in 1700 seconds +72.05 % in 1711 seconds +73.57 % in 1724 seconds +74.14 % in 1734 seconds +75.48 % in 1752 seconds +76.81 % in 1763 seconds +77.57 % in 1778 seconds +79.09 % in 1789 seconds +79.47 % in 1800 seconds +80.99 % in 1813 seconds +81.37 % in 1823 seconds +82.89 % in 1840 seconds +83.84 % in 1850 seconds +84.60 % in 1863 seconds +85.93 % in 1874 seconds +86.31 % in 1885 seconds +87.45 % in 1895 seconds +88.21 % in 1908 seconds +89.54 % in 1925 seconds +90.87 % in 1935 seconds +91.25 % in 1947 seconds +92.40 % in 1958 seconds +93.35 % in 1969 seconds +93.92 % in 1980 seconds +95.06 % in 1990 seconds +95.82 % in 2000 seconds +96.39 % in 2011 seconds +97.53 % in 2026 seconds +98.48 % in 2037 seconds +99.43 % in 2047 seconds + 0.19 % in 17 seconds + 0.38 % in 35 seconds + 0.76 % in 51 seconds + 1.14 % in 67 seconds + 1.52 % in 83 seconds + 1.90 % in 99 seconds + 2.09 % in 125 seconds + 2.28 % in 173 seconds + 2.47 % in 222 seconds + 2.66 % in 270 seconds + 2.85 % in 320 seconds + 3.04 % in 370 seconds + 3.23 % in 419 seconds + 3.42 % in 467 seconds + 3.99 % in 481 seconds + 4.18 % in 496 seconds + 4.37 % in 509 seconds + 4.75 % in 520 seconds + 4.94 % in 534 seconds + 5.32 % in 546 seconds + 5.51 % in 556 seconds + 5.70 % in 567 seconds + 6.27 % in 585 seconds + 6.46 % in 600 seconds + 6.84 % in 615 seconds + 7.22 % in 629 seconds + 7.60 % in 647 seconds + 8.37 % in 666 seconds + 8.75 % in 679 seconds + 9.13 % in 697 seconds + 9.51 % in 707 seconds +10.27 % in 720 seconds +10.65 % in 734 seconds +11.03 % in 750 seconds +11.41 % in 762 seconds +12.36 % in 775 seconds +12.74 % in 788 seconds +13.12 % in 801 seconds +13.50 % in 816 seconds +14.64 % in 829 seconds +15.02 % in 840 seconds +15.40 % in 854 seconds +15.78 % in 869 seconds +17.11 % in 882 seconds +17.49 % in 894 seconds +17.87 % in 908 seconds +18.25 % in 925 seconds +19.58 % in 935 seconds +20.15 % in 949 seconds +20.34 % in 959 seconds +20.72 % in 971 seconds +21.86 % in 981 seconds +22.24 % in 994 seconds +22.62 % in 1008 seconds +23.00 % in 1022 seconds +24.52 % in 1032 seconds +24.90 % in 1043 seconds +25.29 % in 1058 seconds +25.67 % in 1073 seconds +27.19 % in 1083 seconds +27.57 % in 1093 seconds +27.95 % in 1107 seconds +28.33 % in 1123 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seconds +32.68 % in 20538 seconds +32.73 % in 20579 seconds +32.78 % in 20600 seconds +32.87 % in 20612 seconds +32.97 % in 20622 seconds +33.06 % in 20632 seconds +33.16 % in 20643 seconds +33.30 % in 20657 seconds +33.44 % in 20671 seconds +33.54 % in 20681 seconds +33.68 % in 20695 seconds +33.78 % in 20705 seconds +33.87 % in 20715 seconds +34.02 % in 20729 seconds +34.11 % in 20739 seconds +34.25 % in 20753 seconds +34.35 % in 20763 seconds +34.49 % in 20777 seconds +34.59 % in 20787 seconds +34.68 % in 20812 seconds +34.73 % in 20842 seconds +34.83 % in 20885 seconds +34.87 % in 20903 seconds +34.92 % in 20942 seconds +34.97 % in 20971 seconds +35.02 % in 20992 seconds +35.06 % in 21037 seconds +35.11 % in 21070 seconds +35.16 % in 21108 seconds diff --git a/cyclopentadiene/cc-pvtz/cyclopentadiene.fci.out b/cyclopentadiene/cc-pvtz/cyclopentadiene.fci.out index 3c5a9ba..41e5992 100644 --- a/cyclopentadiene/cc-pvtz/cyclopentadiene.fci.out +++ b/cyclopentadiene/cc-pvtz/cyclopentadiene.fci.out @@ -3478,3 +3478,557 @@ Iter Energy S^2 Residual 86 -193.6912274660 0.375E-03 0.9401376139 0.0228460320 34393.8162 91 -193.6913526123 0.362E-03 0.9410168804 0.0228634379 35906.0120 96 -193.6913239526 0.358E-03 0.9409313858 0.0228470834 36737.6863 + 97 -193.6913507280 0.355E-03 0.9412131130 0.0228500596 39334.3141 + 113 -193.6912982938 0.328E-03 0.9404918580 0.0228480784 41084.8571 + 123 -193.6913711675 0.304E-03 0.9408002749 0.0228632947 41449.6133 + 124 -193.6913602098 0.302E-03 0.9407201917 0.0228621786 41566.0732 + 125 -193.6913291227 0.301E-03 0.9404831417 0.0228578738 42453.7683 + 128 -193.6912941711 0.295E-03 0.9399563725 0.0228565588 42606.1433 + 131 -193.6913177200 0.290E-03 0.9398068491 0.0228652187 43399.3912 + 134 -193.6913110538 0.284E-03 0.9394946297 0.0228680312 43428.0223 + 135 -193.6913124496 0.282E-03 0.9394156587 0.0228695681 43689.2578 + 136 -193.6912955896 0.280E-03 0.9392728409 0.0228673925 44681.3662 + 138 -193.6913023508 0.276E-03 0.9391943205 0.0228711799 44983.9292 + 141 -193.6912701258 0.268E-03 0.9393247557 0.0228570285 45372.6210 + 142 -193.6912890185 0.267E-03 0.9394079302 0.0228621409 46678.3031 + 143 -193.6912853271 0.265E-03 0.9394682093 0.0228599404 47165.2451 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 24.876247 GB ] [ VIRT MEM : 28.718983 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 94947.329946 s ] [ CPU TIME: 6745619.683493 s ] <<<<< .. + +* Number of generators 2621434 + +.. >>>>> [ RES MEM : 24.876247 GB ] [ VIRT MEM : 28.718983 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 94947.336550 s ] [ CPU TIME: 6745620.152377 s ] <<<<< .. + +* Number of selectors 2621434 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8391756467393500 + +Summary at N_det = 2621440 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.55468885 +# PT2 -0.13659648 0.00026515 +# rPT2 -0.13354368 0.00025923 +# +# E+PT2 -193.69128533 0.00026515 +# E+rPT2 -193.68823253 0.00025923 +# ============ ============================= + + N_det = 2621440 + N_states = 1 + + * State 1 + < S^2 > = 1.504950573694084E-003 + E = -193.554688847587 + Variance = 0.939468209296127 + PT norm = 0.151195040821503 + PT2 = -0.136596479538327 + rPT2 = -0.133543678999734 + E+PT2 = -193.691285327126 +/- 2.651514271726570E-004 + E+rPT2 = -193.688232526587 +/- 2.592255466344675E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.214991624719 + Vee = 219.464664225875 + Vecp = 0.000000000000000E+000 + T = 193.305622675092 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1429 -193.71518674 + -0.1692 -193.72098006 + -0.2179 -193.70985694 + -0.2741 -193.71149067 + -0.3356 -193.71277612 + -0.3945 -193.71502944 + -0.4485 -193.71735872 + =========== =================== + +* Number of unique beta determinants 646298 +* Number of unique alpha determinants 631818 + +.. >>>>> [ RES MEM : 27.164162 GB ] [ VIRT MEM : 31.685364 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 97209.399819 s ] [ CPU TIME: 6893205.218567 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5242880 +* Number of threads for diagonalization 72 +* Memory(Gb) 9.555917780846357 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.5546888479 0.001505 0.114E-02 + 2 -193.5595014260 0.002641 0.287E-03 + 3 -193.5598061964 0.002922 0.483E-04 + 4 -193.5599276121 0.003138 0.174E-04 + 5 -193.5599608024 0.003192 0.124E-05 + 6 -193.5599647295 0.003168 0.206E-06 + 7 -193.5599651754 0.003156 0.112E-07 + 8 -193.5599652027 0.003151 0.994E-09 + 9 -193.5599652048 0.003149 0.881E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 31.933395 GB ] [ VIRT MEM : 37.624340 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 117259.189067 s ] [ CPU TIME: 8199907.497379 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 27.089886 GB ] [ VIRT MEM : 31.606747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 117259.729992 s ] [ CPU TIME: 8199913.784743 s ] <<<<< .. + +* Energy of state 1 -193.5599652048467 +* S^2 of state 1 0.3149127056743814E-02 +* Saved determinants 5242880 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 25.811470 GB ] [ VIRT MEM : 29.824699 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 117365.519955 s ] [ CPU TIME: 8201432.041001 s ] <<<<< .. + +* Number of generators 5242815 + +.. >>>>> [ RES MEM : 25.811470 GB ] [ VIRT MEM : 29.824699 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 117365.531712 s ] [ CPU TIME: 8201432.885676 s ] <<<<< .. + +* Number of selectors 5242815 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 +* PT2 Energy denominator -193.5599652048467 + +.. >>>>> [ RES MEM : 27.441170 GB ] [ VIRT MEM : 31.456078 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 117369.862160 s ] [ CPU TIME: 8201606.891113 s ] <<<<< .. + +* Number of generators 5242815 + +.. >>>>> [ RES MEM : 27.441170 GB ] [ VIRT MEM : 31.456078 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 117369.873332 s ] [ CPU TIME: 8201606.902200 s ] <<<<< .. + +* Number of selectors 5242815 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 +* Number of tasks 9217115 +* Number of fragmented tasks 107455 +* Number of threads for PT2 72 +* Memory (Gb) 102.1437992790714 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.6966756012 0.161E-02 0.9655117525 0.0221392020 11378.6595 + 8 -193.6953974860 0.116E-02 0.9455793743 0.0222639573 12414.3589 + 9 -193.6940958285 0.169E-02 0.9349923229 0.0220781515 15506.9935 + 15 -193.6932548558 0.118E-02 0.9235089457 0.0220304006 15535.7957 + 17 -193.6930500960 0.119E-02 0.9225697865 0.0219793108 15872.5642 + 18 -193.6926539995 0.119E-02 0.9207311321 0.0218970938 17192.3539 + 19 -193.6925292302 0.113E-02 0.9201388711 0.0218754243 21084.4346 + 23 -193.6924144586 0.951E-03 0.9198839455 0.0218648722 22897.3900 + 29 -193.6925447153 0.858E-03 0.9222880038 0.0218433596 26398.3448 + 34 -193.6926990464 0.744E-03 0.9233752481 0.0218701450 27267.9162 + 35 -193.6927917893 0.749E-03 0.9232417122 0.0219001858 27363.3637 + 36 -193.6929017626 0.736E-03 0.9243264578 0.0219113287 27874.1887 + 37 -193.6929833572 0.720E-03 0.9249772783 0.0219225792 28164.6188 + 38 -193.6928887386 0.707E-03 0.9244943746 0.0219052288 28856.3833 + 39 -193.6928758578 0.689E-03 0.9243377094 0.0219056755 29715.7805 + 40 -193.6930013383 0.683E-03 0.9252905848 0.0219237513 32109.7516 + 41 -193.6929619367 0.667E-03 0.9249227821 0.0219163086 32767.6867 + 44 -193.6931245884 0.640E-03 0.9267327417 0.0219338456 35384.0227 + 48 -193.6931659319 0.591E-03 0.9272522326 0.0219360552 37100.2716 + 54 -193.6930541488 0.528E-03 0.9258304769 0.0219385479 37751.2286 + 55 -193.6929624378 0.527E-03 0.9252920551 0.0219195600 37993.8587 + 56 -193.6929661802 0.517E-03 0.9253702364 0.0219200810 39600.0225 + 57 -193.6929396712 0.509E-03 0.9252101436 0.0219167799 39676.6576 + 60 -193.6930285849 0.491E-03 0.9259865290 0.0219262299 39766.4959 + 61 -193.6929548919 0.488E-03 0.9256101165 0.0219141778 40219.7883 + 62 -193.6929728044 0.480E-03 0.9258022180 0.0219191666 41442.5776 + 63 -193.6930936345 0.488E-03 0.9264797860 0.0219442510 41641.4014 + 65 -193.6930919157 0.473E-03 0.9265127107 0.0219406546 41919.3670 + 67 -193.6931102734 0.463E-03 0.9265886280 0.0219471664 42461.6157 + 68 -193.6931223198 0.457E-03 0.9266408321 0.0219509344 43168.7512 + 69 -193.6930192078 0.422E-03 0.9255760958 0.0219466462 43532.7359 + 70 -193.6930735921 0.419E-03 0.9261450159 0.0219520413 43610.3849 + 71 -193.6930877751 0.413E-03 0.9265181246 0.0219500532 44411.4178 + 72 -193.6930885184 0.408E-03 0.9263972773 0.0219531513 45112.6244 + 74 -193.6931109074 0.398E-03 0.9263271211 0.0219629629 48248.4465 + 76 -193.6931632807 0.390E-03 0.9268519119 0.0219675999 51915.6995 + 87 -193.6931782594 0.356E-03 0.9268676268 0.0219726286 52138.1837 + 89 -193.6932181109 0.350E-03 0.9269108157 0.0219831755 52295.3065 + 90 -193.6932052958 0.347E-03 0.9267283650 0.0219825544 52431.6700 + 91 -193.6932536468 0.338E-03 0.9274917870 0.0219806939 54483.7960 + 93 -193.6932763851 0.332E-03 0.9274413446 0.0219906551 55635.7818 + 97 -193.6932228346 0.322E-03 0.9268743604 0.0219889983 55776.1418 + 98 -193.6931987769 0.320E-03 0.9267039840 0.0219853394 56236.7845 + 99 -193.6931994909 0.317E-03 0.9267657953 0.0219846364 56382.2227 + 100 -193.6932361881 0.316E-03 0.9269878883 0.0219901864 56591.9348 + 101 -193.6931944812 0.315E-03 0.9268304140 0.0219811469 56787.4197 + 102 -193.6931655669 0.313E-03 0.9265805660 0.0219754862 57068.9722 + 103 -193.6932127625 0.314E-03 0.9267048810 0.0219859634 57642.7047 + 104 -193.6932329045 0.312E-03 0.9270734552 0.0219832297 58425.1678 + 105 -193.6932348869 0.309E-03 0.9271733885 0.0219816989 58707.2922 + 107 -193.6932606923 0.303E-03 0.9271401822 0.0219907095 59104.0017 + 108 -193.6932656696 0.301E-03 0.9270881828 0.0219931465 59296.9510 + 109 -193.6932728001 0.298E-03 0.9271443125 0.0219926798 60103.0941 + 110 -193.6932514818 0.294E-03 0.9268376865 0.0219935609 60645.7070 + 111 -193.6932383813 0.291E-03 0.9266666255 0.0219919041 60867.5198 + 113 -193.6932327858 0.290E-03 0.9265468446 0.0219933487 61389.4526 + 114 -193.6932369279 0.288E-03 0.9266759193 0.0219919951 62123.0665 + 115 -193.6932592677 0.286E-03 0.9268409710 0.0219949670 62737.9658 + 118 -193.6932097947 0.282E-03 0.9265397211 0.0219878282 62926.8298 + 119 -193.6932252883 0.280E-03 0.9267757529 0.0219892374 63218.5277 + 120 -193.6932321285 0.278E-03 0.9266572577 0.0219931798 63960.9717 + 122 -193.6932335168 0.273E-03 0.9267498581 0.0219917366 64571.4714 + 123 -193.6932765902 0.274E-03 0.9272213962 0.0219946206 69341.6465 + 127 -193.6932865563 0.267E-03 0.9271121202 0.0220008388 69872.1164 + 134 -193.6931134539 0.261E-03 0.9254860078 0.0219824890 70256.0963 + 135 -193.6930976785 0.260E-03 0.9254280082 0.0219788295 71278.2726 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 28.539337 GB ] [ VIRT MEM : 32.355606 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 188678.203827 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 5242815 + +.. >>>>> [ RES MEM : 28.539337 GB ] [ VIRT MEM : 32.355606 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 188678.215857 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 5242815 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8434572963378427 + +Summary at N_det = 5242880 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.55996520 +# PT2 -0.13317237 0.00025933 +# rPT2 -0.13030774 0.00025376 +# +# E+PT2 -193.69313758 0.00025933 +# E+rPT2 -193.69027294 0.00025376 +# ============ ============================= + + N_det = 5242880 + N_states = 1 + + * State 1 + < S^2 > = 3.149127056743814E-003 + E = -193.559965204847 + Variance = 0.925877842874325 + PT norm = 0.148268624890572 + PT2 = -0.133172370395541 + rPT2 = -0.130307739119899 + E+PT2 = -193.693137575242 +/- 2.593344639331821E-004 + E+rPT2 = -193.690272943967 +/- 2.537559973636660E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.220013421382 + Vee = 219.456013275932 + Vecp = 0.000000000000000E+000 + T = 193.314019064439 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1335 -193.77243831 + -0.1429 -193.72728633 + -0.1692 -193.72353892 + -0.2179 -193.71219946 + -0.2741 -193.71283174 + -0.3356 -193.71363595 + -0.3945 -193.71546197 + =========== =================== + +* Number of unique beta determinants 1145771 +* Number of unique alpha determinants 1030335 + +.. >>>>> [ RES MEM : 31.870251 GB ] [ VIRT MEM : 37.677849 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 194091.795387 s ] [ CPU TIME: ************** s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 10485760 +* Number of threads for diagonalization 72 +* Memory(Gb) 18.52043993771076 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.5599652061 0.003149 0.941E-03 + 2 -193.5640702259 0.004147 0.113E-03 + 3 -193.5641947184 0.004290 0.187E-04 + 4 -193.5642316337 0.004476 0.491E-05 + 5 -193.5642434295 0.004594 0.684E-06 + 6 -193.5642455338 0.004603 0.136E-06 + 7 -193.5642459234 0.004596 0.134E-07 + 8 -193.5642459548 0.004592 0.117E-08 + 9 -193.5642459574 0.004591 0.679E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 42.420959 GB ] [ VIRT MEM : 50.575855 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 241881.870666 s ] [ CPU TIME: ************** s ] <<<<< .. + + +.. >>>>> [ RES MEM : 32.733547 GB ] [ VIRT MEM : 38.542637 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 241882.970569 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Energy of state 1 -193.5642459574383 +* S^2 of state 1 0.4591337980645282E-02 +* Saved determinants 10485760 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 30.853783 GB ] [ VIRT MEM : 35.334808 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 242093.446789 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 10485649 + +.. >>>>> [ RES MEM : 30.853783 GB ] [ VIRT MEM : 35.334808 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 242093.470596 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 10485649 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -193.5642459574383 + +.. >>>>> [ RES MEM : 32.651123 GB ] [ VIRT MEM : 37.132683 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 242102.725771 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 10485649 + +.. >>>>> [ RES MEM : 32.651123 GB ] [ VIRT MEM : 37.132683 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 242102.748713 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 10485649 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 15243363 +* Number of fragmented tasks 110528 +* Number of threads for PT2 72 +* Memory (Gb) 202.8368210503087 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.6950201049 0.418E-02 0.9223598579 0.0212466624 8573.7479 + 4 -193.6953746089 0.288E-02 0.9284105972 0.0211774024 9940.7580 + 5 -193.6948419095 0.225E-02 0.9177362346 0.0212479690 11132.8418 + 6 -193.6945406301 0.184E-02 0.9133742204 0.0212494195 12460.4418 + 7 -193.6941039083 0.161E-02 0.9079688472 0.0212232209 13781.9979 + 8 -193.6946077588 0.149E-02 0.9114063730 0.0213149694 15078.6928 + 9 -193.6948008898 0.133E-02 0.9150200626 0.0213144152 19834.1948 + 13 -193.6943403852 0.974E-03 0.9140361594 0.0211932862 20258.8398 + 14 -193.6944775411 0.911E-03 0.9159390631 0.0212081239 21646.3446 + 15 -193.6944278384 0.848E-03 0.9150909330 0.0212075172 22344.9033 + 16 -193.6946286837 0.818E-03 0.9165011165 0.0212467415 22490.6749 + 17 -193.6946770019 0.769E-03 0.9156431422 0.0212948093 23508.8982 + 18 -193.6947502142 0.728E-03 0.9186609129 0.0212841472 24499.6618 + 19 -193.6948040666 0.691E-03 0.9175973697 0.0213247663 25892.0980 + 20 -193.6946257598 0.679E-03 0.9164760596 0.0212902678 26859.7189 + 21 -193.6945325026 0.665E-03 0.9159714988 0.0212736893 27619.2708 + 22 -193.6946037660 0.638E-03 0.9169853453 0.0212700737 28401.3695 + 23 -193.6947123539 0.619E-03 0.9180662626 0.0212798248 32804.4568 + 28 -193.6949915897 0.531E-03 0.9209715933 0.0212846637 34283.9512 + 29 -193.6950414700 0.514E-03 0.9213268243 0.0212950638 35041.2959 + 30 -193.6951177260 0.503E-03 0.9212731414 0.0213185263 37411.2068 + 32 -193.6949792709 0.491E-03 0.9195841610 0.0213124785 39712.8680 + 34 -193.6950213419 0.469E-03 0.9200593648 0.0213156220 40460.8447 + 35 -193.6948866925 0.475E-03 0.9187045517 0.0213025627 40666.7846 + 36 -193.6948761597 0.462E-03 0.9179811952 0.0213084522 41585.3673 + 37 -193.6947919200 0.463E-03 0.9174555503 0.0212903217 42201.7883 + 38 -193.6947996610 0.451E-03 0.9173168691 0.0212919029 42725.5929 + 39 -193.6947607257 0.441E-03 0.9170348891 0.0212858019 46287.6058 + 42 -193.6947651417 0.420E-03 0.9173379431 0.0212772000 50073.7472 + 45 -193.6946763329 0.407E-03 0.9166812549 0.0212631880 52675.0261 + 50 -193.6945255068 0.414E-03 0.9149781998 0.0212550081 53177.2259 + 51 -193.6945280443 0.402E-03 0.9146031573 0.0212650351 54025.5869 + 52 -193.6945085272 0.395E-03 0.9143288842 0.0212675556 54454.9238 + 53 -193.6945174321 0.388E-03 0.9146248787 0.0212646513 55218.0019 + 54 -193.6945549626 0.382E-03 0.9148024802 0.0212715661 56047.6130 + 55 -193.6945819721 0.376E-03 0.9147394216 0.0212782301 56958.4788 + 56 -193.6945574282 0.370E-03 0.9149675900 0.0212643323 59543.0560 + 61 -193.6946368922 0.381E-03 0.9155707538 0.0212698459 59854.8177 + 62 -193.6947202016 0.384E-03 0.9160656526 0.0212858318 63768.3448 + 63 -193.6948044853 0.388E-03 0.9169751616 0.0212920998 65294.4379 + 71 -193.6947872312 0.359E-03 0.9166970974 0.0212961801 65943.4639 + 72 -193.6947006487 0.365E-03 0.9160597283 0.0212825134 66360.8849 + 73 -193.6947123967 0.360E-03 0.9160377075 0.0212852783 66878.6949 + 74 -193.6946348394 0.364E-03 0.9155728783 0.0212728995 67732.5748 + 75 -193.6946531877 0.359E-03 0.9155865218 0.0212785008 68373.9790 + 76 -193.6946604203 0.354E-03 0.9159857989 0.0212727094 71109.6150 + 78 -193.6946790006 0.350E-03 0.9161090795 0.0212773184 73955.7264 + 84 -193.6947072195 0.329E-03 0.9166130761 0.0212717733 76067.5498 + 86 -193.6947430529 0.324E-03 0.9169551387 0.0212745221 76612.7070 + 87 -193.6947455080 0.320E-03 0.9169097624 0.0212768420 77321.0709 + 89 -193.6946982638 0.315E-03 0.9163962932 0.0212709474 78061.6138 + 90 -193.6946659375 0.313E-03 0.9160981481 0.0212682981 78610.8310 + 91 -193.6946632901 0.310E-03 0.9160750639 0.0212694100 79276.4774 + 92 -193.6946790234 0.306E-03 0.9161503915 0.0212753021 79993.1310 + 93 -193.6946486544 0.305E-03 0.9159482586 0.0212715723 80753.8303 + 94 -193.6945847193 0.308E-03 0.9153567289 0.0212625716 80923.3119 + 95 -193.6946518046 0.312E-03 0.9159848924 0.0212709308 82317.5198 + 97 -193.6946650979 0.306E-03 0.9163468127 0.0212674271 83549.0729 + 98 -193.6946663050 0.303E-03 0.9165988590 0.0212634749 87365.0308 + 106 -193.6947164702 0.292E-03 0.9169007521 0.0212737030 87528.4965 + 107 -193.6946797821 0.292E-03 0.9167419420 0.0212662588 88408.4309 + 109 -193.6947340770 0.289E-03 0.9171698725 0.0212716850 88959.5850 + 110 -193.6947673244 0.288E-03 0.9173891929 0.0212785604 89560.3880 + 111 -193.6947899512 0.287E-03 0.9176463881 0.0212800558 94451.2458 + 120 -193.6947673507 0.271E-03 0.9170805749 0.0212834906 95049.7571 + 121 -193.6947897592 0.269E-03 0.9172203321 0.0212865509 95286.3280 + 122 -193.6947485456 0.270E-03 0.9169982738 0.0212790283 96217.2210 + 123 -193.6948007351 0.273E-03 0.9174500012 0.0212853410 96983.6789 + 124 -193.6948129328 0.271E-03 0.9174864022 0.0212871719 97602.6314 + 125 -193.6947767316 0.271E-03 0.9171550804 0.0212831022 ********** + 131 -193.6947028430 0.266E-03 0.9166772185 0.0212729617 ********** + 132 -193.6947245903 0.265E-03 0.9167744493 0.0212770747 ********** + 133 -193.6947513946 0.264E-03 0.9169524667 0.0212812686 ********** + 135 -193.6947668480 0.262E-03 0.9170320161 0.0212837044 ********** + 142 -193.6948824316 0.252E-03 0.9176786081 0.0213034139 ********** + 143 -193.6948545188 0.252E-03 0.9175466166 0.0212980768 ********** + 149 -193.6947870851 0.247E-03 0.9171367916 0.0212862240 ********** +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 34.329124 GB ] [ VIRT MEM : 38.487381 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 355748.535850 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 10485649 + +.. >>>>> [ RES MEM : 34.329124 GB ] [ VIRT MEM : 38.487381 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 355748.559679 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 10485649 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +Summary at N_det = 10485760 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.56424596 +# PT2 -0.13053540 0.00024571 +# rPT2 -0.12781466 0.00024058 +# +# E+PT2 -193.69478135 0.00024571 +# E+rPT2 -193.69206062 0.00024058 +# ============ ============================= + + N_det = 10485760 + N_states = 1 + + * State 1 + < S^2 > = 4.591337980645282E-003 + E = -193.564245957438 + Variance = 0.917075120331964 + PT norm = 0.145899217604953 + PT2 = -0.130535397335213 + rPT2 = -0.127814660130184 + E+PT2 = -193.694781354774 +/- 2.457061936847233E-004 + E+rPT2 = -193.692060617568 +/- 2.405849622309471E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.235151060093 + Vee = 219.456199142016 + Vecp = 0.000000000000000E+000 + T = 193.324690084474 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1303 -193.78371070 + -0.1335 -193.77718626 + -0.1429 -193.73688459 + -0.1692 -193.72665299 + -0.2179 -193.71446909 + -0.2741 -193.71428188 + -0.3356 -193.71467909 + =========== =================== + +Wall time: 98:51:26 + diff --git a/cyclopentadiene/cc-pvtz/cyclopentadiene.natorb.out b/cyclopentadiene/cc-pvtz/cyclopentadiene.natorb.out new file mode 100644 index 0000000..c08f701 --- /dev/null +++ b/cyclopentadiene/cc-pvtz/cyclopentadiene.natorb.out @@ -0,0 +1,406 @@ +Date: 31/10/2020 14:06:33 +=============== +Quantum Package +=============== + +Git Commit: Fix space in size for EZFIO.cfg +Git Date : Fri Oct 16 14:24:01 2020 +0200 +Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b +EZFIO Dir : cyclopentadiene + + +Task server running : tcp://172.28.0.243:41279 +.. >>>>> [ IO READ: n_states ] <<<<< .. + +.. >>>>> [ RES MEM : 0.009022 GB ] [ VIRT MEM : 0.137962 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.029031 s ] [ CPU TIME: 0.021459 s ] <<<<< .. + +.. >>>>> [ IO READ: read_wf ] <<<<< .. + +.. >>>>> [ RES MEM : 0.009197 GB ] [ VIRT MEM : 0.137962 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.030835 s ] [ CPU TIME: 0.022082 s ] <<<<< .. + +.. >>>>> [ IO READ: elec_beta_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.009197 GB ] [ VIRT MEM : 0.137962 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.048050 s ] [ CPU TIME: 0.022998 s ] <<<<< .. + +.. >>>>> [ IO READ: elec_alpha_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.009197 GB ] [ VIRT MEM : 0.137962 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.048618 s ] [ CPU TIME: 0.023406 s ] <<<<< .. + +* mo_num 234 + Read mo_occ +.. >>>>> [ IO READ: mo_class ] <<<<< .. + +.. >>>>> [ RES MEM : 0.011059 GB ] [ VIRT MEM : 4.857159 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.116423 s ] [ CPU TIME: 1.467286 s ] <<<<< .. + +* Number of virtual MOs 0 + Virtual MOs: + +.. >>>>> [ IO READ: ao_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.011059 GB ] [ VIRT MEM : 4.857159 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.140642 s ] [ CPU TIME: 2.960737 s ] <<<<< .. + + Read mo_coef + * mo_label Canonical +* Number of determinants 10485760 +* Dimension of the psi arrays 10485760 +* N_int 4 + Read psi_det +* Number of unique beta determinants 1145771 +* Number of unique alpha determinants 1030335 + Read psi_coef 10485760 1 +.. >>>>> [ IO READ: weight_one_e_dm ] <<<<< .. + +.. >>>>> [ RES MEM : 3.835121 GB ] [ VIRT MEM : 8.766762 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 313.740459 s ] [ CPU TIME: 11795.810909 s ] <<<<< .. + +* Number of active MOs 229 +* Number of core MOs 5 +* Number of inactive MOs 0 + Core MOs: + 1 2 3 4 5 + Active MOs: + 6 7 8 9 10 11 + 12 13 14 15 16 17 + 18 19 20 21 22 23 + 24 25 26 27 28 29 + 30 31 32 33 34 35 + 36 37 38 39 40 41 + 42 43 44 45 46 47 + 48 49 50 51 52 53 + 54 55 56 57 58 59 + 60 61 62 63 64 65 + 66 67 68 69 70 71 + 72 73 74 75 76 77 + 78 79 80 81 82 83 + 84 85 86 87 88 89 + 90 91 92 93 94 95 + 96 97 98 99 100 101 + 102 103 104 105 106 107 + 108 109 110 111 112 113 + 114 115 116 117 118 119 + 120 121 122 123 124 125 + 126 127 128 129 130 131 + 132 133 134 135 136 137 + 138 139 140 141 142 143 + 144 145 146 147 148 149 + 150 151 152 153 154 155 + 156 157 158 159 160 161 + 162 163 164 165 166 167 + 168 169 170 171 172 173 + 174 175 176 177 178 179 + 180 181 182 183 184 185 + 186 187 188 189 190 191 + 192 193 194 195 196 197 + 198 199 200 201 202 203 + 204 205 206 207 208 209 + 210 211 212 213 214 215 + 216 217 218 219 220 221 + 222 223 224 225 226 227 + 228 229 230 231 232 233 + 234 + Core, Inactive and Active MOs: + 1 2 3 4 5 6 + 7 8 9 10 11 12 + 13 14 15 16 17 18 + 19 20 21 22 23 24 + 25 26 27 28 29 30 + 31 32 33 34 35 36 + 37 38 39 40 41 42 + 43 44 45 46 47 48 + 49 50 51 52 53 54 + 55 56 57 58 59 60 + 61 62 63 64 65 66 + 67 68 69 70 71 72 + 73 74 75 76 77 78 + 79 80 81 82 83 84 + 85 86 87 88 89 90 + 91 92 93 94 95 96 + 97 98 99 100 101 102 + 103 104 105 106 107 108 + 109 110 111 112 113 114 + 115 116 117 118 119 120 + 121 122 123 124 125 126 + 127 128 129 130 131 132 + 133 134 135 136 137 138 + 139 140 141 142 143 144 + 145 146 147 148 149 150 + 151 152 153 154 155 156 + 157 158 159 160 161 162 + 163 164 165 166 167 168 + 169 170 171 172 173 174 + 175 176 177 178 179 180 + 181 182 183 184 185 186 + 187 188 189 190 191 192 + 193 194 195 196 197 198 + 199 200 201 202 203 204 + 205 206 207 208 209 210 + 211 212 213 214 215 216 + 217 218 219 220 221 222 + 223 224 225 226 227 228 + 229 230 231 232 233 234 + +.. >>>>> [ RES MEM : 3.835522 GB ] [ VIRT MEM : 8.766762 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 313.746357 s ] [ CPU TIME: 11796.232005 s ] <<<<< .. + +MOs are now **Natural** + +Eigenvalues +----------- + +======== ================ ================ + MO Eigenvalue Cumulative +======== ================ ================ + 1 2.0000000000 2.0000000000 + 2 2.0000000000 4.0000000000 + 3 2.0000000000 6.0000000000 + 4 2.0000000000 8.0000000000 + 5 2.0000000000 10.0000000000 + 6 1.9860811655 11.9860811655 + 7 1.9833488309 13.9694299964 + 8 1.9832322671 15.9526622634 + 9 1.9792266661 17.9318889296 + 10 1.9787904673 19.9106793968 + 11 1.9774470997 21.8881264965 + 12 1.9751599999 23.8632864964 + 13 1.9740507354 25.8373372318 + 14 1.9717762724 27.8091135042 + 15 1.9706615639 29.7797750682 + 16 1.9697125348 31.7494876030 + 17 1.9569603051 33.7064479081 + 18 1.9366820929 35.6431300010 + 19 0.0504693262 35.6935993272 + 20 0.0294829838 35.7230823110 + 21 0.0166759443 35.7397582553 + 22 0.0157901085 35.7555483638 + 23 0.0135461739 35.7690945378 + 24 0.0135172648 35.7826118026 + 25 0.0124739873 35.7950857899 + 26 0.0120146143 35.8071004043 + 27 0.0115189348 35.8186193391 + 28 0.0109990426 35.8296183817 + 29 0.0103128037 35.8399311854 + 30 0.0097690608 35.8497002462 + 31 0.0093525549 35.8590528011 + 32 0.0070344642 35.8660872653 + 33 0.0063989799 35.8724862452 + 34 0.0062824301 35.8787686753 + 35 0.0060944558 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35.9998784526 + 218 0.0000113677 35.9998898203 + 219 0.0000112186 35.9999010389 + 220 0.0000102751 35.9999113140 + 221 0.0000094900 35.9999208040 + 222 0.0000094194 35.9999302234 + 223 0.0000092451 35.9999394686 + 224 0.0000085130 35.9999479815 + 225 0.0000079034 35.9999558850 + 226 0.0000079032 35.9999637881 + 227 0.0000069283 35.9999707165 + 228 0.0000066340 35.9999773504 + 229 0.0000054294 35.9999827798 + 230 0.0000041810 35.9999869608 + 231 0.0000037895 35.9999907503 + 232 0.0000033272 35.9999940775 + 233 0.0000029867 35.9999970641 + 234 0.0000029359 36.0000000000 +======== ================ ================ + + +.. >>>>> [ RES MEM : 3.844185 GB ] [ VIRT MEM : 8.876984 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 313.788967 s ] [ CPU TIME: 11799.249142 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_md5 ] <<<<< .. + +.. >>>>> [ RES MEM : 3.844185 GB ] [ VIRT MEM : 8.876984 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 313.790020 s ] [ CPU TIME: 11799.323469 s ] <<<<< .. + +* Saved determinants 1 +Wall time: 0:05:19 + diff --git a/cyclopentadiene/cc-pvtz/cyclopentadiene.nofci.out b/cyclopentadiene/cc-pvtz/cyclopentadiene.nofci.out new file mode 100644 index 0000000..4a1ecb6 --- /dev/null +++ b/cyclopentadiene/cc-pvtz/cyclopentadiene.nofci.out @@ -0,0 +1,4160 @@ +Date: 31/10/2020 14:11:53 +=============== +Quantum Package +=============== + +Git Commit: Fix space in size for EZFIO.cfg +Git Date : Fri Oct 16 14:24:01 2020 +0200 +Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b +EZFIO Dir : cyclopentadiene + + +Task server running : tcp://172.28.0.243:41279 +* mo_num 234 +.. >>>>> [ IO READ: mo_class ] <<<<< .. + +.. >>>>> [ RES MEM : 0.010864 GB ] [ VIRT MEM : 4.857994 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.001161 s ] [ CPU TIME: 0.170757 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_two_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.010864 GB ] [ VIRT MEM : 4.857994 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.006827 s ] [ CPU TIME: 0.518295 s ] <<<<< .. + +* N_int 4 + MO map initialized: 378001260 +.. >>>>> [ IO READ: io_ao_two_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.013817 GB ] [ VIRT MEM : 4.871525 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.024950 s ] [ CPU TIME: 1.707551 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.013817 GB ] [ VIRT MEM : 4.871525 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.027274 s ] [ CPU TIME: 1.863392 s ] <<<<< .. + + AO map initialized : 621122635 +.. >>>>> [ IO READ: ao_power ] <<<<< .. + +.. >>>>> [ RES MEM : 0.018406 GB ] [ VIRT MEM : 4.874496 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.063949 s ] [ CPU TIME: 4.285282 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_prim_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.018456 GB ] [ VIRT MEM : 4.874496 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.068310 s ] [ CPU TIME: 4.570046 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_expo ] <<<<< .. + +.. >>>>> [ RES MEM : 0.018494 GB ] [ VIRT MEM : 4.874496 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.076582 s ] [ CPU TIME: 5.002638 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_coef ] <<<<< .. + +.. >>>>> [ RES MEM : 0.018593 GB ] [ VIRT MEM : 4.874496 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.083518 s ] [ CPU TIME: 5.355777 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_nucl ] <<<<< .. + +.. >>>>> [ RES MEM : 0.018829 GB ] [ VIRT MEM : 4.874496 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.088741 s ] [ CPU TIME: 5.705082 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_integrals_threshold ] <<<<< .. + +.. >>>>> [ RES MEM : 0.018829 GB ] [ VIRT MEM : 4.874496 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.089966 s ] [ CPU TIME: 5.791745 s ] <<<<< .. + + Providing the AO integrals +.. >>>>> [ IO READ: nucl_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.020309 GB ] [ VIRT MEM : 5.092533 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.233714 s ] [ CPU TIME: 15.027727 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_label ] <<<<< .. + +.. >>>>> [ RES MEM : 0.020466 GB ] [ VIRT MEM : 5.092533 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.246838 s ] [ CPU TIME: 15.906062 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_charge ] <<<<< .. + +.. >>>>> [ RES MEM : 0.020496 GB ] [ VIRT MEM : 5.092533 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.250292 s ] [ CPU TIME: 16.137977 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.020508 GB ] [ VIRT MEM : 5.092533 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.269861 s ] [ CPU TIME: 17.465458 s ] <<<<< .. + + +Nuclear Coordinates (Angstroms) +=============================== + +================ ============ ============ ============ ============ + Atom Charge X Y Z +================ ============ ============ ============ ============ +C 6.000000 0.000000 0.000000 -1.233581 +C 6.000000 0.000000 1.175880 -0.300949 +C 6.000000 0.000000 -1.175880 -0.300949 +C 6.000000 0.000000 0.732987 0.972484 +C 6.000000 0.000000 -0.732987 0.972484 +H 1.000000 0.879125 0.000000 -1.886063 +H 1.000000 -0.879125 0.000000 -1.886063 +H 1.000000 0.000000 2.204290 -0.625046 +H 1.000000 0.000000 -2.204290 -0.625046 +H 1.000000 0.000000 1.346833 1.859276 +H 1.000000 0.000000 -1.346833 1.859276 +================ ============ ============ ============ ============ + + Sorting the map + AO integrals provided: + Size of AO map : 4881.58933830261 MB + Number of AO integrals : 409206539 + cpu time : 4033.70612100000 s + wall time : 66.0087788105011 s ( x 61.1086312107064 ) + + AO -> MO integrals transformation + --------------------------------- + + Read mo_coef +.. >>>>> [ IO READ: mo_integrals_threshold ] <<<<< .. + +.. >>>>> [ RES MEM : 4.150719 GB ] [ VIRT MEM : 10.143108 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 66.246699 s ] [ CPU TIME: 4041.698034 s ] <<<<< .. + + Buffers : 464.9230 MB / core + 6.415094 % in 40.3412711620331 s 6798.69118881226 MB + 36.98113 % in 106.058315038681 s 7169.12696075439 MB + 70.18868 % in 152.023572206497 s 7172.29220581055 MB + 90.18868 % in 178.447679996490 s 7132.35373687744 MB + Molecular integrals provided: + Size of MO map 7121.92868423462 MB + Number of MO integrals: 369603874 + cpu time : 13517.6901250000 s + wall time : 209.733070850372 s ( x 64.4518771893813 ) +.. >>>>> [ IO READ: n_states ] <<<<< .. + +.. >>>>> [ RES MEM : 14.365543 GB ] [ VIRT MEM : 20.453335 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 275.847899 s ] [ CPU TIME: 17558.202552 s ] <<<<< .. + + * mo_label Natural +.. >>>>> [ IO READ: read_wf ] <<<<< .. + +.. >>>>> [ RES MEM : 14.365543 GB ] [ VIRT MEM : 20.453335 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 275.849528 s ] [ CPU TIME: 17558.308702 s ] <<<<< .. + +* Number of determinants 1 +* Dimension of the psi arrays 100000 + Read psi_coef 1 1 +.. >>>>> [ IO READ: elec_beta_num ] <<<<< .. + +.. >>>>> [ RES MEM : 14.366505 GB ] [ VIRT MEM : 20.453335 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 275.874341 s ] [ CPU TIME: 17559.919130 s ] <<<<< .. + +.. >>>>> [ IO READ: elec_alpha_num ] <<<<< .. + +.. >>>>> [ RES MEM : 14.366505 GB ] [ VIRT MEM : 20.453335 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 275.875132 s ] [ CPU TIME: 17559.971101 s ] <<<<< .. + + Read psi_det +.. >>>>> [ IO READ: do_pt2 ] <<<<< .. + +.. >>>>> [ RES MEM : 14.372501 GB ] [ VIRT MEM : 20.459305 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 275.901743 s ] [ CPU TIME: 17561.703252 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 14.372574 GB ] [ VIRT MEM : 20.459305 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 275.964317 s ] [ CPU TIME: 17565.746347 s ] <<<<< .. + +.. >>>>> [ IO READ: selection_factor ] <<<<< .. + +.. >>>>> [ RES MEM : 14.372574 GB ] [ VIRT MEM : 20.459305 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 275.965117 s ] [ CPU TIME: 17565.798949 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_max ] <<<<< .. + +.. >>>>> [ RES MEM : 14.372814 GB ] [ VIRT MEM : 20.465275 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 275.966610 s ] [ CPU TIME: 17565.890693 s ] <<<<< .. + +.. >>>>> [ IO READ: s2_eig ] <<<<< .. + +.. >>>>> [ RES MEM : 14.412376 GB ] [ VIRT MEM : 20.520016 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 275.972503 s ] [ CPU TIME: 17566.265464 s ] <<<<< .. + +.. >>>>> [ IO READ: variance_max ] <<<<< .. + +.. >>>>> [ RES MEM : 14.412376 GB ] [ VIRT MEM : 20.520016 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 275.973316 s ] [ CPU TIME: 17566.319548 s ] <<<<< .. + +.. >>>>> [ IO READ: distributed_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 14.412376 GB ] [ VIRT MEM : 20.520016 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 275.996831 s ] [ CPU TIME: 17567.868282 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_max_full ] <<<<< .. + +.. >>>>> [ RES MEM : 14.412376 GB ] [ VIRT MEM : 20.520016 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 275.997616 s ] [ CPU TIME: 17567.920761 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_integrals_e_n ] <<<<< .. + +.. >>>>> [ RES MEM : 16.476974 GB ] [ VIRT MEM : 22.586430 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 285.929697 s ] [ CPU TIME: 17655.069179 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_integrals_e_n ] <<<<< .. + +.. >>>>> [ RES MEM : 16.476974 GB ] [ VIRT MEM : 22.586430 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 285.945180 s ] [ CPU TIME: 17655.070120 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_integrals_kinetic ] <<<<< .. + +.. >>>>> [ RES MEM : 16.481331 GB ] [ VIRT MEM : 22.652649 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 285.975752 s ] [ CPU TIME: 17657.021229 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_integrals_kinetic ] <<<<< .. + +.. >>>>> [ RES MEM : 16.481331 GB ] [ VIRT MEM : 22.652649 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 285.976642 s ] [ CPU TIME: 17657.082684 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_one_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 16.483974 GB ] [ VIRT MEM : 22.652649 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 285.997706 s ] [ CPU TIME: 17658.094819 s ] <<<<< .. + + Providing the one-electron integrals +.. >>>>> [ IO READ: do_pseudo ] <<<<< .. + +.. >>>>> [ RES MEM : 16.483974 GB ] [ VIRT MEM : 22.652649 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 286.013343 s ] [ CPU TIME: 17659.187424 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_relative_error ] <<<<< .. + +.. >>>>> [ RES MEM : 16.483974 GB ] [ VIRT MEM : 22.652649 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 286.084008 s ] [ CPU TIME: 17664.181491 s ] <<<<< .. + +.. >>>>> [ IO READ: correlation_energy_ratio_max ] <<<<< .. + +.. >>>>> [ RES MEM : 16.483974 GB ] [ VIRT MEM : 22.652649 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 286.084862 s ] [ CPU TIME: 17664.242002 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 16.483974 GB ] [ VIRT MEM : 22.652649 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 286.086133 s ] [ CPU TIME: 17664.331107 s ] <<<<< .. + + Read n_states_diag +.. >>>>> [ IO READ: io_nuclear_repulsion ] <<<<< .. + +.. >>>>> [ RES MEM : 16.483974 GB ] [ VIRT MEM : 22.652649 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 286.086972 s ] [ CPU TIME: 17664.390233 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 16.483974 GB ] [ VIRT MEM : 22.652649 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 286.087316 s ] [ CPU TIME: 17664.414826 s ] <<<<< .. + +* Nuclear repulsion energy 156.8900158761648 +.. >>>>> [ IO READ: weight_one_e_dm ] <<<<< .. + +.. >>>>> [ RES MEM : 16.483974 GB ] [ VIRT MEM : 22.652649 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 286.088529 s ] [ CPU TIME: 17664.499655 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_max ] <<<<< .. + +.. >>>>> [ RES MEM : 16.492142 GB ] [ VIRT MEM : 22.658619 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 286.112919 s ] [ CPU TIME: 17666.211259 s ] <<<<< .. + +.. >>>>> [ IO READ: threshold_generators ] <<<<< .. + +.. >>>>> [ RES MEM : 16.492142 GB ] [ VIRT MEM : 22.658619 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 286.113706 s ] [ CPU TIME: 17666.267035 s ] <<<<< .. + +* Target maximum memory (GB) 2000 +.. >>>>> [ IO READ: threshold_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 16.492142 GB ] [ VIRT MEM : 22.658619 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 286.114700 s ] [ CPU TIME: 17666.336837 s ] <<<<< .. + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 16.493183 GB ] [ VIRT MEM : 22.658619 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 286.125669 s ] [ CPU TIME: 17667.099453 s ] <<<<< .. + +* Energy of state 1 -192.8560306113623 +* S^2 of state 1 0.000000000000000 +* Saved determinants 1 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 1 +* Number of unique alpha determinants 1 +.. >>>>> [ IO READ: weight_selection ] <<<<< .. + +.. >>>>> [ RES MEM : 16.493862 GB ] [ VIRT MEM : 22.670925 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 286.250964 s ] [ CPU TIME: 17675.844981 s ] <<<<< .. + + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +.. >>>>> [ IO READ: pseudo_sym ] <<<<< .. + +.. >>>>> [ RES MEM : 16.493862 GB ] [ VIRT MEM : 22.670925 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 286.251847 s ] [ CPU TIME: 17675.906729 s ] <<<<< .. + +.. >>>>> [ IO READ: h0_type ] <<<<< .. + +.. >>>>> [ RES MEM : 16.494461 GB ] [ VIRT MEM : 22.676895 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 286.254301 s ] [ CPU TIME: 17676.072191 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 16.494461 GB ] [ VIRT MEM : 22.676895 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 286.254768 s ] [ CPU TIME: 17676.104416 s ] <<<<< .. + +* Number of generators 1 + +.. >>>>> [ RES MEM : 16.494461 GB ] [ VIRT MEM : 22.676895 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 286.255146 s ] [ CPU TIME: 17676.131583 s ] <<<<< .. + +* Number of selectors 1 +* Number of comb teeth 1 +* Number of core MOs 5 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -192.8560306113623 +* Estimated memory/thread (Gb) 0.2384185791015625E-06 +* Number of virtual MOs 0 +* Number of active MOs 229 + Active MOs: + 6 7 8 9 10 11 + 12 13 14 15 16 17 + 18 19 20 21 22 23 + 24 25 26 27 28 29 + 30 31 32 33 34 35 + 36 37 38 39 40 41 + 42 43 44 45 46 47 + 48 49 50 51 52 53 + 54 55 56 57 58 59 + 60 61 62 63 64 65 + 66 67 68 69 70 71 + 72 73 74 75 76 77 + 78 79 80 81 82 83 + 84 85 86 87 88 89 + 90 91 92 93 94 95 + 96 97 98 99 100 101 + 102 103 104 105 106 107 + 108 109 110 111 112 113 + 114 115 116 117 118 119 + 120 121 122 123 124 125 + 126 127 128 129 130 131 + 132 133 134 135 136 137 + 138 139 140 141 142 143 + 144 145 146 147 148 149 + 150 151 152 153 154 155 + 156 157 158 159 160 161 + 162 163 164 165 166 167 + 168 169 170 171 172 173 + 174 175 176 177 178 179 + 180 181 182 183 184 185 + 186 187 188 189 190 191 + 192 193 194 195 196 197 + 198 199 200 201 202 203 + 204 205 206 207 208 209 + 210 211 212 213 214 215 + 216 217 218 219 220 221 + 222 223 224 225 226 227 + 228 229 230 231 232 233 + 234 +* Number of inactive MOs 0 +.. >>>>> [ IO READ: pert_2rdm ] <<<<< .. + +.. >>>>> [ RES MEM : 16.496708 GB ] [ VIRT MEM : 22.693340 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 286.303065 s ] [ CPU TIME: 17678.858474 s ] <<<<< .. + +.. >>>>> [ IO READ: pruning ] <<<<< .. + +.. >>>>> [ RES MEM : 16.496807 GB ] [ VIRT MEM : 22.693340 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 299.904349 s ] [ CPU TIME: 17704.825100 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 16.497589 GB ] [ VIRT MEM : 22.693340 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 299.912200 s ] [ CPU TIME: 17705.367870 s ] <<<<< .. + +* Number of generators 1 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Saved determinants 5 +* Number of unique beta determinants 4 +* Number of unique alpha determinants 4 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.497692 GB ] [ VIRT MEM : 22.693348 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 299.969425 s ] [ CPU TIME: 17709.361016 s ] <<<<< .. + +* Number of selectors 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio -0.2545646578486976E-02 + +Summary at N_det = 5 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -192.85603061 +# PT2 -1.08042387 0.00000000 +# rPT2 -0.72155464 0.00000000 +# +# E+PT2 -193.93645448 0.00000000 +# E+rPT2 -193.57758525 0.00000000 +# ============ ============================= + + N_det = 5 + N_states = 1 + + * State 1 + < S^2 > = 0.000000000000000E+000 + E = -192.856030611362 + Variance = 3.17975430946335 + PT norm = 0.705234417959411 + PT2 = -1.08042387289359 + rPT2 = -0.721554642224170 + E+PT2 = -193.936454484256 +/- 0.000000000000000E+000 + E+rPT2 = -193.577585253586 +/- 0.000000000000000E+000 + + ----- +.. >>>>> [ IO READ: io_mo_integrals_pseudo ] <<<<< .. + +.. >>>>> [ RES MEM : 16.497692 GB ] [ VIRT MEM : 22.693348 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 299.971879 s ] [ CPU TIME: 17709.534523 s ] <<<<< .. + + Energy components + ================= + + Vnn : Nucleus-Nucleus potential energy + Ven : Electron-Nucleus potential energy + Vee : Electron-Electron potential energy + Vecp : Potential energy of the pseudo-potentials + T : Electronic kinetic energy + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.140975391204 + Vee = 220.519393805189 + Vecp = 0.000000000000000E+000 + T = 192.875535098489 + + +.. >>>>> [ IO READ: energy_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 16.500526 GB ] [ VIRT MEM : 22.693348 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 300.040465 s ] [ CPU TIME: 17714.329748 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 16.500526 GB ] [ VIRT MEM : 22.693348 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 300.043878 s ] [ CPU TIME: 17714.556055 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 16.500526 GB ] [ VIRT MEM : 22.693348 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 300.055474 s ] [ CPU TIME: 17715.338913 s ] <<<<< .. + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 16.500946 GB ] [ VIRT MEM : 22.693348 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 300.098076 s ] [ CPU TIME: 17718.274217 s ] <<<<< .. + +* Energy of state 1 -192.8852071744452 +* S^2 of state 1 0.2589634195451527E-01 +* Saved determinants 5 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 4 +* Number of unique alpha determinants 4 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.501114 GB ] [ VIRT MEM : 22.693348 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 300.205399 s ] [ CPU TIME: 17725.771260 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 16.501114 GB ] [ VIRT MEM : 22.693348 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 300.205778 s ] [ CPU TIME: 17725.797917 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -192.8852071744452 + +.. >>>>> [ RES MEM : 16.507656 GB ] [ VIRT MEM : 22.703228 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 300.215509 s ] [ CPU TIME: 17726.486900 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 16.507656 GB ] [ VIRT MEM : 22.703228 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 300.215891 s ] [ CPU TIME: 17726.513999 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 5 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2950760852545500E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.8249969716 0.879E-01 3.1322028979 0.3562644248 6.2285 + 4 -193.8951242520 0.00 3.1256540809 0.4152774972 6.2286 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.513268 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 306.473486 s ] [ CPU TIME: 17771.661139 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 16.513268 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 306.473832 s ] [ CPU TIME: 17771.685357 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.3690567649459342E-01 + +Summary at N_det = 5 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -192.88520717 +# PT2 -1.00991708 0.00000000 +# rPT2 -0.71358237 0.00000000 +# +# E+PT2 -193.89512425 0.00000000 +# E+rPT2 -193.59878955 0.00000000 +# ============ ============================= + + N_det = 5 + N_states = 1 + + * State 1 + < S^2 > = 2.589634195451527E-002 + E = -192.885207174445 + Variance = 3.12565408090697 + PT norm = 0.644420279972478 + PT2 = -1.00991707753340 + rPT2 = -0.713582374836754 + E+PT2 = -193.895124251979 +/- 0.000000000000000E+000 + E+rPT2 = -193.598789549282 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.217811796914 + Vee = 220.509595255709 + Vecp = 0.000000000000000E+000 + T = 192.932993490595 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7216 -195.49674542 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 16.513466 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 306.537870 s ] [ CPU TIME: 17776.025529 s ] <<<<< .. + +* Energy of state 1 -192.9085274899933 +* S^2 of state 1 0.9424155199863117E-02 +* Saved determinants 10 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 6 +* Number of unique alpha determinants 6 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.513638 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 306.603972 s ] [ CPU TIME: 17780.505463 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 16.513638 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 306.604295 s ] [ CPU TIME: 17780.528426 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -192.9085274899933 + +.. >>>>> [ RES MEM : 16.513638 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 306.608740 s ] [ CPU TIME: 17780.832894 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 16.513638 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 306.609074 s ] [ CPU TIME: 17780.856618 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 10 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2960497401654720E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7666486596 0.125 3.0998059542 0.2979817125 7.0189 + 9 -193.8647039609 0.00 3.0712882458 0.3665800345 7.0191 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.513676 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 313.644061 s ] [ CPU TIME: 17861.771127 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 16.513676 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 313.644434 s ] [ CPU TIME: 17861.796134 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.6752141408426648E-01 + +Summary at N_det = 10 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -192.90852749 +# PT2 -0.95617647 0.00000000 +# rPT2 -0.69968567 0.00000000 +# +# E+PT2 -193.86470396 0.00000000 +# E+rPT2 -193.60821316 0.00000000 +# ============ ============================= + + N_det = 10 + N_states = 1 + + * State 1 + < S^2 > = 9.424155199863117E-003 + E = -192.908527489993 + Variance = 3.07128824580758 + PT norm = 0.605458532434653 + PT2 = -0.956176470951355 + rPT2 = -0.699685672857536 + E+PT2 = -193.864703960945 +/- 0.000000000000000E+000 + E+rPT2 = -193.608213162851 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.277116341864 + Vee = 220.498217818221 + Vecp = 0.000000000000000E+000 + T = 192.980355157484 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7136 -194.08268311 + -0.7216 -194.53389452 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 16.513714 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 313.732905 s ] [ CPU TIME: 17867.540414 s ] <<<<< .. + +* Energy of state 1 -192.9210759882857 +* S^2 of state 1 0.9724949231556611E-02 +* Saved determinants 20 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 13 +* Number of unique alpha determinants 13 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.513813 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 313.786633 s ] [ CPU TIME: 17871.012983 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 16.513813 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 313.786966 s ] [ CPU TIME: 17871.035169 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -192.9210759882857 + +.. >>>>> [ RES MEM : 16.513813 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 313.792132 s ] [ CPU TIME: 17871.374840 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 16.513813 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 313.792493 s ] [ CPU TIME: 17871.399025 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 20 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2979970499873161E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7640357543 0.115 3.1382719654 0.2844817676 7.2591 + 19 -193.8523194820 0.00 3.0404727061 0.3484858709 7.2594 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.513813 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 321.096472 s ] [ CPU TIME: 18022.079061 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 16.513813 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 321.096858 s ] [ CPU TIME: 18022.105303 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8385965235250346E-01 + +Summary at N_det = 20 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -192.92107599 +# PT2 -0.93124349 0.00000000 +# rPT2 -0.69058454 0.00000000 +# +# E+PT2 -193.85231948 0.00000000 +# E+rPT2 -193.61166053 0.00000000 +# ============ ============================= + + N_det = 20 + N_states = 1 + + * State 1 + < S^2 > = 9.724949231556611E-003 + E = -192.921075988286 + Variance = 3.04047270613754 + PT norm = 0.590326918662363 + PT2 = -0.931243493717506 + rPT2 = -0.690584539160040 + E+PT2 = -193.852319482003 +/- 0.000000000000000E+000 + E+rPT2 = -193.611660527446 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.294646359398 + Vee = 220.485348059464 + Vecp = 0.000000000000000E+000 + T = 192.998206435484 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6997 -193.87324296 + -0.7136 -194.00558063 + -0.7216 -194.31971770 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 16.514229 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 321.153951 s ] [ CPU TIME: 18025.916700 s ] <<<<< .. + +* Energy of state 1 -192.9348629822616 +* S^2 of state 1 0.1204388200142237E-01 +* Saved determinants 40 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 19 +* Number of unique alpha determinants 19 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.514305 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 321.238227 s ] [ CPU TIME: 18031.523113 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 16.514305 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 321.238554 s ] [ CPU TIME: 18031.545916 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -192.9348629822616 + +.. >>>>> [ RES MEM : 16.514305 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 321.243125 s ] [ CPU TIME: 18031.855312 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 16.514305 GB ] [ VIRT MEM : 22.708477 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 321.243449 s ] [ CPU TIME: 18031.877493 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 40 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.3018916696310043E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7502911970 0.115 3.0475974169 0.2708163231 8.9565 + 39 -193.8405591650 0.00 3.0057773014 0.3308526023 8.9571 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.514828 GB ] [ VIRT MEM : 22.708622 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 330.222159 s ] [ CPU TIME: 18359.777541 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 16.514828 GB ] [ VIRT MEM : 22.708622 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 330.222515 s ] [ CPU TIME: 18359.799694 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1016452754052232 + +Summary at N_det = 40 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -192.93486298 +# PT2 -0.90569618 0.00000000 +# rPT2 -0.68053831 0.00000000 +# +# E+PT2 -193.84055916 0.00000000 +# E+rPT2 -193.61540129 0.00000000 +# ============ ============================= + + N_det = 40 + N_states = 1 + + * State 1 + < S^2 > = 1.204388200142237E-002 + E = -192.934862982262 + Variance = 3.00577730138265 + PT norm = 0.575197881033715 + PT2 = -0.905696182716613 + rPT2 = -0.680538311395485 + E+PT2 = -193.840559164978 +/- 0.000000000000000E+000 + E+rPT2 = -193.615401293657 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.301268667693 + Vee = 220.465734567674 + Vecp = 0.000000000000000E+000 + T = 193.010655241592 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6906 -193.86880334 + -0.6997 -193.87085673 + -0.7136 -193.95665825 + -0.7216 -194.18724890 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 16.515594 GB ] [ VIRT MEM : 22.710533 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 330.302840 s ] [ CPU TIME: 18364.677133 s ] <<<<< .. + +* Energy of state 1 -192.9525305674946 +* S^2 of state 1 0.2235786174244760E-01 +* Saved determinants 80 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 31 +* Number of unique alpha determinants 31 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.515778 GB ] [ VIRT MEM : 22.710701 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 330.417980 s ] [ CPU TIME: 18371.854994 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 16.515778 GB ] [ VIRT MEM : 22.710701 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 330.418353 s ] [ CPU TIME: 18371.879658 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -192.9525305674946 + +.. >>>>> [ RES MEM : 16.515778 GB ] [ VIRT MEM : 22.710701 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 330.424674 s ] [ CPU TIME: 18372.282581 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 16.515778 GB ] [ VIRT MEM : 22.710701 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 330.425052 s ] [ CPU TIME: 18372.306754 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 80 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.3096809089183807E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7329925691 0.115 3.0637591978 0.2493535432 13.0324 + 72 -193.8170120910 0.774E-02 2.9727441467 0.3040711974 16.6567 + 78 -193.8261085615 0.00 2.9594091142 0.3107865542 17.4235 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.521667 GB ] [ VIRT MEM : 22.716541 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 347.877094 s ] [ CPU TIME: 19231.335094 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 16.521667 GB ] [ VIRT MEM : 22.716541 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 347.877462 s ] [ CPU TIME: 19231.357941 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1243794191566114 + +Summary at N_det = 80 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -192.95253057 +# PT2 -0.87357799 0.00000000 +# rPT2 -0.66645328 0.00000000 +# +# E+PT2 -193.82610856 0.00000000 +# E+rPT2 -193.61898384 0.00000000 +# ============ ============================= + + N_det = 80 + N_states = 1 + + * State 1 + < S^2 > = 2.235786174244760E-002 + E = -192.952530567495 + Variance = 2.95940911416350 + PT norm = 0.557482335290176 + PT2 = -0.873577994011557 + rPT2 = -0.666453276651885 + E+PT2 = -193.826108561506 +/- 0.000000000000000E+000 + E+rPT2 = -193.618983844146 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.305305922127 + Vee = 220.437032098739 + Vecp = 0.000000000000000E+000 + T = 193.025727379729 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6805 -193.78849727 + -0.6906 -193.81931571 + -0.6997 -193.83601668 + -0.7136 -193.90066106 + -0.7216 -194.06792037 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 16.521961 GB ] [ VIRT MEM : 22.716541 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 347.973162 s ] [ CPU TIME: 19237.399100 s ] <<<<< .. + +* Energy of state 1 -192.9767893713810 +* S^2 of state 1 0.3158732671965413E-01 +* Saved determinants 160 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 66 +* Number of unique alpha determinants 65 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.522041 GB ] [ VIRT MEM : 22.716541 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 348.043940 s ] [ CPU TIME: 19242.071414 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 16.522041 GB ] [ VIRT MEM : 22.716541 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 348.044306 s ] [ CPU TIME: 19242.097007 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -192.9767893713810 + +.. >>>>> [ RES MEM : 16.522041 GB ] [ VIRT MEM : 22.716541 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 348.049699 s ] [ CPU TIME: 19242.467532 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 16.522041 GB ] [ VIRT MEM : 22.716541 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 348.050098 s ] [ CPU TIME: 19242.495036 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 160 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.3252593874931335E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7126989583 0.114 2.8965335829 0.2303897967 16.6731 + 68 -193.7940727987 0.783E-02 2.8841656560 0.2782233161 21.1871 + 74 -193.7965516564 0.732E-02 2.8897699899 0.2791544492 22.2173 + 96 -193.7999310666 0.566E-02 2.8799630513 0.2822035812 23.2331 + 138 -193.8033397142 0.396E-02 2.8741707673 0.2848308838 24.7180 + 140 -193.8034534065 0.390E-02 2.8737822717 0.2849398677 27.4783 + 147 -193.8048213465 0.386E-02 2.8813682629 0.2851023334 28.5467 + 154 -193.8090171941 0.00 2.8946432271 0.2863213047 28.6487 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.522354 GB ] [ VIRT MEM : 22.716541 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 376.722750 s ] [ CPU TIME: 20957.732207 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 16.522354 GB ] [ VIRT MEM : 22.716541 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 376.723076 s ] [ CPU TIME: 20957.753479 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1552750144515807 + +Summary at N_det = 160 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -192.97678937 +# PT2 -0.83222782 0.00000000 +# rPT2 -0.64698285 0.00000000 +# +# E+PT2 -193.80901719 0.00000000 +# E+rPT2 -193.62377222 0.00000000 +# ============ ============================= + + N_det = 160 + N_states = 1 + + * State 1 + < S^2 > = 3.158732671965413E-002 + E = -192.976789371381 + Variance = 2.89464322713237 + PT norm = 0.535089996805248 + PT2 = -0.832227822710855 + rPT2 = -0.646982849216834 + E+PT2 = -193.809017194092 +/- 0.000000000000000E+000 + E+rPT2 = -193.623772220598 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.309522148032 + Vee = 220.400530352877 + Vecp = 0.000000000000000E+000 + T = 193.042186547609 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6665 -193.78288519 + -0.6805 -193.78505039 + -0.6906 -193.80011260 + -0.6997 -193.81301892 + -0.7136 -193.85679657 + -0.7216 -193.97206641 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 16.530914 GB ] [ VIRT MEM : 22.716541 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 376.853933 s ] [ CPU TIME: 20966.448896 s ] <<<<< .. + +* Energy of state 1 -193.0077165860177 +* S^2 of state 1 0.3452612559833889E-01 +* Saved determinants 320 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 118 +* Number of unique alpha determinants 118 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.530914 GB ] [ VIRT MEM : 22.716541 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 376.928707 s ] [ CPU TIME: 20971.329718 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 16.530914 GB ] [ VIRT MEM : 22.716541 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 376.929081 s ] [ CPU TIME: 20971.356407 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -193.0077165860177 + +.. >>>>> [ RES MEM : 16.530914 GB ] [ VIRT MEM : 22.716541 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 376.934971 s ] [ CPU TIME: 20971.772934 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 16.530914 GB ] [ VIRT MEM : 22.716541 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 376.935329 s ] [ CPU TIME: 20971.798641 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 320 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.3564163446426392E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.6699712017 0.136 2.7615692994 0.1991432611 22.6173 + 72 -193.7736954594 0.835E-02 2.7956129714 0.2513038779 24.1322 + 124 -193.7819749872 0.542E-02 2.7843856862 0.2570308029 26.7042 + 139 -193.7826154878 0.484E-02 2.7796749353 0.2577962363 32.5732 + 147 -193.7817872550 0.470E-02 2.7797464329 0.2572620424 33.7352 + 164 -193.7835303066 0.437E-02 2.7812153863 0.2581342030 35.7374 + 208 -193.7867561422 0.413E-02 2.8012132610 0.2582429084 37.7903 + 211 -193.7867725519 0.407E-02 2.8003533482 0.2583265233 43.2955 + 224 -193.7856116164 0.403E-02 2.7971753448 0.2579253229 44.7188 + 250 -193.7862926272 0.364E-02 2.7969343725 0.2583551468 45.7286 + 277 -193.7881821376 0.357E-02 2.8126596913 0.2581507365 46.7615 + 280 -193.7881792250 0.353E-02 2.8118890453 0.2582147338 47.9414 + 283 -193.7881763741 0.349E-02 2.8111347380 0.2582773743 49.8435 + 286 -193.7881735830 0.345E-02 2.8103962554 0.2583387007 50.8641 + 307 -193.7885556727 0.359E-02 2.8165149409 0.2580602622 51.8889 + 313 -193.7909316347 0.00 2.8121731886 0.2596538441 52.1475 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.531120 GB ] [ VIRT MEM : 22.716770 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 429.110832 s ] [ CPU TIME: 24447.929950 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 16.531120 GB ] [ VIRT MEM : 22.716770 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 429.111192 s ] [ CPU TIME: 24447.952703 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1942057781498282 + +Summary at N_det = 320 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.00771659 +# PT2 -0.78321505 0.00000000 +# rPT2 -0.62177006 0.00000000 +# +# E+PT2 -193.79093163 0.00000000 +# E+rPT2 -193.62948665 0.00000000 +# ============ ============================= + + N_det = 320 + N_states = 1 + + * State 1 + < S^2 > = 3.452612559833889E-002 + E = -193.007716586018 + Variance = 2.81217318859148 + PT norm = 0.509562404493440 + PT2 = -0.783215048692455 + rPT2 = -0.621770061971867 + E+PT2 = -193.790931634710 +/- 0.000000000000000E+000 + E+rPT2 = -193.629486647990 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.304203506097 + Vee = 220.345202553595 + Vecp = 0.000000000000000E+000 + T = 193.061268490319 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6470 -193.77040958 + -0.6665 -193.77544393 + -0.6805 -193.77854211 + -0.6906 -193.78769439 + -0.6997 -193.79691312 + -0.7136 -193.82581172 + -0.7216 -193.90310373 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 16.542553 GB ] [ VIRT MEM : 22.725960 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 429.358541 s ] [ CPU TIME: 24464.976355 s ] <<<<< .. + +* Energy of state 1 -193.0474845177712 +* S^2 of state 1 0.3257970367834703E-01 +* Saved determinants 640 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 204 +* Number of unique alpha determinants 204 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.542553 GB ] [ VIRT MEM : 22.725960 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 429.460554 s ] [ CPU TIME: 24471.419466 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 16.542553 GB ] [ VIRT MEM : 22.725960 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 429.460930 s ] [ CPU TIME: 24471.446691 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -193.0474845177712 + +.. >>>>> [ RES MEM : 16.542553 GB ] [ VIRT MEM : 22.725960 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 429.467089 s ] [ CPU TIME: 24471.888539 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 16.542553 GB ] [ VIRT MEM : 22.725960 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 429.467448 s ] [ CPU TIME: 24471.914706 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 640 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.4187302589416504E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.6397667434 0.140 2.6008865486 0.1704518513 33.8124 + 140 -193.7591231443 0.615E-02 2.6575425484 0.2257909709 35.6494 + 153 -193.7592294850 0.562E-02 2.6590965163 0.2257078690 36.8354 + 173 -193.7621865256 0.535E-02 2.6666968430 0.2266978230 37.9913 + 190 -193.7633725824 0.504E-02 2.6696353542 0.2271048863 40.0225 + 197 -193.7643352451 0.504E-02 2.6767011718 0.2271416413 41.1445 + 198 -193.7643173288 0.501E-02 2.6763184355 0.2271603144 42.6253 + 200 -193.7651122871 0.503E-02 2.6841557891 0.2270149373 43.6544 + 208 -193.7652976949 0.485E-02 2.6900332626 0.2266213899 45.7454 + 222 -193.7640439363 0.465E-02 2.6861495933 0.2262491916 46.8504 + 226 -193.7639863059 0.457E-02 2.6846410940 0.2263304256 49.7604 + 264 -193.7677098853 0.436E-02 2.6955397811 0.2275299344 52.0625 + 269 -193.7685257824 0.438E-02 2.6973081448 0.2278690836 53.7164 + 275 -193.7676477194 0.435E-02 2.6966384588 0.2274462305 55.2587 + 281 -193.7679625581 0.428E-02 2.7009404011 0.2273141620 56.3508 + 290 -193.7676834141 0.414E-02 2.7006159874 0.2271612752 58.2177 + 302 -193.7670910955 0.449E-02 2.7050016161 0.2264845198 59.4474 + 317 -193.7667928332 0.428E-02 2.7000765893 0.2266905636 60.9592 + 329 -193.7673461052 0.419E-02 2.6993437788 0.2270688810 62.6953 + 340 -193.7685681238 0.426E-02 2.7047469215 0.2273229504 63.9244 + 343 -193.7685000745 0.423E-02 2.7038388089 0.2273537022 66.9336 + 364 -193.7672936383 0.418E-02 2.6999654703 0.2269683691 68.2553 + 373 -193.7671366615 0.408E-02 2.6975756184 0.2270617603 69.2744 + 374 -193.7671196860 0.407E-02 2.6973171792 0.2270718596 70.6875 + 399 -193.7670040512 0.395E-02 2.6993555084 0.2268588989 73.0135 + 405 -193.7678329529 0.400E-02 2.7039474263 0.2269818228 74.4596 + 413 -193.7679946102 0.403E-02 2.7064601889 0.2268734529 75.5023 + 418 -193.7685162674 0.402E-02 2.7074675759 0.2270995618 76.5514 + 425 -193.7683889753 0.396E-02 2.7057126645 0.2271611511 78.6804 + 436 -193.7686136041 0.388E-02 2.7053302068 0.2272976884 80.2483 + 455 -193.7682868131 0.372E-02 2.7009701944 0.2274455637 81.3394 + 469 -193.7683975153 0.363E-02 2.7029634202 0.2273692284 82.5223 + 471 -193.7683652024 0.361E-02 2.7025301121 0.2273839617 85.1106 + 486 -193.7700530419 0.366E-02 2.7090841300 0.2278305118 86.2897 + 488 -193.7700150697 0.365E-02 2.7086408318 0.2278428413 87.9634 + 507 -193.7709166912 0.362E-02 2.7114643735 0.2281358910 89.2537 + 519 -193.7706951144 0.360E-02 2.7108792937 0.2280667380 90.4524 + 535 -193.7708465842 0.355E-02 2.7127577373 0.2279996335 92.8073 + 542 -193.7703245404 0.353E-02 2.7116185644 0.2277919924 93.9645 + 549 -193.7707534512 0.352E-02 2.7124620113 0.2279671431 95.5575 + 558 -193.7710480676 0.349E-02 2.7123632804 0.2281473083 96.9231 + 569 -193.7713808732 0.346E-02 2.7123844821 0.2283308531 97.9805 + 572 -193.7712155345 0.345E-02 2.7133676998 0.2281692849 99.0554 + 598 -193.7717837749 0.337E-02 2.7158175240 0.2283062376 100.5305 + 608 -193.7716029204 0.332E-02 2.7139277520 0.2283478934 101.7061 + 616 -193.7718749429 0.330E-02 2.7140003572 0.2285014882 102.8130 + 625 -193.7714230803 0.00 2.7064831718 0.2287010946 103.2131 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.543324 GB ] [ VIRT MEM : 22.725960 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 532.708498 s ] [ CPU TIME: 31613.184006 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 16.543324 GB ] [ VIRT MEM : 22.725960 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 532.708874 s ] [ CPU TIME: 31613.206846 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.2434756734951097 + +Summary at N_det = 640 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.04748452 +# PT2 -0.72393856 0.00000000 +# rPT2 -0.58919013 0.00000000 +# +# E+PT2 -193.77142308 0.00000000 +# E+rPT2 -193.63667465 0.00000000 +# ============ ============================= + + N_det = 640 + N_states = 1 + + * State 1 + < S^2 > = 3.257970367834703E-002 + E = -193.047484517771 + Variance = 2.70648317182429 + PT norm = 0.478227032444424 + PT2 = -0.723938562544450 + rPT2 = -0.589190133995396 + E+PT2 = -193.771423080316 +/- 0.000000000000000E+000 + E+rPT2 = -193.636674651767 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.303742769852 + Vee = 220.279371733071 + Vecp = 0.000000000000000E+000 + T = 193.086870642845 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6218 -193.76666576 + -0.6470 -193.76816447 + -0.6665 -193.77121969 + -0.6805 -193.77373130 + -0.6906 -193.77959905 + -0.6997 -193.78600396 + -0.7136 -193.80493601 + =========== =================== + +* Number of unique alpha determinants 349 +* Number of unique beta determinants 349 +.. >>>>> [ IO READ: davidson_sze_max ] <<<<< .. + +.. >>>>> [ RES MEM : 16.543560 GB ] [ VIRT MEM : 22.725960 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 532.835461 s ] [ CPU TIME: 31621.194610 s ] <<<<< .. + +.. >>>>> [ IO READ: state_following ] <<<<< .. + +.. >>>>> [ RES MEM : 16.543560 GB ] [ VIRT MEM : 22.725960 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 532.836514 s ] [ CPU TIME: 31621.264984 s ] <<<<< .. + +.. >>>>> [ IO READ: only_expected_s2 ] <<<<< .. + +.. >>>>> [ RES MEM : 16.543560 GB ] [ VIRT MEM : 22.725960 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 532.837595 s ] [ CPU TIME: 31621.336933 s ] <<<<< .. + +.. >>>>> [ IO READ: disk_based_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 16.543560 GB ] [ VIRT MEM : 22.725960 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 532.838319 s ] [ CPU TIME: 31621.385187 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 16.543560 GB ] [ VIRT MEM : 22.725960 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 532.838654 s ] [ CPU TIME: 31621.407681 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 1280 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.3228627145290375E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.0475947024 0.032586 0.222E-01 + 2 -193.0938816868 0.039344 0.167E-02 + 3 -193.0944697270 0.038108 0.635E-04 + 4 -193.0945322892 0.038471 0.102E-05 + 5 -193.0945339320 0.038460 0.181E-07 + 6 -193.0945339628 0.038461 0.370E-09 + 7 -193.0945339635 0.038461 0.567E-11 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 16.544323 GB ] [ VIRT MEM : 22.725960 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 532.905984 s ] [ CPU TIME: 31625.931678 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 16.544323 GB ] [ VIRT MEM : 22.725960 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 532.906365 s ] [ CPU TIME: 31625.957925 s ] <<<<< .. + +* Energy of state 1 -193.0945339634582 +* S^2 of state 1 0.3846134569519073E-01 +* Saved determinants 1280 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.544495 GB ] [ VIRT MEM : 22.725960 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 533.022920 s ] [ CPU TIME: 31632.177396 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 16.544495 GB ] [ VIRT MEM : 22.725960 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 533.023291 s ] [ CPU TIME: 31632.202941 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 64 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -193.0945339634582 + +.. >>>>> [ RES MEM : 16.544495 GB ] [ VIRT MEM : 22.725960 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 533.034488 s ] [ CPU TIME: 31632.959722 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 16.544495 GB ] [ VIRT MEM : 22.725960 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 533.034858 s ] [ CPU TIME: 31632.985005 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 64 +* pt2_n_tasks_max 1 +* Number of tasks 1280 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.5433768630027771E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7517447397 0.232E-03 2.5813992051 0.1955283630 59.9752 + 5 -193.7518273629 0.178E-03 2.5820303001 0.1955299438 66.4733 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.543331 GB ] [ VIRT MEM : 22.722897 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 603.861990 s ] [ CPU TIME: 36351.109814 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 16.543331 GB ] [ VIRT MEM : 22.722897 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 603.862365 s ] [ CPU TIME: 36351.134289 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 64 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.3009308559575440 + +Summary at N_det = 1280 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.09453396 +# PT2 -0.65729340 0.00017794 +# rPT2 -0.54979250 0.00014884 +# +# E+PT2 -193.75182736 0.00017794 +# E+rPT2 -193.64432647 0.00014884 +# ============ ============================= + + N_det = 1280 + N_states = 1 + + * State 1 + < S^2 > = 3.846134569519073E-002 + E = -193.094533963458 + Variance = 2.58203030006293 + PT norm = 0.442187679424580 + PT2 = -0.657293399424462 + rPT2 = -0.549792502324171 + E+PT2 = -193.751827362883 +/- 1.779378558913314E-004 + E+rPT2 = -193.644326465782 +/- 1.488359675212827E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.307878135338 + Vee = 220.209628119085 + Vecp = 0.000000000000000E+000 + T = 193.113700176630 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.5892 -193.75110725 + -0.6218 -193.75759396 + -0.6470 -193.76098769 + -0.6665 -193.76419600 + -0.6805 -193.76676948 + -0.6906 -193.77112619 + -0.6997 -193.77591206 + =========== =================== + +* Number of unique alpha determinants 585 +* Number of unique beta determinants 586 + +.. >>>>> [ RES MEM : 16.543400 GB ] [ VIRT MEM : 22.722897 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 603.936956 s ] [ CPU TIME: 36356.022995 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 2560 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.5880575627088547E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.0947254953 0.038414 0.242E-01 + 2 -193.1503388727 0.041309 0.172E-02 + 3 -193.1510663330 0.039603 0.693E-04 + 4 -193.1511435676 0.039935 0.125E-05 + 5 -193.1511456741 0.039916 0.316E-07 + 6 -193.1511457290 0.039909 0.580E-09 + 7 -193.1511457301 0.039910 0.860E-11 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 16.545288 GB ] [ VIRT MEM : 22.726807 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 603.980109 s ] [ CPU TIME: 36359.063446 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 16.545288 GB ] [ VIRT MEM : 22.726807 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 603.980501 s ] [ CPU TIME: 36359.091805 s ] <<<<< .. + +* Energy of state 1 -193.1511457301216 +* S^2 of state 1 0.3991007743242163E-01 +* Saved determinants 2560 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.545334 GB ] [ VIRT MEM : 22.726807 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 604.209358 s ] [ CPU TIME: 36371.706406 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 16.545334 GB ] [ VIRT MEM : 22.726807 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 604.209744 s ] [ CPU TIME: 36371.734004 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 84 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -193.1511457301216 + +.. >>>>> [ RES MEM : 16.545334 GB ] [ VIRT MEM : 22.726807 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 604.218180 s ] [ CPU TIME: 36372.338628 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 16.545334 GB ] [ VIRT MEM : 22.726807 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 604.218551 s ] [ CPU TIME: 36372.365861 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 84 +* pt2_n_tasks_max 1 +* Number of tasks 2560 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.7926384806632995E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7357297058 0.709E-03 2.4352509190 0.1621182310 104.9337 + 7 -193.7351714721 0.439E-03 2.4326099319 0.1619806939 112.6925 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.590366 GB ] [ VIRT MEM : 22.769833 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 723.885714 s ] [ CPU TIME: 44252.765230 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 16.590366 GB ] [ VIRT MEM : 22.769833 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 723.886094 s ] [ CPU TIME: 44252.791908 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 84 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.3684944357656683 + +Summary at N_det = 2560 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.15114573 +# PT2 -0.58402574 0.00043923 +# rPT2 -0.50261226 0.00037800 +# +# E+PT2 -193.73517147 0.00043923 +# E+rPT2 -193.65375799 0.00037800 +# ============ ============================= + + N_det = 2560 + N_states = 1 + + * State 1 + < S^2 > = 3.991007743242163E-002 + E = -193.151145730122 + Variance = 2.43260993185033 + PT norm = 0.402468252035976 + PT2 = -0.584025741932994 + rPT2 = -0.502612259395091 + E+PT2 = -193.735171472055 +/- 4.392260380816261E-004 + E+rPT2 = -193.653757989517 +/- 3.779977071810109E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.309885669164 + Vee = 220.124969227165 + Vecp = 0.000000000000000E+000 + T = 193.143754835713 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.5498 -193.75423224 + -0.5892 -193.75293765 + -0.6218 -193.75560325 + -0.6470 -193.75790417 + -0.6665 -193.76029240 + -0.6805 -193.76235487 + -0.6906 -193.76551479 + =========== =================== + +* Number of unique alpha determinants 985 +* Number of unique beta determinants 987 + +.. >>>>> [ RES MEM : 16.591579 GB ] [ VIRT MEM : 22.769833 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 723.971379 s ] [ CPU TIME: 44258.657627 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5120 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.1089049875736237E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.1512251921 0.039922 0.247E-01 + 2 -193.2129109208 0.041180 0.173E-02 + 3 -193.2137450315 0.039519 0.677E-04 + 4 -193.2138326208 0.039773 0.116E-05 + 5 -193.2138347930 0.039744 0.284E-07 + 6 -193.2138348468 0.039740 0.644E-09 + 7 -193.2138348481 0.039741 0.125E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 16.598103 GB ] [ VIRT MEM : 22.774433 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 724.050864 s ] [ CPU TIME: 44264.207966 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 16.596954 GB ] [ VIRT MEM : 22.772133 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 724.051411 s ] [ CPU TIME: 44264.246611 s ] <<<<< .. + +* Energy of state 1 -193.2138348480890 +* S^2 of state 1 0.3974066467736076E-01 +* Saved determinants 5120 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.598560 GB ] [ VIRT MEM : 22.776043 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 724.363178 s ] [ CPU TIME: 44278.686415 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 16.598560 GB ] [ VIRT MEM : 22.776043 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 724.363576 s ] [ CPU TIME: 44278.714657 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 100 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -193.2138348480890 + +.. >>>>> [ RES MEM : 16.599525 GB ] [ VIRT MEM : 22.776043 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 724.372095 s ] [ CPU TIME: 44279.308638 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 16.599525 GB ] [ VIRT MEM : 22.776043 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 724.372472 s ] [ CPU TIME: 44279.335344 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 100 +* pt2_n_tasks_max 1 +* Number of tasks 5120 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1291154563426971 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7213093789 0.131E-02 2.2592264244 0.1301022617 200.7751 + 12 -193.7214002414 0.392E-03 2.2579621789 0.1301641553 204.2384 + 13 -193.7213442852 0.368E-03 2.2580703033 0.1301391342 210.8963 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.718800 GB ] [ VIRT MEM : 22.891190 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 945.019876 s ] [ CPU TIME: 60095.342790 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 16.718800 GB ] [ VIRT MEM : 22.891190 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 945.020281 s ] [ CPU TIME: 60095.372393 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 100 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.4421792678097918 + +Summary at N_det = 5120 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.21383485 +# PT2 -0.50750944 0.00036834 +# rPT2 -0.44906810 0.00032593 +# +# E+PT2 -193.72134429 0.00036834 +# E+rPT2 -193.66290295 0.00032593 +# ============ ============================= + + N_det = 5120 + N_states = 1 + + * State 1 + < S^2 > = 3.974066467736076E-002 + E = -193.213834848089 + Variance = 2.25807030333879 + PT norm = 0.360748020327771 + PT2 = -0.507509437140551 + rPT2 = -0.449068103028832 + E+PT2 = -193.721344285230 +/- 3.683415617958129E-004 + E+rPT2 = -193.662902951118 +/- 3.259258534270643E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.336980657374 + Vee = 220.047261960420 + Vecp = 0.000000000000000E+000 + T = 193.185867972699 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.5026 -193.73960059 + -0.5498 -193.74581483 + -0.5892 -193.74772866 + -0.6218 -193.75041061 + -0.6470 -193.75267684 + -0.6665 -193.75485464 + -0.6805 -193.75673202 + =========== =================== + +* Number of unique alpha determinants 1706 +* Number of unique beta determinants 1707 + +.. >>>>> [ RES MEM : 16.720203 GB ] [ VIRT MEM : 22.891190 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 945.147237 s ] [ CPU TIME: 60104.321345 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 10240 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.2058012783527374E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.2138512018 0.039714 0.233E-01 + 2 -193.2784079615 0.034938 0.137E-02 + 3 -193.2792093564 0.033416 0.695E-04 + 4 -193.2793011874 0.033521 0.129E-05 + 5 -193.2793036839 0.033504 0.524E-07 + 6 -193.2793037769 0.033498 0.166E-08 + 7 -193.2793037802 0.033499 0.453E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 16.731323 GB ] [ VIRT MEM : 22.900368 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 945.293545 s ] [ CPU TIME: 60114.815627 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 16.728897 GB ] [ VIRT MEM : 22.895779 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 945.294302 s ] [ CPU TIME: 60114.870450 s ] <<<<< .. + +* Energy of state 1 -193.2793037801558 +* S^2 of state 1 0.3349859923367423E-01 +* Saved determinants 10240 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.728901 GB ] [ VIRT MEM : 22.895779 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 945.829718 s ] [ CPU TIME: 60137.674925 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 16.728901 GB ] [ VIRT MEM : 22.895779 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 945.830129 s ] [ CPU TIME: 60137.704661 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 100 +* pt2_n_tasks_max 2 +* PT2 Energy denominator -193.2793037801558 + +.. >>>>> [ RES MEM : 16.724396 GB ] [ VIRT MEM : 22.891190 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 945.840914 s ] [ CPU TIME: 60138.478547 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 16.724396 GB ] [ VIRT MEM : 22.891190 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 945.841305 s ] [ CPU TIME: 60138.507189 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 100 +* pt2_n_tasks_max 2 +* Number of tasks 10610 +* Number of fragmented tasks 370 +* Number of threads for PT2 72 +* Memory (Gb) 0.2288544952869415 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7130789869 0.202E-02 2.0708702381 0.1022071693 200.7612 + 8 -193.7121729627 0.827E-03 2.0652170120 0.1020782451 206.8180 + 9 -193.7122637865 0.758E-03 2.0656017095 0.1021010383 225.9622 + 10 -193.7123501078 0.660E-03 2.0661061543 0.1021140796 232.9083 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.911552 GB ] [ VIRT MEM : 23.051311 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1186.354490 s ] [ CPU TIME: 77391.016061 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 16.911552 GB ] [ VIRT MEM : 23.051311 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1186.354901 s ] [ CPU TIME: 77391.045442 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 100 +* pt2_n_tasks_max 2 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.5175091690908412 + +Summary at N_det = 10240 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.27930378 +# PT2 -0.43304633 0.00066047 +# rPT2 -0.39292332 0.00059928 +# +# E+PT2 -193.71235011 0.00066047 +# E+rPT2 -193.67222710 0.00059928 +# ============ ============================= + + N_det = 10240 + N_states = 1 + + * State 1 + < S^2 > = 3.349859923367423E-002 + E = -193.279303780156 + Variance = 2.06610615433881 + PT norm = 0.319552937110610 + PT2 = -0.433046327670462 + rPT2 = -0.392923324073074 + E+PT2 = -193.712350107826 +/- 6.604697931809947E-004 + E+rPT2 = -193.672227104229 +/- 5.992753430852694E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.360329036973 + Vee = 219.965302322178 + Vecp = 0.000000000000000E+000 + T = 193.225707058475 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4491 -193.73748121 + -0.5026 -193.73842119 + -0.5498 -193.74205761 + -0.5892 -193.74405078 + -0.6218 -193.74635968 + -0.6470 -193.74836993 + -0.6665 -193.75026870 + =========== =================== + +* Number of unique alpha determinants 3024 +* Number of unique beta determinants 3022 + +.. >>>>> [ RES MEM : 16.913551 GB ] [ VIRT MEM : 23.051311 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1186.530325 s ] [ CPU TIME: 77403.435124 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 20480 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.3946406021714211E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.2793063127 0.033503 0.208E-01 + 2 -193.3441947501 0.026089 0.116E-02 + 3 -193.3450109537 0.025101 0.778E-04 + 4 -193.3451190174 0.025212 0.128E-05 + 5 -193.3451218322 0.025195 0.590E-07 + 6 -193.3451219449 0.025190 0.234E-08 + 7 -193.3451219499 0.025190 0.741E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 16.933975 GB ] [ VIRT MEM : 23.074463 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1186.909383 s ] [ CPU TIME: 77430.555851 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 16.926678 GB ] [ VIRT MEM : 23.060593 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1186.910821 s ] [ CPU TIME: 77430.659488 s ] <<<<< .. + +* Energy of state 1 -193.3451219498513 +* S^2 of state 1 0.2519020291511761E-01 +* Saved determinants 20480 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.918991 GB ] [ VIRT MEM : 23.051311 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1187.632135 s ] [ CPU TIME: 77458.808981 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 16.918991 GB ] [ VIRT MEM : 23.051311 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1187.632556 s ] [ CPU TIME: 77458.839787 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 +* PT2 Energy denominator -193.3451219498513 + +.. >>>>> [ RES MEM : 16.920322 GB ] [ VIRT MEM : 23.053764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1187.646443 s ] [ CPU TIME: 77459.836223 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 16.920322 GB ] [ VIRT MEM : 23.053764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1187.646879 s ] [ CPU TIME: 77459.867761 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 +* Number of tasks 21398 +* Number of fragmented tasks 459 +* Number of threads for PT2 72 +* Memory (Gb) 0.4282957971096039 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7100881722 0.145E-02 1.8709597212 0.0790177610 268.6820 + 9 -193.7090969050 0.643E-03 1.8660921896 0.0787888456 302.0757 + 10 -193.7092714793 0.560E-03 1.8672597014 0.0788178062 304.6284 + 11 -193.7092666742 0.505E-03 1.8668061014 0.0788340701 307.3462 + 12 -193.7095593675 0.532E-03 1.8683925060 0.0788889929 349.5870 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 17.272877 GB ] [ VIRT MEM : 23.356377 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1537.319696 s ] [ CPU TIME: 102549.393873 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 17.272877 GB ] [ VIRT MEM : 23.356377 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1537.320130 s ] [ CPU TIME: 102549.425103 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.5904695403252895 + +Summary at N_det = 20480 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.34512195 +# PT2 -0.36461928 0.00057481 +# rPT2 -0.33794711 0.00053276 +# +# E+PT2 -193.70974123 0.00057481 +# E+rPT2 -193.68306906 0.00053276 +# ============ ============================= + + N_det = 20480 + N_states = 1 + + * State 1 + < S^2 > = 2.519020291511761E-002 + E = -193.345121949851 + Variance = 1.86925467194042 + PT norm = 0.280934314454138 + PT2 = -0.364619279680785 + rPT2 = -0.337947111743470 + E+PT2 = -193.709741229532 +/- 5.748126670149507E-004 + E+rPT2 = -193.683069061595 +/- 5.327646985132829E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.385965461226 + Vee = 219.888406069062 + Vecp = 0.000000000000000E+000 + T = 193.262421566148 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3929 -193.74971622 + -0.4491 -193.74408954 + -0.5026 -193.74235621 + -0.5498 -193.74353297 + -0.5892 -193.74451207 + -0.6218 -193.74596358 + -0.6470 -193.74737102 + =========== =================== + +* Number of unique alpha determinants 5419 +* Number of unique beta determinants 5418 + +.. >>>>> [ RES MEM : 17.278442 GB ] [ VIRT MEM : 23.356377 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1537.571867 s ] [ CPU TIME: 102567.279716 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 40960 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.7626946270465851E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.3451244806 0.025190 0.171E-01 + 2 -193.4052784296 0.019036 0.793E-03 + 3 -193.4060150169 0.018509 0.843E-04 + 4 -193.4061213725 0.018639 0.147E-05 + 5 -193.4061249090 0.018640 0.706E-07 + 6 -193.4061250630 0.018637 0.303E-08 + 7 -193.4061250701 0.018637 0.115E-09 + 8 -193.4061250704 0.018637 0.428E-11 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 17.313126 GB ] [ VIRT MEM : 23.402775 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1538.912714 s ] [ CPU TIME: 102663.574781 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 17.296673 GB ] [ VIRT MEM : 23.374935 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1538.915349 s ] [ CPU TIME: 102663.764549 s ] <<<<< .. + +* Energy of state 1 -193.4061250704185 +* S^2 of state 1 0.1863710921305642E-01 +* Saved determinants 40960 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 17.284950 GB ] [ VIRT MEM : 23.357807 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1540.013986 s ] [ CPU TIME: 102703.317180 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 17.284950 GB ] [ VIRT MEM : 23.357807 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1540.014450 s ] [ CPU TIME: 102703.351580 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 +* PT2 Energy denominator -193.4061250704185 + +.. >>>>> [ RES MEM : 17.293556 GB ] [ VIRT MEM : 23.367596 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1540.037954 s ] [ CPU TIME: 102705.038388 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 17.293556 GB ] [ VIRT MEM : 23.367596 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1540.038387 s ] [ CPU TIME: 102705.070571 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 +* Number of tasks 52291 +* Number of fragmented tasks 9621 +* Number of threads for PT2 72 +* Memory (Gb) 0.8271784007549285 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7069934983 0.763E-03 1.6514837078 0.0601651059 340.2286 + 8 -193.7059054404 0.985E-03 1.6463486970 0.0598744349 345.8897 + 9 -193.7064392301 0.103E-02 1.6498720891 0.0599557358 370.3928 + 10 -193.7068891561 0.113E-02 1.6531357660 0.0600155333 383.1160 + 11 -193.7069395868 0.102E-02 1.6529958221 0.0600311220 409.2384 + 12 -193.7066164949 0.961E-03 1.6500515395 0.0600110413 436.3819 + 13 -193.7064336211 0.902E-03 1.6478144891 0.0600173300 443.3907 + 14 -193.7065914518 0.849E-03 1.6484535735 0.0600595012 471.6899 + 15 -193.7062174656 0.805E-03 1.6470385195 0.0599687678 506.3096 + 16 -193.7064652923 0.794E-03 1.6485752372 0.0600072042 512.6638 + 18 -193.7066810658 0.672E-03 1.6499959001 0.0600418868 560.8166 + 19 -193.7066115334 0.624E-03 1.6500782968 0.0600149286 586.3759 + 20 -193.7066785072 0.595E-03 1.6506021518 0.0600221909 607.9817 + 21 -193.7067327369 0.568E-03 1.6509006735 0.0600304841 613.3691 + 22 -193.7065591841 0.545E-03 1.6500686079 0.0599947540 634.5040 + 23 -193.7065151825 0.522E-03 1.6499701793 0.0599808793 644.9990 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 17.942509 GB ] [ VIRT MEM : 23.928696 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2203.080542 s ] [ CPU TIME: 150275.806426 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 17.942509 GB ] [ VIRT MEM : 23.928696 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2203.081030 s ] [ CPU TIME: 150275.841380 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.6592430212168420 + +Summary at N_det = 40960 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.40612507 +# PT2 -0.30039011 0.00052191 +# rPT2 -0.28339201 0.00049237 +# +# E+PT2 -193.70651518 0.00052191 +# E+rPT2 -193.68951708 0.00049237 +# ============ ============================= + + N_det = 40960 + N_states = 1 + + * State 1 + < S^2 > = 1.863710921305642E-002 + E = -193.406125070419 + Variance = 1.64997017931514 + PT norm = 0.244909941213946 + PT2 = -0.300390112045385 + rPT2 = -0.283392010091940 + E+PT2 = -193.706515182464 +/- 5.219052769673722E-004 + E+rPT2 = -193.689517080510 +/- 4.923723504421749E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.395525889094 + Vee = 219.810487728509 + Vecp = 0.000000000000000E+000 + T = 193.288897214002 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3379 -193.72301197 + -0.3929 -193.73499006 + -0.4491 -193.73704827 + -0.5026 -193.73789726 + -0.5498 -193.73957826 + -0.5892 -193.74086775 + -0.6218 -193.74232924 + =========== =================== + +* Number of unique alpha determinants 10057 +* Number of unique beta determinants 10057 + +.. >>>>> [ RES MEM : 17.951622 GB ] [ VIRT MEM : 23.928696 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2203.776946 s ] [ CPU TIME: 150325.574689 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 81920 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.1492681577801704 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.4061264434 0.018637 0.129E-01 + 2 -193.4576908901 0.012963 0.490E-03 + 3 -193.4583340578 0.012634 0.847E-04 + 4 -193.4584251212 0.012715 0.165E-05 + 5 -193.4584292532 0.012722 0.990E-07 + 6 -193.4584294642 0.012720 0.548E-08 + 7 -193.4584294773 0.012720 0.301E-09 + 8 -193.4584294781 0.012720 0.175E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 18.017509 GB ] [ VIRT MEM : 24.035099 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2208.488341 s ] [ CPU TIME: 150663.938113 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 17.984550 GB ] [ VIRT MEM : 23.979427 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2208.493147 s ] [ CPU TIME: 150664.283938 s ] <<<<< .. + +* Energy of state 1 -193.4584294780728 +* S^2 of state 1 0.1272044267394022E-01 +* Saved determinants 81920 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 17.953865 GB ] [ VIRT MEM : 23.944187 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2210.463296 s ] [ CPU TIME: 150728.152621 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 17.953865 GB ] [ VIRT MEM : 23.944187 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2210.463896 s ] [ CPU TIME: 150728.195875 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 +* PT2 Energy denominator -193.4584294780728 + +.. >>>>> [ RES MEM : 17.976669 GB ] [ VIRT MEM : 23.964703 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2210.504923 s ] [ CPU TIME: 150731.141814 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 17.976669 GB ] [ VIRT MEM : 23.964703 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2210.505479 s ] [ CPU TIME: 150731.182216 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 +* Number of tasks 113556 +* Number of fragmented tasks 13781 +* Number of threads for PT2 72 +* Memory (Gb) 1.624943608045578 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7055811963 0.970E-03 1.4411868708 0.0461489437 377.4695 + 6 -193.7051253270 0.550E-03 1.4398638585 0.0460071550 400.7415 + 7 -193.7050259329 0.472E-03 1.4372388159 0.0460433854 431.0234 + 8 -193.7055557837 0.640E-03 1.4417665220 0.0461002664 494.5759 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 18.885056 GB ] [ VIRT MEM : 24.669495 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2748.782866 s ] [ CPU TIME: 189354.462233 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 18.885056 GB ] [ VIRT MEM : 24.669495 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2748.783429 s ] [ CPU TIME: 189354.502760 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7176923122916591 + +Summary at N_det = 81920 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.45842948 +# PT2 -0.24712631 0.00063969 +# rPT2 -0.23623577 0.00061150 +# +# E+PT2 -193.70555578 0.00063969 +# E+rPT2 -193.69466525 0.00061150 +# ============ ============================= + + N_det = 81920 + N_states = 1 + + * State 1 + < S^2 > = 1.272044267394022E-002 + E = -193.458429478073 + Variance = 1.44176652199540 + PT norm = 0.214709725873219 + PT2 = -0.247126305613393 + rPT2 = -0.236235773524359 + E+PT2 = -193.705555783686 +/- 6.396853006567326E-004 + E+rPT2 = -193.694665251597 +/- 6.114952086453062E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.396475666555 + Vee = 219.730554047208 + Vecp = 0.000000000000000E+000 + T = 193.317476265110 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2834 -193.72045574 + -0.3379 -193.72170577 + -0.3929 -193.72899688 + -0.4491 -193.73195903 + -0.5026 -193.73364952 + -0.5498 -193.73555011 + -0.5892 -193.73701487 + =========== =================== + +* Number of unique beta determinants 19039 +* Number of unique alpha determinants 19050 + +.. >>>>> [ RES MEM : 18.838943 GB ] [ VIRT MEM : 24.615845 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2751.501823 s ] [ CPU TIME: 189549.138864 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 163840 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.2941258959472179 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.4584301533 0.012720 0.900E-02 + 2 -193.4992481631 0.008360 0.319E-03 + 3 -193.4998510676 0.008198 0.732E-04 + 4 -193.4999213129 0.008278 0.273E-05 + 5 -193.4999279421 0.008315 0.330E-06 + 6 -193.4999285554 0.008320 0.240E-07 + 7 -193.4999286180 0.008322 0.226E-08 + 8 -193.4999286237 0.008322 0.201E-09 + 9 -193.4999286242 0.008322 0.183E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 19.038670 GB ] [ VIRT MEM : 24.832302 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2774.821431 s ] [ CPU TIME: 191208.662597 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 18.965473 GB ] [ VIRT MEM : 24.721455 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2774.834835 s ] [ CPU TIME: 191209.626416 s ] <<<<< .. + +* Energy of state 1 -193.4999286241959 +* S^2 of state 1 0.8321916771700327E-02 +* Saved determinants 163840 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 18.885540 GB ] [ VIRT MEM : 24.637463 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2778.544224 s ] [ CPU TIME: 191303.418772 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 18.885540 GB ] [ VIRT MEM : 24.637463 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2778.545002 s ] [ CPU TIME: 191303.475087 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 +* PT2 Energy denominator -193.4999286241959 + +.. >>>>> [ RES MEM : 18.892281 GB ] [ VIRT MEM : 24.645054 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2778.626957 s ] [ CPU TIME: 191309.360583 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 18.892281 GB ] [ VIRT MEM : 24.645054 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2778.627712 s ] [ CPU TIME: 191309.415499 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 +* Number of tasks 228199 +* Number of fragmented tasks 18112 +* Number of threads for PT2 72 +* Memory (Gb) 3.220474022626877 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7072859710 0.213E-02 1.2746761530 0.0366693986 469.3667 + 4 -193.7079657279 0.161E-02 1.2766141910 0.0368630167 491.3038 + 5 -193.7077686187 0.128E-02 1.2747419992 0.0368184723 596.2548 + 6 -193.7072560489 0.116E-02 1.2676138280 0.0368173751 667.8106 + 7 -193.7069894645 0.104E-02 1.2648241589 0.0368083151 735.3308 + 8 -193.7075466417 0.106E-02 1.2680095263 0.0369170694 822.3037 + 9 -193.7075213979 0.949E-03 1.2690794392 0.0368743081 874.9673 + 11 -193.7075862464 0.841E-03 1.2699709379 0.0368697027 880.2871 + 12 -193.7076907443 0.733E-03 1.2697213540 0.0369123456 970.3098 + 13 -193.7075672771 0.684E-03 1.2685951320 0.0368982278 988.7709 + 14 -193.7078941202 0.715E-03 1.2705035532 0.0369562010 1046.3568 + 15 -193.7074490638 0.804E-03 1.2670366528 0.0368943418 1090.9688 + 17 -193.7077025583 0.720E-03 1.2688121794 0.0369300130 1116.5227 + 18 -193.7076708945 0.679E-03 1.2684114465 0.0369323411 1155.6006 + 19 -193.7071871553 0.808E-03 1.2654267255 0.0368500418 1264.7227 + 20 -193.7071849198 0.759E-03 1.2657624594 0.0368414242 1305.3896 + 21 -193.7069987037 0.746E-03 1.2643206847 0.0368145180 1314.8721 + 23 -193.7067079911 0.722E-03 1.2616821691 0.0367953455 1382.1380 + 24 -193.7066416594 0.695E-03 1.2614728500 0.0367800874 1420.9783 + 25 -193.7065516935 0.672E-03 1.2606956456 0.0367696679 1430.2905 + 26 -193.7064921373 0.648E-03 1.2607307677 0.0367495036 1447.8566 + 27 -193.7064858221 0.624E-03 1.2609674334 0.0367376756 1598.7876 + 28 -193.7066197810 0.616E-03 1.2616963797 0.0367632089 1626.2396 + 29 -193.7066480826 0.558E-03 1.2621932252 0.0367545211 1651.2895 + 30 -193.7066829069 0.540E-03 1.2621633233 0.0367683525 1753.2676 + 32 -193.7067689851 0.509E-03 1.2632001773 0.0367702588 1845.9238 + 34 -193.7069254551 0.503E-03 1.2641214176 0.0367973053 1858.7706 + 35 -193.7068955968 0.490E-03 1.2637451786 0.0367974079 1875.8019 + 36 -193.7069602634 0.478E-03 1.2641138318 0.0368052169 1930.1716 + 37 -193.7069439209 0.465E-03 1.2638027082 0.0368088707 1955.6217 + 38 -193.7069957487 0.456E-03 1.2641700634 0.0368161603 1969.4542 + 39 -193.7069845803 0.444E-03 1.2639836664 0.0368193000 1989.3876 + 40 -193.7071193792 0.453E-03 1.2648867674 0.0368400233 2059.9158 + 41 -193.7072448908 0.438E-03 1.2660859198 0.0368486067 2109.9198 + 42 -193.7071564469 0.437E-03 1.2652084801 0.0368430690 2593.3527 + 58 -193.7070024479 0.323E-03 1.2643512091 0.0368194188 2639.6377 + 59 -193.7070223628 0.318E-03 1.2644797960 0.0368235573 2640.7049 + 61 -193.7069933557 0.309E-03 1.2643144487 0.0368180039 2682.7954 + 63 -193.7070041916 0.301E-03 1.2644076235 0.0368191012 2745.5047 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 20.532593 GB ] [ VIRT MEM : 25.733101 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5524.883338 s ] [ CPU TIME: 388360.571198 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 20.532593 GB ] [ VIRT MEM : 25.733101 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5524.884125 s ] [ CPU TIME: 388360.627355 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7627043703229196 + +Summary at N_det = 163840 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.49992862 +# PT2 -0.20711828 0.00029969 +# rPT2 -0.19976209 0.00028905 +# +# E+PT2 -193.70704691 0.00029969 +# E+rPT2 -193.69969072 0.00028905 +# ============ ============================= + + N_det = 163840 + N_states = 1 + + * State 1 + < S^2 > = 8.321916771700327E-003 + E = -193.499928624196 + Variance = 1.26474991932434 + PT norm = 0.191897768620307 + PT2 = -0.207118282453209 + rPT2 = -0.199762092613795 + E+PT2 = -193.707046906649 +/- 2.996916568600736E-004 + E+rPT2 = -193.699690716810 +/- 2.890475519793316E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.418816271207 + Vee = 219.677120785111 + Vecp = 0.000000000000000E+000 + T = 193.351750985736 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2362 -193.72721460 + -0.2834 -193.72365287 + -0.3379 -193.72314334 + -0.3929 -193.72756267 + -0.4491 -193.72997153 + -0.5026 -193.73157030 + -0.5498 -193.73329150 + =========== =================== + +* Number of unique beta determinants 37601 +* Number of unique alpha determinants 37553 + +.. >>>>> [ RES MEM : 20.553139 GB ] [ VIRT MEM : 25.745804 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5537.304581 s ] [ CPU TIME: 389241.895618 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 327680 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.5861166492104530 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.4999286950 0.008322 0.595E-02 + 2 -193.5299255648 0.005668 0.245E-03 + 3 -193.5305149055 0.005731 0.521E-04 + 4 -193.5305761580 0.005887 0.634E-05 + 5 -193.5305893481 0.005993 0.125E-05 + 6 -193.5305917012 0.006046 0.110E-06 + 7 -193.5305920112 0.006062 0.107E-07 + 8 -193.5305920404 0.006064 0.987E-09 + 9 -193.5305920432 0.006064 0.872E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 20.796627 GB ] [ VIRT MEM : 26.062202 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5641.532265 s ] [ CPU TIME: 396680.390300 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 20.503735 GB ] [ VIRT MEM : 25.694515 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5641.567583 s ] [ CPU TIME: 396682.927310 s ] <<<<< .. + +* Energy of state 1 -193.5305920431693 +* S^2 of state 1 0.6063920222345456E-02 +* Saved determinants 327680 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 20.445942 GB ] [ VIRT MEM : 25.632969 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5648.479992 s ] [ CPU TIME: 396827.925350 s ] <<<<< .. + +* Number of generators 327679 + +.. >>>>> [ RES MEM : 20.445942 GB ] [ VIRT MEM : 25.632969 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5648.481171 s ] [ CPU TIME: 396828.010351 s ] <<<<< .. + +* Number of selectors 327679 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 +* PT2 Energy denominator -193.5305920431693 + +.. >>>>> [ RES MEM : 20.542404 GB ] [ VIRT MEM : 25.732101 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5648.654603 s ] [ CPU TIME: 396840.465149 s ] <<<<< .. + +* Number of generators 327679 + +.. >>>>> [ RES MEM : 20.542404 GB ] [ VIRT MEM : 25.732101 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5648.655744 s ] [ CPU TIME: 396840.547094 s ] <<<<< .. + +* Number of selectors 327679 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 +* Number of tasks 438187 +* Number of fragmented tasks 21845 +* Number of threads for PT2 72 +* Memory (Gb) 6.411534824706614 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7093635561 0.140E-02 1.1347875719 0.0306284132 808.8254 + 4 -193.7086287061 0.124E-02 1.1254751055 0.0306440112 948.7926 + 5 -193.7082185923 0.108E-02 1.1240794915 0.0305217921 1021.6457 + 6 -193.7077351946 0.101E-02 1.1193068913 0.0304859744 1054.9384 + 7 -193.7064095566 0.155E-02 1.1089300194 0.0302956440 1195.2964 + 8 -193.7067557975 0.138E-02 1.1097698360 0.0303854389 1208.4529 + 9 -193.7074098571 0.135E-02 1.1138688700 0.0305006824 1378.4745 + 10 -193.7076971981 0.124E-02 1.1143976406 0.0305851228 1380.3154 + 11 -193.7074965793 0.114E-02 1.1135046892 0.0305371034 1441.5614 + 12 -193.7073860964 0.997E-03 1.1120590694 0.0305460253 1458.7114 + 13 -193.7073569608 0.915E-03 1.1114212446 0.0305467007 1561.9004 + 14 -193.7073943863 0.847E-03 1.1109636665 0.0305711000 1669.7904 + 15 -193.7073133180 0.792E-03 1.1104123451 0.0305665034 1794.4545 + 18 -193.7074027808 0.697E-03 1.1115852533 0.0305533849 1893.1094 + 19 -193.7072095205 0.687E-03 1.1100376963 0.0305305057 1991.6444 + 20 -193.7071990444 0.652E-03 1.1106061223 0.0305073754 2081.9070 + 22 -193.7074360051 0.614E-03 1.1129745708 0.0305228709 2176.5125 + 24 -193.7069986379 0.640E-03 1.1095161024 0.0304673794 2257.5551 + 25 -193.7069928359 0.613E-03 1.1094840253 0.0304625551 2294.6677 + 27 -193.7069660818 0.588E-03 1.1094503580 0.0304557119 2537.8483 + 28 -193.7069899555 0.553E-03 1.1089979683 0.0304788445 2571.0784 + 29 -193.7070997451 0.545E-03 1.1095810497 0.0305014048 2717.6065 + 32 -193.7070573894 0.521E-03 1.1096044113 0.0304860138 2809.1356 + 33 -193.7071643701 0.457E-03 1.1102001654 0.0305054829 2825.8894 + 34 -193.7070908434 0.450E-03 1.1096693797 0.0304949991 3517.9454 + 45 -193.7072129666 0.386E-03 1.1102444487 0.0305190408 3750.0814 + 49 -193.7071966048 0.372E-03 1.1103829725 0.0305137839 3771.6364 + 50 -193.7073291518 0.383E-03 1.1108212639 0.0305475535 3780.7254 + 51 -193.7073059240 0.376E-03 1.1106896552 0.0305435984 3837.3166 + 52 -193.7072677053 0.371E-03 1.1103068741 0.0305405416 3856.2334 + 53 -193.7072515394 0.364E-03 1.1102702476 0.0305355074 3888.6104 + 54 -193.7071617491 0.369E-03 1.1095724706 0.0305241897 3950.1996 + 55 -193.7071489105 0.353E-03 1.1096508640 0.0305182851 3966.3070 + 56 -193.7071899314 0.349E-03 1.1101182575 0.0305200277 3976.4435 + 57 -193.7071241995 0.349E-03 1.1095765156 0.0305110760 3978.1962 + 58 -193.7071162531 0.343E-03 1.1094048125 0.0305138343 4030.5593 + 59 -193.7071144063 0.338E-03 1.1093555009 0.0305144494 4159.7913 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 24.728565 GB ] [ VIRT MEM : 29.196243 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9809.799248 s ] [ CPU TIME: 695425.047445 s ] <<<<< .. + +* Number of generators 327679 + +.. >>>>> [ RES MEM : 24.728817 GB ] [ VIRT MEM : 29.196243 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9809.800405 s ] [ CPU TIME: 695425.130976 s ] <<<<< .. + +* Number of selectors 327679 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7970724948746984 + +Summary at N_det = 327680 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.53059204 +# PT2 -0.17649591 0.00032736 +# rPT2 -0.17127084 0.00031767 +# +# E+PT2 -193.70708795 0.00032736 +# E+rPT2 -193.70186288 0.00031767 +# ============ ============================= + + N_det = 327680 + N_states = 1 + + * State 1 + < S^2 > = 6.063920222345456E-003 + E = -193.530592043169 + Variance = 1.10928401513012 + PT norm = 0.174664394631411 + PT2 = -0.176495907353074 + rPT2 = -0.171270836489458 + E+PT2 = -193.707087950522 +/- 3.273573787859018E-004 + E+rPT2 = -193.701862879659 +/- 3.176661313936198E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.433195805928 + Vee = 219.631054607345 + Vecp = 0.000000000000000E+000 + T = 193.381533279249 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1998 -193.71492051 + -0.2362 -193.72141657 + -0.2834 -193.72167020 + -0.3379 -193.72199410 + -0.3929 -193.72551156 + -0.4491 -193.72774749 + -0.5026 -193.72934653 + =========== =================== + +* Number of unique beta determinants 74057 +* Number of unique alpha determinants 74081 + +.. >>>>> [ RES MEM : 24.600323 GB ] [ VIRT MEM : 29.059513 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9861.000494 s ] [ CPU TIME: 699082.333949 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 655360 +* Number of threads for diagonalization 72 +* Memory(Gb) 1.167593337595463 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.5305921379 0.006064 0.379E-02 + 2 -193.5508397511 0.004812 0.193E-03 + 3 -193.5513725823 0.004976 0.247E-04 + 4 -193.5514395721 0.005177 0.827E-05 + 5 -193.5514563196 0.005298 0.176E-05 + 6 -193.5514601766 0.005338 0.280E-06 + 7 -193.5514609610 0.005356 0.265E-07 + 8 -193.5514610486 0.005352 0.287E-08 + 9 -193.5514610571 0.005350 0.264E-09 + 10 -193.5514610580 0.005349 0.288E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 25.181633 GB ] [ VIRT MEM : 29.763130 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10356.352416 s ] [ CPU TIME: 734339.555044 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 24.566437 GB ] [ VIRT MEM : 29.029232 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10356.464967 s ] [ CPU TIME: 734347.106899 s ] <<<<< .. + +* Energy of state 1 -193.5514610580460 +* S^2 of state 1 0.5348786066280488E-02 +* Saved determinants 655360 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 24.451099 GB ] [ VIRT MEM : 28.909092 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10369.810956 s ] [ CPU TIME: 734582.244997 s ] <<<<< .. + +* Number of generators 655360 + +.. >>>>> [ RES MEM : 24.451099 GB ] [ VIRT MEM : 28.909092 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10369.812816 s ] [ CPU TIME: 734582.373891 s ] <<<<< .. + +* Number of selectors 655360 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 +* PT2 Energy denominator -193.5514610580460 + +.. >>>>> [ RES MEM : 24.665855 GB ] [ VIRT MEM : 29.126396 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10370.193368 s ] [ CPU TIME: 734609.550384 s ] <<<<< .. + +* Number of generators 655360 + +.. >>>>> [ RES MEM : 24.665855 GB ] [ VIRT MEM : 29.126396 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10370.195206 s ] [ CPU TIME: 734609.682941 s ] <<<<< .. + +* Number of selectors 655360 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 +* Number of tasks 878576 +* Number of fragmented tasks 24754 +* Number of threads for PT2 72 +* Memory (Gb) 12.79369328618050 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7097313425 0.280E-02 1.0084128906 0.0270044308 1298.2115 + 4 -193.7099136101 0.189E-02 1.0104572741 0.0270145311 1303.2767 + 5 -193.7100571003 0.157E-02 1.0132354923 0.0269939634 1874.3069 + 7 -193.7094140657 0.122E-02 1.0087934489 0.0268810956 1955.2255 + 8 -193.7097056891 0.110E-02 1.0134244395 0.0268698285 2147.0295 + 9 -193.7092215949 0.109E-02 1.0093804401 0.0268098019 2360.9872 + 11 -193.7092559410 0.898E-03 1.0106536242 0.0267922683 2369.0005 + 12 -193.7087286622 0.970E-03 1.0076312937 0.0266905252 2527.0315 + 13 -193.7082943145 0.995E-03 1.0045560853 0.0266236823 2850.7855 + 14 -193.7082244368 0.922E-03 1.0035792279 0.0266296891 2949.0506 + 17 -193.7084699911 0.781E-03 1.0048873907 0.0266839795 3067.3376 + 18 -193.7081795676 0.792E-03 1.0029244392 0.0266382440 3246.5735 + 19 -193.7080045093 0.769E-03 1.0025284700 0.0265901500 3332.7715 + 20 -193.7077709310 0.777E-03 1.0005284903 0.0265651223 3620.9765 + 24 -193.7076177738 0.689E-03 0.9990646784 0.0265531104 3909.9155 + 25 -193.7076506215 0.662E-03 0.9997144259 0.0265494214 3913.7535 + 27 -193.7076620219 0.648E-03 0.9997287034 0.0265493884 4113.5195 + 28 -193.7074984657 0.646E-03 0.9984014305 0.0265299680 5118.6465 + 36 -193.7079313914 0.566E-03 1.0015802511 0.0265930551 5129.6695 + 37 -193.7077718881 0.573E-03 1.0006099977 0.0265625351 5212.4745 + 38 -193.7078171751 0.560E-03 1.0009557449 0.0265681516 5286.0286 + 39 -193.7078529905 0.539E-03 1.0012874403 0.0265690373 5319.5544 + 40 -193.7077461308 0.536E-03 1.0007808385 0.0265475232 5475.0188 + 41 -193.7078048226 0.526E-03 1.0013282483 0.0265546150 5797.0045 + 42 -193.7078089352 0.513E-03 1.0011459113 0.0265590187 5810.5145 + 44 -193.7076848010 0.523E-03 1.0002658632 0.0265396249 5858.5747 + 45 -193.7076760085 0.511E-03 1.0000302752 0.0265417806 6018.6036 + 47 -193.7076065944 0.496E-03 0.9993110599 0.0265376891 6786.2667 + 58 -193.7076015111 0.420E-03 0.9982690321 0.0265590208 6803.1511 + 59 -193.7075775680 0.414E-03 0.9982055893 0.0265536331 6859.0835 + 60 -193.7075865184 0.407E-03 0.9982581353 0.0265536619 6885.6065 + 62 -193.7075914022 0.397E-03 0.9981159407 0.0265581871 6998.2276 + 63 -193.7076358483 0.389E-03 0.9987350159 0.0265525454 7256.3466 + 68 -193.7077021822 0.382E-03 0.9995222584 0.0265570840 7337.9325 + 69 -193.7076603613 0.379E-03 0.9993543752 0.0265479647 7347.5795 + 70 -193.7076322958 0.374E-03 0.9990439394 0.0265456151 7619.6705 + 71 -193.7077052886 0.365E-03 0.9995995253 0.0265552507 7784.2086 + 74 -193.7078283200 0.367E-03 1.0004313737 0.0265734740 7889.0716 + 77 -193.7079678257 0.366E-03 1.0013550260 0.0265959518 8090.2915 + 78 -193.7079394559 0.362E-03 1.0012102406 0.0265900859 8156.7025 + 80 -193.7080203078 0.359E-03 1.0017304548 0.0266034755 8236.2606 + 81 -193.7079086323 0.372E-03 1.0008144214 0.0265897496 8312.1805 + 84 -193.7078878680 0.361E-03 1.0006118937 0.0265876263 8534.2485 + 86 -193.7078873125 0.352E-03 1.0005789223 0.0265875732 8611.5227 + 89 -193.7077750890 0.353E-03 0.9996418876 0.0265747370 8675.0655 + 90 -193.7077437162 0.351E-03 0.9994486302 0.0265693388 8968.5625 + 94 -193.7077464097 0.343E-03 0.9992956627 0.0265736807 9059.2945 + 96 -193.7077619301 0.334E-03 0.9992630916 0.0265803511 9077.2446 + 97 -193.7077649439 0.331E-03 0.9991579924 0.0265828103 9093.0775 + 98 -193.7077801235 0.328E-03 0.9992341946 0.0265858073 9115.9415 + 100 -193.7078201817 0.328E-03 0.9993799977 0.0265941714 9164.6685 + 101 -193.7078176467 0.325E-03 0.9993052058 0.0265955499 9240.6116 + 102 -193.7078120647 0.321E-03 0.9993642562 0.0265923285 9284.4005 + 103 -193.7077943472 0.319E-03 0.9992847472 0.0265888004 9406.3316 + 104 -193.7078561220 0.311E-03 0.9995333540 0.0266029879 9476.6257 + 105 -193.7078845667 0.309E-03 0.9997200095 0.0266077731 9610.4182 + 108 -193.7079904782 0.308E-03 1.0006241163 0.0266210783 9626.8245 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 26.116852 GB ] [ VIRT MEM : 30.106174 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 19999.763360 s ] [ CPU TIME: 1425542.514090 s ] <<<<< .. + +* Number of generators 655360 + +.. >>>>> [ RES MEM : 26.116852 GB ] [ VIRT MEM : 30.106174 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 19999.765779 s ] [ CPU TIME: 1425542.684826 s ] <<<<< .. + +* Number of selectors 655360 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8197888572165002 + +Summary at N_det = 655360 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.55146106 +# PT2 -0.15653015 0.00030561 +# rPT2 -0.15247114 0.00029769 +# +# E+PT2 -193.70799120 0.00030561 +# E+rPT2 -193.70393220 0.00029769 +# ============ ============================= + + N_det = 655360 + N_states = 1 + + * State 1 + < S^2 > = 5.348786066280488E-003 + E = -193.551461058046 + Variance = 1.00060369584768 + PT norm = 0.163160898251033 + PT2 = -0.156530145234058 + rPT2 = -0.152471138076629 + E+PT2 = -193.707991203280 +/- 3.056125076036282E-004 + E+rPT2 = -193.703932196123 +/- 2.976876228863229E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.442648570488 + Vee = 219.595603006233 + Vecp = 0.000000000000000E+000 + T = 193.405568630044 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1713 -193.72071497 + -0.1998 -193.71728894 + -0.2362 -193.72059671 + -0.2834 -193.72109070 + -0.3379 -193.72151364 + -0.3929 -193.72439494 + -0.4491 -193.72639470 + =========== =================== + +* Number of unique beta determinants 146669 +* Number of unique alpha determinants 146402 + +.. >>>>> [ RES MEM : 26.177784 GB ] [ VIRT MEM : 30.230682 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 20170.940078 s ] [ CPU TIME: 1437446.988546 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 1310720 +* Number of threads for diagonalization 72 +* Memory(Gb) 2.329048655927181 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.5514610747 0.005349 0.259E-02 + 2 -193.5649145972 0.005304 0.218E-03 + 3 -193.5653862440 0.005644 0.420E-04 + 4 -193.5654851664 0.006022 0.173E-04 + 5 -193.5655175470 0.006282 0.180E-05 + 6 -193.5655231046 0.006408 0.349E-06 + 7 -193.5655241816 0.006438 0.729E-07 + 8 -193.5655243785 0.006432 0.840E-08 + 9 -193.5655244042 0.006430 0.873E-09 + 10 -193.5655244071 0.006429 0.111E-09 + 11 -193.5655244074 0.006429 0.122E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 27.187519 GB ] [ VIRT MEM : 31.401497 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 22009.646122 s ] [ CPU TIME: 1564897.230751 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 25.898533 GB ] [ VIRT MEM : 29.935177 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 22009.795061 s ] [ CPU TIME: 1564903.283159 s ] <<<<< .. + +* Energy of state 1 -193.5655244074364 +* S^2 of state 1 0.6428579963759977E-02 +* Saved determinants 1310720 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 25.665943 GB ] [ VIRT MEM : 29.697849 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 22035.932300 s ] [ CPU TIME: 1565329.915193 s ] <<<<< .. + +* Number of generators 1310714 + +.. >>>>> [ RES MEM : 25.665943 GB ] [ VIRT MEM : 29.697849 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 22035.935591 s ] [ CPU TIME: 1565330.151821 s ] <<<<< .. + +* Number of selectors 1310714 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 +* PT2 Energy denominator -193.5655244074364 + +.. >>>>> [ RES MEM : 26.017010 GB ] [ VIRT MEM : 30.050400 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 22036.831712 s ] [ CPU TIME: 1565384.996137 s ] <<<<< .. + +* Number of generators 1310714 + +.. >>>>> [ RES MEM : 26.017010 GB ] [ VIRT MEM : 30.050400 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 22036.834970 s ] [ CPU TIME: 1565385.230666 s ] <<<<< .. + +* Number of selectors 1310714 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 +* Number of tasks 1688332 +* Number of fragmented tasks 27138 +* Number of threads for PT2 72 +* Memory (Gb) 25.55800999246538 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7086441418 0.842E-03 0.9255711023 0.0240164244 2368.0289 + 4 -193.7082905116 0.685E-03 0.9232015475 0.0239771261 2534.0054 + 5 -193.7085496754 0.742E-03 0.9265531906 0.0239777014 2789.8720 + 6 -193.7083549745 0.614E-03 0.9283053478 0.0238884848 3098.7031 + 7 -193.7090638496 0.901E-03 0.9330861130 0.0239971411 3942.7303 + 8 -193.7090230332 0.771E-03 0.9338820274 0.0239654629 4273.2644 + 12 -193.7099089525 0.667E-03 0.9371632784 0.0241538223 4714.6900 + 14 -193.7098539409 0.744E-03 0.9368056007 0.0241521269 4878.7241 + 15 -193.7095985781 0.739E-03 0.9345826792 0.0241243797 5323.0563 + 18 -193.7098861288 0.721E-03 0.9355683946 0.0241929069 5703.0750 + 19 -193.7097587844 0.694E-03 0.9349961748 0.0241629973 5712.6310 + 20 -193.7097050343 0.701E-03 0.9343309281 0.0241600786 5765.8031 + 21 -193.7099009724 0.695E-03 0.9361273397 0.0241768651 6008.9730 + 22 -193.7100083252 0.671E-03 0.9370217847 0.0241853044 6055.3281 + 23 -193.7096709110 0.711E-03 0.9356481188 0.0241138580 6220.1410 + 24 -193.7098149423 0.696E-03 0.9370418794 0.0241276082 6635.1367 + 26 -193.7098428729 0.647E-03 0.9375067791 0.0241263030 6659.5353 + 27 -193.7098158819 0.623E-03 0.9370778220 0.0241235964 6848.2572 + 28 -193.7096523288 0.623E-03 0.9358466173 0.0240997293 7958.0981 + 30 -193.7096377177 0.638E-03 0.9357970860 0.0240953375 7989.4321 + 32 -193.7096681418 0.598E-03 0.9360771257 0.0240967476 8030.4481 + 33 -193.7097069182 0.581E-03 0.9368627317 0.0240933154 8223.1881 + 34 -193.7095960977 0.574E-03 0.9363161474 0.0240718366 8226.1730 + 35 -193.7097367276 0.533E-03 0.9366430429 0.0241058831 8309.2161 + 36 -193.7097249869 0.518E-03 0.9366619418 0.0241032946 8757.7565 + 39 -193.7097925419 0.492E-03 0.9365991420 0.0241249756 8766.9811 + 40 -193.7097536247 0.461E-03 0.9363236587 0.0241176821 9200.0411 + 41 -193.7097669357 0.450E-03 0.9364257407 0.0241206187 9851.6210 + 45 -193.7094766431 0.419E-03 0.9341092311 0.0240841353 9997.6051 + 47 -193.7092733970 0.426E-03 0.9326268975 0.0240533410 11029.1070 + 55 -193.7092586692 0.374E-03 0.9320931924 0.0240605139 11263.5111 + 57 -193.7092479599 0.371E-03 0.9321894837 0.0240548703 11329.7683 + 58 -193.7091709822 0.369E-03 0.9315880398 0.0240471690 11794.0451 + 62 -193.7091742861 0.352E-03 0.9315178985 0.0240518435 11967.6615 + 63 -193.7092312760 0.351E-03 0.9315820933 0.0240690793 12409.2361 + 69 -193.7092295434 0.349E-03 0.9312288484 0.0240737688 12505.2671 + 71 -193.7091370464 0.349E-03 0.9303658222 0.0240634099 12990.1512 + 74 -193.7092782078 0.342E-03 0.9310263792 0.0240935680 13078.8150 + 75 -193.7092299244 0.341E-03 0.9306401431 0.0240878187 13100.1103 + 77 -193.7092728067 0.343E-03 0.9310865087 0.0240896866 13288.3789 + 78 -193.7092608751 0.339E-03 0.9310214140 0.0240867677 13399.4390 + 79 -193.7092757059 0.335E-03 0.9311781412 0.0240869044 13647.8100 + 80 -193.7092858388 0.331E-03 0.9311566132 0.0240894000 13740.7202 + 82 -193.7092864555 0.319E-03 0.9310033209 0.0240934970 13778.7524 + 83 -193.7092498096 0.318E-03 0.9307164605 0.0240886777 13831.4948 + 84 -193.7092468612 0.314E-03 0.9307421051 0.0240877312 13970.2761 + 85 -193.7092319563 0.311E-03 0.9306107847 0.0240857483 13987.7601 + 86 -193.7091975499 0.309E-03 0.9302593476 0.0240838330 14424.8351 + 87 -193.7092570215 0.311E-03 0.9306039054 0.0240937309 14461.6906 + 90 -193.7092481404 0.301E-03 0.9306338587 0.0240915870 14479.9755 + 91 -193.7092801508 0.292E-03 0.9309359148 0.0240947717 14745.2141 + 92 -193.7093254188 0.292E-03 0.9312202382 0.0241016652 14785.0801 + 93 -193.7093163581 0.289E-03 0.9311018255 0.0241016998 14866.7421 + 95 -193.7093542404 0.286E-03 0.9314028032 0.0241070049 15022.0766 + 96 -193.7093376046 0.284E-03 0.9313278926 0.0241033455 15073.7093 + 97 -193.7093451962 0.281E-03 0.9313421199 0.0241055803 15246.3382 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 27.622200 GB ] [ VIRT MEM : 31.248005 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 37357.913844 s ] [ CPU TIME: 2664242.590393 s ] <<<<< .. + +* Number of generators 1310714 + +.. >>>>> [ RES MEM : 27.622200 GB ] [ VIRT MEM : 31.248005 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 37357.917111 s ] [ CPU TIME: 2664242.822156 s ] <<<<< .. + +* Number of selectors 1310714 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8344771826657953 + +Summary at N_det = 1310720 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.56552441 +# PT2 -0.14375134 0.00028659 +# rPT2 -0.14036831 0.00027984 +# +# E+PT2 -193.70927575 0.00028659 +# E+rPT2 -193.70589271 0.00027984 +# ============ ============================= + + N_det = 1310720 + N_states = 1 + + * State 1 + < S^2 > = 6.428579963759977E-003 + E = -193.565524407436 + Variance = 0.930577008807010 + PT norm = 0.155245449399272 + PT2 = -0.143751342736966 + rPT2 = -0.140368305219502 + E+PT2 = -193.709275750173 +/- 2.865884556212285E-004 + E+rPT2 = -193.705892712656 +/- 2.798438960297904E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.445723869372 + Vee = 219.568039410217 + Vecp = 0.000000000000000E+000 + T = 193.422144175554 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1525 -193.72863073 + -0.1713 -193.72379777 + -0.1998 -193.71974990 + -0.2362 -193.72128148 + -0.2834 -193.72144329 + -0.3379 -193.72169376 + -0.3929 -193.72405954 + =========== =================== + +* Number of unique beta determinants 281731 +* Number of unique alpha determinants 280480 + +.. >>>>> [ RES MEM : 27.855385 GB ] [ VIRT MEM : 31.726898 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 37841.158026 s ] [ CPU TIME: 2696817.224670 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 2621440 +* Number of threads for diagonalization 72 +* Memory(Gb) 4.611229822039604 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.5655244177 0.006429 0.187E-02 + 2 -193.5749055504 0.007093 0.210E-03 + 3 -193.5752335837 0.007467 0.442E-04 + 4 -193.5753302349 0.007897 0.136E-04 + 5 -193.5753655586 0.008245 0.203E-05 + 6 -193.5753720411 0.008442 0.422E-06 + 7 -193.5753737142 0.008518 0.103E-06 + 8 -193.5753740059 0.008517 0.139E-07 + 9 -193.5753740464 0.008518 0.168E-08 + 10 -193.5753740517 0.008516 0.208E-09 + 11 -193.5753740525 0.008516 0.285E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 31.008263 GB ] [ VIRT MEM : 35.213757 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 43157.608839 s ] [ CPU TIME: 3054761.968165 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 28.430367 GB ] [ VIRT MEM : 32.282593 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 43157.925293 s ] [ CPU TIME: 3054768.184885 s ] <<<<< .. + +* Energy of state 1 -193.5753740524566 +* S^2 of state 1 0.8515629183348101E-02 +* Saved determinants 2621440 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 27.366833 GB ] [ VIRT MEM : 31.006386 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 43208.983208 s ] [ CPU TIME: 3055545.418388 s ] <<<<< .. + +* Number of generators 2621404 + +.. >>>>> [ RES MEM : 27.366833 GB ] [ VIRT MEM : 31.006386 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 43208.989342 s ] [ CPU TIME: 3055545.859173 s ] <<<<< .. + +* Number of selectors 2621404 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 +* PT2 Energy denominator -193.5753740524566 + +.. >>>>> [ RES MEM : 28.137043 GB ] [ VIRT MEM : 31.778378 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 43211.103794 s ] [ CPU TIME: 3055643.987317 s ] <<<<< .. + +* Number of generators 2621404 + +.. >>>>> [ RES MEM : 28.137043 GB ] [ VIRT MEM : 31.778378 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 43211.109651 s ] [ CPU TIME: 3055644.143888 s ] <<<<< .. + +* Number of selectors 2621404 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 +* Number of tasks 3274208 +* Number of fragmented tasks 29079 +* Number of threads for PT2 72 +* Memory (Gb) 51.08660614147782 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7115068489 0.340E-02 0.8965476943 0.0223879005 4278.5432 + 4 -193.7110652984 0.233E-02 0.8929581354 0.0223841226 5591.7274 + 7 -193.7113754292 0.134E-02 0.8929763756 0.0224599334 6071.9093 + 8 -193.7114087440 0.118E-02 0.8952232210 0.0224091155 6756.5642 + 9 -193.7116562948 0.107E-02 0.8955877006 0.0224779973 9390.4436 + 18 -193.7111887033 0.807E-03 0.8914782435 0.0224162834 9411.4353 + 19 -193.7109282517 0.790E-03 0.8897048682 0.0223804250 9760.4443 + 20 -193.7106537441 0.799E-03 0.8883482834 0.0223243202 10283.4544 + 22 -193.7103932489 0.759E-03 0.8872748800 0.0222677316 10467.4862 + 23 -193.7102294172 0.775E-03 0.8858480490 0.0222541914 10735.0240 + 24 -193.7102559227 0.742E-03 0.8857699205 0.0222590986 10871.4773 + 25 -193.7101272633 0.723E-03 0.8857168187 0.0222210239 11022.2802 + 26 -193.7102254236 0.702E-03 0.8867847628 0.0222261785 11235.8104 + 27 -193.7101143985 0.684E-03 0.8861417228 0.0222086027 11926.7305 + 28 -193.7104425840 0.738E-03 0.8881314055 0.0222655150 12242.4012 + 29 -193.7106494701 0.732E-03 0.8897313710 0.0222916061 12350.9433 + 30 -193.7106482993 0.707E-03 0.8891300361 0.0223064896 12896.9333 + 31 -193.7107758616 0.696E-03 0.8903158682 0.0223200774 12916.4745 + 32 -193.7109035029 0.686E-03 0.8913908413 0.0223373485 13572.9552 + 33 -193.7107928452 0.674E-03 0.8907393506 0.0223145917 13646.0609 + 34 -193.7107589975 0.643E-03 0.8905290329 0.0223109731 14483.4004 + 36 -193.7109245774 0.630E-03 0.8908225929 0.0223527937 14675.5891 + 37 -193.7111409435 0.650E-03 0.8921844406 0.0223896474 14810.2262 + 39 -193.7110992438 0.621E-03 0.8917232672 0.0223858113 15236.8623 + 40 -193.7110858070 0.605E-03 0.8917908733 0.0223809498 15440.8683 + 41 -193.7110404032 0.592E-03 0.8911601912 0.0223819426 15873.3263 + 42 -193.7109362509 0.587E-03 0.8905655011 0.0223631715 17167.6233 + 47 -193.7110640068 0.528E-03 0.8923968564 0.0223654643 17299.0303 + 48 -193.7111236363 0.521E-03 0.8926560086 0.0223801012 17452.6016 + 49 -193.7111475267 0.510E-03 0.8930941604 0.0223792702 17639.1093 + 50 -193.7111422093 0.500E-03 0.8931631727 0.0223786576 18269.3733 + 52 -193.7110598146 0.472E-03 0.8927919171 0.0223607192 18277.0504 + 53 -193.7109879463 0.468E-03 0.8923539528 0.0223482903 18369.2876 + 54 -193.7110423224 0.463E-03 0.8927050402 0.0223566592 18740.7111 + 55 -193.7110739170 0.455E-03 0.8931104595 0.0223570122 19172.6506 + 57 -193.7109988508 0.461E-03 0.8926961794 0.0223434328 19686.7484 + 60 -193.7110317845 0.441E-03 0.8925818754 0.0223559767 19747.6173 + 61 -193.7109015799 0.453E-03 0.8917432624 0.0223353289 19819.3192 + 62 -193.7109035948 0.445E-03 0.8920486917 0.0223286260 20174.2914 + 63 -193.7109627378 0.442E-03 0.8926090913 0.0223348800 20197.0193 + 64 -193.7109680760 0.415E-03 0.8927496143 0.0223348763 21663.2298 + 73 -193.7110183358 0.365E-03 0.8925270810 0.0223505468 21849.5612 + 74 -193.7110011263 0.361E-03 0.8925883628 0.0223444595 21856.2352 + 75 -193.7110407404 0.358E-03 0.8928035815 0.0223516885 21870.1642 + 76 -193.7110397682 0.353E-03 0.8928900488 0.0223495089 22140.6482 + 77 -193.7109806935 0.354E-03 0.8924830908 0.0223407613 22600.4263 + 78 -193.7109757204 0.349E-03 0.8924492480 0.0223403769 22899.6341 + 79 -193.7109533237 0.345E-03 0.8924093835 0.0223346738 23951.9918 + 86 -193.7109641877 0.328E-03 0.8923329075 0.0223414020 24009.6373 + 87 -193.7110178108 0.329E-03 0.8926304060 0.0223511982 24444.7254 + 88 -193.7110068221 0.325E-03 0.8926747261 0.0223479805 24975.8014 + 90 -193.7110948349 0.323E-03 0.8929724114 0.0223686865 25053.6504 + 91 -193.7111158490 0.321E-03 0.8932303521 0.0223699751 25347.9523 + 94 -193.7110602091 0.314E-03 0.8926551263 0.0223662387 26096.2003 + 101 -193.7109934264 0.294E-03 0.8919804359 0.0223593203 26173.2878 + 103 -193.7109600492 0.290E-03 0.8916759828 0.0223570847 26558.3993 + 104 -193.7109210630 0.289E-03 0.8915165014 0.0223487862 26931.0761 + 105 -193.7109057476 0.287E-03 0.8913373233 0.0223479292 27001.5223 + 106 -193.7108865960 0.285E-03 0.8912375401 0.0223438849 27438.6143 + 108 -193.7109090120 0.282E-03 0.8912779352 0.0223486892 27868.1514 + 112 -193.7109105150 0.274E-03 0.8913561465 0.0223468806 28503.6573 + 117 -193.7108312164 0.267E-03 0.8909123232 0.0223334102 29234.1394 + 118 -193.7108209112 0.265E-03 0.8908281887 0.0223320062 29247.1336 + 121 -193.7107529965 0.261E-03 0.8904782661 0.0223192437 29408.4079 + 123 -193.7106755034 0.265E-03 0.8900462625 0.0223055361 29592.0080 + 125 -193.7106384363 0.264E-03 0.8897429343 0.0223003863 29655.4968 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 35.854828 GB ] [ VIRT MEM : 39.407784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 72877.894258 s ] [ CPU TIME: 5183359.788429 s ] <<<<< .. + +* Number of generators 2621404 + +.. >>>>> [ RES MEM : 35.854828 GB ] [ VIRT MEM : 39.407784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 72877.900847 s ] [ CPU TIME: 5183360.261211 s ] <<<<< .. + +* Number of selectors 2621404 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8443047291384095 + +Summary at N_det = 2621440 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.57537405 +# PT2 -0.13526438 0.00026412 +# rPT2 -0.13231374 0.00025836 +# +# E+PT2 -193.71063844 0.00026412 +# E+rPT2 -193.70768779 0.00025836 +# ============ ============================= + + N_det = 2621440 + N_states = 1 + + * State 1 + < S^2 > = 8.515629183348101E-003 + E = -193.575374052457 + Variance = 0.889742934324410 + PT norm = 0.149333138779825 + PT2 = -0.135264383872800 + rPT2 = -0.132313736432552 + E+PT2 = -193.710638436329 +/- 2.641232025706465E-004 + E+rPT2 = -193.707687788889 +/- 2.583616382233891E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.450438622711 + Vee = 219.547032690227 + Vecp = 0.000000000000000E+000 + T = 193.438016003862 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1404 -193.73717580 + -0.1525 -193.73196802 + -0.1713 -193.72667665 + -0.1998 -193.72211518 + -0.2362 -193.72248464 + -0.2834 -193.72224089 + -0.3379 -193.72225291 + =========== =================== + +* Number of unique beta determinants 509794 +* Number of unique alpha determinants 515480 + +.. >>>>> [ RES MEM : 36.469040 GB ] [ VIRT MEM : 40.790939 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 74166.018089 s ] [ CPU TIME: 5268987.149442 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5242880 +* Number of threads for diagonalization 72 +* Memory(Gb) 9.029108617454767 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.5753740552 0.008516 0.152E-02 + 2 -193.5827749103 0.009296 0.159E-03 + 3 -193.5829851102 0.009428 0.253E-04 + 4 -193.5830398853 0.009572 0.429E-05 + 5 -193.5830539458 0.009712 0.960E-06 + 6 -193.5830568263 0.009809 0.179E-06 + 7 -193.5830574475 0.009864 0.403E-07 + 8 -193.5830575613 0.009901 0.874E-08 + 9 -193.5830575888 0.009929 0.147E-08 + 10 -193.5830575944 0.009939 0.208E-09 + 11 -193.5830575952 0.009942 0.309E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 41.926342 GB ] [ VIRT MEM : 46.957138 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 88458.996133 s ] [ CPU TIME: 6218848.210172 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 36.613991 GB ] [ VIRT MEM : 40.939545 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 88459.597082 s ] [ CPU TIME: 6218854.807913 s ] <<<<< .. + +* Energy of state 1 -193.5830575951782 +* S^2 of state 1 0.9941986912629614E-02 +* Saved determinants 5242880 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 35.638531 GB ] [ VIRT MEM : 39.438747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 88562.729536 s ] [ CPU TIME: 6220341.815992 s ] <<<<< .. + +* Number of generators 5242643 + +.. >>>>> [ RES MEM : 35.638531 GB ] [ VIRT MEM : 39.438747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 88562.741293 s ] [ CPU TIME: 6220342.637212 s ] <<<<< .. + +* Number of selectors 5242643 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 +* PT2 Energy denominator -193.5830575951782 + +.. >>>>> [ RES MEM : 37.179905 GB ] [ VIRT MEM : 40.980259 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 88567.110784 s ] [ CPU TIME: 6220511.587774 s ] <<<<< .. + +* Number of generators 5242643 + +.. >>>>> [ RES MEM : 37.179905 GB ] [ VIRT MEM : 40.980259 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 88567.121984 s ] [ CPU TIME: 6220511.598888 s ] <<<<< .. + +* Number of selectors 5242643 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 +* Number of tasks 6322826 +* Number of fragmented tasks 30455 +* Number of threads for PT2 72 +* Memory (Gb) 102.1437946208194 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7139246823 0.317E-03 0.8705488470 0.0213840756 6103.2399 + 4 -193.7130288984 0.100E-02 0.8671386679 0.0211447509 6881.4312 + 5 -193.7137797363 0.109E-02 0.8715347006 0.0212710157 7965.8071 + 6 -193.7146637750 0.129E-02 0.8763493473 0.0214398148 8939.7478 + 7 -193.7141746955 0.119E-02 0.8708922211 0.0214112235 9115.9165 + 8 -193.7141578902 0.999E-03 0.8705970984 0.0214184263 10287.4700 + 9 -193.7132643413 0.127E-02 0.8652246505 0.0212557180 11061.5980 + 10 -193.7125377473 0.136E-02 0.8594619418 0.0211522672 11209.2860 + 11 -193.7122317539 0.121E-02 0.8579308977 0.0210884283 11525.1460 + 12 -193.7123627455 0.111E-02 0.8596353929 0.0210932831 12468.4449 + 13 -193.7121419162 0.104E-02 0.8588086080 0.0210428115 12698.0901 + 14 -193.7121180793 0.966E-03 0.8589334208 0.0210276756 13804.5439 + 15 -193.7122775903 0.913E-03 0.8596806821 0.0210585864 14283.0510 + 16 -193.7118583183 0.928E-03 0.8568747842 0.0209935209 15613.8011 + 19 -193.7119866968 0.762E-03 0.8578720562 0.0210024466 15991.8681 + 20 -193.7121781194 0.748E-03 0.8592402478 0.0210333948 17445.0635 + 23 -193.7122568400 0.694E-03 0.8587349621 0.0210648151 17446.1850 + 24 -193.7119747773 0.723E-03 0.8566346972 0.0210251899 18217.0898 + 25 -193.7118401089 0.706E-03 0.8560904685 0.0209956820 18604.2771 + 27 -193.7120173711 0.675E-03 0.8567964847 0.0210324668 19763.6800 + 28 -193.7118460345 0.672E-03 0.8556788454 0.0210039754 20500.9150 + 29 -193.7120705361 0.687E-03 0.8569298045 0.0210437229 21369.2680 + 30 -193.7120508750 0.664E-03 0.8569037903 0.0210370938 21460.2090 + 32 -193.7116677780 0.736E-03 0.8540384766 0.0209822540 22242.0408 + 33 -193.7119159699 0.765E-03 0.8560283526 0.0210122398 22699.5058 + 34 -193.7117818416 0.754E-03 0.8552585302 0.0209870318 23836.0889 + 35 -193.7119593508 0.754E-03 0.8563528735 0.0210163995 24050.9790 + 37 -193.7121287476 0.764E-03 0.8574470325 0.0210398200 24284.7670 + 39 -193.7122653973 0.750E-03 0.8582215851 0.0210668431 24640.3300 + 40 -193.7121651486 0.737E-03 0.8575782372 0.0210515699 25236.9408 + 41 -193.7122639842 0.726E-03 0.8581408947 0.0210674522 26242.0479 + 43 -193.7121603674 0.709E-03 0.8577306936 0.0210467290 28173.8640 + 47 -193.7119064830 0.688E-03 0.8563599346 0.0209985846 28499.8825 + 48 -193.7119568194 0.676E-03 0.8567950404 0.0210068653 28605.3320 + 49 -193.7119823078 0.662E-03 0.8571074369 0.0210064723 28669.1510 + 50 -193.7121220882 0.657E-03 0.8580156763 0.0210275759 29354.7130 + 51 -193.7121970171 0.649E-03 0.8587921270 0.0210342610 29741.4544 + 52 -193.7121432317 0.638E-03 0.8586256148 0.0210216535 29996.4720 + 53 -193.7120951976 0.628E-03 0.8580847042 0.0210178999 30272.2449 + 54 -193.7120817175 0.616E-03 0.8581675977 0.0210130004 30890.2006 + 56 -193.7120691876 0.636E-03 0.8575038547 0.0210246123 31079.0850 + 57 -193.7120005518 0.628E-03 0.8569878499 0.0210144494 31704.1252 + 58 -193.7119316068 0.621E-03 0.8567042591 0.0210007864 31744.5500 + 59 -193.7118914323 0.612E-03 0.8564401426 0.0209936058 32298.9890 + 61 -193.7118681604 0.597E-03 0.8563090810 0.0209898599 33435.1611 + 64 -193.7117185614 0.571E-03 0.8555193047 0.0209581842 33959.4690 + 69 -193.7115734352 0.549E-03 0.8543772539 0.0209399630 34662.9398 + 70 -193.7116281712 0.544E-03 0.8546617083 0.0209493177 34982.2970 + 71 -193.7116235026 0.536E-03 0.8545981456 0.0209493760 35215.0611 + 72 -193.7116067925 0.534E-03 0.8545357984 0.0209471372 35349.8381 + 74 -193.7115476296 0.522E-03 0.8542614659 0.0209361671 35671.6772 + 75 -193.7115462127 0.515E-03 0.8542751699 0.0209353335 37418.4400 + 80 -193.7114353855 0.491E-03 0.8533365723 0.0209214683 37840.3710 + 82 -193.7114903947 0.484E-03 0.8538463542 0.0209269603 38359.2610 + 84 -193.7114993559 0.472E-03 0.8538036659 0.0209294872 38368.8864 + 85 -193.7114441109 0.470E-03 0.8534512029 0.0209206442 38472.9786 + 86 -193.7114171863 0.465E-03 0.8532980387 0.0209156287 39251.1507 + 87 -193.7114215687 0.460E-03 0.8533629790 0.0209163675 39451.4647 + 88 -193.7114869735 0.459E-03 0.8537190167 0.0209289558 40286.1242 + 91 -193.7116184292 0.448E-03 0.8549242312 0.0209427268 40617.8100 + 93 -193.7116575700 0.439E-03 0.8552357184 0.0209479071 40948.8413 + 95 -193.7116660127 0.428E-03 0.8551967488 0.0209511373 41138.3140 + 96 -193.7117029881 0.425E-03 0.8554883873 0.0209559782 41737.2850 + 97 -193.7116669696 0.422E-03 0.8553322938 0.0209485082 41875.4910 + 98 -193.7117220014 0.422E-03 0.8555234068 0.0209604907 42195.3570 + 101 -193.7117003783 0.415E-03 0.8552597475 0.0209593681 42406.8235 + 102 -193.7117151839 0.412E-03 0.8553566286 0.0209618547 42498.4640 + 103 -193.7117199511 0.408E-03 0.8553602588 0.0209632333 43017.6989 + 104 -193.7116773631 0.406E-03 0.8550976707 0.0209562457 43273.9769 + 105 -193.7117302406 0.405E-03 0.8554503953 0.0209643872 43551.6790 + 106 -193.7117541420 0.403E-03 0.8555340806 0.0209697799 44278.7011 + 108 -193.7117846570 0.396E-03 0.8558083383 0.0209728302 45693.3508 + 116 -193.7115958336 0.381E-03 0.8543742457 0.0209460411 46315.0477 + 117 -193.7115795598 0.378E-03 0.8543402363 0.0209418946 46460.7270 + 120 -193.7116060555 0.370E-03 0.8545541571 0.0209447611 46943.0230 + 121 -193.7115274913 0.372E-03 0.8540795383 0.0209313642 47299.3558 + 123 -193.7115015086 0.367E-03 0.8538656725 0.0209284011 47516.6454 + 124 -193.7115356599 0.365E-03 0.8541622453 0.0209322706 47575.5871 + 125 -193.7115515783 0.363E-03 0.8542397200 0.0209351419 48787.0238 + 128 -193.7115509454 0.362E-03 0.8542337954 0.0209356808 49337.4050 + 129 -193.7116257386 0.367E-03 0.8547917428 0.0209467362 50044.1192 + 134 -193.7117247700 0.356E-03 0.8555521068 0.0209599289 50482.1960 + 136 -193.7117432089 0.353E-03 0.8557914348 0.0209613836 50728.7731 + 137 -193.7116884940 0.355E-03 0.8554596538 0.0209523612 50848.7212 + 138 -193.7116997525 0.352E-03 0.8555573575 0.0209535068 51069.5680 + 140 -193.7117280889 0.352E-03 0.8557764517 0.0209570769 51860.9118 + 143 -193.7116725982 0.347E-03 0.8554644742 0.0209470156 52342.5113 + 145 -193.7116401940 0.344E-03 0.8553235387 0.0209390814 54400.9453 + 150 -193.7115557139 0.338E-03 0.8547046546 0.0209269500 54965.2313 + 156 -193.7116028527 0.328E-03 0.8554081784 0.0209272731 55151.6571 + 157 -193.7116538687 0.329E-03 0.8557812835 0.0209345021 55578.1110 + 158 -193.7116502981 0.327E-03 0.8557878599 0.0209341078 55665.9682 + 159 -193.7116346656 0.326E-03 0.8556886422 0.0209317478 56229.0277 + 160 -193.7116168892 0.324E-03 0.8555024294 0.0209300536 56287.2061 + 161 -193.7116159362 0.322E-03 0.8554904877 0.0209298939 56952.9261 + 164 -193.7117170244 0.322E-03 0.8561796513 0.0209453604 57091.9820 + 165 -193.7116959224 0.321E-03 0.8560450018 0.0209419627 57158.3160 + 166 -193.7116994588 0.319E-03 0.8561229587 0.0209416820 57386.7311 + 167 -193.7116686845 0.319E-03 0.8559576151 0.0209363168 57568.5981 + 168 -193.7116415814 0.318E-03 0.8557640451 0.0209326534 58016.3810 + 169 -193.7116767137 0.318E-03 0.8560268168 0.0209374062 58410.8600 + 172 -193.7117146833 0.317E-03 0.8561338090 0.0209463193 58743.4033 + 174 -193.7116913475 0.314E-03 0.8560375205 0.0209423766 59118.6660 + 176 -193.7117545849 0.314E-03 0.8564203726 0.0209535107 59418.1690 + 177 -193.7117547293 0.312E-03 0.8564304118 0.0209532327 59858.5050 + 178 -193.7117602236 0.311E-03 0.8565487686 0.0209524197 59937.1639 + 179 -193.7117220654 0.311E-03 0.8563669939 0.0209455147 60190.3402 + 181 -193.7116983377 0.308E-03 0.8561921512 0.0209420033 60597.2594 + 182 -193.7117269413 0.309E-03 0.8563352621 0.0209479886 60824.0280 + 183 -193.7117152676 0.307E-03 0.8562706745 0.0209459112 61088.4150 + 187 -193.7117189349 0.301E-03 0.8563272602 0.0209458983 61686.5853 + 191 -193.7116795309 0.291E-03 0.8560212209 0.0209400511 61869.9400 + 192 -193.7116732740 0.290E-03 0.8559964216 0.0209389921 61886.8620 + 193 -193.7116790797 0.288E-03 0.8560841495 0.0209389732 62290.5742 + 194 -193.7116687451 0.287E-03 0.8560476356 0.0209367894 62818.1693 + 197 -193.7117055580 0.283E-03 0.8562698521 0.0209422893 62879.1482 + 198 -193.7117097986 0.282E-03 0.8563618814 0.0209416277 63580.4385 + 201 -193.7117184847 0.278E-03 0.8565449744 0.0209407871 63840.2480 + 203 -193.7117592446 0.273E-03 0.8568639766 0.0209469691 63920.1181 + 205 -193.7117810878 0.272E-03 0.8570355520 0.0209499901 64251.8958 + 206 -193.7117766494 0.270E-03 0.8570495932 0.0209488151 64583.7180 + 207 -193.7117574332 0.270E-03 0.8569518030 0.0209450702 64650.4990 + 210 -193.7117410956 0.268E-03 0.8567854018 0.0209433757 64738.1020 + 212 -193.7116992436 0.263E-03 0.8564853357 0.0209375428 65296.6843 + 215 -193.7116560006 0.260E-03 0.8561897045 0.0209303768 65580.5420 + 216 -193.7116634679 0.259E-03 0.8562375896 0.0209317657 65857.0131 + 217 -193.7116750774 0.258E-03 0.8563405045 0.0209329800 65918.4180 + 218 -193.7116885687 0.257E-03 0.8564125681 0.0209358869 66568.7202 + 219 -193.7116808400 0.256E-03 0.8563801034 0.0209345647 66831.8365 + 220 -193.7116957334 0.256E-03 0.8564585981 0.0209372562 66853.3594 + 224 -193.7116708007 0.250E-03 0.8563638303 0.0209309424 67326.5000 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 36.557331 GB ] [ VIRT MEM : 40.405201 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 155917.464871 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 5242643 + +.. >>>>> [ RES MEM : 36.557331 GB ] [ VIRT MEM : 40.405201 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 155917.477001 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 5242643 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8519976728183842 + +Summary at N_det = 5242880 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -193.58305760 +# PT2 -0.12861187 0.00024887 +# rPT2 -0.12597513 0.00024376 +# +# E+PT2 -193.71166947 0.00024887 +# E+rPT2 -193.70903273 0.00024376 +# ============ ============================= + + N_det = 5242880 + N_states = 1 + + * State 1 + < S^2 > = 9.941986912629614E-003 + E = -193.583057595178 + Variance = 0.856343618923676 + PT norm = 0.144674192467506 + PT2 = -0.128611872770227 + rPT2 = -0.125975134845641 + E+PT2 = -193.711669467948 +/- 2.488651031124780E-004 + E+rPT2 = -193.709032730024 +/- 2.437629920760037E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 156.890015876165 + Ven = -763.456593318682 + Vee = 219.530778059581 + Vecp = 0.000000000000000E+000 + T = 193.452741787758 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1323 -193.73576247 + -0.1404 -193.73655580 + -0.1525 -193.73325568 + -0.1713 -193.72850035 + -0.1998 -193.72389894 + -0.2362 -193.72357659 + -0.2834 -193.72303467 + =========== =================== + +* Number of unique beta determinants 950231 +* Number of unique alpha determinants 869949 + +.. >>>>> [ RES MEM : 38.933125 GB ] [ VIRT MEM : 44.542698 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 159176.483162 s ] [ CPU TIME: ************** s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 10485760 +* Number of threads for diagonalization 72 +* Memory(Gb) 17.73299276828766 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -193.5830575967 0.009942 0.124E-02 + 2 -193.5890761706 0.011081 0.104E-03 + 3 -193.5892158765 0.011038 0.154E-04 + 4 -193.5892431465 0.010996 0.103E-05 + 5 -193.5892470123 0.010931 0.201E-06 + 6 -193.5892476228 0.010878 0.482E-07 + 7 -193.5892477669 0.010841 0.148E-07 + 8 -193.5892478069 0.010826 0.321E-08 + 9 -193.5892478160 0.010826 0.730E-09 + 10 -193.5892478184 0.010828 0.152E-09 + 11 -193.5892478189 0.010830 0.287E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 50.363117 GB ] [ VIRT MEM : 57.383018 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 195028.002698 s ] [ CPU TIME: ************** s ] <<<<< .. + + +.. >>>>> [ RES MEM : 39.738220 GB ] [ VIRT MEM : 45.349800 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 195029.204377 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Energy of state 1 -193.5892478188823 +* S^2 of state 1 0.1083019847051782E-01 +* Saved determinants 10485760 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 38.133278 GB ] [ VIRT MEM : 42.563847 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 195245.257021 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 10484955 + +.. >>>>> [ RES MEM : 38.133278 GB ] [ VIRT MEM : 42.563847 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 195245.280056 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 10484955 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -193.5892478188823 + +.. >>>>> [ RES MEM : 41.257523 GB ] [ VIRT MEM : 45.688866 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 195254.428061 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 10484955 + +.. >>>>> [ RES MEM : 41.257523 GB ] [ VIRT MEM : 45.688866 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 195254.450081 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 10484955 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 11749581 +* Number of fragmented tasks 30778 +* Number of threads for PT2 72 +* Memory (Gb) 204.2430521206930 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -193.7113363101 0.168E-02 0.8252617217 0.0195505824 8411.1225 + 4 -193.7119923422 0.134E-02 0.8286520256 0.0196776025 9701.3231 + 5 -193.7132948971 0.177E-02 0.8396790475 0.0198309617 11095.7702 + 6 -193.7132818742 0.145E-02 0.8388214332 0.0198497521 12490.9401 + 7 -193.7126647149 0.137E-02 0.8347604545 0.0197521187 13446.3202 + 8 -193.7120289259 0.136E-02 0.8287405076 0.0196858497 14904.7791 + 9 -193.7115898446 0.128E-02 0.8249449291 0.0196335517 16375.6862 + 10 -193.7110968106 0.125E-02 0.8211108804 0.0195739724 16635.2753 + 11 -193.7110097989 0.114E-02 0.8205902363 0.0195536368 17213.1233 + 12 -193.7112812233 0.107E-02 0.8226726329 0.0195818502 18074.2584 + 13 -193.7110432196 0.101E-02 0.8208870974 0.0195522814 19873.9011 + 15 -193.7116224711 0.901E-03 0.8246194774 0.0196472986 21388.6520 + 16 -193.7116348332 0.842E-03 0.8247827855 0.0196506965 21803.7092 + 17 -193.7116250776 0.790E-03 0.8250533154 0.0196425133 21873.8056 + 18 -193.7116478528 0.727E-03 0.8261363755 0.0196347969 22583.0963 + 19 -193.7114672350 0.711E-03 0.8246827204 0.0196148907 23877.6489 + 20 -193.7113866988 0.679E-03 0.8236615137 0.0196136495 24583.1675 + 21 -193.7117261054 0.731E-03 0.8258300890 0.0196695715 24954.5164 + 22 -193.7121751386 0.810E-03 0.8281161886 0.0197643959 25885.2563 + 23 -193.7122241125 0.775E-03 0.8283053698 0.0197757350 26283.6011 + 24 -193.7123084285 0.746E-03 0.8289899901 0.0197910434 27395.0292 + 25 -193.7123156431 0.715E-03 0.8287806019 0.0197980581 27757.5122 + 27 -193.7123547584 0.681E-03 0.8288814365 0.0198084571 29149.8781 + 28 -193.7123911237 0.657E-03 0.8288178499 0.0198218726 29893.1887 + 29 -193.7123899273 0.634E-03 0.8289804111 0.0198184128 31029.0082 + 30 -193.7121769496 0.649E-03 0.8275986310 0.0197820577 32010.7962 + 31 -193.7120739072 0.636E-03 0.8268889982 0.0197671598 32338.3512 + 32 -193.7120705868 0.600E-03 0.8269139832 0.0197629680 33546.9600 + 33 -193.7120752564 0.581E-03 0.8272094971 0.0197627878 34233.9421 + 34 -193.7119728484 0.573E-03 0.8264229220 0.0197513928 34929.2225 + 35 -193.7121064409 0.572E-03 0.8273527220 0.0197675367 35818.3302 + 36 -193.7120848408 0.556E-03 0.8270446846 0.0197700415 36142.2352 + 37 -193.7122339435 0.586E-03 0.8280983224 0.0197908740 36563.0525 + 38 -193.7123085337 0.575E-03 0.8286769087 0.0198011325 36801.4627 + 39 -193.7123465833 0.562E-03 0.8288326536 0.0198087650 37420.3263 + 40 -193.7123895285 0.549E-03 0.8292878126 0.0198133419 38016.2261 + 41 -193.7122514396 0.553E-03 0.8284845326 0.0197889352 39068.3563 + 42 -193.7123328709 0.540E-03 0.8289774299 0.0198033375 39874.1124 + 43 -193.7122946392 0.529E-03 0.8286710500 0.0197982093 40648.3234 + 44 -193.7123481895 0.519E-03 0.8291247494 0.0198032267 40827.8973 + 45 -193.7123509633 0.508E-03 0.8293005715 0.0198002842 41622.6313 + 47 -193.7122058922 0.503E-03 0.8282754003 0.0197798300 42700.5910 + 48 -193.7122282656 0.493E-03 0.8285147050 0.0197803030 43014.4921 + 49 -193.7122747300 0.485E-03 0.8287911844 0.0197869641 43617.0279 + 50 -193.7122659978 0.473E-03 0.8287379849 0.0197844025 44536.4741 + 51 -193.7122791474 0.464E-03 0.8289535491 0.0197849683 44690.6751 + 52 -193.7123308366 0.457E-03 0.8290655663 0.0197969727 45386.4441 + 53 -193.7122462407 0.457E-03 0.8285149386 0.0197839761 45415.7453 + 54 -193.7122882518 0.450E-03 0.8287814595 0.0197899556 46192.8588 + 55 -193.7122274360 0.452E-03 0.8282430534 0.0197847800 46694.0710 + 56 -193.7123361992 0.457E-03 0.8290345652 0.0198007952 47103.3896 + 57 -193.7124086673 0.455E-03 0.8295408658 0.0198125675 47555.3299 + 59 -193.7123155773 0.449E-03 0.8288163658 0.0197991348 49701.6332 diff --git a/cyclopentadiene/cc-pvtz/slurm-486865.out b/cyclopentadiene/cc-pvtz/slurm-486865.out index 7d16e90..f05cff3 100644 --- a/cyclopentadiene/cc-pvtz/slurm-486865.out +++ b/cyclopentadiene/cc-pvtz/slurm-486865.out @@ -8028,3 +8028,41405 @@ 9.88 % in 38998 seconds 9.88 % in 39008 seconds 9.88 % in 39018 seconds + 9.88 % in 39028 seconds + 9.89 % in 39038 seconds + 9.89 % in 39048 seconds + 9.89 % in 39058 seconds + 9.90 % in 39068 seconds + 9.90 % in 39078 seconds + 9.90 % in 39088 seconds + 9.91 % in 39098 seconds + 9.91 % in 39108 seconds + 9.91 % in 39118 seconds + 9.92 % in 39129 seconds + 9.92 % in 39139 seconds + 9.92 % in 39152 seconds + 9.93 % in 39163 seconds + 9.93 % in 39175 seconds + 9.93 % in 39185 seconds + 9.93 % in 39195 seconds + 9.93 % in 39205 seconds + 9.93 % in 39215 seconds + 9.94 % in 39225 seconds + 9.94 % in 39235 seconds + 9.94 % in 39245 seconds + 9.95 % in 39256 seconds + 9.95 % in 39267 seconds + 9.95 % in 39278 seconds + 9.95 % in 39289 seconds + 9.95 % in 39299 seconds + 9.95 % in 39310 seconds + 9.95 % in 39320 seconds + 9.95 % in 39330 seconds + 9.95 % in 39340 seconds + 9.96 % in 39350 seconds + 9.96 % in 39360 seconds + 9.96 % in 39371 seconds + 9.96 % in 39381 seconds + 9.96 % in 39391 seconds + 9.97 % in 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seconds + 8.83 % in 112484 seconds + 8.83 % in 112615 seconds + 8.83 % in 113638 seconds + + unset COMMAND ++ qp run save_natorb ++ case $1 in ++ which qp_run ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' cyclopentadiene +++ qp_run save_natorb cyclopentadiene ++ unset COMMAND ++ qp set determinants n_det_max 1e8 ++ case $1 in ++ ezfio set determinants n_det_max 1e8 ++ case $1 in ++ shift ++ _ezfio_set determinants n_det_max 1e8 ++ _require_ezfio_file ++ [[ -z cyclopentadiene ]] ++ [[ ! -d cyclopentadiene ]] ++ _require_first_argument determinants n_det_max 1e8 ++ [[ -z determinants ]] ++ return 0 ++ _require_second_argument determinants n_det_max 1e8 ++ [[ -z n_det_max ]] ++ [[ -z 1e8 ]] ++ _ezfio_py set determinants n_det_max ++ echo 1e8 ++ python2 /tmpdir/veril/qp2/external/ezfio/Python/ezfio.py set determinants n_det_max ++ return 0 ++ qp run fci ++ case $1 in ++ which qp_run ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' cyclopentadiene +++ qp_run fci cyclopentadiene + 0.00 % in 3 seconds +32.74 % in 13 seconds +48.96 % in 23 seconds +59.64 % in 33 seconds +72.85 % in 43 seconds +85.39 % in 53 seconds +97.13 % in 63 seconds + 50.00 % in 13 seconds + 16.67 % in 6 seconds + 9.09 % in 6 seconds + 4.76 % in 7 seconds + 2.44 % in 7 seconds + 1.23 % in 10 seconds + 0.62 % in 11 seconds +45.34 % in 21 seconds + 0.31 % in 10 seconds +22.12 % in 21 seconds +44.55 % in 32 seconds +66.98 % in 43 seconds + 0.16 % in 9 seconds +10.76 % in 19 seconds +20.44 % in 29 seconds +30.89 % in 39 seconds +40.72 % in 49 seconds +49.77 % in 59 seconds +59.91 % in 69 seconds +70.98 % in 79 seconds +81.75 % in 89 seconds +92.36 % in 99 seconds + 0.08 % in 11 seconds + 5.15 % in 21 seconds + 9.99 % in 31 seconds +14.13 % in 41 seconds +18.97 % in 51 seconds +24.12 % in 61 seconds +29.59 % in 71 seconds + 0.04 % in 10 seconds + 2.30 % in 20 seconds + 4.65 % in 33 seconds + 7.38 % in 43 seconds + 9.06 % in 53 seconds +11.28 % in 63 seconds +13.90 % in 73 seconds +15.78 % in 83 seconds +17.69 % in 93 seconds +20.38 % in 103 seconds +23.31 % in 114 seconds + 0.02 % in 11 seconds + 0.70 % in 21 seconds + 1.86 % in 31 seconds + 2.56 % in 41 seconds + 3.93 % in 51 seconds + 4.53 % in 61 seconds + 5.86 % in 71 seconds + 6.52 % in 81 seconds + 7.77 % in 91 seconds + 8.49 % in 101 seconds + 9.80 % in 111 seconds +10.45 % in 121 seconds +11.79 % in 131 seconds +12.71 % in 141 seconds +13.88 % in 153 seconds +15.23 % in 163 seconds +15.99 % in 173 seconds +17.30 % in 183 seconds +18.53 % in 193 seconds +19.92 % in 203 seconds +20.91 % in 214 seconds + 0.01 % in 11 seconds + 0.62 % in 22 seconds + 0.77 % in 32 seconds + 1.46 % in 42 seconds + 1.79 % in 52 seconds + 2.28 % in 62 seconds + 2.82 % in 72 seconds + 3.36 % in 83 seconds + 4.01 % in 93 seconds + 4.40 % in 103 seconds + 5.02 % in 113 seconds + 5.61 % in 123 seconds + 5.93 % in 133 seconds + 6.65 % in 143 seconds + 6.90 % in 153 seconds + 7.67 % in 163 seconds + 7.93 % in 173 seconds + 8.78 % in 183 seconds + 9.03 % in 193 seconds + 9.78 % in 203 seconds +10.08 % in 213 seconds +10.90 % in 223 seconds +11.13 % in 233 seconds + 0.00 % in 7 seconds + 0.28 % in 17 seconds + 0.35 % in 27 seconds + 0.63 % in 37 seconds + 0.80 % in 47 seconds + 0.96 % in 57 seconds + 1.28 % in 67 seconds + 1.53 % in 77 seconds + 1.71 % in 87 seconds + 1.97 % in 97 seconds + 2.21 % in 107 seconds + 2.50 % in 117 seconds + 2.78 % in 127 seconds + 3.03 % in 137 seconds + 3.22 % in 147 seconds + 3.47 % in 157 seconds + 3.70 % in 167 seconds + 4.00 % in 177 seconds + 4.21 % in 187 seconds + 4.45 % in 197 seconds + 4.72 % in 207 seconds + 4.97 % in 217 seconds + 5.22 % in 227 seconds + 5.50 % in 237 seconds + 5.72 % in 248 seconds + 6.02 % in 258 seconds + 6.22 % in 268 seconds + 6.47 % in 278 seconds + 6.72 % in 288 seconds + 7.00 % in 299 seconds + 7.25 % in 310 seconds + 7.51 % in 320 seconds + 7.72 % in 330 seconds + 7.80 % in 344 seconds + 0.00 % in 6 seconds + 0.08 % in 16 seconds + 0.19 % in 26 seconds + 0.34 % in 36 seconds + 0.38 % in 47 seconds + 0.47 % in 57 seconds + 0.61 % in 67 seconds + 0.76 % in 77 seconds + 0.89 % in 87 seconds + 1.02 % in 97 seconds + 1.15 % in 108 seconds + 1.28 % in 118 seconds + 1.40 % in 128 seconds + 1.53 % in 138 seconds + 1.66 % in 148 seconds + 1.79 % in 158 seconds + 1.88 % in 168 seconds + 2.09 % in 178 seconds + 2.19 % in 188 seconds + 2.33 % in 198 seconds + 2.44 % in 208 seconds + 2.56 % in 218 seconds + 2.68 % in 228 seconds + 2.82 % in 238 seconds + 2.93 % in 248 seconds + 3.09 % in 258 seconds + 3.21 % in 269 seconds + 3.37 % in 279 seconds + 3.47 % in 289 seconds + 3.60 % in 299 seconds + 3.71 % in 309 seconds + 3.86 % in 319 seconds + 4.05 % in 329 seconds + 4.14 % in 339 seconds + 4.27 % in 349 seconds + 4.42 % in 359 seconds + 4.56 % in 369 seconds + 4.69 % in 379 seconds + 4.84 % in 389 seconds + 4.94 % in 399 seconds + 5.10 % in 409 seconds + 5.25 % in 419 seconds + 5.39 % in 429 seconds + 5.53 % in 439 seconds + 5.65 % in 449 seconds + 5.78 % in 459 seconds + 6.00 % in 469 seconds + 6.09 % in 479 seconds + 6.23 % in 489 seconds + 6.34 % in 499 seconds + 6.48 % in 509 seconds + 6.65 % in 519 seconds + 6.79 % in 529 seconds + 6.90 % in 540 seconds + 7.09 % in 550 seconds + 7.21 % in 560 seconds + 7.35 % in 570 seconds + 7.47 % in 580 seconds + 7.62 % in 590 seconds + 7.76 % in 601 seconds + 7.92 % in 611 seconds + 8.05 % in 621 seconds + 8.16 % in 631 seconds + 8.28 % in 641 seconds + 8.34 % in 661 seconds + 0.00 % in 7 seconds + 0.05 % in 17 seconds + 0.08 % in 27 seconds + 0.16 % in 39 seconds + 0.20 % in 49 seconds + 0.28 % in 59 seconds + 0.32 % in 70 seconds + 0.37 % in 80 seconds + 0.43 % in 91 seconds + 0.54 % in 102 seconds + 0.60 % in 112 seconds + 0.66 % in 122 seconds + 0.71 % in 133 seconds + 0.80 % in 143 seconds + 0.89 % in 153 seconds + 0.94 % in 163 seconds + 1.00 % in 173 seconds + 1.06 % in 183 seconds + 1.14 % in 193 seconds + 1.21 % in 204 seconds + 1.30 % in 214 seconds + 1.36 % in 224 seconds + 1.42 % in 235 seconds + 1.49 % in 245 seconds + 1.56 % in 255 seconds + 1.64 % in 265 seconds + 1.70 % in 276 seconds + 1.76 % in 286 seconds + 1.86 % in 296 seconds + 1.91 % in 306 seconds + 1.97 % in 316 seconds + 2.05 % in 327 seconds + 2.12 % in 337 seconds + 2.20 % in 347 seconds + 2.27 % in 357 seconds + 2.35 % in 367 seconds + 2.41 % in 377 seconds + 2.48 % in 387 seconds + 2.56 % in 399 seconds + 2.64 % in 410 seconds + 2.71 % in 420 seconds + 2.80 % in 430 seconds + 2.88 % in 440 seconds + 2.96 % in 450 seconds + 3.00 % in 460 seconds + 3.05 % in 470 seconds + 3.06 % in 488 seconds + 3.07 % in 512 seconds + 3.08 % in 525 seconds + 3.09 % in 538 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 16.67 % in 0 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 16.67 % in 0 seconds + 0.00 % in 6 seconds + 0.02 % in 16 seconds + 0.03 % in 26 seconds + 0.06 % in 36 seconds + 0.07 % in 46 seconds + 0.11 % in 56 seconds + 0.14 % in 66 seconds + 0.18 % in 76 seconds + 0.23 % in 86 seconds + 0.25 % in 97 seconds + 0.27 % in 107 seconds + 0.29 % in 117 seconds + 0.31 % in 127 seconds + 0.34 % in 137 seconds + 0.38 % in 147 seconds + 0.42 % in 158 seconds + 0.47 % in 170 seconds + 0.52 % in 182 seconds + 0.54 % in 195 seconds + 0.56 % in 205 seconds + 0.59 % in 217 seconds + 0.63 % in 228 seconds + 0.67 % in 238 seconds + 0.72 % in 248 seconds + 0.75 % in 258 seconds + 0.78 % in 268 seconds + 0.82 % in 279 seconds + 0.84 % in 289 seconds + 0.87 % in 299 seconds + 0.89 % in 310 seconds + 0.91 % in 320 seconds + 0.96 % in 330 seconds + 1.01 % in 340 seconds + 1.03 % in 350 seconds + 1.07 % in 360 seconds + 1.10 % in 371 seconds + 1.12 % in 381 seconds + 1.15 % in 391 seconds + 1.19 % in 401 seconds + 1.23 % in 411 seconds + 1.27 % in 421 seconds + 1.33 % in 432 seconds + 1.38 % in 442 seconds + 1.41 % in 453 seconds + 1.44 % in 463 seconds + 1.48 % in 473 seconds + 1.53 % in 483 seconds + 1.60 % in 493 seconds + 1.65 % in 503 seconds + 1.70 % in 513 seconds + 1.72 % in 523 seconds + 1.75 % in 533 seconds + 1.80 % in 543 seconds + 1.86 % in 553 seconds + 1.90 % in 563 seconds + 1.93 % in 573 seconds + 1.97 % in 583 seconds + 2.01 % in 594 seconds + 2.07 % in 604 seconds + 2.13 % in 614 seconds + 2.17 % in 624 seconds + 2.22 % in 634 seconds + 2.24 % in 644 seconds + 2.28 % in 654 seconds + 2.32 % in 664 seconds + 2.37 % in 674 seconds + 2.40 % in 684 seconds + 2.44 % in 694 seconds + 2.46 % in 704 seconds + 2.51 % in 715 seconds + 2.55 % in 725 seconds + 2.58 % in 735 seconds + 2.63 % in 745 seconds + 2.66 % in 758 seconds + 2.69 % in 769 seconds + 2.73 % in 779 seconds + 2.77 % in 789 seconds + 2.81 % in 799 seconds + 2.86 % in 809 seconds + 2.91 % in 819 seconds + 2.96 % in 829 seconds + 3.00 % in 840 seconds + 3.03 % in 850 seconds + 3.08 % in 861 seconds + 3.11 % in 871 seconds + 3.14 % in 881 seconds + 3.19 % in 891 seconds + 3.24 % in 901 seconds + 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% in 59 seconds + 0.04 % in 70 seconds + 0.05 % in 80 seconds + 0.06 % in 90 seconds + 0.07 % in 100 seconds + 0.08 % in 110 seconds + 0.10 % in 120 seconds + 0.13 % in 130 seconds + 0.14 % in 140 seconds + 0.15 % in 150 seconds + 0.17 % in 160 seconds + 0.19 % in 171 seconds + 0.21 % in 181 seconds + 0.23 % in 194 seconds + 0.24 % in 204 seconds + 0.25 % in 214 seconds + 0.26 % in 224 seconds + 0.27 % in 235 seconds + 0.28 % in 246 seconds + 0.30 % in 256 seconds + 0.30 % in 266 seconds + 0.32 % in 277 seconds + 0.34 % in 289 seconds + 0.35 % in 299 seconds + 0.36 % in 309 seconds + 0.37 % in 320 seconds + 0.39 % in 330 seconds + 0.41 % in 340 seconds + 0.42 % in 350 seconds + 0.44 % in 360 seconds + 0.46 % in 370 seconds + 0.48 % in 380 seconds + 0.49 % in 390 seconds + 0.50 % in 400 seconds + 0.52 % in 410 seconds + 0.53 % in 420 seconds + 0.54 % in 430 seconds + 0.55 % in 440 seconds + 0.57 % in 450 seconds + 0.59 % in 460 seconds + 0.62 % in 471 seconds + 0.65 % in 481 seconds + 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+ 2.62 % in 1323 seconds + 2.64 % in 1333 seconds + 2.66 % in 1343 seconds + 2.68 % in 1353 seconds + 2.71 % in 1364 seconds + 2.73 % in 1374 seconds + 2.75 % in 1384 seconds + 2.77 % in 1394 seconds + 2.80 % in 1404 seconds + 2.82 % in 1414 seconds + 2.85 % in 1424 seconds + 2.87 % in 1434 seconds + 2.88 % in 1444 seconds + 2.91 % in 1454 seconds + 2.94 % in 1465 seconds + 2.97 % in 1475 seconds + 2.99 % in 1485 seconds + 3.02 % in 1495 seconds + 3.06 % in 1505 seconds + 3.07 % in 1516 seconds + 3.09 % in 1526 seconds + 3.11 % in 1536 seconds + 3.13 % in 1546 seconds + 3.15 % in 1558 seconds + 3.17 % in 1569 seconds + 3.17 % in 1580 seconds + 3.18 % in 1590 seconds + 3.20 % in 1602 seconds + 3.22 % in 1612 seconds + 3.25 % in 1622 seconds + 3.27 % in 1632 seconds + 3.30 % in 1642 seconds + 3.33 % in 1652 seconds + 3.35 % in 1662 seconds + 3.37 % in 1672 seconds + 3.39 % in 1682 seconds + 3.41 % in 1694 seconds + 3.42 % in 1704 seconds + 3.46 % in 1714 seconds + 3.49 % in 1724 seconds + 3.53 % in 1734 seconds + 3.55 % in 1749 seconds + 3.57 % in 1759 seconds + 3.59 % in 1770 seconds + 3.61 % in 1780 seconds + 3.64 % in 1790 seconds + 3.66 % in 1800 seconds + 3.70 % in 1810 seconds + 3.73 % in 1820 seconds + 3.76 % in 1830 seconds + 3.79 % in 1842 seconds + 3.80 % in 1855 seconds + 3.81 % in 1865 seconds + 3.82 % in 1876 seconds + 3.84 % in 1886 seconds + 3.87 % in 1896 seconds + 3.90 % in 1906 seconds + 3.91 % in 1917 seconds + 3.93 % in 1927 seconds + 3.95 % in 1937 seconds + 3.97 % in 1947 seconds + 3.98 % in 1958 seconds + 3.99 % in 1969 seconds + 4.00 % in 1979 seconds + 4.02 % in 1989 seconds + 4.03 % in 1999 seconds + 4.06 % in 2009 seconds + 4.09 % in 2019 seconds + 4.12 % in 2029 seconds + 4.14 % in 2039 seconds + 4.16 % in 2050 seconds + 4.17 % in 2060 seconds + 4.19 % in 2071 seconds + 4.21 % in 2083 seconds + 4.23 % in 2093 seconds + 4.24 % in 2103 seconds + 4.26 % in 2113 seconds + 4.27 % in 2123 seconds + 4.29 % in 2133 seconds + 4.31 % in 2143 seconds + 4.33 % in 2153 seconds + 4.35 % in 2163 seconds + 4.37 % in 2173 seconds + 4.40 % in 2183 seconds + 4.43 % in 2193 seconds + 4.46 % in 2203 seconds + 4.49 % in 2213 seconds + 4.51 % in 2223 seconds + 4.53 % in 2233 seconds + 4.54 % in 2243 seconds + 4.57 % in 2253 seconds + 4.59 % in 2263 seconds + 4.62 % in 2273 seconds + 4.66 % in 2283 seconds + 4.68 % in 2293 seconds + 4.70 % in 2303 seconds + 4.72 % in 2313 seconds + 4.74 % in 2323 seconds + 4.77 % in 2334 seconds + 4.79 % in 2344 seconds + 4.82 % in 2354 seconds + 4.83 % in 2364 seconds + 4.84 % in 2374 seconds + 4.85 % in 2385 seconds + 4.87 % in 2395 seconds + 4.89 % in 2405 seconds + 4.93 % in 2415 seconds + 4.97 % in 2425 seconds + 5.00 % in 2435 seconds + 5.02 % in 2446 seconds + 5.04 % in 2456 seconds + 5.06 % in 2466 seconds + 5.07 % in 2476 seconds + 5.08 % in 2487 seconds + 5.09 % in 2497 seconds + 5.10 % in 2507 seconds + 5.12 % in 2518 seconds + 5.13 % in 2528 seconds + 5.15 % in 2538 seconds + 5.19 % in 2548 seconds + 5.23 % in 2558 seconds + 5.25 % in 2568 seconds + 5.28 % in 2578 seconds + 5.29 % in 2588 seconds + 5.31 % in 2598 seconds + 5.33 % in 2608 seconds + 5.35 % in 2618 seconds + 5.37 % in 2629 seconds + 5.39 % in 2640 seconds + 5.41 % in 2650 seconds + 5.42 % in 2660 seconds + 5.44 % in 2670 seconds + 5.47 % in 2680 seconds + 5.50 % in 2690 seconds + 5.52 % in 2700 seconds + 5.54 % in 2710 seconds + 5.57 % in 2721 seconds + 5.58 % in 2731 seconds + 5.61 % in 2741 seconds + 5.63 % in 2751 seconds + 5.65 % in 2761 seconds + 5.66 % in 2771 seconds + 5.68 % in 2781 seconds + 5.70 % in 2791 seconds + 5.72 % in 2801 seconds + 5.74 % in 2812 seconds + 5.75 % in 2822 seconds + 5.77 % in 2833 seconds + 5.79 % in 2843 seconds + 5.81 % in 2853 seconds + 5.83 % in 2863 seconds + 5.85 % in 2873 seconds + 5.87 % in 2884 seconds + 5.88 % in 2894 seconds + 5.89 % in 2904 seconds + 5.91 % in 2914 seconds + 5.92 % in 2924 seconds + 5.94 % in 2934 seconds + 5.96 % in 2944 seconds + 5.97 % in 2954 seconds + 5.99 % in 2964 seconds + 6.01 % in 2974 seconds + 6.02 % in 2984 seconds + 6.04 % in 2994 seconds + 6.06 % in 3004 seconds + 6.07 % in 3014 seconds + 6.09 % in 3025 seconds + 6.11 % in 3035 seconds + 6.13 % in 3045 seconds + 6.16 % in 3055 seconds + 6.19 % in 3065 seconds + 6.23 % in 3075 seconds + 6.24 % in 3086 seconds + 6.26 % in 3096 seconds + 6.28 % in 3106 seconds + 6.30 % in 3116 seconds + 6.32 % in 3126 seconds + 6.34 % in 3136 seconds + 6.37 % in 3146 seconds + 6.39 % in 3158 seconds + 6.42 % in 3168 seconds + 6.43 % in 3178 seconds + 6.46 % in 3188 seconds + 6.47 % in 3198 seconds + 6.49 % in 3208 seconds + 6.53 % in 3219 seconds + 6.55 % in 3229 seconds + 6.57 % in 3239 seconds + 6.59 % in 3249 seconds + 6.61 % in 3260 seconds + 6.62 % in 3270 seconds + 6.63 % in 3280 seconds + 6.65 % in 3291 seconds + 6.68 % in 3301 seconds + 6.71 % in 3311 seconds + 6.74 % in 3321 seconds + 6.76 % in 3332 seconds + 6.77 % in 3342 seconds + 6.77 % in 3353 seconds + 6.78 % in 3363 seconds + 6.81 % in 3373 seconds + 6.84 % in 3383 seconds + 6.86 % in 3393 seconds + 6.90 % in 3403 seconds + 6.93 % in 3413 seconds + 6.94 % in 3423 seconds + 6.97 % in 3433 seconds + 6.98 % in 3443 seconds + 7.00 % in 3453 seconds + 7.00 % in 3463 seconds + 7.03 % in 3473 seconds + 7.05 % in 3484 seconds + 7.07 % in 3494 seconds + 7.09 % in 3504 seconds + 7.11 % in 3515 seconds + 7.13 % in 3525 seconds + 7.15 % in 3535 seconds + 7.17 % in 3545 seconds + 7.19 % in 3555 seconds + 7.21 % in 3565 seconds + 7.22 % in 3575 seconds + 7.24 % in 3585 seconds + 7.26 % in 3595 seconds + 7.27 % in 3605 seconds + 7.28 % in 3615 seconds + 7.30 % in 3625 seconds + 7.31 % in 3635 seconds + 7.33 % in 3645 seconds + 7.36 % in 3655 seconds + 7.38 % in 3665 seconds + 7.39 % in 3675 seconds + 7.41 % in 3685 seconds + 7.43 % in 3695 seconds + 7.44 % in 3705 seconds + 7.46 % in 3715 seconds + 7.48 % in 3725 seconds + 7.50 % in 3735 seconds + 7.53 % in 3745 seconds + 7.54 % in 3755 seconds + 7.56 % in 3765 seconds + 7.57 % in 3775 seconds + 7.59 % in 3785 seconds + 7.60 % in 3795 seconds + 7.62 % in 3806 seconds + 7.64 % in 3816 seconds + 7.65 % in 3826 seconds + 7.68 % in 3836 seconds + 7.70 % in 3846 seconds + 7.73 % in 3856 seconds + 7.76 % in 3866 seconds + 7.77 % in 3876 seconds + 7.78 % in 3886 seconds + 7.81 % in 3896 seconds + 7.82 % in 3906 seconds + 7.83 % in 3917 seconds + 7.85 % in 3927 seconds + 7.86 % in 3937 seconds + 7.88 % in 3947 seconds + 7.90 % in 3957 seconds + 7.91 % in 3967 seconds + 7.94 % in 3977 seconds + 7.96 % in 3988 seconds + 7.97 % in 3998 seconds + 7.98 % in 4014 seconds + 7.99 % in 4025 seconds + 8.01 % in 4036 seconds + 8.01 % in 4049 seconds + 8.02 % in 4060 seconds + 8.02 % in 4070 seconds + 8.03 % in 4161 seconds + 5.56 % in 4 seconds +16.67 % in 17 seconds +38.89 % in 27 seconds +61.11 % in 37 seconds +83.33 % in 49 seconds + 5.56 % in 3 seconds +16.67 % in 17 seconds +44.44 % in 29 seconds +66.67 % in 39 seconds +88.89 % in 50 seconds + 5.56 % in 3 seconds +16.67 % in 17 seconds +44.44 % in 29 seconds +66.67 % in 39 seconds +88.89 % in 49 seconds + 5.56 % in 3 seconds +16.67 % in 16 seconds +38.89 % in 26 seconds +61.11 % in 36 seconds +83.33 % in 48 seconds + 5.56 % in 3 seconds +16.67 % in 17 seconds +44.44 % in 29 seconds +66.67 % in 39 seconds +88.89 % in 50 seconds + 5.56 % in 3 seconds +16.67 % in 17 seconds +38.89 % in 27 seconds +61.11 % in 37 seconds +83.33 % in 49 seconds + 5.56 % in 4 seconds +16.67 % in 17 seconds +38.89 % in 27 seconds +61.11 % in 37 seconds +83.33 % in 48 seconds + 5.56 % in 4 seconds +16.67 % in 17 seconds +44.44 % in 28 seconds +66.67 % in 39 seconds +88.89 % in 49 seconds + 5.56 % in 3 seconds +16.67 % in 16 seconds +44.44 % in 28 seconds +66.67 % in 38 seconds +88.89 % in 48 seconds + 5.56 % in 3 seconds +16.67 % in 16 seconds +38.89 % in 26 seconds +61.11 % in 36 seconds +83.33 % in 47 seconds + 5.56 % in 3 seconds +16.67 % in 16 seconds +44.44 % in 28 seconds +66.67 % in 38 seconds +88.89 % in 48 seconds + 0.00 % in 25 seconds + 0.00 % in 45 seconds + 0.00 % in 58 seconds + 0.00 % in 70 seconds + 0.00 % in 81 seconds + 0.00 % in 99 seconds + 0.00 % in 110 seconds + 0.00 % in 130 seconds + 0.00 % in 147 seconds + 0.00 % in 158 seconds + 0.00 % in 171 seconds + 0.00 % in 181 seconds + 0.01 % in 195 seconds + 0.01 % in 213 seconds + 0.01 % in 226 seconds + 0.01 % in 236 seconds + 0.01 % in 249 seconds + 0.01 % in 260 seconds + 0.01 % in 271 seconds + 0.01 % in 282 seconds + 0.01 % in 292 seconds + 0.01 % in 304 seconds + 0.01 % in 315 seconds + 0.01 % in 328 seconds + 0.01 % in 338 seconds + 0.01 % in 348 seconds + 0.01 % in 358 seconds + 0.01 % in 368 seconds + 0.02 % in 378 seconds + 0.02 % in 388 seconds + 0.02 % in 398 seconds + 0.03 % in 408 seconds + 0.03 % in 418 seconds + 0.04 % in 428 seconds + 0.04 % in 439 seconds + 0.05 % in 449 seconds + 0.06 % in 459 seconds + 0.07 % in 469 seconds + 0.08 % in 479 seconds + 0.09 % in 489 seconds + 0.11 % in 499 seconds + 0.13 % in 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in 1350 seconds + 1.32 % in 1360 seconds + 1.34 % in 1370 seconds + 1.35 % in 1380 seconds + 1.38 % in 1390 seconds + 1.40 % in 1401 seconds + 1.42 % in 1413 seconds + 1.42 % in 1423 seconds + 1.44 % in 1433 seconds + 1.45 % in 1444 seconds + 1.46 % in 1454 seconds + 1.47 % in 1464 seconds + 1.49 % in 1474 seconds + 1.50 % in 1484 seconds + 1.52 % in 1494 seconds + 1.53 % in 1504 seconds + 1.56 % in 1514 seconds + 1.57 % in 1524 seconds + 1.59 % in 1534 seconds + 1.60 % in 1544 seconds + 1.61 % in 1554 seconds + 1.62 % in 1564 seconds + 1.64 % in 1574 seconds + 1.64 % in 1584 seconds + 1.65 % in 1594 seconds + 1.66 % in 1604 seconds + 1.67 % in 1614 seconds + 1.69 % in 1624 seconds + 1.70 % in 1635 seconds + 1.71 % in 1645 seconds + 1.73 % in 1655 seconds + 1.74 % in 1666 seconds + 1.76 % in 1676 seconds + 1.78 % in 1686 seconds + 1.80 % in 1696 seconds + 1.82 % in 1706 seconds + 1.84 % in 1717 seconds + 1.85 % in 1728 seconds + 1.86 % in 1740 seconds + 1.87 % in 1752 seconds + 1.88 % 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in 2167 seconds + 2.41 % in 2177 seconds + 2.43 % in 2187 seconds + 2.44 % in 2197 seconds + 2.44 % in 2207 seconds + 2.45 % in 2218 seconds + 2.46 % in 2230 seconds + 2.47 % in 2240 seconds + 2.50 % in 2251 seconds + 2.52 % in 2261 seconds + 2.53 % in 2271 seconds + 2.54 % in 2281 seconds + 2.55 % in 2291 seconds + 2.56 % in 2301 seconds + 2.57 % in 2311 seconds + 2.58 % in 2321 seconds + 2.59 % in 2331 seconds + 2.61 % in 2341 seconds + 2.61 % in 2351 seconds + 2.63 % in 2361 seconds + 2.65 % in 2371 seconds + 2.66 % in 2382 seconds + 2.68 % in 2392 seconds + 2.70 % in 2402 seconds + 2.72 % in 2412 seconds + 2.73 % in 2422 seconds + 2.75 % in 2432 seconds + 2.76 % in 2443 seconds + 2.77 % in 2453 seconds + 2.78 % in 2463 seconds + 2.79 % in 2473 seconds + 2.80 % in 2483 seconds + 2.81 % in 2493 seconds + 2.83 % in 2503 seconds + 2.84 % in 2513 seconds + 2.86 % in 2523 seconds + 2.87 % in 2533 seconds + 2.90 % in 2545 seconds + 2.91 % in 2556 seconds + 2.92 % in 2566 seconds + 2.92 % in 2576 seconds + 2.93 % in 2587 seconds + 2.93 % in 2597 seconds + 2.95 % in 2607 seconds + 2.95 % in 2617 seconds + 2.96 % in 2627 seconds + 2.97 % in 2637 seconds + 2.98 % in 2648 seconds + 2.98 % in 2658 seconds + 2.99 % in 2668 seconds + 3.00 % in 2678 seconds + 3.01 % in 2688 seconds + 3.02 % in 2698 seconds + 3.02 % in 2708 seconds + 3.03 % in 2718 seconds + 3.05 % in 2728 seconds + 3.06 % in 2739 seconds + 3.07 % in 2749 seconds + 3.08 % in 2759 seconds + 3.10 % in 2769 seconds + 3.12 % in 2779 seconds + 3.13 % in 2789 seconds + 3.15 % in 2802 seconds + 3.17 % in 2812 seconds + 3.18 % in 2823 seconds + 3.18 % in 2834 seconds + 3.20 % in 2844 seconds + 3.21 % in 2854 seconds + 3.22 % in 2864 seconds + 3.23 % in 2874 seconds + 3.24 % in 2884 seconds + 3.26 % in 2894 seconds + 3.27 % in 2904 seconds + 3.29 % in 2915 seconds + 3.31 % in 2925 seconds + 3.33 % in 2937 seconds + 3.34 % in 2947 seconds + 3.36 % in 2958 seconds + 3.37 % in 2968 seconds + 3.38 % in 2978 seconds + 3.39 % in 2988 seconds + 3.40 % in 2998 seconds + 3.42 % in 3008 seconds + 3.43 % in 3018 seconds + 3.45 % in 3028 seconds + 3.46 % in 3038 seconds + 3.47 % in 3048 seconds + 3.49 % in 3058 seconds + 3.51 % in 3068 seconds + 3.53 % in 3078 seconds + 3.54 % in 3088 seconds + 3.56 % in 3099 seconds + 3.57 % in 3109 seconds + 3.58 % in 3119 seconds + 3.59 % in 3129 seconds + 3.60 % in 3140 seconds + 3.60 % in 3150 seconds + 3.62 % in 3160 seconds + 3.63 % in 3170 seconds + 3.64 % in 3180 seconds + 3.65 % in 3190 seconds + 3.66 % in 3200 seconds + 3.68 % in 3210 seconds + 3.69 % in 3220 seconds + 3.71 % in 3230 seconds + 3.73 % in 3240 seconds + 3.74 % in 3250 seconds + 3.75 % in 3260 seconds + 3.77 % in 3270 seconds + 3.78 % in 3280 seconds + 3.79 % in 3290 seconds + 3.80 % in 3301 seconds + 3.82 % in 3311 seconds + 3.83 % in 3321 seconds + 3.84 % in 3331 seconds + 3.84 % in 3342 seconds + 3.85 % in 3353 seconds + 3.85 % in 3363 seconds + 3.86 % in 3373 seconds + 3.88 % in 3383 seconds + 3.89 % 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49725 seconds + 4.21 % in 49735 seconds + 4.21 % in 49745 seconds + 4.21 % in 49755 seconds + 4.21 % in 49765 seconds + 4.21 % in 49775 seconds + 4.21 % in 49786 seconds + 4.21 % in 49796 seconds + 4.21 % in 49806 seconds + 4.21 % in 49816 seconds + 4.21 % in 49826 seconds + 4.21 % in 49836 seconds + 4.21 % in 49846 seconds + 4.21 % in 49856 seconds + 4.21 % in 49868 seconds + 4.21 % in 49878 seconds + 4.21 % in 49889 seconds + 4.21 % in 49899 seconds + 4.21 % in 49909 seconds + 4.21 % in 49919 seconds + 4.21 % in 49929 seconds + 4.21 % in 49940 seconds + 4.22 % in 49950 seconds + 4.22 % in 49960 seconds + 4.22 % in 49971 seconds + 4.22 % in 49981 seconds + 4.22 % in 49991 seconds + 4.22 % in 50002 seconds + 4.22 % in 50012 seconds + 4.22 % in 50022 seconds + 4.22 % in 50032 seconds diff --git a/imidazole/cc-pvdz/imidazole.fci.out b/imidazole/cc-pvdz/imidazole.fci.out index f7975d8..f749711 100644 --- a/imidazole/cc-pvdz/imidazole.fci.out +++ b/imidazole/cc-pvdz/imidazole.fci.out @@ -3165,3 +3165,1299 @@ Iter Energy S^2 Residual 141 -225.5831404876 0.253E-03 0.7081760001 0.0215924595 1119.2079 142 -225.5831265620 0.252E-03 0.7080037903 0.0215918552 1132.1730 143 -225.5831364884 0.250E-03 0.7080399178 0.0215941793 1133.4480 + 145 -225.5831513748 0.248E-03 0.7080904518 0.0215981049 1151.8790 + 148 -225.5831455595 0.243E-03 0.7080440083 0.0215975070 1162.9410 + 149 -225.5831572679 0.242E-03 0.7080257185 0.0216015988 1172.3119 + 151 -225.5831677471 0.228E-03 0.7078435200 0.0216114999 1185.4669 + 152 -225.5831446740 0.228E-03 0.7077177954 0.0216072722 1189.6178 + 153 -225.5831799209 0.229E-03 0.7079819811 0.0216117139 1202.6609 + 155 -225.5831189008 0.230E-03 0.7075207406 0.0216033537 1211.7794 + 156 -225.5831298452 0.229E-03 0.7076659155 0.0216034621 1213.3845 + 158 -225.5832190805 0.235E-03 0.7081442392 0.0216197334 1226.5320 + 160 -225.5831825066 0.233E-03 0.7078472365 0.0216148974 1244.3732 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 3.418526 GB ] [ VIRT MEM : 9.447792 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2403.384612 s ] [ CPU TIME: 170766.722469 s ] <<<<< .. + +* Number of generators 655356 + +.. >>>>> [ RES MEM : 3.418526 GB ] [ VIRT MEM : 9.447792 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2403.386486 s ] [ CPU TIME: 170766.855532 s ] <<<<< .. + +* Number of selectors 655356 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8440440415287040 + +Summary at N_det = 655360 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.46444217 +# PT2 -0.11875030 0.00023043 +# rPT2 -0.11623757 0.00022555 +# +# E+PT2 -225.58319247 0.00023043 +# E+rPT2 -225.58067974 0.00022555 +# ============ ============================= + + N_det = 655360 + N_states = 1 + + * State 1 + < S^2 > = 1.191698430059806E-003 + E = -225.464442169195 + Variance = 0.707865603966537 + PT norm = 0.147027883289984 + PT2 = -0.118750296552565 + rPT2 = -0.116237566018877 + E+PT2 = -225.583192465747 +/- 2.304290574729975E-004 + E+rPT2 = -225.580679735214 +/- 2.255532285667097E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -852.936569518008 + Vee = 238.841782979264 + Vecp = 0.000000000000000E+000 + T = 225.125994648486 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1278 -225.61594215 + -0.1629 -225.60553459 + -0.2138 -225.60510140 + -0.2716 -225.60502521 + -0.3300 -225.60469167 + -0.3849 -225.60439113 + -0.4337 -225.60422847 + =========== =================== + +* Number of unique beta determinants 161111 +* Number of unique alpha determinants 164635 + +.. >>>>> [ RES MEM : 3.556309 GB ] [ VIRT MEM : 9.639435 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2461.794515 s ] [ CPU TIME: 174920.022771 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 1310720 +* Number of threads for diagonalization 72 +* Memory(Gb) 2.224763169884682 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.4644421868 0.001192 0.783E-03 + 2 -225.4676288880 0.001525 0.148E-03 + 3 -225.4677829517 0.001591 0.202E-04 + 4 -225.4678244701 0.001666 0.563E-05 + 5 -225.4678320795 0.001688 0.323E-06 + 6 -225.4678327657 0.001687 0.647E-07 + 7 -225.4678328925 0.001684 0.817E-08 + 8 -225.4678329114 0.001683 0.941E-09 + 9 -225.4678329134 0.001683 0.841E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 4.438057 GB ] [ VIRT MEM : 10.815575 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2968.913120 s ] [ CPU TIME: 210675.886074 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 3.266193 GB ] [ VIRT MEM : 9.349255 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2969.057833 s ] [ CPU TIME: 210681.118034 s ] <<<<< .. + +* Energy of state 1 -225.4678329134319 +* S^2 of state 1 0.1683351073407312E-02 +* Saved determinants 1310720 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 3.085873 GB ] [ VIRT MEM : 9.109661 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2985.403696 s ] [ CPU TIME: 210944.299375 s ] <<<<< .. + +* Number of generators 1310711 + +.. >>>>> [ RES MEM : 3.085873 GB ] [ VIRT MEM : 9.109661 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2985.407100 s ] [ CPU TIME: 210944.544093 s ] <<<<< .. + +* Number of selectors 1310711 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 +* PT2 Energy denominator -225.4678329134319 + +.. >>>>> [ RES MEM : 3.261147 GB ] [ VIRT MEM : 9.288887 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2986.129148 s ] [ CPU TIME: 210995.559470 s ] <<<<< .. + +* Number of generators 1310711 + +.. >>>>> [ RES MEM : 3.261147 GB ] [ VIRT MEM : 9.288887 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2986.132562 s ] [ CPU TIME: 210995.804906 s ] <<<<< .. + +* Number of selectors 1310711 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 +* Number of tasks 2088404 +* Number of fragmented tasks 53170 +* Number of threads for PT2 72 +* Memory (Gb) 14.20485668245703 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5828329941 0.144E-02 0.6957102071 0.0206155488 175.1708 + 4 -225.5832109543 0.106E-02 0.6982953224 0.0206110271 229.6966 + 5 -225.5822993173 0.126E-02 0.6929870905 0.0204675418 269.7896 + 7 -225.5831290196 0.117E-02 0.6986535190 0.0205840753 284.0046 + 8 -225.5826520533 0.101E-02 0.6945578580 0.0205503527 337.6026 + 9 -225.5838397251 0.151E-02 0.7024567478 0.0207402451 349.0531 + 10 -225.5843126537 0.143E-02 0.7065267794 0.0207915470 363.6746 + 11 -225.5843076637 0.129E-02 0.7062498647 0.0207982125 365.3986 + 12 -225.5845137170 0.115E-02 0.7073939973 0.0208366349 415.9276 + 13 -225.5842437660 0.109E-02 0.7057247833 0.0207936162 436.6332 + 15 -225.5840245379 0.990E-03 0.7038750273 0.0207831692 495.3356 + 18 -225.5845330949 0.902E-03 0.7061048955 0.0209005461 522.9766 + 19 -225.5844297582 0.859E-03 0.7056279500 0.0208780142 538.6566 + 20 -225.5845757256 0.828E-03 0.7070174289 0.0208966778 595.5204 + 23 -225.5840965900 0.935E-03 0.7034820134 0.0208240902 613.0096 + 24 -225.5841888976 0.900E-03 0.7036190962 0.0208523553 651.7229 + 25 -225.5841526492 0.864E-03 0.7032507571 0.0208519667 664.7516 + 26 -225.5840177568 0.932E-03 0.7017052324 0.0208546187 672.5086 + 27 -225.5839009799 0.904E-03 0.7003902031 0.0208498836 687.1487 + 28 -225.5840543587 0.885E-03 0.7010638810 0.0208791812 696.8526 + 29 -225.5839611143 0.858E-03 0.7006092484 0.0208547565 742.5406 + 30 -225.5840551992 0.834E-03 0.7015684842 0.0208570349 754.8701 + 31 -225.5839208274 0.818E-03 0.7004375677 0.0208406015 781.8266 + 32 -225.5838177023 0.799E-03 0.6994911903 0.0208314603 790.0876 + 33 -225.5837734655 0.775E-03 0.6991817256 0.0208215373 814.7476 + 35 -225.5840449138 0.770E-03 0.7014056053 0.0208591862 864.0476 + 36 -225.5839881583 0.750E-03 0.7008081785 0.0208540757 869.4226 + 37 -225.5841001031 0.731E-03 0.7012008181 0.0208852159 900.3616 + 38 -225.5841630948 0.715E-03 0.7017927307 0.0208931252 914.5366 + 39 -225.5842639218 0.703E-03 0.7026885239 0.0208997169 915.6597 + 40 -225.5842295407 0.686E-03 0.7022892857 0.0209007830 936.4516 + 41 -225.5841247699 0.677E-03 0.7015691291 0.0208817141 947.0827 + 42 -225.5841420771 0.661E-03 0.7011897342 0.0208973308 973.5868 + 43 -225.5840722498 0.649E-03 0.7007151072 0.0208886444 1006.0088 + 44 -225.5841258831 0.637E-03 0.7010044953 0.0209003069 1034.9028 + 48 -225.5839588854 0.585E-03 0.6997664959 0.0208812980 1059.3931 + 49 -225.5838631483 0.581E-03 0.6987328531 0.0208784489 1102.7027 + 50 -225.5838659028 0.570E-03 0.6989752754 0.0208725096 1104.9734 + 51 -225.5838815182 0.558E-03 0.6990482044 0.0208764925 1106.4948 + 52 -225.5839272013 0.549E-03 0.6992993478 0.0208877540 1125.0653 + 53 -225.5839114978 0.539E-03 0.6992724722 0.0208835489 1156.3397 + 55 -225.5838988623 0.521E-03 0.6992107338 0.0208790442 1188.1093 + 57 -225.5838482199 0.508E-03 0.6987481306 0.0208746987 1189.7627 + 58 -225.5839988050 0.510E-03 0.6997992494 0.0208926815 1210.8337 + 61 -225.5840506793 0.490E-03 0.7001746911 0.0208993184 1223.0665 + 62 -225.5839992802 0.484E-03 0.6998314840 0.0208911426 1235.9737 + 63 -225.5839278436 0.482E-03 0.6993744335 0.0208792045 1243.1527 + 64 -225.5839018884 0.475E-03 0.6991581196 0.0208777123 1267.1479 + 65 -225.5838266965 0.474E-03 0.6987375726 0.0208630445 1280.5737 + 67 -225.5838017072 0.460E-03 0.6985096138 0.0208623733 1303.0307 + 69 -225.5838536484 0.451E-03 0.6986678575 0.0208772430 1327.9540 + 71 -225.5838179988 0.457E-03 0.6984162321 0.0208730075 1348.8427 + 73 -225.5838604584 0.446E-03 0.6987467915 0.0208777759 1355.6987 + 74 -225.5838115793 0.442E-03 0.6983998873 0.0208697232 1383.1372 + 75 -225.5838379587 0.437E-03 0.6984870463 0.0208758008 1385.9396 + 76 -225.5838761799 0.433E-03 0.6992545082 0.0208706492 1409.3128 + 77 -225.5839230170 0.430E-03 0.6994883014 0.0208801658 1414.0721 + 78 -225.5839325735 0.425E-03 0.6996703641 0.0208780626 1481.5734 + 80 -225.5839513519 0.416E-03 0.6997797245 0.0208798240 1502.6113 + 86 -225.5840391777 0.392E-03 0.7003102737 0.0208961550 1546.3797 + 87 -225.5840573711 0.388E-03 0.7005808343 0.0208952147 1550.3747 + 89 -225.5840342298 0.381E-03 0.7005182384 0.0208912816 1574.8217 + 91 -225.5839600603 0.378E-03 0.6999257403 0.0208818877 1592.0237 + 93 -225.5839124319 0.372E-03 0.6996427232 0.0208744021 1634.1557 + 96 -225.5838915461 0.364E-03 0.6994039205 0.0208729730 1675.2949 + 100 -225.5838491900 0.359E-03 0.6988992192 0.0208721396 1687.5637 + 101 -225.5838247975 0.356E-03 0.6986567359 0.0208700758 1707.0307 + 103 -225.5837971197 0.350E-03 0.6983048282 0.0208701198 1714.0558 + 104 -225.5837532730 0.334E-03 0.6981760658 0.0208557559 1736.6934 + 105 -225.5837898428 0.333E-03 0.6983486828 0.0208622540 1752.8377 + 106 -225.5837657324 0.331E-03 0.6982733726 0.0208567129 1762.2807 + 110 -225.5837198457 0.320E-03 0.6977978432 0.0208532175 1788.5417 + 111 -225.5837111327 0.317E-03 0.6979095794 0.0208481777 1790.8567 + 112 -225.5837402220 0.316E-03 0.6981856861 0.0208505490 1792.9107 + 113 -225.5837316434 0.313E-03 0.6980805036 0.0208503055 1797.9587 + 114 -225.5837503680 0.311E-03 0.6982690321 0.0208521121 1856.6624 + 115 -225.5837258489 0.309E-03 0.6980188151 0.0208499182 1859.5338 + 118 -225.5836572344 0.305E-03 0.6974281532 0.0208408830 1872.9807 + 120 -225.5835691376 0.302E-03 0.6968431117 0.0208269381 1887.5457 + 122 -225.5835343805 0.301E-03 0.6965759601 0.0208223842 1904.9717 + 123 -225.5835831529 0.302E-03 0.6967869695 0.0208332909 1911.6177 + 124 -225.5835979063 0.300E-03 0.6970256550 0.0208324170 1977.7328 + 125 -225.5836123691 0.298E-03 0.6971442935 0.0208340428 1981.1147 + 126 -225.5836201499 0.296E-03 0.6971599212 0.0208353296 1993.3709 + 128 -225.5836683112 0.293E-03 0.6973936117 0.0208461285 2000.7114 + 129 -225.5836949506 0.292E-03 0.6976604250 0.0208479647 2003.6801 + 131 -225.5836894044 0.290E-03 0.6976860442 0.0208448541 2037.7368 + 134 -225.5837227565 0.284E-03 0.6979855708 0.0208472886 2059.9277 + 137 -225.5836814426 0.273E-03 0.6976798971 0.0208399328 2078.5478 + 138 -225.5836672735 0.271E-03 0.6975705237 0.0208376670 2096.6788 + 139 -225.5836514879 0.269E-03 0.6974972226 0.0208341894 2102.3787 + 141 -225.5836910164 0.268E-03 0.6976560580 0.0208429988 2131.3287 + 143 -225.5836925245 0.268E-03 0.6977213074 0.0208424809 2152.2358 + 144 -225.5836768860 0.266E-03 0.6976163536 0.0208403427 2213.2847 + 151 -225.5836628239 0.256E-03 0.6974288453 0.0208412736 2221.0817 + 152 -225.5835252629 0.248E-03 0.6964994908 0.0208197809 2227.4242 + 153 -225.5835170188 0.246E-03 0.6964884174 0.0208173638 2260.7528 + 154 -225.5834922774 0.246E-03 0.6963661025 0.0208126144 2277.6467 + 155 -225.5835246662 0.246E-03 0.6965969551 0.0208170987 2353.6617 + 163 -225.5836296844 0.241E-03 0.6972004899 0.0208359587 2379.3202 + 165 -225.5836676964 0.240E-03 0.6975594359 0.0208398245 2405.2082 + 168 -225.5836663074 0.236E-03 0.6973840648 0.0208442293 2413.4017 + 169 -225.5836654210 0.234E-03 0.6973373939 0.0208451604 2424.6417 + 170 -225.5836602944 0.233E-03 0.6972090664 0.0208465204 2479.0203 + 171 -225.5836498045 0.232E-03 0.6971523466 0.0208444361 2490.2865 + 175 -225.5836481440 0.234E-03 0.6971677119 0.0208443526 2523.2468 + 176 -225.5836166000 0.234E-03 0.6969697421 0.0208392790 2524.9485 + 179 -225.5836644805 0.232E-03 0.6973517772 0.0208459050 2532.7530 + 182 -225.5837230742 0.233E-03 0.6977164346 0.0208557262 2584.3738 + 187 -225.5837278812 0.228E-03 0.6977943936 0.0208572257 2638.9187 + 188 -225.5836980195 0.229E-03 0.6975635473 0.0208531188 2645.6557 + 192 -225.5836347282 0.227E-03 0.6973191367 0.0208390127 2648.4553 + 193 -225.5836475364 0.227E-03 0.6973231730 0.0208428660 2671.4946 + 197 -225.5836220136 0.223E-03 0.6972010480 0.0208370346 2707.6833 + 198 -225.5836364081 0.222E-03 0.6972997986 0.0208389844 2710.4493 + 201 -225.5837142221 0.217E-03 0.6976691035 0.0208557304 2718.5623 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.237041 GB ] [ VIRT MEM : 10.488945 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5714.537024 s ] [ CPU TIME: 405682.007264 s ] <<<<< .. + +* Number of generators 1310711 + +.. >>>>> [ RES MEM : 4.237041 GB ] [ VIRT MEM : 10.488945 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5714.540372 s ] [ CPU TIME: 405682.248763 s ] <<<<< .. + +* Number of selectors 1310711 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8479003785233515 + +Summary at N_det = 1310720 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.46783291 +# PT2 -0.11582146 0.00021970 +# rPT2 -0.11345601 0.00021522 +# +# E+PT2 -225.58365438 0.00021970 +# E+rPT2 -225.58128892 0.00021522 +# ============ ============================= + + N_det = 1310720 + N_states = 1 + + * State 1 + < S^2 > = 1.683351073407312E-003 + E = -225.467832913432 + Variance = 0.697151570391790 + PT norm = 0.144392200134754 + PT2 = -0.115821462426501 + rPT2 = -0.113456005966158 + E+PT2 = -225.583654375858 +/- 2.197027214205451E-004 + E+rPT2 = -225.581288919398 +/- 2.152156668552571E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -852.938811711335 + Vee = 238.834554656210 + Vecp = 0.000000000000000E+000 + T = 225.132074420629 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1162 -225.60613670 + -0.1278 -225.61448012 + -0.1629 -225.60624120 + -0.2138 -225.60553175 + -0.2716 -225.60533532 + -0.3300 -225.60498163 + -0.3849 -225.60467856 + =========== =================== + +* Number of unique beta determinants 302977 +* Number of unique alpha determinants 305856 + +.. >>>>> [ RES MEM : 4.303612 GB ] [ VIRT MEM : 10.643131 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5835.252308 s ] [ CPU TIME: 414194.770490 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 2621440 +* Number of threads for diagonalization 72 +* Memory(Gb) 4.380233172327280 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.4678329140 0.001683 0.239E-03 + 2 -225.4689282899 0.002044 0.968E-05 + 3 -225.4689388592 0.002051 0.147E-05 + 4 -225.4689412385 0.002073 0.229E-06 + 5 -225.4689417405 0.002087 0.377E-07 + 6 -225.4689418142 0.002087 0.383E-08 + 7 -225.4689418231 0.002086 0.420E-09 + 8 -225.4689418240 0.002086 0.392E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 6.421787 GB ] [ VIRT MEM : 13.448181 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6764.608994 s ] [ CPU TIME: 479453.659727 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 4.195309 GB ] [ VIRT MEM : 10.517017 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6764.847923 s ] [ CPU TIME: 479460.281157 s ] <<<<< .. + +* Energy of state 1 -225.4689418240497 +* S^2 of state 1 0.2085696818185221E-02 +* Saved determinants 2621440 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.052231 GB ] [ VIRT MEM : 10.153183 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6796.603244 s ] [ CPU TIME: 479914.645623 s ] <<<<< .. + +* Number of generators 2621415 + +.. >>>>> [ RES MEM : 4.052231 GB ] [ VIRT MEM : 10.153183 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6796.609318 s ] [ CPU TIME: 479915.082004 s ] <<<<< .. + +* Number of selectors 2621415 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 +* PT2 Energy denominator -225.4689418240497 + +.. >>>>> [ RES MEM : 4.332779 GB ] [ VIRT MEM : 10.435219 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6798.248814 s ] [ CPU TIME: 480017.950157 s ] <<<<< .. + +* Number of generators 2621415 + +.. >>>>> [ RES MEM : 4.332779 GB ] [ VIRT MEM : 10.435219 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6798.254900 s ] [ CPU TIME: 480018.387646 s ] <<<<< .. + +* Number of selectors 2621415 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 +* Number of tasks 3933480 +* Number of fragmented tasks 53632 +* Number of threads for PT2 72 +* Memory (Gb) 18.30065291766077 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5829958497 0.306E-02 0.6919607102 0.0203305502 330.6768 + 4 -225.5834355198 0.211E-02 0.6921762165 0.0205112916 375.1620 + 5 -225.5825816479 0.197E-02 0.6868879194 0.0203600229 450.1210 + 6 -225.5831230994 0.169E-02 0.6876975058 0.0205209538 571.9566 + 8 -225.5818457719 0.153E-02 0.6769657561 0.0203555285 640.2739 + 9 -225.5821420307 0.138E-02 0.6781442369 0.0204251519 691.4178 + 11 -225.5826742569 0.126E-02 0.6823022339 0.0205051759 740.8131 + 12 -225.5827062080 0.121E-02 0.6825810847 0.0204903506 803.9688 + 13 -225.5822401346 0.121E-02 0.6800891537 0.0203970827 844.2673 + 14 -225.5821677503 0.112E-02 0.6804508211 0.0203594701 891.9005 + 15 -225.5826300663 0.115E-02 0.6824176676 0.0204707141 954.1716 + 16 -225.5825164169 0.108E-02 0.6810012703 0.0204737257 955.6378 + 17 -225.5824594456 0.101E-02 0.6820372046 0.0204314935 961.4338 + 18 -225.5823167563 0.964E-03 0.6808635203 0.0204221311 1047.5167 + 19 -225.5820926375 0.971E-03 0.6796383275 0.0203910103 1068.0458 + 20 -225.5821403627 0.922E-03 0.6805787564 0.0203851477 1134.5168 + 21 -225.5821493123 0.877E-03 0.6805118806 0.0203917721 1149.1625 + 22 -225.5824488574 0.889E-03 0.6824010695 0.0204469118 1202.7058 + 23 -225.5821477420 0.902E-03 0.6803272041 0.0203981427 1245.4078 + 24 -225.5821162188 0.863E-03 0.6795664351 0.0204042507 1301.8718 + 26 -225.5819519373 0.821E-03 0.6786139745 0.0203697767 1335.0357 + 27 -225.5820658222 0.798E-03 0.6798637966 0.0203761067 1406.3047 + 28 -225.5824894093 0.758E-03 0.6818291334 0.0204725430 1415.5968 + 29 -225.5825896425 0.738E-03 0.6821195368 0.0204976986 1506.7212 + 30 -225.5825231924 0.716E-03 0.6818782661 0.0204848939 1555.2567 + 31 -225.5825251150 0.692E-03 0.6826524794 0.0204638554 1565.3318 + 32 -225.5826933672 0.691E-03 0.6844147639 0.0204708698 1613.7797 + 33 -225.5828549608 0.689E-03 0.6849306077 0.0205145125 1630.4458 + 34 -225.5828440713 0.669E-03 0.6849893460 0.0205055278 1721.1212 + 35 -225.5826497250 0.678E-03 0.6834983627 0.0204824967 1746.8517 + 36 -225.5827518585 0.667E-03 0.6841850544 0.0205067422 1792.8914 + 37 -225.5826846941 0.652E-03 0.6837131842 0.0204956957 1794.4543 + 38 -225.5828755060 0.663E-03 0.6851193348 0.0205188241 1841.5917 + 39 -225.5829596276 0.622E-03 0.6853370764 0.0205397882 1914.1036 + 41 -225.5830226999 0.596E-03 0.6863188489 0.0205379797 1921.2106 + 42 -225.5830301025 0.581E-03 0.6858667417 0.0205544262 1962.7022 + 43 -225.5830435097 0.568E-03 0.6864266679 0.0205418557 2070.2398 + 45 -225.5831343009 0.546E-03 0.6875645561 0.0205402025 2091.6637 + 47 -225.5830394653 0.530E-03 0.6874337292 0.0205094570 2140.0617 + 48 -225.5830661787 0.519E-03 0.6873547251 0.0205204946 2173.9053 + 49 -225.5831360582 0.491E-03 0.6875814956 0.0205388572 2244.2377 + 51 -225.5831460674 0.493E-03 0.6875973734 0.0205388767 2257.7477 + 52 -225.5832040994 0.487E-03 0.6879629945 0.0205480763 2339.5389 + 54 -225.5832227063 0.477E-03 0.6880099722 0.0205525441 2388.0518 + 55 -225.5832301520 0.468E-03 0.6879129303 0.0205578772 2394.1832 + 56 -225.5833786253 0.483E-03 0.6890454426 0.0205800703 2419.2750 + 58 -225.5834420244 0.471E-03 0.6890873627 0.0205984066 2486.5001 + 59 -225.5834373794 0.462E-03 0.6892144775 0.0205943100 2497.7671 + 60 -225.5834520485 0.455E-03 0.6894429688 0.0205929367 2526.1842 + 62 -225.5834745446 0.448E-03 0.6899232778 0.0205929065 2550.6027 + 63 -225.5835419887 0.446E-03 0.6901457601 0.0206126475 2635.7657 + 68 -225.5834899322 0.430E-03 0.6900193192 0.0205974451 2682.2141 + 69 -225.5835043418 0.424E-03 0.6900743892 0.0206009588 2704.0035 + 70 -225.5835263415 0.418E-03 0.6899905662 0.0206107983 2748.0923 + 71 -225.5834484714 0.419E-03 0.6895594972 0.0205947209 2770.1326 + 72 -225.5835198156 0.420E-03 0.6899265171 0.0206083374 2783.5480 + 74 -225.5835004605 0.409E-03 0.6897182834 0.0206072733 2870.4217 + 76 -225.5835587948 0.398E-03 0.6895879292 0.0206304683 2883.5573 + 77 -225.5835201054 0.395E-03 0.6891865726 0.0206281575 2982.8715 + 80 -225.5835996023 0.386E-03 0.6897560746 0.0206386389 3003.8279 + 82 -225.5836723425 0.385E-03 0.6903435113 0.0206483963 3059.2008 + 84 -225.5838003990 0.388E-03 0.6913329143 0.0206629641 3105.8148 + 85 -225.5837946584 0.384E-03 0.6911579395 0.0206651170 3136.6978 + 86 -225.5838810277 0.389E-03 0.6918472836 0.0206763694 3186.9240 + 87 -225.5838560253 0.385E-03 0.6916344090 0.0206733442 3195.2378 + 88 -225.5838852209 0.382E-03 0.6918521460 0.0206761120 3203.5087 + 89 -225.5839319023 0.380E-03 0.6920976394 0.0206846982 3229.5686 + 91 -225.5839467334 0.380E-03 0.6922451535 0.0206871689 3266.4295 + 92 -225.5839626145 0.376E-03 0.6923472223 0.0206897903 3308.6078 + 93 -225.5839601042 0.372E-03 0.6922877950 0.0206896472 3354.9727 + 96 -225.5839184704 0.367E-03 0.6918843320 0.0206859592 3391.5378 + 97 -225.5838944798 0.364E-03 0.6917049541 0.0206830194 3417.5978 + 100 -225.5838689296 0.355E-03 0.6917629534 0.0206715245 3430.8853 + 101 -225.5838139324 0.355E-03 0.6915389898 0.0206598280 3476.4851 + 103 -225.5838042545 0.349E-03 0.6913895899 0.0206604857 3503.9015 + 104 -225.5838220190 0.346E-03 0.6915569829 0.0206624582 3569.5287 + 105 -225.5838172570 0.343E-03 0.6914924718 0.0206626931 3594.9529 + 107 -225.5838403273 0.329E-03 0.6916201038 0.0206664550 3613.1586 + 110 -225.5838223059 0.326E-03 0.6913272768 0.0206670067 3650.8205 + 111 -225.5838306564 0.323E-03 0.6912319862 0.0206719701 3744.4899 + 112 -225.5838153992 0.321E-03 0.6911462037 0.0206693825 3766.2265 + 114 -225.5838149424 0.315E-03 0.6910500605 0.0206716648 3768.8801 + 115 -225.5838307135 0.313E-03 0.6909913446 0.0206780761 3815.3658 + 117 -225.5838663366 0.308E-03 0.6912399775 0.0206832297 3850.5039 + 120 -225.5838631792 0.311E-03 0.6913010014 0.0206807648 3880.6122 + 121 -225.5838779705 0.309E-03 0.6913527840 0.0206838421 3903.3788 + 123 -225.5839289316 0.308E-03 0.6917411622 0.0206909941 3983.7526 + 124 -225.5839786743 0.298E-03 0.6919750172 0.0207017094 3985.8644 + 125 -225.5840338783 0.301E-03 0.6922727807 0.0207127403 4017.1000 + 126 -225.5839814763 0.303E-03 0.6919489920 0.0207033118 4066.2957 + 128 -225.5839646028 0.299E-03 0.6917707380 0.0207011916 4125.0292 + 131 -225.5839401217 0.293E-03 0.6916695526 0.0206943515 4155.9388 + 134 -225.5839096068 0.288E-03 0.6914710703 0.0206901515 4187.6071 + 135 -225.5838939841 0.286E-03 0.6912890622 0.0206900486 4253.9257 + 137 -225.5839065765 0.277E-03 0.6914452220 0.0206921570 4268.1013 + 138 -225.5838956037 0.275E-03 0.6913675576 0.0206908314 4361.0707 + 142 -225.5839709432 0.272E-03 0.6918558670 0.0207042457 4388.1120 + 143 -225.5839892919 0.270E-03 0.6919520229 0.0207074002 4403.1079 + 144 -225.5839722722 0.269E-03 0.6918595068 0.0207049926 4468.2094 + 147 -225.5839980826 0.265E-03 0.6921775634 0.0207061337 4482.8962 + 148 -225.5840186050 0.264E-03 0.6923814810 0.0207082295 4493.5788 + 149 -225.5840023790 0.263E-03 0.6922943692 0.0207053842 4565.3627 + 151 -225.5839434231 0.263E-03 0.6919384996 0.0206953689 4583.2162 + 153 -225.5839516530 0.262E-03 0.6920903675 0.0206947044 4618.1921 + 154 -225.5839824200 0.254E-03 0.6924625233 0.0206950694 4665.4634 + 155 -225.5839686451 0.252E-03 0.6923395482 0.0206938719 4726.4660 + 156 -225.5839445805 0.252E-03 0.6921919703 0.0206893666 4729.2738 + 157 -225.5839508733 0.250E-03 0.6922175778 0.0206908656 4747.9263 + 158 -225.5839677133 0.249E-03 0.6923716158 0.0206927175 4748.9457 + 160 -225.5839780694 0.248E-03 0.6924467438 0.0206938332 4799.7107 + 161 -225.5840032723 0.247E-03 0.6926588362 0.0206966078 4831.9537 + 162 -225.5840378847 0.248E-03 0.6928895089 0.0207025255 4843.2950 + 163 -225.5840365590 0.247E-03 0.6928597048 0.0207028667 4872.8821 + 165 -225.5840694296 0.246E-03 0.6930089116 0.0207094835 4935.0684 + 168 -225.5840403709 0.247E-03 0.6927479873 0.0207059711 4943.0305 + 169 -225.5840662248 0.245E-03 0.6928371719 0.0207117830 4974.4341 + 170 -225.5840953882 0.245E-03 0.6929805713 0.0207174222 5015.9176 + 171 -225.5840743521 0.245E-03 0.6928381834 0.0207143547 5023.9845 + 172 -225.5840550033 0.244E-03 0.6927015799 0.0207112884 5043.1003 + 173 -225.5840832481 0.244E-03 0.6928997811 0.0207155113 5074.0113 + 175 -225.5840732705 0.241E-03 0.6928782147 0.0207126035 5144.4488 + 176 -225.5840685294 0.240E-03 0.6928008992 0.0207126682 5161.1498 + 177 -225.5840832243 0.239E-03 0.6928519406 0.0207162163 5173.4259 + 181 -225.5840411244 0.238E-03 0.6925719700 0.0207102346 5182.6668 + 182 -225.5840203031 0.237E-03 0.6924528654 0.0207062111 5248.9808 + 185 -225.5840172416 0.231E-03 0.6925017015 0.0207037023 5295.3001 + 189 -225.5840298409 0.229E-03 0.6925563829 0.0207064422 5308.7497 + 190 -225.5840316939 0.228E-03 0.6926728759 0.0207049715 5355.0633 + 191 -225.5840304805 0.227E-03 0.6926833358 0.0207041516 5371.9620 + 193 -225.5840532989 0.227E-03 0.6927857407 0.0207084677 5421.3530 + 194 -225.5840472912 0.226E-03 0.6927825494 0.0207063828 5436.1839 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 5.387646 GB ] [ VIRT MEM : 11.809334 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12246.396633 s ] [ CPU TIME: 863926.333615 s ] <<<<< .. + +* Number of generators 2621415 + +.. >>>>> [ RES MEM : 5.387646 GB ] [ VIRT MEM : 11.809334 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12246.402763 s ] [ CPU TIME: 863926.774317 s ] <<<<< .. + +* Number of selectors 2621415 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8489052486509879 + +Summary at N_det = 2621440 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.46894182 +# PT2 -0.11510547 0.00022634 +# rPT2 -0.11277040 0.00022175 +# +# E+PT2 -225.58404729 0.00022634 +# E+rPT2 -225.58171222 0.00022175 +# ============ ============================= + + N_det = 2621440 + N_states = 1 + + * State 1 + < S^2 > = 2.085696818185221E-003 + E = -225.468941824050 + Variance = 0.692782549351766 + PT norm = 0.143897125875059 + PT2 = -0.115105467180190 + rPT2 = -0.112770400103185 + E+PT2 = -225.584047291230 +/- 2.263408138669266E-004 + E+rPT2 = -225.581712224153 +/- 2.217491902404343E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -852.939425862584 + Vee = 238.831851398746 + Vecp = 0.000000000000000E+000 + T = 225.134282918724 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1135 -225.65133859 + -0.1162 -225.61262915 + -0.1278 -225.61502725 + -0.1629 -225.60685058 + -0.2138 -225.60592001 + -0.2716 -225.60562954 + -0.3300 -225.60525051 + =========== =================== + +* Number of unique beta determinants 549134 +* Number of unique alpha determinants 557549 + +.. >>>>> [ RES MEM : 5.017788 GB ] [ VIRT MEM : 11.744289 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12537.373077 s ] [ CPU TIME: 884297.462155 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5242880 +* Number of threads for diagonalization 72 +* Memory(Gb) 8.600335858762264 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.4689418248 0.002086 0.316E-03 + 2 -225.4703920094 0.002450 0.202E-04 + 3 -225.4704145814 0.002471 0.386E-05 + 4 -225.4704227613 0.002504 0.120E-05 + 5 -225.4704255898 0.002509 0.115E-06 + 6 -225.4704258271 0.002507 0.145E-07 + 7 -225.4704258623 0.002506 0.183E-08 + 8 -225.4704258665 0.002505 0.191E-09 + 9 -225.4704258668 0.002505 0.190E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 10.220501 GB ] [ VIRT MEM : 18.124149 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15082.284571 s ] [ CPU TIME: 1062334.517504 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 5.376907 GB ] [ VIRT MEM : 12.106556 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15082.787619 s ] [ CPU TIME: 1062341.241354 s ] <<<<< .. + +* Energy of state 1 -225.4704258668128 +* S^2 of state 1 0.2504960725742637E-02 +* Saved determinants 5242880 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 5.263435 GB ] [ VIRT MEM : 11.675865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15153.516318 s ] [ CPU TIME: 1063223.284233 s ] <<<<< .. + +* Number of generators 5242768 + +.. >>>>> [ RES MEM : 5.263435 GB ] [ VIRT MEM : 11.675865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15153.528088 s ] [ CPU TIME: 1063224.129684 s ] <<<<< .. + +* Number of selectors 5242768 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 +* PT2 Energy denominator -225.4704258668128 + +.. >>>>> [ RES MEM : 6.101482 GB ] [ VIRT MEM : 12.515232 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15157.162785 s ] [ CPU TIME: 1063409.509637 s ] <<<<< .. + +* Number of generators 5242768 + +.. >>>>> [ RES MEM : 6.101482 GB ] [ VIRT MEM : 12.515232 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15157.173991 s ] [ CPU TIME: 1063409.520752 s ] <<<<< .. + +* Number of selectors 5242768 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 +* Number of tasks 7409747 +* Number of fragmented tasks 54135 +* Number of threads for PT2 72 +* Memory (Gb) 18.57659448444843 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5838602199 0.133E-02 0.6863287167 0.0202986688 681.6599 + 4 -225.5835401991 0.961E-03 0.6858420551 0.0201917756 833.7849 + 5 -225.5834196525 0.813E-03 0.6834698988 0.0202198171 947.6180 + 6 -225.5838241123 0.781E-03 0.6854343662 0.0202959380 1164.0170 + 7 -225.5846054566 0.105E-02 0.6907039994 0.0204297840 1242.4074 + 8 -225.5843472667 0.974E-03 0.6873817986 0.0204512459 1384.8906 + 9 -225.5851659768 0.120E-02 0.6907957877 0.0206330113 1520.6779 + 10 -225.5846878368 0.118E-02 0.6868412211 0.0205736450 1557.2390 + 11 -225.5855701725 0.140E-02 0.6932286177 0.0207126639 1643.9249 + 12 -225.5859346953 0.133E-02 0.6944975019 0.0208000694 1757.6832 + 13 -225.5856493352 0.126E-02 0.6939260684 0.0207163812 1900.4711 + 14 -225.5854768646 0.117E-02 0.6932152830 0.0206764635 2027.2419 + 15 -225.5853797511 0.110E-02 0.6929334916 0.0206510222 2129.8701 + 16 -225.5854758762 0.103E-02 0.6925214718 0.0206903601 2132.5570 + 17 -225.5853934370 0.968E-03 0.6919991881 0.0206729984 2262.1105 + 18 -225.5854214301 0.939E-03 0.6945828311 0.0206185821 2381.0739 + 19 -225.5851802579 0.920E-03 0.6939674574 0.0205581665 2456.7490 + 20 -225.5851556102 0.873E-03 0.6938926844 0.0205521391 2610.5613 + 21 -225.5851154506 0.831E-03 0.6939807697 0.0205315082 2639.1000 + 22 -225.5848993176 0.821E-03 0.6927592366 0.0204922026 2763.8063 + 23 -225.5846730559 0.817E-03 0.6915695841 0.0204427115 2859.4579 + 24 -225.5845405652 0.793E-03 0.6903163969 0.0204353740 2932.4800 + 25 -225.5843459634 0.785E-03 0.6891294261 0.0204019800 3036.0399 + 26 -225.5843241011 0.755E-03 0.6891933569 0.0203916998 3098.0440 + 27 -225.5844090442 0.731E-03 0.6893236105 0.0204166828 3232.3507 + 28 -225.5843408502 0.707E-03 0.6889638136 0.0204011116 3313.3639 + 29 -225.5846223303 0.738E-03 0.6903769874 0.0204607871 3522.0530 + 30 -225.5845250400 0.720E-03 0.6897388240 0.0204470730 3640.1354 + 31 -225.5841548323 0.790E-03 0.6873023337 0.0203902592 3661.8989 + 32 -225.5839842174 0.784E-03 0.6857175464 0.0203768813 3828.5932 + 33 -225.5840286633 0.761E-03 0.6867069408 0.0203670492 3943.5400 + 34 -225.5837624536 0.785E-03 0.6846350431 0.0203293179 3981.7021 + 35 -225.5837610900 0.762E-03 0.6845507107 0.0203269668 4072.8474 + 36 -225.5837634633 0.741E-03 0.6845151922 0.0203262195 4195.9705 + 37 -225.5837648161 0.720E-03 0.6844161891 0.0203259538 4250.4760 + 38 -225.5835784402 0.710E-03 0.6831706318 0.0202947847 4284.0932 + 39 -225.5837308650 0.708E-03 0.6838483121 0.0203308140 4377.6238 + 40 -225.5837929731 0.693E-03 0.6840713578 0.0203471867 4504.7474 + 41 -225.5838372681 0.677E-03 0.6839060635 0.0203680245 4594.4719 + 42 -225.5838376418 0.661E-03 0.6837772534 0.0203695516 4715.0101 + 43 -225.5838871038 0.647E-03 0.6841378613 0.0203750461 4788.1472 + 44 -225.5839909706 0.640E-03 0.6847114857 0.0203986961 4834.6461 + 45 -225.5841532911 0.647E-03 0.6853521463 0.0204352445 4908.2189 + 46 -225.5839870699 0.654E-03 0.6842361673 0.0204082111 4961.9883 + 47 -225.5838406246 0.657E-03 0.6830723167 0.0203855829 5089.3979 + 48 -225.5837923901 0.645E-03 0.6825866736 0.0203841701 5113.7422 + 49 -225.5838501007 0.629E-03 0.6835670941 0.0203695954 5184.9160 + 50 -225.5839126550 0.620E-03 0.6842617729 0.0203740517 5314.9866 + 51 -225.5839670227 0.610E-03 0.6843913392 0.0203902081 5385.8464 + 52 -225.5838632655 0.607E-03 0.6839243868 0.0203701228 5496.2609 + 54 -225.5838398649 0.585E-03 0.6837073506 0.0203712094 5671.8961 + 55 -225.5838388828 0.574E-03 0.6838491388 0.0203669133 5683.4910 + 57 -225.5837892191 0.555E-03 0.6835600240 0.0203590956 5744.7671 + 58 -225.5837178028 0.550E-03 0.6833578341 0.0203388606 5872.3162 + 59 -225.5837326613 0.540E-03 0.6831995015 0.0203492428 5879.8120 + 61 -225.5836731910 0.521E-03 0.6827689411 0.0203466670 5966.0041 + 62 -225.5837979090 0.527E-03 0.6835653879 0.0203656107 6027.5859 + 63 -225.5837620558 0.520E-03 0.6829816376 0.0203686040 6100.6680 + 64 -225.5838228473 0.516E-03 0.6833772381 0.0203769514 6141.9719 + 67 -225.5838204218 0.496E-03 0.6835139657 0.0203760141 6196.8482 + 68 -225.5838718811 0.492E-03 0.6836974734 0.0203879877 6294.1530 + 69 -225.5837828365 0.493E-03 0.6830202882 0.0203746540 6408.6592 + 71 -225.5836046073 0.480E-03 0.6820890594 0.0203391546 6485.9513 + 72 -225.5835504385 0.477E-03 0.6818943035 0.0203241825 6540.0058 + 73 -225.5835720393 0.471E-03 0.6819872230 0.0203302028 6561.6437 + 74 -225.5836091704 0.466E-03 0.6822172804 0.0203374268 6695.6589 + 75 -225.5836306231 0.460E-03 0.6823897131 0.0203404746 6699.5069 + 76 -225.5835514998 0.461E-03 0.6820245070 0.0203230671 6738.6150 + 77 -225.5835863141 0.456E-03 0.6822508547 0.0203278971 6841.0599 + 78 -225.5836177840 0.451E-03 0.6823555753 0.0203348364 6969.1612 + 80 -225.5835820572 0.442E-03 0.6823736732 0.0203216239 7044.8989 + 81 -225.5835493647 0.438E-03 0.6823056699 0.0203129438 7063.0469 + 82 -225.5836331867 0.440E-03 0.6829681698 0.0203247373 7165.7889 + 84 -225.5837043328 0.435E-03 0.6835570328 0.0203317270 7253.8269 + 85 -225.5836888679 0.430E-03 0.6836085136 0.0203249048 7296.5690 + 86 -225.5836855192 0.425E-03 0.6835745693 0.0203239600 7399.2402 + 87 -225.5836681533 0.420E-03 0.6834242812 0.0203211839 7513.4954 + 89 -225.5836005340 0.400E-03 0.6831634096 0.0203013647 7524.1075 + 91 -225.5836395655 0.392E-03 0.6834977768 0.0203047052 7665.1819 + 92 -225.5836870904 0.391E-03 0.6839527242 0.0203087717 7684.8259 + 93 -225.5837079342 0.387E-03 0.6839544479 0.0203156742 7749.7209 + 94 -225.5837513985 0.385E-03 0.6841917932 0.0203239105 7778.5475 + 95 -225.5836906931 0.386E-03 0.6836519654 0.0203177397 7827.3386 + 96 -225.5837151561 0.383E-03 0.6839175281 0.0203197517 7928.6901 + 97 -225.5836905254 0.380E-03 0.6838420555 0.0203142821 7981.7429 + 100 -225.5836400718 0.375E-03 0.6833388406 0.0203105078 8024.7209 + 101 -225.5835993764 0.374E-03 0.6830133497 0.0203049194 8037.0423 + 103 -225.5836101104 0.366E-03 0.6829853932 0.0203088056 8166.8759 + 104 -225.5836452817 0.365E-03 0.6831493563 0.0203160779 8258.0919 + 105 -225.5837241521 0.360E-03 0.6836396587 0.0203316156 8351.4401 + 106 -225.5837177165 0.357E-03 0.6836037731 0.0203303932 8352.5479 + 107 -225.5837809665 0.359E-03 0.6840504986 0.0203402176 8375.6770 + 109 -225.5836741916 0.360E-03 0.6833249439 0.0203241126 8411.0102 + 110 -225.5836656899 0.357E-03 0.6833193028 0.0203212440 8484.6860 + 111 -225.5836993096 0.355E-03 0.6835236669 0.0203271173 8550.4469 + 112 -225.5837279980 0.353E-03 0.6836111967 0.0203335812 8645.8839 + 113 -225.5837215713 0.350E-03 0.6835809226 0.0203324138 8652.0165 + 114 -225.5837726125 0.351E-03 0.6839793727 0.0203381916 8723.0226 + 115 -225.5837588266 0.348E-03 0.6840076643 0.0203332520 8756.8608 + 116 -225.5838053700 0.348E-03 0.6843094771 0.0203410401 8761.9997 + 117 -225.5837811419 0.346E-03 0.6841497242 0.0203374526 8823.6869 + 118 -225.5837756347 0.343E-03 0.6841464363 0.0203364855 8884.3770 + 120 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0.6855506735 0.0203603564 11555.8400 + 173 -225.5839586102 0.263E-03 0.6855774070 0.0203636388 11592.1426 + 174 -225.5839619629 0.262E-03 0.6856009873 0.0203640730 11643.1307 + 175 -225.5839700862 0.260E-03 0.6857102515 0.0203640183 11684.6217 + 176 -225.5839535062 0.259E-03 0.6856173930 0.0203609345 11742.7220 + 177 -225.5839535625 0.258E-03 0.6855758957 0.0203619032 11779.0496 + 179 -225.5839854374 0.258E-03 0.6859657513 0.0203623077 11844.7069 + 181 -225.5839779674 0.252E-03 0.6860814791 0.0203556672 11908.8499 + 182 -225.5839651741 0.251E-03 0.6859474886 0.0203548329 11968.0107 + 183 -225.5839484879 0.250E-03 0.6858072212 0.0203528614 12010.1095 + 184 -225.5839424774 0.249E-03 0.6857196266 0.0203531168 12025.7336 + 187 -225.5838876584 0.247E-03 0.6853556876 0.0203451152 12037.4589 + 188 -225.5839135665 0.247E-03 0.6855835668 0.0203473726 12167.9263 + 190 -225.5839095647 0.246E-03 0.6854858608 0.0203486489 12219.9199 + 191 -225.5839224756 0.245E-03 0.6856076358 0.0203501427 12251.5992 + 192 -225.5839106428 0.244E-03 0.6855308400 0.0203480821 12274.8932 + 193 -225.5839266901 0.243E-03 0.6855928195 0.0203516072 12317.3838 + 194 -225.5839273204 0.242E-03 0.6855876916 0.0203520714 12448.5279 + 197 -225.5839076740 0.239E-03 0.6855031956 0.0203474777 12462.6556 + 198 -225.5839873771 0.236E-03 0.6858129045 0.0203661867 12550.3372 + 201 -225.5840011297 0.233E-03 0.6858065308 0.0203705880 12581.8079 + 202 -225.5840074345 0.232E-03 0.6858200802 0.0203719061 12617.7409 + 203 -225.5840216002 0.231E-03 0.6858687866 0.0203752869 12645.8511 + 204 -225.5840004461 0.231E-03 0.6857012781 0.0203723600 12681.4804 + 205 -225.5839810983 0.231E-03 0.6855698009 0.0203690313 12720.0831 + 206 -225.5839679334 0.230E-03 0.6855179054 0.0203661468 12799.3901 + 207 -225.5839719685 0.229E-03 0.6855894674 0.0203661527 12851.7690 + 208 -225.5839796691 0.228E-03 0.6856398892 0.0203672176 12860.4185 + 209 -225.5839542673 0.228E-03 0.6854653371 0.0203632934 12863.7340 + 212 -225.5839885975 0.230E-03 0.6856470613 0.0203695694 12933.6482 + 213 -225.5840074742 0.229E-03 0.6857503678 0.0203730682 13004.7849 + 215 -225.5840004708 0.228E-03 0.6855949626 0.0203748361 13020.8260 + 216 -225.5840116763 0.227E-03 0.6856337629 0.0203772103 13090.2679 + 217 -225.5840269822 0.226E-03 0.6856894884 0.0203808862 13141.7140 + 218 -225.5840387376 0.225E-03 0.6857514095 0.0203832942 13219.1348 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 6.670895 GB ] [ VIRT MEM : 12.550816 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 28399.599856 s ] [ CPU TIME: 1997986.788891 s ] <<<<< .. + +* Number of generators 5242768 + +.. >>>>> [ RES MEM : 6.670895 GB ] [ VIRT MEM : 12.550816 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 28399.611028 s ] [ CPU TIME: 1997986.799980 s ] <<<<< .. + +* Number of selectors 5242768 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8508637386507135 + +Summary at N_det = 5242880 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.47042587 +# PT2 -0.11358059 0.00021829 +# rPT2 -0.11131258 0.00021393 +# +# E+PT2 -225.58400645 0.00021829 +# E+rPT2 -225.58173845 0.00021393 +# ============ ============================= + + N_det = 5242880 + N_states = 1 + + * State 1 + < S^2 > = 2.504960725742637E-003 + E = -225.470425866813 + Variance = 0.685634500479369 + PT norm = 0.142741358739979 + PT2 = -0.113580585708092 + rPT2 = -0.111312581235629 + E+PT2 = -225.584006452521 +/- 2.182881063807722E-004 + E+rPT2 = -225.581738448048 +/- 2.139292769340779E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -852.940619132566 + Vee = 238.828217793643 + Vecp = 0.000000000000000E+000 + T = 225.137625751046 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1128 -225.58374079 + -0.1135 -225.60179871 + -0.1162 -225.60745506 + -0.1278 -225.61388865 + -0.1629 -225.60690305 + -0.2138 -225.60599494 + -0.2716 -225.60570051 + =========== =================== + +* Number of unique beta determinants 950253 +* Number of unique alpha determinants 968758 + +.. >>>>> [ RES MEM : 7.718277 GB ] [ VIRT MEM : 15.161880 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 29239.455719 s ] [ CPU TIME: 2056407.263804 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 10485760 +* Number of threads for diagonalization 72 +* Memory(Gb) 16.76823606714606 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.4704258673 0.002505 0.311E-03 + 2 -225.4719171172 0.003014 0.120E-04 + 3 -225.4719303911 0.003031 0.198E-05 + 4 -225.4719338606 0.003050 0.343E-06 + 5 -225.4719349892 0.003055 0.781E-07 + 6 -225.4719351469 0.003055 0.632E-08 + 7 -225.4719351650 0.003052 0.117E-08 + 8 -225.4719351674 0.003052 0.136E-09 + 9 -225.4719351678 0.003052 0.166E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 18.088837 GB ] [ VIRT MEM : 27.856239 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 36594.405666 s ] [ CPU TIME: 2568841.222369 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.401566 GB ] [ VIRT MEM : 15.823021 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 36595.361424 s ] [ CPU TIME: 2568847.866875 s ] <<<<< .. + +* Energy of state 1 -225.4719351677995 +* S^2 of state 1 0.3052006978681041E-02 +* Saved determinants 10485760 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 7.467560 GB ] [ VIRT MEM : 14.315590 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 36725.421758 s ] [ CPU TIME: 2570496.359232 s ] <<<<< .. + +* Number of generators 10485533 + +.. >>>>> [ RES MEM : 7.467560 GB ] [ VIRT MEM : 14.315590 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 36725.444680 s ] [ CPU TIME: 2570498.005881 s ] <<<<< .. + +* Number of selectors 10485533 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -225.4719351677995 + +.. >>>>> [ RES MEM : 8.521282 GB ] [ VIRT MEM : 15.369801 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 36732.552880 s ] [ CPU TIME: 2570858.648722 s ] <<<<< .. + +* Number of generators 10485533 + +.. >>>>> [ RES MEM : 8.521282 GB ] [ VIRT MEM : 15.369801 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 36732.574835 s ] [ CPU TIME: 2570858.670567 s ] <<<<< .. + +* Number of selectors 10485533 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 13040953 +* Number of fragmented tasks 54473 +* Number of threads for PT2 72 +* Memory (Gb) 18.33211432736367 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5806309896 0.297E-02 0.6511677671 0.0196069872 1225.8223 + 4 -225.5819612202 0.247E-02 0.6620560306 0.0197766040 1435.6978 + 5 -225.5810551716 0.224E-02 0.6562509911 0.0196263439 1711.4417 + 6 -225.5815321319 0.187E-02 0.6599749001 0.0197247472 2047.0332 + 7 -225.5817431305 0.158E-02 0.6591449637 0.0197969061 2290.1082 + 8 -225.5830335716 0.198E-02 0.6688218721 0.0199850179 2555.0863 + 9 -225.5836365177 0.185E-02 0.6730462192 0.0200682183 2848.5248 + 10 -225.5837317098 0.164E-02 0.6740215444 0.0200635114 2940.1460 + 11 -225.5834114318 0.151E-02 0.6725712526 0.0200088782 3172.6452 + 12 -225.5837173493 0.141E-02 0.6749700372 0.0200409630 3327.0002 + 13 -225.5835453964 0.131E-02 0.6747820983 0.0199788042 3578.0124 + 14 -225.5833843989 0.122E-02 0.6737930493 0.0199451155 3757.3147 + 15 -225.5839821589 0.129E-02 0.6774203113 0.0200499170 4037.1357 + 16 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19777.0995 + 155 -225.5844910584 0.256E-03 0.6813546811 0.0201285444 19927.2123 + 156 -225.5845137208 0.255E-03 0.6814922829 0.0201324202 20075.8191 + 158 -225.5845199919 0.252E-03 0.6815718815 0.0201327240 20086.7085 + 159 -225.5845290744 0.251E-03 0.6816828527 0.0201330655 20242.5783 + 160 -225.5845089689 0.250E-03 0.6815274140 0.0201296750 20299.6052 + 161 -225.5845015988 0.249E-03 0.6814256661 0.0201300160 20318.9753 + 162 -225.5845041654 0.247E-03 0.6814751944 0.0201296924 20367.2482 + 163 -225.5844967753 0.246E-03 0.6814516917 0.0201277377 20560.1552 + 165 -225.5844868117 0.243E-03 0.6813503694 0.0201282305 20749.7273 + 167 -225.5844687729 0.241E-03 0.6812383163 0.0201253625 20800.0570 + 168 -225.5844511219 0.240E-03 0.6811516741 0.0201217600 20872.7194 + 169 -225.5844557206 0.228E-03 0.6812774729 0.0201214477 20988.6113 + 170 -225.5844666164 0.227E-03 0.6813237710 0.0201236181 21112.6075 + 171 -225.5844765113 0.226E-03 0.6814258138 0.0201250665 21223.3408 + 172 -225.5844610820 0.225E-03 0.6813413312 0.0201223791 21386.9614 + 173 -225.5844607743 0.224E-03 0.6813153235 0.0201231540 21424.2377 + 174 -225.5844840145 0.224E-03 0.6814698355 0.0201271966 21473.8518 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 11.272049 GB ] [ VIRT MEM : 17.161625 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 58247.496443 s ] [ CPU TIME: 4109288.679803 s ] <<<<< .. + +* Number of generators 10485533 + +.. >>>>> [ RES MEM : 11.272049 GB ] [ VIRT MEM : 17.161625 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 58247.520113 s ] [ CPU TIME: 4109288.702704 s ] <<<<< .. + +* Number of selectors 10485533 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +Summary at N_det = 10485760 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.47193517 +# PT2 -0.11254885 0.00022362 +# rPT2 -0.11032825 0.00021921 +# +# E+PT2 -225.58448401 0.00022362 +# E+rPT2 -225.58226342 0.00021921 +# ============ ============================= + + N_det = 10485760 + N_states = 1 + + * State 1 + < S^2 > = 3.052006978681041E-003 + E = -225.471935167799 + Variance = 0.681469835530987 + PT norm = 0.141870351447676 + PT2 = -0.112548846691349 + rPT2 = -0.110328248344197 + E+PT2 = -225.584484014491 +/- 2.236226555105656E-004 + E+rPT2 = -225.582263416144 +/- 2.192105614393205E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -852.941022089662 + Vee = 238.824017585071 + Vecp = 0.000000000000000E+000 + T = 225.140719615728 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1113 -225.64110409 + -0.1128 -225.60529914 + -0.1135 -225.61080307 + -0.1162 -225.61011468 + -0.1278 -225.61396928 + -0.1629 -225.60718178 + -0.2138 -225.60618415 + =========== =================== + +Wall time: 16:11:24 + diff --git a/imidazole/cc-pvdz/imidazole.natorb.out b/imidazole/cc-pvdz/imidazole.natorb.out new file mode 100644 index 0000000..4547f95 --- /dev/null +++ b/imidazole/cc-pvdz/imidazole.natorb.out @@ -0,0 +1,214 @@ +Date: 29/10/2020 03:20:28 +=============== +Quantum Package +=============== + +Git Commit: Fix space in size for EZFIO.cfg +Git Date : Fri Oct 16 14:24:01 2020 +0200 +Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b +EZFIO Dir : imidazole + + +Task server running : tcp://172.28.0.238:41279 +.. >>>>> [ IO READ: n_states ] <<<<< .. + +.. >>>>> [ RES MEM : 0.009010 GB ] [ VIRT MEM : 0.137966 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.027578 s ] [ CPU TIME: 0.021544 s ] <<<<< .. + +.. >>>>> [ IO READ: read_wf ] <<<<< .. + +.. >>>>> [ RES MEM : 0.009197 GB ] [ VIRT MEM : 0.137966 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.029817 s ] [ CPU TIME: 0.022395 s ] <<<<< .. + +.. >>>>> [ IO READ: elec_beta_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.009197 GB ] [ VIRT MEM : 0.137966 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.044630 s ] [ CPU TIME: 0.023441 s ] <<<<< .. + +.. >>>>> [ IO READ: elec_alpha_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.009197 GB ] [ VIRT MEM : 0.137966 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.045266 s ] [ CPU TIME: 0.023881 s ] <<<<< .. + +* mo_num 90 + Read mo_occ +.. >>>>> [ IO READ: mo_class ] <<<<< .. + +.. >>>>> [ RES MEM : 0.011032 GB ] [ VIRT MEM : 4.857162 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.101769 s ] [ CPU TIME: 1.359214 s ] <<<<< .. + +* Number of virtual MOs 0 + Virtual MOs: + +.. >>>>> [ IO READ: ao_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.011032 GB ] [ VIRT MEM : 4.857162 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.119288 s ] [ CPU TIME: 2.424758 s ] <<<<< .. + + Read mo_coef + * mo_label Canonical +* Number of determinants 10485760 +* Dimension of the psi arrays 10485760 +* N_int 2 + Read psi_det +* Number of unique beta determinants 950253 +* Number of unique alpha determinants 968758 + Read psi_coef 10485760 1 +.. >>>>> [ IO READ: weight_one_e_dm ] <<<<< .. + +.. >>>>> [ RES MEM : 2.212677 GB ] [ VIRT MEM : 7.142673 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 140.547786 s ] [ CPU TIME: 3695.789602 s ] <<<<< .. + +* Number of active MOs 85 +* Number of core MOs 5 +* Number of inactive MOs 0 + Core MOs: + 1 2 3 4 5 + Active MOs: + 6 7 8 9 10 11 + 12 13 14 15 16 17 + 18 19 20 21 22 23 + 24 25 26 27 28 29 + 30 31 32 33 34 35 + 36 37 38 39 40 41 + 42 43 44 45 46 47 + 48 49 50 51 52 53 + 54 55 56 57 58 59 + 60 61 62 63 64 65 + 66 67 68 69 70 71 + 72 73 74 75 76 77 + 78 79 80 81 82 83 + 84 85 86 87 88 89 + 90 + Core, Inactive and Active MOs: + 1 2 3 4 5 6 + 7 8 9 10 11 12 + 13 14 15 16 17 18 + 19 20 21 22 23 24 + 25 26 27 28 29 30 + 31 32 33 34 35 36 + 37 38 39 40 41 42 + 43 44 45 46 47 48 + 49 50 51 52 53 54 + 55 56 57 58 59 60 + 61 62 63 64 65 66 + 67 68 69 70 71 72 + 73 74 75 76 77 78 + 79 80 81 82 83 84 + 85 86 87 88 89 90 + +.. >>>>> [ RES MEM : 2.212845 GB ] [ VIRT MEM : 7.142673 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 140.551779 s ] [ CPU TIME: 3696.074213 s ] <<<<< .. + +MOs are now **Natural** + +Eigenvalues +----------- + +======== ================ ================ + MO Eigenvalue Cumulative +======== ================ ================ + 1 2.0000000000 2.0000000000 + 2 2.0000000000 4.0000000000 + 3 2.0000000000 6.0000000000 + 4 2.0000000000 8.0000000000 + 5 2.0000000000 10.0000000000 + 6 1.9885799357 11.9885799357 + 7 1.9860205969 13.9746005326 + 8 1.9843574478 15.9589579804 + 9 1.9798705610 17.9388285414 + 10 1.9795557503 19.9183842917 + 11 1.9791071183 21.8974914100 + 12 1.9749448933 23.8724363034 + 13 1.9741694381 25.8466057414 + 14 1.9736442220 27.8202499634 + 15 1.9718914667 29.7921414301 + 16 1.9711316607 31.7632730907 + 17 1.9553359976 33.7186090883 + 18 1.9401612494 35.6587703377 + 19 0.0508353951 35.7096057328 + 20 0.0400727162 35.7496784490 + 21 0.0194433540 35.7691218030 + 22 0.0172578591 35.7863796621 + 23 0.0158980485 35.8022777106 + 24 0.0156305442 35.8179082548 + 25 0.0133319551 35.8312402099 + 26 0.0127684787 35.8440086886 + 27 0.0118427946 35.8558514831 + 28 0.0108024742 35.8666539573 + 29 0.0097314824 35.8763854397 + 30 0.0074810417 35.8838664814 + 31 0.0072307737 35.8910972551 + 32 0.0066575415 35.8977547966 + 33 0.0056958311 35.9034506277 + 34 0.0056267786 35.9090774063 + 35 0.0055975350 35.9146749413 + 36 0.0054559949 35.9201309362 + 37 0.0051706825 35.9253016186 + 38 0.0051168771 35.9304184958 + 39 0.0050441615 35.9354626573 + 40 0.0048518708 35.9403145281 + 41 0.0044467106 35.9447612387 + 42 0.0043895478 35.9491507865 + 43 0.0040704060 35.9532211925 + 44 0.0032325404 35.9564537329 + 45 0.0031425373 35.9595962701 + 46 0.0029175943 35.9625138644 + 47 0.0026641351 35.9651779995 + 48 0.0024173276 35.9675953271 + 49 0.0022885091 35.9698838361 + 50 0.0022184877 35.9721023239 + 51 0.0021060300 35.9742083539 + 52 0.0020217646 35.9762301185 + 53 0.0017622695 35.9779923881 + 54 0.0016013678 35.9795937559 + 55 0.0015478211 35.9811415770 + 56 0.0012477552 35.9823893322 + 57 0.0011294411 35.9835187733 + 58 0.0011081297 35.9846269030 + 59 0.0010417993 35.9856687023 + 60 0.0010232923 35.9866919946 + 61 0.0009952824 35.9876872770 + 62 0.0009570383 35.9886443153 + 63 0.0009405703 35.9895848856 + 64 0.0009341338 35.9905190194 + 65 0.0008551737 35.9913741931 + 66 0.0007492813 35.9921234744 + 67 0.0007365546 35.9928600290 + 68 0.0007266091 35.9935866381 + 69 0.0006349265 35.9942215646 + 70 0.0005869170 35.9948084816 + 71 0.0005204093 35.9953288909 + 72 0.0004878908 35.9958167817 + 73 0.0004790242 35.9962958059 + 74 0.0004345460 35.9967303519 + 75 0.0003987616 35.9971291134 + 76 0.0003675210 35.9974966344 + 77 0.0003245943 35.9978212288 + 78 0.0003087542 35.9981299830 + 79 0.0002648503 35.9983948333 + 80 0.0002616593 35.9986564925 + 81 0.0002262765 35.9988827690 + 82 0.0001824563 35.9990652253 + 83 0.0001782590 35.9992434843 + 84 0.0001494122 35.9993928964 + 85 0.0001304700 35.9995233664 + 86 0.0001210330 35.9996443994 + 87 0.0001129960 35.9997573954 + 88 0.0000926426 35.9998500380 + 89 0.0000844096 35.9999344475 + 90 0.0000655525 36.0000000000 +======== ================ ================ + + +.. >>>>> [ RES MEM : 2.215916 GB ] [ VIRT MEM : 7.224915 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 140.581871 s ] [ CPU TIME: 3698.204640 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_md5 ] <<<<< .. + +.. >>>>> [ RES MEM : 2.215916 GB ] [ VIRT MEM : 7.224915 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 140.582872 s ] [ CPU TIME: 3698.275495 s ] <<<<< .. + +* Saved determinants 1 +Wall time: 0:02:25 + diff --git a/imidazole/cc-pvdz/imidazole.nofci.out b/imidazole/cc-pvdz/imidazole.nofci.out new file mode 100644 index 0000000..1be7e22 --- /dev/null +++ b/imidazole/cc-pvdz/imidazole.nofci.out @@ -0,0 +1,4973 @@ +Date: 29/10/2020 03:22:54 +=============== +Quantum Package +=============== + +Git Commit: Fix space in size for EZFIO.cfg +Git Date : Fri Oct 16 14:24:01 2020 +0200 +Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b +EZFIO Dir : imidazole + + +Task server running : tcp://172.28.0.238:41279 +* mo_num 90 +.. >>>>> [ IO READ: mo_class ] <<<<< .. + +.. >>>>> [ RES MEM : 0.010880 GB ] [ VIRT MEM : 4.857998 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.001074 s ] [ CPU TIME: 0.159626 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_two_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.010880 GB ] [ VIRT MEM : 4.857998 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.008604 s ] [ CPU TIME: 0.648715 s ] <<<<< .. + +* N_int 2 + MO map initialized: 8386560 +.. >>>>> [ IO READ: io_ao_two_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.011082 GB ] [ VIRT MEM : 4.857998 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.026399 s ] [ CPU TIME: 1.816379 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.011082 GB ] [ VIRT MEM : 4.857998 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.028963 s ] [ CPU TIME: 1.985954 s ] <<<<< .. + + AO map initialized : 10399080 +.. >>>>> [ IO READ: ao_power ] <<<<< .. + +.. >>>>> [ RES MEM : 0.011314 GB ] [ VIRT MEM : 4.857998 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.034639 s ] [ CPU TIME: 2.350752 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_prim_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.011349 GB ] [ VIRT MEM : 4.857998 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.038460 s ] [ CPU TIME: 2.600426 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_expo ] <<<<< .. + +.. >>>>> [ RES MEM : 0.011387 GB ] [ VIRT MEM : 4.857998 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.043201 s ] [ CPU TIME: 2.894963 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_coef ] <<<<< .. + +.. >>>>> [ RES MEM : 0.011425 GB ] [ VIRT MEM : 4.857998 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.047093 s ] [ CPU TIME: 3.138939 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_nucl ] <<<<< .. + +.. >>>>> [ RES MEM : 0.011604 GB ] [ VIRT MEM : 4.857998 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.051592 s ] [ CPU TIME: 3.450832 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_integrals_threshold ] <<<<< .. + +.. >>>>> [ RES MEM : 0.011604 GB ] [ VIRT MEM : 4.857998 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.053137 s ] [ CPU TIME: 3.560809 s ] <<<<< .. + + Providing the AO integrals +.. >>>>> [ IO READ: nucl_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.013077 GB ] [ VIRT MEM : 5.002682 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.145238 s ] [ CPU TIME: 9.378656 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_label ] <<<<< .. + +.. >>>>> [ RES MEM : 0.013237 GB ] [ VIRT MEM : 5.002682 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.149984 s ] [ CPU TIME: 9.695262 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_charge ] <<<<< .. + +.. >>>>> [ RES MEM : 0.013256 GB ] [ VIRT MEM : 5.002682 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.153998 s ] [ CPU TIME: 9.962464 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.013271 GB ] [ VIRT MEM : 5.002682 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.157243 s ] [ CPU TIME: 10.178549 s ] <<<<< .. + + +Nuclear Coordinates (Angstroms) +=============================== + +================ ============ ============ ============ ============ + Atom Charge X Y Z +================ ============ ============ ============ ============ +C 6.000000 0.220470 1.090138 0.000000 +C 6.000000 -0.807622 -0.859083 0.000000 +C 6.000000 0.551194 -1.021351 0.000000 +N 7.000000 -1.007266 0.502268 0.000000 +N 7.000000 1.186497 0.201529 0.000000 +H 1.000000 0.346620 2.157711 0.000000 +H 1.000000 -1.891812 0.974232 0.000000 +H 1.000000 -1.621208 -1.558740 0.000000 +H 1.000000 1.104255 -1.942086 0.000000 +================ ============ ============ ============ ============ + + Sorting the map + AO integrals provided: + Size of AO map : 67.8052654266357 MB + Number of AO integrals : 5515596 + cpu time : 258.698570000000 s + wall time : 4.08543395996094 s ( x 63.3221764285901 ) + + AO -> MO integrals transformation + --------------------------------- + + Read mo_coef +.. >>>>> [ IO READ: mo_integrals_threshold ] <<<<< .. + +.. >>>>> [ RES MEM : 0.087067 GB ] [ VIRT MEM : 5.138603 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.159516 s ] [ CPU TIME: 262.630833 s ] <<<<< .. + + Buffers : 25.31765 MB / core + 16.84211 % in 3.69443988800049 s 93.2782287597656 MB + Molecular integrals provided: + Size of MO map 93.2102127075195 MB + Number of MO integrals: 4874209 + cpu time : 297.615628000000 s + wall time : 4.49402189254761 s ( x 66.2247837496148 ) +.. >>>>> [ IO READ: n_states ] <<<<< .. + +.. >>>>> [ RES MEM : 0.682873 GB ] [ VIRT MEM : 5.807007 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.635410 s ] [ CPU TIME: 560.059666 s ] <<<<< .. + + * mo_label Natural +.. >>>>> [ IO READ: read_wf ] <<<<< .. + +.. >>>>> [ RES MEM : 0.682873 GB ] [ VIRT MEM : 5.807007 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.637174 s ] [ CPU TIME: 560.185187 s ] <<<<< .. + +* Number of determinants 1 +* Dimension of the psi arrays 100000 + Read psi_coef 1 1 +.. >>>>> [ IO READ: elec_beta_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.683815 GB ] [ VIRT MEM : 5.807007 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.658165 s ] [ CPU TIME: 561.673794 s ] <<<<< .. + +.. >>>>> [ IO READ: elec_alpha_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.683815 GB ] [ VIRT MEM : 5.807007 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.658956 s ] [ CPU TIME: 561.730316 s ] <<<<< .. + + Read psi_det +.. >>>>> [ IO READ: do_pt2 ] <<<<< .. + +.. >>>>> [ RES MEM : 0.686832 GB ] [ VIRT MEM : 5.809994 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.683312 s ] [ CPU TIME: 563.459978 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.686905 GB ] [ VIRT MEM : 5.809994 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.749303 s ] [ CPU TIME: 568.111892 s ] <<<<< .. + +.. >>>>> [ IO READ: selection_factor ] <<<<< .. + +.. >>>>> [ RES MEM : 0.686905 GB ] [ VIRT MEM : 5.809994 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.750086 s ] [ CPU TIME: 568.167981 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_max ] <<<<< .. + +.. >>>>> [ RES MEM : 0.686905 GB ] [ VIRT MEM : 5.812981 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.751066 s ] [ CPU TIME: 568.236222 s ] <<<<< .. + +.. >>>>> [ IO READ: s2_eig ] <<<<< .. + +.. >>>>> [ RES MEM : 0.698681 GB ] [ VIRT MEM : 5.836441 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.753573 s ] [ CPU TIME: 568.409740 s ] <<<<< .. + +.. >>>>> [ IO READ: variance_max ] <<<<< .. + +.. >>>>> [ RES MEM : 0.698681 GB ] [ VIRT MEM : 5.836441 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.754351 s ] [ CPU TIME: 568.465599 s ] <<<<< .. + +.. >>>>> [ IO READ: distributed_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 0.698681 GB ] [ VIRT MEM : 5.836441 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.763735 s ] [ CPU TIME: 569.130560 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_max_full ] <<<<< .. + +.. >>>>> [ RES MEM : 0.698681 GB ] [ VIRT MEM : 5.836441 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.764445 s ] [ CPU TIME: 569.181634 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_integrals_e_n ] <<<<< .. + +.. >>>>> [ RES MEM : 1.293640 GB ] [ VIRT MEM : 7.722313 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.130065 s ] [ CPU TIME: 593.695265 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_integrals_e_n ] <<<<< .. + +.. >>>>> [ RES MEM : 1.293640 GB ] [ VIRT MEM : 7.722313 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.165036 s ] [ CPU TIME: 594.289564 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_integrals_kinetic ] <<<<< .. + +.. >>>>> [ RES MEM : 1.296345 GB ] [ VIRT MEM : 7.788532 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.192283 s ] [ CPU TIME: 595.168381 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_integrals_kinetic ] <<<<< .. + +.. >>>>> [ RES MEM : 1.296345 GB ] [ VIRT MEM : 7.788532 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.193086 s ] [ CPU TIME: 595.224181 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_one_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 1.296803 GB ] [ VIRT MEM : 7.788532 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.199012 s ] [ CPU TIME: 595.616222 s ] <<<<< .. + + Providing the one-electron integrals +.. >>>>> [ IO READ: do_pseudo ] <<<<< .. + +.. >>>>> [ RES MEM : 1.296803 GB ] [ VIRT MEM : 7.788532 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.212976 s ] [ CPU TIME: 596.605718 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_relative_error ] <<<<< .. + +.. >>>>> [ RES MEM : 1.296982 GB ] [ VIRT MEM : 7.788532 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.218333 s ] [ CPU TIME: 596.988411 s ] <<<<< .. + +.. >>>>> [ IO READ: correlation_energy_ratio_max ] <<<<< .. + +.. >>>>> [ RES MEM : 1.296982 GB ] [ VIRT MEM : 7.788532 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.219078 s ] [ CPU TIME: 597.041734 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 1.296982 GB ] [ VIRT MEM : 7.788532 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.220256 s ] [ CPU TIME: 597.125449 s ] <<<<< .. + + Read n_states_diag +.. >>>>> [ IO READ: io_nuclear_repulsion ] <<<<< .. + +.. >>>>> [ RES MEM : 1.296982 GB ] [ VIRT MEM : 7.788532 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.221027 s ] [ CPU TIME: 597.180588 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 1.296982 GB ] [ VIRT MEM : 7.788532 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.221372 s ] [ CPU TIME: 597.205646 s ] <<<<< .. + +* Nuclear repulsion energy 163.5043497210638 +.. >>>>> [ IO READ: weight_one_e_dm ] <<<<< .. + +.. >>>>> [ RES MEM : 1.296982 GB ] [ VIRT MEM : 7.788532 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.222552 s ] [ CPU TIME: 597.289308 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_max ] <<<<< .. + +.. >>>>> [ RES MEM : 1.302101 GB ] [ VIRT MEM : 7.788532 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.231172 s ] [ CPU TIME: 597.905840 s ] <<<<< .. + +.. >>>>> [ IO READ: threshold_generators ] <<<<< .. + +.. >>>>> [ RES MEM : 1.302101 GB ] [ VIRT MEM : 7.788532 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.231942 s ] [ CPU TIME: 597.960894 s ] <<<<< .. + +* Target maximum memory (GB) 2000 +.. >>>>> [ IO READ: threshold_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 1.302101 GB ] [ VIRT MEM : 7.788532 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.232923 s ] [ CPU TIME: 598.030915 s ] <<<<< .. + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 1.302803 GB ] [ VIRT MEM : 7.788532 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.249172 s ] [ CPU TIME: 599.182084 s ] <<<<< .. + +* Energy of state 1 -224.8337650274628 +* S^2 of state 1 0.000000000000000 +* Saved determinants 1 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 1 +* Number of unique alpha determinants 1 +.. >>>>> [ IO READ: weight_selection ] <<<<< .. + +.. >>>>> [ RES MEM : 1.303326 GB ] [ VIRT MEM : 7.791786 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.341560 s ] [ CPU TIME: 605.726932 s ] <<<<< .. + + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +.. >>>>> [ IO READ: pseudo_sym ] <<<<< .. + +.. >>>>> [ RES MEM : 1.303326 GB ] [ VIRT MEM : 7.791786 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.342455 s ] [ CPU TIME: 605.791146 s ] <<<<< .. + +.. >>>>> [ IO READ: h0_type ] <<<<< .. + +.. >>>>> [ RES MEM : 1.303967 GB ] [ VIRT MEM : 7.794773 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.343442 s ] [ CPU TIME: 605.861033 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 1.303967 GB ] [ VIRT MEM : 7.794773 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.343824 s ] [ CPU TIME: 605.888532 s ] <<<<< .. + +* Number of generators 1 + +.. >>>>> [ RES MEM : 1.303967 GB ] [ VIRT MEM : 7.794773 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.344196 s ] [ CPU TIME: 605.915440 s ] <<<<< .. + +* Number of selectors 1 +* Number of comb teeth 1 +* Number of core MOs 5 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -224.8337650274628 +* Estimated memory/thread (Gb) 0.1490116119384766E-06 +* Number of virtual MOs 0 +* Number of active MOs 85 + Active MOs: + 6 7 8 9 10 11 + 12 13 14 15 16 17 + 18 19 20 21 22 23 + 24 25 26 27 28 29 + 30 31 32 33 34 35 + 36 37 38 39 40 41 + 42 43 44 45 46 47 + 48 49 50 51 52 53 + 54 55 56 57 58 59 + 60 61 62 63 64 65 + 66 67 68 69 70 71 + 72 73 74 75 76 77 + 78 79 80 81 82 83 + 84 85 86 87 88 89 + 90 +* Number of inactive MOs 0 +.. >>>>> [ IO READ: pert_2rdm ] <<<<< .. + +.. >>>>> [ RES MEM : 1.306450 GB ] [ VIRT MEM : 7.805496 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.376676 s ] [ CPU TIME: 607.736837 s ] <<<<< .. + +.. >>>>> [ IO READ: pruning ] <<<<< .. + +.. >>>>> [ RES MEM : 1.306770 GB ] [ VIRT MEM : 7.805496 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.797670 s ] [ CPU TIME: 620.793392 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 1.307121 GB ] [ VIRT MEM : 7.805496 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.804485 s ] [ CPU TIME: 621.251743 s ] <<<<< .. + +* Number of generators 1 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Saved determinants 5 +* Number of unique beta determinants 5 +* Number of unique alpha determinants 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.307152 GB ] [ VIRT MEM : 7.805504 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.847050 s ] [ CPU TIME: 624.225707 s ] <<<<< .. + +* Number of selectors 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio -0.2409109981510442E-02 + +Summary at N_det = 5 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -224.83376503 +# PT2 -0.96958766 0.00000000 +# rPT2 -0.66228686 0.00000000 +# +# E+PT2 -225.80335269 0.00000000 +# E+rPT2 -225.49605189 0.00000000 +# ============ ============================= + + N_det = 5 + N_states = 1 + + * State 1 + < S^2 > = 0.000000000000000E+000 + E = -224.833765027463 + Variance = 2.45989528361614 + PT norm = 0.681175113692903 + PT2 = -0.969587658432539 + rPT2 = -0.662286862059534 + E+PT2 = -225.803352685895 +/- 0.000000000000000E+000 + E+rPT2 = -225.496051889522 +/- 0.000000000000000E+000 + + ----- +.. >>>>> [ IO READ: io_mo_integrals_pseudo ] <<<<< .. + +.. >>>>> [ RES MEM : 1.307152 GB ] [ VIRT MEM : 7.805504 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.849110 s ] [ CPU TIME: 624.371405 s ] <<<<< .. + + Energy components + ================= + + Vnn : Nucleus-Nucleus potential energy + Ven : Electron-Nucleus potential energy + Vee : Electron-Electron potential energy + Vecp : Potential energy of the pseudo-potentials + T : Electronic kinetic energy + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -852.870895080993 + Vee = 239.797683117410 + Vecp = 0.000000000000000E+000 + T = 224.735097215057 + + +.. >>>>> [ IO READ: energy_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 1.307186 GB ] [ VIRT MEM : 7.805504 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.880218 s ] [ CPU TIME: 626.541592 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 1.307186 GB ] [ VIRT MEM : 7.805504 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.883375 s ] [ CPU TIME: 626.753908 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 1.307186 GB ] [ VIRT MEM : 7.805504 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.886871 s ] [ CPU TIME: 626.991770 s ] <<<<< .. + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 1.307590 GB ] [ VIRT MEM : 7.805504 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.912350 s ] [ CPU TIME: 628.756396 s ] <<<<< .. + +* Energy of state 1 -224.8588479611232 +* S^2 of state 1 0.000000000000000 +* Saved determinants 5 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 5 +* Number of unique alpha determinants 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.307762 GB ] [ VIRT MEM : 7.805504 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.963307 s ] [ CPU TIME: 632.319097 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 1.307762 GB ] [ VIRT MEM : 7.805504 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.963689 s ] [ CPU TIME: 632.346285 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -224.8588479611232 + +.. >>>>> [ RES MEM : 1.311283 GB ] [ VIRT MEM : 7.808491 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.970573 s ] [ CPU TIME: 632.833348 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 1.311283 GB ] [ VIRT MEM : 7.808491 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.970960 s ] [ CPU TIME: 632.861126 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 5 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.4436166398227215E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 4 -225.7695211458 0.00 2.4120432791 0.4030961656 0.2914 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.314957 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.282447 s ] [ CPU TIME: 647.715179 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 1.314957 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.282829 s ] [ CPU TIME: 647.742393 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.3492931521420727E-01 + +Summary at N_det = 5 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -224.85884796 +# PT2 -0.91067318 0.00000000 +# rPT2 -0.64904545 0.00000000 +# +# E+PT2 -225.76952115 0.00000000 +# E+rPT2 -225.50789341 0.00000000 +# ============ ============================= + + N_det = 5 + N_states = 1 + + * State 1 + < S^2 > = 0.000000000000000E+000 + E = -224.858847961123 + Variance = 2.41204327911928 + PT norm = 0.634898547496820 + PT2 = -0.910673184665281 + rPT2 = -0.649045451754225 + E+PT2 = -225.769521145788 +/- 0.000000000000000E+000 + E+rPT2 = -225.507893412877 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -852.940097402876 + Vee = 239.792138224493 + Vecp = 0.000000000000000E+000 + T = 224.784761496196 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6623 -226.08832153 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 1.314976 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.324272 s ] [ CPU TIME: 650.584289 s ] <<<<< .. + +* Energy of state 1 -224.8719506438153 +* S^2 of state 1 0.2877022601510184E-02 +* Saved determinants 10 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 7 +* Number of unique alpha determinants 7 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.315147 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.373968 s ] [ CPU TIME: 654.053567 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 1.315147 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.374337 s ] [ CPU TIME: 654.080159 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -224.8719506438153 + +.. >>>>> [ RES MEM : 1.315147 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.378672 s ] [ CPU TIME: 654.386235 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 1.315147 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.379039 s ] [ CPU TIME: 654.412499 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 10 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.4490318521857261E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 9 -225.7501111883 0.00 2.3832604839 0.3698755364 0.2968 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.315434 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.693331 s ] [ CPU TIME: 670.100452 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 1.315434 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.693706 s ] [ CPU TIME: 670.127446 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.5400160059569870E-01 + +Summary at N_det = 10 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -224.87195064 +# PT2 -0.87816054 0.00000000 +# rPT2 -0.64105134 0.00000000 +# +# E+PT2 -225.75011119 0.00000000 +# E+rPT2 -225.51300198 0.00000000 +# ============ ============================= + + N_det = 10 + N_states = 1 + + * State 1 + < S^2 > = 2.877022601510184E-003 + E = -224.871950643815 + Variance = 2.38326048390421 + PT norm = 0.608173936008347 + PT2 = -0.878160544451016 + rPT2 = -0.641051337213623 + E+PT2 = -225.750111188266 +/- 0.000000000000000E+000 + E+rPT2 = -225.513001981029 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -852.973991313152 + Vee = 239.786573701369 + Vecp = 0.000000000000000E+000 + T = 224.811117246904 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6490 -225.92266016 + -0.6623 -226.03140516 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 1.315475 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.735854 s ] [ CPU TIME: 673.062634 s ] <<<<< .. + +* Energy of state 1 -224.8876879016392 +* S^2 of state 1 0.6318957166565888E-02 +* Saved determinants 20 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 12 +* Number of unique alpha determinants 12 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.315571 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.786496 s ] [ CPU TIME: 676.587896 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 1.315571 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.786873 s ] [ CPU TIME: 676.615488 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -224.8876879016392 + +.. >>>>> [ RES MEM : 1.315571 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.791214 s ] [ CPU TIME: 676.922456 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 1.315571 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.791594 s ] [ CPU TIME: 676.949425 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 20 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.4598622769117355E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 19 -225.7320203587 0.00 2.3450927106 0.3432555676 0.3258 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.315750 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.133941 s ] [ CPU TIME: 694.275461 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 1.315750 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.134264 s ] [ CPU TIME: 694.296762 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7685557899979600E-01 + +Summary at N_det = 20 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -224.88768790 +# PT2 -0.84433246 0.00000000 +# rPT2 -0.62857172 0.00000000 +# +# E+PT2 -225.73202036 0.00000000 +# E+rPT2 -225.51625962 0.00000000 +# ============ ============================= + + N_det = 20 + N_states = 1 + + * State 1 + < S^2 > = 6.318957166565888E-003 + E = -224.887687901639 + Variance = 2.34509271062336 + PT norm = 0.585880164908812 + PT2 = -0.844332457105492 + rPT2 = -0.628571715949005 + E+PT2 = -225.732020358745 +/- 0.000000000000000E+000 + E+rPT2 = -225.516259617588 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.007826700614 + Vee = 239.774857391370 + Vecp = 0.000000000000000E+000 + T = 224.840931686541 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6411 -225.68033977 + -0.6490 -225.76545605 + -0.6623 -225.89806179 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 1.316097 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.193666 s ] [ CPU TIME: 698.177766 s ] <<<<< .. + +* Energy of state 1 -224.9031219116346 +* S^2 of state 1 0.9692747649463870E-02 +* Saved determinants 40 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 19 +* Number of unique alpha determinants 19 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.316189 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.246259 s ] [ CPU TIME: 701.858631 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 1.316189 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.246644 s ] [ CPU TIME: 701.886548 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -224.9031219116346 + +.. >>>>> [ RES MEM : 1.316189 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.250989 s ] [ CPU TIME: 702.198125 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 1.316189 GB ] [ VIRT MEM : 7.810760 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.251367 s ] [ CPU TIME: 702.225663 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 40 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.4815231263637543E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 39 -225.7146121318 0.00 2.3010977970 0.3213774223 0.3886 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.316494 GB ] [ VIRT MEM : 7.810902 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.657918 s ] [ CPU TIME: 724.804845 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 1.316494 GB ] [ VIRT MEM : 7.810902 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.658301 s ] [ CPU TIME: 724.829686 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9937853482597088E-01 + +Summary at N_det = 40 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -224.90312191 +# PT2 -0.81149022 0.00000000 +# rPT2 -0.61412448 0.00000000 +# +# E+PT2 -225.71461213 0.00000000 +# E+rPT2 -225.51724639 0.00000000 +# ============ ============================= + + N_det = 40 + N_states = 1 + + * State 1 + < S^2 > = 9.692747649463870E-003 + E = -224.903121911635 + Variance = 2.30109779702763 + PT norm = 0.566901598391753 + PT2 = -0.811490220136680 + rPT2 = -0.614124478341167 + E+PT2 = -225.714612131771 +/- 0.000000000000000E+000 + E+rPT2 = -225.517246389976 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.027551280961 + Vee = 239.754975883635 + Vecp = 0.000000000000000E+000 + T = 224.865103764628 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6286 -225.55919220 + -0.6411 -225.61301595 + -0.6490 -225.67414994 + -0.6623 -225.78213968 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 1.317150 GB ] [ VIRT MEM : 7.822784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.703388 s ] [ CPU TIME: 727.831629 s ] <<<<< .. + +* Energy of state 1 -224.9215026888852 +* S^2 of state 1 0.9538293509899544E-02 +* Saved determinants 80 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 34 +* Number of unique alpha determinants 34 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.317318 GB ] [ VIRT MEM : 7.822784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.760114 s ] [ CPU TIME: 731.789410 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 1.317318 GB ] [ VIRT MEM : 7.822784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.760499 s ] [ CPU TIME: 731.816734 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -224.9215026888852 + +.. >>>>> [ RES MEM : 1.317318 GB ] [ VIRT MEM : 7.822784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.765252 s ] [ CPU TIME: 732.153467 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 1.317318 GB ] [ VIRT MEM : 7.822784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.765646 s ] [ CPU TIME: 732.181602 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 80 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.5248448252677918E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 77 -225.6989964750 0.00 2.2535440350 0.2996152951 0.6648 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.317776 GB ] [ VIRT MEM : 7.822784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12.447955 s ] [ CPU TIME: 775.240994 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 1.317776 GB ] [ VIRT MEM : 7.822784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12.448331 s ] [ CPU TIME: 775.267366 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1258716889215296 + +Summary at N_det = 80 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -224.92150269 +# PT2 -0.77749379 0.00000000 +# rPT2 -0.59824918 0.00000000 +# +# E+PT2 -225.69899648 0.00000000 +# E+rPT2 -225.51975187 0.00000000 +# ============ ============================= + + N_det = 80 + N_states = 1 + + * State 1 + < S^2 > = 9.538293509899544E-003 + E = -224.921502688885 + Variance = 2.25354403503053 + PT norm = 0.547371258899623 + PT2 = -0.777493786120472 + rPT2 = -0.598249181177095 + E+PT2 = -225.698996475006 +/- 0.000000000000000E+000 + E+rPT2 = -225.519751870062 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.038198486809 + Vee = 239.729866029814 + Vecp = 0.000000000000000E+000 + T = 224.882480047046 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6141 -225.61416909 + -0.6286 -225.58885656 + -0.6411 -225.60809717 + -0.6490 -225.64528457 + -0.6623 -225.72097699 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 1.318748 GB ] [ VIRT MEM : 7.822853 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12.499256 s ] [ CPU TIME: 778.747155 s ] <<<<< .. + +* Energy of state 1 -224.9458093479920 +* S^2 of state 1 0.1779208651099716E-01 +* Saved determinants 160 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 57 +* Number of unique alpha determinants 57 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.318817 GB ] [ VIRT MEM : 7.822853 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12.552981 s ] [ CPU TIME: 782.425145 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 1.318817 GB ] [ VIRT MEM : 7.822853 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12.553354 s ] [ CPU TIME: 782.452114 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -224.9458093479920 + +.. >>>>> [ RES MEM : 1.318817 GB ] [ VIRT MEM : 7.822853 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12.557783 s ] [ CPU TIME: 782.765048 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 1.318817 GB ] [ VIRT MEM : 7.822853 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12.558156 s ] [ CPU TIME: 782.791741 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 160 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.6114882230758667E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 140 -225.6742785538 0.585E-02 2.1720727239 0.2709880357 1.0102 + 154 -225.6805699868 0.00 2.1909564943 0.2728535354 1.0267 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.319378 GB ] [ VIRT MEM : 7.822853 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13.602310 s ] [ CPU TIME: 850.899445 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 1.319378 GB ] [ VIRT MEM : 7.822853 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13.602694 s ] [ CPU TIME: 850.924741 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1606099481231850 + +Summary at N_det = 160 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -224.94580935 +# PT2 -0.73476064 0.00000000 +# rPT2 -0.57725466 0.00000000 +# +# E+PT2 -225.68056999 0.00000000 +# E+rPT2 -225.52306401 0.00000000 +# ============ ============================= + + N_det = 160 + N_states = 1 + + * State 1 + < S^2 > = 1.779208651099716E-002 + E = -224.945809347992 + Variance = 2.19095649430931 + PT norm = 0.522353841184184 + PT2 = -0.734760638816985 + rPT2 = -0.577254663150350 + E+PT2 = -225.680569986809 +/- 0.000000000000000E+000 + E+rPT2 = -225.523064011142 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.055704001296 + Vee = 239.699371177740 + Vecp = 0.000000000000000E+000 + T = 224.906173754501 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.5982 -225.61413297 + -0.6141 -225.61414735 + -0.6286 -225.60155526 + -0.6411 -225.60912840 + -0.6490 -225.63146651 + -0.6623 -225.68243378 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 1.326771 GB ] [ VIRT MEM : 7.826923 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13.699256 s ] [ CPU TIME: 857.516727 s ] <<<<< .. + +* Energy of state 1 -224.9753569165813 +* S^2 of state 1 0.1983171532124476E-01 +* Saved determinants 320 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 116 +* Number of unique alpha determinants 116 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.326939 GB ] [ VIRT MEM : 7.826923 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13.753745 s ] [ CPU TIME: 861.236404 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 1.326939 GB ] [ VIRT MEM : 7.826923 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13.754115 s ] [ CPU TIME: 861.263333 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -224.9753569165813 + +.. >>>>> [ RES MEM : 1.326939 GB ] [ VIRT MEM : 7.826923 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13.758785 s ] [ CPU TIME: 861.598144 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 1.326939 GB ] [ VIRT MEM : 7.826923 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13.759152 s ] [ CPU TIME: 861.624815 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 320 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.7847750186920166E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 141 -225.6544776112 0.538E-02 2.0782081605 0.2446708791 1.0125 + 313 -225.6638963090 0.00 2.1139035607 0.2470513413 1.6607 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.326962 GB ] [ VIRT MEM : 7.826923 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15.438065 s ] [ CPU TIME: 976.319810 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 1.326962 GB ] [ VIRT MEM : 7.826923 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15.438469 s ] [ CPU TIME: 976.348514 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.2022732152096855 + +Summary at N_det = 320 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -224.97535692 +# PT2 -0.68853939 0.00000000 +# rPT2 -0.55213396 0.00000000 +# +# E+PT2 -225.66389631 0.00000000 +# E+rPT2 -225.52749087 0.00000000 +# ============ ============================= + + N_det = 320 + N_states = 1 + + * State 1 + < S^2 > = 1.983171532124476E-002 + E = -224.975356916581 + Variance = 2.11390356067851 + PT norm = 0.497042595091844 + PT2 = -0.688539392449112 + rPT2 = -0.552133957621715 + E+PT2 = -225.663896309030 +/- 0.000000000000000E+000 + E+rPT2 = -225.527490874203 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.054044596129 + Vee = 239.651366026065 + Vecp = 0.000000000000000E+000 + T = 224.922971932419 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.5773 -225.62478995 + -0.5982 -225.62023584 + -0.6141 -225.61843655 + -0.6286 -225.61040070 + -0.6411 -225.61316919 + -0.6490 -225.62665064 + -0.6623 -225.66058484 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 1.336926 GB ] [ VIRT MEM : 7.960747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15.624631 s ] [ CPU TIME: 989.588856 s ] <<<<< .. + +* Energy of state 1 -225.0122901101165 +* S^2 of state 1 0.3027728901732866E-01 +* Saved determinants 640 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 186 +* Number of unique alpha determinants 185 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.336926 GB ] [ VIRT MEM : 7.960747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15.690849 s ] [ CPU TIME: 993.897218 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 1.336926 GB ] [ VIRT MEM : 7.960747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15.691224 s ] [ CPU TIME: 993.924228 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -225.0122901101165 + +.. >>>>> [ RES MEM : 1.336926 GB ] [ VIRT MEM : 7.960747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15.696136 s ] [ CPU TIME: 994.271409 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 1.336926 GB ] [ VIRT MEM : 7.960747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15.696517 s ] [ CPU TIME: 994.297963 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 640 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1131348609924316E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5237732658 0.127 1.9834484283 0.1595114251 1.0850 + 385 -225.6416446443 0.522E-02 2.0166093872 0.2156434694 2.1471 + 628 -225.6438197901 0.00 2.0130376973 0.2170815501 3.0721 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.337646 GB ] [ VIRT MEM : 7.960747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18.786305 s ] [ CPU TIME: 1207.837242 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 1.337646 GB ] [ VIRT MEM : 7.960747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18.786697 s ] [ CPU TIME: 1207.864232 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.2542796999497264 + +Summary at N_det = 640 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.01229011 +# PT2 -0.63152968 0.00000000 +# rPT2 -0.51888855 0.00000000 +# +# E+PT2 -225.64381979 0.00000000 +# E+rPT2 -225.53117866 0.00000000 +# ============ ============================= + + N_det = 640 + N_states = 1 + + * State 1 + < S^2 > = 3.027728901732866E-002 + E = -225.012290110117 + Variance = 2.01303769731085 + PT norm = 0.465920111240351 + PT2 = -0.631529679979264 + rPT2 = -0.518888549373749 + E+PT2 = -225.643819790096 +/- 0.000000000000000E+000 + E+rPT2 = -225.531178659490 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.054431331042 + Vee = 239.589850225820 + Vecp = 0.000000000000000E+000 + T = 224.947941274042 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.5521 -225.58873697 + -0.5773 -225.60282027 + -0.5982 -225.60718760 + -0.6141 -225.60910457 + -0.6286 -225.60620487 + -0.6411 -225.60852839 + -0.6490 -225.61759484 + =========== =================== + +* Number of unique alpha determinants 317 +* Number of unique beta determinants 316 +.. >>>>> [ IO READ: davidson_sze_max ] <<<<< .. + +.. >>>>> [ RES MEM : 1.337688 GB ] [ VIRT MEM : 7.960747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18.835744 s ] [ CPU TIME: 1211.231256 s ] <<<<< .. + +.. >>>>> [ IO READ: state_following ] <<<<< .. + +.. >>>>> [ RES MEM : 1.337688 GB ] [ VIRT MEM : 7.960747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18.836666 s ] [ CPU TIME: 1211.295711 s ] <<<<< .. + +.. >>>>> [ IO READ: only_expected_s2 ] <<<<< .. + +.. >>>>> [ RES MEM : 1.337688 GB ] [ VIRT MEM : 7.960747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18.837720 s ] [ CPU TIME: 1211.369164 s ] <<<<< .. + +.. >>>>> [ IO READ: disk_based_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 1.337688 GB ] [ VIRT MEM : 7.960747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18.838473 s ] [ CPU TIME: 1211.422561 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 1.337688 GB ] [ VIRT MEM : 7.960747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18.838827 s ] [ CPU TIME: 1211.447350 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 1280 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.2758584916591644E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.0123579147 0.030328 0.211E-01 + 2 -225.0574383577 0.037418 0.192E-02 + 3 -225.0580994596 0.036093 0.770E-04 + 4 -225.0581732164 0.036504 0.113E-05 + 5 -225.0581751394 0.036514 0.198E-07 + 6 -225.0581751739 0.036507 0.420E-09 + 7 -225.0581751747 0.036506 0.870E-11 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 1.338528 GB ] [ VIRT MEM : 7.960747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18.866308 s ] [ CPU TIME: 1213.390443 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 1.338528 GB ] [ VIRT MEM : 7.960747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18.866709 s ] [ CPU TIME: 1213.418708 s ] <<<<< .. + +* Energy of state 1 -225.0581751746660 +* S^2 of state 1 0.3650624841573746E-01 +* Saved determinants 1280 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.338772 GB ] [ VIRT MEM : 7.960747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18.947062 s ] [ CPU TIME: 1218.233707 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 1.338772 GB ] [ VIRT MEM : 7.960747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18.947442 s ] [ CPU TIME: 1218.260980 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 61 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -225.0581751746660 + +.. >>>>> [ RES MEM : 1.338772 GB ] [ VIRT MEM : 7.960747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18.958108 s ] [ CPU TIME: 1219.015957 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 1.338772 GB ] [ VIRT MEM : 7.960747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18.958494 s ] [ CPU TIME: 1219.043005 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 61 +* pt2_n_tasks_max 1 +* Number of tasks 1280 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1824674606323242E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.6230709396 0.357E-03 1.8883295097 0.1841224382 1.6740 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.337025 GB ] [ VIRT MEM : 7.973309 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 21.089570 s ] [ CPU TIME: 1364.816669 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 1.337025 GB ] [ VIRT MEM : 7.973309 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 21.089947 s ] [ CPU TIME: 1364.842143 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 61 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.3183388904747682 + +Summary at N_det = 1280 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.05817517 +# PT2 -0.56498456 0.00018318 +# rPT2 -0.47712260 0.00015469 +# +# E+PT2 -225.62315973 0.00018318 +# E+rPT2 -225.53529777 0.00015469 +# ============ ============================= + + N_det = 1280 + N_states = 1 + + * State 1 + < S^2 > = 3.650624841573746E-002 + E = -225.058175174666 + Variance = 1.88848861922440 + PT norm = 0.429126607369567 + PT2 = -0.564984555507015 + rPT2 = -0.477122598330253 + E+PT2 = -225.623159730173 +/- 1.831755172445752E-004 + E+rPT2 = -225.535297772996 +/- 1.546895006002241E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.055846864494 + Vee = 239.517744519183 + Vecp = 0.000000000000000E+000 + T = 224.975577449582 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.5189 -225.58235338 + -0.5521 -225.58491267 + -0.5773 -225.59267123 + -0.5982 -225.59718155 + -0.6141 -225.59993388 + -0.6286 -225.59949885 + -0.6411 -225.60172992 + =========== =================== + +* Number of unique alpha determinants 539 +* Number of unique beta determinants 541 + +.. >>>>> [ RES MEM : 1.337261 GB ] [ VIRT MEM : 7.973309 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 21.142030 s ] [ CPU TIME: 1368.419357 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 2560 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.5117855966091156E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.0582462970 0.036484 0.226E-01 + 2 -225.1113376502 0.040596 0.180E-02 + 3 -225.1120632916 0.038902 0.714E-04 + 4 -225.1121402035 0.039173 0.117E-05 + 5 -225.1121422507 0.039186 0.304E-07 + 6 -225.1121423052 0.039181 0.759E-09 + 7 -225.1121423065 0.039181 0.157E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 1.340141 GB ] [ VIRT MEM : 7.973309 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 21.234512 s ] [ CPU TIME: 1374.980658 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 1.340141 GB ] [ VIRT MEM : 7.973309 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 21.234901 s ] [ CPU TIME: 1375.009465 s ] <<<<< .. + +* Energy of state 1 -225.1121423065018 +* S^2 of state 1 0.3918131344944004E-01 +* Saved determinants 2560 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.340168 GB ] [ VIRT MEM : 7.973309 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 21.344361 s ] [ CPU TIME: 1381.019338 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 1.340168 GB ] [ VIRT MEM : 7.973309 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 21.344707 s ] [ CPU TIME: 1381.044412 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 77 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -225.1121423065018 + +.. >>>>> [ RES MEM : 1.340199 GB ] [ VIRT MEM : 7.973309 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 21.353092 s ] [ CPU TIME: 1381.644709 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 1.340199 GB ] [ VIRT MEM : 7.973309 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 21.353467 s ] [ CPU TIME: 1381.672028 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 77 +* pt2_n_tasks_max 1 +* Number of tasks 2560 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.3211016654968261E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.6041531868 0.102E-02 1.7339620994 0.1513963728 3.0108 + 13 -225.6046857019 0.175E-03 1.7378848623 0.1514472491 4.2657 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.351688 GB ] [ VIRT MEM : 7.973389 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 26.053092 s ] [ CPU TIME: 1706.827636 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 1.351688 GB ] [ VIRT MEM : 7.973389 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 26.053471 s ] [ CPU TIME: 1706.853505 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 77 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.3928767351940805 + +Summary at N_det = 2560 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.11214231 +# PT2 -0.49249221 0.00014671 +# rPT2 -0.42772442 0.00012742 +# +# E+PT2 -225.60463452 0.00014671 +# E+rPT2 -225.53986672 0.00012742 +# ============ ============================= + + N_det = 2560 + N_states = 1 + + * State 1 + < S^2 > = 3.918131344944004E-002 + E = -225.112142306502 + Variance = 1.73790157284909 + PT norm = 0.389132532057683 + PT2 = -0.492492212395908 + rPT2 = -0.427724415904689 + E+PT2 = -225.604634518898 +/- 1.467123127688281E-004 + E+rPT2 = -225.539866722407 +/- 1.274181331310617E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.048963054720 + Vee = 239.429906148270 + Vecp = 0.000000000000000E+000 + T = 225.002564878884 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4771 -225.57942792 + -0.5189 -225.58063546 + -0.5521 -225.58238755 + -0.5773 -225.58708781 + -0.5982 -225.59058893 + -0.6141 -225.59308694 + -0.6286 -225.59356544 + =========== =================== + +* Number of unique alpha determinants 971 +* Number of unique beta determinants 975 + +.. >>>>> [ RES MEM : 1.352036 GB ] [ VIRT MEM : 7.973389 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 26.110830 s ] [ CPU TIME: 1710.745010 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5120 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.9795039892196655E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.1122172070 0.039198 0.233E-01 + 2 -225.1708873922 0.038520 0.174E-02 + 3 -225.1716968468 0.036755 0.705E-04 + 4 -225.1717843904 0.036899 0.134E-05 + 5 -225.1717868994 0.036881 0.463E-07 + 6 -225.1717869858 0.036870 0.109E-08 + 7 -225.1717869880 0.036871 0.262E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 1.358875 GB ] [ VIRT MEM : 7.977989 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 26.176974 s ] [ CPU TIME: 1715.414459 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 1.357697 GB ] [ VIRT MEM : 7.975689 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 26.177568 s ] [ CPU TIME: 1715.456999 s ] <<<<< .. + +* Energy of state 1 -225.1717869879877 +* S^2 of state 1 0.3687062593118198E-01 +* Saved determinants 5120 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.357697 GB ] [ VIRT MEM : 7.975689 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 26.366093 s ] [ CPU TIME: 1725.173839 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 1.357697 GB ] [ VIRT MEM : 7.975689 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 26.366481 s ] [ CPU TIME: 1725.201487 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 93 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -225.1717869879877 + +.. >>>>> [ RES MEM : 1.357807 GB ] [ VIRT MEM : 7.975170 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 26.374365 s ] [ CPU TIME: 1725.758960 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 1.357807 GB ] [ VIRT MEM : 7.975170 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 26.374776 s ] [ CPU TIME: 1725.788147 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 93 +* pt2_n_tasks_max 1 +* Number of tasks 5120 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.5983653068542481E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5920007382 0.194E-02 1.5793443664 0.1208796441 5.6211 + 17 -225.5916452057 0.446E-03 1.5757897251 0.1208756811 6.6743 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.409225 GB ] [ VIRT MEM : 8.036076 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 33.602748 s ] [ CPU TIME: 2232.669387 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 1.409225 GB ] [ VIRT MEM : 8.036076 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 33.603139 s ] [ CPU TIME: 2232.698182 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 93 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.4731435043787413 + +Summary at N_det = 5120 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.17178699 +# PT2 -0.41991229 0.00041563 +# rPT2 -0.37462308 0.00037080 +# +# E+PT2 -225.59169928 0.00041563 +# E+rPT2 -225.54641006 0.00037080 +# ============ ============================= + + N_det = 5120 + N_states = 1 + + * State 1 + < S^2 > = 3.687062593118198E-002 + E = -225.171786987988 + Variance = 1.57588892197083 + PT norm = 0.347696366633291 + PT2 = -0.419912294290455 + rPT2 = -0.374623075474212 + E+PT2 = -225.591699282278 +/- 4.156279060327905E-004 + E+rPT2 = -225.546410063462 +/- 3.708007756096085E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.063580501876 + Vee = 239.349570921926 + Vecp = 0.000000000000000E+000 + T = 225.037872870898 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4277 -225.59257249 + -0.4771 -225.58684074 + -0.5189 -225.58517393 + -0.5521 -225.58514079 + -0.5773 -225.58747992 + -0.5982 -225.58959098 + -0.6141 -225.59128300 + =========== =================== + +* Number of unique alpha determinants 1708 +* Number of unique beta determinants 1706 + +.. >>>>> [ RES MEM : 1.410255 GB ] [ VIRT MEM : 8.036076 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 33.672231 s ] [ CPU TIME: 2237.571850 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 10240 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.1875059679150581E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.1717941328 0.036864 0.228E-01 + 2 -225.2342756770 0.034633 0.150E-02 + 3 -225.2351179630 0.033211 0.753E-04 + 4 -225.2352152659 0.033261 0.175E-05 + 5 -225.2352183468 0.033245 0.747E-07 + 6 -225.2352184808 0.033234 0.212E-08 + 7 -225.2352184851 0.033233 0.572E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 1.421028 GB ] [ VIRT MEM : 8.045254 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 33.818779 s ] [ CPU TIME: 2248.056616 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 1.417431 GB ] [ VIRT MEM : 8.036758 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 33.819718 s ] [ CPU TIME: 2248.124525 s ] <<<<< .. + +* Energy of state 1 -225.2352184851179 +* S^2 of state 1 0.3323332308409045E-01 +* Saved determinants 10240 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.421600 GB ] [ VIRT MEM : 8.036758 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 34.103929 s ] [ CPU TIME: 2261.204135 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 1.421600 GB ] [ VIRT MEM : 8.036758 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 34.104333 s ] [ CPU TIME: 2261.233555 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 100 +* pt2_n_tasks_max 2 +* PT2 Energy denominator -225.2352184851179 + +.. >>>>> [ RES MEM : 1.414547 GB ] [ VIRT MEM : 8.024357 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 34.114559 s ] [ CPU TIME: 2261.966859 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 1.414547 GB ] [ VIRT MEM : 8.024357 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 34.114959 s ] [ CPU TIME: 2261.996035 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 100 +* pt2_n_tasks_max 2 +* Number of tasks 10608 +* Number of fragmented tasks 368 +* Number of threads for PT2 72 +* Memory (Gb) 0.1153252899646759 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5833870990 0.215E-02 1.4027214044 0.0930872442 5.6454 + 9 -225.5848348586 0.777E-03 1.4089856867 0.0934107627 6.9953 + 13 -225.5848406343 0.587E-03 1.4083513726 0.0934371007 8.0055 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.546993 GB ] [ VIRT MEM : 8.157558 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 43.480474 s ] [ CPU TIME: 2924.137358 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 1.546993 GB ] [ VIRT MEM : 8.157558 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 43.480890 s ] [ CPU TIME: 2924.167226 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 100 +* pt2_n_tasks_max 2 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.5557751733129923 + +Summary at N_det = 10240 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.23521849 +# PT2 -0.34946205 0.00056604 +# rPT2 -0.31960500 0.00051768 +# +# E+PT2 -225.58468054 0.00056604 +# E+rPT2 -225.55482349 0.00051768 +# ============ ============================= + + N_det = 10240 + N_states = 1 + + * State 1 + < S^2 > = 3.323332308409045E-002 + E = -225.235218485118 + Variance = 1.40721766303001 + PT norm = 0.305644560962957 + PT2 = -0.349462053557084 + rPT2 = -0.319605002429406 + E+PT2 = -225.584680538675 +/- 5.660440229206050E-004 + E+rPT2 = -225.554823487547 +/- 5.176828198634146E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.081282046170 + Vee = 239.266926273583 + Vecp = 0.000000000000000E+000 + T = 225.074787566405 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3746 -225.60369784 + -0.4277 -225.59880155 + -0.4771 -225.59375234 + -0.5189 -225.59112193 + -0.5521 -225.59003402 + -0.5773 -225.59086764 + -0.5982 -225.59188805 + =========== =================== + +* Number of unique alpha determinants 3075 +* Number of unique beta determinants 3075 + +.. >>>>> [ RES MEM : 1.549122 GB ] [ VIRT MEM : 8.153652 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 43.584174 s ] [ CPU TIME: 2931.432293 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 20480 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.3636924922466278E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.2352189633 0.033235 0.209E-01 + 2 -225.2978217642 0.028450 0.120E-02 + 3 -225.2986629235 0.027383 0.881E-04 + 4 -225.2987747734 0.027522 0.203E-05 + 5 -225.2987785787 0.027520 0.107E-06 + 6 -225.2987787765 0.027510 0.358E-08 + 7 -225.2987787844 0.027510 0.125E-09 + 8 -225.2987787847 0.027510 0.437E-11 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 1.569885 GB ] [ VIRT MEM : 8.177444 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 44.016206 s ] [ CPU TIME: 2962.425357 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 1.561775 GB ] [ VIRT MEM : 8.163574 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 44.017731 s ] [ CPU TIME: 2962.535299 s ] <<<<< .. + +* Energy of state 1 -225.2987787846953 +* S^2 of state 1 0.2751005865502315E-01 +* Saved determinants 20480 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.566193 GB ] [ VIRT MEM : 8.163574 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 44.424008 s ] [ CPU TIME: 2980.521718 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 1.566193 GB ] [ VIRT MEM : 8.163574 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 44.424443 s ] [ CPU TIME: 2980.553427 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 +* PT2 Energy denominator -225.2987787846953 + +.. >>>>> [ RES MEM : 1.555923 GB ] [ VIRT MEM : 8.148945 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 44.439392 s ] [ CPU TIME: 2981.626075 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 1.555923 GB ] [ VIRT MEM : 8.148945 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 44.439830 s ] [ CPU TIME: 2981.657739 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 +* Number of tasks 21402 +* Number of fragmented tasks 461 +* Number of threads for PT2 72 +* Memory (Gb) 0.2262656152248383 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5814647526 0.738E-03 1.2284890134 0.0697452663 7.4129 + 8 -225.5811371919 0.358E-03 1.2277264913 0.0696233882 9.1256 + 11 -225.5810677581 0.386E-03 1.2260103449 0.0696706756 10.5474 + 12 -225.5811624449 0.517E-03 1.2266806882 0.0696711100 11.7972 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.771362 GB ] [ VIRT MEM : 8.339222 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 56.316567 s ] [ CPU TIME: 3825.420813 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 1.771362 GB ] [ VIRT MEM : 8.339222 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 56.316994 s ] [ CPU TIME: 3825.451808 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.6370823141249975 + +Summary at N_det = 20480 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.29877878 +# PT2 -0.28238366 0.00051718 +# rPT2 -0.26399111 0.00048349 +# +# E+PT2 -225.58116244 0.00051718 +# E+rPT2 -225.56276989 0.00048349 +# ============ ============================= + + N_det = 20480 + N_states = 1 + + * State 1 + < S^2 > = 2.751005865502315E-002 + E = -225.298778784695 + Variance = 1.22668068820795 + PT norm = 0.263952855728895 + PT2 = -0.282383660186533 + rPT2 = -0.263991106737481 + E+PT2 = -225.581162444882 +/- 5.171781490700591E-004 + E+rPT2 = -225.562769891433 +/- 4.834926775269483E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.098954071562 + Vee = 239.186730052815 + Vecp = 0.000000000000000E+000 + T = 225.109095512987 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3196 -225.60049032 + -0.3746 -225.60189752 + -0.4277 -225.59990801 + -0.4771 -225.59667228 + -0.5189 -225.59446645 + -0.5521 -225.59326707 + -0.5773 -225.59346448 + =========== =================== + +* Number of unique alpha determinants 5482 +* Number of unique beta determinants 5476 + +.. >>>>> [ RES MEM : 1.773453 GB ] [ VIRT MEM : 8.339222 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 56.524021 s ] [ CPU TIME: 3840.133326 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 40960 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.7064054533839226E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.2987797026 0.027512 0.177E-01 + 2 -225.3570841149 0.020558 0.875E-03 + 3 -225.3578728812 0.019785 0.967E-04 + 4 -225.3579893677 0.019855 0.220E-05 + 5 -225.3579939359 0.019847 0.138E-06 + 6 -225.3579942008 0.019841 0.564E-08 + 7 -225.3579942137 0.019841 0.219E-09 + 8 -225.3579942142 0.019841 0.906E-11 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 1.810123 GB ] [ VIRT MEM : 8.390503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 57.730707 s ] [ CPU TIME: 3926.790607 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 1.793831 GB ] [ VIRT MEM : 8.362663 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 57.733222 s ] [ CPU TIME: 3926.971710 s ] <<<<< .. + +* Energy of state 1 -225.3579942141869 +* S^2 of state 1 0.1984080262103268E-01 +* Saved determinants 40960 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.778133 GB ] [ VIRT MEM : 8.344913 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 58.389983 s ] [ CPU TIME: 3955.156394 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 1.778133 GB ] [ VIRT MEM : 8.344913 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 58.390461 s ] [ CPU TIME: 3955.191210 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 +* PT2 Energy denominator -225.3579942141869 + +.. >>>>> [ RES MEM : 1.778564 GB ] [ VIRT MEM : 8.344913 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 58.404852 s ] [ CPU TIME: 3956.223996 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 1.778564 GB ] [ VIRT MEM : 8.344913 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 58.405319 s ] [ CPU TIME: 3956.257956 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 +* Number of tasks 53078 +* Number of fragmented tasks 10354 +* Number of threads for PT2 72 +* Memory (Gb) 0.4481462657451630 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5807415700 0.811E-03 1.0446099098 0.0506692251 8.9348 + 6 -225.5809306883 0.585E-03 1.0465533447 0.0506678642 10.0880 + 7 -225.5808025904 0.508E-03 1.0463325122 0.0506159797 11.2835 + 8 -225.5811024795 0.516E-03 1.0479904015 0.0506651309 12.7946 + 10 -225.5818411040 0.602E-03 1.0531905885 0.0507894857 13.9966 + 12 -225.5817183282 0.504E-03 1.0521274020 0.0507698277 15.1900 + 14 -225.5818517271 0.569E-03 1.0530041688 0.0507885422 17.2536 + 15 -225.5818344262 0.529E-03 1.0528931543 0.0507866974 18.4650 + 18 -225.5826036899 0.573E-03 1.0567696660 0.0509448818 20.3099 + 20 -225.5823427568 0.604E-03 1.0559862261 0.0508730786 21.4110 + 22 -225.5824767152 0.568E-03 1.0561235596 0.0509219522 22.6981 + 24 -225.5825457646 0.538E-03 1.0564011639 0.0509350101 23.9659 + 27 -225.5823667574 0.509E-03 1.0548360793 0.0509214680 26.2881 + 29 -225.5826244118 0.459E-03 1.0561863739 0.0509686971 27.9781 + 30 -225.5826027004 0.444E-03 1.0556977606 0.0509774468 29.0149 + 32 -225.5825105340 0.413E-03 1.0548604079 0.0509732061 30.5059 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 2.084549 GB ] [ VIRT MEM : 8.602356 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 90.308684 s ] [ CPU TIME: 6227.707784 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 2.084549 GB ] [ VIRT MEM : 8.602356 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 90.309163 s ] [ CPU TIME: 6227.742550 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7097917733254006 + +Summary at N_det = 40960 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.35799421 +# PT2 -0.22458296 0.00040615 +# rPT2 -0.21368760 0.00038644 +# +# E+PT2 -225.58257717 0.00040615 +# E+rPT2 -225.57168182 0.00038644 +# ============ ============================= + + N_det = 40960 + N_states = 1 + + * State 1 + < S^2 > = 1.984080262103268E-002 + E = -225.357994214187 + Variance = 1.05516061789846 + PT norm = 0.225803703400961 + PT2 = -0.224582958428343 + rPT2 = -0.213687601899420 + E+PT2 = -225.582577172615 +/- 4.061467973326966E-004 + E+rPT2 = -225.571681816086 +/- 3.864431021325471E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.126064134070 + Vee = 239.117754124942 + Vecp = 0.000000000000000E+000 + T = 225.145966073878 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2640 -225.60953937 + -0.3196 -225.60531571 + -0.3746 -225.60445613 + -0.4277 -225.60259055 + -0.4771 -225.59996309 + -0.5189 -225.59796273 + -0.5521 -225.59670719 + =========== =================== + +* Number of unique alpha determinants 10292 +* Number of unique beta determinants 10285 + +.. >>>>> [ RES MEM : 2.088165 GB ] [ VIRT MEM : 8.602356 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 90.829722 s ] [ CPU TIME: 6265.053532 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 81920 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.1391713209450245 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.3579947782 0.019842 0.136E-01 + 2 -225.4071149185 0.012211 0.549E-03 + 3 -225.4078510458 0.011769 0.103E-03 + 4 -225.4079542158 0.011836 0.253E-05 + 5 -225.4079597601 0.011836 0.174E-06 + 6 -225.4079601109 0.011834 0.729E-08 + 7 -225.4079601294 0.011834 0.275E-09 + 8 -225.4079601302 0.011834 0.137E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 2.158264 GB ] [ VIRT MEM : 8.704906 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 94.642229 s ] [ CPU TIME: 6538.866471 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 2.125290 GB ] [ VIRT MEM : 8.649235 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 94.646940 s ] [ CPU TIME: 6539.205351 s ] <<<<< .. + +* Energy of state 1 -225.4079601302093 +* S^2 of state 1 0.1183390080009971E-01 +* Saved determinants 81920 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 2.092876 GB ] [ VIRT MEM : 8.612122 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 95.784626 s ] [ CPU TIME: 6585.159053 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 2.092876 GB ] [ VIRT MEM : 8.612122 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 95.785210 s ] [ CPU TIME: 6585.201451 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 +* PT2 Energy denominator -225.4079601302093 + +.. >>>>> [ RES MEM : 2.102699 GB ] [ VIRT MEM : 8.621910 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 95.814826 s ] [ CPU TIME: 6587.327793 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 2.102699 GB ] [ VIRT MEM : 8.621910 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 95.815396 s ] [ CPU TIME: 6587.369192 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 +* Number of tasks 116700 +* Number of fragmented tasks 15251 +* Number of threads for PT2 72 +* Memory (Gb) 0.8919075667858124 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5849962626 0.134E-02 0.8972709747 0.0371299504 11.4441 + 4 -225.5854321808 0.102E-02 0.8986758707 0.0372476820 13.3863 + 5 -225.5843503053 0.128E-02 0.8947566954 0.0369658743 15.3441 + 6 -225.5843632328 0.101E-02 0.8956933749 0.0369362847 17.2759 + 7 -225.5842464805 0.855E-03 0.8957702335 0.0368898957 19.2971 + 9 -225.5841783695 0.708E-03 0.8941182532 0.0369007524 21.6851 + 10 -225.5843743582 0.602E-03 0.8952960574 0.0369378730 23.1861 + 12 -225.5842228577 0.726E-03 0.8935908051 0.0369303165 26.6714 + 15 -225.5845102376 0.616E-03 0.8940945038 0.0370193727 30.1754 + 18 -225.5846308406 0.627E-03 0.8941191043 0.0370607582 32.5404 + 19 -225.5849048093 0.654E-03 0.8954619009 0.0371168908 34.0947 + 20 -225.5847409713 0.642E-03 0.8944451638 0.0370877319 35.3393 + 22 -225.5849412857 0.646E-03 0.8968858465 0.0370873326 36.9575 + 24 -225.5853397473 0.675E-03 0.8991401962 0.0371550982 39.8331 + 25 -225.5855211885 0.673E-03 0.9003608266 0.0371825455 41.9427 + 28 -225.5853591814 0.616E-03 0.8997788496 0.0371428206 44.5271 + 29 -225.5854412443 0.599E-03 0.9000762995 0.0371622886 46.3361 + 30 -225.5855233228 0.597E-03 0.9003101909 0.0371844910 48.0540 + 32 -225.5855814452 0.563E-03 0.9008092814 0.0371882904 50.1321 + 34 -225.5854341307 0.540E-03 0.8998202068 0.0371655016 57.0734 + 41 -225.5852696678 0.470E-03 0.8980829013 0.0371562992 59.0371 + 42 -225.5853598806 0.468E-03 0.8985891976 0.0371733271 60.3501 + 44 -225.5852379655 0.466E-03 0.8978595556 0.0371505125 61.6371 + 45 -225.5852419148 0.455E-03 0.8977997629 0.0371535766 62.6683 + 47 -225.5852292841 0.427E-03 0.8979972828 0.0371424245 64.7391 + 50 -225.5852457753 0.403E-03 0.8981537544 0.0371450447 67.0031 + 52 -225.5853165477 0.387E-03 0.8984492783 0.0371612131 68.4081 + 54 -225.5853369264 0.378E-03 0.8987232338 0.0371604564 70.6107 + 58 -225.5854037402 0.356E-03 0.8993592860 0.0371657836 72.6171 + 61 -225.5854204981 0.340E-03 0.8994865147 0.0371679526 74.4272 + 62 -225.5853614801 0.340E-03 0.8991815778 0.0371561528 75.9350 + 67 -225.5852813337 0.320E-03 0.8985877610 0.0371454296 77.8525 + 68 -225.5852512882 0.317E-03 0.8983367006 0.0371423948 79.1068 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 2.820580 GB ] [ VIRT MEM : 9.227940 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 175.630624 s ] [ CPU TIME: 12274.765112 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 2.820580 GB ] [ VIRT MEM : 9.227940 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 175.631225 s ] [ CPU TIME: 12274.808944 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7700530467324854 + +Summary at N_det = 81920 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.40796013 +# PT2 -0.17733876 0.00031560 +# rPT2 -0.17098616 0.00030429 +# +# E+PT2 -225.58529889 0.00031560 +# E+rPT2 -225.57894629 0.00030429 +# ============ ============================= + + N_det = 81920 + N_states = 1 + + * State 1 + < S^2 > = 1.183390080009971E-002 + E = -225.407960130209 + Variance = 0.898528688631529 + PT norm = 0.192750384281511 + PT2 = -0.177338755751694 + rPT2 = -0.170986156553694 + E+PT2 = -225.585298885961 +/- 3.155996686990933E-004 + E+rPT2 = -225.578946286763 +/- 3.042943102411032E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.121963213149 + Vee = 239.040271733507 + Vecp = 0.000000000000000E+000 + T = 225.169381628369 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2137 -225.60803486 + -0.2640 -225.60876075 + -0.3196 -225.60662490 + -0.3746 -225.60572627 + -0.4277 -225.60421413 + -0.4771 -225.60211907 + -0.5189 -225.60040611 + =========== =================== + +* Number of unique beta determinants 20133 +* Number of unique alpha determinants 20119 + +.. >>>>> [ RES MEM : 2.814541 GB ] [ VIRT MEM : 9.218262 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 177.505138 s ] [ CPU TIME: 12408.810158 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 163840 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.2768857404589653 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.4079603895 0.011834 0.882E-02 + 2 -225.4427400432 0.005945 0.288E-03 + 3 -225.4433934487 0.005757 0.541E-04 + 4 -225.4434482274 0.005790 0.388E-05 + 5 -225.4434544055 0.005791 0.416E-06 + 6 -225.4434551084 0.005790 0.188E-07 + 7 -225.4434551620 0.005791 0.105E-08 + 8 -225.4434551650 0.005791 0.605E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 2.953785 GB ] [ VIRT MEM : 9.422375 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 192.297606 s ] [ CPU TIME: 13462.584255 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 2.887966 GB ] [ VIRT MEM : 9.311527 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 192.306436 s ] [ CPU TIME: 13463.219240 s ] <<<<< .. + +* Energy of state 1 -225.4434551649908 +* S^2 of state 1 0.5790721777031290E-02 +* Saved determinants 163840 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 2.818108 GB ] [ VIRT MEM : 9.237793 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 194.469108 s ] [ CPU TIME: 13529.805807 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 2.818108 GB ] [ VIRT MEM : 9.237793 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 194.469903 s ] [ CPU TIME: 13529.863169 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 +* PT2 Energy denominator -225.4434551649908 + +.. >>>>> [ RES MEM : 2.829502 GB ] [ VIRT MEM : 9.252335 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 194.525029 s ] [ CPU TIME: 13533.821754 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 2.829502 GB ] [ VIRT MEM : 9.252335 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 194.525788 s ] [ CPU TIME: 13533.876576 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 +* Number of tasks 234060 +* Number of fragmented tasks 19953 +* Number of threads for PT2 72 +* Memory (Gb) 1.779430168867111 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5918417333 0.225E-02 0.7987844646 0.0291020590 21.7100 + 4 -225.5899080253 0.256E-02 0.7894863474 0.0286989709 26.9518 + 5 -225.5904310571 0.201E-02 0.7916880050 0.0288222677 28.4317 + 6 -225.5894314321 0.192E-02 0.7864678636 0.0286155833 32.3957 + 7 -225.5886134055 0.182E-02 0.7833178894 0.0284242453 35.6958 + 8 -225.5891898666 0.165E-02 0.7868406610 0.0285268882 38.0387 + 9 -225.5893846091 0.146E-02 0.7886216628 0.0285520668 42.1084 + 11 -225.5890735905 0.122E-02 0.7875085703 0.0284753596 44.6837 + 12 -225.5895048818 0.118E-02 0.7892222066 0.0285804305 48.9494 + 13 -225.5898655464 0.114E-02 0.7915517525 0.0286349958 60.3327 + 19 -225.5896540379 0.749E-03 0.7908492674 0.0285834277 62.3192 + 20 -225.5895372222 0.720E-03 0.7902493406 0.0285591157 65.3117 + 21 -225.5894223526 0.694E-03 0.7895061929 0.0285384154 67.0677 + 22 -225.5894935543 0.650E-03 0.7898301495 0.0285553772 69.4897 + 24 -225.5895945250 0.627E-03 0.7911943834 0.0285546631 71.7917 + 25 -225.5896544107 0.553E-03 0.7913240463 0.0285726304 75.9968 + 27 -225.5897174160 0.519E-03 0.7915389819 0.0285855080 79.7737 + 28 -225.5895747779 0.520E-03 0.7908258811 0.0285587986 81.1822 + 29 -225.5894662816 0.514E-03 0.7899577463 0.0285471322 84.9367 + 30 -225.5894124904 0.499E-03 0.7891681224 0.0285523389 87.7310 + 32 -225.5893870720 0.489E-03 0.7886655179 0.0285615755 90.8277 + 33 -225.5892760008 0.486E-03 0.7878807106 0.0285445559 93.1141 + 34 -225.5890014677 0.522E-03 0.7861915562 0.0284981552 104.8863 + 41 -225.5889272875 0.423E-03 0.7858147299 0.0284858291 106.8543 + 42 -225.5889806806 0.416E-03 0.7861559842 0.0284947911 108.5967 + 43 -225.5890083420 0.389E-03 0.7859473584 0.0285094624 111.4169 + 45 -225.5890454058 0.373E-03 0.7859201516 0.0285237395 115.4128 + 47 -225.5889484741 0.367E-03 0.7855888125 0.0284989841 117.1319 + 48 -225.5889753010 0.360E-03 0.7856513752 0.0285081037 120.5116 + 50 -225.5890104441 0.348E-03 0.7856437650 0.0285212354 123.1939 + 53 -225.5890931496 0.361E-03 0.7859014962 0.0285429308 124.2635 + 54 -225.5890842983 0.355E-03 0.7859543342 0.0285390326 130.9100 + 58 -225.5889594649 0.342E-03 0.7853006878 0.0285136701 132.7966 + 60 -225.5888580817 0.338E-03 0.7848175566 0.0284944053 135.1967 + 62 -225.5888549226 0.327E-03 0.7848132916 0.0284914912 137.8050 + 63 -225.5888548946 0.321E-03 0.7847804976 0.0284919400 139.1291 + 67 -225.5888328241 0.306E-03 0.7844653361 0.0284919969 142.4781 + 69 -225.5886594274 0.284E-03 0.7833359899 0.0284638833 145.5907 + 71 -225.5886536315 0.276E-03 0.7833645677 0.0284603235 148.1562 + 75 -225.5885085415 0.285E-03 0.7823237565 0.0284397731 150.9276 + 76 -225.5884836407 0.282E-03 0.7822514590 0.0284336437 152.2708 + 77 -225.5884719373 0.279E-03 0.7822322198 0.0284300911 154.5864 + 78 -225.5884118267 0.282E-03 0.7819035852 0.0284192357 155.8097 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 3.168682 GB ] [ VIRT MEM : 9.383904 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 353.661876 s ] [ CPU TIME: 24890.235265 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 3.168682 GB ] [ VIRT MEM : 9.383904 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 353.663312 s ] [ CPU TIME: 24890.337511 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8118137356897602 + +Summary at N_det = 163840 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.44345516 +# PT2 -0.14496964 0.00026388 +# rPT2 -0.14096309 0.00025659 +# +# E+PT2 -225.58842481 0.00026388 +# E+rPT2 -225.58441826 0.00025659 +# ============ ============================= + + N_det = 163840 + N_states = 1 + + * State 1 + < S^2 > = 5.790721777031290E-003 + E = -225.443455164991 + Variance = 0.782005793346901 + PT norm = 0.168590237957780 + PT2 = -0.144969640937763 + rPT2 = -0.140963093678706 + E+PT2 = -225.588424805929 +/- 2.638820090776648E-004 + E+rPT2 = -225.584418258670 +/- 2.565890632350341E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.098309521050 + Vee = 238.969647926615 + Vecp = 0.000000000000000E+000 + T = 225.180856708380 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1710 -225.61011004 + -0.2137 -225.60897489 + -0.2640 -225.60905289 + -0.3196 -225.60752271 + -0.3746 -225.60667900 + -0.4277 -225.60540247 + -0.4771 -225.60366526 + =========== =================== + +* Number of unique beta determinants 40833 +* Number of unique alpha determinants 40951 + +.. >>>>> [ RES MEM : 3.249355 GB ] [ VIRT MEM : 9.468754 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 360.406533 s ] [ CPU TIME: 25373.469317 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 327680 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.5556704998016357 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.4434553637 0.005791 0.465E-02 + 2 -225.4626695577 0.002854 0.266E-03 + 3 -225.4632305600 0.002780 0.300E-04 + 4 -225.4632976751 0.002807 0.649E-05 + 5 -225.4633081449 0.002815 0.166E-05 + 6 -225.4633101329 0.002819 0.159E-06 + 7 -225.4633104681 0.002821 0.109E-07 + 8 -225.4633104956 0.002822 0.937E-09 + 9 -225.4633104979 0.002822 0.103E-09 + 10 -225.4633104981 0.002822 0.927E-11 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 3.641666 GB ] [ VIRT MEM : 9.871944 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 424.735833 s ] [ CPU TIME: 29931.118459 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 3.334122 GB ] [ VIRT MEM : 9.504257 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 424.785583 s ] [ CPU TIME: 29934.692458 s ] <<<<< .. + +* Energy of state 1 -225.4633104981314 +* S^2 of state 1 0.2821536464935281E-02 +* Saved determinants 327680 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 3.338127 GB ] [ VIRT MEM : 9.504257 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 428.950820 s ] [ CPU TIME: 30032.873279 s ] <<<<< .. + +* Number of generators 327680 + +.. >>>>> [ RES MEM : 3.338127 GB ] [ VIRT MEM : 9.504257 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 428.951994 s ] [ CPU TIME: 30032.958036 s ] <<<<< .. + +* Number of selectors 327680 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 +* PT2 Energy denominator -225.4633104981314 + +.. >>>>> [ RES MEM : 3.379215 GB ] [ VIRT MEM : 9.544304 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 429.075169 s ] [ CPU TIME: 30041.804178 s ] <<<<< .. + +* Number of generators 327680 + +.. >>>>> [ RES MEM : 3.379215 GB ] [ VIRT MEM : 9.544304 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 429.076325 s ] [ CPU TIME: 30041.887649 s ] <<<<< .. + +* Number of selectors 327680 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 +* Number of tasks 444216 +* Number of fragmented tasks 23156 +* Number of threads for PT2 72 +* Memory (Gb) 3.554475373029709 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5919439179 0.145E-02 0.7260924818 0.0240679994 49.0069 + 4 -225.5913072402 0.145E-02 0.7190309839 0.0240431719 50.2631 + 5 -225.5908149132 0.121E-02 0.7133161409 0.0240270390 55.0729 + 6 -225.5904767809 0.111E-02 0.7143896270 0.0238689495 72.2661 + 7 -225.5900189611 0.105E-02 0.7106018629 0.0238208918 76.0539 + 8 -225.5892439056 0.134E-02 0.7061484761 0.0236814844 78.3226 + 9 -225.5891964203 0.118E-02 0.7056579537 0.0236795256 81.9371 + 10 -225.5896965911 0.117E-02 0.7086454336 0.0237587485 84.6101 + 11 -225.5893996535 0.110E-02 0.7065307519 0.0237227411 95.7602 + 13 -225.5907149897 0.122E-02 0.7144370578 0.0239609430 105.5011 + 15 -225.5910620201 0.110E-02 0.7160471646 0.0240385533 109.7451 + 18 -225.5905885621 0.980E-03 0.7123918471 0.0239783952 117.8981 + 19 -225.5904301128 0.940E-03 0.7114139334 0.0239504128 125.6138 + 21 -225.5904366060 0.937E-03 0.7118005149 0.0239424649 129.9984 + 23 -225.5903385830 0.822E-03 0.7113470018 0.0239195005 135.9211 + 25 -225.5905722774 0.775E-03 0.7128780146 0.0239540982 144.1011 + 27 -225.5906883210 0.741E-03 0.7136227303 0.0239742400 156.8381 + 28 -225.5907355005 0.716E-03 0.7137671732 0.0239864355 159.5556 + 29 -225.5906754295 0.707E-03 0.7133075573 0.0239797468 161.9051 + 30 -225.5908231149 0.699E-03 0.7141675315 0.0240073003 164.5912 + 31 -225.5908010519 0.676E-03 0.7142967846 0.0239943821 166.6764 + 32 -225.5906695031 0.668E-03 0.7131425079 0.0239803894 179.5922 + 35 -225.5905928045 0.578E-03 0.7129310071 0.0239603312 186.6446 + 36 -225.5906410442 0.564E-03 0.7133535528 0.0239652819 190.3091 + 39 -225.5908857388 0.545E-03 0.7144555974 0.0240174257 198.5641 + 41 -225.5908884347 0.529E-03 0.7141134640 0.0240259980 204.8611 + 42 -225.5908934565 0.485E-03 0.7139963315 0.0240297311 207.0194 + 43 -225.5909734802 0.480E-03 0.7146682758 0.0240378551 212.2441 + 44 -225.5910009473 0.470E-03 0.7148293265 0.0240424202 219.5101 + 46 -225.5908565450 0.477E-03 0.7149010107 0.0239885311 222.0751 + 48 -225.5908663991 0.460E-03 0.7149594382 0.0239891478 232.5971 + 51 -225.5909044171 0.446E-03 0.7147245692 0.0240101618 237.5470 + 52 -225.5908176932 0.446E-03 0.7142467747 0.0239937492 240.0456 + 54 -225.5908905515 0.409E-03 0.7147760362 0.0240041342 241.4511 + 55 -225.5908439483 0.404E-03 0.7145230055 0.0239950569 246.1157 + 58 -225.5908375478 0.387E-03 0.7143382718 0.0239971948 248.0144 + 60 -225.5908287808 0.375E-03 0.7140960696 0.0240007939 256.2181 + 62 -225.5909204851 0.380E-03 0.7145630687 0.0240195825 260.9611 + 63 -225.5909854194 0.379E-03 0.7149764065 0.0240311303 263.0731 + 65 -225.5909755512 0.368E-03 0.7151408373 0.0240220182 265.2401 + 67 -225.5909209613 0.374E-03 0.7146726756 0.0240157618 269.0916 + 69 -225.5909879093 0.367E-03 0.7149151709 0.0240324381 274.1492 + 72 -225.5909674430 0.355E-03 0.7149789652 0.0240227210 275.8065 + 74 -225.5909789037 0.350E-03 0.7148958065 0.0240300046 281.1441 + 75 -225.5909804714 0.345E-03 0.7148983883 0.0240306424 285.0811 + 76 -225.5909584896 0.341E-03 0.7147578497 0.0240272583 286.6492 + 77 -225.5909098954 0.340E-03 0.7144575065 0.0240194175 288.8169 + 78 -225.5909806224 0.343E-03 0.7150136582 0.0240281661 292.1841 + 79 -225.5909708912 0.338E-03 0.7147778378 0.0240321616 298.0211 + 80 -225.5910143865 0.336E-03 0.7150895190 0.0240382363 304.8139 + 82 -225.5909863063 0.331E-03 0.7149887188 0.0240319520 307.3583 + 83 -225.5910358353 0.331E-03 0.7153254673 0.0240396935 310.0471 + 85 -225.5910969210 0.328E-03 0.7157008138 0.0240494340 311.1441 + 87 -225.5910206848 0.325E-03 0.7150850541 0.0240396340 313.1321 + 89 -225.5910912175 0.311E-03 0.7156062399 0.0240485453 323.7011 + 92 -225.5910244118 0.306E-03 0.7149842035 0.0240424303 326.9573 + 93 -225.5909998849 0.304E-03 0.7149020068 0.0240365252 328.2056 + 95 -225.5910225776 0.299E-03 0.7150386867 0.0240407158 331.0101 + 96 -225.5910379635 0.296E-03 0.7151287901 0.0240434385 333.1701 + 97 -225.5909820212 0.296E-03 0.7149465646 0.0240280650 338.7821 + 103 -225.5908683032 0.287E-03 0.7141610294 0.0240108599 345.8380 + 104 -225.5908790651 0.284E-03 0.7143589636 0.0240090468 355.1152 + 106 -225.5908375801 0.283E-03 0.7140298842 0.0240041528 356.1420 + 109 -225.5907792288 0.267E-03 0.7136889591 0.0239940360 357.7606 + 111 -225.5907496684 0.264E-03 0.7134868930 0.0239895168 363.8211 + 113 -225.5907747947 0.260E-03 0.7136467255 0.0239933709 371.0341 + 115 -225.5907520274 0.255E-03 0.7135390575 0.0239890465 373.3571 + 119 -225.5906478473 0.253E-03 0.7128071254 0.0239735679 376.9294 + 120 -225.5906344192 0.252E-03 0.7127046083 0.0239722821 378.4481 + 121 -225.5906115262 0.251E-03 0.7125117289 0.0239698710 380.7290 + 123 -225.5906720646 0.249E-03 0.7128039111 0.0239823377 390.6411 + 125 -225.5906851000 0.247E-03 0.7129283334 0.0239833658 395.2162 + 126 -225.5907143592 0.247E-03 0.7131039102 0.0239884473 396.2464 + 129 -225.5906872843 0.245E-03 0.7128664657 0.0239852992 398.7516 + 131 -225.5906701419 0.245E-03 0.7127416435 0.0239831782 402.5451 + 133 -225.5907528548 0.239E-03 0.7133453748 0.0239937839 406.4626 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.077061 GB ] [ VIRT MEM : 9.788429 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 836.818307 s ] [ CPU TIME: 59215.247321 s ] <<<<< .. + +* Number of generators 327680 + +.. >>>>> [ RES MEM : 4.077061 GB ] [ VIRT MEM : 9.788429 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 836.820537 s ] [ CPU TIME: 59215.405249 s ] <<<<< .. + +* Number of selectors 327680 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8345814088175231 + +Summary at N_det = 327680 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.46331050 +# PT2 -0.12745040 0.00023760 +# rPT2 -0.12446387 0.00023204 +# +# E+PT2 -225.59076089 0.00023760 +# E+rPT2 -225.58777437 0.00023204 +# ============ ============================= + + N_det = 327680 + N_states = 1 + + * State 1 + < S^2 > = 2.821536464935281E-003 + E = -225.463310498131 + Variance = 0.713393179055780 + PT norm = 0.154903627877382 + PT2 = -0.127450395014666 + rPT2 = -0.124463867836536 + E+PT2 = -225.590760893146 +/- 2.376036779057344E-004 + E+rPT2 = -225.587774365968 +/- 2.320359443447078E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.079946630836 + Vee = 238.920297867903 + Vecp = 0.000000000000000E+000 + T = 225.191988543737 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1410 -225.61309156 + -0.1710 -225.61118485 + -0.2137 -225.60985961 + -0.2640 -225.60960528 + -0.3196 -225.60828158 + -0.3746 -225.60746638 + -0.4277 -225.60632749 + =========== =================== + +* Number of unique beta determinants 81053 +* Number of unique alpha determinants 81176 + +.. >>>>> [ RES MEM : 3.895657 GB ] [ VIRT MEM : 9.600327 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 856.959470 s ] [ CPU TIME: 60652.755415 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 655360 +* Number of threads for diagonalization 72 +* Memory(Gb) 1.109071705490351 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.4633106125 0.002821 0.189E-02 + 2 -225.4713591665 0.002171 0.205E-03 + 3 -225.4716968826 0.002181 0.391E-04 + 4 -225.4717804651 0.002218 0.133E-04 + 5 -225.4718044248 0.002219 0.200E-05 + 6 -225.4718086395 0.002230 0.216E-06 + 7 -225.4718092567 0.002229 0.331E-07 + 8 -225.4718093380 0.002227 0.446E-08 + 9 -225.4718093493 0.002226 0.536E-09 + 10 -225.4718093507 0.002226 0.631E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 4.498669 GB ] [ VIRT MEM : 10.322418 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1051.367201 s ] [ CPU TIME: 74409.664477 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 3.883434 GB ] [ VIRT MEM : 9.588520 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1051.443342 s ] [ CPU TIME: 74415.133576 s ] <<<<< .. + +* Energy of state 1 -225.4718093506852 +* S^2 of state 1 0.2225797798946368E-02 +* Saved determinants 655360 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 3.881134 GB ] [ VIRT MEM : 9.582436 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1059.320791 s ] [ CPU TIME: 74555.666150 s ] <<<<< .. + +* Number of generators 655352 + +.. >>>>> [ RES MEM : 3.881134 GB ] [ VIRT MEM : 9.582436 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1059.322716 s ] [ CPU TIME: 74555.800955 s ] <<<<< .. + +* Number of selectors 655352 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 +* PT2 Energy denominator -225.4718093506852 + +.. >>>>> [ RES MEM : 3.958103 GB ] [ VIRT MEM : 9.660069 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1059.639624 s ] [ CPU TIME: 74578.267860 s ] <<<<< .. + +* Number of generators 655352 + +.. >>>>> [ RES MEM : 3.958103 GB ] [ VIRT MEM : 9.660069 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1059.641466 s ] [ CPU TIME: 74578.400704 s ] <<<<< .. + +* Number of selectors 655352 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 +* Number of tasks 881899 +* Number of fragmented tasks 24973 +* Number of threads for PT2 72 +* Memory (Gb) 7.104602340757847 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5904857381 0.329E-02 0.6820026658 0.0217343895 100.8579 + 4 -225.5897262841 0.236E-02 0.6759951838 0.0216735871 125.4798 + 5 -225.5900842896 0.168E-02 0.6783263176 0.0217148808 128.7374 + 6 -225.5894009785 0.154E-02 0.6728190690 0.0216338086 142.5408 + 7 -225.5899355066 0.140E-02 0.6741124735 0.0217979930 155.3886 + 8 -225.5897208075 0.126E-02 0.6738675568 0.0217222992 157.4262 + 9 -225.5899606836 0.113E-02 0.6757642800 0.0217361454 172.5198 + 10 -225.5899836054 0.101E-02 0.6763420702 0.0217205695 176.8846 + 11 -225.5900245990 0.909E-03 0.6757093709 0.0217629538 179.6389 + 12 -225.5905258532 0.957E-03 0.6788253427 0.0218452706 186.6838 + 13 -225.5908295330 0.932E-03 0.6818876305 0.0218614161 204.3075 + 14 -225.5913313726 0.100E-02 0.6847827204 0.0219498051 219.2319 + 17 -225.5919143028 0.873E-03 0.6883073423 0.0220491311 237.0178 + 19 -225.5917452972 0.824E-03 0.6862863330 0.0220459140 247.9638 + 20 -225.5917985212 0.763E-03 0.6862458394 0.0220653266 249.4189 + 21 -225.5919291701 0.737E-03 0.6869955394 0.0220891862 269.9149 + 22 -225.5918929170 0.703E-03 0.6866575317 0.0220851024 271.0780 + 23 -225.5919387227 0.651E-03 0.6870579255 0.0220910170 273.8739 + 24 -225.5920360412 0.631E-03 0.6876880655 0.0221089810 279.2359 + 25 -225.5920306082 0.605E-03 0.6876547336 0.0221078488 295.3869 + 27 -225.5923240628 0.636E-03 0.6897873091 0.0221510837 304.4309 + 28 -225.5922787035 0.614E-03 0.6891223269 0.0221555213 329.6879 + 30 -225.5921862680 0.577E-03 0.6877372564 0.0221691011 340.0688 + 31 -225.5920295956 0.579E-03 0.6869825990 0.0221360007 343.7048 + 32 -225.5921462436 0.573E-03 0.6879872897 0.0221496102 348.3359 + 34 -225.5919414455 0.535E-03 0.6866875178 0.0221157484 381.6459 + 39 -225.5918223643 0.492E-03 0.6854931150 0.0221095625 387.7969 + 41 -225.5917894205 0.480E-03 0.6851909142 0.0221054554 411.8939 + 42 -225.5918607151 0.473E-03 0.6858625601 0.0221116390 419.1109 + 43 -225.5919012438 0.472E-03 0.6863190005 0.0221116620 427.3759 + 45 -225.5920673844 0.465E-03 0.6871516638 0.0221432531 446.8244 + 48 -225.5920363585 0.432E-03 0.6868544953 0.0221414733 458.3409 + 49 -225.5919965630 0.425E-03 0.6865223574 0.0221380526 459.7956 + 50 -225.5919244600 0.423E-03 0.6859799997 0.0221300330 462.8019 + 51 -225.5919545472 0.416E-03 0.6861815848 0.0221349714 471.2068 + 52 -225.5920005891 0.396E-03 0.6861018891 0.0221547194 476.1069 + 53 -225.5919197413 0.397E-03 0.6857859516 0.0221352884 492.3596 + 58 -225.5919369545 0.364E-03 0.6861290556 0.0221322271 506.9198 + 61 -225.5918306406 0.346E-03 0.6852441948 0.0221196762 509.7788 + 62 -225.5918828168 0.344E-03 0.6854589874 0.0221310213 514.8181 + 63 -225.5918650657 0.339E-03 0.6852594385 0.0221312164 534.3588 + 68 -225.5920392893 0.324E-03 0.6861286215 0.0221689054 538.8908 + 69 -225.5920553711 0.320E-03 0.6861776259 0.0221731126 540.6381 + 70 -225.5920779992 0.316E-03 0.6863833266 0.0221746426 561.1999 + 71 -225.5921039882 0.312E-03 0.6866148384 0.0221784234 562.8259 + 74 -225.5920408657 0.306E-03 0.6862465661 0.0221658402 568.6930 + 76 -225.5921042820 0.301E-03 0.6866785019 0.0221766290 587.6779 + 78 -225.5921139111 0.294E-03 0.6867283939 0.0221783403 604.2729 + 80 -225.5921311247 0.289E-03 0.6868851777 0.0221790745 612.5229 + 83 -225.5921267725 0.284E-03 0.6869540200 0.0221736580 616.9319 + 84 -225.5920669020 0.287E-03 0.6864652733 0.0221675123 621.0809 + 86 -225.5920923650 0.282E-03 0.6865866081 0.0221730437 622.8529 + 88 -225.5921224385 0.279E-03 0.6866706186 0.0221802552 625.3269 + 89 -225.5921181157 0.276E-03 0.6866153748 0.0221799994 635.5979 + 90 -225.5921664851 0.277E-03 0.6868571919 0.0221895639 640.4898 + 91 -225.5921690872 0.274E-03 0.6868017171 0.0221918003 660.4868 + 92 -225.5921917347 0.272E-03 0.6869548265 0.0221954485 670.7759 + 98 -225.5921628755 0.276E-03 0.6865645024 0.0221975438 684.6478 + 100 -225.5921563221 0.271E-03 0.6864993382 0.0221979945 694.3758 + 101 -225.5921949115 0.271E-03 0.6866959167 0.0222051017 699.6698 + 104 -225.5921596562 0.266E-03 0.6864436453 0.0222000744 704.2571 + 105 -225.5922602613 0.267E-03 0.6869434733 0.0222216615 716.0348 + 112 -225.5923244621 0.253E-03 0.6874000861 0.0222312718 718.8749 + 114 -225.5922406408 0.256E-03 0.6868106675 0.0222195902 740.5408 + 119 -225.5921405451 0.239E-03 0.6864653091 0.0221958739 748.1410 + 120 -225.5921135929 0.239E-03 0.6863258337 0.0221907783 756.9148 + 121 -225.5921011585 0.237E-03 0.6862453497 0.0221886812 762.9808 + 123 -225.5920711539 0.236E-03 0.6860771522 0.0221826312 772.1058 + 124 -225.5920705169 0.234E-03 0.6860344775 0.0221835584 774.4750 + 125 -225.5920709971 0.232E-03 0.6860459079 0.0221837263 776.3843 + 126 -225.5921231951 0.236E-03 0.6863651948 0.0221926510 785.6721 + 127 -225.5922253708 0.233E-03 0.6869100298 0.0222116911 791.8089 + 131 -225.5922813372 0.231E-03 0.6873687057 0.0222177615 794.0733 + 133 -225.5922918207 0.229E-03 0.6874172805 0.0222201158 807.1521 + 134 -225.5922522934 0.231E-03 0.6871326752 0.0222145556 808.6025 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.170406 GB ] [ VIRT MEM : 9.737690 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1870.816623 s ] [ CPU TIME: 132593.066176 s ] <<<<< .. + +* Number of generators 655352 + +.. >>>>> [ RES MEM : 4.170406 GB ] [ VIRT MEM : 9.737690 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1870.818499 s ] [ CPU TIME: 132593.200593 s ] <<<<< .. + +* Number of selectors 655352 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8437903795324442 + +Summary at N_det = 655360 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.47180935 +# PT2 -0.12044294 0.00023089 +# rPT2 -0.11782550 0.00022587 +# +# E+PT2 -225.59225229 0.00023089 +# E+rPT2 -225.58963485 0.00022587 +# ============ ============================= + + N_det = 655360 + N_states = 1 + + * State 1 + < S^2 > = 2.225797798946368E-003 + E = -225.471809350685 + Variance = 0.687132675175622 + PT norm = 0.149045481747885 + PT2 = -0.120442942739361 + rPT2 = -0.117825501579944 + E+PT2 = -225.592252293425 +/- 2.308861571434843E-004 + E+rPT2 = -225.589634852265 +/- 2.258685868558282E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.073981548762 + Vee = 238.896563023570 + Vecp = 0.000000000000000E+000 + T = 225.201259453442 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1245 -225.62265694 + -0.1410 -225.61554035 + -0.1710 -225.61255486 + -0.2137 -225.61084893 + -0.2640 -225.61031734 + -0.3196 -225.60902884 + -0.3746 -225.60820239 + =========== =================== + +* Number of unique beta determinants 148999 +* Number of unique alpha determinants 152182 + +.. >>>>> [ RES MEM : 4.074951 GB ] [ VIRT MEM : 9.724419 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1919.102237 s ] [ CPU TIME: 136031.850828 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 1310720 +* Number of threads for diagonalization 72 +* Memory(Gb) 2.187975075095892 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.4718093526 0.002226 0.784E-03 + 2 -225.4751432486 0.002588 0.755E-04 + 3 -225.4752579911 0.002638 0.159E-04 + 4 -225.4752840618 0.002692 0.302E-05 + 5 -225.4752900887 0.002716 0.375E-06 + 6 -225.4752909028 0.002722 0.436E-07 + 7 -225.4752910181 0.002721 0.616E-08 + 8 -225.4752910351 0.002720 0.788E-09 + 9 -225.4752910371 0.002720 0.103E-09 + 10 -225.4752910374 0.002720 0.148E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 5.001301 GB ] [ VIRT MEM : 10.883163 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2389.449855 s ] [ CPU TIME: 169215.162140 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 3.770985 GB ] [ VIRT MEM : 9.416843 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2389.596679 s ] [ CPU TIME: 169220.981668 s ] <<<<< .. + +* Energy of state 1 -225.4752910373738 +* S^2 of state 1 0.2719651392175785E-02 +* Saved determinants 1310720 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 3.693668 GB ] [ VIRT MEM : 9.278942 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2405.166667 s ] [ CPU TIME: 169467.035851 s ] <<<<< .. + +* Number of generators 1310639 + +.. >>>>> [ RES MEM : 3.693668 GB ] [ VIRT MEM : 9.278942 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2405.169939 s ] [ CPU TIME: 169467.271344 s ] <<<<< .. + +* Number of selectors 1310639 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 +* PT2 Energy denominator -225.4752910373738 + +.. >>>>> [ RES MEM : 3.854145 GB ] [ VIRT MEM : 9.440102 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2405.894069 s ] [ CPU TIME: 169518.817032 s ] <<<<< .. + +* Number of generators 1310639 + +.. >>>>> [ RES MEM : 3.854145 GB ] [ VIRT MEM : 9.440102 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2405.897310 s ] [ CPU TIME: 169519.050193 s ] <<<<< .. + +* Number of selectors 1310639 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 +* Number of tasks 1676930 +* Number of fragmented tasks 25727 +* Number of threads for PT2 72 +* Memory (Gb) 14.20485473249108 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5942147894 0.245E-02 0.6829481023 0.0217594849 211.8864 + 4 -225.5942914265 0.164E-02 0.6820952580 0.0218237208 223.3238 + 5 -225.5940880725 0.113E-02 0.6848497525 0.0216704870 265.4097 + 7 -225.5929938258 0.118E-02 0.6756554703 0.0215715792 300.7986 + 8 -225.5928932006 0.957E-03 0.6766987522 0.0215040472 354.0441 + 9 -225.5933702406 0.994E-03 0.6811729354 0.0215388545 374.1551 + 12 -225.5933495546 0.872E-03 0.6799355423 0.0215612587 408.9804 + 14 -225.5937792322 0.927E-03 0.6817299534 0.0216588959 439.0723 + 15 -225.5935288991 0.894E-03 0.6802896532 0.0216109967 461.2611 + 18 -225.5931290148 0.872E-03 0.6780192329 0.0215352355 465.9621 + 19 -225.5931487685 0.762E-03 0.6784260179 0.0215285816 525.8461 + 20 -225.5929309280 0.755E-03 0.6773262596 0.0214845139 543.3531 + 22 -225.5928618441 0.704E-03 0.6765897090 0.0214826712 554.3061 + 24 -225.5928550066 0.647E-03 0.6762696942 0.0214906217 560.2121 + 25 -225.5927691734 0.626E-03 0.6758092444 0.0214741609 586.0291 + 27 -225.5930523949 0.590E-03 0.6776566048 0.0215246310 614.7441 + 28 -225.5933420029 0.639E-03 0.6789186516 0.0215862590 651.9618 + 29 -225.5933304168 0.617E-03 0.6784687017 0.0215946305 680.5349 + 31 -225.5931677230 0.587E-03 0.6771283444 0.0215795396 700.2385 + 32 -225.5932250444 0.571E-03 0.6776586874 0.0215859044 715.2171 + 34 -225.5932127848 0.543E-03 0.6773750009 0.0215889629 737.7715 + 35 -225.5933374046 0.542E-03 0.6780625616 0.0216128457 747.7992 + 36 -225.5932604758 0.532E-03 0.6773756035 0.0216070785 763.6512 + 38 -225.5932988793 0.505E-03 0.6777842160 0.0216060466 769.2492 + 39 -225.5932441078 0.495E-03 0.6771573707 0.0216044992 805.9321 + 41 -225.5932752304 0.473E-03 0.6776689918 0.0215988693 821.4001 + 42 -225.5934099828 0.481E-03 0.6784212383 0.0216226960 870.4362 + 43 -225.5933780585 0.469E-03 0.6782281698 0.0216177839 909.5621 + 45 -225.5932824034 0.460E-03 0.6774560426 0.0216054559 920.3291 + 50 -225.5932261459 0.441E-03 0.6771988563 0.0215925866 922.3661 + 51 -225.5932062826 0.432E-03 0.6768922475 0.0215950564 961.2321 + 52 -225.5932844526 0.422E-03 0.6775273980 0.0216023148 965.3231 + 55 -225.5933423787 0.406E-03 0.6779675175 0.0216102968 972.8063 + 56 -225.5932852719 0.403E-03 0.6776866312 0.0215982392 1005.8031 + 58 -225.5932946490 0.389E-03 0.6778693491 0.0215955990 1021.6051 + 64 -225.5932073533 0.381E-03 0.6771010508 0.0215843371 1030.8142 + 65 -225.5931754558 0.369E-03 0.6769456923 0.0215791090 1032.7591 + 67 -225.5932136138 0.360E-03 0.6772263869 0.0215838881 1071.8061 + 68 -225.5932169735 0.355E-03 0.6773842464 0.0215802189 1105.9931 + 69 -225.5931954870 0.350E-03 0.6773223722 0.0215749459 1109.1901 + 74 -225.5930965484 0.345E-03 0.6767132298 0.0215584280 1173.4811 + 77 -225.5932055676 0.355E-03 0.6773310069 0.0215781624 1207.9693 + 80 -225.5931588201 0.358E-03 0.6767657496 0.0215785533 1209.6851 + 84 -225.5931024302 0.350E-03 0.6765566280 0.0215647675 1213.1972 + 85 -225.5931068676 0.345E-03 0.6765204471 0.0215682043 1285.5141 + 92 -225.5931925517 0.330E-03 0.6769724018 0.0215833214 1300.7411 + 93 -225.5932191386 0.329E-03 0.6769931405 0.0215922656 1305.3013 + 96 -225.5932603862 0.325E-03 0.6774329244 0.0215949019 1313.3442 + 97 -225.5932468762 0.322E-03 0.6772799051 0.0215946610 1327.9272 + 103 -225.5931363628 0.315E-03 0.6765534824 0.0215767105 1341.6662 + 104 -225.5931562870 0.313E-03 0.6767787250 0.0215778226 1394.1765 + 105 -225.5931426471 0.310E-03 0.6767529518 0.0215740883 1430.5272 + 114 -225.5932556623 0.295E-03 0.6774957005 0.0215892904 1483.0331 + 122 -225.5932605241 0.280E-03 0.6775219240 0.0215908485 1495.2571 + 123 -225.5932122900 0.282E-03 0.6772388735 0.0215826970 1498.0598 + 124 -225.5931916272 0.281E-03 0.6772523776 0.0215759289 1508.2851 + 125 -225.5932095633 0.279E-03 0.6773605499 0.0215796660 1521.9382 + 126 -225.5932075988 0.277E-03 0.6773614348 0.0215788897 1542.3131 + 127 -225.5932408250 0.277E-03 0.6775526155 0.0215848577 1545.2562 + 128 -225.5932241282 0.272E-03 0.6775885877 0.0215778704 1568.6883 + 131 -225.5932647021 0.270E-03 0.6779663311 0.0215811778 1584.5628 + 135 -225.5933469853 0.273E-03 0.6785227911 0.0215935950 1590.6637 + 137 -225.5932690905 0.264E-03 0.6781330354 0.0215781789 1600.2709 + 138 -225.5932843726 0.262E-03 0.6782546289 0.0215799557 1648.9952 + 139 -225.5932897068 0.260E-03 0.6782552147 0.0215816358 1673.3545 + 148 -225.5933210397 0.245E-03 0.6785802335 0.0215829171 1681.8227 + 149 -225.5933288710 0.244E-03 0.6786666726 0.0215834561 1701.8072 + 153 -225.5933196229 0.238E-03 0.6787201803 0.0215795505 1740.9652 + 155 -225.5933042149 0.235E-03 0.6786123779 0.0215769035 1769.5855 + 156 -225.5933312487 0.235E-03 0.6787860342 0.0215815780 1775.4887 + 162 -225.5933255364 0.230E-03 0.6787736351 0.0215809345 1813.4923 + 168 -225.5933459599 0.226E-03 0.6789017467 0.0215847470 1825.1124 + 170 -225.5933599468 0.225E-03 0.6790178957 0.0215865018 1852.5984 + 172 -225.5933652732 0.223E-03 0.6790730055 0.0215869850 1854.4110 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.804131 GB ] [ VIRT MEM : 10.455944 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4314.882917 s ] [ CPU TIME: 305466.626847 s ] <<<<< .. + +* Number of generators 1310639 + +.. >>>>> [ RES MEM : 4.804131 GB ] [ VIRT MEM : 10.455944 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4314.886240 s ] [ CPU TIME: 305466.865822 s ] <<<<< .. + +* Number of selectors 1310639 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8470635918737247 + +Summary at N_det = 1310720 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.47529104 +# PT2 -0.11803315 0.00021177 +# rPT2 -0.11553944 0.00020730 +# +# E+PT2 -225.59332418 0.00021177 +# E+rPT2 -225.59083048 0.00020730 +# ============ ============================= + + N_det = 1310720 + N_states = 1 + + * State 1 + < S^2 > = 2.719651392175785E-003 + E = -225.475291037374 + Variance = 0.678703361765323 + PT norm = 0.146911916839643 + PT2 = -0.118033145033822 + rPT2 = -0.115539444345868 + E+PT2 = -225.593324182408 +/- 2.117720513993353E-004 + E+rPT2 = -225.590830481720 +/- 2.072979173744161E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.072442766325 + Vee = 238.886015261655 + Vecp = 0.000000000000000E+000 + T = 225.206786746232 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1178 -225.65125870 + -0.1245 -225.62859676 + -0.1410 -225.61821513 + -0.1710 -225.61404907 + -0.2137 -225.61189654 + -0.2640 -225.61110721 + -0.3196 -225.60978072 + =========== =================== + +* Number of unique beta determinants 281630 +* Number of unique alpha determinants 287334 + +.. >>>>> [ RES MEM : 4.980621 GB ] [ VIRT MEM : 10.786804 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4419.152840 s ] [ CPU TIME: 312822.749434 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 2621440 +* Number of threads for diagonalization 72 +* Memory(Gb) 4.325516309589148 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.4752910376 0.002720 0.334E-03 + 2 -225.4768001992 0.003186 0.149E-04 + 3 -225.4768284885 0.003217 0.350E-05 + 4 -225.4768327376 0.003242 0.341E-06 + 5 -225.4768335815 0.003256 0.581E-07 + 6 -225.4768337275 0.003260 0.127E-07 + 7 -225.4768337555 0.003262 0.202E-08 + 8 -225.4768337610 0.003262 0.436E-09 + 9 -225.4768337621 0.003262 0.674E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 7.117508 GB ] [ VIRT MEM : 13.497887 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5326.540034 s ] [ CPU TIME: 376399.316627 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 4.773888 GB ] [ VIRT MEM : 10.566723 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5326.806032 s ] [ CPU TIME: 376406.281653 s ] <<<<< .. + +* Energy of state 1 -225.4768337621087 +* S^2 of state 1 0.3262108247356288E-02 +* Saved determinants 2621440 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.791489 GB ] [ VIRT MEM : 10.584846 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5358.315088 s ] [ CPU TIME: 376863.650736 s ] <<<<< .. + +* Number of generators 2620816 + +.. >>>>> [ RES MEM : 4.791489 GB ] [ VIRT MEM : 10.584846 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5358.321299 s ] [ CPU TIME: 376864.084614 s ] <<<<< .. + +* Number of selectors 2620816 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 +* PT2 Energy denominator -225.4768337621087 + +.. >>>>> [ RES MEM : 5.055218 GB ] [ VIRT MEM : 10.850792 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5360.075461 s ] [ CPU TIME: 376971.573634 s ] <<<<< .. + +* Number of generators 2620816 + +.. >>>>> [ RES MEM : 5.055218 GB ] [ VIRT MEM : 10.850792 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5360.081563 s ] [ CPU TIME: 376972.012300 s ] <<<<< .. + +* Number of selectors 2620816 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 +* Number of tasks 3232628 +* Number of fragmented tasks 25951 +* Number of threads for PT2 72 +* Memory (Gb) 18.30063669502735 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5924806982 0.141E-02 0.6617708651 0.0212342539 334.4156 + 4 -225.5921780352 0.100E-02 0.6585432088 0.0212452098 415.3215 + 5 -225.5925742076 0.876E-03 0.6637281449 0.0212312503 440.2376 + 6 -225.5928482227 0.762E-03 0.6643883859 0.0213134516 518.3855 + 7 -225.5929572027 0.648E-03 0.6642542319 0.0213589713 574.5646 + 8 -225.5929622600 0.514E-03 0.6665685111 0.0212878514 642.0048 + 9 -225.5927904920 0.460E-03 0.6659111440 0.0212405964 701.5847 + 11 -225.5936343573 0.708E-03 0.6717273820 0.0213620163 723.0419 + 12 -225.5941866006 0.767E-03 0.6745003206 0.0214743378 767.4083 + 13 -225.5941997521 0.705E-03 0.6744654328 0.0214823760 810.2876 + 14 -225.5944888130 0.715E-03 0.6761124008 0.0215327432 866.8883 + 15 -225.5942804948 0.673E-03 0.6750950481 0.0214857959 917.6386 + 18 -225.5945901779 0.611E-03 0.6769757973 0.0215355429 964.9157 + 19 -225.5943661719 0.620E-03 0.6758465636 0.0214896020 1021.4795 + 20 -225.5943391704 0.625E-03 0.6764085941 0.0214620060 1033.8007 + 21 -225.5941784298 0.616E-03 0.6754539154 0.0214313183 1037.4270 + 22 -225.5942206874 0.588E-03 0.6764915450 0.0214173259 1121.5146 + 24 -225.5940100672 0.597E-03 0.6753115992 0.0213747141 1147.6695 + 25 -225.5937662169 0.623E-03 0.6740506526 0.0213249318 1184.4659 + 26 -225.5938892044 0.611E-03 0.6746257252 0.0213542126 1204.5061 + 27 -225.5937101146 0.615E-03 0.6731418534 0.0213355548 1228.5293 + 28 -225.5936556129 0.599E-03 0.6728496920 0.0213273342 1309.4146 + 29 -225.5936671751 0.578E-03 0.6729124554 0.0213286384 1337.2096 + 30 -225.5936260245 0.559E-03 0.6725510640 0.0213244048 1341.6377 + 31 -225.5936410051 0.541E-03 0.6723632716 0.0213360727 1402.7864 + 32 -225.5937063718 0.528E-03 0.6728800351 0.0213431477 1430.0330 + 33 -225.5936696862 0.501E-03 0.6726572621 0.0213338120 1464.0119 + 34 -225.5937839917 0.499E-03 0.6733990207 0.0213513166 1471.3222 + 35 -225.5939288761 0.506E-03 0.6741265505 0.0213797833 1547.5326 + 36 -225.5938267392 0.503E-03 0.6733252655 0.0213678662 1558.6682 + 37 -225.5938762165 0.491E-03 0.6735617253 0.0213790012 1569.2719 + 39 -225.5938534233 0.471E-03 0.6733931842 0.0213756509 1596.0160 + 40 -225.5939732216 0.475E-03 0.6741490359 0.0213940463 1634.0436 + 41 -225.5940044186 0.464E-03 0.6745527569 0.0213939069 1712.1746 + 43 -225.5939086411 0.452E-03 0.6743018013 0.0213677464 1782.9415 + 44 -225.5940145718 0.454E-03 0.6747466803 0.0213912138 1786.0819 + 45 -225.5939397333 0.450E-03 0.6742178056 0.0213800157 1795.9216 + 47 -225.5939067980 0.449E-03 0.6741010964 0.0213734355 1868.5966 + 49 -225.5937823954 0.454E-03 0.6733422129 0.0213528577 1892.9736 + 50 -225.5936420914 0.466E-03 0.6721802438 0.0213369963 1933.6964 + 51 -225.5937737070 0.476E-03 0.6730250421 0.0213584092 1965.4063 + 53 -225.5934795010 0.486E-03 0.6715039386 0.0213010085 1971.6642 + 54 -225.5934020330 0.483E-03 0.6707831636 0.0212940165 1996.4816 + 55 -225.5934066821 0.474E-03 0.6710443803 0.0212888687 2006.6096 + 56 -225.5933620421 0.468E-03 0.6708806792 0.0212774883 2020.4299 + 58 -225.5934655315 0.463E-03 0.6713450409 0.0212996496 2076.9402 + 61 -225.5934069779 0.417E-03 0.6713538407 0.0212804025 2091.6716 + 62 -225.5934187846 0.410E-03 0.6714266129 0.0212824612 2098.4167 + 63 -225.5934387046 0.404E-03 0.6715473703 0.0212853050 2146.9361 + 67 -225.5934969300 0.380E-03 0.6713958745 0.0213104774 2184.3826 + 68 -225.5934786128 0.375E-03 0.6713059111 0.0213070314 2237.2806 + 70 -225.5934413827 0.366E-03 0.6712001290 0.0212971286 2267.6149 + 73 -225.5934672969 0.370E-03 0.6714477612 0.0212984677 2299.6770 + 74 -225.5934339963 0.366E-03 0.6713049917 0.0212911686 2330.9516 + 75 -225.5934274383 0.361E-03 0.6711821263 0.0212922354 2341.1306 + 77 -225.5933686944 0.354E-03 0.6708475572 0.0212810434 2355.9653 + 78 -225.5933579424 0.350E-03 0.6707154708 0.0212804504 2422.0846 + 80 -225.5933340405 0.344E-03 0.6707462694 0.0212720399 2469.0766 + 83 -225.5934046691 0.333E-03 0.6717237054 0.0212700450 2493.2748 + 85 -225.5934253185 0.326E-03 0.6717887159 0.0212753989 2524.0716 + 88 -225.5934611382 0.323E-03 0.6721818329 0.0212768470 2542.2286 + 89 -225.5934753754 0.320E-03 0.6722407688 0.0212802005 2562.1456 + 91 -225.5934915054 0.313E-03 0.6723950180 0.0212811589 2614.3536 + 92 -225.5934995967 0.310E-03 0.6723932288 0.0212839688 2639.0751 + 94 -225.5934737019 0.294E-03 0.6721879113 0.0212811957 2703.4898 + 97 -225.5934404455 0.287E-03 0.6720164501 0.0212743158 2766.0316 + 103 -225.5936109557 0.283E-03 0.6730836694 0.0213026709 2769.9460 + 104 -225.5935879615 0.282E-03 0.6729683906 0.0212977436 2771.4233 + 105 -225.5935361090 0.284E-03 0.6726562912 0.0212889458 2810.1131 + 108 -225.5935728614 0.289E-03 0.6727654493 0.0212987624 2852.1946 + 109 -225.5935872749 0.287E-03 0.6728246428 0.0213019214 2880.5721 + 113 -225.5936187907 0.278E-03 0.6731261716 0.0213035485 2903.3260 + 114 -225.5936479627 0.277E-03 0.6732357626 0.0213102581 2968.9008 + 118 -225.5936915834 0.269E-03 0.6735834363 0.0213149910 2970.0570 + 119 -225.5937658617 0.277E-03 0.6739304603 0.0213304713 3000.7737 + 120 -225.5937450670 0.275E-03 0.6738168235 0.0213264092 3061.3837 + 123 -225.5937526791 0.269E-03 0.6738855795 0.0213273250 3082.6742 + 124 -225.5937082554 0.271E-03 0.6735735732 0.0213206487 3110.9280 + 125 -225.5936830726 0.270E-03 0.6734183853 0.0213162083 3119.3485 + 126 -225.5936545729 0.269E-03 0.6731973089 0.0213123438 3126.6391 + 128 -225.5936450279 0.269E-03 0.6731148764 0.0213112384 3193.1862 + 135 -225.5935504729 0.267E-03 0.6724713738 0.0212967090 3213.9659 + 136 -225.5935353485 0.265E-03 0.6723987190 0.0212939419 3225.2844 + 137 -225.5934605549 0.256E-03 0.6719924924 0.0212805599 3309.1261 + 141 -225.5934657146 0.250E-03 0.6720666951 0.0212799529 3377.8870 + 145 -225.5934163260 0.249E-03 0.6717201141 0.0212730766 3378.8934 + 147 -225.5933041767 0.238E-03 0.6712217472 0.0212484507 3409.5773 + 148 -225.5933073135 0.236E-03 0.6712325584 0.0212493888 3435.5611 + 150 -225.5933078899 0.233E-03 0.6713251941 0.0212477755 3442.2874 + 151 -225.5933119625 0.232E-03 0.6713429925 0.0212487928 3469.2765 + 152 -225.5933259399 0.231E-03 0.6714497231 0.0212504455 3479.3255 + 153 -225.5933243583 0.229E-03 0.6714195698 0.0212505723 3505.8044 + 154 -225.5933234237 0.228E-03 0.6713983802 0.0212508468 3510.1440 + 156 -225.5932378546 0.216E-03 0.6709751152 0.0212337201 3534.9308 + 158 -225.5932509152 0.213E-03 0.6710399962 0.0212362335 3543.8965 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 5.995941 GB ] [ VIRT MEM : 11.772282 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8914.253452 s ] [ CPU TIME: 620040.988100 s ] <<<<< .. + +* Number of generators 2620816 + +.. >>>>> [ RES MEM : 5.995941 GB ] [ VIRT MEM : 11.772282 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8914.259714 s ] [ CPU TIME: 620041.438151 s ] <<<<< .. + +* Number of selectors 2620816 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8491326083516070 + +Summary at N_det = 2621440 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.47683376 +# PT2 -0.11639258 0.00021343 +# rPT2 -0.11397274 0.00020900 +# +# E+PT2 -225.59322634 0.00021343 +# E+rPT2 -225.59080650 0.00020900 +# ============ ============================= + + N_det = 2621440 + N_states = 1 + + * State 1 + < S^2 > = 3.262108247356288E-003 + E = -225.476833762109 + Variance = 0.670902010866012 + PT norm = 0.145711091771359 + PT2 = -0.116392576277199 + rPT2 = -0.113972738742416 + E+PT2 = -225.593226338386 +/- 2.134347849209270E-004 + E+rPT2 = -225.590806500851 +/- 2.089974099585408E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.072251161990 + Vee = 238.881603734297 + Vecp = 0.000000000000000E+000 + T = 225.209463944520 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1155 -225.58906197 + -0.1178 -225.62748348 + -0.1245 -225.62595411 + -0.1410 -225.61835027 + -0.1710 -225.61441834 + -0.2137 -225.61227093 + -0.2640 -225.61143321 + =========== =================== + +* Number of unique beta determinants 504304 +* Number of unique alpha determinants 511863 + +.. >>>>> [ RES MEM : 5.637024 GB ] [ VIRT MEM : 11.685673 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9155.376152 s ] [ CPU TIME: 636896.887096 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5242880 +* Number of threads for diagonalization 72 +* Memory(Gb) 8.465372323989868 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.4768337630 0.003262 0.337E-03 + 2 -225.4784081524 0.003742 0.153E-04 + 3 -225.4784384165 0.003778 0.378E-05 + 4 -225.4784431299 0.003800 0.412E-06 + 5 -225.4784442120 0.003808 0.871E-07 + 6 -225.4784444624 0.003811 0.153E-07 + 7 -225.4784445104 0.003813 0.257E-08 + 8 -225.4784445177 0.003813 0.544E-09 + 9 -225.4784445192 0.003812 0.903E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 10.858303 GB ] [ VIRT MEM : 18.083237 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11273.347372 s ] [ CPU TIME: 784925.992472 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 6.014709 GB ] [ VIRT MEM : 12.065643 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11273.811965 s ] [ CPU TIME: 784932.908941 s ] <<<<< .. + +* Energy of state 1 -225.4784445191615 +* S^2 of state 1 0.3812231824485266E-02 +* Saved determinants 5242880 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 5.957134 GB ] [ VIRT MEM : 11.816189 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11336.847063 s ] [ CPU TIME: 785791.010035 s ] <<<<< .. + +* Number of generators 5240586 + +.. >>>>> [ RES MEM : 5.957134 GB ] [ VIRT MEM : 11.816189 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11336.858864 s ] [ CPU TIME: 785791.846158 s ] <<<<< .. + +* Number of selectors 5240586 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 +* PT2 Energy denominator -225.4784445191615 + +.. >>>>> [ RES MEM : 6.786274 GB ] [ VIRT MEM : 12.649033 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11340.567165 s ] [ CPU TIME: 785981.205940 s ] <<<<< .. + +* Number of generators 5240586 + +.. >>>>> [ RES MEM : 6.786274 GB ] [ VIRT MEM : 12.649033 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11340.578320 s ] [ CPU TIME: 785981.217009 s ] <<<<< .. + +* Number of selectors 5240586 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 +* Number of tasks 6244827 +* Number of fragmented tasks 26192 +* Number of threads for PT2 72 +* Memory (Gb) 18.57653538964689 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5917661894 0.517E-03 0.6580222030 0.0204783352 692.3951 + 4 -225.5928276223 0.121E-02 0.6615434741 0.0207698974 834.8188 + 5 -225.5927911992 0.796E-03 0.6621832631 0.0207518307 1011.7462 + 6 -225.5922906118 0.830E-03 0.6589454299 0.0206842361 1068.3585 + 7 -225.5912726507 0.127E-02 0.6512884035 0.0205567681 1223.5937 + 8 -225.5913879705 0.110E-02 0.6525044868 0.0205578186 1361.4659 + 9 -225.5919112377 0.113E-02 0.6554970207 0.0206482808 1481.1056 + 10 -225.5923893955 0.112E-02 0.6589091909 0.0207180204 1504.4965 + 11 -225.5920532727 0.107E-02 0.6563743012 0.0206732196 1646.4565 + 12 -225.5925228565 0.115E-02 0.6588070330 0.0207706063 1707.5428 + 13 -225.5922958754 0.108E-02 0.6577690376 0.0207283913 1736.7375 + 14 -225.5923769329 0.100E-02 0.6574754964 0.0207607810 1911.1573 + 15 -225.5923040441 0.897E-03 0.6571056481 0.0207494114 1975.9894 + 17 -225.5925146808 0.800E-03 0.6583557543 0.0207848041 2019.0499 + 18 -225.5923759626 0.766E-03 0.6584459865 0.0207364530 2149.4123 + 19 -225.5925963799 0.758E-03 0.6597459921 0.0207727693 2235.8536 + 20 -225.5923002619 0.785E-03 0.6574557868 0.0207405303 2357.8255 + 22 -225.5921209783 0.730E-03 0.6568469016 0.0206958244 2458.1400 + 24 -225.5922581462 0.669E-03 0.6579963983 0.0207078557 2549.1845 + 25 -225.5922076251 0.644E-03 0.6580944600 0.0206913519 2609.3479 + 26 -225.5922666652 0.621E-03 0.6585472977 0.0206985976 2611.8716 + 27 -225.5923787639 0.608E-03 0.6590548384 0.0207247236 2766.0425 + 28 -225.5926659135 0.685E-03 0.6609975087 0.0207704796 2871.0297 + 29 -225.5928450008 0.685E-03 0.6619961489 0.0208006226 3008.2283 + 30 -225.5928644736 0.662E-03 0.6616279210 0.0208183049 3029.5796 + 31 -225.5928549562 0.640E-03 0.6617166219 0.0208130438 3056.1076 + 32 -225.5927955556 0.623E-03 0.6612771729 0.0208032630 3212.1249 + 33 -225.5925634863 0.584E-03 0.6598102696 0.0207662608 3239.2065 + 34 -225.5923684036 0.599E-03 0.6585681434 0.0207350560 3359.6696 + 35 -225.5923586890 0.582E-03 0.6581288304 0.0207447458 3422.9765 + 36 -225.5924170805 0.569E-03 0.6585194705 0.0207553233 3444.4605 + 37 -225.5924867035 0.557E-03 0.6591100351 0.0207629338 3464.6564 + 38 -225.5927619268 0.591E-03 0.6607076728 0.0208109884 3520.4710 + 39 -225.5927609636 0.576E-03 0.6608211953 0.0208047794 3603.1665 + 41 -225.5928292350 0.558E-03 0.6615284043 0.0208091094 3785.6080 + 42 -225.5928264603 0.544E-03 0.6616676964 0.0208040491 3898.9075 + 43 -225.5926675500 0.548E-03 0.6607419106 0.0207748018 3907.8366 + 44 -225.5927190109 0.538E-03 0.6611544669 0.0207809937 3928.5391 + 45 -225.5927097953 0.526E-03 0.6612289748 0.0207754546 3991.4553 + 47 -225.5927352018 0.516E-03 0.6616082871 0.0207737521 4109.2300 + 49 -225.5926947305 0.504E-03 0.6612297097 0.0207702943 4168.5854 + 50 -225.5927783012 0.501E-03 0.6615767606 0.0207895959 4225.8214 + 51 -225.5927591603 0.491E-03 0.6614410955 0.0207863896 4246.8026 + 52 -225.5927933013 0.473E-03 0.6613866763 0.0208004216 4329.4850 + 54 -225.5929007839 0.463E-03 0.6619392415 0.0208212604 4403.8656 + 55 -225.5929507443 0.457E-03 0.6622294621 0.0208304997 4444.6446 + 58 -225.5929851121 0.453E-03 0.6625077485 0.0208332574 4524.4492 + 60 -225.5929161035 0.436E-03 0.6621642725 0.0208201417 4548.8619 + 61 -225.5928490882 0.434E-03 0.6615954880 0.0208130984 4638.3258 + 62 -225.5928312170 0.428E-03 0.6613610707 0.0208129883 4639.6014 + 63 -225.5928993172 0.426E-03 0.6616429588 0.0208284656 4700.8667 + 65 -225.5927952304 0.420E-03 0.6610541467 0.0208098889 4745.7006 + 67 -225.5929512271 0.422E-03 0.6619228981 0.0208390253 4748.3029 + 68 -225.5929433915 0.416E-03 0.6619766076 0.0208351936 4788.7215 + 69 -225.5929136194 0.411E-03 0.6618330598 0.0208287310 4873.7190 + 70 -225.5928208534 0.413E-03 0.6609475181 0.0208243663 4888.0548 + 71 -225.5928697726 0.410E-03 0.6614049416 0.0208290765 4972.0635 + 73 -225.5929557716 0.411E-03 0.6619058521 0.0208424536 4975.4465 + 74 -225.5929076289 0.408E-03 0.6615078472 0.0208368753 5079.8136 + 76 -225.5928956541 0.385E-03 0.6613677666 0.0208369983 5102.9101 + 77 -225.5928809605 0.380E-03 0.6611249087 0.0208386141 5147.7188 + 78 -225.5928575708 0.376E-03 0.6610449751 0.0208326915 5231.1062 + 80 -225.5927776241 0.373E-03 0.6604561787 0.0208209652 5285.8498 + 81 -225.5927293597 0.371E-03 0.6601199224 0.0208143732 5300.2035 + 82 -225.5926878019 0.369E-03 0.6599106727 0.0208060288 5369.1857 + 84 -225.5927481137 0.357E-03 0.6604151455 0.0208119175 5448.1701 + 85 -225.5928001842 0.356E-03 0.6608673817 0.0208172091 5474.1233 + 86 -225.5927744129 0.353E-03 0.6607403031 0.0208118804 5475.3825 + 87 -225.5927750704 0.349E-03 0.6607039139 0.0208132504 5484.6120 + 88 -225.5927148241 0.350E-03 0.6602520568 0.0208055669 5491.8715 + 89 -225.5926682468 0.349E-03 0.6599691264 0.0207971939 5535.7805 + 91 -225.5926992504 0.345E-03 0.6603944801 0.0207973563 5630.3846 + 92 -225.5927515320 0.345E-03 0.6606496844 0.0208087318 5639.6736 + 93 -225.5927737162 0.343E-03 0.6607717246 0.0208118914 5709.0155 + 95 -225.5927484307 0.337E-03 0.6607525156 0.0208044500 5711.6997 + 96 -225.5927376556 0.334E-03 0.6606087073 0.0208042662 5805.9676 + 97 -225.5927705608 0.332E-03 0.6608653065 0.0208082101 5813.5185 + 98 -225.5927649950 0.328E-03 0.6608444016 0.0208067828 5866.9887 + 101 -225.5927421593 0.320E-03 0.6605759915 0.0208065424 5937.3456 + 103 -225.5927447701 0.317E-03 0.6607329237 0.0208027709 6017.5860 + 104 -225.5927037620 0.316E-03 0.6604025461 0.0207978643 6052.0535 + 105 -225.5927314616 0.315E-03 0.6606231881 0.0208007176 6074.1449 + 106 -225.5927188444 0.312E-03 0.6605015555 0.0207993166 6105.2476 + 107 -225.5926909726 0.311E-03 0.6602569165 0.0207964892 6124.4363 + 108 -225.5926979025 0.308E-03 0.6603435313 0.0207962180 6151.8996 + 111 -225.5927305148 0.300E-03 0.6604576998 0.0208036920 6189.0940 + 112 -225.5927519542 0.299E-03 0.6605695841 0.0208076890 6315.6386 + 116 -225.5928398108 0.282E-03 0.6610236341 0.0208248674 6328.8549 + 117 -225.5928470930 0.280E-03 0.6610504165 0.0208263062 6367.9380 + 118 -225.5928370317 0.277E-03 0.6609879123 0.0208246025 6420.3307 + 120 -225.5928833708 0.275E-03 0.6612420171 0.0208326201 6498.6447 + 121 -225.5929325713 0.277E-03 0.6615065769 0.0208416450 6527.3274 + 123 -225.5929119443 0.277E-03 0.6613333491 0.0208396715 6574.1627 + 124 -225.5929463194 0.277E-03 0.6616055227 0.0208438940 6658.8367 + 126 -225.5929857435 0.277E-03 0.6618003904 0.0208516092 6695.3505 + 128 -225.5930154180 0.275E-03 0.6619971948 0.0208561873 6728.1232 + 129 -225.5930354985 0.274E-03 0.6621681187 0.0208583680 6757.3903 + 131 -225.5930479286 0.271E-03 0.6621142248 0.0208634854 6818.8215 + 133 -225.5930224822 0.269E-03 0.6619224813 0.0208600619 6886.4900 + 135 -225.5929983865 0.269E-03 0.6618341913 0.0208545095 6925.8030 + 136 -225.5929803354 0.267E-03 0.6617304116 0.0208514171 6947.7075 + 137 -225.5929277816 0.263E-03 0.6615250183 0.0208388313 6970.8926 + 138 -225.5929598207 0.263E-03 0.6617423109 0.0208437091 7078.4535 + 142 -225.5929767433 0.257E-03 0.6617405530 0.0208485296 7110.9935 + 143 -225.5929808218 0.255E-03 0.6617673148 0.0208494156 7162.2815 + 145 -225.5929980626 0.255E-03 0.6619171238 0.0208514311 7177.6188 + 146 -225.5929726910 0.255E-03 0.6616576885 0.0208496025 7184.7987 + 147 -225.5929742264 0.253E-03 0.6616498152 0.0208502746 7225.1506 + 148 -225.5929775097 0.252E-03 0.6616639971 0.0208509980 7292.3385 + 150 -225.5929881396 0.249E-03 0.6617489400 0.0208521486 7304.5657 + 152 -225.5929785660 0.246E-03 0.6616761581 0.0208508266 7361.4673 + 153 -225.5929431854 0.247E-03 0.6614444810 0.0208454817 7436.7995 + 154 -225.5929353291 0.245E-03 0.6613754420 0.0208446960 7479.9149 + 155 -225.5929291654 0.244E-03 0.6613382485 0.0208435343 7496.6985 + 156 -225.5929330315 0.242E-03 0.6613757471 0.0208438436 7511.1845 + 157 -225.5929684897 0.243E-03 0.6616125323 0.0208494994 7531.1544 + 158 -225.5929521073 0.239E-03 0.6614287091 0.0208491331 7599.7776 + 162 -225.5929457797 0.235E-03 0.6613726927 0.0208481254 7614.7036 + 163 -225.5929667072 0.234E-03 0.6614919892 0.0208519225 7673.0025 + 165 -225.5929897837 0.234E-03 0.6616640750 0.0208548626 7698.8943 + 167 -225.5929976120 0.232E-03 0.6617173574 0.0208562001 7782.9928 + 168 -225.5929922611 0.231E-03 0.6617072683 0.0208548526 7788.4335 + 169 -225.5929846594 0.226E-03 0.6615451768 0.0208561039 7862.3002 + 170 -225.5929468697 0.228E-03 0.6612773905 0.0208506609 7881.1102 + 174 -225.5929548289 0.224E-03 0.6613307883 0.0208520758 7887.1238 + 175 -225.5929546570 0.223E-03 0.6613114721 0.0208524648 7908.5114 + 176 -225.5929691161 0.222E-03 0.6613764211 0.0208555474 7928.7153 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.020416 GB ] [ VIRT MEM : 13.645912 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 19289.177253 s ] [ CPU TIME: 1340133.155081 s ] <<<<< .. + +* Number of generators 5240586 + +.. >>>>> [ RES MEM : 8.020416 GB ] [ VIRT MEM : 13.645912 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 19289.188443 s ] [ CPU TIME: 1340133.166185 s ] <<<<< .. + +* Number of selectors 5240586 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8514643577258497 + +Summary at N_det = 5242880 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.47844452 +# PT2 -0.11452460 0.00022177 +# rPT2 -0.11218492 0.00021724 +# +# E+PT2 -225.59296912 0.00022177 +# E+rPT2 -225.59062944 0.00021724 +# ============ ============================= + + N_det = 5242880 + N_states = 1 + + * State 1 + < S^2 > = 3.812231824485266E-003 + E = -225.478444519162 + Variance = 0.661376421080550 + PT norm = 0.144414498407750 + PT2 = -0.114524596957591 + rPT2 = -0.112184919066013 + E+PT2 = -225.592969116119 +/- 2.217727277319247E-004 + E+rPT2 = -225.590629438228 +/- 2.172420263645894E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.074043659956 + Vee = 238.878178475346 + Vecp = 0.000000000000000E+000 + T = 225.213070944384 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1140 -225.57951883 + -0.1155 -225.58382511 + -0.1178 -225.61022985 + -0.1245 -225.62041916 + -0.1410 -225.61721970 + -0.1710 -225.61415352 + -0.2137 -225.61223474 + =========== =================== + +* Number of unique beta determinants 847564 +* Number of unique alpha determinants 874708 + +.. >>>>> [ RES MEM : 8.236927 GB ] [ VIRT MEM : 14.872902 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 19976.917756 s ] [ CPU TIME: 1388147.604370 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 10485760 +* Number of threads for diagonalization 72 +* Memory(Gb) 16.49039776995778 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.4784445193 0.003812 0.371E-03 + 2 -225.4802161842 0.004443 0.157E-04 + 3 -225.4802470896 0.004486 0.399E-05 + 4 -225.4802515342 0.004510 0.213E-06 + 5 -225.4802521507 0.004519 0.412E-07 + 6 -225.4802522805 0.004524 0.125E-07 + 7 -225.4802523128 0.004527 0.238E-08 + 8 -225.4802523195 0.004527 0.370E-09 + 9 -225.4802523206 0.004527 0.736E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 18.769630 GB ] [ VIRT MEM : 27.738186 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 26057.279817 s ] [ CPU TIME: 1812346.342393 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 9.082233 GB ] [ VIRT MEM : 15.704967 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 26058.236884 s ] [ CPU TIME: 1812353.092914 s ] <<<<< .. + +* Energy of state 1 -225.4802523206055 +* S^2 of state 1 0.4526611489600436E-02 +* Saved determinants 10485760 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.175552 GB ] [ VIRT MEM : 14.288723 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 26186.990570 s ] [ CPU TIME: 1814024.769270 s ] <<<<< .. + +* Number of generators 10480503 + +.. >>>>> [ RES MEM : 8.175552 GB ] [ VIRT MEM : 14.288723 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 26187.014388 s ] [ CPU TIME: 1814026.480163 s ] <<<<< .. + +* Number of selectors 10480503 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -225.4802523206055 + +.. >>>>> [ RES MEM : 10.012623 GB ] [ VIRT MEM : 16.128902 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 26194.916237 s ] [ CPU TIME: 1814391.473062 s ] <<<<< .. + +* Number of generators 10480503 + +.. >>>>> [ RES MEM : 10.012623 GB ] [ VIRT MEM : 16.128902 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 26194.938984 s ] [ CPU TIME: 1814391.495677 s ] <<<<< .. + +* Number of selectors 10480503 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 11667618 +* Number of fragmented tasks 26399 +* Number of threads for PT2 72 +* Memory (Gb) 19.11322802606970 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5927225334 0.303E-02 0.6513867758 0.0204224515 1172.5519 + 4 -225.5954356291 0.360E-02 0.6629932697 0.0210203812 1480.4700 + 5 -225.5954174529 0.272E-02 0.6651804027 0.0209627908 1733.1239 + 6 -225.5942613088 0.251E-02 0.6579808799 0.0207656363 1971.4150 + 7 -225.5945220958 0.212E-02 0.6593085811 0.0208198597 2303.7758 + 8 -225.5939123516 0.195E-02 0.6568697845 0.0206624368 2500.5308 + 9 -225.5940538302 0.169E-02 0.6580949622 0.0206715076 2736.2530 + 10 -225.5941363440 0.151E-02 0.6586159723 0.0206835914 2811.0680 + 11 -225.5939524793 0.137E-02 0.6572807792 0.0206547841 2943.7660 + 12 -225.5941254867 0.127E-02 0.6575276242 0.0207078243 3149.6890 + 13 -225.5937680895 0.122E-02 0.6553964410 0.0206489595 3346.4659 + 14 -225.5939613328 0.114E-02 0.6568045905 0.0206700242 3555.7143 + 15 -225.5936877010 0.106E-02 0.6555665995 0.0206084180 3621.1836 + 16 -225.5936727715 0.989E-03 0.6551356151 0.0206146880 3666.6510 + 17 -225.5938737870 0.950E-03 0.6563276773 0.0206511632 3813.5119 + 18 -225.5938547521 0.895E-03 0.6562384105 0.0206486000 4012.9050 + 19 -225.5941346008 0.866E-03 0.6578610525 0.0207054093 4133.1059 + 20 -225.5938367645 0.875E-03 0.6565222447 0.0206432354 4437.2101 + 22 -225.5938666125 0.790E-03 0.6568758289 0.0206461056 4582.9303 + 23 -225.5939404107 0.758E-03 0.6572111926 0.0206646199 4696.3900 + 24 -225.5939452005 0.726E-03 0.6569050596 0.0206757299 4887.7180 + 25 -225.5940513669 0.704E-03 0.6576840284 0.0206900436 4913.3446 + 26 -225.5937594406 0.738E-03 0.6562813251 0.0206303779 4919.7239 + 27 -225.5938400351 0.718E-03 0.6561811827 0.0206606578 5167.7630 + 28 -225.5939091528 0.696E-03 0.6564827249 0.0206781719 5391.7150 + 29 -225.5937804022 0.683E-03 0.6559670207 0.0206484775 5603.4144 + 30 -225.5938232816 0.661E-03 0.6558783420 0.0206671493 5738.4504 + 31 -225.5937193191 0.648E-03 0.6552467110 0.0206474133 5789.0970 + 32 -225.5937558890 0.628E-03 0.6551227388 0.0206639138 6042.5760 + 33 -225.5938959581 0.614E-03 0.6562701893 0.0206784789 6222.7320 + 34 -225.5939715779 0.601E-03 0.6568290850 0.0206907773 6320.5430 + 35 -225.5939979151 0.584E-03 0.6568492340 0.0206995808 6410.0725 + 36 -225.5938551062 0.585E-03 0.6560721223 0.0206727501 6631.8230 + 38 -225.5937449835 0.557E-03 0.6549399072 0.0206670026 6678.9540 + 39 -225.5936865857 0.546E-03 0.6544511319 0.0206599907 6691.3151 + 40 -225.5936671889 0.532E-03 0.6544358686 0.0206531783 6835.0089 + 41 -225.5935699865 0.528E-03 0.6538493768 0.0206360918 7113.8430 + 42 -225.5934663750 0.526E-03 0.6531563993 0.0206205729 7217.3550 + 43 -225.5934382509 0.491E-03 0.6531375231 0.0206130665 7486.2029 + 45 -225.5934579731 0.469E-03 0.6534481122 0.0206125299 7507.1610 + 46 -225.5934035720 0.462E-03 0.6530174344 0.0206055851 7564.8843 + 47 -225.5934067112 0.461E-03 0.6532240811 0.0206011870 7774.0349 + 48 -225.5932805477 0.469E-03 0.6523796911 0.0205823644 7811.8890 + 49 -225.5932176641 0.463E-03 0.6521215470 0.0205682777 7866.6110 + 50 -225.5933262796 0.467E-03 0.6528323264 0.0205856592 8012.7649 + 51 -225.5932953151 0.459E-03 0.6525001963 0.0205847613 8089.5680 + 52 -225.5932908521 0.443E-03 0.6525690375 0.0205811117 8113.1497 + 53 -225.5933129413 0.435E-03 0.6528006221 0.0205815753 8171.9441 + 54 -225.5932410404 0.433E-03 0.6522874879 0.0205707324 8261.8203 + 55 -225.5932540025 0.425E-03 0.6526280213 0.0205659136 8340.1840 + 56 -225.5932045998 0.420E-03 0.6525448013 0.0205519481 8436.5100 + 58 -225.5931692170 0.414E-03 0.6522470364 0.0205480518 8532.7689 + 59 -225.5930160643 0.417E-03 0.6514749805 0.0205160939 8534.9191 + 60 -225.5930147954 0.410E-03 0.6514840690 0.0205155314 8709.1260 + 62 -225.5928302997 0.421E-03 0.6503824724 0.0204831284 8736.4060 + 63 -225.5928623519 0.415E-03 0.6506215960 0.0204866892 8847.9699 + 65 -225.5927894398 0.407E-03 0.6501230042 0.0204774831 8855.1829 + 67 -225.5927995015 0.395E-03 0.6500980703 0.0204819558 8949.0491 + 68 -225.5928131395 0.389E-03 0.6502854927 0.0204811730 9118.6590 + 70 -225.5928741549 0.372E-03 0.6508302380 0.0204876252 9175.1452 + 71 -225.5928350826 0.368E-03 0.6507193073 0.0204788735 9301.6748 + 72 -225.5928172279 0.364E-03 0.6507336373 0.0204726147 9316.1311 + 73 -225.5927758325 0.361E-03 0.6504185079 0.0204670250 9367.0621 + 74 -225.5927690711 0.356E-03 0.6503243157 0.0204672945 9512.8013 + 77 -225.5928274911 0.341E-03 0.6506189466 0.0204794011 9708.2439 + 78 -225.5928600536 0.338E-03 0.6508362109 0.0204839824 9754.7476 + 80 -225.5928525583 0.331E-03 0.6508776242 0.0204814160 9912.6080 + 82 -225.5929095468 0.334E-03 0.6511754075 0.0204931649 9990.3169 + 84 -225.5929391639 0.330E-03 0.6512905267 0.0204995274 10134.5939 + 86 -225.5928923245 0.321E-03 0.6508467106 0.0204967735 10157.0205 + 87 -225.5929202463 0.319E-03 0.6510331499 0.0205006718 10284.0884 + 89 -225.5928908864 0.313E-03 0.6508701877 0.0204953499 10371.9468 + 91 -225.5928690310 0.311E-03 0.6507685407 0.0204910646 10484.8100 + 92 -225.5928799794 0.308E-03 0.6507481380 0.0204946440 10680.1301 + 95 -225.5928934333 0.294E-03 0.6508049743 0.0204976403 10747.7030 + 96 -225.5928672077 0.292E-03 0.6506139020 0.0204935223 10841.0950 + 100 -225.5929096342 0.289E-03 0.6509734252 0.0204984501 10981.6380 + 101 -225.5928888470 0.287E-03 0.6508328385 0.0204954275 11045.0500 + 103 -225.5927987991 0.290E-03 0.6502581582 0.0204812551 11209.4370 + 104 -225.5928218022 0.288E-03 0.6504089025 0.0204849369 11227.4419 + 105 -225.5927176951 0.293E-03 0.6497400089 0.0204686003 11304.7870 + 107 -225.5927993836 0.299E-03 0.6501836276 0.0204838514 11363.1120 + 108 -225.5927890744 0.297E-03 0.6501329205 0.0204824421 11365.7718 + 109 -225.5927904141 0.294E-03 0.6500911080 0.0204839012 11431.6260 + 111 -225.5927847234 0.292E-03 0.6500942733 0.0204822296 11607.9760 + 112 -225.5927765990 0.289E-03 0.6499909813 0.0204820853 11624.4782 + 113 -225.5927936209 0.287E-03 0.6500284360 0.0204867779 11710.1710 + 114 -225.5928454855 0.277E-03 0.6503614892 0.0204952997 11734.3660 + 117 -225.5928567034 0.270E-03 0.6505058210 0.0204953832 11778.8980 + 118 -225.5928317187 0.269E-03 0.6504358775 0.0204895488 11800.0779 + 119 -225.5928346248 0.267E-03 0.6504149593 0.0204909271 11845.9714 + 120 -225.5928098628 0.266E-03 0.6502467193 0.0204873484 11953.4064 + 121 -225.5928001039 0.264E-03 0.6501936249 0.0204855563 11993.7629 + 122 -225.5928517108 0.267E-03 0.6505425773 0.0204932752 12049.6579 + 123 -225.5928800509 0.266E-03 0.6506695910 0.0204993198 12215.1440 + 125 -225.5928308296 0.264E-03 0.6504287000 0.0204894394 12365.2290 + 126 -225.5928277363 0.262E-03 0.6504324078 0.0204881925 12436.4041 + 128 -225.5929025779 0.256E-03 0.6509769232 0.0204975555 12480.3919 + 129 -225.5929238411 0.255E-03 0.6511383198 0.0205005095 12525.2430 + 131 -225.5929708792 0.255E-03 0.6513809781 0.0205097977 12599.6951 + 134 -225.5930334482 0.255E-03 0.6518489329 0.0205180051 12716.6961 + 135 -225.5930422579 0.253E-03 0.6519589902 0.0205181689 12776.0310 + 137 -225.5930693743 0.250E-03 0.6521586146 0.0205212754 12946.7629 + 139 -225.5931001983 0.251E-03 0.6522655722 0.0205289553 12966.2410 + 140 -225.5931093274 0.249E-03 0.6523359619 0.0205306199 12976.6592 + 141 -225.5930981470 0.247E-03 0.6522378558 0.0205295379 13072.2163 + 143 -225.5931048137 0.245E-03 0.6522254657 0.0205322808 13242.8569 + 145 -225.5930699427 0.244E-03 0.6519230165 0.0205290424 13309.7949 + 147 -225.5929595980 0.243E-03 0.6512430175 0.0205113137 13359.6988 + 148 -225.5929935245 0.244E-03 0.6514424549 0.0205171587 13403.4780 + 150 -225.5929706564 0.241E-03 0.6513381466 0.0205123415 13438.0220 + 151 -225.5929582883 0.240E-03 0.6512815760 0.0205096155 13548.8420 + 152 -225.5929592900 0.238E-03 0.6513484496 0.0205083937 13617.3239 + 153 -225.5929464067 0.237E-03 0.6512783710 0.0205059553 13719.6409 + 154 -225.5929680150 0.237E-03 0.6513876133 0.0205109540 13783.8315 + 157 -225.5929833289 0.234E-03 0.6515160617 0.0205120019 13916.9423 + 158 -225.5929793012 0.233E-03 0.6514799823 0.0205112547 13996.7320 + 160 -225.5929828580 0.230E-03 0.6515763921 0.0205100564 14042.5099 + 161 -225.5929622449 0.230E-03 0.6514347221 0.0205067136 14092.2159 + 162 -225.5929613467 0.228E-03 0.6514253295 0.0205067072 14113.4519 + 165 -225.5929692924 0.225E-03 0.6515291050 0.0205069563 14192.0389 + 166 -225.5929517199 0.224E-03 0.6513979095 0.0205043510 14229.4363 + 167 -225.5929761466 0.224E-03 0.6514991128 0.0205101675 14247.6276 + 168 -225.5930232975 0.228E-03 0.6517570096 0.0205190350 14320.8071 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 11.885490 GB ] [ VIRT MEM : 17.092987 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 40556.467987 s ] [ CPU TIME: 2841135.659977 s ] <<<<< .. + +* Number of generators 10480503 + +.. >>>>> [ RES MEM : 11.885490 GB ] [ VIRT MEM : 17.092987 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 40556.490846 s ] [ CPU TIME: 2841135.682722 s ] <<<<< .. + +* Number of selectors 10480503 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8536384432867656 + +Summary at N_det = 10485760 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.48025232 +# PT2 -0.11284138 0.00022135 +# rPT2 -0.11057131 0.00021690 +# +# E+PT2 -225.59309370 0.00022135 +# E+rPT2 -225.59082364 0.00021690 +# ============ ============================= + + N_det = 10485760 + N_states = 1 + + * State 1 + < S^2 > = 4.526611489600436E-003 + E = -225.480252320605 + Variance = 0.652206848805533 + PT norm = 0.143283954309224 + PT2 = -0.112841375826117 + rPT2 = -0.110571314500964 + E+PT2 = -225.593093696432 +/- 2.213493440462090E-004 + E+rPT2 = -225.590823635106 +/- 2.168963977613159E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.074825802104 + Vee = 238.873606827555 + Vecp = 0.000000000000000E+000 + T = 225.216616932880 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1122 -225.60413086 + -0.1140 -225.59110913 + -0.1155 -225.58937151 + -0.1178 -225.60533557 + -0.1245 -225.61669943 + -0.1410 -225.61621580 + -0.1710 -225.61387029 + =========== =================== + +* Number of unique beta determinants 1408673 +* Number of unique alpha determinants 1429002 + +.. >>>>> [ RES MEM : 13.618465 GB ] [ VIRT MEM : 21.090057 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 42965.732822 s ] [ CPU TIME: 3008552.820733 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 20971520 +* Number of threads for diagonalization 72 +* Memory(Gb) 32.03411827608943 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.4802523209 0.004527 0.509E-03 + 2 -225.4827143497 0.005493 0.252E-04 + 3 -225.4827576254 0.005539 0.595E-05 + 4 -225.4827643505 0.005569 0.156E-06 + 5 -225.4827648797 0.005576 0.263E-07 + 6 -225.4827649391 0.005577 0.543E-08 + 7 -225.4827649541 0.005578 0.118E-08 + 8 -225.4827649579 0.005579 0.233E-09 + 9 -225.4827649586 0.005579 0.449E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 32.998127 GB ] [ VIRT MEM : 45.154526 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 64482.101402 s ] [ CPU TIME: 4503146.673605 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 13.467018 GB ] [ VIRT MEM : 20.933315 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 64484.015457 s ] [ CPU TIME: 4503154.171736 s ] <<<<< .. + +* Energy of state 1 -225.4827649586250 +* S^2 of state 1 0.5579368379505713E-02 +* Saved determinants 20971520 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 12.906097 GB ] [ VIRT MEM : 18.105614 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 64735.770348 s ] [ CPU TIME: 4506251.003799 s ] <<<<< .. + +* Number of generators 20959975 + +.. >>>>> [ RES MEM : 12.906097 GB ] [ VIRT MEM : 18.105614 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 64735.815728 s ] [ CPU TIME: 4506254.263597 s ] <<<<< .. + +* Number of selectors 20959975 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -225.4827649586250 + +.. >>>>> [ RES MEM : 16.462627 GB ] [ VIRT MEM : 21.664532 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 64751.624676 s ] [ CPU TIME: 4506936.095429 s ] <<<<< .. + +* Number of generators 20959975 + +.. >>>>> [ RES MEM : 16.462627 GB ] [ VIRT MEM : 21.664532 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 64751.668359 s ] [ CPU TIME: 4506936.138946 s ] <<<<< .. + +* Number of selectors 20959975 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 22149582 +* Number of fragmented tasks 26605 +* Number of threads for PT2 72 +* Memory (Gb) 20.17829210404307 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5941067728 0.472E-02 0.6463743271 0.0201605264 1874.0550 + 4 -225.5954335168 0.343E-02 0.6539344103 0.0204158861 2398.0326 + 5 -225.5950545443 0.262E-02 0.6524415038 0.0203369731 2778.3056 + 6 -225.5938827075 0.245E-02 0.6437236030 0.0201747658 3178.0307 + 7 -225.5939504778 0.205E-02 0.6438575046 0.0201942431 3677.7935 + 8 -225.5935608916 0.183E-02 0.6422303381 0.0200906133 3996.5174 + 9 -225.5937702806 0.164E-02 0.6436469521 0.0201229635 4485.9577 + 10 -225.5941756939 0.152E-02 0.6463870071 0.0201874630 4759.0585 + 11 -225.5939019145 0.140E-02 0.6445702281 0.0201491679 4875.7978 + 12 -225.5937455082 0.130E-02 0.6443437654 0.0201023595 5189.8493 + 13 -225.5935168941 0.122E-02 0.6430962387 0.0200602108 5429.3476 + 14 -225.5936057254 0.113E-02 0.6432475299 0.0200855979 5826.5325 + 15 -225.5932665223 0.111E-02 0.6408706446 0.0200375723 6138.8537 + 17 -225.5935864289 0.104E-02 0.6420280002 0.0201170132 6425.6418 + 18 -225.5937855864 0.100E-02 0.6429277023 0.0201596128 6556.2776 + 19 -225.5936904649 0.938E-03 0.6424046165 0.0201447381 7022.1455 + 20 -225.5936428567 0.891E-03 0.6422257039 0.0201352014 7366.1534 + 21 -225.5935862596 0.848E-03 0.6417361054 0.0201279564 7459.4149 + 22 -225.5935399753 0.839E-03 0.6420205231 0.0201049139 7734.1335 + 23 -225.5935069036 0.802E-03 0.6420844197 0.0200934507 7877.9786 + 24 -225.5934739463 0.768E-03 0.6422996211 0.0200762866 8202.5314 + 26 -225.5932979581 0.732E-03 0.6413847213 0.0200451465 8295.5107 + 27 -225.5931693804 0.702E-03 0.6406419703 0.0200237917 8805.3115 + 28 -225.5930067175 0.696E-03 0.6397521607 0.0199921654 9120.6845 + 29 -225.5930938546 0.677E-03 0.6402795253 0.0200060154 9413.0517 + 30 -225.5931622127 0.658E-03 0.6409711319 0.0200100856 9622.8618 + 31 -225.5929899807 0.659E-03 0.6398081778 0.0199832160 9651.3096 + 32 -225.5931808653 0.667E-03 0.6409158975 0.0200154492 10002.6887 + 33 -225.5933178350 0.678E-03 0.6414162508 0.0200483839 10310.3836 + 34 -225.5933760958 0.660E-03 0.6418480095 0.0200570671 10568.9819 + 35 -225.5933551086 0.641E-03 0.6417067980 0.0200537351 10618.2805 + 36 -225.5933307809 0.623E-03 0.6415066251 0.0200519855 10943.1701 + 37 -225.5933665031 0.607E-03 0.6417267285 0.0200558664 11132.1007 + 39 -225.5936211283 0.579E-03 0.6433425356 0.0200986649 11307.9860 + 40 -225.5935785108 0.566E-03 0.6429241405 0.0200949983 11381.9051 + 41 -225.5935844519 0.552E-03 0.6427420177 0.0201005722 11768.4325 + 42 -225.5936092875 0.519E-03 0.6427565760 0.0201092534 12115.3054 + 43 -225.5935095249 0.516E-03 0.6421345898 0.0200920709 12440.6249 + 45 -225.5934211707 0.499E-03 0.6417222605 0.0200729238 12609.2115 + 47 -225.5933442270 0.476E-03 0.6416383440 0.0200508258 12937.8946 + 48 -225.5933549153 0.466E-03 0.6418957802 0.0200467570 13046.0087 + 49 -225.5932760203 0.463E-03 0.6413964856 0.0200331211 13164.9396 + 50 -225.5932038906 0.455E-03 0.6407837383 0.0200276955 13399.7615 + 51 -225.5931988355 0.446E-03 0.6406636591 0.0200290868 13516.7116 + 52 -225.5932724743 0.444E-03 0.6411863624 0.0200395647 13693.9887 + 54 -225.5932616924 0.434E-03 0.6410884847 0.0200383979 13872.3546 + 55 -225.5932496793 0.426E-03 0.6408599761 0.0200412159 13987.5486 + 58 -225.5932446657 0.396E-03 0.6410385187 0.0200349763 14213.3886 + 59 -225.5931720574 0.396E-03 0.6404356263 0.0200267173 14257.8215 + 60 -225.5931291699 0.391E-03 0.6401104177 0.0200205746 14370.0079 + 61 -225.5930798934 0.388E-03 0.6398165211 0.0200117931 14470.0916 + 63 -225.5932206402 0.389E-03 0.6405652570 0.0200383870 14768.2722 + 64 -225.5932177847 0.382E-03 0.6404439452 0.0200404006 14811.3666 + 65 -225.5932577947 0.379E-03 0.6407905669 0.0200454165 14907.4765 + 67 -225.5932753168 0.370E-03 0.6407801084 0.0200508705 15027.6755 + 68 -225.5933202937 0.367E-03 0.6410335893 0.0200582489 15126.7585 + 69 -225.5934738159 0.356E-03 0.6420350998 0.0200823688 15271.0626 + 70 -225.5934777477 0.351E-03 0.6420510058 0.0200832374 15367.3011 + 71 -225.5934729875 0.346E-03 0.6419272229 0.0200852915 15540.1921 + 72 -225.5934489106 0.342E-03 0.6417428982 0.0200821188 15601.1165 + 73 -225.5935277979 0.347E-03 0.6422678815 0.0200941640 15605.4665 + 74 -225.5935063478 0.343E-03 0.6422690383 0.0200868599 15834.7822 + 75 -225.5934697942 0.340E-03 0.6421008010 0.0200792768 15874.1945 + 76 -225.5935246668 0.339E-03 0.6424644865 0.0200874208 15895.9506 + 77 -225.5935318544 0.335E-03 0.6424162437 0.0200915701 16184.3444 + 78 -225.5935506894 0.331E-03 0.6425386355 0.0200944303 16242.1773 + 79 -225.5935743254 0.328E-03 0.6428127215 0.0200954176 16286.5046 + 80 -225.5935396635 0.325E-03 0.6425392019 0.0200907174 16567.9788 + 81 -225.5935100635 0.323E-03 0.6423717866 0.0200856305 16681.9705 + 83 -225.5935467070 0.318E-03 0.6427420616 0.0200878683 16808.4085 + 84 -225.5935432739 0.315E-03 0.6426152398 0.0200903111 16858.7367 + 85 -225.5936424134 0.327E-03 0.6432849007 0.0201051275 16927.9465 + 86 -225.5937166538 0.332E-03 0.6436673806 0.0201194639 17164.3587 + 88 -225.5936387458 0.329E-03 0.6430705967 0.0201099478 17314.8307 + 89 -225.5936741448 0.327E-03 0.6432948666 0.0201155648 17383.0366 + 90 -225.5936365132 0.326E-03 0.6430207870 0.0201103751 17515.1206 + 91 -225.5936429531 0.322E-03 0.6431854795 0.0201084737 17644.1526 + 92 -225.5935681705 0.328E-03 0.6426077716 0.0200988755 17678.9327 + 93 -225.5935878129 0.325E-03 0.6427294872 0.0201017707 17763.1975 + 94 -225.5935450503 0.324E-03 0.6424481762 0.0200949764 17890.7545 + 95 -225.5935369342 0.321E-03 0.6424665076 0.0200919984 18016.1075 + 97 -225.5935992109 0.319E-03 0.6428394619 0.0201022817 18059.7946 + 98 -225.5936668184 0.323E-03 0.6432726468 0.0201129702 18331.9185 + 101 -225.5935951185 0.317E-03 0.6427296281 0.0201031526 18335.2215 + 103 -225.5935663080 0.311E-03 0.6425121035 0.0200993512 18562.1495 + 104 -225.5935331035 0.310E-03 0.6422643653 0.0200946338 18619.1365 + 105 -225.5934677874 0.309E-03 0.6419149371 0.0200819323 18816.1506 + 106 -225.5934627130 0.306E-03 0.6418788317 0.0200810359 18998.5316 + 110 -225.5934618078 0.296E-03 0.6418388891 0.0200813735 19084.1317 + 111 -225.5934829629 0.294E-03 0.6420731865 0.0200825175 19233.6476 + 112 -225.5934993492 0.292E-03 0.6422035564 0.0200848057 19536.9586 + 114 -225.5935480463 0.289E-03 0.6424529543 0.0200944226 19547.8238 + 115 -225.5935316684 0.292E-03 0.6423941267 0.0200906012 19607.8716 + 116 -225.5935341124 0.289E-03 0.6423486606 0.0200931909 19747.4015 + 118 -225.5935109030 0.286E-03 0.6421581239 0.0200906344 19882.3836 + 119 -225.5935596561 0.288E-03 0.6423982659 0.0201005426 19970.8747 + 120 -225.5935737966 0.286E-03 0.6425013992 0.0201020415 20039.9186 + 121 -225.5935372218 0.286E-03 0.6423100771 0.0200950759 20215.5094 + 123 -225.5935252953 0.282E-03 0.6422583789 0.0200927571 20362.7571 + 124 -225.5934952150 0.281E-03 0.6420742931 0.0200878544 20604.6615 + 126 -225.5934911389 0.279E-03 0.6419498386 0.0200896613 20740.0044 + 127 -225.5934338425 0.279E-03 0.6415948289 0.0200800748 20822.2394 + 128 -225.5934431228 0.277E-03 0.6416631709 0.0200813715 21053.5401 + 131 -225.5934516283 0.272E-03 0.6417086144 0.0200825062 21242.9083 + 132 -225.5934684418 0.270E-03 0.6417869937 0.0200855783 21348.3606 + 134 -225.5934612896 0.267E-03 0.6416391633 0.0200868258 21399.5916 + 136 -225.5934014588 0.267E-03 0.6413874564 0.0200729265 21442.5375 + 137 -225.5933738639 0.266E-03 0.6411924884 0.0200689470 21710.2696 + 138 -225.5933359508 0.267E-03 0.6409138683 0.0200640757 21817.8665 + 139 -225.5933545900 0.266E-03 0.6410483937 0.0200664785 21972.4745 + 143 -225.5933389870 0.260E-03 0.6410358939 0.0200620120 22295.6094 + 144 -225.5933640440 0.260E-03 0.6412532622 0.0200646363 22338.2677 + 147 -225.5934005981 0.252E-03 0.6415733350 0.0200684351 22417.1071 + 148 -225.5933875278 0.251E-03 0.6414972010 0.0200661942 22594.6958 + 150 -225.5934125415 0.250E-03 0.6418071015 0.0200665235 22737.6398 + 152 -225.5934517651 0.249E-03 0.6421448173 0.0200706265 22868.9577 + 153 -225.5934489180 0.247E-03 0.6421514233 0.0200695641 22935.7715 + 154 -225.5934280970 0.247E-03 0.6420142971 0.0200664383 23039.9905 + 155 -225.5933828490 0.236E-03 0.6416995715 0.0200599293 23169.5286 + 156 -225.5933563357 0.236E-03 0.6415271075 0.0200553981 23256.2546 + 157 -225.5933566364 0.235E-03 0.6415518579 0.0200549527 23342.4146 + 158 -225.5933666007 0.234E-03 0.6416013256 0.0200567582 23552.4585 + 160 -225.5933240549 0.233E-03 0.6413320856 0.0200496869 23838.2584 + 164 -225.5934100993 0.233E-03 0.6418934982 0.0200632264 23891.3636 + 165 -225.5934112419 0.232E-03 0.6419455849 0.0200624377 23988.7861 + 167 -225.5934317965 0.231E-03 0.6420322792 0.0200668937 24127.9592 + 169 -225.5934495338 0.228E-03 0.6421786702 0.0200692259 24192.6276 + 170 -225.5934400802 0.227E-03 0.6421298626 0.0200674352 24285.9725 + 171 -225.5934598161 0.226E-03 0.6422419560 0.0200709194 24360.2326 + 172 -225.5934464856 0.225E-03 0.6421617301 0.0200685966 24459.7568 + 174 -225.5934579888 0.223E-03 0.6422851819 0.0200693702 24558.3546 + 175 -225.5934704987 0.222E-03 0.6423889891 0.0200707893 24646.1867 + 176 -225.5934869950 0.222E-03 0.6424691774 0.0200741855 24686.4724 + 177 -225.5935135690 0.222E-03 0.6426352466 0.0200784485 24769.4145 + 179 -225.5935492190 0.221E-03 0.6428159160 0.0200855856 24795.9945 + 180 -225.5935419338 0.217E-03 0.6427894000 0.0200831566 24854.7500 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 19.585117 GB ] [ VIRT MEM : 24.778156 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 89688.145369 s ] [ CPU TIME: 6286846.196656 s ] <<<<< .. + +* Number of generators 20959975 + +.. >>>>> [ RES MEM : 19.585117 GB ] [ VIRT MEM : 24.778156 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 89688.189855 s ] [ CPU TIME: 6286846.240348 s ] <<<<< .. + +* Number of selectors 20959975 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8563552762351927 + +Summary at N_det = 20971520 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.48276496 +# PT2 -0.11077698 0.00021686 +# rPT2 -0.10859602 0.00021259 +# +# E+PT2 -225.59354193 0.00021686 +# E+rPT2 -225.59136098 0.00021259 +# ============ ============================= + + N_det = 20971520 + N_states = 1 + + * State 1 + < S^2 > = 5.579368379505713E-003 + E = -225.482764958625 + Variance = 0.642789399991603 + PT norm = 0.141715054219292 + PT2 = -0.110776975212957 + rPT2 = -0.108596024252583 + E+PT2 = -225.593541933838 +/- 2.168576682728453E-004 + E+rPT2 = -225.591360982878 +/- 2.125882256474716E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.075415859961 + Vee = 238.867089073842 + Vecp = 0.000000000000000E+000 + T = 225.221212106430 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1106 -225.62090289 + -0.1122 -225.61372942 + -0.1140 -225.60277474 + -0.1155 -225.59813103 + -0.1178 -225.60637159 + -0.1245 -225.61508819 + -0.1410 -225.61567763 + =========== =================== + +* Number of unique beta determinants 2181055 +* Number of unique alpha determinants 2188324 + +.. >>>>> [ RES MEM : 24.103516 GB ] [ VIRT MEM : 32.671059 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 99147.457599 s ] [ CPU TIME: 6937225.224731 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 41943040 +* Number of threads for diagonalization 72 +* Memory(Gb) 62.08977331593633 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.4827649593 0.005579 0.898E-03 + 2 -225.4871059888 0.007125 0.682E-04 + 3 -225.4871985998 0.007204 0.118E-04 + 4 -225.4872146865 0.007261 0.364E-06 + 5 -225.4872159174 0.007269 0.814E-07 + 6 -225.4872160848 0.007268 0.136E-07 + 7 -225.4872161271 0.007267 0.290E-08 + 8 -225.4872161363 0.007268 0.597E-09 + 9 -225.4872161383 0.007267 0.138E-09 + 10 -225.4872161387 0.007268 0.228E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 64.682827 GB ] [ VIRT MEM : 80.719391 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 194644.451344 s ] [ CPU TIME: ************** s ] <<<<< .. + + +.. >>>>> [ RES MEM : 23.745552 GB ] [ VIRT MEM : 32.279430 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 194648.401799 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Energy of state 1 -225.4872161386884 +* S^2 of state 1 0.7267544011466382E-02 +* Saved determinants 41943040 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 22.553288 GB ] [ VIRT MEM : 27.771984 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 195152.343620 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 41920989 + +.. >>>>> [ RES MEM : 22.553288 GB ] [ VIRT MEM : 27.771984 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 195152.438333 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 41920989 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -225.4872161386884 + +.. >>>>> [ RES MEM : 30.054119 GB ] [ VIRT MEM : 35.276718 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 195189.775420 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 41920989 + +.. >>>>> [ RES MEM : 30.054119 GB ] [ VIRT MEM : 35.276718 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 195189.868106 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 41920989 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 43113684 +* Number of fragmented tasks 26938 +* Number of threads for PT2 72 +* Memory (Gb) 22.30847632151097 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.5926092902 0.115E-02 0.6208578529 0.0188348384 3504.4637 + 4 -225.5935244969 0.112E-02 0.6239249526 0.0190538155 4320.1982 + 5 -225.5937749899 0.886E-03 0.6259651805 0.0191006814 5178.1823 + 6 -225.5945585180 0.109E-02 0.6304444479 0.0192405893 6032.2378 + 7 -225.5942631664 0.964E-03 0.6275421793 0.0192193546 6809.6395 + 8 -225.5937388864 0.100E-02 0.6256349774 0.0190981637 7652.0005 + 9 -225.5934363544 0.925E-03 0.6226959636 0.0190804671 8487.2164 + 10 -225.5929263914 0.977E-03 0.6181812295 0.0190394198 8714.6617 + 11 -225.5934526826 0.103E-02 0.6213196448 0.0191270842 9040.0280 + 12 -225.5936122361 0.974E-03 0.6216263308 0.0191722133 9672.9074 + 13 -225.5935125586 0.900E-03 0.6219594010 0.0191310174 10234.9184 + 14 -225.5938663862 0.906E-03 0.6236255700 0.0192061403 10817.1756 + 15 -225.5939194231 0.828E-03 0.6236514421 0.0192219485 11347.0104 + 16 -225.5936232619 0.830E-03 0.6211992330 0.0191907758 11614.9065 + 17 -225.5935175600 0.786E-03 0.6203318892 0.0191775800 11639.9408 + 18 -225.5936696730 0.757E-03 0.6216073957 0.0191958060 12156.3677 + 19 -225.5936264214 0.723E-03 0.6214131970 0.0191827560 12871.3734 + 20 -225.5937316049 0.694E-03 0.6223675693 0.0191930136 13554.7577 + 21 -225.5938262367 0.667E-03 0.6230003358 0.0192083809 13865.3565 + 22 -225.5936597040 0.647E-03 0.6217311153 0.0191887965 14099.3178 + 23 -225.5934761446 0.645E-03 0.6203375788 0.0191667289 14425.2016 + 24 -225.5933934874 0.623E-03 0.6199706704 0.0191454346 14899.3901 + 25 -225.5933674613 0.598E-03 0.6199805055 0.0191394072 15292.6745 + 26 -225.5933595828 0.574E-03 0.6206224565 0.0191201824 15428.5855 + 27 -225.5931663123 0.599E-03 0.6190868407 0.0190997214 16085.2574 + 28 -225.5932986146 0.592E-03 0.6202592136 0.0191125466 16758.1897 + 29 -225.5932795586 0.572E-03 0.6198417658 0.0191157073 17366.7124 + 30 -225.5936851574 0.687E-03 0.6218919632 0.0191940744 17928.8921 + 31 -225.5935870520 0.672E-03 0.6217092893 0.0191656576 18181.8075 + 32 -225.5935915380 0.648E-03 0.6213772881 0.0191768189 18761.1516 + 33 -225.5935134940 0.632E-03 0.6212939454 0.0191538466 19106.1083 + 34 -225.5934428278 0.618E-03 0.6208305679 0.0191415299 19683.6394 + 35 -225.5935737614 0.614E-03 0.6215117725 0.0191649045 20057.5065 + 36 -225.5936309557 0.599E-03 0.6219419780 0.0191710830 20341.6657 + 37 -225.5936950136 0.577E-03 0.6224661821 0.0191783627 20605.2995 + 38 -225.5936410525 0.565E-03 0.6222107815 0.0191688177 20777.7335 + 39 -225.5936652381 0.550E-03 0.6223518625 0.0191729962 21098.7405 + 40 -225.5937842281 0.549E-03 0.6230031585 0.0191949405 21425.2684 + 41 -225.5937195223 0.540E-03 0.6225059602 0.0191875418 21998.4106 + 42 -225.5936898628 0.528E-03 0.6223658712 0.0191805967 22546.4401 + 43 -225.5938597925 0.540E-03 0.6233400234 0.0192094871 23166.7315 + 44 -225.5938463857 0.528E-03 0.6231586404 0.0192089632 23253.7765 + 45 -225.5938039558 0.517E-03 0.6228098533 0.0192048637 23549.5927 + 46 -225.5936558797 0.527E-03 0.6219529836 0.0191768487 23759.6845 + 47 -225.5937501304 0.525E-03 0.6226086041 0.0191908091 24183.1088 + 48 -225.5939399540 0.548E-03 0.6234837965 0.0192305242 24471.8595 + 49 -225.5938482956 0.545E-03 0.6228120288 0.0192189455 24737.2395 + 50 -225.5939338951 0.541E-03 0.6234008802 0.0192314840 25100.3566 + 51 -225.5939601146 0.530E-03 0.6235196040 0.0192378539 25387.8285 + 52 -225.5939124039 0.525E-03 0.6233154803 0.0192268359 25639.8919 + 53 -225.5938636516 0.518E-03 0.6228982883 0.0192228477 25794.6015 + 54 -225.5938124617 0.510E-03 0.6225128216 0.0192152305 26187.9525 + 55 -225.5937556898 0.504E-03 0.6221766651 0.0192058627 26403.3365 + 56 -225.5937877588 0.496E-03 0.6225605103 0.0192065977 26553.2456 + 57 -225.5937921714 0.487E-03 0.6225479649 0.0192077861 26591.7586 + 58 -225.5938344891 0.481E-03 0.6227509615 0.0192152369 26901.4355 + 59 -225.5937875795 0.475E-03 0.6224003022 0.0192090901 27060.3676 + 60 -225.5938506790 0.471E-03 0.6227559966 0.0192201383 27120.4457 + 61 -225.5939237905 0.454E-03 0.6232405412 0.0192309931 27443.5374 + 62 -225.5939189246 0.446E-03 0.6231435616 0.0192315883 27690.4416 + 63 -225.5939035224 0.439E-03 0.6230774831 0.0192284351 28077.2799 + 64 -225.5939866274 0.440E-03 0.6233777468 0.0192485550 28220.4625 + 65 -225.5939793713 0.434E-03 0.6235599762 0.0192410543 28294.3368 + 67 -225.5940575527 0.425E-03 0.6239132274 0.0192572667 28741.0306 + 69 -225.5940359869 0.423E-03 0.6237470104 0.0192551848 28993.0324 + 70 -225.5940641141 0.418E-03 0.6240240239 0.0192569901 29212.0396 + 71 -225.5939712384 0.422E-03 0.6234497311 0.0192419145 29464.4194 + 72 -225.5940018138 0.417E-03 0.6236632486 0.0192463435 29618.1703 + 73 -225.5939760329 0.412E-03 0.6235069993 0.0192418639 29627.9096 + 74 -225.5939190682 0.411E-03 0.6231075099 0.0192333848 30088.3272 + 75 -225.5939002921 0.405E-03 0.6231093054 0.0192269739 30461.8176 + 77 -225.5938400067 0.397E-03 0.6225955681 0.0192210292 30895.4285 + 78 -225.5938055595 0.393E-03 0.6223017740 0.0192169789 31087.2809 + 79 -225.5937461898 0.393E-03 0.6219547550 0.0192069618 31252.1916 + 80 -225.5937363210 0.388E-03 0.6219199942 0.0192045284 31574.7555 + 81 -225.5937217697 0.383E-03 0.6218654815 0.0192013738 32007.6778 + 83 -225.5936599486 0.371E-03 0.6216873414 0.0191862909 32133.6805 + 84 -225.5936371606 0.367E-03 0.6214900410 0.0191837786 32305.8296 + 85 -225.5936236631 0.363E-03 0.6214136280 0.0191814250 32385.4999 + 86 -225.5935618247 0.364E-03 0.6209287801 0.0191736859 32612.2938 + 87 -225.5935129957 0.363E-03 0.6204425708 0.0191700975 32939.4950 + 88 -225.5935285445 0.360E-03 0.6206183727 0.0191709588 33067.8209 + 89 -225.5934966111 0.357E-03 0.6204170149 0.0191655943 33158.6215 + 90 -225.5934510250 0.356E-03 0.6200810149 0.0191592658 33519.4090 + 91 -225.5934414086 0.352E-03 0.6200304605 0.0191579255 33652.2225 + 92 -225.5934645766 0.349E-03 0.6202236408 0.0191599827 33827.0725 + 93 -225.5934496533 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0.268E-03 0.6193002586 0.0191608831 40055.1210 + 131 -225.5933415567 0.270E-03 0.6189684771 0.0191561443 40113.1004 + 132 -225.5933642903 0.269E-03 0.6190596771 0.0191610428 40277.6769 + 133 -225.5933409858 0.268E-03 0.6188740749 0.0191582377 40367.6941 + 134 -225.5933294842 0.266E-03 0.6188880961 0.0191548487 40420.6114 + 135 -225.5933494975 0.265E-03 0.6190064967 0.0191581193 40585.0047 + 136 -225.5933812568 0.265E-03 0.6192358367 0.0191629410 40687.5826 + 137 -225.5933489871 0.262E-03 0.6189809264 0.0191591984 41004.0048 + 138 -225.5933742000 0.262E-03 0.6191353120 0.0191631763 41258.2265 + 139 -225.5933667306 0.260E-03 0.6190759911 0.0191618653 41538.7299 + 140 -225.5933750757 0.258E-03 0.6191284805 0.0191629491 41541.0795 + 142 -225.5934098656 0.259E-03 0.6193824815 0.0191680770 41671.0117 + 143 -225.5934051197 0.257E-03 0.6193576934 0.0191672474 41930.3225 + 144 -225.5934016210 0.255E-03 0.6193267480 0.0191671377 42163.3608 + 145 -225.5933978317 0.253E-03 0.6192663069 0.0191674808 42410.4595 + 147 -225.5934265781 0.252E-03 0.6194319132 0.0191728416 42504.0306 + 148 -225.5933795329 0.255E-03 0.6190860741 0.0191664442 42800.0847 + 149 -225.5933840539 0.249E-03 0.6190805428 0.0191675782 42836.7185 + 150 -225.5933574690 0.248E-03 0.6189012041 0.0191633224 43050.3429 + 152 -225.5933448944 0.245E-03 0.6188351435 0.0191612277 43285.7402 + 153 -225.5933623996 0.244E-03 0.6189066600 0.0191646262 43521.9865 + 154 -225.5933667611 0.243E-03 0.6189223864 0.0191659901 43681.9229 + 155 -225.5933789763 0.242E-03 0.6189795032 0.0191686363 43959.7387 + 156 -225.5934013553 0.241E-03 0.6191592733 0.0191711205 44059.5014 + 157 -225.5934173470 0.240E-03 0.6192740122 0.0191733860 44238.1200 + 158 -225.5934094050 0.239E-03 0.6192159558 0.0191721198 44315.1666 + 159 -225.5934393893 0.235E-03 0.6193427449 0.0191790318 44518.4578 + 160 -225.5934275875 0.234E-03 0.6192936720 0.0191765106 44721.6806 + 161 -225.5934431172 0.233E-03 0.6193706688 0.0191795825 44970.3526 + 163 -225.5934185876 0.231E-03 0.6192160639 0.0191752280 45108.7185 + 164 -225.5934318211 0.230E-03 0.6193182259 0.0191767951 45209.5285 + 165 -225.5934237056 0.229E-03 0.6192675321 0.0191757451 45326.7795 + 166 -225.5934383089 0.228E-03 0.6193856752 0.0191776516 45430.7097 + 167 -225.5934362565 0.227E-03 0.6193709888 0.0191777037 45625.2654 + 168 -225.5934403140 0.225E-03 0.6194281355 0.0191773229 45627.3665 + 169 -225.5934406782 0.224E-03 0.6194747174 0.0191762976 45873.4415 + 170 -225.5934483704 0.223E-03 0.6195530244 0.0191767856 46033.9195 + 171 -225.5934149852 0.222E-03 0.6193903386 0.0191709241 46220.3486 + 172 -225.5934230702 0.220E-03 0.6194703524 0.0191715753 46397.3035 + 173 -225.5934111544 0.219E-03 0.6193837298 0.0191697663 46427.9451 + 174 -225.5934212572 0.218E-03 0.6194216064 0.0191720188 46566.6338 + 175 -225.5934245652 0.217E-03 0.6194943838 0.0191713135 46727.0625 + 176 -225.5934298815 0.216E-03 0.6195318560 0.0191719374 46844.2296 + 177 -225.5934474771 0.216E-03 0.6196941889 0.0191735419 46999.8082 + 179 -225.5934341019 0.213E-03 0.6196395079 0.0191708833 47064.8825 + 180 -225.5934358836 0.207E-03 0.6197290838 0.0191687933 47118.4847 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 37.305134 GB ] [ VIRT MEM : 51.388042 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 242580.387669 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 41920989 + +.. >>>>> [ RES MEM : 37.305134 GB ] [ VIRT MEM : 51.388042 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 242580.480167 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 41920989 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8621551308505244 + +Summary at N_det = 41943040 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.48721614 +# PT2 -0.10621974 0.00020692 +# rPT2 -0.10422194 0.00020302 +# +# E+PT2 -225.59343588 0.00020692 +# E+rPT2 -225.59143807 0.00020302 +# ============ ============================= + + N_det = 41943040 + N_states = 1 + + * State 1 + < S^2 > = 7.267544011466382E-003 + E = -225.487216138688 + Variance = 0.619729083793786 + PT norm = 0.138451411329078 + PT2 = -0.106219744889975 + rPT2 = -0.104221936138906 + E+PT2 = -225.593435883578 +/- 2.069153251632630E-004 + E+rPT2 = -225.591438074827 +/- 2.030236075944647E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.076852577173 + Vee = 238.855711513360 + Vecp = 0.000000000000000E+000 + T = 225.229575204061 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1086 -225.59327495 + -0.1106 -225.60022608 + -0.1122 -225.60229971 + -0.1140 -225.60022677 + -0.1155 -225.59844466 + -0.1178 -225.60303657 + -0.1245 -225.61058798 + =========== =================== + +* Number of unique beta determinants 3205609 +* Number of unique alpha determinants 3187483 + +.. >>>>> [ RES MEM : 45.044914 GB ] [ VIRT MEM : 54.890980 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 281892.531495 s ] [ CPU TIME: ************** s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 83886080 +* Number of threads for diagonalization 72 +* Memory(Gb) 120.7199910953641 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.4872161388 0.007268 0.178E-02 + 2 -225.4956731083 0.009608 0.237E-03 + 3 -225.4959329226 0.009781 0.279E-04 + 4 -225.4959807234 0.009917 0.134E-05 diff --git a/imidazole/cc-pvdz/slurm-487471.out b/imidazole/cc-pvdz/slurm-487471.out index 4bdda35..ada6738 100644 --- a/imidazole/cc-pvdz/slurm-487471.out +++ b/imidazole/cc-pvdz/slurm-487471.out @@ -522,3 +522,29146 @@ 13.07 % in 1116 seconds 13.18 % in 1126 seconds 13.30 % in 1136 seconds +13.42 % in 1146 seconds +13.53 % in 1156 seconds +13.64 % in 1167 seconds +13.73 % in 1177 seconds +13.84 % in 1187 seconds +13.93 % in 1197 seconds +14.07 % in 1208 seconds +14.14 % in 1219 seconds +14.18 % in 1229 seconds +14.21 % in 1241 seconds + 2.94 % in 3 seconds +11.76 % in 16 seconds +26.47 % in 26 seconds +47.06 % in 36 seconds +73.53 % in 46 seconds + 2.94 % in 3 seconds +11.76 % in 16 seconds +26.47 % in 26 seconds +47.06 % in 36 seconds +73.53 % in 46 seconds + 2.94 % in 3 seconds +11.76 % in 16 seconds +26.47 % in 26 seconds +50.00 % in 36 seconds +73.53 % in 46 seconds + 2.94 % in 3 seconds +11.76 % in 16 seconds +26.47 % in 26 seconds +47.06 % in 36 seconds +73.53 % in 46 seconds + 2.94 % in 2 seconds +11.76 % in 16 seconds +29.41 % in 27 seconds +52.94 % in 37 seconds +76.47 % in 47 seconds + 2.94 % in 2 seconds +11.76 % in 16 seconds +26.47 % in 26 seconds +50.00 % in 37 seconds +76.47 % in 47 seconds + 2.94 % in 2 seconds +11.76 % in 16 seconds +26.47 % in 26 seconds +50.00 % in 37 seconds +76.47 % in 47 seconds + 2.94 % in 3 seconds +11.76 % in 16 seconds +26.47 % in 26 seconds +47.06 % in 36 seconds +70.59 % in 46 seconds +94.12 % in 56 seconds + 2.94 % in 2 seconds + 8.82 % in 12 seconds +20.59 % in 23 seconds +41.18 % in 33 seconds +64.71 % in 43 seconds +91.18 % in 54 seconds + 2.94 % in 2 seconds +11.76 % in 15 seconds +26.47 % in 25 seconds +47.06 % in 35 seconds +73.53 % in 45 seconds + 0.00 % in 10 seconds + 0.01 % in 20 seconds + 0.04 % in 30 seconds + 0.11 % in 40 seconds + 0.19 % in 50 seconds + 0.21 % in 60 seconds + 0.26 % in 70 seconds + 0.35 % in 81 seconds + 0.38 % in 93 seconds + 0.44 % in 103 seconds + 0.54 % in 113 seconds + 0.60 % in 125 seconds + 0.63 % in 135 seconds + 0.78 % in 145 seconds + 0.87 % in 156 seconds + 0.89 % in 167 seconds + 0.98 % in 177 seconds + 1.10 % in 187 seconds + 1.13 % in 197 seconds + 1.19 % in 207 seconds + 1.29 % in 217 seconds + 1.35 % in 227 seconds + 1.41 % in 239 seconds + 1.48 % in 249 seconds + 1.55 % in 259 seconds + 1.62 % in 271 seconds + 1.68 % in 281 seconds + 1.79 % in 291 seconds + 1.83 % in 301 seconds + 1.86 % in 311 seconds + 1.95 % in 321 seconds + 2.02 % in 331 seconds + 2.08 % in 341 seconds + 2.14 % in 351 seconds + 2.24 % in 361 seconds + 2.31 % in 371 seconds + 2.38 % in 381 seconds + 2.42 % in 392 seconds + 2.50 % in 402 seconds + 2.56 % in 412 seconds + 2.62 % in 422 seconds + 2.69 % in 432 seconds + 2.75 % in 442 seconds + 2.84 % in 452 seconds + 2.92 % in 463 seconds + 2.99 % in 473 seconds + 3.05 % in 483 seconds + 3.11 % in 493 seconds + 3.19 % in 503 seconds + 3.25 % in 513 seconds + 3.31 % in 524 seconds + 3.39 % in 534 seconds + 3.47 % in 544 seconds + 3.51 % in 554 seconds + 3.57 % in 564 seconds + 3.64 % in 574 seconds + 3.69 % in 584 seconds + 3.75 % in 595 seconds + 3.82 % in 605 seconds + 3.90 % in 615 seconds + 3.98 % in 626 seconds + 4.04 % in 636 seconds + 4.12 % in 646 seconds + 4.17 % in 656 seconds + 4.25 % in 666 seconds + 4.33 % in 677 seconds + 4.41 % in 687 seconds + 4.45 % in 697 seconds + 4.52 % in 707 seconds + 4.61 % in 717 seconds + 4.66 % in 728 seconds + 4.70 % in 738 seconds + 4.77 % in 748 seconds + 4.87 % in 758 seconds + 4.93 % in 769 seconds + 4.97 % in 779 seconds + 5.08 % in 789 seconds + 5.13 % in 799 seconds + 5.18 % in 809 seconds + 5.22 % in 819 seconds + 5.30 % in 830 seconds + 5.36 % in 840 seconds + 5.41 % in 850 seconds + 5.48 % in 860 seconds + 5.54 % in 870 seconds + 5.63 % in 880 seconds + 5.67 % in 890 seconds + 5.74 % in 900 seconds + 5.81 % in 910 seconds + 5.88 % in 920 seconds + 5.92 % in 930 seconds + 5.97 % in 940 seconds + 6.06 % in 950 seconds + 6.10 % in 960 seconds + 6.15 % in 970 seconds + 6.22 % in 980 seconds + 6.29 % in 990 seconds + 6.34 % in 1000 seconds + 6.40 % in 1010 seconds + 6.47 % in 1020 seconds + 6.55 % in 1031 seconds + 6.61 % in 1041 seconds + 6.67 % in 1051 seconds + 6.74 % in 1061 seconds + 6.79 % in 1071 seconds + 6.86 % in 1081 seconds + 6.87 % in 1091 seconds + 6.94 % in 1101 seconds + 7.01 % in 1111 seconds + 7.05 % in 1121 seconds + 7.10 % in 1131 seconds + 7.17 % in 1141 seconds + 7.23 % in 1151 seconds + 7.27 % in 1161 seconds + 7.34 % in 1171 seconds + 7.39 % in 1181 seconds + 7.45 % in 1191 seconds + 7.51 % in 1201 seconds + 7.58 % in 1211 seconds + 7.63 % in 1221 seconds + 7.69 % in 1231 seconds + 7.75 % in 1241 seconds + 7.80 % in 1251 seconds + 7.86 % in 1261 seconds + 7.93 % in 1271 seconds + 7.96 % in 1282 seconds + 8.03 % in 1292 seconds + 8.10 % in 1302 seconds + 8.15 % in 1312 seconds + 8.19 % in 1323 seconds + 8.29 % in 1333 seconds + 8.32 % in 1343 seconds + 8.37 % in 1353 seconds + 8.45 % in 1363 seconds + 8.50 % in 1373 seconds + 8.56 % in 1383 seconds + 8.63 % in 1394 seconds + 8.69 % in 1404 seconds + 8.74 % in 1414 seconds + 8.78 % in 1424 seconds + 8.84 % in 1435 seconds + 8.90 % in 1445 seconds + 8.97 % in 1457 seconds + 9.05 % in 1469 seconds + 9.09 % in 1479 seconds + 9.16 % in 1489 seconds + 9.22 % in 1500 seconds + 9.31 % in 1511 seconds + 9.35 % in 1521 seconds + 9.40 % in 1532 seconds + 9.44 % in 1542 seconds + 9.50 % in 1552 seconds + 9.57 % in 1562 seconds + 9.61 % in 1573 seconds + 9.67 % in 1583 seconds + 9.73 % in 1593 seconds + 9.79 % in 1603 seconds + 9.82 % in 1613 seconds + 9.88 % in 1623 seconds + 9.97 % in 1634 seconds +10.05 % in 1644 seconds +10.09 % in 1654 seconds +10.18 % in 1664 seconds +10.21 % in 1675 seconds +10.26 % in 1685 seconds +10.32 % in 1695 seconds +10.39 % in 1705 seconds +10.42 % in 1715 seconds +10.45 % in 1725 seconds +10.52 % in 1735 seconds +10.59 % in 1745 seconds +10.64 % in 1755 seconds +10.71 % in 1766 seconds +10.76 % in 1776 seconds +10.83 % in 1786 seconds +10.88 % in 1796 seconds +10.94 % in 1806 seconds +10.97 % in 1816 seconds +11.02 % in 1826 seconds +11.08 % in 1836 seconds +11.13 % in 1846 seconds +11.19 % in 1856 seconds +11.30 % in 1866 seconds +11.35 % in 1876 seconds +11.42 % in 1886 seconds +11.48 % in 1896 seconds +11.53 % in 1906 seconds +11.58 % in 1916 seconds +11.64 % in 1926 seconds +11.69 % in 1936 seconds +11.72 % in 1946 seconds +11.76 % in 1956 seconds +11.79 % in 1966 seconds +11.84 % in 1976 seconds +11.89 % in 1986 seconds +11.96 % in 1996 seconds +12.03 % in 2006 seconds +12.08 % in 2016 seconds +12.14 % in 2026 seconds +12.20 % in 2036 seconds +12.25 % in 2046 seconds +12.31 % in 2056 seconds +12.34 % in 2066 seconds +12.40 % in 2076 seconds +12.45 % in 2086 seconds +12.49 % in 2096 seconds +12.56 % in 2106 seconds +12.60 % in 2116 seconds +12.64 % in 2126 seconds +12.68 % in 2136 seconds +12.75 % in 2146 seconds +12.82 % in 2156 seconds +12.87 % in 2166 seconds +12.92 % in 2177 seconds +12.98 % in 2187 seconds +13.04 % in 2197 seconds +13.12 % in 2207 seconds +13.16 % in 2217 seconds +13.21 % in 2227 seconds +13.26 % in 2239 seconds +13.32 % in 2249 seconds +13.34 % in 2259 seconds +13.39 % in 2269 seconds +13.45 % in 2279 seconds +13.51 % in 2289 seconds +13.55 % in 2299 seconds +13.61 % in 2309 seconds +13.66 % in 2320 seconds +13.70 % in 2330 seconds +13.76 % in 2340 seconds +13.83 % in 2350 seconds +13.88 % in 2360 seconds +13.93 % in 2370 seconds +13.99 % in 2380 seconds +14.04 % in 2390 seconds +14.11 % in 2400 seconds +14.15 % in 2411 seconds +14.21 % in 2421 seconds +14.25 % in 2431 seconds +14.29 % in 2442 seconds +14.32 % in 2452 seconds +14.38 % in 2462 seconds +14.44 % in 2473 seconds +14.49 % in 2483 seconds +14.56 % in 2495 seconds +14.60 % in 2505 seconds +14.66 % in 2515 seconds +14.72 % in 2525 seconds +14.75 % in 2535 seconds +14.82 % in 2546 seconds +14.86 % in 2556 seconds +14.92 % in 2566 seconds +14.96 % in 2576 seconds +15.01 % in 2586 seconds +15.07 % in 2597 seconds +15.09 % in 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20735 seconds + 9.05 % in 20745 seconds + 9.06 % in 20755 seconds + 9.06 % in 20765 seconds + 9.06 % in 20775 seconds + 9.06 % in 20785 seconds + 9.07 % in 20796 seconds + 9.07 % in 20806 seconds + 9.07 % in 20816 seconds + 9.08 % in 20826 seconds + 9.08 % in 20836 seconds + 9.09 % in 20846 seconds + 9.10 % in 20856 seconds + 9.10 % in 20868 seconds + 9.11 % in 20878 seconds + 9.11 % in 20888 seconds + 9.11 % in 20898 seconds + 9.12 % in 20909 seconds + 9.12 % in 20919 seconds + 9.12 % in 20929 seconds + 9.13 % in 20939 seconds + 9.13 % in 20949 seconds + 9.14 % in 20959 seconds + 9.15 % in 20969 seconds + 9.15 % in 20979 seconds + 9.15 % in 20989 seconds + 9.16 % in 20999 seconds + 9.16 % in 21010 seconds + 9.17 % in 21021 seconds + 9.17 % in 21032 seconds + 9.17 % in 21042 seconds + 9.18 % in 21052 seconds + 9.18 % in 21062 seconds + 9.18 % in 21072 seconds + 9.19 % in 21082 seconds + 9.19 % in 21093 seconds + 9.20 % in 21104 seconds + 9.20 % in 21114 seconds + 9.20 % in 21125 seconds + 9.21 % in 21137 seconds + 9.21 % in 21147 seconds + 9.21 % in 21157 seconds + 9.22 % in 21167 seconds + 9.22 % in 21178 seconds + 9.23 % in 21188 seconds + 9.23 % in 21198 seconds + 9.24 % in 21208 seconds + 9.24 % in 21219 seconds + 9.25 % in 21229 seconds + 9.26 % in 21239 seconds + 9.26 % in 21253 seconds + 9.26 % in 21263 seconds + 9.26 % in 21273 seconds + 9.27 % in 21283 seconds + 9.27 % in 21293 seconds + 9.27 % in 21303 seconds + 9.27 % in 21313 seconds + 9.28 % in 21323 seconds + 9.28 % in 21333 seconds + 9.29 % in 21343 seconds + 9.29 % in 21353 seconds + 9.30 % in 21363 seconds + 9.30 % in 21373 seconds + 9.31 % in 21384 seconds + 9.31 % in 21395 seconds + 9.31 % in 21405 seconds + 9.32 % in 21415 seconds + 9.32 % in 21458 seconds + 9.33 % in 21468 seconds + 9.34 % in 21479 seconds + 9.34 % in 21491 seconds + 9.34 % in 21508 seconds + + unset COMMAND ++ qp run save_natorb ++ case $1 in ++ which qp_run ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' imidazole +++ qp_run save_natorb imidazole ++ unset COMMAND ++ qp set determinants n_det_max 1e8 ++ case $1 in ++ ezfio set determinants n_det_max 1e8 ++ case $1 in ++ shift ++ _ezfio_set determinants n_det_max 1e8 ++ _require_ezfio_file ++ [[ -z imidazole ]] ++ [[ ! -d imidazole ]] ++ _require_first_argument determinants n_det_max 1e8 ++ [[ -z determinants ]] ++ return 0 ++ _require_second_argument determinants n_det_max 1e8 ++ [[ -z n_det_max ]] ++ [[ -z 1e8 ]] ++ echo 1e8 ++ _ezfio_py set determinants n_det_max ++ python2 /tmpdir/veril/qp2/external/ezfio/Python/ezfio.py set determinants n_det_max ++ return 0 ++ qp run fci ++ case $1 in ++ which qp_run ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' imidazole +++ qp_run fci imidazole + 0.02 % in 1 seconds + 50.00 % in 1 seconds + 16.67 % in 0 seconds + 9.09 % in 1 seconds + 4.76 % in 0 seconds + 2.44 % in 1 seconds + 1.23 % in 0 seconds + 0.62 % in 0 seconds + 0.31 % in 0 seconds + 0.16 % in 0 seconds + 0.08 % in 0 seconds + 0.04 % in 1 seconds + 0.02 % in 1 seconds + 0.01 % in 0 seconds + 0.00 % in 1 seconds + 7.33 % in 11 seconds + 0.00 % in 1 seconds + 3.25 % in 11 seconds + 7.06 % in 21 seconds +10.98 % in 31 seconds + 0.00 % in 1 seconds + 1.40 % in 11 seconds + 3.12 % in 21 seconds + 4.94 % in 31 seconds + 6.61 % in 41 seconds + 8.38 % in 51 seconds +10.13 % in 61 seconds +11.82 % in 71 seconds + 16.67 % in 0 seconds + 16.67 % in 0 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 16.67 % in 0 seconds + 16.67 % in 0 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 0.00 % in 1 seconds + 0.48 % in 11 seconds + 1.26 % in 21 seconds + 2.06 % in 31 seconds + 2.85 % in 41 seconds + 3.58 % in 51 seconds + 4.38 % in 61 seconds + 5.11 % in 71 seconds + 5.86 % in 81 seconds + 6.63 % in 91 seconds + 7.40 % in 101 seconds + 8.11 % in 111 seconds + 8.83 % in 121 seconds + 9.58 % in 131 seconds +10.21 % in 141 seconds +10.96 % in 151 seconds + 10.00 % in 1 seconds + 10.00 % in 1 seconds + 10.00 % in 1 seconds + 10.00 % in 1 seconds + 10.00 % in 1 seconds + 10.00 % in 1 seconds + 10.00 % in 1 seconds + 10.00 % in 1 seconds + 10.00 % in 1 seconds + 10.00 % in 1 seconds + 10.00 % in 1 seconds + 0.00 % in 2 seconds + 0.16 % in 12 seconds + 0.46 % in 22 seconds + 0.81 % in 32 seconds + 1.19 % in 42 seconds + 1.63 % in 52 seconds + 2.05 % in 62 seconds + 2.37 % in 72 seconds + 2.75 % in 82 seconds + 3.06 % in 92 seconds + 3.47 % in 102 seconds + 3.84 % in 112 seconds + 4.06 % in 122 seconds + 4.44 % in 132 seconds + 4.84 % in 142 seconds + 5.16 % in 152 seconds + 5.50 % in 162 seconds + 5.78 % in 172 seconds + 6.13 % in 182 seconds + 6.52 % in 192 seconds + 6.81 % in 202 seconds + 7.12 % in 212 seconds + 7.34 % in 222 seconds + 7.63 % in 232 seconds + 7.90 % in 242 seconds + 8.21 % in 252 seconds + 8.53 % in 262 seconds + 8.81 % in 272 seconds + 9.11 % in 282 seconds + 9.38 % in 292 seconds + 9.64 % in 302 seconds + 9.92 % in 312 seconds +10.17 % in 322 seconds +10.51 % in 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in 206 seconds +90.98 % in 216 seconds +96.24 % in 227 seconds + 0.75 % in 6 seconds + 3.01 % in 25 seconds + 3.76 % in 35 seconds + 4.51 % in 46 seconds + 6.77 % in 59 seconds + 9.02 % in 70 seconds +11.28 % in 80 seconds +14.29 % in 90 seconds +18.05 % in 100 seconds +22.56 % in 110 seconds +27.82 % in 120 seconds +33.83 % in 130 seconds +40.60 % in 140 seconds +47.37 % in 150 seconds +54.14 % in 160 seconds +62.41 % in 172 seconds +70.68 % in 182 seconds +77.44 % in 192 seconds +82.71 % in 202 seconds +88.72 % in 212 seconds +93.98 % in 223 seconds + 0.75 % in 5 seconds + 2.26 % in 15 seconds + 3.01 % in 25 seconds + 3.76 % in 35 seconds + 4.51 % in 45 seconds + 6.02 % in 55 seconds + 8.27 % in 66 seconds +11.28 % in 79 seconds +14.29 % in 90 seconds +18.05 % in 100 seconds +22.56 % in 110 seconds +28.57 % in 122 seconds +36.09 % in 132 seconds +42.11 % in 142 seconds +48.87 % in 152 seconds +55.64 % in 162 seconds +63.91 % in 172 seconds +71.43 % in 183 seconds +78.20 % in 193 seconds +84.21 % in 204 seconds +90.23 % in 214 seconds +94.74 % in 224 seconds + 0.75 % in 5 seconds + 2.26 % in 15 seconds + 3.01 % in 25 seconds + 3.76 % in 35 seconds + 4.51 % in 45 seconds + 6.77 % in 58 seconds + 9.02 % in 69 seconds +11.28 % in 79 seconds +14.29 % in 90 seconds +18.80 % in 100 seconds +23.31 % in 111 seconds +28.57 % in 121 seconds +35.34 % in 131 seconds +42.11 % in 141 seconds +48.87 % in 151 seconds +55.64 % in 161 seconds +63.16 % in 171 seconds +71.43 % in 182 seconds +78.20 % in 193 seconds +84.21 % in 203 seconds +89.47 % in 213 seconds +94.74 % in 223 seconds + 0.75 % in 5 seconds + 2.26 % in 15 seconds + 3.01 % in 25 seconds + 3.76 % in 35 seconds + 4.51 % in 45 seconds + 6.02 % in 55 seconds + 8.27 % in 66 seconds +11.28 % in 79 seconds +14.29 % in 90 seconds +18.05 % in 100 seconds +23.31 % in 111 seconds +28.57 % in 121 seconds +34.59 % in 131 seconds +42.11 % in 142 seconds +48.87 % in 152 seconds +56.39 % in 162 seconds +63.91 % in 172 seconds +71.43 % in 183 seconds +78.20 % in 193 seconds +84.21 % in 204 seconds +89.47 % in 214 seconds +94.74 % in 225 seconds + 0.75 % in 5 seconds + 2.26 % in 15 seconds + 3.76 % in 34 seconds + 4.51 % in 44 seconds + 6.77 % in 57 seconds + 9.02 % in 68 seconds +11.28 % in 78 seconds +14.29 % in 89 seconds +18.05 % in 99 seconds +23.31 % in 110 seconds +28.57 % in 121 seconds +36.09 % in 131 seconds +42.11 % in 141 seconds +48.87 % in 151 seconds +56.39 % in 161 seconds +63.91 % in 171 seconds +71.43 % in 182 seconds +78.20 % in 192 seconds +84.21 % in 203 seconds +90.23 % in 213 seconds +94.74 % in 223 seconds + 0.75 % in 6 seconds + 3.01 % in 26 seconds + 3.76 % in 36 seconds + 5.26 % in 53 seconds + 7.52 % in 63 seconds + 9.77 % in 73 seconds +12.78 % in 86 seconds +16.54 % in 96 seconds +20.30 % in 106 seconds +25.56 % in 116 seconds +31.58 % in 127 seconds +38.35 % in 137 seconds +45.11 % in 147 seconds +52.63 % in 157 seconds +60.15 % in 168 seconds +67.67 % in 178 seconds +75.19 % in 189 seconds +81.20 % in 199 seconds +87.22 % in 210 seconds +92.48 % in 220 seconds +97.74 % in 231 seconds + 0.75 % in 5 seconds + 2.26 % in 15 seconds + 3.01 % in 25 seconds + 3.76 % in 35 seconds + 4.51 % in 45 seconds + 6.77 % in 59 seconds + 9.02 % in 69 seconds +11.28 % in 79 seconds +14.29 % in 89 seconds +18.05 % in 99 seconds +22.56 % in 109 seconds +27.82 % in 119 seconds +33.83 % in 130 seconds +40.60 % in 140 seconds +48.12 % in 150 seconds +55.64 % in 162 seconds +63.16 % in 172 seconds +70.68 % in 182 seconds +77.44 % in 193 seconds +83.46 % in 203 seconds +88.72 % in 213 seconds +93.98 % in 223 seconds + 0.75 % in 6 seconds + 2.26 % in 16 seconds + 3.01 % in 26 seconds + 3.76 % in 36 seconds + 4.51 % in 46 seconds + 6.77 % in 60 seconds + 9.02 % in 71 seconds +11.28 % in 81 seconds +14.29 % in 91 seconds +18.05 % in 101 seconds +22.56 % in 111 seconds +28.57 % in 122 seconds +34.59 % in 132 seconds +42.11 % in 143 seconds +48.87 % in 153 seconds +56.39 % in 163 seconds +63.91 % in 173 seconds +71.43 % in 184 seconds +78.20 % in 194 seconds +84.21 % in 205 seconds +90.23 % in 215 seconds +94.74 % in 225 seconds + 0.00 % in 20 seconds + 0.00 % in 30 seconds + 0.01 % in 40 seconds + 0.01 % in 50 seconds + 0.02 % in 61 seconds + 0.02 % in 72 seconds + 0.04 % in 82 seconds + 0.04 % in 92 seconds + 0.06 % in 102 seconds + 0.07 % in 115 seconds + 0.08 % in 125 seconds + 0.10 % in 139 seconds + 0.12 % in 149 seconds + 0.14 % in 159 seconds + 0.16 % in 169 seconds + 0.16 % in 179 seconds + 0.18 % in 189 seconds + 0.21 % in 199 seconds + 0.22 % in 209 seconds + 0.24 % in 219 seconds + 0.27 % in 230 seconds + 0.28 % in 240 seconds + 0.30 % in 251 seconds + 0.33 % in 261 seconds + 0.34 % in 271 seconds + 0.34 % in 281 seconds + 0.36 % in 291 seconds + 0.38 % in 301 seconds + 0.39 % in 311 seconds + 0.41 % in 321 seconds + 0.44 % in 331 seconds + 0.45 % in 341 seconds + 0.46 % in 351 seconds + 0.49 % in 361 seconds + 0.52 % in 371 seconds + 0.53 % in 381 seconds + 0.54 % in 392 seconds + 0.57 % in 403 seconds + 0.58 % in 413 seconds + 0.59 % in 423 seconds + 0.61 % in 433 seconds + 0.62 % in 443 seconds + 0.64 % in 453 seconds + 0.66 % in 463 seconds + 0.68 % in 473 seconds + 0.71 % in 483 seconds + 0.72 % in 493 seconds + 0.74 % in 503 seconds + 0.76 % in 513 seconds + 0.78 % in 523 seconds + 0.80 % in 534 seconds + 0.81 % in 545 seconds + 0.82 % in 555 seconds + 0.84 % in 565 seconds + 0.86 % in 575 seconds + 0.87 % in 586 seconds + 0.89 % in 597 seconds + 0.90 % in 607 seconds + 0.93 % in 617 seconds + 0.95 % in 627 seconds + 0.96 % in 638 seconds + 0.98 % in 648 seconds + 1.00 % in 658 seconds + 1.02 % in 668 seconds + 1.03 % in 679 seconds + 1.04 % in 689 seconds + 1.05 % in 699 seconds + 1.07 % in 709 seconds + 1.09 % in 719 seconds + 1.10 % in 729 seconds + 1.12 % in 739 seconds + 1.14 % in 749 seconds + 1.16 % in 759 seconds + 1.18 % in 769 seconds + 1.20 % in 780 seconds + 1.22 % in 790 seconds + 1.24 % in 800 seconds + 1.25 % in 810 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in 1226 seconds + 1.94 % in 1236 seconds + 1.95 % in 1246 seconds + 1.98 % in 1256 seconds + 2.00 % in 1266 seconds + 2.01 % in 1276 seconds + 2.03 % in 1286 seconds + 2.05 % in 1296 seconds + 2.06 % in 1307 seconds + 2.09 % in 1317 seconds + 2.10 % in 1327 seconds + 2.12 % in 1337 seconds + 2.13 % in 1348 seconds + 2.15 % in 1358 seconds + 2.16 % in 1369 seconds + 2.17 % in 1379 seconds + 2.18 % in 1389 seconds + 2.20 % in 1400 seconds + 2.21 % in 1410 seconds + 2.22 % in 1420 seconds + 2.23 % in 1430 seconds + 2.24 % in 1440 seconds + 2.26 % in 1450 seconds + 2.27 % in 1460 seconds + 2.28 % in 1470 seconds + 2.30 % in 1480 seconds + 2.32 % in 1490 seconds + 2.33 % in 1501 seconds + 2.36 % in 1511 seconds + 2.39 % in 1521 seconds + 2.40 % in 1531 seconds + 2.40 % in 1541 seconds + 2.42 % in 1552 seconds + 2.44 % in 1562 seconds + 2.46 % in 1572 seconds + 2.48 % in 1582 seconds + 2.49 % in 1592 seconds + 2.50 % in 1603 seconds + 2.51 % in 1613 seconds + 2.53 % in 1623 seconds + 2.54 % in 1633 seconds + 2.56 % in 1643 seconds + 2.58 % in 1653 seconds + 2.60 % in 1663 seconds + 2.61 % in 1673 seconds + 2.63 % in 1684 seconds + 2.64 % in 1694 seconds + 2.67 % in 1704 seconds + 2.68 % in 1716 seconds + 2.70 % in 1726 seconds + 2.71 % in 1736 seconds + 2.73 % in 1746 seconds + 2.75 % in 1759 seconds + 2.76 % in 1769 seconds + 2.78 % in 1779 seconds + 2.80 % in 1789 seconds + 2.81 % in 1799 seconds + 2.83 % in 1811 seconds + 2.84 % in 1821 seconds + 2.85 % in 1831 seconds + 2.87 % in 1841 seconds + 2.88 % in 1851 seconds + 2.89 % in 1863 seconds + 2.90 % in 1873 seconds + 2.92 % in 1884 seconds + 2.93 % in 1894 seconds + 2.95 % in 1904 seconds + 2.96 % in 1914 seconds + 2.98 % in 1924 seconds + 2.99 % in 1934 seconds + 3.02 % in 1944 seconds + 3.03 % in 1954 seconds + 3.05 % in 1964 seconds + 3.06 % in 1974 seconds + 3.08 % in 1984 seconds + 3.09 % in 1994 seconds + 3.11 % in 2004 seconds + 3.13 % in 2014 seconds + 3.14 % in 2024 seconds + 3.16 % in 2034 seconds + 3.18 % in 2044 seconds + 3.20 % in 2054 seconds + 3.22 % in 2064 seconds + 3.24 % in 2074 seconds + 3.25 % in 2084 seconds + 3.26 % in 2094 seconds + 3.28 % in 2105 seconds + 3.29 % in 2115 seconds + 3.31 % in 2125 seconds + 3.32 % in 2135 seconds + 3.34 % in 2146 seconds + 3.36 % in 2156 seconds + 3.38 % in 2166 seconds + 3.40 % in 2176 seconds + 3.42 % in 2186 seconds + 3.43 % in 2196 seconds + 3.45 % in 2206 seconds + 3.46 % in 2216 seconds + 3.47 % in 2226 seconds + 3.48 % in 2236 seconds + 3.49 % in 2247 seconds + 3.51 % in 2257 seconds + 3.53 % in 2267 seconds + 3.54 % in 2278 seconds + 3.55 % in 2288 seconds + 3.56 % in 2298 seconds + 3.58 % in 2308 seconds + 3.59 % in 2318 seconds + 3.61 % in 2328 seconds + 3.61 % in 2338 seconds + 3.62 % in 2348 seconds + 3.64 % in 2358 seconds + 3.65 % in 2368 seconds + 3.67 % in 2378 seconds + 3.68 % in 2388 seconds + 3.69 % in 2398 seconds + 3.72 % in 2408 seconds + 3.73 % in 2418 seconds + 3.74 % in 2430 seconds + 3.76 % in 2440 seconds + 3.77 % in 2450 seconds + 3.77 % in 2460 seconds + 3.78 % in 2470 seconds + 3.79 % in 2480 seconds + 3.79 % in 2490 seconds + 3.81 % in 2500 seconds + 3.82 % in 2510 seconds + 3.83 % in 2520 seconds + 3.84 % in 2530 seconds + 3.85 % in 2540 seconds + 3.88 % in 2550 seconds + 3.90 % in 2560 seconds + 3.92 % in 2570 seconds + 3.94 % in 2580 seconds + 3.95 % in 2590 seconds + 3.97 % in 2600 seconds + 3.98 % in 2610 seconds + 3.99 % in 2620 seconds + 4.01 % in 2630 seconds + 4.03 % in 2640 seconds + 4.05 % in 2650 seconds + 4.06 % in 2660 seconds + 4.08 % in 2671 seconds + 4.10 % in 2681 seconds + 4.12 % in 2691 seconds + 4.14 % in 2701 seconds + 4.15 % in 2713 seconds + 4.16 % in 2723 seconds + 4.18 % in 2733 seconds + 4.19 % in 2743 seconds + 4.21 % in 2753 seconds + 4.23 % in 2765 seconds + 4.24 % in 2775 seconds + 4.27 % in 2785 seconds + 4.29 % in 2795 seconds + 4.31 % in 2805 seconds + 4.32 % in 2815 seconds + 4.33 % in 2825 seconds + 4.34 % in 2835 seconds + 4.36 % in 2845 seconds + 4.38 % in 2855 seconds + 4.40 % in 2865 seconds + 4.41 % in 2875 seconds + 4.43 % in 2885 seconds + 4.44 % in 2895 seconds + 4.46 % in 2907 seconds + 4.47 % in 2917 seconds + 4.48 % in 2930 seconds + 4.49 % in 2940 seconds + 4.51 % in 2950 seconds + 4.51 % in 2960 seconds + 4.52 % in 2970 seconds + 4.54 % in 2980 seconds + 4.56 % in 2990 seconds + 4.57 % in 3000 seconds + 4.59 % in 3010 seconds + 4.61 % in 3020 seconds + 4.62 % in 3030 seconds + 4.64 % in 3040 seconds + 4.65 % in 3050 seconds + 4.67 % in 3060 seconds + 4.69 % in 3070 seconds + 4.70 % in 3080 seconds + 4.71 % in 3090 seconds + 4.72 % in 3100 seconds + 4.73 % in 3110 seconds + 4.75 % in 3120 seconds + 4.76 % in 3130 seconds + 4.78 % in 3140 seconds + 4.79 % in 3150 seconds + 4.81 % in 3160 seconds + 4.83 % in 3170 seconds + 4.85 % in 3180 seconds + 4.87 % in 3191 seconds + 4.88 % in 3203 seconds + 4.90 % in 3213 seconds + 4.91 % in 3223 seconds + 4.93 % in 3234 seconds + 4.94 % in 3244 seconds + 4.95 % in 3254 seconds + 4.97 % in 3264 seconds + 4.98 % in 3274 seconds + 4.99 % in 3284 seconds + 5.01 % in 3294 seconds + 5.01 % in 3304 seconds + 5.02 % in 3315 seconds + 5.03 % in 3325 seconds + 5.04 % in 3335 seconds + 5.05 % in 3345 seconds + 5.06 % in 3355 seconds + 5.08 % in 3365 seconds + 5.09 % in 3375 seconds + 5.10 % in 3386 seconds + 5.11 % in 3396 seconds + 5.12 % in 3406 seconds + 5.14 % in 3417 seconds + 5.15 % in 3428 seconds + 5.16 % in 3438 seconds + 5.17 % in 3448 seconds + 5.18 % in 3458 seconds + 5.19 % in 3468 seconds + 5.21 % in 3478 seconds + 5.22 % in 3489 seconds + 5.23 % in 3499 seconds + 5.24 % in 3510 seconds + 5.26 % in 3520 seconds + 5.27 % in 3530 seconds + 5.29 % in 3540 seconds + 5.31 % in 3550 seconds + 5.33 % in 3560 seconds + 5.35 % in 3570 seconds + 5.36 % in 3580 seconds + 5.38 % in 3590 seconds + 5.40 % in 3601 seconds + 5.41 % in 3611 seconds + 5.43 % in 3621 seconds + 5.45 % in 3631 seconds + 5.47 % in 3641 seconds + 5.49 % in 3651 seconds + 5.51 % in 3661 seconds + 5.52 % in 3671 seconds + 5.53 % in 3681 seconds + 5.54 % in 3691 seconds + 5.57 % in 3701 seconds + 5.59 % in 3712 seconds + 5.59 % in 3722 seconds + 5.61 % in 3732 seconds + 5.63 % in 3742 seconds + 5.65 % in 3752 seconds + 5.66 % in 3762 seconds + 5.67 % in 3772 seconds + 5.68 % in 3783 seconds + 5.69 % in 3794 seconds + 5.71 % in 3806 seconds + 5.72 % in 3817 seconds + 5.73 % in 3827 seconds + 5.74 % in 3837 seconds + 5.75 % in 3847 seconds + 5.76 % in 3857 seconds + 5.77 % in 3867 seconds + 5.78 % in 3877 seconds + 5.80 % in 3887 seconds + 5.81 % in 3897 seconds + 5.83 % in 3907 seconds + 5.85 % in 3917 seconds + 5.86 % in 3927 seconds + 5.89 % in 3937 seconds + 5.91 % in 3947 seconds + 5.92 % in 3957 seconds + 5.92 % in 3967 seconds + 5.94 % in 3977 seconds + 5.95 % in 3987 seconds + 5.96 % in 3997 seconds + 5.97 % in 4007 seconds + 5.98 % in 4017 seconds + 5.99 % in 4027 seconds + 6.00 % in 4037 seconds + 6.02 % in 4047 seconds + 6.03 % in 4057 seconds + 6.04 % in 4067 seconds + 6.06 % in 4077 seconds + 6.07 % in 4088 seconds + 6.08 % in 4098 seconds + 6.08 % in 4109 seconds + 6.09 % in 4119 seconds + 6.10 % in 4129 seconds + 6.11 % in 4139 seconds + 6.13 % in 4150 seconds + 6.14 % in 4160 seconds + 6.15 % in 4172 seconds + 6.16 % in 4182 seconds + 6.17 % in 4192 seconds + 6.18 % in 4202 seconds + 6.18 % in 4212 seconds + 6.20 % in 4222 seconds + 6.21 % in 4232 seconds + 6.22 % in 4242 seconds + 6.23 % in 4252 seconds + 6.24 % in 4262 seconds + 6.26 % in 4272 seconds + 6.28 % in 4282 seconds + 6.30 % in 4292 seconds + 6.30 % in 4302 seconds + 6.31 % in 4312 seconds + 6.32 % in 4322 seconds + 6.33 % in 4332 seconds + 6.34 % in 4342 seconds + 6.35 % in 4352 seconds + 6.37 % in 4362 seconds + 6.38 % in 4373 seconds + 6.39 % in 4384 seconds + 6.40 % in 4394 seconds + 6.41 % in 4405 seconds + 6.43 % in 4415 seconds + 6.44 % in 4427 seconds + 6.45 % in 4437 seconds + 6.46 % in 4448 seconds + 6.46 % in 4458 seconds + 6.47 % in 4468 seconds + 6.48 % in 4479 seconds + 6.49 % in 4489 seconds + 6.50 % in 4499 seconds + 6.52 % in 4509 seconds + 6.53 % in 4520 seconds + 6.54 % in 4530 seconds + 6.56 % in 4540 seconds + 6.58 % in 4550 seconds + 6.59 % in 4560 seconds + 6.60 % in 4570 seconds + 6.60 % in 4580 seconds + 6.61 % in 4590 seconds + 6.62 % in 4600 seconds + 6.63 % in 4611 seconds + 6.64 % in 4623 seconds + 6.64 % in 4633 seconds + 6.65 % in 4643 seconds + 6.67 % in 4653 seconds + 6.68 % in 4664 seconds + 6.69 % in 4674 seconds + 6.70 % in 4684 seconds + 6.72 % in 4694 seconds + 6.73 % in 4704 seconds + 6.74 % in 4714 seconds + 6.75 % in 4725 seconds + 6.76 % in 4735 seconds + 6.77 % in 4745 seconds + 6.78 % in 4756 seconds + 6.80 % in 4766 seconds + 6.81 % in 4776 seconds + 6.83 % in 4787 seconds + 6.84 % in 4797 seconds + 6.85 % in 4807 seconds + 6.86 % in 4818 seconds + 6.87 % in 4828 seconds + 6.88 % in 4838 seconds + 6.89 % in 4849 seconds + 6.91 % in 4860 seconds + 6.93 % in 4870 seconds + 6.95 % in 4881 seconds + 6.96 % in 4891 seconds + 6.98 % in 4902 seconds + 6.99 % in 4912 seconds + 7.00 % in 4922 seconds + 7.01 % in 4932 seconds + 7.02 % in 4942 seconds + 7.03 % in 4952 seconds + 7.04 % in 4962 seconds + 7.04 % in 4972 seconds + 7.06 % in 4982 seconds + 7.07 % in 4994 seconds + 7.08 % in 5004 seconds + 7.10 % in 5014 seconds + 7.12 % in 5026 seconds + 7.14 % in 5036 seconds + 7.15 % in 5047 seconds + 7.16 % in 5057 seconds + 7.17 % in 5068 seconds + 7.17 % in 5078 seconds + 7.18 % in 5088 seconds + 7.20 % in 5098 seconds + 7.21 % in 5108 seconds + 7.23 % in 5118 seconds + 7.25 % in 5128 seconds + 7.26 % in 5138 seconds + 7.27 % in 5148 seconds + 7.28 % in 5159 seconds + 7.30 % in 5169 seconds + 7.31 % in 5179 seconds + 7.32 % in 5189 seconds + 7.33 % in 5199 seconds + 7.34 % in 5209 seconds + 7.35 % in 5219 seconds + 7.36 % in 5229 seconds + 7.37 % in 5239 seconds + 7.38 % in 5249 seconds + 7.38 % in 5262 seconds + 7.39 % in 5272 seconds + 7.40 % in 5282 seconds + 7.41 % in 5292 seconds + 7.42 % in 5302 seconds + 7.43 % in 5313 seconds + 7.44 % in 5323 seconds + 7.45 % in 5333 seconds + 7.47 % in 5343 seconds + 7.47 % in 5353 seconds + 7.48 % in 5366 seconds + 7.49 % in 5376 seconds + 7.51 % in 5386 seconds + 7.52 % in 5396 seconds + 7.53 % in 5408 seconds + 7.54 % in 5418 seconds + 7.55 % in 5429 seconds + 7.55 % in 5439 seconds + 7.57 % in 5449 seconds + 7.58 % in 5459 seconds + 7.59 % in 5469 seconds + 7.61 % in 5479 seconds + 7.62 % in 5489 seconds + 7.64 % in 5499 seconds + 7.66 % in 5509 seconds + 7.67 % in 5519 seconds + 7.68 % in 5529 seconds + 7.69 % in 5539 seconds + 7.69 % in 5549 seconds + 7.70 % in 5562 seconds + 7.71 % in 5572 seconds + 7.72 % in 5583 seconds + 7.73 % in 5593 seconds + 7.74 % in 5603 seconds + 7.75 % in 5613 seconds + 7.76 % in 5623 seconds + 7.77 % in 5634 seconds + 7.78 % in 5644 seconds + 7.80 % in 5654 seconds + 7.81 % in 5664 seconds + 7.82 % in 5674 seconds + 7.83 % in 5684 seconds + 7.84 % in 5695 seconds + 7.85 % in 5705 seconds + 7.86 % in 5715 seconds + 7.87 % in 5725 seconds + 7.88 % in 5735 seconds + 7.88 % in 5746 seconds + 7.89 % in 5757 seconds + 7.90 % in 5767 seconds + 7.91 % in 5777 seconds + 7.92 % in 5787 seconds + 7.93 % in 5797 seconds + 7.95 % in 5807 seconds + 7.97 % in 5817 seconds + 7.98 % in 5827 seconds + 7.99 % in 5837 seconds + 8.00 % in 5847 seconds + 8.02 % in 5857 seconds + 8.04 % in 5871 seconds + 8.05 % in 5881 seconds + 8.06 % in 5891 seconds + 8.07 % in 5901 seconds + 8.07 % in 5911 seconds + 8.09 % in 5921 seconds + 8.10 % in 5934 seconds + 8.10 % in 5945 seconds + 8.11 % in 5955 seconds + 8.12 % in 5965 seconds + 8.13 % in 5977 seconds + 8.14 % in 5987 seconds + 8.15 % in 5997 seconds + 8.15 % in 6007 seconds + 8.16 % in 6017 seconds + 8.18 % in 6027 seconds + 8.19 % in 6039 seconds + 8.20 % in 6049 seconds + 8.21 % in 6059 seconds + 8.22 % in 6069 seconds + 8.23 % in 6080 seconds + 8.24 % in 6090 seconds + 8.25 % in 6100 seconds + 8.27 % in 6110 seconds + 8.29 % in 6120 seconds + 8.30 % in 6130 seconds + 8.31 % in 6140 seconds + 8.32 % in 6150 seconds + 8.33 % in 6160 seconds + 8.33 % in 6170 seconds + 8.34 % in 6180 seconds + 8.36 % in 6190 seconds + 8.37 % in 6200 seconds + 8.38 % in 6211 seconds + 8.39 % in 6222 seconds + 8.40 % in 6232 seconds + 8.41 % in 6243 seconds + 8.42 % in 6253 seconds + 8.43 % in 6263 seconds + 8.44 % in 6273 seconds + 8.45 % in 6284 seconds + 8.46 % in 6294 seconds + 8.47 % in 6304 seconds + 8.48 % in 6315 seconds + 8.50 % in 6325 seconds + 8.52 % in 6335 seconds + 8.52 % in 6345 seconds + 8.54 % in 6355 seconds + 8.54 % in 6365 seconds + 8.55 % in 6375 seconds + 8.56 % in 6385 seconds + 8.58 % in 6395 seconds + 8.59 % in 6405 seconds + 8.60 % in 6415 seconds + 8.61 % in 6425 seconds + 8.62 % in 6435 seconds + 8.64 % in 6445 seconds + 8.65 % in 6456 seconds + 8.67 % in 6466 seconds + 8.68 % in 6476 seconds + 8.68 % in 6486 seconds + 8.69 % in 6498 seconds + 8.71 % in 6508 seconds + 8.72 % in 6518 seconds + 8.73 % in 6528 seconds + 8.75 % in 6538 seconds + 8.76 % 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8018 seconds + 2.86 % in 8288 seconds + 2.91 % in 8556 seconds + 2.95 % in 8838 seconds + 3.00 % in 9040 seconds + 3.05 % in 9092 seconds + 3.10 % in 9112 seconds + 3.14 % in 9122 seconds + 3.19 % in 9142 seconds + 3.29 % in 9159 seconds + 3.38 % in 9220 seconds + 3.43 % in 9286 seconds + 3.48 % in 9351 seconds + 3.53 % in 9416 seconds + 3.57 % in 9486 seconds + 3.62 % in 9555 seconds + 3.67 % in 9621 seconds + 3.72 % in 9635 seconds + 3.81 % in 9649 seconds + 3.91 % in 9664 seconds + 3.95 % in 9734 seconds + 4.00 % in 9811 seconds + 4.05 % in 9879 seconds + 4.10 % in 9947 seconds + 4.14 % in 10010 seconds + 4.24 % in 10059 seconds + 4.29 % in 10086 seconds + 4.34 % in 10113 seconds + 4.43 % in 10128 seconds + 4.48 % in 10191 seconds + 4.53 % in 10254 seconds + 4.57 % in 10313 seconds + 4.62 % in 10379 seconds + 4.67 % in 10432 seconds + 4.72 % in 10462 seconds + 4.76 % in 10503 seconds + 4.81 % in 10553 seconds + 4.86 % in 10601 seconds + 4.91 % in 10654 seconds + 4.95 % in 10711 seconds + 5.00 % in 10763 seconds + 5.05 % in 10816 seconds + 5.10 % in 10868 seconds + 5.15 % in 10918 seconds + 5.19 % in 10928 seconds + 5.29 % in 10944 seconds + 5.38 % in 10957 seconds + 5.43 % in 10999 seconds + 5.48 % in 11062 seconds + 5.53 % in 11131 seconds + 5.57 % in 11197 seconds + 5.62 % in 11263 seconds + 5.67 % in 11317 seconds + 5.76 % in 11332 seconds + 5.86 % in 11346 seconds + 5.91 % in 11364 seconds + 5.96 % in 11426 seconds + 6.00 % in 11488 seconds + 6.05 % in 11551 seconds + 6.10 % in 11611 seconds + 6.15 % in 11672 seconds + 6.19 % in 11691 seconds + 6.24 % in 11727 seconds + 6.29 % in 11763 seconds + 6.34 % in 11773 seconds + 6.38 % in 11830 seconds + 6.43 % in 11887 seconds + 6.48 % in 11924 seconds + 6.53 % in 11969 seconds + 6.57 % in 12012 seconds + 6.62 % in 12056 seconds + 6.67 % in 12111 seconds + 6.72 % in 12165 seconds + 6.77 % in 12215 seconds + 6.81 % in 12265 seconds + 6.86 % in 12318 seconds + 6.91 % in 12366 seconds + 6.96 % in 12383 seconds + 7.00 % in 12399 seconds + 7.05 % in 12414 seconds + 7.10 % in 12427 seconds + 7.15 % in 12440 seconds + 7.24 % in 12453 seconds + 7.34 % in 12514 seconds + 7.38 % in 12532 seconds + 7.43 % in 12569 seconds + 7.48 % in 12587 seconds + 7.58 % in 12598 seconds + 7.62 % in 12641 seconds + 7.67 % in 12706 seconds + 7.72 % in 12765 seconds + 7.77 % in 12822 seconds + 7.81 % in 12844 seconds + 7.91 % in 12862 seconds + 7.96 % in 12930 seconds + 8.00 % in 12991 seconds + 8.05 % in 13053 seconds + 8.10 % in 13103 seconds + 8.15 % in 13137 seconds + 8.19 % in 13159 seconds + 8.24 % in 13215 seconds + 8.29 % in 13234 seconds + 8.34 % in 13297 seconds + 8.38 % in 13348 seconds + 8.43 % in 13388 seconds + 8.48 % in 13437 seconds + 8.53 % in 13489 seconds + 8.58 % in 13536 seconds + 8.62 % in 13584 seconds + 8.67 % in 13637 seconds + 8.72 % in 13686 seconds + 8.77 % in 13736 seconds + 8.81 % in 13781 seconds + 8.86 % in 13791 seconds + 8.91 % in 13801 seconds + 9.00 % in 13817 seconds + 9.10 % in 13832 seconds + 9.19 % in 13846 seconds + 9.29 % in 13863 seconds + 9.39 % in 13879 seconds + 9.48 % in 13891 seconds + 9.62 % in 13945 seconds + 9.67 % in 13955 seconds + 9.72 % in 13995 seconds + 9.77 % in 14022 seconds + 9.86 % in 14048 seconds + 9.91 % in 14107 seconds + 9.96 % in 14167 seconds +10.00 % in 14186 seconds +10.05 % in 14213 seconds +10.10 % in 14268 seconds +10.15 % in 14278 seconds +10.20 % in 14335 seconds +10.24 % in 14349 seconds +10.29 % in 14372 seconds +10.34 % in 14432 seconds +10.39 % in 14490 seconds +10.43 % in 14525 seconds +10.48 % in 14557 seconds +10.53 % in 14621 seconds +10.58 % in 14668 seconds +10.62 % in 14709 seconds +10.67 % in 14764 seconds +10.72 % in 14806 seconds +10.77 % in 14851 seconds +10.81 % in 14901 seconds +10.86 % in 14950 seconds +10.91 % in 15001 seconds +10.96 % in 15055 seconds +11.01 % in 15104 seconds +11.05 % in 15151 seconds +11.10 % in 15176 seconds +11.20 % in 15194 seconds +11.29 % in 15209 seconds +11.39 % in 15224 seconds +11.48 % in 15237 seconds +11.58 % in 15254 seconds +11.67 % in 15268 seconds +11.77 % in 15278 seconds +11.86 % in 15291 seconds +11.96 % in 15306 seconds +12.05 % in 15318 seconds +12.15 % in 15330 seconds +12.20 % in 15366 seconds +12.24 % in 15381 seconds +12.29 % in 15429 seconds +12.39 % in 15459 seconds +12.43 % in 15522 seconds +12.48 % in 15571 seconds +12.58 % in 15589 seconds +12.63 % in 15645 seconds +12.67 % in 15701 seconds +12.72 % in 15743 seconds +12.77 % in 15774 seconds +12.86 % in 15837 seconds +12.91 % in 15893 seconds +12.96 % in 15923 seconds +13.01 % in 15973 seconds +13.05 % in 16010 seconds +13.10 % in 16044 seconds +13.15 % in 16098 seconds +13.20 % in 16154 seconds +13.24 % in 16200 seconds +13.29 % in 16246 seconds +13.34 % in 16292 seconds +13.39 % in 16340 seconds +13.43 % in 16385 seconds +13.48 % in 16433 seconds +13.53 % in 16457 seconds +13.58 % in 16467 seconds +13.67 % in 16483 seconds +13.77 % in 16498 seconds +13.86 % in 16511 seconds +13.96 % in 16527 seconds +14.05 % in 16540 seconds +14.15 % in 16550 seconds +14.24 % in 16565 seconds +14.34 % in 16580 seconds +14.48 % in 16596 seconds +14.58 % in 16609 seconds +14.67 % in 16619 seconds +14.77 % in 16670 seconds +14.82 % in 16706 seconds +14.86 % in 16729 seconds +14.91 % in 16753 seconds +15.01 % in 16795 seconds +15.05 % in 16858 seconds +15.10 % in 16895 seconds +15.20 % in 16949 seconds +15.25 % in 17004 seconds +15.29 % in 17028 seconds +15.34 % in 17078 seconds +15.39 % in 17088 seconds +15.44 % in 17127 seconds +15.48 % in 17183 seconds +15.53 % in 17216 seconds +15.58 % in 17254 seconds +15.63 % in 17309 seconds +15.67 % in 17343 seconds +15.72 % in 17383 seconds +15.77 % in 17430 seconds +15.82 % in 17478 seconds +15.86 % in 17523 seconds +15.91 % in 17573 seconds +15.96 % in 17618 seconds +16.01 % in 17666 seconds +16.06 % in 17714 seconds +16.10 % in 17761 seconds +16.15 % in 17774 seconds +16.20 % in 17784 seconds +16.29 % in 17800 seconds +16.39 % in 17813 seconds +16.48 % in 17827 seconds +16.58 % in 17844 seconds +16.67 % in 17857 seconds +16.77 % in 17867 seconds +16.87 % in 17883 seconds +16.96 % in 17894 seconds +17.06 % in 17905 seconds +17.15 % in 17918 seconds +17.25 % in 17930 seconds +17.34 % in 17941 seconds +17.44 % in 17954 seconds +17.53 % in 17964 seconds +17.58 % in 17977 seconds +17.63 % in 18010 seconds +17.68 % in 18039 seconds +17.77 % in 18097 seconds +17.82 % in 18122 seconds +17.87 % in 18148 seconds +17.91 % in 18203 seconds +17.96 % in 18223 seconds +18.01 % in 18244 seconds +18.06 % in 18282 seconds +18.10 % in 18334 seconds +18.15 % in 18370 seconds +18.20 % in 18407 seconds +18.25 % in 18462 seconds +18.29 % in 18489 seconds +18.34 % in 18535 seconds +18.39 % in 18591 seconds +18.44 % in 18635 seconds +18.48 % in 18677 seconds +18.53 % in 18717 seconds diff --git a/imidazole/cc-pvtz/imidazole.fci.out b/imidazole/cc-pvtz/imidazole.fci.out index a51611a..0a5e657 100644 --- a/imidazole/cc-pvtz/imidazole.fci.out +++ b/imidazole/cc-pvtz/imidazole.fci.out @@ -2720,3 +2720,1484 @@ Iter Energy S^2 Residual ========== ================= =========== =============== =============== ================= 3 -225.7698072642 0.463E-02 2.2692942004 0.0676093161 248.6867 4 -225.7705759593 0.316E-02 2.2764679717 0.0677312316 257.0994 + 5 -225.7711096858 0.246E-02 2.2821355686 0.0677381506 386.5492 + 8 -225.7716098431 0.164E-02 2.2861294260 0.0677733745 556.6329 + 13 -225.7727731874 0.134E-02 2.2953606226 0.0678914453 567.0761 + 15 -225.7725537545 0.117E-02 2.2934917245 0.0678538078 597.5774 + 16 -225.7728501574 0.114E-02 2.2955545977 0.0679026168 805.9962 + 20 -225.7728163179 0.102E-02 2.2928651044 0.0679811289 854.7832 + 27 -225.7729490708 0.915E-03 2.2915994801 0.0680853940 869.2483 + 28 -225.7728633005 0.877E-03 2.2904690243 0.0680882591 913.9284 + 29 -225.7730265765 0.862E-03 2.2915683182 0.0681089220 966.7392 + 31 -225.7731961110 0.814E-03 2.2928883365 0.0681350452 1004.9768 + 33 -225.7732499200 0.765E-03 2.2933470825 0.0681394543 1037.9842 + 34 -225.7733390473 0.747E-03 2.2940055735 0.0681561892 1090.7333 + 37 -225.7733882055 0.705E-03 2.2939593653 0.0681642010 1153.8082 + 38 -225.7734062160 0.577E-03 2.2936036315 0.0681959866 1155.0032 + 41 -225.7733775625 0.545E-03 2.2936588688 0.0681827949 1179.2993 + 43 -225.7733773677 0.523E-03 2.2939683657 0.0681751962 1198.6455 + 44 -225.7734969574 0.525E-03 2.2947895944 0.0681918732 1213.8493 + 45 -225.7735417286 0.515E-03 2.2949714405 0.0682022531 1248.3343 + 46 -225.7736217514 0.510E-03 2.2958537454 0.0682090079 1273.4378 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 11.331177 GB ] [ VIRT MEM : 16.125233 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3158.067088 s ] [ CPU TIME: 222330.629195 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 11.331177 GB ] [ VIRT MEM : 16.125233 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3158.067875 s ] [ CPU TIME: 222330.685200 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.6046636515271959 + +Summary at N_det = 163840 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.41223035 +# PT2 -0.36139140 0.00051011 +# rPT2 -0.33831525 0.00047754 +# +# E+PT2 -225.77362175 0.00051011 +# E+rPT2 -225.75054560 0.00047754 +# ============ ============================= + + N_det = 163840 + N_states = 1 + + * State 1 + < S^2 > = 2.976017069224303E-002 + E = -225.412230350077 + Variance = 2.29585374544096 + PT norm = 0.261168543044641 + PT2 = -0.361391401356343 + rPT2 = -0.338315253561571 + E+PT2 = -225.773621751433 +/- 5.101112796042552E-004 + E+rPT2 = -225.750545603638 +/- 4.775388298012192E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -852.632416101203 + Vee = 238.793228480403 + Vecp = 0.000000000000000E+000 + T = 224.922607549659 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3991 -225.84043054 + -0.4594 -225.83239287 + -0.5123 -225.83280055 + -0.5583 -225.83312657 + -0.5969 -225.83427172 + -0.6281 -225.83618876 + -0.6528 -225.83860631 + =========== =================== + +* Number of unique beta determinants 37433 +* Number of unique alpha determinants 37435 + +.. >>>>> [ RES MEM : 11.153477 GB ] [ VIRT MEM : 15.947475 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3172.513190 s ] [ CPU TIME: 223366.760477 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 327680 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.5854481607675552 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.4122309359 0.029760 0.174E-01 + 2 -225.4870942026 0.021687 0.906E-03 + 3 -225.4877319565 0.020952 0.351E-04 + 4 -225.4877965304 0.020936 0.769E-06 + 5 -225.4877982145 0.020917 0.316E-07 + 6 -225.4877982785 0.020911 0.120E-08 + 7 -225.4877982810 0.020910 0.452E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 11.337646 GB ] [ VIRT MEM : 16.264851 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3270.234801 s ] [ CPU TIME: 230356.021890 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 11.073990 GB ] [ VIRT MEM : 15.897163 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3270.299552 s ] [ CPU TIME: 230360.660258 s ] <<<<< .. + +* Energy of state 1 -225.4877982810461 +* S^2 of state 1 0.2090978507355641E-01 +* Saved determinants 327680 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 11.037048 GB ] [ VIRT MEM : 15.856133 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3276.517186 s ] [ CPU TIME: 230485.327249 s ] <<<<< .. + +* Number of generators 327680 + +.. >>>>> [ RES MEM : 11.037048 GB ] [ VIRT MEM : 15.856133 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3276.518350 s ] [ CPU TIME: 230485.408882 s ] <<<<< .. + +* Number of selectors 327680 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 +* PT2 Energy denominator -225.4877982810461 + +.. >>>>> [ RES MEM : 11.102798 GB ] [ VIRT MEM : 15.924492 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3276.689418 s ] [ CPU TIME: 230497.468375 s ] <<<<< .. + +* Number of generators 327680 + +.. >>>>> [ RES MEM : 11.102798 GB ] [ VIRT MEM : 15.924492 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3276.690582 s ] [ CPU TIME: 230497.551474 s ] <<<<< .. + +* Number of selectors 327680 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 +* Number of tasks 690868 +* Number of fragmented tasks 70623 +* Number of threads for PT2 72 +* Memory (Gb) 6.404925888776779 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.7802571361 0.167E-02 1.9941428359 0.0506057999 462.1071 + 4 -225.7788550561 0.190E-02 1.9889022059 0.0502393777 493.7961 + 5 -225.7804287119 0.221E-02 2.0004715309 0.0504824542 561.5331 + 6 -225.7794952474 0.211E-02 1.9906789045 0.0504093112 755.2221 + 9 -225.7773875700 0.183E-02 1.9734682972 0.0501053374 813.9280 + 12 -225.7781388660 0.156E-02 1.9802506477 0.0502233608 847.5641 + 13 -225.7779823475 0.146E-02 1.9794173286 0.0501879602 863.2302 + 14 -225.7774675011 0.145E-02 1.9771963282 0.0500667720 866.0903 + 15 -225.7773529306 0.135E-02 1.9764870657 0.0500637554 1039.0421 + 19 -225.7771974536 0.106E-02 1.9755953746 0.0500323036 1347.9262 + 26 -225.7773767085 0.843E-03 1.9777462888 0.0500524470 1438.3511 + 28 -225.7776924881 0.827E-03 1.9787485810 0.0501301138 1446.4871 + 29 -225.7775242483 0.815E-03 1.9775635297 0.0500979570 1489.8251 + 31 -225.7775872516 0.763E-03 1.9782689974 0.0501042672 1701.4738 + 34 -225.7777218983 0.704E-03 1.9785598138 0.0501391297 1727.5382 + 36 -225.7774742487 0.677E-03 1.9774585161 0.0500704712 1773.9845 + 37 -225.7774613519 0.658E-03 1.9771531912 0.0500719645 1850.3691 + 38 -225.7773162752 0.657E-03 1.9761982853 0.0500435520 1920.6021 + 42 -225.7770723306 0.614E-03 1.9753663114 0.0499769821 2066.4982 + 47 -225.7767773946 0.605E-03 1.9732538282 0.0499346397 2068.9051 + 48 -225.7769448237 0.609E-03 1.9743986173 0.0499624936 2132.9063 + 49 -225.7770706711 0.610E-03 1.9751649368 0.0499849590 2176.0429 + 50 -225.7770480774 0.598E-03 1.9749922786 0.0499794939 2187.4592 + 51 -225.7770522310 0.586E-03 1.9747346348 0.0499861030 2219.1631 + 52 -225.7769142944 0.591E-03 1.9736512841 0.0499646551 2264.9332 + 53 -225.7769431370 0.580E-03 1.9736754125 0.0499762140 2324.0572 + 55 -225.7770036984 0.562E-03 1.9735548599 0.0499967787 2376.3972 + 56 -225.7770076096 0.552E-03 1.9732617557 0.0500054449 2379.1381 + 58 -225.7769800716 0.545E-03 1.9726395320 0.0500099065 2503.2340 + 61 -225.7771733344 0.573E-03 1.9737994524 0.0500493359 2690.4454 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 14.919842 GB ] [ VIRT MEM : 19.016827 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5969.135160 s ] [ CPU TIME: 423628.782137 s ] <<<<< .. + +* Number of generators 327680 + +.. >>>>> [ RES MEM : 14.919842 GB ] [ VIRT MEM : 19.016827 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5969.136339 s ] [ CPU TIME: 423628.867229 s ] <<<<< .. + +* Number of selectors 327680 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.6827280370345166 + +Summary at N_det = 327680 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.48779828 +# PT2 -0.28937478 0.00054605 +# rPT2 -0.27558276 0.00052002 +# +# E+PT2 -225.77717306 0.00054605 +# E+rPT2 -225.76338104 0.00052002 +# ============ ============================= + + N_det = 327680 + N_states = 1 + + * State 1 + < S^2 > = 2.090978507355641E-002 + E = -225.487798281046 + Variance = 1.97394125114434 + PT norm = 0.223711307768696 + PT2 = -0.289374782933127 + rPT2 = -0.275582761574277 + E+PT2 = -225.777173063979 +/- 5.460453827672376E-004 + E+rPT2 = -225.763381042620 +/- 5.200200687931195E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -852.832987262715 + Vee = 238.784093008721 + Vecp = 0.000000000000000E+000 + T = 225.056746251884 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3383 -225.81976691 + -0.3991 -225.82862934 + -0.4594 -225.82831758 + -0.5123 -225.82954954 + -0.5583 -225.83036272 + -0.5969 -225.83150835 + -0.6281 -225.83310538 + =========== =================== + +* Number of unique beta determinants 74122 +* Number of unique alpha determinants 74124 + +.. >>>>> [ RES MEM : 15.006084 GB ] [ VIRT MEM : 19.081776 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6037.678210 s ] [ CPU TIME: 428305.203707 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 655360 +* Number of threads for diagonalization 72 +* Memory(Gb) 1.167766500264406 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.4877996187 0.020910 0.131E-01 + 2 -225.5550565739 0.012998 0.635E-03 + 3 -225.5555602481 0.012633 0.286E-04 + 4 -225.5556165831 0.012622 0.644E-06 + 5 -225.5556181032 0.012612 0.259E-07 + 6 -225.5556181613 0.012608 0.102E-08 + 7 -225.5556181637 0.012608 0.399E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 15.500477 GB ] [ VIRT MEM : 19.824455 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6473.973206 s ] [ CPU TIME: 459044.177685 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 14.973137 GB ] [ VIRT MEM : 19.090557 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6474.039682 s ] [ CPU TIME: 459048.952670 s ] <<<<< .. + +* Energy of state 1 -225.5556181637091 +* S^2 of state 1 0.1260768926699831E-01 +* Saved determinants 655360 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 14.857491 GB ] [ VIRT MEM : 18.970417 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6486.298835 s ] [ CPU TIME: 459263.888233 s ] <<<<< .. + +* Number of generators 655358 + +.. >>>>> [ RES MEM : 14.857491 GB ] [ VIRT MEM : 18.970417 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6486.300765 s ] [ CPU TIME: 459264.023197 s ] <<<<< .. + +* Number of selectors 655358 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 +* PT2 Energy denominator -225.5556181637091 + +.. >>>>> [ RES MEM : 15.013271 GB ] [ VIRT MEM : 19.127655 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6486.657181 s ] [ CPU TIME: 459288.910154 s ] <<<<< .. + +* Number of generators 655358 + +.. >>>>> [ RES MEM : 15.013271 GB ] [ VIRT MEM : 19.127655 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6486.659065 s ] [ CPU TIME: 459289.042080 s ] <<<<< .. + +* Number of selectors 655358 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 +* Number of tasks 1593791 +* Number of fragmented tasks 103819 +* Number of threads for PT2 72 +* Memory (Gb) 12.78708426900208 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.7778042774 0.418E-02 1.5980678636 0.0359037999 931.8616 + 5 -225.7807044829 0.287E-02 1.6195614709 0.0364014383 1051.6714 + 8 -225.7812825200 0.194E-02 1.6325360655 0.0364106956 1697.7625 + 17 -225.7797602510 0.124E-02 1.6229554877 0.0361579523 1806.2976 + 19 -225.7800203337 0.117E-02 1.6244675971 0.0362143901 1867.1857 + 20 -225.7799286776 0.112E-02 1.6237091638 0.0361981698 1879.7146 + 21 -225.7802730585 0.112E-02 1.6267187878 0.0362447232 2254.4546 + 24 -225.7798408509 0.108E-02 1.6246278066 0.0361737361 2395.7266 + 28 -225.7805539497 0.950E-03 1.6296819640 0.0362950071 2504.7597 + 29 -225.7805261564 0.917E-03 1.6289420835 0.0362953227 2512.6557 + 30 -225.7807582602 0.916E-03 1.6299820949 0.0363484435 2620.0850 + 32 -225.7807468253 0.870E-03 1.6298352221 0.0363397187 2645.2957 + 33 -225.7806838912 0.846E-03 1.6290261655 0.0363348365 2752.6126 + 35 -225.7806633001 0.812E-03 1.6286523468 0.0363300122 2880.8456 + 36 -225.7805899666 0.792E-03 1.6285493015 0.0363096493 3013.5094 + 38 -225.7804466570 0.758E-03 1.6272697796 0.0362911824 3114.5099 + 40 -225.7804618270 0.732E-03 1.6282610588 0.0362826462 3216.3007 + 41 -225.7805567596 0.720E-03 1.6290936006 0.0362995291 3282.7632 + 42 -225.7805193813 0.704E-03 1.6287024832 0.0362946001 3600.6314 + 43 -225.7804383229 0.692E-03 1.6280727328 0.0362794301 3706.2508 + 48 -225.7805689670 0.637E-03 1.6291239054 0.0363125340 4199.9676 + 58 -225.7806879539 0.579E-03 1.6301067396 0.0363236982 4202.0826 + 59 -225.7807197243 0.570E-03 1.6302803717 0.0363300619 4226.8476 + 60 -225.7806376123 0.566E-03 1.6293365655 0.0363253613 4266.5016 + 62 -225.7805569726 0.553E-03 1.6287141248 0.0363136081 4319.6086 + 63 -225.7805839209 0.519E-03 1.6287914668 0.0363155000 4359.9488 + 65 -225.7804444898 0.513E-03 1.6277456513 0.0362962387 4363.2997 + 67 -225.7805512421 0.504E-03 1.6283577843 0.0363164065 4556.6186 + 68 -225.7806198154 0.501E-03 1.6285888495 0.0363330325 4570.5719 + 69 -225.7806372182 0.494E-03 1.6289629197 0.0363324704 4655.4766 + 71 -225.7806598902 0.481E-03 1.6288819040 0.0363416188 4766.9587 + 73 -225.7805260968 0.480E-03 1.6281983958 0.0363152991 4951.3847 + 76 -225.7803847258 0.471E-03 1.6266727769 0.0363041203 4964.6056 + 77 -225.7802839419 0.475E-03 1.6260102861 0.0362858064 5028.2118 + 78 -225.7803524990 0.474E-03 1.6264604571 0.0362974407 5038.2248 + 79 -225.7802184581 0.487E-03 1.6251505909 0.0362839525 5083.4356 + 80 -225.7802030281 0.481E-03 1.6253169334 0.0362747694 5179.1366 + 81 -225.7801934550 0.475E-03 1.6254494728 0.0362687824 5267.8313 + 82 -225.7801945567 0.469E-03 1.6256840181 0.0362666432 5424.1806 + 84 -225.7802049164 0.470E-03 1.6254519962 0.0362762746 5452.5508 + 85 -225.7802954690 0.473E-03 1.6262666102 0.0362856329 5548.7766 + 86 -225.7803203325 0.468E-03 1.6264949088 0.0362877489 5847.0894 + 93 -225.7803439669 0.418E-03 1.6264098173 0.0362946071 5950.1167 + 94 -225.7804113014 0.419E-03 1.6267791207 0.0363086163 5956.4491 + 96 -225.7804124394 0.414E-03 1.6266340450 0.0363107377 6040.8046 + 97 -225.7804300986 0.411E-03 1.6267674266 0.0363133403 6163.0176 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 12.560425 GB ] [ VIRT MEM : 15.922138 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12788.877915 s ] [ CPU TIME: 911336.673492 s ] <<<<< .. + +* Number of generators 655358 + +.. >>>>> [ RES MEM : 12.560425 GB ] [ VIRT MEM : 15.922138 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12788.879805 s ] [ CPU TIME: 911336.809475 s ] <<<<< .. + +* Number of selectors 655358 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7528644752234588 + +Summary at N_det = 655360 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.55561816 +# PT2 -0.22480411 0.00039485 +# rPT2 -0.21692694 0.00038102 +# +# E+PT2 -225.78042227 0.00039485 +# E+rPT2 -225.77254511 0.00038102 +# ============ ============================= + + N_det = 655360 + N_states = 1 + + * State 1 + < S^2 > = 1.260768926699831E-002 + E = -225.555618163709 + Variance = 1.62663383792052 + PT norm = 0.190558484981712 + PT2 = -0.224804110740941 + rPT2 = -0.216926943261328 + E+PT2 = -225.780422274450 +/- 3.948536473246849E-004 + E+rPT2 = -225.772545106970 +/- 3.810179203014517E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.029327678811 + Vee = 238.794544236560 + Vecp = 0.000000000000000E+000 + T = 225.174815557478 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2756 -225.80643659 + -0.3383 -225.81242294 + -0.3991 -225.81951256 + -0.4594 -225.82165402 + -0.5123 -225.82372976 + -0.5583 -225.82515444 + -0.5969 -225.82656325 + =========== =================== + +* Number of unique beta determinants 153699 +* Number of unique alpha determinants 153714 + +.. >>>>> [ RES MEM : 12.791058 GB ] [ VIRT MEM : 16.167362 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13050.955931 s ] [ CPU TIME: 929451.204857 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 1310720 +* Number of threads for diagonalization 72 +* Memory(Gb) 2.357419144362211 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.5556182055 0.012608 0.852E-02 + 2 -225.6074502765 0.005791 0.357E-03 + 3 -225.6077759043 0.005660 0.219E-04 + 4 -225.6078180071 0.005652 0.523E-06 + 5 -225.6078192715 0.005649 0.209E-07 + 6 -225.6078193201 0.005648 0.883E-09 + 7 -225.6078193222 0.005648 0.351E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 13.996540 GB ] [ VIRT MEM : 17.782135 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 14844.474398 s ] [ CPU TIME: 1053168.795296 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 12.942028 GB ] [ VIRT MEM : 16.315815 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 14844.616134 s ] [ CPU TIME: 1053175.598934 s ] <<<<< .. + +* Energy of state 1 -225.6078193221949 +* S^2 of state 1 0.5647967247259337E-02 +* Saved determinants 1310720 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 12.712391 GB ] [ VIRT MEM : 16.083382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 14869.164098 s ] [ CPU TIME: 1053564.909726 s ] <<<<< .. + +* Number of generators 1310720 + +.. >>>>> [ RES MEM : 12.712391 GB ] [ VIRT MEM : 16.083382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 14869.167362 s ] [ CPU TIME: 1053565.144461 s ] <<<<< .. + +* Number of selectors 1310720 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 +* PT2 Energy denominator -225.6078193221949 + +.. >>>>> [ RES MEM : 13.062927 GB ] [ VIRT MEM : 16.436909 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 14870.022340 s ] [ CPU TIME: 1053616.405918 s ] <<<<< .. + +* Number of generators 1310720 + +.. >>>>> [ RES MEM : 13.062927 GB ] [ VIRT MEM : 16.436909 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 14870.025564 s ] [ CPU TIME: 1053616.637821 s ] <<<<< .. + +* Number of selectors 1310720 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 +* Number of tasks 3188239 +* Number of fragmented tasks 136339 +* Number of threads for PT2 72 +* Memory (Gb) 25.55140119194984 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.7888862952 0.392E-02 1.3717175722 0.0281189576 1492.8678 + 4 -225.7867793982 0.350E-02 1.3457798165 0.0279705144 1537.9419 + 5 -225.7847461048 0.344E-02 1.3316631777 0.0276479706 1723.6259 + 7 -225.7846868219 0.232E-02 1.3348025712 0.0275447889 1840.6469 + 8 -225.7840861055 0.209E-02 1.3264306956 0.0274990437 2171.0729 + 10 -225.7836049517 0.185E-02 1.3254012476 0.0273332500 2514.5730 + 12 -225.7837760053 0.152E-02 1.3278831416 0.0273272543 2667.4491 + 14 -225.7835987350 0.130E-02 1.3240444126 0.0273571543 3044.1534 + 15 -225.7831730443 0.129E-02 1.3218011398 0.0272610128 3101.3859 + 18 -225.7837195868 0.143E-02 1.3245850546 0.0273500700 3320.3900 + 19 -225.7834363103 0.139E-02 1.3213973124 0.0273257445 4679.5681 + 28 -225.7837862617 0.122E-02 1.3198223538 0.0274486797 5231.8689 + 29 -225.7838846406 0.118E-02 1.3211353789 0.0274534798 5828.0878 + 30 -225.7840068992 0.115E-02 1.3224043638 0.0274586934 6098.4530 + 39 -225.7841020925 0.978E-03 1.3201408321 0.0275379115 6396.0710 + 42 -225.7844383908 0.978E-03 1.3234795411 0.0275742372 7027.9541 + 48 -225.7840259622 0.885E-03 1.3207910393 0.0274861241 7364.6190 + 50 -225.7840254765 0.875E-03 1.3208727515 0.0274805557 8377.5580 + 58 -225.7844783124 0.804E-03 1.3251434555 0.0275374612 9454.1760 + 63 -225.7843924544 0.756E-03 1.3242787245 0.0275292922 9611.5850 + 68 -225.7842448798 0.713E-03 1.3236625982 0.0274966769 9713.4109 + 69 -225.7842626820 0.703E-03 1.3238669611 0.0274996822 10724.0329 + 78 -225.7847345357 0.607E-03 1.3269576169 0.0275790419 10976.2799 + 86 -225.7847823230 0.564E-03 1.3272321330 0.0275875733 10981.0971 + 87 -225.7847544826 0.558E-03 1.3269155152 0.0275858632 11080.2422 + 89 -225.7846329295 0.554E-03 1.3257383678 0.0275704682 11187.2620 + 91 -225.7845784862 0.548E-03 1.3249661245 0.0275689661 11380.0790 + 92 -225.7846626384 0.549E-03 1.3255284780 0.0275823528 11574.0450 + 93 -225.7847439922 0.549E-03 1.3258452039 0.0275984908 12290.9470 + 98 -225.7849075337 0.523E-03 1.3275142128 0.0276177549 12789.9348 + 110 -225.7851140768 0.482E-03 1.3285032680 0.0276597786 13228.9463 + 113 -225.7851262760 0.470E-03 1.3288793703 0.0276608643 13506.6164 + 115 -225.7851716954 0.464E-03 1.3288762194 0.0276724049 13549.6451 + 118 -225.7851524713 0.446E-03 1.3290229098 0.0276638497 13611.2662 + 120 -225.7851397625 0.439E-03 1.3289624334 0.0276628405 13803.0942 + 122 -225.7852013340 0.434E-03 1.3289037653 0.0276825579 13927.9440 + 123 -225.7851813256 0.431E-03 1.3288888754 0.0276770789 14092.5359 + 124 -225.7851600273 0.428E-03 1.3288119833 0.0276721677 14247.6550 + 125 -225.7852254231 0.430E-03 1.3295245455 0.0276775561 15009.4497 + 126 -225.7852076800 0.427E-03 1.3296566148 0.0276693670 15469.9372 + 137 -225.7853553640 0.415E-03 1.3306738353 0.0276936362 15649.4500 + 142 -225.7853341679 0.406E-03 1.3305515277 0.0276886399 15882.8289 + 143 -225.7853379262 0.398E-03 1.3304290454 0.0276921991 15972.3430 + 145 -225.7852864644 0.397E-03 1.3301727059 0.0276793762 15981.4342 + 146 -225.7852727074 0.395E-03 1.3300221007 0.0276781855 16090.7762 + 147 -225.7852877552 0.392E-03 1.3300028349 0.0276821441 16266.5430 + 148 -225.7853142484 0.390E-03 1.3301786051 0.0276868838 16544.8572 + 151 -225.7853421445 0.383E-03 1.3305847922 0.0276877992 17189.2801 + 157 -225.7852865963 0.373E-03 1.3300045341 0.0276799050 17196.4831 + 158 -225.7852802030 0.371E-03 1.3298928282 0.0276801755 17227.3510 + 159 -225.7852110541 0.375E-03 1.3294145365 0.0276691232 17462.1632 + 160 -225.7851890144 0.374E-03 1.3293113941 0.0276656845 17997.4690 + 165 -225.7850992905 0.369E-03 1.3285492727 0.0276547175 19096.1188 + 181 -225.7850412901 0.341E-03 1.3275270850 0.0276559137 19146.3202 + 182 -225.7850870240 0.342E-03 1.3280125528 0.0276602837 19485.5945 + 186 -225.7850963051 0.339E-03 1.3280788719 0.0276624979 19501.7263 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 13.488407 GB ] [ VIRT MEM : 16.695782 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 34381.040771 s ] [ CPU TIME: 2453421.365914 s ] <<<<< .. + +* Number of generators 1310720 + +.. >>>>> [ RES MEM : 13.488407 GB ] [ VIRT MEM : 16.695782 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 34381.060651 s ] [ CPU TIME: 2453422.777977 s ] <<<<< .. + +* Number of selectors 1310720 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8051988553701166 + +Summary at N_det = 1310720 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.60781932 +# PT2 -0.17727698 0.00033867 +# rPT2 -0.17250506 0.00032955 +# +# E+PT2 -225.78509631 0.00033867 +# E+rPT2 -225.78032438 0.00032955 +# ============ ============================= + + N_det = 1310720 + N_states = 1 + + * State 1 + < S^2 > = 5.647967247259337E-003 + E = -225.607819322195 + Variance = 1.32807887186787 + PT norm = 0.166320467518718 + PT2 = -0.177276982870926 + rPT2 = -0.172505061954181 + E+PT2 = -225.785096305066 +/- 3.386663172012683E-004 + E+rPT2 = -225.780324384149 +/- 3.295501372173917E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.199326557628 + Vee = 238.813743326591 + Vecp = 0.000000000000000E+000 + T = 225.273414187778 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2169 -225.81053393 + -0.2756 -225.80842673 + -0.3383 -225.81122975 + -0.3991 -225.81604166 + -0.4594 -225.81819536 + -0.5123 -225.82019127 + -0.5583 -225.82165525 + =========== =================== + +* Number of unique beta determinants 347998 +* Number of unique alpha determinants 347990 + +.. >>>>> [ RES MEM : 14.147438 GB ] [ VIRT MEM : 17.475819 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 35541.501604 s ] [ CPU TIME: 2531512.619706 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 2621440 +* Number of threads for diagonalization 72 +* Memory(Gb) 4.878089603036642 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.6078193550 0.005648 0.411E-02 + 2 -225.6361354773 0.001383 0.102E-03 + 3 -225.6362665449 0.001352 0.130E-04 + 4 -225.6362843426 0.001352 0.465E-06 + 5 -225.6362853629 0.001358 0.240E-07 + 6 -225.6362854138 0.001358 0.916E-09 + 7 -225.6362854159 0.001358 0.378E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 16.934105 GB ] [ VIRT MEM : 21.079411 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 43693.004335 s ] [ CPU TIME: 3080700.505924 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 14.824913 GB ] [ VIRT MEM : 18.148247 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 43693.242677 s ] [ CPU TIME: 3080706.833869 s ] <<<<< .. + +* Energy of state 1 -225.6362854158591 +* S^2 of state 1 0.1358346564631423E-02 +* Saved determinants 2621440 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 13.605293 GB ] [ VIRT MEM : 16.913090 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 43742.412885 s ] [ CPU TIME: 3081435.056027 s ] <<<<< .. + +* Number of generators 2621435 + +.. >>>>> [ RES MEM : 13.605293 GB ] [ VIRT MEM : 16.913090 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 43742.418981 s ] [ CPU TIME: 3081435.494047 s ] <<<<< .. + +* Number of selectors 2621435 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 +* PT2 Energy denominator -225.6362854158591 + +.. >>>>> [ RES MEM : 14.280048 GB ] [ VIRT MEM : 17.590164 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 43744.258376 s ] [ CPU TIME: 3081518.020206 s ] <<<<< .. + +* Number of generators 2621435 + +.. >>>>> [ RES MEM : 14.280048 GB ] [ VIRT MEM : 17.590164 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 43744.264124 s ] [ CPU TIME: 3081518.025882 s ] <<<<< .. + +* Number of selectors 2621435 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 +* Number of tasks 6104059 +* Number of fragmented tasks 156807 +* Number of threads for PT2 72 +* Memory (Gb) 51.07999801803381 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.7829025257 0.310E-02 1.1109880510 0.0227078615 3954.4781 + 5 -225.7864335349 0.280E-02 1.1413404546 0.0231855840 4927.7458 + 8 -225.7891904844 0.250E-02 1.1588886710 0.0236600659 5127.5670 + 10 -225.7883274834 0.201E-02 1.1487479191 0.0235654428 5339.5749 + 11 -225.7876982637 0.192E-02 1.1411051575 0.0235098510 5456.8767 + 12 -225.7880580128 0.179E-02 1.1473706443 0.0234954353 6925.5029 + 16 -225.7879844760 0.152E-02 1.1463417638 0.0234875458 7470.6946 + 18 -225.7878476651 0.137E-02 1.1457657243 0.0234800793 7492.5269 + 19 -225.7872598678 0.142E-02 1.1415092786 0.0234008941 7987.8191 + 20 -225.7872113075 0.135E-02 1.1428731157 0.0233624121 8180.4513 + 22 -225.7872145856 0.123E-02 1.1423918165 0.0233727863 9453.5469 + 25 -225.7867889819 0.115E-02 1.1377340271 0.0233343066 9469.8107 + 26 -225.7867173364 0.110E-02 1.1373309565 0.0233221982 9866.0430 + 27 -225.7864238276 0.110E-02 1.1343676256 0.0232892528 9883.7019 + 28 -225.7865624613 0.107E-02 1.1361428188 0.0232992959 10479.1459 + 29 -225.7863361483 0.106E-02 1.1342995223 0.0232688620 10729.3200 + 30 -225.7863584420 0.102E-02 1.1344012106 0.0232770026 10869.4380 + 31 -225.7861047901 0.102E-02 1.1322619657 0.0232437116 11336.9989 + 32 -225.7861270669 0.989E-03 1.1319696096 0.0232523184 11575.6769 + 33 -225.7860622808 0.100E-02 1.1306553570 0.0232628782 12535.8286 + 37 -225.7862331742 0.923E-03 1.1336832096 0.0232607034 12740.5129 + 38 -225.7862415680 0.898E-03 1.1337996786 0.0232570348 13193.4959 + 40 -225.7864773026 0.868E-03 1.1356911494 0.0232912170 14067.7918 + 42 -225.7863952798 0.828E-03 1.1349216385 0.0232794192 14075.8301 + 43 -225.7864662621 0.812E-03 1.1360233134 0.0232804197 16026.5349 + 48 -225.7866654564 0.769E-03 1.1367215169 0.0233157852 16068.6998 + 50 -225.7866939824 0.780E-03 1.1364122922 0.0233373630 16407.9079 + 51 -225.7867559811 0.767E-03 1.1368055117 0.0233466083 16646.5228 + 52 -225.7865376592 0.783E-03 1.1347070928 0.0233225450 16756.0919 + 53 -225.7866331095 0.774E-03 1.1353124561 0.0233404092 17050.0910 + 54 -225.7865246903 0.768E-03 1.1345266975 0.0233237780 17205.2899 + 55 -225.7865302651 0.753E-03 1.1348028427 0.0233172362 17575.7530 + 56 -225.7866626966 0.752E-03 1.1359497434 0.0233362413 17814.1936 + 58 -225.7866472453 0.742E-03 1.1352614825 0.0233396215 18409.4081 + 61 -225.7867185640 0.707E-03 1.1356390409 0.0233538457 18685.1036 + 62 -225.7866639056 0.698E-03 1.1353585143 0.0233445570 19007.8879 + 63 -225.7866977526 0.688E-03 1.1356171518 0.0233495237 19496.4279 + 65 -225.7867356972 0.667E-03 1.1361718908 0.0233516432 19996.9595 + 67 -225.7868809735 0.655E-03 1.1370498990 0.0233787751 21232.9687 + 73 -225.7870449182 0.621E-03 1.1393708560 0.0233860513 21742.2229 + 76 -225.7871471066 0.599E-03 1.1401277028 0.0233989150 21744.4801 + 77 -225.7871666824 0.592E-03 1.1402983135 0.0234009816 22257.0799 + 78 -225.7871736619 0.584E-03 1.1401466047 0.0234055812 22606.8129 + 80 -225.7870749946 0.554E-03 1.1396418618 0.0233883906 23000.8541 + 81 -225.7869861448 0.555E-03 1.1390937973 0.0233703754 24296.7179 + 85 -225.7870158921 0.530E-03 1.1389201965 0.0233814611 25264.0155 + 89 -225.7870222627 0.522E-03 1.1389590645 0.0233814684 25546.4579 + 92 -225.7868899793 0.511E-03 1.1382941696 0.0233554879 25650.6999 + 95 -225.7869407809 0.498E-03 1.1390590144 0.0233611305 25834.3909 + 96 -225.7868737950 0.498E-03 1.1382181268 0.0233569287 26514.5679 + 97 -225.7868497211 0.493E-03 1.1376432444 0.0233582825 26618.7929 + 98 -225.7868086006 0.490E-03 1.1370785638 0.0233548063 27004.0771 + 100 -225.7868587154 0.457E-03 1.1380763142 0.0233485969 27162.2029 + 101 -225.7868817686 0.453E-03 1.1384133915 0.0233498210 29343.5567 + 109 -225.7869200301 0.425E-03 1.1378530084 0.0233696206 30386.8520 + 117 -225.7869290930 0.402E-03 1.1379547576 0.0233664435 32481.6058 + 119 -225.7869468247 0.399E-03 1.1381167859 0.0233675613 32698.9643 + 125 -225.7870587499 0.388E-03 1.1396975427 0.0233735880 33388.5348 + 133 -225.7872000037 0.372E-03 1.1402478376 0.0234012120 33742.2099 + 135 -225.7871868794 0.367E-03 1.1402032705 0.0233979442 33978.5807 + 136 -225.7872166098 0.365E-03 1.1402574471 0.0234053886 34313.7860 + 137 -225.7872203138 0.362E-03 1.1404618479 0.0234037598 37317.8140 + 145 -225.7872419385 0.356E-03 1.1408053823 0.0234036180 37697.2140 + 149 -225.7872424451 0.348E-03 1.1405545163 0.0234064017 37823.2878 + 152 -225.7873610196 0.344E-03 1.1412812618 0.0234261734 39401.9352 + 157 -225.7872860488 0.344E-03 1.1406937717 0.0234138576 40286.5099 + 159 -225.7871908366 0.346E-03 1.1396084862 0.0234051933 41297.5522 + 170 -225.7871780927 0.345E-03 1.1395416853 0.0234036883 41587.6510 + 171 -225.7871680609 0.343E-03 1.1394583802 0.0234027374 42571.7759 + 174 -225.7871136121 0.338E-03 1.1390114299 0.0233946733 42917.2559 + 179 -225.7870390874 0.323E-03 1.1385301358 0.0233799763 44658.7266 + 189 -225.7870775437 0.311E-03 1.1383290075 0.0233917800 44939.3221 + 190 -225.7870318428 0.312E-03 1.1379375611 0.0233862809 45065.3770 + 192 -225.7870052695 0.310E-03 1.1377513085 0.0233814225 45076.6759 + 193 -225.7870302102 0.309E-03 1.1378173116 0.0233869065 45672.3606 + 194 -225.7869957362 0.310E-03 1.1375816737 0.0233807222 45856.5651 + 195 -225.7870082208 0.308E-03 1.1376920377 0.0233823707 45912.8489 + 197 -225.7870080059 0.305E-03 1.1375910559 0.0233840042 47532.8399 + 205 -225.7870795473 0.291E-03 1.1384112602 0.0233885641 48059.8558 + 206 -225.7870694549 0.290E-03 1.1383453570 0.0233867252 48080.6350 + 208 -225.7870531631 0.287E-03 1.1385118685 0.0233803188 48240.4549 + 213 -225.7870644746 0.281E-03 1.1383358779 0.0233864773 48653.8593 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 14.801929 GB ] [ VIRT MEM : 18.151520 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 92416.465204 s ] [ CPU TIME: 6565114.136250 s ] <<<<< .. + +* Number of generators 2621435 + +.. >>>>> [ RES MEM : 14.801929 GB ] [ VIRT MEM : 18.151520 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 92416.471397 s ] [ CPU TIME: 6565114.141974 s ] <<<<< .. + +* Number of selectors 2621435 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8342405441933214 + +Summary at N_det = 2621440 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.63628542 +# PT2 -0.15077906 0.00028092 +# rPT2 -0.14733345 0.00027450 +# +# E+PT2 -225.78706447 0.00028092 +# E+rPT2 -225.78361886 0.00027450 +# ============ ============================= + + N_det = 2621440 + N_states = 1 + + * State 1 + < S^2 > = 1.358346564631423E-003 + E = -225.636285415859 + Variance = 1.13833587793073 + PT norm = 0.152926378694488 + PT2 = -0.150779058743803 + rPT2 = -0.147333448397240 + E+PT2 = -225.787064474603 +/- 2.809221382940737E-004 + E+rPT2 = -225.783618864256 +/- 2.745024919960472E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.297497898367 + Vee = 238.825608110899 + Vecp = 0.000000000000000E+000 + T = 225.331254650545 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1725 -225.80290198 + -0.2169 -225.80762823 + -0.2756 -225.80748525 + -0.3383 -225.80978977 + -0.3991 -225.81366312 + -0.4594 -225.81570691 + -0.5123 -225.81757574 + =========== =================== + +* Number of unique beta determinants 708882 +* Number of unique alpha determinants 695600 + +.. >>>>> [ RES MEM : 17.336609 GB ] [ VIRT MEM : 21.054424 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 96017.605899 s ] [ CPU TIME: 6800923.617658 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5242880 +* Number of threads for diagonalization 72 +* Memory(Gb) 9.807945977896452 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.6362854183 0.001358 0.115E-02 + 2 -225.6431548438 0.001440 0.811E-04 + 3 -225.6432589465 0.001461 0.931E-05 + 4 -225.6432801721 0.001517 0.278E-05 + 5 -225.6432843223 0.001529 0.136E-06 + 6 -225.6432845704 0.001528 0.833E-08 + 7 -225.6432845922 0.001526 0.405E-09 + 8 -225.6432845932 0.001526 0.220E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 22.301079 GB ] [ VIRT MEM : 27.428501 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 125034.424143 s ] [ CPU TIME: 8702247.647536 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 17.691833 GB ] [ VIRT MEM : 21.410908 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 125034.937174 s ] [ CPU TIME: 8702254.250004 s ] <<<<< .. + +* Energy of state 1 -225.6432845931686 +* S^2 of state 1 0.1526496152807629E-02 +* Saved determinants 5242880 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.012989 GB ] [ VIRT MEM : 19.488235 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 125134.065439 s ] [ CPU TIME: 8703653.943516 s ] <<<<< .. + +* Number of generators 5242848 + +.. >>>>> [ RES MEM : 16.012989 GB ] [ VIRT MEM : 19.488235 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 125134.077690 s ] [ CPU TIME: 8703654.823595 s ] <<<<< .. + +* Number of selectors 5242848 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 +* PT2 Energy denominator -225.6432845931686 + +.. >>>>> [ RES MEM : 17.526997 GB ] [ VIRT MEM : 21.004673 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 125138.705289 s ] [ CPU TIME: 8703839.575913 s ] <<<<< .. + +* Number of generators 5242848 + +.. >>>>> [ RES MEM : 17.526997 GB ] [ VIRT MEM : 21.004673 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 125138.717052 s ] [ CPU TIME: 8703839.587593 s ] <<<<< .. + +* Number of selectors 5242848 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 +* Number of tasks 10890421 +* Number of fragmented tasks 161314 +* Number of threads for PT2 72 +* Memory (Gb) 102.1371912097931 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.7836246145 0.119E-02 1.0588117933 0.0217142488 5576.1026 + 4 -225.7849192352 0.163E-02 1.0689374579 0.0219128426 6976.6515 + 6 -225.7863210348 0.141E-02 1.0847918155 0.0220233539 7714.7219 + 8 -225.7857721971 0.130E-02 1.0784875710 0.0219348918 8377.3726 + 9 -225.7855406963 0.119E-02 1.0788015588 0.0218960908 10774.7698 + 10 -225.7851565963 0.113E-02 1.0765942107 0.0218241867 11924.5325 + 13 -225.7851151773 0.104E-02 1.0821389961 0.0217827551 13752.5857 + 18 -225.7847799547 0.934E-03 1.0782113373 0.0217838431 18036.1224 + 23 -225.7851776758 0.819E-03 1.0812363723 0.0218296662 18043.7006 + 25 -225.7855030060 0.786E-03 1.0813619853 0.0219099481 18273.3326 + 26 -225.7856324300 0.766E-03 1.0824444273 0.0219237350 19384.5336 + 27 -225.7857172526 0.741E-03 1.0822394587 0.0219473398 19610.0935 + 28 -225.7855794969 0.728E-03 1.0813748142 0.0219233502 21370.6129 + 30 -225.7856775377 0.739E-03 1.0807076308 0.0219619695 22063.3315 + 31 -225.7857397542 0.717E-03 1.0811482827 0.0219689678 22281.0560 + 32 -225.7857929264 0.696E-03 1.0814702815 0.0219750748 23259.4035 + 33 -225.7858285463 0.675E-03 1.0819676848 0.0219730736 23289.1166 + 34 -225.7858302130 0.655E-03 1.0831721509 0.0219553836 24047.4471 + 35 -225.7859779994 0.653E-03 1.0831162851 0.0219947824 24863.5627 + 36 -225.7860631470 0.640E-03 1.0838773988 0.0220098877 25444.3416 + 37 -225.7858886761 0.647E-03 1.0825851694 0.0219791442 26940.4744 + 38 -225.7858869370 0.630E-03 1.0822035534 0.0219842611 28329.4285 + 42 -225.7863179862 0.613E-03 1.0873244349 0.0220210915 28507.5283 + 43 -225.7862997116 0.598E-03 1.0868103523 0.0220248876 29831.9026 + 45 -225.7861726401 0.580E-03 1.0864292913 0.0219902302 29986.8386 + 46 -225.7859965201 0.595E-03 1.0854356439 0.0219632591 30293.4590 + 47 -225.7860565625 0.585E-03 1.0857395383 0.0219750512 30858.3504 + 48 -225.7862399211 0.555E-03 1.0872309125 0.0220006559 31392.3386 + 49 -225.7862388767 0.544E-03 1.0869340062 0.0220024969 32346.3886 + 50 -225.7861535361 0.539E-03 1.0859533251 0.0219958632 32503.3536 + 51 -225.7862637769 0.540E-03 1.0868769715 0.0220079288 33567.7616 + 52 -225.7861917156 0.535E-03 1.0863815902 0.0219941544 33840.0209 + 53 -225.7861154659 0.530E-03 1.0856795611 0.0219860274 34146.2686 + 54 -225.7860998824 0.520E-03 1.0851343911 0.0219881915 34863.7145 + 55 -225.7862860947 0.544E-03 1.0862341993 0.0220239186 35332.0936 + 56 -225.7861865189 0.543E-03 1.0853081119 0.0220133204 35468.9364 + 57 -225.7862059768 0.534E-03 1.0847597915 0.0220258259 36090.4126 + 58 -225.7861930649 0.525E-03 1.0842250480 0.0220288581 36485.9597 + 59 -225.7862418831 0.518E-03 1.0846816287 0.0220320167 39380.3094 + 65 -225.7863613675 0.483E-03 1.0855724043 0.0220523441 40047.1335 + 68 -225.7865313990 0.483E-03 1.0873103213 0.0220733586 40238.1446 + 69 -225.7866093968 0.483E-03 1.0879433548 0.0220844394 41098.4153 + 70 -225.7865525268 0.479E-03 1.0875860857 0.0220760311 41270.2236 + 71 -225.7865414836 0.472E-03 1.0876185175 0.0220709232 42217.8286 + 72 -225.7867012034 0.489E-03 1.0888322760 0.0220960129 42819.8037 + 74 -225.7867984209 0.482E-03 1.0891597245 0.0221174211 43376.9695 + 76 -225.7868105580 0.472E-03 1.0896651717 0.0221126774 43826.6867 + 77 -225.7868070824 0.466E-03 1.0894114028 0.0221154258 44590.6708 + 78 -225.7868920686 0.468E-03 1.0908395876 0.0221190754 47471.1644 + 83 -225.7868281137 0.454E-03 1.0898771426 0.0221219801 50297.3456 + 85 -225.7869221465 0.454E-03 1.0909340287 0.0221314840 50492.7058 + 88 -225.7869950751 0.448E-03 1.0913801438 0.0221438948 50703.5125 + 91 -225.7870441269 0.435E-03 1.0914370784 0.0221527156 50975.0696 + 92 -225.7870230051 0.431E-03 1.0911281814 0.0221522986 51083.1237 + 93 -225.7870813751 0.430E-03 1.0914929110 0.0221612829 51772.3895 + 94 -225.7871029044 0.426E-03 1.0918756828 0.0221601424 51827.9167 + 95 -225.7871514090 0.424E-03 1.0921966115 0.0221673587 56182.6755 + 104 -225.7873942485 0.382E-03 1.0941557425 0.0222059270 56212.1032 + 105 -225.7874318819 0.380E-03 1.0944897749 0.0222112818 56698.4246 + 107 -225.7874625773 0.381E-03 1.0948464624 0.0222145906 58242.6391 + 109 -225.7874690247 0.375E-03 1.0949160896 0.0222171272 60199.3114 + 114 -225.7876531659 0.375E-03 1.0972083944 0.0222307755 62730.0025 + 115 -225.7877126569 0.376E-03 1.0977989927 0.0222377068 63514.1324 + 123 -225.7876497471 0.362E-03 1.0967908934 0.0222412593 63641.1936 + 124 -225.7875061102 0.357E-03 1.0957227668 0.0222189452 64854.0714 + 125 -225.7875429765 0.356E-03 1.0961193571 0.0222232125 68401.7195 + 135 -225.7874058454 0.339E-03 1.0946944598 0.0222099045 71221.1445 + 142 -225.7874319405 0.328E-03 1.0950523368 0.0222082701 75345.1045 + 149 -225.7874930911 0.327E-03 1.0955882681 0.0222126846 76985.4556 + 154 -225.7875054189 0.319E-03 1.0956366539 0.0222135041 79181.2596 + 160 -225.7874317150 0.314E-03 1.0945905445 0.0222108830 79551.3064 + 161 -225.7874299953 0.312E-03 1.0944854227 0.0222122428 79676.6245 + 162 -225.7874243663 0.310E-03 1.0944847412 0.0222110588 80221.3486 + 163 -225.7874912006 0.315E-03 1.0950772641 0.0222201975 80826.6436 + 164 -225.7875165256 0.314E-03 1.0955846755 0.0222189661 83624.6222 + 165 -225.7875436182 0.314E-03 1.0957577834 0.0222232208 86216.7729 + 177 -225.7877021374 0.302E-03 1.0974117684 0.0222370492 87321.9706 + 178 -225.7877027732 0.300E-03 1.0973751201 0.0222374008 87467.7956 + 180 -225.7877009401 0.297E-03 1.0970878469 0.0222410875 89014.7952 + 184 -225.7877229822 0.294E-03 1.0971568857 0.0222455659 91834.2844 + 187 -225.7877266719 0.289E-03 1.0972674801 0.0222441512 92812.6718 + 195 -225.7878483372 0.280E-03 1.0982041506 0.0222594992 93142.7555 + 196 -225.7878586735 0.279E-03 1.0982308770 0.0222616985 93181.9676 + 197 -225.7878575463 0.278E-03 1.0983520337 0.0222593329 96447.9705 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 18.895157 GB ] [ VIRT MEM : 22.380325 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 221620.840997 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 5242848 + +.. >>>>> [ RES MEM : 18.895157 GB ] [ VIRT MEM : 22.380325 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 221620.852704 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 5242848 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8410830034898520 + +Summary at N_det = 5242880 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.64328459 +# PT2 -0.14457295 0.00027771 +# rPT2 -0.14142493 0.00027166 +# +# E+PT2 -225.78785755 0.00027771 +# E+rPT2 -225.78470952 0.00027166 +# ============ ============================= + + N_det = 5242880 + N_states = 1 + + * State 1 + < S^2 > = 1.526496152807629E-003 + E = -225.643284593169 + Variance = 1.09835203370170 + PT norm = 0.149195619594891 + PT2 = -0.144572953145833 + rPT2 = -0.141424928579335 + E+PT2 = -225.787857546314 +/- 2.777087441298779E-004 + E+rPT2 = -225.784709521748 +/- 2.716617351297213E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.319034392655 + Vee = 238.825551612302 + Vecp = 0.000000000000000E+000 + T = 225.345848466120 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1473 -225.81081524 + -0.1725 -225.80411196 + -0.2169 -225.80738005 + -0.2756 -225.80736065 + -0.3383 -225.80932427 + -0.3991 -225.81265619 + -0.4594 -225.81452168 + =========== =================== + +* Number of unique beta determinants 1099100 +* Number of unique alpha determinants 1071064 + +.. >>>>> [ RES MEM : 23.840626 GB ] [ VIRT MEM : 28.502472 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 228876.628519 s ] [ CPU TIME: ************** s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 10485760 +* Number of threads for diagonalization 72 +* Memory(Gb) 18.33249400928617 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.6432845968 0.001526 0.884E-03 + 2 -225.6472831717 0.002883 0.946E-04 + 3 -225.6473892257 0.002960 0.129E-04 + 4 -225.6474098043 0.003022 0.145E-05 + 5 -225.6474131350 0.003054 0.152E-06 + 6 -225.6474134484 0.003053 0.129E-07 + 7 -225.6474134811 0.003052 0.148E-08 + 8 -225.6474134844 0.003052 0.122E-09 + 9 -225.6474134847 0.003052 0.130E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 33.529392 GB ] [ VIRT MEM : 40.535690 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 293712.568045 s ] [ CPU TIME: ************** s ] <<<<< .. + + +.. >>>>> [ RES MEM : 23.842022 GB ] [ VIRT MEM : 28.502472 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 293713.572995 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Energy of state 1 -225.6474134846838 +* S^2 of state 1 0.3051715035100827E-02 +* Saved determinants 10485760 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 20.701801 GB ] [ VIRT MEM : 24.179825 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 293915.260251 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 10485695 + +.. >>>>> [ RES MEM : 20.701801 GB ] [ VIRT MEM : 24.179825 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 293915.283263 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 10485695 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -225.6474134846838 + +.. >>>>> [ RES MEM : 22.287121 GB ] [ VIRT MEM : 25.763145 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 293924.768359 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 10485695 + +.. >>>>> [ RES MEM : 22.287121 GB ] [ VIRT MEM : 25.763145 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 293924.790329 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 10485695 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 17050633 +* Number of fragmented tasks 163148 +* Number of threads for PT2 72 +* Memory (Gb) 202.8302133331075 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.7895353935 0.215E-02 1.1044357326 0.0215269916 6369.7251 + 4 -225.7891203349 0.151E-02 1.1023051357 0.0213977643 7727.5862 + 5 -225.7878418460 0.174E-02 1.0940633740 0.0211601960 8729.3040 + 6 -225.7877849884 0.140E-02 1.0889917897 0.0212080410 9789.4891 + 7 -225.7889562457 0.170E-02 1.0991527390 0.0213574510 10960.6669 + 8 -225.7890746303 0.147E-02 1.0998151653 0.0213568753 12126.9629 + 9 -225.7890593886 0.126E-02 1.1017761035 0.0213176813 13136.7680 + 10 -225.7886286815 0.121E-02 1.0965133975 0.0212790149 14473.9612 + 11 -225.7889651963 0.114E-02 1.0954432000 0.0214025342 14747.6320 + 12 -225.7892841656 0.109E-02 1.0947802984 0.0215002916 15912.3339 + 13 -225.7893635330 0.100E-02 1.0942131635 0.0215224602 16880.6382 + 14 -225.7897670064 0.985E-03 1.0985769877 0.0215760059 18868.1717 + 15 -225.7892585678 0.105E-02 1.0928629204 0.0215393664 20758.3799 + 16 -225.7890895948 0.997E-03 1.0928316173 0.0214896030 21948.2811 + 18 -225.7894172360 0.109E-02 1.0923637470 0.0215716763 22765.4930 + 19 -225.7896342637 0.106E-02 1.0957377444 0.0215719258 22915.5812 + 20 -225.7894781637 0.101E-02 1.0938474944 0.0215563933 23740.0387 + 21 -225.7901463250 0.118E-02 1.0992140242 0.0216477086 24485.0750 + 22 -225.7904136485 0.116E-02 1.1028329884 0.0216832349 25492.4629 + 23 -225.7904123119 0.110E-02 1.1028274100 0.0216839903 26126.8155 + 24 -225.7901456376 0.109E-02 1.0998797726 0.0216572869 26971.6201 + 25 -225.7903071171 0.101E-02 1.1007012424 0.0216909564 27875.3879 + 26 -225.7903557405 0.969E-03 1.1017794211 0.0216814695 28916.5431 + 27 -225.7905348274 0.949E-03 1.1027866845 0.0217130304 29953.7809 + 28 -225.7905034439 0.915E-03 1.1026085045 0.0217044620 31026.5457 + 29 -225.7907471515 0.916E-03 1.1042348580 0.0217451343 33599.0462 + 31 -225.7908956694 0.871E-03 1.1052100757 0.0217613115 35386.1749 + 33 -225.7906863125 0.830E-03 1.1027862832 0.0217402167 35750.0362 + 34 -225.7906939701 0.805E-03 1.1036738597 0.0217312541 36718.9227 + 35 -225.7908287952 0.793E-03 1.1039520739 0.0217592054 37519.8033 + 36 -225.7909956985 0.789E-03 1.1048354692 0.0217922305 38504.2312 + 37 -225.7908365885 0.783E-03 1.1031981811 0.0217732418 39152.6681 + 38 -225.7907733535 0.765E-03 1.1035507786 0.0217553350 39839.3739 + 39 -225.7907182434 0.747E-03 1.1034564561 0.0217461831 40571.7471 + 40 -225.7907276456 0.728E-03 1.1035245420 0.0217467893 41728.3986 + 41 -225.7905970256 0.722E-03 1.1022117345 0.0217302523 42358.5633 + 42 -225.7905815029 0.705E-03 1.1021371894 0.0217230678 45351.2549 + 45 -225.7903455000 0.705E-03 1.0997642031 0.0216858325 45803.6442 + 46 -225.7903724348 0.690E-03 1.1002615569 0.0216860505 46014.7193 + 47 -225.7904793702 0.684E-03 1.1009578855 0.0217001437 47111.9331 + 48 -225.7905228747 0.671E-03 1.1010732818 0.0217068682 47780.6371 + 49 -225.7903355078 0.683E-03 1.0994702285 0.0216824988 48545.0892 + 50 -225.7903308910 0.670E-03 1.0990374071 0.0216883956 49803.2549 + 51 -225.7902062667 0.668E-03 1.0979679878 0.0216694790 50436.6273 + 52 -225.7900502322 0.674E-03 1.0966516011 0.0216508336 53407.2010 + 55 -225.7901050580 0.639E-03 1.0966511920 0.0216664518 53516.0855 + 56 -225.7901921605 0.633E-03 1.0980524772 0.0216712115 56953.7230 + 58 -225.7900431645 0.620E-03 1.0969381872 0.0216523010 58339.1582 + 61 -225.7899263241 0.603E-03 1.0964928884 0.0216327897 59864.7081 + 67 -225.7899597125 0.553E-03 1.0958258426 0.0216554288 59931.5040 + 68 -225.7899096936 0.547E-03 1.0956337164 0.0216471371 60775.5990 + 69 -225.7898822598 0.539E-03 1.0952495242 0.0216454737 61702.1329 + 70 -225.7897879130 0.540E-03 1.0942239065 0.0216350429 62054.0781 + 71 -225.7897453428 0.534E-03 1.0939154153 0.0216289850 63004.9308 + 73 -225.7896316969 0.530E-03 1.0933388790 0.0216064769 63674.5875 + 74 -225.7895903064 0.525E-03 1.0932523108 0.0215942470 64744.4371 + 75 -225.7895375707 0.520E-03 1.0924463121 0.0215929768 65033.3470 + 76 -225.7896698801 0.530E-03 1.0937752294 0.0216097728 65708.9779 + 77 -225.7896662955 0.523E-03 1.0937883718 0.0216093975 66706.4295 + 78 -225.7897319826 0.521E-03 1.0946165159 0.0216147028 67569.9492 + 79 -225.7896971934 0.515E-03 1.0941126239 0.0216148230 67782.7131 + 80 -225.7896888243 0.509E-03 1.0939855282 0.0216118405 68876.3820 + 81 -225.7896381771 0.505E-03 1.0937482707 0.0216019015 69551.6361 + 82 -225.7895814050 0.502E-03 1.0933192514 0.0215924006 71835.4929 + 85 -225.7898205098 0.504E-03 1.0952514800 0.0216270680 71899.9286 + 86 -225.7899270251 0.510E-03 1.0962669265 0.0216373529 74034.4654 + 89 -225.7897463385 0.475E-03 1.0945497009 0.0216145163 74511.6170 + 90 -225.7896901790 0.473E-03 1.0939496444 0.0216090849 74655.9094 + 91 -225.7896643159 0.469E-03 1.0941831041 0.0216003776 75689.1111 + 92 -225.7897243301 0.467E-03 1.0940932527 0.0216205196 76434.8034 + 93 -225.7896360264 0.471E-03 1.0932973751 0.0216118038 78595.2542 + 96 -225.7895231908 0.464E-03 1.0922648377 0.0215973462 78826.5042 + 97 -225.7895817500 0.463E-03 1.0933513049 0.0216004352 79769.3605 + 98 -225.7895355140 0.461E-03 1.0928597931 0.0215942414 80103.1711 + 99 -225.7894920700 0.458E-03 1.0922804298 0.0215914935 80694.7430 + 100 -225.7894442748 0.456E-03 1.0918761531 0.0215856779 81274.2585 + 101 -225.7893591540 0.459E-03 1.0910087360 0.0215776724 81630.5244 + 102 -225.7893105495 0.457E-03 1.0905220413 0.0215719446 82149.5817 + 103 -225.7892524303 0.457E-03 1.0899792850 0.0215650979 86640.5581 + 105 -225.7893114708 0.451E-03 1.0903950015 0.0215708836 87027.6412 + 111 -225.7892889243 0.431E-03 1.0902514662 0.0215708697 87352.0650 + 112 -225.7893183288 0.428E-03 1.0910068154 0.0215680415 87691.0363 + 113 -225.7892357200 0.420E-03 1.0902391096 0.0215589236 88627.9677 + 114 -225.7892459368 0.417E-03 1.0902398344 0.0215613738 89510.1161 + 115 -225.7892722785 0.414E-03 1.0904938926 0.0215624400 90017.4300 + 116 -225.7892604690 0.410E-03 1.0905350436 0.0215591894 93380.5269 + 118 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1.0907359952 0.0215607444 ********** + 148 -225.7893395775 0.361E-03 1.0908626233 0.0215648635 ********** + 149 -225.7893216009 0.359E-03 1.0906256616 0.0215630954 ********** + 150 -225.7893106529 0.357E-03 1.0905219578 0.0215626255 ********** + 151 -225.7893007474 0.355E-03 1.0904711331 0.0215610139 ********** + 153 -225.7892937139 0.350E-03 1.0909059058 0.0215524464 ********** + 154 -225.7893255249 0.349E-03 1.0912889823 0.0215552407 ********** + 155 -225.7893145548 0.347E-03 1.0913499940 0.0215505049 ********** + 156 -225.7893028150 0.345E-03 1.0912196298 0.0215501472 ********** + 157 -225.7893578244 0.347E-03 1.0916441103 0.0215586268 ********** + 158 -225.7893599695 0.345E-03 1.0918868786 0.0215571311 ********** + 159 -225.7893450134 0.343E-03 1.0916759727 0.0215562276 ********** + 160 -225.7893371589 0.341E-03 1.0913739662 0.0215578944 ********** + 161 -225.7893626658 0.340E-03 1.0915611807 0.0215626765 ********** + 162 -225.7893278717 0.340E-03 1.0913791367 0.0215556161 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0.321E-03 1.0915584514 0.0215529137 ********** + 181 -225.7893573197 0.321E-03 1.0917313029 0.0215572703 ********** + 187 -225.7892714495 0.316E-03 1.0908748759 0.0215471993 ********** + 188 -225.7892675332 0.314E-03 1.0907365034 0.0215470575 ********** + 190 -225.7892292345 0.312E-03 1.0905626697 0.0215393703 ********** + 191 -225.7892753727 0.314E-03 1.0910025627 0.0215454731 ********** + 195 -225.7892926234 0.304E-03 1.0911460040 0.0215451180 ********** + 196 -225.7893136180 0.304E-03 1.0912860935 0.0215477029 ********** + 200 -225.7893472301 0.299E-03 1.0914553557 0.0215532756 ********** + 202 -225.7893562401 0.297E-03 1.0914120647 0.0215555773 ********** + 209 -225.7893082662 0.290E-03 1.0907334441 0.0215518860 ********** + 210 -225.7893109651 0.289E-03 1.0908009222 0.0215523158 ********** + 211 -225.7893207533 0.287E-03 1.0906914090 0.0215569641 ********** + 213 -225.7893063461 0.285E-03 1.0904371078 0.0215562248 ********** + 214 -225.7893059708 0.284E-03 1.0903428394 0.0215583540 ********** +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 24.676327 GB ] [ VIRT MEM : 28.178452 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 438306.903174 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 10485695 + +.. >>>>> [ RES MEM : 24.676327 GB ] [ VIRT MEM : 28.178452 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 438306.925969 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 10485695 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +Summary at N_det = 10485760 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.64741348 +# PT2 -0.14189249 0.00028372 +# rPT2 -0.13889807 0.00027773 +# +# E+PT2 -225.78930597 0.00028372 +# E+rPT2 -225.78631156 0.00027773 +# ============ ============================= + + N_det = 10485760 + N_states = 1 + + * State 1 + < S^2 > = 3.051715035100827E-003 + E = -225.647413484684 + Variance = 1.09034283936104 + PT norm = 0.146827633757645 + PT2 = -0.141892486072882 + rPT2 = -0.138898072256417 + E+PT2 = -225.789305970757 +/- 2.837224217907748E-004 + E+rPT2 = -225.786311556940 +/- 2.777349141829742E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.326214819076 + Vee = 238.821214687233 + Vecp = 0.000000000000000E+000 + T = 225.353236926096 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1414 -225.87437339 + -0.1473 -225.82697478 + -0.1725 -225.80769477 + -0.2169 -225.80864651 + -0.2756 -225.80814347 + -0.3383 -225.80970014 + -0.3991 -225.81259742 + =========== =================== + +Wall time: 121:48:29 + diff --git a/imidazole/cc-pvtz/imidazole.natorb.out b/imidazole/cc-pvtz/imidazole.natorb.out new file mode 100644 index 0000000..800c622 --- /dev/null +++ b/imidazole/cc-pvtz/imidazole.natorb.out @@ -0,0 +1,369 @@ +Date: 02/11/2020 12:59:59 +=============== +Quantum Package +=============== + +Git Commit: Fix space in size for EZFIO.cfg +Git Date : Fri Oct 16 14:24:01 2020 +0200 +Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b +EZFIO Dir : imidazole + + +Task server running : tcp://172.28.1.29:41279 +.. >>>>> [ IO READ: n_states ] <<<<< .. + +.. >>>>> [ RES MEM : 0.009010 GB ] [ VIRT MEM : 0.137966 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.047205 s ] [ CPU TIME: 0.020320 s ] <<<<< .. + +.. >>>>> [ IO READ: read_wf ] <<<<< .. + +.. >>>>> [ RES MEM : 0.009201 GB ] [ VIRT MEM : 0.137966 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.180566 s ] [ CPU TIME: 0.020864 s ] <<<<< .. + +.. >>>>> [ IO READ: elec_beta_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.009201 GB ] [ VIRT MEM : 0.137966 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.221508 s ] [ CPU TIME: 0.021975 s ] <<<<< .. + +.. >>>>> [ IO READ: elec_alpha_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.009201 GB ] [ VIRT MEM : 0.137966 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.222083 s ] [ CPU TIME: 0.022382 s ] <<<<< .. + +* mo_num 206 + Read mo_occ +.. >>>>> [ IO READ: mo_class ] <<<<< .. + +.. >>>>> [ RES MEM : 0.011093 GB ] [ VIRT MEM : 4.857162 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.443580 s ] [ CPU TIME: 4.410130 s ] <<<<< .. + +* Number of virtual MOs 0 + Virtual MOs: + +.. >>>>> [ IO READ: ao_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.011093 GB ] [ VIRT MEM : 4.857162 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.479949 s ] [ CPU TIME: 6.820228 s ] <<<<< .. + + Read mo_coef + * mo_label Canonical +* Number of determinants 10485760 +* Dimension of the psi arrays 10485760 +* N_int 4 + Read psi_det +* Number of unique beta determinants 1099100 +* Number of unique alpha determinants 1071064 + Read psi_coef 10485760 1 +.. >>>>> [ IO READ: weight_one_e_dm ] <<<<< .. + +.. >>>>> [ RES MEM : 3.822987 GB ] [ VIRT MEM : 8.758938 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 390.319755 s ] [ CPU TIME: 16646.038610 s ] <<<<< .. + +* Number of active MOs 201 +* Number of core MOs 5 +* Number of inactive MOs 0 + Core MOs: + 1 2 3 4 5 + Active MOs: + 6 7 8 9 10 11 + 12 13 14 15 16 17 + 18 19 20 21 22 23 + 24 25 26 27 28 29 + 30 31 32 33 34 35 + 36 37 38 39 40 41 + 42 43 44 45 46 47 + 48 49 50 51 52 53 + 54 55 56 57 58 59 + 60 61 62 63 64 65 + 66 67 68 69 70 71 + 72 73 74 75 76 77 + 78 79 80 81 82 83 + 84 85 86 87 88 89 + 90 91 92 93 94 95 + 96 97 98 99 100 101 + 102 103 104 105 106 107 + 108 109 110 111 112 113 + 114 115 116 117 118 119 + 120 121 122 123 124 125 + 126 127 128 129 130 131 + 132 133 134 135 136 137 + 138 139 140 141 142 143 + 144 145 146 147 148 149 + 150 151 152 153 154 155 + 156 157 158 159 160 161 + 162 163 164 165 166 167 + 168 169 170 171 172 173 + 174 175 176 177 178 179 + 180 181 182 183 184 185 + 186 187 188 189 190 191 + 192 193 194 195 196 197 + 198 199 200 201 202 203 + 204 205 206 + Core, Inactive and Active MOs: + 1 2 3 4 5 6 + 7 8 9 10 11 12 + 13 14 15 16 17 18 + 19 20 21 22 23 24 + 25 26 27 28 29 30 + 31 32 33 34 35 36 + 37 38 39 40 41 42 + 43 44 45 46 47 48 + 49 50 51 52 53 54 + 55 56 57 58 59 60 + 61 62 63 64 65 66 + 67 68 69 70 71 72 + 73 74 75 76 77 78 + 79 80 81 82 83 84 + 85 86 87 88 89 90 + 91 92 93 94 95 96 + 97 98 99 100 101 102 + 103 104 105 106 107 108 + 109 110 111 112 113 114 + 115 116 117 118 119 120 + 121 122 123 124 125 126 + 127 128 129 130 131 132 + 133 134 135 136 137 138 + 139 140 141 142 143 144 + 145 146 147 148 149 150 + 151 152 153 154 155 156 + 157 158 159 160 161 162 + 163 164 165 166 167 168 + 169 170 171 172 173 174 + 175 176 177 178 179 180 + 181 182 183 184 185 186 + 187 188 189 190 191 192 + 193 194 195 196 197 198 + 199 200 201 202 203 204 + 205 206 + +.. >>>>> [ RES MEM : 3.823101 GB ] [ VIRT MEM : 8.758938 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 390.324555 s ] [ CPU TIME: 16646.381211 s ] <<<<< .. + +MOs are now **Natural** + +Eigenvalues +----------- + +======== ================ ================ + MO Eigenvalue Cumulative +======== ================ ================ + 1 2.0000000000 2.0000000000 + 2 2.0000000000 4.0000000000 + 3 2.0000000000 6.0000000000 + 4 2.0000000000 8.0000000000 + 5 2.0000000000 10.0000000000 + 6 1.9873371353 11.9873371353 + 7 1.9849678592 13.9723049944 + 8 1.9838426564 15.9561476508 + 9 1.9799613048 17.9361089556 + 10 1.9795705195 19.9156794752 + 11 1.9784000795 21.8940795547 + 12 1.9746976237 23.8687771783 + 13 1.9736658644 25.8424430427 + 14 1.9731298213 27.8155728640 + 15 1.9717117708 29.7872846349 + 16 1.9709021139 31.7581867487 + 17 1.9604595536 33.7186463023 + 18 1.9530442811 35.6716905835 + 19 0.0373843881 35.7090749716 + 20 0.0307326221 35.7398075936 + 21 0.0180621668 35.7578697605 + 22 0.0160168524 35.7738866129 + 23 0.0147537006 35.7886403135 + 24 0.0143454064 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================ ================ + + +.. >>>>> [ RES MEM : 3.828239 GB ] [ VIRT MEM : 8.865211 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 390.370967 s ] [ CPU TIME: 16649.665426 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_md5 ] <<<<< .. + +.. >>>>> [ RES MEM : 3.828239 GB ] [ VIRT MEM : 8.865211 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 390.372007 s ] [ CPU TIME: 16649.738683 s ] <<<<< .. + +* Saved determinants 1 +Wall time: 0:06:36 + diff --git a/imidazole/cc-pvtz/imidazole.nofci.out b/imidazole/cc-pvtz/imidazole.nofci.out new file mode 100644 index 0000000..97da2aa --- /dev/null +++ b/imidazole/cc-pvtz/imidazole.nofci.out @@ -0,0 +1,3750 @@ +Date: 02/11/2020 13:06:35 +=============== +Quantum Package +=============== + +Git Commit: Fix space in size for EZFIO.cfg +Git Date : Fri Oct 16 14:24:01 2020 +0200 +Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b +EZFIO Dir : imidazole + + +Task server running : tcp://172.28.1.29:41279 +* mo_num 206 +.. >>>>> [ IO READ: mo_class ] <<<<< .. + +.. >>>>> [ RES MEM : 0.010914 GB ] [ VIRT MEM : 4.857998 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.001089 s ] [ CPU TIME: 0.144124 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_two_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.010914 GB ] [ VIRT MEM : 4.857998 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.008331 s ] [ CPU TIME: 0.591668 s ] <<<<< .. + +* N_int 4 + MO map initialized: 227303181 +.. >>>>> [ IO READ: io_ao_two_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.012623 GB ] [ VIRT MEM : 4.870811 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.027012 s ] [ CPU TIME: 1.776668 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.012623 GB ] [ VIRT MEM : 4.870811 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.029326 s ] [ CPU TIME: 1.924990 s ] <<<<< .. + + AO map initialized : 384490315 +.. >>>>> [ IO READ: ao_power ] <<<<< .. + +.. >>>>> [ RES MEM : 0.015865 GB ] [ VIRT MEM : 4.872654 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.047514 s ] [ CPU TIME: 3.062447 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_prim_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.015911 GB ] [ VIRT MEM : 4.872654 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.051479 s ] [ CPU TIME: 3.309585 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_expo ] <<<<< .. + +.. >>>>> [ RES MEM : 0.015957 GB ] [ VIRT MEM : 4.872654 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.059566 s ] [ CPU TIME: 3.732460 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_coef ] <<<<< .. + +.. >>>>> [ RES MEM : 0.016045 GB ] [ VIRT MEM : 4.872654 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.066119 s ] [ CPU TIME: 4.066059 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_nucl ] <<<<< .. + +.. >>>>> [ RES MEM : 0.016262 GB ] [ VIRT MEM : 4.872654 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.071066 s ] [ CPU TIME: 4.382547 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_integrals_threshold ] <<<<< .. + +.. >>>>> [ RES MEM : 0.016262 GB ] [ VIRT MEM : 4.872654 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.072515 s ] [ CPU TIME: 4.478680 s ] <<<<< .. + + Providing the AO integrals +.. >>>>> [ IO READ: nucl_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017738 GB ] [ VIRT MEM : 5.070198 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.211466 s ] [ CPU TIME: 10.904619 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_label ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017879 GB ] [ VIRT MEM : 5.070198 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.216108 s ] [ CPU TIME: 11.201773 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_charge ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017902 GB ] [ VIRT MEM : 5.070198 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.219690 s ] [ CPU TIME: 11.431348 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.017914 GB ] [ VIRT MEM : 5.070198 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.222592 s ] [ CPU TIME: 11.617388 s ] <<<<< .. + + +Nuclear Coordinates (Angstroms) +=============================== + +================ ============ ============ ============ ============ + Atom Charge X Y Z +================ ============ ============ ============ ============ +C 6.000000 0.220470 1.090138 0.000000 +C 6.000000 -0.807622 -0.859083 0.000000 +C 6.000000 0.551194 -1.021351 0.000000 +N 7.000000 -1.007266 0.502268 0.000000 +N 7.000000 1.186497 0.201529 0.000000 +H 1.000000 0.346620 2.157711 0.000000 +H 1.000000 -1.891812 0.974232 0.000000 +H 1.000000 -1.621208 -1.558740 0.000000 +H 1.000000 1.104255 -1.942086 0.000000 +================ ============ ============ ============ ============ + + Sorting the map + AO integrals provided: + Size of AO map : 2202.68785476685 MB + Number of AO integrals : 191596254 + cpu time : 3544.71400400000 s + wall time : 53.6202049255371 s ( x 66.1078041182904 ) + + AO -> MO integrals transformation + --------------------------------- + + Read mo_coef +.. >>>>> [ IO READ: mo_integrals_threshold ] <<<<< .. + +.. >>>>> [ RES MEM : 1.980488 GB ] [ VIRT MEM : 7.399471 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 53.795015 s ] [ CPU TIME: 3550.874553 s ] <<<<< .. + + Buffers : 364.4832 MB / core + 26.80851 % in 16.5871849060059 s 1416.19925308228 MB + 34.46809 % in 47.7203240394592 s 3358.64888000488 MB + 73.61702 % in 61.2159440517426 s 3361.73462677002 MB + 91.06383 % in 72.3824141025543 s 3360.75054931641 MB + Molecular integrals provided: + Size of MO map 3364.97252273560 MB + Number of MO integrals: 174393041 + cpu time : 5520.37556000000 s + wall time : 88.0055088996887 s ( x 62.7276136348724 ) +.. >>>>> [ IO READ: n_states ] <<<<< .. + +.. >>>>> [ RES MEM : 6.801121 GB ] [ VIRT MEM : 12.297386 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 141.713420 s ] [ CPU TIME: 9070.605344 s ] <<<<< .. + + * mo_label Natural +.. >>>>> [ IO READ: read_wf ] <<<<< .. + +.. >>>>> [ RES MEM : 6.801121 GB ] [ VIRT MEM : 12.297386 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 141.715168 s ] [ CPU TIME: 9070.727932 s ] <<<<< .. + +* Number of determinants 1 +* Dimension of the psi arrays 100000 + Read psi_coef 1 1 +.. >>>>> [ IO READ: elec_beta_num ] <<<<< .. + +.. >>>>> [ RES MEM : 6.801186 GB ] [ VIRT MEM : 12.297386 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 141.827016 s ] [ CPU TIME: 9078.538778 s ] <<<<< .. + +.. >>>>> [ IO READ: elec_alpha_num ] <<<<< .. + +.. >>>>> [ RES MEM : 6.801186 GB ] [ VIRT MEM : 12.297386 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 141.827806 s ] [ CPU TIME: 9078.593988 s ] <<<<< .. + + Read psi_det +.. >>>>> [ IO READ: do_pt2 ] <<<<< .. + +.. >>>>> [ RES MEM : 6.807186 GB ] [ VIRT MEM : 12.303356 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 141.847946 s ] [ CPU TIME: 9080.007901 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 6.807259 GB ] [ VIRT MEM : 12.303356 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 141.890992 s ] [ CPU TIME: 9082.982264 s ] <<<<< .. + +.. >>>>> [ IO READ: selection_factor ] <<<<< .. + +.. >>>>> [ RES MEM : 6.807259 GB ] [ VIRT MEM : 12.303356 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 141.891745 s ] [ CPU TIME: 9083.035084 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_max ] <<<<< .. + +.. >>>>> [ RES MEM : 6.807987 GB ] [ VIRT MEM : 12.309326 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 141.893078 s ] [ CPU TIME: 9083.120085 s ] <<<<< .. + +.. >>>>> [ IO READ: s2_eig ] <<<<< .. + +.. >>>>> [ RES MEM : 6.808956 GB ] [ VIRT MEM : 12.309326 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 141.895361 s ] [ CPU TIME: 9083.281216 s ] <<<<< .. + +.. >>>>> [ IO READ: variance_max ] <<<<< .. + +.. >>>>> [ RES MEM : 6.808956 GB ] [ VIRT MEM : 12.309326 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 141.896132 s ] [ CPU TIME: 9083.335749 s ] <<<<< .. + +.. >>>>> [ IO READ: distributed_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 6.808956 GB ] [ VIRT MEM : 12.309326 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 141.950025 s ] [ CPU TIME: 9087.099438 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_max_full ] <<<<< .. + +.. >>>>> [ RES MEM : 6.808956 GB ] [ VIRT MEM : 12.309326 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 141.950802 s ] [ CPU TIME: 9087.154034 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_integrals_e_n ] <<<<< .. + +.. >>>>> [ RES MEM : 8.811848 GB ] [ VIRT MEM : 14.315193 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 147.409495 s ] [ CPU TIME: 9161.552254 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_integrals_e_n ] <<<<< .. + +.. >>>>> [ RES MEM : 8.811848 GB ] [ VIRT MEM : 14.315193 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 147.433553 s ] [ CPU TIME: 9161.553345 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_integrals_kinetic ] <<<<< .. + +.. >>>>> [ RES MEM : 8.813293 GB ] [ VIRT MEM : 14.381413 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 147.512443 s ] [ CPU TIME: 9166.295202 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_integrals_kinetic ] <<<<< .. + +.. >>>>> [ RES MEM : 8.813293 GB ] [ VIRT MEM : 14.381413 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 147.513274 s ] [ CPU TIME: 9166.352368 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_one_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 8.813293 GB ] [ VIRT MEM : 14.381413 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 147.535037 s ] [ CPU TIME: 9167.836133 s ] <<<<< .. + + Providing the one-electron integrals +.. >>>>> [ IO READ: do_pseudo ] <<<<< .. + +.. >>>>> [ RES MEM : 8.813293 GB ] [ VIRT MEM : 14.381413 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 147.563192 s ] [ CPU TIME: 9169.801210 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_relative_error ] <<<<< .. + +.. >>>>> [ RES MEM : 8.813461 GB ] [ VIRT MEM : 14.381413 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 147.630512 s ] [ CPU TIME: 9174.579135 s ] <<<<< .. + +.. >>>>> [ IO READ: correlation_energy_ratio_max ] <<<<< .. + +.. >>>>> [ RES MEM : 8.813461 GB ] [ VIRT MEM : 14.381413 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 147.631307 s ] [ CPU TIME: 9174.635997 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.813461 GB ] [ VIRT MEM : 14.381413 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 147.644886 s ] [ CPU TIME: 9175.598093 s ] <<<<< .. + + Read n_states_diag +.. >>>>> [ IO READ: io_nuclear_repulsion ] <<<<< .. + +.. >>>>> [ RES MEM : 8.813461 GB ] [ VIRT MEM : 14.381413 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 147.645693 s ] [ CPU TIME: 9175.656150 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.813461 GB ] [ VIRT MEM : 14.381413 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 147.646000 s ] [ CPU TIME: 9175.677978 s ] <<<<< .. + +* Nuclear repulsion energy 163.5043497210638 +.. >>>>> [ IO READ: weight_one_e_dm ] <<<<< .. + +.. >>>>> [ RES MEM : 8.813461 GB ] [ VIRT MEM : 14.381413 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 147.647159 s ] [ CPU TIME: 9175.760387 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_max ] <<<<< .. + +.. >>>>> [ RES MEM : 8.821606 GB ] [ VIRT MEM : 14.391293 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 147.658027 s ] [ CPU TIME: 9176.538568 s ] <<<<< .. + +.. >>>>> [ IO READ: threshold_generators ] <<<<< .. + +.. >>>>> [ RES MEM : 8.821606 GB ] [ VIRT MEM : 14.391293 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 147.658833 s ] [ CPU TIME: 9176.595811 s ] <<<<< .. + +* Target maximum memory (GB) 2000 +.. >>>>> [ IO READ: threshold_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 8.821606 GB ] [ VIRT MEM : 14.391293 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 147.659811 s ] [ CPU TIME: 9176.665775 s ] <<<<< .. + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.821846 GB ] [ VIRT MEM : 14.391293 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 147.686463 s ] [ CPU TIME: 9178.553714 s ] <<<<< .. + +* Energy of state 1 -224.8927918045908 +* S^2 of state 1 0.000000000000000 +* Saved determinants 1 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 1 +* Number of unique alpha determinants 1 +.. >>>>> [ IO READ: weight_selection ] <<<<< .. + +.. >>>>> [ RES MEM : 8.822147 GB ] [ VIRT MEM : 14.403496 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 148.080778 s ] [ CPU TIME: 9199.587291 s ] <<<<< .. + + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +.. >>>>> [ IO READ: pseudo_sym ] <<<<< .. + +.. >>>>> [ RES MEM : 8.822147 GB ] [ VIRT MEM : 14.403496 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 148.081646 s ] [ CPU TIME: 9199.650264 s ] <<<<< .. + +.. >>>>> [ IO READ: h0_type ] <<<<< .. + +.. >>>>> [ RES MEM : 8.822365 GB ] [ VIRT MEM : 14.409466 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 148.082616 s ] [ CPU TIME: 9199.719522 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.822365 GB ] [ VIRT MEM : 14.409466 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 148.082993 s ] [ CPU TIME: 9199.746518 s ] <<<<< .. + +* Number of generators 1 + +.. >>>>> [ RES MEM : 8.822365 GB ] [ VIRT MEM : 14.409466 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 148.083360 s ] [ CPU TIME: 9199.773212 s ] <<<<< .. + +* Number of selectors 1 +* Number of comb teeth 1 +* Number of core MOs 5 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -224.8927918045908 +* Estimated memory/thread (Gb) 0.2384185791015625E-06 +* Number of virtual MOs 0 +* Number of active MOs 201 + Active MOs: + 6 7 8 9 10 11 + 12 13 14 15 16 17 + 18 19 20 21 22 23 + 24 25 26 27 28 29 + 30 31 32 33 34 35 + 36 37 38 39 40 41 + 42 43 44 45 46 47 + 48 49 50 51 52 53 + 54 55 56 57 58 59 + 60 61 62 63 64 65 + 66 67 68 69 70 71 + 72 73 74 75 76 77 + 78 79 80 81 82 83 + 84 85 86 87 88 89 + 90 91 92 93 94 95 + 96 97 98 99 100 101 + 102 103 104 105 106 107 + 108 109 110 111 112 113 + 114 115 116 117 118 119 + 120 121 122 123 124 125 + 126 127 128 129 130 131 + 132 133 134 135 136 137 + 138 139 140 141 142 143 + 144 145 146 147 148 149 + 150 151 152 153 154 155 + 156 157 158 159 160 161 + 162 163 164 165 166 167 + 168 169 170 171 172 173 + 174 175 176 177 178 179 + 180 181 182 183 184 185 + 186 187 188 189 190 191 + 192 193 194 195 196 197 + 198 199 200 201 202 203 + 204 205 206 +* Number of inactive MOs 0 +.. >>>>> [ IO READ: pert_2rdm ] <<<<< .. + +.. >>>>> [ RES MEM : 8.824402 GB ] [ VIRT MEM : 14.426155 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 148.127614 s ] [ CPU TIME: 9202.266822 s ] <<<<< .. + +.. >>>>> [ IO READ: pruning ] <<<<< .. + +.. >>>>> [ RES MEM : 8.824425 GB ] [ VIRT MEM : 14.426155 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 155.988368 s ] [ CPU TIME: 9222.396578 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.824627 GB ] [ VIRT MEM : 14.426155 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 155.995806 s ] [ CPU TIME: 9222.911602 s ] <<<<< .. + +* Number of generators 1 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Saved determinants 5 +* Number of unique beta determinants 5 +* Number of unique alpha determinants 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.824883 GB ] [ VIRT MEM : 14.426163 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 157.460344 s ] [ CPU TIME: 9237.434948 s ] <<<<< .. + +* Number of selectors 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio -0.2507208206863066E-02 + +Summary at N_det = 5 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -224.89279180 +# PT2 -1.18752237 0.00000000 +# rPT2 -0.79497522 0.00000000 +# +# E+PT2 -226.08031418 0.00000000 +# E+rPT2 -225.68776702 0.00000000 +# ============ ============================= + + N_det = 5 + N_states = 1 + + * State 1 + < S^2 > = 0.000000000000000E+000 + E = -224.892791804591 + Variance = 3.83283640127353 + PT norm = 0.702698655539853 + PT2 = -1.18752237116673 + rPT2 = -0.794975215831683 + E+PT2 = -226.080314175758 +/- 0.000000000000000E+000 + E+rPT2 = -225.687767020423 +/- 0.000000000000000E+000 + + ----- +.. >>>>> [ IO READ: io_mo_integrals_pseudo ] <<<<< .. + +.. >>>>> [ RES MEM : 8.824883 GB ] [ VIRT MEM : 14.426163 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 157.461966 s ] [ CPU TIME: 9237.551431 s ] <<<<< .. + + Energy components + ================= + + Vnn : Nucleus-Nucleus potential energy + Ven : Electron-Nucleus potential energy + Vee : Electron-Electron potential energy + Vecp : Potential energy of the pseudo-potentials + T : Electronic kinetic energy + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.209486432738 + Vee = 239.952969734381 + Vecp = 0.000000000000000E+000 + T = 224.859375172702 + + +.. >>>>> [ IO READ: energy_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 8.825748 GB ] [ VIRT MEM : 14.426163 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 157.523842 s ] [ CPU TIME: 9241.935939 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 8.825748 GB ] [ VIRT MEM : 14.426163 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 157.527175 s ] [ CPU TIME: 9242.165246 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 8.825748 GB ] [ VIRT MEM : 14.426163 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 157.530444 s ] [ CPU TIME: 9242.390585 s ] <<<<< .. + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.826183 GB ] [ VIRT MEM : 14.426163 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 157.555548 s ] [ CPU TIME: 9244.150860 s ] <<<<< .. + +* Energy of state 1 -224.9168820464424 +* S^2 of state 1 0.000000000000000 +* Saved determinants 5 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 5 +* Number of unique alpha determinants 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.826355 GB ] [ VIRT MEM : 14.426163 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 157.604200 s ] [ CPU TIME: 9247.590857 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 8.826355 GB ] [ VIRT MEM : 14.426163 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 157.604578 s ] [ CPU TIME: 9247.618017 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -224.9168820464424 + +.. >>>>> [ RES MEM : 8.832897 GB ] [ VIRT MEM : 14.432133 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 157.614161 s ] [ CPU TIME: 9248.296320 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 8.832897 GB ] [ VIRT MEM : 14.432133 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 157.614532 s ] [ CPU TIME: 9248.323129 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 5 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2289864551275968E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.9603633871 0.103 3.7797445065 0.3705120531 3.7965 + 4 -226.0461813382 0.00 3.7837542014 0.4366845862 3.7967 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.838753 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 161.441148 s ] [ CPU TIME: 9281.355742 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 8.838753 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 161.441520 s ] [ CPU TIME: 9281.381797 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.2734904178896818E-01 + +Summary at N_det = 5 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -224.91688205 +# PT2 -1.12929929 0.00000000 +# rPT2 -0.78604539 0.00000000 +# +# E+PT2 -226.04618134 0.00000000 +# E+rPT2 -225.70292743 0.00000000 +# ============ ============================= + + N_det = 5 + N_states = 1 + + * State 1 + < S^2 > = 0.000000000000000E+000 + E = -224.916882046442 + Variance = 3.78375420137483 + PT norm = 0.660821145402316 + PT2 = -1.12929929179913 + rPT2 = -0.786045387162947 + E+PT2 = -226.046181338242 +/- 0.000000000000000E+000 + E+rPT2 = -225.702927433605 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.285131114297 + Vee = 239.953823976178 + Vecp = 0.000000000000000E+000 + T = 224.910075370613 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7950 -227.03741808 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.838943 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 161.492916 s ] [ CPU TIME: 9284.822246 s ] <<<<< .. + +* Energy of state 1 -224.9293884254357 +* S^2 of state 1 0.2363634578965737E-02 +* Saved determinants 10 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 7 +* Number of unique alpha determinants 7 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.839115 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 161.543972 s ] [ CPU TIME: 9288.277583 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 8.839115 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 161.544345 s ] [ CPU TIME: 9288.303536 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -224.9293884254357 + +.. >>>>> [ RES MEM : 8.839115 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 161.549393 s ] [ CPU TIME: 9288.650395 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 8.839115 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 161.549760 s ] [ CPU TIME: 9288.675917 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 10 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2299601100385189E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.9383860541 0.108 3.8656989089 0.3372250828 3.7546 + 9 -226.0274953365 0.00 3.7554884196 0.4064950445 3.7548 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.839195 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 165.321991 s ] [ CPU TIME: 9338.019474 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 8.839195 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 165.322364 s ] [ CPU TIME: 9338.045101 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.4244619425667052E-01 + +Summary at N_det = 10 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -224.92938843 +# PT2 -1.09810691 0.00000000 +# rPT2 -0.78073998 0.00000000 +# +# E+PT2 -226.02749534 0.00000000 +# E+rPT2 -225.71012840 0.00000000 +# ============ ============================= + + N_det = 10 + N_states = 1 + + * State 1 + < S^2 > = 2.363634578965737E-003 + E = -224.929388425436 + Variance = 3.75548841958625 + PT norm = 0.637569638979866 + PT2 = -1.09810691110441 + rPT2 = -0.780739978686942 + E+PT2 = -226.027495336540 +/- 0.000000000000000E+000 + E+rPT2 = -225.710128404123 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.319100842888 + Vee = 239.950377496785 + Vecp = 0.000000000000000E+000 + T = 224.934985199603 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7860 -226.76981789 + -0.7950 -226.94734015 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.839233 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 165.372699 s ] [ CPU TIME: 9341.364012 s ] <<<<< .. + +* Energy of state 1 -224.9434015279857 +* S^2 of state 1 0.6968594978405529E-02 +* Saved determinants 20 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 11 +* Number of unique alpha determinants 11 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.839340 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 165.421291 s ] [ CPU TIME: 9344.547601 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 8.839340 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 165.421618 s ] [ CPU TIME: 9344.569963 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -224.9434015279857 + +.. >>>>> [ RES MEM : 8.839340 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 165.425903 s ] [ CPU TIME: 9344.855592 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 8.839340 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 165.426230 s ] [ CPU TIME: 9344.877841 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 20 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2319074198603630E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.8820387656 0.154 3.5801508521 0.3101727572 4.1932 + 19 -226.0101191350 0.00 3.7183685048 0.3828639306 4.2216 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.839363 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 169.669914 s ] [ CPU TIME: 9438.851865 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 8.839363 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 169.670286 s ] [ CPU TIME: 9438.877216 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.5929423874940491E-01 + +Summary at N_det = 20 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -224.94340153 +# PT2 -1.06671761 0.00000000 +# rPT2 -0.77138291 0.00000000 +# +# E+PT2 -226.01011914 0.00000000 +# E+rPT2 -225.71478444 0.00000000 +# ============ ============================= + + N_det = 20 + N_states = 1 + + * State 1 + < S^2 > = 6.968594978405529E-003 + E = -224.943401527986 + Variance = 3.71836850475966 + PT norm = 0.618759994307717 + PT2 = -1.06671760702947 + rPT2 = -0.771382912996234 + E+PT2 = -226.010119135015 +/- 0.000000000000000E+000 + E+rPT2 = -225.714784440982 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.350978363152 + Vee = 239.941173299965 + Vecp = 0.000000000000000E+000 + T = 224.962053814138 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7807 -226.09862136 + -0.7860 -226.31174926 + -0.7950 -226.60575558 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.839844 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 169.788897 s ] [ CPU TIME: 9446.621742 s ] <<<<< .. + +* Energy of state 1 -224.9596192819849 +* S^2 of state 1 0.1780107864433090E-01 +* Saved determinants 40 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 17 +* Number of unique alpha determinants 17 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.839928 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 169.862622 s ] [ CPU TIME: 9451.598314 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 8.839928 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 169.862993 s ] [ CPU TIME: 9451.624071 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -224.9596192819849 + +.. >>>>> [ RES MEM : 8.839928 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 169.868237 s ] [ CPU TIME: 9451.984463 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 8.839928 GB ] [ VIRT MEM : 14.437382 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 169.868605 s ] [ CPU TIME: 9452.010127 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 40 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2358020395040512E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.8426258510 0.175 3.6377636820 0.2766939749 5.2337 + 39 -225.9894232421 0.00 3.6655073439 0.3592233797 5.2343 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.840015 GB ] [ VIRT MEM : 14.437527 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 175.127147 s ] [ CPU TIME: 9647.925232 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 8.840015 GB ] [ VIRT MEM : 14.437527 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 175.127517 s ] [ CPU TIME: 9647.947856 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7883381464073939E-01 + +Summary at N_det = 40 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -224.95961928 +# PT2 -1.02980396 0.00000000 +# rPT2 -0.75764144 0.00000000 +# +# E+PT2 -225.98942324 0.00000000 +# E+rPT2 -225.71726072 0.00000000 +# ============ ============================= + + N_det = 40 + N_states = 1 + + * State 1 + < S^2 > = 1.780107864433090E-002 + E = -224.959619281985 + Variance = 3.66550734387456 + PT norm = 0.599352467023283 + PT2 = -1.02980396016354 + rPT2 = -0.757641441078251 + E+PT2 = -225.989423242148 +/- 0.000000000000000E+000 + E+rPT2 = -225.717260723063 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.372701858401 + Vee = 239.921011384662 + Vecp = 0.000000000000000E+000 + T = 224.987721470690 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7714 -225.85379151 + -0.7807 -225.94442893 + -0.7860 -226.06978656 + -0.7950 -226.28719798 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.840988 GB ] [ VIRT MEM : 14.439438 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 175.182195 s ] [ CPU TIME: 9651.327569 s ] <<<<< .. + +* Energy of state 1 -224.9797587937194 +* S^2 of state 1 0.1189149902799937E-01 +* Saved determinants 80 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 35 +* Number of unique alpha determinants 35 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.841240 GB ] [ VIRT MEM : 14.439606 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 175.244380 s ] [ CPU TIME: 9655.427672 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 8.841240 GB ] [ VIRT MEM : 14.439606 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 175.244756 s ] [ CPU TIME: 9655.453424 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -224.9797587937194 + +.. >>>>> [ RES MEM : 8.841240 GB ] [ VIRT MEM : 14.439606 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 175.250001 s ] [ CPU TIME: 9655.808912 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 8.841240 GB ] [ VIRT MEM : 14.439606 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 175.250371 s ] [ CPU TIME: 9655.834143 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 80 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2435912787914276E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.8341233802 0.162 3.6056989389 0.2596181886 7.7601 + 70 -225.9597362162 0.960E-02 3.6308676049 0.3266105633 8.7970 + 75 -225.9606989766 0.897E-02 3.6270897425 0.3275331404 9.8337 + 76 -225.9700358043 0.00 3.6076184079 0.3346313437 9.8338 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.848747 GB ] [ VIRT MEM : 14.445446 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 185.111755 s ] [ CPU TIME: 10149.791360 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 8.848747 GB ] [ VIRT MEM : 14.445446 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 185.112143 s ] [ CPU TIME: 10149.815551 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1027599525489090 + +Summary at N_det = 80 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -224.97975879 +# PT2 -0.99027701 0.00000000 +# rPT2 -0.74198543 0.00000000 +# +# E+PT2 -225.97003580 0.00000000 +# E+rPT2 -225.72174422 0.00000000 +# ============ ============================= + + N_det = 80 + N_states = 1 + + * State 1 + < S^2 > = 1.189149902799937E-002 + E = -224.979758793719 + Variance = 3.60761840792695 + PT norm = 0.578473286946020 + PT2 = -0.990277010549334 + rPT2 = -0.741985429321980 + E+PT2 = -225.970035804269 +/- 0.000000000000000E+000 + E+rPT2 = -225.721744223041 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.387527502516 + Vee = 239.894987935368 + Vecp = 0.000000000000000E+000 + T = 225.008431052365 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7576 -225.93423076 + -0.7714 -225.89801591 + -0.7807 -225.93169255 + -0.7860 -226.00250967 + -0.7950 -226.14112215 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.849342 GB ] [ VIRT MEM : 14.445446 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 185.178921 s ] [ CPU TIME: 10154.145407 s ] <<<<< .. + +* Energy of state 1 -225.0038188958702 +* S^2 of state 1 0.1544912496249237E-01 +* Saved determinants 160 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 58 +* Number of unique alpha determinants 58 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.849400 GB ] [ VIRT MEM : 14.445446 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 186.087402 s ] [ CPU TIME: 10170.788430 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 8.849400 GB ] [ VIRT MEM : 14.445446 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 186.087808 s ] [ CPU TIME: 10170.816380 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -225.0038188958702 + +.. >>>>> [ RES MEM : 8.849400 GB ] [ VIRT MEM : 14.445446 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 186.093239 s ] [ CPU TIME: 10171.201591 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 8.849400 GB ] [ VIRT MEM : 14.445446 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 186.093620 s ] [ CPU TIME: 10171.229065 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 160 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2591697573661804E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.8107021706 0.161 3.5405194438 0.2363838028 9.4967 + 70 -225.9370196992 0.955E-02 3.5552703960 0.3005119727 10.8125 + 72 -225.9391582239 0.949E-02 3.5645403655 0.3010128184 12.2595 + 116 -225.9434255800 0.589E-02 3.5350739733 0.3057555454 13.4986 + 140 -225.9454789556 0.496E-02 3.5328194816 0.3070389039 15.1117 + 152 -225.9466268737 0.464E-02 3.5381463073 0.3072326260 16.2061 + 154 -225.9493328013 0.00 3.5367971392 0.3085702557 16.2063 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.850140 GB ] [ VIRT MEM : 14.445446 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 202.324206 s ] [ CPU TIME: 11144.657697 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 8.850140 GB ] [ VIRT MEM : 14.445446 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 202.324574 s ] [ CPU TIME: 11144.681153 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1311203873141441 + +Summary at N_det = 160 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.00381890 +# PT2 -0.94551391 0.00000000 +# rPT2 -0.72255494 0.00000000 +# +# E+PT2 -225.94933280 0.00000000 +# E+rPT2 -225.72637384 0.00000000 +# ============ ============================= + + N_det = 160 + N_states = 1 + + * State 1 + < S^2 > = 1.544912496249237E-002 + E = -225.003818895870 + Variance = 3.53679713918089 + PT norm = 0.555491004141993 + PT2 = -0.945513905452268 + rPT2 = -0.722554942194521 + E+PT2 = -225.949332801322 +/- 0.000000000000000E+000 + E+rPT2 = -225.726373838065 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.406447389756 + Vee = 239.863757626164 + Vecp = 0.000000000000000E+000 + T = 225.034521146658 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7420 -225.89853376 + -0.7576 -225.91355499 + -0.7714 -225.90171822 + -0.7807 -225.91993340 + -0.7860 -225.96396097 + -0.7950 -226.05489828 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.856541 GB ] [ VIRT MEM : 14.449356 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 202.462958 s ] [ CPU TIME: 11153.760967 s ] <<<<< .. + +* Energy of state 1 -225.0335820647977 +* S^2 of state 1 0.2154315181978051E-01 +* Saved determinants 320 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 117 +* Number of unique alpha determinants 117 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.856575 GB ] [ VIRT MEM : 14.449356 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 202.529651 s ] [ CPU TIME: 11157.901377 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 8.856575 GB ] [ VIRT MEM : 14.449356 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 202.529989 s ] [ CPU TIME: 11157.924500 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -225.0335820647977 + +.. >>>>> [ RES MEM : 8.856575 GB ] [ VIRT MEM : 14.449356 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 202.535918 s ] [ CPU TIME: 11158.326306 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 8.856575 GB ] [ VIRT MEM : 14.449356 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 202.536277 s ] [ CPU TIME: 11158.350928 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 320 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2903267145156860E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.7640656078 0.185 3.3786945879 0.2059851322 13.0633 + 96 -225.9106232199 0.920E-02 3.4188512569 0.2727115658 15.2623 + 137 -225.9194921219 0.801E-02 3.4326707188 0.2765017930 16.6444 + 142 -225.9196744383 0.773E-02 3.4308554939 0.2767255748 17.6863 + 147 -225.9215035918 0.766E-02 3.4428050212 0.2768461586 19.3683 + 183 -225.9254401151 0.644E-02 3.4477703759 0.2786231825 20.5447 + 195 -225.9235256347 0.633E-02 3.4400971812 0.2780246628 21.6699 + 214 -225.9260120124 0.604E-02 3.4539442287 0.2783082706 23.2213 + 222 -225.9239229208 0.617E-02 3.4471922696 0.2775834980 24.3023 + 230 -225.9248133183 0.602E-02 3.4496954661 0.2778708193 25.3053 + 266 -225.9274922831 0.554E-02 3.4550440712 0.2789591852 26.5590 + 286 -225.9252326389 0.538E-02 3.4482301667 0.2781285695 28.0025 + 300 -225.9245348059 0.537E-02 3.4540781689 0.2773231480 29.2014 + 313 -225.9283084069 0.00 3.4538566166 0.2793840823 29.7333 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.857731 GB ] [ VIRT MEM : 14.449585 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 232.293332 s ] [ CPU TIME: 13126.296998 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 8.857731 GB ] [ VIRT MEM : 14.449585 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 232.293695 s ] [ CPU TIME: 13126.320290 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1656065688485564 + +Summary at N_det = 320 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.03358206 +# PT2 -0.89472634 0.00000000 +# rPT2 -0.69934147 0.00000000 +# +# E+PT2 -225.92830841 0.00000000 +# E+rPT2 -225.73292353 0.00000000 +# ============ ============================= + + N_det = 320 + N_states = 1 + + * State 1 + < S^2 > = 2.154315181978051E-002 + E = -225.033582064798 + Variance = 3.45385661657800 + PT norm = 0.528567954258408 + PT2 = -0.894726342121243 + rPT2 = -0.699341467915166 + E+PT2 = -225.928308406919 +/- 0.000000000000000E+000 + E+rPT2 = -225.732923532713 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.417006280880 + Vee = 239.820308655892 + Vecp = 0.000000000000000E+000 + T = 225.058765839127 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7226 -225.93024312 + -0.7420 -225.91656749 + -0.7576 -225.91862226 + -0.7714 -225.91061965 + -0.7807 -225.92006355 + -0.7860 -225.94792868 + -0.7950 -226.00847463 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.869709 GB ] [ VIRT MEM : 14.455711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 232.580433 s ] [ CPU TIME: 13145.815743 s ] <<<<< .. + +* Energy of state 1 -225.0721995250705 +* S^2 of state 1 0.3173850213944733E-01 +* Saved determinants 640 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 184 +* Number of unique alpha determinants 184 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.869709 GB ] [ VIRT MEM : 14.455711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 233.114139 s ] [ CPU TIME: 13161.720982 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 8.869709 GB ] [ VIRT MEM : 14.455711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 233.114506 s ] [ CPU TIME: 13161.747103 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -225.0721995250705 + +.. >>>>> [ RES MEM : 8.869709 GB ] [ VIRT MEM : 14.455711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 233.120913 s ] [ CPU TIME: 13162.193762 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 8.869709 GB ] [ VIRT MEM : 14.455711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 233.121276 s ] [ CPU TIME: 13162.219470 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 640 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.3526406288146973E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.7403717954 0.178 3.1560727042 0.1817360780 18.9766 + 141 -225.8889456194 0.921E-02 3.2672686909 0.2445284359 20.1951 + 166 -225.8918294306 0.841E-02 3.2759507112 0.2454608684 22.6725 + 197 -225.8974163543 0.833E-02 3.2981547921 0.2470206258 24.5766 + 201 -225.8983193135 0.822E-02 3.3095736613 0.2468013007 26.8729 + 242 -225.8983026592 0.711E-02 3.3169143420 0.2462425395 28.7156 + 273 -225.9008857016 0.683E-02 3.3284683096 0.2468884836 30.6096 + 279 -225.9012115126 0.670E-02 3.3310561799 0.2468552553 32.1971 + 306 -225.9010838284 0.643E-02 3.3346794925 0.2465292641 34.0767 + 319 -225.9008112428 0.617E-02 3.3304109063 0.2466689253 35.9136 + 344 -225.9017193357 0.580E-02 3.3338087657 0.2469145087 37.0446 + 366 -225.8996136062 0.559E-02 3.3261834854 0.2462726961 38.0686 + 378 -225.8993335619 0.545E-02 3.3304038949 0.2458783294 39.3138 + 386 -225.8992312082 0.534E-02 3.3283216370 0.2459628476 40.5734 + 409 -225.9005367009 0.522E-02 3.3368058992 0.2460795353 41.7876 + 414 -225.9024093705 0.551E-02 3.3445470563 0.2465573995 43.8528 + 448 -225.9028338846 0.519E-02 3.3400130911 0.2470842982 44.9247 + 455 -225.9027040555 0.511E-02 3.3383195813 0.2471284834 46.3346 + 483 -225.9043685228 0.495E-02 3.3445152630 0.2476366380 47.5126 + 488 -225.9037250866 0.493E-02 3.3423692412 0.2474054238 48.7206 + 508 -225.9042009175 0.481E-02 3.3427673692 0.2476255118 50.3882 + 536 -225.9037214194 0.476E-02 3.3469931393 0.2471104753 51.4637 + 548 -225.9035171911 0.466E-02 3.3444298214 0.2471727934 52.4935 + 567 -225.9038014529 0.454E-02 3.3430694636 0.2474261853 53.5048 + 575 -225.9037772090 0.453E-02 3.3442971071 0.2473015311 54.5752 + 589 -225.9028684701 0.447E-02 3.3399166119 0.2470862529 55.7191 + 621 -225.9029704780 0.428E-02 3.3365102778 0.2473803407 56.7763 + 626 -225.9039998078 0.00 3.3349828873 0.2479933565 57.2903 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.870346 GB ] [ VIRT MEM : 14.455711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 290.437386 s ] [ CPU TIME: 17114.588515 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 8.870346 GB ] [ VIRT MEM : 14.455711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 290.437749 s ] [ CPU TIME: 17114.611153 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.2102302268998099 + +Summary at N_det = 640 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.07219953 +# PT2 -0.83180028 0.00000000 +# rPT2 -0.66651018 0.00000000 +# +# E+PT2 -225.90399981 0.00000000 +# E+rPT2 -225.73870971 0.00000000 +# ============ ============================= + + N_det = 640 + N_states = 1 + + * State 1 + < S^2 > = 3.173850213944733E-002 + E = -225.072199525070 + Variance = 3.33498288732295 + PT norm = 0.497989313612460 + PT2 = -0.831800282694446 + rPT2 = -0.666510184834441 + E+PT2 = -225.903999807765 +/- 0.000000000000000E+000 + E+rPT2 = -225.738709709905 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.420312566551 + Vee = 239.754444222550 + Vecp = 0.000000000000000E+000 + T = 225.089319097868 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6993 -225.85617530 + -0.7226 -225.88386694 + -0.7420 -225.89106057 + -0.7576 -225.89793368 + -0.7714 -225.89726709 + -0.7807 -225.90487030 + -0.7860 -225.92390422 + =========== =================== + +* Number of unique alpha determinants 325 +* Number of unique beta determinants 325 +.. >>>>> [ IO READ: davidson_sze_max ] <<<<< .. + +.. >>>>> [ RES MEM : 8.870495 GB ] [ VIRT MEM : 14.455711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 290.515803 s ] [ CPU TIME: 17119.574517 s ] <<<<< .. + +.. >>>>> [ IO READ: state_following ] <<<<< .. + +.. >>>>> [ RES MEM : 8.870495 GB ] [ VIRT MEM : 14.455711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 290.516900 s ] [ CPU TIME: 17119.650260 s ] <<<<< .. + +.. >>>>> [ IO READ: only_expected_s2 ] <<<<< .. + +.. >>>>> [ RES MEM : 8.870495 GB ] [ VIRT MEM : 14.455711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 290.518012 s ] [ CPU TIME: 17119.726280 s ] <<<<< .. + +.. >>>>> [ IO READ: disk_based_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 8.870495 GB ] [ VIRT MEM : 14.455711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 290.518733 s ] [ CPU TIME: 17119.775775 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.870495 GB ] [ VIRT MEM : 14.455711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 290.519139 s ] [ CPU TIME: 17119.803603 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 1280 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.3131978213787079E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.0723174357 0.031766 0.209E-01 + 2 -225.1179690654 0.035792 0.161E-02 + 3 -225.1185760667 0.034223 0.790E-04 + 4 -225.1186407572 0.034556 0.110E-05 + 5 -225.1186425133 0.034552 0.211E-07 + 6 -225.1186425495 0.034539 0.542E-09 + 7 -225.1186425505 0.034538 0.122E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 8.871078 GB ] [ VIRT MEM : 14.455711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 290.587156 s ] [ CPU TIME: 17124.539961 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.871078 GB ] [ VIRT MEM : 14.455711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 290.587558 s ] [ CPU TIME: 17124.568858 s ] <<<<< .. + +* Energy of state 1 -225.1186425505148 +* S^2 of state 1 0.3453819011665903E-01 +* Saved determinants 1280 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.871220 GB ] [ VIRT MEM : 14.455711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 290.688841 s ] [ CPU TIME: 17130.072894 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 8.871220 GB ] [ VIRT MEM : 14.455711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 290.689214 s ] [ CPU TIME: 17130.099655 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 60 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -225.1186425505148 + +.. >>>>> [ RES MEM : 8.871220 GB ] [ VIRT MEM : 14.455711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 290.700745 s ] [ CPU TIME: 17130.913331 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 8.871220 GB ] [ VIRT MEM : 14.455711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 290.701123 s ] [ CPU TIME: 17130.940206 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 60 +* pt2_n_tasks_max 1 +* Number of tasks 1280 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.4772860407829285E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.8792160612 0.894E-03 3.1915882227 0.2143074831 32.9960 + 4 -225.8787013872 0.800E-03 3.1887800571 0.2142098661 34.3593 + 5 -225.8788000913 0.591E-03 3.1900348528 0.2141995065 37.8605 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.869324 GB ] [ VIRT MEM : 14.452648 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 330.641625 s ] [ CPU TIME: 19760.286737 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 8.869324 GB ] [ VIRT MEM : 14.452648 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 330.641980 s ] [ CPU TIME: 19760.308408 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 60 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.2633927887601599 + +Summary at N_det = 1280 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.11864255 +# PT2 -0.76015754 0.00059075 +# rPT2 -0.62605654 0.00048653 +# +# E+PT2 -225.87880009 0.00059075 +# E+rPT2 -225.74469909 0.00048653 +# ============ ============================= + + N_det = 1280 + N_states = 1 + + * State 1 + < S^2 > = 3.453819011665903E-002 + E = -225.118642550515 + Variance = 3.19003485283070 + PT norm = 0.462816925493097 + PT2 = -0.760157540751914 + rPT2 = -0.626056539035159 + E+PT2 = -225.878800091267 +/- 5.907454187267229E-004 + E+rPT2 = -225.744699089550 +/- 4.865307682577203E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.424120971739 + Vee = 239.681121914997 + Vecp = 0.000000000000000E+000 + T = 225.120006785163 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6665 -225.83739012 + -0.6993 -225.84514553 + -0.7226 -225.86147047 + -0.7420 -225.87006386 + -0.7576 -225.87752568 + -0.7714 -225.88004802 + -0.7807 -225.88668398 + =========== =================== + +* Number of unique alpha determinants 559 +* Number of unique beta determinants 559 + +.. >>>>> [ RES MEM : 8.869591 GB ] [ VIRT MEM : 14.452648 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 330.712536 s ] [ CPU TIME: 19764.701025 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 2560 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.5771845579147339E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.1186715697 0.034505 0.227E-01 + 2 -225.1725916716 0.039857 0.193E-02 + 3 -225.1733543299 0.038200 0.659E-04 + 4 -225.1734314386 0.038367 0.114E-05 + 5 -225.1734334712 0.038357 0.317E-07 + 6 -225.1734335284 0.038354 0.832E-09 + 7 -225.1734335299 0.038354 0.196E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 8.871044 GB ] [ VIRT MEM : 14.453804 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 330.755333 s ] [ CPU TIME: 19767.605067 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.871044 GB ] [ VIRT MEM : 14.453804 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 330.755719 s ] [ CPU TIME: 19767.631996 s ] <<<<< .. + +* Energy of state 1 -225.1734335299114 +* S^2 of state 1 0.3835412144423875E-01 +* Saved determinants 2560 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.871056 GB ] [ VIRT MEM : 14.453804 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 331.036565 s ] [ CPU TIME: 19783.655088 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 8.871056 GB ] [ VIRT MEM : 14.453804 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 331.036965 s ] [ CPU TIME: 19783.683629 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 76 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -225.1734335299114 + +.. >>>>> [ RES MEM : 8.871056 GB ] [ VIRT MEM : 14.453804 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 331.047221 s ] [ CPU TIME: 19784.408232 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 8.871056 GB ] [ VIRT MEM : 14.453804 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 331.047613 s ] [ CPU TIME: 19784.436491 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 76 +* pt2_n_tasks_max 1 +* Number of tasks 2560 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.7265464663505554E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.8552125151 0.744E-03 3.0179445182 0.1803190323 60.3417 + 7 -225.8550391013 0.770E-03 3.0180810286 0.1802307966 62.4571 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.875595 GB ] [ VIRT MEM : 14.452663 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 398.134908 s ] [ CPU TIME: 24341.333098 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 8.875595 GB ] [ VIRT MEM : 14.452663 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 398.135283 s ] [ CPU TIME: 24341.356047 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 76 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.3254642799235350 + +Summary at N_det = 2560 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.17343353 +# PT2 -0.68160557 0.00077048 +# rPT2 -0.57751888 0.00065282 +# +# E+PT2 -225.85503910 0.00077048 +# E+rPT2 -225.75095241 0.00065282 +# ============ ============================= + + N_det = 2560 + N_states = 1 + + * State 1 + < S^2 > = 3.835412144423875E-002 + E = -225.173433529911 + Variance = 3.01808102862384 + PT norm = 0.424535977992536 + PT2 = -0.681605571419340 + rPT2 = -0.577518883066840 + E+PT2 = -225.855039101331 +/- 7.704799501308578E-004 + E+rPT2 = -225.750952412978 +/- 6.528214247110573E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.414203312048 + Vee = 239.589707995726 + Vecp = 0.000000000000000E+000 + T = 225.146712065347 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6261 -225.82535676 + -0.6665 -225.83036474 + -0.6993 -225.83632501 + -0.7226 -225.84705781 + -0.7420 -225.85438053 + -0.7576 -225.86094101 + -0.7714 -225.86435918 + =========== =================== + +* Number of unique alpha determinants 980 +* Number of unique beta determinants 980 + +.. >>>>> [ RES MEM : 8.876225 GB ] [ VIRT MEM : 14.452663 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 398.212643 s ] [ CPU TIME: 24346.159452 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5120 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.1086230948567390E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.1735124614 0.038432 0.238E-01 + 2 -225.2347424694 0.040454 0.164E-02 + 3 -225.2355444522 0.038764 0.751E-04 + 4 -225.2356327946 0.039044 0.153E-05 + 5 -225.2356355630 0.039044 0.528E-07 + 6 -225.2356356552 0.039034 0.114E-08 + 7 -225.2356356575 0.039034 0.313E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 8.880997 GB ] [ VIRT MEM : 14.457264 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 398.303614 s ] [ CPU TIME: 24352.502595 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.879807 GB ] [ VIRT MEM : 14.454964 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 398.304199 s ] [ CPU TIME: 24352.544744 s ] <<<<< .. + +* Energy of state 1 -225.2356356574756 +* S^2 of state 1 0.3903397281146177E-01 +* Saved determinants 5120 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.880749 GB ] [ VIRT MEM : 14.458874 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 398.553942 s ] [ CPU TIME: 24363.412196 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 8.880749 GB ] [ VIRT MEM : 14.458874 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 398.554329 s ] [ CPU TIME: 24363.440657 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 93 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -225.2356356574756 + +.. >>>>> [ RES MEM : 8.882236 GB ] [ VIRT MEM : 14.458874 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 398.563026 s ] [ CPU TIME: 24364.063867 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 8.882236 GB ] [ VIRT MEM : 14.458874 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 398.563408 s ] [ CPU TIME: 24364.091775 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 93 +* pt2_n_tasks_max 1 +* Number of tasks 5120 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1225062847137451 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.8364453521 0.725E-03 2.8284494572 0.1476932595 120.3661 + 14 -225.8365070076 0.330E-03 2.8275682910 0.1477368493 122.5676 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.980919 GB ] [ VIRT MEM : 14.550560 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 529.447498 s ] [ CPU TIME: 33735.508928 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 8.980919 GB ] [ VIRT MEM : 14.550560 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 529.447934 s ] [ CPU TIME: 33735.540168 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 93 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.3943341762303880 + +Summary at N_det = 5120 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.23563566 +# PT2 -0.60087135 0.00032972 +# rPT2 -0.52352711 0.00028728 +# +# E+PT2 -225.83650701 0.00032972 +# E+rPT2 -225.75916276 0.00028728 +# ============ ============================= + + N_det = 5120 + N_states = 1 + + * State 1 + < S^2 > = 3.903397281146177E-002 + E = -225.235635657476 + Variance = 2.82756829100550 + PT norm = 0.384365515178264 + PT2 = -0.600871350117316 + rPT2 = -0.523527105107448 + E+PT2 = -225.836507007593 +/- 3.297172704267235E-004 + E+rPT2 = -225.759162762583 +/- 2.872760168324385E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.416311393205 + Vee = 239.493117998005 + Vecp = 0.000000000000000E+000 + T = 225.183208016661 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.5775 -225.83877378 + -0.6261 -225.83293614 + -0.6665 -225.83315489 + -0.6993 -225.83587466 + -0.7226 -225.84236941 + -0.7420 -225.84753124 + -0.7576 -225.85244658 + =========== =================== + +* Number of unique alpha determinants 1775 +* Number of unique beta determinants 1775 + +.. >>>>> [ RES MEM : 8.982834 GB ] [ VIRT MEM : 14.550560 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 529.553409 s ] [ CPU TIME: 33742.980080 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 10240 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.2085396647453308E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.2356741135 0.039009 0.234E-01 + 2 -225.3015413210 0.036615 0.163E-02 + 3 -225.3024440540 0.035020 0.719E-04 + 4 -225.3025423428 0.035116 0.175E-05 + 5 -225.3025454379 0.035104 0.811E-07 + 6 -225.3025455852 0.035093 0.342E-08 + 7 -225.3025455917 0.035094 0.126E-09 + 8 -225.3025455920 0.035094 0.471E-11 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 8.993206 GB ] [ VIRT MEM : 14.559738 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 529.723948 s ] [ CPU TIME: 33755.228514 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.990578 GB ] [ VIRT MEM : 14.555149 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 529.724722 s ] [ CPU TIME: 33755.285021 s ] <<<<< .. + +* Energy of state 1 -225.3025455919541 +* S^2 of state 1 0.3509376532189801E-01 +* Saved determinants 10240 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.989609 GB ] [ VIRT MEM : 14.552433 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 530.181499 s ] [ CPU TIME: 33773.710974 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 8.989609 GB ] [ VIRT MEM : 14.552433 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 530.181912 s ] [ CPU TIME: 33773.740756 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 100 +* pt2_n_tasks_max 2 +* PT2 Energy denominator -225.3025455919541 + +.. >>>>> [ RES MEM : 8.987392 GB ] [ VIRT MEM : 14.550560 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 530.192024 s ] [ CPU TIME: 33774.466623 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 8.987392 GB ] [ VIRT MEM : 14.550560 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 530.192418 s ] [ CPU TIME: 33774.495395 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 100 +* pt2_n_tasks_max 2 +* Number of tasks 10608 +* Number of fragmented tasks 368 +* Number of threads for PT2 72 +* Memory (Gb) 0.2222455322742462 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.8187607655 0.730E-03 2.5902047330 0.1174437741 117.8961 + 8 -225.8213724604 0.100E-02 2.6059530376 0.1179199997 124.2678 + 9 -225.8216854520 0.888E-03 2.6080732137 0.1179719061 139.4630 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 9.154423 GB ] [ VIRT MEM : 14.696537 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 669.710443 s ] [ CPU TIME: 43777.527974 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 9.154423 GB ] [ VIRT MEM : 14.696537 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 669.710859 s ] [ CPU TIME: 43777.557852 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 100 +* pt2_n_tasks_max 2 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.4675545132601303 + +Summary at N_det = 10240 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.30254559 +# PT2 -0.51913986 0.00088778 +# rPT2 -0.46435859 0.00079410 +# +# E+PT2 -225.82168545 0.00088778 +# E+rPT2 -225.76690418 0.00079410 +# ============ ============================= + + N_det = 10240 + N_states = 1 + + * State 1 + < S^2 > = 3.509376532189801E-002 + E = -225.302545591954 + Variance = 2.60807321374284 + PT norm = 0.343470386048643 + PT2 = -0.519139860001502 + rPT2 = -0.464358591814733 + E+PT2 = -225.821685451956 +/- 8.877818483222722E-004 + E+rPT2 = -225.766904183769 +/- 7.941003199492692E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.429582253296 + Vee = 239.399750737621 + Vecp = 0.000000000000000E+000 + T = 225.222936202658 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.5235 -225.82765939 + -0.5775 -225.83247858 + -0.6261 -225.83147637 + -0.6665 -225.83195419 + -0.6993 -225.83383629 + -0.7226 -225.83824715 + -0.7420 -225.84206750 + =========== =================== + +* Number of unique alpha determinants 3151 +* Number of unique beta determinants 3151 + +.. >>>>> [ RES MEM : 9.155346 GB ] [ VIRT MEM : 14.696537 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 669.843493 s ] [ CPU TIME: 43786.897368 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 20480 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.3997549414634705E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.3025592039 0.035107 0.219E-01 + 2 -225.3712896481 0.031254 0.126E-02 + 3 -225.3721625687 0.030009 0.801E-04 + 4 -225.3722729812 0.030092 0.198E-05 + 5 -225.3722766174 0.030081 0.109E-06 + 6 -225.3722768208 0.030071 0.367E-08 + 7 -225.3722768293 0.030070 0.142E-09 + 8 -225.3722768297 0.030070 0.533E-11 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 9.174603 GB ] [ VIRT MEM : 14.719688 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 670.341650 s ] [ CPU TIME: 43822.528774 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 9.166447 GB ] [ VIRT MEM : 14.705818 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 670.343241 s ] [ CPU TIME: 43822.643512 s ] <<<<< .. + +* Energy of state 1 -225.3722768296676 +* S^2 of state 1 0.3007019662132597E-01 +* Saved determinants 20480 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 9.159302 GB ] [ VIRT MEM : 14.696537 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 673.224897 s ] [ CPU TIME: 43864.020941 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 9.159302 GB ] [ VIRT MEM : 14.696537 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 673.225326 s ] [ CPU TIME: 43864.052199 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 +* PT2 Energy denominator -225.3722768296676 + +.. >>>>> [ RES MEM : 9.165218 GB ] [ VIRT MEM : 14.701443 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 673.252074 s ] [ CPU TIME: 43865.961298 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 9.165218 GB ] [ VIRT MEM : 14.701443 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 673.252490 s ] [ CPU TIME: 43865.991553 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 +* Number of tasks 21420 +* Number of fragmented tasks 470 +* Number of threads for PT2 72 +* Memory (Gb) 0.4216868340969085 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.8154205807 0.464E-03 2.3926073236 0.0924581765 157.1572 + 7 -225.8135229742 0.182E-02 2.3821951402 0.0920692532 158.4325 + 8 -225.8137685441 0.151E-02 2.3833426391 0.0921338793 173.4642 + 9 -225.8136645140 0.131E-02 2.3826090300 0.0921206794 186.4577 + 10 -225.8134416000 0.119E-02 2.3811146703 0.0920863703 195.4298 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 9.402122 GB ] [ VIRT MEM : 14.881672 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 868.783999 s ] [ CPU TIME: 57895.756306 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 9.402122 GB ] [ VIRT MEM : 14.881672 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 868.784379 s ] [ CPU TIME: 57895.785571 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.5417843077245177 + +Summary at N_det = 20480 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.37227683 +# PT2 -0.44101944 0.00107872 +# rPT2 -0.40384438 0.00098779 +# +# E+PT2 -225.81329627 0.00107872 +# E+rPT2 -225.77612121 0.00098779 +# ============ ============================= + + N_det = 20480 + N_states = 1 + + * State 1 + < S^2 > = 3.007019662132597E-002 + E = -225.372276829668 + Variance = 2.38050661685416 + PT norm = 0.303402265183892 + PT2 = -0.441019436099687 + rPT2 = -0.403844376183147 + E+PT2 = -225.813296265767 +/- 1.078723158435781E-003 + E+rPT2 = -225.776121205851 +/- 9.877938370370203E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.430451999020 + Vee = 239.297848967571 + Vecp = 0.000000000000000E+000 + T = 225.255976480718 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4644 -225.83763142 + -0.5235 -225.83314844 + -0.5775 -225.83391308 + -0.6261 -225.83296164 + -0.6665 -225.83297276 + -0.6993 -225.83404653 + -0.7226 -225.83698509 + =========== =================== + +* Number of unique alpha determinants 5686 +* Number of unique beta determinants 5690 + +.. >>>>> [ RES MEM : 9.405998 GB ] [ VIRT MEM : 14.881672 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 869.101575 s ] [ CPU TIME: 57918.434782 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 40960 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.7736079022288322E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.3722774080 0.030070 0.189E-01 + 2 -225.4386814236 0.023839 0.101E-02 + 3 -225.4395332866 0.022957 0.863E-04 + 4 -225.4396529929 0.023036 0.203E-05 + 5 -225.4396572230 0.023032 0.125E-06 + 6 -225.4396574707 0.023026 0.533E-08 + 7 -225.4396574831 0.023026 0.241E-09 + 8 -225.4396574837 0.023026 0.120E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 9.441448 GB ] [ VIRT MEM : 14.928070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 870.502281 s ] [ CPU TIME: 58019.033520 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 9.425110 GB ] [ VIRT MEM : 14.900230 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 870.504961 s ] [ CPU TIME: 58019.226272 s ] <<<<< .. + +* Energy of state 1 -225.4396574836856 +* S^2 of state 1 0.2302600715607681E-01 +* Saved determinants 40960 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 9.411812 GB ] [ VIRT MEM : 14.882465 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 872.281062 s ] [ CPU TIME: 58070.215300 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 9.411812 GB ] [ VIRT MEM : 14.882465 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 872.281535 s ] [ CPU TIME: 58070.249778 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 +* PT2 Energy denominator -225.4396574836856 + +.. >>>>> [ RES MEM : 9.418114 GB ] [ VIRT MEM : 14.889805 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 872.304848 s ] [ CPU TIME: 58071.923305 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 9.418114 GB ] [ VIRT MEM : 14.889805 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 872.305317 s ] [ CPU TIME: 58071.957467 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 +* Number of tasks 53587 +* Number of fragmented tasks 10824 +* Number of threads for PT2 72 +* Memory (Gb) 0.8205694377422332 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.8078576387 0.311E-02 2.1225032797 0.0708681348 188.2617 + 7 -225.8079126779 0.129E-02 2.1249533731 0.0708221796 190.8076 + 8 -225.8089632102 0.156E-02 2.1334361817 0.0709401076 219.4961 + 9 -225.8086644105 0.144E-02 2.1321537781 0.0708811758 233.5998 + 11 -225.8082014414 0.142E-02 2.1291855899 0.0708033994 239.4926 + 12 -225.8079548399 0.132E-02 2.1274232561 0.0707670136 266.0617 + 13 -225.8077444752 0.123E-02 2.1259237236 0.0707375216 276.4127 + 14 -225.8076406719 0.108E-02 2.1259337956 0.0707110183 291.1426 + 15 -225.8075947733 0.101E-02 2.1256464659 0.0706996549 302.0795 + 17 -225.8074392704 0.892E-03 2.1253362425 0.0706591674 312.0826 + 18 -225.8075738457 0.852E-03 2.1258620365 0.0706867844 329.8081 + 19 -225.8075178820 0.807E-03 2.1264722521 0.0706454624 352.2036 + 20 -225.8076602205 0.778E-03 2.1272557301 0.0706738358 366.6927 + 22 -225.8078872326 0.659E-03 2.1276982683 0.0707392045 377.9834 + 23 -225.8078872108 0.630E-03 2.1286500307 0.0707084909 400.0572 + 24 -225.8078720628 0.603E-03 2.1278874874 0.0707260175 405.3094 + 25 -225.8078674202 0.578E-03 2.1276565208 0.0707300141 415.4606 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 10.062012 GB ] [ VIRT MEM : 15.456352 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1287.977873 s ] [ CPU TIME: 87894.731961 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 10.062012 GB ] [ VIRT MEM : 15.456352 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1287.978356 s ] [ CPU TIME: 87894.766975 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.6130731036079300 + +Summary at N_det = 40960 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.43965748 +# PT2 -0.36820994 0.00057779 +# rPT2 -0.34388682 0.00053963 +# +# E+PT2 -225.80786742 0.00057779 +# E+rPT2 -225.78354430 0.00053963 +# ============ ============================= + + N_det = 40960 + N_states = 1 + + * State 1 + < S^2 > = 2.302600715607681E-002 + E = -225.439657483686 + Variance = 2.12765652077620 + PT norm = 0.265951149844897 + PT2 = -0.368209936520414 + rPT2 = -0.343886817097023 + E+PT2 = -225.807867420206 +/- 5.777941571684162E-004 + E+rPT2 = -225.783544300783 +/- 5.396263759842550E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.464959472200 + Vee = 239.223917362454 + Vecp = 0.000000000000000E+000 + T = 225.297034904997 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4038 -225.82611949 + -0.4644 -225.83133858 + -0.5235 -225.83105589 + -0.5775 -225.83205794 + -0.6261 -225.83183012 + -0.6665 -225.83201819 + -0.6993 -225.83287477 + =========== =================== + +* Number of unique alpha determinants 10331 +* Number of unique beta determinants 10330 + +.. >>>>> [ RES MEM : 10.073811 GB ] [ VIRT MEM : 15.456352 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1288.677499 s ] [ CPU TIME: 87944.831939 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 81920 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.1503715664148331 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.4396625871 0.023033 0.151E-01 + 2 -225.4998930761 0.016627 0.672E-03 + 3 -225.5006744191 0.016101 0.950E-04 + 4 -225.5007912628 0.016194 0.214E-05 + 5 -225.5007962958 0.016196 0.143E-06 + 6 -225.5007966006 0.016192 0.704E-08 + 7 -225.5007966186 0.016192 0.376E-09 + 8 -225.5007966196 0.016192 0.255E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 10.136845 GB ] [ VIRT MEM : 15.560303 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1293.480025 s ] [ CPU TIME: 88289.738388 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 10.103901 GB ] [ VIRT MEM : 15.504631 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1293.484664 s ] [ CPU TIME: 88290.072062 s ] <<<<< .. + +* Energy of state 1 -225.5007966196197 +* S^2 of state 1 0.1619226797000526E-01 +* Saved determinants 81920 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 10.073616 GB ] [ VIRT MEM : 15.469391 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1295.322958 s ] [ CPU TIME: 88349.370530 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 10.073616 GB ] [ VIRT MEM : 15.469391 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1295.323529 s ] [ CPU TIME: 88349.412243 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 +* PT2 Energy denominator -225.5007966196197 + +.. >>>>> [ RES MEM : 10.094933 GB ] [ VIRT MEM : 15.489906 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1295.363511 s ] [ CPU TIME: 88352.282861 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 10.094933 GB ] [ VIRT MEM : 15.489906 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1295.364090 s ] [ CPU TIME: 88352.324363 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 +* Number of tasks 119136 +* Number of fragmented tasks 16367 +* Number of threads for PT2 72 +* Memory (Gb) 1.618334645032883 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.8056270125 0.782E-03 1.8786095498 0.0542729240 214.0028 + 5 -225.8055131487 0.104E-02 1.8786844490 0.0542249576 220.7368 + 6 -225.8051714898 0.912E-03 1.8756362330 0.0541951219 262.8467 + 7 -225.8059672190 0.131E-02 1.8804856987 0.0543242464 295.1237 + 8 -225.8048675256 0.160E-02 1.8752555104 0.0540788796 412.4676 + 14 -225.8058073338 0.106E-02 1.8794408631 0.0543019564 425.2956 + 15 -225.8058487343 0.990E-03 1.8802081739 0.0542958992 440.5086 + 17 -225.8061133074 0.835E-03 1.8815020045 0.0543549741 462.2326 + 18 -225.8058922831 0.818E-03 1.8797697091 0.0543260605 496.8646 + 19 -225.8060692110 0.794E-03 1.8813048103 0.0543477002 522.9597 + 20 -225.8058576088 0.780E-03 1.8800624985 0.0543070835 550.4567 + 22 -225.8057769851 0.759E-03 1.8789972959 0.0543093309 553.7461 + 23 -225.8057901745 0.699E-03 1.8790157691 0.0543137928 565.7453 + 24 -225.8058434194 0.671E-03 1.8794423394 0.0543202345 616.7929 + 27 -225.8056219350 0.647E-03 1.8776479710 0.0542964268 640.7796 + 28 -225.8056136530 0.623E-03 1.8775184863 0.0542938556 668.6252 + 29 -225.8055370861 0.617E-03 1.8765352408 0.0542995349 683.0971 + 30 -225.8055123977 0.596E-03 1.8760401033 0.0543058184 692.0946 + 31 -225.8054915502 0.577E-03 1.8758580233 0.0543024889 721.4544 + 32 -225.8054372265 0.561E-03 1.8752886004 0.0543008798 730.7613 + 33 -225.8054187938 0.543E-03 1.8757218834 0.0542821840 740.1818 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 10.737347 GB ] [ VIRT MEM : 15.949276 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2062.665351 s ] [ CPU TIME: 143405.662142 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 10.737347 GB ] [ VIRT MEM : 15.949276 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2062.665940 s ] [ CPU TIME: 143405.704147 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.6771478883485255 + +Summary at N_det = 81920 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.50079662 +# PT2 -0.30462217 0.00054296 +# rPT2 -0.28893799 0.00051500 +# +# E+PT2 -225.80541879 0.00054296 +# E+rPT2 -225.78973461 0.00051500 +# ============ ============================= + + N_det = 81920 + N_states = 1 + + * State 1 + < S^2 > = 1.619226797000526E-002 + E = -225.500796619620 + Variance = 1.87572188340499 + PT norm = 0.232985372999415 + PT2 = -0.304622174153760 + rPT2 = -0.288937989057973 + E+PT2 = -225.805418793773 +/- 5.429573253284985E-004 + E+rPT2 = -225.789734608678 +/- 5.150018975490769E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.479527989945 + Vee = 239.138785486991 + Vecp = 0.000000000000000E+000 + T = 225.335596162271 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3439 -225.82228517 + -0.4038 -225.82410069 + -0.4644 -225.82773569 + -0.5235 -225.82854715 + -0.5775 -225.82973886 + -0.6261 -225.82997725 + -0.6665 -225.83035882 + =========== =================== + +* Number of unique beta determinants 18992 +* Number of unique alpha determinants 18981 + +.. >>>>> [ RES MEM : 10.733257 GB ] [ VIRT MEM : 15.936657 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2065.350495 s ] [ CPU TIME: 143597.882926 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 163840 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.2938923276960850 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.5007975470 0.016193 0.111E-01 + 2 -225.5516676493 0.010805 0.446E-03 + 3 -225.5524016046 0.010515 0.928E-04 + 4 -225.5525036336 0.010588 0.237E-05 + 5 -225.5525096975 0.010589 0.186E-06 + 6 -225.5525101099 0.010586 0.967E-08 + 7 -225.5525101375 0.010587 0.553E-09 + 8 -225.5525101392 0.010587 0.430E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 10.864174 GB ] [ VIRT MEM : 16.134174 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2085.555663 s ] [ CPU TIME: 145040.852477 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 10.798332 GB ] [ VIRT MEM : 16.023327 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2085.565132 s ] [ CPU TIME: 145041.533118 s ] <<<<< .. + +* Energy of state 1 -225.5525101391822 +* S^2 of state 1 0.1058659248254737E-01 +* Saved determinants 163840 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 10.727997 GB ] [ VIRT MEM : 15.949593 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2088.963616 s ] [ CPU TIME: 145124.717644 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 10.727997 GB ] [ VIRT MEM : 15.949593 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2088.964439 s ] [ CPU TIME: 145124.776979 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 +* PT2 Energy denominator -225.5525101391822 + +.. >>>>> [ RES MEM : 10.745899 GB ] [ VIRT MEM : 15.967442 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2089.039798 s ] [ CPU TIME: 145130.188260 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 10.745899 GB ] [ VIRT MEM : 15.967442 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2089.040555 s ] [ CPU TIME: 145130.243843 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 +* Number of tasks 243343 +* Number of fragmented tasks 22718 +* Number of threads for PT2 72 +* Memory (Gb) 3.213865059614181 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.8023828357 0.179E-02 1.6255900485 0.0419359191 285.9106 + 4 -225.8021505327 0.123E-02 1.6256593856 0.0418966000 343.9917 + 5 -225.8024500579 0.122E-02 1.6289427350 0.0418910210 360.8834 + 6 -225.8033496276 0.137E-02 1.6325950732 0.0420843689 410.4915 + 7 -225.8037071056 0.117E-02 1.6334669913 0.0421801152 447.2134 + 8 -225.8040722533 0.994E-03 1.6354274583 0.0422324095 479.6064 + 9 -225.8040237766 0.874E-03 1.6339898927 0.0422519530 501.3364 + 10 -225.8034041384 0.985E-03 1.6288450299 0.0421684461 548.3454 + 12 -225.8040066651 0.986E-03 1.6312195778 0.0423095909 559.4104 + 13 -225.8040193438 0.852E-03 1.6312540016 0.0423125644 612.6162 + 14 -225.8044421132 0.898E-03 1.6350169221 0.0423496791 648.5854 + 15 -225.8049109572 0.961E-03 1.6381464231 0.0424147891 672.3384 + 16 -225.8048794285 0.899E-03 1.6372253218 0.0424265495 706.3606 + 18 -225.8050039243 0.841E-03 1.6390527754 0.0424152307 738.1624 + 19 -225.8054260018 0.903E-03 1.6427930614 0.0424618003 802.1394 + 20 -225.8051762140 0.864E-03 1.6412049013 0.0424171948 849.8786 + 21 -225.8052451730 0.824E-03 1.6417603898 0.0424225908 854.4054 + 24 -225.8052635191 0.724E-03 1.6423163738 0.0424183110 881.2674 + 25 -225.8050642051 0.665E-03 1.6410337835 0.0423832434 901.0574 + 26 -225.8049256949 0.653E-03 1.6397080061 0.0423696225 904.8054 + 27 -225.8049937486 0.632E-03 1.6399863512 0.0423855937 949.6694 + 28 -225.8053260404 0.695E-03 1.6423784828 0.0424351085 1008.5739 + 29 -225.8053578431 0.671E-03 1.6419784527 0.0424587339 1026.6364 + 30 -225.8053941452 0.649E-03 1.6427212999 0.0424508071 1105.9214 + 32 -225.8055507948 0.579E-03 1.6437956290 0.0424771693 1121.2998 + 33 -225.8056609311 0.572E-03 1.6445793000 0.0424927817 1124.3625 + 34 -225.8055265027 0.571E-03 1.6437277267 0.0424699072 1178.9204 + 35 -225.8054571426 0.559E-03 1.6437218623 0.0424478733 1307.0834 + 36 -225.8053679292 0.550E-03 1.6432987392 0.0424323724 1311.9864 + 40 -225.8056350268 0.533E-03 1.6447194381 0.0424861196 1457.1921 + 49 -225.8056895810 0.519E-03 1.6444706190 0.0425118703 1478.3584 + 50 -225.8056641616 0.492E-03 1.6439371188 0.0425182162 1547.0294 + 54 -225.8057005257 0.464E-03 1.6438430870 0.0425305934 1595.7894 + 58 -225.8054420657 0.481E-03 1.6427283867 0.0424726878 1621.5502 + 60 -225.8055399711 0.470E-03 1.6433317693 0.0424913221 1644.3502 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 12.426254 GB ] [ VIRT MEM : 17.282646 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3734.092707 s ] [ CPU TIME: 263167.863319 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 12.426254 GB ] [ VIRT MEM : 17.282646 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3734.093490 s ] [ CPU TIME: 263167.918441 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7304487827718225 + +Summary at N_det = 163840 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.55251014 +# PT2 -0.25302983 0.00046976 +# rPT2 -0.24271649 0.00045061 +# +# E+PT2 -225.80553997 0.00046976 +# E+rPT2 -225.79522663 0.00045061 +# ============ ============================= + + N_det = 163840 + N_states = 1 + + * State 1 + < S^2 > = 1.058659248254737E-002 + E = -225.552510139182 + Variance = 1.64333176927917 + PT norm = 0.206134233135279 + PT2 = -0.253029831878851 + rPT2 = -0.242716487439303 + E+PT2 = -225.805539971061 +/- 4.697608500862583E-004 + E+rPT2 = -225.795226626621 +/- 4.506136791176031E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.504937660281 + Vee = 239.075531101591 + Vecp = 0.000000000000000E+000 + T = 225.372546698444 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2889 -225.82406609 + -0.3439 -225.82317637 + -0.4038 -225.82390815 + -0.4644 -225.82630240 + -0.5235 -225.82718226 + -0.5775 -225.82827152 + -0.6261 -225.82865755 + =========== =================== + +* Number of unique beta determinants 36448 +* Number of unique alpha determinants 36440 + +.. >>>>> [ RES MEM : 12.442062 GB ] [ VIRT MEM : 17.294865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3745.330122 s ] [ CPU TIME: 263974.526126 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 327680 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.5814734734594822 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.5525110435 0.010586 0.765E-02 + 2 -225.5923247089 0.006757 0.307E-03 + 3 -225.5930209269 0.006584 0.744E-04 + 4 -225.5931022649 0.006624 0.323E-05 + 5 -225.5931098613 0.006627 0.354E-06 + 6 -225.5931106030 0.006625 0.199E-07 + 7 -225.5931106689 0.006625 0.149E-08 + 8 -225.5931106742 0.006625 0.161E-09 + 9 -225.5931106748 0.006625 0.205E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 12.791332 GB ] [ VIRT MEM : 17.680016 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3844.134312 s ] [ CPU TIME: 271019.922500 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 12.498573 GB ] [ VIRT MEM : 17.312328 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3844.205091 s ] [ CPU TIME: 271025.005234 s ] <<<<< .. + +* Energy of state 1 -225.5931106747513 +* S^2 of state 1 0.6624902492069253E-02 +* Saved determinants 327680 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 12.463051 GB ] [ VIRT MEM : 17.270805 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3850.736349 s ] [ CPU TIME: 271156.020969 s ] <<<<< .. + +* Number of generators 327680 + +.. >>>>> [ RES MEM : 12.463051 GB ] [ VIRT MEM : 17.270805 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3850.737524 s ] [ CPU TIME: 271156.105643 s ] <<<<< .. + +* Number of selectors 327680 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 +* PT2 Energy denominator -225.5931106747513 + +.. >>>>> [ RES MEM : 12.558430 GB ] [ VIRT MEM : 17.369938 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3850.908951 s ] [ CPU TIME: 271168.417378 s ] <<<<< .. + +* Number of generators 327680 + +.. >>>>> [ RES MEM : 12.558430 GB ] [ VIRT MEM : 17.369938 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3850.910066 s ] [ CPU TIME: 271168.497781 s ] <<<<< .. + +* Number of selectors 327680 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 +* Number of tasks 470004 +* Number of fragmented tasks 28840 +* Number of threads for PT2 72 +* Memory (Gb) 6.404925888776779 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.8060598316 0.335E-02 1.4457194256 0.0341904543 484.1397 + 4 -225.8056453362 0.239E-02 1.4335625203 0.0343831342 579.4967 + 5 -225.8059203095 0.183E-02 1.4329618776 0.0344942207 582.3677 + 6 -225.8056282141 0.151E-02 1.4304367509 0.0344631143 657.3567 + 7 -225.8047180700 0.159E-02 1.4238282900 0.0343413760 806.1627 + 9 -225.8048253520 0.134E-02 1.4259160027 0.0343112812 851.4220 + 11 -225.8036732000 0.134E-02 1.4158713136 0.0341771049 903.8157 + 12 -225.8036045473 0.130E-02 1.4152857520 0.0341641484 1003.4927 + 14 -225.8039528902 0.113E-02 1.4194623164 0.0341628041 1078.5767 + 15 -225.8038869834 0.108E-02 1.4198841182 0.0341426359 1089.1440 + 18 -225.8041123009 0.938E-03 1.4213416670 0.0341768454 1162.3499 + 19 -225.8046039619 0.107E-02 1.4248567477 0.0342512897 1262.4608 + 20 -225.8048166371 0.104E-02 1.4267811336 0.0342680464 1352.4756 + 22 -225.8044430400 0.982E-03 1.4241937694 0.0342071843 1435.6388 + 25 -225.8043540691 0.905E-03 1.4241216945 0.0341734408 1478.0168 + 27 -225.8046012702 0.857E-03 1.4260657272 0.0342027309 1581.1966 + 28 -225.8046704031 0.828E-03 1.4268428353 0.0342040976 1644.6486 + 29 -225.8047548935 0.803E-03 1.4275289708 0.0342166218 1699.2657 + 32 -225.8050844831 0.725E-03 1.4295279729 0.0342761050 1826.7596 + 34 -225.8052224987 0.691E-03 1.4310828408 0.0342868649 1893.2863 + 35 -225.8051467034 0.676E-03 1.4307659834 0.0342703696 1944.5686 + 36 -225.8051715353 0.627E-03 1.4306107062 0.0342840864 1962.0447 + 37 -225.8051518635 0.610E-03 1.4300411241 0.0342899899 2057.3416 + 41 -225.8052340680 0.588E-03 1.4317724375 0.0342862398 2207.5547 + 42 -225.8053657341 0.589E-03 1.4327453028 0.0343044507 2226.8367 + 44 -225.8053030700 0.563E-03 1.4322362898 0.0342953351 2238.4467 + 45 -225.8052329385 0.555E-03 1.4321885598 0.0342762548 2250.5367 + 47 -225.8052459401 0.565E-03 1.4324262062 0.0342782555 2277.9067 + 48 -225.8052989278 0.555E-03 1.4327181055 0.0342890392 2369.0438 + 50 -225.8053965110 0.538E-03 1.4333241172 0.0343049783 2523.9648 + 54 -225.8054376501 0.505E-03 1.4330957722 0.0343212481 2579.3137 + 58 -225.8053113054 0.490E-03 1.4317188216 0.0343089239 2738.5377 + 68 -225.8051356958 0.437E-03 1.4314075290 0.0342618825 2827.4638 + 70 -225.8051142303 0.426E-03 1.4310261038 0.0342637503 2878.4287 + 71 -225.8050847329 0.421E-03 1.4307884481 0.0342603448 2906.4697 + 72 -225.8051348506 0.418E-03 1.4311725224 0.0342671742 2963.2516 + 76 -225.8050458332 0.434E-03 1.4303466073 0.0342567019 3019.8745 + 77 -225.8050573059 0.428E-03 1.4303592698 0.0342591453 3042.4880 + 78 -225.8050213805 0.424E-03 1.4301934494 0.0342514416 3120.3541 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.665211 GB ] [ VIRT MEM : 20.434727 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6972.848614 s ] [ CPU TIME: 495168.176123 s ] <<<<< .. + +* Number of generators 327680 + +.. >>>>> [ RES MEM : 16.665211 GB ] [ VIRT MEM : 20.434727 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6972.849774 s ] [ CPU TIME: 495168.259406 s ] <<<<< .. + +* Number of selectors 327680 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7731958379112137 + +Summary at N_det = 327680 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.59311067 +# PT2 -0.21185780 0.00042238 +# rPT2 -0.20484371 0.00040839 +# +# E+PT2 -225.80496847 0.00042238 +# E+rPT2 -225.79795439 0.00040839 +# ============ ============================= + + N_det = 327680 + N_states = 1 + + * State 1 + < S^2 > = 6.624902492069253E-003 + E = -225.593110674751 + Variance = 1.42994523098166 + PT norm = 0.185043655067949 + PT2 = -0.211857798064536 + rPT2 = -0.204843712888062 + E+PT2 = -225.804968472816 +/- 4.223765104603463E-004 + E+rPT2 = -225.797954387639 +/- 4.083926739059412E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.519053146904 + Vee = 239.018305787297 + Vecp = 0.000000000000000E+000 + T = 225.403286963792 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2427 -225.81270812 + -0.2889 -225.81848910 + -0.3439 -225.82019300 + -0.4038 -225.82162188 + -0.4644 -225.82387241 + -0.5235 -225.82499377 + -0.5775 -225.82615367 + =========== =================== + +* Number of unique beta determinants 72286 +* Number of unique alpha determinants 72382 + +.. >>>>> [ RES MEM : 16.736279 GB ] [ VIRT MEM : 20.487331 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7024.955100 s ] [ CPU TIME: 498879.723796 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 655360 +* Number of threads for diagonalization 72 +* Memory(Gb) 1.160751398652792 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.5931106811 0.006625 0.487E-02 + 2 -225.6214420984 0.004195 0.205E-03 + 3 -225.6220729070 0.004094 0.525E-04 + 4 -225.6221370693 0.004114 0.414E-05 + 5 -225.6221465369 0.004120 0.657E-06 + 6 -225.6221478421 0.004118 0.588E-07 + 7 -225.6221480427 0.004120 0.716E-08 + 8 -225.6221480668 0.004121 0.699E-09 + 9 -225.6221480694 0.004121 0.985E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 17.287045 GB ] [ VIRT MEM : 21.190948 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7481.918917 s ] [ CPU TIME: 531372.278706 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 16.701290 GB ] [ VIRT MEM : 20.457050 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7481.989086 s ] [ CPU TIME: 531377.308519 s ] <<<<< .. + +* Energy of state 1 -225.6221480694322 +* S^2 of state 1 0.4120718936517069E-02 +* Saved determinants 655360 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.586464 GB ] [ VIRT MEM : 20.336910 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7494.764725 s ] [ CPU TIME: 531602.078231 s ] <<<<< .. + +* Number of generators 655360 + +.. >>>>> [ RES MEM : 16.586464 GB ] [ VIRT MEM : 20.336910 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7494.766651 s ] [ CPU TIME: 531602.217039 s ] <<<<< .. + +* Number of selectors 655360 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 +* PT2 Energy denominator -225.6221480694322 + +.. >>>>> [ RES MEM : 16.791492 GB ] [ VIRT MEM : 20.534679 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7495.155429 s ] [ CPU TIME: 531630.137971 s ] <<<<< .. + +* Number of generators 655360 + +.. >>>>> [ RES MEM : 16.791492 GB ] [ VIRT MEM : 20.534679 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7495.157302 s ] [ CPU TIME: 531630.272912 s ] <<<<< .. + +* Number of selectors 655360 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 +* Number of tasks 952442 +* Number of fragmented tasks 33906 +* Number of threads for PT2 72 +* Memory (Gb) 12.78708432316780 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.8060754986 0.207E-02 1.2786002204 0.0288954133 951.6905 + 4 -225.8069167230 0.138E-02 1.2828023183 0.0291065797 1010.4315 + 5 -225.8073932702 0.116E-02 1.2841336729 0.0292247625 1075.6035 + 6 -225.8058082347 0.191E-02 1.2728323570 0.0289936240 1186.9935 + 7 -225.8054876623 0.164E-02 1.2695070445 0.0289636654 1269.9375 + 8 -225.8051920331 0.142E-02 1.2671900246 0.0289008563 1321.8065 + 9 -225.8050267885 0.120E-02 1.2643117280 0.0289073023 1444.8375 + 10 -225.8043237229 0.129E-02 1.2582636482 0.0288314220 1482.4447 + 11 -225.8045530466 0.119E-02 1.2601130191 0.0288596742 1513.7044 + 12 -225.8039007609 0.127E-02 1.2549616525 0.0287713629 1860.0754 + 14 -225.8032635526 0.126E-02 1.2499754354 0.0286873891 1876.8245 + 15 -225.8041214554 0.146E-02 1.2570202589 0.0288124346 2159.1288 + 18 -225.8043954583 0.119E-02 1.2577858336 0.0288851408 2275.9545 + 21 -225.8046038386 0.104E-02 1.2586115057 0.0289252447 2286.3015 + 22 -225.8044474481 0.101E-02 1.2571527035 0.0289083623 2310.6336 + 23 -225.8047305529 0.100E-02 1.2580692060 0.0289699881 2454.8864 + 24 -225.8046389564 0.964E-03 1.2572814108 0.0289606511 2472.7404 + 25 -225.8046829084 0.925E-03 1.2575877911 0.0289676730 2559.8845 + 26 -225.8047691675 0.891E-03 1.2583835661 0.0289735932 2606.0315 + 27 -225.8047400613 0.857E-03 1.2582447068 0.0289658901 2652.3955 + 28 -225.8049707908 0.858E-03 1.2590450981 0.0290173282 2961.6224 + 29 -225.8050778686 0.835E-03 1.2592657369 0.0290433229 3075.4645 + 32 -225.8051836183 0.758E-03 1.2604699007 0.0290480574 3100.5970 + 34 -225.8052526511 0.732E-03 1.2605459404 0.0290688623 3374.3924 + 36 -225.8051073388 0.706E-03 1.2592424878 0.0290567763 3480.1976 + 40 -225.8049286616 0.675E-03 1.2582063762 0.0290211700 3538.9904 + 41 -225.8047921264 0.672E-03 1.2572353999 0.0289989328 3652.0774 + 42 -225.8048131333 0.656E-03 1.2573147008 0.0290040424 3738.6705 + 43 -225.8048170579 0.641E-03 1.2578500887 0.0289977144 3893.6005 + 47 -225.8045687688 0.612E-03 1.2556875352 0.0289667987 4074.3607 + 50 -225.8048251913 0.548E-03 1.2569243001 0.0290193701 4188.6384 + 53 -225.8048944363 0.503E-03 1.2573280592 0.0290304656 4265.2646 + 54 -225.8048563842 0.495E-03 1.2571916745 0.0290201306 4352.9015 + 58 -225.8048170903 0.483E-03 1.2571654537 0.0290090238 4618.5547 + 61 -225.8047432743 0.469E-03 1.2566200939 0.0289983310 4825.2733 + 68 -225.8048762606 0.448E-03 1.2579638727 0.0290134117 4844.5394 + 71 -225.8048528742 0.431E-03 1.2575458760 0.0290164054 4997.3505 + 72 -225.8047416647 0.439E-03 1.2566368935 0.0290027980 5074.5304 + 74 -225.8047657034 0.428E-03 1.2567876803 0.0290073227 5227.1814 + 77 -225.8047343124 0.420E-03 1.2563899772 0.0290080571 5346.8255 + 80 -225.8046671545 0.408E-03 1.2558809550 0.0289988739 5447.5904 + 82 -225.8046790036 0.399E-03 1.2560378329 0.0289996815 5664.5653 + 84 -225.8047348893 0.391E-03 1.2563306026 0.0290103456 5672.3214 + 89 -225.8046081012 0.363E-03 1.2553196649 0.0289925825 5764.9004 + 90 -225.8046355840 0.360E-03 1.2554079479 0.0289989011 5768.6254 + 91 -225.8046105702 0.357E-03 1.2551303928 0.0289974697 5854.4460 + 94 -225.8046228523 0.350E-03 1.2551821804 0.0289993039 5870.2274 + 96 -225.8046124734 0.343E-03 1.2550846149 0.0289979524 5910.3717 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 14.638088 GB ] [ VIRT MEM : 17.630741 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13408.528403 s ] [ CPU TIME: 955884.891028 s ] <<<<< .. + +* Number of generators 655360 + +.. >>>>> [ RES MEM : 14.638088 GB ] [ VIRT MEM : 17.630741 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13408.530326 s ] [ CPU TIME: 955885.027678 s ] <<<<< .. + +* Number of selectors 655360 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8039965962754653 + +Summary at N_det = 655360 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.62214807 +# PT2 -0.18246440 0.00034322 +# rPT2 -0.17732242 0.00033355 +# +# E+PT2 -225.80461247 0.00034322 +# E+rPT2 -225.79947049 0.00033355 +# ============ ============================= + + N_det = 655360 + N_states = 1 + + * State 1 + < S^2 > = 4.120718936517069E-003 + E = -225.622148069432 + Variance = 1.25508461490163 + PT norm = 0.170287851498814 + PT2 = -0.182464403968050 + rPT2 = -0.177322416967047 + E+PT2 = -225.804612473400 +/- 3.432180313515516E-004 + E+rPT2 = -225.799470486399 +/- 3.335458837033520E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.544994413138 + Vee = 238.980913667302 + Vecp = 0.000000000000000E+000 + T = 225.437582955340 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2048 -225.80923886 + -0.2427 -225.81115809 + -0.2889 -225.81552587 + -0.3439 -225.81773213 + -0.4038 -225.81945615 + -0.4644 -225.82163539 + -0.5235 -225.82289562 + =========== =================== + +* Number of unique beta determinants 146836 +* Number of unique alpha determinants 147234 + +.. >>>>> [ RES MEM : 14.872135 GB ] [ VIRT MEM : 17.885895 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13616.375339 s ] [ CPU TIME: 970306.806956 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 1310720 +* Number of threads for diagonalization 72 +* Memory(Gb) 2.331323932856321 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.6221481303 0.004121 0.290E-02 + 2 -225.6397782979 0.003179 0.117E-03 + 3 -225.6402953876 0.003142 0.154E-04 + 4 -225.6403369444 0.003165 0.276E-05 + 5 -225.6403426404 0.003166 0.493E-06 + 6 -225.6403434734 0.003165 0.643E-07 + 7 -225.6403436344 0.003168 0.691E-08 + 8 -225.6403436588 0.003169 0.833E-09 + 9 -225.6403436623 0.003169 0.111E-09 + 10 -225.6403436628 0.003169 0.146E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 16.251160 GB ] [ VIRT MEM : 19.500668 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15669.441183 s ] [ CPU TIME: 1112358.689482 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 15.020916 GB ] [ VIRT MEM : 18.034348 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15669.587444 s ] [ CPU TIME: 1112365.210477 s ] <<<<< .. + +* Energy of state 1 -225.6403436627712 +* S^2 of state 1 0.3169111657181257E-02 +* Saved determinants 1310720 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 14.691113 GB ] [ VIRT MEM : 17.694443 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15695.338310 s ] [ CPU TIME: 1112787.645630 s ] <<<<< .. + +* Number of generators 1310715 + +.. >>>>> [ RES MEM : 14.691113 GB ] [ VIRT MEM : 17.694443 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15695.341698 s ] [ CPU TIME: 1112787.887590 s ] <<<<< .. + +* Number of selectors 1310715 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 +* PT2 Energy denominator -225.6403436627712 + +.. >>>>> [ RES MEM : 15.100880 GB ] [ VIRT MEM : 18.108540 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15696.249578 s ] [ CPU TIME: 1112839.110523 s ] <<<<< .. + +* Number of generators 1310715 + +.. >>>>> [ RES MEM : 15.100880 GB ] [ VIRT MEM : 18.108540 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15696.252922 s ] [ CPU TIME: 1112839.350967 s ] <<<<< .. + +* Number of selectors 1310715 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 +* Number of tasks 1810391 +* Number of fragmented tasks 37190 +* Number of threads for PT2 72 +* Memory (Gb) 25.55140105653554 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.8025043026 0.325E-02 1.1289620619 0.0254990633 1740.7044 + 4 -225.8031328237 0.233E-02 1.1302498899 0.0256552808 1888.0144 + 5 -225.8025319268 0.188E-02 1.1273343156 0.0255834459 2064.2420 + 6 -225.8052028092 0.319E-02 1.1456285069 0.0259852678 2336.1724 + 8 -225.8039345855 0.292E-02 1.1340112394 0.0258358285 2647.8364 + 11 -225.8044049547 0.209E-02 1.1361430527 0.0259401611 3004.8815 + 12 -225.8046484150 0.192E-02 1.1361808590 0.0260138744 3087.0854 + 13 -225.8048151994 0.177E-02 1.1374125355 0.0260313046 3439.1456 + 14 -225.8048862989 0.164E-02 1.1380946284 0.0260414165 3531.0584 + 15 -225.8055361548 0.166E-02 1.1435846489 0.0261215214 3678.4344 + 18 -225.8052635340 0.135E-02 1.1405181257 0.0261138116 3683.2774 + 19 -225.8051041876 0.128E-02 1.1394640025 0.0260870435 4117.1184 + 20 -225.8053466515 0.118E-02 1.1419015615 0.0261003262 4197.3444 + 22 -225.8053258699 0.108E-02 1.1417584176 0.0260942403 4270.7164 + 23 -225.8050716840 0.106E-02 1.1397278018 0.0260605024 4468.8314 + 25 -225.8050558755 0.962E-03 1.1389855847 0.0260695519 4941.5688 + 27 -225.8051043429 0.913E-03 1.1395612004 0.0260762990 4966.9224 + 28 -225.8050053039 0.885E-03 1.1391091582 0.0260614413 5543.8413 + 31 -225.8051057420 0.818E-03 1.1405755271 0.0260599746 5611.6355 + 32 -225.8051606428 0.793E-03 1.1412941286 0.0260594150 5870.4104 + 34 -225.8051667697 0.752E-03 1.1418200483 0.0260497036 6070.5667 + 37 -225.8053626224 0.707E-03 1.1435131641 0.0260745892 6246.9245 + 39 -225.8054491785 0.677E-03 1.1441536822 0.0260830464 6581.2600 + 40 -225.8054999377 0.661E-03 1.1447517116 0.0260873124 6725.6964 + 41 -225.8054875316 0.645E-03 1.1449537031 0.0260794196 6780.1583 + 42 -225.8053109216 0.654E-03 1.1437473275 0.0260503201 6857.4564 + 43 -225.8053811482 0.642E-03 1.1441867024 0.0260633878 7120.6659 + 47 -225.8055710487 0.589E-03 1.1460598324 0.0260806101 7523.0284 + 48 -225.8056787851 0.534E-03 1.1470057929 0.0260934274 7983.7744 + 54 -225.8057654530 0.516E-03 1.1477356869 0.0261005092 8195.2664 + 58 -225.8058647740 0.491E-03 1.1483952219 0.0261178880 8386.3454 + 60 -225.8058478519 0.464E-03 1.1480864384 0.0261197764 8434.6405 + 63 -225.8058509552 0.443E-03 1.1483165768 0.0261151298 8998.5594 + 69 -225.8061968292 0.413E-03 1.1512369339 0.0261580835 9046.0314 + 71 -225.8061376625 0.408E-03 1.1508556741 0.0261473972 9302.8607 + 74 -225.8060854293 0.396E-03 1.1505433760 0.0261369252 9713.9684 + 78 -225.8059185395 0.385E-03 1.1494486853 0.0261104374 9766.9381 + 80 -225.8059179358 0.377E-03 1.1496817039 0.0261062367 10131.3204 + 84 -225.8061241767 0.379E-03 1.1515165516 0.0261281060 10227.5684 + 86 -225.8060306759 0.389E-03 1.1506204271 0.0261188341 10594.5134 + 87 -225.8060181778 0.384E-03 1.1504952607 0.0261179459 10656.7464 + 88 -225.8060356128 0.380E-03 1.1505458703 0.0261216707 10700.4524 + 91 -225.8059620054 0.373E-03 1.1499782002 0.0261136516 10998.4934 + 96 -225.8060456046 0.371E-03 1.1506645459 0.0261233628 11064.7998 + 97 -225.8060269226 0.367E-03 1.1504686599 0.0261208242 11112.3204 + 98 -225.8060087478 0.350E-03 1.1504108469 0.0261164001 11316.6834 + 100 -225.8060779972 0.348E-03 1.1511447240 0.0261230985 11367.3024 + 103 -225.8059918920 0.342E-03 1.1505950247 0.0261094644 11676.3754 + 104 -225.8060314557 0.341E-03 1.1507506129 0.0261179915 11756.2904 + 105 -225.8059463408 0.348E-03 1.1500053556 0.0261080816 11773.4455 + 108 -225.8059108447 0.339E-03 1.1498149874 0.0261042082 12076.9633 + 112 -225.8058582821 0.334E-03 1.1491925971 0.0261025127 12135.2654 + 113 -225.8058380917 0.332E-03 1.1489854224 0.0261007573 12363.5954 + 116 -225.8059224454 0.328E-03 1.1496965627 0.0261105135 12550.0785 + 117 -225.8059219672 0.325E-03 1.1496601368 0.0261110104 12556.6525 + 120 -225.8058850278 0.327E-03 1.1496846774 0.0261014903 12711.7609 + 123 -225.8058170293 0.322E-03 1.1491521839 0.0260913218 13017.9323 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 18.308620 GB ] [ VIRT MEM : 21.144176 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 28720.182984 s ] [ CPU TIME: 2047290.140757 s ] <<<<< .. + +* Number of generators 1310715 + +.. >>>>> [ RES MEM : 18.308620 GB ] [ VIRT MEM : 21.144176 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 28720.186233 s ] [ CPU TIME: 2047290.371164 s ] <<<<< .. + +* Number of selectors 1310715 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8221653052449290 + +Summary at N_det = 1310720 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.64034366 +# PT2 -0.16547337 0.00032249 +# rPT2 -0.16126573 0.00031429 +# +# E+PT2 -225.80581703 0.00032249 +# E+rPT2 -225.80160939 0.00031429 +# ============ ============================= + + N_det = 1310720 + N_states = 1 + + * State 1 + < S^2 > = 3.169111657181257E-003 + E = -225.640343662771 + Variance = 1.14915218390378 + PT norm = 0.161528083654984 + PT2 = -0.165473366506683 + rPT2 = -0.161265730437046 + E+PT2 = -225.805817029278 +/- 3.224897762870311E-004 + E+rPT2 = -225.801609393208 +/- 3.142895465857778E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.549613223058 + Vee = 238.948593952616 + Vecp = 0.000000000000000E+000 + T = 225.456325886607 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1773 -225.82309156 + -0.2048 -225.81430661 + -0.2427 -225.81319752 + -0.2889 -225.81572076 + -0.3439 -225.81738730 + -0.4038 -225.81885364 + -0.4644 -225.82074678 + =========== =================== + +* Number of unique beta determinants 296245 +* Number of unique alpha determinants 297553 + +.. >>>>> [ RES MEM : 19.383709 GB ] [ VIRT MEM : 22.462212 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 29446.800705 s ] [ CPU TIME: 2096370.659511 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 2621440 +* Number of threads for diagonalization 72 +* Memory(Gb) 4.674945630133152 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.6403436907 0.003169 0.181E-02 + 2 -225.6505749194 0.003573 0.117E-03 + 3 -225.6509476292 0.003631 0.242E-04 + 4 -225.6509991709 0.003675 0.632E-05 + 5 -225.6510115421 0.003671 0.893E-06 + 6 -225.6510138907 0.003677 0.131E-06 + 7 -225.6510143464 0.003683 0.208E-07 + 8 -225.6510144155 0.003686 0.269E-08 + 9 -225.6510144266 0.003685 0.441E-09 + 10 -225.6510144284 0.003684 0.702E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 21.702866 GB ] [ VIRT MEM : 25.202259 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 36660.961310 s ] [ CPU TIME: 2583293.266794 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 19.241966 GB ] [ VIRT MEM : 22.271095 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 36661.269320 s ] [ CPU TIME: 2583299.969467 s ] <<<<< .. + +* Energy of state 1 -225.6510144283693 +* S^2 of state 1 0.3684375274338281E-02 +* Saved determinants 2621440 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 18.795410 GB ] [ VIRT MEM : 21.830166 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 36710.188283 s ] [ CPU TIME: 2584012.740423 s ] <<<<< .. + +* Number of generators 2621377 + +.. >>>>> [ RES MEM : 18.795410 GB ] [ VIRT MEM : 21.830166 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 36710.194412 s ] [ CPU TIME: 2584013.174816 s ] <<<<< .. + +* Number of selectors 2621377 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 +* PT2 Energy denominator -225.6510144283693 + +.. >>>>> [ RES MEM : 19.588871 GB ] [ VIRT MEM : 22.625927 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 36712.191992 s ] [ CPU TIME: 2584104.738957 s ] <<<<< .. + +* Number of generators 2621377 + +.. >>>>> [ RES MEM : 19.588871 GB ] [ VIRT MEM : 22.625927 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 36712.197717 s ] [ CPU TIME: 2584104.744608 s ] <<<<< .. + +* Number of selectors 2621377 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 +* Number of tasks 3466598 +* Number of fragmented tasks 39091 +* Number of threads for PT2 72 +* Memory (Gb) 51.07999644722790 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -225.8028054999 0.149E-02 1.0613691186 0.0237508027 3229.6213 + 4 -225.8012582988 0.180E-02 1.0534545518 0.0234922308 3303.3540 + 5 -225.8015094094 0.139E-02 1.0592119679 0.0234747691 4193.6082 + 6 -225.8020869792 0.127E-02 1.0617284843 0.0236097123 4493.6771 + 8 -225.8033370748 0.139E-02 1.0704097290 0.0237963013 4801.9842 + 9 -225.8035233945 0.123E-02 1.0714595125 0.0238335550 5415.6774 + 11 -225.8041018894 0.147E-02 1.0757314834 0.0239176413 5527.4454 + 12 -225.8044408157 0.138E-02 1.0764570106 0.0240020101 5759.1414 + 13 -225.8060399986 0.196E-02 1.0875469710 0.0242447154 5888.9212 + 14 -225.8055255621 0.189E-02 1.0830117481 0.0241781227 6405.7572 + 15 -225.8055570174 0.176E-02 1.0830720639 0.0241857799 7129.0871 + 18 -225.8059187660 0.148E-02 1.0871686175 0.0242161359 7179.3972 + 19 -225.8060034050 0.136E-02 1.0875262554 0.0242262655 7697.4732 + 20 -225.8061504779 0.130E-02 1.0880176112 0.0242603214 8374.8573 + 24 -225.8059128863 0.116E-02 1.0874948359 0.0242050029 8617.5243 + 25 -225.8056994298 0.113E-02 1.0856184735 0.0241772276 8728.2812 + 27 -225.8058930573 0.105E-02 1.0874418759 0.0241934240 9562.9316 + 28 -225.8057103674 0.102E-02 1.0855587785 0.0241748716 9973.9495 + 29 -225.8059280071 0.101E-02 1.0873727267 0.0242034295 10310.2951 + 31 -225.8060189386 0.948E-03 1.0879950686 0.0242142852 10364.0466 + 32 -225.8057932332 0.945E-03 1.0867450326 0.0241722539 11501.9544 + 34 -225.8054248858 0.941E-03 1.0837929731 0.0241190608 11568.5484 + 35 -225.8055200084 0.918E-03 1.0852649280 0.0241212683 11605.5479 + 36 -225.8054056643 0.899E-03 1.0846314033 0.0241004385 11893.2878 + 37 -225.8055035816 0.880E-03 1.0853041299 0.0241159778 12143.3445 + 39 -225.8054631818 0.831E-03 1.0848466248 0.0241094892 12466.4252 + 41 -225.8053310309 0.799E-03 1.0829590703 0.0241069027 12760.3411 + 42 -225.8054428895 0.767E-03 1.0833119079 0.0241330035 13098.0266 + 44 -225.8056974692 0.753E-03 1.0849629480 0.0241731766 13461.0352 + 45 -225.8056680179 0.737E-03 1.0844550846 0.0241742344 13504.2411 + 46 -225.8056793200 0.720E-03 1.0846599704 0.0241739105 13598.1768 + 47 -225.8056481641 0.688E-03 1.0845417970 0.0241682304 14381.6840 + 50 -225.8056338971 0.666E-03 1.0842973228 0.0241686589 14654.5832 + 51 -225.8054677158 0.623E-03 1.0829406800 0.0241469341 14775.6212 + 52 -225.8054062376 0.614E-03 1.0827929728 0.0241331133 14810.5853 + 53 -225.8053414233 0.606E-03 1.0823798934 0.0241220794 15159.8663 + 54 -225.8052733303 0.598E-03 1.0815846692 0.0241172068 15900.9082 + 58 -225.8052821354 0.573E-03 1.0818213992 0.0241131360 15952.2626 + 59 -225.8053055999 0.564E-03 1.0818237362 0.0241208536 16184.0151 + 63 -225.8054950617 0.563E-03 1.0830940455 0.0241524042 16530.8415 + 64 -225.8055619107 0.558E-03 1.0836091169 0.0241610005 17159.1151 + 69 -225.8054996930 0.531E-03 1.0831718000 0.0241472361 17200.5596 + 70 -225.8054355310 0.527E-03 1.0826454572 0.0241384187 17262.6072 + 71 -225.8055174115 0.526E-03 1.0833638517 0.0241480251 17636.3550 + 72 -225.8056207922 0.529E-03 1.0843288521 0.0241581750 17718.7915 + 73 -225.8055739638 0.524E-03 1.0838642602 0.0241534986 17831.4615 + 74 -225.8054536967 0.531E-03 1.0829157125 0.0241368364 17906.4558 + 75 -225.8055313727 0.529E-03 1.0835571923 0.0241455763 18002.4812 + 76 -225.8054595247 0.527E-03 1.0831356456 0.0241337659 18369.0461 + 77 -225.8054609717 0.496E-03 1.0833083914 0.0241301162 18542.0412 + 78 -225.8054493583 0.490E-03 1.0829465193 0.0241333060 18627.2452 + 79 -225.8053628541 0.491E-03 1.0822780986 0.0241212835 18721.0932 + 80 -225.8054064663 0.487E-03 1.0825838616 0.0241276128 19792.0733 + 85 -225.8055128920 0.465E-03 1.0832998608 0.0241441659 19912.4003 + 86 -225.8055678367 0.463E-03 1.0836803899 0.0241527275 20125.3303 + 87 -225.8055557085 0.458E-03 1.0836484220 0.0241492578 20488.4145 + 88 -225.8057027292 0.470E-03 1.0849859643 0.0241680608 21001.0713 + 95 -225.8056805338 0.444E-03 1.0846722234 0.0241661781 21011.1553 + 96 -225.8056815883 0.440E-03 1.0846547211 0.0241671272 21478.9237 + 100 -225.8056547162 0.417E-03 1.0841492412 0.0241696461 21741.5845 + 103 -225.8056449993 0.407E-03 1.0839276125 0.0241715694 22174.2265 + 104 -225.8056169564 0.404E-03 1.0837340443 0.0241678627 22175.2955 + 105 -225.8056274501 0.401E-03 1.0838181659 0.0241688492 22241.5522 + 106 -225.8056483769 0.397E-03 1.0840602687 0.0241700949 23039.7361 + 108 -225.8056408559 0.390E-03 1.0841978376 0.0241647821 23329.7799 + 112 -225.8056213978 0.374E-03 1.0839980888 0.0241602431 23711.9653 + 116 -225.8057451560 0.367E-03 1.0847069787 0.0241807750 24946.5733 + 126 -225.8058814811 0.341E-03 1.0858614641 0.0241992186 25082.7433 + 127 -225.8059082517 0.339E-03 1.0860369816 0.0242035822 25413.6914 + 131 -225.8058926373 0.330E-03 1.0857781536 0.0242033106 25577.3193 + 132 -225.8058759209 0.328E-03 1.0857049328 0.0242002919 25601.4853 + 133 -225.8058555347 0.326E-03 1.0855498264 0.0241964969 25974.2932 + 135 -225.8058369093 0.323E-03 1.0855194686 0.0241919828 26089.5592 + 137 -225.8058014643 0.320E-03 1.0852032385 0.0241874308 26651.2942 + 139 -225.8057509471 0.313E-03 1.0847480944 0.0241820169 27256.5521 + 144 -225.8057682445 0.310E-03 1.0850004271 0.0241826795 27409.4811 + 146 -225.8057468352 0.308E-03 1.0849209262 0.0241775509 27874.5113 + 147 -225.8057450494 0.306E-03 1.0849484314 0.0241762195 27887.0806 + 150 -225.8058235107 0.306E-03 1.0855831308 0.0241848697 28240.9543 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 20.639290 GB ] [ VIRT MEM : 23.599274 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 64965.570279 s ] [ CPU TIME: 4610727.394079 s ] <<<<< .. + +* Number of generators 2621377 + +.. >>>>> [ RES MEM : 20.639290 GB ] [ VIRT MEM : 23.599274 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 64965.576789 s ] [ CPU TIME: 4610727.399996 s ] <<<<< .. + +* Number of selectors 2621377 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8333720830507787 + +Summary at N_det = 2621440 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -225.65101443 +# PT2 -0.15486245 0.00030571 +# rPT2 -0.15120469 0.00029849 +# +# E+PT2 -225.80587688 0.00030571 +# E+rPT2 -225.80221912 0.00029849 +# ============ ============================= + + N_det = 2621440 + N_states = 1 + + * State 1 + < S^2 > = 3.684375274338281E-003 + E = -225.651014428369 + Variance = 1.08605777462330 + PT norm = 0.155533775388245 + PT2 = -0.154862448137284 + rPT2 = -0.151204692424665 + E+PT2 = -225.805876876507 +/- 3.057126874879292E-004 + E+rPT2 = -225.802219120794 +/- 2.984919419648588E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 163.504349721064 + Ven = -853.543896819691 + Vee = 238.922823780262 + Vecp = 0.000000000000000E+000 + T = 225.465708889996 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1613 -225.81138256 + -0.1773 -225.81870386 + -0.2048 -225.81462981 + -0.2427 -225.81360063 + -0.2889 -225.81553680 + -0.3439 -225.81698632 + -0.4038 -225.81832136 + =========== =================== + +* Number of unique beta determinants 540547 +* Number of unique alpha determinants 541423 + +.. >>>>> [ RES MEM : 22.757992 GB ] [ VIRT MEM : 26.205204 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 66984.538523 s ] [ CPU TIME: 4744374.363060 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5242880 +* Number of threads for diagonalization 72 +* Memory(Gb) 9.133582085371017 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -225.6510144365 0.003684 0.143E-02 + 2 -225.6582785174 0.004908 0.143E-03 + 3 -225.6585245744 0.005011 0.284E-04 + 4 -225.6585800876 0.005080 0.454E-05 diff --git a/imidazole/cc-pvtz/slurm-487477.out b/imidazole/cc-pvtz/slurm-487477.out index 0a5f5b0..5bcf3cb 100644 --- a/imidazole/cc-pvtz/slurm-487477.out +++ b/imidazole/cc-pvtz/slurm-487477.out @@ -487,3 +487,40319 @@ 1.15 % in 238 seconds 1.20 % in 249 seconds 1.26 % in 259 seconds + 1.34 % in 269 seconds + 1.40 % in 279 seconds + 1.46 % in 289 seconds + 1.51 % in 301 seconds + 1.56 % in 311 seconds + 1.61 % in 321 seconds + 1.70 % in 331 seconds + 1.72 % in 342 seconds + 1.79 % in 352 seconds + 1.89 % in 364 seconds + 1.95 % in 374 seconds + 2.01 % in 384 seconds + 2.09 % in 394 seconds + 2.15 % in 404 seconds + 2.21 % in 414 seconds + 2.26 % in 424 seconds + 2.34 % in 434 seconds + 2.40 % in 444 seconds + 2.47 % in 454 seconds + 2.53 % in 464 seconds + 2.62 % in 474 seconds + 2.66 % in 484 seconds + 2.74 % in 494 seconds + 2.78 % in 504 seconds + 2.83 % in 514 seconds + 2.90 % in 524 seconds + 2.95 % in 534 seconds + 3.02 % in 544 seconds + 3.08 % in 554 seconds + 3.16 % in 564 seconds + 3.23 % in 574 seconds + 3.29 % in 586 seconds + 3.36 % in 596 seconds + 3.42 % in 606 seconds + 3.49 % in 616 seconds + 3.55 % in 626 seconds + 3.62 % in 636 seconds + 3.68 % in 646 seconds + 3.74 % in 656 seconds + 3.78 % in 666 seconds + 3.83 % in 676 seconds + 3.90 % in 686 seconds + 3.98 % in 696 seconds + 4.04 % in 706 seconds + 4.10 % in 716 seconds + 4.17 % in 726 seconds + 4.27 % in 736 seconds + 4.31 % in 746 seconds + 4.36 % in 756 seconds + 4.45 % in 766 seconds + 4.51 % in 776 seconds + 4.58 % in 786 seconds + 4.62 % in 796 seconds + 4.69 % in 807 seconds + 4.76 % in 817 seconds + 4.84 % in 828 seconds + 4.90 % in 838 seconds + 4.97 % in 848 seconds + 5.03 % in 858 seconds + 5.08 % in 868 seconds + 5.15 % in 879 seconds + 5.21 % in 890 seconds + 5.30 % in 900 seconds + 5.36 % in 911 seconds + 5.46 % in 921 seconds + 5.53 % in 932 seconds + 5.58 % in 942 seconds + 5.66 % in 952 seconds + 5.69 % in 962 seconds + 5.76 % in 972 seconds + 5.81 % in 983 seconds + 5.87 % in 993 seconds + 5.93 % in 1003 seconds + 5.98 % in 1013 seconds + 6.05 % in 1023 seconds + 6.11 % in 1033 seconds + 6.16 % in 1043 seconds + 6.22 % in 1053 seconds + 6.29 % in 1063 seconds + 6.34 % in 1073 seconds + 6.44 % in 1083 seconds + 6.53 % in 1093 seconds + 6.59 % in 1103 seconds + 6.65 % in 1114 seconds + 6.72 % in 1124 seconds + 6.77 % in 1135 seconds + 6.81 % in 1146 seconds + 6.90 % in 1156 seconds + 6.95 % in 1166 seconds + 7.02 % in 1176 seconds + 7.08 % in 1186 seconds + 7.10 % in 1199 seconds + 7.12 % in 1210 seconds + 7.15 % in 1223 seconds + 7.15 % in 1249 seconds + 7.16 % in 1273 seconds + 10.00 % in 2 seconds +60.00 % in 12 seconds + 10.00 % in 2 seconds +60.00 % in 12 seconds + 10.00 % in 1 seconds +60.00 % in 12 seconds + 10.00 % in 1 seconds +60.00 % in 12 seconds + 10.00 % in 1 seconds +60.00 % in 12 seconds + 10.00 % in 1 seconds +60.00 % in 12 seconds + 10.00 % in 1 seconds +60.00 % in 11 seconds + 10.00 % in 1 seconds +60.00 % in 12 seconds + 0.00 % in 4 seconds + 0.01 % in 14 seconds + 0.02 % in 25 seconds + 0.03 % in 35 seconds + 0.05 % in 45 seconds + 0.06 % in 55 seconds + 0.07 % in 65 seconds + 0.10 % in 75 seconds + 0.12 % in 85 seconds + 0.14 % in 96 seconds + 0.16 % in 106 seconds + 0.18 % in 116 seconds + 0.20 % in 128 seconds + 0.22 % in 138 seconds + 0.24 % in 148 seconds + 0.26 % in 166 seconds + 0.28 % in 177 seconds + 0.30 % in 190 seconds + 0.30 % in 204 seconds + 0.32 % in 214 seconds + 0.34 % in 226 seconds + 0.38 % in 236 seconds + 0.41 % in 246 seconds + 0.44 % in 256 seconds + 0.47 % in 266 seconds + 0.49 % in 276 seconds + 0.52 % in 286 seconds + 0.54 % in 296 seconds + 0.56 % in 306 seconds + 0.59 % in 316 seconds + 0.63 % in 326 seconds + 0.66 % in 336 seconds + 0.70 % in 346 seconds + 0.71 % in 356 seconds + 0.75 % in 366 seconds + 0.78 % in 376 seconds + 0.83 % in 386 seconds + 0.87 % in 396 seconds + 0.89 % in 406 seconds + 0.94 % in 416 seconds + 0.99 % in 428 seconds + 1.01 % in 438 seconds + 1.06 % in 448 seconds + 1.08 % in 458 seconds + 1.11 % in 469 seconds + 1.16 % in 479 seconds + 1.20 % in 489 seconds + 1.23 % in 499 seconds + 1.28 % in 509 seconds + 1.30 % in 519 seconds + 1.33 % in 529 seconds + 1.36 % in 540 seconds + 1.40 % in 551 seconds + 1.43 % in 561 seconds + 1.45 % in 571 seconds + 1.48 % in 581 seconds + 1.52 % in 592 seconds + 1.55 % in 602 seconds + 1.58 % in 612 seconds + 1.60 % in 622 seconds + 1.63 % in 632 seconds + 1.66 % in 643 seconds + 1.69 % in 653 seconds + 1.73 % in 663 seconds + 1.77 % in 673 seconds + 1.80 % in 683 seconds + 1.82 % in 693 seconds + 1.84 % in 703 seconds + 1.88 % in 713 seconds + 1.92 % in 723 seconds + 1.95 % in 733 seconds + 1.97 % in 743 seconds + 2.00 % in 753 seconds + 2.05 % in 763 seconds + 2.09 % in 773 seconds + 2.11 % in 783 seconds + 2.14 % in 793 seconds + 2.18 % in 803 seconds + 2.22 % in 813 seconds + 2.24 % in 824 seconds + 2.28 % in 834 seconds + 2.30 % in 844 seconds + 2.34 % in 854 seconds + 2.37 % in 864 seconds + 2.41 % in 874 seconds + 2.44 % in 884 seconds + 2.47 % in 895 seconds + 2.49 % in 906 seconds + 2.53 % in 916 seconds + 2.55 % in 926 seconds + 2.60 % in 936 seconds + 2.64 % in 946 seconds + 2.67 % in 956 seconds + 2.70 % in 968 seconds + 2.72 % in 978 seconds + 2.74 % in 988 seconds + 2.77 % in 998 seconds + 2.82 % in 1008 seconds + 2.85 % in 1018 seconds + 2.89 % in 1028 seconds + 2.93 % in 1038 seconds + 2.98 % in 1049 seconds + 3.00 % in 1059 seconds + 3.02 % in 1069 seconds + 3.06 % in 1079 seconds + 3.10 % in 1089 seconds + 3.14 % in 1099 seconds + 3.17 % in 1109 seconds + 3.21 % in 1119 seconds + 3.25 % in 1129 seconds + 3.28 % in 1140 seconds + 3.31 % in 1150 seconds + 3.35 % in 1161 seconds + 3.37 % in 1171 seconds + 3.39 % in 1181 seconds + 3.42 % in 1191 seconds + 3.45 % in 1201 seconds + 3.47 % in 1211 seconds + 3.51 % in 1221 seconds + 3.53 % in 1231 seconds + 3.57 % in 1241 seconds + 3.61 % in 1251 seconds + 3.64 % in 1262 seconds + 3.67 % in 1272 seconds + 3.70 % in 1282 seconds + 3.74 % in 1292 seconds + 3.78 % in 1304 seconds + 3.82 % in 1314 seconds + 3.84 % in 1324 seconds + 3.87 % in 1334 seconds + 3.91 % in 1344 seconds + 3.93 % in 1354 seconds + 3.97 % in 1365 seconds + 4.00 % in 1375 seconds + 4.04 % in 1385 seconds + 4.07 % in 1395 seconds + 4.11 % in 1405 seconds + 4.15 % in 1417 seconds + 4.18 % in 1427 seconds + 4.21 % in 1437 seconds + 4.25 % in 1448 seconds + 4.27 % in 1458 seconds + 4.31 % in 1468 seconds + 4.34 % in 1480 seconds + 4.37 % in 1491 seconds + 4.42 % in 1501 seconds + 4.46 % in 1511 seconds + 4.48 % in 1521 seconds + 4.51 % in 1531 seconds + 4.55 % in 1541 seconds + 4.59 % in 1551 seconds + 4.62 % in 1563 seconds + 4.64 % in 1573 seconds + 4.68 % in 1583 seconds + 4.71 % in 1593 seconds + 4.74 % in 1603 seconds + 4.77 % in 1613 seconds + 4.79 % in 1624 seconds + 4.83 % in 1634 seconds + 4.86 % in 1644 seconds + 4.90 % in 1654 seconds + 4.92 % in 1664 seconds + 4.96 % in 1674 seconds + 4.99 % in 1684 seconds + 5.03 % in 1694 seconds + 5.06 % in 1704 seconds + 5.08 % in 1715 seconds + 5.11 % in 1725 seconds + 5.15 % in 1735 seconds + 5.17 % in 1745 seconds + 5.19 % in 1755 seconds + 5.22 % in 1765 seconds + 5.26 % in 1776 seconds + 5.30 % in 1786 seconds + 5.33 % in 1796 seconds + 5.35 % in 1807 seconds + 5.40 % in 1817 seconds + 5.45 % in 1828 seconds + 5.49 % in 1838 seconds + 5.52 % in 1848 seconds + 5.54 % in 1858 seconds + 5.56 % in 1868 seconds + 5.60 % in 1878 seconds + 5.63 % in 1888 seconds + 5.65 % in 1898 seconds + 5.68 % in 1908 seconds + 5.72 % in 1918 seconds + 5.76 % in 1928 seconds + 5.79 % in 1938 seconds + 5.82 % in 1948 seconds + 5.85 % in 1958 seconds + 5.89 % in 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2375 seconds + 7.25 % in 2387 seconds + 7.28 % in 2397 seconds + 7.30 % in 2407 seconds + 7.31 % in 2418 seconds + 7.32 % in 2432 seconds + 7.33 % in 2443 seconds + 7.33 % in 2459 seconds + 7.34 % in 2472 seconds + 7.35 % in 2488 seconds + 7.36 % in 2500 seconds + 7.38 % in 2534 seconds + 7.38 % in 2561 seconds + 7.38 % in 2604 seconds + 7.39 % in 2665 seconds + 7.39 % in 2692 seconds + 5.56 % in 3 seconds +16.67 % in 19 seconds +33.33 % in 31 seconds +50.00 % in 41 seconds +66.67 % in 52 seconds +83.33 % in 63 seconds + 5.56 % in 4 seconds +16.67 % in 19 seconds +33.33 % in 31 seconds +50.00 % in 41 seconds +66.67 % in 51 seconds +83.33 % in 62 seconds + 5.56 % in 4 seconds +16.67 % in 19 seconds +33.33 % in 30 seconds +50.00 % in 41 seconds +66.67 % in 51 seconds +83.33 % in 61 seconds + 5.56 % in 3 seconds +16.67 % in 18 seconds +33.33 % in 30 seconds +50.00 % in 40 seconds +66.67 % in 50 seconds +83.33 % in 60 seconds + 5.56 % in 4 seconds +16.67 % in 19 seconds +33.33 % in 30 seconds +50.00 % in 40 seconds +66.67 % in 50 seconds +83.33 % in 60 seconds + 5.56 % in 4 seconds +16.67 % in 19 seconds +33.33 % in 30 seconds +50.00 % in 40 seconds +66.67 % in 51 seconds +83.33 % in 61 seconds + 5.56 % in 3 seconds +16.67 % in 18 seconds +33.33 % in 29 seconds +50.00 % in 39 seconds +66.67 % in 50 seconds +83.33 % in 60 seconds + 5.56 % in 4 seconds +16.67 % in 18 seconds +33.33 % in 29 seconds +50.00 % in 40 seconds +66.67 % in 50 seconds +83.33 % in 60 seconds + 0.00 % in 9 seconds + 0.00 % in 21 seconds + 0.00 % in 32 seconds + 0.00 % in 42 seconds + 0.00 % in 58 seconds + 0.00 % in 80 seconds + 0.01 % in 90 seconds + 0.01 % in 102 seconds + 0.01 % in 115 seconds + 0.01 % in 131 seconds + 0.01 % in 154 seconds + 0.01 % in 168 seconds + 0.01 % in 179 seconds + 0.02 % in 193 seconds + 0.02 % in 207 seconds + 0.02 % in 219 seconds + 0.02 % in 229 seconds + 0.03 % in 239 seconds + 0.03 % in 249 seconds + 0.04 % in 259 seconds + 0.05 % in 269 seconds + 0.06 % in 279 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determinants n_det_max ++ python2 /tmpdir/veril/qp2/external/ezfio/Python/ezfio.py set determinants n_det_max ++ return 0 ++ qp run fci ++ case $1 in ++ which qp_run ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' imidazole +++ qp_run fci imidazole + 0.00 % in 2 seconds +35.66 % in 12 seconds +51.68 % in 22 seconds +67.97 % in 32 seconds +83.67 % in 42 seconds +97.78 % in 52 seconds + 50.00 % in 8 seconds + 16.67 % in 4 seconds + 9.09 % in 4 seconds + 4.76 % in 3 seconds + 2.44 % in 4 seconds + 1.23 % in 4 seconds + 0.62 % in 4 seconds +85.09 % in 14 seconds + 0.31 % in 4 seconds +35.20 % in 14 seconds +72.59 % in 24 seconds + 0.16 % in 4 seconds +12.32 % in 14 seconds +32.14 % in 24 seconds +50.23 % in 34 seconds +69.58 % in 44 seconds +89.70 % in 54 seconds + 0.08 % in 5 seconds + 7.03 % in 15 seconds +14.99 % in 25 seconds +23.81 % in 35 seconds + 0.04 % in 5 seconds + 2.69 % in 15 seconds + 6.95 % in 25 seconds +10.66 % in 35 seconds +14.10 % in 45 seconds +18.63 % in 55 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1 seconds + 16.67 % in 0 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 0.00 % in 5 seconds + 0.02 % in 15 seconds + 0.06 % in 25 seconds + 0.09 % in 36 seconds + 0.15 % in 46 seconds + 0.19 % in 56 seconds + 0.23 % in 66 seconds + 0.27 % in 76 seconds + 0.30 % in 86 seconds + 0.35 % in 96 seconds + 0.40 % in 107 seconds + 0.45 % in 118 seconds + 0.48 % in 128 seconds + 0.54 % in 139 seconds + 0.59 % in 149 seconds + 0.64 % in 159 seconds + 0.70 % in 169 seconds + 0.76 % in 179 seconds + 0.81 % in 190 seconds + 0.88 % in 200 seconds + 0.94 % in 210 seconds + 0.97 % in 220 seconds + 1.03 % in 230 seconds + 1.10 % in 240 seconds + 1.15 % in 251 seconds + 1.22 % in 261 seconds + 1.27 % in 272 seconds + 1.36 % in 282 seconds + 1.43 % in 292 seconds + 1.48 % in 304 seconds + 1.55 % in 314 seconds + 1.65 % in 325 seconds + 1.73 % in 335 seconds + 1.77 % in 345 seconds + 1.85 % in 355 seconds + 1.91 % in 365 seconds + 1.97 % in 375 seconds + 2.03 % in 385 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10.00 % in 1 seconds +80.00 % in 11 seconds + 10.00 % in 1 seconds + 10.00 % in 2 seconds + 10.00 % in 2 seconds + 10.00 % in 1 seconds +70.00 % in 11 seconds + 10.00 % in 1 seconds +70.00 % in 11 seconds + 10.00 % in 1 seconds +70.00 % in 11 seconds + 10.00 % in 2 seconds + 10.00 % in 1 seconds + 10.00 % in 1 seconds + 0.00 % in 6 seconds + 0.01 % in 20 seconds + 0.02 % in 30 seconds + 0.03 % in 40 seconds + 0.05 % in 50 seconds + 0.06 % in 60 seconds + 0.07 % in 70 seconds + 0.09 % in 80 seconds + 0.11 % in 91 seconds + 0.14 % in 101 seconds + 0.16 % in 111 seconds + 0.19 % in 123 seconds + 0.22 % in 134 seconds + 0.23 % in 144 seconds + 0.24 % in 160 seconds + 0.26 % in 170 seconds + 0.27 % in 181 seconds + 0.30 % in 191 seconds + 0.32 % in 202 seconds + 0.34 % in 212 seconds + 0.37 % in 222 seconds + 0.40 % in 232 seconds + 0.44 % in 242 seconds + 0.47 % in 252 seconds + 0.50 % in 262 seconds + 0.52 % in 272 seconds + 0.56 % in 282 seconds + 0.60 % in 292 seconds + 0.64 % in 302 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