diff --git a/benzene/cc-pvdz/benzene.restart2.nofci.out b/benzene/cc-pvdz/benzene.restart2.nofci.out index 3586e52..7759a19 100644 --- a/benzene/cc-pvdz/benzene.restart2.nofci.out +++ b/benzene/cc-pvdz/benzene.restart2.nofci.out @@ -499,3 +499,31 @@ Summary at N_det = 83885883 * Number of unique beta determinants 13494337 * Number of unique alpha determinants 13838024 + +.. >>>>> [ RES MEM : 78.611374 GB ] [ VIRT MEM : 84.003284 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 624952.792379 s ] [ CPU TIME: ************** s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 167750559 +* Number of threads for diagonalization 64 +* Memory(Gb) 91.33614299073815 + Using swap space to reduce RAM + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -231.4469531055 0.008873 0.467E-03 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 117.648800 GB ] [ VIRT MEM : 138.695381 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 894540.259357 s ] [ CPU TIME: ************** s ] <<<<< .. + +Program exited with code 174. +Wall time: 248:29:17 + diff --git a/furan/6-31g/furan.ang b/furan/6-31g/furan.ang new file mode 100644 index 0000000..2d64383 --- /dev/null +++ b/furan/6-31g/furan.ang @@ -0,0 +1,11 @@ + 9 + + C 0.00000000 1.09204092 -0.31777753 + C 0.00000000 -1.09204092 -0.31777753 + C 0.00000000 0.71623383 0.98604985 + C 0.00000000 -0.71623383 0.98604985 + O 0.00000000 0.00000000 -1.13214994 + H 0.00000000 2.04440888 -0.81369302 + H 0.00000000 -2.04440888 -0.81369302 + H 0.00000000 1.37146217 1.83713421 + H 0.00000000 -1.37146217 1.83713421 diff --git a/furan/6-31g/furan.fc.out b/furan/6-31g/furan.fc.out new file mode 100644 index 0000000..fb5125f --- /dev/null +++ b/furan/6-31g/furan.fc.out @@ -0,0 +1,5 @@ +Core : (1, 2, 3, 4, 5) +Inactive +Active : (6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53) +Virtual +Deleted diff --git a/furan/6-31g/furan.fci.out b/furan/6-31g/furan.fci.out new file mode 100644 index 0000000..3fb0ee4 --- /dev/null +++ b/furan/6-31g/furan.fci.out @@ -0,0 +1,4198 @@ +Date: 14/12/2020 22:04:14 +=============== +Quantum Package +=============== + +Git Commit: Fix space in size for EZFIO.cfg +Git Date : Fri Oct 16 14:24:01 2020 +0200 +Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b +EZFIO Dir : furan + + +Task server running : tcp://172.28.1.83:41279 +* mo_num 53 +.. >>>>> [ IO READ: mo_class ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019234 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.045943 s ] [ CPU TIME: 3.746950 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_two_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019234 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.065470 s ] [ CPU TIME: 4.878043 s ] <<<<< .. + +* N_int 1 + MO map initialized: 1024596 +.. >>>>> [ IO READ: io_ao_two_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019436 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.078201 s ] [ CPU TIME: 5.634164 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019436 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.081689 s ] [ CPU TIME: 5.846222 s ] <<<<< .. + + AO map initialized : 1024596 +.. >>>>> [ IO READ: ao_power ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019566 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.097887 s ] [ CPU TIME: 6.821087 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_prim_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019600 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.101476 s ] [ CPU TIME: 7.049559 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_expo ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019619 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.105968 s ] [ CPU TIME: 7.329862 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_coef ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019642 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.109360 s ] [ CPU TIME: 7.538537 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_nucl ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019798 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.130240 s ] [ CPU TIME: 8.891378 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_integrals_threshold ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019798 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.131535 s ] [ CPU TIME: 8.976029 s ] <<<<< .. + + Providing the AO integrals +.. >>>>> [ IO READ: nucl_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.021271 GB ] [ VIRT MEM : 5.066597 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.206831 s ] [ CPU TIME: 12.932451 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_label ] <<<<< .. + +.. >>>>> [ RES MEM : 0.021427 GB ] [ VIRT MEM : 5.066597 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.210653 s ] [ CPU TIME: 13.172233 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_charge ] <<<<< .. + +.. >>>>> [ RES MEM : 0.021454 GB ] [ VIRT MEM : 5.066597 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.223382 s ] [ CPU TIME: 13.971450 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.021465 GB ] [ VIRT MEM : 5.066597 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.226723 s ] [ CPU TIME: 14.180837 s ] <<<<< .. + + +Nuclear Coordinates (Angstroms) +=============================== + +================ ============ ============ ============ ============ + Atom Charge X Y Z +================ ============ ============ ============ ============ +C 6.000000 0.000000 1.092041 -0.317778 +C 6.000000 0.000000 -1.092041 -0.317778 +C 6.000000 0.000000 0.716234 0.986050 +C 6.000000 0.000000 -0.716234 0.986050 +O 8.000000 0.000000 0.000000 -1.132150 +H 1.000000 0.000000 2.044409 -0.813693 +H 1.000000 0.000000 -2.044409 -0.813693 +H 1.000000 0.000000 1.371462 1.837134 +H 1.000000 0.000000 -1.371462 1.837134 +================ ============ ============ ============ ============ + + Sorting the map + AO integrals provided: + Size of AO map : 7.19726371765137 MB + Number of AO integrals : 580388 + cpu time : 53.1622110000000 s + wall time : 0.862008094787598 s ( x 61.6725194594598 ) + + AO -> MO integrals transformation + --------------------------------- + + Read mo_coef +.. >>>>> [ IO READ: mo_integrals_threshold ] <<<<< .. + +.. >>>>> [ RES MEM : 0.030472 GB ] [ VIRT MEM : 5.134045 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1.032900 s ] [ CPU TIME: 64.800016 s ] <<<<< .. + + Buffers : 4.587036 MB / core + Molecular integrals provided: + Size of MO map 11.3928489685059 MB + Number of MO integrals: 591273 + cpu time : 75.0081670000000 s + wall time : 1.31757998466492 s ( x 56.9287389555146 ) +.. >>>>> [ IO READ: n_states ] <<<<< .. + +.. >>>>> [ RES MEM : 0.343559 GB ] [ VIRT MEM : 5.623501 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.314270 s ] [ CPU TIME: 137.370668 s ] <<<<< .. + + * mo_label Canonical +.. >>>>> [ IO READ: read_wf ] <<<<< .. + +.. >>>>> [ RES MEM : 0.343559 GB ] [ VIRT MEM : 5.623501 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.316386 s ] [ CPU TIME: 137.518195 s ] <<<<< .. + +* Number of determinants 1 +* Dimension of the psi arrays 100000 +.. >>>>> [ IO READ: elec_beta_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.344276 GB ] [ VIRT MEM : 5.623501 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.329678 s ] [ CPU TIME: 138.445788 s ] <<<<< .. + +.. >>>>> [ IO READ: elec_alpha_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.344276 GB ] [ VIRT MEM : 5.623501 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.330484 s ] [ CPU TIME: 138.502106 s ] <<<<< .. + +.. >>>>> [ IO READ: do_pt2 ] <<<<< .. + +.. >>>>> [ RES MEM : 0.345783 GB ] [ VIRT MEM : 5.625000 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.350005 s ] [ CPU TIME: 139.866127 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.346001 GB ] [ VIRT MEM : 5.625000 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.376964 s ] [ CPU TIME: 141.738377 s ] <<<<< .. + +.. >>>>> [ IO READ: selection_factor ] <<<<< .. + +.. >>>>> [ RES MEM : 0.346001 GB ] [ VIRT MEM : 5.625000 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.377803 s ] [ CPU TIME: 141.797136 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_max ] <<<<< .. + +.. >>>>> [ RES MEM : 0.346596 GB ] [ VIRT MEM : 5.626499 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.378960 s ] [ CPU TIME: 141.878578 s ] <<<<< .. + +.. >>>>> [ IO READ: s2_eig ] <<<<< .. + +.. >>>>> [ RES MEM : 0.347958 GB ] [ VIRT MEM : 5.626499 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.380457 s ] [ CPU TIME: 141.978641 s ] <<<<< .. + +.. >>>>> [ IO READ: variance_max ] <<<<< .. + +.. >>>>> [ RES MEM : 0.347958 GB ] [ VIRT MEM : 5.626499 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.381304 s ] [ CPU TIME: 142.038243 s ] <<<<< .. + +.. >>>>> [ IO READ: distributed_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 0.347958 GB ] [ VIRT MEM : 5.626499 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.398143 s ] [ CPU TIME: 143.215920 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_max_full ] <<<<< .. + +.. >>>>> [ RES MEM : 0.347958 GB ] [ VIRT MEM : 5.626499 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.398962 s ] [ CPU TIME: 143.274478 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_integrals_e_n ] <<<<< .. + +.. >>>>> [ RES MEM : 0.423168 GB ] [ VIRT MEM : 7.501499 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.503903 s ] [ CPU TIME: 150.752956 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_integrals_e_n ] <<<<< .. + +.. >>>>> [ RES MEM : 0.423168 GB ] [ VIRT MEM : 7.501499 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.548632 s ] [ CPU TIME: 153.920617 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_integrals_kinetic ] <<<<< .. + +.. >>>>> [ RES MEM : 0.424957 GB ] [ VIRT MEM : 7.567719 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.570737 s ] [ CPU TIME: 154.949435 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_integrals_kinetic ] <<<<< .. + +.. >>>>> [ RES MEM : 0.424957 GB ] [ VIRT MEM : 7.567719 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.572046 s ] [ CPU TIME: 155.042109 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_one_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.425201 GB ] [ VIRT MEM : 7.567719 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.576768 s ] [ CPU TIME: 155.350035 s ] <<<<< .. + + Providing the one-electron integrals +.. >>>>> [ IO READ: do_pseudo ] <<<<< .. + +.. >>>>> [ RES MEM : 0.425201 GB ] [ VIRT MEM : 7.567719 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.585648 s ] [ CPU TIME: 155.970629 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_relative_error ] <<<<< .. + +.. >>>>> [ RES MEM : 0.425400 GB ] [ VIRT MEM : 7.567719 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.589448 s ] [ CPU TIME: 156.237302 s ] <<<<< .. + +.. >>>>> [ IO READ: correlation_energy_ratio_max ] <<<<< .. + +.. >>>>> [ RES MEM : 0.425400 GB ] [ VIRT MEM : 7.567719 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.590259 s ] [ CPU TIME: 156.294479 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.425400 GB ] [ VIRT MEM : 7.567719 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.591546 s ] [ CPU TIME: 156.385237 s ] <<<<< .. + + Read n_states_diag +.. >>>>> [ IO READ: io_nuclear_repulsion ] <<<<< .. + +.. >>>>> [ RES MEM : 0.425400 GB ] [ VIRT MEM : 7.567719 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.592776 s ] [ CPU TIME: 156.472857 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.425400 GB ] [ VIRT MEM : 7.567719 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.593140 s ] [ CPU TIME: 156.498958 s ] <<<<< .. + +* Nuclear repulsion energy 161.1082297787890 +.. >>>>> [ IO READ: weight_one_e_dm ] <<<<< .. + +.. >>>>> [ RES MEM : 0.425400 GB ] [ VIRT MEM : 7.567719 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.594366 s ] [ CPU TIME: 156.586088 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_max ] <<<<< .. + +.. >>>>> [ RES MEM : 0.429485 GB ] [ VIRT MEM : 7.575539 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.602154 s ] [ CPU TIME: 157.142433 s ] <<<<< .. + +.. >>>>> [ IO READ: threshold_generators ] <<<<< .. + +.. >>>>> [ RES MEM : 0.429485 GB ] [ VIRT MEM : 7.575539 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.602961 s ] [ CPU TIME: 157.200149 s ] <<<<< .. + +* Target maximum memory (GB) 170 +.. >>>>> [ IO READ: threshold_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 0.429485 GB ] [ VIRT MEM : 7.575539 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.619272 s ] [ CPU TIME: 158.355977 s ] <<<<< .. + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 0.429913 GB ] [ VIRT MEM : 7.575539 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.668573 s ] [ CPU TIME: 161.841615 s ] <<<<< .. + +* Energy of state 1 -228.5239900739183 +* S^2 of state 1 0.000000000000000 +* Saved determinants 1 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 1 +* Number of unique alpha determinants 1 +.. >>>>> [ IO READ: weight_selection ] <<<<< .. + +.. >>>>> [ RES MEM : 0.430183 GB ] [ VIRT MEM : 7.579704 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.723180 s ] [ CPU TIME: 165.711345 s ] <<<<< .. + + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +.. >>>>> [ IO READ: pseudo_sym ] <<<<< .. + +.. >>>>> [ RES MEM : 0.430183 GB ] [ VIRT MEM : 7.579704 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.724039 s ] [ CPU TIME: 165.772862 s ] <<<<< .. + +.. >>>>> [ IO READ: h0_type ] <<<<< .. + +.. >>>>> [ RES MEM : 0.430183 GB ] [ VIRT MEM : 7.579704 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.724938 s ] [ CPU TIME: 165.837046 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.430183 GB ] [ VIRT MEM : 7.579704 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.725315 s ] [ CPU TIME: 165.864481 s ] <<<<< .. + +* Number of generators 1 + +.. >>>>> [ RES MEM : 0.430183 GB ] [ VIRT MEM : 7.579704 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.725692 s ] [ CPU TIME: 165.891625 s ] <<<<< .. + +* Number of selectors 1 +* Number of comb teeth 1 +* Number of core MOs 5 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.5239900739183 +* Estimated memory/thread (Gb) 0.1043081283569336E-06 +* Number of virtual MOs 0 +* Number of active MOs 48 + Active MOs: + 6 7 8 9 10 11 + 12 13 14 15 16 17 + 18 19 20 21 22 23 + 24 25 26 27 28 29 + 30 31 32 33 34 35 + 36 37 38 39 40 41 + 42 43 44 45 46 47 + 48 49 50 51 52 53 +* Number of inactive MOs 0 +.. >>>>> [ IO READ: pert_2rdm ] <<<<< .. + +.. >>>>> [ RES MEM : 0.432598 GB ] [ VIRT MEM : 7.585957 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.759758 s ] [ CPU TIME: 167.621483 s ] <<<<< .. + +.. >>>>> [ IO READ: pruning ] <<<<< .. + +.. >>>>> [ RES MEM : 0.432846 GB ] [ VIRT MEM : 7.585957 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.936875 s ] [ CPU TIME: 179.640244 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.432846 GB ] [ VIRT MEM : 7.585957 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.941128 s ] [ CPU TIME: 179.935479 s ] <<<<< .. + +* Number of generators 1 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Saved determinants 5 +* Number of unique beta determinants 4 +* Number of unique alpha determinants 4 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.432892 GB ] [ VIRT MEM : 7.585964 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.157733 s ] [ CPU TIME: 194.729278 s ] <<<<< .. + +* Number of selectors 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.2912798453604483E-11 + +Summary at N_det = 5 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.52399007 +# PT2 -0.60193038 0.00000000 +# rPT2 -0.44884624 0.00000000 +# +# E+PT2 -229.12592046 0.00000000 +# E+rPT2 -228.97283631 0.00000000 +# ============ ============================= + + N_det = 5 + N_states = 1 + + * State 1 + < S^2 > = 0.000000000000000E+000 + E = -228.523990073918 + Variance = 1.34446756383607 + PT norm = 0.584004653699243 + PT2 = -0.601930382959834 + rPT2 = -0.448846240005695 + E+PT2 = -229.125920456878 +/- 0.000000000000000E+000 + E+rPT2 = -228.972836313924 +/- 0.000000000000000E+000 + + ----- +.. >>>>> [ IO READ: io_mo_integrals_pseudo ] <<<<< .. + +.. >>>>> [ RES MEM : 0.432892 GB ] [ VIRT MEM : 7.585964 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.159499 s ] [ CPU TIME: 194.855826 s ] <<<<< .. + + Energy components + ================= + + Vnn : Nucleus-Nucleus potential energy + Ven : Electron-Nucleus potential energy + Vee : Electron-Electron potential energy + Vecp : Potential energy of the pseudo-potentials + T : Electronic kinetic energy + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.395913627544 + Vee = 239.114616192791 + Vecp = 0.000000000000000E+000 + T = 228.649077582045 + + +.. >>>>> [ IO READ: energy_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 0.433552 GB ] [ VIRT MEM : 7.585964 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.177467 s ] [ CPU TIME: 196.114931 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 0.433552 GB ] [ VIRT MEM : 7.585964 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.180652 s ] [ CPU TIME: 196.333435 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 0.433552 GB ] [ VIRT MEM : 7.585964 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.184142 s ] [ CPU TIME: 196.572118 s ] <<<<< .. + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 0.433964 GB ] [ VIRT MEM : 7.585964 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.207172 s ] [ CPU TIME: 198.186210 s ] <<<<< .. + +* Energy of state 1 -228.5474997080522 +* S^2 of state 1 0.1674054687649811E-01 +* Saved determinants 5 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 4 +* Number of unique alpha determinants 4 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.434132 GB ] [ VIRT MEM : 7.585964 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.270057 s ] [ CPU TIME: 202.636922 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 0.434132 GB ] [ VIRT MEM : 7.585964 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.270447 s ] [ CPU TIME: 202.664893 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.5474997080522 + +.. >>>>> [ RES MEM : 0.436646 GB ] [ VIRT MEM : 7.591373 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.275637 s ] [ CPU TIME: 203.032224 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 0.436646 GB ] [ VIRT MEM : 7.591373 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.276034 s ] [ CPU TIME: 203.060503 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 5 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1576246134936809E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 4 -229.0991087761 0.00 1.3074795228 0.2751443446 0.0897 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.437637 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.379594 s ] [ CPU TIME: 209.495424 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 0.437637 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.379988 s ] [ CPU TIME: 209.522737 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.5154545129083560E-01 + +Summary at N_det = 5 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.54749971 +# PT2 -0.55160907 0.00000000 +# rPT2 -0.43258559 0.00000000 +# +# E+PT2 -229.09910878 0.00000000 +# E+rPT2 -228.98008530 0.00000000 +# ============ ============================= + + N_det = 5 + N_states = 1 + + * State 1 + < S^2 > = 1.674054687649811E-002 + E = -228.547499708052 + Variance = 1.30747952275042 + PT norm = 0.524542033242225 + PT2 = -0.551609068054861 + rPT2 = -0.432585589525165 + E+PT2 = -229.099108776107 +/- 0.000000000000000E+000 + E+rPT2 = -228.980085297577 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.360534679662 + Vee = 239.040381233163 + Vecp = 0.000000000000000E+000 + T = 228.664423959658 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4488 -229.17293157 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 0.438248 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.419565 s ] [ CPU TIME: 212.241076 s ] <<<<< .. + +* Energy of state 1 -228.5608491130544 +* S^2 of state 1 0.3788739703921844E-01 +* Saved determinants 10 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 7 +* Number of unique alpha determinants 8 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.438427 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.476643 s ] [ CPU TIME: 216.258208 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 0.438427 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.477041 s ] [ CPU TIME: 216.286586 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.5608491130544 + +.. >>>>> [ RES MEM : 0.438427 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.480337 s ] [ CPU TIME: 216.519830 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 0.438427 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.480725 s ] [ CPU TIME: 216.547616 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 10 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1608791574835777E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 9 -229.0874091739 0.00 1.2810239657 0.2488421921 0.1847 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.438919 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.679191 s ] [ CPU TIME: 229.951265 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 0.438919 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.679580 s ] [ CPU TIME: 229.979705 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8039090457123423E-01 + +Summary at N_det = 10 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.56084911 +# PT2 -0.52656006 0.00000000 +# rPT2 -0.42163859 0.00000000 +# +# E+PT2 -229.08740917 0.00000000 +# E+rPT2 -228.98248770 0.00000000 +# ============ ============================= + + N_det = 10 + N_states = 1 + + * State 1 + < S^2 > = 3.788739703921844E-002 + E = -228.560849113054 + Variance = 1.28102396571869 + PT norm = 0.498840848502636 + PT2 = -0.526560060826974 + rPT2 = -0.421638589842042 + E+PT2 = -229.087409173881 +/- 0.000000000000000E+000 + E+rPT2 = -228.982487702896 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.323834033710 + Vee = 238.987090146456 + Vecp = 0.000000000000000E+000 + T = 228.667664995410 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4326 -229.07501961 + -0.4488 -229.13558885 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 0.438957 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.720403 s ] [ CPU TIME: 232.842497 s ] <<<<< .. + +* Energy of state 1 -228.5707973904942 +* S^2 of state 1 0.2133286491026041E-01 +* Saved determinants 20 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 11 +* Number of unique alpha determinants 10 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.439056 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.771718 s ] [ CPU TIME: 236.425608 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 0.439056 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.772120 s ] [ CPU TIME: 236.454268 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.5707973904942 + +.. >>>>> [ RES MEM : 0.439056 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.775339 s ] [ CPU TIME: 236.681881 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 0.439056 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.775719 s ] [ CPU TIME: 236.709075 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 20 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1673882454633713E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 19 -229.0790751817 0.00 1.2537410527 0.2351212463 0.1285 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.439182 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.917430 s ] [ CPU TIME: 245.854560 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 0.439182 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.917824 s ] [ CPU TIME: 245.882668 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1021262694686911 + +Summary at N_det = 20 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.57079739 +# PT2 -0.50827779 0.00000000 +# rPT2 -0.41152056 0.00000000 +# +# E+PT2 -229.07907518 0.00000000 +# E+rPT2 -228.98231795 0.00000000 +# ============ ============================= + + N_det = 20 + N_states = 1 + + * State 1 + < S^2 > = 2.133286491026041E-002 + E = -228.570797390494 + Variance = 1.25374105266756 + PT norm = 0.484893025646720 + PT2 = -0.508277791173657 + rPT2 = -0.411520563416515 + E+PT2 = -229.079075181668 +/- 0.000000000000000E+000 + E+rPT2 = -228.982317953911 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.381011941484 + Vee = 239.001658924766 + Vecp = 0.000000000000000E+000 + T = 228.700325847435 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4216 -228.97541392 + -0.4326 -229.02700094 + -0.4488 -229.09219443 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 0.440395 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.958447 s ] [ CPU TIME: 248.720305 s ] <<<<< .. + +* Energy of state 1 -228.5835624319038 +* S^2 of state 1 0.1624874300979929E-01 +* Saved determinants 40 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 17 +* Number of unique alpha determinants 17 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.440475 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.012320 s ] [ CPU TIME: 252.489791 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 0.440475 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.012702 s ] [ CPU TIME: 252.517234 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.5835624319038 + +.. >>>>> [ RES MEM : 0.440475 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.016054 s ] [ CPU TIME: 252.753926 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 0.440475 GB ] [ VIRT MEM : 7.592152 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.016436 s ] [ CPU TIME: 252.781322 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 40 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1804064214229584E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 39 -229.0677502729 0.00 1.2166595463 0.2183515312 0.1630 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.441257 GB ] [ VIRT MEM : 7.592293 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.192731 s ] [ CPU TIME: 264.189326 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 0.441257 GB ] [ VIRT MEM : 7.592293 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.193149 s ] [ CPU TIME: 264.219371 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1303596555569246 + +Summary at N_det = 40 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.58356243 +# PT2 -0.48418784 0.00000000 +# rPT2 -0.39741226 0.00000000 +# +# E+PT2 -229.06775027 0.00000000 +# E+rPT2 -228.98097470 0.00000000 +# ============ ============================= + + N_det = 40 + N_states = 1 + + * State 1 + < S^2 > = 1.624874300979929E-002 + E = -228.583562431904 + Variance = 1.21665954628651 + PT norm = 0.467280998089805 + PT2 = -0.484187841005006 + rPT2 = -0.397412264535612 + E+PT2 = -229.067750272909 +/- 0.000000000000000E+000 + E+rPT2 = -228.980974696439 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.458861608921 + Vee = 239.024370744704 + Vecp = 0.000000000000000E+000 + T = 228.742698653524 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4115 -228.94313690 + -0.4216 -228.95545764 + -0.4326 -228.98877849 + -0.4488 -229.04530710 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 0.442238 GB ] [ VIRT MEM : 7.604176 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.238364 s ] [ CPU TIME: 267.392686 s ] <<<<< .. + +* Energy of state 1 -228.5979216848747 +* S^2 of state 1 0.8315359434275417E-02 +* Saved determinants 80 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 33 +* Number of unique alpha determinants 32 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.442421 GB ] [ VIRT MEM : 7.604176 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.291877 s ] [ CPU TIME: 271.163197 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 0.442421 GB ] [ VIRT MEM : 7.604176 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.292271 s ] [ CPU TIME: 271.192017 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.5979216848747 + +.. >>>>> [ RES MEM : 0.442421 GB ] [ VIRT MEM : 7.604176 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.296048 s ] [ CPU TIME: 271.462918 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 0.442421 GB ] [ VIRT MEM : 7.604176 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.296436 s ] [ CPU TIME: 271.491133 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 80 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2064427733421326E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 78 -229.0601085715 0.00 1.1810273415 0.2031967007 0.2571 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.443821 GB ] [ VIRT MEM : 7.619801 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.567539 s ] [ CPU TIME: 289.433745 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 0.443821 GB ] [ VIRT MEM : 7.619801 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.567936 s ] [ CPU TIME: 289.462139 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1614001590245737 + +Summary at N_det = 80 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.59792168 +# PT2 -0.46218689 0.00000000 +# rPT2 -0.38413244 0.00000000 +# +# E+PT2 -229.06010857 0.00000000 +# E+rPT2 -228.98205413 0.00000000 +# ============ ============================= + + N_det = 80 + N_states = 1 + + * State 1 + < S^2 > = 8.315359434275417E-003 + E = -228.597921684875 + Variance = 1.18102734146159 + PT norm = 0.450773447249287 + PT2 = -0.462186886616583 + rPT2 = -0.384132441794764 + E+PT2 = -229.060108571491 +/- 0.000000000000000E+000 + E+rPT2 = -228.982054126669 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.452804595134 + Vee = 238.996434009488 + Vecp = 0.000000000000000E+000 + T = 228.750219121983 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3974 -229.01327775 + -0.4115 -228.97759793 + -0.4216 -228.97362874 + -0.4326 -228.98900276 + -0.4488 -229.02731413 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 0.450592 GB ] [ VIRT MEM : 7.619869 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.621062 s ] [ CPU TIME: 293.208239 s ] <<<<< .. + +* Energy of state 1 -228.6164456644224 +* S^2 of state 1 0.1688481393925026E-01 +* Saved determinants 160 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 60 +* Number of unique alpha determinants 59 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.450657 GB ] [ VIRT MEM : 7.619869 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.678401 s ] [ CPU TIME: 297.231328 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 0.450657 GB ] [ VIRT MEM : 7.619869 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.678809 s ] [ CPU TIME: 297.260763 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.6164456644224 + +.. >>>>> [ RES MEM : 0.450657 GB ] [ VIRT MEM : 7.619869 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.682314 s ] [ CPU TIME: 297.509311 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 0.450657 GB ] [ VIRT MEM : 7.619869 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.682697 s ] [ CPU TIME: 297.536656 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 160 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2585154771804809E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 154 -229.0507389373 0.00 1.1342374201 0.1859930306 0.4236 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.450745 GB ] [ VIRT MEM : 7.619869 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5.196147 s ] [ CPU TIME: 331.903194 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 0.450745 GB ] [ VIRT MEM : 7.619869 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5.196539 s ] [ CPU TIME: 331.932123 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.2015859954074189 + +Summary at N_det = 160 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.61644566 +# PT2 -0.43429327 0.00000000 +# rPT2 -0.36618535 0.00000000 +# +# E+PT2 -229.05073894 0.00000000 +# E+rPT2 -228.98263101 0.00000000 +# ============ ============================= + + N_det = 160 + N_states = 1 + + * State 1 + < S^2 > = 1.688481393925026E-002 + E = -228.616445664422 + Variance = 1.13423742009709 + PT norm = 0.431269093083377 + PT2 = -0.434293272902519 + rPT2 = -0.366185349896095 + E+PT2 = -229.050738937325 +/- 0.000000000000000E+000 + E+rPT2 = -228.982631014319 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.434446787182 + Vee = 238.952920052185 + Vecp = 0.000000000000000E+000 + T = 228.756851291786 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3841 -228.99440160 + -0.3974 -229.00172453 + -0.4115 -228.98760273 + -0.4216 -228.98282143 + -0.4326 -228.99030389 + -0.4488 -229.01563330 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 0.455235 GB ] [ VIRT MEM : 7.620029 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5.330635 s ] [ CPU TIME: 341.398106 s ] <<<<< .. + +* Energy of state 1 -228.6410503150071 +* S^2 of state 1 0.2230960135085567E-01 +* Saved determinants 320 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 105 +* Number of unique alpha determinants 105 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.455353 GB ] [ VIRT MEM : 7.620029 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5.386991 s ] [ CPU TIME: 345.283755 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 0.455353 GB ] [ VIRT MEM : 7.620029 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5.387377 s ] [ CPU TIME: 345.311505 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.6410503150071 + +.. >>>>> [ RES MEM : 0.455353 GB ] [ VIRT MEM : 7.620029 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5.391060 s ] [ CPU TIME: 345.571690 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 0.455353 GB ] [ VIRT MEM : 7.620029 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5.391443 s ] [ CPU TIME: 345.599067 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 320 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.3626608848571777E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 313 -229.0406489170 0.00 1.0739796110 0.1654523499 0.6204 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.455429 GB ] [ VIRT MEM : 7.620029 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6.025868 s ] [ CPU TIME: 387.755409 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 0.455429 GB ] [ VIRT MEM : 7.620029 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6.026261 s ] [ CPU TIME: 387.784183 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.2545174039340782 + +Summary at N_det = 320 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.64105032 +# PT2 -0.39959860 0.00000000 +# rPT2 -0.34286996 0.00000000 +# +# E+PT2 -229.04064892 0.00000000 +# E+rPT2 -228.98392028 0.00000000 +# ============ ============================= + + N_det = 320 + N_states = 1 + + * State 1 + < S^2 > = 2.230960135085567E-002 + E = -228.641050315007 + Variance = 1.07397961100258 + PT norm = 0.406758343310829 + PT2 = -0.399598602031036 + rPT2 = -0.342869961248478 + E+PT2 = -229.040648917038 +/- 0.000000000000000E+000 + E+rPT2 = -228.983920276256 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.597458531299 + Vee = 239.018697624580 + Vecp = 0.000000000000000E+000 + T = 228.829480812923 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3662 -229.00287982 + -0.3841 -228.99952759 + -0.3974 -229.00155068 + -0.4115 -228.99405068 + -0.4216 -228.99003161 + -0.4326 -228.99341197 + -0.4488 -229.00940119 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 0.467655 GB ] [ VIRT MEM : 7.752735 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6.252057 s ] [ CPU TIME: 403.842906 s ] <<<<< .. + +* Energy of state 1 -228.6729045984280 +* S^2 of state 1 0.2546306276571611E-01 +* Saved determinants 640 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 187 +* Number of unique alpha determinants 187 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.467655 GB ] [ VIRT MEM : 7.752735 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6.314067 s ] [ CPU TIME: 408.113049 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 0.467655 GB ] [ VIRT MEM : 7.752735 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6.314455 s ] [ CPU TIME: 408.141293 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.6729045984280 + +.. >>>>> [ RES MEM : 0.467655 GB ] [ VIRT MEM : 7.752735 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6.317990 s ] [ CPU TIME: 408.394453 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 0.467655 GB ] [ VIRT MEM : 7.752735 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6.318372 s ] [ CPU TIME: 408.422298 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 640 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.5709517002105713E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 476 -229.0281209003 0.223E-02 0.9876386492 0.1416331964 1.0031 + 629 -229.0304260918 0.00 0.9941501244 0.1426344027 1.1806 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.469185 GB ] [ VIRT MEM : 7.752735 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.513999 s ] [ CPU TIME: 488.386207 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 0.469185 GB ] [ VIRT MEM : 7.752735 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.514394 s ] [ CPU TIME: 488.414876 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.3224606486389189 + +Summary at N_det = 640 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.67290460 +# PT2 -0.35752149 0.00000000 +# rPT2 -0.31289229 0.00000000 +# +# E+PT2 -229.03042609 0.00000000 +# E+rPT2 -228.98579689 0.00000000 +# ============ ============================= + + N_det = 640 + N_states = 1 + + * State 1 + < S^2 > = 2.546306276571611E-002 + E = -228.672904598428 + Variance = 0.994150124443947 + PT norm = 0.377669700573644 + PT2 = -0.357521493336968 + rPT2 = -0.312892288629100 + E+PT2 = -229.030426091765 +/- 0.000000000000000E+000 + E+rPT2 = -228.985796887057 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.602332369042 + Vee = 238.967519410552 + Vecp = 0.000000000000000E+000 + T = 228.853678581272 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3429 -229.00538403 + -0.3662 -229.00440308 + -0.3841 -229.00240918 + -0.3974 -229.00287304 + -0.4115 -228.99845766 + -0.4216 -228.99544180 + -0.4326 -228.99681280 + =========== =================== + +* Number of unique alpha determinants 296 +* Number of unique beta determinants 297 +.. >>>>> [ IO READ: davidson_sze_max ] <<<<< .. + +.. >>>>> [ RES MEM : 0.469704 GB ] [ VIRT MEM : 7.752735 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.562509 s ] [ CPU TIME: 491.773969 s ] <<<<< .. + +.. >>>>> [ IO READ: state_following ] <<<<< .. + +.. >>>>> [ RES MEM : 0.469704 GB ] [ VIRT MEM : 7.752735 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.563609 s ] [ CPU TIME: 491.851761 s ] <<<<< .. + +.. >>>>> [ IO READ: only_expected_s2 ] <<<<< .. + +.. >>>>> [ RES MEM : 0.469704 GB ] [ VIRT MEM : 7.752735 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.564935 s ] [ CPU TIME: 491.945858 s ] <<<<< .. + +.. >>>>> [ IO READ: disk_based_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 0.469704 GB ] [ VIRT MEM : 7.752735 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.565745 s ] [ CPU TIME: 492.003917 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.469704 GB ] [ VIRT MEM : 7.752735 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.566123 s ] [ CPU TIME: 492.030807 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 1280 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.2539642155170441E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.6730949081 0.025580 0.189E-01 + 2 -228.7125540322 0.034188 0.154E-02 + 3 -228.7130099381 0.033633 0.621E-04 + 4 -228.7130628888 0.034250 0.190E-05 + 5 -228.7130649981 0.034269 0.102E-06 + 6 -228.7130651266 0.034268 0.492E-08 + 7 -228.7130651317 0.034269 0.149E-09 + 8 -228.7130651319 0.034269 0.262E-11 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 0.470222 GB ] [ VIRT MEM : 7.782455 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.629154 s ] [ CPU TIME: 496.552943 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.470222 GB ] [ VIRT MEM : 7.782455 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.629554 s ] [ CPU TIME: 496.582085 s ] <<<<< .. + +* Energy of state 1 -228.7130651318980 +* S^2 of state 1 0.3426935407558218E-01 +* Saved determinants 1280 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.470333 GB ] [ VIRT MEM : 7.782455 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.696827 s ] [ CPU TIME: 501.024921 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 0.470333 GB ] [ VIRT MEM : 7.782455 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.697221 s ] [ CPU TIME: 501.054248 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 56 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.7130651318980 + +.. >>>>> [ RES MEM : 0.470333 GB ] [ VIRT MEM : 7.782455 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.707012 s ] [ CPU TIME: 501.754075 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 0.470333 GB ] [ VIRT MEM : 7.782455 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.707398 s ] [ CPU TIME: 501.782251 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 56 +* pt2_n_tasks_max 1 +* Number of tasks 1280 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.9876972436904908E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 14 -229.0225048423 0.105E-03 0.8982829537 0.1177175876 1.0358 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.471622 GB ] [ VIRT MEM : 7.795017 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.889860 s ] [ CPU TIME: 582.021619 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 0.471622 GB ] [ VIRT MEM : 7.795017 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.890256 s ] [ CPU TIME: 582.050919 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 56 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.4058255079857565 + +Summary at N_det = 1280 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.71306513 +# PT2 -0.30941252 0.00005645 +# rPT2 -0.27682729 0.00005051 +# +# E+PT2 -229.02247765 0.00005645 +# E+rPT2 -228.98989242 0.00005051 +# ============ ============================= + + N_det = 1280 + N_states = 1 + + * State 1 + < S^2 > = 3.426935407558218E-002 + E = -228.713065131898 + Variance = 0.898128634858828 + PT norm = 0.343088308547429 + PT2 = -0.309412518692571 + rPT2 = -0.276827292315866 + E+PT2 = -229.022477650591 +/- 5.645003074206753E-005 + E+rPT2 = -228.989892424214 +/- 5.050509665060017E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.584356951660 + Vee = 238.891039380213 + Vecp = 0.000000000000000E+000 + T = 228.872022660761 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3129 -229.02132890 + -0.3429 -229.01488807 + -0.3662 -229.01174671 + -0.3841 -229.00918442 + -0.3974 -229.00840365 + -0.4115 -229.00506561 + -0.4216 -229.00249330 + =========== =================== + +* Number of unique alpha determinants 460 +* Number of unique beta determinants 460 + +.. >>>>> [ RES MEM : 0.472012 GB ] [ VIRT MEM : 7.795017 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.945901 s ] [ CPU TIME: 586.011729 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 2560 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.4631269723176956E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.7130858561 0.034267 0.210E-01 + 2 -228.7606662333 0.039742 0.176E-02 + 3 -228.7613089240 0.038737 0.716E-04 + 4 -228.7613767316 0.039413 0.206E-05 + 5 -228.7613786725 0.039447 0.889E-07 + 6 -228.7613787696 0.039452 0.355E-08 + 7 -228.7613787740 0.039454 0.104E-09 + 8 -228.7613787741 0.039454 0.281E-11 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 0.475883 GB ] [ VIRT MEM : 7.795017 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.991207 s ] [ CPU TIME: 589.264018 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.475883 GB ] [ VIRT MEM : 7.795017 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.991610 s ] [ CPU TIME: 589.293471 s ] <<<<< .. + +* Energy of state 1 -228.7613787741117 +* S^2 of state 1 0.3945419799547314E-01 +* Saved determinants 2560 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.475960 GB ] [ VIRT MEM : 7.795017 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.081575 s ] [ CPU TIME: 594.826795 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 0.475960 GB ] [ VIRT MEM : 7.795017 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.081978 s ] [ CPU TIME: 594.855542 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 71 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.7613787741117 + +.. >>>>> [ RES MEM : 0.456966 GB ] [ VIRT MEM : 7.772663 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.093326 s ] [ CPU TIME: 595.656915 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 0.456966 GB ] [ VIRT MEM : 7.772663 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.093711 s ] [ CPU TIME: 595.684571 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 71 +* pt2_n_tasks_max 1 +* Number of tasks 2560 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1820905208587647E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0168907955 0.108E-02 0.7881768489 0.0916816642 1.2581 + 38 -229.0164682462 0.692E-04 0.7846376934 0.0916561990 2.2911 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.463783 GB ] [ VIRT MEM : 7.772678 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.491898 s ] [ CPU TIME: 757.626598 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 0.463783 GB ] [ VIRT MEM : 7.772678 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.492290 s ] [ CPU TIME: 757.655058 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 71 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.5039835394019390 + +Summary at N_det = 2560 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.76137877 +# PT2 -0.25504842 0.00006766 +# rPT2 -0.23363601 0.00006198 +# +# E+PT2 -229.01642719 0.00006766 +# E+rPT2 -228.99501478 0.00006198 +# ============ ============================= + + N_det = 2560 + N_states = 1 + + * State 1 + < S^2 > = 3.945419799547314E-002 + E = -228.761378774112 + Variance = 0.784399668148189 + PT norm = 0.302735148939426 + PT2 = -0.255048415455714 + rPT2 = -0.233636009216291 + E+PT2 = -229.016427189567 +/- 6.765994012756917E-005 + E+rPT2 = -228.995014783328 +/- 6.197959852827733E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.622963664953 + Vee = 238.837012437631 + Vecp = 0.000000000000000E+000 + T = 228.916342674420 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2768 -229.02272333 + -0.3129 -229.02217530 + -0.3429 -229.01888520 + -0.3662 -229.01640854 + -0.3841 -229.01424780 + -0.3974 -229.01319060 + -0.4115 -229.01067686 + =========== =================== + +* Number of unique alpha determinants 762 +* Number of unique beta determinants 762 + +.. >>>>> [ RES MEM : 0.462769 GB ] [ VIRT MEM : 7.769325 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.549937 s ] [ CPU TIME: 761.684262 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5120 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.8756499737501144E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.7614074462 0.039503 0.222E-01 + 2 -228.8149110401 0.036696 0.150E-02 + 3 -228.8155512568 0.035218 0.634E-04 + 4 -228.8156211113 0.035467 0.131E-05 + 5 -228.8156233262 0.035443 0.629E-07 + 6 -228.8156234268 0.035440 0.215E-08 + 7 -228.8156234304 0.035442 0.598E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 0.467884 GB ] [ VIRT MEM : 7.773926 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.615874 s ] [ CPU TIME: 766.392020 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.466667 GB ] [ VIRT MEM : 7.771626 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.616444 s ] [ CPU TIME: 766.433915 s ] <<<<< .. + +* Energy of state 1 -228.8156234304253 +* S^2 of state 1 0.3544160724598618E-01 +* Saved determinants 5120 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.466667 GB ] [ VIRT MEM : 7.771626 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.748717 s ] [ CPU TIME: 774.033524 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 0.466667 GB ] [ VIRT MEM : 7.771626 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.749131 s ] [ CPU TIME: 774.063221 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 87 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.8156234304253 + +.. >>>>> [ RES MEM : 0.468239 GB ] [ VIRT MEM : 7.771626 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.756681 s ] [ CPU TIME: 774.597661 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 0.468239 GB ] [ VIRT MEM : 7.771626 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.757094 s ] [ CPU TIME: 774.627176 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 87 +* pt2_n_tasks_max 1 +* Number of tasks 5120 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.3487279415130615E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0152339350 0.106E-02 0.6617217023 0.0666976333 2.3877 + 42 -229.0146536981 0.114E-03 0.6604121915 0.0664958617 3.4994 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.477325 GB ] [ VIRT MEM : 7.744873 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15.396647 s ] [ CPU TIME: 1020.486437 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 0.477325 GB ] [ VIRT MEM : 7.744873 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15.397029 s ] [ CPU TIME: 1020.514020 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 87 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.6098460143745065 + +Summary at N_det = 5120 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.81562343 +# PT2 -0.19898064 0.00009895 +# rPT2 -0.18657483 0.00009278 +# +# E+PT2 -229.01460407 0.00009895 +# E+rPT2 -229.00219826 0.00009278 +# ============ ============================= + + N_det = 5120 + N_states = 1 + + * State 1 + < S^2 > = 3.544160724598618E-002 + E = -228.815623430425 + Variance = 0.660019096880662 + PT norm = 0.257861210745017 + PT2 = -0.198980638842653 + rPT2 = -0.186574829876958 + E+PT2 = -229.014604069268 +/- 9.894986486222108E-005 + E+rPT2 = -229.002198260302 +/- 9.278065599947977E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.633920232296 + Vee = 238.750722886549 + Vecp = 0.000000000000000E+000 + T = 228.959344136533 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2336 -229.03067727 + -0.2768 -229.02743837 + -0.3129 -229.02584124 + -0.3429 -229.02331839 + -0.3662 -229.02121455 + -0.3841 -229.01935390 + -0.3974 -229.01823188 + =========== =================== + +* Number of unique alpha determinants 1321 +* Number of unique beta determinants 1321 + +.. >>>>> [ RES MEM : 0.464653 GB ] [ VIRT MEM : 7.696812 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15.649094 s ] [ CPU TIME: 1038.388357 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 10240 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.1689816266298294E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.8156536217 0.035433 0.210E-01 + 2 -228.8695828339 0.029757 0.125E-02 + 3 -228.8702286851 0.028511 0.711E-04 + 4 -228.8703066943 0.028584 0.136E-05 + 5 -228.8703090956 0.028552 0.769E-07 + 6 -228.8703092105 0.028541 0.453E-08 + 7 -228.8703092164 0.028541 0.184E-09 + 8 -228.8703092168 0.028541 0.541E-11 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 0.477367 GB ] [ VIRT MEM : 7.705990 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15.801239 s ] [ CPU TIME: 1049.314089 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.474739 GB ] [ VIRT MEM : 7.701401 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15.802132 s ] [ CPU TIME: 1049.378543 s ] <<<<< .. + +* Energy of state 1 -228.8703092167507 +* S^2 of state 1 0.2854112554245418E-01 +* Saved determinants 10240 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.476131 GB ] [ VIRT MEM : 7.701401 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.005759 s ] [ CPU TIME: 1060.517580 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 0.476131 GB ] [ VIRT MEM : 7.701401 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.006184 s ] [ CPU TIME: 1060.547959 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 100 +* pt2_n_tasks_max 2 +* PT2 Energy denominator -228.8703092167507 + +.. >>>>> [ RES MEM : 0.469913 GB ] [ VIRT MEM : 7.696812 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.014903 s ] [ CPU TIME: 1061.165290 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 0.469913 GB ] [ VIRT MEM : 7.696812 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.015316 s ] [ CPU TIME: 1061.194939 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 100 +* pt2_n_tasks_max 2 +* Number of tasks 10629 +* Number of fragmented tasks 389 +* Number of threads for PT2 72 +* Memory (Gb) 0.6823648810386658E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0171796913 0.176E-03 0.5382359668 0.0445991082 2.3458 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.473362 GB ] [ VIRT MEM : 7.701508 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18.878881 s ] [ CPU TIME: 1259.933251 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 0.473362 GB ] [ VIRT MEM : 7.701508 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18.879296 s ] [ CPU TIME: 1259.963416 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 100 +* pt2_n_tasks_max 2 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7111003560602436 + +Summary at N_det = 10240 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.87030922 +# PT2 -0.14698523 0.00024641 +# rPT2 -0.14069952 0.00023587 +# +# E+PT2 -229.01729444 0.00024641 +# E+rPT2 -229.01100873 0.00023587 +# ============ ============================= + + N_det = 10240 + N_states = 1 + + * State 1 + < S^2 > = 2.854112554245418E-002 + E = -228.870309216751 + Variance = 0.537896384598995 + PT norm = 0.211363892142150 + PT2 = -0.146985225608824 + rPT2 = -0.140699517587804 + E+PT2 = -229.017294442360 +/- 2.464050660090792E-004 + E+rPT2 = -229.011008734339 +/- 2.358677464014932E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.701914168448 + Vee = 238.700185499539 + Vecp = 0.000000000000000E+000 + T = 229.023189673370 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1866 -229.03803045 + -0.2336 -229.03490164 + -0.2768 -229.03200516 + -0.3129 -229.03014273 + -0.3429 -229.02796539 + -0.3662 -229.02610599 + -0.3841 -229.02446659 + =========== =================== + +* Number of unique alpha determinants 2575 +* Number of unique beta determinants 2575 + +.. >>>>> [ RES MEM : 0.457024 GB ] [ VIRT MEM : 7.677483 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18.978428 s ] [ CPU TIME: 1266.932227 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 20480 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.3351029753684998E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.8703096114 0.028540 0.168E-01 + 2 -228.9161997425 0.016785 0.821E-03 + 3 -228.9167288826 0.015878 0.723E-04 + 4 -228.9168027061 0.015765 0.137E-05 + 5 -228.9168050877 0.015713 0.109E-06 + 6 -228.9168052346 0.015697 0.513E-08 + 7 -228.9168052432 0.015695 0.250E-09 + 8 -228.9168052436 0.015695 0.971E-11 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 0.477219 GB ] [ VIRT MEM : 7.701275 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 19.362332 s ] [ CPU TIME: 1294.459586 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.468483 GB ] [ VIRT MEM : 7.683498 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 19.364029 s ] [ CPU TIME: 1294.581798 s ] <<<<< .. + +* Energy of state 1 -228.9168052435818 +* S^2 of state 1 0.1569469883673651E-01 +* Saved determinants 20480 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.471653 GB ] [ VIRT MEM : 7.683498 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 19.794410 s ] [ CPU TIME: 1320.164460 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 0.471653 GB ] [ VIRT MEM : 7.683498 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 19.794864 s ] [ CPU TIME: 1320.196819 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 +* PT2 Energy denominator -228.9168052435818 + +.. >>>>> [ RES MEM : 0.460461 GB ] [ VIRT MEM : 7.670311 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 19.805820 s ] [ CPU TIME: 1320.983361 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 0.460461 GB ] [ VIRT MEM : 7.670311 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 19.806256 s ] [ CPU TIME: 1321.015285 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 +* Number of tasks 21432 +* Number of fragmented tasks 476 +* Number of threads for PT2 72 +* Memory (Gb) 0.1349263250827789 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0218867432 0.112E-02 0.4318284310 0.0283399679 3.1298 + 15 -229.0223289580 0.409E-03 0.4351256841 0.0283691042 4.4077 + 24 -229.0225141344 0.302E-03 0.4369779563 0.0283683672 5.6369 + 30 -229.0223731344 0.268E-03 0.4360651816 0.0283460841 7.0104 + 41 -229.0224574136 0.180E-03 0.4367073361 0.0283614234 8.2990 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.629749 GB ] [ VIRT MEM : 7.829475 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 28.994964 s ] [ CPU TIME: 1965.045541 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 0.629749 GB ] [ VIRT MEM : 7.829475 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 28.995403 s ] [ CPU TIME: 1965.077347 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7926375495292134 + +Summary at N_det = 20480 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.91680524 +# PT2 -0.10568032 0.00016664 +# rPT2 -0.10276464 0.00016204 +# +# E+PT2 -229.02248556 0.00016664 +# E+rPT2 -229.01956989 0.00016204 +# ============ ============================= + + N_det = 20480 + N_states = 1 + + * State 1 + < S^2 > = 1.569469883673651E-002 + E = -228.916805243582 + Variance = 0.436691390111424 + PT norm = 0.168440841085260 + PT2 = -0.105680315783914 + rPT2 = -0.102764644713315 + E+PT2 = -229.022485559366 +/- 1.666377457643678E-004 + E+rPT2 = -229.019569888295 +/- 1.620402873730773E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.725062183118 + Vee = 238.625391194226 + Vecp = 0.000000000000000E+000 + T = 229.074635966521 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1407 -229.04276185 + -0.1866 -229.04056231 + -0.2336 -229.03803767 + -0.2768 -229.03558985 + -0.3129 -229.03381781 + -0.3429 -229.03193434 + -0.3662 -229.03030643 + =========== =================== + +* Number of unique alpha determinants 5488 +* Number of unique beta determinants 5488 + +.. >>>>> [ RES MEM : 0.633366 GB ] [ VIRT MEM : 7.829475 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 29.169064 s ] [ CPU TIME: 1977.470346 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 40960 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.6771374121308327E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9168063786 0.015693 0.991E-02 + 2 -228.9455786134 0.004794 0.272E-03 + 3 -228.9459343607 0.004375 0.540E-04 + 4 -228.9459698684 0.004329 0.246E-05 + 5 -228.9459733340 0.004303 0.184E-06 + 6 -228.9459736111 0.004297 0.799E-08 + 7 -228.9459736259 0.004296 0.482E-09 + 8 -228.9459736267 0.004296 0.266E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 0.674179 GB ] [ VIRT MEM : 7.884453 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30.278273 s ] [ CPU TIME: 2057.086978 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.657887 GB ] [ VIRT MEM : 7.856613 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30.280789 s ] [ CPU TIME: 2057.268204 s ] <<<<< .. + +* Energy of state 1 -228.9459736267031 +* S^2 of state 1 0.4296378777527486E-02 +* Saved determinants 40960 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.640850 GB ] [ VIRT MEM : 7.837212 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30.719867 s ] [ CPU TIME: 2079.364686 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 0.640850 GB ] [ VIRT MEM : 7.837212 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30.720350 s ] [ CPU TIME: 2079.400414 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 +* PT2 Energy denominator -228.9459736267031 + +.. >>>>> [ RES MEM : 0.639610 GB ] [ VIRT MEM : 7.835979 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30.733846 s ] [ CPU TIME: 2080.368639 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 0.639610 GB ] [ VIRT MEM : 7.835979 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30.734319 s ] [ CPU TIME: 2080.403332 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 +* Number of tasks 50515 +* Number of fragmented tasks 7917 +* Number of threads for PT2 72 +* Memory (Gb) 0.2683059990406036 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0259211998 0.127E-02 0.3656914679 0.0190257916 3.6827 + 8 -229.0266188535 0.577E-03 0.3697087002 0.0191031016 5.3819 + 12 -229.0269450994 0.453E-03 0.3709568145 0.0192034827 6.4111 + 17 -229.0268275961 0.333E-03 0.3699031092 0.0191931932 7.6319 + 20 -229.0266755896 0.328E-03 0.3690083564 0.0191627283 8.9133 + 24 -229.0264988479 0.308E-03 0.3684460421 0.0191158892 10.3489 + 29 -229.0264330163 0.310E-03 0.3686908931 0.0190787863 11.9061 + 36 -229.0264823447 0.288E-03 0.3687678745 0.0190920709 13.1878 + 42 -229.0266973974 0.300E-03 0.3700387697 0.0191229457 14.2611 + 47 -229.0269420570 0.280E-03 0.3715427757 0.0191658508 15.3602 + 48 -229.0269004896 0.277E-03 0.3712244857 0.0191621168 16.9805 + 62 -229.0268494806 0.226E-03 0.3708975716 0.0191538080 18.2517 + 74 -229.0268667256 0.197E-03 0.3710922406 0.0191542230 19.4412 + 77 -229.0268557849 0.189E-03 0.3710111624 0.0191528076 20.6770 + 89 -229.0269648958 0.158E-03 0.3720317619 0.0191576653 21.9382 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.921547 GB ] [ VIRT MEM : 8.096523 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 53.588073 s ] [ CPU TIME: 3695.555363 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 0.921547 GB ] [ VIRT MEM : 8.096523 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 53.588559 s ] [ CPU TIME: 3695.590413 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8415816506248428 + +Summary at N_det = 40960 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.94597363 +# PT2 -0.08095465 0.00014289 +# rPT2 -0.07943369 0.00014021 +# +# E+PT2 -229.02692827 0.00014289 +# E+rPT2 -229.02540732 0.00014021 +# ============ ============================= + + N_det = 40960 + N_states = 1 + + * State 1 + < S^2 > = 4.296378777527486E-003 + E = -228.945973626703 + Variance = 0.371981934913092 + PT norm = 0.138374453538098 + PT2 = -8.095464809856812E-002 + rPT2 = -7.943369231755298E-002 + E+PT2 = -229.026928274802 +/- 1.428945821073536E-004 + E+rPT2 = -229.025407319021 +/- 1.402099142613851E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.773552908304 + Vee = 238.606552947388 + Vecp = 0.000000000000000E+000 + T = 229.112796555424 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1028 -229.04528172 + -0.1407 -229.04386055 + -0.1866 -229.04205453 + -0.2336 -229.03997216 + -0.2768 -229.03790939 + -0.3129 -229.03632983 + -0.3429 -229.03470571 + =========== =================== + +* Number of unique alpha determinants 10695 +* Number of unique beta determinants 10671 + +.. >>>>> [ RES MEM : 0.924576 GB ] [ VIRT MEM : 8.096523 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 53.964535 s ] [ CPU TIME: 3722.407388 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 81920 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.1346240639686584 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9459738271 0.004296 0.375E-02 + 2 -228.9574565407 0.001721 0.505E-03 + 3 -228.9578960890 0.001791 0.744E-04 + 4 -228.9579927970 0.001927 0.191E-04 + 5 -228.9580148489 0.002016 0.159E-05 + 6 -228.9580169905 0.002039 0.126E-06 + 7 -228.9580172055 0.002041 0.106E-07 + 8 -228.9580172249 0.002040 0.756E-09 + 9 -228.9580172264 0.002040 0.488E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 1.026451 GB ] [ VIRT MEM : 8.215652 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 56.925263 s ] [ CPU TIME: 3935.041102 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.989887 GB ] [ VIRT MEM : 8.159981 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 56.929988 s ] [ CPU TIME: 3935.381014 s ] <<<<< .. + +* Energy of state 1 -228.9580172264235 +* S^2 of state 1 0.2040073004776351E-02 +* Saved determinants 81920 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.956322 GB ] [ VIRT MEM : 8.121784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 57.710104 s ] [ CPU TIME: 3973.922457 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 0.956322 GB ] [ VIRT MEM : 8.121784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 57.710701 s ] [ CPU TIME: 3973.965852 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 +* PT2 Energy denominator -228.9580172264235 + +.. >>>>> [ RES MEM : 0.956203 GB ] [ VIRT MEM : 8.121784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 57.737013 s ] [ CPU TIME: 3975.854983 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 0.956203 GB ] [ VIRT MEM : 8.121784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 57.737587 s ] [ CPU TIME: 3975.896562 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 +* Number of tasks 103052 +* Number of fragmented tasks 8856 +* Number of threads for PT2 72 +* Memory (Gb) 0.5350653469562531 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0304112679 0.112E-02 0.3511640224 0.0160226152 5.1825 + 5 -229.0302161631 0.661E-03 0.3516406130 0.0158905671 8.6770 + 8 -229.0296049016 0.504E-03 0.3477328759 0.0157806184 10.8586 + 12 -229.0292798662 0.565E-03 0.3465704547 0.0157100346 12.1439 + 14 -229.0289049580 0.561E-03 0.3430733894 0.0156977617 14.1755 + 15 -229.0289688814 0.532E-03 0.3439504847 0.0156914922 16.0911 + 24 -229.0288483082 0.360E-03 0.3415896511 0.0157160455 17.3876 + 27 -229.0288952427 0.332E-03 0.3421494528 0.0157106203 18.7326 + 28 -229.0288489349 0.318E-03 0.3417085633 0.0157092828 19.8492 + 31 -229.0290773815 0.316E-03 0.3432554626 0.0157408282 21.2756 + 32 -229.0290673419 0.316E-03 0.3428893267 0.0157500682 23.4618 + 41 -229.0288727748 0.265E-03 0.3423259966 0.0157032476 25.3335 + 43 -229.0289297070 0.256E-03 0.3425114356 0.0157181686 26.4646 + 49 -229.0290235942 0.235E-03 0.3432089247 0.0157211879 27.6098 + 52 -229.0289358881 0.231E-03 0.3423724997 0.0157171102 28.7684 + 58 -229.0289783748 0.220E-03 0.3424715954 0.0157306588 29.9850 + 62 -229.0289691504 0.201E-03 0.3423740160 0.0157289053 32.1326 + 74 -229.0291048320 0.181E-03 0.3435287254 0.0157395550 33.3915 + 77 -229.0290613352 0.170E-03 0.3431487902 0.0157362506 34.5916 + 84 -229.0290288228 0.157E-03 0.3430094994 0.0157288109 35.6846 + 89 -229.0289790248 0.153E-03 0.3427175998 0.0157213606 37.1586 + 95 -229.0289534843 0.145E-03 0.3424533771 0.0157199638 38.3886 + 103 -229.0289666958 0.143E-03 0.3425449040 0.0157217145 39.8320 + 107 -229.0289045300 0.139E-03 0.3420340421 0.0157163599 41.6131 + 114 -229.0288843489 0.134E-03 0.3418347722 0.0157152987 42.6807 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.409904 GB ] [ VIRT MEM : 8.542595 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 101.678759 s ] [ CPU TIME: 6963.408744 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 1.409904 GB ] [ VIRT MEM : 8.542595 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 101.679356 s ] [ CPU TIME: 6963.451376 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8615316578605998 + +Summary at N_det = 81920 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.95801723 +# PT2 -0.07085441 0.00012332 +# rPT2 -0.06975834 0.00012141 +# +# E+PT2 -229.02887164 0.00012332 +# E+rPT2 -229.02777557 0.00012141 +# ============ ============================= + + N_det = 81920 + N_states = 1 + + * State 1 + < S^2 > = 2.040073004776351E-003 + E = -228.958017226424 + Variance = 0.341739190954400 + PT norm = 0.125349036034254 + PT2 = -7.085441189314846E-002 + rPT2 = -6.975834225326663E-002 + E+PT2 = -229.028871638317 +/- 1.233223934508588E-004 + E+rPT2 = -229.027775568677 +/- 1.214146797634897E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.773634501168 + Vee = 238.580275668162 + Vecp = 0.000000000000000E+000 + T = 229.127111827793 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0794 -229.04485042 + -0.1028 -229.04515519 + -0.1407 -229.04415231 + -0.1866 -229.04266675 + -0.2336 -229.04090641 + -0.2768 -229.03913606 + -0.3129 -229.03774340 + =========== =================== + +* Number of unique beta determinants 18066 +* Number of unique alpha determinants 18009 + +.. >>>>> [ RES MEM : 1.452229 GB ] [ VIRT MEM : 8.579811 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 102.463508 s ] [ CPU TIME: 7019.438274 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 163840 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.2610876075923443 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9580172466 0.002040 0.163E-02 + 2 -228.9635382373 0.002256 0.412E-03 + 3 -228.9638513239 0.002664 0.713E-04 + 4 -228.9639623210 0.003172 0.185E-04 + 5 -228.9639884542 0.003464 0.115E-05 + 6 -228.9639907971 0.003539 0.183E-06 + 7 -228.9639911646 0.003553 0.246E-07 + 8 -228.9639912140 0.003548 0.295E-08 + 9 -228.9639912199 0.003545 0.406E-09 + 10 -228.9639912206 0.003543 0.408E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 1.565342 GB ] [ VIRT MEM : 8.715096 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 110.171159 s ] [ CPU TIME: 7554.255678 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 1.484955 GB ] [ VIRT MEM : 8.604248 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 110.185597 s ] [ CPU TIME: 7555.293147 s ] <<<<< .. + +* Energy of state 1 -228.9639912206344 +* S^2 of state 1 0.3542782849647478E-02 +* Saved determinants 163840 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.416611 GB ] [ VIRT MEM : 8.530514 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 111.608848 s ] [ CPU TIME: 7604.056335 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 1.416611 GB ] [ VIRT MEM : 8.530514 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 111.609642 s ] [ CPU TIME: 7604.114485 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 +* PT2 Energy denominator -228.9639912206344 + +.. >>>>> [ RES MEM : 1.417362 GB ] [ VIRT MEM : 8.530514 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 111.656603 s ] [ CPU TIME: 7607.486835 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 1.417362 GB ] [ VIRT MEM : 8.530514 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 111.657380 s ] [ CPU TIME: 7607.542781 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 +* Number of tasks 199597 +* Number of fragmented tasks 9397 +* Number of threads for PT2 72 +* Memory (Gb) 1.068584042787552 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0295252547 0.181E-02 0.3225340843 0.0141062261 8.7732 + 5 -229.0293781995 0.100E-02 0.3228595955 0.0140357587 10.2207 + 6 -229.0294409315 0.809E-03 0.3226643917 0.0140763673 11.4632 + 7 -229.0294771652 0.728E-03 0.3236872552 0.0140661199 13.5063 + 9 -229.0292978877 0.666E-03 0.3226463916 0.0140305133 15.0134 + 11 -229.0291318612 0.565E-03 0.3221734684 0.0139842942 16.1038 + 13 -229.0292575622 0.580E-03 0.3224426416 0.0140323931 17.6161 + 14 -229.0293591034 0.546E-03 0.3230408838 0.0140497693 18.8302 + 15 -229.0293971881 0.514E-03 0.3227037564 0.0140880003 20.3072 + 19 -229.0291843390 0.487E-03 0.3215257235 0.0140499151 21.5322 + 20 -229.0291970506 0.462E-03 0.3215434530 0.0140561703 23.1772 + 24 -229.0290460789 0.420E-03 0.3204790115 0.0140372165 24.2032 + 27 -229.0289822075 0.408E-03 0.3201309218 0.0140246795 26.7295 + 29 -229.0292000514 0.435E-03 0.3212872091 0.0140732904 27.9742 + 31 -229.0290076079 0.439E-03 0.3199382245 0.0140488429 29.4962 + 34 -229.0291058200 0.401E-03 0.3206496489 0.0140606903 31.0080 + 36 -229.0290934508 0.376E-03 0.3205645213 0.0140582139 32.9362 + 40 -229.0295048583 0.368E-03 0.3233551674 0.0141122544 34.7711 + 43 -229.0296539247 0.335E-03 0.3242097052 0.0141386328 37.0042 + 47 -229.0295852894 0.326E-03 0.3235990608 0.0141336652 38.0322 + 49 -229.0295601321 0.307E-03 0.3234186414 0.0141299302 39.3073 + 51 -229.0295381088 0.282E-03 0.3231762960 0.0141307976 40.5672 + 55 -229.0297937677 0.269E-03 0.3247452687 0.0141735410 42.0151 + 62 -229.0298180632 0.233E-03 0.3250011535 0.0141740439 43.9268 + 65 -229.0298421652 0.229E-03 0.3249755384 0.0141862577 45.4322 + 71 -229.0298903356 0.212E-03 0.3252453337 0.0141935878 46.8126 + 76 -229.0298990162 0.201E-03 0.3253273129 0.0141929161 47.8672 + 80 -229.0299025448 0.193E-03 0.3254311519 0.0141910795 49.7136 + 85 -229.0299363058 0.193E-03 0.3257109409 0.0141937187 51.2802 + 91 -229.0299502335 0.175E-03 0.3259973293 0.0141886696 55.0662 + 103 -229.0299168005 0.151E-03 0.3258197886 0.0141833683 56.6816 + 110 -229.0299090930 0.140E-03 0.3257410317 0.0141845336 57.9444 + 114 -229.0298896658 0.136E-03 0.3257032444 0.0141789295 59.3746 + 122 -229.0299023769 0.129E-03 0.3258325138 0.0141791123 60.5452 + 125 -229.0299097382 0.129E-03 0.3258762774 0.0141803018 61.9232 + 128 -229.0299377309 0.126E-03 0.3259345314 0.0141887547 62.9783 + 134 -229.0299713330 0.122E-03 0.3261687854 0.0141945655 65.1728 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.970680 GB ] [ VIRT MEM : 9.059185 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 177.394085 s ] [ CPU TIME: 12271.050636 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 1.970680 GB ] [ VIRT MEM : 9.059185 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 177.394877 s ] [ CPU TIME: 12271.107226 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8711958742210002 + +Summary at N_det = 163840 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.96399122 +# PT2 -0.06597638 0.00012037 +# rPT2 -0.06505307 0.00011869 +# +# E+PT2 -229.02996760 0.00012037 +# E+rPT2 -229.02904429 0.00011869 +# ============ ============================= + + N_det = 163840 + N_states = 1 + + * State 1 + < S^2 > = 3.542782849647478E-003 + E = -228.963991220634 + Variance = 0.326172130491168 + PT norm = 0.119135323872637 + PT2 = -6.597637922420911E-002 + rPT2 = -6.505306639034461E-002 + E+PT2 = -229.029967599859 +/- 1.203696639492322E-004 + E+rPT2 = -229.029044287025 +/- 1.186851390201724E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.777018032241 + Vee = 238.564175921673 + Vecp = 0.000000000000000E+000 + T = 229.140621111144 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0698 -229.04658503 + -0.0794 -229.04538383 + -0.1028 -229.04528337 + -0.1407 -229.04437939 + -0.1866 -229.04305300 + -0.2336 -229.04148485 + -0.2768 -229.03990560 + =========== =================== + +* Number of unique beta determinants 33568 +* Number of unique alpha determinants 32653 + +.. >>>>> [ RES MEM : 2.056019 GB ] [ VIRT MEM : 9.141247 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 178.927860 s ] [ CPU TIME: 12380.892782 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 327680 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.5158521570265293 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9639912356 0.003543 0.920E-03 + 2 -228.9673655530 0.003753 0.136E-03 + 3 -228.9674623939 0.003964 0.200E-04 + 4 -228.9674963837 0.004230 0.514E-05 + 5 -228.9675050497 0.004422 0.771E-06 + 6 -228.9675064727 0.004533 0.122E-06 + 7 -228.9675067351 0.004578 0.243E-07 + 8 -228.9675067778 0.004591 0.230E-08 + 9 -228.9675067824 0.004594 0.215E-09 + 10 -228.9675067828 0.004593 0.311E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 2.393654 GB ] [ VIRT MEM : 9.537739 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 193.082202 s ] [ CPU TIME: 13347.027713 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 2.086102 GB ] [ VIRT MEM : 9.170052 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 193.114679 s ] [ CPU TIME: 13349.360937 s ] <<<<< .. + +* Energy of state 1 -228.9675067827952 +* S^2 of state 1 0.4593265093367724E-02 +* Saved determinants 327680 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 2.029621 GB ] [ VIRT MEM : 9.108505 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 195.967768 s ] [ CPU TIME: 13421.693987 s ] <<<<< .. + +* Number of generators 327679 + +.. >>>>> [ RES MEM : 2.029621 GB ] [ VIRT MEM : 9.108505 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 195.968951 s ] [ CPU TIME: 13421.779249 s ] <<<<< .. + +* Number of selectors 327679 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 +* PT2 Energy denominator -228.9675067827952 + +.. >>>>> [ RES MEM : 2.050549 GB ] [ VIRT MEM : 9.127796 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 196.090094 s ] [ CPU TIME: 13430.478927 s ] <<<<< .. + +* Number of generators 327679 + +.. >>>>> [ RES MEM : 2.050549 GB ] [ VIRT MEM : 9.127796 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 196.091259 s ] [ CPU TIME: 13430.562883 s ] <<<<< .. + +* Number of selectors 327679 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 +* Number of tasks 383395 +* Number of fragmented tasks 9778 +* Number of threads for PT2 72 +* Memory (Gb) 2.135621407367289 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0302906829 0.650E-03 0.3169232993 0.0131553890 15.8375 + 4 -229.0296057759 0.881E-03 0.3115615574 0.0130859019 16.9546 + 6 -229.0309065111 0.117E-02 0.3202520049 0.0132911176 22.3620 + 7 -229.0306303351 0.102E-02 0.3182577560 0.0132748502 24.1354 + 8 -229.0303799497 0.917E-03 0.3166139222 0.0132371814 25.5074 + 10 -229.0306235566 0.742E-03 0.3164650366 0.0133340000 27.0015 + 12 -229.0306987058 0.648E-03 0.3156971832 0.0133998925 28.8718 + 13 -229.0306408323 0.594E-03 0.3153726778 0.0133841451 31.2875 + 17 -229.0308522604 0.464E-03 0.3156925539 0.0134578402 33.7624 + 18 -229.0307075717 0.461E-03 0.3148748288 0.0134315177 36.0917 + 20 -229.0305034542 0.445E-03 0.3140550462 0.0133838759 37.4995 + 22 -229.0303372183 0.384E-03 0.3134246931 0.0133420785 40.8735 + 27 -229.0299983530 0.337E-03 0.3116090820 0.0132746768 43.0774 + 28 -229.0300513637 0.329E-03 0.3122271155 0.0132769422 44.4140 + 30 -229.0300921432 0.316E-03 0.3123988757 0.0132875255 47.9194 + 32 -229.0302608484 0.315E-03 0.3135159330 0.0133098002 49.3488 + 33 -229.0303700287 0.325E-03 0.3143904526 0.0133227614 50.4274 + 35 -229.0303606180 0.314E-03 0.3140525127 0.0133316767 55.6605 + 42 -229.0303860082 0.274E-03 0.3144618461 0.0133271882 57.1484 + 44 -229.0304048716 0.278E-03 0.3145787595 0.0133310551 58.7584 + 45 -229.0303921564 0.272E-03 0.3145759306 0.0133253485 59.8119 + 50 -229.0304247490 0.258E-03 0.3147932503 0.0133303404 62.4704 + 53 -229.0304356123 0.259E-03 0.3148115585 0.0133351782 64.7007 + 58 -229.0304396958 0.218E-03 0.3153076692 0.0133214325 67.6428 + 68 -229.0304916361 0.184E-03 0.3160980906 0.0133121362 69.5076 + 69 -229.0304763685 0.182E-03 0.3160522491 0.0133077670 71.3018 + 71 -229.0304425843 0.182E-03 0.3157748384 0.0133061824 72.8764 + 77 -229.0304311961 0.171E-03 0.3158347132 0.0133023606 75.1740 + 80 -229.0304604893 0.161E-03 0.3160231951 0.0133065744 77.2086 + 85 -229.0303940239 0.154E-03 0.3156250201 0.0132965163 78.3652 + 87 -229.0303983478 0.151E-03 0.3156013628 0.0132986849 80.2592 + 91 -229.0304416698 0.154E-03 0.3160460201 0.0133003435 82.1754 + 97 -229.0304537819 0.146E-03 0.3161388862 0.0133009414 84.4304 + 104 -229.0303503226 0.144E-03 0.3155075551 0.0132831710 86.3245 + 107 -229.0303729919 0.143E-03 0.3156163674 0.0132872291 88.1342 + 114 -229.0303059711 0.140E-03 0.3152696706 0.0132734747 89.4871 + 118 -229.0303345568 0.142E-03 0.3154225372 0.0132797473 94.4735 + 125 -229.0302921387 0.135E-03 0.3151109270 0.0132747326 96.9005 + 128 -229.0303055540 0.132E-03 0.3151346567 0.0132786675 98.2168 + 138 -229.0302506048 0.132E-03 0.3145841302 0.0132752555 99.2295 + 143 -229.0302145978 0.130E-03 0.3143478202 0.0132709710 100.3835 + 145 -229.0302227106 0.126E-03 0.3144472836 0.0132705909 101.6304 + 151 -229.0301912956 0.123E-03 0.3142505375 0.0132653262 103.4758 + 152 -229.0301914429 0.122E-03 0.3142433195 0.0132655895 104.6604 + 156 -229.0301891028 0.124E-03 0.3141687151 0.0132670937 106.3771 + 159 -229.0302286130 0.125E-03 0.3144086172 0.0132738501 108.0332 + 165 -229.0302582028 0.123E-03 0.3145266376 0.0132810300 110.4815 + 172 -229.0302652325 0.122E-03 0.3145949354 0.0132818585 113.3111 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 2.240368 GB ] [ VIRT MEM : 9.284863 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 310.435984 s ] [ CPU TIME: 21552.507530 s ] <<<<< .. + +* Number of generators 327679 + +.. >>>>> [ RES MEM : 2.240368 GB ] [ VIRT MEM : 9.284863 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 310.437124 s ] [ CPU TIME: 21552.588616 s ] <<<<< .. + +* Number of selectors 327679 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8774803471348104 + +Summary at N_det = 327680 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.96750678 +# PT2 -0.06274913 0.00012080 +# rPT2 -0.06192676 0.00011922 +# +# E+PT2 -229.03025592 0.00012080 +# E+rPT2 -229.02943354 0.00011922 +# ============ ============================= + + N_det = 327680 + N_states = 1 + + * State 1 + < S^2 > = 4.593265093367724E-003 + E = -228.967506782795 + Variance = 0.314548817070182 + PT norm = 0.115238141971120 + PT2 = -6.274913490049855E-002 + rPT2 = -6.192675811954607E-002 + E+PT2 = -229.030255917696 +/- 1.208044562205209E-004 + E+rPT2 = -229.029433540915 +/- 1.192212187784608E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.784446504604 + Vee = 238.557405969938 + Vecp = 0.000000000000000E+000 + T = 229.151303973082 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0651 -229.03714399 + -0.0698 -229.04293721 + -0.0794 -229.04427213 + -0.1028 -229.04487241 + -0.1407 -229.04426181 + -0.1866 -229.04312164 + -0.2336 -229.04172230 + =========== =================== + +* Number of unique beta determinants 64930 +* Number of unique alpha determinants 65203 + +.. >>>>> [ RES MEM : 2.257774 GB ] [ VIRT MEM : 9.280045 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 314.044538 s ] [ CPU TIME: 21809.412310 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 655360 +* Number of threads for diagonalization 72 +* Memory(Gb) 1.026906833052635 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9675067911 0.004593 0.495E-03 + 2 -228.9694856560 0.004864 0.349E-04 + 3 -228.9695126766 0.004800 0.498E-05 + 4 -228.9695191188 0.004730 0.522E-06 + 5 -228.9695201279 0.004707 0.589E-07 + 6 -228.9695202354 0.004694 0.769E-08 + 7 -228.9695202496 0.004694 0.135E-08 + 8 -228.9695202523 0.004695 0.194E-09 + 9 -228.9695202527 0.004696 0.225E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 2.804161 GB ] [ VIRT MEM : 9.976467 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 343.968615 s ] [ CPU TIME: 23806.937406 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 2.218239 GB ] [ VIRT MEM : 9.242569 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 344.064652 s ] [ CPU TIME: 23813.347368 s ] <<<<< .. + +* Energy of state 1 -228.9695202526946 +* S^2 of state 1 0.4695824470905827E-02 +* Saved determinants 655360 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 2.101902 GB ] [ VIRT MEM : 9.122429 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 350.614140 s ] [ CPU TIME: 23915.790172 s ] <<<<< .. + +* Number of generators 655356 + +.. >>>>> [ RES MEM : 2.101902 GB ] [ VIRT MEM : 9.122429 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 350.616012 s ] [ CPU TIME: 23915.924989 s ] <<<<< .. + +* Number of selectors 655356 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 +* PT2 Energy denominator -228.9695202526946 + +.. >>>>> [ RES MEM : 2.155670 GB ] [ VIRT MEM : 9.178097 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 350.889907 s ] [ CPU TIME: 23935.594831 s ] <<<<< .. + +* Number of generators 655356 + +.. >>>>> [ RES MEM : 2.155670 GB ] [ VIRT MEM : 9.178097 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 350.891734 s ] [ CPU TIME: 23935.726417 s ] <<<<< .. + +* Number of selectors 655356 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 +* Number of tasks 759727 +* Number of fragmented tasks 9947 +* Number of threads for PT2 72 +* Memory (Gb) 2.605947904735804 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0294395019 0.123E-02 0.3018601514 0.0126366938 32.4803 + 4 -229.0293603360 0.833E-03 0.3011755366 0.0126364351 33.9385 + 5 -229.0294639503 0.682E-03 0.3035015409 0.0125868986 36.9178 + 6 -229.0300208407 0.805E-03 0.3066059262 0.0126796580 43.7330 + 8 -229.0296592289 0.665E-03 0.3040710595 0.0126215880 46.1695 + 9 -229.0299599053 0.607E-03 0.3058366024 0.0126689950 52.8105 + 12 -229.0300046086 0.446E-03 0.3054307997 0.0127067350 54.3525 + 14 -229.0302025520 0.436E-03 0.3060279319 0.0127676680 57.2725 + 15 -229.0302938455 0.412E-03 0.3065433589 0.0127802864 64.6189 + 19 -229.0300749809 0.404E-03 0.3052233529 0.0127403478 67.6148 + 20 -229.0300790371 0.383E-03 0.3056477707 0.0127261242 71.2654 + 24 -229.0301201023 0.349E-03 0.3057498912 0.0127403646 73.3045 + 27 -229.0300558460 0.316E-03 0.3051942094 0.0127353350 78.8864 + 28 -229.0300928494 0.306E-03 0.3053678066 0.0127425793 80.9610 + 29 -229.0300112789 0.307E-03 0.3047324887 0.0127342478 84.7915 + 30 -229.0300506725 0.299E-03 0.3047841441 0.0127462850 85.7985 + 31 -229.0300979023 0.293E-03 0.3051621970 0.0127510381 87.3976 + 32 -229.0300430880 0.306E-03 0.3048221838 0.0127405821 88.9941 + 33 -229.0300122896 0.299E-03 0.3046160489 0.0127349351 90.5863 + 35 -229.0300233593 0.287E-03 0.3044663716 0.0127430933 95.3336 + 36 -229.0300884612 0.286E-03 0.3048007508 0.0127577057 97.0037 + 40 -229.0303092036 0.294E-03 0.3062158843 0.0127922179 98.4436 + 41 -229.0303251903 0.288E-03 0.3062771835 0.0127969993 102.2201 + 43 -229.0304212164 0.279E-03 0.3066081163 0.0128223766 107.7072 + 47 -229.0305251107 0.276E-03 0.3070826807 0.0128471002 110.5435 + 50 -229.0305852833 0.275E-03 0.3074593051 0.0128579318 114.9515 + 53 -229.0304862928 0.270E-03 0.3071503627 0.0128301012 116.7865 + 58 -229.0304390667 0.249E-03 0.3071683281 0.0128129408 119.1525 + 62 -229.0304274047 0.238E-03 0.3070621977 0.0128106159 122.4488 + 63 -229.0304121771 0.235E-03 0.3069886264 0.0128071918 123.9625 + 69 -229.0304581673 0.224E-03 0.3073493779 0.0128119092 130.6074 + 74 -229.0304461937 0.215E-03 0.3071000132 0.0128146541 131.7035 + 77 -229.0304145593 0.211E-03 0.3068944004 0.0128089148 134.2066 + 80 -229.0304511084 0.204E-03 0.3070796643 0.0128158277 137.8865 + 84 -229.0304670500 0.198E-03 0.3072274570 0.0128167608 140.6065 + 86 -229.0304708280 0.194E-03 0.3072220846 0.0128179066 144.8795 + 96 -229.0305807312 0.181E-03 0.3080814197 0.0128292060 146.2584 + 97 -229.0305960936 0.180E-03 0.3082027113 0.0128311344 149.3491 + 103 -229.0305011009 0.179E-03 0.3075850530 0.0128166720 153.4285 + 104 -229.0304958402 0.177E-03 0.3075640521 0.0128155379 154.8486 + 107 -229.0305265997 0.176E-03 0.3078025894 0.0128194358 155.9965 + 110 -229.0305041893 0.171E-03 0.3077205079 0.0128140077 160.4922 + 115 -229.0304488604 0.165E-03 0.3075034061 0.0127996579 164.5935 + 124 -229.0303919948 0.151E-03 0.3071027091 0.0127918359 165.6385 + 127 -229.0304104010 0.147E-03 0.3072347038 0.0127938763 170.2071 + 138 -229.0303373790 0.136E-03 0.3066822755 0.0127854862 174.5785 + 141 -229.0303102282 0.135E-03 0.3064699662 0.0127822531 176.0735 + 142 -229.0303149422 0.134E-03 0.3064859893 0.0127833876 177.1775 + 144 -229.0303075885 0.133E-03 0.3064744780 0.0127809386 179.7035 + 151 -229.0302481945 0.126E-03 0.3060838755 0.0127722311 183.6880 + 158 -229.0302644771 0.122E-03 0.3060710224 0.0127783203 190.4455 + 170 -229.0302367303 0.114E-03 0.3057769682 0.0127772717 192.7945 + 171 -229.0302487907 0.114E-03 0.3058536194 0.0127790565 196.4351 + 175 -229.0303019736 0.120E-03 0.3060934641 0.0127910372 198.6835 + 186 -229.0302755308 0.117E-03 0.3059996396 0.0127844387 199.8738 + 188 -229.0303242191 0.114E-03 0.3063241793 0.0127918148 203.1900 + 199 -229.0303709945 0.112E-03 0.3066015592 0.0128007663 204.3539 + 201 -229.0303856999 0.111E-03 0.3066738837 0.0128038046 206.3379 + 205 -229.0303786435 0.110E-03 0.3066794351 0.0128007389 207.6778 + 207 -229.0303682409 0.109E-03 0.3066148794 0.0127988815 210.1250 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 2.457169 GB ] [ VIRT MEM : 9.477890 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 563.557819 s ] [ CPU TIME: 39035.455183 s ] <<<<< .. + +* Number of generators 655356 + +.. >>>>> [ RES MEM : 2.457169 GB ] [ VIRT MEM : 9.477890 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 563.559700 s ] [ CPU TIME: 39035.589685 s ] <<<<< .. + +* Number of selectors 655356 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8811355344782460 + +Summary at N_det = 655360 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.96952025 +# PT2 -0.06087123 0.00010567 +# rPT2 -0.06010166 0.00010434 +# +# E+PT2 -229.03039148 0.00010567 +# E+rPT2 -229.02962191 0.00010434 +# ============ ============================= + + N_det = 655360 + N_states = 1 + + * State 1 + < S^2 > = 4.695824470905827E-003 + E = -228.969520252695 + Variance = 0.306694123314383 + PT norm = 0.113157000266743 + PT2 = -6.087123011683984E-002 + rPT2 = -6.010165803330823E-002 + E+PT2 = -229.030391482811 +/- 1.056728318132037E-004 + E+rPT2 = -229.029621910728 +/- 1.043368499183894E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.788835689039 + Vee = 238.553477264765 + Vecp = 0.000000000000000E+000 + T = 229.157608392791 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0619 -229.03582504 + -0.0651 -229.03669440 + -0.0698 -229.04131214 + -0.0794 -229.04336141 + -0.1028 -229.04443711 + -0.1407 -229.04407239 + -0.1866 -229.04308464 + =========== =================== + +* Number of unique beta determinants 126609 +* Number of unique alpha determinants 122588 + +.. >>>>> [ RES MEM : 2.529076 GB ] [ VIRT MEM : 9.564510 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 571.785482 s ] [ CPU TIME: 39603.900529 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 1310720 +* Number of threads for diagonalization 72 +* Memory(Gb) 2.044509567320347 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9695202546 0.004696 0.274E-03 + 2 -228.9706762353 0.004949 0.111E-04 + 3 -228.9706865083 0.004903 0.186E-05 + 4 -228.9706884134 0.004869 0.103E-06 + 5 -228.9706886491 0.004846 0.276E-07 + 6 -228.9706886912 0.004829 0.353E-08 + 7 -228.9706886981 0.004824 0.406E-09 + 8 -228.9706886990 0.004822 0.654E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 3.769836 GB ] [ VIRT MEM : 11.153809 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 632.841721 s ] [ CPU TIME: 43559.333550 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 2.656666 GB ] [ VIRT MEM : 9.687489 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 632.949177 s ] [ CPU TIME: 43563.408679 s ] <<<<< .. + +* Energy of state 1 -228.9706886989749 +* S^2 of state 1 0.4822488586973868E-02 +* Saved determinants 1310720 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 2.389336 GB ] [ VIRT MEM : 9.413502 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 645.661823 s ] [ CPU TIME: 43716.290920 s ] <<<<< .. + +* Number of generators 1310702 + +.. >>>>> [ RES MEM : 2.389336 GB ] [ VIRT MEM : 9.413502 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 645.665212 s ] [ CPU TIME: 43716.535770 s ] <<<<< .. + +* Number of selectors 1310702 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 +* PT2 Energy denominator -228.9706886989749 + +.. >>>>> [ RES MEM : 2.517124 GB ] [ VIRT MEM : 9.542900 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 646.304163 s ] [ CPU TIME: 43762.426822 s ] <<<<< .. + +* Number of generators 1310702 + +.. >>>>> [ RES MEM : 2.517124 GB ] [ VIRT MEM : 9.542900 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 646.307494 s ] [ CPU TIME: 43762.666254 s ] <<<<< .. + +* Number of selectors 1310702 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 +* Number of tasks 1483180 +* Number of fragmented tasks 10012 +* Number of threads for PT2 72 +* Memory (Gb) 2.655420644357800 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0331861274 0.139E-02 0.3190416228 0.0129894848 67.3415 + 4 -229.0327719954 0.110E-02 0.3145752541 0.0129807049 70.9574 + 5 -229.0321335586 0.988E-03 0.3110614123 0.0128613037 82.1835 + 6 -229.0321572209 0.822E-03 0.3123291436 0.0128187051 88.3087 + 7 -229.0322593650 0.697E-03 0.3127961451 0.0128457773 92.1695 + 8 -229.0319685127 0.709E-03 0.3115309660 0.0127765461 103.6978 + 9 -229.0321935059 0.659E-03 0.3130362153 0.0128001787 117.4994 + 12 -229.0323423650 0.622E-03 0.3140935736 0.0128188570 121.0675 + 14 -229.0323356528 0.545E-03 0.3136269207 0.0128507511 130.4580 + 17 -229.0322336392 0.488E-03 0.3129735637 0.0128405822 134.8382 + 18 -229.0322941140 0.464E-03 0.3132638980 0.0128510018 141.9276 + 19 -229.0320654131 0.496E-03 0.3121000961 0.0128015513 147.4495 + 20 -229.0320425885 0.464E-03 0.3119990630 0.0127939654 152.4414 + 22 -229.0320329990 0.421E-03 0.3120161322 0.0127898255 156.5745 + 24 -229.0319590332 0.411E-03 0.3114818999 0.0127814697 162.0205 + 27 -229.0321286905 0.379E-03 0.3120031134 0.0128299764 172.5381 + 28 -229.0320862466 0.368E-03 0.3117488638 0.0128223961 174.9955 + 29 -229.0319728635 0.359E-03 0.3108085505 0.0128143125 185.3776 + 32 -229.0320257288 0.365E-03 0.3105556936 0.0128436174 197.8308 + 34 -229.0319840125 0.353E-03 0.3101939716 0.0128404031 199.7840 + 36 -229.0319141761 0.327E-03 0.3097752371 0.0128281867 205.1705 + 39 -229.0321742083 0.362E-03 0.3112615043 0.0128731169 208.4142 + 40 -229.0321839099 0.357E-03 0.3115582618 0.0128643715 210.8725 + 41 -229.0321111608 0.356E-03 0.3112132762 0.0128486875 217.9165 + 42 -229.0320947178 0.348E-03 0.3111363245 0.0128442841 222.9465 + 43 -229.0320245288 0.347E-03 0.3107191877 0.0128313035 229.6569 + 47 -229.0318144341 0.344E-03 0.3093671285 0.0127961527 240.8495 + 48 -229.0318092476 0.337E-03 0.3093056219 0.0127971454 242.6486 + 58 -229.0317070256 0.281E-03 0.3089537682 0.0127717316 255.9965 + 63 -229.0316081781 0.263E-03 0.3084180006 0.0127511894 262.6812 + 68 -229.0315550175 0.257E-03 0.3080118805 0.0127448975 264.6334 + 69 -229.0315636254 0.253E-03 0.3080431247 0.0127467530 268.3635 + 71 -229.0315117607 0.249E-03 0.3077306242 0.0127380742 275.4305 + 74 -229.0314423180 0.238E-03 0.3073780585 0.0127237484 276.6506 + 77 -229.0314035521 0.232E-03 0.3072750079 0.0127129690 280.9155 + 80 -229.0314325356 0.217E-03 0.3074792379 0.0127165115 283.0265 + 82 -229.0313854908 0.215E-03 0.3072184492 0.0127072619 285.0485 + 84 -229.0313714172 0.214E-03 0.3071678011 0.0127031955 286.8585 + 86 -229.0313379873 0.215E-03 0.3068868932 0.0126998495 291.9501 + 91 -229.0313449750 0.211E-03 0.3070032842 0.0126978699 295.6135 + 93 -229.0312783234 0.209E-03 0.3065441712 0.0126887097 297.7625 + 96 -229.0312841715 0.204E-03 0.3065123164 0.0126922005 309.5655 + 97 -229.0312759091 0.202E-03 0.3064269560 0.0126918918 310.9625 + 101 -229.0313063190 0.196E-03 0.3066857555 0.0126948281 322.5035 + 111 -229.0311971523 0.179E-03 0.3062640167 0.0126687569 330.0975 + 120 -229.0311524416 0.172E-03 0.3060538084 0.0126581738 333.4862 + 122 -229.0311434322 0.169E-03 0.3060569520 0.0126554415 336.7226 + 123 -229.0311270979 0.163E-03 0.3059255608 0.0126537263 344.0911 + 128 -229.0311019387 0.158E-03 0.3057613014 0.0126500969 348.8240 + 131 -229.0311204131 0.155E-03 0.3058217586 0.0126547729 361.4815 + 149 -229.0310817539 0.140E-03 0.3056701237 0.0126446436 363.1055 + 152 -229.0310567835 0.138E-03 0.3055337544 0.0126398840 366.5156 + 153 -229.0310599772 0.138E-03 0.3055453536 0.0126409485 371.2935 + 154 -229.0310422468 0.138E-03 0.3054180822 0.0126386425 375.3314 + 155 -229.0310368159 0.137E-03 0.3053648056 0.0126383452 376.7475 + 165 -229.0309264201 0.123E-03 0.3045824372 0.0126241723 381.0615 + 168 -229.0309363470 0.122E-03 0.3046334007 0.0126262740 383.7965 + 171 -229.0308836350 0.119E-03 0.3042371678 0.0126199373 386.0456 + 172 -229.0308994230 0.120E-03 0.3043199082 0.0126231051 398.4064 + 182 -229.0309161270 0.115E-03 0.3044488685 0.0126249312 408.7459 + 198 -229.0309163556 0.108E-03 0.3045145370 0.0126235691 416.7913 + 220 -229.0308447983 0.984E-04 0.3040355554 0.0126120186 424.5794 + 221 -229.0308380012 0.982E-04 0.3039845888 0.0126110883 430.2324 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 2.676064 GB ] [ VIRT MEM : 9.830013 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1081.209387 s ] [ CPU TIME: 74658.932715 s ] <<<<< .. + +* Number of generators 1310702 + +.. >>>>> [ RES MEM : 2.676064 GB ] [ VIRT MEM : 9.830013 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1081.212743 s ] [ CPU TIME: 74659.170735 s ] <<<<< .. + +* Number of selectors 1310702 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8826236797262768 + +Summary at N_det = 1310720 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.97068870 +# PT2 -0.06015368 0.00009677 +# rPT2 -0.05940453 0.00009557 +# +# E+PT2 -229.03084238 0.00009677 +# E+rPT2 -229.03009322 0.00009557 +# ============ ============================= + + N_det = 1310720 + N_states = 1 + + * State 1 + < S^2 > = 4.822488586973868E-003 + E = -228.970688698975 + Variance = 0.304030263519679 + PT norm = 0.112299093511944 + PT2 = -6.015368109400405E-002 + rPT2 = -5.940452549028099E-002 + E+PT2 = -229.030842380069 +/- 9.677297802618605E-005 + E+rPT2 = -229.030093224465 +/- 9.556776468830254E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.790266955058 + Vee = 238.550528214867 + Vecp = 0.000000000000000E+000 + T = 229.160820262427 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0601 -229.07025513 + -0.0619 -229.04359727 + -0.0651 -229.03950305 + -0.0698 -229.04202925 + -0.0794 -229.04348305 + -0.1028 -229.04441363 + -0.1407 -229.04408173 + =========== =================== + +* Number of unique beta determinants 261619 +* Number of unique alpha determinants 261743 + +.. >>>>> [ RES MEM : 3.020775 GB ] [ VIRT MEM : 10.170818 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1101.810028 s ] [ CPU TIME: 76073.611618 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 2621440 +* Number of threads for diagonalization 72 +* Memory(Gb) 4.109506100416183 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9706886994 0.004822 0.130E-03 + 2 -228.9712571307 0.004998 0.294E-05 + 3 -228.9712610371 0.004975 0.721E-06 + 4 -228.9712615737 0.004961 0.236E-07 + 5 -228.9712616276 0.004947 0.741E-08 + 6 -228.9712616395 0.004935 0.145E-08 + 7 -228.9712616425 0.004929 0.148E-09 + 8 -228.9712616429 0.004928 0.222E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 5.332249 GB ] [ VIRT MEM : 13.192337 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1259.563229 s ] [ CPU TIME: 86356.170102 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 3.105900 GB ] [ VIRT MEM : 10.261173 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1259.769853 s ] [ CPU TIME: 86362.923744 s ] <<<<< .. + +* Energy of state 1 -228.9712616428534 +* S^2 of state 1 0.4927677199200033E-02 +* Saved determinants 2621440 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 2.444271 GB ] [ VIRT MEM : 9.589237 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1281.351257 s ] [ CPU TIME: 86637.013902 s ] <<<<< .. + +* Number of generators 2621041 + +.. >>>>> [ RES MEM : 2.444271 GB ] [ VIRT MEM : 9.589237 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1281.357583 s ] [ CPU TIME: 86637.468587 s ] <<<<< .. + +* Number of selectors 2621041 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 +* PT2 Energy denominator -228.9712616428534 + +.. >>>>> [ RES MEM : 2.825447 GB ] [ VIRT MEM : 9.972095 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1282.747748 s ] [ CPU TIME: 86730.671974 s ] <<<<< .. + +* Number of generators 2621041 + +.. >>>>> [ RES MEM : 2.825447 GB ] [ VIRT MEM : 9.972095 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1282.754016 s ] [ CPU TIME: 86731.122524 s ] <<<<< .. + +* Number of selectors 2621041 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 +* Number of tasks 2919347 +* Number of fragmented tasks 10040 +* Number of threads for PT2 72 +* Memory (Gb) 2.754319787286222 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0315629769 0.625E-03 0.3057657718 0.0126166566 166.4633 + 4 -229.0322394206 0.904E-03 0.3087741799 0.0127661051 198.2833 + 6 -229.0327222170 0.559E-03 0.3131156730 0.0128008832 230.0683 + 7 -229.0325472935 0.502E-03 0.3122260396 0.0127554128 234.2603 + 8 -229.0321792186 0.594E-03 0.3103361882 0.0126728583 266.5633 + 9 -229.0317810071 0.660E-03 0.3087170703 0.0125764217 292.6573 + 10 -229.0313733418 0.722E-03 0.3063992285 0.0124997376 297.1852 + 11 -229.0315041889 0.665E-03 0.3070078710 0.0125241830 304.0803 + 14 -229.0315359412 0.578E-03 0.3075718370 0.0125237307 345.4058 + 18 -229.0312949919 0.597E-03 0.3056753219 0.0125033889 357.4132 + 19 -229.0311581961 0.581E-03 0.3047792468 0.0124779381 369.8633 + 20 -229.0310555861 0.561E-03 0.3042236581 0.0124588496 376.4323 + 21 -229.0310804579 0.534E-03 0.3045084361 0.0124581085 399.9632 + 22 -229.0310198359 0.512E-03 0.3039528615 0.0124554860 418.7203 + 27 -229.0312377740 0.501E-03 0.3050611976 0.0125017135 452.3653 + 29 -229.0311023490 0.493E-03 0.3042198054 0.0124817720 480.6373 + 31 -229.0310945334 0.462E-03 0.3041734237 0.0124783120 483.5683 + 32 -229.0311124073 0.446E-03 0.3044552129 0.0124738509 508.5263 + 34 -229.0308697031 0.434E-03 0.3028386492 0.0124376611 522.1793 + 36 -229.0307648698 0.417E-03 0.3020488125 0.0124233711 533.8482 + 40 -229.0309804305 0.388E-03 0.3032603167 0.0124685218 536.9079 + 41 -229.0309611604 0.379E-03 0.3031896597 0.0124637897 554.1592 + 42 -229.0309621685 0.377E-03 0.3033087863 0.0124589394 569.5642 + 43 -229.0309154295 0.368E-03 0.3028440437 0.0124568593 585.9041 + 47 -229.0308801526 0.323E-03 0.3022511974 0.0124646012 587.4233 + 48 -229.0308806735 0.316E-03 0.3020711505 0.0124709490 607.9012 + 50 -229.0308733935 0.309E-03 0.3021470107 0.0124656886 609.7852 + 52 -229.0308127357 0.302E-03 0.3018833272 0.0124514444 617.0623 + 54 -229.0308436866 0.292E-03 0.3021680529 0.0124536283 633.4473 + 58 -229.0309812193 0.300E-03 0.3031258696 0.0124731051 643.1923 + 62 -229.0309082141 0.275E-03 0.3027112118 0.0124592480 656.4283 + 63 -229.0308467724 0.278E-03 0.3023205263 0.0124492418 689.2683 + 74 -229.0308998424 0.250E-03 0.3027289415 0.0124567056 701.2592 + 77 -229.0309397525 0.242E-03 0.3028613933 0.0124671345 741.8403 + 87 -229.0307970844 0.207E-03 0.3018892953 0.0124469042 742.8563 + 96 -229.0308634391 0.189E-03 0.3021339155 0.0124626836 751.6653 + 100 -229.0308163649 0.185E-03 0.3018368286 0.0124549806 757.7343 + 102 -229.0307273481 0.193E-03 0.3012622022 0.0124409375 758.8662 + 103 -229.0307104176 0.192E-03 0.3011585501 0.0124382673 788.9927 + 107 -229.0306627709 0.187E-03 0.3008753968 0.0124297540 804.8183 + 109 -229.0306864400 0.184E-03 0.3009820473 0.0124348831 824.4502 + 135 -229.0306508805 0.159E-03 0.3005506803 0.0124360173 827.5713 + 138 -229.0306350799 0.158E-03 0.3004918295 0.0124320331 828.9293 + 139 -229.0306554620 0.156E-03 0.3005672831 0.0124374400 835.2073 + 143 -229.0306274392 0.158E-03 0.3004116169 0.0124322795 847.8702 + 148 -229.0306110114 0.149E-03 0.3002239270 0.0124336801 856.4783 + 149 -229.0306140891 0.148E-03 0.3002756715 0.0124331374 859.5511 + 151 -229.0306290580 0.146E-03 0.3003467571 0.0124362706 861.4753 + 153 -229.0306266866 0.145E-03 0.3003151707 0.0124363537 864.2717 + 154 -229.0306236176 0.145E-03 0.3003123280 0.0124351281 869.5327 + 156 -229.0305987547 0.144E-03 0.3001779133 0.0124305296 879.4302 + 159 -229.0305879605 0.142E-03 0.3001204497 0.0124286110 881.6162 + 160 -229.0305860734 0.141E-03 0.3001006299 0.0124284912 885.8032 + 163 -229.0306191081 0.141E-03 0.3003211534 0.0124330111 890.3113 + 165 -229.0306550051 0.142E-03 0.3005537493 0.0124386420 897.1443 + 169 -229.0306209904 0.140E-03 0.3003522053 0.0124325262 905.6483 + 170 -229.0306289045 0.139E-03 0.3003675875 0.0124349752 906.8614 + 172 -229.0305768014 0.135E-03 0.2999822648 0.0124281333 934.8083 + 182 -229.0305655839 0.130E-03 0.2999441687 0.0124251210 953.2293 + 195 -229.0305916689 0.118E-03 0.3000940655 0.0124305097 957.0362 + 196 -229.0306150071 0.119E-03 0.3002020582 0.0124357584 966.4040 + 213 -229.0306111162 0.111E-03 0.3001361905 0.0124364183 969.9265 + 214 -229.0306097126 0.111E-03 0.3001198242 0.0124364141 977.7263 + 216 -229.0305972461 0.110E-03 0.3000537258 0.0124338498 981.7408 + 221 -229.0306460078 0.111E-03 0.3002503571 0.0124454021 993.4906 + 226 -229.0306512235 0.109E-03 0.3003261525 0.0124449312 995.2118 + 227 -229.0306435586 0.109E-03 0.3002892751 0.0124432474 996.3756 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 3.587410 GB ] [ VIRT MEM : 10.677006 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2289.198638 s ] [ CPU TIME: 158310.206301 s ] <<<<< .. + +* Number of generators 2621041 + +.. >>>>> [ RES MEM : 3.587410 GB ] [ VIRT MEM : 10.677006 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2289.204723 s ] [ CPU TIME: 158310.643697 s ] <<<<< .. + +* Number of selectors 2621041 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8840611562735848 + +Summary at N_det = 2621440 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.97126164 +# PT2 -0.05938667 0.00010708 +# rPT2 -0.05865674 0.00010577 +# +# E+PT2 -229.03064832 0.00010708 +# E+rPT2 -229.02991839 0.00010577 +# ============ ============================= + + N_det = 2621440 + N_states = 1 + + * State 1 + < S^2 > = 4.927677199200033E-003 + E = -228.971261642853 + Variance = 0.300313659272669 + PT norm = 0.111553051806766 + PT2 = -5.938667296611448E-002 + rPT2 = -5.865674355920337E-002 + E+PT2 = -229.030648315820 +/- 1.070824913963468E-004 + E+rPT2 = -229.029918386413 +/- 1.057663264129995E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.790705132521 + Vee = 238.548970328626 + Vecp = 0.000000000000000E+000 + T = 229.162243382253 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0594 -229.01620392 + -0.0601 -229.04174816 + -0.0619 -229.04053503 + -0.0651 -229.03887846 + -0.0698 -229.04144189 + -0.0794 -229.04308672 + -0.1028 -229.04418366 + =========== =================== + +* Number of unique beta determinants 515834 +* Number of unique alpha determinants 520428 + +.. >>>>> [ RES MEM : 3.445808 GB ] [ VIRT MEM : 11.126812 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2351.484666 s ] [ CPU TIME: 162587.656706 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5242865 +* Number of threads for diagonalization 72 +* Memory(Gb) 8.211474899202585 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9712616112 0.004928 0.101E-03 + 2 -228.9717162188 0.005090 0.189E-05 + 3 -228.9717190366 0.005080 0.498E-06 + 4 -228.9717193833 0.005075 0.120E-07 + 5 -228.9717194102 0.005069 0.317E-08 + 6 -228.9717194151 0.005065 0.696E-09 + 7 -228.9717194166 0.005062 0.774E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 8.127056 GB ] [ VIRT MEM : 17.456417 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2766.616224 s ] [ CPU TIME: 190513.887653 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 3.752254 GB ] [ VIRT MEM : 11.440777 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2767.006303 s ] [ CPU TIME: 190520.622966 s ] <<<<< .. + +* Energy of state 1 -228.9717194166205 +* S^2 of state 1 0.5061805547594074E-02 +* Saved determinants 5242865 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 3.388943 GB ] [ VIRT MEM : 11.094433 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2809.793390 s ] [ CPU TIME: 190993.638318 s ] <<<<< .. + +* Number of generators 5235877 + +.. >>>>> [ RES MEM : 3.388943 GB ] [ VIRT MEM : 11.094433 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2809.805157 s ] [ CPU TIME: 190994.483801 s ] <<<<< .. + +* Number of selectors 5235877 +* Number of comb teeth 100 +* pt2_n_tasks_max 524 +* PT2 Energy denominator -228.9717194166205 + +.. >>>>> [ RES MEM : 3.938637 GB ] [ VIRT MEM : 11.526077 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2812.797559 s ] [ CPU TIME: 191164.670537 s ] <<<<< .. + +* Number of generators 5235877 + +.. >>>>> [ RES MEM : 3.938637 GB ] [ VIRT MEM : 11.526077 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2812.808747 s ] [ CPU TIME: 191164.681640 s ] <<<<< .. + +* Number of selectors 5235877 +* Number of comb teeth 100 +* pt2_n_tasks_max 524 +* Number of tasks 5747940 +* Number of fragmented tasks 10065 +* Number of threads for PT2 72 +* Memory (Gb) 2.951922408454120 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0318757284 0.148E-02 0.3078893351 0.0124493073 333.9687 + 4 -229.0322219266 0.106E-02 0.3077511472 0.0125995431 382.7656 + 5 -229.0323546490 0.883E-03 0.3086915365 0.0126111360 442.6956 + 6 -229.0319189409 0.891E-03 0.3064068591 0.0125125527 478.0017 + 7 -229.0316928231 0.783E-03 0.3043286266 0.0124997418 518.7277 + 8 -229.0317490770 0.680E-03 0.3048981800 0.0124976451 600.0707 + 9 -229.0316689777 0.647E-03 0.3054377456 0.0124545789 639.3967 + 10 -229.0315994915 0.581E-03 0.3057477437 0.0124202344 644.0227 + 11 -229.0317012845 0.534E-03 0.3068865558 0.0124325175 657.7006 + 12 -229.0317882231 0.495E-03 0.3074095697 0.0124523517 712.7187 + 13 -229.0316816816 0.498E-03 0.3063135238 0.0124601230 725.4010 + 14 -229.0317292994 0.463E-03 0.3066150395 0.0124675208 745.8597 + 15 -229.0317665403 0.432E-03 0.3069572083 0.0124703084 789.5031 + 17 -229.0315605091 0.442E-03 0.3060634514 0.0124254142 793.1607 + 18 -229.0315729208 0.417E-03 0.3061793943 0.0124271913 842.1937 + 19 -229.0315993137 0.395E-03 0.3063285540 0.0124259140 904.1456 + 20 -229.0315473679 0.375E-03 0.3059325767 0.0124212506 928.0867 + 21 -229.0316491627 0.371E-03 0.3066043180 0.0124375515 937.2720 + 22 -229.0317190259 0.360E-03 0.3071273060 0.0124471882 945.0847 + 23 -229.0316097768 0.341E-03 0.3063171723 0.0124320795 983.5148 + 26 -229.0315033427 0.358E-03 0.3054417159 0.0124215919 997.3487 + 27 -229.0314512989 0.348E-03 0.3049704421 0.0124186935 1045.0516 + 28 -229.0311960522 0.423E-03 0.3033397042 0.0123787697 1073.2368 + 29 -229.0312738869 0.415E-03 0.3035137113 0.0124028466 1119.4397 + 30 -229.0313312573 0.405E-03 0.3036047837 0.0124199003 1147.9810 + 31 -229.0312562841 0.399E-03 0.3030297859 0.0124110837 1165.4287 + 32 -229.0312879811 0.396E-03 0.3033603613 0.0124098418 1207.2098 + 34 -229.0310781859 0.400E-03 0.3019927733 0.0123769821 1274.7768 + 39 -229.0309535409 0.359E-03 0.3002805024 0.0123882145 1299.5858 + 40 -229.0310045240 0.353E-03 0.3007079847 0.0123933516 1306.6608 + 41 -229.0309108463 0.357E-03 0.3002730965 0.0123729022 1367.2558 + 43 -229.0309641602 0.335E-03 0.3007820848 0.0123715802 1438.3687 + 46 -229.0309681973 0.323E-03 0.3008281226 0.0123721024 1454.7762 + 47 -229.0309811964 0.299E-03 0.3006804797 0.0123801168 1497.8647 + 50 -229.0309630909 0.280E-03 0.3003710914 0.0123846936 1522.4092 + 51 -229.0309811445 0.275E-03 0.3004210106 0.0123905437 1527.0397 + 54 -229.0307900634 0.274E-03 0.2994363031 0.0123514100 1559.7717 + 58 -229.0307935254 0.257E-03 0.2995268692 0.0123507527 1589.5557 + 60 -229.0306561589 0.258E-03 0.2987460656 0.0123256015 1592.3807 + 63 -229.0306773802 0.246E-03 0.2989268571 0.0123266044 1599.8713 + 65 -229.0306942799 0.242E-03 0.2989142722 0.0123333840 1629.8218 + 67 -229.0307393520 0.237E-03 0.2991369513 0.0123420837 1662.1460 + 73 -229.0306269155 0.213E-03 0.2982527566 0.0123305270 1670.2024 + 74 -229.0306360862 0.210E-03 0.2982867010 0.0123324965 1684.6958 + 75 -229.0306356422 0.207E-03 0.2982311805 0.0123342637 1712.7848 + 77 -229.0306587201 0.206E-03 0.2985083863 0.0123340461 1717.4969 + 78 -229.0306766988 0.204E-03 0.2985584837 0.0123395673 1721.7059 + 80 -229.0307221291 0.209E-03 0.2989646900 0.0123423409 1751.2399 + 81 -229.0307493156 0.209E-03 0.2991416970 0.0123468372 1758.2877 + 84 -229.0308094899 0.205E-03 0.2994425035 0.0123598969 1771.8977 + 85 -229.0308305543 0.204E-03 0.2995333217 0.0123645622 1779.0527 + 87 -229.0308173327 0.203E-03 0.2994401510 0.0123622891 1790.1597 + 89 -229.0307792458 0.199E-03 0.2992484066 0.0123542042 1805.9613 + 91 -229.0307998956 0.200E-03 0.2993477782 0.0123588080 1835.8490 + 92 -229.0308217927 0.199E-03 0.2994705654 0.0123628171 1847.2848 + 93 -229.0308229295 0.196E-03 0.2994794487 0.0123627160 1870.1463 + 100 -229.0308186325 0.184E-03 0.2993731117 0.0123656250 1891.9020 + 103 -229.0307934549 0.182E-03 0.2992120801 0.0123619628 1903.1898 + 104 -229.0308026213 0.180E-03 0.2992686314 0.0123632879 1907.6974 + 105 -229.0307751183 0.181E-03 0.2991046963 0.0123584864 1937.1068 + 107 -229.0307990985 0.178E-03 0.2993134124 0.0123604421 1959.9156 + 123 -229.0308286344 0.161E-03 0.2993798371 0.0123694064 1966.6768 + 124 -229.0308191506 0.161E-03 0.2994041579 0.0123648013 1969.7351 + 125 -229.0308214634 0.159E-03 0.2994162567 0.0123654763 1980.4639 + 126 -229.0308139412 0.158E-03 0.2993705613 0.0123641222 1986.5469 + 127 -229.0308372893 0.159E-03 0.2995458575 0.0123668327 1991.1131 + 128 -229.0308270791 0.158E-03 0.2995053898 0.0123643880 2013.7395 + 136 -229.0307621985 0.150E-03 0.2990855903 0.0123549733 2035.4274 + 137 -229.0307626265 0.149E-03 0.2991163495 0.0123542111 2038.4898 + 138 -229.0307506416 0.148E-03 0.2990949290 0.0123503927 2045.5108 + 141 -229.0307991700 0.148E-03 0.2993927636 0.0123587228 2057.8710 + 144 -229.0307715553 0.148E-03 0.2992267381 0.0123542512 2063.9757 + 146 -229.0307573347 0.147E-03 0.2991345792 0.0123522212 2079.2817 + 148 -229.0307544814 0.145E-03 0.2990605865 0.0123537019 2082.9477 + 149 -229.0307587518 0.145E-03 0.2991065092 0.0123539651 2099.8969 + 151 -229.0307684618 0.144E-03 0.2991789232 0.0123551605 2102.2879 + 152 -229.0307605296 0.143E-03 0.2991393416 0.0123533628 2105.8556 + 153 -229.0307606437 0.142E-03 0.2991271207 0.0123538914 2110.7767 + 154 -229.0307574855 0.142E-03 0.2990888981 0.0123539941 2124.9608 + 156 -229.0307325114 0.138E-03 0.2989147170 0.0123506884 2126.7868 + 157 -229.0307199451 0.138E-03 0.2988260291 0.0123486783 2140.9127 + 158 -229.0307268724 0.137E-03 0.2988530464 0.0123503041 2147.5787 + 160 -229.0307059042 0.136E-03 0.2987279734 0.0123466150 2150.6683 + 162 -229.0307149849 0.135E-03 0.2987798815 0.0123482661 2163.0497 + 163 -229.0306775789 0.135E-03 0.2985603848 0.0123417307 2165.6597 + 167 -229.0306670694 0.133E-03 0.2985234955 0.0123389758 2168.6877 + 168 -229.0306695693 0.132E-03 0.2985270376 0.0123395440 2174.0900 + 169 -229.0306815010 0.132E-03 0.2986011499 0.0123415443 2181.4234 + 170 -229.0306755013 0.131E-03 0.2985636264 0.0123405713 2205.4751 + 172 -229.0306804813 0.130E-03 0.2985895321 0.0123417797 2214.8995 + 177 -229.0306849259 0.127E-03 0.2986101569 0.0123424108 2230.3767 + 181 -229.0306882648 0.121E-03 0.2986294653 0.0123430428 2240.6217 + 182 -229.0306795415 0.121E-03 0.2985796400 0.0123414534 2251.5947 + 187 -229.0307056869 0.121E-03 0.2987141552 0.0123470491 2253.3417 + 190 -229.0307095578 0.120E-03 0.2987371572 0.0123474557 2264.3069 + 191 -229.0306969501 0.120E-03 0.2986349220 0.0123461501 2274.6568 + 195 -229.0307088557 0.116E-03 0.2986917710 0.0123481872 2279.1768 + 196 -229.0307238187 0.117E-03 0.2988385139 0.0123494083 2298.3887 + 201 -229.0307202593 0.112E-03 0.2988082928 0.0123491356 2322.8093 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.739159 GB ] [ VIRT MEM : 12.100971 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5154.243680 s ] [ CPU TIME: 357632.330297 s ] <<<<< .. + +* Number of generators 5235877 + +.. >>>>> [ RES MEM : 4.739159 GB ] [ VIRT MEM : 12.100971 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5154.255237 s ] [ CPU TIME: 357632.341768 s ] <<<<< .. + +* Number of selectors 5235877 +* Number of comb teeth 100 +* pt2_n_tasks_max 524 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8848233803765859 + +Summary at N_det = 5242865 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.97171942 +# PT2 -0.05900043 0.00010755 +# rPT2 -0.05828050 0.00010624 +# +# E+PT2 -229.03071984 0.00010755 +# E+rPT2 -229.02999992 0.00010624 +# ============ ============================= + + N_det = 5242865 + N_states = 1 + + * State 1 + < S^2 > = 5.061805547594074E-003 + E = -228.971719416621 + Variance = 0.298684963837065 + PT norm = 0.111142873121117 + PT2 = -5.900042739824979E-002 + rPT2 = -5.828050359254832E-002 + E+PT2 = -229.030719844019 +/- 1.075543161990307E-004 + E+rPT2 = -229.029999920213 +/- 1.062419373561628E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.791384994182 + Vee = 238.547873391351 + Vecp = 0.000000000000000E+000 + T = 229.163562407421 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0587 -229.04262971 + -0.0594 -229.02387067 + -0.0601 -229.03924341 + -0.0619 -229.03972480 + -0.0651 -229.03870445 + -0.0698 -229.04114596 + -0.0794 -229.04284201 + =========== =================== + +* Number of unique beta determinants 970338 +* Number of unique alpha determinants 982000 + +.. >>>>> [ RES MEM : 5.083576 GB ] [ VIRT MEM : 13.803692 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5368.224040 s ] [ CPU TIME: 372379.826468 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 10481654 +* Number of threads for diagonalization 72 +* Memory(Gb) 16.27512321248651 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9717113152 0.005067 0.104E-03 + 2 -228.9722005919 0.005299 0.185E-05 + 3 -228.9722031367 0.005297 0.499E-06 + 4 -228.9722034788 0.005294 0.834E-08 + 5 -228.9722034997 0.005289 0.303E-08 + 6 -228.9722035042 0.005285 0.578E-09 + 7 -228.9722035055 0.005283 0.858E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 14.643520 GB ] [ VIRT MEM : 26.636978 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6812.213746 s ] [ CPU TIME: 471569.826512 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 5.897133 GB ] [ VIRT MEM : 14.609131 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6812.998603 s ] [ CPU TIME: 471576.977359 s ] <<<<< .. + +* Energy of state 1 -228.9722035054773 +* S^2 of state 1 0.5282599554492923E-02 +* Saved determinants 10481654 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 5.015278 GB ] [ VIRT MEM : 12.653137 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6900.127904 s ] [ CPU TIME: 472474.440760 s ] <<<<< .. + +* Number of generators 9600597 + +.. >>>>> [ RES MEM : 5.015278 GB ] [ VIRT MEM : 12.653137 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6900.149834 s ] [ CPU TIME: 472476.015350 s ] <<<<< .. + +* Number of selectors 9600597 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -228.9722035054773 + +.. >>>>> [ RES MEM : 5.786842 GB ] [ VIRT MEM : 13.446445 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6905.494014 s ] [ CPU TIME: 472754.477059 s ] <<<<< .. + +* Number of generators 9600597 + +.. >>>>> [ RES MEM : 5.786842 GB ] [ VIRT MEM : 13.446445 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6905.515198 s ] [ CPU TIME: 472754.498133 s ] <<<<< .. + +* Number of selectors 9600597 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 10210413 +* Number of fragmented tasks 10084 +* Number of threads for PT2 72 +* Memory (Gb) 2.839949697963894 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0299652896 0.173E-02 0.2961303824 0.0119574808 525.5678 + 4 -229.0306530791 0.137E-02 0.2992711241 0.0121093765 621.0649 + 5 -229.0300475702 0.121E-02 0.2960842565 0.0119975873 702.2538 + 6 -229.0306161185 0.103E-02 0.2983741383 0.0121315564 799.8416 + 7 -229.0308139801 0.884E-03 0.2987800700 0.0121927861 917.9768 + 8 -229.0308459991 0.757E-03 0.2984673127 0.0122117946 965.7469 + 9 -229.0307902215 0.632E-03 0.2976069662 0.0122270491 1097.9203 + 12 -229.0307623422 0.523E-03 0.2982387654 0.0121976679 1167.2547 + 13 -229.0307009294 0.504E-03 0.2976393693 0.0122017436 1207.8717 + 14 -229.0305451550 0.492E-03 0.2964725226 0.0121800615 1315.1096 + 15 -229.0307226366 0.492E-03 0.2974572091 0.0122142773 1355.8919 + 17 -229.0304465131 0.493E-03 0.2951634720 0.0121895182 1369.4686 + 18 -229.0304162013 0.466E-03 0.2951788359 0.0121775537 1445.0566 + 19 -229.0304681885 0.443E-03 0.2957137301 0.0121753289 1533.0646 + 20 -229.0304977539 0.432E-03 0.2957144506 0.0121884475 1596.4316 + 21 -229.0305453966 0.414E-03 0.2960987592 0.0121931493 1607.2456 + 23 -229.0305972877 0.396E-03 0.2963663803 0.0122032563 1645.8676 + 24 -229.0307042561 0.394E-03 0.2970325738 0.0122214358 1695.6617 + 25 -229.0306018322 0.392E-03 0.2964838909 0.0122010833 1744.6821 + 27 -229.0305210258 0.371E-03 0.2960174800 0.0121869441 1815.7568 + 28 -229.0304311693 0.346E-03 0.2952813746 0.0121782500 1857.4249 + 29 -229.0305280662 0.348E-03 0.2957165384 0.0122013736 1987.3466 + 30 -229.0304640225 0.342E-03 0.2950742384 0.0121996195 2018.6856 + 32 -229.0304103791 0.321E-03 0.2947858426 0.0121880786 2065.8332 + 33 -229.0303820564 0.312E-03 0.2945113435 0.0121865522 2101.2473 + 34 -229.0304227960 0.302E-03 0.2947897411 0.0121916040 2158.9277 + 35 -229.0303730948 0.298E-03 0.2945001164 0.0121811149 2194.1106 + 36 -229.0304633383 0.303E-03 0.2950018929 0.0121978599 2196.9996 + 37 -229.0304624981 0.295E-03 0.2950111356 0.0121962210 2260.1056 + 40 -229.0305371262 0.276E-03 0.2955938544 0.0122063782 2274.1193 + 41 -229.0305238711 0.269E-03 0.2955949051 0.0122007709 2347.0309 + 42 -229.0305732595 0.267E-03 0.2961069024 0.0122029160 2394.5057 + 43 -229.0306569395 0.267E-03 0.2965113883 0.0122189738 2462.3773 + 44 -229.0306155257 0.264E-03 0.2962258243 0.0122151937 2479.7600 + 45 -229.0306415808 0.259E-03 0.2963632492 0.0122204809 2485.7769 + 46 -229.0305868797 0.259E-03 0.2960046756 0.0122129012 2489.5726 + 47 -229.0306350541 0.250E-03 0.2960135509 0.0122285854 2563.6216 + 48 -229.0306993608 0.253E-03 0.2963158177 0.0122427953 2605.7149 + 50 -229.0308420074 0.262E-03 0.2972346719 0.0122642290 2620.6548 + 51 -229.0307595266 0.270E-03 0.2967192992 0.0122511189 2633.4622 + 53 -229.0307384884 0.276E-03 0.2966897989 0.0122433352 2677.4966 + 54 -229.0307749718 0.260E-03 0.2968297455 0.0122521335 2693.8406 + 55 -229.0307226052 0.260E-03 0.2965663867 0.0122419501 2716.2576 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3073.6117 + 84 -229.0308165701 0.210E-03 0.2972634809 0.0122547395 3088.2046 + 85 -229.0308081322 0.208E-03 0.2972251555 0.0122526269 3093.2070 + 86 -229.0308297775 0.206E-03 0.2973238152 0.0122570435 3123.5736 + 87 -229.0308323054 0.204E-03 0.2973151957 0.0122587357 3145.1498 + 89 -229.0308301026 0.200E-03 0.2972795228 0.0122595859 3153.4026 + 90 -229.0308336091 0.197E-03 0.2973382119 0.0122585789 3191.1736 + 92 -229.0308200343 0.197E-03 0.2972525348 0.0122563146 3193.7227 + 93 -229.0307899100 0.200E-03 0.2970584744 0.0122516132 3226.3136 + 96 -229.0307945094 0.194E-03 0.2970626979 0.0122532899 3262.1997 + 100 -229.0308062299 0.186E-03 0.2970802719 0.0122564224 3265.6928 + 102 -229.0308439173 0.190E-03 0.2973343581 0.0122612929 3283.3706 + 103 -229.0308346560 0.188E-03 0.2972800612 0.0122596159 3301.3328 + 104 -229.0308060265 0.188E-03 0.2971088605 0.0122548420 3337.8928 + 111 -229.0308541398 0.180E-03 0.2973908769 0.0122642553 3345.3416 + 113 -229.0308810318 0.178E-03 0.2975311939 0.0122696334 3365.0606 + 114 -229.0308732677 0.177E-03 0.2974473013 0.0122692127 3382.0936 + 118 -229.0308320436 0.173E-03 0.2972703703 0.0122592411 3409.4726 + 120 -229.0308170443 0.170E-03 0.2971325973 0.0122576689 3423.8517 + 123 -229.0307713002 0.170E-03 0.2968291732 0.0122511111 3430.1267 + 124 -229.0307630407 0.169E-03 0.2968056820 0.0122487188 3452.3056 + 125 -229.0307400942 0.169E-03 0.2966811168 0.0122442768 3468.1026 + 126 -229.0307640421 0.170E-03 0.2968581756 0.0122473269 3486.0576 + 127 -229.0307520374 0.169E-03 0.2967615697 0.0122461301 3492.5667 + 128 -229.0307698101 0.168E-03 0.2968447330 0.0122499631 3505.6926 + 131 -229.0307762859 0.166E-03 0.2969371720 0.0122494879 3510.7646 + 134 -229.0307775700 0.158E-03 0.2969883466 0.0122487107 3528.6086 + 135 -229.0307818698 0.157E-03 0.2970735510 0.0122473408 3543.8083 + 136 -229.0307666643 0.156E-03 0.2969846236 0.0122448173 3552.6676 + 137 -229.0307406910 0.157E-03 0.2968285250 0.0122403372 3558.8386 + 138 -229.0307374752 0.156E-03 0.2967963903 0.0122400699 3566.3066 + 141 -229.0307736470 0.155E-03 0.2969996078 0.0122462822 3582.2486 + 142 -229.0307866620 0.155E-03 0.2970651094 0.0122486579 3600.9867 + 143 -229.0307813034 0.154E-03 0.2970211937 0.0122480791 3607.3876 + 144 -229.0308015723 0.154E-03 0.2971103657 0.0122528070 3610.2800 + 146 -229.0307997932 0.152E-03 0.2970711443 0.0122530532 3615.0792 + 147 -229.0307929800 0.151E-03 0.2970349188 0.0122518758 3620.0356 + 148 -229.0307972785 0.146E-03 0.2969867599 0.0122550201 3641.5442 + 149 -229.0307792807 0.146E-03 0.2969033299 0.0122511018 3651.2676 + 152 -229.0307938160 0.143E-03 0.2969524835 0.0122542545 3659.6446 + 153 -229.0308232774 0.146E-03 0.2971121964 0.0122598532 3685.7266 + 155 -229.0308165810 0.144E-03 0.2970741466 0.0122583697 3705.8426 + 156 -229.0308304345 0.138E-03 0.2971566363 0.0122605464 3708.0636 + 157 -229.0308389808 0.137E-03 0.2972038844 0.0122619249 3724.3538 + 158 -229.0308476323 0.137E-03 0.2972385481 0.0122640236 3728.0198 + 159 -229.0308366622 0.136E-03 0.2972037651 0.0122612943 3762.4666 + 167 -229.0308849961 0.134E-03 0.2974457087 0.0122710776 3780.3406 + 168 -229.0308909597 0.133E-03 0.2974642289 0.0122727019 3789.4266 + 169 -229.0308905057 0.133E-03 0.2974400525 0.0122732778 3797.7199 + 170 -229.0308902023 0.132E-03 0.2974684365 0.0122721905 3828.5788 + 172 -229.0309086149 0.130E-03 0.2975205034 0.0122770873 3846.0323 + 173 -229.0309088253 0.129E-03 0.2975044958 0.0122776696 3851.2056 + 176 -229.0308847181 0.128E-03 0.2973627357 0.0122734314 3875.3350 + 177 -229.0308888195 0.127E-03 0.2973906358 0.0122741601 3882.5926 + 181 -229.0308901386 0.126E-03 0.2974199694 0.0122733889 3899.3116 + 182 -229.0308810038 0.125E-03 0.2973486068 0.0122724029 3916.4286 + 186 -229.0308811023 0.124E-03 0.2972772167 0.0122746096 3921.6767 + 188 -229.0308819433 0.123E-03 0.2972881279 0.0122742261 3938.8196 + 190 -229.0308703843 0.123E-03 0.2972112978 0.0122723141 3953.3449 + 193 -229.0308513078 0.122E-03 0.2970940280 0.0122689025 3974.6777 + 194 -229.0308194721 0.122E-03 0.2968604019 0.0122653873 3984.0995 + 197 -229.0308194316 0.121E-03 0.2968469307 0.0122658489 3994.4016 + 201 -229.0308232209 0.119E-03 0.2968578122 0.0122668372 4006.7816 + 203 -229.0308340360 0.118E-03 0.2968696165 0.0122708583 4033.4645 + 207 -229.0308099512 0.118E-03 0.2967555318 0.0122657316 4049.1056 + 214 -229.0308064379 0.116E-03 0.2967226986 0.0122656894 4066.0757 + 215 -229.0308047964 0.115E-03 0.2967135797 0.0122652887 4096.1258 + 218 -229.0307814905 0.111E-03 0.2965506919 0.0122617748 4097.7472 + 224 -229.0307556888 0.108E-03 0.2964428855 0.0122559160 4107.9500 + 226 -229.0307605785 0.108E-03 0.2964866711 0.0122562964 4116.7110 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 7.120766 GB ] [ VIRT MEM : 14.984615 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11052.300959 s ] [ CPU TIME: 767230.288639 s ] <<<<< .. + +* Number of generators 9600597 + +.. >>>>> [ RES MEM : 7.120766 GB ] [ VIRT MEM : 14.984615 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11052.321198 s ] [ CPU TIME: 767230.308775 s ] <<<<< .. + +* Number of selectors 9600597 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +Summary at N_det = 10481654 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.97220351 +# PT2 -0.05855921 0.00010764 +# rPT2 -0.05785017 0.00010634 +# +# E+PT2 -229.03076272 0.00010764 +# E+rPT2 -229.03005368 0.00010634 +# ============ ============================= + + N_det = 10481654 + N_states = 1 + + * State 1 + < S^2 > = 5.282599554492923E-003 + E = -228.972203505477 + Variance = 0.296502055598110 + PT norm = 0.110709338056575 + PT2 = -5.855921443329637E-002 + rPT2 = -5.785017049039137E-002 + E+PT2 = -229.030762719911 +/- 1.076404409376584E-004 + E+rPT2 = -229.030053675968 +/- 1.063371139822497E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.791483101976 + Vee = 238.546310250911 + Vecp = 0.000000000000000E+000 + T = 229.164739566798 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0583 -229.03728012 + -0.0587 -229.03970383 + -0.0594 -229.02851039 + -0.0601 -229.03824587 + -0.0619 -229.03920409 + -0.0651 -229.03856667 + -0.0698 -229.04090594 + =========== =================== + +Wall time: 3:04:26 + diff --git a/furan/6-31g/furan.localized.nofci.out b/furan/6-31g/furan.localized.nofci.out new file mode 100644 index 0000000..89b3f12 --- /dev/null +++ b/furan/6-31g/furan.localized.nofci.out @@ -0,0 +1,4998 @@ +Date: 28/12/2020 12:52:42 +=============== +Quantum Package +=============== + +Git Commit: Fix space in size for EZFIO.cfg +Git Date : Fri Oct 16 14:24:01 2020 +0200 +Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b +EZFIO Dir : furan.localized + + +Task server running : tcp://172.28.1.79:41279 +* mo_num 53 +.. >>>>> [ IO READ: mo_class ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019249 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.085026 s ] [ CPU TIME: 7.423319 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_two_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019249 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.120281 s ] [ CPU TIME: 9.863228 s ] <<<<< .. + +* N_int 1 + MO map initialized: 1024596 +.. >>>>> [ IO READ: io_ao_two_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019451 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.190653 s ] [ CPU TIME: 14.792615 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019451 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.217321 s ] [ CPU TIME: 16.655530 s ] <<<<< .. + + AO map initialized : 1024596 +.. >>>>> [ IO READ: ao_power ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019547 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.270895 s ] [ CPU TIME: 20.347651 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_prim_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019581 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.274357 s ] [ CPU TIME: 20.585912 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_expo ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019600 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.279690 s ] [ CPU TIME: 20.945061 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_coef ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019627 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.283260 s ] [ CPU TIME: 21.182056 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_nucl ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019779 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.287593 s ] [ CPU TIME: 21.482718 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_integrals_threshold ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019779 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.289032 s ] [ CPU TIME: 21.583893 s ] <<<<< .. + + Providing the AO integrals +.. >>>>> [ IO READ: nucl_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.021252 GB ] [ VIRT MEM : 5.058784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.529107 s ] [ CPU TIME: 35.964923 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_label ] <<<<< .. + +.. >>>>> [ RES MEM : 0.021393 GB ] [ VIRT MEM : 5.058784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.533046 s ] [ CPU TIME: 36.223258 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_charge ] <<<<< .. + +.. >>>>> [ RES MEM : 0.021420 GB ] [ VIRT MEM : 5.058784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.538941 s ] [ CPU TIME: 36.612027 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.021431 GB ] [ VIRT MEM : 5.058784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.542159 s ] [ CPU TIME: 36.825079 s ] <<<<< .. + + +Nuclear Coordinates (Angstroms) +=============================== + +================ ============ ============ ============ ============ + Atom Charge X Y Z +================ ============ ============ ============ ============ +C 6.000000 0.000000 1.092041 -0.317778 +C 6.000000 0.000000 -1.092041 -0.317778 +C 6.000000 0.000000 0.716234 0.986050 +C 6.000000 0.000000 -0.716234 0.986050 +O 8.000000 0.000000 0.000000 -1.132150 +H 1.000000 0.000000 2.044409 -0.813693 +H 1.000000 0.000000 -2.044409 -0.813693 +H 1.000000 0.000000 1.371462 1.837134 +H 1.000000 0.000000 -1.371462 1.837134 +================ ============ ============ ============ ============ + + Sorting the map + AO integrals provided: + Size of AO map : 7.19726371765137 MB + Number of AO integrals : 580388 + cpu time : 56.1421050000000 s + wall time : 0.912712097167969 s ( x 61.5112971266645 ) + + AO -> MO integrals transformation + --------------------------------- + + Read mo_coef +.. >>>>> [ IO READ: mo_integrals_threshold ] <<<<< .. + +.. >>>>> [ RES MEM : 0.030430 GB ] [ VIRT MEM : 5.134060 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1.223115 s ] [ CPU TIME: 79.060580 s ] <<<<< .. + + Buffers : 4.587036 MB / core + Molecular integrals provided: + Size of MO map 18.4139328002930 MB + Number of MO integrals: 947113 + cpu time : 84.9447100000000 s + wall time : 1.53543400764465 s ( x 55.3229312214497 ) +.. >>>>> [ IO READ: n_states ] <<<<< .. + +.. >>>>> [ RES MEM : 0.428020 GB ] [ VIRT MEM : 5.709026 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.740103 s ] [ CPU TIME: 162.877795 s ] <<<<< .. + + * mo_label Natural +.. >>>>> [ IO READ: read_wf ] <<<<< .. + +.. >>>>> [ RES MEM : 0.428020 GB ] [ VIRT MEM : 5.709026 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.745851 s ] [ CPU TIME: 163.274212 s ] <<<<< .. + +* Number of determinants 1 +* Dimension of the psi arrays 41535888 +.. >>>>> [ IO READ: elec_beta_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.737408 GB ] [ VIRT MEM : 6.018600 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.008482 s ] [ CPU TIME: 175.966793 s ] <<<<< .. + +.. >>>>> [ IO READ: elec_alpha_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.737408 GB ] [ VIRT MEM : 6.018600 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.009150 s ] [ CPU TIME: 175.967258 s ] <<<<< .. + +.. >>>>> [ IO READ: do_pt2 ] <<<<< .. + +.. >>>>> [ RES MEM : 1.356510 GB ] [ VIRT MEM : 6.637745 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.923841 s ] [ CPU TIME: 176.856506 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 1.356621 GB ] [ VIRT MEM : 6.637745 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.018282 s ] [ CPU TIME: 178.454548 s ] <<<<< .. + +.. >>>>> [ IO READ: selection_factor ] <<<<< .. + +.. >>>>> [ RES MEM : 1.356621 GB ] [ VIRT MEM : 6.637745 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.019087 s ] [ CPU TIME: 178.510817 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_max ] <<<<< .. + +.. >>>>> [ RES MEM : 1.357014 GB ] [ VIRT MEM : 7.256889 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.020375 s ] [ CPU TIME: 178.595350 s ] <<<<< .. + +.. >>>>> [ IO READ: s2_eig ] <<<<< .. + +.. >>>>> [ RES MEM : 1.358757 GB ] [ VIRT MEM : 7.256889 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.021763 s ] [ CPU TIME: 178.691944 s ] <<<<< .. + +.. >>>>> [ IO READ: variance_max ] <<<<< .. + +.. >>>>> [ RES MEM : 1.358757 GB ] [ VIRT MEM : 7.256889 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.022523 s ] [ CPU TIME: 178.744948 s ] <<<<< .. + +.. >>>>> [ IO READ: distributed_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 1.358757 GB ] [ VIRT MEM : 7.256889 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.025015 s ] [ CPU TIME: 178.917026 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_max_full ] <<<<< .. + +.. >>>>> [ RES MEM : 1.358757 GB ] [ VIRT MEM : 7.256889 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.025765 s ] [ CPU TIME: 178.969422 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_integrals_e_n ] <<<<< .. + +.. >>>>> [ RES MEM : 1.434662 GB ] [ VIRT MEM : 9.131889 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.127184 s ] [ CPU TIME: 186.003611 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_integrals_e_n ] <<<<< .. + +.. >>>>> [ RES MEM : 1.434662 GB ] [ VIRT MEM : 9.131889 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.199083 s ] [ CPU TIME: 190.953884 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_integrals_kinetic ] <<<<< .. + +.. >>>>> [ RES MEM : 1.436687 GB ] [ VIRT MEM : 9.198109 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.343571 s ] [ CPU TIME: 200.226950 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_integrals_kinetic ] <<<<< .. + +.. >>>>> [ RES MEM : 1.436687 GB ] [ VIRT MEM : 9.198109 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.345082 s ] [ CPU TIME: 200.333984 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_one_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 1.436920 GB ] [ VIRT MEM : 9.198109 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.366724 s ] [ CPU TIME: 201.846502 s ] <<<<< .. + + Providing the one-electron integrals +.. >>>>> [ IO READ: do_pseudo ] <<<<< .. + +.. >>>>> [ RES MEM : 1.437084 GB ] [ VIRT MEM : 9.198109 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.416094 s ] [ CPU TIME: 205.342547 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_relative_error ] <<<<< .. + +.. >>>>> [ RES MEM : 1.437084 GB ] [ VIRT MEM : 9.198109 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.436647 s ] [ CPU TIME: 206.797588 s ] <<<<< .. + +.. >>>>> [ IO READ: correlation_energy_ratio_max ] <<<<< .. + +.. >>>>> [ RES MEM : 1.437084 GB ] [ VIRT MEM : 9.198109 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.437562 s ] [ CPU TIME: 206.862404 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 1.437084 GB ] [ VIRT MEM : 9.198109 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.438885 s ] [ CPU TIME: 206.955951 s ] <<<<< .. + + Read n_states_diag +.. >>>>> [ IO READ: io_nuclear_repulsion ] <<<<< .. + +.. >>>>> [ RES MEM : 1.437084 GB ] [ VIRT MEM : 9.198109 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.440104 s ] [ CPU TIME: 207.042092 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 1.437084 GB ] [ VIRT MEM : 9.198109 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.440460 s ] [ CPU TIME: 207.067637 s ] <<<<< .. + +* Nuclear repulsion energy 161.1082297787890 +.. >>>>> [ IO READ: weight_one_e_dm ] <<<<< .. + +.. >>>>> [ RES MEM : 1.437084 GB ] [ VIRT MEM : 9.198109 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.441635 s ] [ CPU TIME: 207.150246 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_max ] <<<<< .. + +.. >>>>> [ RES MEM : 3.139153 GB ] [ VIRT MEM : 10.900764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5.903338 s ] [ CPU TIME: 222.017014 s ] <<<<< .. + +.. >>>>> [ IO READ: threshold_generators ] <<<<< .. + +.. >>>>> [ RES MEM : 3.139153 GB ] [ VIRT MEM : 10.900764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5.904060 s ] [ CPU TIME: 222.017487 s ] <<<<< .. + +* Target maximum memory (GB) 170 +.. >>>>> [ IO READ: threshold_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 3.139153 GB ] [ VIRT MEM : 10.900764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5.906057 s ] [ CPU TIME: 222.018157 s ] <<<<< .. + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 3.139397 GB ] [ VIRT MEM : 10.900764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5.931370 s ] [ CPU TIME: 222.064800 s ] <<<<< .. + +* Energy of state 1 -228.5222359495301 +* S^2 of state 1 0.000000000000000 +* Saved determinants 1 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 1 +* Number of unique alpha determinants 1 +.. >>>>> [ IO READ: weight_selection ] <<<<< .. + +.. >>>>> [ RES MEM : 3.139500 GB ] [ VIRT MEM : 12.139309 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6.492594 s ] [ CPU TIME: 238.431713 s ] <<<<< .. + + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +.. >>>>> [ IO READ: pseudo_sym ] <<<<< .. + +.. >>>>> [ RES MEM : 3.139500 GB ] [ VIRT MEM : 12.139309 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6.493496 s ] [ CPU TIME: 238.495647 s ] <<<<< .. + +.. >>>>> [ IO READ: h0_type ] <<<<< .. + +.. >>>>> [ RES MEM : 3.139500 GB ] [ VIRT MEM : 13.068027 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6.495054 s ] [ CPU TIME: 238.605689 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 3.139500 GB ] [ VIRT MEM : 13.068027 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6.495476 s ] [ CPU TIME: 238.635840 s ] <<<<< .. + +* Number of generators 1 + +.. >>>>> [ RES MEM : 3.139500 GB ] [ VIRT MEM : 13.068027 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6.495854 s ] [ CPU TIME: 238.662590 s ] <<<<< .. + +* Number of selectors 1 +* Number of comb teeth 1 +* Number of core MOs 5 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.5222359495301 +* Estimated memory/thread (Gb) 0.1043081283569336E-06 +* Number of virtual MOs 0 +* Number of active MOs 48 + Active MOs: + 6 7 8 9 10 11 + 12 13 14 15 16 17 + 18 19 20 21 22 23 + 24 25 26 27 28 29 + 30 31 32 33 34 35 + 36 37 38 39 40 41 + 42 43 44 45 46 47 + 48 49 50 51 52 53 +* Number of inactive MOs 0 +.. >>>>> [ IO READ: pert_2rdm ] <<<<< .. + +.. >>>>> [ RES MEM : 3.140793 GB ] [ VIRT MEM : 15.235138 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.999891 s ] [ CPU TIME: 254.196749 s ] <<<<< .. + +.. >>>>> [ IO READ: pruning ] <<<<< .. + +.. >>>>> [ RES MEM : 3.140144 GB ] [ VIRT MEM : 15.235138 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.173455 s ] [ CPU TIME: 266.217007 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 3.140144 GB ] [ VIRT MEM : 15.235138 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.558692 s ] [ CPU TIME: 294.471183 s ] <<<<< .. + +* Number of generators 1 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Saved determinants 5 +* Number of unique beta determinants 5 +* Number of unique alpha determinants 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 3.140171 GB ] [ VIRT MEM : 15.235142 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.610323 s ] [ CPU TIME: 296.796491 s ] <<<<< .. + +* Number of selectors 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio -0.3823022732469839E-02 + +Summary at N_det = 5 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.52223595 +# PT2 -0.61620117 0.00000000 +# rPT2 -0.46058592 0.00000000 +# +# E+PT2 -229.13843712 0.00000000 +# E+rPT2 -228.98282187 0.00000000 +# ============ ============================= + + N_det = 5 + N_states = 1 + + * State 1 + < S^2 > = 0.000000000000000E+000 + E = -228.522235949530 + Variance = 1.36122476191512 + PT norm = 0.581260408899340 + PT2 = -0.616201166690144 + rPT2 = -0.460585920488828 + E+PT2 = -229.138437116220 +/- 0.000000000000000E+000 + E+rPT2 = -228.982821870019 +/- 0.000000000000000E+000 + + ----- +.. >>>>> [ IO READ: io_mo_integrals_pseudo ] <<<<< .. + +.. >>>>> [ RES MEM : 3.140171 GB ] [ VIRT MEM : 15.235142 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.612084 s ] [ CPU TIME: 296.922900 s ] <<<<< .. + + Energy components + ================= + + Vnn : Nucleus-Nucleus potential energy + Ven : Electron-Nucleus potential energy + Vee : Electron-Electron potential energy + Vecp : Potential energy of the pseudo-potentials + T : Electronic kinetic energy + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.616184774650 + Vee = 239.228806629143 + Vecp = 0.000000000000000E+000 + T = 228.756912417188 + + +.. >>>>> [ IO READ: energy_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 3.140999 GB ] [ VIRT MEM : 15.235142 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.634056 s ] [ CPU TIME: 298.466338 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 3.140999 GB ] [ VIRT MEM : 15.235142 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.637411 s ] [ CPU TIME: 298.694540 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 3.140999 GB ] [ VIRT MEM : 15.235142 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10.641118 s ] [ CPU TIME: 298.946913 s ] <<<<< .. + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 3.141449 GB ] [ VIRT MEM : 15.235142 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12.074590 s ] [ CPU TIME: 341.904842 s ] <<<<< .. + +* Energy of state 1 -228.5883185863498 +* S^2 of state 1 0.000000000000000 +* Saved determinants 5 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 5 +* Number of unique alpha determinants 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 3.141624 GB ] [ VIRT MEM : 15.235142 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12.713537 s ] [ CPU TIME: 364.931021 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 3.141624 GB ] [ VIRT MEM : 15.235142 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12.713926 s ] [ CPU TIME: 364.958771 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.5883185863498 + +.. >>>>> [ RES MEM : 4.224735 GB ] [ VIRT MEM : 16.318649 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 14.329437 s ] [ CPU TIME: 392.984797 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 4.224735 GB ] [ VIRT MEM : 16.318649 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 14.329726 s ] [ CPU TIME: 392.985034 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 5 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1576246134936809E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 4 -229.0880043972 0.00 1.2295432061 0.2288260207 0.1585 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.224850 GB ] [ VIRT MEM : 16.318649 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 17.912123 s ] [ CPU TIME: 431.928177 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 4.224850 GB ] [ VIRT MEM : 16.318649 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 17.912415 s ] [ CPU TIME: 431.928418 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1365886584758019 + +Summary at N_det = 5 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.58831859 +# PT2 -0.49968581 0.00000000 +# rPT2 -0.40663674 0.00000000 +# +# E+PT2 -229.08800440 0.00000000 +# E+rPT2 -228.99495533 0.00000000 +# ============ ============================= + + N_det = 5 + N_states = 1 + + * State 1 + < S^2 > = 0.000000000000000E+000 + E = -228.588318586350 + Variance = 1.22954320607964 + PT norm = 0.478357628474660 + PT2 = -0.499685810820149 + rPT2 = -0.406636743033331 + E+PT2 = -229.088004397170 +/- 0.000000000000000E+000 + E+rPT2 = -228.994955329383 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.712981772397 + Vee = 239.148745448833 + Vecp = 0.000000000000000E+000 + T = 228.867687958425 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4606 -229.08641011 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 4.224857 GB ] [ VIRT MEM : 16.318649 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 20.362193 s ] [ CPU TIME: 500.815193 s ] <<<<< .. + +* Energy of state 1 -228.6402957396053 +* S^2 of state 1 0.000000000000000 +* Saved determinants 10 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 10 +* Number of unique alpha determinants 10 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.225037 GB ] [ VIRT MEM : 16.318687 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 21.037725 s ] [ CPU TIME: 526.368743 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 4.225037 GB ] [ VIRT MEM : 16.318687 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 21.038125 s ] [ CPU TIME: 526.397828 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.6402957396053 + +.. >>>>> [ RES MEM : 4.225037 GB ] [ VIRT MEM : 16.318687 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 22.009623 s ] [ CPU TIME: 554.160518 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 4.225037 GB ] [ VIRT MEM : 16.318687 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 22.009924 s ] [ CPU TIME: 554.160768 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 10 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1608791574835777E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 9 -229.0690672299 0.00 1.0947929944 0.1907067188 0.1544 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.225067 GB ] [ VIRT MEM : 16.318687 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 25.905050 s ] [ CPU TIME: 593.598732 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 4.225067 GB ] [ VIRT MEM : 16.318687 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 25.905345 s ] [ CPU TIME: 593.598975 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.2441324357483733 + +Summary at N_det = 10 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.64029574 +# PT2 -0.42877149 0.00000000 +# rPT2 -0.36009832 0.00000000 +# +# E+PT2 -229.06906723 0.00000000 +# E+rPT2 -229.00039406 0.00000000 +# ============ ============================= + + N_det = 10 + N_states = 1 + + * State 1 + < S^2 > = 0.000000000000000E+000 + E = -228.640295739605 + Variance = 1.09479299441169 + PT norm = 0.436699803964594 + PT2 = -0.428771490324086 + rPT2 = -0.360098321073075 + E+PT2 = -229.069067229929 +/- 0.000000000000000E+000 + E+rPT2 = -229.000394060678 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.738426773072 + Vee = 239.062615239475 + Vecp = 0.000000000000000E+000 + T = 228.927286015202 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4066 -229.04247709 + -0.4606 -229.06480333 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 4.225067 GB ] [ VIRT MEM : 16.318687 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 28.109689 s ] [ CPU TIME: 638.514664 s ] <<<<< .. + +* Energy of state 1 -228.6863633626103 +* S^2 of state 1 0.1545801916525623E-01 +* Saved determinants 20 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 15 +* Number of unique alpha determinants 16 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.225174 GB ] [ VIRT MEM : 16.318733 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 28.797368 s ] [ CPU TIME: 654.615271 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 4.225174 GB ] [ VIRT MEM : 16.318733 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 28.797751 s ] [ CPU TIME: 654.643354 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.6863633626103 + +.. >>>>> [ RES MEM : 4.225174 GB ] [ VIRT MEM : 16.318733 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 29.894115 s ] [ CPU TIME: 682.532673 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 4.225174 GB ] [ VIRT MEM : 16.318733 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 29.894404 s ] [ CPU TIME: 682.532911 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 20 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1673882454633713E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 19 -229.0470358814 0.00 0.9632683441 0.1544142577 0.1260 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.225208 GB ] [ VIRT MEM : 16.318733 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 33.207249 s ] [ CPU TIME: 719.855290 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 4.225208 GB ] [ VIRT MEM : 16.318733 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 33.207543 s ] [ CPU TIME: 719.855530 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.3419808300546752 + +Summary at N_det = 20 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.68636336 +# PT2 -0.36067252 0.00000000 +# rPT2 -0.31242902 0.00000000 +# +# E+PT2 -229.04703588 0.00000000 +# E+rPT2 -228.99879239 0.00000000 +# ============ ============================= + + N_det = 20 + N_states = 1 + + * State 1 + < S^2 > = 1.545801916525623E-002 + E = -228.686363362610 + Variance = 0.963268344141991 + PT norm = 0.392955796095425 + PT2 = -0.360672518762130 + rPT2 = -0.312429023083452 + E+PT2 = -229.047035881372 +/- 0.000000000000000E+000 + E+rPT2 = -228.998792385694 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.752971644354 + Vee = 238.987902721316 + Vecp = 0.000000000000000E+000 + T = 228.970475781638 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3601 -228.98829486 + -0.4066 -229.01259035 + -0.4606 -229.03670235 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 4.225349 GB ] [ VIRT MEM : 16.318733 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 35.443624 s ] [ CPU TIME: 777.456865 s ] <<<<< .. + +* Energy of state 1 -228.7140521179563 +* S^2 of state 1 0.1954795543908402E-01 +* Saved determinants 40 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 21 +* Number of unique alpha determinants 20 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.225475 GB ] [ VIRT MEM : 16.318790 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 36.154550 s ] [ CPU TIME: 799.919606 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 4.225475 GB ] [ VIRT MEM : 16.318790 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 36.154940 s ] [ CPU TIME: 799.947645 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.7140521179563 + +.. >>>>> [ RES MEM : 4.225475 GB ] [ VIRT MEM : 16.318790 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 37.264566 s ] [ CPU TIME: 834.188010 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 4.225475 GB ] [ VIRT MEM : 16.318790 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 37.264856 s ] [ CPU TIME: 834.188249 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 40 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1804064214229584E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 39 -229.0347099380 0.00 0.8678363427 0.1359606895 0.2719 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.225513 GB ] [ VIRT MEM : 16.318790 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 40.530686 s ] [ CPU TIME: 886.925045 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 4.225513 GB ] [ VIRT MEM : 16.318790 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 40.531014 s ] [ CPU TIME: 886.925320 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.4023831004586446 + +Summary at N_det = 40 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.71405212 +# PT2 -0.32065782 0.00000000 +# rPT2 -0.28227898 0.00000000 +# +# E+PT2 -229.03470994 0.00000000 +# E+rPT2 -228.99633109 0.00000000 +# ============ ============================= + + N_det = 40 + N_states = 1 + + * State 1 + < S^2 > = 1.954795543908402E-002 + E = -228.714052117956 + Variance = 0.867836342716446 + PT norm = 0.368728476701425 + PT2 = -0.320657819997048 + rPT2 = -0.282278975806427 + E+PT2 = -229.034709937953 +/- 0.000000000000000E+000 + E+rPT2 = -228.996331093763 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.747255791864 + Vee = 238.934517349072 + Vecp = 0.000000000000000E+000 + T = 228.990456546046 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3124 -228.97328732 + -0.3601 -228.98242446 + -0.4066 -229.00065532 + -0.4606 -229.02137472 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 4.226414 GB ] [ VIRT MEM : 16.330673 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 42.769002 s ] [ CPU TIME: 944.547362 s ] <<<<< .. + +* Energy of state 1 -228.7444542721082 +* S^2 of state 1 0.1896797263811636E-01 +* Saved determinants 80 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 36 +* Number of unique alpha determinants 36 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.226681 GB ] [ VIRT MEM : 16.330856 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 43.479928 s ] [ CPU TIME: 967.046913 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 4.226681 GB ] [ VIRT MEM : 16.330856 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 43.480315 s ] [ CPU TIME: 967.076066 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.7444542721082 + +.. >>>>> [ RES MEM : 4.226681 GB ] [ VIRT MEM : 16.330856 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 44.595842 s ] [ CPU TIME: 1001.324530 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 4.226681 GB ] [ VIRT MEM : 16.330856 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 44.596145 s ] [ CPU TIME: 1001.324781 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 80 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2064427733421326E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 76 -229.0250655181 0.00 0.7881092556 0.1124312582 0.2875 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.228756 GB ] [ VIRT MEM : 16.330856 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 47.689339 s ] [ CPU TIME: 1052.769243 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 4.228756 GB ] [ VIRT MEM : 16.330856 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 47.689629 s ] [ CPU TIME: 1052.769484 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.4663790631278594 + +Summary at N_det = 80 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.74445427 +# PT2 -0.28061125 0.00000000 +# rPT2 -0.25225041 0.00000000 +# +# E+PT2 -229.02506552 0.00000000 +# E+rPT2 -228.99670469 0.00000000 +# ============ ============================= + + N_det = 80 + N_states = 1 + + * State 1 + < S^2 > = 1.896797263811636E-002 + E = -228.744454272108 + Variance = 0.788109255615853 + PT norm = 0.335307706810081 + PT2 = -0.280611245989267 + rPT2 = -0.252250414494514 + E+PT2 = -229.025065518097 +/- 0.000000000000000E+000 + E+rPT2 = -228.996704686603 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.746671906317 + Vee = 238.883671252785 + Vecp = 0.000000000000000E+000 + T = 229.010316602635 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2823 -228.99984300 + -0.3124 -228.98747297 + -0.3601 -228.98642019 + -0.4066 -228.99776242 + -0.4606 -229.01390337 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 4.231106 GB ] [ VIRT MEM : 16.330925 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 49.616834 s ] [ CPU TIME: 1103.053938 s ] <<<<< .. + +* Energy of state 1 -228.7792808193126 +* S^2 of state 1 0.2372584640136797E-01 +* Saved determinants 160 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 51 +* Number of unique alpha determinants 51 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.231174 GB ] [ VIRT MEM : 16.330925 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 50.471261 s ] [ CPU TIME: 1122.194162 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 4.231174 GB ] [ VIRT MEM : 16.330925 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 50.471663 s ] [ CPU TIME: 1122.222794 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.7792808193126 + +.. >>>>> [ RES MEM : 4.231174 GB ] [ VIRT MEM : 16.330925 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 51.453721 s ] [ CPU TIME: 1152.571843 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 4.231174 GB ] [ VIRT MEM : 16.330925 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 51.454024 s ] [ CPU TIME: 1152.572094 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 160 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2585154771804809E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 154 -229.0183223513 0.00 0.7095368806 0.0912144350 0.4586 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.231808 GB ] [ VIRT MEM : 16.330925 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 54.911669 s ] [ CPU TIME: 1226.085062 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 4.231808 GB ] [ VIRT MEM : 16.330925 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 54.911976 s ] [ CPU TIME: 1226.085317 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.5381897248772369 + +Summary at N_det = 160 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.77928082 +# PT2 -0.23904153 0.00000000 +# rPT2 -0.21906009 0.00000000 +# +# E+PT2 -229.01832235 0.00000000 +# E+rPT2 -228.99834091 0.00000000 +# ============ ============================= + + N_det = 160 + N_states = 1 + + * State 1 + < S^2 > = 2.372584640136797E-002 + E = -228.779280819313 + Variance = 0.709536880601033 + PT norm = 0.302017276040035 + PT2 = -0.239041531938249 + rPT2 = -0.219060089626117 + E+PT2 = -229.018322351251 +/- 0.000000000000000E+000 + E+rPT2 = -228.998340908939 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.762129576447 + Vee = 238.836262590509 + Vecp = 0.000000000000000E+000 + T = 229.038356387836 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2523 -229.00914017 + -0.2823 -229.00518836 + -0.3124 -228.99685811 + -0.3601 -228.99266193 + -0.4066 -228.99877214 + -0.4606 -229.01054134 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 4.238926 GB ] [ VIRT MEM : 16.336540 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 57.210094 s ] [ CPU TIME: 1285.884996 s ] <<<<< .. + +* Energy of state 1 -228.8173881364121 +* S^2 of state 1 0.2999381223708358E-01 +* Saved determinants 320 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 102 +* Number of unique alpha determinants 102 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.239086 GB ] [ VIRT MEM : 16.336540 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 57.935381 s ] [ CPU TIME: 1309.310308 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 4.239086 GB ] [ VIRT MEM : 16.336540 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 57.935767 s ] [ CPU TIME: 1309.338473 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.8173881364121 + +.. >>>>> [ RES MEM : 4.239086 GB ] [ VIRT MEM : 16.336540 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 59.050190 s ] [ CPU TIME: 1343.403369 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 4.239086 GB ] [ VIRT MEM : 16.336540 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 59.050482 s ] [ CPU TIME: 1343.403608 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 320 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.3626608848571777E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 313 -229.0148736391 0.00 0.6170511947 0.0713297570 0.7961 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.239254 GB ] [ VIRT MEM : 16.336540 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 62.612086 s ] [ CPU TIME: 1438.146325 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 4.239254 GB ] [ VIRT MEM : 16.336540 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 62.612379 s ] [ CPU TIME: 1438.146568 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.6141441277882330 + +Summary at N_det = 320 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.81738814 +# PT2 -0.19748550 0.00000000 +# rPT2 -0.18433680 0.00000000 +# +# E+PT2 -229.01487364 0.00000000 +# E+rPT2 -229.00172494 0.00000000 +# ============ ============================= + + N_det = 320 + N_states = 1 + + * State 1 + < S^2 > = 2.999381223708358E-002 + E = -228.817388136412 + Variance = 0.617051194746653 + PT norm = 0.267076313043874 + PT2 = -0.197485502731269 + rPT2 = -0.184336803344553 + E+PT2 = -229.014873639143 +/- 0.000000000000000E+000 + E+rPT2 = -229.001724939757 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.794094867990 + Vee = 238.794347303284 + Vecp = 0.000000000000000E+000 + T = 229.074129649505 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2191 -229.01968987 + -0.2523 -229.01511848 + -0.2823 -229.01119090 + -0.3124 -229.00480832 + -0.3601 -228.99974346 + -0.4066 -229.00228817 + -0.4606 -229.01028790 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 4.251343 GB ] [ VIRT MEM : 16.470764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 64.691773 s ] [ CPU TIME: 1497.719458 s ] <<<<< .. + +* Energy of state 1 -228.8517591212160 +* S^2 of state 1 0.1842309580710883E-01 +* Saved determinants 640 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 198 +* Number of unique alpha determinants 198 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.251373 GB ] [ VIRT MEM : 16.470764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 66.363088 s ] [ CPU TIME: 1517.568124 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 4.251373 GB ] [ VIRT MEM : 16.470764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 66.363476 s ] [ CPU TIME: 1517.596601 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.8517591212160 + +.. >>>>> [ RES MEM : 4.251373 GB ] [ VIRT MEM : 16.470764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 67.346584 s ] [ CPU TIME: 1548.798966 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 4.251373 GB ] [ VIRT MEM : 16.470764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 67.346874 s ] [ CPU TIME: 1548.799205 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 640 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.5709517002105713E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 408 -229.0101730035 0.626E-02 0.5243321086 0.0538287399 1.0047 + 630 -229.0146216104 0.00 0.5424142117 0.0549514447 1.3330 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.251503 GB ] [ VIRT MEM : 16.470764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 71.555044 s ] [ CPU TIME: 1681.348612 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 4.251503 GB ] [ VIRT MEM : 16.470764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 71.555339 s ] [ CPU TIME: 1681.348857 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.6798097779914881 + +Summary at N_det = 640 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.85175912 +# PT2 -0.16286249 0.00000000 +# rPT2 -0.15437913 0.00000000 +# +# E+PT2 -229.01462161 0.00000000 +# E+rPT2 -229.00613825 0.00000000 +# ============ ============================= + + N_det = 640 + N_states = 1 + + * State 1 + < S^2 > = 1.842309580710883E-002 + E = -228.851759121216 + Variance = 0.542414211660980 + PT norm = 0.234417244837104 + PT2 = -0.162862489217116 + rPT2 = -0.154379132839595 + E+PT2 = -229.014621610433 +/- 0.000000000000000E+000 + E+rPT2 = -229.006138254056 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.833482721002 + Vee = 238.767347927830 + Vecp = 0.000000000000000E+000 + T = 229.106145893167 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1843 -229.02888113 + -0.2191 -229.02436848 + -0.2523 -229.02017681 + -0.2823 -229.01648805 + -0.3124 -229.01123583 + -0.3601 -229.00621623 + -0.4066 -229.00671883 + =========== =================== + +* Number of unique alpha determinants 334 +* Number of unique beta determinants 334 +.. >>>>> [ IO READ: davidson_sze_max ] <<<<< .. + +.. >>>>> [ RES MEM : 4.252007 GB ] [ VIRT MEM : 16.470764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 73.510106 s ] [ CPU TIME: 1735.243115 s ] <<<<< .. + +.. >>>>> [ IO READ: state_following ] <<<<< .. + +.. >>>>> [ RES MEM : 4.252007 GB ] [ VIRT MEM : 16.470764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 73.511269 s ] [ CPU TIME: 1735.311122 s ] <<<<< .. + +.. >>>>> [ IO READ: only_expected_s2 ] <<<<< .. + +.. >>>>> [ RES MEM : 4.252007 GB ] [ VIRT MEM : 16.470764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 73.512509 s ] [ CPU TIME: 1735.399838 s ] <<<<< .. + +.. >>>>> [ IO READ: disk_based_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 4.252007 GB ] [ VIRT MEM : 16.470764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 73.513317 s ] [ CPU TIME: 1735.457413 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 4.252007 GB ] [ VIRT MEM : 16.470764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 73.513681 s ] [ CPU TIME: 1735.483880 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 1280 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.2629097551107407E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.8517940282 0.018410 0.125E-01 + 2 -228.8834611409 0.010794 0.260E-03 + 3 -228.8838319808 0.010444 0.549E-04 + 4 -228.8838643472 0.010440 0.258E-05 + 5 -228.8838683095 0.010370 0.724E-07 + 6 -228.8838684853 0.010368 0.326E-08 + 7 -228.8838684923 0.010370 0.920E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 4.252266 GB ] [ VIRT MEM : 16.473557 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 73.562442 s ] [ CPU TIME: 1738.959965 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 4.252266 GB ] [ VIRT MEM : 16.473557 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 73.562841 s ] [ CPU TIME: 1738.989215 s ] <<<<< .. + +* Energy of state 1 -228.8838684923194 +* S^2 of state 1 0.1037047460280267E-01 +* Saved determinants 1280 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.252350 GB ] [ VIRT MEM : 16.473557 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 74.132867 s ] [ CPU TIME: 1759.198389 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 4.252350 GB ] [ VIRT MEM : 16.473557 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 74.133269 s ] [ CPU TIME: 1759.227597 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 48 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.8838684923194 + +.. >>>>> [ RES MEM : 4.252350 GB ] [ VIRT MEM : 16.473557 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 75.119879 s ] [ CPU TIME: 1790.439850 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 4.252350 GB ] [ VIRT MEM : 16.473557 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 75.120186 s ] [ CPU TIME: 1790.440104 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 48 +* pt2_n_tasks_max 1 +* Number of tasks 1280 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.9876734018325806E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 8 -229.0162445657 0.128E-03 0.4705092401 0.0419212638 1.0037 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.251690 GB ] [ VIRT MEM : 16.486118 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 80.066599 s ] [ CPU TIME: 1902.226914 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 4.251690 GB ] [ VIRT MEM : 16.486118 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 80.066893 s ] [ CPU TIME: 1902.227159 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 48 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7390140597536038 + +Summary at N_det = 1280 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.88386849 +# PT2 -0.13242169 0.00010423 +# rPT2 -0.12709259 0.00010004 +# +# E+PT2 -229.01629019 0.00010423 +# E+rPT2 -229.01096108 0.00010004 +# ============ ============================= + + N_det = 1280 + N_states = 1 + + * State 1 + < S^2 > = 1.037047460280267E-002 + E = -228.883868492319 + Variance = 0.470782952602495 + PT norm = 0.204770390886760 + PT2 = -0.132421693398478 + rPT2 = -0.127092585264837 + E+PT2 = -229.016290185718 +/- 1.042328237476876E-004 + E+rPT2 = -229.010961077584 +/- 1.000381334777583E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.852857751646 + Vee = 238.725526407769 + Vecp = 0.000000000000000E+000 + T = 229.135233072768 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1544 -229.03342435 + -0.1843 -229.03129147 + -0.2191 -229.02778488 + -0.2523 -229.02417562 + -0.2823 -229.02086520 + -0.3124 -229.01644958 + -0.3601 -229.01179718 + =========== =================== + +* Number of unique alpha determinants 560 +* Number of unique beta determinants 560 + +.. >>>>> [ RES MEM : 4.252415 GB ] [ VIRT MEM : 16.486118 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 82.001999 s ] [ CPU TIME: 1953.974889 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 2560 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.4873041063547134E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.8838884847 0.010422 0.107E-01 + 2 -228.9103381203 0.009486 0.193E-03 + 3 -228.9106849826 0.009505 0.120E-04 + 4 -228.9107042180 0.009521 0.235E-05 + 5 -228.9107060917 0.009516 0.159E-06 + 6 -228.9107063198 0.009516 0.630E-08 + 7 -228.9107063322 0.009515 0.235E-09 + 8 -228.9107063327 0.009515 0.151E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 4.256748 GB ] [ VIRT MEM : 16.486118 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 82.044711 s ] [ CPU TIME: 1957.042695 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 4.256748 GB ] [ VIRT MEM : 16.486118 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 82.045134 s ] [ CPU TIME: 1957.073178 s ] <<<<< .. + +* Energy of state 1 -228.9107063326993 +* S^2 of state 1 0.9514657138959553E-02 +* Saved determinants 2560 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.256935 GB ] [ VIRT MEM : 16.486118 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 82.630434 s ] [ CPU TIME: 1978.258234 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 4.256935 GB ] [ VIRT MEM : 16.486118 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 82.630831 s ] [ CPU TIME: 1978.287231 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 56 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.9107063326993 + +.. >>>>> [ RES MEM : 4.257156 GB ] [ VIRT MEM : 16.486118 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 83.616763 s ] [ CPU TIME: 2009.508203 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 4.257156 GB ] [ VIRT MEM : 16.486118 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 83.617056 s ] [ CPU TIME: 2009.508455 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 56 +* pt2_n_tasks_max 1 +* Number of tasks 2560 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1820860505104065E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0189225013 0.610E-03 0.4163514966 0.0314551346 1.2966 + 43 -229.0188608678 0.359E-04 0.4162482436 0.0314374134 2.2979 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.266552 GB ] [ VIRT MEM : 16.486137 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 89.958386 s ] [ CPU TIME: 2212.032472 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 4.266552 GB ] [ VIRT MEM : 16.486137 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 89.958685 s ] [ CPU TIME: 2212.032720 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 56 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7867100458356009 + +Summary at N_det = 2560 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.91070633 +# PT2 -0.10814127 0.00002918 +# rPT2 -0.10484510 0.00002829 +# +# E+PT2 -229.01884761 0.00002918 +# E+rPT2 -229.01555143 0.00002829 +# ============ ============================= + + N_det = 2560 + N_states = 1 + + * State 1 + < S^2 > = 9.514657138959553E-003 + E = -228.910706332699 + Variance = 0.416062557870366 + PT norm = 0.177309090486288 + PT2 = -0.108141273684267 + rPT2 = -0.104845099597907 + E+PT2 = -229.018847606384 +/- 2.917710192959161E-005 + E+rPT2 = -229.015551432297 +/- 2.828777629083330E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.953260006954 + Vee = 238.745519223158 + Vecp = 0.000000000000000E+000 + T = 229.188804672308 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1271 -229.03718427 + -0.1544 -229.03529107 + -0.1843 -229.03333266 + -0.2191 -229.03041305 + -0.2523 -229.02729382 + -0.2823 -229.02435304 + -0.3124 -229.02057429 + =========== =================== + +* Number of unique alpha determinants 1063 +* Number of unique beta determinants 1063 + +.. >>>>> [ RES MEM : 4.261162 GB ] [ VIRT MEM : 16.477196 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 92.238320 s ] [ CPU TIME: 2270.522966 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5120 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.9484231472015381E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9107224760 0.009514 0.803E-02 + 2 -228.9334722714 0.008091 0.196E-03 + 3 -228.9337702591 0.008055 0.468E-04 + 4 -228.9338021315 0.008015 0.212E-05 + 5 -228.9338052505 0.008016 0.106E-06 + 6 -228.9338054482 0.008014 0.699E-08 + 7 -228.9338054631 0.008015 0.328E-09 + 8 -228.9338054638 0.008015 0.160E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 4.267757 GB ] [ VIRT MEM : 16.482952 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 92.310893 s ] [ CPU TIME: 2275.735511 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 4.266418 GB ] [ VIRT MEM : 16.480652 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 92.311568 s ] [ CPU TIME: 2275.784099 s ] <<<<< .. + +* Energy of state 1 -228.9338054638263 +* S^2 of state 1 0.8015195988509543E-02 +* Saved determinants 5120 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.266426 GB ] [ VIRT MEM : 16.480652 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 93.097546 s ] [ CPU TIME: 2301.832773 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 4.266426 GB ] [ VIRT MEM : 16.480652 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 93.097958 s ] [ CPU TIME: 2301.862175 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 63 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.9338054638263 + +.. >>>>> [ RES MEM : 4.265373 GB ] [ VIRT MEM : 16.479561 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 94.219865 s ] [ CPU TIME: 2336.183823 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 4.265373 GB ] [ VIRT MEM : 16.479561 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 94.220185 s ] [ CPU TIME: 2336.184090 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 63 +* pt2_n_tasks_max 1 +* Number of tasks 5120 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.3487207889556885E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0217552008 0.148E-03 0.3614736236 0.0237927259 2.2197 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.249161 GB ] [ VIRT MEM : 16.396381 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 100.079546 s ] [ CPU TIME: 2532.984457 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 4.249161 GB ] [ VIRT MEM : 16.396381 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 100.079851 s ] [ CPU TIME: 2532.984711 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 63 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8269314000941618 + +Summary at N_det = 5120 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.93380546 +# PT2 -0.08781019 0.00006559 +# rPT2 -0.08577033 0.00006407 +# +# E+PT2 -229.02161565 0.00006559 +# E+rPT2 -229.01957579 0.00006407 +# ============ ============================= + + N_det = 5120 + N_states = 1 + + * State 1 + < S^2 > = 8.015195988509543E-003 + E = -228.933805463826 + Variance = 0.360330617469312 + PT norm = 0.154216800977899 + PT2 = -8.781018635310023E-002 + rPT2 = -8.577032598277030E-002 + E+PT2 = -229.021615650179 +/- 6.558933423722295E-005 + E+rPT2 = -229.019575789809 +/- 6.406567178775690E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.940539626062 + Vee = 238.695328702836 + Vecp = 0.000000000000000E+000 + T = 229.203175680611 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1048 -229.03767144 + -0.1271 -229.03743472 + -0.1544 -229.03621397 + -0.1843 -229.03464292 + -0.2191 -229.03225250 + -0.2523 -229.02959326 + -0.2823 -229.02701598 + =========== =================== + +* Number of unique alpha determinants 1969 +* Number of unique beta determinants 1969 + +.. >>>>> [ RES MEM : 4.248341 GB ] [ VIRT MEM : 16.395172 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 102.024302 s ] [ CPU TIME: 2585.725904 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 10240 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.1846484094858170E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9338201491 0.008018 0.627E-02 + 2 -228.9529304164 0.006306 0.279E-03 + 3 -228.9532045914 0.006343 0.523E-04 + 4 -228.9532534835 0.006334 0.166E-05 + 5 -228.9532568686 0.006345 0.114E-06 + 6 -228.9532571198 0.006346 0.107E-07 + 7 -228.9532571422 0.006347 0.591E-09 + 8 -228.9532571435 0.006346 0.282E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 4.261070 GB ] [ VIRT MEM : 16.404907 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 102.157570 s ] [ CPU TIME: 2595.297666 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 4.258362 GB ] [ VIRT MEM : 16.400318 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 102.158460 s ] [ CPU TIME: 2595.361890 s ] <<<<< .. + +* Energy of state 1 -228.9532571435361 +* S^2 of state 1 0.6346411260745178E-02 +* Saved determinants 10240 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.258595 GB ] [ VIRT MEM : 16.400620 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 102.851197 s ] [ CPU TIME: 2621.656662 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 4.258595 GB ] [ VIRT MEM : 16.400620 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 102.851611 s ] [ CPU TIME: 2621.686999 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 69 +* pt2_n_tasks_max 2 +* PT2 Energy denominator -228.9532571435361 + +.. >>>>> [ RES MEM : 4.259941 GB ] [ VIRT MEM : 16.400620 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 103.839828 s ] [ CPU TIME: 2653.055731 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 4.259941 GB ] [ VIRT MEM : 16.400620 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 103.840161 s ] [ CPU TIME: 2653.056006 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 69 +* pt2_n_tasks_max 2 +* Number of tasks 10434 +* Number of fragmented tasks 194 +* Number of threads for PT2 72 +* Memory (Gb) 0.6823556423187256E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0249924109 0.728E-03 0.3123467040 0.0181791364 1.9644 + 20 -229.0248569200 0.199E-03 0.3114015835 0.0181471470 3.0217 + 39 -229.0247851412 0.104E-03 0.3108388051 0.0181410096 4.0783 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.262711 GB ] [ VIRT MEM : 16.396259 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 111.465052 s ] [ CPU TIME: 3005.707892 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 4.262711 GB ] [ VIRT MEM : 16.396259 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 111.465378 s ] [ CPU TIME: 3005.708165 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 69 +* pt2_n_tasks_max 2 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8593816773813840 + +Summary at N_det = 10240 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.95325714 +# PT2 -0.07151372 0.00009604 +# rPT2 -0.07023982 0.00009432 +# +# E+PT2 -229.02477087 0.00009604 +# E+rPT2 -229.02349696 0.00009432 +# ============ ============================= + + N_det = 10240 + N_states = 1 + + * State 1 + < S^2 > = 6.346411260745178E-003 + E = -228.953257143536 + Variance = 0.310814945512076 + PT norm = 0.134671729953331 + PT2 = -7.151372385983658E-002 + rPT2 = -7.023982111088721E-002 + E+PT2 = -229.024770867396 +/- 9.603515034270840E-005 + E+rPT2 = -229.023496964647 +/- 9.432443755341047E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.934511151954 + Vee = 238.653172380510 + Vecp = 0.000000000000000E+000 + T = 229.219851849118 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0858 -229.04123126 + -0.1048 -229.03944518 + -0.1271 -229.03861577 + -0.1544 -229.03742040 + -0.1843 -229.03598929 + -0.2191 -229.03391221 + -0.2523 -229.03157913 + =========== =================== + +* Number of unique alpha determinants 3636 +* Number of unique beta determinants 3636 + +.. >>>>> [ RES MEM : 4.263981 GB ] [ VIRT MEM : 16.396259 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 113.799235 s ] [ CPU TIME: 3067.749693 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 20480 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.3607549145817757E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9532572857 0.006346 0.495E-02 + 2 -228.9692064111 0.004645 0.296E-03 + 3 -228.9694625306 0.004638 0.455E-04 + 4 -228.9695121330 0.004613 0.145E-05 + 5 -228.9695154726 0.004596 0.111E-06 + 6 -228.9695157329 0.004592 0.929E-08 + 7 -228.9695157562 0.004592 0.725E-09 + 8 -228.9695157579 0.004591 0.518E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 4.280262 GB ] [ VIRT MEM : 16.417816 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 114.121761 s ] [ CPU TIME: 3090.908374 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 4.272152 GB ] [ VIRT MEM : 16.403946 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 114.123404 s ] [ CPU TIME: 3091.026652 s ] <<<<< .. + +* Energy of state 1 -228.9695157578976 +* S^2 of state 1 0.4591461996088076E-02 +* Saved determinants 20480 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.265457 GB ] [ VIRT MEM : 16.395142 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 115.051349 s ] [ CPU TIME: 3124.984406 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 4.265457 GB ] [ VIRT MEM : 16.395142 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 115.051802 s ] [ CPU TIME: 3125.017125 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 75 +* pt2_n_tasks_max 3 +* PT2 Energy denominator -228.9695157578976 + +.. >>>>> [ RES MEM : 4.267174 GB ] [ VIRT MEM : 16.395142 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 116.180114 s ] [ CPU TIME: 3159.558581 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 4.267174 GB ] [ VIRT MEM : 16.395142 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 116.180463 s ] [ CPU TIME: 3159.558876 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 75 +* pt2_n_tasks_max 3 +* Number of tasks 20882 +* Number of fragmented tasks 201 +* Number of threads for PT2 72 +* Memory (Gb) 0.1349255800247192 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0269696535 0.586E-03 0.2631442008 0.0136456477 2.2720 + 9 -229.0279272492 0.525E-03 0.2686354862 0.0138192804 3.5428 + 19 -229.0281068420 0.263E-03 0.2701646006 0.0138400147 4.5871 + 32 -229.0278591398 0.186E-03 0.2684231742 0.0138064912 5.6025 + 43 -229.0277779306 0.132E-03 0.2677870034 0.0137967376 6.6864 + 67 -229.0277885067 0.964E-04 0.2678308538 0.0137994308 7.7210 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.436470 GB ] [ VIRT MEM : 16.559334 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 127.926659 s ] [ CPU TIME: 3772.318605 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 4.436470 GB ] [ VIRT MEM : 16.559334 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 127.927020 s ] [ CPU TIME: 3772.318913 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 75 +* pt2_n_tasks_max 3 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8857493657888252 + +Summary at N_det = 20480 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.96951576 +# PT2 -0.05826018 0.00008857 +# rPT2 -0.05746726 0.00008736 +# +# E+PT2 -229.02777594 0.00008857 +# E+rPT2 -229.02698302 0.00008736 +# ============ ============================= + + N_det = 20480 + N_states = 1 + + * State 1 + < S^2 > = 4.591461996088076E-003 + E = -228.969515757898 + Variance = 0.267722254055069 + PT norm = 0.117463795616247 + PT2 = -5.826018176656507E-002 + rPT2 = -5.746726322159623E-002 + E+PT2 = -229.027775939664 +/- 8.856860499950843E-005 + E+rPT2 = -229.026983021119 +/- 8.736319012992364E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.924608962914 + Vee = 238.612999001574 + Vecp = 0.000000000000000E+000 + T = 229.233864424653 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0702 -229.04266775 + -0.0858 -229.04195174 + -0.1048 -229.04059092 + -0.1271 -229.03966966 + -0.1544 -229.03852479 + -0.1843 -229.03720254 + -0.2191 -229.03535625 + =========== =================== + +* Number of unique alpha determinants 6410 +* Number of unique beta determinants 6398 + +.. >>>>> [ RES MEM : 4.440609 GB ] [ VIRT MEM : 16.555428 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 129.972995 s ] [ CPU TIME: 3831.500237 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 40960 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.6994287297129631E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9695161817 0.004592 0.351E-02 + 2 -228.9816092452 0.003530 0.289E-03 + 3 -228.9818329208 0.003521 0.362E-04 + 4 -228.9818793349 0.003502 0.171E-05 + 5 -228.9818834877 0.003490 0.207E-06 + 6 -228.9818839197 0.003489 0.213E-07 + 7 -228.9818839640 0.003489 0.165E-08 + 8 -228.9818839681 0.003490 0.136E-09 + 9 -228.9818839684 0.003490 0.127E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 4.494507 GB ] [ VIRT MEM : 16.614429 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 130.882762 s ] [ CPU TIME: 3896.825211 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 4.476177 GB ] [ VIRT MEM : 16.586590 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 130.885419 s ] [ CPU TIME: 3897.016368 s ] <<<<< .. + +* Energy of state 1 -228.9818839683896 +* S^2 of state 1 0.3489701767924276E-02 +* Saved determinants 40960 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.463020 GB ] [ VIRT MEM : 16.569946 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 131.828023 s ] [ CPU TIME: 3935.344181 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 4.463020 GB ] [ VIRT MEM : 16.569946 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 131.828512 s ] [ CPU TIME: 3935.379350 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 80 +* pt2_n_tasks_max 5 +* PT2 Energy denominator -228.9818839683896 + +.. >>>>> [ RES MEM : 4.463520 GB ] [ VIRT MEM : 16.569946 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 132.821350 s ] [ CPU TIME: 3967.088581 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 4.463520 GB ] [ VIRT MEM : 16.569946 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 132.821739 s ] [ CPU TIME: 3967.088913 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 80 +* pt2_n_tasks_max 5 +* Number of tasks 44219 +* Number of fragmented tasks 2593 +* Number of threads for PT2 72 +* Memory (Gb) 0.2683054029941559 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0295646979 0.870E-03 0.2279911599 0.0106935441 3.5306 + 7 -229.0297956397 0.569E-03 0.2300099659 0.0107122786 4.7324 + 12 -229.0304308520 0.410E-03 0.2345479663 0.0107994454 5.9383 + 19 -229.0303268770 0.290E-03 0.2337551312 0.0107883012 7.0632 + 27 -229.0303218486 0.223E-03 0.2336038091 0.0107913586 8.3132 + 35 -229.0302828607 0.170E-03 0.2333754936 0.0107853679 9.6370 + 47 -229.0302331360 0.139E-03 0.2330412400 0.0107775107 11.0141 + 63 -229.0302421891 0.122E-03 0.2331508534 0.0107776779 12.1157 + 78 -229.0302360097 0.102E-03 0.2330510338 0.0107781313 13.2666 + 96 -229.0303832814 0.101E-03 0.2340319307 0.0108007247 14.3080 + 113 -229.0303970722 0.912E-04 0.2341549359 0.0108023153 15.3201 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.701759 GB ] [ VIRT MEM : 16.763840 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 152.559533 s ] [ CPU TIME: 5149.145762 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 4.701759 GB ] [ VIRT MEM : 16.763840 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 152.559936 s ] [ CPU TIME: 5149.146109 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 80 +* pt2_n_tasks_max 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9049725128502368 + +Summary at N_det = 40960 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.98188397 +# PT2 -0.04860163 0.00008181 +# rPT2 -0.04808158 0.00008094 +# +# E+PT2 -229.03048560 0.00008181 +# E+rPT2 -229.02996555 0.00008094 +# ============ ============================= + + N_det = 40960 + N_states = 1 + + * State 1 + < S^2 > = 3.489701767924276E-003 + E = -228.981883968390 + Variance = 0.234764263232965 + PT norm = 0.104000072351515 + PT2 = -4.860162874562295E-002 + rPT2 = -4.808157767787362E-002 + E+PT2 = -229.030485597135 +/- 8.181048314148418E-005 + E+rPT2 = -229.029965546067 +/- 8.093508801154939E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.891648098778 + Vee = 238.553002374961 + Vecp = 0.000000000000000E+000 + T = 229.248531976638 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0575 -229.04524461 + -0.0702 -229.04385611 + -0.0858 -229.04291856 + -0.1048 -229.04165842 + -0.1271 -229.04069183 + -0.1544 -229.03957461 + -0.1843 -229.03832514 + =========== =================== + +* Number of unique alpha determinants 11261 +* Number of unique beta determinants 11273 + +.. >>>>> [ RES MEM : 4.707291 GB ] [ VIRT MEM : 16.766293 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 154.751671 s ] [ CPU TIME: 5219.360294 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 81920 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.1360215023159981 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9818841377 0.003490 0.240E-02 + 2 -228.9908166525 0.003035 0.203E-03 + 3 -228.9909779831 0.003037 0.246E-04 + 4 -228.9910098423 0.003034 0.110E-05 + 5 -228.9910127116 0.003025 0.134E-06 + 6 -228.9910130191 0.003025 0.165E-07 + 7 -228.9910130540 0.003025 0.155E-08 + 8 -228.9910130577 0.003025 0.162E-09 + 9 -228.9910130581 0.003025 0.188E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 4.808617 GB ] [ VIRT MEM : 16.886524 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 157.107096 s ] [ CPU TIME: 5388.523363 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 4.772076 GB ] [ VIRT MEM : 16.830853 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 157.111740 s ] [ CPU TIME: 5388.857873 s ] <<<<< .. + +* Energy of state 1 -228.9910130580814 +* S^2 of state 1 0.3025308256991632E-02 +* Saved determinants 81920 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.733418 GB ] [ VIRT MEM : 16.788834 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 158.370306 s ] [ CPU TIME: 5442.452169 s ] <<<<< .. + +* Number of generators 81916 + +.. >>>>> [ RES MEM : 4.733418 GB ] [ VIRT MEM : 16.788834 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 158.370892 s ] [ CPU TIME: 5442.494747 s ] <<<<< .. + +* Number of selectors 81916 +* Number of comb teeth 84 +* pt2_n_tasks_max 9 +* PT2 Energy denominator -228.9910130580814 + +.. >>>>> [ RES MEM : 4.733509 GB ] [ VIRT MEM : 16.788834 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 159.375139 s ] [ CPU TIME: 5474.863962 s ] <<<<< .. + +* Number of generators 81916 + +.. >>>>> [ RES MEM : 4.733509 GB ] [ VIRT MEM : 16.788834 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 159.375624 s ] [ CPU TIME: 5474.864392 s ] <<<<< .. + +* Number of selectors 81916 +* Number of comb teeth 84 +* pt2_n_tasks_max 9 +* Number of tasks 89302 +* Number of fragmented tasks 3000 +* Number of threads for PT2 72 +* Memory (Gb) 0.5350647617876529 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0337714406 0.209E-02 0.2178368994 0.0089628487 5.8648 + 5 -229.0327522982 0.126E-02 0.2116175752 0.0087908593 7.3198 + 8 -229.0327670272 0.722E-03 0.2109303548 0.0088169854 8.8900 + 13 -229.0323607355 0.461E-03 0.2084169797 0.0087458143 10.1878 + 18 -229.0321087592 0.354E-03 0.2064503419 0.0087149166 11.3956 + 22 -229.0320508696 0.310E-03 0.2060470474 0.0087078537 12.4500 + 27 -229.0323726054 0.320E-03 0.2083557140 0.0087520366 13.5641 + 31 -229.0323521294 0.288E-03 0.2082022672 0.0087489456 14.9268 + 39 -229.0321004561 0.260E-03 0.2064239460 0.0087120267 16.1135 + 43 -229.0320377151 0.253E-03 0.2060201273 0.0087020238 17.4664 + 51 -229.0320650906 0.223E-03 0.2062533428 0.0087043409 18.5989 + 58 -229.0320634811 0.198E-03 0.2062245529 0.0087050952 19.6357 + 71 -229.0321828543 0.190E-03 0.2069709946 0.0087248357 20.7891 + 84 -229.0320681542 0.152E-03 0.2060198271 0.0087122672 21.8081 + 87 -229.0320542962 0.148E-03 0.2059421478 0.0087099876 22.8679 + 100 -229.0319848917 0.124E-03 0.2053589853 0.0087029995 24.0144 + 113 -229.0320033608 0.113E-03 0.2055330757 0.0087047237 25.1503 + 125 -229.0319816460 0.107E-03 0.2054001841 0.0087013220 26.5623 + 136 -229.0319859000 0.101E-03 0.2054088872 0.0087025163 27.6304 + 147 -229.0319658945 0.100E-03 0.2052756064 0.0086997928 28.7603 + 163 -229.0319956798 0.903E-04 0.2054749956 0.0087045156 29.9019 + 177 -229.0320308981 0.864E-04 0.2057479401 0.0087091157 31.3543 + 194 -229.0320533586 0.826E-04 0.2058919642 0.0087128755 32.4611 + 213 -229.0321114192 0.754E-04 0.2062372459 0.0087229420 33.4780 + 231 -229.0320921978 0.694E-04 0.2061116680 0.0087196852 34.8342 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 5.099869 GB ] [ VIRT MEM : 17.089958 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 197.918493 s ] [ CPU TIME: 8035.343405 s ] <<<<< .. + +* Number of generators 81916 + +.. >>>>> [ RES MEM : 5.099869 GB ] [ VIRT MEM : 17.089958 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 197.919005 s ] [ CPU TIME: 8035.343860 s ] <<<<< .. + +* Number of selectors 81916 +* Number of comb teeth 84 +* pt2_n_tasks_max 9 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9198425417271242 + +Summary at N_det = 81920 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.99101306 +# PT2 -0.04105223 0.00006488 +# rPT2 -0.04069759 0.00006432 +# +# E+PT2 -229.03206529 0.00006488 +# E+rPT2 -229.03171065 0.00006432 +# ============ ============================= + + N_det = 81920 + N_states = 1 + + * State 1 + < S^2 > = 3.025308256991632E-003 + E = -228.991013058081 + Variance = 0.205980963652713 + PT norm = 9.334851477307529E-002 + PT2 = -4.105222737860322E-002 + rPT2 = -4.069759080216040E-002 + E+PT2 = -229.032065285460 +/- 6.488262140257998E-005 + E+rPT2 = -229.031710648884 +/- 6.432212195604228E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.888465579783 + Vee = 238.526884121907 + Vecp = 0.000000000000000E+000 + T = 229.262338621006 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0481 -229.04132896 + -0.0575 -229.04337359 + -0.0702 -229.04331713 + -0.0858 -229.04285212 + -0.1048 -229.04193739 + -0.1271 -229.04112323 + -0.1544 -229.04014211 + =========== =================== + +* Number of unique beta determinants 21040 +* Number of unique alpha determinants 20852 + +.. >>>>> [ RES MEM : 5.146893 GB ] [ VIRT MEM : 17.129112 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 203.027678 s ] [ CPU TIME: 8160.865280 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 163840 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.2682778872549534 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9910131835 0.003025 0.153E-02 + 2 -228.9970978828 0.002958 0.125E-03 + 3 -228.9972100457 0.002971 0.185E-04 + 4 -228.9972328852 0.002978 0.106E-05 + 5 -228.9972357014 0.002972 0.153E-06 + 6 -228.9972360467 0.002971 0.213E-07 + 7 -228.9972360898 0.002972 0.212E-08 + 8 -228.9972360948 0.002972 0.244E-09 + 9 -228.9972360953 0.002972 0.269E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 5.281010 GB ] [ VIRT MEM : 17.301384 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 230.097586 s ] [ CPU TIME: 8630.638548 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 5.207863 GB ] [ VIRT MEM : 17.190536 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 230.106664 s ] [ CPU TIME: 8631.291000 s ] <<<<< .. + +* Energy of state 1 -228.9972360953381 +* S^2 of state 1 0.2972037957979116E-02 +* Saved determinants 163840 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 5.133236 GB ] [ VIRT MEM : 17.109444 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 232.205993 s ] [ CPU TIME: 8701.574598 s ] <<<<< .. + +* Number of generators 163836 + +.. >>>>> [ RES MEM : 5.133236 GB ] [ VIRT MEM : 17.109444 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 232.206785 s ] [ CPU TIME: 8701.631970 s ] <<<<< .. + +* Number of selectors 163836 +* Number of comb teeth 87 +* pt2_n_tasks_max 17 +* PT2 Energy denominator -228.9972360953381 + +.. >>>>> [ RES MEM : 5.135498 GB ] [ VIRT MEM : 17.109444 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 233.380957 s ] [ CPU TIME: 8738.304243 s ] <<<<< .. + +* Number of generators 163836 + +.. >>>>> [ RES MEM : 5.135498 GB ] [ VIRT MEM : 17.109444 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 233.381648 s ] [ CPU TIME: 8738.304874 s ] <<<<< .. + +* Number of selectors 163836 +* Number of comb teeth 87 +* pt2_n_tasks_max 17 +* Number of tasks 177805 +* Number of fragmented tasks 3664 +* Number of threads for PT2 72 +* Memory (Gb) 1.068583547025919 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0336749484 0.101E-02 0.1886658702 0.0074567197 10.8196 + 4 -229.0340124701 0.752E-03 0.1911286808 0.0075042657 13.1718 + 6 -229.0339803638 0.861E-03 0.1900922639 0.0075204566 14.3826 + 8 -229.0338426479 0.656E-03 0.1892391946 0.0074925997 15.8729 + 11 -229.0339937670 0.495E-03 0.1906105684 0.0075009084 17.6369 + 14 -229.0337369477 0.458E-03 0.1889080837 0.0074625769 20.0013 + 20 -229.0335624527 0.461E-03 0.1877907416 0.0074359403 21.5540 + 25 -229.0336044961 0.388E-03 0.1881330429 0.0074426354 23.3578 + 29 -229.0336343193 0.322E-03 0.1885476572 0.0074411063 24.4928 + 31 -229.0335546135 0.304E-03 0.1880101011 0.0074277760 25.6201 + 34 -229.0336376362 0.274E-03 0.1886328837 0.0074390233 27.6348 + 41 -229.0335941396 0.231E-03 0.1881591853 0.0074361104 29.1665 + 43 -229.0336105849 0.221E-03 0.1883501685 0.0074363968 30.2078 + 48 -229.0335047671 0.211E-03 0.1875756541 0.0074219162 31.6348 + 52 -229.0334720506 0.200E-03 0.1872708261 0.0074188486 32.8468 + 62 -229.0334025245 0.181E-03 0.1865830119 0.0074140310 33.9356 + 69 -229.0335840796 0.191E-03 0.1878440846 0.0074413547 35.6279 + 78 -229.0335205831 0.182E-03 0.1874332079 0.0074306291 37.1125 + 80 -229.0335012309 0.178E-03 0.1873285648 0.0074268834 38.4095 + 89 -229.0334321241 0.168E-03 0.1869753332 0.0074131686 39.8948 + 100 -229.0335406298 0.161E-03 0.1876499577 0.0074312464 41.2588 + 105 -229.0334741672 0.158E-03 0.1871807438 0.0074218847 42.3118 + 115 -229.0335124704 0.147E-03 0.1874643355 0.0074267520 43.6437 + 126 -229.0334751781 0.138E-03 0.1872274112 0.0074203299 45.3554 + 134 -229.0334325110 0.133E-03 0.1869179649 0.0074143493 46.9418 + 143 -229.0333977268 0.122E-03 0.1866895147 0.0074091016 47.9680 + 153 -229.0333235936 0.122E-03 0.1861590706 0.0073987992 49.4239 + 155 -229.0333018279 0.116E-03 0.1860129906 0.0073956105 50.9148 + 169 -229.0333459327 0.109E-03 0.1862909911 0.0074027487 52.1814 + 175 -229.0333494642 0.106E-03 0.1863369108 0.0074027089 53.2128 + 188 -229.0333146009 0.100E-03 0.1860801732 0.0073979267 54.7918 + 201 -229.0333526865 0.924E-04 0.1863690183 0.0074029511 56.2948 + 215 -229.0333605324 0.911E-04 0.1864518104 0.0074036731 57.7166 + 228 -229.0333355433 0.874E-04 0.1862741405 0.0074000254 59.1779 + 244 -229.0333815627 0.785E-04 0.1865750526 0.0074073030 60.3813 + 248 -229.0333931808 0.776E-04 0.1866521230 0.0074090642 61.4082 + 267 -229.0333977214 0.709E-04 0.1867419426 0.0074083374 62.4668 + 281 -229.0333959364 0.691E-04 0.1867329843 0.0074079364 63.5149 + 284 -229.0333955532 0.685E-04 0.1867270883 0.0074079768 64.8849 + 299 -229.0334149945 0.646E-04 0.1868530663 0.0074109826 66.1638 + 312 -229.0333908974 0.593E-04 0.1867215611 0.0074066530 67.2430 + 317 -229.0333975319 0.593E-04 0.1867680713 0.0074076284 68.4443 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 5.698654 GB ] [ VIRT MEM : 17.559917 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 305.851244 s ] [ CPU TIME: 13656.769110 s ] <<<<< .. + +* Number of generators 163836 + +.. >>>>> [ RES MEM : 5.698654 GB ] [ VIRT MEM : 17.559917 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 305.851939 s ] [ CPU TIME: 13656.769745 s ] <<<<< .. + +* Number of selectors 163836 +* Number of comb teeth 87 +* pt2_n_tasks_max 17 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9294870599695249 + +Summary at N_det = 163840 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.99723610 +# PT2 -0.03616747 0.00005822 +# rPT2 -0.03590149 0.00005779 +# +# E+PT2 -229.03340357 0.00005822 +# E+rPT2 -229.03313758 0.00005779 +# ============ ============================= + + N_det = 163840 + N_states = 1 + + * State 1 + < S^2 > = 2.972037957979116E-003 + E = -228.997236095338 + Variance = 0.186801518282000 + PT norm = 8.607415501702483E-002 + PT2 = -3.616747329562994E-002 + rPT2 = -3.590148778318909E-002 + E+PT2 = -229.033403568634 +/- 5.821923024219065E-005 + E+rPT2 = -229.033137583121 +/- 5.779107006458290E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.877975809578 + Vee = 238.503025507533 + Vecp = 0.000000000000000E+000 + T = 229.269484427919 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0407 -229.04381898 + -0.0481 -229.04234333 + -0.0575 -229.04326353 + -0.0702 -229.04326436 + -0.0858 -229.04292348 + -0.1048 -229.04217775 + -0.1271 -229.04146205 + =========== =================== + +* Number of unique beta determinants 39482 +* Number of unique alpha determinants 39561 + +.. >>>>> [ RES MEM : 5.760201 GB ] [ VIRT MEM : 17.606293 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 311.665778 s ] [ CPU TIME: 13841.815525 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 327680 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.5303415134549141 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9972361177 0.002972 0.888E-03 + 2 -229.0010250182 0.003119 0.628E-04 + 3 -229.0010924609 0.003125 0.122E-04 + 4 -229.0011058233 0.003129 0.763E-06 + 5 -229.0011077651 0.003120 0.137E-06 + 6 -229.0011080749 0.003117 0.204E-07 + 7 -229.0011081229 0.003118 0.257E-08 + 8 -229.0011081292 0.003119 0.329E-09 + 9 -229.0011081300 0.003119 0.463E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 5.793270 GB ] [ VIRT MEM : 17.702606 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 347.350633 s ] [ CPU TIME: 14838.058057 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 5.500301 GB ] [ VIRT MEM : 17.334919 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 347.393007 s ] [ CPU TIME: 14841.101721 s ] <<<<< .. + +* Energy of state 1 -229.0011081300453 +* S^2 of state 1 0.3118629701111814E-02 +* Saved determinants 327680 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 5.426929 GB ] [ VIRT MEM : 17.253796 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 350.697047 s ] [ CPU TIME: 14919.672719 s ] <<<<< .. + +* Number of generators 327666 + +.. >>>>> [ RES MEM : 5.426929 GB ] [ VIRT MEM : 17.253796 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 350.698163 s ] [ CPU TIME: 14919.753301 s ] <<<<< .. + +* Number of selectors 327666 +* Number of comb teeth 89 +* pt2_n_tasks_max 33 +* PT2 Energy denominator -229.0011081300453 + +.. >>>>> [ RES MEM : 5.451336 GB ] [ VIRT MEM : 17.273815 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 351.933680 s ] [ CPU TIME: 14960.316855 s ] <<<<< .. + +* Number of generators 327666 + +.. >>>>> [ RES MEM : 5.451336 GB ] [ VIRT MEM : 17.273815 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 351.934738 s ] [ CPU TIME: 14960.317853 s ] <<<<< .. + +* Number of selectors 327666 +* Number of comb teeth 89 +* pt2_n_tasks_max 33 +* Number of tasks 349722 +* Number of fragmented tasks 3834 +* Number of threads for PT2 72 +* Memory (Gb) 2.135620727464557 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0363089939 0.118E-02 0.1885727741 0.0069379797 21.9328 + 4 -229.0356818884 0.107E-02 0.1843901914 0.0068455464 26.6337 + 7 -229.0348107934 0.930E-03 0.1785630009 0.0067135017 28.5906 + 8 -229.0344935000 0.881E-03 0.1762103053 0.0066735669 29.8296 + 12 -229.0343042302 0.619E-03 0.1747418074 0.0066463238 33.0819 + 14 -229.0342367124 0.537E-03 0.1739642773 0.0066445783 34.6956 + 18 -229.0341492106 0.410E-03 0.1736237007 0.0066239604 36.3308 + 19 -229.0341328830 0.393E-03 0.1734811972 0.0066237224 38.9076 + 22 -229.0339846851 0.357E-03 0.1728337601 0.0065916615 40.4546 + 24 -229.0339150162 0.340E-03 0.1723089928 0.0065832990 41.6366 + 27 -229.0339609091 0.313E-03 0.1726778653 0.0065895398 43.0836 + 28 -229.0340188165 0.308E-03 0.1729326754 0.0066019345 44.0860 + 29 -229.0339067382 0.316E-03 0.1721515516 0.0065857533 47.4535 + 34 -229.0340025514 0.289E-03 0.1726734479 0.0066036814 48.6547 + 40 -229.0338669865 0.261E-03 0.1716211909 0.0065876599 50.2872 + 42 -229.0338019035 0.253E-03 0.1711650913 0.0065777870 51.4426 + 43 -229.0338229649 0.248E-03 0.1713391157 0.0065799293 52.9598 + 47 -229.0338063262 0.242E-03 0.1713314326 0.0065745369 55.6480 + 50 -229.0338683188 0.231E-03 0.1717476905 0.0065846553 57.0626 + 58 -229.0338705409 0.196E-03 0.1717707759 0.0065845653 62.3611 + 69 -229.0339512716 0.186E-03 0.1722474642 0.0065984480 63.6346 + 78 -229.0340029454 0.173E-03 0.1726604769 0.0066056260 64.7683 + 82 -229.0339873637 0.168E-03 0.1725887032 0.0066022886 67.9008 + 86 -229.0340088122 0.167E-03 0.1727318468 0.0066057432 69.0639 + 94 -229.0340205925 0.146E-03 0.1727526641 0.0066099939 71.3331 + 104 -229.0340263456 0.141E-03 0.1727511634 0.0066120229 73.0645 + 105 -229.0340098822 0.140E-03 0.1726452414 0.0066092769 75.1336 + 120 -229.0340321018 0.130E-03 0.1727223947 0.0066148836 76.4621 + 123 -229.0340173924 0.128E-03 0.1726634838 0.0066117282 78.4014 + 125 -229.0340158838 0.126E-03 0.1726770331 0.0066110659 80.2543 + 134 -229.0340584983 0.120E-03 0.1729817822 0.0066170660 81.5295 + 141 -229.0340671828 0.116E-03 0.1730471048 0.0066182119 82.7266 + 146 -229.0340748349 0.112E-03 0.1730628507 0.0066201681 83.7888 + 149 -229.0341198912 0.114E-03 0.1733595352 0.0066271937 85.2390 + 154 -229.0341756109 0.109E-03 0.1738163424 0.0066337133 86.5616 + 158 -229.0341588741 0.107E-03 0.1736969059 0.0066313384 88.0239 + 165 -229.0341830358 0.102E-03 0.1738550938 0.0066351565 89.8676 + 170 -229.0341722013 0.101E-03 0.1737831447 0.0066335956 91.6416 + 181 -229.0341424593 0.960E-04 0.1735570062 0.0066298264 93.0152 + 190 -229.0341465439 0.939E-04 0.1735879007 0.0066304599 94.7036 + 197 -229.0341278330 0.923E-04 0.1734560436 0.0066277850 96.1018 + 198 -229.0341332750 0.920E-04 0.1734934574 0.0066285988 97.4546 + 203 -229.0341466270 0.878E-04 0.1736209178 0.0066299944 98.5136 + 215 -229.0341247698 0.858E-04 0.1734620749 0.0066269783 99.7296 + 229 -229.0341334316 0.838E-04 0.1735320037 0.0066280040 102.9966 + 241 -229.0341040522 0.818E-04 0.1733853513 0.0066222404 104.1836 + 251 -229.0341183325 0.778E-04 0.1734564833 0.0066248819 105.7858 + 263 -229.0341156619 0.738E-04 0.1734431100 0.0066242906 106.9688 + 267 -229.0341206782 0.737E-04 0.1734813645 0.0066249777 109.1396 + 281 -229.0341315324 0.703E-04 0.1735627904 0.0066264872 110.9691 + 292 -229.0341232420 0.693E-04 0.1735254015 0.0066247336 112.4018 + 302 -229.0341325444 0.660E-04 0.1735605364 0.0066267591 113.8984 + 303 -229.0341398487 0.662E-04 0.1736073629 0.0066279571 115.0226 + 310 -229.0341278311 0.656E-04 0.1735282145 0.0066260555 116.3023 + 317 -229.0341348891 0.650E-04 0.1735883041 0.0066268030 119.0857 + 346 -229.0341591450 0.603E-04 0.1737044926 0.0066315358 120.1421 + 359 -229.0341710213 0.567E-04 0.1738102583 0.0066327716 121.8696 + 361 -229.0341665273 0.565E-04 0.1737751688 0.0066321843 123.9156 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 5.791508 GB ] [ VIRT MEM : 17.538139 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 482.990361 s ] [ CPU TIME: 24048.722103 s ] <<<<< .. + +* Number of generators 327666 + +.. >>>>> [ RES MEM : 5.791508 GB ] [ VIRT MEM : 17.538139 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 482.991432 s ] [ CPU TIME: 24048.723116 s ] <<<<< .. + +* Number of selectors 327666 +* Number of comb teeth 89 +* pt2_n_tasks_max 33 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9356418856968334 + +Summary at N_det = 327680 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.00110813 +# PT2 -0.03303611 0.00005273 +# rPT2 -0.03281856 0.00005239 +# +# E+PT2 -229.03414424 0.00005273 +# E+rPT2 -229.03392669 0.00005239 +# ============ ============================= + + N_det = 327680 + N_states = 1 + + * State 1 + < S^2 > = 3.118629701111814E-003 + E = -229.001108130045 + Variance = 0.173616262159854 + PT norm = 8.141785200073880E-002 + PT2 = -3.303610881147006E-002 + rPT2 = -3.281855896131006E-002 + E+PT2 = -229.034144238857 +/- 5.273462888145747E-005 + E+rPT2 = -229.033926689007 +/- 5.238736005882237E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.865988611974 + Vee = 238.483188194260 + Vecp = 0.000000000000000E+000 + T = 229.273462508879 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0359 -229.04232692 + -0.0407 -229.04323469 + -0.0481 -229.04248248 + -0.0575 -229.04313063 + -0.0702 -229.04317716 + -0.0858 -229.04292167 + -0.1048 -229.04229730 + =========== =================== + +* Number of unique beta determinants 75375 +* Number of unique alpha determinants 74532 + +.. >>>>> [ RES MEM : 5.851536 GB ] [ VIRT MEM : 17.561344 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 491.604984 s ] [ CPU TIME: 24422.000457 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 655360 +* Number of threads for diagonalization 72 +* Memory(Gb) 1.051499813795090 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.0011081386 0.003119 0.435E-03 + 2 -229.0031191631 0.003325 0.238E-04 + 3 -229.0031541141 0.003337 0.634E-05 + 4 -229.0031600262 0.003346 0.394E-06 + 5 -229.0031610517 0.003344 0.727E-07 + 6 -229.0031612271 0.003343 0.125E-07 + 7 -229.0031612555 0.003344 0.175E-08 + 8 -229.0031612600 0.003344 0.290E-09 + 9 -229.0031612607 0.003344 0.414E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 6.442314 GB ] [ VIRT MEM : 18.302952 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 548.807569 s ] [ CPU TIME: 26918.951834 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 5.856422 GB ] [ VIRT MEM : 17.569054 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 548.888540 s ] [ CPU TIME: 26924.707937 s ] <<<<< .. + +* Energy of state 1 -229.0031612607074 +* S^2 of state 1 0.3344054688598087E-02 +* Saved determinants 655360 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 5.740013 GB ] [ VIRT MEM : 17.448914 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 554.632330 s ] [ CPU TIME: 27035.151261 s ] <<<<< .. + +* Number of generators 655327 + +.. >>>>> [ RES MEM : 5.740013 GB ] [ VIRT MEM : 17.448914 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 554.634195 s ] [ CPU TIME: 27035.285664 s ] <<<<< .. + +* Number of selectors 655327 +* Number of comb teeth 91 +* pt2_n_tasks_max 66 +* PT2 Energy denominator -229.0031612607074 + +.. >>>>> [ RES MEM : 5.816360 GB ] [ VIRT MEM : 17.516632 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 555.901432 s ] [ CPU TIME: 27081.997603 s ] <<<<< .. + +* Number of generators 655327 + +.. >>>>> [ RES MEM : 5.816360 GB ] [ VIRT MEM : 17.516632 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 555.903136 s ] [ CPU TIME: 27081.999243 s ] <<<<< .. + +* Number of selectors 655327 +* Number of comb teeth 91 +* pt2_n_tasks_max 66 +* Number of tasks 698820 +* Number of fragmented tasks 4233 +* Number of threads for PT2 72 +* Memory (Gb) 2.605946851111948 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0356523845 0.190E-02 0.1754542393 0.0063574876 44.6825 + 4 -229.0348123761 0.158E-02 0.1697465708 0.0062323755 47.8345 + 5 -229.0352072309 0.124E-02 0.1723894928 0.0062944976 54.6605 + 6 -229.0346033393 0.117E-02 0.1678718764 0.0062170109 57.1364 + 8 -229.0340493556 0.937E-03 0.1643249178 0.0061276153 60.1394 + 9 -229.0340268218 0.819E-03 0.1638348494 0.0061356370 64.9836 + 14 -229.0342804730 0.551E-03 0.1653294314 0.0061804838 70.9284 + 19 -229.0342987033 0.440E-03 0.1651989620 0.0061925204 74.3475 + 20 -229.0343353222 0.417E-03 0.1653841100 0.0061983508 76.0590 + 22 -229.0345272056 0.395E-03 0.1665786216 0.0062297789 78.5175 + 23 -229.0345119894 0.378E-03 0.1664504594 0.0062274448 79.7633 + 26 -229.0346102147 0.340E-03 0.1671009126 0.0062417470 88.4835 + 28 -229.0345882492 0.315E-03 0.1669867741 0.0062377196 96.2624 + 37 -229.0344578789 0.283E-03 0.1660706312 0.0062196116 98.4224 + 40 -229.0344796394 0.281E-03 0.1662307349 0.0062224725 102.0005 + 43 -229.0345017496 0.265E-03 0.1664286956 0.0062241063 104.2005 + 44 -229.0344963745 0.262E-03 0.1663987153 0.0062229360 106.1005 + 45 -229.0344581489 0.258E-03 0.1661416491 0.0062167610 107.6434 + 46 -229.0344053260 0.258E-03 0.1657563707 0.0062092558 110.5604 + 52 -229.0343602064 0.243E-03 0.1654144473 0.0062035712 113.0262 + 54 -229.0343885830 0.235E-03 0.1656160367 0.0062074377 114.1764 + 56 -229.0343322239 0.230E-03 0.1652001789 0.0061996619 116.1585 + 58 -229.0342902426 0.224E-03 0.1649120247 0.0061932701 122.9679 + 71 -229.0344009154 0.186E-03 0.1656109613 0.0062114844 128.4234 + 78 -229.0343889220 0.184E-03 0.1654336366 0.0062118786 130.0614 + 82 -229.0344434611 0.179E-03 0.1657464517 0.0062212787 133.2784 + 87 -229.0344842258 0.185E-03 0.1660422866 0.0062271114 134.3055 + 93 -229.0344941037 0.177E-03 0.1661354542 0.0062283308 143.0915 + 107 -229.0345038408 0.164E-03 0.1662127827 0.0062299546 145.3215 + 111 -229.0344929759 0.159E-03 0.1661480287 0.0062283089 148.7694 + 120 -229.0344791651 0.151E-03 0.1660208112 0.0062272740 151.7775 + 126 -229.0344784399 0.141E-03 0.1659987736 0.0062275470 154.4457 + 128 -229.0344535565 0.140E-03 0.1658163547 0.0062240465 161.6325 + 148 -229.0344615375 0.123E-03 0.1657560817 0.0062281574 163.7907 + 156 -229.0344533461 0.118E-03 0.1656276191 0.0062287832 167.9285 + 160 -229.0344637490 0.116E-03 0.1657171170 0.0062298888 169.0094 + 169 -229.0344857660 0.111E-03 0.1658898225 0.0062325176 170.2388 + 172 -229.0344761834 0.110E-03 0.1658219251 0.0062312029 174.9633 + 177 -229.0344429097 0.103E-03 0.1655886656 0.0062263593 178.5254 + 188 -229.0345137641 0.101E-03 0.1660704323 0.0062372188 179.9585 + 197 -229.0344735151 0.990E-04 0.1657752712 0.0062317904 181.0724 + 198 -229.0344794674 0.987E-04 0.1658244547 0.0062325728 182.3055 + 201 -229.0344657547 0.979E-04 0.1657508831 0.0062300239 187.4024 + 207 -229.0344439090 0.922E-04 0.1655975923 0.0062268222 188.8824 + 216 -229.0344300409 0.898E-04 0.1655230740 0.0062242752 190.9074 + 221 -229.0344335633 0.889E-04 0.1655509246 0.0062246464 193.0914 + 229 -229.0344604067 0.859E-04 0.1657595225 0.0062278707 199.2434 + 248 -229.0345164239 0.818E-04 0.1661482494 0.0062365263 201.2334 + 258 -229.0345256901 0.763E-04 0.1662438711 0.0062373032 204.5064 + 264 -229.0345416210 0.756E-04 0.1663769991 0.0062392059 206.4755 + 266 -229.0345452052 0.754E-04 0.1663985964 0.0062398431 209.3477 + 281 -229.0345428012 0.709E-04 0.1663449855 0.0062404268 212.5924 + 297 -229.0345186016 0.681E-04 0.1661746194 0.0062368279 217.2673 + 317 -229.0345317556 0.655E-04 0.1662586559 0.0062388873 218.9314 + 325 -229.0345698065 0.642E-04 0.1665207487 0.0062444079 220.2994 + 329 -229.0345657984 0.637E-04 0.1664861184 0.0062439207 222.5944 + 338 -229.0345515787 0.627E-04 0.1663978832 0.0062415489 223.6745 + 339 -229.0345533647 0.625E-04 0.1664111045 0.0062417925 226.0045 + 342 -229.0345518442 0.621E-04 0.1663922164 0.0062417019 228.0150 + 359 -229.0345573394 0.594E-04 0.1664411803 0.0062423012 232.7061 + 382 -229.0345676356 0.566E-04 0.1665147976 0.0062437320 237.1257 + 384 -229.0345618758 0.565E-04 0.1664721580 0.0062429363 239.5925 + 423 -229.0345553720 0.529E-04 0.1664053272 0.0062424807 246.4551 + 454 -229.0345434263 0.505E-04 0.1663154972 0.0062408681 254.4834 + 483 -229.0345535688 0.475E-04 0.1664207536 0.0062416155 262.4098 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 6.338097 GB ] [ VIRT MEM : 18.064678 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 823.893836 s ] [ CPU TIME: 45943.817018 s ] <<<<< .. + +* Number of generators 655327 + +.. >>>>> [ RES MEM : 6.338097 GB ] [ VIRT MEM : 18.064678 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 823.895616 s ] [ CPU TIME: 45943.818735 s ] <<<<< .. + +* Number of selectors 655327 +* Number of comb teeth 91 +* pt2_n_tasks_max 66 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9388731906227993 + +Summary at N_det = 655360 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.00316126 +# PT2 -0.03139191 0.00004724 +# rPT2 -0.03119719 0.00004694 +# +# E+PT2 -229.03455317 0.00004724 +# E+rPT2 -229.03435845 0.00004694 +# ============ ============================= + + N_det = 655360 + N_states = 1 + + * State 1 + < S^2 > = 3.344054688598087E-003 + E = -229.003161260707 + Variance = 0.166421334247654 + PT norm = 7.900279106060580E-002 + PT2 = -3.139190593528456E-002 + rPT2 = -3.119719051148593E-002 + E+PT2 = -229.034553166643 +/- 4.723539214052248E-005 + E+rPT2 = -229.034358451219 +/- 4.694240389642234E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.862480884580 + Vee = 238.474196190011 + Vecp = 0.000000000000000E+000 + T = 229.276893655073 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0328 -229.04266611 + -0.0359 -229.04243554 + -0.0407 -229.04306708 + -0.0481 -229.04253547 + -0.0575 -229.04305902 + -0.0702 -229.04312159 + -0.0858 -229.04291466 + =========== =================== + +* Number of unique beta determinants 145486 +* Number of unique alpha determinants 146824 + +.. >>>>> [ RES MEM : 6.191063 GB ] [ VIRT MEM : 17.846992 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 839.864615 s ] [ CPU TIME: 46798.812278 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 1310720 +* Number of threads for diagonalization 72 +* Memory(Gb) 2.093383643776178 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.0031612661 0.003344 0.192E-03 + 2 -229.0040978094 0.003496 0.749E-05 + 3 -229.0041135226 0.003509 0.228E-05 + 4 -229.0041153624 0.003517 0.134E-06 + 5 -229.0041156918 0.003517 0.253E-07 + 6 -229.0041157503 0.003517 0.489E-08 + 7 -229.0041157617 0.003518 0.642E-09 + 8 -229.0041157635 0.003518 0.912E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 7.613274 GB ] [ VIRT MEM : 19.608109 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 941.667752 s ] [ CPU TIME: 52554.612398 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 6.500027 GB ] [ VIRT MEM : 18.141788 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 941.789512 s ] [ CPU TIME: 52559.378389 s ] <<<<< .. + +* Energy of state 1 -229.0041157634807 +* S^2 of state 1 0.3517693995282023E-02 +* Saved determinants 1310720 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 6.099342 GB ] [ VIRT MEM : 17.735424 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 952.825055 s ] [ CPU TIME: 52724.784330 s ] <<<<< .. + +* Number of generators 1310335 + +.. >>>>> [ RES MEM : 6.099342 GB ] [ VIRT MEM : 17.735424 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 952.828329 s ] [ CPU TIME: 52725.019756 s ] <<<<< .. + +* Number of selectors 1310335 +* Number of comb teeth 91 +* pt2_n_tasks_max 132 +* PT2 Energy denominator -229.0041157634807 + +.. >>>>> [ RES MEM : 6.236530 GB ] [ VIRT MEM : 17.854084 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 954.425132 s ] [ CPU TIME: 52790.116319 s ] <<<<< .. + +* Number of generators 1310335 + +.. >>>>> [ RES MEM : 6.236530 GB ] [ VIRT MEM : 17.854084 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 954.428185 s ] [ CPU TIME: 52790.119307 s ] <<<<< .. + +* Number of selectors 1310335 +* Number of comb teeth 91 +* pt2_n_tasks_max 132 +* Number of tasks 1382233 +* Number of fragmented tasks 4310 +* Number of threads for PT2 72 +* Memory (Gb) 2.655410436727107 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0352257221 0.135E-02 0.1667442780 0.0061295890 118.1498 + 4 -229.0347430857 0.108E-02 0.1631181898 0.0060679246 119.1557 + 5 -229.0348861046 0.845E-03 0.1637660834 0.0061035766 122.1558 + 6 -229.0350205824 0.689E-03 0.1648395336 0.0061139588 130.3712 + 7 -229.0349380024 0.584E-03 0.1639220159 0.0061094498 133.2807 + 9 -229.0346018524 0.491E-03 0.1617929405 0.0060527183 141.4768 + 12 -229.0350986576 0.476E-03 0.1651921190 0.0061277335 144.9118 + 14 -229.0348543437 0.435E-03 0.1633947190 0.0060943219 146.1498 + 18 -229.0348290109 0.373E-03 0.1632333039 0.0060899431 151.3663 + 19 -229.0348778232 0.356E-03 0.1636781862 0.0060934356 156.0977 + 20 -229.0348957175 0.344E-03 0.1639273691 0.0060913591 158.2537 + 24 -229.0350110807 0.286E-03 0.1648780563 0.0061045322 162.9643 + 28 -229.0350362876 0.259E-03 0.1649544629 0.0061107111 191.4404 + 29 -229.0350321329 0.250E-03 0.1649083960 0.0061112444 198.6037 + 31 -229.0350763886 0.282E-03 0.1652849752 0.0061159552 207.9127 + 39 -229.0350529221 0.263E-03 0.1652789931 0.0061097675 209.2316 + 43 -229.0349497379 0.241E-03 0.1647661722 0.0060897570 211.1457 + 46 -229.0349910289 0.227E-03 0.1650779308 0.0060951613 215.2310 + 54 -229.0349032358 0.209E-03 0.1643830666 0.0060841824 217.5378 + 56 -229.0349463503 0.207E-03 0.1646848939 0.0060903317 219.3737 + 58 -229.0349303612 0.200E-03 0.1646174245 0.0060866179 227.6530 + 64 -229.0349250246 0.186E-03 0.1646633909 0.0060828771 239.9727 + 80 -229.0347778000 0.164E-03 0.1637689170 0.0060583962 241.9182 + 82 -229.0347691467 0.161E-03 0.1636453139 0.0060585871 248.3717 + 84 -229.0347492829 0.158E-03 0.1635081135 0.0060556616 250.6737 + 85 -229.0347012904 0.154E-03 0.1631247095 0.0060500092 252.8387 + 87 -229.0346709559 0.153E-03 0.1628997138 0.0060457202 259.7687 + 89 -229.0346514158 0.150E-03 0.1627580193 0.0060428433 270.7747 + 106 -229.0345583947 0.134E-03 0.1618865898 0.0060353490 272.8499 + 111 -229.0345889778 0.130E-03 0.1620900655 0.0060400525 282.4617 + 126 -229.0345483600 0.120E-03 0.1617841815 0.0060346108 302.6337 + 148 -229.0345327753 0.110E-03 0.1616668344 0.0060326860 305.9107 + 151 -229.0345143892 0.109E-03 0.1615289198 0.0060301302 307.1948 + 154 -229.0345880400 0.106E-03 0.1620689354 0.0060403768 310.6604 + 157 -229.0345996442 0.104E-03 0.1621481920 0.0060419842 314.6411 + 161 -229.0345801152 0.102E-03 0.1620150821 0.0060388802 317.9317 + 168 -229.0345989013 0.986E-04 0.1621416178 0.0060417082 319.0617 + 170 -229.0346008366 0.988E-04 0.1621524295 0.0060421581 325.6951 + 172 -229.0345919882 0.983E-04 0.1620957377 0.0060407249 344.5787 + 193 -229.0346025141 0.958E-04 0.1621872462 0.0060419217 347.8687 + 221 -229.0345808174 0.873E-04 0.1620151972 0.0060393293 355.0708 + 229 -229.0345991973 0.868E-04 0.1621352207 0.0060421210 374.9691 + 254 -229.0345928562 0.800E-04 0.1620869191 0.0060414498 376.3937 + 267 -229.0345836785 0.740E-04 0.1619778292 0.0060411363 388.5317 + 275 -229.0345856255 0.731E-04 0.1619992057 0.0060411957 392.5417 + 302 -229.0346113111 0.695E-04 0.1621682576 0.0060453011 406.5158 + 333 -229.0345610258 0.635E-04 0.1618379796 0.0060372979 412.1698 + 351 -229.0345501419 0.616E-04 0.1617786281 0.0060354103 421.3947 + 359 -229.0345848912 0.600E-04 0.1620053503 0.0060411867 425.6700 + 360 -229.0345856585 0.598E-04 0.1620135928 0.0060412356 430.6846 + 361 -229.0345880502 0.597E-04 0.1620335185 0.0060415405 443.6488 + 423 -229.0345735017 0.513E-04 0.1618518281 0.0060412578 448.6050 + 462 -229.0346002277 0.479E-04 0.1620167512 0.0060456513 451.2704 + 473 -229.0346073961 0.455E-04 0.1620743409 0.0060466830 457.8384 + 520 -229.0346048449 0.428E-04 0.1620357615 0.0060467383 459.8667 + 544 -229.0346118994 0.422E-04 0.1620830092 0.0060478873 461.0606 + 547 -229.0346117863 0.420E-04 0.1620745779 0.0060480388 466.0575 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 6.509418 GB ] [ VIRT MEM : 18.204548 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1427.777582 s ] [ CPU TIME: 86270.535612 s ] <<<<< .. + +* Number of generators 1310335 + +.. >>>>> [ RES MEM : 6.509418 GB ] [ VIRT MEM : 18.204548 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1427.780653 s ] [ CPU TIME: 86270.538620 s ] <<<<< .. + +* Number of selectors 1310335 +* Number of comb teeth 91 +* pt2_n_tasks_max 132 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9406092381856613 + +Summary at N_det = 1310720 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.00411576 +# PT2 -0.03049885 0.00004173 +# rPT2 -0.03031549 0.00004148 +# +# E+PT2 -229.03461462 0.00004173 +# E+rPT2 -229.03443125 0.00004148 +# ============ ============================= + + N_det = 1310720 + N_states = 1 + + * State 1 + < S^2 > = 3.517693995282023E-003 + E = -229.004115763481 + Variance = 0.162092650013956 + PT norm = 7.777198239122762E-002 + PT2 = -3.049885322427845E-002 + rPT2 = -3.031549054826245E-002 + E+PT2 = -229.034614616705 +/- 4.173362546236384E-005 + E+rPT2 = -229.034431254029 +/- 4.148271802042314E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.861027478065 + Vee = 238.470046143508 + Vecp = 0.000000000000000E+000 + T = 229.278635792287 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0312 -229.03693443 + -0.0328 -229.04082951 + -0.0359 -229.04178975 + -0.0407 -229.04265784 + -0.0481 -229.04237695 + -0.0575 -229.04289660 + -0.0702 -229.04300100 + =========== =================== + +* Number of unique beta determinants 283886 +* Number of unique alpha determinants 287335 + +.. >>>>> [ RES MEM : 6.202194 GB ] [ VIRT MEM : 17.821869 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1460.368769 s ] [ CPU TIME: 88315.236707 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 2621440 +* Number of threads for diagonalization 72 +* Memory(Gb) 4.171380221843719 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.0041157648 0.003518 0.967E-04 + 2 -229.0046115559 0.003636 0.285E-05 + 3 -229.0046194813 0.003645 0.749E-06 + 4 -229.0046200759 0.003649 0.535E-07 + 5 -229.0046201882 0.003651 0.786E-08 + 6 -229.0046202074 0.003651 0.158E-08 + 7 -229.0046202116 0.003651 0.290E-09 + 8 -229.0046202124 0.003651 0.566E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 8.911171 GB ] [ VIRT MEM : 21.243168 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1694.742235 s ] [ CPU TIME: 102996.535031 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 6.684608 GB ] [ VIRT MEM : 18.312004 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1694.947139 s ] [ CPU TIME: 103003.150458 s ] <<<<< .. + +* Energy of state 1 -229.0046202123951 +* S^2 of state 1 0.3651343637658288E-02 +* Saved determinants 2621440 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 5.983711 GB ] [ VIRT MEM : 17.573654 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1716.481983 s ] [ CPU TIME: 103269.200249 s ] <<<<< .. + +* Number of generators 2619164 + +.. >>>>> [ RES MEM : 5.983711 GB ] [ VIRT MEM : 17.573654 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1716.488053 s ] [ CPU TIME: 103269.637322 s ] <<<<< .. + +* Number of selectors 2619164 +* Number of comb teeth 92 +* pt2_n_tasks_max 262 +* PT2 Energy denominator -229.0046202123951 + +.. >>>>> [ RES MEM : 6.252842 GB ] [ VIRT MEM : 17.803646 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1718.862843 s ] [ CPU TIME: 103369.798054 s ] <<<<< .. + +* Number of generators 2619164 + +.. >>>>> [ RES MEM : 6.252842 GB ] [ VIRT MEM : 17.803646 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1718.868595 s ] [ CPU TIME: 103369.803735 s ] <<<<< .. + +* Number of selectors 2619164 +* Number of comb teeth 92 +* pt2_n_tasks_max 262 +* Number of tasks 2742500 +* Number of fragmented tasks 4106 +* Number of threads for PT2 72 +* Memory (Gb) 2.754231938272715 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0354511249 0.591E-03 0.1655367581 0.0060660412 241.5378 + 4 -229.0345548511 0.105E-02 0.1593611924 0.0059270333 255.8232 + 6 -229.0341966872 0.698E-03 0.1564982729 0.0058861529 325.3887 + 15 -229.0346336622 0.459E-03 0.1594663683 0.0059539373 372.5420 + 24 -229.0352138570 0.363E-03 0.1637861273 0.0060311759 382.4187 + 28 -229.0352039342 0.312E-03 0.1638328034 0.0060263792 425.2693 + 30 -229.0352559844 0.298E-03 0.1639425003 0.0060404189 440.5987 + 32 -229.0352898696 0.290E-03 0.1640684503 0.0060483077 465.2432 + 36 -229.0350881686 0.287E-03 0.1625823913 0.0060209230 476.3127 + 69 -229.0349784051 0.192E-03 0.1618085936 0.0060067026 483.8100 + 76 -229.0349955530 0.189E-03 0.1618757660 0.0060103372 487.9947 + 80 -229.0350644756 0.184E-03 0.1623215320 0.0060210599 491.9267 + 82 -229.0350520561 0.182E-03 0.1622651375 0.0060182936 519.4075 + 93 -229.0349995673 0.171E-03 0.1619170315 0.0060098020 523.6678 + 97 -229.0349680707 0.165E-03 0.1617391471 0.0060044420 528.9198 + 103 -229.0349627124 0.163E-03 0.1616857099 0.0060041121 536.9728 + 104 -229.0349677777 0.162E-03 0.1617155116 0.0060047992 546.4531 + 107 -229.0349838506 0.158E-03 0.1618255576 0.0060073690 547.5466 + 110 -229.0350172745 0.163E-03 0.1620118063 0.0060133936 552.2727 + 113 -229.0350021296 0.162E-03 0.1619755887 0.0060095746 553.8567 + 114 -229.0349916775 0.160E-03 0.1619094351 0.0060080134 556.0800 + 120 -229.0349219041 0.155E-03 0.1614362344 0.0059970985 577.8718 + 127 -229.0348987683 0.157E-03 0.1612644666 0.0059938825 582.5517 + 128 -229.0349138261 0.157E-03 0.1613605226 0.0059962204 588.0397 + 136 -229.0349058835 0.150E-03 0.1612968605 0.0059952223 592.5368 + 138 -229.0349271730 0.150E-03 0.1614626238 0.0059978689 595.9297 + 142 -229.0349337175 0.146E-03 0.1615034417 0.0059988792 597.1578 + 143 -229.0349318548 0.145E-03 0.1615079404 0.0059982432 598.3767 + 144 -229.0349359153 0.144E-03 0.1615179648 0.0059992090 619.0749 + 154 -229.0349168850 0.131E-03 0.1613989292 0.0059960009 625.0617 + 161 -229.0348845619 0.128E-03 0.1612236548 0.0059902339 631.1872 + 165 -229.0348805082 0.125E-03 0.1612369737 0.0059886971 634.4688 + 170 -229.0348647502 0.124E-03 0.1611075115 0.0059868563 646.0037 + 175 -229.0348674523 0.119E-03 0.1611478494 0.0059866131 653.5197 + 186 -229.0348908322 0.117E-03 0.1613497543 0.0059893759 654.9377 + 190 -229.0348878297 0.115E-03 0.1613374314 0.0059887068 667.1422 + 201 -229.0348598273 0.109E-03 0.1611511370 0.0059843575 694.2131 + 218 -229.0348462282 0.103E-03 0.1610896440 0.0059815515 710.4227 + 234 -229.0347766403 0.896E-04 0.1606080301 0.0059712495 712.4347 + 235 -229.0347712833 0.894E-04 0.1605654261 0.0059706047 720.7942 + 251 -229.0347528925 0.832E-04 0.1603994631 0.0059688424 726.0326 + 253 -229.0347486237 0.826E-04 0.1603773062 0.0059680709 733.9577 + 267 -229.0347137208 0.770E-04 0.1601700174 0.0059618297 741.3493 + 278 -229.0346914971 0.724E-04 0.1599692153 0.0059594327 743.8086 + 284 -229.0347183451 0.724E-04 0.1601969881 0.0059624452 754.7557 + 297 -229.0347107101 0.682E-04 0.1601682459 0.0059608350 759.9477 + 299 -229.0347110543 0.678E-04 0.1601669927 0.0059609771 766.5307 + 302 -229.0347006605 0.675E-04 0.1600921269 0.0059595027 786.3647 + 338 -229.0347077290 0.634E-04 0.1601116093 0.0059613243 791.4087 + 348 -229.0346934943 0.620E-04 0.1600010356 0.0059594434 795.9898 + 350 -229.0347032969 0.620E-04 0.1600697481 0.0059609196 802.8257 + 359 -229.0347080541 0.608E-04 0.1601034923 0.0059615787 814.9917 + 378 -229.0347154780 0.551E-04 0.1601928993 0.0059616519 839.1947 + 379 -229.0347134853 0.550E-04 0.1601787062 0.0059613574 847.6682 + 439 -229.0347538129 0.509E-04 0.1604610037 0.0059674574 852.0345 + 459 -229.0347570109 0.501E-04 0.1604837365 0.0059679018 869.0867 + 488 -229.0347751464 0.487E-04 0.1606196350 0.0059703705 873.5625 + 503 -229.0347700586 0.467E-04 0.1605536390 0.0059702702 882.6160 + 522 -229.0347653121 0.459E-04 0.1605217590 0.0059695289 885.5219 + 544 -229.0347609544 0.449E-04 0.1604928800 0.0059687860 887.1986 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 7.119659 GB ] [ VIRT MEM : 18.877293 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2617.739724 s ] [ CPU TIME: 167030.833567 s ] <<<<< .. + +* Number of generators 2619164 + +.. >>>>> [ RES MEM : 7.119659 GB ] [ VIRT MEM : 18.877293 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2617.745634 s ] [ CPU TIME: 167030.839405 s ] <<<<< .. + +* Number of selectors 2619164 +* Number of comb teeth 92 +* pt2_n_tasks_max 262 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9413139978701354 + +Summary at N_det = 2621440 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.00462021 +# PT2 -0.03014364 0.00004433 +# rPT2 -0.02996477 0.00004407 +# +# E+PT2 -229.03476385 0.00004433 +# E+rPT2 -229.03458499 0.00004407 +# ============ ============================= + + N_det = 2621440 + N_states = 1 + + * State 1 + < S^2 > = 3.651343637658288E-003 + E = -229.004620212395 + Variance = 0.160513005405594 + PT norm = 7.726027024841314E-002 + PT2 = -3.014363834102517E-002 + rPT2 = -2.996477412874625E-002 + E+PT2 = -229.034763850736 +/- 4.433180232325379E-005 + E+rPT2 = -229.034584986524 +/- 4.406874937616936E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.860595135114 + Vee = 238.468030529010 + Vecp = 0.000000000000000E+000 + T = 229.279714614920 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0303 -229.04771970 + -0.0312 -229.03946575 + -0.0328 -229.04109500 + -0.0359 -229.04178398 + -0.0407 -229.04257002 + -0.0481 -229.04235035 + -0.0575 -229.04283743 + =========== =================== + +* Number of unique beta determinants 519231 +* Number of unique alpha determinants 529429 + +.. >>>>> [ RES MEM : 6.591873 GB ] [ VIRT MEM : 18.427807 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2705.652976 s ] [ CPU TIME: 172808.973527 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5242099 +* Number of threads for diagonalization 72 +* Memory(Gb) 8.232220865786076 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.0046192050 0.003652 0.631E-04 + 2 -229.0049545657 0.003749 0.154E-05 + 3 -229.0049594980 0.003759 0.345E-06 + 4 -229.0049597812 0.003762 0.271E-07 + 5 -229.0049598311 0.003762 0.253E-08 + 6 -229.0049598378 0.003763 0.465E-09 + 7 -229.0049598390 0.003763 0.889E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 11.309383 GB ] [ VIRT MEM : 24.790611 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3267.657703 s ] [ CPU TIME: 210424.075206 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 6.935204 GB ] [ VIRT MEM : 18.774971 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3268.054399 s ] [ CPU TIME: 210430.974406 s ] <<<<< .. + +* Energy of state 1 -229.0049598389617 +* S^2 of state 1 0.3762851574026850E-02 +* Saved determinants 5242099 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 6.675964 GB ] [ VIRT MEM : 18.039886 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3309.648482 s ] [ CPU TIME: 210874.743007 s ] <<<<< .. + +* Number of generators 5235992 + +.. >>>>> [ RES MEM : 6.675964 GB ] [ VIRT MEM : 18.039886 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3309.660242 s ] [ CPU TIME: 210875.587964 s ] <<<<< .. + +* Number of selectors 5235992 +* Number of comb teeth 92 +* pt2_n_tasks_max 524 +* PT2 Energy denominator -229.0049598389617 + +.. >>>>> [ RES MEM : 7.019405 GB ] [ VIRT MEM : 18.306499 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3313.233569 s ] [ CPU TIME: 211033.915483 s ] <<<<< .. + +* Number of generators 5235992 + +.. >>>>> [ RES MEM : 7.019405 GB ] [ VIRT MEM : 18.306499 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3313.244751 s ] [ CPU TIME: 211033.926580 s ] <<<<< .. + +* Number of selectors 5235992 +* Number of comb teeth 92 +* pt2_n_tasks_max 524 +* Number of tasks 5449331 +* Number of fragmented tasks 4135 +* Number of threads for PT2 72 +* Memory (Gb) 2.951891041696072 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0340696727 0.518E-03 0.1540744638 0.0057802872 460.1145 + 4 -229.0332521112 0.941E-03 0.1483617350 0.0056679590 506.8229 + 5 -229.0330726029 0.750E-03 0.1469020510 0.0056494554 549.8064 + 6 -229.0339341746 0.111E-02 0.1532430649 0.0057672291 601.5093 + 8 -229.0340916747 0.792E-03 0.1540369856 0.0058005292 628.6244 + 9 -229.0345647864 0.849E-03 0.1576731636 0.0058629561 692.3194 + 14 -229.0348132919 0.584E-03 0.1595633395 0.0058964022 704.4116 + 15 -229.0349670346 0.563E-03 0.1603676810 0.0059268427 767.7374 + 25 -229.0347011197 0.394E-03 0.1587379884 0.0058826691 792.5315 + 27 -229.0347917075 0.371E-03 0.1593334732 0.0058955399 867.7437 + 28 -229.0346874701 0.372E-03 0.1586255288 0.0058793446 933.9923 + 55 -229.0347434615 0.197E-03 0.1586727804 0.0058950001 945.2166 + 60 -229.0346946054 0.197E-03 0.1583611604 0.0058866004 963.5244 + 61 -229.0346685323 0.196E-03 0.1581717726 0.0058829264 968.5987 + 62 -229.0346721194 0.193E-03 0.1582212863 0.0058829526 971.2964 + 67 -229.0347701243 0.186E-03 0.1589475226 0.0058968666 974.2845 + 68 -229.0347592335 0.184E-03 0.1588650704 0.0058952363 994.3964 + 73 -229.0347275717 0.177E-03 0.1586752252 0.0058896787 1007.0954 + 78 -229.0347587557 0.170E-03 0.1589187121 0.0058934950 1008.6168 + 80 -229.0347893979 0.168E-03 0.1591268526 0.0058983381 1017.2156 + 82 -229.0347892568 0.164E-03 0.1591077352 0.0058986911 1022.9864 + 84 -229.0348375488 0.166E-03 0.1594204559 0.0059064024 1040.3074 + 89 -229.0348371992 0.156E-03 0.1593472719 0.0059077691 1053.0797 + 91 -229.0348215627 0.154E-03 0.1592601428 0.0059050929 1057.7369 + 92 -229.0348293739 0.154E-03 0.1593471142 0.0059055489 1060.5378 + 93 -229.0348197184 0.152E-03 0.1592986468 0.0059036181 1077.1995 + 103 -229.0348736014 0.145E-03 0.1596368022 0.0059126655 1089.5176 + 105 -229.0348737338 0.147E-03 0.1596524732 0.0059123547 1100.9009 + 109 -229.0348826506 0.142E-03 0.1596846745 0.0059145506 1116.0369 + 115 -229.0348571869 0.137E-03 0.1594958051 0.0059110923 1125.2115 + 118 -229.0348543250 0.134E-03 0.1594509248 0.0059113462 1134.0924 + 122 -229.0348393169 0.132E-03 0.1593671608 0.0059085565 1138.5884 + 123 -229.0348397693 0.131E-03 0.1593709486 0.0059085373 1139.9545 + 125 -229.0348453911 0.129E-03 0.1593956896 0.0059096387 1149.3162 + 126 -229.0348704325 0.130E-03 0.1595781211 0.0059131625 1169.7515 + 134 -229.0348743691 0.124E-03 0.1595983087 0.0059140300 1171.3427 + 137 -229.0348804918 0.119E-03 0.1596870067 0.0059138579 1177.6815 + 138 -229.0348823887 0.119E-03 0.1596907620 0.0059142868 1181.3805 + 142 -229.0348566494 0.117E-03 0.1595076254 0.0059105288 1198.4982 + 144 -229.0348792014 0.116E-03 0.1596793720 0.0059136845 1204.8485 + 146 -229.0348613119 0.115E-03 0.1595472983 0.0059112539 1208.7767 + 148 -229.0348673244 0.114E-03 0.1595754645 0.0059125402 1218.6158 + 151 -229.0348552995 0.112E-03 0.1594890023 0.0059109185 1225.0981 + 154 -229.0348467213 0.115E-03 0.1594204301 0.0059099632 1232.4185 + 160 -229.0348763327 0.117E-03 0.1596354197 0.0059142771 1235.9226 + 162 -229.0348973750 0.116E-03 0.1597624434 0.0059178716 1238.6415 + 163 -229.0349078539 0.116E-03 0.1598355745 0.0059193650 1243.1635 + 165 -229.0348860214 0.116E-03 0.1596913714 0.0059158797 1254.6389 + 168 -229.0348891926 0.116E-03 0.1597340720 0.0059160003 1259.0654 + 169 -229.0348915571 0.116E-03 0.1597460382 0.0059164764 1267.1085 + 172 -229.0348831983 0.115E-03 0.1596831468 0.0059153232 1271.6575 + 174 -229.0349023438 0.115E-03 0.1598327578 0.0059177569 1274.0854 + 175 -229.0349000008 0.114E-03 0.1598182032 0.0059173906 1281.1116 + 181 -229.0349252470 0.113E-03 0.1599542309 0.0059220134 1282.7656 + 182 -229.0349301825 0.112E-03 0.1599920049 0.0059226752 1294.4231 + 184 -229.0349324032 0.112E-03 0.1600245812 0.0059226067 1295.8624 + 190 -229.0349183094 0.109E-03 0.1599390082 0.0059201983 1300.5124 + 192 -229.0349017481 0.109E-03 0.1598210184 0.0059178985 1312.3845 + 193 -229.0348958725 0.109E-03 0.1597812884 0.0059170254 1322.4544 + 201 -229.0348566969 0.102E-03 0.1594495380 0.0059129624 1325.7625 + 203 -229.0348435123 0.102E-03 0.1593508019 0.0059111768 1334.6275 + 214 -229.0348627492 0.956E-04 0.1594814207 0.0059143150 1340.1447 + 215 -229.0348532225 0.956E-04 0.1594190493 0.0059128009 1347.2486 + 221 -229.0348304364 0.918E-04 0.1591847979 0.0059112745 1360.0699 + 228 -229.0348247131 0.903E-04 0.1591479335 0.0059104322 1366.5806 + 234 -229.0348225021 0.889E-04 0.1591629615 0.0059093152 1374.6366 + 239 -229.0348426503 0.861E-04 0.1592636822 0.0059135137 1386.5384 + 241 -229.0348346996 0.857E-04 0.1592031241 0.0059124353 1391.7454 + 249 -229.0348564823 0.843E-04 0.1593864171 0.0059148709 1400.0224 + 258 -229.0348463272 0.820E-04 0.1592962443 0.0059138102 1405.7835 + 264 -229.0348413846 0.812E-04 0.1592681482 0.0059129185 1442.8684 + 288 -229.0348517729 0.754E-04 0.1593482604 0.0059144054 1445.2694 + 290 -229.0348509194 0.750E-04 0.1593411001 0.0059143336 1454.0121 + 306 -229.0348398630 0.707E-04 0.1592601594 0.0059127338 1455.4244 + 308 -229.0348346507 0.704E-04 0.1592153188 0.0059121524 1459.0732 + 310 -229.0348458820 0.705E-04 0.1592994918 0.0059137183 1465.9514 + 311 -229.0348437347 0.703E-04 0.1592905659 0.0059132674 1483.7484 + 317 -229.0348466522 0.698E-04 0.1593144697 0.0059136248 1489.7025 + 332 -229.0348864232 0.683E-04 0.1595492009 0.0059203242 1493.8458 + 342 -229.0348913700 0.664E-04 0.1595735960 0.0059213424 1496.5734 + 343 -229.0348896453 0.662E-04 0.1595625499 0.0059210753 1513.2964 + 352 -229.0348913342 0.652E-04 0.1595790499 0.0059212693 1523.1384 + 362 -229.0348990259 0.642E-04 0.1596203718 0.0059226875 1527.7105 + 378 -229.0348726460 0.603E-04 0.1594187666 0.0059190926 1533.0837 + 384 -229.0348707219 0.599E-04 0.1594145393 0.0059186161 1540.5655 + 388 -229.0348757341 0.594E-04 0.1594385660 0.0059195872 1542.6315 + 389 -229.0348780014 0.593E-04 0.1594502642 0.0059200095 1558.1979 + 417 -229.0348529529 0.529E-04 0.1592791547 0.0059162794 1572.0043 + 432 -229.0348610731 0.522E-04 0.1593183285 0.0059179432 1587.7741 + 446 -229.0348617645 0.513E-04 0.1593265404 0.0059179745 1590.4883 + 452 -229.0348543727 0.508E-04 0.1592843178 0.0059166315 1591.7106 + 454 -229.0348569575 0.506E-04 0.1593067593 0.0059169126 1592.8744 + 455 -229.0348605514 0.507E-04 0.1593284905 0.0059175191 1602.1897 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 7.735275 GB ] [ VIRT MEM : 19.046673 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4935.275620 s ] [ CPU TIME: 325788.991832 s ] <<<<< .. + +* Number of generators 5235992 + +.. >>>>> [ RES MEM : 7.735275 GB ] [ VIRT MEM : 19.046673 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4935.287069 s ] [ CPU TIME: 325789.003195 s ] <<<<< .. + +* Number of selectors 5235992 +* Number of comb teeth 92 +* pt2_n_tasks_max 524 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9418009258897916 + +Summary at N_det = 5242099 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.00495984 +# PT2 -0.02989765 0.00005029 +# rPT2 -0.02972177 0.00005000 +# +# E+PT2 -229.03485749 0.00005029 +# E+rPT2 -229.03468161 0.00005000 +# ============ ============================= + + N_det = 5242099 + N_states = 1 + + * State 1 + < S^2 > = 3.762851574026850E-003 + E = -229.004959838962 + Variance = 0.159299046260363 + PT norm = 7.692373807514660E-002 + PT2 = -2.989764628629143E-002 + rPT2 = -2.972177477332424E-002 + E+PT2 = -229.034857485248 +/- 5.029087823759035E-005 + E+rPT2 = -229.034681613735 +/- 4.999504448668571E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.860924246840 + Vee = 238.467048217090 + Vecp = 0.000000000000000E+000 + T = 229.280686412000 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0300 -229.04650030 + -0.0303 -229.04725203 + -0.0312 -229.04084442 + -0.0328 -229.04143217 + -0.0359 -229.04187117 + -0.0407 -229.04256119 + -0.0481 -229.04235870 + =========== =================== + +* Number of unique beta determinants 892185 +* Number of unique alpha determinants 928439 + +.. >>>>> [ RES MEM : 8.474236 GB ] [ VIRT MEM : 20.440723 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5214.442835 s ] [ CPU TIME: 344933.833259 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 10462547 +* Number of threads for diagonalization 72 +* Memory(Gb) 16.12028829753399 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.0049433180 0.003768 0.667E-04 + 2 -229.0052843109 0.003873 0.190E-05 + 3 -229.0052902130 0.003884 0.277E-06 + 4 -229.0052905635 0.003887 0.450E-07 + 5 -229.0052906185 0.003887 0.348E-08 + 6 -229.0052906277 0.003887 0.556E-09 + 7 -229.0052906292 0.003887 0.970E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 17.280174 GB ] [ VIRT MEM : 32.510368 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7082.273825 s ] [ CPU TIME: 473700.804425 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.549679 GB ] [ VIRT MEM : 20.504982 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7083.075134 s ] [ CPU TIME: 473707.617248 s ] <<<<< .. + +* Energy of state 1 -229.0052906292084 +* S^2 of state 1 0.3887321552994409E-02 +* Saved determinants 10462547 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.313728 GB ] [ VIRT MEM : 19.289986 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7166.066749 s ] [ CPU TIME: 474546.557731 s ] <<<<< .. + +* Number of generators 10440204 + +.. >>>>> [ RES MEM : 8.313728 GB ] [ VIRT MEM : 19.289986 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7166.089697 s ] [ CPU TIME: 474548.206060 s ] <<<<< .. + +* Number of selectors 10440204 +* Number of comb teeth 92 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -229.0052906292084 + +.. >>>>> [ RES MEM : 9.208076 GB ] [ VIRT MEM : 20.030228 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7172.543410 s ] [ CPU TIME: 474823.530576 s ] <<<<< .. + +* Number of generators 10440204 + +.. >>>>> [ RES MEM : 9.208076 GB ] [ VIRT MEM : 20.030228 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7172.565311 s ] [ CPU TIME: 474823.552367 s ] <<<<< .. + +* Number of selectors 10440204 +* Number of comb teeth 92 +* pt2_n_tasks_max 638 +* Number of tasks 10694496 +* Number of fragmented tasks 4159 +* Number of threads for PT2 72 +* Memory (Gb) 3.330400672107935 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0365930110 0.630E-03 0.1676991456 0.0061576389 769.4351 + 4 -229.0365745895 0.449E-03 0.1687681673 0.0061235647 791.3053 + 5 -229.0362700106 0.471E-03 0.1660423110 0.0060992385 954.5173 + 7 -229.0360020119 0.433E-03 0.1655100330 0.0060230287 985.5194 + 8 -229.0356800630 0.517E-03 0.1633489886 0.0059759708 1038.2664 + 9 -229.0353644629 0.545E-03 0.1609333592 0.0059353194 1072.7726 + 10 -229.0353816920 0.488E-03 0.1613076958 0.0059341127 1086.8022 + 11 -229.0357177692 0.561E-03 0.1637027755 0.0059805536 1094.1173 + 12 -229.0356673256 0.514E-03 0.1632637013 0.0059741882 1122.7823 + 13 -229.0356149180 0.472E-03 0.1627926033 0.0059689066 1126.0011 + 14 -229.0355300848 0.446E-03 0.1621827137 0.0059565669 1135.9693 + 15 -229.0353088250 0.470E-03 0.1605744990 0.0059263773 1173.9442 + 17 -229.0352856466 0.418E-03 0.1603544235 0.0059235533 1206.5322 + 18 -229.0352862843 0.402E-03 0.1603608161 0.0059231741 1212.0953 + 19 -229.0351243169 0.406E-03 0.1593842959 0.0058954394 1231.0413 + 20 -229.0351344867 0.386E-03 0.1593503185 0.0058992212 1260.6104 + 21 -229.0351695845 0.377E-03 0.1596349593 0.0059027636 1264.6301 + 23 -229.0351253667 0.345E-03 0.1593751857 0.0058934570 1290.6326 + 25 -229.0350699357 0.318E-03 0.1588133156 0.0058895164 1292.6683 + 27 -229.0350312708 0.289E-03 0.1585156071 0.0058843538 1354.1003 + 28 -229.0349963363 0.290E-03 0.1582249221 0.0058795445 1395.3716 + 29 -229.0349781181 0.285E-03 0.1580172182 0.0058788359 1445.2503 + 41 -229.0350791090 0.242E-03 0.1585179664 0.0058978548 1471.8646 + 43 -229.0350180920 0.235E-03 0.1581843925 0.0058871271 1502.5345 + 45 -229.0350500799 0.227E-03 0.1583930156 0.0058914518 1506.8503 + 49 -229.0350261381 0.216E-03 0.1582886722 0.0058870081 1518.2137 + 50 -229.0349925672 0.215E-03 0.1580643250 0.0058819080 1527.1092 + 51 -229.0349893476 0.211E-03 0.1580233605 0.0058816772 1530.3967 + 52 -229.0349966282 0.212E-03 0.1579944751 0.0058848471 1545.1393 + 55 -229.0350117000 0.203E-03 0.1581549041 0.0058864877 1570.2874 + 61 -229.0350058256 0.185E-03 0.1581290039 0.0058848686 1577.3760 + 62 -229.0350154220 0.182E-03 0.1582477965 0.0058851512 1581.0713 + 63 -229.0349764506 0.184E-03 0.1579738099 0.0058794421 1592.7917 + 65 -229.0350096990 0.180E-03 0.1583474431 0.0058810368 1607.4084 + 69 -229.0350351341 0.178E-03 0.1584900970 0.0058851111 1618.6238 + 71 -229.0349838753 0.177E-03 0.1581621969 0.0058763017 1634.0270 + 75 -229.0349655648 0.178E-03 0.1580453252 0.0058733778 1648.9072 + 78 -229.0349525480 0.173E-03 0.1579465438 0.0058717111 1654.0443 + 80 -229.0349630239 0.161E-03 0.1580531430 0.0058721217 1670.5072 + 81 -229.0349795378 0.160E-03 0.1581516221 0.0058750949 1672.7560 + 83 -229.0349895049 0.157E-03 0.1581946216 0.0058770756 1675.1879 + 84 -229.0349774735 0.155E-03 0.1581141348 0.0058751615 1711.2583 + 91 -229.0349809385 0.149E-03 0.1581222035 0.0058762410 1714.0079 + 93 -229.0350193969 0.149E-03 0.1583943790 0.0058818127 1721.5110 + 96 -229.0349799576 0.149E-03 0.1581246128 0.0058756955 1740.1669 + 98 -229.0349774951 0.146E-03 0.1581594887 0.0058741926 1744.9593 + 103 -229.0349498691 0.143E-03 0.1579637156 0.0058704585 1763.0403 + 104 -229.0349786517 0.145E-03 0.1581337887 0.0058754492 1785.1823 + 105 -229.0349656722 0.144E-03 0.1580684532 0.0058729786 1803.2422 + 114 -229.0349405377 0.137E-03 0.1578927588 0.0058691584 1831.3683 + 120 -229.0349332740 0.133E-03 0.1579068907 0.0058666916 1842.2363 + 123 -229.0348905389 0.132E-03 0.1576154770 0.0058601440 1856.7673 + 125 -229.0349027747 0.130E-03 0.1577168226 0.0058616898 1863.1842 + 128 -229.0349024972 0.128E-03 0.1577521694 0.0058608930 1881.9606 + 131 -229.0349075812 0.126E-03 0.1577691327 0.0058619985 1893.2206 + 134 -229.0349337501 0.124E-03 0.1580184257 0.0058642611 1896.1234 + 136 -229.0349850699 0.132E-03 0.1584050390 0.0058712227 1902.5283 + 138 -229.0349853396 0.131E-03 0.1584087345 0.0058712031 1910.7585 + 144 -229.0349921714 0.126E-03 0.1584066071 0.0058736253 1933.0073 + 149 -229.0350307479 0.123E-03 0.1586625857 0.0058795263 1964.1961 + 153 -229.0350264534 0.121E-03 0.1586169440 0.0058793489 1967.3233 + 156 -229.0350674898 0.123E-03 0.1589434847 0.0058844233 1998.0525 + 163 -229.0350329833 0.120E-03 0.1587477260 0.0058782160 2010.2003 + 170 -229.0350486745 0.125E-03 0.1588663092 0.0058803359 2023.5692 + 172 -229.0350348519 0.124E-03 0.1587757749 0.0058781023 2054.5302 + 176 -229.0350341936 0.122E-03 0.1587911173 0.0058774709 2060.0812 + 181 -229.0350528164 0.117E-03 0.1589630809 0.0058792533 2077.9613 + 182 -229.0350538853 0.117E-03 0.1589584455 0.0058796548 2083.4103 + 188 -229.0350763690 0.114E-03 0.1591237564 0.0058827717 2111.6662 + 198 -229.0351042289 0.113E-03 0.1593349086 0.0058865348 2118.4372 + 201 -229.0350916123 0.112E-03 0.1592659105 0.0058842796 2130.4433 + 210 -229.0350685532 0.109E-03 0.1590936557 0.0058810962 2142.3632 + 214 -229.0350768276 0.107E-03 0.1591562188 0.0058822243 2146.9193 + 216 -229.0350735897 0.107E-03 0.1591353025 0.0058816678 2149.9093 + 217 -229.0350856338 0.107E-03 0.1592043428 0.0058837490 2157.6211 + 218 -229.0350869974 0.106E-03 0.1592117621 0.0058840148 2181.1813 + 228 -229.0350670978 0.105E-03 0.1590604212 0.0058817943 2198.6211 + 229 -229.0350550548 0.105E-03 0.1589794616 0.0058799237 2203.4532 + 231 -229.0350506197 0.104E-03 0.1589607004 0.0058789951 2204.5792 + 235 -229.0350365715 0.103E-03 0.1588581047 0.0058769859 2216.9083 + 244 -229.0350549782 0.963E-04 0.1589204207 0.0058814598 2241.2733 + 258 -229.0350472906 0.930E-04 0.1588378987 0.0058808169 2244.2563 + 263 -229.0350316595 0.893E-04 0.1587379345 0.0058782100 2275.8331 + 272 -229.0350453536 0.874E-04 0.1588188968 0.0058805391 2282.3852 + 284 -229.0350466576 0.821E-04 0.1588221470 0.0058809315 2300.7456 + 290 -229.0350324488 0.811E-04 0.1587229483 0.0058787323 2303.3477 + 292 -229.0350301880 0.806E-04 0.1587064033 0.0058784086 2317.4052 + 302 -229.0350376725 0.757E-04 0.1587530219 0.0058796572 2331.2425 + 310 -229.0350303337 0.743E-04 0.1587000732 0.0058786077 2358.9937 + 322 -229.0350160627 0.729E-04 0.1586269419 0.0058759880 2377.8110 + 331 -229.0349854336 0.694E-04 0.1584108410 0.0058715373 2380.7822 + 343 -229.0349818612 0.689E-04 0.1583815229 0.0058711321 2388.7328 + 344 -229.0349763440 0.689E-04 0.1583461888 0.0058702384 2396.5133 + 346 -229.0349783237 0.686E-04 0.1583591796 0.0058705719 2408.7020 + 350 -229.0349804675 0.679E-04 0.1583807775 0.0058707656 2411.2843 + 357 -229.0349871706 0.671E-04 0.1584275247 0.0058718544 2419.9013 + 359 -229.0349803877 0.670E-04 0.1583754721 0.0058709674 2425.9607 + 364 -229.0349954990 0.668E-04 0.1584902551 0.0058729747 2427.8210 + 369 -229.0349962148 0.663E-04 0.1584961376 0.0058730328 2436.6272 + 374 -229.0350025350 0.656E-04 0.1585272383 0.0058742630 2443.9233 + 378 -229.0349899779 0.653E-04 0.1584435429 0.0058723368 2452.6782 + 394 -229.0349681281 0.632E-04 0.1583233281 0.0058683490 2482.5247 + 402 -229.0349574465 0.623E-04 0.1582391824 0.0058669545 2486.8869 + 418 -229.0349632188 0.616E-04 0.1582964843 0.0058674037 2489.2782 + 421 -229.0349422754 0.607E-04 0.1581714846 0.0058637843 2505.6523 + 423 -229.0349405978 0.604E-04 0.1581524031 0.0058636951 2518.1856 + 446 -229.0349247455 0.583E-04 0.1580330151 0.0058615060 2525.0843 + 447 -229.0349245323 0.582E-04 0.1580294939 0.0058615141 2557.0554 + 487 -229.0349140130 0.546E-04 0.1579491830 0.0058601115 2561.3976 + 511 -229.0349149156 0.519E-04 0.1579535204 0.0058603391 2575.8055 + 518 -229.0349077650 0.513E-04 0.1579043135 0.0058592438 2577.4553 + 520 -229.0349055092 0.511E-04 0.1578850546 0.0058589936 2578.6003 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 10.139267 GB ] [ VIRT MEM : 21.192425 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9787.056145 s ] [ CPU TIME: 659042.717101 s ] <<<<< .. + +* Number of generators 10440204 + +.. >>>>> [ RES MEM : 10.139267 GB ] [ VIRT MEM : 21.192425 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9787.078002 s ] [ CPU TIME: 659042.738849 s ] <<<<< .. + +* Number of selectors 10440204 +* Number of comb teeth 92 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9423582057371738 + +Summary at N_det = 10462547 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.00529063 +# PT2 -0.02961248 0.00005090 +# rPT2 -0.02944000 0.00005061 +# +# E+PT2 -229.03490311 0.00005090 +# E+rPT2 -229.03473063 0.00005061 +# ============ ============================= + + N_det = 10462547 + N_states = 1 + + * State 1 + < S^2 > = 3.887321552994409E-003 + E = -229.005290629208 + Variance = 0.157867774692132 + PT norm = 7.654203594554612E-002 + PT2 = -2.961248178059211E-002 + rPT2 = -2.944000213272582E-002 + E+PT2 = -229.034903110989 +/- 5.090491957212781E-005 + E+rPT2 = -229.034730631341 +/- 5.060842086366031E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.861289112024 + Vee = 238.466223365413 + Vecp = 0.000000000000000E+000 + T = 229.281545338614 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0297 -229.03985206 + -0.0300 -229.04282988 + -0.0303 -229.04503755 + -0.0312 -229.04126688 + -0.0328 -229.04153560 + -0.0359 -229.04188425 + -0.0407 -229.04252887 + =========== =================== + +* Number of unique beta determinants 1496703 +* Number of unique alpha determinants 1548180 + +.. >>>>> [ RES MEM : 10.923298 GB ] [ VIRT MEM : 22.816158 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10791.189423 s ] [ CPU TIME: 728967.339010 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 20788608 +* Number of threads for diagonalization 72 +* Memory(Gb) 31.31310107186437 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.0051341505 0.003912 0.128E-03 + 2 -229.0057228264 0.004032 0.484E-05 + 3 -229.0057391014 0.004062 0.445E-06 + 4 -229.0057400545 0.004066 0.128E-06 + 5 -229.0057401883 0.004065 0.117E-07 + 6 -229.0057402135 0.004065 0.134E-08 + 7 -229.0057402170 0.004065 0.208E-09 + 8 -229.0057402176 0.004065 0.379E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 29.202484 GB ] [ VIRT MEM : 46.669689 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18623.073237 s ] [ CPU TIME: 1274503.910443 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 10.771004 GB ] [ VIRT MEM : 22.660881 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18624.830826 s ] [ CPU TIME: 1274511.258069 s ] <<<<< .. + +* Energy of state 1 -229.0057402175535 +* S^2 of state 1 0.4064881850721799E-02 +* Saved determinants 20788608 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 10.448246 GB ] [ VIRT MEM : 20.373951 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18792.860843 s ] [ CPU TIME: 1276097.822307 s ] <<<<< .. + +* Number of generators 20725986 + +.. >>>>> [ RES MEM : 10.448246 GB ] [ VIRT MEM : 20.373951 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18792.907590 s ] [ CPU TIME: 1276101.180388 s ] <<<<< .. + +* Number of selectors 20725986 +* Number of comb teeth 93 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -229.0057402175535 + +.. >>>>> [ RES MEM : 12.526901 GB ] [ VIRT MEM : 22.148380 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18807.277508 s ] [ CPU TIME: 1276634.672314 s ] <<<<< .. + +* Number of generators 20725986 + +.. >>>>> [ RES MEM : 12.526901 GB ] [ VIRT MEM : 22.148380 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 18807.322573 s ] [ CPU TIME: 1276634.717212 s ] <<<<< .. + +* Number of selectors 20725986 +* Number of comb teeth 93 +* pt2_n_tasks_max 638 +* Number of tasks 20982148 +* Number of fragmented tasks 4288 +* Number of threads for PT2 72 +* Memory (Gb) 4.070579999014735 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0341066025 0.981E-03 0.1493681264 0.0056675677 1055.4176 + 4 -229.0347548654 0.101E-02 0.1538467135 0.0057649374 1251.2246 + 5 -229.0350945523 0.820E-03 0.1565760857 0.0058100541 1308.3015 + 6 -229.0351963198 0.665E-03 0.1577775864 0.0058110523 1439.5139 + 7 -229.0349260456 0.623E-03 0.1559164824 0.0057693818 1473.5756 + 8 -229.0350356263 0.542E-03 0.1569183516 0.0057765208 1599.0044 + 9 -229.0349935920 0.475E-03 0.1566021238 0.0057706076 1600.1025 + 10 -229.0348278670 0.457E-03 0.1554179281 0.0057467672 1612.8189 + 11 -229.0346809760 0.439E-03 0.1544882724 0.0057222765 1623.9774 + 12 -229.0347577870 0.407E-03 0.1548146620 0.0057378849 1679.4875 + 13 -229.0347689009 0.376E-03 0.1550251587 0.0057379145 1701.9885 + 14 -229.0348997753 0.364E-03 0.1555283063 0.0057674539 1716.3278 + 15 -229.0348394567 0.345E-03 0.1552084050 0.0057556316 1727.0285 + 17 -229.0350921779 0.405E-03 0.1566104666 0.0058024695 1784.3355 + 18 -229.0351534889 0.384E-03 0.1570683289 0.0058106655 1792.2175 + 19 -229.0350275398 0.388E-03 0.1561664851 0.0057933093 1851.3885 + 20 -229.0349113858 0.386E-03 0.1554225464 0.0057746215 1927.9765 + 23 -229.0350498195 0.348E-03 0.1562665038 0.0057976088 1936.9025 + 25 -229.0350906900 0.320E-03 0.1564371570 0.0058076173 1968.9456 + 27 -229.0351266262 0.329E-03 0.1567266603 0.0058114028 2014.1854 + 28 -229.0351803542 0.321E-03 0.1570612805 0.0058200088 2090.5105 + 30 -229.0351277734 0.304E-03 0.1566484414 0.0058136831 2105.1095 + 32 -229.0351699607 0.275E-03 0.1569116350 0.0058197383 2117.4815 + 33 -229.0352561078 0.278E-03 0.1575485004 0.0058317228 2121.5885 + 35 -229.0352477077 0.267E-03 0.1574172169 0.0058316511 2144.0530 + 36 -229.0352782913 0.261E-03 0.1576393540 0.0058355871 2171.4215 + 37 -229.0352714034 0.254E-03 0.1576555254 0.0058327577 2182.7889 + 40 -229.0352301211 0.248E-03 0.1573521883 0.0058268636 2184.2802 + 41 -229.0351919496 0.241E-03 0.1570833769 0.0058212047 2202.0145 + 42 -229.0351499501 0.239E-03 0.1567677662 0.0058164140 2237.7088 + 43 -229.0351473991 0.234E-03 0.1568114513 0.0058146779 2300.3745 + 48 -229.0350300986 0.217E-03 0.1561165394 0.0057954355 2305.6198 + 49 -229.0349915607 0.216E-03 0.1558742168 0.0057889258 2360.3985 + 52 -229.0350608980 0.207E-03 0.1563520312 0.0057990606 2367.2616 + 53 -229.0350821557 0.204E-03 0.1564845418 0.0058025549 2376.2785 + 55 -229.0351420955 0.200E-03 0.1568956578 0.0058114978 2410.0453 + 62 -229.0351379707 0.195E-03 0.1568429467 0.0058115978 2420.3055 + 63 -229.0351064319 0.194E-03 0.1566178052 0.0058073834 2428.7625 + 65 -229.0350826267 0.189E-03 0.1564941244 0.0058029880 2436.6235 + 67 -229.0350514396 0.186E-03 0.1562495876 0.0057990097 2445.5080 + 69 -229.0350497024 0.180E-03 0.1563383399 0.0057962052 2462.2264 + 73 -229.0350388084 0.166E-03 0.1562673345 0.0057947441 2471.8675 + 75 -229.0350047434 0.164E-03 0.1560677881 0.0057887916 2487.5665 + 77 -229.0350113417 0.162E-03 0.1560420305 0.0057915520 2523.2674 + 80 -229.0350363211 0.156E-03 0.1561782859 0.0057958568 2535.1005 + 82 -229.0349933210 0.156E-03 0.1558714206 0.0057894720 2545.7775 + 84 -229.0349920479 0.155E-03 0.1558619697 0.0057892964 2565.1749 + 85 -229.0349585996 0.155E-03 0.1556523971 0.0057837883 2569.3525 + 86 -229.0349747769 0.154E-03 0.1557485970 0.0057866706 2571.4043 + 89 -229.0350145827 0.163E-03 0.1560460165 0.0057921684 2635.3055 + 96 -229.0349580072 0.153E-03 0.1556636752 0.0057835928 2670.2024 + 103 -229.0349184463 0.147E-03 0.1554693799 0.0057755886 2677.9735 + 104 -229.0348948443 0.148E-03 0.1553172726 0.0057717762 2688.9841 + 105 -229.0348651381 0.149E-03 0.1551129654 0.0057672923 2694.4815 + 110 -229.0348369413 0.147E-03 0.1548896767 0.0057637942 2706.1625 + 111 -229.0348633136 0.148E-03 0.1550778493 0.0057675892 2718.0422 + 113 -229.0349013936 0.146E-03 0.1553166765 0.0057738530 2739.1805 + 114 -229.0348797013 0.147E-03 0.1551646948 0.0057706179 2776.9163 + 123 -229.0348687792 0.139E-03 0.1550817822 0.0057691383 2795.7861 + 124 -229.0348768532 0.136E-03 0.1551137815 0.0057709495 2820.1776 + 126 -229.0348860471 0.135E-03 0.1551670183 0.0057724925 2861.1545 + 134 -229.0348987888 0.130E-03 0.1552550648 0.0057741924 2872.0748 + 136 -229.0348703458 0.129E-03 0.1550763875 0.0057694922 2894.0358 + 142 -229.0348690108 0.128E-03 0.1550078074 0.0057706270 2903.0797 + 143 -229.0348737069 0.128E-03 0.1550530012 0.0057710805 2905.2218 + 144 -229.0348831774 0.127E-03 0.1551354513 0.0057721688 2918.3667 + 146 -229.0348850897 0.126E-03 0.1551446713 0.0057725089 2940.6122 + 147 -229.0348929989 0.125E-03 0.1552187908 0.0057732842 2946.8075 + 149 -229.0348768650 0.125E-03 0.1551093976 0.0057709898 2950.2976 + 150 -229.0348893957 0.124E-03 0.1551901497 0.0057729745 2953.9905 + 152 -229.0348824560 0.123E-03 0.1551432879 0.0057718776 2979.6335 + 154 -229.0349061968 0.123E-03 0.1553087324 0.0057754352 2996.9685 + 159 -229.0349323949 0.120E-03 0.1555098056 0.0057789049 3021.7245 + 160 -229.0349441033 0.120E-03 0.1555922407 0.0057805738 3028.2920 + 161 -229.0349538766 0.119E-03 0.1556625516 0.0057819321 3042.7808 + 167 -229.0349833259 0.118E-03 0.1558587832 0.0057863964 3060.5965 + 171 -229.0349980511 0.114E-03 0.1559008061 0.0057900170 3113.6865 + 181 -229.0349721013 0.108E-03 0.1557412568 0.0057858139 3146.1435 + 190 -229.0349861006 0.106E-03 0.1558318668 0.0057878650 3153.4553 + 192 -229.0349896888 0.107E-03 0.1558669459 0.0057881553 3211.4825 + 208 -229.0349985847 0.101E-03 0.1559184902 0.0057896531 3218.7825 + 213 -229.0350141451 0.967E-04 0.1559991933 0.0057924927 3259.9256 + 218 -229.0350180961 0.949E-04 0.1560418411 0.0057927455 3261.6182 + 220 -229.0350143437 0.941E-04 0.1560087253 0.0057923438 3285.9515 + 227 -229.0350073302 0.930E-04 0.1559531208 0.0057914839 3287.1965 + 230 -229.0350179857 0.901E-04 0.1560559245 0.0057924101 3314.6993 + 231 -229.0350147672 0.898E-04 0.1560336009 0.0057919425 3323.2755 + 239 -229.0350001488 0.875E-04 0.1559292887 0.0057897830 3341.0874 + 248 -229.0349669369 0.837E-04 0.1556815103 0.0057853751 3343.4415 + 250 -229.0349585667 0.833E-04 0.1556207891 0.0057842383 3354.6823 + 252 -229.0349797287 0.840E-04 0.1557841136 0.0057869920 3368.5645 + 255 -229.0349783837 0.833E-04 0.1557797592 0.0057866981 3373.4265 + 258 -229.0349791617 0.826E-04 0.1557803343 0.0057868736 3390.0837 + 259 -229.0349699146 0.828E-04 0.1557157762 0.0057854983 3394.1130 + 266 -229.0349860125 0.785E-04 0.1558719873 0.0057869793 3403.7594 + 270 -229.0349931038 0.780E-04 0.1559246928 0.0057879126 3418.9817 + 271 -229.0349933666 0.777E-04 0.1559224114 0.0057880584 3421.5796 + 272 -229.0349931164 0.774E-04 0.1559219008 0.0057880196 3445.1923 + 284 -229.0349835715 0.755E-04 0.1558970112 0.0057857677 3447.7255 + 288 -229.0349879489 0.737E-04 0.1559368637 0.0057862336 3467.7255 + 290 -229.0349883621 0.737E-04 0.1559306286 0.0057865505 3471.4772 + 292 -229.0349923339 0.733E-04 0.1559669895 0.0057869885 3483.9636 + 293 -229.0349911922 0.730E-04 0.1559576804 0.0057868539 3487.0398 + 296 -229.0349856979 0.725E-04 0.1559154837 0.0057861359 3509.0375 + 299 -229.0349760150 0.722E-04 0.1558489127 0.0057846394 3519.1026 + 311 -229.0349677685 0.699E-04 0.1557908031 0.0057832961 3540.2167 + 317 -229.0349612396 0.690E-04 0.1557554885 0.0057820543 3542.6697 + 325 -229.0349549450 0.681E-04 0.1557080662 0.0057812443 3543.9626 + 328 -229.0349635013 0.680E-04 0.1557696110 0.0057824504 3550.7895 + 330 -229.0349655423 0.677E-04 0.1557907926 0.0057825946 3563.8865 + 331 -229.0349679003 0.675E-04 0.1558015511 0.0057830589 3566.4695 + 339 -229.0349528567 0.633E-04 0.1556985591 0.0057808067 3571.8640 + 342 -229.0349464936 0.629E-04 0.1556565068 0.0057797810 3576.0788 + 343 -229.0349466954 0.627E-04 0.1556637524 0.0057797115 3580.9205 + 344 -229.0349516165 0.627E-04 0.1556966793 0.0057804653 3592.1265 + 346 -229.0349493596 0.624E-04 0.1556725279 0.0057803317 3601.1845 + 347 -229.0349528064 0.623E-04 0.1556927865 0.0057809036 3604.6775 + 359 -229.0349949531 0.617E-04 0.1559560860 0.0057878529 3631.2035 + 369 -229.0349947352 0.603E-04 0.1559618619 0.0057876861 3636.5373 + 371 -229.0349980526 0.602E-04 0.1559914150 0.0057880542 3645.1465 + 374 -229.0349978504 0.600E-04 0.1559825816 0.0057881586 3655.3725 + 378 -229.0349901473 0.596E-04 0.1559362586 0.0057868957 3672.2835 + 380 -229.0349889662 0.593E-04 0.1559289586 0.0057866921 3721.3985 + 421 -229.0349758401 0.542E-04 0.1558394967 0.0057846228 3725.9076 + 422 -229.0349699020 0.544E-04 0.1557987316 0.0057837295 3781.8991 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 13.462776 GB ] [ VIRT MEM : 23.791706 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 22660.056983 s ] [ CPU TIME: 1545640.907233 s ] <<<<< .. + +* Number of generators 20725986 + +.. >>>>> [ RES MEM : 13.462776 GB ] [ VIRT MEM : 23.791706 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 22660.100068 s ] [ CPU TIME: 1545640.950155 s ] <<<<< .. + +* Number of selectors 20725986 +* Number of comb teeth 93 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9430847227394598 + +Summary at N_det = 20788608 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.00574022 +# PT2 -0.02924188 0.00005220 +# rPT2 -0.02907368 0.00005190 +# +# E+PT2 -229.03498210 0.00005220 +# E+rPT2 -229.03481390 0.00005190 +# ============ ============================= + + N_det = 20788608 + N_states = 1 + + * State 1 + < S^2 > = 4.064881850721799E-003 + E = -229.005740217554 + Variance = 0.155895433625910 + PT norm = 7.606150189520436E-002 + PT2 = -2.924188099866797E-002 + rPT2 = -2.907367952662001E-002 + E+PT2 = -229.034982098552 +/- 5.219676761885212E-005 + E+rPT2 = -229.034813897080 +/- 5.189652793351737E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.861411888937 + Vee = 238.464701295677 + Vecp = 0.000000000000000E+000 + T = 229.282740596918 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0294 -229.04142239 + -0.0297 -229.04077866 + -0.0300 -229.04197983 + -0.0303 -229.04362421 + -0.0312 -229.04147712 + -0.0328 -229.04159145 + -0.0359 -229.04188260 + =========== =================== + +* Number of unique beta determinants 2442426 +* Number of unique alpha determinants 2472734 + +.. >>>>> [ RES MEM : 16.288063 GB ] [ VIRT MEM : 27.456066 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 26478.108486 s ] [ CPU TIME: 1809192.354078 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 41149068 +* Number of threads for diagonalization 72 +* Memory(Gb) 60.55051785334945 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.0055365879 0.004084 0.186E-03 + 2 -229.0063949251 0.004260 0.771E-05 + 3 -229.0064191173 0.004300 0.867E-06 + 4 -229.0064205826 0.004306 0.221E-06 + 5 -229.0064208259 0.004305 0.168E-07 + 6 -229.0064208679 0.004304 0.290E-08 + 7 -229.0064208748 0.004304 0.544E-09 + 8 -229.0064208762 0.004304 0.118E-09 + 9 -229.0064208764 0.004304 0.196E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 54.306385 GB ] [ VIRT MEM : 74.671413 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 60686.037256 s ] [ CPU TIME: 4168166.366541 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 15.983345 GB ] [ VIRT MEM : 27.149422 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 60690.186701 s ] [ CPU TIME: 4168174.998917 s ] <<<<< .. + +* Energy of state 1 -229.0064208764451 +* S^2 of state 1 0.4304424303517339E-02 +* Saved determinants 41149068 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 15.147556 GB ] [ VIRT MEM : 23.282322 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 61024.246213 s ] [ CPU TIME: 4171228.795282 s ] <<<<< .. + +* Number of generators 40933231 + +.. >>>>> [ RES MEM : 15.147556 GB ] [ VIRT MEM : 23.282322 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 61024.334678 s ] [ CPU TIME: 4171235.149539 s ] <<<<< .. + +* Number of selectors 40933231 +* Number of comb teeth 93 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -229.0064208764451 + +.. >>>>> [ RES MEM : 19.248169 GB ] [ VIRT MEM : 26.782822 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 61053.746348 s ] [ CPU TIME: 4172313.154350 s ] <<<<< .. + +* Number of generators 40933231 + +.. >>>>> [ RES MEM : 19.248169 GB ] [ VIRT MEM : 26.782822 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 61053.831075 s ] [ CPU TIME: 4172313.238828 s ] <<<<< .. + +* Number of selectors 40933231 +* Number of comb teeth 93 +* pt2_n_tasks_max 638 +* Number of tasks 41191278 +* Number of fragmented tasks 4341 +* Number of threads for PT2 72 +* Memory (Gb) 5.528033485151827 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0362086574 0.117E-02 0.1585744029 0.0058921492 70970.3211 + 4 -229.0358936488 0.871E-03 0.1567786374 0.0058323110 82701.3325 + 5 -229.0355885457 0.721E-03 0.1546461675 0.0057875202 91863.9278 + 6 -229.0353791566 0.605E-03 0.1535378370 0.0057489753 99922.5862 + 7 -229.0351814250 0.547E-03 0.1520309984 0.0057229327 ********** + 8 -229.0350021990 0.495E-03 0.1504665269 0.0057068981 ********** + 9 -229.0353707195 0.588E-03 0.1528924697 0.0057643515 ********** + 10 -229.0353345600 0.527E-03 0.1526316947 0.0057586214 ********** + 11 -229.0354790609 0.497E-03 0.1534816738 0.0057837405 ********** + 12 -229.0356619373 0.491E-03 0.1552154112 0.0057978736 ********** + 13 -229.0361166290 0.644E-03 0.1588803216 0.0058524748 ********** + 14 -229.0359943507 0.608E-03 0.1580466907 0.0058328010 ********** + 15 -229.0359759766 0.568E-03 0.1578308898 0.0058341764 ********** + 16 -229.0361236327 0.547E-03 0.1587270465 0.0058597227 ********** + 17 -229.0360163392 0.520E-03 0.1581014099 0.0058405413 ********** + 18 -229.0361216932 0.502E-03 0.1587719172 0.0058567968 ********** + 19 -229.0361830760 0.477E-03 0.1592653671 0.0058650556 ********** + 20 -229.0361096884 0.457E-03 0.1589321016 0.0058494077 ********** + 21 -229.0362234989 0.447E-03 0.1597281441 0.0058655758 ********** + 22 -229.0362842642 0.432E-03 0.1599885741 0.0058783898 ********** + 23 -229.0362535189 0.414E-03 0.1599073565 0.0058707833 ********** + 24 -229.0362327247 0.397E-03 0.1597718387 0.0058674214 ********** + 25 -229.0362825848 0.380E-03 0.1601717534 0.0058744026 ********** + 26 -229.0361971495 0.372E-03 0.1595980923 0.0058609964 ********** + 27 -229.0361155533 0.367E-03 0.1591166331 0.0058463852 ********** + 28 -229.0361268818 0.354E-03 0.1590815217 0.0058506237 ********** + 29 -229.0360601072 0.352E-03 0.1586143880 0.0058405294 ********** + 30 -229.0359340166 0.342E-03 0.1578419033 0.0058191119 ********** + 31 -229.0359239889 0.331E-03 0.1577978445 0.0058171874 ********** + 32 -229.0357804634 0.343E-03 0.1568651423 0.0057942299 ********** + 33 -229.0357441292 0.331E-03 0.1566101442 0.0057890362 ********** + 34 -229.0358682435 0.345E-03 0.1574982041 0.0058062638 ********** + 35 -229.0358878391 0.336E-03 0.1575668926 0.0058108691 ********** + 36 -229.0358836742 0.326E-03 0.1575559042 0.0058098752 ********** + 37 -229.0358903775 0.318E-03 0.1576214757 0.0058095895 ********** + 38 -229.0359066213 0.310E-03 0.1577873093 0.0058107314 ********** + 39 -229.0358069966 0.298E-03 0.1572021925 0.0057935102 ********** + 40 -229.0357708617 0.293E-03 0.1569399454 0.0057880930 ********** + 41 -229.0357696990 0.287E-03 0.1569708106 0.0057865519 ********** + 42 -229.0358109584 0.284E-03 0.1572333921 0.0057931725 ********** + 43 -229.0357554821 0.283E-03 0.1568384073 0.0057852005 ********** + 44 -229.0357823332 0.278E-03 0.1570404631 0.0057881753 ********** + 45 -229.0357649752 0.273E-03 0.1569635670 0.0057846523 ********** + 46 -229.0357292908 0.270E-03 0.1567228160 0.0057792201 ********** + 47 -229.0356844743 0.268E-03 0.1564236496 0.0057723473 ********** + 48 -229.0356369599 0.266E-03 0.1560620195 0.0057661873 ********** + 49 -229.0356646764 0.262E-03 0.1562611687 0.0057702670 ********** + 50 -229.0356287595 0.255E-03 0.1561048840 0.0057627369 ********** + 51 -229.0356915561 0.258E-03 0.1565518668 0.0057719432 ********** + 52 -229.0356788340 0.253E-03 0.1564832132 0.0057697735 ********** + 53 -229.0356755264 0.249E-03 0.1564631792 0.0057694234 ********** + 54 -229.0356550381 0.245E-03 0.1563499189 0.0057654236 ********** + 55 -229.0356207397 0.243E-03 0.1561234168 0.0057600201 ********** + 56 -229.0356335785 0.238E-03 0.1562019255 0.0057626283 ********** + 57 -229.0356123584 0.235E-03 0.1560659273 0.0057593767 ********** + 58 -229.0355841900 0.233E-03 0.1558512277 0.0057554747 ********** + 59 -229.0356001763 0.229E-03 0.1559312010 0.0057585118 ********** + 60 -229.0355779347 0.226E-03 0.1557720181 0.0057555066 ********** + 61 -229.0355698893 0.223E-03 0.1557408111 0.0057534198 ********** + 62 -229.0355908197 0.222E-03 0.1558434049 0.0057575485 ********** + 63 -229.0355586169 0.220E-03 0.1555991129 0.0057534875 ********** + 64 -229.0355488900 0.217E-03 0.1555121211 0.0057525148 ********** + 65 -229.0355528353 0.214E-03 0.1555847093 0.0057522652 ********** + 66 -229.0355335019 0.211E-03 0.1554301130 0.0057498334 ********** + 67 -229.0355007731 0.211E-03 0.1552369301 0.0057441475 ********** + 68 -229.0355405856 0.210E-03 0.1554899749 0.0057505032 ********** + 69 -229.0355264363 0.207E-03 0.1553744131 0.0057488018 ********** + 71 -229.0354798278 0.206E-03 0.1550606387 0.0057418040 ********** + 72 -229.0354604490 0.204E-03 0.1548999899 0.0057393582 ********** + 73 -229.0354611518 0.201E-03 0.1549121798 0.0057391579 ********** + 74 -229.0354576950 0.199E-03 0.1548911905 0.0057390513 ********** + 75 -229.0354407426 0.197E-03 0.1547880379 0.0057363277 ********** + 76 -229.0354052674 0.197E-03 0.1545451059 0.0057310300 ********** + 77 -229.0353886119 0.196E-03 0.1544383121 0.0057283069 ********** + 78 -229.0353612912 0.195E-03 0.1542568855 0.0057240208 ********** + 79 -229.0353697251 0.190E-03 0.1543291857 0.0057247423 ********** + 80 -229.0353607600 0.188E-03 0.1542803693 0.0057230369 ********** + 81 -229.0353394651 0.187E-03 0.1541368477 0.0057197550 ********** + 82 -229.0353438895 0.184E-03 0.1541609717 0.0057204558 ********** + 83 -229.0353428572 0.182E-03 0.1541706442 0.0057198562 ********** + 84 -229.0353409265 0.180E-03 0.1541279412 0.0057201948 ********** + 85 -229.0353286425 0.181E-03 0.1540602742 0.0057180612 ********** + 86 -229.0353344512 0.179E-03 0.1541174195 0.0057184090 ********** + 87 -229.0353175435 0.178E-03 0.1539804071 0.0057163522 ********** + 88 -229.0353173740 0.176E-03 0.1540043894 0.0057157834 ********** + 89 -229.0353210958 0.174E-03 0.1540240763 0.0057163706 ********** + 90 -229.0353202325 0.172E-03 0.1540057585 0.0057166113 ********** + 91 -229.0353265219 0.172E-03 0.1540416216 0.0057176158 ********** + 92 -229.0353258683 0.170E-03 0.1540654714 0.0057167489 ********** + 93 -229.0353198777 0.168E-03 0.1540355318 0.0057155298 ********** + 94 -229.0353412716 0.168E-03 0.1541726285 0.0057189286 ********** + 95 -229.0353458794 0.166E-03 0.1542178311 0.0057193719 ********** + 96 -229.0353460141 0.164E-03 0.1542019791 0.0057198460 ********** + 97 -229.0353140424 0.165E-03 0.1539841637 0.0057149913 ********** + 98 -229.0353307520 0.166E-03 0.1540868303 0.0057177722 ********** + 100 -229.0353185841 0.163E-03 0.1540562927 0.0057147150 ********** + 101 -229.0353246652 0.161E-03 0.1541005234 0.0057154808 ********** + 102 -229.0353450575 0.161E-03 0.1542197048 0.0057189510 ********** + 103 -229.0353205298 0.161E-03 0.1540392835 0.0057156211 ********** + 104 -229.0353158183 0.160E-03 0.1540211915 0.0057145616 ********** + 105 -229.0353044430 0.159E-03 0.1539413404 0.0057129652 ********** + 106 -229.0353003263 0.157E-03 0.1539349064 0.0057117135 ********** + 107 -229.0352901909 0.156E-03 0.1538749005 0.0057098309 ********** + 108 -229.0352857094 0.154E-03 0.1538450267 0.0057091912 ********** + 109 -229.0352758139 0.153E-03 0.1537542703 0.0057083422 ********** + 110 -229.0352875593 0.152E-03 0.1538731158 0.0057092653 ********** + 111 -229.0352914304 0.151E-03 0.1539083246 0.0057095685 ********** + 112 -229.0352876355 0.150E-03 0.1538688641 0.0057092466 ********** + 113 -229.0352651100 0.150E-03 0.1537322456 0.0057055495 ********** + 114 -229.0352631983 0.149E-03 0.1537499618 0.0057045590 ********** + 115 -229.0352601193 0.147E-03 0.1537181944 0.0057042507 ********** + 116 -229.0352408679 0.146E-03 0.1535955171 0.0057010848 ********** + 117 -229.0352300743 0.145E-03 0.1535353387 0.0056990621 ********** + 118 -229.0352077540 0.146E-03 0.1533838837 0.0056957041 ********** + 119 -229.0352031180 0.145E-03 0.1533567360 0.0056947940 ********** + 120 -229.0352013396 0.144E-03 0.1533459208 0.0056945039 ********** + 121 -229.0352019748 0.142E-03 0.1533264931 0.0056952182 ********** + 122 -229.0352006907 0.141E-03 0.1533273326 0.0056947223 ********** + 123 -229.0352021340 0.140E-03 0.1533330466 0.0056950199 ********** + 124 -229.0351916926 0.139E-03 0.1532778423 0.0056930030 ********** + 125 -229.0351803892 0.139E-03 0.1531918487 0.0056914759 ********** + 126 -229.0351689844 0.138E-03 0.1531010942 0.0056900409 ********** + 127 -229.0351612921 0.137E-03 0.1530539006 0.0056887409 ********** + 128 -229.0351680285 0.136E-03 0.1531002295 0.0056898436 ********** + 129 -229.0351694334 0.135E-03 0.1531008499 0.0056902138 ********** + 130 -229.0351679558 0.134E-03 0.1531074496 0.0056894988 ********** + 131 -229.0351563228 0.133E-03 0.1530386673 0.0056874804 ********** + 132 -229.0351604835 0.132E-03 0.1530758507 0.0056879064 ********** + 133 -229.0351378801 0.133E-03 0.1529098125 0.0056847497 ********** + 134 -229.0351269442 0.133E-03 0.1528403686 0.0056829483 ********** + 135 -229.0351306163 0.132E-03 0.1528665185 0.0056834251 ********** + 136 -229.0351334456 0.131E-03 0.1529049589 0.0056835515 ********** + 137 -229.0351383484 0.130E-03 0.1529350772 0.0056843763 ********** + 138 -229.0351413966 0.129E-03 0.1529744874 0.0056843396 ********** + 139 -229.0351401958 0.128E-03 0.1529781270 0.0056839024 ********** + 140 -229.0351342147 0.127E-03 0.1529289361 0.0056832482 ********** + 141 -229.0351341948 0.126E-03 0.1529498062 0.0056828077 ********** + 142 -229.0351244475 0.126E-03 0.1528803059 0.0056813992 ********** + 143 -229.0350811811 0.128E-03 0.1525675611 0.0056752254 ********** + 144 -229.0350928086 0.128E-03 0.1526439690 0.0056769909 ********** + 145 -229.0350776925 0.128E-03 0.1525439447 0.0056745711 ********** + 146 -229.0350845596 0.127E-03 0.1525698434 0.0056761957 ********** + 147 -229.0350720705 0.127E-03 0.1524829430 0.0056743044 ********** + 148 -229.0350616932 0.127E-03 0.1524084937 0.0056728355 ********** + 149 -229.0350641377 0.126E-03 0.1524295252 0.0056732287 ********** + 150 -229.0350676216 0.125E-03 0.1524627837 0.0056735449 ********** + 151 -229.0350709338 0.124E-03 0.1525037933 0.0056735904 ********** + 152 -229.0350754085 0.119E-03 0.1525334069 0.0056742434 ********** + 153 -229.0350880827 0.119E-03 0.1526305647 0.0056758832 ********** + 154 -229.0350861736 0.118E-03 0.1526335384 0.0056752268 ********** + 155 -229.0350939136 0.117E-03 0.1526765997 0.0056766484 ********** + 156 -229.0350834463 0.117E-03 0.1526029125 0.0056751000 ********** + 157 -229.0350831570 0.116E-03 0.1525926482 0.0056752113 ********** + 158 -229.0350661873 0.117E-03 0.1524823441 0.0056725201 ********** + 159 -229.0350894353 0.118E-03 0.1526364499 0.0056760925 ********** + 160 -229.0350855986 0.118E-03 0.1526057155 0.0056756306 ********** + 161 -229.0350876809 0.117E-03 0.1526229183 0.0056758335 ********** + 162 -229.0351073966 0.118E-03 0.1527485634 0.0056791914 ********** + 163 -229.0351246740 0.117E-03 0.1528812706 0.0056816719 ********** + 164 -229.0351189900 0.116E-03 0.1528336690 0.0056810516 ********** + 165 -229.0351318733 0.116E-03 0.1529210163 0.0056830166 ********** + 166 -229.0351352041 0.116E-03 0.1529575613 0.0056833005 ********** + 167 -229.0351357947 0.115E-03 0.1529693845 0.0056832720 ********** + 168 -229.0351345610 0.114E-03 0.1529555649 0.0056832234 ********** + 169 -229.0351367874 0.114E-03 0.1529784674 0.0056833408 ********** + 170 -229.0351267783 0.113E-03 0.1529059863 0.0056818857 ********** + 171 -229.0351148748 0.113E-03 0.1528395477 0.0056797550 ********** + 172 -229.0351180705 0.113E-03 0.1528654422 0.0056800923 ********** + 173 -229.0351239640 0.113E-03 0.1529221878 0.0056805389 ********** + 174 -229.0351314152 0.113E-03 0.1529852489 0.0056813796 ********** + 175 -229.0351457092 0.113E-03 0.1530760086 0.0056837349 ********** + 176 -229.0351491812 0.113E-03 0.1530987556 0.0056842696 ********** + 177 -229.0351494717 0.112E-03 0.1531032732 0.0056843184 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0.1531335570 0.0056782419 ********** + 238 -229.0351321111 0.839E-04 0.1531184155 0.0056783530 ********** + 239 -229.0351308748 0.836E-04 0.1531141351 0.0056780549 ********** + 240 -229.0351285254 0.832E-04 0.1530992278 0.0056776669 ********** + 241 -229.0351198572 0.833E-04 0.1530401134 0.0056763476 ********** + 242 -229.0351191374 0.830E-04 0.1530338210 0.0056762529 ********** + 243 -229.0351110721 0.831E-04 0.1529806531 0.0056749842 ********** + 244 -229.0351051401 0.829E-04 0.1529354395 0.0056741851 ********** + 245 -229.0351089808 0.827E-04 0.1529534221 0.0056749433 ********** + 247 -229.0351157061 0.834E-04 0.1529984287 0.0056759936 ********** + 248 -229.0351233377 0.834E-04 0.1530414659 0.0056773415 ********** + 249 -229.0351175827 0.833E-04 0.1529963624 0.0056766249 ********** + 250 -229.0350998148 0.826E-04 0.1528898328 0.0056735583 ********** + 251 -229.0351094487 0.829E-04 0.1529556387 0.0056750464 ********** + 253 -229.0351117623 0.822E-04 0.1529665196 0.0056755148 ********** + 254 -229.0351084999 0.820E-04 0.1529434891 0.0056750193 ********** + 255 -229.0351060613 0.817E-04 0.1529365368 0.0056744646 ********** + 257 -229.0350992964 0.812E-04 0.1528905804 0.0056733930 ********** + 258 -229.0351071890 0.813E-04 0.1529488804 0.0056744964 ********** + 259 -229.0351008105 0.812E-04 0.1528990577 0.0056736860 ********** + 260 -229.0350922778 0.813E-04 0.1528409996 0.0056723850 ********** + 261 -229.0350961813 0.811E-04 0.1528747671 0.0056728383 ********** + 262 -229.0350949440 0.808E-04 0.1528617253 0.0056727583 ********** + 263 -229.0350931595 0.805E-04 0.1528489198 0.0056724923 ********** + 264 -229.0350981087 0.804E-04 0.1528795994 0.0056733068 ********** + 265 -229.0351014941 0.801E-04 0.1529022529 0.0056737928 ********** + 266 -229.0351037877 0.799E-04 0.1529260179 0.0056739936 ********** + 267 -229.0351050004 0.796E-04 0.1529322635 0.0056742089 ********** + 268 -229.0350967078 0.797E-04 0.1528746581 0.0056729665 ********** + 269 -229.0351026355 0.796E-04 0.1529150423 0.0056738614 ********** + 270 -229.0351230628 0.779E-04 0.1530556912 0.0056769102 ********** + 271 -229.0351203298 0.776E-04 0.1530419599 0.0056764050 ********** + 272 -229.0351215193 0.774E-04 0.1530448385 0.0056767493 ********** + 273 -229.0351230499 0.771E-04 0.1530500458 0.0056770847 ********** + 274 -229.0351218538 0.768E-04 0.1530446425 0.0056768214 ********** + 275 -229.0351268562 0.767E-04 0.1530817929 0.0056775566 ********** + 276 -229.0351378906 0.772E-04 0.1531517564 0.0056793334 ********** + 277 -229.0351327234 0.771E-04 0.1531132317 0.0056786351 ********** + 278 -229.0351382738 0.770E-04 0.1531542378 0.0056793959 ********** + 279 -229.0351467400 0.772E-04 0.1532131883 0.0056806018 ********** + 280 -229.0351470932 0.770E-04 0.1532231619 0.0056805078 ********** + 281 -229.0351440574 0.767E-04 0.1532084157 0.0056799551 ********** + 283 -229.0351436049 0.762E-04 0.1532208912 0.0056795961 ********** + 284 -229.0351405796 0.760E-04 0.1532012935 0.0056791094 ********** + 285 -229.0351359018 0.759E-04 0.1531645945 0.0056785028 ********** + 286 -229.0351313857 0.757E-04 0.1531348722 0.0056777817 ********** + 287 -229.0351298143 0.755E-04 0.1531227694 0.0056775563 ********** + 288 -229.0351296092 0.752E-04 0.1531278606 0.0056774004 ********** + 289 -229.0351247802 0.751E-04 0.1530915702 0.0056767409 ********** + 290 -229.0351267378 0.749E-04 0.1531118188 0.0056768989 ********** + 291 -229.0351271846 0.746E-04 0.1531119218 0.0056770210 ********** + 292 -229.0351076667 0.727E-04 0.1529986558 0.0056736558 ********** + 293 -229.0351111116 0.725E-04 0.1530294642 0.0056740092 ********** + 294 -229.0351106554 0.723E-04 0.1530266731 0.0056739120 ********** + 296 -229.0351231296 0.724E-04 0.1531146461 0.0056757070 ********** + 297 -229.0351263801 0.723E-04 0.1531339303 0.0056762587 ********** + 298 -229.0351221196 0.721E-04 0.1531103683 0.0056754993 ********** + 299 -229.0351202638 0.719E-04 0.1530965079 0.0056752437 ********** + 300 -229.0351176922 0.717E-04 0.1530830513 0.0056747639 ********** + 301 -229.0351203052 0.715E-04 0.1531023092 0.0056751511 ********** + 302 -229.0351278985 0.717E-04 0.1531672799 0.0056760215 ********** + 304 -229.0351229644 0.713E-04 0.1531295389 0.0056753587 ********** + 305 -229.0351213436 0.711E-04 0.1531153076 0.0056751712 ********** + 306 -229.0351201568 0.709E-04 0.1531040373 0.0056750471 ********** + 307 -229.0351182444 0.707E-04 0.1530962099 0.0056746452 ********** + 308 -229.0351180575 0.705E-04 0.1530935369 0.0056746501 ********** + 309 -229.0351150164 0.703E-04 0.1530702038 0.0056742541 ********** + 310 -229.0351139209 0.701E-04 0.1530708323 0.0056739053 ********** + 311 -229.0351204998 0.702E-04 0.1531140078 0.0056749187 ********** + 312 -229.0351147894 0.702E-04 0.1530733908 0.0056740796 ********** + 313 -229.0351126787 0.700E-04 0.1530577797 0.0056737722 ********** + 314 -229.0351114278 0.698E-04 0.1530485357 0.0056735831 ********** + 315 -229.0351096745 0.674E-04 0.1530493888 0.0056730218 ********** + 316 -229.0351089461 0.672E-04 0.1530476678 0.0056728252 ********** + 317 -229.0351039080 0.672E-04 0.1530133902 0.0056720522 ********** + 318 -229.0351021143 0.670E-04 0.1529971739 0.0056718681 ********** + 319 -229.0351031445 0.668E-04 0.1529974294 0.0056721914 ********** + 320 -229.0351032665 0.666E-04 0.1529972297 0.0056722681 ********** + 321 -229.0351054210 0.664E-04 0.1530043278 0.0056728031 ********** + 322 -229.0351084838 0.663E-04 0.1530336992 0.0056731250 ********** + 324 -229.0351130744 0.661E-04 0.1530706869 0.0056737256 ********** + 325 -229.0351126234 0.659E-04 0.1530654206 0.0056737354 ********** + 326 -229.0351109559 0.658E-04 0.1530523780 0.0056734992 ********** + 327 -229.0351081387 0.656E-04 0.1530347354 0.0056730231 ********** + 328 -229.0351095058 0.654E-04 0.1530430432 0.0056732622 ********** + 329 -229.0351118477 0.653E-04 0.1530578773 0.0056736255 ********** + 330 -229.0351106321 0.651E-04 0.1530500335 0.0056734237 ********** + 331 -229.0351090161 0.649E-04 0.1530398598 0.0056731506 ********** + 332 -229.0351088246 0.647E-04 0.1530353233 0.0056731755 ********** + 333 -229.0351126376 0.646E-04 0.1530655975 0.0056736653 ********** + 334 -229.0351094383 0.645E-04 0.1530415708 0.0056732458 ********** + 335 -229.0351063388 0.644E-04 0.1530185707 0.0056728117 ********** + 336 -229.0351060972 0.642E-04 0.1530201491 0.0056726964 ********** + 337 -229.0351041128 0.640E-04 0.1530090968 0.0056723506 ********** + 338 -229.0351055157 0.639E-04 0.1530197098 0.0056725338 ********** + 340 -229.0350912174 0.621E-04 0.1529228796 0.0056703274 ********** + 341 -229.0350874832 0.620E-04 0.1528971239 0.0056697713 ********** + 342 -229.0350885662 0.619E-04 0.1529045082 0.0056699161 ********** + 343 -229.0350908852 0.617E-04 0.1529268611 0.0056701272 ********** + 344 -229.0350893175 0.616E-04 0.1529116746 0.0056700048 ********** + 345 -229.0350842638 0.616E-04 0.1528773284 0.0056692367 ********** + 346 -229.0350850697 0.614E-04 0.1528857181 0.0056692870 ********** + 347 -229.0350886484 0.613E-04 0.1529147115 0.0056697544 ********** + 348 -229.0350913699 0.612E-04 0.1529391088 0.0056700237 ********** + 349 -229.0350944386 0.611E-04 0.1529599215 0.0056704863 ********** + 350 -229.0350922870 0.610E-04 0.1529447594 0.0056701577 ********** + 351 -229.0350920472 0.608E-04 0.1529418671 0.0056701277 ********** + 352 -229.0350958164 0.608E-04 0.1529713167 0.0056706271 ********** + 353 -229.0350971227 0.606E-04 0.1529851787 0.0056707261 ********** + 355 -229.0350985440 0.605E-04 0.1530015903 0.0056707960 ********** + 356 -229.0350989248 0.604E-04 0.1530001058 0.0056709518 ********** + 357 -229.0351008370 0.602E-04 0.1530152363 0.0056711826 ********** + 358 -229.0350947497 0.604E-04 0.1529743995 0.0056702341 ********** + 359 -229.0350962035 0.602E-04 0.1529848891 0.0056704161 ********** + 360 -229.0350957777 0.601E-04 0.1529816128 0.0056703439 ********** + 361 -229.0350951039 0.599E-04 0.1529804051 0.0056701482 ********** + 362 -229.0350954635 0.597E-04 0.1529751224 0.0056703917 ********** + 363 -229.0350948850 0.596E-04 0.1529698186 0.0056703208 ********** + 364 -229.0350963724 0.594E-04 0.1529820146 0.0056704712 ********** + 366 -229.0350893619 0.593E-04 0.1529344918 0.0056693980 ********** + 367 -229.0350864205 0.592E-04 0.1529137274 0.0056689686 ********** + 368 -229.0350915396 0.565E-04 0.1529225568 0.0056703814 ********** + 369 -229.0350876406 0.565E-04 0.1528949729 0.0056698089 ********** +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 18.910969 GB ] [ VIRT MEM : 27.213249 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 317304.884080 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 40933231 + +.. >>>>> [ RES MEM : 18.910969 GB ] [ VIRT MEM : 27.213249 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 317304.968734 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 40933231 +* Number of comb teeth 93 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9442099434099025 + +Summary at N_det = 41149068 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.00642088 +# PT2 -0.02866676 0.00005650 +# rPT2 -0.02850515 0.00005618 +# +# E+PT2 -229.03508764 0.00005650 +# E+rPT2 -229.03492602 0.00005618 +# ============ ============================= + + N_det = 41149068 + N_states = 1 + + * State 1 + < S^2 > = 4.304424303517339E-003 + E = -229.006420876445 + Variance = 0.152894972936187 + PT norm = 7.529813376923319E-002 + PT2 = -2.866676418048950E-002 + rPT2 = -2.850514545171115E-002 + E+PT2 = -229.035087640626 +/- 5.650241553239065E-005 + E+rPT2 = -229.034926021897 +/- 5.618386375885403E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.861798343180 + Vee = 238.462521778721 + Vecp = 0.000000000000000E+000 + T = 229.284625909225 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0291 -229.04054773 + -0.0294 -229.04085647 + -0.0297 -229.04072742 + -0.0300 -229.04133684 + -0.0303 -229.04242835 + -0.0312 -229.04142490 + -0.0328 -229.04154699 + =========== =================== + +* Number of unique beta determinants 2893073 +* Number of unique alpha determinants 2915145 + +.. >>>>> [ RES MEM : 30.067604 GB ] [ VIRT MEM : 39.915333 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 338081.699076 s ] [ CPU TIME: ************** s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 82298136 +* Number of threads for diagonalization 72 +* Memory(Gb) 116.1921725347638 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.0064208768 0.004304 0.519E-02 + 2 -229.0304772157 0.000706 0.268E-02 + 3 -229.0328931695 0.000632 0.256E-03 + 4 -229.0333576508 0.000644 0.373E-04 + 5 -229.0334657140 0.000667 0.866E-05 diff --git a/furan/6-31g/furan.natorb.out b/furan/6-31g/furan.natorb.out new file mode 100644 index 0000000..87e1cfd --- /dev/null +++ b/furan/6-31g/furan.natorb.out @@ -0,0 +1,164 @@ +Date: 15/12/2020 01:08:41 +=============== +Quantum Package +=============== + +Git Commit: Fix space in size for EZFIO.cfg +Git Date : Fri Oct 16 14:24:01 2020 +0200 +Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b +EZFIO Dir : furan + + +Task server running : tcp://172.28.1.83:41279 +.. >>>>> [ IO READ: n_states ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017433 GB ] [ VIRT MEM : 0.201935 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.028101 s ] [ CPU TIME: 0.033311 s ] <<<<< .. + +.. >>>>> [ IO READ: read_wf ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017433 GB ] [ VIRT MEM : 0.201935 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.031261 s ] [ CPU TIME: 0.033843 s ] <<<<< .. + +.. >>>>> [ IO READ: elec_beta_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017433 GB ] [ VIRT MEM : 0.201935 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.043946 s ] [ CPU TIME: 0.035085 s ] <<<<< .. + +* mo_num 53 +.. >>>>> [ IO READ: elec_alpha_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017635 GB ] [ VIRT MEM : 0.201935 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.057191 s ] [ CPU TIME: 0.036131 s ] <<<<< .. + + Read mo_occ +.. >>>>> [ IO READ: mo_class ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019489 GB ] [ VIRT MEM : 4.921257 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.205531 s ] [ CPU TIME: 7.408546 s ] <<<<< .. + +* Number of virtual MOs 0 + Virtual MOs: + +.. >>>>> [ IO READ: ao_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019489 GB ] [ VIRT MEM : 4.921257 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.232030 s ] [ CPU TIME: 9.205525 s ] <<<<< .. + + Read mo_coef + * mo_label Canonical +* Number of determinants 10481654 +* Dimension of the psi arrays 10481654 +* N_int 1 + Read psi_det +* Number of unique beta determinants 970338 +* Number of unique alpha determinants 982000 + Read psi_coef 10481654 1 +.. >>>>> [ IO READ: weight_one_e_dm ] <<<<< .. + +.. >>>>> [ RES MEM : 1.642048 GB ] [ VIRT MEM : 6.611076 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 66.388321 s ] [ CPU TIME: 1388.545005 s ] <<<<< .. + +* Number of active MOs 48 +* Number of core MOs 5 +* Number of inactive MOs 0 + Core MOs: + 1 2 3 4 5 + Active MOs: + 6 7 8 9 10 11 + 12 13 14 15 16 17 + 18 19 20 21 22 23 + 24 25 26 27 28 29 + 30 31 32 33 34 35 + 36 37 38 39 40 41 + 42 43 44 45 46 47 + 48 49 50 51 52 53 + Core, Inactive and Active MOs: + 1 2 3 4 5 6 + 7 8 9 10 11 12 + 13 14 15 16 17 18 + 19 20 21 22 23 24 + 25 26 27 28 29 30 + 31 32 33 34 35 36 + 37 38 39 40 41 42 + 43 44 45 46 47 48 + 49 50 51 52 53 + +.. >>>>> [ RES MEM : 1.642147 GB ] [ VIRT MEM : 6.611076 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 66.407135 s ] [ CPU TIME: 1389.878851 s ] <<<<< .. + +MOs are now **Natural** + +Eigenvalues +----------- + +======== ================ ================ + MO Eigenvalue Cumulative +======== ================ ================ + 1 2.0000000000 2.0000000000 + 2 2.0000000000 4.0000000000 + 3 2.0000000000 6.0000000000 + 4 2.0000000000 8.0000000000 + 5 2.0000000000 10.0000000000 + 6 1.9915369807 11.9915369807 + 7 1.9887530164 13.9802899972 + 8 1.9861057283 15.9663957255 + 9 1.9834030984 17.9497988239 + 10 1.9821746490 19.9319734729 + 11 1.9819784855 21.9139519583 + 12 1.9786516965 23.8926036548 + 13 1.9774347935 25.8700384483 + 14 1.9758355001 27.8458739484 + 15 1.9750197646 29.8208937130 + 16 1.9717971271 31.7926908401 + 17 1.9452425628 33.7379334029 + 18 1.9171585410 35.6550919440 + 19 0.0832459252 35.7383378692 + 20 0.0524312968 35.7907691660 + 21 0.0236936793 35.8144628453 + 22 0.0222513395 35.8367141848 + 23 0.0167661833 35.8534803681 + 24 0.0163121799 35.8697925480 + 25 0.0140792631 35.8838718111 + 26 0.0136983921 35.8975702032 + 27 0.0135010782 35.9110712814 + 28 0.0124794808 35.9235507622 + 29 0.0107941342 35.9343448964 + 30 0.0094954586 35.9438403550 + 31 0.0089435136 35.9527838686 + 32 0.0052929017 35.9580767703 + 33 0.0047668196 35.9628435899 + 34 0.0041722529 35.9670158428 + 35 0.0038807810 35.9708966238 + 36 0.0038739635 35.9747705874 + 37 0.0035199336 35.9782905209 + 38 0.0032878393 35.9815783602 + 39 0.0025639989 35.9841423591 + 40 0.0021653273 35.9863076865 + 41 0.0021538165 35.9884615030 + 42 0.0019697575 35.9904312604 + 43 0.0019223144 35.9923535748 + 44 0.0017124643 35.9940660391 + 45 0.0012998635 35.9953659026 + 46 0.0010679906 35.9964338933 + 47 0.0008748179 35.9973087111 + 48 0.0007982420 35.9981069531 + 49 0.0005391501 35.9986461032 + 50 0.0005292977 35.9991754009 + 51 0.0002955328 35.9994709338 + 52 0.0002893535 35.9997602872 + 53 0.0002397128 36.0000000000 +======== ================ ================ + + +.. >>>>> [ RES MEM : 1.644325 GB ] [ VIRT MEM : 6.685276 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 66.421185 s ] [ CPU TIME: 1390.874365 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_md5 ] <<<<< .. + +.. >>>>> [ RES MEM : 1.644325 GB ] [ VIRT MEM : 6.685276 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 66.422218 s ] [ CPU TIME: 1390.947249 s ] <<<<< .. + +* Saved determinants 1 +Wall time: 0:01:11 + diff --git a/furan/6-31g/furan.nofci.out b/furan/6-31g/furan.nofci.out new file mode 100644 index 0000000..1acedfc --- /dev/null +++ b/furan/6-31g/furan.nofci.out @@ -0,0 +1,5073 @@ +Date: 15/12/2020 01:09:53 +=============== +Quantum Package +=============== + +Git Commit: Fix space in size for EZFIO.cfg +Git Date : Fri Oct 16 14:24:01 2020 +0200 +Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b +EZFIO Dir : furan + + +Task server running : tcp://172.28.1.83:41279 +* mo_num 53 +.. >>>>> [ IO READ: mo_class ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019249 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.000958 s ] [ CPU TIME: 2.299821 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_two_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019249 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.002588 s ] [ CPU TIME: 2.373791 s ] <<<<< .. + +* N_int 1 + MO map initialized: 1024596 +.. >>>>> [ IO READ: io_ao_two_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019459 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.018877 s ] [ CPU TIME: 3.107161 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019459 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.020167 s ] [ CPU TIME: 3.165970 s ] <<<<< .. + + AO map initialized : 1024596 +.. >>>>> [ IO READ: ao_power ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019562 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.035025 s ] [ CPU TIME: 3.849277 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_prim_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019604 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.038010 s ] [ CPU TIME: 3.996582 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_expo ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019627 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.041096 s ] [ CPU TIME: 4.156307 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_coef ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019650 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.044545 s ] [ CPU TIME: 4.355135 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_nucl ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019806 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.048434 s ] [ CPU TIME: 4.591211 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_integrals_threshold ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019806 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.049212 s ] [ CPU TIME: 4.639316 s ] <<<<< .. + + Providing the AO integrals +.. >>>>> [ IO READ: nucl_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.021282 GB ] [ VIRT MEM : 5.058784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.089000 s ] [ CPU TIME: 6.684405 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_label ] <<<<< .. + +.. >>>>> [ RES MEM : 0.021416 GB ] [ VIRT MEM : 5.058784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.092246 s ] [ CPU TIME: 6.895084 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_charge ] <<<<< .. + +.. >>>>> [ RES MEM : 0.021446 GB ] [ VIRT MEM : 5.058784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.095276 s ] [ CPU TIME: 7.092536 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.021458 GB ] [ VIRT MEM : 5.058784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.098268 s ] [ CPU TIME: 7.288249 s ] <<<<< .. + + +Nuclear Coordinates (Angstroms) +=============================== + +================ ============ ============ ============ ============ + Atom Charge X Y Z +================ ============ ============ ============ ============ +C 6.000000 0.000000 1.092041 -0.317778 +C 6.000000 0.000000 -1.092041 -0.317778 +C 6.000000 0.000000 0.716234 0.986050 +C 6.000000 0.000000 -0.716234 0.986050 +O 8.000000 0.000000 0.000000 -1.132150 +H 1.000000 0.000000 2.044409 -0.813693 +H 1.000000 0.000000 -2.044409 -0.813693 +H 1.000000 0.000000 1.371462 1.837134 +H 1.000000 0.000000 -1.371462 1.837134 +================ ============ ============ ============ ============ + + Sorting the map + AO integrals provided: + Size of AO map : 7.19726371765137 MB + Number of AO integrals : 580388 + cpu time : 42.8951900000000 s + wall time : 0.709718942642212 s ( x 60.4396859414595 ) + + AO -> MO integrals transformation + --------------------------------- + + Read mo_coef +.. >>>>> [ IO READ: mo_integrals_threshold ] <<<<< .. + +.. >>>>> [ RES MEM : 0.030418 GB ] [ VIRT MEM : 5.134060 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.781892 s ] [ CPU TIME: 49.019552 s ] <<<<< .. + + Buffers : 4.587036 MB / core + 33.96227 % in 1.26099109649658 s 17.3644523620605 MB + Molecular integrals provided: + Size of MO map 17.2086219787598 MB + Number of MO integrals: 872151 + cpu time : 82.8504130000000 s + wall time : 1.47565293312073 s ( x 56.1449180497930 ) +.. >>>>> [ IO READ: n_states ] <<<<< .. + +.. >>>>> [ RES MEM : 0.436756 GB ] [ VIRT MEM : 5.715717 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.236773 s ] [ CPU TIME: 130.544062 s ] <<<<< .. + + * mo_label Natural +.. >>>>> [ IO READ: read_wf ] <<<<< .. + +.. >>>>> [ RES MEM : 0.436756 GB ] [ VIRT MEM : 5.715717 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.238052 s ] [ CPU TIME: 130.635337 s ] <<<<< .. + +* Number of determinants 1 +* Dimension of the psi arrays 100000 + Read psi_coef 1 1 +.. >>>>> [ IO READ: elec_beta_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.437561 GB ] [ VIRT MEM : 5.719627 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.243875 s ] [ CPU TIME: 131.049939 s ] <<<<< .. + +.. >>>>> [ IO READ: elec_alpha_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.437561 GB ] [ VIRT MEM : 5.719627 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.244682 s ] [ CPU TIME: 131.107870 s ] <<<<< .. + + Read psi_det +.. >>>>> [ IO READ: do_pt2 ] <<<<< .. + +.. >>>>> [ RES MEM : 0.439091 GB ] [ VIRT MEM : 5.719627 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.260157 s ] [ CPU TIME: 132.206939 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.439163 GB ] [ VIRT MEM : 5.719627 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.289361 s ] [ CPU TIME: 134.252144 s ] <<<<< .. + +.. >>>>> [ IO READ: selection_factor ] <<<<< .. + +.. >>>>> [ RES MEM : 0.439163 GB ] [ VIRT MEM : 5.719627 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.290130 s ] [ CPU TIME: 134.307307 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_max ] <<<<< .. + +.. >>>>> [ RES MEM : 0.439163 GB ] [ VIRT MEM : 5.719627 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.291029 s ] [ CPU TIME: 134.371509 s ] <<<<< .. + +.. >>>>> [ IO READ: s2_eig ] <<<<< .. + +.. >>>>> [ RES MEM : 0.441345 GB ] [ VIRT MEM : 5.719627 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.292539 s ] [ CPU TIME: 134.479580 s ] <<<<< .. + +.. >>>>> [ IO READ: variance_max ] <<<<< .. + +.. >>>>> [ RES MEM : 0.441345 GB ] [ VIRT MEM : 5.719627 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.293295 s ] [ CPU TIME: 134.533608 s ] <<<<< .. + +.. >>>>> [ IO READ: distributed_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 0.441345 GB ] [ VIRT MEM : 5.719627 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.311538 s ] [ CPU TIME: 135.826221 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_max_full ] <<<<< .. + +.. >>>>> [ RES MEM : 0.441345 GB ] [ VIRT MEM : 5.719627 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.312290 s ] [ CPU TIME: 135.880193 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_integrals_e_n ] <<<<< .. + +.. >>>>> [ RES MEM : 0.516403 GB ] [ VIRT MEM : 7.594627 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.360907 s ] [ CPU TIME: 139.370673 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_integrals_e_n ] <<<<< .. + +.. >>>>> [ RES MEM : 0.516403 GB ] [ VIRT MEM : 7.594627 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.371047 s ] [ CPU TIME: 140.090138 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_integrals_kinetic ] <<<<< .. + +.. >>>>> [ RES MEM : 0.518436 GB ] [ VIRT MEM : 7.660847 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.396267 s ] [ CPU TIME: 141.101551 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_integrals_kinetic ] <<<<< .. + +.. >>>>> [ RES MEM : 0.518436 GB ] [ VIRT MEM : 7.660847 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.397171 s ] [ CPU TIME: 141.164654 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_one_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.518436 GB ] [ VIRT MEM : 7.660847 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.400847 s ] [ CPU TIME: 141.420729 s ] <<<<< .. + + Providing the one-electron integrals +.. >>>>> [ IO READ: do_pseudo ] <<<<< .. + +.. >>>>> [ RES MEM : 0.518616 GB ] [ VIRT MEM : 7.660847 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.414428 s ] [ CPU TIME: 142.368883 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_relative_error ] <<<<< .. + +.. >>>>> [ RES MEM : 0.518616 GB ] [ VIRT MEM : 7.660847 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.417812 s ] [ CPU TIME: 142.605460 s ] <<<<< .. + +.. >>>>> [ IO READ: correlation_energy_ratio_max ] <<<<< .. + +.. >>>>> [ RES MEM : 0.518616 GB ] [ VIRT MEM : 7.660847 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.418631 s ] [ CPU TIME: 142.663850 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.518616 GB ] [ VIRT MEM : 7.660847 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.419461 s ] [ CPU TIME: 142.722062 s ] <<<<< .. + + Read n_states_diag +.. >>>>> [ IO READ: io_nuclear_repulsion ] <<<<< .. + +.. >>>>> [ RES MEM : 0.518616 GB ] [ VIRT MEM : 7.660847 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.420897 s ] [ CPU TIME: 142.822697 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.518616 GB ] [ VIRT MEM : 7.660847 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.421255 s ] [ CPU TIME: 142.848448 s ] <<<<< .. + +* Nuclear repulsion energy 161.1082297787890 +.. >>>>> [ IO READ: weight_one_e_dm ] <<<<< .. + +.. >>>>> [ RES MEM : 0.518616 GB ] [ VIRT MEM : 7.660847 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.422106 s ] [ CPU TIME: 142.908156 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_max ] <<<<< .. + +.. >>>>> [ RES MEM : 0.522240 GB ] [ VIRT MEM : 7.664757 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.429406 s ] [ CPU TIME: 143.422409 s ] <<<<< .. + +.. >>>>> [ IO READ: threshold_generators ] <<<<< .. + +.. >>>>> [ RES MEM : 0.522240 GB ] [ VIRT MEM : 7.664757 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.430197 s ] [ CPU TIME: 143.478205 s ] <<<<< .. + +* Target maximum memory (GB) 170 +.. >>>>> [ IO READ: threshold_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 0.522491 GB ] [ VIRT MEM : 7.664757 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.431205 s ] [ CPU TIME: 143.549273 s ] <<<<< .. + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 0.522491 GB ] [ VIRT MEM : 7.664757 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.432500 s ] [ CPU TIME: 143.640316 s ] <<<<< .. + +* Energy of state 1 -228.5220391118149 +* S^2 of state 1 0.000000000000000 +* Saved determinants 1 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 1 +* Number of unique alpha determinants 1 +.. >>>>> [ IO READ: weight_selection ] <<<<< .. + +.. >>>>> [ RES MEM : 0.522629 GB ] [ VIRT MEM : 7.668919 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.501060 s ] [ CPU TIME: 148.442796 s ] <<<<< .. + + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +.. >>>>> [ IO READ: pseudo_sym ] <<<<< .. + +.. >>>>> [ RES MEM : 0.522629 GB ] [ VIRT MEM : 7.668919 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.501975 s ] [ CPU TIME: 148.508152 s ] <<<<< .. + +.. >>>>> [ IO READ: h0_type ] <<<<< .. + +.. >>>>> [ RES MEM : 0.522629 GB ] [ VIRT MEM : 7.670418 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.502910 s ] [ CPU TIME: 148.575075 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.522629 GB ] [ VIRT MEM : 7.670418 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.503287 s ] [ CPU TIME: 148.602575 s ] <<<<< .. + +* Number of generators 1 + +.. >>>>> [ RES MEM : 0.522629 GB ] [ VIRT MEM : 7.670418 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.503668 s ] [ CPU TIME: 148.629865 s ] <<<<< .. + +* Number of selectors 1 +* Number of comb teeth 1 +* Number of core MOs 5 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.5220391118149 +* Estimated memory/thread (Gb) 0.1043081283569336E-06 +* Number of virtual MOs 0 +* Number of active MOs 48 + Active MOs: + 6 7 8 9 10 11 + 12 13 14 15 16 17 + 18 19 20 21 22 23 + 24 25 26 27 28 29 + 30 31 32 33 34 35 + 36 37 38 39 40 41 + 42 43 44 45 46 47 + 48 49 50 51 52 53 +* Number of inactive MOs 0 +.. >>>>> [ IO READ: pert_2rdm ] <<<<< .. + +.. >>>>> [ RES MEM : 0.524601 GB ] [ VIRT MEM : 7.676674 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.534637 s ] [ CPU TIME: 150.142472 s ] <<<<< .. + +.. >>>>> [ IO READ: pruning ] <<<<< .. + +.. >>>>> [ RES MEM : 0.524841 GB ] [ VIRT MEM : 7.676674 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.685630 s ] [ CPU TIME: 160.300916 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.525047 GB ] [ VIRT MEM : 7.676674 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.690422 s ] [ CPU TIME: 160.645562 s ] <<<<< .. + +* Number of generators 1 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Saved determinants 5 +* Number of unique beta determinants 5 +* Number of unique alpha determinants 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.525097 GB ] [ VIRT MEM : 7.676678 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.736829 s ] [ CPU TIME: 163.939578 s ] <<<<< .. + +* Number of selectors 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio -0.4067278618377695E-02 + +Summary at N_det = 5 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.52203911 +# PT2 -0.66884635 0.00000000 +# rPT2 -0.48162356 0.00000000 +# +# E+PT2 -229.19088546 0.00000000 +# E+rPT2 -229.00366267 0.00000000 +# ============ ============================= + + N_det = 5 + N_states = 1 + + * State 1 + < S^2 > = 0.000000000000000E+000 + E = -228.522039111815 + Variance = 1.36119090968189 + PT norm = 0.623484261596316 + PT2 = -0.668846350754778 + rPT2 = -0.481623560198042 + E+PT2 = -229.190885462570 +/- 0.000000000000000E+000 + E+rPT2 = -229.003662672013 +/- 0.000000000000000E+000 + + ----- +.. >>>>> [ IO READ: io_mo_integrals_pseudo ] <<<<< .. + +.. >>>>> [ RES MEM : 0.525097 GB ] [ VIRT MEM : 7.676678 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.739288 s ] [ CPU TIME: 164.113909 s ] <<<<< .. + + Energy components + ================= + + Vnn : Nucleus-Nucleus potential energy + Ven : Electron-Nucleus potential energy + Vee : Electron-Electron potential energy + Vecp : Potential energy of the pseudo-potentials + T : Electronic kinetic energy + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.612942612462 + Vee = 239.226253338923 + Vecp = 0.000000000000000E+000 + T = 228.756420382935 + + +.. >>>>> [ IO READ: energy_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 0.525360 GB ] [ VIRT MEM : 7.676678 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.770984 s ] [ CPU TIME: 166.347990 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 0.525360 GB ] [ VIRT MEM : 7.676678 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.774321 s ] [ CPU TIME: 166.573759 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 0.525360 GB ] [ VIRT MEM : 7.676678 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.777695 s ] [ CPU TIME: 166.802795 s ] <<<<< .. + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 0.525597 GB ] [ VIRT MEM : 7.676678 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.803180 s ] [ CPU TIME: 168.573309 s ] <<<<< .. + +* Energy of state 1 -228.5534186588093 +* S^2 of state 1 0.000000000000000 +* Saved determinants 5 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 5 +* Number of unique alpha determinants 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.525768 GB ] [ VIRT MEM : 7.676678 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.856470 s ] [ CPU TIME: 172.298430 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 0.525768 GB ] [ VIRT MEM : 7.676678 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.856866 s ] [ CPU TIME: 172.326677 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.5534186588093 + +.. >>>>> [ RES MEM : 0.528282 GB ] [ VIRT MEM : 7.682087 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.861986 s ] [ CPU TIME: 172.688871 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 0.528282 GB ] [ VIRT MEM : 7.682087 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.862369 s ] [ CPU TIME: 172.716274 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 5 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1576246134936809E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 4 -229.1575946328 0.00 1.2934382920 0.3260104467 0.1075 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.529926 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.983545 s ] [ CPU TIME: 180.504023 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 0.529926 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.983953 s ] [ CPU TIME: 180.533677 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.6066961574454823E-01 + +Summary at N_det = 5 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.55341866 +# PT2 -0.60417597 0.00000000 +# rPT2 -0.45563440 0.00000000 +# +# E+PT2 -229.15759463 0.00000000 +# E+rPT2 -229.00905306 0.00000000 +# ============ ============================= + + N_det = 5 + N_states = 1 + + * State 1 + < S^2 > = 0.000000000000000E+000 + E = -228.553418658809 + Variance = 1.29343829195560 + PT norm = 0.570973245205487 + PT2 = -0.604175974009506 + rPT2 = -0.455634399785200 + E+PT2 = -229.157594632819 +/- 0.000000000000000E+000 + E+rPT2 = -229.009053058594 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.706856698637 + Vee = 239.219582875531 + Vecp = 0.000000000000000E+000 + T = 228.825625385508 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4816 -229.10355575 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 0.530346 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.025772 s ] [ CPU TIME: 183.499658 s ] <<<<< .. + +* Energy of state 1 -228.5792854825897 +* S^2 of state 1 0.5417426093245142E-01 +* Saved determinants 10 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 7 +* Number of unique alpha determinants 7 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.530521 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.081459 s ] [ CPU TIME: 187.433729 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 0.530521 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.081880 s ] [ CPU TIME: 187.463640 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.5792854825897 + +.. >>>>> [ RES MEM : 0.530521 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.085150 s ] [ CPU TIME: 187.694864 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 0.530521 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.085532 s ] [ CPU TIME: 187.722241 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 10 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1608791574835777E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 9 -229.1196791608 0.00 1.2332673009 0.2603244388 0.1241 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.530560 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.221864 s ] [ CPU TIME: 196.575830 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 0.530560 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.222255 s ] [ CPU TIME: 196.604315 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1142304567255497 + +Summary at N_det = 10 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.57928548 +# PT2 -0.54039368 0.00000000 +# rPT2 -0.42877347 0.00000000 +# +# E+PT2 -229.11967916 0.00000000 +# E+rPT2 -229.00805895 0.00000000 +# ============ ============================= + + N_det = 10 + N_states = 1 + + * State 1 + < S^2 > = 5.417426093245142E-002 + E = -228.579285482590 + Variance = 1.23326730087074 + PT norm = 0.510219990555514 + PT2 = -0.540393678248588 + rPT2 = -0.428773466282388 + E+PT2 = -229.119679160838 +/- 0.000000000000000E+000 + E+rPT2 = -229.008058948872 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.772740993151 + Vee = 239.203003340697 + Vecp = 0.000000000000000E+000 + T = 228.882222391075 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4556 -228.99219026 + -0.4816 -229.04449631 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 0.530598 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.263080 s ] [ CPU TIME: 199.458772 s ] <<<<< .. + +* Energy of state 1 -228.6000728465838 +* S^2 of state 1 0.5305165973812025E-01 +* Saved determinants 20 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 11 +* Number of unique alpha determinants 10 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.530697 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.313976 s ] [ CPU TIME: 202.991769 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 0.530697 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.314363 s ] [ CPU TIME: 203.019211 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.6000728465838 + +.. >>>>> [ RES MEM : 0.530697 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.317610 s ] [ CPU TIME: 203.245405 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 0.530697 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.318007 s ] [ CPU TIME: 203.272990 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 20 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1673882454633713E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 19 -229.1003344716 0.00 1.1722773477 0.2331146053 0.1391 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.531494 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.471397 s ] [ CPU TIME: 213.617592 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 0.531494 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.471787 s ] [ CPU TIME: 213.646287 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1579226947693455 + +Summary at N_det = 20 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.60007285 +# PT2 -0.50026163 0.00000000 +# rPT2 -0.40568948 0.00000000 +# +# E+PT2 -229.10033447 0.00000000 +# E+rPT2 -229.00576233 0.00000000 +# ============ ============================= + + N_det = 20 + N_states = 1 + + * State 1 + < S^2 > = 5.305165973812025E-002 + E = -228.600072846584 + Variance = 1.17227734773750 + PT norm = 0.482819433432809 + PT2 = -0.500261625039507 + rPT2 = -0.405689481650123 + E+PT2 = -229.100334471623 +/- 0.000000000000000E+000 + E+rPT2 = -229.005762328234 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.790485194076 + Vee = 239.179005814985 + Vecp = 0.000000000000000E+000 + T = 228.903176753718 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4288 -228.96540037 + -0.4556 -228.97962721 + -0.4816 -229.01645248 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 0.532318 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.513598 s ] [ CPU TIME: 216.607943 s ] <<<<< .. + +* Energy of state 1 -228.6204435129727 +* S^2 of state 1 0.6108108663124758E-01 +* Saved determinants 40 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 17 +* Number of unique alpha determinants 17 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.532375 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.567250 s ] [ CPU TIME: 220.356527 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 0.532375 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.567633 s ] [ CPU TIME: 220.384418 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.6204435129727 + +.. >>>>> [ RES MEM : 0.532375 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.570848 s ] [ CPU TIME: 220.614427 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 0.532375 GB ] [ VIRT MEM : 7.682865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.571234 s ] [ CPU TIME: 220.642633 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 40 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1804064214229584E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 39 -229.0835548246 0.00 1.1105287110 0.2097773994 0.2130 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.532730 GB ] [ VIRT MEM : 7.683006 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.797850 s ] [ CPU TIME: 235.600222 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 0.532730 GB ] [ VIRT MEM : 7.683006 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.798272 s ] [ CPU TIME: 235.630915 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.2012547293729836 + +Summary at N_det = 40 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.62044351 +# PT2 -0.46311131 0.00000000 +# rPT2 -0.38280705 0.00000000 +# +# E+PT2 -229.08355482 0.00000000 +# E+rPT2 -229.00325056 0.00000000 +# ============ ============================= + + N_det = 40 + N_states = 1 + + * State 1 + < S^2 > = 6.108108663124758E-002 + E = -228.620443512973 + Variance = 1.11052871095780 + PT norm = 0.458014627963415 + PT2 = -0.463111311610681 + rPT2 = -0.382807045188205 + E+PT2 = -229.083554824583 +/- 0.000000000000000E+000 + E+rPT2 = -229.003250558161 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.806309104432 + Vee = 239.148507685658 + Vecp = 0.000000000000000E+000 + T = 228.929128127013 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4057 -228.96123041 + -0.4288 -228.96324884 + -0.4556 -228.97271476 + -0.4816 -228.99958268 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 0.534168 GB ] [ VIRT MEM : 7.694889 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.840158 s ] [ CPU TIME: 238.573088 s ] <<<<< .. + +* Energy of state 1 -228.6473283800480 +* S^2 of state 1 0.4367762803356989E-01 +* Saved determinants 80 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 28 +* Number of unique alpha determinants 28 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.534332 GB ] [ VIRT MEM : 7.694889 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.894903 s ] [ CPU TIME: 242.419917 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 0.534332 GB ] [ VIRT MEM : 7.694889 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.895283 s ] [ CPU TIME: 242.447569 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.6473283800480 + +.. >>>>> [ RES MEM : 0.534332 GB ] [ VIRT MEM : 7.694889 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.898813 s ] [ CPU TIME: 242.700285 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 0.534332 GB ] [ VIRT MEM : 7.694889 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3.899193 s ] [ CPU TIME: 242.727968 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 80 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2064427733421326E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 76 -229.0666349695 0.00 1.0403795359 0.1827762641 0.3201 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.535641 GB ] [ VIRT MEM : 7.710514 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.234211 s ] [ CPU TIME: 265.427469 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 0.535641 GB ] [ VIRT MEM : 7.710514 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.234596 s ] [ CPU TIME: 265.455255 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.2581115781829105 + +Summary at N_det = 80 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.64732838 +# PT2 -0.41930659 0.00000000 +# rPT2 -0.35451049 0.00000000 +# +# E+PT2 -229.06663497 0.00000000 +# E+rPT2 -229.00183887 0.00000000 +# ============ ============================= + + N_det = 80 + N_states = 1 + + * State 1 + < S^2 > = 4.367762803356989E-002 + E = -228.647328380048 + Variance = 1.04037953586280 + PT norm = 0.427523407667915 + PT2 = -0.419306589413886 + rPT2 = -0.354510487012125 + E+PT2 = -229.066634969462 +/- 0.000000000000000E+000 + E+rPT2 = -229.001838867060 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.805760853197 + Vee = 239.100805839059 + Vecp = 0.000000000000000E+000 + T = 228.949396855301 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3828 -228.98415264 + -0.4057 -228.97480528 + -0.4288 -228.97115493 + -0.4556 -228.97434586 + -0.4816 -228.99185280 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 0.536526 GB ] [ VIRT MEM : 7.710583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.282155 s ] [ CPU TIME: 268.802445 s ] <<<<< .. + +* Energy of state 1 -228.6783522273296 +* S^2 of state 1 0.2449384594525392E-01 +* Saved determinants 160 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 55 +* Number of unique alpha determinants 55 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.536602 GB ] [ VIRT MEM : 7.710583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.338183 s ] [ CPU TIME: 272.723344 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 0.536602 GB ] [ VIRT MEM : 7.710583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.338571 s ] [ CPU TIME: 272.751261 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.6783522273296 + +.. >>>>> [ RES MEM : 0.536602 GB ] [ VIRT MEM : 7.710583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.342295 s ] [ CPU TIME: 273.014756 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 0.536602 GB ] [ VIRT MEM : 7.710583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.342675 s ] [ CPU TIME: 273.041987 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 160 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2585154771804809E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 154 -229.0538755623 0.00 0.9695955220 0.1557641925 0.4646 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.536606 GB ] [ VIRT MEM : 7.710583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.821892 s ] [ CPU TIME: 305.939485 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 0.536606 GB ] [ VIRT MEM : 7.710583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.822279 s ] [ CPU TIME: 305.967602 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.3220738782699640 + +Summary at N_det = 160 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.67835223 +# PT2 -0.37552333 0.00000000 +# rPT2 -0.32491345 0.00000000 +# +# E+PT2 -229.05387556 0.00000000 +# E+rPT2 -229.00326568 0.00000000 +# ============ ============================= + + N_det = 160 + N_states = 1 + + * State 1 + < S^2 > = 2.449384594525392E-002 + E = -228.678352227330 + Variance = 0.969595522032378 + PT norm = 0.394669725909685 + PT2 = -0.375523334996460 + rPT2 = -0.324913453295392 + E+PT2 = -229.053875562326 +/- 0.000000000000000E+000 + E+rPT2 = -229.003265680625 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.808727805229 + Vee = 239.051391546208 + Vecp = 0.000000000000000E+000 + T = 228.970754252903 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3545 -229.01892911 + -0.3828 -229.00300748 + -0.4057 -228.99212280 + -0.4288 -228.98537373 + -0.4556 -228.98381678 + -0.4816 -228.99372469 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 0.544926 GB ] [ VIRT MEM : 7.710743 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.925828 s ] [ CPU TIME: 313.261424 s ] <<<<< .. + +* Energy of state 1 -228.7134945268671 +* S^2 of state 1 0.2504485633912035E-01 +* Saved determinants 320 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 95 +* Number of unique alpha determinants 95 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.545094 GB ] [ VIRT MEM : 7.710743 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.981491 s ] [ CPU TIME: 317.082806 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 0.545094 GB ] [ VIRT MEM : 7.710743 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.981882 s ] [ CPU TIME: 317.110799 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.7134945268671 + +.. >>>>> [ RES MEM : 0.545094 GB ] [ VIRT MEM : 7.710743 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.985643 s ] [ CPU TIME: 317.376629 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 0.545094 GB ] [ VIRT MEM : 7.710743 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.986019 s ] [ CPU TIME: 317.403447 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 320 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.3626608848571777E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 313 -229.0438397320 0.00 0.8869222802 0.1316527099 0.8730 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.545238 GB ] [ VIRT MEM : 7.710743 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5.877534 s ] [ CPU TIME: 378.100350 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 0.545238 GB ] [ VIRT MEM : 7.710743 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 5.877935 s ] [ CPU TIME: 378.129352 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.3936377470941339 + +Summary at N_det = 320 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.71349453 +# PT2 -0.33034521 0.00000000 +# rPT2 -0.29191394 0.00000000 +# +# E+PT2 -229.04383973 0.00000000 +# E+rPT2 -229.00540847 0.00000000 +# ============ ============================= + + N_det = 320 + N_states = 1 + + * State 1 + < S^2 > = 2.504485633912035E-002 + E = -228.713494526867 + Variance = 0.886922280194933 + PT norm = 0.362839785401062 + PT2 = -0.330345205100851 + rPT2 = -0.291913943403036 + E+PT2 = -229.043839731968 +/- 0.000000000000000E+000 + E+rPT2 = -229.005408470270 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.807455159386 + Vee = 238.993426933590 + Vecp = 0.000000000000000E+000 + T = 228.992303920140 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3249 -229.02436361 + -0.3545 -229.02201690 + -0.3828 -229.01257082 + -0.4057 -229.00384711 + -0.4288 -228.99715579 + -0.4556 -228.99373330 + -0.4816 -228.99881803 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 0.556473 GB ] [ VIRT MEM : 7.841503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6.096641 s ] [ CPU TIME: 393.747785 s ] <<<<< .. + +* Energy of state 1 -228.7536552847379 +* S^2 of state 1 0.2787556774369790E-01 +* Saved determinants 640 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 160 +* Number of unique alpha determinants 159 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.556473 GB ] [ VIRT MEM : 7.841503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6.156800 s ] [ CPU TIME: 397.864187 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 0.556473 GB ] [ VIRT MEM : 7.841503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6.157187 s ] [ CPU TIME: 397.892830 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.7536552847379 + +.. >>>>> [ RES MEM : 0.556473 GB ] [ VIRT MEM : 7.841503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6.161047 s ] [ CPU TIME: 398.169363 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 0.556473 GB ] [ VIRT MEM : 7.841503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6.161427 s ] [ CPU TIME: 398.197063 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 640 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.5709517002105713E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 424 -229.0306559580 0.506E-02 0.7828165617 0.1052221051 1.0013 + 626 -229.0356713282 0.00 0.7949317785 0.1071506994 1.3515 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.557274 GB ] [ VIRT MEM : 7.841503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.528294 s ] [ CPU TIME: 490.828106 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 0.557274 GB ] [ VIRT MEM : 7.841503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.528699 s ] [ CPU TIME: 490.856947 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.4741352230044054 + +Summary at N_det = 640 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.75365528 +# PT2 -0.28201604 0.00000000 +# rPT2 -0.25472236 0.00000000 +# +# E+PT2 -229.03567133 0.00000000 +# E+rPT2 -229.00837765 0.00000000 +# ============ ============================= + + N_det = 640 + N_states = 1 + + * State 1 + < S^2 > = 2.787556774369790E-002 + E = -228.753655284738 + Variance = 0.794931778505677 + PT norm = 0.327338814412063 + PT2 = -0.282016043490233 + rPT2 = -0.254722364026681 + E+PT2 = -229.035671328228 +/- 0.000000000000000E+000 + E+rPT2 = -229.008377648765 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.800893917500 + Vee = 238.922673503149 + Vecp = 0.000000000000000E+000 + T = 229.016335350824 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2919 -229.02871333 + -0.3249 -229.02688494 + -0.3545 -229.02489950 + -0.3828 -229.01877053 + -0.4057 -229.01219855 + -0.4288 -229.00646587 + -0.4556 -229.00263603 + =========== =================== + +* Number of unique alpha determinants 256 +* Number of unique beta determinants 256 +.. >>>>> [ IO READ: davidson_sze_max ] <<<<< .. + +.. >>>>> [ RES MEM : 0.557491 GB ] [ VIRT MEM : 7.841503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.576906 s ] [ CPU TIME: 494.162423 s ] <<<<< .. + +.. >>>>> [ IO READ: state_following ] <<<<< .. + +.. >>>>> [ RES MEM : 0.557491 GB ] [ VIRT MEM : 7.841503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.578049 s ] [ CPU TIME: 494.240902 s ] <<<<< .. + +.. >>>>> [ IO READ: only_expected_s2 ] <<<<< .. + +.. >>>>> [ RES MEM : 0.557491 GB ] [ VIRT MEM : 7.841503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.579286 s ] [ CPU TIME: 494.325530 s ] <<<<< .. + +.. >>>>> [ IO READ: disk_based_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 0.557491 GB ] [ VIRT MEM : 7.841503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.580095 s ] [ CPU TIME: 494.380766 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.557491 GB ] [ VIRT MEM : 7.841503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.580470 s ] [ CPU TIME: 494.407004 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 1280 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.2440515905618668E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.7540025188 0.027849 0.196E-01 + 2 -228.7974394075 0.031754 0.118E-02 + 3 -228.7980493604 0.031113 0.111E-03 + 4 -228.7981385150 0.031614 0.132E-05 + 5 -228.7981410494 0.031613 0.231E-07 + 6 -228.7981410953 0.031609 0.456E-09 + 7 -228.7981410962 0.031609 0.948E-11 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 0.557945 GB ] [ VIRT MEM : 7.841503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.635197 s ] [ CPU TIME: 498.188077 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.557945 GB ] [ VIRT MEM : 7.841503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.635588 s ] [ CPU TIME: 498.215931 s ] <<<<< .. + +* Energy of state 1 -228.7981410962452 +* S^2 of state 1 0.3160925550840818E-01 +* Saved determinants 1280 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.558090 GB ] [ VIRT MEM : 7.841503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.707246 s ] [ CPU TIME: 502.855924 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 0.558090 GB ] [ VIRT MEM : 7.841503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.707648 s ] [ CPU TIME: 502.884805 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 61 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.7981410962452 + +.. >>>>> [ RES MEM : 0.558277 GB ] [ VIRT MEM : 7.841503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.716939 s ] [ CPU TIME: 503.539709 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 0.558277 GB ] [ VIRT MEM : 7.841503 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 7.717339 s ] [ CPU TIME: 503.568364 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 61 +* pt2_n_tasks_max 1 +* Number of tasks 1280 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.9877121448516846E-02 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 8 -229.0296125910 0.179E-03 0.6954052519 0.0828042881 1.0565 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.556362 GB ] [ VIRT MEM : 7.852947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.959823 s ] [ CPU TIME: 588.965486 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 0.556362 GB ] [ VIRT MEM : 7.852947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8.960246 s ] [ CPU TIME: 588.995966 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 61 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.5619017101394546 + +Summary at N_det = 1280 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.79814110 +# PT2 -0.23144357 0.00014276 +# rPT2 -0.21374751 0.00013185 +# +# E+PT2 -229.02958467 0.00014276 +# E+rPT2 -229.01188861 0.00013185 +# ============ ============================= + + N_det = 1280 + N_states = 1 + + * State 1 + < S^2 > = 3.160925550840818E-002 + E = -228.798141096245 + Variance = 0.695417677923376 + PT norm = 0.287731684315824 + PT2 = -0.231443569299970 + rPT2 = -0.213747514695601 + E+PT2 = -229.029584665545 +/- 1.427627251882709E-004 + E+rPT2 = -229.011888610941 +/- 1.318471616751368E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.804286296751 + Vee = 238.853272024539 + Vecp = 0.000000000000000E+000 + T = 229.044643397178 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2547 -229.03020373 + -0.2919 -229.02958257 + -0.3249 -229.02840186 + -0.3545 -229.02693387 + -0.3828 -229.02284316 + -0.4057 -229.01803283 + -0.4288 -229.01345392 + =========== =================== + +* Number of unique alpha determinants 431 +* Number of unique beta determinants 431 + +.. >>>>> [ RES MEM : 0.556858 GB ] [ VIRT MEM : 7.852947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.014443 s ] [ CPU TIME: 592.747155 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 2560 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.4561156034469604E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.7981662108 0.031610 0.196E-01 + 2 -228.8433263604 0.028529 0.101E-02 + 3 -228.8439594651 0.027377 0.117E-03 + 4 -228.8440527744 0.027462 0.236E-05 + 5 -228.8440570207 0.027411 0.870E-07 + 6 -228.8440571780 0.027394 0.206E-08 + 7 -228.8440571822 0.027392 0.514E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 0.559879 GB ] [ VIRT MEM : 7.852947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.068259 s ] [ CPU TIME: 596.551515 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.559879 GB ] [ VIRT MEM : 7.852947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.068958 s ] [ CPU TIME: 596.601130 s ] <<<<< .. + +* Energy of state 1 -228.8440571822045 +* S^2 of state 1 0.2739194656811864E-01 +* Saved determinants 2560 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.559948 GB ] [ VIRT MEM : 7.852947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.159872 s ] [ CPU TIME: 602.163016 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 0.559948 GB ] [ VIRT MEM : 7.852947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.160262 s ] [ CPU TIME: 602.190740 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 76 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.8440571822045 + +.. >>>>> [ RES MEM : 0.559948 GB ] [ VIRT MEM : 7.852947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.167783 s ] [ CPU TIME: 602.713645 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 0.559948 GB ] [ VIRT MEM : 7.852947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.168183 s ] [ CPU TIME: 602.741572 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 76 +* pt2_n_tasks_max 1 +* Number of tasks 2560 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1820920109748840E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0260378122 0.397E-03 0.5946976363 0.0600849299 1.4173 + 24 -229.0260238578 0.123E-03 0.5932678989 0.0601437836 2.4574 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.565163 GB ] [ VIRT MEM : 7.845142 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.798255 s ] [ CPU TIME: 784.173496 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 0.565163 GB ] [ VIRT MEM : 7.845142 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.798653 s ] [ CPU TIME: 784.202691 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 76 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.6508656738551459 + +Summary at N_det = 2560 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.84405718 +# PT2 -0.18201658 0.00012473 +# rPT2 -0.17168890 0.00011765 +# +# E+PT2 -229.02607376 0.00012473 +# E+rPT2 -229.01574609 0.00011765 +# ============ ============================= + + N_det = 2560 + N_states = 1 + + * State 1 + < S^2 > = 2.739194656811864E-002 + E = -228.844057182204 + Variance = 0.593547466207842 + PT norm = 0.245261910656286 + PT2 = -0.182016576108844 + rPT2 = -0.171688903965704 + E+PT2 = -229.026073758313 +/- 1.247283540129740E-004 + E+rPT2 = -229.015746086170 +/- 1.176512318368639E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.861712883155 + Vee = 238.815772586689 + Vecp = 0.000000000000000E+000 + T = 229.093653335473 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2137 -229.03149282 + -0.2547 -229.03094293 + -0.2919 -229.03040064 + -0.3249 -229.02954701 + -0.3545 -229.02845283 + -0.3828 -229.02562816 + -0.4057 -229.02211316 + =========== =================== + +* Number of unique alpha determinants 852 +* Number of unique beta determinants 852 + +.. >>>>> [ RES MEM : 0.565464 GB ] [ VIRT MEM : 7.845142 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.856576 s ] [ CPU TIME: 788.322662 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5120 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.8974093943834305E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.8440702575 0.027385 0.163E-01 + 2 -228.8842026945 0.018683 0.905E-03 + 3 -228.8848014105 0.017432 0.102E-03 + 4 -228.8848908408 0.017244 0.240E-05 + 5 -228.8848950031 0.017191 0.119E-06 + 6 -228.8848952158 0.017178 0.399E-08 + 7 -228.8848952239 0.017177 0.133E-09 + 8 -228.8848952242 0.017177 0.425E-11 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 0.572338 GB ] [ VIRT MEM : 7.847507 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.935857 s ] [ CPU TIME: 794.002929 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.570976 GB ] [ VIRT MEM : 7.845207 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11.936463 s ] [ CPU TIME: 794.046979 s ] <<<<< .. + +* Energy of state 1 -228.8848952241606 +* S^2 of state 1 0.1717683789133680E-01 +* Saved determinants 5120 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.570976 GB ] [ VIRT MEM : 7.845207 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12.263779 s ] [ CPU TIME: 814.799642 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 0.570976 GB ] [ VIRT MEM : 7.845207 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12.264188 s ] [ CPU TIME: 814.829238 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 88 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.8848952241606 + +.. >>>>> [ RES MEM : 0.570297 GB ] [ VIRT MEM : 7.844597 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12.271794 s ] [ CPU TIME: 815.374025 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 0.570297 GB ] [ VIRT MEM : 7.844597 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12.272190 s ] [ CPU TIME: 815.402949 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 88 +* pt2_n_tasks_max 1 +* Number of tasks 5120 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.3487282395362854E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0274065601 0.450E-03 0.5084635034 0.0429965171 2.5736 + 29 -229.0271200660 0.130E-03 0.5073575348 0.0429314487 3.6049 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.586651 GB ] [ VIRT MEM : 7.826267 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.245361 s ] [ CPU TIME: 1088.171650 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 0.586651 GB ] [ VIRT MEM : 7.826267 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.245728 s ] [ CPU TIME: 1088.199185 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 88 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7257957120439537 + +Summary at N_det = 5120 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.88489522 +# PT2 -0.14220262 0.00011499 +# rPT2 -0.13634930 0.00011026 +# +# E+PT2 -229.02709785 0.00011499 +# E+rPT2 -229.02124453 0.00011026 +# ============ ============================= + + N_det = 5120 + N_states = 1 + + * State 1 + < S^2 > = 1.717683789133680E-002 + E = -228.884895224161 + Variance = 0.507217207409194 + PT norm = 0.207192763349371 + PT2 = -0.142202620983081 + rPT2 = -0.136349303392162 + E+PT2 = -229.027097845144 +/- 1.149923118778054E-004 + E+rPT2 = -229.021244527553 +/- 1.102590199224141E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.899110068500 + Vee = 238.775542225240 + Vecp = 0.000000000000000E+000 + T = 229.130442840311 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1717 -229.04245893 + -0.2137 -229.03715849 + -0.2547 -229.03495622 + -0.2919 -229.03365037 + -0.3249 -229.03250209 + -0.3545 -229.03133864 + -0.3828 -229.02904946 + =========== =================== + +* Number of unique alpha determinants 1618 +* Number of unique beta determinants 1618 + +.. >>>>> [ RES MEM : 0.585701 GB ] [ VIRT MEM : 7.824577 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.358754 s ] [ CPU TIME: 1096.164954 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 10240 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.1761622354388237E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.8849058473 0.017183 0.125E-01 + 2 -228.9180469818 0.010858 0.457E-03 + 3 -228.9185283050 0.010401 0.852E-04 + 4 -228.9185858675 0.010422 0.277E-05 + 5 -228.9185902072 0.010408 0.205E-06 + 6 -228.9185905519 0.010402 0.113E-07 + 7 -228.9185905730 0.010401 0.480E-09 + 8 -228.9185905739 0.010401 0.220E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 0.584179 GB ] [ VIRT MEM : 7.786812 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.519732 s ] [ CPU TIME: 1107.565072 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.581558 GB ] [ VIRT MEM : 7.782223 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.520618 s ] [ CPU TIME: 1107.628248 s ] <<<<< .. + +* Energy of state 1 -228.9185905739354 +* S^2 of state 1 0.1040070041295927E-01 +* Saved determinants 10240 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.582527 GB ] [ VIRT MEM : 7.782223 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.725088 s ] [ CPU TIME: 1118.635944 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 0.582527 GB ] [ VIRT MEM : 7.782223 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.725499 s ] [ CPU TIME: 1118.665480 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 96 +* pt2_n_tasks_max 2 +* PT2 Energy denominator -228.9185905739354 + +.. >>>>> [ RES MEM : 0.580986 GB ] [ VIRT MEM : 7.781216 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.734320 s ] [ CPU TIME: 1119.289257 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 0.580986 GB ] [ VIRT MEM : 7.781216 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.734725 s ] [ CPU TIME: 1119.318278 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 96 +* pt2_n_tasks_max 2 +* Number of tasks 10535 +* Number of fragmented tasks 295 +* Number of threads for PT2 72 +* Memory (Gb) 0.6823636889457703E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0292241471 0.645E-03 0.4276167628 0.0305481879 2.4634 + 18 -229.0294616547 0.188E-03 0.4315734900 0.0304807041 3.5451 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.592987 GB ] [ VIRT MEM : 7.796856 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 20.683808 s ] [ CPU TIME: 1394.576429 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 0.592987 GB ] [ VIRT MEM : 7.796856 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 20.684235 s ] [ CPU TIME: 1394.607627 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 96 +* pt2_n_tasks_max 2 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7858792557524775 + +Summary at N_det = 10240 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.91859057 +# PT2 -0.11078863 0.00018546 +# rPT2 -0.10751289 0.00017997 +# +# E+PT2 -229.02937921 0.00018546 +# E+rPT2 -229.02610347 0.00017997 +# ============ ============================= + + N_det = 10240 + N_states = 1 + + * State 1 + < S^2 > = 1.040070041295927E-002 + E = -228.918590573935 + Variance = 0.431100848487557 + PT norm = 0.174551827351019 + PT2 = -0.110788632961978 + rPT2 = -0.107512893521385 + E+PT2 = -229.029379206897 +/- 1.854572391620085E-004 + E+rPT2 = -229.026103467457 +/- 1.799737380425831E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.887211407066 + Vee = 238.714943289725 + Vecp = 0.000000000000000E+000 + T = 229.145447764616 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1363 -229.04421941 + -0.1717 -229.04335686 + -0.2137 -229.03990746 + -0.2547 -229.03774543 + -0.2919 -229.03630331 + -0.3249 -229.03509381 + -0.3545 -229.03394355 + =========== =================== + +* Number of unique alpha determinants 2987 +* Number of unique beta determinants 2987 + +.. >>>>> [ RES MEM : 0.584217 GB ] [ VIRT MEM : 7.781208 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 20.770705 s ] [ CPU TIME: 1400.703830 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 20480 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.3450639545917511E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9185923633 0.010400 0.828E-02 + 2 -228.9423299557 0.006473 0.230E-03 + 3 -228.9427646697 0.006378 0.169E-04 + 4 -228.9427915352 0.006408 0.177E-05 + 5 -228.9427941825 0.006412 0.235E-06 + 6 -228.9427944938 0.006417 0.166E-07 + 7 -228.9427945279 0.006420 0.136E-08 + 8 -228.9427945306 0.006421 0.102E-09 + 9 -228.9427945308 0.006421 0.672E-11 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 0.605946 GB ] [ VIRT MEM : 8.120155 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 21.164728 s ] [ CPU TIME: 1428.996161 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.596817 GB ] [ VIRT MEM : 8.106285 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 21.166528 s ] [ CPU TIME: 1429.125602 s ] <<<<< .. + +* Energy of state 1 -228.9427945308355 +* S^2 of state 1 0.6421016867668177E-02 +* Saved determinants 20480 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.598454 GB ] [ VIRT MEM : 8.102379 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 21.447359 s ] [ CPU TIME: 1443.927526 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 0.598454 GB ] [ VIRT MEM : 8.102379 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 21.447807 s ] [ CPU TIME: 1443.959351 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 +* PT2 Energy denominator -228.9427945308355 + +.. >>>>> [ RES MEM : 0.597752 GB ] [ VIRT MEM : 8.098473 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 21.458444 s ] [ CPU TIME: 1444.712655 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 0.597752 GB ] [ VIRT MEM : 8.098473 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 21.458894 s ] [ CPU TIME: 1444.744626 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 +* Number of tasks 21120 +* Number of fragmented tasks 320 +* Number of threads for PT2 72 +* Memory (Gb) 0.1349263250827789 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0320599626 0.582E-03 0.3750962203 0.0225432572 3.0844 + 9 -229.0318942397 0.259E-03 0.3732999136 0.0225428668 4.1180 + 15 -229.0320365393 0.206E-03 0.3738830993 0.0225752981 5.2903 + 24 -229.0321325189 0.167E-03 0.3746920198 0.0225796973 6.6342 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.765392 GB ] [ VIRT MEM : 8.248375 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 28.993381 s ] [ CPU TIME: 1974.611750 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 0.765392 GB ] [ VIRT MEM : 8.248375 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 28.993836 s ] [ CPU TIME: 1974.644055 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8274338980707671 + +Summary at N_det = 20480 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.94279453 +# PT2 -0.08931700 0.00015168 +# rPT2 -0.08734408 0.00014833 +# +# E+PT2 -229.03211153 0.00015168 +# E+rPT2 -229.03013861 0.00014833 +# ============ ============================= + + N_det = 20480 + N_states = 1 + + * State 1 + < S^2 > = 6.421016867668177E-003 + E = -228.942794530835 + Variance = 0.374296779432435 + PT norm = 0.150292709419989 + PT2 = -8.931699923036267E-002 + rPT2 = -8.734408001596676E-002 + E+PT2 = -229.032111530066 +/- 1.516844864367213E-004 + E+rPT2 = -229.030138610851 +/- 1.483339345776632E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.891773089516 + Vee = 238.672424514545 + Vecp = 0.000000000000000E+000 + T = 229.168324265346 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1075 -229.04761341 + -0.1363 -229.04576753 + -0.1717 -229.04460068 + -0.2137 -229.04185653 + -0.2547 -229.03985785 + -0.2919 -229.03843174 + -0.3249 -229.03724170 + =========== =================== + +* Number of unique alpha determinants 5414 +* Number of unique beta determinants 5414 + +.. >>>>> [ RES MEM : 0.767555 GB ] [ VIRT MEM : 8.249607 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 29.148887 s ] [ CPU TIME: 1985.702269 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 40960 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.6753483042120934E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9427952963 0.006421 0.507E-02 + 2 -228.9584453295 0.004197 0.317E-03 + 3 -228.9588338936 0.004272 0.685E-04 + 4 -228.9589033048 0.004376 0.108E-04 + 5 -228.9589175784 0.004452 0.155E-05 + 6 -228.9589199827 0.004469 0.152E-06 + 7 -228.9589202661 0.004470 0.151E-07 + 8 -228.9589202935 0.004470 0.123E-08 + 9 -228.9589202960 0.004469 0.121E-09 + 10 -228.9589202963 0.004469 0.102E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 0.816414 GB ] [ VIRT MEM : 8.301834 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30.259039 s ] [ CPU TIME: 2065.431764 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.796352 GB ] [ VIRT MEM : 8.273994 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30.262002 s ] [ CPU TIME: 2065.645016 s ] <<<<< .. + +* Energy of state 1 -228.9589202962724 +* S^2 of state 1 0.4469182235206865E-02 +* Saved determinants 40960 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 0.781013 GB ] [ VIRT MEM : 8.256119 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30.707290 s ] [ CPU TIME: 2088.129566 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 0.781013 GB ] [ VIRT MEM : 8.256119 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30.707735 s ] [ CPU TIME: 2088.163019 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 +* PT2 Energy denominator -228.9589202962724 + +.. >>>>> [ RES MEM : 0.780758 GB ] [ VIRT MEM : 8.254887 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30.722124 s ] [ CPU TIME: 2089.194643 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 0.780758 GB ] [ VIRT MEM : 8.254887 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30.722563 s ] [ CPU TIME: 2089.227545 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 +* Number of tasks 46090 +* Number of fragmented tasks 4149 +* Number of threads for PT2 72 +* Memory (Gb) 0.2683059990406036 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0326492046 0.430E-03 0.3273187223 0.0174434137 3.1949 + 5 -229.0330430998 0.328E-03 0.3285553797 0.0175558752 4.3395 + 8 -229.0332543646 0.216E-03 0.3290713066 0.0176294165 5.8111 + 12 -229.0337383469 0.382E-03 0.3318586156 0.0177181060 6.8551 + 17 -229.0334432926 0.332E-03 0.3307943489 0.0176374860 7.9010 + 20 -229.0333919471 0.292E-03 0.3302495910 0.0176380194 8.9681 + 27 -229.0334371284 0.237E-03 0.3302406535 0.0176588366 10.4974 + 32 -229.0334472124 0.200E-03 0.3302277339 0.0176664600 11.7281 + 39 -229.0333930075 0.173E-03 0.3298194234 0.0176608312 13.0690 + 44 -229.0335624498 0.173E-03 0.3307105803 0.0176930149 14.2618 + 52 -229.0335518706 0.164E-03 0.3308880233 0.0176816401 15.3206 + 63 -229.0335004013 0.137E-03 0.3305316565 0.0176743077 16.5531 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.046642 GB ] [ VIRT MEM : 8.494038 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 48.423684 s ] [ CPU TIME: 3341.705692 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 1.046642 GB ] [ VIRT MEM : 8.494038 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 48.424190 s ] [ CPU TIME: 3341.742509 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8556996907977323 + +Summary at N_det = 40960 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.95892030 +# PT2 -0.07464141 0.00012051 +# rPT2 -0.07334415 0.00011842 +# +# E+PT2 -229.03356171 0.00012051 +# E+rPT2 -229.03226445 0.00011842 +# ============ ============================= + + N_det = 40960 + N_states = 1 + + * State 1 + < S^2 > = 4.469182235206865E-003 + E = -228.958920296272 + Variance = 0.330826152781365 + PT norm = 0.132993902520073 + PT2 = -7.464141463131577E-002 + rPT2 = -7.334414893709128E-002 + E+PT2 = -229.033561710904 +/- 1.205125920972999E-004 + E+rPT2 = -229.032264445209 +/- 1.184180866244051E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.897422171848 + Vee = 238.640238384900 + Vecp = 0.000000000000000E+000 + T = 229.190033711887 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0873 -229.04340147 + -0.1075 -229.04574613 + -0.1363 -229.04538108 + -0.1717 -229.04468390 + -0.2137 -229.04260775 + -0.2547 -229.04091448 + -0.2919 -229.03963508 + =========== =================== + +* Number of unique alpha determinants 9638 +* Number of unique beta determinants 9553 + +.. >>>>> [ RES MEM : 1.049274 GB ] [ VIRT MEM : 8.494038 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 48.741668 s ] [ CPU TIME: 3364.493235 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 81920 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.1320685409009457 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9589204045 0.004469 0.308E-02 + 2 -228.9690605625 0.003826 0.382E-03 + 3 -228.9693708552 0.003995 0.649E-04 + 4 -228.9694574184 0.004198 0.883E-05 + 5 -228.9694745450 0.004337 0.126E-05 + 6 -228.9694767175 0.004395 0.160E-06 + 7 -228.9694770241 0.004421 0.203E-07 + 8 -228.9694770651 0.004431 0.228E-08 + 9 -228.9694770697 0.004434 0.228E-09 + 10 -228.9694770702 0.004435 0.209E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 1.133770 GB ] [ VIRT MEM : 8.594673 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 51.490377 s ] [ CPU TIME: 3561.903346 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 1.093697 GB ] [ VIRT MEM : 8.539001 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 51.495622 s ] [ CPU TIME: 3562.280544 s ] <<<<< .. + +* Energy of state 1 -228.9694770702259 +* S^2 of state 1 0.4435423067108269E-02 +* Saved determinants 81920 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.064976 GB ] [ VIRT MEM : 8.505711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 52.374765 s ] [ CPU TIME: 3601.867726 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 1.064976 GB ] [ VIRT MEM : 8.505711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 52.375363 s ] [ CPU TIME: 3601.910905 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 +* PT2 Energy denominator -228.9694770702259 + +.. >>>>> [ RES MEM : 1.064533 GB ] [ VIRT MEM : 8.505711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 52.397011 s ] [ CPU TIME: 3603.465278 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 1.064533 GB ] [ VIRT MEM : 8.505711 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 52.397581 s ] [ CPU TIME: 3603.506574 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 +* Number of tasks 93200 +* Number of fragmented tasks 4632 +* Number of threads for PT2 72 +* Memory (Gb) 0.5350653469562531 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0343668151 0.137E-03 0.2989104368 0.0146870420 5.4856 + 4 -229.0346182557 0.351E-03 0.3001437445 0.0147291391 6.7180 + 6 -229.0345967214 0.219E-03 0.2991675481 0.0147590673 7.7866 + 8 -229.0342758916 0.306E-03 0.2981537196 0.0146726813 9.6084 + 12 -229.0342841675 0.350E-03 0.2976083967 0.0147037072 11.0125 + 15 -229.0344992775 0.327E-03 0.2991595342 0.0147241151 12.3133 + 19 -229.0345211164 0.270E-03 0.2993984072 0.0147231628 13.4251 + 24 -229.0344122750 0.252E-03 0.2989100092 0.0146990422 14.9707 + 27 -229.0344413375 0.215E-03 0.2989574951 0.0147103804 16.1045 + 29 -229.0344915005 0.219E-03 0.2991679630 0.0147225192 17.1758 + 33 -229.0345510146 0.194E-03 0.2993294494 0.0147403370 18.4194 + 36 -229.0346264272 0.183E-03 0.2999291342 0.0147470178 19.4268 + 41 -229.0344790966 0.189E-03 0.2991421721 0.0147172140 20.6044 + 45 -229.0344129342 0.179E-03 0.2987127427 0.0147084421 22.1731 + 53 -229.0345021961 0.171E-03 0.2993534356 0.0147192398 23.2843 + 62 -229.0344863942 0.145E-03 0.2993639951 0.0147126770 24.3968 + 69 -229.0343744985 0.136E-03 0.2987549914 0.0146912113 25.6395 + 77 -229.0343332041 0.127E-03 0.2986161845 0.0146799374 27.0320 + 85 -229.0343595366 0.127E-03 0.2988103127 0.0146825955 28.1985 + 92 -229.0344280249 0.128E-03 0.2992781235 0.0146914151 29.2789 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.485615 GB ] [ VIRT MEM : 8.853573 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 82.172354 s ] [ CPU TIME: 5714.621060 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 1.485615 GB ] [ VIRT MEM : 8.853573 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 82.173451 s ] [ CPU TIME: 5714.699262 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8743653434967026 + +Summary at N_det = 81920 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.96947707 +# PT2 -0.06495095 0.00012798 +# rPT2 -0.06401055 0.00012613 +# +# E+PT2 -229.03442802 0.00012798 +# E+rPT2 -229.03348762 0.00012613 +# ============ ============================= + + N_det = 81920 + N_states = 1 + + * State 1 + < S^2 > = 4.435423067108269E-003 + E = -228.969477070226 + Variance = 0.299278123501156 + PT norm = 0.121208147857821 + PT2 = -6.495095465586825E-002 + rPT2 = -6.401054910769224E-002 + E+PT2 = -229.034428024882 +/- 1.279793944567668E-004 + E+rPT2 = -229.033487619334 +/- 1.261264188810110E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.892581042398 + Vee = 238.606140441100 + Vecp = 0.000000000000000E+000 + T = 229.208733752284 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0733 -229.04187624 + -0.0873 -229.04276291 + -0.1075 -229.04466424 + -0.1363 -229.04482693 + -0.1717 -229.04445815 + -0.2137 -229.04285313 + -0.2547 -229.04142887 + =========== =================== + +* Number of unique beta determinants 17389 +* Number of unique alpha determinants 17822 + +.. >>>>> [ RES MEM : 1.529148 GB ] [ VIRT MEM : 8.892288 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 83.875421 s ] [ CPU TIME: 5776.990428 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 163840 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.2604976855218410 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9694771643 0.004435 0.185E-02 + 2 -228.9760417597 0.004394 0.238E-03 + 3 -228.9762130709 0.004501 0.335E-04 + 4 -228.9762631423 0.004631 0.465E-05 + 5 -228.9762732985 0.004713 0.706E-06 + 6 -228.9762746152 0.004760 0.872E-07 + 7 -228.9762747951 0.004785 0.144E-07 + 8 -228.9762748260 0.004798 0.225E-08 + 9 -228.9762748308 0.004804 0.281E-09 + 10 -228.9762748314 0.004806 0.323E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 1.672935 GB ] [ VIRT MEM : 9.067516 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 90.234284 s ] [ CPU TIME: 6224.909985 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 1.592514 GB ] [ VIRT MEM : 8.956669 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 90.244085 s ] [ CPU TIME: 6225.614716 s ] <<<<< .. + +* Energy of state 1 -228.9762748314460 +* S^2 of state 1 0.4805850694596527E-02 +* Saved determinants 163840 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.497364 GB ] [ VIRT MEM : 8.856010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 91.645584 s ] [ CPU TIME: 6273.856885 s ] <<<<< .. + +* Number of generators 163838 + +.. >>>>> [ RES MEM : 1.497364 GB ] [ VIRT MEM : 8.856010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 91.646409 s ] [ CPU TIME: 6273.916419 s ] <<<<< .. + +* Number of selectors 163838 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 +* PT2 Energy denominator -228.9762748314460 + +.. >>>>> [ RES MEM : 1.495674 GB ] [ VIRT MEM : 8.853996 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 91.694415 s ] [ CPU TIME: 6277.363770 s ] <<<<< .. + +* Number of generators 163838 + +.. >>>>> [ RES MEM : 1.495674 GB ] [ VIRT MEM : 8.853996 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 91.695202 s ] [ CPU TIME: 6277.420546 s ] <<<<< .. + +* Number of selectors 163838 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 +* Number of tasks 183164 +* Number of fragmented tasks 4973 +* Number of threads for PT2 72 +* Memory (Gb) 1.068583988621831 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0360055223 0.180E-02 0.2855668764 0.0129663972 9.7046 + 4 -229.0352032897 0.139E-02 0.2811339735 0.0128253080 11.2369 + 6 -229.0352210990 0.104E-02 0.2805861924 0.0128578715 12.7733 + 7 -229.0352269565 0.858E-03 0.2797946007 0.0128962611 14.7042 + 9 -229.0349687483 0.667E-03 0.2780657521 0.0128618952 17.7402 + 14 -229.0353354246 0.614E-03 0.2807785939 0.0129012388 19.9460 + 19 -229.0357777282 0.521E-03 0.2829345204 0.0129907133 22.1491 + 22 -229.0356498890 0.539E-03 0.2822398395 0.0129676266 23.9870 + 27 -229.0352970626 0.480E-03 0.2800294672 0.0129130046 27.3998 + 33 -229.0353142332 0.402E-03 0.2800047466 0.0129189451 29.0172 + 35 -229.0352386370 0.372E-03 0.2795461412 0.0129080403 30.4390 + 37 -229.0352752371 0.367E-03 0.2797489700 0.0129147142 32.0115 + 42 -229.0351972814 0.327E-03 0.2792687613 0.0129032085 33.4980 + 48 -229.0352629625 0.292E-03 0.2796325122 0.0129162661 34.8440 + 52 -229.0351209604 0.276E-03 0.2788712437 0.0128892108 36.6730 + 60 -229.0349834101 0.262E-03 0.2780684007 0.0128651957 38.0790 + 63 -229.0349613167 0.252E-03 0.2779629041 0.0128610228 39.3861 + 67 -229.0349103451 0.250E-03 0.2777305572 0.0128502739 40.8930 + 76 -229.0349086000 0.224E-03 0.2776636768 0.0128516678 42.4762 + 86 -229.0348687625 0.204E-03 0.2775557512 0.0128397449 43.8470 + 91 -229.0348636297 0.193E-03 0.2775440391 0.0128383614 44.9450 + 98 -229.0349001668 0.186E-03 0.2777329252 0.0128458860 46.7730 + 103 -229.0349399262 0.179E-03 0.2778553198 0.0128570751 47.9200 + 110 -229.0348878201 0.171E-03 0.2775162388 0.0128489662 48.9525 + 118 -229.0349006513 0.162E-03 0.2775432267 0.0128533424 50.4713 + 123 -229.0348954242 0.157E-03 0.2774821427 0.0128537674 51.8614 + 131 -229.0349115099 0.146E-03 0.2775865315 0.0128561231 54.1402 + 147 -229.0349792959 0.145E-03 0.2778901258 0.0128713755 55.4530 + 148 -229.0350039028 0.146E-03 0.2780110369 0.0128763329 57.5990 + 157 -229.0350258438 0.141E-03 0.2781337541 0.0128803038 58.6220 + 163 -229.0350224465 0.136E-03 0.2781034011 0.0128800263 59.8200 + 171 -229.0350457243 0.136E-03 0.2781952688 0.0128857777 60.9867 + 181 -229.0350479330 0.130E-03 0.2782371005 0.0128853900 62.7412 + 191 -229.0350607408 0.126E-03 0.2782986734 0.0128883986 63.7628 + 198 -229.0350642883 0.122E-03 0.2783172604 0.0128892904 65.1312 + 214 -229.0350672187 0.113E-03 0.2783377700 0.0128898871 66.2460 + 220 -229.0350456381 0.112E-03 0.2782214376 0.0128857815 67.4354 + 228 -229.0350525499 0.110E-03 0.2782286411 0.0128881161 68.9585 + 236 -229.0350184909 0.103E-03 0.2780611063 0.0128809821 70.0744 + 251 -229.0349325401 0.924E-04 0.2776092698 0.0128643489 71.1742 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 2.077770 GB ] [ VIRT MEM : 9.337650 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 163.462222 s ] [ CPU TIME: 11366.428178 s ] <<<<< .. + +* Number of generators 163838 + +.. >>>>> [ RES MEM : 2.077770 GB ] [ VIRT MEM : 9.337650 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 163.463022 s ] [ CPU TIME: 11366.485252 s ] <<<<< .. + +* Number of selectors 163838 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8864869442771554 + +Summary at N_det = 163840 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.97627483 +# PT2 -0.05865931 0.00009177 +# rPT2 -0.05791425 0.00009060 +# +# E+PT2 -229.03493414 0.00009177 +# E+rPT2 -229.03418908 0.00009060 +# ============ ============================= + + N_det = 163840 + N_states = 1 + + * State 1 + < S^2 > = 4.805850694596527E-003 + E = -228.976274831446 + Variance = 0.277611692472775 + PT norm = 0.113423289127982 + PT2 = -5.865930584492211E-002 + rPT2 = -5.791424816283932E-002 + E+PT2 = -229.034934137291 +/- 9.176939169693843E-005 + E+rPT2 = -229.034189079609 +/- 9.060378822995184E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.885953676284 + Vee = 238.581143155110 + Vecp = 0.000000000000000E+000 + T = 229.220305910939 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0640 -229.04085288 + -0.0733 -229.04146689 + -0.0873 -229.04229836 + -0.1075 -229.04395141 + -0.1363 -229.04434141 + -0.1717 -229.04417572 + -0.2137 -229.04289108 + =========== =================== + +* Number of unique beta determinants 32560 +* Number of unique alpha determinants 32440 + +.. >>>>> [ RES MEM : 2.170414 GB ] [ VIRT MEM : 9.431976 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 165.676353 s ] [ CPU TIME: 11488.826892 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 327680 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.5134151019155979 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9762748420 0.004806 0.107E-02 + 2 -228.9803214352 0.005289 0.103E-03 + 3 -228.9803976212 0.005376 0.134E-04 + 4 -228.9804169615 0.005470 0.142E-05 + 5 -228.9804202730 0.005538 0.442E-06 + 6 -228.9804210302 0.005584 0.833E-07 + 7 -228.9804212029 0.005614 0.166E-07 + 8 -228.9804212386 0.005627 0.378E-08 + 9 -228.9804212460 0.005633 0.618E-09 + 10 -228.9804212472 0.005636 0.801E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 2.261726 GB ] [ VIRT MEM : 9.562771 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 179.147573 s ] [ CPU TIME: 12397.995397 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 1.954144 GB ] [ VIRT MEM : 9.195084 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 179.203376 s ] [ CPU TIME: 12402.003591 s ] <<<<< .. + +* Energy of state 1 -228.9804212472253 +* S^2 of state 1 0.5635624106168405E-02 +* Saved determinants 327680 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 1.879898 GB ] [ VIRT MEM : 9.116543 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 181.836078 s ] [ CPU TIME: 12464.725543 s ] <<<<< .. + +* Number of generators 327679 + +.. >>>>> [ RES MEM : 1.879898 GB ] [ VIRT MEM : 9.116543 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 181.837258 s ] [ CPU TIME: 12464.810666 s ] <<<<< .. + +* Number of selectors 327679 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 +* PT2 Energy denominator -228.9804212472253 + +.. >>>>> [ RES MEM : 1.891346 GB ] [ VIRT MEM : 9.127270 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 181.953650 s ] [ CPU TIME: 12473.169196 s ] <<<<< .. + +* Number of generators 327679 + +.. >>>>> [ RES MEM : 1.891346 GB ] [ VIRT MEM : 9.127270 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 181.954799 s ] [ CPU TIME: 12473.251466 s ] <<<<< .. + +* Number of selectors 327679 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 +* Number of tasks 358139 +* Number of fragmented tasks 5207 +* Number of threads for PT2 72 +* Memory (Gb) 2.135621407367289 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0353443824 0.199E-02 0.2653418470 0.0117978149 19.7912 + 5 -229.0351553910 0.109E-02 0.2624181160 0.0118361076 21.9252 + 6 -229.0351509903 0.912E-03 0.2624622628 0.0118293276 25.8352 + 8 -229.0352709628 0.125E-02 0.2634104094 0.0118407158 27.0194 + 9 -229.0352438728 0.109E-02 0.2634562182 0.0118274152 29.1865 + 12 -229.0353408636 0.862E-03 0.2641949128 0.0118309006 30.8911 + 15 -229.0354623853 0.683E-03 0.2651158559 0.0118432170 35.1404 + 19 -229.0350666132 0.571E-03 0.2630070054 0.0117658585 36.3999 + 20 -229.0349949879 0.546E-03 0.2623343818 0.0117643969 39.9323 + 24 -229.0348384794 0.444E-03 0.2611990995 0.0117470071 41.1933 + 28 -229.0350536510 0.401E-03 0.2622969418 0.0117913872 44.5742 + 32 -229.0350278248 0.361E-03 0.2624042327 0.0117766979 45.6663 + 34 -229.0351153107 0.344E-03 0.2630039146 0.0117872391 47.4383 + 35 -229.0351513174 0.336E-03 0.2632381763 0.0117925709 48.7253 + 37 -229.0352273906 0.314E-03 0.2636749528 0.0118063234 50.6313 + 38 -229.0352120786 0.306E-03 0.2636191220 0.0118026532 52.3333 + 43 -229.0351400729 0.279E-03 0.2632747794 0.0117858880 54.0842 + 47 -229.0351886156 0.281E-03 0.2636279622 0.0117911808 55.2143 + 49 -229.0352802825 0.295E-03 0.2640362142 0.0118121106 57.8802 + 51 -229.0352345402 0.285E-03 0.2636784289 0.0118078293 58.9865 + 56 -229.0352164100 0.280E-03 0.2635692855 0.0118042286 60.1143 + 60 -229.0352013516 0.261E-03 0.2634801395 0.0118018218 61.1173 + 63 -229.0351873008 0.252E-03 0.2633148583 0.0118029721 62.9302 + 68 -229.0352581096 0.244E-03 0.2636419420 0.0118184230 64.1857 + 76 -229.0352644801 0.225E-03 0.2636866634 0.0118190172 67.1172 + 84 -229.0352825998 0.211E-03 0.2636890358 0.0118258818 68.7415 + 85 -229.0352870395 0.211E-03 0.2637308136 0.0118257792 71.4982 + 92 -229.0354586267 0.216E-03 0.2646633771 0.0118580493 73.2053 + 97 -229.0354766404 0.209E-03 0.2647933737 0.0118603971 74.7753 + 105 -229.0353463559 0.197E-03 0.2640414647 0.0118374409 78.1029 + 123 -229.0351770743 0.181E-03 0.2629995293 0.0118098258 80.4902 + 125 -229.0352304674 0.183E-03 0.2632411166 0.0118215497 82.4364 + 134 -229.0352725629 0.175E-03 0.2635013614 0.0118286922 84.5028 + 138 -229.0352440354 0.171E-03 0.2633521864 0.0118230474 85.6792 + 144 -229.0352156286 0.164E-03 0.2632122695 0.0118172438 89.2872 + 155 -229.0352125410 0.154E-03 0.2631936472 0.0118163219 90.4083 + 161 -229.0352220908 0.148E-03 0.2632151906 0.0118194063 91.9212 + 167 -229.0352416042 0.144E-03 0.2633407630 0.0118224423 93.5232 + 172 -229.0352364560 0.141E-03 0.2633640548 0.0118196222 95.9142 + 180 -229.0352134245 0.136E-03 0.2632017195 0.0118169073 96.9282 + 186 -229.0351994607 0.132E-03 0.2631436206 0.0118136824 98.0882 + 192 -229.0351635285 0.130E-03 0.2629451089 0.0118069494 99.1639 + 203 -229.0351573004 0.125E-03 0.2629271935 0.0118051528 101.9423 + 216 -229.0351404524 0.115E-03 0.2628305505 0.0118020916 104.1592 + 221 -229.0351084669 0.113E-03 0.2626581458 0.0117960753 105.5801 + 231 -229.0351120295 0.113E-03 0.2626610095 0.0117974341 106.5993 + 241 -229.0351005003 0.112E-03 0.2626182307 0.0117944839 107.8852 + 247 -229.0351390438 0.112E-03 0.2628256413 0.0118017353 109.7670 + 259 -229.0351991799 0.110E-03 0.2631295001 0.0118141836 110.7962 + 264 -229.0352059155 0.110E-03 0.2631707012 0.0118153001 111.9804 + 271 -229.0352174128 0.108E-03 0.2632266285 0.0118176647 113.5123 + 278 -229.0351804276 0.107E-03 0.2630274932 0.0118105981 116.8692 + 307 -229.0351407892 0.100E-03 0.2628281642 0.0118026543 118.9812 + 317 -229.0351219738 0.979E-04 0.2627528306 0.0117981657 120.3558 + 329 -229.0351232003 0.960E-04 0.2627394046 0.0117992028 122.6528 + 336 -229.0351059711 0.921E-04 0.2626401601 0.0117961095 124.0284 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 2.188389 GB ] [ VIRT MEM : 9.394901 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 306.969475 s ] [ CPU TIME: 21367.956506 s ] <<<<< .. + +* Number of generators 327679 + +.. >>>>> [ RES MEM : 2.188389 GB ] [ VIRT MEM : 9.394901 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 306.970622 s ] [ CPU TIME: 21368.038213 s ] <<<<< .. + +* Number of selectors 327679 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8940269941314765 + +Summary at N_det = 327680 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.98042125 +# PT2 -0.05474169 0.00009001 +# rPT2 -0.05410282 0.00008896 +# +# E+PT2 -229.03516293 0.00009001 +# E+rPT2 -229.03452407 0.00008896 +# ============ ============================= + + N_det = 327680 + N_states = 1 + + * State 1 + < S^2 > = 5.635624106168405E-003 + E = -228.980421247225 + Variance = 0.262916274086333 + PT norm = 0.108666127679364 + PT2 = -5.474168592183641E-002 + rPT2 = -5.410282209047718E-002 + E+PT2 = -229.035162933147 +/- 9.000787662232324E-005 + E+rPT2 = -229.034524069316 +/- 8.895743807730743E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.881958071977 + Vee = 238.565062030334 + Vecp = 0.000000000000000E+000 + T = 229.228245015628 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0579 -229.03927922 + -0.0640 -229.04026203 + -0.0733 -229.04102222 + -0.0873 -229.04188202 + -0.1075 -229.04341105 + -0.1363 -229.04392441 + -0.1717 -229.04389216 + =========== =================== + +* Number of unique beta determinants 63277 +* Number of unique alpha determinants 64192 + +.. >>>>> [ RES MEM : 2.304314 GB ] [ VIRT MEM : 9.483868 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 310.349503 s ] [ CPU TIME: 21610.120896 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 655360 +* Number of threads for diagonalization 72 +* Memory(Gb) 1.024462524801493 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9804212551 0.005636 0.562E-03 + 2 -228.9826671506 0.005858 0.358E-04 + 3 -228.9827022614 0.005777 0.700E-05 + 4 -228.9827099345 0.005709 0.425E-06 + 5 -228.9827109745 0.005650 0.135E-06 + 6 -228.9827111934 0.005611 0.225E-07 + 7 -228.9827112391 0.005595 0.332E-08 + 8 -228.9827112470 0.005589 0.702E-09 + 9 -228.9827112486 0.005586 0.114E-09 + 10 -228.9827112489 0.005585 0.182E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 2.994324 GB ] [ VIRT MEM : 10.292496 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 340.881740 s ] [ CPU TIME: 23635.930347 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 2.379105 GB ] [ VIRT MEM : 9.558598 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 340.949932 s ] [ CPU TIME: 23640.828400 s ] <<<<< .. + +* Energy of state 1 -228.9827112489124 +* S^2 of state 1 0.5585099886851244E-02 +* Saved determinants 655360 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 2.262764 GB ] [ VIRT MEM : 9.436882 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 346.129761 s ] [ CPU TIME: 23733.798392 s ] <<<<< .. + +* Number of generators 655309 + +.. >>>>> [ RES MEM : 2.262764 GB ] [ VIRT MEM : 9.436882 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 346.131612 s ] [ CPU TIME: 23733.931773 s ] <<<<< .. + +* Number of selectors 655309 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 +* PT2 Energy denominator -228.9827112489124 + +.. >>>>> [ RES MEM : 2.344200 GB ] [ VIRT MEM : 9.521385 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 346.427985 s ] [ CPU TIME: 23755.217286 s ] <<<<< .. + +* Number of generators 655309 + +.. >>>>> [ RES MEM : 2.344200 GB ] [ VIRT MEM : 9.521385 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 346.429812 s ] [ CPU TIME: 23755.348458 s ] <<<<< .. + +* Number of selectors 655309 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 +* Number of tasks 712745 +* Number of fragmented tasks 5330 +* Number of threads for PT2 72 +* Memory (Gb) 2.605946631841361 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0345095617 0.620E-03 0.2495858822 0.0111310512 36.1305 + 4 -229.0350589107 0.781E-03 0.2519989863 0.0112599325 39.8793 + 5 -229.0343317091 0.102E-02 0.2480485796 0.0111259433 43.7294 + 6 -229.0347702835 0.904E-03 0.2510135241 0.0111849581 47.2317 + 7 -229.0352624349 0.938E-03 0.2531291913 0.0112948777 51.5408 + 9 -229.0347634272 0.733E-03 0.2509028275 0.0111802179 55.9107 + 12 -229.0350793993 0.641E-03 0.2525901063 0.0112399200 58.8587 + 14 -229.0350534333 0.584E-03 0.2525594291 0.0112279911 60.1788 + 15 -229.0349904249 0.513E-03 0.2524149177 0.0112079050 62.7948 + 18 -229.0348735930 0.477E-03 0.2518287663 0.0111830000 64.2907 + 19 -229.0350510653 0.485E-03 0.2526728319 0.0112213870 70.3287 + 20 -229.0351209758 0.477E-03 0.2531799772 0.0112296057 71.9601 + 24 -229.0353646503 0.461E-03 0.2545177973 0.0112769646 74.3477 + 27 -229.0355797803 0.440E-03 0.2558090880 0.0113149228 78.2243 + 28 -229.0355158298 0.429E-03 0.2554316295 0.0113039024 81.7484 + 32 -229.0354201191 0.396E-03 0.2548251991 0.0112880976 91.0497 + 39 -229.0352228628 0.343E-03 0.2540692615 0.0112396192 93.3128 + 42 -229.0350797255 0.329E-03 0.2533697135 0.0112093067 95.8111 + 43 -229.0350758438 0.321E-03 0.2533672703 0.0112077844 99.7677 + 46 -229.0348868430 0.311E-03 0.2522597329 0.0111758417 102.8033 + 47 -229.0348838742 0.305E-03 0.2522611992 0.0111745147 104.3997 + 49 -229.0348672268 0.298E-03 0.2520772365 0.0111749898 105.7127 + 50 -229.0349249256 0.297E-03 0.2524422161 0.0111835649 107.6596 + 61 -229.0348892582 0.249E-03 0.2522701551 0.0111764048 110.6349 + 63 -229.0349728755 0.255E-03 0.2526775989 0.0111936426 112.0966 + 67 -229.0349406238 0.239E-03 0.2524560398 0.0111897725 113.7517 + 69 -229.0349533632 0.235E-03 0.2525179110 0.0111924397 116.1517 + 71 -229.0349570148 0.227E-03 0.2525434011 0.0111927778 119.6029 + 83 -229.0349229489 0.198E-03 0.2524605568 0.0111828916 122.0247 + 84 -229.0349109723 0.196E-03 0.2524161037 0.0111798464 123.8077 + 86 -229.0349235619 0.191E-03 0.2524826053 0.0111820967 128.1345 + 93 -229.0348781283 0.186E-03 0.2522439026 0.0111732576 133.0757 + 107 -229.0349019002 0.170E-03 0.2522832866 0.0111813873 138.5815 + 111 -229.0349598244 0.171E-03 0.2525590097 0.0111936005 141.3291 + 126 -229.0349644927 0.159E-03 0.2526913386 0.0111907072 144.1566 + 129 -229.0349453678 0.154E-03 0.2525624380 0.0111879198 145.2057 + 131 -229.0349378164 0.152E-03 0.2525239453 0.0111863395 148.1931 + 139 -229.0349765275 0.152E-03 0.2526768868 0.0111956974 149.8657 + 146 -229.0349547183 0.149E-03 0.2525280124 0.0111926681 151.0307 + 148 -229.0349621121 0.147E-03 0.2525751865 0.0111941398 153.0905 + 151 -229.0349483717 0.146E-03 0.2524890257 0.0111919257 154.7013 + 157 -229.0349398176 0.141E-03 0.2524372400 0.0111902108 157.4828 + 159 -229.0349385472 0.140E-03 0.2524389184 0.0111897149 158.7219 + 162 -229.0349636539 0.137E-03 0.2525918661 0.0111938731 160.6137 + 169 -229.0349952353 0.136E-03 0.2527790577 0.0111994175 162.3470 + 170 -229.0350020122 0.136E-03 0.2528068002 0.0112010631 164.1388 + 171 -229.0350036967 0.135E-03 0.2528132911 0.0112013992 165.2262 + 176 -229.0349938483 0.132E-03 0.2527844268 0.0111985755 167.1247 + 188 -229.0349857626 0.129E-03 0.2527600345 0.0111965374 168.3849 + 190 -229.0349851600 0.127E-03 0.2527585853 0.0111961976 169.8117 + 191 -229.0349929937 0.127E-03 0.2528035793 0.0111975536 171.2410 + 194 -229.0349788920 0.126E-03 0.2527242264 0.0111951276 176.3957 + 218 -229.0350124745 0.115E-03 0.2528636680 0.0112027640 183.0323 + 227 -229.0350582560 0.113E-03 0.2530655441 0.0112130875 184.3757 + 236 -229.0350679461 0.110E-03 0.2530934383 0.0112156506 187.3662 + 248 -229.0350572442 0.105E-03 0.2530167013 0.0112142986 192.7787 + 268 -229.0350782268 0.998E-04 0.2531213096 0.0112186839 194.0913 + 269 -229.0350779883 0.994E-04 0.2531193813 0.0112186438 196.6103 + 281 -229.0351018668 0.974E-04 0.2531941599 0.0112249847 200.6940 + 302 -229.0350659352 0.924E-04 0.2530264987 0.0112171216 204.5242 + 322 -229.0351248114 0.889E-04 0.2533222107 0.0112290062 206.1081 + 336 -229.0351473126 0.896E-04 0.2534678505 0.0112323860 208.6963 + 339 -229.0351388952 0.892E-04 0.2534210178 0.0112308741 214.9418 + 374 -229.0351305202 0.804E-04 0.2533891673 0.0112290830 221.0028 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 2.588619 GB ] [ VIRT MEM : 9.855659 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 569.500586 s ] [ CPU TIME: 39618.350995 s ] <<<<< .. + +* Number of generators 655309 + +.. >>>>> [ RES MEM : 2.588619 GB ] [ VIRT MEM : 9.855659 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 569.502460 s ] [ CPU TIME: 39618.486033 s ] <<<<< .. + +* Number of selectors 655309 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8984742951099878 + +Summary at N_det = 655360 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.98271125 +# PT2 -0.05241657 0.00007982 +# rPT2 -0.05183453 0.00007893 +# +# E+PT2 -229.03512782 0.00007982 +# E+rPT2 -229.03454578 0.00007893 +# ============ ============================= + + N_det = 655360 + N_states = 1 + + * State 1 + < S^2 > = 5.585099886851244E-003 + E = -228.982711248912 + Variance = 0.253363460120457 + PT norm = 0.105966546503790 + PT2 = -5.241657278290118E-002 + rPT2 = -5.183452759067102E-002 + E+PT2 = -229.035127821695 +/- 7.981735683382215E-005 + E+rPT2 = -229.034545776503 +/- 7.893104728828849E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.880242480341 + Vee = 238.556614537280 + Vecp = 0.000000000000000E+000 + T = 229.232686915359 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0541 -229.03504182 + -0.0579 -229.03778977 + -0.0640 -229.03936448 + -0.0733 -229.04041958 + -0.0873 -229.04140623 + -0.1075 -229.04291264 + -0.1363 -229.04352435 + =========== =================== + +* Number of unique beta determinants 127774 +* Number of unique alpha determinants 127189 + +.. >>>>> [ RES MEM : 2.554031 GB ] [ VIRT MEM : 9.819721 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 577.745536 s ] [ CPU TIME: 40191.685378 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 1310720 +* Number of threads for diagonalization 72 +* Memory(Gb) 2.047326203435659 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9827112494 0.005585 0.281E-03 + 2 -228.9838758727 0.005780 0.120E-04 + 3 -228.9838947474 0.005759 0.356E-05 + 4 -228.9838976157 0.005751 0.139E-06 + 5 -228.9838979382 0.005733 0.328E-07 + 6 -228.9838979944 0.005721 0.661E-08 + 7 -228.9838980087 0.005714 0.975E-09 + 8 -228.9838980111 0.005711 0.166E-09 + 9 -228.9838980115 0.005710 0.248E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 4.038036 GB ] [ VIRT MEM : 11.601978 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 645.095949 s ] [ CPU TIME: 44613.005459 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 2.866302 GB ] [ VIRT MEM : 10.135658 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 645.216282 s ] [ CPU TIME: 44618.575556 s ] <<<<< .. + +* Energy of state 1 -228.9838980114851 +* S^2 of state 1 0.5710096076521339E-02 +* Saved determinants 1310720 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 2.450874 GB ] [ VIRT MEM : 9.717266 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 659.025237 s ] [ CPU TIME: 44777.183614 s ] <<<<< .. + +* Number of generators 1309983 + +.. >>>>> [ RES MEM : 2.450874 GB ] [ VIRT MEM : 9.717266 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 659.028567 s ] [ CPU TIME: 44777.423135 s ] <<<<< .. + +* Number of selectors 1309983 +* Number of comb teeth 100 +* pt2_n_tasks_max 131 +* PT2 Energy denominator -228.9838980114851 + +.. >>>>> [ RES MEM : 2.617840 GB ] [ VIRT MEM : 9.881355 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 659.680847 s ] [ CPU TIME: 44824.270008 s ] <<<<< .. + +* Number of generators 1309983 + +.. >>>>> [ RES MEM : 2.617840 GB ] [ VIRT MEM : 9.881355 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 659.684097 s ] [ CPU TIME: 44824.504213 s ] <<<<< .. + +* Number of selectors 1309983 +* Number of comb teeth 100 +* pt2_n_tasks_max 131 +* Number of tasks 1405103 +* Number of fragmented tasks 5372 +* Number of threads for PT2 72 +* Memory (Gb) 2.655364395715296 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0346458114 0.362E-03 0.2463245734 0.0108264674 75.3657 + 4 -229.0351631982 0.597E-03 0.2503728273 0.0108740125 87.2657 + 5 -229.0351687555 0.413E-03 0.2490775712 0.0109297889 93.8967 + 6 -229.0360512169 0.971E-03 0.2539810312 0.0110890508 108.2097 + 7 -229.0359545341 0.825E-03 0.2534206197 0.0110721218 114.9243 + 8 -229.0357973397 0.775E-03 0.2520624295 0.0110634744 120.7588 + 9 -229.0356928236 0.649E-03 0.2514714293 0.0110452827 123.0677 + 12 -229.0357164098 0.552E-03 0.2522831602 0.0110214650 128.0575 + 14 -229.0358698302 0.494E-03 0.2528138323 0.0110596292 129.3721 + 15 -229.0358289627 0.481E-03 0.2524394329 0.0110577842 132.8277 + 18 -229.0359363919 0.446E-03 0.2527883645 0.0110872595 141.2541 + 19 -229.0359166777 0.422E-03 0.2526513970 0.0110860408 142.5692 + 20 -229.0359756557 0.406E-03 0.2529190605 0.0110998557 148.1717 + 23 -229.0359005086 0.387E-03 0.2525675382 0.0110842528 151.2807 + 24 -229.0358270998 0.377E-03 0.2521822528 0.0110696745 152.8228 + 25 -229.0357943087 0.363E-03 0.2519465933 0.0110665958 154.1400 + 27 -229.0356597255 0.348E-03 0.2512527265 0.0110388155 165.0107 + 28 -229.0356553546 0.331E-03 0.2513247567 0.0110334086 167.1448 + 30 -229.0356041133 0.317E-03 0.2508948289 0.0110301377 176.6127 + 32 -229.0356763926 0.308E-03 0.2513528862 0.0110398199 178.6587 + 34 -229.0354226493 0.330E-03 0.2499432652 0.0109946783 183.9671 + 39 -229.0355952686 0.313E-03 0.2507441322 0.0110345664 190.2431 + 41 -229.0355602225 0.305E-03 0.2505978199 0.0110259317 192.1187 + 42 -229.0355987296 0.300E-03 0.2506989175 0.0110371935 199.4413 + 44 -229.0356236625 0.290E-03 0.2508948793 0.0110400121 204.6521 + 46 -229.0355689889 0.274E-03 0.2505985922 0.0110296022 210.3797 + 49 -229.0356246664 0.265E-03 0.2509214297 0.0110397447 213.7797 + 54 -229.0354733269 0.275E-03 0.2501416103 0.0110102209 219.0847 + 60 -229.0353667231 0.245E-03 0.2495163697 0.0109919096 223.1977 + 63 -229.0353218206 0.234E-03 0.2492287038 0.0109851775 240.6317 + 78 -229.0351852840 0.203E-03 0.2486281346 0.0109550740 246.8547 + 87 -229.0352213010 0.191E-03 0.2489882496 0.0109550850 252.7278 + 93 -229.0352071562 0.183E-03 0.2488585551 0.0109539555 256.3127 + 98 -229.0351410507 0.177E-03 0.2484792001 0.0109423476 258.8308 + 100 -229.0351195416 0.174E-03 0.2483735945 0.0109378136 260.4168 + 105 -229.0351468227 0.177E-03 0.2485540606 0.0109415477 266.0409 + 114 -229.0350638181 0.168E-03 0.2480278401 0.0109291414 268.4267 + 115 -229.0350483209 0.167E-03 0.2479381966 0.0109263866 281.3267 + 126 -229.0350001971 0.159E-03 0.2477049097 0.0109158367 286.3239 + 138 -229.0350422753 0.152E-03 0.2478713505 0.0109256107 293.4487 + 145 -229.0350340396 0.146E-03 0.2478280110 0.0109242931 295.8187 + 149 -229.0350434370 0.144E-03 0.2478507997 0.0109272405 303.3957 + 154 -229.0350558770 0.143E-03 0.2479191127 0.0109297683 309.9817 + 155 -229.0351157084 0.149E-03 0.2482524504 0.0109407553 315.5617 + 176 -229.0351359250 0.135E-03 0.2484306006 0.0109424155 317.4477 + 181 -229.0351716993 0.135E-03 0.2486099751 0.0109496085 323.3169 + 194 -229.0351306416 0.130E-03 0.2483296598 0.0109443413 324.6659 + 198 -229.0351419308 0.129E-03 0.2483702222 0.0109472591 330.1823 + 201 -229.0351340263 0.127E-03 0.2483327434 0.0109455987 333.5511 + 205 -229.0351475595 0.126E-03 0.2483941897 0.0109485430 337.7478 + 213 -229.0351485558 0.124E-03 0.2484037079 0.0109486035 339.8942 + 221 -229.0351073247 0.117E-03 0.2481791163 0.0109407425 345.1567 + 226 -229.0351302920 0.114E-03 0.2483049699 0.0109450087 353.7547 + 241 -229.0350814731 0.110E-03 0.2480361986 0.0109357923 363.4407 + 258 -229.0350772360 0.105E-03 0.2479875829 0.0109359341 367.0047 + 264 -229.0350651690 0.103E-03 0.2479102201 0.0109340253 369.8247 + 287 -229.0350586702 0.959E-04 0.2479357176 0.0109304668 375.8476 + 288 -229.0350566257 0.956E-04 0.2479269657 0.0109299740 381.2183 + 313 -229.0350789953 0.901E-04 0.2480110614 0.0109355013 385.9923 + 317 -229.0350823169 0.917E-04 0.2480192460 0.0109364591 392.3937 + 359 -229.0350288501 0.823E-04 0.2477099823 0.0109269288 398.4900 + 362 -229.0350505452 0.826E-04 0.2478313214 0.0109310865 402.4853 + 367 -229.0350458308 0.819E-04 0.2478085334 0.0109300703 410.9316 + 394 -229.0350366089 0.773E-04 0.2477706360 0.0109278798 421.5610 + 423 -229.0350493544 0.737E-04 0.2478273158 0.0109306704 424.0982 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 3.010677 GB ] [ VIRT MEM : 10.307865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1088.974053 s ] [ CPU TIME: 75352.271884 s ] <<<<< .. + +* Number of generators 1309983 + +.. >>>>> [ RES MEM : 3.010677 GB ] [ VIRT MEM : 10.307865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1088.977389 s ] [ CPU TIME: 75352.508570 s ] <<<<< .. + +* Number of selectors 1309983 +* Number of comb teeth 100 +* pt2_n_tasks_max 131 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9008213080899830 + +Summary at N_det = 1310720 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.98389801 +# PT2 -0.05118876 0.00006827 +# rPT2 -0.05063498 0.00006753 +# +# E+PT2 -229.03508677 0.00006827 +# E+rPT2 -229.03453299 0.00006753 +# ============ ============================= + + N_det = 1310720 + N_states = 1 + + * State 1 + < S^2 > = 5.710096076521339E-003 + E = -228.983898011485 + Variance = 0.248062137654027 + PT norm = 0.104579087635761 + PT2 = -5.118876249152007E-002 + rPT2 = -5.063497858832119E-002 + E+PT2 = -229.035086773977 +/- 6.826800384146246E-005 + E+rPT2 = -229.034532990073 +/- 6.752944874087403E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.880032798664 + Vee = 238.552632555041 + Vecp = 0.000000000000000E+000 + T = 229.235272453348 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0518 -229.03399325 + -0.0541 -229.03471611 + -0.0579 -229.03706775 + -0.0640 -229.03876696 + -0.0733 -229.03996106 + -0.0873 -229.04102614 + -0.1075 -229.04252095 + =========== =================== + +* Number of unique beta determinants 261798 +* Number of unique alpha determinants 255173 + +.. >>>>> [ RES MEM : 2.972172 GB ] [ VIRT MEM : 10.310429 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1109.958531 s ] [ CPU TIME: 76793.680206 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 2621440 +* Number of threads for diagonalization 72 +* Memory(Gb) 4.109639074653387 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9838980125 0.005710 0.142E-03 + 2 -228.9844923632 0.005837 0.449E-05 + 3 -228.9845026762 0.005828 0.147E-05 + 4 -228.9845036971 0.005826 0.611E-07 + 5 -228.9845038309 0.005817 0.879E-08 + 6 -228.9845038478 0.005812 0.201E-08 + 7 -228.9845038521 0.005808 0.376E-09 + 8 -228.9845038530 0.005806 0.719E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 5.440704 GB ] [ VIRT MEM : 13.394527 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1263.554087 s ] [ CPU TIME: 86928.837230 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 3.214333 GB ] [ VIRT MEM : 10.463364 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1263.799164 s ] [ CPU TIME: 86935.446789 s ] <<<<< .. + +* Energy of state 1 -228.9845038529839 +* S^2 of state 1 0.5805548523999603E-02 +* Saved determinants 2621440 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 2.758858 GB ] [ VIRT MEM : 10.001919 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1284.818563 s ] [ CPU TIME: 87205.020284 s ] <<<<< .. + +* Number of generators 2617346 + +.. >>>>> [ RES MEM : 2.758858 GB ] [ VIRT MEM : 10.001919 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1284.824690 s ] [ CPU TIME: 87205.460437 s ] <<<<< .. + +* Number of selectors 2617346 +* Number of comb teeth 100 +* pt2_n_tasks_max 262 +* PT2 Energy denominator -228.9845038529839 + +.. >>>>> [ RES MEM : 3.080418 GB ] [ VIRT MEM : 10.324696 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1286.237938 s ] [ CPU TIME: 87298.561594 s ] <<<<< .. + +* Number of generators 2617346 + +.. >>>>> [ RES MEM : 3.080418 GB ] [ VIRT MEM : 10.324696 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1286.244012 s ] [ CPU TIME: 87298.998205 s ] <<<<< .. + +* Number of selectors 2617346 +* Number of comb teeth 100 +* pt2_n_tasks_max 262 +* Number of tasks 2783537 +* Number of fragmented tasks 5405 +* Number of threads for PT2 72 +* Memory (Gb) 2.754182940050959 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0339002282 0.127E-02 0.2383532969 0.0106049861 207.3872 + 4 -229.0349281994 0.140E-02 0.2451768117 0.0107472407 214.4210 + 5 -229.0351549161 0.105E-02 0.2459126145 0.0108110491 245.7142 + 7 -229.0346476223 0.734E-03 0.2438850541 0.0106764842 299.2371 + 12 -229.0342218204 0.527E-03 0.2413162488 0.0106090718 305.0932 + 13 -229.0342460092 0.483E-03 0.2412583430 0.0106222462 312.1031 + 15 -229.0342754169 0.502E-03 0.2417397369 0.0106108965 336.3512 + 18 -229.0343079867 0.451E-03 0.2414655167 0.0106356306 337.8061 + 19 -229.0343207745 0.426E-03 0.2414509649 0.0106418138 342.5531 + 20 -229.0342963584 0.407E-03 0.2413750204 0.0106349738 354.8979 + 22 -229.0342078875 0.371E-03 0.2407381163 0.0106252328 360.6961 + 23 -229.0341932804 0.355E-03 0.2406313956 0.0106238318 367.9870 + 27 -229.0342863119 0.356E-03 0.2413537842 0.0106369751 431.5656 + 34 -229.0344146364 0.315E-03 0.2421252898 0.0106557867 451.1501 + 40 -229.0346710524 0.298E-03 0.2435945577 0.0107027487 456.8521 + 41 -229.0347058150 0.293E-03 0.2437810674 0.0107091812 478.2989 + 42 -229.0347055838 0.286E-03 0.2438073427 0.0107078455 490.2771 + 71 -229.0347343146 0.200E-03 0.2438682042 0.0107165981 510.1621 + 76 -229.0347364931 0.199E-03 0.2439339779 0.0107148263 511.9300 + 78 -229.0347136910 0.194E-03 0.2438193557 0.0107101454 530.1231 + 85 -229.0347286684 0.184E-03 0.2438355650 0.0107147209 531.5001 + 89 -229.0347999522 0.188E-03 0.2441431247 0.0107306778 548.1113 + 96 -229.0347684127 0.176E-03 0.2439518676 0.0107251561 551.4530 + 103 -229.0347394024 0.166E-03 0.2437794272 0.0107206288 562.7570 + 110 -229.0347950134 0.160E-03 0.2440551674 0.0107320150 567.1380 + 112 -229.0348220078 0.159E-03 0.2441608095 0.0107391403 573.2921 + 115 -229.0348102598 0.156E-03 0.2440673551 0.0107380638 576.7091 + 120 -229.0349175262 0.162E-03 0.2446169207 0.0107595529 582.3031 + 121 -229.0349211898 0.161E-03 0.2446574455 0.0107596063 591.8262 + 123 -229.0349389499 0.158E-03 0.2447509992 0.0107627731 594.0341 + 126 -229.0349432513 0.155E-03 0.2447593699 0.0107639036 604.7801 + 136 -229.0349380222 0.150E-03 0.2447274357 0.0107628543 606.3282 + 137 -229.0349572145 0.151E-03 0.2448498320 0.0107658492 610.7000 + 138 -229.0349516869 0.150E-03 0.2448075009 0.0107652331 613.0820 + 139 -229.0349465229 0.149E-03 0.2447865931 0.0107639318 614.7463 + 142 -229.0350162323 0.150E-03 0.2451475936 0.0107778108 619.6640 + 144 -229.0350384676 0.149E-03 0.2452874501 0.0107813678 625.7550 + 149 -229.0350418601 0.145E-03 0.2453333652 0.0107809150 635.9415 + 154 -229.0350941475 0.149E-03 0.2455977417 0.0107916263 643.7291 + 160 -229.0350508928 0.143E-03 0.2453532698 0.0107836065 655.7310 + 170 -229.0351090592 0.138E-03 0.2456947922 0.0107936855 664.5170 + 172 -229.0351233252 0.136E-03 0.2457581134 0.0107968678 682.8291 + 182 -229.0351506484 0.130E-03 0.2459118204 0.0108015909 686.8351 + 192 -229.0351688799 0.125E-03 0.2460515443 0.0108034836 690.2071 + 201 -229.0351299134 0.120E-03 0.2458426298 0.0107959607 693.8082 + 203 -229.0351881587 0.119E-03 0.2461513545 0.0108073134 696.1001 + 211 -229.0351687628 0.115E-03 0.2460258788 0.0108043499 701.7441 + 213 -229.0351636263 0.114E-03 0.2460101898 0.0108030473 703.0521 + 215 -229.0351602831 0.113E-03 0.2459934856 0.0108023392 711.0451 + 220 -229.0351511532 0.113E-03 0.2459479822 0.0108003916 712.1881 + 221 -229.0351494607 0.112E-03 0.2459315206 0.0108004338 719.9971 + 224 -229.0351621003 0.113E-03 0.2460297221 0.0108018626 724.4731 + 232 -229.0351878135 0.113E-03 0.2461545175 0.0108071953 734.4001 + 239 -229.0351794414 0.110E-03 0.2460910386 0.0108062580 744.4020 + 253 -229.0351636681 0.105E-03 0.2460102344 0.0108027907 753.9830 + 270 -229.0351561219 0.104E-03 0.2459218020 0.0108033096 761.1351 + 272 -229.0351502812 0.103E-03 0.2458894812 0.0108022162 763.4781 + 279 -229.0351492502 0.999E-04 0.2458848792 0.0108019643 765.9471 + 280 -229.0351441051 0.997E-04 0.2458580328 0.0108010059 775.9720 + 297 -229.0351829264 0.959E-04 0.2460883754 0.0108077386 778.3393 + 302 -229.0351934903 0.950E-04 0.2461410383 0.0108099829 796.9730 + 317 -229.0352111090 0.922E-04 0.2462251635 0.0108138101 798.7495 + 322 -229.0352222073 0.926E-04 0.2462692187 0.0108164693 802.3148 + 331 -229.0352020658 0.915E-04 0.2461539200 0.0108127673 804.6947 + 338 -229.0352043265 0.905E-04 0.2461608127 0.0108132863 810.0180 + 350 -229.0351912744 0.862E-04 0.2460517300 0.0108121743 821.6590 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 4.086342 GB ] [ VIRT MEM : 11.727516 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2116.875280 s ] [ CPU TIME: 146277.575828 s ] <<<<< .. + +* Number of generators 2617346 + +.. >>>>> [ RES MEM : 4.086342 GB ] [ VIRT MEM : 11.727516 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2116.881384 s ] [ CPU TIME: 146278.014478 s ] <<<<< .. + +* Number of selectors 2617346 +* Number of comb teeth 100 +* pt2_n_tasks_max 262 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9017615936342622 + +Summary at N_det = 2621440 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.98450385 +# PT2 -0.05071128 0.00008520 +# rPT2 -0.05016863 0.00008429 +# +# E+PT2 -229.03521513 0.00008520 +# E+rPT2 -229.03467248 0.00008429 +# ============ ============================= + + N_det = 2621440 + N_states = 1 + + * State 1 + < S^2 > = 5.805548523999603E-003 + E = -228.984503852984 + Variance = 0.246182285198738 + PT norm = 0.104002889006785 + PT2 = -5.071127959462747E-002 + rPT2 = -5.016862559279710E-002 + E+PT2 = -229.035215132579 +/- 8.519855453846160E-005 + E+rPT2 = -229.034672478577 +/- 8.428685724073936E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.879850244806 + Vee = 238.550476451090 + Vecp = 0.000000000000000E+000 + T = 229.236640161943 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0506 -229.04967816 + -0.0518 -229.03757782 + -0.0541 -229.03585791 + -0.0579 -229.03728130 + -0.0640 -229.03870621 + -0.0733 -229.03982566 + -0.0873 -229.04086236 + =========== =================== + +* Number of unique beta determinants 501199 +* Number of unique alpha determinants 481071 + +.. >>>>> [ RES MEM : 3.968178 GB ] [ VIRT MEM : 12.105019 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2177.292837 s ] [ CPU TIME: 150376.830663 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5242541 +* Number of threads for diagonalization 72 +* Memory(Gb) 8.164554998278618 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9845038240 0.005806 0.955E-04 + 2 -228.9849197865 0.005933 0.260E-05 + 3 -228.9849266748 0.005930 0.797E-06 + 4 -228.9849272274 0.005928 0.397E-07 + 5 -228.9849273072 0.005923 0.488E-08 + 6 -228.9849273169 0.005918 0.100E-08 + 7 -228.9849273191 0.005916 0.222E-09 + 8 -228.9849273196 0.005915 0.464E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 8.755096 GB ] [ VIRT MEM : 18.264999 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2620.894081 s ] [ CPU TIME: 180228.738324 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 4.146198 GB ] [ VIRT MEM : 12.249359 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2621.309392 s ] [ CPU TIME: 180235.629122 s ] <<<<< .. + +* Energy of state 1 -228.9849273196118 +* S^2 of state 1 0.5914711214097032E-02 +* Saved determinants 5242541 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 3.579494 GB ] [ VIRT MEM : 11.310047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2663.245812 s ] [ CPU TIME: 180722.715664 s ] <<<<< .. + +* Number of generators 5225284 + +.. >>>>> [ RES MEM : 3.579494 GB ] [ VIRT MEM : 11.310047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2663.257540 s ] [ CPU TIME: 180723.559276 s ] <<<<< .. + +* Number of selectors 5225284 +* Number of comb teeth 100 +* pt2_n_tasks_max 523 +* PT2 Energy denominator -228.9849273196118 + +.. >>>>> [ RES MEM : 4.147644 GB ] [ VIRT MEM : 11.879719 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2666.085736 s ] [ CPU TIME: 180891.010938 s ] <<<<< .. + +* Number of generators 5225284 + +.. >>>>> [ RES MEM : 4.147644 GB ] [ VIRT MEM : 11.879719 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2666.096862 s ] [ CPU TIME: 180891.021981 s ] <<<<< .. + +* Number of selectors 5225284 +* Number of comb teeth 100 +* pt2_n_tasks_max 523 +* Number of tasks 5513056 +* Number of fragmented tasks 5425 +* Number of threads for PT2 72 +* Memory (Gb) 2.951584259718656 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0360351758 0.573E-03 0.2489649471 0.0108581875 371.0461 + 4 -229.0362115317 0.388E-03 0.2503505885 0.0108803103 446.2535 + 5 -229.0359427837 0.418E-03 0.2484247006 0.0108497487 479.7401 + 6 -229.0353400712 0.719E-03 0.2447820066 0.0107462281 534.9022 + 7 -229.0355808538 0.630E-03 0.2465373434 0.0107747296 556.9962 + 8 -229.0352439718 0.629E-03 0.2443427067 0.0107277565 620.3252 + 9 -229.0353988230 0.581E-03 0.2447954631 0.0107736059 684.9162 + 12 -229.0353749795 0.474E-03 0.2448934217 0.0107592884 693.0280 + 14 -229.0354446866 0.422E-03 0.2456466260 0.0107572410 720.4472 + 15 -229.0359191839 0.595E-03 0.2483314191 0.0108418520 737.1094 + 17 -229.0359413370 0.572E-03 0.2486130643 0.0108409929 756.6922 + 18 -229.0358138678 0.542E-03 0.2479234899 0.0108169229 780.6202 + 19 -229.0357129412 0.522E-03 0.2474186569 0.0107977680 802.9502 + 20 -229.0356745943 0.493E-03 0.2471683122 0.0107915954 838.8022 + 23 -229.0354030752 0.468E-03 0.2455079685 0.0107474961 857.4292 + 25 -229.0354274287 0.426E-03 0.2456733884 0.0107492538 858.5602 + 27 -229.0356134515 0.445E-03 0.2466178878 0.0107881218 925.7362 + 28 -229.0356602680 0.439E-03 0.2468973675 0.0107953153 927.6562 + 29 -229.0356273987 0.424E-03 0.2466586672 0.0107904104 940.5171 + 30 -229.0358508293 0.456E-03 0.2478248401 0.0108357657 959.4771 + 31 -229.0357583816 0.444E-03 0.2472441026 0.0108217088 984.4812 + 34 -229.0356776892 0.397E-03 0.2469507104 0.0107991713 1018.4024 + 39 -229.0355674699 0.361E-03 0.2460376637 0.0107923956 1022.8874 + 40 -229.0354578752 0.368E-03 0.2453875118 0.0107733800 1035.7572 + 41 -229.0354066270 0.362E-03 0.2451496342 0.0107619822 1070.9952 + 43 -229.0355246295 0.353E-03 0.2457350346 0.0107859242 1088.1741 + 47 -229.0356007748 0.345E-03 0.2460768990 0.0108017652 1103.7111 + 56 -229.0356798921 0.305E-03 0.2465945117 0.0108132057 1110.7322 + 58 -229.0356207079 0.298E-03 0.2463296551 0.0108004718 1114.7022 + 60 -229.0356629199 0.305E-03 0.2466051588 0.0108070653 1136.5006 + 63 -229.0356765495 0.295E-03 0.2466424117 0.0108103460 1150.5096 + 68 -229.0355519310 0.288E-03 0.2459557358 0.0107873167 1155.2061 + 71 -229.0355831907 0.278E-03 0.2462209365 0.0107892819 1169.2971 + 72 -229.0355427553 0.277E-03 0.2460062128 0.0107815122 1173.6122 + 74 -229.0355728962 0.272E-03 0.2461082700 0.0107896538 1179.3481 + 76 -229.0355876273 0.265E-03 0.2461312821 0.0107948283 1184.4101 + 78 -229.0355274329 0.262E-03 0.2458008315 0.0107834818 1194.3241 + 80 -229.0355528733 0.256E-03 0.2458956789 0.0107904313 1195.8152 + 81 -229.0355356750 0.253E-03 0.2458214296 0.0107865471 1202.7472 + 84 -229.0354597789 0.249E-03 0.2454269140 0.0107716276 1207.2141 + 86 -229.0354956452 0.246E-03 0.2456354064 0.0107782373 1211.5481 + 87 -229.0355345330 0.246E-03 0.2458304810 0.0107860388 1228.8451 + 91 -229.0355075017 0.240E-03 0.2456510479 0.0107820635 1239.5908 + 93 -229.0355036541 0.236E-03 0.2456613294 0.0107800494 1267.7422 + 103 -229.0354294653 0.220E-03 0.2452789728 0.0107655520 1274.3794 + 104 -229.0354126214 0.219E-03 0.2452162858 0.0107616456 1282.0614 + 105 -229.0354230447 0.217E-03 0.2452664501 0.0107638191 1289.5179 + 110 -229.0354513164 0.211E-03 0.2454728990 0.0107670166 1301.1485 + 113 -229.0354300214 0.206E-03 0.2453423344 0.0107637252 1309.9983 + 114 -229.0354199310 0.204E-03 0.2452836802 0.0107620162 1314.3123 + 123 -229.0353562509 0.196E-03 0.2449443996 0.0107498736 1321.3008 + 124 -229.0353409079 0.195E-03 0.2448728904 0.0107465243 1336.9003 + 125 -229.0353633118 0.195E-03 0.2449822427 0.0107514154 1353.5152 + 126 -229.0353550659 0.193E-03 0.2449258402 0.0107502428 1356.2562 + 131 -229.0353902287 0.188E-03 0.2451668105 0.0107548614 1367.2452 + 134 -229.0353529190 0.187E-03 0.2449523826 0.0107482016 1371.9212 + 137 -229.0353668151 0.184E-03 0.2449963806 0.0107521264 1383.8803 + 142 -229.0354288746 0.179E-03 0.2453344340 0.0107638436 1394.1023 + 144 -229.0354010039 0.178E-03 0.2452090856 0.0107579181 1399.5838 + 146 -229.0353787347 0.177E-03 0.2450558339 0.0107548113 1400.6873 + 149 -229.0353680658 0.173E-03 0.2450250958 0.0107520225 1422.9712 + 152 -229.0353520371 0.170E-03 0.2449314693 0.0107491906 1430.9262 + 157 -229.0353455064 0.165E-03 0.2449325749 0.0107467838 1438.3524 + 159 -229.0353373336 0.164E-03 0.2448940387 0.0107450420 1442.4063 + 162 -229.0353284635 0.162E-03 0.2448864853 0.0107417801 1444.6304 + 167 -229.0353497044 0.159E-03 0.2450178292 0.0107453740 1454.5062 + 168 -229.0353564201 0.158E-03 0.2450703242 0.0107458272 1466.3431 + 170 -229.0353463892 0.156E-03 0.2450106634 0.0107441437 1470.5813 + 171 -229.0353510045 0.155E-03 0.2450208395 0.0107454789 1482.7083 + 175 -229.0353992667 0.154E-03 0.2452748392 0.0107549293 1486.2438 + 181 -229.0354154160 0.149E-03 0.2453545755 0.0107581529 1493.1573 + 182 -229.0354263811 0.149E-03 0.2454259418 0.0107597830 1506.2555 + 186 -229.0354196097 0.147E-03 0.2454113463 0.0107578350 1526.5613 + 194 -229.0353895975 0.142E-03 0.2451983851 0.0107540995 1539.2653 + 198 -229.0354202253 0.139E-03 0.2453346106 0.0107610838 1541.8991 + 201 -229.0354131107 0.138E-03 0.2452890105 0.0107598780 1556.2252 + 216 -229.0354123699 0.127E-03 0.2452309630 0.0107614953 1560.4513 + 218 -229.0354054119 0.126E-03 0.2451917046 0.0107601261 1564.0303 + 221 -229.0353908859 0.125E-03 0.2451064900 0.0107575377 1580.3753 + 228 -229.0354026034 0.122E-03 0.2451579786 0.0107602603 1586.3662 + 232 -229.0354033398 0.121E-03 0.2451643081 0.0107602616 1598.8532 + 239 -229.0353638330 0.123E-03 0.2449729793 0.0107519455 1609.7938 + 245 -229.0353557847 0.121E-03 0.2449366722 0.0107501003 1612.4063 + 250 -229.0353737591 0.118E-03 0.2450232521 0.0107538058 1614.5932 + 251 -229.0353745117 0.118E-03 0.2450405809 0.0107535721 1620.1383 + 253 -229.0353797197 0.117E-03 0.2450789947 0.0107542761 1621.1604 + 255 -229.0353944825 0.117E-03 0.2451769206 0.0107565085 1632.3543 + 264 -229.0353814163 0.115E-03 0.2450685327 0.0107553813 1640.9102 + 271 -229.0353680730 0.114E-03 0.2449934009 0.0107530989 1657.7063 + 272 -229.0353551487 0.112E-03 0.2449339375 0.0107501670 1658.9415 + 281 -229.0353369730 0.110E-03 0.2448282798 0.0107469224 1668.4524 + 288 -229.0353153076 0.108E-03 0.2447217877 0.0107423666 1672.6605 + 297 -229.0353144121 0.107E-03 0.2447131946 0.0107423767 1679.2266 + 300 -229.0353071839 0.107E-03 0.2446770718 0.0107409319 1686.4882 + 308 -229.0353094915 0.105E-03 0.2446710567 0.0107419430 1688.9708 + 310 -229.0353052469 0.105E-03 0.2446467227 0.0107411553 1693.2002 + 312 -229.0353060058 0.104E-03 0.2446566189 0.0107411397 1701.2775 + 317 -229.0352985224 0.103E-03 0.2446153887 0.0107398392 1712.7790 + 322 -229.0353007222 0.102E-03 0.2446198855 0.0107405466 1714.3637 + 329 -229.0353106445 0.101E-03 0.2446731301 0.0107424629 1728.2822 + 339 -229.0353106563 0.991E-04 0.2446801303 0.0107421062 1729.7912 + 340 -229.0353044788 0.990E-04 0.2446479325 0.0107408908 1747.3299 + 350 -229.0353188808 0.986E-04 0.2447291282 0.0107436456 1754.3913 + 369 -229.0353264352 0.942E-04 0.2447734529 0.0107451181 1759.7161 + 378 -229.0353060817 0.932E-04 0.2446680880 0.0107410369 1761.8910 + 379 -229.0353008614 0.931E-04 0.2446434646 0.0107399311 1768.9176 + 380 -229.0353016810 0.928E-04 0.2446452676 0.0107401728 1771.9249 + 388 -229.0353080562 0.924E-04 0.2446967065 0.0107408014 1779.9634 + 389 -229.0353146334 0.924E-04 0.2447312590 0.0107420729 1783.6802 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 5.636921 GB ] [ VIRT MEM : 13.278938 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4467.264176 s ] [ CPU TIME: 308725.379718 s ] <<<<< .. + +* Number of generators 5225284 + +.. >>>>> [ RES MEM : 5.636921 GB ] [ VIRT MEM : 13.278938 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4467.275310 s ] [ CPU TIME: 308725.390770 s ] <<<<< .. + +* Number of selectors 5225284 +* Number of comb teeth 100 +* pt2_n_tasks_max 523 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9023972396947106 + +Summary at N_det = 5242541 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.98492732 +# PT2 -0.05039025 0.00009085 +# rPT2 -0.04985470 0.00008989 +# +# E+PT2 -229.03531757 0.00009085 +# E+rPT2 -229.03478202 0.00008989 +# ============ ============================= + + N_det = 5242541 + N_states = 1 + + * State 1 + < S^2 > = 5.914711214097032E-003 + E = -228.984927319612 + Variance = 0.244760201658405 + PT norm = 0.103644607662937 + PT2 = -5.039025369528850E-002 + rPT2 = -4.985470425702106E-002 + E+PT2 = -229.035317573307 +/- 9.085386567838499E-005 + E+rPT2 = -229.034782023869 +/- 8.988826750889147E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.879290890579 + Vee = 238.548738903102 + Vecp = 0.000000000000000E+000 + T = 229.237394889077 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0502 -229.05217921 + -0.0506 -229.05061321 + -0.0518 -229.03998258 + -0.0541 -229.03694500 + -0.0579 -229.03765681 + -0.0640 -229.03880315 + -0.0733 -229.03981384 + =========== =================== + +* Number of unique beta determinants 868985 +* Number of unique alpha determinants 879879 + +.. >>>>> [ RES MEM : 5.416641 GB ] [ VIRT MEM : 13.803497 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4666.094440 s ] [ CPU TIME: 322404.061601 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 10475291 +* Number of threads for diagonalization 72 +* Memory(Gb) 16.01978527009487 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9849254312 0.005915 0.106E-03 + 2 -228.9854033731 0.006105 0.290E-05 + 3 -228.9854108408 0.006112 0.891E-06 + 4 -228.9854114531 0.006114 0.410E-07 + 5 -228.9854115342 0.006111 0.531E-08 + 6 -228.9854115443 0.006110 0.816E-09 + 7 -228.9854115461 0.006109 0.151E-09 + 8 -228.9854115465 0.006109 0.292E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 14.696724 GB ] [ VIRT MEM : 25.885727 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6200.654811 s ] [ CPU TIME: 427467.920703 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 5.487305 GB ] [ VIRT MEM : 13.865204 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6201.471713 s ] [ CPU TIME: 427475.136123 s ] <<<<< .. + +* Energy of state 1 -228.9854115464583 +* S^2 of state 1 0.6108559261379354E-02 +* Saved determinants 10475291 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 5.381359 GB ] [ VIRT MEM : 12.812603 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6286.123511 s ] [ CPU TIME: 428366.315449 s ] <<<<< .. + +* Number of generators 10422625 + +.. >>>>> [ RES MEM : 5.381359 GB ] [ VIRT MEM : 12.812603 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6286.146461 s ] [ CPU TIME: 428367.964144 s ] <<<<< .. + +* Number of selectors 10422625 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -228.9854115464583 + +.. >>>>> [ RES MEM : 6.296005 GB ] [ VIRT MEM : 13.731384 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6291.962911 s ] [ CPU TIME: 428675.518685 s ] <<<<< .. + +* Number of generators 10422625 + +.. >>>>> [ RES MEM : 6.296005 GB ] [ VIRT MEM : 13.731384 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6291.984753 s ] [ CPU TIME: 428675.540417 s ] <<<<< .. + +* Number of selectors 10422625 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 10766701 +* Number of fragmented tasks 5448 +* Number of threads for PT2 72 +* Memory (Gb) 3.330494522117078 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0352178107 0.134E-02 0.2399134422 0.0106976259 631.1996 + 4 -229.0349294365 0.103E-02 0.2388300990 0.0106270200 737.9884 + 5 -229.0350250746 0.794E-03 0.2390149320 0.0106608053 821.6100 + 6 -229.0349177159 0.647E-03 0.2391104903 0.0106050504 920.2098 + 7 -229.0350596533 0.592E-03 0.2405675004 0.0106036307 991.4184 + 8 -229.0351669431 0.562E-03 0.2413647380 0.0106174084 1083.4691 + 9 -229.0354973794 0.601E-03 0.2429417433 0.0106906108 1145.8614 + 11 -229.0357164913 0.552E-03 0.2440767223 0.0107302825 1176.9814 + 12 -229.0357294920 0.502E-03 0.2444441068 0.0107198467 1208.9564 + 14 -229.0352565381 0.565E-03 0.2420319399 0.0106246164 1274.4098 + 15 -229.0352445501 0.531E-03 0.2422624021 0.0106101786 1300.5654 + 17 -229.0352636633 0.469E-03 0.2422805147 0.0106182246 1309.1225 + 18 -229.0353345479 0.457E-03 0.2426842200 0.0106313953 1341.8864 + 19 -229.0352553202 0.439E-03 0.2422733192 0.0106155001 1387.6654 + 20 -229.0353185228 0.421E-03 0.2425858510 0.0106276274 1451.3180 + 21 -229.0352549554 0.405E-03 0.2422247544 0.0106160157 1460.3694 + 22 -229.0352329155 0.390E-03 0.2420915765 0.0106125559 1492.9676 + 23 -229.0351983532 0.374E-03 0.2420272673 0.0106019982 1499.9098 + 25 -229.0351271853 0.361E-03 0.2417275303 0.0105847751 1501.0055 + 26 -229.0351387986 0.346E-03 0.2417157806 0.0105900311 1514.6326 + 27 -229.0350707370 0.340E-03 0.2412464739 0.0105817152 1592.1121 + 28 -229.0350772013 0.322E-03 0.2413276604 0.0105807955 1644.4870 + 29 -229.0350343714 0.311E-03 0.2409619957 0.0105784236 1650.8724 + 30 -229.0351648110 0.328E-03 0.2416068120 0.0106057818 1702.7285 + 31 -229.0351241495 0.307E-03 0.2414648263 0.0105949268 1719.2174 + 32 -229.0350840327 0.300E-03 0.2413774936 0.0105836703 1763.8249 + 34 -229.0351785072 0.300E-03 0.2420208492 0.0105968586 1775.4944 + 35 -229.0352209901 0.294E-03 0.2421797575 0.0106074632 1789.4044 + 36 -229.0351369427 0.287E-03 0.2417339949 0.0105931758 1835.5525 + 40 -229.0351856406 0.294E-03 0.2418376972 0.0106086329 1837.2664 + 41 -229.0351439632 0.290E-03 0.2415950622 0.0106011685 1886.9650 + 42 -229.0351887026 0.286E-03 0.2418309274 0.0106097341 1892.3158 + 43 -229.0351622964 0.282E-03 0.2416665842 0.0106053595 1904.2124 + 44 -229.0351718423 0.276E-03 0.2417514854 0.0106063480 1907.5405 + 45 -229.0352056212 0.267E-03 0.2419189830 0.0106136715 1948.3174 + 48 -229.0351356481 0.254E-03 0.2415656127 0.0105996626 1979.6285 + 52 -229.0351315602 0.248E-03 0.2416196735 0.0105963570 1985.0144 + 53 -229.0351388124 0.244E-03 0.2416422950 0.0105983839 1987.0584 + 54 -229.0351235779 0.239E-03 0.2415283829 0.0105967858 1992.3204 + 55 -229.0351622380 0.238E-03 0.2417809703 0.0106025656 2014.0335 + 58 -229.0351615374 0.227E-03 0.2417090749 0.0106045714 2025.3215 + 63 -229.0351077053 0.213E-03 0.2415063493 0.0105910305 2053.8164 + 67 -229.0350779842 0.204E-03 0.2412922859 0.0105876844 2064.9145 + 69 -229.0351235460 0.201E-03 0.2415270586 0.0105964704 2084.5205 + 73 -229.0351098637 0.196E-03 0.2415685824 0.0105893948 2087.0426 + 74 -229.0351054214 0.194E-03 0.2415307294 0.0105888324 2099.0334 + 75 -229.0351826540 0.206E-03 0.2419108180 0.0106046286 2100.1434 + 77 -229.0352254615 0.199E-03 0.2421414141 0.0106124466 2128.5115 + 78 -229.0351837931 0.201E-03 0.2419093380 0.0106047038 2134.0746 + 80 -229.0351682968 0.202E-03 0.2417603713 0.0106043923 2149.5044 + 81 -229.0351419999 0.198E-03 0.2416531676 0.0105977485 2162.7975 + 84 -229.0351255470 0.192E-03 0.2415243007 0.0105959003 2188.3885 + 86 -229.0351097567 0.189E-03 0.2413988657 0.0105942737 2192.5595 + 87 -229.0351091983 0.187E-03 0.2413964989 0.0105941949 2194.4274 + 89 -229.0351444801 0.182E-03 0.2415617502 0.0106017198 2197.6535 + 91 -229.0351404317 0.180E-03 0.2415643559 0.0105997420 2225.4494 + 93 -229.0351682217 0.177E-03 0.2416639599 0.0106068818 2232.5270 + 96 -229.0351351841 0.174E-03 0.2414883157 0.0106003470 2241.9866 + 97 -229.0351501940 0.172E-03 0.2415799044 0.0106029565 2254.8594 + 100 -229.0351935499 0.176E-03 0.2418130244 0.0106109648 2261.4615 + 103 -229.0352439968 0.177E-03 0.2420818226 0.0106207383 2263.3305 + 104 -229.0352405612 0.174E-03 0.2420742723 0.0106195258 2277.5544 + 105 -229.0352481486 0.172E-03 0.2421592403 0.0106196649 2306.4589 + 113 -229.0352536218 0.163E-03 0.2422221689 0.0106194973 2312.8064 + 114 -229.0353005449 0.168E-03 0.2424454625 0.0106294646 2330.8435 + 118 -229.0353136380 0.163E-03 0.2425434625 0.0106313910 2339.3934 + 120 -229.0352981247 0.161E-03 0.2424678086 0.0106281835 2363.9825 + 123 -229.0353212808 0.158E-03 0.2425672795 0.0106335171 2383.2191 + 124 -229.0352954525 0.158E-03 0.2424165345 0.0106289141 2385.0915 + 125 -229.0352947602 0.156E-03 0.2424173724 0.0106286054 2386.6096 + 126 -229.0353204253 0.157E-03 0.2425312885 0.0106343677 2398.3939 + 128 -229.0353355495 0.158E-03 0.2426338013 0.0106365057 2419.1599 + 131 -229.0353059243 0.157E-03 0.2424868316 0.0106302895 2420.3713 + 134 -229.0352857824 0.154E-03 0.2423892766 0.0106261712 2436.5164 + 136 -229.0352925256 0.152E-03 0.2424325010 0.0106273300 2460.5794 + 142 -229.0352794130 0.152E-03 0.2423511247 0.0106252508 2474.8950 + 144 -229.0352771251 0.150E-03 0.2423116167 0.0106259384 2495.9565 + 149 -229.0352809763 0.147E-03 0.2423522609 0.0106260666 2501.8642 + 151 -229.0352559366 0.144E-03 0.2422120779 0.0106214713 2503.6387 + 152 -229.0352523686 0.143E-03 0.2421922496 0.0106208325 2556.8324 + 159 -229.0353109808 0.143E-03 0.2424987822 0.0106322934 2579.2230 + 165 -229.0353275000 0.139E-03 0.2425745084 0.0106361198 2591.5941 + 168 -229.0353280219 0.137E-03 0.2425981766 0.0106355738 2593.9590 + 169 -229.0353162025 0.137E-03 0.2425451022 0.0106330891 2605.8084 + 171 -229.0353084896 0.136E-03 0.2425109338 0.0106313555 2611.1546 + 172 -229.0353231929 0.136E-03 0.2426046176 0.0106335373 2621.1610 + 175 -229.0352976467 0.135E-03 0.2424715761 0.0106285262 2638.0336 + 176 -229.0353165608 0.135E-03 0.2425607470 0.0106325794 2641.3907 + 177 -229.0353006623 0.133E-03 0.2424753144 0.0106295913 2663.7063 + 182 -229.0353096389 0.130E-03 0.2425122232 0.0106316892 2675.5064 + 189 -229.0353296321 0.128E-03 0.2426192139 0.0106354427 2696.1660 + 191 -229.0353278378 0.126E-03 0.2426284152 0.0106346229 2697.2332 + 194 -229.0353308407 0.127E-03 0.2426411979 0.0106353815 2712.4896 + 195 -229.0353177172 0.127E-03 0.2425665143 0.0106330026 2714.5215 + 197 -229.0353346247 0.127E-03 0.2426624105 0.0106360092 2721.6113 + 201 -229.0353107365 0.124E-03 0.2425290894 0.0106315624 2737.7944 + 214 -229.0352364741 0.117E-03 0.2421552976 0.0106162981 2756.1226 + 215 -229.0352324110 0.116E-03 0.2421401305 0.0106154076 2771.4135 + 216 -229.0352428320 0.116E-03 0.2421937605 0.0106175402 2777.1029 + 221 -229.0352630280 0.117E-03 0.2422608485 0.0106229729 2781.5105 + 227 -229.0352641479 0.113E-03 0.2422658040 0.0106232696 2789.9925 + 228 -229.0352686243 0.112E-03 0.2422924687 0.0106240380 2796.1034 + 230 -229.0352584865 0.112E-03 0.2422395768 0.0106220233 2798.4391 + 232 -229.0352562390 0.111E-03 0.2422293939 0.0106215090 2823.3655 + 242 -229.0352629974 0.108E-03 0.2422623914 0.0106227466 2837.0187 + 244 -229.0352468240 0.108E-03 0.2421729857 0.0106196933 2849.7924 + 251 -229.0352815828 0.106E-03 0.2423495980 0.0106266525 2865.4986 + 260 -229.0353014808 0.105E-03 0.2425036710 0.0106290460 2881.4514 + 264 -229.0353044206 0.105E-03 0.2424907041 0.0106308346 2898.8395 + 270 -229.0353032974 0.104E-03 0.2425080199 0.0106298148 2906.9095 + 272 -229.0353092377 0.103E-03 0.2425268892 0.0106313673 2908.1669 + 276 -229.0353320545 0.104E-03 0.2426453149 0.0106359384 2913.9094 + 277 -229.0353244439 0.104E-03 0.2426024105 0.0106345557 2924.8125 + 284 -229.0353534751 0.103E-03 0.2427329232 0.0106409646 2942.4116 + 292 -229.0353401179 0.101E-03 0.2426749372 0.0106378619 2943.4988 + 293 -229.0353385034 0.100E-03 0.2426652919 0.0106375703 2947.2954 + 294 -229.0353392575 0.100E-03 0.2426691877 0.0106376766 2959.0964 + 297 -229.0353432647 0.998E-04 0.2426929324 0.0106383894 2964.2985 + 298 -229.0353532412 0.999E-04 0.2427587317 0.0106399504 2995.8463 + 307 -229.0353714926 0.979E-04 0.2428532408 0.0106436153 2996.8857 + 322 -229.0353792123 0.952E-04 0.2428884764 0.0106452502 2998.8446 + 325 -229.0353898993 0.947E-04 0.2429479745 0.0106471852 3003.8965 + 328 -229.0353932651 0.939E-04 0.2429524019 0.0106482790 3005.7593 + 331 -229.0353923805 0.938E-04 0.2429552797 0.0106477896 3046.2729 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 7.264854 GB ] [ VIRT MEM : 15.574547 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9372.682741 s ] [ CPU TIME: 646400.519227 s ] <<<<< .. + +* Number of generators 10422625 + +.. >>>>> [ RES MEM : 7.264854 GB ] [ VIRT MEM : 15.574547 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9372.705487 s ] [ CPU TIME: 646400.541854 s ] <<<<< .. + +* Number of selectors 10422625 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9032032865030245 + +Summary at N_det = 10475291 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.98541155 +# PT2 -0.04997727 0.00009300 +# rPT2 -0.04945075 0.00009202 +# +# E+PT2 -229.03538882 0.00009300 +# E+rPT2 -229.03486230 0.00009202 +# ============ ============================= + + N_det = 10475291 + N_states = 1 + + * State 1 + < S^2 > = 6.108559261379354E-003 + E = -228.985411546458 + Variance = 0.242929430497387 + PT norm = 0.103185800175506 + PT2 = -4.997726984894135E-002 + rPT2 = -4.945075239026332E-002 + E+PT2 = -229.035388816307 +/- 9.300127300387955E-005 + E+rPT2 = -229.034862298849 +/- 9.202149171402859E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.879439944553 + Vee = 238.547223175624 + Vecp = 0.000000000000000E+000 + T = 229.238575443682 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0499 -229.04468936 + -0.0502 -229.04779373 + -0.0506 -229.04889998 + -0.0518 -229.04147990 + -0.0541 -229.03785915 + -0.0579 -229.03802112 + -0.0640 -229.03892719 + =========== =================== + +* Number of unique beta determinants 1530835 +* Number of unique alpha determinants 1497588 + +.. >>>>> [ RES MEM : 8.544426 GB ] [ VIRT MEM : 17.994793 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 10098.168457 s ] [ CPU TIME: 696568.268270 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 20874179 +* Number of threads for diagonalization 72 +* Memory(Gb) 31.38465037941933 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9854070377 0.006111 0.156E-03 + 2 -228.9861137784 0.006392 0.502E-05 + 3 -228.9861251269 0.006403 0.165E-05 + 4 -228.9861262405 0.006407 0.559E-07 + 5 -228.9861263643 0.006404 0.870E-08 + 6 -228.9861263803 0.006403 0.117E-08 + 7 -228.9861263831 0.006402 0.183E-09 + 8 -228.9861263835 0.006402 0.282E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 26.819542 GB ] [ VIRT MEM : 41.868340 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15774.850623 s ] [ CPU TIME: 1089420.296734 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.312286 GB ] [ VIRT MEM : 17.760899 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15776.568299 s ] [ CPU TIME: 1089427.660264 s ] <<<<< .. + +* Energy of state 1 -228.9861263835472 +* S^2 of state 1 0.6401710654425602E-02 +* Saved determinants 20874179 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.189919 GB ] [ VIRT MEM : 15.500404 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15946.747271 s ] [ CPU TIME: 1091116.358119 s ] <<<<< .. + +* Number of generators 20394048 + +.. >>>>> [ RES MEM : 8.189919 GB ] [ VIRT MEM : 15.500404 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15946.791621 s ] [ CPU TIME: 1091119.543743 s ] <<<<< .. + +* Number of selectors 20394048 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -228.9861263835472 + +.. >>>>> [ RES MEM : 10.548588 GB ] [ VIRT MEM : 17.877865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15959.446853 s ] [ CPU TIME: 1091683.721494 s ] <<<<< .. + +* Number of generators 20394048 + +.. >>>>> [ RES MEM : 10.548588 GB ] [ VIRT MEM : 17.877865 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15959.489262 s ] [ CPU TIME: 1091683.763742 s ] <<<<< .. + +* Number of selectors 20394048 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 20739457 +* Number of fragmented tasks 5478 +* Number of threads for PT2 72 +* Memory (Gb) 4.065415698885918 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0359969659 0.118E-02 0.2417275586 0.0106404371 939.4206 + 4 -229.0357976592 0.868E-03 0.2415644275 0.0105739089 1070.9896 + 5 -229.0360324614 0.704E-03 0.2415867267 0.0106698552 1270.8977 + 6 -229.0365469139 0.783E-03 0.2448869031 0.0107419024 1387.7192 + 7 -229.0361939990 0.786E-03 0.2433732922 0.0106617574 1456.0397 + 8 -229.0357032097 0.853E-03 0.2404896754 0.0105784970 1597.2600 + 9 -229.0356376294 0.739E-03 0.2394681083 0.0105946404 1712.1116 + 10 -229.0355368920 0.666E-03 0.2387897320 0.0105837236 1724.8007 + 11 -229.0355884973 0.618E-03 0.2398219662 0.0105671252 1741.4388 + 12 -229.0358647207 0.669E-03 0.2415271494 0.0106081539 1815.2806 + 13 -229.0355855666 0.675E-03 0.2398981534 0.0105610638 1839.0856 + 14 -229.0355249489 0.631E-03 0.2395112213 0.0105493733 1882.9737 + 15 -229.0354348024 0.609E-03 0.2390394179 0.0105308829 2014.3346 + 18 -229.0357408002 0.580E-03 0.2404304173 0.0106034738 2042.8226 + 19 -229.0357024313 0.550E-03 0.2404678400 0.0105865713 2125.9586 + 20 -229.0356276724 0.522E-03 0.2400322531 0.0105730340 2188.6074 + 21 -229.0355307829 0.506E-03 0.2395469286 0.0105548273 2196.9196 + 23 -229.0355013628 0.463E-03 0.2396634411 0.0105387025 2229.8187 + 24 -229.0353924897 0.446E-03 0.2392412513 0.0105094948 2258.1906 + 25 -229.0355804208 0.468E-03 0.2403510163 0.0105430413 2268.5267 + 26 -229.0353848575 0.491E-03 0.2392511059 0.0105082280 2346.5141 + 27 -229.0353496621 0.476E-03 0.2391113915 0.0104981397 2405.4237 + 28 -229.0353700760 0.459E-03 0.2392231475 0.0105030176 2478.9536 + 29 -229.0353070176 0.448E-03 0.2389280282 0.0104881595 2503.8116 + 30 -229.0352802792 0.438E-03 0.2388569023 0.0104794889 2544.9205 + 31 -229.0352898071 0.419E-03 0.2388940518 0.0104821075 2546.8006 + 32 -229.0353093127 0.406E-03 0.2389750776 0.0104865517 2618.5676 + 33 -229.0352535262 0.398E-03 0.2386184549 0.0104781869 2649.4978 + 34 -229.0353433778 0.386E-03 0.2392747733 0.0104880165 2706.7226 + 36 -229.0352826624 0.376E-03 0.2388976994 0.0104778231 2784.2779 + 40 -229.0352735413 0.339E-03 0.2387186456 0.0104787692 2789.0507 + 41 -229.0352768073 0.330E-03 0.2386956027 0.0104806328 2795.7496 + 42 -229.0352532571 0.323E-03 0.2386220794 0.0104745028 2870.0766 + 43 -229.0353182502 0.315E-03 0.2389813634 0.0104870161 2880.8996 + 44 -229.0353510935 0.309E-03 0.2391549166 0.0104935927 2927.6277 + 46 -229.0353833317 0.298E-03 0.2394076165 0.0104971087 2943.8587 + 49 -229.0353694874 0.283E-03 0.2394896719 0.0104888551 2955.3986 + 50 -229.0353989432 0.279E-03 0.2396482464 0.0104948425 2965.3461 + 51 -229.0354004644 0.273E-03 0.2395745576 0.0104982323 3006.0996 + 52 -229.0354135216 0.266E-03 0.2396982818 0.0104987778 3020.2246 + 54 -229.0354133500 0.264E-03 0.2396886962 0.0104994615 3029.7867 + 56 -229.0353416661 0.261E-03 0.2393315159 0.0104844441 3040.9437 + 58 -229.0353144217 0.249E-03 0.2391442966 0.0104802864 3060.8326 + 60 -229.0353225325 0.239E-03 0.2392502081 0.0104795651 3068.7938 + 61 -229.0353310340 0.235E-03 0.2393459180 0.0104793331 3081.0103 + 63 -229.0352544324 0.234E-03 0.2389524922 0.0104640806 3110.5395 + 67 -229.0353610719 0.240E-03 0.2394582533 0.0104867059 3130.3256 + 70 -229.0353364806 0.231E-03 0.2393357195 0.0104816067 3138.5127 + 71 -229.0353766511 0.232E-03 0.2394996343 0.0104913025 3166.1048 + 74 -229.0352942385 0.231E-03 0.2390354218 0.0104758715 3187.1435 + 76 -229.0352663897 0.226E-03 0.2388941184 0.0104698864 3213.8596 + 77 -229.0352818688 0.218E-03 0.2389932912 0.0104721569 3233.2825 + 78 -229.0352574439 0.217E-03 0.2388719771 0.0104671062 3241.0668 + 80 -229.0352314084 0.212E-03 0.2387631178 0.0104614280 3254.5036 + 81 -229.0352656359 0.208E-03 0.2389730349 0.0104669338 3258.0732 + 82 -229.0352474988 0.206E-03 0.2388725205 0.0104635363 3295.6510 + 84 -229.0352680919 0.204E-03 0.2389870461 0.0104672139 3302.9747 + 85 -229.0352561828 0.202E-03 0.2389260422 0.0104648337 3324.0900 + 86 -229.0352700160 0.200E-03 0.2390333715 0.0104662952 3344.5700 + 89 -229.0352904717 0.197E-03 0.2391077052 0.0104714131 3350.9268 + 91 -229.0352750844 0.197E-03 0.2390175206 0.0104684932 3365.6426 + 92 -229.0352566327 0.196E-03 0.2389118564 0.0104651048 3374.8817 + 93 -229.0352631458 0.194E-03 0.2389590742 0.0104661520 3405.4628 + 98 -229.0352593054 0.188E-03 0.2389003891 0.0104669460 3413.3806 + 100 -229.0352043820 0.189E-03 0.2386021903 0.0104563771 3419.3046 + 101 -229.0351816804 0.188E-03 0.2384901445 0.0104517016 3441.2945 + 103 -229.0351489729 0.186E-03 0.2383137466 0.0104454803 3458.6347 + 104 -229.0351770858 0.187E-03 0.2385189374 0.0104487615 3469.3517 + 107 -229.0351659285 0.185E-03 0.2384384677 0.0104474792 3488.4886 + 109 -229.0351764455 0.182E-03 0.2385213976 0.0104484151 3489.6567 + 110 -229.0351687520 0.181E-03 0.2384837468 0.0104467028 3524.1677 + 113 -229.0352075942 0.178E-03 0.2387094015 0.0104531893 3541.9766 + 114 -229.0351788911 0.179E-03 0.2385350654 0.0104483827 3560.7266 + 118 -229.0351574363 0.176E-03 0.2384398760 0.0104434505 3573.1349 + 120 -229.0351587318 0.173E-03 0.2384537346 0.0104434584 3577.0058 + 122 -229.0351472409 0.172E-03 0.2383982223 0.0104411756 3586.1267 + 123 -229.0351581144 0.170E-03 0.2384566395 0.0104434198 3619.8306 + 124 -229.0351382598 0.170E-03 0.2383656177 0.0104392054 3645.8076 + 128 -229.0351843688 0.167E-03 0.2386191757 0.0104477065 3670.7369 + 129 -229.0351564501 0.168E-03 0.2384668888 0.0104424194 3685.5807 + 134 -229.0351502803 0.163E-03 0.2384690388 0.0104398736 3697.4434 + 136 -229.0351212318 0.160E-03 0.2383145780 0.0104342233 3735.8966 + 137 -229.0351310887 0.160E-03 0.2383825707 0.0104355411 3744.7476 + 138 -229.0351300738 0.158E-03 0.2383637874 0.0104357605 3748.4427 + 143 -229.0351252587 0.158E-03 0.2383264823 0.0104351416 3774.4173 + 146 -229.0351040858 0.157E-03 0.2382166771 0.0104308809 3778.0423 + 147 -229.0351276407 0.158E-03 0.2383611194 0.0104348235 3785.0457 + 148 -229.0351061567 0.158E-03 0.2382476719 0.0104306321 3810.4179 + 149 -229.0351150399 0.157E-03 0.2382987889 0.0104321587 3818.4476 + 152 -229.0350932783 0.156E-03 0.2381944502 0.0104276791 3845.5988 + 153 -229.0350926596 0.155E-03 0.2381891482 0.0104275772 3856.7769 + 154 -229.0350813311 0.154E-03 0.2381274393 0.0104255162 3868.1037 + 156 -229.0350705839 0.152E-03 0.2380608353 0.0104237436 3893.9469 + 157 -229.0350760713 0.150E-03 0.2380824059 0.0104251222 3898.6137 + 160 -229.0350640323 0.149E-03 0.2380037644 0.0104231543 3941.0861 + 163 -229.0350472870 0.147E-03 0.2379187269 0.0104197028 3997.4286 + 174 -229.0350877308 0.145E-03 0.2381556116 0.0104265228 3998.5346 + 175 -229.0350909667 0.144E-03 0.2381764002 0.0104269826 4027.8466 + 177 -229.0350773401 0.143E-03 0.2381179649 0.0104238429 4035.0439 + 182 -229.0350717424 0.140E-03 0.2380948845 0.0104224040 4061.5837 + 186 -229.0350318266 0.138E-03 0.2378722677 0.0104149783 4083.1356 + 188 -229.0350365954 0.137E-03 0.2378808024 0.0104164726 4084.5197 + 190 -229.0350386793 0.138E-03 0.2378840485 0.0104171320 4098.2592 + 191 -229.0350418602 0.137E-03 0.2378924118 0.0104180927 4103.6985 + 193 -229.0350633345 0.137E-03 0.2380227648 0.0104218132 4106.1877 + 194 -229.0350737818 0.137E-03 0.2380843720 0.0104236236 4120.7057 + 197 -229.0350969064 0.135E-03 0.2381787490 0.0104290285 4131.1001 + 201 -229.0350967249 0.134E-03 0.2381703909 0.0104292091 4152.0950 + 203 -229.0350974764 0.131E-03 0.2381603981 0.0104297990 4161.3680 + 207 -229.0350902553 0.129E-03 0.2381078300 0.0104288744 4198.2496 + 215 -229.0351324134 0.126E-03 0.2383351287 0.0104372717 4204.0439 + 216 -229.0351255715 0.126E-03 0.2382962708 0.0104360182 4226.3014 + 221 -229.0351263276 0.123E-03 0.2382883805 0.0104365923 4238.3843 + 224 -229.0351643508 0.122E-03 0.2384597395 0.0104453644 4252.3329 + 227 -229.0351765080 0.122E-03 0.2385314784 0.0104475462 4257.0279 + 229 -229.0351614009 0.122E-03 0.2384445225 0.0104449166 4265.3387 + 230 -229.0351631850 0.121E-03 0.2384681755 0.0104447776 4270.1790 + 231 -229.0351596361 0.121E-03 0.2384393403 0.0104444196 4290.1297 + 232 -229.0351492791 0.121E-03 0.2383784029 0.0104426607 4300.8821 + 241 -229.0351296351 0.119E-03 0.2382503303 0.0104398244 4320.7946 + 245 -229.0351303123 0.117E-03 0.2382467575 0.0104402251 4338.2553 + 247 -229.0351287861 0.116E-03 0.2382175446 0.0104407732 4339.4794 + 250 -229.0351201952 0.115E-03 0.2381669949 0.0104392121 4343.0691 + 251 -229.0351077808 0.115E-03 0.2381021721 0.0104367747 4364.1467 + 257 -229.0351497320 0.116E-03 0.2383282039 0.0104447564 4369.4998 + 258 -229.0351602770 0.116E-03 0.2383866324 0.0104466918 4381.9156 + 259 -229.0351742672 0.116E-03 0.2384574135 0.0104495745 4385.7705 + 264 -229.0351701706 0.114E-03 0.2384555408 0.0104481110 4433.4186 + 270 -229.0351669862 0.111E-03 0.2384290980 0.0104477579 4435.7674 + 271 -229.0351679062 0.111E-03 0.2384360887 0.0104478270 4447.7607 + 272 -229.0351706007 0.110E-03 0.2384692982 0.0104475809 4460.3709 + 276 -229.0351572249 0.109E-03 0.2384099695 0.0104448233 4474.5785 + 286 -229.0351898304 0.107E-03 0.2385742333 0.0104514938 4476.8286 + 288 -229.0351943588 0.106E-03 0.2385819858 0.0104529198 4494.6936 + 293 -229.0351915772 0.105E-03 0.2385574453 0.0104527029 4518.8425 + 297 -229.0352117940 0.105E-03 0.2386660597 0.0104565653 4542.4426 + 302 -229.0352240316 0.103E-03 0.2387025027 0.0104600610 4561.7468 + 308 -229.0352337437 0.102E-03 0.2387345224 0.0104625888 4578.1717 + 311 -229.0352298715 0.102E-03 0.2387129640 0.0104618840 4581.9965 + 313 -229.0352243895 0.101E-03 0.2386803583 0.0104609257 4586.9666 + 316 -229.0352206819 0.101E-03 0.2386531467 0.0104604094 4590.6026 + 322 -229.0352192594 0.990E-04 0.2386266102 0.0104608036 4611.7437 + 328 -229.0352312696 0.976E-04 0.2386927146 0.0104630528 4619.7306 + 329 -229.0352335734 0.973E-04 0.2387137251 0.0104632142 4676.4754 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 11.221844 GB ] [ VIRT MEM : 18.798542 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 20703.723527 s ] [ CPU TIME: 1424843.181628 s ] <<<<< .. + +* Number of generators 20394048 + +.. >>>>> [ RES MEM : 11.221844 GB ] [ VIRT MEM : 18.798542 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 20703.766192 s ] [ CPU TIME: 1424843.224133 s ] <<<<< .. + +* Number of selectors 20394048 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9048192442324852 + +Summary at N_det = 20874179 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.98612638 +# PT2 -0.04912232 0.00009333 +# rPT2 -0.04861356 0.00009237 +# +# E+PT2 -229.03524871 0.00009333 +# E+rPT2 -229.03473994 0.00009237 +# ============ ============================= + + N_det = 20874179 + N_states = 1 + + * State 1 + < S^2 > = 6.401710654425602E-003 + E = -228.986126383547 + Variance = 0.238809820818507 + PT norm = 0.102300821544905 + PT2 = -4.912232161077743E-002 + rPT2 = -4.861355845224981E-002 + E+PT2 = -229.035248705158 +/- 9.333227992781128E-005 + E+rPT2 = -229.034739941999 +/- 9.236563128475856E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.879637447024 + Vee = 238.544960736150 + Vecp = 0.000000000000000E+000 + T = 229.240320548537 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0495 -229.02763501 + -0.0499 -229.03228816 + -0.0502 -229.03616083 + -0.0506 -229.03988651 + -0.0518 -229.03923883 + -0.0541 -229.03751452 + -0.0579 -229.03784917 + =========== =================== + +* Number of unique beta determinants 2536040 +* Number of unique alpha determinants 2544601 + +.. >>>>> [ RES MEM : 15.462521 GB ] [ VIRT MEM : 26.321381 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 23621.094129 s ] [ CPU TIME: 1626360.272615 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 41535888 +* Number of threads for diagonalization 72 +* Memory(Gb) 61.23727364093065 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9861136432 0.006407 0.242E-03 + 2 -228.9871979513 0.006806 0.997E-05 + 3 -228.9872169779 0.006817 0.320E-05 + 4 -228.9872192753 0.006820 0.107E-06 + 5 -228.9872195212 0.006814 0.204E-07 + 6 -228.9872195593 0.006808 0.347E-08 + 7 -228.9872195679 0.006803 0.779E-09 + 8 -228.9872195698 0.006801 0.149E-09 + 9 -228.9872195702 0.006800 0.281E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 53.833603 GB ] [ VIRT MEM : 73.976215 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 49559.182430 s ] [ CPU TIME: 3416346.475533 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 15.150467 GB ] [ VIRT MEM : 26.007446 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 49562.723128 s ] [ CPU TIME: 3416355.182074 s ] <<<<< .. + +* Energy of state 1 -228.9872195701786 +* S^2 of state 1 0.6799588768914223E-02 +* Saved determinants 41535888 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 14.539852 GB ] [ VIRT MEM : 21.973328 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 49903.417683 s ] [ CPU TIME: 3419484.820796 s ] <<<<< .. + +* Number of generators 37162639 + +.. >>>>> [ RES MEM : 14.539852 GB ] [ VIRT MEM : 21.973328 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 49903.501175 s ] [ CPU TIME: 3419490.815183 s ] <<<<< .. + +* Number of selectors 37162639 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -228.9872195701786 + +.. >>>>> [ RES MEM : 18.904877 GB ] [ VIRT MEM : 26.461136 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 49928.996946 s ] [ CPU TIME: 3420566.956819 s ] <<<<< .. + +* Number of generators 37162639 + +.. >>>>> [ RES MEM : 18.904877 GB ] [ VIRT MEM : 26.461136 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 49929.077767 s ] [ CPU TIME: 3420567.037388 s ] <<<<< .. + +* Number of selectors 37162639 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 37508131 +* Number of fragmented tasks 5507 +* Number of threads for PT2 72 +* Memory (Gb) 5.443207478262484 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0323412951 0.650E-03 0.2189284866 0.0096391553 55483.9493 + 4 -229.0331329386 0.953E-03 0.2228319978 0.0098007467 67357.8899 + 5 -229.0337213725 0.930E-03 0.2245446817 0.0099682578 77778.8509 + 6 -229.0342103582 0.894E-03 0.2276708685 0.0100387531 88184.2083 + 7 -229.0343276857 0.792E-03 0.2283764038 0.0100542075 95368.1613 + 8 -229.0342254119 0.699E-03 0.2275014781 0.0100491321 ********** + 9 -229.0345781730 0.697E-03 0.2295966528 0.0101114562 ********** + 10 -229.0347013428 0.604E-03 0.2304754835 0.0101285053 ********** + 11 -229.0345518865 0.538E-03 0.2296879853 0.0100968458 ********** + 12 -229.0344327510 0.490E-03 0.2289127550 0.0100782293 ********** + 13 -229.0344923095 0.459E-03 0.2294660747 0.0100858892 ********** + 14 -229.0344964021 0.417E-03 0.2296455906 0.0100795258 ********** + 15 -229.0347270557 0.437E-03 0.2307933120 0.0101262316 ********** + 16 -229.0348549041 0.429E-03 0.2318527177 0.0101386058 ********** + 17 -229.0347117751 0.411E-03 0.2308808501 0.0101196552 ********** + 18 -229.0347098490 0.387E-03 0.2307855176 0.0101222618 ********** + 19 -229.0347558307 0.369E-03 0.2311836359 0.0101259757 ********** + 20 -229.0347050602 0.358E-03 0.2307091363 0.0101237645 ********** + 21 -229.0346932634 0.341E-03 0.2305843786 0.0101241364 ********** + 22 -229.0347670226 0.324E-03 0.2310228154 0.0101365026 ********** + 23 -229.0346794014 0.322E-03 0.2305739426 0.0101193864 ********** + 24 -229.0347271507 0.312E-03 0.2309748690 0.0101230489 ********** + 25 -229.0347568209 0.299E-03 0.2312614191 0.0101226810 ********** + 26 -229.0347708699 0.287E-03 0.2314339933 0.0101221765 ********** + 27 -229.0347938630 0.277E-03 0.2315014655 0.0101278957 ********** + 28 -229.0348954858 0.281E-03 0.2320219979 0.0101481917 ********** + 29 -229.0349142194 0.271E-03 0.2321095013 0.0101526175 ********** + 30 -229.0348674088 0.266E-03 0.2318394297 0.0101441070 ********** + 31 -229.0348134006 0.263E-03 0.2316528443 0.0101297397 ********** + 32 -229.0347418896 0.265E-03 0.2313681408 0.0101123647 ********** + 33 -229.0347394795 0.256E-03 0.2312819145 0.0101146564 ********** + 34 -229.0347135673 0.255E-03 0.2310438142 0.0101141004 ********** + 35 -229.0347342715 0.248E-03 0.2311335854 0.0101190281 ********** + 36 -229.0347694898 0.248E-03 0.2313832779 0.0101237279 ********** + 37 -229.0348104320 0.244E-03 0.2315882602 0.0101322961 ********** + 38 -229.0348320346 0.239E-03 0.2317169636 0.0101353083 ********** + 39 -229.0348276348 0.233E-03 0.2316761127 0.0101351280 ********** + 40 -229.0349141288 0.239E-03 0.2320750288 0.0101537287 ********** + 41 -229.0350019232 0.245E-03 0.2325468186 0.0101697556 ********** + 42 -229.0349405052 0.247E-03 0.2322337939 0.0101574950 ********** + 43 -229.0349705459 0.250E-03 0.2323773703 0.0101635773 ********** + 44 -229.0350632232 0.261E-03 0.2328793305 0.0101812611 ********** + 45 -229.0350548459 0.264E-03 0.2328079086 0.0101805192 ********** + 46 -229.0349920854 0.266E-03 0.2325219739 0.0101668515 ********** + 47 -229.0348994989 0.276E-03 0.2320856436 0.0101471574 ********** + 48 -229.0349348891 0.277E-03 0.2322487307 0.0101546661 ********** + 49 -229.0349561937 0.268E-03 0.2323300822 0.0101600295 ********** + 50 -229.0350524542 0.280E-03 0.2329277230 0.0101756163 ********** + 51 -229.0350046613 0.277E-03 0.2326318190 0.0101679418 ********** + 52 -229.0349991819 0.272E-03 0.2326216597 0.0101664041 ********** + 53 -229.0349537656 0.271E-03 0.2323709935 0.0101583458 ********** + 54 -229.0350630423 0.284E-03 0.2328836309 0.0101822579 ********** + 55 -229.0351019269 0.281E-03 0.2331244906 0.0101887234 ********** + 56 -229.0350287112 0.286E-03 0.2327091803 0.0101756784 ********** + 57 -229.0350476557 0.282E-03 0.2328540803 0.0101777123 ********** + 58 -229.0350827424 0.279E-03 0.2330702933 0.0101836126 ********** + 60 -229.0351501135 0.274E-03 0.2334764903 0.0101956593 ********** + 61 -229.0351030166 0.273E-03 0.2332101354 0.0101872008 ********** + 62 -229.0350919672 0.266E-03 0.2330774811 0.0101872559 ********** + 63 -229.0351417693 0.267E-03 0.2333461028 0.0101969158 ********** + 64 -229.0351760218 0.265E-03 0.2335261352 0.0102034696 ********** + 65 -229.0351669236 0.261E-03 0.2335102999 0.0102005105 ********** + 67 -229.0351641833 0.258E-03 0.2334625621 0.0102009097 ********** + 68 -229.0351946018 0.253E-03 0.2336017125 0.0102076216 ********** + 69 -229.0352198544 0.250E-03 0.2337523447 0.0102119076 ********** + 70 -229.0352267865 0.247E-03 0.2337852622 0.0102133428 ********** + 71 -229.0351860967 0.247E-03 0.2335434587 0.0102063988 ********** + 72 -229.0351876433 0.243E-03 0.2335533687 0.0102064984 ********** + 73 -229.0351386259 0.245E-03 0.2332783560 0.0101975379 ********** + 74 -229.0351613998 0.243E-03 0.2334095474 0.0102014164 ********** + 75 -229.0352210814 0.244E-03 0.2336868582 0.0102148511 ********** + 76 -229.0352277158 0.240E-03 0.2337819527 0.0102142718 ********** + 77 -229.0352092541 0.238E-03 0.2336854281 0.0102105842 ********** + 78 -229.0352038444 0.235E-03 0.2336639050 0.0102094200 ********** + 79 -229.0352073789 0.230E-03 0.2337039776 0.0102091041 ********** + 80 -229.0351977266 0.227E-03 0.2336235052 0.0102082414 ********** + 81 -229.0351964685 0.224E-03 0.2335979776 0.0102086317 ********** + 82 -229.0351835125 0.222E-03 0.2335047428 0.0102068823 ********** + 83 -229.0351787353 0.219E-03 0.2334806308 0.0102057515 ********** + 84 -229.0351779098 0.217E-03 0.2334868646 0.0102051995 ********** + 85 -229.0352126351 0.211E-03 0.2336622063 0.0102120895 ********** + 86 -229.0351913674 0.209E-03 0.2335217755 0.0102088275 ********** + 87 -229.0351767477 0.207E-03 0.2334453269 0.0102058129 ********** + 88 -229.0351899903 0.206E-03 0.2334873760 0.0102093170 ********** + 89 -229.0351971989 0.203E-03 0.2335319509 0.0102104047 ********** + 90 -229.0352069695 0.201E-03 0.2335776652 0.0102125790 ********** + 91 -229.0352482349 0.203E-03 0.2338181493 0.0102198972 ********** + 92 -229.0352593692 0.202E-03 0.2338742532 0.0102221583 ********** + 93 -229.0352667436 0.200E-03 0.2339051638 0.0102237337 ********** + 94 -229.0352727029 0.198E-03 0.2339464899 0.0102245238 ********** + 95 -229.0352987120 0.198E-03 0.2340585530 0.0102305495 ********** + 96 -229.0352663468 0.199E-03 0.2338840467 0.0102244576 ********** + 97 -229.0352804408 0.196E-03 0.2338935423 0.0102294627 ********** + 98 -229.0353071955 0.195E-03 0.2341189446 0.0102321780 ********** + 99 -229.0353587378 0.200E-03 0.2344020708 0.0102418148 ********** + 100 -229.0353317471 0.200E-03 0.2342583295 0.0102365262 ********** + 101 -229.0353305123 0.198E-03 0.2342415306 0.0102368113 ********** + 102 -229.0353499520 0.197E-03 0.2343860132 0.0102394284 ********** + 103 -229.0353631296 0.193E-03 0.2344545793 0.0102419312 ********** + 104 -229.0353602426 0.192E-03 0.2344397378 0.0102413754 ********** + 105 -229.0353496626 0.190E-03 0.2343633083 0.0102399911 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0.2339297985 0.0102340284 ********** + 240 -229.0352907678 0.114E-03 0.2339296621 0.0102334452 ********** + 241 -229.0352861619 0.114E-03 0.2339158783 0.0102322101 ********** + 242 -229.0352776144 0.114E-03 0.2338745411 0.0102304537 ********** + 243 -229.0352825216 0.113E-03 0.2339101354 0.0102310496 ********** + 244 -229.0352718950 0.113E-03 0.2338500392 0.0102290961 ********** + 245 -229.0352641782 0.113E-03 0.2338098023 0.0102275603 ********** + 246 -229.0352688163 0.113E-03 0.2338395581 0.0102282324 ********** + 247 -229.0352629865 0.112E-03 0.2338120979 0.0102270028 ********** + 248 -229.0352615523 0.112E-03 0.2338033357 0.0102267159 ********** + 249 -229.0352556217 0.112E-03 0.2337725963 0.0102255243 ********** + 250 -229.0352521287 0.111E-03 0.2337554291 0.0102247732 ********** + 251 -229.0352523871 0.108E-03 0.2337587479 0.0102247505 ********** + 253 -229.0352637379 0.108E-03 0.2338190348 0.0102268846 ********** + 254 -229.0352543912 0.108E-03 0.2337690980 0.0102250761 ********** + 255 -229.0352475403 0.108E-03 0.2337301851 0.0102238702 ********** + 256 -229.0352536042 0.107E-03 0.2337665279 0.0102249066 ********** + 257 -229.0352447595 0.107E-03 0.2337206646 0.0102231815 ********** + 258 -229.0352474200 0.107E-03 0.2337383464 0.0102235443 ********** + 259 -229.0352447874 0.107E-03 0.2337249332 0.0102229788 ********** + 260 -229.0352372188 0.106E-03 0.2336883354 0.0102214165 ********** + 261 -229.0352401520 0.106E-03 0.2337059521 0.0102218985 ********** + 262 -229.0352442081 0.106E-03 0.2337341374 0.0102224299 ********** + 263 -229.0352362232 0.106E-03 0.2336891990 0.0102209419 ********** + 264 -229.0352388575 0.104E-03 0.2337076776 0.0102212379 ********** + 265 -229.0352446076 0.104E-03 0.2337398396 0.0102222809 ********** + 266 -229.0352447464 0.104E-03 0.2337369519 0.0102225141 ********** + 267 -229.0352425229 0.103E-03 0.2337249470 0.0102220693 ********** + 268 -229.0352410793 0.103E-03 0.2337166189 0.0102217849 ********** + 269 -229.0352464508 0.103E-03 0.2337422392 0.0102229834 ********** + 270 -229.0352594597 0.103E-03 0.2338122330 0.0102254318 ********** + 271 -229.0352486492 0.103E-03 0.2337513820 0.0102234370 ********** + 272 -229.0352420569 0.103E-03 0.2337222012 0.0102219884 ********** + 273 -229.0352357657 0.103E-03 0.2336872543 0.0102208577 ********** + 274 -229.0352351920 0.102E-03 0.2336881930 0.0102206072 ********** + 275 -229.0352358675 0.100E-03 0.2336907712 0.0102207858 ********** + 276 -229.0352367546 0.100E-03 0.2336986481 0.0102208989 ********** + 277 -229.0352307817 0.999E-04 0.2336675857 0.0102196968 ********** + 278 -229.0352250242 0.997E-04 0.2336362579 0.0102185920 ********** + 279 -229.0352209140 0.994E-04 0.2336234919 0.0102175310 ********** + 280 -229.0352134139 0.993E-04 0.2335832912 0.0102160698 ********** + 281 -229.0352153083 0.990E-04 0.2335894025 0.0102165944 ********** + 282 -229.0352092194 0.988E-04 0.2335570744 0.0102154222 ********** + 284 -229.0352090063 0.981E-04 0.2335461109 0.0102157346 ********** + 285 -229.0351995337 0.983E-04 0.2334926572 0.0102139964 ********** + 286 -229.0351953420 0.980E-04 0.2334699018 0.0102131945 ********** + 287 -229.0351969145 0.977E-04 0.2334773284 0.0102134908 ********** + 288 -229.0352114656 0.984E-04 0.2335494515 0.0102164910 ********** + 289 -229.0352101887 0.981E-04 0.2335515547 0.0102159946 ********** + 290 -229.0352022749 0.981E-04 0.2335092982 0.0102144695 ********** + 291 -229.0351962264 0.979E-04 0.2334784559 0.0102132460 ********** + 292 -229.0351968324 0.976E-04 0.2334759548 0.0102135541 ********** + 293 -229.0351968312 0.956E-04 0.2334723363 0.0102136513 ********** +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 18.493557 GB ] [ VIRT MEM : 27.169033 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 341369.429200 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 37162639 + +.. >>>>> [ RES MEM : 18.493557 GB ] [ VIRT MEM : 27.169033 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 341369.509276 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 37162639 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.9070096425804415 + +Summary at N_det = 41535888 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.98721957 +# PT2 -0.04797726 0.00009557 +# rPT2 -0.04749219 0.00009460 +# +# E+PT2 -229.03519683 0.00009557 +# E+rPT2 -229.03471176 0.00009460 +# ============ ============================= + + N_det = 41535888 + N_states = 1 + + * State 1 + < S^2 > = 6.799588768914223E-003 + E = -228.987219570179 + Variance = 0.233472336322019 + PT norm = 0.101062610889032 + PT2 = -4.797726106079422E-002 + rPT2 = -4.749219236754364E-002 + E+PT2 = -229.035196831239 +/- 9.556674766119508E-005 + E+rPT2 = -229.034711762546 +/- 9.460053082469240E-005 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -857.879329817248 + Vee = 238.541158674957 + Vecp = 0.000000000000000E+000 + T = 229.242721793323 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0486 -229.03351830 + -0.0495 -229.03118018 + -0.0499 -229.03247817 + -0.0502 -229.03425999 + -0.0506 -229.03646263 + -0.0518 -229.03719904 + -0.0541 -229.03685176 + =========== =================== + +* Number of unique beta determinants 2859956 +* Number of unique alpha determinants 2873636 + +.. >>>>> [ RES MEM : 28.815216 GB ] [ VIRT MEM : 39.824444 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 355426.519618 s ] [ CPU TIME: ************** s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 83071776 +* Number of threads for diagonalization 72 +* Memory(Gb) 117.1178196258843 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9872195705 0.006800 0.898E-02 + 2 -229.0225996845 0.002089 0.585E-02 + 3 -229.0266055045 0.001815 0.392E-03 + 4 -229.0273347297 0.001582 0.672E-04 + 5 -229.0274930379 0.001467 0.174E-04 + 6 -229.0275370979 0.001381 0.389E-05 + 7 -229.0275474639 0.001349 0.858E-06 + 8 -229.0275497856 0.001340 0.167E-06 + 9 -229.0275502380 0.001338 0.384E-07 + 10 -229.0275503332 0.001337 0.771E-08 + 11 -229.0275503541 0.001336 0.161E-08 + 12 -229.0275503588 0.001336 0.358E-09 + 13 -229.0275503599 0.001336 0.797E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 120.422520 GB ] [ VIRT MEM : 135.141354 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 538045.128662 s ] [ CPU TIME: ************** s ] <<<<< .. + + +.. >>>>> [ RES MEM : 28.201485 GB ] [ VIRT MEM : 39.205299 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 538054.058525 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Energy of state 1 -229.0275503598790 +* S^2 of state 1 0.1336160349909896E-02 +* Saved determinants 83071776 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 27.029648 GB ] [ VIRT MEM : 34.862125 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 538730.744200 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 78776658 + +.. >>>>> [ RES MEM : 27.029648 GB ] [ VIRT MEM : 34.862125 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 538730.920457 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 78776658 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -229.0275503598790 + +.. >>>>> [ RES MEM : 36.316711 GB ] [ VIRT MEM : 44.140942 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 538795.675209 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 78776658 + +.. >>>>> [ RES MEM : 36.316711 GB ] [ VIRT MEM : 44.140942 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 538795.844962 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 78776658 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 79136516 +* Number of fragmented tasks 6361 +* Number of threads for PT2 72 +* Memory (Gb) 8.427033035680651 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.0377298448 0.549E-04 0.0635509917 0.0016882608 ********** + 4 -229.0386004822 0.955E-03 0.0684481909 0.0018487574 ********** + 5 -229.0387425396 0.737E-03 0.0686517499 0.0018874085 ********** + 6 -229.0389622024 0.637E-03 0.0701351506 0.0019200280 ********** + 7 -229.0388575308 0.545E-03 0.0696556974 0.0018970537 ********** + 8 -229.0383232102 0.726E-03 0.0665521519 0.0018035806 ********** + 9 -229.0380411372 0.701E-03 0.0647645462 0.0017565321 ********** + 10 -229.0378210584 0.665E-03 0.0632004721 0.0017241021 ********** + 11 -229.0381914921 0.710E-03 0.0653806396 0.0017899293 ********** + 12 -229.0387548235 0.866E-03 0.0683707038 0.0018977701 ********** + 13 -229.0389001107 0.809E-03 0.0692271461 0.0019217226 ********** + 14 -229.0390319379 0.760E-03 0.0699148893 0.0019452824 ********** + 15 -229.0390680351 0.707E-03 0.0700637472 0.0019541331 ********** + 16 -229.0388630700 0.693E-03 0.0686384592 0.0019240193 ********** + 17 -229.0389599910 0.658E-03 0.0690562732 0.0019452319 ********** + 18 -229.0388692842 0.626E-03 0.0686735800 0.0019259692 ********** + 19 -229.0390259525 0.613E-03 0.0695049675 0.0019550513 ********** + 20 -229.0390301244 0.581E-03 0.0696597102 0.0019529857 ********** + 21 -229.0393247224 0.627E-03 0.0712808199 0.0020086551 ********** + 22 -229.0393501351 0.598E-03 0.0714251832 0.0020124754 ********** + 23 -229.0392986452 0.574E-03 0.0712359599 0.0020004359 ********** + 24 -229.0392305322 0.553E-03 0.0709264978 0.0019862775 ********** + 25 -229.0393353384 0.541E-03 0.0715898051 0.0020030966 ********** + 26 -229.0393431388 0.520E-03 0.0717137100 0.0020024547 ********** + 27 -229.0392105197 0.518E-03 0.0708720376 0.0019806535 ********** + 28 -229.0391761195 0.500E-03 0.0705825742 0.0019767604 ********** + 29 -229.0391260209 0.485E-03 0.0703067267 0.0019671879 ********** diff --git a/furan/6-31g/furan.scf.out b/furan/6-31g/furan.scf.out new file mode 100644 index 0000000..e308d00 --- /dev/null +++ b/furan/6-31g/furan.scf.out @@ -0,0 +1,301 @@ +Date: 14/12/2020 22:04:07 +=============== +Quantum Package +=============== + +Git Commit: Fix space in size for EZFIO.cfg +Git Date : Fri Oct 16 14:24:01 2020 +0200 +Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b +EZFIO Dir : furan + + +Task server running : tcp://172.28.1.83:41279 +.. >>>>> [ IO READ: mo_guess_type ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017384 GB ] [ VIRT MEM : 0.201355 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.001304 s ] [ CPU TIME: 0.055537 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017384 GB ] [ VIRT MEM : 0.201355 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.024483 s ] [ CPU TIME: 0.056603 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_one_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017384 GB ] [ VIRT MEM : 0.201355 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.044944 s ] [ CPU TIME: 0.057361 s ] <<<<< .. + +.. >>>>> [ IO READ: do_pseudo ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017601 GB ] [ VIRT MEM : 0.201355 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.056080 s ] [ CPU TIME: 0.058520 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_integrals_kinetic ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017601 GB ] [ VIRT MEM : 0.201355 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.056680 s ] [ CPU TIME: 0.058960 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_prim_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019226 GB ] [ VIRT MEM : 4.924583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.103844 s ] [ CPU TIME: 1.249360 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_expo ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019489 GB ] [ VIRT MEM : 4.924583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.108645 s ] [ CPU TIME: 1.477626 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_coef ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019508 GB ] [ VIRT MEM : 4.924583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.112019 s ] [ CPU TIME: 1.657752 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_power ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019508 GB ] [ VIRT MEM : 4.924583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.115234 s ] [ CPU TIME: 1.840518 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_nucl ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019661 GB ] [ VIRT MEM : 4.924583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.121934 s ] [ CPU TIME: 2.246595 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019661 GB ] [ VIRT MEM : 4.924583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.150313 s ] [ CPU TIME: 3.974462 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_label ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019688 GB ] [ VIRT MEM : 4.924583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.153797 s ] [ CPU TIME: 4.187051 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_charge ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019695 GB ] [ VIRT MEM : 4.924583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.156818 s ] [ CPU TIME: 4.371973 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.019695 GB ] [ VIRT MEM : 4.924583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.159493 s ] [ CPU TIME: 4.535300 s ] <<<<< .. + + +Nuclear Coordinates (Angstroms) +=============================== + +================ ============ ============ ============ ============ + Atom Charge X Y Z +================ ============ ============ ============ ============ +C 6.000000 0.000000 1.092041 -0.317778 +C 6.000000 0.000000 -1.092041 -0.317778 +C 6.000000 0.000000 0.716234 0.986050 +C 6.000000 0.000000 -0.716234 0.986050 +O 8.000000 0.000000 0.000000 -1.132150 +H 1.000000 0.000000 2.044409 -0.813693 +H 1.000000 0.000000 -2.044409 -0.813693 +H 1.000000 0.000000 1.371462 1.837134 +H 1.000000 0.000000 -1.371462 1.837134 +================ ============ ============ ============ ============ + +.. >>>>> [ IO READ: io_ao_integrals_e_n ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019695 GB ] [ VIRT MEM : 4.924583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.163622 s ] [ CPU TIME: 4.790578 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_cartesian ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019695 GB ] [ VIRT MEM : 4.924583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.167650 s ] [ CPU TIME: 5.039738 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_integrals_overlap ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019695 GB ] [ VIRT MEM : 4.924583 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.168973 s ] [ CPU TIME: 5.121973 s ] <<<<< .. + +* mo_num 53 +.. >>>>> [ IO READ: elec_beta_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.022316 GB ] [ VIRT MEM : 4.998783 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.229107 s ] [ CPU TIME: 8.846656 s ] <<<<< .. + +.. >>>>> [ IO READ: level_shift ] <<<<< .. + +.. >>>>> [ RES MEM : 0.022316 GB ] [ VIRT MEM : 4.998783 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.229900 s ] [ CPU TIME: 8.896320 s ] <<<<< .. + +.. >>>>> [ IO READ: elec_alpha_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.022316 GB ] [ VIRT MEM : 4.998783 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.230659 s ] [ CPU TIME: 8.944000 s ] <<<<< .. + +.. >>>>> [ IO READ: do_direct_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.022316 GB ] [ VIRT MEM : 4.998783 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.272202 s ] [ CPU TIME: 11.514049 s ] <<<<< .. + + AO map initialized : 1024596 +.. >>>>> [ IO READ: io_ao_two_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.022545 GB ] [ VIRT MEM : 4.998783 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.273550 s ] [ CPU TIME: 11.599737 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_integrals_threshold ] <<<<< .. + +.. >>>>> [ RES MEM : 0.022545 GB ] [ VIRT MEM : 4.998783 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.274479 s ] [ CPU TIME: 11.659023 s ] <<<<< .. + + Providing the AO integrals + Sorting the map + AO integrals provided: + Size of AO map : 7.19726371765137 MB + Number of AO integrals : 580388 + cpu time : 36.4497720000000 s + wall time : 0.622107982635498 s ( x 58.5907479366913 ) +.. >>>>> [ IO READ: frozen_orb_scf ] <<<<< .. + +.. >>>>> [ RES MEM : 0.049015 GB ] [ VIRT MEM : 5.228554 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.905218 s ] [ CPU TIME: 48.706437 s ] <<<<< .. + + Read mo_occ +.. >>>>> [ IO READ: ao_md5 ] <<<<< .. + +.. >>>>> [ RES MEM : 0.049877 GB ] [ VIRT MEM : 5.228554 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.908158 s ] [ CPU TIME: 48.910780 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.049877 GB ] [ VIRT MEM : 5.228554 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.908662 s ] [ CPU TIME: 48.946091 s ] <<<<< .. + + * mo_label no_label +.. >>>>> [ IO READ: io_nuclear_repulsion ] <<<<< .. + +.. >>>>> [ RES MEM : 0.054768 GB ] [ VIRT MEM : 5.228554 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1.008597 s ] [ CPU TIME: 55.806986 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.054768 GB ] [ VIRT MEM : 5.228554 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1.008965 s ] [ CPU TIME: 55.833452 s ] <<<<< .. + +* Nuclear repulsion energy 161.1082297787890 +.. >>>>> [ IO READ: max_dim_diis ] <<<<< .. + +.. >>>>> [ RES MEM : 0.056576 GB ] [ VIRT MEM : 5.228554 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1.015773 s ] [ CPU TIME: 56.314360 s ] <<<<< .. + +.. >>>>> [ IO READ: scf_algorithm ] <<<<< .. + +.. >>>>> [ RES MEM : 0.056652 GB ] [ VIRT MEM : 5.228554 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1.017420 s ] [ CPU TIME: 56.429064 s ] <<<<< .. + +.. >>>>> [ IO READ: n_it_scf_max ] <<<<< .. + +.. >>>>> [ RES MEM : 0.056660 GB ] [ VIRT MEM : 5.228554 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1.018557 s ] [ CPU TIME: 56.508248 s ] <<<<< .. + +.. >>>>> [ IO READ: thresh_scf ] <<<<< .. + +.. >>>>> [ RES MEM : 0.056660 GB ] [ VIRT MEM : 5.228554 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1.019335 s ] [ CPU TIME: 56.562305 s ] <<<<< .. + +.. >>>>> [ IO READ: threshold_diis ] <<<<< .. + +.. >>>>> [ RES MEM : 0.056660 GB ] [ VIRT MEM : 5.228554 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1.020112 s ] [ CPU TIME: 56.616270 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.056660 GB ] [ VIRT MEM : 5.228554 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1.020492 s ] [ CPU TIME: 56.642889 s ] <<<<< .. + + Energy of the guess = -225.314064717958 +==== ================ ================ ================ ================ + N Energy Energy diff DIIS error Level shift +==== ================ ================ ================ ================ + 1 -228.1568280834 -2.8427633655 0.4529808269 0.0000000000 1 + 2 -228.3643911882 -0.2075631047 0.3111160119 0.0000000000 2 + 3 -228.5218348856 -0.1574436974 0.0182945768 0.0000000000 3 + 4 -228.5235940656 -0.0017591800 0.0102608499 0.0000000000 4 + 5 -228.5239150670 -0.0003210014 0.0041641041 0.0000000000 5 + 6 -228.5239734692 -0.0000584023 0.0016344829 0.0000000000 6 + 7 -228.5239896493 -0.0000161801 0.0002990064 0.0000000000 7 + 8 -228.5239900394 -0.0000003901 0.0000988344 0.0000000000 8 + 9 -228.5239900734 -0.0000000340 0.0000116298 0.0000000000 9 + 10 -228.5239900739 -0.0000000005 0.0000014199 0.0000000000 10 + 11 -228.5239900739 -0.0000000000 0.0000005869 0.0000000000 0 +==== ================ ================ ================ ================ + + +.. >>>>> [ RES MEM : 0.057819 GB ] [ VIRT MEM : 5.228554 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.107498 s ] [ CPU TIME: 130.413025 s ] <<<<< .. + +MOs are now **Canonical** + +Eigenvalues +----------- + +======== ================ + 1 -20.6298079250 + 2 -11.2960534035 + 3 -11.2959928267 + 4 -11.2403892106 + 5 -11.2394535050 + 6 -1.4741833534 + 7 -1.0937823616 + 8 -1.0137889464 + 9 -0.8083306954 + 10 -0.7807452159 + 11 -0.7419895575 + 12 -0.6319869655 + 13 -0.6049820574 + 14 -0.5822293957 + 15 -0.5656604532 + 16 -0.5358059070 + 17 -0.3986702235 + 18 -0.3249501799 + 19 0.1602437934 + 20 0.2392537603 + 21 0.2611934429 + 22 0.2929816144 + 23 0.2989141653 + 24 0.3082660821 + 25 0.3573564515 + 26 0.3780394506 + 27 0.4765802774 + 28 0.5533401975 + 29 0.6528923391 + 30 0.7348116857 + 31 0.7560647499 + 32 0.8149328681 + 33 0.8313542395 + 34 0.8497155953 + 35 0.8554330224 + 36 0.8837814081 + 37 0.9021064106 + 38 0.9205493774 + 39 0.9379647470 + 40 1.0854490796 + 41 1.1285468600 + 42 1.1302384788 + 43 1.1813549344 + 44 1.2221790617 + 45 1.2635195573 + 46 1.2838090680 + 47 1.3407566205 + 48 1.3923541095 + 49 1.4037673830 + 50 1.4585771482 + 51 1.6991361295 + 52 1.9002842179 + 53 2.1731585545 +======== ================ + + +.. >>>>> [ RES MEM : 0.057961 GB ] [ VIRT MEM : 5.367275 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.111577 s ] [ CPU TIME: 130.681971 s ] <<<<< .. + +* SCF energy -228.5239900739170 + +.. >>>>> [ RES MEM : 0.058083 GB ] [ VIRT MEM : 5.367275 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 2.192156 s ] [ CPU TIME: 136.166670 s ] <<<<< .. + +Wall time: 0:00:06 + diff --git a/furan/6-31g/slurm-514499.out b/furan/6-31g/slurm-514499.out new file mode 100644 index 0000000..ba6c68b --- /dev/null +++ b/furan/6-31g/slurm-514499.out @@ -0,0 +1,76857 @@ ++ INPUT=furan ++ source /users/p18005/loos/tmpdir/qp2/quantum_package.rc +++ QP_ROOT=/NOT/FOUND +++ case "$(ps -p $$ -ocomm=)" in ++++ ps -p 33320 -ocomm= ++++ dirname '/users/p18005/loos/tmpdir/qp2/quantum_package.rc[0]' +++ QP_ROOT=/users/p18005/loos/tmpdir/qp2 ++++ cd /users/p18005/loos/tmpdir/qp2 ++++ pwd -P +++ export QP_ROOT=/tmpdir/loos/qp2 +++ QP_ROOT=/tmpdir/loos/qp2 +++ WD=/users/p18005/loos/tmpdir/Ec/furan/6-31g +++ cd /tmpdir/loos/qp2/etc +++ for SCRIPT in '*.rc' +++ source 00.qp_root.rc ++++ export QP_ROOT=/tmpdir/loos/qp2 ++++ QP_ROOT=/tmpdir/loos/qp2 +++ for SCRIPT in '*.rc' +++ source autocomplete.rc +++++ ps -p 33320 -ocomm= ++++ [[ slurm_script == \z\s\h ]] +++ for SCRIPT in '*.rc' +++ source configure.rc ++++ source /tmpdir/loos/qp2/etc/autocomplete.rc ++++++ ps -p 33320 -ocomm= +++++ [[ slurm_script == \z\s\h ]] ++++ complete -F _configure_Complete configure +++ for SCRIPT in '*.rc' +++ source ezfio.rc ++++ export QP_EZFIO=/tmpdir/loos/qp2/external/ezfio ++++ QP_EZFIO=/tmpdir/loos/qp2/external/ezfio ++++ source /tmpdir/loos/qp2/etc/autocomplete.rc ++++++ ps -p 33320 -ocomm= +++++ [[ slurm_script == \z\s\h ]] ++++ source_if_exists /tmpdir/loos/qp2/external/ezfio/Bash/ezfio.sh +++ for SCRIPT in '*.rc' +++ source irpf90.rc ++++ export IRPF90_PATH=/tmpdir/loos/qp2/external/irpf90-v1.7.6 ++++ IRPF90_PATH=/tmpdir/loos/qp2/external/irpf90-v1.7.6 ++++ export PATH=/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ++++ PATH=/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ++++ export IRPF90=/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin/irpf90 ++++ IRPF90=/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin/irpf90 ++++ source /tmpdir/loos/qp2/etc/autocomplete.rc ++++++ ps -p 33320 -ocomm= +++++ [[ slurm_script == \z\s\h ]] ++++ source_if_exists /tmpdir/loos/qp2/external/irpf90-v1.7.6/irpman-completions.bash +++ for SCRIPT in '*.rc' +++ source libraries.rc ++++ QP_LIB= +++ for SCRIPT in '*.rc' +++ source local.rc +++ for SCRIPT in '*.rc' +++ source ninja.rc ++++ export NINJA=/tmpdir/loos/qp2/bin/ninja ++++ NINJA=/tmpdir/loos/qp2/bin/ninja +++ for SCRIPT in '*.rc' +++ source ocaml.rc ++++ [[ -z /tmpdir/loos/qp2/external/opam ]] ++++ source /tmpdir/loos/qp2/external/opam/opam-init/init.sh +++ for SCRIPT in '*.rc' +++ source paths.rc ++++ QP_PYTHON= ++++ for i in ezfio.rc irpf90.rc ninja.rc ocaml.rc ++++ source ezfio.rc +++++ export QP_EZFIO=/tmpdir/loos/qp2/external/ezfio +++++ QP_EZFIO=/tmpdir/loos/qp2/external/ezfio +++++ source /tmpdir/loos/qp2/etc/autocomplete.rc +++++++ ps -p 33320 -ocomm= ++++++ [[ slurm_script == \z\s\h ]] +++++ source_if_exists /tmpdir/loos/qp2/external/ezfio/Bash/ezfio.sh ++++ for i in ezfio.rc irpf90.rc ninja.rc ocaml.rc ++++ source irpf90.rc +++++ export IRPF90_PATH=/tmpdir/loos/qp2/external/irpf90-v1.7.6 +++++ IRPF90_PATH=/tmpdir/loos/qp2/external/irpf90-v1.7.6 +++++ export PATH=/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin +++++ PATH=/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin +++++ export IRPF90=/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin/irpf90 +++++ IRPF90=/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin/irpf90 +++++ source /tmpdir/loos/qp2/etc/autocomplete.rc +++++++ ps -p 33320 -ocomm= ++++++ [[ slurm_script == \z\s\h ]] +++++ source_if_exists /tmpdir/loos/qp2/external/irpf90-v1.7.6/irpman-completions.bash ++++ for i in ezfio.rc irpf90.rc ninja.rc ocaml.rc ++++ source ninja.rc +++++ export NINJA=/tmpdir/loos/qp2/bin/ninja +++++ NINJA=/tmpdir/loos/qp2/bin/ninja ++++ for i in ezfio.rc irpf90.rc ninja.rc ocaml.rc ++++ source ocaml.rc +++++ [[ -z /tmpdir/loos/qp2/external/opam ]] +++++ source /tmpdir/loos/qp2/external/opam/opam-init/init.sh ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile +++++ qp_prepend_export PYTHONPATH /tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile +++++ eval 'value_1=${PYTHONPATH}' ++++++ value_1=/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: +++++ [[ -z /tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: ]] +++++ echo /tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: ++++ export PYTHONPATH=/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: ++++ PYTHONPATH=/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: +++++ qp_prepend_export PATH :/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml +++++ eval 'value_1=${PATH}' ++++++ value_1=/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin +++++ [[ -z /tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ]] +++++ echo :/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ++++ export PATH=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ++++ PATH=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin +++++ qp_prepend_export LD_LIBRARY_PATH /tmpdir/loos/qp2/lib +++++ eval 'value_1=${LD_LIBRARY_PATH}' ++++++ value_1=/tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib +++++ [[ -z /tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib ]] +++++ echo /tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib ++++ export LD_LIBRARY_PATH=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib ++++ LD_LIBRARY_PATH=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib +++++ qp_prepend_export LIBRARY_PATH /tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64 +++++ eval 'value_1=${LIBRARY_PATH}' ++++++ value_1=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 +++++ [[ -z /tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 ]] +++++ echo /tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 ++++ export LIBRARY_PATH=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 ++++ LIBRARY_PATH=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 +++++ qp_prepend_export C_INCLUDE_PATH /tmpdir/loos/qp2/include +++++ eval 'value_1=${C_INCLUDE_PATH}' ++++++ value_1=/tmpdir/loos/qp2/include: +++++ [[ -z /tmpdir/loos/qp2/include: ]] +++++ echo /tmpdir/loos/qp2/include:/tmpdir/loos/qp2/include: ++++ export C_INCLUDE_PATH=/tmpdir/loos/qp2/include:/tmpdir/loos/qp2/include: ++++ C_INCLUDE_PATH=/tmpdir/loos/qp2/include:/tmpdir/loos/qp2/include: +++ for SCRIPT in '*.rc' +++ source qp.rc +++++ ps -p 33320 -ocomm= ++++ [[ slurm_script == \z\s\h ]] ++++ source /tmpdir/loos/qp2/etc/ezfio.rc +++++ export QP_EZFIO=/tmpdir/loos/qp2/external/ezfio +++++ QP_EZFIO=/tmpdir/loos/qp2/external/ezfio +++++ source /tmpdir/loos/qp2/etc/autocomplete.rc +++++++ ps -p 33320 -ocomm= ++++++ [[ slurm_script == \z\s\h ]] +++++ source_if_exists /tmpdir/loos/qp2/external/ezfio/Bash/ezfio.sh ++++ complete -F _qp_Complete qp +++ cd /users/p18005/loos/tmpdir/Ec/furan/6-31g +++ [[ -z /tmpdir/loos/qp2 ]] ++ set -e ++ qp set_file furan ++ case $1 in ++ [[ -d furan ]] ++ ezfio set_file furan ++ case $1 in ++ shift ++ _ezfio_set_file furan ++ _require_first_argument furan ++ [[ -z furan ]] ++ return 0 ++ [[ ! -d furan ]] ++ export EZFIO_FILE=furan ++ EZFIO_FILE=furan ++ _ezfio_info 'Set file furan' ++ : ++ return 0 ++ qp set determinants n_states 1 ++ case $1 in ++ ezfio set determinants n_states 1 ++ case $1 in ++ shift ++ _ezfio_set determinants n_states 1 ++ _require_ezfio_file ++ [[ -z furan ]] ++ [[ ! -d furan ]] ++ _require_first_argument determinants n_states 1 ++ [[ -z determinants ]] ++ return 0 ++ _require_second_argument determinants n_states 1 ++ [[ -z n_states ]] ++ [[ -z 1 ]] ++ _ezfio_py set determinants n_states ++ echo 1 ++ python2 /tmpdir/loos/qp2/external/ezfio/Python/ezfio.py set determinants n_states ++ return 0 ++ qp set determinants read_wf True ++ case $1 in ++ ezfio set determinants read_wf True ++ case $1 in ++ shift ++ _ezfio_set determinants read_wf True ++ _require_ezfio_file ++ [[ -z furan ]] ++ [[ ! -d furan ]] ++ _require_first_argument determinants read_wf True ++ [[ -z determinants ]] ++ return 0 ++ _require_second_argument determinants read_wf True ++ [[ -z read_wf ]] ++ [[ -z True ]] ++ echo True ++ _ezfio_py set determinants read_wf ++ python2 /tmpdir/loos/qp2/external/ezfio/Python/ezfio.py set determinants read_wf ++ return 0 ++ qp set determinants s2_eig False ++ case $1 in ++ ezfio set determinants s2_eig False ++ case $1 in ++ shift ++ _ezfio_set determinants s2_eig False ++ _require_ezfio_file ++ [[ -z furan ]] ++ [[ ! -d furan ]] ++ _require_first_argument determinants s2_eig False ++ [[ -z determinants ]] ++ return 0 ++ _require_second_argument determinants s2_eig False ++ [[ -z s2_eig ]] ++ [[ -z False ]] ++ echo False ++ _ezfio_py set determinants s2_eig ++ python2 /tmpdir/loos/qp2/external/ezfio/Python/ezfio.py set determinants s2_eig ++ return 0 ++ qp set determinants n_det_max 1e7 ++ case $1 in ++ ezfio set determinants n_det_max 1e7 ++ case $1 in ++ shift ++ _ezfio_set determinants n_det_max 1e7 ++ _require_ezfio_file ++ [[ -z furan ]] ++ [[ ! -d furan ]] ++ _require_first_argument determinants n_det_max 1e7 ++ [[ -z determinants ]] ++ return 0 ++ _require_second_argument determinants n_det_max 1e7 ++ [[ -z n_det_max ]] ++ [[ -z 1e7 ]] ++ _ezfio_py set determinants n_det_max ++ echo 1e7 ++ python2 /tmpdir/loos/qp2/external/ezfio/Python/ezfio.py set determinants n_det_max ++ return 0 ++ qp run scf ++ case $1 in ++ which qp_run ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' furan +++ qp_run scf furan + 0.07 % in 0 seconds + + unset COMMAND ++ qp set_frozen_core ++ case $1 in ++ which qp_set_frozen_core ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' furan +++ qp_set_frozen_core furan ++ unset COMMAND ++ qp run fci ++ case $1 in ++ which qp_run ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' furan +++ qp_run fci furan + 0.07 % in 1 seconds + 50.00 % in 0 seconds + 16.67 % in 0 seconds + 9.09 % in 0 seconds + 4.76 % in 0 seconds + 2.44 % in 0 seconds + 1.23 % in 0 seconds + 0.62 % in 0 seconds + 0.31 % in 0 seconds + 0.16 % in 0 seconds + 0.08 % in 0 seconds + 0.04 % in 1 seconds + 0.02 % in 0 seconds + 0.01 % in 0 seconds + 0.00 % in 0 seconds + 0.00 % in 0 seconds + 8.85 % in 10 seconds +18.87 % in 20 seconds + 0.00 % in 1 seconds + 3.57 % in 11 seconds + 8.24 % in 21 seconds +12.75 % in 31 seconds +17.16 % in 41 seconds + 16.67 % in 0 seconds + 16.67 % in 0 seconds + 16.67 % in 0 seconds + 16.67 % in 0 seconds + 16.67 % in 0 seconds + 16.67 % in 0 seconds + 16.67 % in 0 seconds + 16.67 % in 1 seconds + 16.67 % in 0 seconds + 16.67 % in 0 seconds + 16.67 % in 0 seconds + 0.00 % in 1 seconds + 2.11 % in 11 seconds + 4.65 % in 21 seconds + 7.06 % in 31 seconds + 9.51 % in 41 seconds +11.71 % in 51 seconds +13.81 % in 61 seconds + 10.00 % in 0 seconds + 10.00 % in 1 seconds + 10.00 % in 0 seconds + 10.00 % in 0 seconds + 10.00 % in 1 seconds + 10.00 % in 0 seconds + 10.00 % in 0 seconds + 10.00 % in 0 seconds + 10.00 % in 1 seconds + 10.00 % in 0 seconds + 10.00 % in 0 seconds + 0.00 % in 2 seconds + 0.94 % in 12 seconds + 2.39 % in 22 seconds + 3.71 % in 32 seconds + 5.06 % in 42 seconds + 6.33 % in 52 seconds + 7.57 % in 62 seconds + 8.65 % in 72 seconds + 9.75 % in 82 seconds +10.69 % in 92 seconds +11.62 % in 102 seconds +12.57 % in 112 seconds + 5.56 % in 1 seconds + 5.56 % in 0 seconds + 5.56 % in 0 seconds + 5.56 % in 0 seconds + 5.56 % in 0 seconds + 5.56 % in 1 seconds + 5.56 % in 1 seconds + 5.56 % in 1 seconds + 5.56 % in 0 seconds + 5.56 % in 1 seconds + 0.00 % in 3 seconds + 0.36 % in 13 seconds + 0.98 % in 23 seconds + 1.65 % in 33 seconds + 2.46 % in 43 seconds + 3.09 % in 53 seconds + 3.78 % in 63 seconds + 4.49 % in 73 seconds + 5.13 % in 83 seconds + 5.81 % in 93 seconds + 6.49 % in 103 seconds + 7.02 % in 113 seconds + 7.59 % in 123 seconds + 8.12 % in 133 seconds + 8.67 % in 143 seconds + 9.13 % in 153 seconds + 9.54 % in 163 seconds +10.01 % in 173 seconds +10.51 % in 183 seconds +10.92 % in 193 seconds +11.38 % in 203 seconds +11.65 % in 213 seconds + 2.94 % in 2 seconds + 2.94 % in 1 seconds + 2.94 % in 2 seconds + 2.94 % in 1 seconds + 2.94 % in 1 seconds + 2.94 % in 1 seconds + 2.94 % in 1 seconds + 2.94 % in 1 seconds + 2.94 % in 1 seconds + 0.00 % in 5 seconds + 0.12 % in 15 seconds + 0.34 % in 25 seconds + 0.61 % in 35 seconds + 0.81 % in 45 seconds + 1.13 % in 55 seconds + 1.50 % in 65 seconds + 1.84 % in 75 seconds + 2.10 % in 85 seconds + 2.46 % in 95 seconds + 2.69 % in 105 seconds + 3.01 % in 115 seconds + 3.34 % in 125 seconds + 3.63 % in 135 seconds + 3.82 % in 145 seconds + 4.18 % in 155 seconds + 4.46 % in 165 seconds + 4.75 % in 175 seconds + 5.00 % in 185 seconds + 5.21 % in 195 seconds + 5.62 % in 205 seconds + 5.80 % in 215 seconds + 6.04 % in 225 seconds + 6.24 % in 235 seconds + 6.58 % in 245 seconds + 6.82 % in 255 seconds + 6.98 % in 265 seconds + 7.17 % in 275 seconds + 7.45 % in 285 seconds + 7.65 % in 295 seconds + 7.81 % in 306 seconds + 8.02 % in 317 seconds + 8.22 % in 327 seconds + 8.37 % in 337 seconds + 8.55 % in 347 seconds + 8.73 % in 357 seconds + 8.92 % in 367 seconds + 9.07 % in 377 seconds + 9.25 % in 387 seconds + 9.43 % in 397 seconds + 9.63 % in 407 seconds + 9.79 % in 417 seconds + 9.89 % in 428 seconds + 1.49 % in 3 seconds +56.72 % in 13 seconds + 1.49 % in 2 seconds +55.22 % in 12 seconds + 1.49 % in 2 seconds +56.72 % in 12 seconds + 1.49 % in 2 seconds +56.72 % in 12 seconds + 1.49 % in 3 seconds +59.70 % in 13 seconds + 1.49 % in 2 seconds +58.21 % in 12 seconds + 1.49 % in 2 seconds +55.22 % in 12 seconds + 1.49 % in 2 seconds +58.21 % in 12 seconds + 1.49 % in 2 seconds +59.70 % in 12 seconds + 0.00 % in 9 seconds + 0.04 % in 19 seconds + 0.09 % in 29 seconds + 0.17 % in 39 seconds + 0.31 % in 55 seconds + 0.49 % in 65 seconds + 0.57 % in 75 seconds + 0.59 % in 85 seconds + 0.70 % in 95 seconds + 0.92 % in 105 seconds + 1.01 % in 116 seconds + 1.05 % in 126 seconds + 1.24 % in 136 seconds + 1.37 % in 146 seconds + 1.42 % in 157 seconds + 1.56 % in 167 seconds + 1.77 % in 178 seconds + 1.83 % in 188 seconds + 1.93 % in 198 seconds + 2.13 % in 208 seconds + 2.23 % in 218 seconds + 2.28 % in 228 seconds + 2.45 % in 238 seconds + 2.56 % in 248 seconds + 2.63 % in 260 seconds + 2.72 % in 270 seconds + 2.87 % in 280 seconds + 2.97 % in 290 seconds + 3.08 % in 300 seconds + 3.24 % in 310 seconds + 3.34 % in 321 seconds + 3.44 % in 331 seconds + 3.54 % in 341 seconds + 3.66 % in 351 seconds + 3.75 % in 361 seconds + 3.87 % in 371 seconds + 3.97 % in 381 seconds + 4.08 % in 391 seconds + 4.19 % in 401 seconds + 4.34 % in 411 seconds + 4.44 % in 421 seconds + 4.55 % in 432 seconds + 4.67 % in 442 seconds + 4.75 % in 452 seconds + 4.81 % in 462 seconds + 4.93 % in 472 seconds + 5.01 % in 482 seconds + 5.10 % in 492 seconds + 5.23 % in 502 seconds + 5.33 % in 512 seconds + 5.43 % in 522 seconds + 5.51 % in 532 seconds + 5.61 % in 542 seconds + 5.73 % in 552 seconds + 5.80 % in 563 seconds + 5.86 % in 573 seconds + 5.94 % in 583 seconds + 6.05 % in 593 seconds + 6.13 % in 605 seconds + 6.25 % in 615 seconds + 6.36 % in 626 seconds + 6.42 % in 636 seconds + 6.50 % in 646 seconds + 6.58 % in 656 seconds + 6.66 % in 666 seconds + 6.74 % in 676 seconds + 6.79 % in 686 seconds + 6.85 % in 696 seconds + 6.97 % in 706 seconds + 7.05 % in 717 seconds + 7.11 % in 728 seconds + 7.20 % in 738 seconds + 7.24 % in 748 seconds + 7.32 % in 758 seconds + 7.39 % in 768 seconds + 7.44 % in 778 seconds + 7.48 % in 788 seconds + 7.56 % in 798 seconds + 7.62 % in 808 seconds + 7.69 % in 818 seconds + 7.74 % in 828 seconds + 7.83 % in 838 seconds + 7.88 % in 848 seconds + 7.93 % in 859 seconds + 7.99 % in 869 seconds + 8.06 % in 879 seconds + 8.10 % in 889 seconds + 8.17 % in 900 seconds + 8.23 % in 910 seconds + 8.29 % in 920 seconds + 8.35 % in 930 seconds + 8.40 % in 940 seconds + 8.45 % in 950 seconds + 8.51 % in 960 seconds + 8.54 % in 974 seconds + 8.67 % in 984 seconds + 8.71 % in 994 seconds + 8.74 % in 1004 seconds + 0.75 % in 5 seconds + 6.77 % in 15 seconds +25.56 % in 25 seconds +48.87 % in 35 seconds +72.93 % in 45 seconds +97.74 % in 55 seconds + 0.75 % in 5 seconds + 8.27 % in 15 seconds +27.82 % in 25 seconds +50.38 % in 35 seconds +74.44 % in 45 seconds + 0.75 % in 5 seconds + 6.77 % in 15 seconds +25.56 % in 25 seconds +48.87 % in 35 seconds +72.93 % in 45 seconds +97.74 % in 55 seconds + 0.75 % in 5 seconds + 7.52 % in 15 seconds +26.32 % in 25 seconds +48.87 % in 35 seconds +72.93 % in 45 seconds +97.74 % in 55 seconds + 0.75 % in 5 seconds + 6.77 % in 15 seconds +26.32 % in 25 seconds +48.87 % in 35 seconds +72.93 % in 45 seconds +97.74 % in 55 seconds + 0.75 % in 5 seconds + 7.52 % in 15 seconds +26.32 % in 25 seconds +48.87 % in 35 seconds +72.93 % in 45 seconds +97.74 % in 55 seconds + 0.75 % in 5 seconds + 7.52 % in 15 seconds +27.07 % in 25 seconds +48.87 % in 35 seconds +73.68 % in 45 seconds +97.74 % in 55 seconds + 0.75 % in 5 seconds + 6.77 % in 15 seconds +25.56 % in 25 seconds +48.87 % in 35 seconds +72.93 % in 45 seconds +96.99 % in 55 seconds + 0.00 % in 17 seconds + 0.00 % in 27 seconds + 0.03 % in 37 seconds + 0.04 % in 47 seconds + 0.08 % in 59 seconds + 0.11 % in 69 seconds + 0.16 % in 79 seconds + 0.16 % in 89 seconds + 0.23 % in 99 seconds + 0.28 % in 110 seconds + 0.29 % in 120 seconds + 0.35 % in 130 seconds + 0.40 % in 140 seconds + 0.42 % in 150 seconds + 0.44 % in 160 seconds + 0.52 % in 170 seconds + 0.57 % in 180 seconds + 0.59 % in 191 seconds + 0.63 % in 201 seconds + 0.69 % in 211 seconds + 0.73 % in 221 seconds + 0.74 % in 231 seconds + 0.81 % in 241 seconds + 0.87 % in 251 seconds + 0.90 % in 262 seconds + 0.92 % in 272 seconds + 0.98 % in 282 seconds + 1.04 % in 293 seconds + 1.08 % in 303 seconds + 1.13 % in 314 seconds + 1.17 % in 325 seconds + 1.19 % in 335 seconds + 1.27 % in 346 seconds + 1.33 % in 356 seconds + 1.35 % in 366 seconds + 1.39 % in 376 seconds + 1.45 % in 386 seconds + 1.49 % in 396 seconds + 1.54 % in 407 seconds + 1.59 % in 417 seconds + 1.61 % in 427 seconds + 1.65 % in 437 seconds + 1.70 % in 447 seconds + 1.77 % in 457 seconds + 1.79 % in 467 seconds + 1.83 % in 477 seconds + 1.89 % in 487 seconds + 1.94 % in 497 seconds + 1.98 % in 508 seconds + 2.01 % in 518 seconds + 2.05 % in 528 seconds + 2.09 % in 538 seconds + 2.17 % in 548 seconds + 2.21 % in 558 seconds + 2.23 % in 568 seconds + 2.24 % in 579 seconds + 2.28 % in 589 seconds + 2.33 % in 599 seconds + 2.36 % in 609 seconds + 2.42 % in 620 seconds + 2.45 % in 630 seconds + 2.49 % in 640 seconds + 2.53 % in 650 seconds + 2.57 % in 660 seconds + 2.61 % in 670 seconds + 2.66 % in 684 seconds + 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% in 1528 seconds + 5.80 % in 1538 seconds + 5.83 % in 1548 seconds + 5.88 % in 1558 seconds + 5.91 % in 1568 seconds + 5.93 % in 1578 seconds + 5.96 % in 1589 seconds + 5.99 % in 1599 seconds + 6.02 % in 1609 seconds + 6.06 % in 1619 seconds + 6.10 % in 1629 seconds + 6.12 % in 1639 seconds + 6.15 % in 1649 seconds + 6.17 % in 1659 seconds + 6.20 % in 1670 seconds + 6.23 % in 1680 seconds + 6.26 % in 1690 seconds + 6.29 % in 1700 seconds + 6.32 % in 1710 seconds + 6.34 % in 1720 seconds + 6.37 % in 1730 seconds + 6.42 % in 1740 seconds + 6.45 % in 1750 seconds + 6.47 % in 1760 seconds + 6.51 % in 1770 seconds + 6.54 % in 1780 seconds + 6.56 % in 1790 seconds + 6.58 % in 1800 seconds + 6.61 % in 1810 seconds + 6.64 % in 1820 seconds + 6.66 % in 1831 seconds + 6.69 % in 1841 seconds + 6.70 % in 1851 seconds + 6.73 % in 1861 seconds + 6.75 % in 1873 seconds + 6.78 % in 1883 seconds + 6.80 % in 1894 seconds + 6.83 % in 1904 seconds + 6.85 % in 1914 seconds + 6.88 % in 1926 seconds + 6.90 % in 1936 seconds + 6.92 % in 1946 seconds + 6.94 % in 1956 seconds + 6.96 % in 1966 seconds + 6.98 % in 1976 seconds + 7.00 % in 1986 seconds + 7.02 % in 1996 seconds + 7.04 % in 2006 seconds + 7.06 % in 2016 seconds + 7.08 % in 2027 seconds + 7.10 % in 2038 seconds + 7.12 % in 2048 seconds + 7.14 % in 2058 seconds + 7.15 % in 2068 seconds + 7.18 % in 2078 seconds + 7.20 % in 2088 seconds + 7.22 % in 2098 seconds + 7.24 % in 2108 seconds + 7.26 % in 2118 seconds + 7.28 % in 2128 seconds + 7.29 % in 2138 seconds + 7.31 % in 2148 seconds + 7.33 % in 2158 seconds + 7.35 % in 2168 seconds + 7.37 % in 2178 seconds + 7.39 % in 2188 seconds + 7.41 % in 2199 seconds + 7.43 % in 2209 seconds + 7.45 % in 2220 seconds + 7.48 % in 2230 seconds + 7.49 % in 2240 seconds + 7.51 % in 2251 seconds + 7.53 % in 2263 seconds + 7.56 % in 2273 seconds + 7.57 % in 2283 seconds + 7.60 % in 2293 seconds + 7.60 % in 2313 seconds + 7.66 % in 2323 seconds + 7.67 % in 2336 seconds + 0.38 % in 12 seconds + 0.76 % in 29 seconds + 2.65 % in 39 seconds + 6.06 % in 49 seconds +10.23 % in 59 seconds +15.15 % in 69 seconds +20.45 % in 79 seconds +26.52 % in 89 seconds +32.20 % in 99 seconds +38.64 % in 109 seconds +45.83 % in 119 seconds +51.89 % in 129 seconds +58.33 % in 139 seconds +65.53 % in 149 seconds +72.35 % in 159 seconds +79.17 % in 169 seconds +86.36 % in 179 seconds +93.56 % in 189 seconds + 0.38 % in 12 seconds + 0.76 % in 29 seconds + 2.65 % in 40 seconds + 6.06 % in 50 seconds +10.61 % in 61 seconds +15.91 % in 71 seconds +21.97 % in 81 seconds +26.89 % in 91 seconds +33.71 % in 101 seconds +40.53 % in 111 seconds +46.97 % in 121 seconds +53.41 % in 131 seconds +60.23 % in 141 seconds +65.91 % in 151 seconds +73.86 % in 161 seconds +80.30 % in 171 seconds +87.12 % in 181 seconds +94.70 % in 191 seconds + 0.38 % in 12 seconds + 0.76 % in 29 seconds + 2.65 % in 39 seconds + 6.06 % in 49 seconds +10.23 % in 59 seconds +15.53 % in 69 seconds +20.83 % in 79 seconds +26.52 % in 89 seconds +32.58 % in 99 seconds +39.39 % in 109 seconds +46.21 % in 119 seconds +52.65 % in 129 seconds +59.09 % in 139 seconds +65.53 % in 149 seconds +73.11 % in 159 seconds +79.55 % in 169 seconds +86.74 % in 179 seconds +93.94 % in 189 seconds + 0.38 % in 11 seconds + 0.76 % in 28 seconds + 2.65 % in 39 seconds + 6.06 % in 49 seconds +10.23 % in 59 seconds +15.53 % in 69 seconds +20.83 % in 79 seconds +26.52 % in 89 seconds +32.20 % in 99 seconds +39.02 % in 109 seconds +46.21 % in 119 seconds +52.27 % in 129 seconds +58.71 % in 139 seconds +65.53 % in 149 seconds +72.35 % in 159 seconds +79.17 % in 169 seconds +86.36 % in 179 seconds +93.56 % in 189 seconds + 0.38 % in 12 seconds + 0.76 % in 29 seconds + 2.65 % in 39 seconds + 6.06 % in 49 seconds +10.23 % in 59 seconds +15.15 % in 69 seconds +20.45 % in 79 seconds +26.52 % in 89 seconds +32.20 % in 99 seconds +38.64 % in 109 seconds +45.83 % in 119 seconds +51.52 % in 129 seconds +58.33 % in 139 seconds +65.53 % in 150 seconds +73.11 % in 160 seconds +79.55 % in 170 seconds +86.74 % in 180 seconds +93.94 % in 190 seconds + 0.38 % in 11 seconds + 0.76 % in 28 seconds + 2.65 % in 39 seconds + 6.06 % in 49 seconds +10.23 % in 59 seconds +15.53 % in 69 seconds +20.83 % in 79 seconds +26.52 % in 89 seconds +32.20 % in 99 seconds +39.02 % in 109 seconds +46.21 % in 119 seconds +52.27 % in 129 seconds +58.33 % in 139 seconds +65.53 % in 149 seconds +72.73 % in 159 seconds +79.17 % in 169 seconds +86.36 % in 179 seconds +93.56 % in 189 seconds + 0.38 % in 11 seconds + 0.76 % in 28 seconds + 2.65 % in 39 seconds + 6.06 % in 49 seconds +10.61 % in 60 seconds +15.91 % in 70 seconds +21.97 % in 81 seconds +28.03 % in 91 seconds +34.47 % in 101 seconds +40.91 % in 112 seconds +47.35 % in 122 seconds +54.55 % in 132 seconds +61.36 % in 142 seconds +67.80 % in 152 seconds +74.62 % in 162 seconds +81.82 % in 172 seconds +88.64 % in 182 seconds +95.08 % in 192 seconds + 0.38 % in 12 seconds + 0.76 % in 29 seconds + 2.65 % in 39 seconds + 6.06 % in 49 seconds +10.23 % in 59 seconds +15.15 % in 69 seconds +20.83 % in 79 seconds +26.52 % in 89 seconds +32.20 % in 99 seconds +39.02 % in 109 seconds +45.83 % in 119 seconds +51.89 % in 129 seconds +58.33 % in 139 seconds +65.53 % in 149 seconds +72.35 % in 159 seconds +79.17 % in 169 seconds +86.36 % in 179 seconds +93.56 % in 189 seconds + 0.00 % in 29 seconds + 0.00 % in 44 seconds + 0.01 % in 57 seconds + 0.02 % in 67 seconds + 0.03 % in 77 seconds + 0.04 % in 87 seconds + 0.04 % in 97 seconds + 0.06 % in 107 seconds + 0.08 % in 117 seconds + 0.09 % in 131 seconds + 0.12 % in 141 seconds + 0.14 % in 153 seconds + 0.14 % in 163 seconds + 0.17 % in 173 seconds + 0.19 % in 185 seconds + 0.19 % in 195 seconds + 0.22 % in 205 seconds + 0.25 % in 215 seconds + 0.26 % in 228 seconds + 0.27 % in 240 seconds + 0.29 % in 250 seconds + 0.30 % in 263 seconds + 0.32 % in 273 seconds + 0.34 % in 283 seconds + 0.35 % in 293 seconds + 0.37 % in 303 seconds + 0.39 % in 313 seconds + 0.41 % in 323 seconds + 0.43 % in 334 seconds + 0.44 % in 345 seconds + 0.45 % in 355 seconds + 0.46 % in 365 seconds + 0.47 % in 376 seconds + 0.49 % in 386 seconds + 0.51 % in 396 seconds + 0.53 % in 406 seconds + 0.55 % in 416 seconds + 0.56 % in 426 seconds + 0.58 % in 436 seconds + 0.61 % in 447 seconds + 0.62 % in 457 seconds + 0.63 % in 470 seconds + 0.64 % in 480 seconds + 0.66 % in 490 seconds + 0.68 % in 500 seconds + 0.69 % in 511 seconds + 0.72 % in 521 seconds + 0.74 % in 531 seconds + 0.75 % in 541 seconds + 0.77 % in 551 seconds + 0.79 % in 562 seconds + 0.80 % in 572 seconds + 0.81 % in 583 seconds + 0.83 % in 593 seconds + 0.85 % in 604 seconds + 0.87 % in 614 seconds + 0.90 % in 624 seconds + 0.91 % in 635 seconds + 0.93 % in 646 seconds + 0.95 % in 656 seconds + 0.96 % in 669 seconds + 0.97 % in 679 seconds + 0.99 % in 689 seconds + 1.02 % in 699 seconds + 1.03 % in 709 seconds + 1.04 % in 719 seconds + 1.07 % in 729 seconds + 1.09 % in 739 seconds + 1.10 % in 750 seconds + 1.11 % in 760 seconds + 1.13 % in 770 seconds + 1.15 % in 780 seconds + 1.16 % in 790 seconds + 1.18 % in 800 seconds + 1.20 % in 810 seconds + 1.22 % in 821 seconds + 1.23 % in 831 seconds + 1.25 % in 841 seconds + 1.26 % in 851 seconds + 1.28 % in 861 seconds + 1.30 % in 872 seconds + 1.32 % in 883 seconds + 1.33 % in 893 seconds + 1.35 % in 903 seconds + 1.37 % in 913 seconds + 1.39 % in 925 seconds + 1.39 % in 935 seconds + 1.42 % in 945 seconds + 1.43 % in 955 seconds + 1.44 % in 965 seconds + 1.46 % in 975 seconds + 1.49 % in 985 seconds + 1.50 % in 995 seconds + 1.52 % in 1005 seconds + 1.53 % in 1015 seconds + 1.53 % in 1027 seconds + 1.54 % in 1037 seconds + 1.55 % in 1048 seconds + 1.56 % in 1059 seconds + 1.58 % in 1069 seconds + 1.60 % in 1079 seconds + 1.62 % in 1089 seconds + 1.63 % in 1099 seconds + 1.66 % in 1109 seconds + 1.67 % in 1119 seconds + 1.68 % in 1129 seconds + 1.69 % in 1139 seconds + 1.71 % in 1150 seconds + 1.71 % in 1160 seconds + 1.72 % in 1170 seconds + 1.75 % in 1180 seconds + 1.76 % in 1191 seconds + 1.78 % in 1201 seconds + 1.80 % in 1211 seconds + 1.82 % in 1221 seconds + 1.84 % in 1233 seconds + 1.85 % in 1243 seconds + 1.86 % in 1253 seconds + 1.88 % in 1263 seconds + 1.90 % in 1273 seconds + 1.91 % in 1283 seconds + 1.94 % in 1293 seconds + 1.95 % in 1303 seconds + 1.95 % in 1314 seconds + 1.96 % in 1324 seconds + 1.99 % in 1334 seconds + 2.00 % in 1344 seconds + 2.01 % in 1354 seconds + 2.03 % in 1364 seconds + 2.05 % in 1375 seconds + 2.07 % in 1385 seconds + 2.08 % in 1395 seconds + 2.10 % in 1405 seconds + 2.11 % in 1416 seconds + 2.13 % in 1426 seconds + 2.15 % in 1436 seconds + 2.16 % in 1446 seconds + 2.18 % in 1456 seconds + 2.20 % in 1466 seconds + 2.21 % in 1476 seconds + 2.23 % in 1486 seconds + 2.25 % in 1496 seconds + 2.26 % in 1506 seconds + 2.27 % in 1516 seconds + 2.30 % in 1526 seconds + 2.32 % in 1536 seconds + 2.33 % in 1546 seconds + 2.34 % in 1556 seconds + 2.35 % in 1566 seconds + 2.36 % in 1576 seconds + 2.37 % in 1586 seconds + 2.39 % in 1596 seconds + 2.40 % in 1606 seconds + 2.41 % in 1616 seconds + 2.44 % in 1626 seconds + 2.45 % in 1636 seconds + 2.46 % in 1646 seconds + 2.47 % in 1656 seconds + 2.48 % in 1666 seconds + 2.49 % in 1676 seconds + 2.50 % in 1688 seconds + 2.52 % in 1698 seconds + 2.54 % in 1708 seconds + 2.55 % in 1718 seconds + 2.58 % in 1729 seconds + 2.60 % in 1739 seconds + 2.61 % in 1749 seconds + 2.62 % in 1759 seconds + 2.64 % in 1769 seconds + 2.66 % in 1779 seconds + 2.67 % in 1792 seconds + 2.70 % in 1802 seconds + 2.72 % in 1812 seconds + 2.72 % in 1822 seconds + 2.73 % in 1832 seconds + 2.76 % in 1842 seconds + 2.78 % in 1852 seconds + 2.79 % in 1862 seconds + 2.81 % in 1872 seconds + 2.83 % in 1882 seconds + 2.84 % in 1892 seconds + 2.85 % in 1902 seconds + 2.86 % in 1912 seconds + 2.88 % in 1922 seconds + 2.89 % in 1932 seconds + 2.92 % in 1942 seconds + 2.92 % in 1952 seconds + 2.93 % in 1962 seconds + 2.95 % in 1972 seconds + 2.96 % in 1982 seconds + 2.98 % in 1992 seconds + 2.99 % in 2002 seconds + 3.01 % in 2012 seconds + 3.03 % in 2024 seconds + 3.04 % in 2034 seconds + 3.05 % in 2044 seconds + 3.07 % in 2054 seconds + 3.08 % in 2064 seconds + 3.09 % in 2074 seconds + 3.11 % in 2084 seconds + 3.13 % in 2094 seconds + 3.14 % in 2104 seconds + 3.16 % in 2114 seconds + 3.17 % in 2124 seconds + 3.18 % in 2134 seconds + 3.19 % in 2144 seconds + 3.20 % in 2154 seconds + 3.22 % in 2164 seconds + 3.23 % in 2174 seconds + 3.24 % in 2184 seconds + 3.25 % in 2194 seconds + 3.26 % in 2204 seconds + 3.28 % in 2214 seconds + 3.29 % in 2224 seconds + 3.30 % in 2234 seconds + 3.32 % in 2244 seconds + 3.33 % in 2254 seconds + 3.34 % in 2264 seconds + 3.36 % in 2274 seconds + 3.38 % in 2284 seconds + 3.39 % in 2294 seconds + 3.40 % in 2304 seconds + 3.42 % in 2314 seconds + 3.43 % in 2324 seconds + 3.45 % in 2335 seconds + 3.47 % in 2345 seconds + 3.48 % in 2355 seconds + 3.49 % in 2365 seconds + 3.50 % in 2375 seconds + 3.52 % in 2386 seconds + 3.54 % in 2396 seconds + 3.55 % in 2406 seconds + 3.57 % in 2416 seconds + 3.58 % in 2426 seconds + 3.60 % in 2436 seconds + 3.61 % in 2449 seconds + 3.62 % in 2459 seconds + 3.63 % in 2469 seconds + 3.65 % in 2479 seconds + 3.66 % in 2489 seconds + 3.68 % in 2499 seconds + 3.70 % in 2509 seconds + 3.71 % in 2520 seconds + 3.72 % in 2530 seconds + 3.73 % in 2540 seconds + 3.75 % in 2550 seconds + 3.76 % in 2560 seconds + 3.76 % in 2570 seconds + 3.78 % in 2580 seconds + 3.79 % in 2590 seconds + 3.80 % in 2600 seconds + 3.81 % in 2611 seconds + 3.82 % in 2621 seconds + 3.83 % in 2631 seconds + 3.85 % in 2641 seconds + 3.86 % in 2651 seconds + 3.88 % in 2661 seconds + 3.89 % in 2672 seconds + 3.90 % in 2682 seconds + 3.91 % in 2692 seconds + 3.92 % in 2702 seconds + 3.93 % in 2712 seconds + 3.95 % in 2724 seconds + 3.96 % in 2735 seconds + 3.98 % in 2745 seconds + 3.99 % in 2757 seconds + 4.00 % in 2767 seconds + 4.02 % in 2777 seconds + 4.03 % in 2787 seconds + 4.04 % in 2797 seconds + 4.05 % in 2807 seconds + 4.06 % in 2817 seconds + 4.07 % in 2827 seconds + 4.08 % in 2837 seconds + 4.10 % in 2847 seconds + 4.11 % in 2857 seconds + 4.12 % in 2867 seconds + 4.15 % in 2877 seconds + 4.15 % in 2887 seconds + 4.17 % in 2897 seconds + 4.18 % in 2907 seconds + 4.19 % in 2918 seconds + 4.20 % in 2928 seconds + 4.21 % in 2939 seconds + 4.22 % in 2949 seconds + 4.23 % in 2959 seconds + 4.24 % in 2969 seconds + 4.26 % in 2979 seconds + 4.27 % in 2991 seconds + 4.28 % in 3002 seconds + 4.30 % in 3012 seconds + 4.31 % in 3022 seconds + 4.33 % in 3032 seconds + 4.33 % in 3042 seconds + 4.34 % in 3055 seconds + 4.35 % in 3066 seconds + 4.37 % in 3076 seconds + 4.38 % in 3086 seconds + 4.39 % in 3096 seconds + 4.40 % in 3106 seconds + 4.42 % in 3116 seconds + 4.43 % in 3126 seconds + 4.43 % in 3136 seconds + 4.45 % in 3146 seconds + 4.46 % in 3156 seconds + 4.47 % in 3166 seconds + 4.48 % in 3176 seconds + 4.49 % in 3187 seconds + 4.50 % in 3197 seconds + 4.51 % in 3207 seconds + 4.52 % in 3217 seconds + 4.53 % in 3227 seconds + 4.54 % in 3237 seconds + 4.55 % in 3247 seconds + 4.56 % in 3257 seconds + 4.56 % in 3267 seconds + 4.57 % in 3277 seconds + 4.58 % in 3287 seconds + 4.59 % in 3297 seconds + 4.60 % in 3307 seconds + 4.61 % in 3317 seconds + 4.62 % in 3327 seconds + 4.63 % in 3337 seconds + 4.63 % in 3348 seconds + 4.64 % in 3358 seconds + 4.65 % in 3368 seconds + 4.66 % in 3379 seconds + 4.66 % in 3389 seconds + 4.67 % in 3399 seconds + 4.68 % in 3409 seconds + 4.68 % in 3419 seconds + 4.69 % in 3429 seconds + 4.70 % in 3439 seconds + 4.71 % in 3449 seconds + 4.72 % in 3459 seconds + 4.73 % in 3469 seconds + 4.73 % in 3479 seconds + 4.74 % in 3489 seconds + 4.75 % in 3499 seconds + 4.75 % in 3509 seconds + 4.76 % in 3519 seconds + 4.77 % in 3529 seconds + 4.78 % in 3539 seconds + 4.78 % in 3550 seconds + 4.79 % in 3560 seconds + 4.80 % in 3570 seconds + 4.81 % in 3580 seconds + 4.81 % in 3590 seconds + 4.82 % in 3600 seconds + 4.83 % in 3610 seconds + 4.83 % in 3620 seconds + 4.84 % in 3630 seconds + 4.85 % in 3640 seconds + 4.86 % in 3650 seconds + 4.86 % in 3660 seconds + 4.87 % in 3670 seconds + 4.88 % in 3680 seconds + 4.89 % in 3690 seconds + 4.89 % in 3700 seconds + 4.90 % in 3710 seconds + 4.91 % in 3720 seconds + 4.92 % in 3730 seconds + 4.92 % in 3740 seconds + 4.93 % in 3750 seconds + 4.94 % in 3760 seconds + 4.94 % in 3770 seconds + 4.95 % in 3780 seconds + 4.96 % in 3790 seconds + 4.97 % in 3800 seconds + 4.98 % in 3810 seconds + 4.98 % in 3821 seconds + 4.99 % in 3831 seconds + 5.00 % in 3841 seconds + 5.00 % in 3851 seconds + 5.01 % in 3861 seconds + 5.02 % in 3871 seconds + 5.03 % in 3882 seconds + 5.03 % in 3892 seconds + 5.04 % in 3902 seconds + 5.05 % in 3912 seconds + 5.06 % in 3922 seconds + 5.06 % in 3932 seconds + 5.07 % in 3942 seconds + 5.08 % in 3953 seconds + 5.09 % in 3963 seconds + 5.09 % in 3973 seconds + 5.10 % in 3983 seconds + 5.11 % in 3994 seconds + 5.12 % in 4004 seconds + 5.12 % in 4014 seconds + 5.13 % in 4024 seconds + 5.14 % in 4034 seconds + 5.15 % in 4044 seconds + 5.15 % in 4054 seconds + 5.16 % in 4065 seconds + 5.17 % in 4075 seconds + 5.18 % in 4085 seconds + 5.18 % in 4121 seconds + 5.21 % in 4133 seconds + + unset COMMAND ++ qp run save_natorb ++ case $1 in ++ which qp_run ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' furan +++ qp_run save_natorb furan ++ unset COMMAND ++ qp set determinants n_det_max 1e8 ++ case $1 in ++ ezfio set determinants n_det_max 1e8 ++ case $1 in ++ shift ++ _ezfio_set determinants n_det_max 1e8 ++ _require_ezfio_file ++ [[ -z furan ]] ++ [[ ! -d furan ]] ++ _require_first_argument determinants n_det_max 1e8 ++ [[ -z determinants ]] ++ return 0 ++ _require_second_argument determinants n_det_max 1e8 ++ [[ -z n_det_max ]] ++ [[ -z 1e8 ]] ++ echo 1e8 ++ _ezfio_py set determinants n_det_max ++ python2 /tmpdir/loos/qp2/external/ezfio/Python/ezfio.py set determinants n_det_max ++ return 0 ++ qp run fci ++ case $1 in ++ which qp_run ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' furan +++ qp_run fci furan + 0.07 % in 0 seconds + 50.00 % in 0 seconds + 16.67 % in 0 seconds + 9.09 % in 0 seconds + 4.76 % in 0 seconds + 2.44 % in 1 seconds + 1.23 % in 0 seconds + 0.62 % in 0 seconds + 0.31 % in 0 seconds + 0.16 % in 0 seconds + 0.08 % in 0 seconds + 0.04 % in 0 seconds + 0.02 % in 0 seconds + 0.01 % in 0 seconds + 0.00 % in 1 seconds + 0.00 % in 0 seconds + 8.80 % in 10 seconds + 0.00 % in 1 seconds + 4.48 % in 11 seconds + 9.12 % in 21 seconds + 16.67 % in 0 seconds + 16.67 % in 0 seconds + 16.67 % in 1 seconds + 16.67 % in 0 seconds + 16.67 % in 0 seconds + 16.67 % in 0 seconds + 16.67 % in 0 seconds + 16.67 % in 1 seconds + 16.67 % in 0 seconds + 16.67 % in 0 seconds + 16.67 % in 0 seconds + 0.00 % in 0 seconds + 2.03 % in 10 seconds + 4.49 % in 20 seconds + 6.69 % in 30 seconds + 8.65 % in 40 seconds +10.69 % in 50 seconds +12.64 % in 60 seconds +14.53 % in 70 seconds + 10.00 % in 1 seconds + 10.00 % in 0 seconds + 10.00 % in 0 seconds + 10.00 % in 0 seconds + 10.00 % in 1 seconds + 10.00 % in 0 seconds + 10.00 % in 0 seconds + 10.00 % in 0 seconds + 10.00 % in 0 seconds + 10.00 % in 1 seconds + 10.00 % in 0 seconds + 0.00 % in 1 seconds + 0.98 % in 11 seconds + 2.37 % in 21 seconds + 3.48 % in 31 seconds + 4.56 % in 41 seconds + 5.49 % in 51 seconds + 6.33 % in 61 seconds + 7.15 % in 71 seconds + 8.02 % in 81 seconds + 8.87 % in 91 seconds + 9.71 % in 101 seconds +10.46 % in 111 seconds +11.21 % in 121 seconds + 5.56 % in 1 seconds + 5.56 % in 0 seconds + 5.56 % in 1 seconds + 5.56 % in 1 seconds + 5.56 % in 0 seconds + 5.56 % in 0 seconds + 5.56 % in 0 seconds + 5.56 % in 1 seconds + 5.56 % in 0 seconds + 5.56 % in 0 seconds + 5.56 % in 1 seconds + 0.00 % in 3 seconds + 0.32 % in 13 seconds + 1.10 % in 23 seconds + 1.74 % in 33 seconds + 2.51 % in 43 seconds + 2.92 % in 53 seconds + 3.54 % in 63 seconds + 4.13 % in 73 seconds + 4.56 % in 83 seconds + 4.94 % in 93 seconds + 5.38 % in 103 seconds + 5.71 % in 113 seconds + 6.15 % in 123 seconds + 6.51 % in 133 seconds + 6.89 % in 143 seconds + 7.27 % in 153 seconds + 7.64 % in 163 seconds + 8.02 % in 173 seconds + 8.35 % in 183 seconds + 8.68 % in 193 seconds + 9.03 % in 203 seconds + 9.33 % in 213 seconds + 9.47 % in 223 seconds + 2.94 % in 1 seconds + 2.94 % in 1 seconds + 2.94 % in 1 seconds + 2.94 % in 1 seconds + 2.94 % in 1 seconds + 2.94 % in 1 seconds + 2.94 % in 1 seconds + 2.94 % in 1 seconds + 2.94 % in 1 seconds + 2.94 % in 1 seconds + 0.00 % in 4 seconds + 0.12 % in 14 seconds + 0.32 % in 25 seconds + 0.65 % in 36 seconds + 1.00 % in 46 seconds + 1.25 % in 56 seconds + 1.60 % in 66 seconds + 1.95 % in 76 seconds + 2.24 % in 86 seconds + 2.49 % in 96 seconds + 2.72 % in 106 seconds + 2.92 % in 116 seconds + 3.20 % in 126 seconds + 3.44 % in 136 seconds + 3.63 % in 146 seconds + 3.88 % in 156 seconds + 4.02 % in 166 seconds + 4.19 % in 176 seconds + 4.39 % in 186 seconds + 4.52 % in 196 seconds + 4.66 % in 207 seconds + 4.82 % in 217 seconds + 4.98 % in 227 seconds + 5.16 % in 237 seconds + 5.29 % in 247 seconds + 5.43 % in 257 seconds + 5.61 % in 267 seconds + 5.74 % in 277 seconds + 5.89 % in 287 seconds + 6.03 % in 297 seconds + 6.17 % in 307 seconds + 6.34 % in 317 seconds + 6.45 % in 327 seconds + 6.61 % in 337 seconds + 6.73 % in 347 seconds + 6.87 % in 357 seconds + 7.00 % in 367 seconds + 7.12 % in 377 seconds + 7.28 % in 388 seconds + 7.41 % in 398 seconds + 7.49 % in 409 seconds + 7.62 % in 419 seconds + 1.49 % in 2 seconds +53.73 % in 12 seconds + 1.49 % in 3 seconds +59.70 % in 13 seconds + 1.49 % in 2 seconds +55.22 % in 12 seconds + 1.49 % in 2 seconds +56.72 % in 12 seconds + 1.49 % in 2 seconds +55.22 % in 12 seconds + 1.49 % in 3 seconds +61.19 % in 13 seconds + 1.49 % in 2 seconds +56.72 % in 12 seconds + 1.49 % in 3 seconds +59.70 % in 13 seconds + 1.49 % in 2 seconds +56.72 % in 12 seconds + 0.00 % in 8 seconds + 0.04 % in 19 seconds + 0.11 % in 29 seconds + 0.17 % in 39 seconds + 0.32 % in 49 seconds + 0.33 % in 60 seconds + 0.61 % in 70 seconds + 0.66 % in 84 seconds + 0.74 % in 94 seconds + 0.99 % in 104 seconds + 1.07 % in 114 seconds + 1.11 % in 124 seconds + 1.33 % in 134 seconds + 1.46 % in 145 seconds + 1.51 % in 155 seconds + 1.66 % in 165 seconds + 1.86 % in 175 seconds + 1.91 % in 185 seconds + 1.98 % in 195 seconds + 2.15 % in 205 seconds + 2.30 % in 215 seconds + 2.41 % in 225 seconds + 2.47 % in 235 seconds + 2.61 % in 245 seconds + 2.66 % in 255 seconds + 2.70 % in 265 seconds + 2.79 % in 275 seconds + 2.93 % in 287 seconds + 3.03 % in 297 seconds + 3.13 % in 307 seconds + 3.23 % in 317 seconds + 3.33 % in 327 seconds + 3.43 % in 337 seconds + 3.56 % in 347 seconds + 3.61 % in 358 seconds + 3.67 % in 368 seconds + 3.75 % in 378 seconds + 3.84 % in 388 seconds + 3.89 % in 398 seconds + 3.94 % in 408 seconds + 3.99 % in 418 seconds + 4.06 % in 428 seconds + 4.13 % in 438 seconds + 4.21 % in 448 seconds + 4.25 % in 458 seconds + 4.35 % in 468 seconds + 4.41 % in 478 seconds + 4.47 % in 488 seconds + 4.55 % in 498 seconds + 4.61 % in 508 seconds + 4.66 % in 519 seconds + 4.70 % in 529 seconds + 4.76 % in 539 seconds + 4.82 % in 549 seconds + 4.88 % in 559 seconds + 4.92 % in 569 seconds + 4.99 % in 580 seconds + 5.04 % in 591 seconds + 5.09 % in 601 seconds + 5.15 % in 611 seconds + 5.20 % in 621 seconds + 5.24 % in 631 seconds + 5.30 % in 641 seconds + 5.37 % in 651 seconds + 5.40 % in 661 seconds + 5.45 % in 671 seconds + 5.50 % in 681 seconds + 5.54 % in 691 seconds + 5.61 % in 701 seconds + 5.65 % in 712 seconds + 5.72 % in 723 seconds + 5.77 % in 733 seconds + 5.81 % in 743 seconds + 5.86 % in 753 seconds + 5.92 % in 763 seconds + 5.96 % in 773 seconds + 5.96 % in 783 seconds + 6.05 % in 793 seconds + 6.10 % in 804 seconds + 6.13 % in 814 seconds + 6.14 % in 828 seconds + 0.75 % in 5 seconds + 9.77 % in 15 seconds +30.83 % in 25 seconds +56.39 % in 35 seconds +81.95 % in 45 seconds + 0.75 % in 5 seconds + 9.77 % in 15 seconds +30.83 % in 25 seconds +56.39 % in 35 seconds +82.71 % in 45 seconds + 0.75 % in 5 seconds + 9.77 % in 15 seconds +30.83 % in 25 seconds +56.39 % in 35 seconds +81.95 % in 45 seconds + 0.75 % in 5 seconds + 9.77 % in 15 seconds +30.83 % in 25 seconds +57.14 % in 35 seconds +83.46 % in 45 seconds + 0.75 % in 5 seconds + 9.02 % in 15 seconds +30.83 % in 25 seconds +57.14 % in 35 seconds +82.71 % in 45 seconds + 0.75 % in 5 seconds + 9.77 % in 15 seconds +30.83 % in 25 seconds +57.14 % in 35 seconds +83.46 % in 45 seconds + 0.75 % in 5 seconds + 9.02 % in 15 seconds +30.83 % in 25 seconds +56.39 % in 35 seconds +81.95 % in 45 seconds + 0.75 % in 5 seconds + 9.77 % in 15 seconds +30.83 % in 25 seconds +57.14 % in 35 seconds +82.71 % in 45 seconds + 0.75 % in 5 seconds + 9.02 % in 15 seconds +30.83 % in 25 seconds +56.39 % in 35 seconds +82.71 % in 45 seconds + 0.00 % in 16 seconds + 0.01 % in 27 seconds + 0.04 % in 37 seconds + 0.06 % in 47 seconds + 0.08 % in 57 seconds + 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0.29 % in 349225 seconds + 0.29 % in 349235 seconds + 0.29 % in 349245 seconds + 0.29 % in 349256 seconds + 0.29 % in 349266 seconds + 0.29 % in 349276 seconds + 0.29 % in 349287 seconds + 0.29 % in 349297 seconds + 0.29 % in 349308 seconds + 0.29 % in 349318 seconds + 0.29 % in 349329 seconds + 0.29 % in 349339 seconds + 0.29 % in 349349 seconds + 0.29 % in 349359 seconds + 0.29 % in 349371 seconds + 0.29 % in 349381 seconds + 0.29 % in 349393 seconds + 0.29 % in 349404 seconds + 0.29 % in 349415 seconds + 0.29 % in 349425 seconds + 0.29 % in 349435 seconds + 0.29 % in 349446 seconds + 0.29 % in 349457 seconds + 0.29 % in 349468 seconds + 0.29 % in 349479 seconds + 0.29 % in 349489 seconds + 0.29 % in 349499 seconds + 0.29 % in 349510 seconds + 0.29 % in 349521 seconds + 0.29 % in 349531 seconds + 0.29 % in 349541 seconds + 0.29 % in 349551 seconds + 0.29 % in 349561 seconds + 0.29 % in 349572 seconds + 0.29 % in 349582 seconds + 0.29 % in 349592 seconds + 0.29 % in 349603 seconds + 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0.29 % in 350008 seconds + 0.29 % in 350019 seconds +slurmstepd: error: *** JOB 514499 ON olympecomp321 CANCELLED AT 2020-12-25T08:04:13 DUE TO TIME LIMIT *** diff --git a/furan/6-31g/slurm-517692.out b/furan/6-31g/slurm-517692.out new file mode 100644 index 0000000..8559052 --- /dev/null +++ b/furan/6-31g/slurm-517692.out @@ -0,0 +1,183 @@ ++ INPUT=furan ++ source /users/p18005/loos/tmpdir/qp2/quantum_package.rc +++ QP_ROOT=/NOT/FOUND +++ case "$(ps -p $$ -ocomm=)" in ++++ ps -p 53519 -ocomm= ++++ dirname '/users/p18005/loos/tmpdir/qp2/quantum_package.rc[0]' +++ QP_ROOT=/users/p18005/loos/tmpdir/qp2 ++++ cd /users/p18005/loos/tmpdir/qp2 ++++ pwd -P +++ export QP_ROOT=/tmpdir/loos/qp2 +++ QP_ROOT=/tmpdir/loos/qp2 +++ WD=/users/p18005/loos/tmpdir/Ec/furan/6-31g +++ cd /tmpdir/loos/qp2/etc +++ for SCRIPT in '*.rc' +++ source 00.qp_root.rc ++++ export QP_ROOT=/tmpdir/loos/qp2 ++++ QP_ROOT=/tmpdir/loos/qp2 +++ for SCRIPT in '*.rc' +++ source autocomplete.rc +++++ ps -p 53519 -ocomm= ++++ [[ slurm_script == \z\s\h ]] +++ for SCRIPT in '*.rc' +++ source configure.rc ++++ source /tmpdir/loos/qp2/etc/autocomplete.rc ++++++ ps -p 53519 -ocomm= +++++ [[ slurm_script == \z\s\h ]] ++++ complete -F _configure_Complete configure +++ for SCRIPT in '*.rc' +++ source ezfio.rc ++++ export QP_EZFIO=/tmpdir/loos/qp2/external/ezfio ++++ QP_EZFIO=/tmpdir/loos/qp2/external/ezfio ++++ source /tmpdir/loos/qp2/etc/autocomplete.rc ++++++ ps -p 53519 -ocomm= +++++ [[ slurm_script == \z\s\h ]] ++++ source_if_exists /tmpdir/loos/qp2/external/ezfio/Bash/ezfio.sh +++ for SCRIPT in '*.rc' +++ source irpf90.rc ++++ export IRPF90_PATH=/tmpdir/loos/qp2/external/irpf90-v1.7.6 ++++ IRPF90_PATH=/tmpdir/loos/qp2/external/irpf90-v1.7.6 ++++ export PATH=/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ++++ PATH=/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ++++ export IRPF90=/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin/irpf90 ++++ IRPF90=/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin/irpf90 ++++ source /tmpdir/loos/qp2/etc/autocomplete.rc ++++++ ps -p 53519 -ocomm= +++++ [[ slurm_script == \z\s\h ]] ++++ source_if_exists /tmpdir/loos/qp2/external/irpf90-v1.7.6/irpman-completions.bash +++ for SCRIPT in '*.rc' +++ source libraries.rc ++++ QP_LIB= +++ for SCRIPT in '*.rc' +++ source local.rc +++ for SCRIPT in '*.rc' +++ source ninja.rc ++++ export NINJA=/tmpdir/loos/qp2/bin/ninja ++++ NINJA=/tmpdir/loos/qp2/bin/ninja +++ for SCRIPT in '*.rc' +++ source ocaml.rc ++++ [[ -z /tmpdir/loos/qp2/external/opam ]] ++++ source /tmpdir/loos/qp2/external/opam/opam-init/init.sh +++ for SCRIPT in '*.rc' +++ source paths.rc ++++ QP_PYTHON= ++++ for i in ezfio.rc irpf90.rc ninja.rc ocaml.rc ++++ source ezfio.rc +++++ export QP_EZFIO=/tmpdir/loos/qp2/external/ezfio +++++ QP_EZFIO=/tmpdir/loos/qp2/external/ezfio +++++ source /tmpdir/loos/qp2/etc/autocomplete.rc +++++++ ps -p 53519 -ocomm= ++++++ [[ slurm_script == \z\s\h ]] +++++ source_if_exists /tmpdir/loos/qp2/external/ezfio/Bash/ezfio.sh ++++ for i in ezfio.rc irpf90.rc ninja.rc ocaml.rc ++++ source irpf90.rc +++++ export IRPF90_PATH=/tmpdir/loos/qp2/external/irpf90-v1.7.6 +++++ IRPF90_PATH=/tmpdir/loos/qp2/external/irpf90-v1.7.6 +++++ export PATH=/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin +++++ PATH=/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin +++++ export IRPF90=/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin/irpf90 +++++ IRPF90=/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin/irpf90 +++++ source /tmpdir/loos/qp2/etc/autocomplete.rc +++++++ ps -p 53519 -ocomm= ++++++ [[ slurm_script == \z\s\h ]] +++++ source_if_exists /tmpdir/loos/qp2/external/irpf90-v1.7.6/irpman-completions.bash ++++ for i in ezfio.rc irpf90.rc ninja.rc ocaml.rc ++++ source ninja.rc +++++ export NINJA=/tmpdir/loos/qp2/bin/ninja +++++ NINJA=/tmpdir/loos/qp2/bin/ninja ++++ for i in ezfio.rc irpf90.rc ninja.rc ocaml.rc ++++ source ocaml.rc +++++ [[ -z /tmpdir/loos/qp2/external/opam ]] +++++ source /tmpdir/loos/qp2/external/opam/opam-init/init.sh ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile +++++ qp_prepend_export PYTHONPATH /tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile +++++ eval 'value_1=${PYTHONPATH}' ++++++ value_1=/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: +++++ [[ -z /tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: ]] +++++ echo /tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: ++++ export PYTHONPATH=/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: ++++ PYTHONPATH=/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: +++++ qp_prepend_export PATH :/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml +++++ eval 'value_1=${PATH}' ++++++ value_1=/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin +++++ [[ -z /tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ]] +++++ echo :/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ++++ export PATH=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ++++ PATH=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin +++++ qp_prepend_export LD_LIBRARY_PATH /tmpdir/loos/qp2/lib +++++ eval 'value_1=${LD_LIBRARY_PATH}' ++++++ value_1=/tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib +++++ [[ -z /tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib ]] +++++ echo /tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib ++++ export LD_LIBRARY_PATH=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib ++++ LD_LIBRARY_PATH=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib +++++ qp_prepend_export LIBRARY_PATH /tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64 +++++ eval 'value_1=${LIBRARY_PATH}' ++++++ value_1=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 +++++ [[ -z /tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 ]] +++++ echo /tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 ++++ export LIBRARY_PATH=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 ++++ LIBRARY_PATH=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 +++++ qp_prepend_export C_INCLUDE_PATH /tmpdir/loos/qp2/include +++++ eval 'value_1=${C_INCLUDE_PATH}' ++++++ value_1=/tmpdir/loos/qp2/include: +++++ [[ -z /tmpdir/loos/qp2/include: ]] +++++ echo /tmpdir/loos/qp2/include:/tmpdir/loos/qp2/include: ++++ export C_INCLUDE_PATH=/tmpdir/loos/qp2/include:/tmpdir/loos/qp2/include: ++++ C_INCLUDE_PATH=/tmpdir/loos/qp2/include:/tmpdir/loos/qp2/include: +++ for SCRIPT in '*.rc' +++ source qp.rc +++++ ps -p 53519 -ocomm= ++++ [[ slurm_script == \z\s\h ]] ++++ source /tmpdir/loos/qp2/etc/ezfio.rc +++++ export QP_EZFIO=/tmpdir/loos/qp2/external/ezfio +++++ QP_EZFIO=/tmpdir/loos/qp2/external/ezfio +++++ source /tmpdir/loos/qp2/etc/autocomplete.rc +++++++ ps -p 53519 -ocomm= ++++++ [[ slurm_script == \z\s\h ]] +++++ source_if_exists /tmpdir/loos/qp2/external/ezfio/Bash/ezfio.sh ++++ complete -F _qp_Complete qp +++ cd /users/p18005/loos/tmpdir/Ec/furan/6-31g +++ [[ -z /tmpdir/loos/qp2 ]] ++ set -e ++ ./localize.sh furan.ang /tmpdir/loos/qp2/data/basis/cc-pvdz furan + +Orbital localization + +Method : Boys_er +Separation type : Sigma/pi +Max number of iterations : 1000000 +cc : 1e-05 +epsilon : 1. +charge : 0 +Rotation pre angle : 0.001 + +Criterion max_angle norm_angle average_angle + +Orbital lists: +Core: [1,2,3,4,5,] +Occupied: [6,7,8,9,10,11,12,13,14,15,16,17,18,] +Virtual: [19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,] +Sigma occ: [6,7,8,9,10,11,12,13,15,16,] +Pi occ: [14,17,18,] +Sigma vir: [21,22,23,24,25,26,27,28,29,31,34,35,36,37,38,40,42,43,44,45,46,47,48,49,50,51,52,53,] +Pi vir: [19,20,30,32,33,39,41,] + +Fatal error: exception Failure("Lacaml.D.gemm: inner dimensions of matrices do not match (95,53)") +cat: furan.mo: No such file or directory +Syntax Error diff --git a/furan/6-31g/slurm-520718.out b/furan/6-31g/slurm-520718.out new file mode 100644 index 0000000..f709abd --- /dev/null +++ b/furan/6-31g/slurm-520718.out @@ -0,0 +1,183 @@ ++ INPUT=furan ++ source /users/p18005/loos/tmpdir/qp2/quantum_package.rc +++ QP_ROOT=/NOT/FOUND +++ case "$(ps -p $$ -ocomm=)" in ++++ ps -p 69629 -ocomm= ++++ dirname '/users/p18005/loos/tmpdir/qp2/quantum_package.rc[0]' +++ QP_ROOT=/users/p18005/loos/tmpdir/qp2 ++++ cd /users/p18005/loos/tmpdir/qp2 ++++ pwd -P +++ export QP_ROOT=/tmpdir/loos/qp2 +++ QP_ROOT=/tmpdir/loos/qp2 +++ WD=/users/p18005/loos/tmpdir/Ec/furan/6-31g +++ cd /tmpdir/loos/qp2/etc +++ for SCRIPT in '*.rc' +++ source 00.qp_root.rc ++++ export QP_ROOT=/tmpdir/loos/qp2 ++++ QP_ROOT=/tmpdir/loos/qp2 +++ for SCRIPT in '*.rc' +++ source autocomplete.rc +++++ ps -p 69629 -ocomm= ++++ [[ slurm_script == \z\s\h ]] +++ for SCRIPT in '*.rc' +++ source configure.rc ++++ source /tmpdir/loos/qp2/etc/autocomplete.rc ++++++ ps -p 69629 -ocomm= +++++ [[ slurm_script == \z\s\h ]] ++++ complete -F _configure_Complete configure +++ for SCRIPT in '*.rc' +++ source ezfio.rc ++++ export QP_EZFIO=/tmpdir/loos/qp2/external/ezfio ++++ QP_EZFIO=/tmpdir/loos/qp2/external/ezfio ++++ source /tmpdir/loos/qp2/etc/autocomplete.rc ++++++ ps -p 69629 -ocomm= +++++ [[ slurm_script == \z\s\h ]] ++++ source_if_exists /tmpdir/loos/qp2/external/ezfio/Bash/ezfio.sh +++ for SCRIPT in '*.rc' +++ source irpf90.rc ++++ export IRPF90_PATH=/tmpdir/loos/qp2/external/irpf90-v1.7.6 ++++ IRPF90_PATH=/tmpdir/loos/qp2/external/irpf90-v1.7.6 ++++ export PATH=/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ++++ PATH=/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ++++ export IRPF90=/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin/irpf90 ++++ IRPF90=/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin/irpf90 ++++ source /tmpdir/loos/qp2/etc/autocomplete.rc ++++++ ps -p 69629 -ocomm= +++++ [[ slurm_script == \z\s\h ]] ++++ source_if_exists /tmpdir/loos/qp2/external/irpf90-v1.7.6/irpman-completions.bash +++ for SCRIPT in '*.rc' +++ source libraries.rc ++++ QP_LIB= +++ for SCRIPT in '*.rc' +++ source local.rc +++ for SCRIPT in '*.rc' +++ source ninja.rc ++++ export NINJA=/tmpdir/loos/qp2/bin/ninja ++++ NINJA=/tmpdir/loos/qp2/bin/ninja +++ for SCRIPT in '*.rc' +++ source ocaml.rc ++++ [[ -z /tmpdir/loos/qp2/external/opam ]] ++++ source /tmpdir/loos/qp2/external/opam/opam-init/init.sh +++ for SCRIPT in '*.rc' +++ source paths.rc ++++ QP_PYTHON= ++++ for i in ezfio.rc irpf90.rc ninja.rc ocaml.rc ++++ source ezfio.rc +++++ export QP_EZFIO=/tmpdir/loos/qp2/external/ezfio +++++ QP_EZFIO=/tmpdir/loos/qp2/external/ezfio +++++ source /tmpdir/loos/qp2/etc/autocomplete.rc +++++++ ps -p 69629 -ocomm= ++++++ [[ slurm_script == \z\s\h ]] +++++ source_if_exists /tmpdir/loos/qp2/external/ezfio/Bash/ezfio.sh ++++ for i in ezfio.rc irpf90.rc ninja.rc ocaml.rc ++++ source irpf90.rc +++++ export IRPF90_PATH=/tmpdir/loos/qp2/external/irpf90-v1.7.6 +++++ IRPF90_PATH=/tmpdir/loos/qp2/external/irpf90-v1.7.6 +++++ export PATH=/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin +++++ PATH=/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin +++++ export IRPF90=/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin/irpf90 +++++ IRPF90=/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin/irpf90 +++++ source /tmpdir/loos/qp2/etc/autocomplete.rc +++++++ ps -p 69629 -ocomm= ++++++ [[ slurm_script == \z\s\h ]] +++++ source_if_exists /tmpdir/loos/qp2/external/irpf90-v1.7.6/irpman-completions.bash ++++ for i in ezfio.rc irpf90.rc ninja.rc ocaml.rc ++++ source ninja.rc +++++ export NINJA=/tmpdir/loos/qp2/bin/ninja +++++ NINJA=/tmpdir/loos/qp2/bin/ninja ++++ for i in ezfio.rc irpf90.rc ninja.rc ocaml.rc ++++ source ocaml.rc +++++ [[ -z /tmpdir/loos/qp2/external/opam ]] +++++ source /tmpdir/loos/qp2/external/opam/opam-init/init.sh ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile +++++ qp_prepend_export PYTHONPATH /tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile +++++ eval 'value_1=${PYTHONPATH}' ++++++ value_1=/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: +++++ [[ -z /tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: ]] +++++ echo /tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: ++++ export PYTHONPATH=/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: ++++ PYTHONPATH=/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: +++++ qp_prepend_export PATH :/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml +++++ eval 'value_1=${PATH}' ++++++ value_1=/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin +++++ [[ -z /tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ]] +++++ echo :/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ++++ export PATH=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ++++ PATH=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin +++++ qp_prepend_export LD_LIBRARY_PATH /tmpdir/loos/qp2/lib +++++ eval 'value_1=${LD_LIBRARY_PATH}' ++++++ value_1=/tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib +++++ [[ -z /tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib ]] +++++ echo /tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib ++++ export LD_LIBRARY_PATH=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib ++++ LD_LIBRARY_PATH=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib +++++ qp_prepend_export LIBRARY_PATH /tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64 +++++ eval 'value_1=${LIBRARY_PATH}' ++++++ value_1=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 +++++ [[ -z /tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 ]] +++++ echo /tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 ++++ export LIBRARY_PATH=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 ++++ LIBRARY_PATH=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 +++++ qp_prepend_export C_INCLUDE_PATH /tmpdir/loos/qp2/include +++++ eval 'value_1=${C_INCLUDE_PATH}' ++++++ value_1=/tmpdir/loos/qp2/include: +++++ [[ -z /tmpdir/loos/qp2/include: ]] +++++ echo /tmpdir/loos/qp2/include:/tmpdir/loos/qp2/include: ++++ export C_INCLUDE_PATH=/tmpdir/loos/qp2/include:/tmpdir/loos/qp2/include: ++++ C_INCLUDE_PATH=/tmpdir/loos/qp2/include:/tmpdir/loos/qp2/include: +++ for SCRIPT in '*.rc' +++ source qp.rc +++++ ps -p 69629 -ocomm= ++++ [[ slurm_script == \z\s\h ]] ++++ source /tmpdir/loos/qp2/etc/ezfio.rc +++++ export QP_EZFIO=/tmpdir/loos/qp2/external/ezfio +++++ QP_EZFIO=/tmpdir/loos/qp2/external/ezfio +++++ source /tmpdir/loos/qp2/etc/autocomplete.rc +++++++ ps -p 69629 -ocomm= ++++++ [[ slurm_script == \z\s\h ]] +++++ source_if_exists /tmpdir/loos/qp2/external/ezfio/Bash/ezfio.sh ++++ complete -F _qp_Complete qp +++ cd /users/p18005/loos/tmpdir/Ec/furan/6-31g +++ [[ -z /tmpdir/loos/qp2 ]] ++ set -e ++ ./localize.sh furan.ang /tmpdir/loos/qp2/data/basis/cc-pvdz furan + +Orbital localization + +Method : Boys_er +Separation type : Sigma/pi +Max number of iterations : 1000000 +cc : 1e-05 +epsilon : 1. +charge : 0 +Rotation pre angle : 0.001 + +Criterion max_angle norm_angle average_angle + +Orbital lists: +Core: [1,2,3,4,5,] +Occupied: [6,7,8,9,10,11,12,13,14,15,16,17,18,] +Virtual: [19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,] +Sigma occ: [6,7,8,9,10,11,12,13,15,16,] +Pi occ: [14,17,18,] +Sigma vir: [21,22,23,24,25,26,27,28,29,31,34,35,36,37,38,40,42,43,44,45,46,47,48,49,50,51,52,53,] +Pi vir: [19,20,30,32,33,39,41,] + +Fatal error: exception Failure("Lacaml.D.gemm: inner dimensions of matrices do not match (95,53)") +cat: furan.mo: No such file or directory +Syntax Error diff --git a/furan/6-31g/slurm-520752.out b/furan/6-31g/slurm-520752.out new file mode 100644 index 0000000..218f048 --- /dev/null +++ b/furan/6-31g/slurm-520752.out @@ -0,0 +1,37192 @@ ++ INPUT=furan ++ source /users/p18005/loos/tmpdir/qp2/quantum_package.rc +++ QP_ROOT=/NOT/FOUND +++ case "$(ps -p $$ -ocomm=)" in ++++ ps -p 61524 -ocomm= ++++ dirname '/users/p18005/loos/tmpdir/qp2/quantum_package.rc[0]' +++ QP_ROOT=/users/p18005/loos/tmpdir/qp2 ++++ cd /users/p18005/loos/tmpdir/qp2 ++++ pwd -P +++ export QP_ROOT=/tmpdir/loos/qp2 +++ QP_ROOT=/tmpdir/loos/qp2 +++ WD=/users/p18005/loos/tmpdir/Ec/furan/6-31g +++ cd /tmpdir/loos/qp2/etc +++ for SCRIPT in '*.rc' +++ source 00.qp_root.rc ++++ export QP_ROOT=/tmpdir/loos/qp2 ++++ QP_ROOT=/tmpdir/loos/qp2 +++ for SCRIPT in '*.rc' +++ source autocomplete.rc +++++ ps -p 61524 -ocomm= ++++ [[ slurm_script == \z\s\h ]] +++ for SCRIPT in '*.rc' +++ source configure.rc ++++ source /tmpdir/loos/qp2/etc/autocomplete.rc ++++++ ps -p 61524 -ocomm= +++++ [[ slurm_script == \z\s\h ]] ++++ complete -F _configure_Complete configure +++ for SCRIPT in '*.rc' +++ source ezfio.rc ++++ export QP_EZFIO=/tmpdir/loos/qp2/external/ezfio ++++ QP_EZFIO=/tmpdir/loos/qp2/external/ezfio ++++ source /tmpdir/loos/qp2/etc/autocomplete.rc ++++++ ps -p 61524 -ocomm= +++++ [[ slurm_script == \z\s\h ]] ++++ source_if_exists /tmpdir/loos/qp2/external/ezfio/Bash/ezfio.sh +++ for SCRIPT in '*.rc' +++ source irpf90.rc ++++ export IRPF90_PATH=/tmpdir/loos/qp2/external/irpf90-v1.7.6 ++++ IRPF90_PATH=/tmpdir/loos/qp2/external/irpf90-v1.7.6 ++++ export PATH=/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ++++ PATH=/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ++++ export IRPF90=/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin/irpf90 ++++ IRPF90=/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin/irpf90 ++++ source /tmpdir/loos/qp2/etc/autocomplete.rc ++++++ ps -p 61524 -ocomm= +++++ [[ slurm_script == \z\s\h ]] ++++ source_if_exists /tmpdir/loos/qp2/external/irpf90-v1.7.6/irpman-completions.bash +++ for SCRIPT in '*.rc' +++ source libraries.rc ++++ QP_LIB= +++ for SCRIPT in '*.rc' +++ source local.rc +++ for SCRIPT in '*.rc' +++ source ninja.rc ++++ export NINJA=/tmpdir/loos/qp2/bin/ninja ++++ NINJA=/tmpdir/loos/qp2/bin/ninja +++ for SCRIPT in '*.rc' +++ source ocaml.rc ++++ [[ -z /tmpdir/loos/qp2/external/opam ]] ++++ source /tmpdir/loos/qp2/external/opam/opam-init/init.sh +++ for SCRIPT in '*.rc' +++ source paths.rc ++++ QP_PYTHON= ++++ for i in ezfio.rc irpf90.rc ninja.rc ocaml.rc ++++ source ezfio.rc +++++ export QP_EZFIO=/tmpdir/loos/qp2/external/ezfio +++++ QP_EZFIO=/tmpdir/loos/qp2/external/ezfio +++++ source /tmpdir/loos/qp2/etc/autocomplete.rc +++++++ ps -p 61524 -ocomm= ++++++ [[ slurm_script == \z\s\h ]] +++++ source_if_exists /tmpdir/loos/qp2/external/ezfio/Bash/ezfio.sh ++++ for i in ezfio.rc irpf90.rc ninja.rc ocaml.rc ++++ source irpf90.rc +++++ export IRPF90_PATH=/tmpdir/loos/qp2/external/irpf90-v1.7.6 +++++ IRPF90_PATH=/tmpdir/loos/qp2/external/irpf90-v1.7.6 +++++ export PATH=/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin +++++ PATH=/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin +++++ export IRPF90=/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin/irpf90 +++++ IRPF90=/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin/irpf90 +++++ source /tmpdir/loos/qp2/etc/autocomplete.rc +++++++ ps -p 61524 -ocomm= ++++++ [[ slurm_script == \z\s\h ]] +++++ source_if_exists /tmpdir/loos/qp2/external/irpf90-v1.7.6/irpman-completions.bash ++++ for i in ezfio.rc irpf90.rc ninja.rc ocaml.rc ++++ source ninja.rc +++++ export NINJA=/tmpdir/loos/qp2/bin/ninja +++++ NINJA=/tmpdir/loos/qp2/bin/ninja ++++ for i in ezfio.rc irpf90.rc ninja.rc ocaml.rc ++++ source ocaml.rc +++++ [[ -z /tmpdir/loos/qp2/external/opam ]] +++++ source /tmpdir/loos/qp2/external/opam/opam-init/init.sh ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python ++++ export QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile ++++ QP_PYTHON=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile +++++ qp_prepend_export PYTHONPATH /tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile +++++ eval 'value_1=${PYTHONPATH}' ++++++ value_1=/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: +++++ [[ -z /tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: ]] +++++ echo /tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: ++++ export PYTHONPATH=/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: ++++ PYTHONPATH=/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/external/ezfio/Python::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile: +++++ qp_prepend_export PATH :/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml +++++ eval 'value_1=${PATH}' ++++++ value_1=/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin +++++ [[ -z /tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ]] +++++ echo :/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ++++ export PATH=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin ++++ PATH=:/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/tmpdir/loos/qp2/external/opam/4.07.1/bin::/tmpdir/loos/qp2/external/ezfio/Python:/tmpdir/loos/qp2/scripts:/tmpdir/loos/qp2/scripts/ezfio_interface:/tmpdir/loos/qp2/scripts/utility:/tmpdir/loos/qp2/scripts/module:/tmpdir/loos/qp2/scripts/compilation:/tmpdir/loos/qp2/external/Python:/tmpdir/loos/qp2/external/Python/resultsFile:/tmpdir/loos/qp2/bin:/tmpdir/loos/qp2/ocaml:/tmpdir/loos/qp2/external/opam/4.07.1/bin:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/bin:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/bin/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/../inspector/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../advisor/bin64:/usr/local/intel/2018.2.046/compilers_and_libraries/../vtune_amplifier/bin64/:/usr/lib64/qt4/bin:/usr/lpp/mmfs/bin/:/usr/local/bin:/usr/bin:/usr/local/sbin:/usr/sbin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/users/p18005/loos/.local/bin:/users/p18005/loos/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin:/tmpdir/loos/qp2/external/irpf90-v1.7.6/bin +++++ qp_prepend_export LD_LIBRARY_PATH /tmpdir/loos/qp2/lib +++++ eval 'value_1=${LD_LIBRARY_PATH}' ++++++ value_1=/tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib +++++ [[ -z /tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib ]] +++++ echo /tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib ++++ export LD_LIBRARY_PATH=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib ++++ LD_LIBRARY_PATH=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64:/usr/local/lib64:/usr/local/lib +++++ qp_prepend_export LIBRARY_PATH /tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64 +++++ eval 'value_1=${LIBRARY_PATH}' ++++++ value_1=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 +++++ [[ -z /tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 ]] +++++ echo /tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 ++++ export LIBRARY_PATH=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 ++++ LIBRARY_PATH=/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/tmpdir/loos/qp2/lib:/tmpdir/loos/qp2/lib64:/usr/local/intel/2018.2.046/impi/2018.2.199/intel64/lib:/usr/local/intel/2018.2.046/compilers_and_libraries/../mkl/lib/intel64:/usr/local/intel/2018.2.046/compilers_and_libraries/linux/lib/intel64 +++++ qp_prepend_export C_INCLUDE_PATH /tmpdir/loos/qp2/include +++++ eval 'value_1=${C_INCLUDE_PATH}' ++++++ value_1=/tmpdir/loos/qp2/include: +++++ [[ -z /tmpdir/loos/qp2/include: ]] +++++ echo /tmpdir/loos/qp2/include:/tmpdir/loos/qp2/include: ++++ export C_INCLUDE_PATH=/tmpdir/loos/qp2/include:/tmpdir/loos/qp2/include: ++++ C_INCLUDE_PATH=/tmpdir/loos/qp2/include:/tmpdir/loos/qp2/include: +++ for SCRIPT in '*.rc' +++ source qp.rc +++++ ps -p 61524 -ocomm= ++++ [[ slurm_script == \z\s\h ]] ++++ source /tmpdir/loos/qp2/etc/ezfio.rc +++++ export QP_EZFIO=/tmpdir/loos/qp2/external/ezfio +++++ QP_EZFIO=/tmpdir/loos/qp2/external/ezfio +++++ source /tmpdir/loos/qp2/etc/autocomplete.rc +++++++ ps -p 61524 -ocomm= ++++++ [[ slurm_script == \z\s\h ]] +++++ source_if_exists /tmpdir/loos/qp2/external/ezfio/Bash/ezfio.sh ++++ complete -F _qp_Complete qp +++ cd /users/p18005/loos/tmpdir/Ec/furan/6-31g +++ [[ -z /tmpdir/loos/qp2 ]] ++ set -e ++ ./localize.sh furan.ang /tmpdir/loos/qp2/data/basis/6-31g furan + +Orbital localization + +Method : Boys_er +Separation type : Sigma/pi +Max number of iterations : 1000000 +cc : 1e-05 +epsilon : 1. +charge : 0 +Rotation pre angle : 0.001 + +Criterion max_angle norm_angle average_angle + +Orbital lists: +Core: [1,2,3,4,5,] +Occupied: [6,7,8,9,10,11,12,13,14,15,16,17,18,] +Virtual: [19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,] +Sigma occ: [6,7,8,9,10,11,12,13,15,16,] +Pi occ: [14,17,18,] +Sigma vir: [21,22,23,24,25,26,27,28,29,31,34,35,36,37,38,40,42,43,44,45,46,47,48,49,50,51,52,53,] +Pi vir: [19,20,30,32,33,39,41,] + +0 20.750954 0.784669 1.109854 0.004188 +1 24.415089 0.784667 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336.326550 -0.000010 0.000101 0.000000 +1204 336.326550 -0.000010 0.000100 0.000000 +1205 336.326550 0.000010 0.000099 0.000000 + +Number of molecular orbitals : 53 +Number of pi orbitals : 10 +Number of occupied pi orbitals : 3 +Number of virtual pi orbitals : 7 +Number of sigma orbitals : 43 +Number of occupied sigma orbitals : 10 +Number of virtual sigma orbitals : 28 + +All MOs before the localization Average : 11.5154533906; Median : 9.86499551399; Variance : 54.5868754974; Standard deviation : 7.38829313829 +All MOs after the localization Average : 3.93074450732; Median : 3.15205123519; Variance : 5.6401367718; Standard deviation : 2.37489721289 + +Distribution of the spatial extent, before localization / sorting before localization / after localization / sorting after localization = + + + + -- 1 -- -- 2 -- -- 3 -- -- 4 -- + 1 0.0532269 0.0532269 0.0532278 0.0532278 + 2 4.35596 1.93082 0.0976874 0.0976868 + 3 4.35598 1.93111 0.0976868 0.0976874 + 4 1.93082 2.846 0.0977314 0.0977307 + 5 1.93111 4.07615 0.0977307 0.0977314 + 6 2.846 4.35596 1.61132 1.61132 + 7 6.19971 4.35598 2.30378 1.73176 + 8 10.0721 4.70206 2.30411 1.73191 + 9 9.42779 4.70841 2.01216 1.98538 + 10 12.4244 5.10446 2.22566 1.98539 + 11 13.3023 5.25061 1.73191 1.99168 + 12 9.31712 5.88412 2.01115 1.99168 + 13 7.95699 6.19971 1.73176 2.01115 + 14 4.07615 6.84906 2.28877 2.01216 + 15 7.91005 7.30468 2.22839 2.22566 + 16 5.88412 7.36418 3.15205 2.22839 + 17 7.36418 7.53056 5.65809 2.28877 + 18 8.71034 7.72784 5.65809 2.30378 + 19 7.8669 7.76408 6.65679 2.30411 + 20 7.30468 7.8669 6.65676 2.33266 + 21 5.10446 7.91005 4.17842 2.33266 + 22 4.70841 7.95699 7.16373 2.47478 + 23 6.84906 8.71034 7.16376 2.47478 + 24 7.76408 9.31712 7.30261 2.64836 + 25 15.2063 9.42779 7.30261 3.07736 + 26 10.0579 9.86309 2.47478 3.07738 + 27 12.0375 9.865 2.47478 3.15205 + 28 13.7553 9.91727 2.64836 3.55592 + 29 9.86309 10.0579 2.33266 4.17842 + 30 4.70206 10.0721 1.98538 5.20445 + 31 5.25061 10.1389 2.33266 5.20446 + 32 9.865 11.7545 1.98539 5.205 + 33 12.9658 12.0375 1.99168 5.20503 + 34 10.1389 12.4244 1.99168 5.29762 + 35 15.657 12.9658 3.07736 5.29764 + 36 7.72784 13.3023 5.29764 5.56748 + 37 11.7545 13.7553 5.61329 5.56749 + 38 7.53056 14.4899 5.20503 5.5911 + 39 15.1904 15.089 8.14628 5.59117 + 40 17.8249 15.1904 3.07738 5.61329 + 41 15.4637 15.2063 5.56749 5.61331 + 42 9.91727 15.4637 3.55592 5.65809 + 43 18.3947 15.6174 5.205 5.65809 + 44 15.089 15.657 8.14634 6.65676 + 45 21.0681 17.8249 5.61331 6.65679 + 46 20.5452 18.3947 5.29762 7.16373 + 47 21.3153 20.5452 5.56748 7.16376 + 48 14.4899 21.0681 7.68237 7.30261 + 49 28.7301 21.3153 5.20446 7.30261 + 50 15.6174 28.7301 7.6824 7.68237 + 51 29.0014 29.0014 5.20445 7.6824 + 52 30.799 30.799 5.59117 8.14628 + 53 32.6446 32.6446 5.5911 8.14634 + + +Occupied orbitals : Number of molecular orbitals : 13 +Occupied orbitals before localization Average : 8.11471291942; Median : 7.95698913741; Variance : 8.84856814893; Standard deviation : 2.97465429066 +Occupied orbitals after localization Average : 2.68594159349; Median : 2.22838991917; Variance : 1.8866785766; Standard deviation : 1.37356418729 + + +Core orbitals : Number of molecular orbitals : 5 +Core orbitalses before localization : Average : 8.19400792036; Median : 9.42779211847; Variance : 13.8810959288; Standard deviation : 3.72573428049 +Core orbitals after localization : Average : 2.0914060969; Median : 2.22566102379; Variance : 0.0862845421955; Standard deviation : 0.293742305764 + + +Valence orbitals : Number of molecular orbitals : 8 +Valence orbitals before localization : Average : 8.06515354383; Median : 7.93351758067; Variance : 7.22962093321; Standard deviation : 2.6887954428 +Valence rbitals after localization : Average : 3.05752627887; Median : 2.25857944927; Variance : 2.77472014852; Standard deviation : 1.66574912532 + + +Virtual orbitals : Number of molecular orbitals : 40 +Virtual orbitals before localization : Average : 12.6206940437; Median : 10.9466814211; Variance : 64.9519735191; Standard deviation : 8.05927872202 +Virtual orbitals after localization : Average : 4.33530545432; Median : 5.20473129112; Variance : 6.25528823065; Standard deviation : 2.5010574225 + ++ qp set_file furan.localized ++ case $1 in ++ [[ -d furan.localized ]] ++ ezfio set_file furan.localized ++ case $1 in ++ shift ++ _ezfio_set_file furan.localized ++ _require_first_argument furan.localized ++ [[ -z furan.localized ]] ++ return 0 ++ [[ ! -d furan.localized ]] ++ export EZFIO_FILE=furan.localized ++ EZFIO_FILE=furan.localized ++ _ezfio_info 'Set file furan.localized' ++ : ++ return 0 ++ qp set determinants n_states 1 ++ case $1 in ++ ezfio set determinants n_states 1 ++ case $1 in ++ shift ++ _ezfio_set determinants n_states 1 ++ _require_ezfio_file ++ [[ -z furan.localized ]] ++ [[ ! -d furan.localized ]] ++ _require_first_argument determinants n_states 1 ++ [[ -z determinants ]] ++ return 0 ++ _require_second_argument determinants n_states 1 ++ [[ -z n_states ]] ++ [[ -z 1 ]] ++ echo 1 ++ _ezfio_py set determinants n_states ++ python2 /tmpdir/loos/qp2/external/ezfio/Python/ezfio.py set determinants n_states ++ return 0 ++ qp set determinants read_wf False ++ case $1 in ++ ezfio set determinants read_wf False ++ case $1 in ++ shift ++ _ezfio_set determinants read_wf False ++ _require_ezfio_file ++ [[ -z furan.localized ]] ++ [[ ! -d furan.localized ]] ++ _require_first_argument determinants read_wf False ++ [[ -z determinants ]] ++ return 0 ++ _require_second_argument determinants read_wf False ++ [[ -z read_wf ]] ++ [[ -z False ]] ++ echo False ++ _ezfio_py set determinants read_wf ++ python2 /tmpdir/loos/qp2/external/ezfio/Python/ezfio.py set determinants read_wf ++ return 0 ++ qp set determinants s2_eig False ++ case $1 in ++ ezfio set determinants s2_eig False ++ case $1 in ++ shift ++ _ezfio_set determinants s2_eig False ++ _require_ezfio_file ++ [[ -z furan.localized ]] ++ [[ ! -d furan.localized ]] ++ _require_first_argument determinants s2_eig False ++ [[ -z determinants ]] ++ return 0 ++ _require_second_argument determinants s2_eig False ++ [[ -z s2_eig ]] ++ [[ -z False ]] ++ _ezfio_py set determinants s2_eig ++ echo False ++ python2 /tmpdir/loos/qp2/external/ezfio/Python/ezfio.py set determinants s2_eig ++ return 0 ++ qp set determinants n_det_max 1e8 ++ case $1 in ++ ezfio set determinants n_det_max 1e8 ++ case $1 in ++ shift ++ _ezfio_set determinants n_det_max 1e8 ++ _require_ezfio_file ++ [[ -z furan.localized ]] ++ [[ ! -d furan.localized ]] ++ _require_first_argument determinants n_det_max 1e8 ++ [[ -z determinants ]] ++ return 0 ++ _require_second_argument determinants n_det_max 1e8 ++ [[ -z n_det_max ]] ++ [[ -z 1e8 ]] ++ _ezfio_py set determinants n_det_max ++ echo 1e8 ++ python2 /tmpdir/loos/qp2/external/ezfio/Python/ezfio.py set determinants n_det_max ++ return 0 ++ qp run fci ++ case $1 in ++ which qp_run ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' furan.localized +++ qp_run fci furan.localized + 0.07 % in 1 seconds + 50.00 % in 3 seconds + 16.67 % in 2 seconds + 9.09 % in 3 seconds + 4.76 % in 2 seconds + 2.44 % in 2 seconds + 1.23 % in 2 seconds + 0.62 % in 2 seconds + 0.31 % in 2 seconds + 0.16 % in 2 seconds + 0.08 % in 3 seconds + 0.04 % in 3 seconds + 0.02 % in 3 seconds + 0.01 % in 2 seconds + 0.00 % in 3 seconds + 0.00 % in 3 seconds + 9.03 % in 13 seconds + 0.00 % in 2 seconds + 4.27 % in 12 seconds + 8.71 % in 22 seconds +13.44 % in 32 seconds + 16.67 % in 3 seconds + 16.67 % in 2 seconds + 16.67 % in 2 seconds + 16.67 % in 3 seconds + 16.67 % in 3 seconds + 16.67 % in 3 seconds + 16.67 % in 3 seconds + 16.67 % in 3 seconds + 16.67 % in 2 seconds + 16.67 % in 3 seconds + 0.00 % in 3 seconds + 2.05 % in 13 seconds + 4.01 % in 23 seconds + 5.76 % in 33 seconds + 7.66 % in 43 seconds + 9.59 % in 53 seconds +11.35 % in 63 seconds + 10.00 % in 3 seconds + 10.00 % in 3 seconds + 10.00 % in 2 seconds + 10.00 % in 3 seconds + 10.00 % in 3 seconds + 10.00 % in 3 seconds + 10.00 % in 3 seconds + 10.00 % in 3 seconds + 10.00 % in 3 seconds + 10.00 % in 3 seconds + 0.00 % in 4 seconds + 0.94 % in 14 seconds + 2.07 % in 24 seconds + 2.91 % in 34 seconds + 3.58 % in 44 seconds + 4.30 % in 54 seconds + 4.95 % in 64 seconds + 5.65 % in 74 seconds + 6.30 % in 84 seconds + 7.02 % in 94 seconds + 7.67 % in 104 seconds + 8.31 % in 114 seconds + 8.95 % in 124 seconds + 5.56 % in 3 seconds + 5.56 % in 2 seconds + 5.56 % in 3 seconds + 5.56 % in 3 seconds + 5.56 % in 3 seconds + 5.56 % in 3 seconds + 5.56 % in 3 seconds + 5.56 % in 3 seconds + 5.56 % in 3 seconds + 5.56 % in 3 seconds + 0.00 % in 5 seconds + 0.32 % in 15 seconds + 0.94 % in 25 seconds + 1.58 % in 35 seconds + 2.06 % in 45 seconds + 2.35 % in 55 seconds + 2.75 % in 65 seconds + 3.03 % in 75 seconds + 3.34 % in 85 seconds + 3.62 % in 95 seconds + 3.92 % in 106 seconds + 4.26 % in 116 seconds + 4.52 % in 126 seconds + 4.83 % in 137 seconds + 5.16 % in 147 seconds + 5.43 % in 157 seconds + 5.74 % in 167 seconds + 5.99 % in 177 seconds + 6.28 % in 187 seconds + 6.53 % in 197 seconds + 6.78 % in 207 seconds + 7.05 % in 217 seconds + 7.28 % in 227 seconds + 7.49 % in 237 seconds + 7.78 % in 247 seconds + 7.95 % in 259 seconds + 2.94 % in 4 seconds + 2.94 % in 5 seconds + 2.94 % in 4 seconds + 2.94 % in 4 seconds + 2.94 % in 4 seconds + 2.94 % in 3 seconds + 2.94 % in 4 seconds + 2.94 % in 4 seconds + 2.94 % in 4 seconds + 0.00 % in 7 seconds + 0.15 % in 17 seconds + 0.33 % in 29 seconds + 0.66 % in 45 seconds + 1.12 % in 55 seconds + 1.25 % in 66 seconds + 1.66 % in 76 seconds + 1.80 % in 86 seconds + 2.04 % in 96 seconds + 2.19 % in 107 seconds + 2.28 % in 117 seconds + 2.41 % in 127 seconds + 2.59 % in 137 seconds + 2.74 % in 147 seconds + 2.90 % in 157 seconds + 3.04 % in 167 seconds + 3.10 % in 177 seconds + 3.22 % in 188 seconds + 3.39 % in 198 seconds + 3.48 % in 208 seconds + 3.63 % in 218 seconds + 3.71 % in 228 seconds + 3.86 % in 238 seconds + 3.96 % in 248 seconds + 4.04 % in 258 seconds + 4.17 % in 268 seconds + 4.28 % in 278 seconds + 4.39 % in 288 seconds + 4.49 % in 298 seconds + 4.61 % in 308 seconds + 4.74 % in 318 seconds + 4.80 % in 328 seconds + 4.90 % in 338 seconds + 5.01 % in 348 seconds + 5.13 % in 358 seconds + 5.21 % in 368 seconds + 5.33 % in 378 seconds + 5.42 % in 388 seconds + 5.54 % in 398 seconds + 5.62 % in 408 seconds + 5.71 % in 418 seconds + 5.79 % in 428 seconds + 5.87 % in 438 seconds + 5.96 % in 448 seconds + 6.06 % in 458 seconds + 6.17 % in 472 seconds + 1.49 % in 5 seconds +28.36 % in 15 seconds +82.09 % in 25 seconds + 1.49 % in 5 seconds +31.34 % in 15 seconds +83.58 % in 25 seconds + 1.49 % in 5 seconds +32.84 % in 15 seconds +86.57 % in 25 seconds + 1.49 % in 5 seconds +32.84 % in 15 seconds +85.07 % in 25 seconds + 1.49 % in 5 seconds +31.34 % in 15 seconds +85.07 % in 25 seconds + 1.49 % in 4 seconds +28.36 % in 14 seconds +82.09 % in 24 seconds + 1.49 % in 5 seconds +28.36 % in 15 seconds +82.09 % in 25 seconds + 1.49 % in 5 seconds +32.84 % in 15 seconds +86.57 % in 25 seconds + 1.49 % in 5 seconds +29.85 % in 15 seconds +83.58 % in 25 seconds + 0.00 % in 10 seconds + 0.04 % in 20 seconds + 0.11 % in 30 seconds + 0.17 % in 40 seconds + 0.32 % in 50 seconds + 0.33 % in 60 seconds + 0.49 % in 70 seconds + 0.65 % in 81 seconds + 0.66 % in 96 seconds + 0.79 % in 106 seconds + 1.07 % in 116 seconds + 1.10 % in 126 seconds + 1.15 % in 136 seconds + 1.33 % in 146 seconds + 1.45 % in 157 seconds + 1.47 % in 168 seconds + 1.66 % in 178 seconds + 1.78 % in 191 seconds + 1.81 % in 201 seconds + 1.96 % in 211 seconds + 2.08 % in 222 seconds + 2.12 % in 233 seconds + 2.18 % in 243 seconds + 2.29 % in 253 seconds + 2.35 % in 263 seconds + 2.39 % in 273 seconds + 2.44 % in 283 seconds + 2.51 % in 293 seconds + 2.58 % in 303 seconds + 2.64 % in 313 seconds + 2.71 % in 323 seconds + 2.77 % in 333 seconds + 2.82 % in 343 seconds + 2.90 % in 353 seconds + 2.96 % in 363 seconds + 3.00 % in 373 seconds + 3.05 % in 383 seconds + 3.09 % in 394 seconds + 3.13 % in 404 seconds + 3.17 % in 414 seconds + 3.24 % in 424 seconds + 3.26 % in 434 seconds + 3.30 % in 444 seconds + 3.36 % in 454 seconds + 3.40 % in 464 seconds + 3.44 % in 474 seconds + 3.48 % in 484 seconds + 3.54 % in 494 seconds + 3.58 % in 504 seconds + 3.62 % in 514 seconds + 3.66 % in 524 seconds + 3.70 % in 534 seconds + 3.74 % in 544 seconds + 3.78 % in 554 seconds + 3.82 % in 564 seconds + 3.86 % in 575 seconds + 3.90 % in 585 seconds + 3.94 % in 595 seconds + 3.98 % in 605 seconds + 4.03 % in 615 seconds + 4.07 % in 625 seconds + 4.10 % in 636 seconds + 4.15 % in 646 seconds + 4.18 % in 656 seconds + 4.24 % in 666 seconds + 4.26 % in 676 seconds + 4.30 % in 686 seconds + 4.33 % in 696 seconds + 4.37 % in 706 seconds + 4.41 % in 716 seconds + 4.44 % in 726 seconds + 4.49 % in 737 seconds + 4.53 % in 747 seconds + 4.56 % in 758 seconds + 4.61 % in 768 seconds + 4.64 % in 778 seconds + 4.67 % in 789 seconds + 4.71 % in 800 seconds + 4.74 % in 810 seconds + 4.77 % in 820 seconds + 4.81 % in 830 seconds + 4.85 % in 840 seconds + 4.87 % in 857 seconds + 4.93 % in 867 seconds + 4.96 % in 877 seconds + 4.98 % in 891 seconds + 0.75 % in 9 seconds + 3.01 % in 19 seconds +12.78 % in 29 seconds +26.32 % in 39 seconds +45.11 % in 49 seconds +63.16 % in 59 seconds +81.95 % in 69 seconds + 0.75 % in 9 seconds + 3.01 % in 19 seconds +12.78 % in 29 seconds +26.32 % in 39 seconds +45.11 % in 49 seconds +63.16 % in 59 seconds +81.95 % in 69 seconds + 0.75 % in 8 seconds + 3.76 % in 18 seconds +12.78 % in 28 seconds +27.07 % in 38 seconds +45.86 % in 48 seconds +63.91 % in 58 seconds +83.46 % in 68 seconds + 0.75 % in 8 seconds + 3.01 % in 18 seconds +12.78 % in 28 seconds +26.32 % in 38 seconds +45.11 % in 48 seconds +63.16 % in 58 seconds +82.71 % in 68 seconds + 0.75 % in 8 seconds + 3.01 % in 18 seconds +12.03 % in 28 seconds +26.32 % in 38 seconds +44.36 % in 48 seconds +61.65 % in 58 seconds +81.20 % in 68 seconds + 0.75 % in 8 seconds + 3.01 % in 18 seconds +12.78 % in 29 seconds +28.57 % in 39 seconds +46.62 % in 49 seconds +65.41 % in 59 seconds +84.21 % in 69 seconds + 0.75 % in 8 seconds + 3.01 % in 18 seconds +12.78 % in 28 seconds +26.32 % in 38 seconds +44.36 % in 48 seconds +62.41 % in 58 seconds +81.95 % in 68 seconds + 0.75 % in 8 seconds + 3.01 % in 18 seconds +12.78 % in 28 seconds +26.32 % in 38 seconds +45.11 % in 48 seconds +63.91 % in 58 seconds +83.46 % in 68 seconds + 0.00 % in 18 seconds + 0.01 % in 29 seconds + 0.04 % in 40 seconds + 0.08 % in 50 seconds + 0.09 % in 60 seconds + 0.14 % in 70 seconds + 0.17 % in 83 seconds + 0.18 % in 93 seconds + 0.26 % in 103 seconds + 0.30 % in 113 seconds + 0.32 % in 123 seconds + 0.41 % in 133 seconds + 0.44 % in 143 seconds + 0.47 % in 153 seconds + 0.54 % in 163 seconds + 0.60 % in 173 seconds + 0.63 % in 191 seconds + 0.70 % in 201 seconds + 0.79 % in 211 seconds + 0.82 % in 221 seconds + 0.86 % in 231 seconds + 0.93 % in 241 seconds + 0.96 % in 251 seconds + 0.97 % in 262 seconds + 1.04 % in 272 seconds + 1.11 % in 282 seconds + 1.13 % in 293 seconds + 1.16 % in 303 seconds + 1.21 % in 313 seconds + 1.26 % in 323 seconds + 1.28 % in 333 seconds + 1.36 % in 343 seconds + 1.41 % in 353 seconds + 1.43 % in 366 seconds + 1.45 % in 376 seconds + 1.53 % in 386 seconds + 1.57 % in 398 seconds + 1.59 % in 408 seconds + 1.66 % in 418 seconds + 1.69 % in 429 seconds + 1.71 % in 439 seconds + 1.76 % in 449 seconds + 1.83 % in 459 seconds + 1.86 % in 469 seconds + 1.90 % in 479 seconds + 1.95 % in 489 seconds + 1.99 % in 499 seconds + 2.00 % in 510 seconds + 2.05 % in 520 seconds + 2.09 % in 530 seconds + 2.13 % in 540 seconds + 2.14 % in 550 seconds + 2.18 % in 560 seconds + 2.23 % in 570 seconds + 2.26 % in 580 seconds + 2.28 % in 590 seconds + 2.32 % in 600 seconds + 2.34 % in 611 seconds + 2.37 % in 621 seconds + 2.41 % in 631 seconds + 2.43 % in 642 seconds + 2.46 % in 652 seconds + 2.49 % in 662 seconds + 2.51 % in 673 seconds + 2.53 % in 683 seconds + 2.56 % in 693 seconds + 2.58 % in 704 seconds + 2.61 % in 715 seconds + 2.64 % in 725 seconds + 2.69 % in 735 seconds + 2.71 % in 745 seconds + 2.74 % in 757 seconds + 2.75 % in 767 seconds + 2.77 % in 779 seconds + 2.78 % in 789 seconds + 2.79 % in 799 seconds + 2.82 % in 809 seconds + 2.84 % in 819 seconds + 2.86 % in 829 seconds + 2.88 % in 840 seconds + 2.90 % in 851 seconds + 2.92 % in 861 seconds + 2.94 % in 871 seconds + 2.96 % in 881 seconds + 2.98 % in 891 seconds + 3.00 % in 901 seconds + 3.01 % in 911 seconds + 3.03 % in 921 seconds + 3.04 % in 932 seconds + 3.06 % in 942 seconds + 3.09 % in 952 seconds + 3.10 % in 962 seconds + 3.12 % in 973 seconds + 3.13 % in 983 seconds + 3.15 % in 993 seconds + 3.17 % in 1004 seconds + 3.19 % in 1016 seconds + 3.21 % in 1026 seconds + 3.22 % in 1036 seconds + 3.24 % in 1046 seconds + 3.25 % in 1056 seconds + 3.27 % in 1066 seconds + 3.29 % in 1076 seconds + 3.30 % in 1086 seconds + 3.32 % in 1096 seconds + 3.34 % in 1106 seconds + 3.35 % in 1116 seconds + 3.37 % in 1127 seconds + 3.39 % in 1137 seconds + 3.40 % in 1147 seconds + 3.42 % in 1157 seconds + 3.43 % in 1167 seconds + 3.46 % in 1177 seconds + 3.47 % in 1187 seconds + 3.49 % in 1197 seconds + 3.50 % in 1207 seconds + 3.52 % in 1217 seconds + 3.53 % in 1228 seconds + 3.55 % in 1238 seconds + 3.57 % in 1248 seconds + 3.59 % in 1258 seconds + 3.60 % in 1269 seconds + 3.62 % in 1279 seconds + 3.63 % in 1290 seconds + 3.65 % in 1300 seconds + 3.67 % in 1310 seconds + 3.68 % in 1320 seconds + 3.69 % in 1330 seconds + 3.71 % in 1340 seconds + 3.73 % in 1350 seconds + 3.74 % in 1360 seconds + 3.76 % in 1370 seconds + 3.77 % in 1380 seconds + 3.79 % in 1390 seconds + 3.80 % in 1400 seconds + 3.82 % in 1410 seconds + 3.83 % in 1420 seconds + 3.85 % in 1430 seconds + 3.86 % in 1441 seconds + 3.88 % in 1451 seconds + 3.90 % in 1461 seconds + 3.91 % in 1471 seconds + 3.93 % in 1481 seconds + 3.94 % in 1491 seconds + 3.95 % in 1501 seconds + 3.97 % in 1512 seconds + 3.98 % in 1522 seconds + 3.99 % in 1532 seconds + 4.01 % in 1542 seconds + 4.02 % in 1552 seconds + 4.03 % in 1574 seconds + 4.07 % in 1584 seconds + 4.08 % in 1595 seconds + 4.08 % in 1606 seconds + 4.08 % in 1618 seconds + 0.38 % in 14 seconds + 0.76 % in 33 seconds + 1.14 % in 43 seconds + 2.28 % in 53 seconds + 3.80 % in 64 seconds + 6.46 % in 74 seconds + 9.13 % in 85 seconds +13.31 % in 95 seconds +17.49 % in 106 seconds +21.29 % in 116 seconds +26.24 % in 126 seconds +31.18 % in 136 seconds +36.12 % in 146 seconds +41.83 % in 156 seconds +47.53 % in 166 seconds +52.85 % in 176 seconds +58.56 % in 186 seconds +64.64 % in 196 seconds +69.58 % in 206 seconds +74.90 % in 216 seconds +80.99 % in 226 seconds +86.31 % in 237 seconds +92.40 % in 247 seconds +98.10 % in 257 seconds + 0.38 % in 15 seconds + 0.76 % in 34 seconds + 1.14 % in 44 seconds + 2.28 % in 54 seconds + 3.80 % in 65 seconds + 6.46 % in 75 seconds + 9.13 % in 86 seconds +12.93 % in 96 seconds +17.49 % in 108 seconds +22.05 % in 118 seconds +27.38 % in 128 seconds +31.56 % in 138 seconds +37.64 % in 148 seconds +42.97 % in 158 seconds +48.67 % in 168 seconds +53.99 % in 178 seconds +58.94 % in 188 seconds +65.40 % in 198 seconds +70.72 % in 208 seconds +75.67 % in 218 seconds +82.13 % in 228 seconds +86.69 % in 238 seconds +93.16 % in 248 seconds +98.86 % in 258 seconds + 0.38 % in 15 seconds + 0.76 % in 34 seconds + 1.14 % in 44 seconds + 2.28 % in 54 seconds + 3.80 % in 65 seconds + 6.46 % in 75 seconds + 9.13 % in 86 seconds +13.31 % in 96 seconds +17.49 % in 107 seconds +21.29 % in 117 seconds +26.62 % in 127 seconds +31.18 % in 137 seconds +36.88 % in 147 seconds +42.21 % in 157 seconds +48.29 % in 167 seconds +53.23 % in 177 seconds +58.94 % in 188 seconds +65.78 % in 199 seconds +71.86 % in 210 seconds +77.95 % in 220 seconds +82.89 % in 230 seconds +88.97 % in 240 seconds +94.68 % in 251 seconds + 0.38 % in 13 seconds + 0.76 % in 23 seconds + 1.14 % in 42 seconds + 2.28 % in 53 seconds + 3.80 % in 64 seconds + 6.46 % in 74 seconds + 9.13 % in 85 seconds +13.31 % in 95 seconds +17.49 % in 106 seconds +21.29 % in 116 seconds +26.62 % in 126 seconds +31.18 % in 136 seconds +37.26 % in 146 seconds +42.59 % in 156 seconds +48.67 % in 167 seconds +54.75 % in 177 seconds +59.32 % in 187 seconds +65.78 % in 198 seconds +71.86 % in 209 seconds +77.95 % in 219 seconds +82.89 % in 229 seconds +88.97 % in 239 seconds +94.68 % in 249 seconds + 0.38 % in 14 seconds + 0.76 % in 24 seconds + 1.14 % in 34 seconds + 1.52 % in 49 seconds + 3.04 % in 60 seconds + 4.94 % in 70 seconds + 7.98 % in 81 seconds +11.41 % in 93 seconds +15.21 % in 103 seconds +20.53 % in 114 seconds +23.95 % in 124 seconds +30.42 % in 134 seconds +34.98 % in 145 seconds +41.44 % in 155 seconds +46.39 % in 165 seconds +52.09 % in 175 seconds +58.56 % in 186 seconds +64.64 % in 196 seconds +69.58 % in 206 seconds +75.29 % in 217 seconds +81.75 % in 227 seconds +86.69 % in 237 seconds +92.78 % in 247 seconds +98.48 % in 257 seconds + 0.38 % in 14 seconds + 0.76 % in 24 seconds + 1.14 % in 34 seconds + 1.52 % in 48 seconds + 3.04 % in 60 seconds + 4.94 % in 70 seconds + 7.98 % in 80 seconds +11.03 % in 90 seconds +14.83 % in 101 seconds +19.39 % in 111 seconds +23.57 % in 121 seconds +28.14 % in 131 seconds +34.60 % in 142 seconds +39.16 % in 152 seconds +45.63 % in 162 seconds +50.95 % in 172 seconds +56.27 % in 182 seconds +62.74 % in 193 seconds +68.82 % in 203 seconds +74.14 % in 213 seconds +78.71 % in 223 seconds +85.17 % in 233 seconds +90.49 % in 244 seconds +96.58 % in 254 seconds + 0.38 % in 14 seconds + 0.76 % in 24 seconds + 1.14 % in 34 seconds + 1.52 % in 49 seconds + 3.04 % in 60 seconds + 4.94 % in 70 seconds + 7.98 % in 81 seconds +11.41 % in 92 seconds +14.83 % in 102 seconds +19.77 % in 112 seconds +23.57 % in 122 seconds +28.14 % in 132 seconds +34.60 % in 143 seconds +39.54 % in 153 seconds +46.01 % in 164 seconds 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seconds +97.23 % in 20384 seconds +97.38 % in 20394 seconds +97.43 % in 20415 seconds +97.47 % in 20437 seconds +97.52 % in 20461 seconds +97.57 % in 20489 seconds +97.62 % in 20516 seconds +97.67 % in 20530 seconds +97.81 % in 20540 seconds +98.06 % in 20550 seconds +98.30 % in 20563 seconds +98.49 % in 20573 seconds +98.69 % in 20583 seconds +98.88 % in 20594 seconds +99.03 % in 20604 seconds +99.22 % in 20615 seconds +99.37 % in 20625 seconds +99.51 % in 20636 seconds +99.66 % in 20648 seconds +99.81 % in 20660 seconds + \ No newline at end of file diff --git a/furan/cc-pvdz/furan.restart.slaves.out b/furan/cc-pvdz/furan.restart.slaves.out index 566a039..1e2b9f6 100644 --- a/furan/cc-pvdz/furan.restart.slaves.out +++ b/furan/cc-pvdz/furan.restart.slaves.out @@ -1,4 +1,4 @@ -Date: 08/12/2020 22:01:31 +Date: 13/12/2020 21:23:12 =============== Quantum Package =============== @@ -9,7 +9,7 @@ Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b EZFIO Dir : furan.restart -Date: 08/12/2020 22:01:31 +Date: 13/12/2020 21:23:12 =============== Quantum Package =============== @@ -20,7 +20,7 @@ Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b EZFIO Dir : furan.restart -Date: 08/12/2020 22:01:31 +Date: 13/12/2020 21:23:12 =============== Quantum Package =============== @@ -31,7 +31,7 @@ Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b EZFIO Dir : furan.restart -Date: 08/12/2020 22:01:31 +Date: 13/12/2020 21:23:12 =============== Quantum Package =============== @@ -42,7 +42,7 @@ Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b EZFIO Dir : furan.restart -Date: 08/12/2020 22:01:31 +Date: 13/12/2020 21:23:12 =============== Quantum Package =============== @@ -53,7 +53,7 @@ Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b EZFIO Dir : furan.restart -Date: 08/12/2020 22:01:31 +Date: 13/12/2020 21:23:12 =============== Quantum Package =============== @@ -64,7 +64,7 @@ Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b EZFIO Dir : furan.restart -Date: 08/12/2020 22:01:31 +Date: 13/12/2020 21:23:12 =============== Quantum Package =============== @@ -75,7 +75,7 @@ Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b EZFIO Dir : furan.restart -Date: 08/12/2020 22:01:31 +Date: 13/12/2020 21:23:12 =============== Quantum Package =============== @@ -86,7 +86,7 @@ Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b EZFIO Dir : furan.restart -Date: 08/12/2020 22:01:31 +Date: 13/12/2020 21:23:12 =============== Quantum Package =============== @@ -97,45 +97,45 @@ Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b EZFIO Dir : furan.restart -Task server running : tcp://172.28.0.166:41279 -Task server running : tcp://172.28.0.169:41279 -Task server running : tcp://172.28.0.170:41279 -Task server running : tcp://172.28.0.165:41279 -Task server running : tcp://172.28.0.164:41279 -Task server running : tcp://172.28.0.167:41279 -Task server running : tcp://172.28.0.163:41279 -Task server running : tcp://172.28.0.171:41279 -Task server running : tcp://172.28.0.168:41279 +Task server running : tcp://172.28.1.76:41279 +Task server running : tcp://172.28.1.71:41279 +Task server running : tcp://172.28.1.73:41279 +Task server running : tcp://172.28.1.74:41279 +Task server running : tcp://172.28.1.77:41279 +Task server running : tcp://172.28.1.78:41279 +Task server running : tcp://172.28.1.72:41279 +Task server running : tcp://172.28.1.70:41279 +Task server running : tcp://172.28.1.69:41279 MPI size: 9 * mo_num 90 .. >>>>> [ IO READ: mo_class ] <<<<< .. -.. >>>>> [ RES MEM : 0.025764 GB ] [ VIRT MEM : 5.000160 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 0.041805 s ] [ CPU TIME: 3.397149 s ] <<<<< .. +.. >>>>> [ RES MEM : 0.025757 GB ] [ VIRT MEM : 5.004066 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.081792 s ] [ CPU TIME: 4.818433 s ] <<<<< .. .. >>>>> [ IO READ: io_mo_two_e_integrals ] <<<<< .. -.. >>>>> [ RES MEM : 0.025764 GB ] [ VIRT MEM : 5.000160 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 0.056289 s ] [ CPU TIME: 4.163504 s ] <<<<< .. +.. >>>>> [ RES MEM : 0.025757 GB ] [ VIRT MEM : 5.004066 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.099814 s ] [ CPU TIME: 5.987364 s ] <<<<< .. * N_int 2 MO map initialized: 8386560 MO map initialized: 8386560 MO map initialized: 8386560 - MO map initialized: 8386560 - MO map initialized: 8386560 .. >>>>> [ IO READ: io_ao_two_e_integrals ] <<<<< .. - MO map initialized: 8386560 - MO map initialized: 8386560 - MO map initialized: 8386560 -.. >>>>> [ RES MEM : 0.025928 GB ] [ VIRT MEM : 5.000160 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 0.109132 s ] [ CPU TIME: 7.154014 s ] <<<<< .. + MO map initialized: 8386560 +.. >>>>> [ RES MEM : 0.025913 GB ] [ VIRT MEM : 5.004066 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.142726 s ] [ CPU TIME: 8.770885 s ] <<<<< .. + MO map initialized: 8386560 + MO map initialized: 8386560 + MO map initialized: 8386560 .. >>>>> [ IO READ: ao_num ] <<<<< .. + MO map initialized: 8386560 -.. >>>>> [ RES MEM : 0.025928 GB ] [ VIRT MEM : 5.000160 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 0.127321 s ] [ CPU TIME: 8.295321 s ] <<<<< .. +.. >>>>> [ RES MEM : 0.025913 GB ] [ VIRT MEM : 5.004066 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.185633 s ] [ CPU TIME: 11.554135 s ] <<<<< .. AO map initialized : 10399080 AO map initialized : 10399080 @@ -147,63 +147,63 @@ Task server running : tcp://172.28.0.168:41279 AO map initialized : 10399080 .. >>>>> [ IO READ: ao_power ] <<<<< .. -.. >>>>> [ RES MEM : 0.026169 GB ] [ VIRT MEM : 5.000160 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 0.156449 s ] [ CPU TIME: 10.096530 s ] <<<<< .. +.. >>>>> [ RES MEM : 0.026165 GB ] [ VIRT MEM : 5.004066 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.214854 s ] [ CPU TIME: 13.404733 s ] <<<<< .. .. >>>>> [ IO READ: ao_prim_num ] <<<<< .. -.. >>>>> [ RES MEM : 0.026203 GB ] [ VIRT MEM : 5.000160 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 0.183262 s ] [ CPU TIME: 11.830943 s ] <<<<< .. +.. >>>>> [ RES MEM : 0.026196 GB ] [ VIRT MEM : 5.004066 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.223797 s ] [ CPU TIME: 13.980509 s ] <<<<< .. .. >>>>> [ IO READ: ao_expo ] <<<<< .. -.. >>>>> [ RES MEM : 0.026241 GB ] [ VIRT MEM : 5.000290 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 0.192449 s ] [ CPU TIME: 12.403636 s ] <<<<< .. +.. >>>>> [ RES MEM : 0.026234 GB ] [ VIRT MEM : 5.004192 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.238457 s ] [ CPU TIME: 14.912743 s ] <<<<< .. .. >>>>> [ IO READ: ao_coef ] <<<<< .. MO map initialized: 8386560 -.. >>>>> [ RES MEM : 0.026283 GB ] [ VIRT MEM : 5.000290 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 0.204449 s ] [ CPU TIME: 13.160126 s ] <<<<< .. +.. >>>>> [ RES MEM : 0.026272 GB ] [ VIRT MEM : 5.004192 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.250284 s ] [ CPU TIME: 15.655913 s ] <<<<< .. .. >>>>> [ IO READ: ao_nucl ] <<<<< .. -.. >>>>> [ RES MEM : 0.026474 GB ] [ VIRT MEM : 5.000290 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 0.221002 s ] [ CPU TIME: 14.229901 s ] <<<<< .. +.. >>>>> [ RES MEM : 0.026463 GB ] [ VIRT MEM : 5.004192 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.277142 s ] [ CPU TIME: 17.394333 s ] <<<<< .. .. >>>>> [ IO READ: ao_integrals_threshold ] <<<<< .. + + Providing the AO integrals + Providing the AO integrals + Providing the AO integrals + Providing the AO integrals + Providing the AO integrals + Providing the AO integrals + Providing the AO integrals +.. >>>>> [ RES MEM : 0.026463 GB ] [ VIRT MEM : 5.004192 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.287152 s ] [ CPU TIME: 18.044186 s ] <<<<< .. + + Providing the AO integrals AO map initialized : 10399080 - - Providing the AO integrals - Providing the AO integrals - Providing the AO integrals - Providing the AO integrals - Providing the AO integrals - Providing the AO integrals - Providing the AO integrals - Providing the AO integrals -.. >>>>> [ RES MEM : 0.026474 GB ] [ VIRT MEM : 5.000290 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 0.232943 s ] [ CPU TIME: 15.004877 s ] <<<<< .. - Providing the AO integrals .. >>>>> [ IO READ: nucl_num ] <<<<< .. -.. >>>>> [ RES MEM : 0.027908 GB ] [ VIRT MEM : 5.144840 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 0.350777 s ] [ CPU TIME: 21.331062 s ] <<<<< .. +.. >>>>> [ RES MEM : 0.027905 GB ] [ VIRT MEM : 5.148743 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.396680 s ] [ CPU TIME: 23.348001 s ] <<<<< .. .. >>>>> [ IO READ: nucl_label ] <<<<< .. -.. >>>>> [ RES MEM : 0.028049 GB ] [ VIRT MEM : 5.144840 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 0.365031 s ] [ CPU TIME: 22.254513 s ] <<<<< .. +.. >>>>> [ RES MEM : 0.028042 GB ] [ VIRT MEM : 5.148743 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.405470 s ] [ CPU TIME: 23.925845 s ] <<<<< .. .. >>>>> [ IO READ: nucl_charge ] <<<<< .. -.. >>>>> [ RES MEM : 0.028084 GB ] [ VIRT MEM : 5.144840 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 0.556074 s ] [ CPU TIME: 35.379164 s ] <<<<< .. +.. >>>>> [ RES MEM : 0.028069 GB ] [ VIRT MEM : 5.148743 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.431249 s ] [ CPU TIME: 25.621772 s ] <<<<< .. -.. >>>>> [ RES MEM : 0.028095 GB ] [ VIRT MEM : 5.144840 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 0.576408 s ] [ CPU TIME: 36.798135 s ] <<<<< .. +.. >>>>> [ RES MEM : 0.028080 GB ] [ VIRT MEM : 5.148743 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.459298 s ] [ CPU TIME: 27.467472 s ] <<<<< .. Nuclear Coordinates (Angstroms) @@ -235,8 +235,8 @@ H 1.000000 0.000000 -1.371462 1.837134 AO integrals provided: Size of AO map : 64.4195499420166 MB Number of AO integrals : 5464954 - cpu time : 232.614977000000 s - wall time : 3.75130510330200 s ( x 62.0090796654332 ) + cpu time : 225.309616000000 s + wall time : 3.59950804710388 s ( x 62.5945582150542 ) AO -> MO integrals transformation --------------------------------- @@ -244,8 +244,8 @@ H 1.000000 0.000000 -1.371462 1.837134 AO integrals provided: Size of AO map : 64.4195499420166 MB Number of AO integrals : 5464954 - cpu time : 238.796737000000 s - wall time : 3.79143095016479 s ( x 62.9832746893678 ) + cpu time : 224.153200000000 s + wall time : 3.59974193572998 s ( x 62.2692415184325 ) AO -> MO integrals transformation --------------------------------- @@ -253,8 +253,8 @@ H 1.000000 0.000000 -1.371462 1.837134 AO integrals provided: Size of AO map : 64.4195499420166 MB Number of AO integrals : 5464954 - cpu time : 238.386204000000 s - wall time : 3.80836892127991 s ( x 62.5953548428506 ) + cpu time : 234.649263000000 s + wall time : 3.71897602081299 s ( x 63.0951266388387 ) AO -> MO integrals transformation --------------------------------- @@ -262,8 +262,8 @@ H 1.000000 0.000000 -1.371462 1.837134 AO integrals provided: Size of AO map : 64.4195499420166 MB Number of AO integrals : 5464954 - cpu time : 241.631174000000 s - wall time : 3.83727192878723 s ( x 62.9695206605719 ) + cpu time : 235.485791000000 s + wall time : 3.69731116294861 s ( x 63.6910935059628 ) AO -> MO integrals transformation --------------------------------- @@ -271,8 +271,8 @@ H 1.000000 0.000000 -1.371462 1.837134 AO integrals provided: Size of AO map : 64.4195499420166 MB Number of AO integrals : 5464954 - cpu time : 244.035661000000 s - wall time : 3.86910915374756 s ( x 63.0728292489838 ) + cpu time : 231.693310000000 s + wall time : 3.73092293739319 s ( x 62.1008029080025 ) AO -> MO integrals transformation --------------------------------- @@ -280,8 +280,8 @@ H 1.000000 0.000000 -1.371462 1.837134 AO integrals provided: Size of AO map : 64.4195499420166 MB Number of AO integrals : 5464954 - cpu time : 246.164469000000 s - wall time : 3.89270687103271 s ( x 63.2373505520835 ) + cpu time : 232.740009000000 s + wall time : 3.73602318763733 s ( x 62.2961896409389 ) AO -> MO integrals transformation --------------------------------- @@ -289,8 +289,8 @@ H 1.000000 0.000000 -1.371462 1.837134 AO integrals provided: Size of AO map : 64.4195499420166 MB Number of AO integrals : 5464954 - cpu time : 248.603740000000 s - wall time : 3.90391111373901 s ( x 63.6806865620199 ) + cpu time : 235.019798000000 s + wall time : 3.75176787376404 s ( x 62.6424144317360 ) AO -> MO integrals transformation --------------------------------- @@ -298,23 +298,23 @@ H 1.000000 0.000000 -1.371462 1.837134 AO integrals provided: Size of AO map : 64.4195499420166 MB Number of AO integrals : 5464954 - cpu time : 246.019085000000 s - wall time : 3.90534210205078 s ( x 62.9955272985713 ) - - AO -> MO integrals transformation - --------------------------------- - - AO integrals provided: - Size of AO map : 64.4195499420166 MB - Number of AO integrals : 5464954 - cpu time : 246.924485000000 s - wall time : 3.91490697860718 s ( x 63.0728868781064 ) + cpu time : 234.782031000000 s + wall time : 3.75499486923218 s ( x 62.5252601338463 ) AO -> MO integrals transformation --------------------------------- Read mo_coef .. >>>>> [ IO READ: mo_integrals_threshold ] <<<<< .. + AO integrals provided: + Size of AO map : 64.4195499420166 MB + Number of AO integrals : 5464954 + cpu time : 237.690127000000 s + wall time : 3.80013799667358 s ( x 62.5477620044482 ) + + AO -> MO integrals transformation + --------------------------------- + Buffers : 25.31765 MB / core Buffers : 25.31765 MB / core @@ -324,81 +324,80 @@ H 1.000000 0.000000 -1.371462 1.837134 Buffers : 25.31765 MB / core Buffers : 25.31765 MB / core Buffers : 25.31765 MB / core -.. >>>>> [ RES MEM : 0.104828 GB ] [ VIRT MEM : 5.279926 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 4.219722 s ] [ CPU TIME: 262.308795 s ] <<<<< .. +.. >>>>> [ RES MEM : 0.103931 GB ] [ VIRT MEM : 5.279884 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 4.126704 s ] [ CPU TIME: 255.248825 s ] <<<<< .. Buffers : 25.31765 MB / core - 23.15789 % in 2.67367506027222 s 3.30056381225586 MB - 23.15789 % in 2.67296004295349 s 3.45374298095703 MB - 11.57895 % in 2.67932510375977 s 3.14070892333984 MB - 69.47369 % in 3.88117408752441 s 123.792201995850 MB - 10.52632 % in 4.03581309318542 s 124.404022216797 MB - 1.052632 % in 4.08975791931152 s 123.915931701660 MB - 2.105263 % in 4.09280490875244 s 124.553501129150 MB - 1.052632 % in 4.11448192596436 s 123.937904357910 MB - 100.0000 % in 4.17010617256165 s 123.628456115723 MB - 90.52631 % in 4.21814322471619 s 125.997097015381 MB - 10.52632 % in 4.22074604034424 s 124.343006134033 MB - 100.0000 % in 4.22940897941589 s 123.435604095459 MB + 28.42105 % in 2.67751407623291 s 4.09926605224609 MB + 7.368421 % in 2.68257308006287 s 4.19467163085938 MB + 1.052632 % in 4.03143692016602 s 124.642059326172 MB + 1.052632 % in 4.09510493278503 s 124.027359008789 MB + 5.263158 % in 4.10759997367859 s 123.940326690674 MB + 5.263158 % in 4.12688398361206 s 123.998882293701 MB + 2.105263 % in 4.13027596473694 s 123.733245849609 MB + 90.52631 % in 4.13519001007080 s 124.733249664307 MB + 30.52632 % in 4.18051290512085 s 124.135524749756 MB + 1.052632 % in 4.22790813446045 s 123.971244812012 MB + 93.68421 % in 4.23730516433716 s 124.060947418213 MB Molecular integrals provided: - Size of MO map 122.970897674561 MB - Number of MO integrals: 6371771 - cpu time : 315.225239000000 s - wall time : 5.03277492523193 s ( x 62.6344797220339 ) + Size of MO map 123.655845642090 MB + Number of MO integrals: 6384048 + cpu time : 317.346706000000 s + wall time : 5.07938504219055 s ( x 62.4773871962934 ) Molecular integrals provided: - Size of MO map 122.997791290283 MB - Number of MO integrals: 6375229 - cpu time : 317.644864000000 s - wall time : 4.94440507888794 s ( x 64.2432929608272 ) + Size of MO map 124.628669738770 MB + Number of MO integrals: 6408132 + cpu time : 314.010389000000 s + wall time : 4.96738100051880 s ( x 63.2144763945436 ) Molecular integrals provided: - Size of MO map 123.097087860107 MB - Number of MO integrals: 6384450 - cpu time : 317.565206000000 s - wall time : 4.95791387557983 s ( x 64.0521828271695 ) + Size of MO map 123.800022125244 MB + Number of MO integrals: 6386985 + cpu time : 317.344246000000 s + wall time : 4.96642613410950 s ( x 63.8979091666086 ) Molecular integrals provided: - Size of MO map 124.242069244385 MB - Number of MO integrals: 6399643 - cpu time : 318.091321000000 s - wall time : 5.11142683029175 s ( x 62.2314143508622 ) + Size of MO map 123.718826293945 MB + Number of MO integrals: 6394020 + cpu time : 318.626403000000 s + wall time : 4.95355606079102 s ( x 64.3227610810807 ) Molecular integrals provided: - Size of MO map 125.844661712646 MB - Number of MO integrals: 6441086 - cpu time : 320.701589000000 s - wall time : 5.02751588821411 s ( x 63.7892740929598 ) - Molecular integrals provided: - Size of MO map 123.976203918457 MB - Number of MO integrals: 6386290 - cpu time : 317.049793000000 s - wall time : 5.05707979202271 s ( x 62.6942437214715 ) - Molecular integrals provided: - Size of MO map 123.569728851318 MB - Number of MO integrals: 6386579 - cpu time : 318.600239000000 s - wall time : 4.96598482131958 s ( x 64.1565068085207 ) - Molecular integrals provided: - Size of MO map 122.734958648682 MB - Number of MO integrals: 6376023 - cpu time : 319.745064000000 s - wall time : 5.00130796432495 s ( x 63.9322885694677 ) - Molecular integrals provided: - Size of MO map 123.269340515137 MB - Number of MO integrals: 6387505 - cpu time : 319.934936000000 s - wall time : 4.96101784706116 s ( x 64.4897772721228 ) + Size of MO map 123.393241882324 MB + Number of MO integrals: 6384505 + cpu time : 318.595563000000 s + wall time : 4.98159694671631 s ( x 63.9545042298147 ) .. >>>>> [ IO READ: n_states ] <<<<< .. + Molecular integrals provided: + Size of MO map 123.273822784424 MB + Number of MO integrals: 6385698 + cpu time : 320.205435000000 s + wall time : 4.98892188072205 s ( x 64.1832930351791 ) -.. >>>>> [ RES MEM : 0.837997 GB ] [ VIRT MEM : 6.089275 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 9.135292 s ] [ CPU TIME: 583.730907 s ] <<<<< .. +.. >>>>> [ RES MEM : 0.834297 GB ] [ VIRT MEM : 6.083271 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.005053 s ] [ CPU TIME: 568.709403 s ] <<<<< .. + Molecular integrals provided: + Size of MO map 124.358493804932 MB + Number of MO integrals: 6385532 + cpu time : 319.196416000000 s + wall time : 4.97301411628723 s ( x 64.1857047931138 ) + Molecular integrals provided: + Size of MO map 123.377506256104 MB + Number of MO integrals: 6391017 + cpu time : 319.891823000000 s + wall time : 4.92928504943848 s ( x 64.8961907845927 ) + Molecular integrals provided: + Size of MO map 122.834178924561 MB + Number of MO integrals: 6379459 + cpu time : 320.419112000000 s + wall time : 5.14145684242249 s ( x 62.3206849382069 ) .. >>>>> [ IO READ: distributed_davidson ] <<<<< .. -.. >>>>> [ RES MEM : 0.838234 GB ] [ VIRT MEM : 6.089275 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 9.171619 s ] [ CPU TIME: 586.303432 s ] <<<<< .. +.. >>>>> [ RES MEM : 0.834297 GB ] [ VIRT MEM : 6.083271 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.058880 s ] [ CPU TIME: 572.522599 s ] <<<<< .. .. >>>>> [ IO READ: read_wf ] <<<<< .. -.. >>>>> [ RES MEM : 0.838234 GB ] [ VIRT MEM : 6.089275 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 9.173969 s ] [ CPU TIME: 586.470658 s ] <<<<< .. +.. >>>>> [ RES MEM : 0.834297 GB ] [ VIRT MEM : 6.083271 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.061567 s ] [ CPU TIME: 572.713426 s ] <<<<< .. * Number of virtual MOs 0 Active MOs: @@ -431,48 +430,6 @@ H 1.000000 0.000000 -1.371462 1.837134 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 - Active MOs: - 6 7 8 9 10 11 - 12 13 14 15 16 17 - 18 19 20 21 22 23 - 24 25 26 27 28 29 - 30 31 32 33 34 35 - 36 37 38 39 40 41 - 42 43 44 45 46 47 - 48 49 50 51 52 53 - 54 55 56 57 58 59 - 60 61 62 63 64 65 - 66 67 68 69 70 71 - 72 73 74 75 76 77 - 78 79 80 81 82 83 - Active MOs: - 6 7 8 9 10 11 - 12 13 14 15 16 17 - 18 19 20 21 22 23 - 24 25 26 27 28 29 - 30 31 32 33 34 35 - 36 37 38 39 40 41 - 42 43 44 45 46 47 - 48 49 50 51 52 53 - 54 55 56 57 58 59 - 60 61 62 63 64 65 - 66 67 68 69 70 71 - 72 73 74 75 76 77 - 78 79 80 81 82 83 - Active MOs: - 6 7 8 9 10 11 - 12 13 14 15 16 17 - 18 19 20 21 22 23 - 24 25 26 27 28 29 - 30 31 32 33 34 35 - 36 37 38 39 40 41 - 42 43 44 45 46 47 - 48 49 50 51 52 53 - 54 55 56 57 58 59 - 60 61 62 63 64 65 - 66 67 68 69 70 71 - 72 73 74 75 76 77 - 78 79 80 81 82 83 * Number of active MOs 85 Active MOs: 6 7 8 9 10 11 @@ -501,25 +458,20 @@ H 1.000000 0.000000 -1.371462 1.837134 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 - 84 85 86 87 88 89 - 90 - 84 85 86 87 88 89 - 90 - 84 85 86 87 88 89 - 90 - 84 85 86 87 88 89 - 90 + Active MOs: + 6 7 8 9 10 11 + 12 13 14 15 16 17 + 18 19 20 21 22 23 + 24 25 26 27 28 29 + 30 31 32 33 34 35 + 36 37 38 39 40 41 + 42 43 44 45 46 47 + 48 49 50 51 52 53 + 54 55 56 57 58 59 + 60 61 62 63 64 65 + 66 67 68 69 70 71 + 72 73 74 75 76 77 78 79 80 81 82 83 - 84 85 86 87 88 89 - 90 -* Number of inactive MOs 0 - 84 85 86 87 88 89 - 90 -.. >>>>> [ IO READ: weight_selection ] <<<<< .. - -.. >>>>> [ RES MEM : 0.838234 GB ] [ VIRT MEM : 6.089275 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 9.189677 s ] [ CPU TIME: 587.583785 s ] <<<<< .. - Active MOs: 6 7 8 9 10 11 12 13 14 15 16 17 @@ -536,6 +488,53 @@ H 1.000000 0.000000 -1.371462 1.837134 78 79 80 81 82 83 84 85 86 87 88 89 90 + 78 79 80 81 82 83 + 84 85 86 87 88 89 + 90 +* Number of inactive MOs 0 + 84 85 86 87 88 89 + 90 + 84 85 86 87 88 89 + 90 + 84 85 86 87 88 89 + 90 + Active MOs: + 6 7 8 9 10 11 + 12 13 14 15 16 17 + 18 19 20 21 22 23 + 24 25 26 27 28 29 + 30 31 32 33 34 35 + 36 37 38 39 40 41 + 42 43 44 45 46 47 + 48 49 50 51 52 53 + 54 55 56 57 58 59 + 60 61 62 63 64 65 + 66 67 68 69 70 71 + 72 73 74 75 76 77 + 78 79 80 81 82 83 + 84 85 86 87 88 89 + 90 +.. >>>>> [ IO READ: weight_selection ] <<<<< .. + Active MOs: + 6 7 8 9 10 11 + 12 13 14 15 16 17 + 18 19 20 21 22 23 + 24 25 26 27 28 29 + 30 31 32 33 34 35 + 36 37 38 39 40 41 + 42 43 44 45 46 47 + 48 49 50 51 52 53 + 54 55 56 57 58 59 + 60 61 62 63 64 65 + 66 67 68 69 70 71 + 72 73 74 75 76 77 + 78 79 80 81 82 83 + 84 85 86 87 88 89 + 90 + +.. >>>>> [ RES MEM : 0.834297 GB ] [ VIRT MEM : 6.083271 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.085609 s ] [ CPU TIME: 574.416819 s ] <<<<< .. + Active MOs: 6 7 8 9 10 11 12 13 14 15 16 17 @@ -578,79 +577,79 @@ H 1.000000 0.000000 -1.371462 1.837134 # Total weight 1.000000 * mo_label Natural * Number of determinants 1 -* Dimension of the psi arrays 41919613 +* Dimension of the psi arrays 83664815 Using pt2-matching weight in selection # PT2 weight 1.000000 # Total weight 1.000000 .. >>>>> [ IO READ: elec_beta_num ] <<<<< .. -.. >>>>> [ RES MEM : 1.150654 GB ] [ VIRT MEM : 6.401779 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 9.679242 s ] [ CPU TIME: 595.659174 s ] <<<<< .. +.. >>>>> [ RES MEM : 1.457840 GB ] [ VIRT MEM : 6.706810 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.901006 s ] [ CPU TIME: 582.469717 s ] <<<<< .. .. >>>>> [ IO READ: elec_alpha_num ] <<<<< .. -.. >>>>> [ RES MEM : 1.150654 GB ] [ VIRT MEM : 6.401779 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 9.688203 s ] [ CPU TIME: 595.659798 s ] <<<<< .. +.. >>>>> [ RES MEM : 1.457840 GB ] [ VIRT MEM : 6.706810 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 9.908194 s ] [ CPU TIME: 582.470366 s ] <<<<< .. .. >>>>> [ IO READ: weight_one_e_dm ] <<<<< .. -.. >>>>> [ RES MEM : 2.399868 GB ] [ VIRT MEM : 7.651295 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 11.070096 s ] [ CPU TIME: 597.032294 s ] <<<<< .. +.. >>>>> [ RES MEM : 3.951118 GB ] [ VIRT MEM : 9.200466 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12.649691 s ] [ CPU TIME: 585.190691 s ] <<<<< .. .. >>>>> [ IO READ: threshold_generators ] <<<<< .. -.. >>>>> [ RES MEM : 4.742531 GB ] [ VIRT MEM : 9.994576 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 12.978188 s ] [ CPU TIME: 612.309089 s ] <<<<< .. +.. >>>>> [ RES MEM : 8.626385 GB ] [ VIRT MEM : 13.876755 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.344888 s ] [ CPU TIME: 602.277706 s ] <<<<< .. -.. >>>>> [ RES MEM : 4.742531 GB ] [ VIRT MEM : 9.994576 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 12.978383 s ] [ CPU TIME: 612.309232 s ] <<<<< .. +.. >>>>> [ RES MEM : 8.626385 GB ] [ VIRT MEM : 13.876755 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.345095 s ] [ CPU TIME: 602.277861 s ] <<<<< .. * Number of generators 1 -.. >>>>> [ RES MEM : 4.742531 GB ] [ VIRT MEM : 9.994576 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 12.978772 s ] [ CPU TIME: 612.309541 s ] <<<<< .. +.. >>>>> [ RES MEM : 8.626385 GB ] [ VIRT MEM : 13.876755 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.345292 s ] [ CPU TIME: 602.277998 s ] <<<<< .. * Number of selectors 1 .. >>>>> [ IO READ: h0_type ] <<<<< .. -.. >>>>> [ RES MEM : 4.742531 GB ] [ VIRT MEM : 11.556595 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 13.010908 s ] [ CPU TIME: 612.311115 s ] <<<<< .. +.. >>>>> [ RES MEM : 8.626385 GB ] [ VIRT MEM : 16.993950 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.388349 s ] [ CPU TIME: 602.279389 s ] <<<<< .. .. >>>>> [ IO READ: io_nuclear_repulsion ] <<<<< .. -.. >>>>> [ RES MEM : 4.742531 GB ] [ VIRT MEM : 11.556595 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 13.018635 s ] [ CPU TIME: 612.311795 s ] <<<<< .. +.. >>>>> [ RES MEM : 8.626385 GB ] [ VIRT MEM : 16.993950 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.412273 s ] [ CPU TIME: 602.280156 s ] <<<<< .. -.. >>>>> [ RES MEM : 4.742531 GB ] [ VIRT MEM : 11.556595 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 13.018829 s ] [ CPU TIME: 612.311928 s ] <<<<< .. +.. >>>>> [ RES MEM : 8.626385 GB ] [ VIRT MEM : 16.993950 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.412466 s ] [ CPU TIME: 602.280289 s ] <<<<< .. * Nuclear repulsion energy 161.1082298389516 .. >>>>> [ IO READ: n_det_max_full ] <<<<< .. -.. >>>>> [ RES MEM : 4.742531 GB ] [ VIRT MEM : 11.556595 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 13.024599 s ] [ CPU TIME: 612.312506 s ] <<<<< .. +.. >>>>> [ RES MEM : 8.626385 GB ] [ VIRT MEM : 16.993950 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.419080 s ] [ CPU TIME: 602.280860 s ] <<<<< .. .. >>>>> [ IO READ: io_mo_integrals_e_n ] <<<<< .. -.. >>>>> [ RES MEM : 5.365528 GB ] [ VIRT MEM : 13.442467 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 13.432384 s ] [ CPU TIME: 638.326698 s ] <<<<< .. +.. >>>>> [ RES MEM : 9.219585 GB ] [ VIRT MEM : 18.879822 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.829567 s ] [ CPU TIME: 627.528310 s ] <<<<< .. .. >>>>> [ IO READ: io_ao_integrals_e_n ] <<<<< .. -.. >>>>> [ RES MEM : 5.365528 GB ] [ VIRT MEM : 13.442467 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 13.457606 s ] [ CPU TIME: 638.755580 s ] <<<<< .. +.. >>>>> [ RES MEM : 9.219585 GB ] [ VIRT MEM : 18.879822 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.858672 s ] [ CPU TIME: 628.022991 s ] <<<<< .. .. >>>>> [ IO READ: io_mo_integrals_kinetic ] <<<<< .. -.. >>>>> [ RES MEM : 5.368042 GB ] [ VIRT MEM : 13.508686 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 13.537144 s ] [ CPU TIME: 643.422332 s ] <<<<< .. +.. >>>>> [ RES MEM : 9.222824 GB ] [ VIRT MEM : 18.946041 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.922981 s ] [ CPU TIME: 632.308175 s ] <<<<< .. .. >>>>> [ IO READ: io_ao_integrals_kinetic ] <<<<< .. -.. >>>>> [ RES MEM : 5.368042 GB ] [ VIRT MEM : 13.508686 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 13.550813 s ] [ CPU TIME: 644.389994 s ] <<<<< .. +.. >>>>> [ RES MEM : 9.222824 GB ] [ VIRT MEM : 18.946041 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.929984 s ] [ CPU TIME: 632.783151 s ] <<<<< .. .. >>>>> [ IO READ: io_mo_one_e_integrals ] <<<<< .. @@ -658,29 +657,37 @@ H 1.000000 0.000000 -1.371462 1.837134 Providing the one-electron integrals Providing the one-electron integrals Providing the one-electron integrals -.. >>>>> [ RES MEM : 5.368252 GB ] [ VIRT MEM : 13.508686 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 13.572065 s ] [ CPU TIME: 645.835300 s ] <<<<< .. + Providing the one-electron integrals + Providing the one-electron integrals + Providing the one-electron integrals + Providing the one-electron integrals +.. >>>>> [ RES MEM : 9.223293 GB ] [ VIRT MEM : 18.946041 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.954694 s ] [ CPU TIME: 634.442988 s ] <<<<< .. Providing the one-electron integrals - Providing the one-electron integrals - Providing the one-electron integrals .. >>>>> [ IO READ: do_pseudo ] <<<<< .. -.. >>>>> [ RES MEM : 5.368252 GB ] [ VIRT MEM : 13.508686 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 13.605925 s ] [ CPU TIME: 648.176245 s ] <<<<< .. +.. >>>>> [ RES MEM : 9.223293 GB ] [ VIRT MEM : 18.946041 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 16.988733 s ] [ CPU TIME: 636.773912 s ] <<<<< .. * PT2 Energy denominator -228.6415303935705 .. >>>>> [ IO READ: threshold_davidson ] <<<<< .. -.. >>>>> [ RES MEM : 5.368431 GB ] [ VIRT MEM : 13.508686 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 13.619932 s ] [ CPU TIME: 649.153761 s ] <<<<< .. +.. >>>>> [ RES MEM : 9.223469 GB ] [ VIRT MEM : 18.946041 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 17.002060 s ] [ CPU TIME: 637.690844 s ] <<<<< .. -.. >>>>> [ RES MEM : 5.368431 GB ] [ VIRT MEM : 13.508686 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 13.634444 s ] [ CPU TIME: 650.166903 s ] <<<<< .. +.. >>>>> [ RES MEM : 9.223469 GB ] [ VIRT MEM : 18.946041 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 17.009192 s ] [ CPU TIME: 638.188959 s ] <<<<< .. Read n_states_diag .. >>>>> [ IO READ: s2_eig ] <<<<< .. + Diagonalization of H using Lapack + + Diagonalization of H using Lapack + Diagonalization of H using Lapack +.. >>>>> [ RES MEM : 9.223469 GB ] [ VIRT MEM : 18.946041 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 17.011987 s ] [ CPU TIME: 638.383547 s ] <<<<< .. Diagonalization of H using Lapack Diagonalization of H using Lapack @@ -688,94 +695,85 @@ H 1.000000 0.000000 -1.371462 1.837134 Diagonalization of H using Lapack Diagonalization of H using Lapack Diagonalization of H using Lapack -.. >>>>> [ RES MEM : 5.368431 GB ] [ VIRT MEM : 13.508686 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 13.637083 s ] [ CPU TIME: 650.350689 s ] <<<<< .. - Diagonalization of H using Lapack - -.. >>>>> [ RES MEM : 5.369251 GB ] [ VIRT MEM : 13.508686 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 13.639354 s ] [ CPU TIME: 650.503501 s ] <<<<< .. +.. >>>>> [ RES MEM : 9.223904 GB ] [ VIRT MEM : 18.946041 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 17.014383 s ] [ CPU TIME: 638.550403 s ] <<<<< .. * Energy of state 1 -228.6415303935705 * S^2 of state 1 0.000000000000000 - Providing the one-electron integrals - Providing the one-electron integrals .. >>>>> [ IO READ: pseudo_sym ] <<<<< .. - Diagonalization of H using Lapack - Diagonalization of H using Lapack - Switched to qp_run master : tcp://172.28.0.162:41279 - Switched to qp_run master : tcp://172.28.0.162:41279 - Switched to qp_run master : tcp://172.28.0.162:41279 - Switched to qp_run master : tcp://172.28.0.162:41279 - Switched to qp_run master : tcp://172.28.0.162:41279 - Switched to qp_run master : tcp://172.28.0.162:41279 - Switched to qp_run master : tcp://172.28.0.162:41279 - Switched to qp_run master : tcp://172.28.0.162:41279 -.. >>>>> [ RES MEM : 5.386669 GB ] [ VIRT MEM : 15.088318 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 13.662841 s ] [ CPU TIME: 652.155753 s ] <<<<< .. + Switched to qp_run master : tcp://172.28.1.68:41279 +.. >>>>> [ RES MEM : 9.243164 GB ] [ VIRT MEM : 22.086720 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 17.032365 s ] [ CPU TIME: 639.776420 s ] <<<<< .. - Switched to qp_run master : tcp://172.28.0.162:41279 + Switched to qp_run master : tcp://172.28.1.68:41279 + Switched to qp_run master : tcp://172.28.1.68:41279 + Switched to qp_run master : tcp://172.28.1.68:41279 + Switched to qp_run master : tcp://172.28.1.68:41279 + Switched to qp_run master : tcp://172.28.1.68:41279 + Switched to qp_run master : tcp://172.28.1.68:41279 + Switched to qp_run master : tcp://172.28.1.68:41279 + Switched to qp_run master : tcp://172.28.1.68:41279 davidson.00000002 -* Broadcast time 6.522017002105713 +* Broadcast time 12.33332610130310 -.. >>>>> [ RES MEM : 5.386559 GB ] [ VIRT MEM : 16.650337 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 400.695302 s ] [ CPU TIME: 668.310423 s ] <<<<< .. +.. >>>>> [ RES MEM : 9.243275 GB ] [ VIRT MEM : 25.203915 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 881.282447 s ] [ CPU TIME: 660.219700 s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 3100701 -* Number of unique alpha determinants 3138402 - 1 : Davidson done - 5 : Davidson done - 4 : Davidson done - 3 : Davidson done - 2 : Davidson done - 6 : Davidson done - 8 : Davidson done - 7 : Davidson done +* Number of unique beta determinants 4572338 +* Number of unique alpha determinants 4612009 0 : Davidson done + 8 : Davidson done + 5 : Davidson done + 7 : Davidson done + 1 : Davidson done + 3 : Davidson done + 4 : Davidson done + 6 : Davidson done + 2 : Davidson done ---------- davidson.00000003 -* Broadcast time 6.623932123184204 +* Broadcast time 13.49100708961487 -.. >>>>> [ RES MEM : 13.384022 GB ] [ VIRT MEM : 27.655666 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 2117.512139 s ] [ CPU TIME: 111665.327678 s ] <<<<< .. +.. >>>>> [ RES MEM : 25.115326 GB ] [ VIRT MEM : 43.700459 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 8051.267100 s ] [ CPU TIME: 471172.026560 s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 3100701 -* Number of unique alpha determinants 3138402 - 3 : Davidson done - 5 : Davidson done - 6 : Davidson done - 2 : Davidson done - 8 : Davidson done - 0 : Davidson done - 7 : Davidson done - 4 : Davidson done +* Number of unique beta determinants 4572338 +* Number of unique alpha determinants 4612009 1 : Davidson done + 5 : Davidson done + 2 : Davidson done + 0 : Davidson done + 3 : Davidson done + 7 : Davidson done + 8 : Davidson done + 6 : Davidson done + 4 : Davidson done ---------- davidson.00000004 -* Broadcast time 7.182302951812744 +* Broadcast time 13.13005185127258 -.. >>>>> [ RES MEM : 13.405678 GB ] [ VIRT MEM : 27.689819 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 3813.311149 s ] [ CPU TIME: 222028.258133 s ] <<<<< .. +.. >>>>> [ RES MEM : 25.112366 GB ] [ VIRT MEM : 43.698502 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 15199.686446 s ] [ CPU TIME: 946413.535372 s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 3100701 -* Number of unique alpha determinants 3138402 - 6 : Davidson done +* Number of unique beta determinants 4572338 +* Number of unique alpha determinants 4612009 5 : Davidson done - 3 : Davidson done - 4 : Davidson done 0 : Davidson done - 7 : Davidson done - 2 : Davidson done - 1 : Davidson done + 3 : Davidson done 8 : Davidson done + 1 : Davidson done + 7 : Davidson done + 6 : Davidson done + 2 : Davidson done + 4 : Davidson done ---------- pt2.00000005 Using pt2-matching weight in selection - Using pt2-matching weight in selection # PT2 weight 1.000000 # Total weight 1.000000 Using pt2-matching weight in selection @@ -787,6 +785,7 @@ H 1.000000 0.000000 -1.371462 1.837134 Using pt2-matching weight in selection # PT2 weight 1.000000 # Total weight 1.000000 + Using pt2-matching weight in selection # PT2 weight 1.000000 # Total weight 1.000000 Using pt2-matching weight in selection @@ -802,502 +801,398 @@ H 1.000000 0.000000 -1.371462 1.837134 # PT2 weight 1.000000 # Total weight 1.000000 -.. >>>>> [ RES MEM : 13.403179 GB ] [ VIRT MEM : 27.687866 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 6011.120012 s ] [ CPU TIME: 331964.934441 s ] <<<<< .. +.. >>>>> [ RES MEM : 25.107826 GB ] [ VIRT MEM : 43.698521 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 23423.896848 s ] [ CPU TIME: 1420642.806976 s ] <<<<< .. -* Number of generators 1091985 +* Number of generators 3590787 -.. >>>>> [ RES MEM : 13.403179 GB ] [ VIRT MEM : 27.687866 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 6011.129693 s ] [ CPU TIME: 331964.937415 s ] <<<<< .. +.. >>>>> [ RES MEM : 25.107826 GB ] [ VIRT MEM : 43.698521 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 23423.922203 s ] [ CPU TIME: 1420642.815339 s ] <<<<< .. -* Number of selectors 41898323 -* Broadcast time 7.618607044219971 +* Number of selectors 83629180 +* Broadcast time 15.04091000556946 * Target maximum memory (GB) 170 -.. >>>>> [ RES MEM : 13.403263 GB ] [ VIRT MEM : 27.687866 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 6012.654846 s ] [ CPU TIME: 331997.480578 s ] <<<<< .. +.. >>>>> [ RES MEM : 25.107910 GB ] [ VIRT MEM : 43.698521 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 23427.413828 s ] [ CPU TIME: 1420701.520694 s ] <<<<< .. -* Number of generators 41898323 +* Number of generators 83629180 * Number of comb teeth 100 * Number of core MOs 5 * pt2_n_tasks_max 638 - N_det 41919613 - N_det_generators 41898323 - N_det_selectors 41898323 - pt2_e0_denominator -390.413628221421 + N_det 83664815 + N_det_generators 83629180 + N_det_selectors 83629180 + pt2_e0_denominator -390.421844962908 pt2_stoch_istate 1 state_average_weight 1.00000000000000 Number of threads 72 Running PT2 -.. >>>>> [ RES MEM : 19.024281 GB ] [ VIRT MEM : 33.309479 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 6018.642185 s ] [ CPU TIME: 332003.518091 s ] <<<<< .. +.. >>>>> [ RES MEM : 36.326588 GB ] [ VIRT MEM : 54.918278 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 23439.388457 s ] [ CPU TIME: 1420713.609495 s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 3100701 -* Number of unique alpha determinants 3138402 +* Number of unique beta determinants 4572338 +* Number of unique alpha determinants 4612009 .. >>>>> [ IO READ: pert_2rdm ] <<<<< .. -.. >>>>> [ RES MEM : 27.535347 GB ] [ VIRT MEM : 35.743229 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 6160.970952 s ] [ CPU TIME: 342204.428804 s ] <<<<< .. +.. >>>>> [ RES MEM : 44.293575 GB ] [ VIRT MEM : 54.076637 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 23732.957414 s ] [ CPU TIME: 1441747.138685 s ] <<<<< .. -.. >>>>> [ RES MEM : 27.536247 GB ] [ VIRT MEM : 35.743229 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 6161.137532 s ] [ CPU TIME: 342216.366877 s ] <<<<< .. +.. >>>>> [ RES MEM : 44.293797 GB ] [ VIRT MEM : 54.076637 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 23733.272484 s ] [ CPU TIME: 1441769.719448 s ] <<<<< .. -* Number of selectors 41898323 - 8 : PT2 done - ------- - 6 : PT2 done - ------- - 0 : PT2 done - ------- +* Number of selectors 83629180 1 : PT2 done ------- - 7 : PT2 done + 8 : PT2 done ------- - 3 : PT2 done + 4 : PT2 done ------- 2 : PT2 done ------- 5 : PT2 done ------- - 4 : PT2 done + 6 : PT2 done + ------- + 3 : PT2 done + ------- + 0 : PT2 done + ------- + 7 : PT2 done ------- ---------- davidson.00000006 -* Broadcast time 13.47077393531799 +* Broadcast time 33.72871708869934 -.. >>>>> [ RES MEM : 38.185246 GB ] [ VIRT MEM : 50.377857 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 9413.363768 s ] [ CPU TIME: 518972.494268 s ] <<<<< .. +.. >>>>> [ RES MEM : 47.728020 GB ] [ VIRT MEM : 52.579567 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 31171.749382 s ] [ CPU TIME: 1803388.510115 s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 4572338 -* Number of unique alpha determinants 4612009 - 1 : Davidson done +* Number of unique beta determinants 6702388 +* Number of unique alpha determinants 6814359 2 : Davidson done 8 : Davidson done - 0 : Davidson done - 7 : Davidson done - 6 : Davidson done 3 : Davidson done + 0 : Davidson done 4 : Davidson done + 7 : Davidson done + 1 : Davidson done + 6 : Davidson done 5 : Davidson done ---------- davidson.00000007 -* Broadcast time 13.96566915512085 +* Broadcast time 27.04258394241333 -.. >>>>> [ RES MEM : 33.764263 GB ] [ VIRT MEM : 44.656357 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 16545.342558 s ] [ CPU TIME: 987204.673529 s ] <<<<< .. +.. >>>>> [ RES MEM : 64.348671 GB ] [ VIRT MEM : 75.360672 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 62042.343754 s ] [ CPU TIME: 3878994.015561 s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 4572338 -* Number of unique alpha determinants 4612009 - 4 : Davidson done - 3 : Davidson done - 5 : Davidson done +* Number of unique beta determinants 6702388 +* Number of unique alpha determinants 6814359 0 : Davidson done - 8 : Davidson done - 2 : Davidson done 6 : Davidson done - 1 : Davidson done + 3 : Davidson done 7 : Davidson done + 2 : Davidson done + 4 : Davidson done + 1 : Davidson done + 8 : Davidson done + 5 : Davidson done ---------- davidson.00000008 -* Broadcast time 13.75415802001953 +* Broadcast time 30.89553499221802 -.. >>>>> [ RES MEM : 33.783062 GB ] [ VIRT MEM : 44.694412 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 23619.926535 s ] [ CPU TIME: 1457006.993978 s ] <<<<< .. +.. >>>>> [ RES MEM : 64.389980 GB ] [ VIRT MEM : 75.420387 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 95895.575622 s ] [ CPU TIME: 5961891.948727 s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 4572338 -* Number of unique alpha determinants 4612009 +* Number of unique beta determinants 6702388 +* Number of unique alpha determinants 6814359 + 4 : Davidson done + 6 : Davidson done + 7 : Davidson done 5 : Davidson done 8 : Davidson done - 1 : Davidson done - 7 : Davidson done - 0 : Davidson done 2 : Davidson done - 4 : Davidson done + 1 : Davidson done 3 : Davidson done - 6 : Davidson done + 0 : Davidson done ---------- davidson.00000009 -* Broadcast time 13.27760410308838 +* Broadcast time 28.03176188468933 -.. >>>>> [ RES MEM : 33.782150 GB ] [ VIRT MEM : 44.694412 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 30714.539482 s ] [ CPU TIME: 1928108.642284 s ] <<<<< .. +.. >>>>> [ RES MEM : 64.389259 GB ] [ VIRT MEM : 75.420387 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 126809.513575 s ] [ CPU TIME: 8027553.562401 s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 4572338 -* Number of unique alpha determinants 4612009 - 1 : Davidson done +* Number of unique beta determinants 6702388 +* Number of unique alpha determinants 6814359 + 8 : Davidson done + 7 : Davidson done 4 : Davidson done 2 : Davidson done - 3 : Davidson done + 1 : Davidson done 0 : Davidson done - 5 : Davidson done 6 : Davidson done - 7 : Davidson done - 8 : Davidson done + 3 : Davidson done + 5 : Davidson done ---------- davidson.00000010 -* Broadcast time 13.74512004852295 +* Broadcast time 27.62621212005615 -.. >>>>> [ RES MEM : 33.783718 GB ] [ VIRT MEM : 44.694412 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 37828.815742 s ] [ CPU TIME: 2394585.397730 s ] <<<<< .. +.. >>>>> [ RES MEM : 64.390327 GB ] [ VIRT MEM : 75.420387 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 158229.135605 s ] [ CPU TIME: ************** s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 4572338 -* Number of unique alpha determinants 4612009 - 5 : Davidson done +* Number of unique beta determinants 6702388 +* Number of unique alpha determinants 6814359 + 1 : Davidson done + 7 : Davidson done + 4 : Davidson done + 3 : Davidson done + 2 : Davidson done + 8 : Davidson done 6 : Davidson done 0 : Davidson done - 4 : Davidson done - 7 : Davidson done - 8 : Davidson done - 1 : Davidson done - 3 : Davidson done - 2 : Davidson done + 5 : Davidson done ---------- davidson.00000011 -* Broadcast time 14.02665114402771 +* Broadcast time 27.41518211364746 -.. >>>>> [ RES MEM : 33.783413 GB ] [ VIRT MEM : 44.694412 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 44996.482315 s ] [ CPU TIME: 2864723.232075 s ] <<<<< .. +.. >>>>> [ RES MEM : 64.389957 GB ] [ VIRT MEM : 75.420387 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 189164.271989 s ] [ CPU TIME: ************** s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 4572338 -* Number of unique alpha determinants 4612009 - 3 : Davidson done +* Number of unique beta determinants 6702388 +* Number of unique alpha determinants 6814359 0 : Davidson done + 1 : Davidson done 2 : Davidson done 5 : Davidson done + 3 : Davidson done 8 : Davidson done - 1 : Davidson done 6 : Davidson done 7 : Davidson done 4 : Davidson done ---------- davidson.00000012 -* Broadcast time 15.02229213714600 +* Broadcast time 31.66601800918579 -.. >>>>> [ RES MEM : 33.782177 GB ] [ VIRT MEM : 44.694412 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 52172.589777 s ] [ CPU TIME: 3332300.623376 s ] <<<<< .. +.. >>>>> [ RES MEM : 64.390457 GB ] [ VIRT MEM : 75.420387 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 220087.143460 s ] [ CPU TIME: ************** s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 4572338 -* Number of unique alpha determinants 4612009 - 0 : Davidson done - 5 : Davidson done - 4 : Davidson done - 1 : Davidson done - 8 : Davidson done +* Number of unique beta determinants 6702388 +* Number of unique alpha determinants 6814359 7 : Davidson done - 2 : Davidson done 6 : Davidson done + 0 : Davidson done + 2 : Davidson done + 5 : Davidson done + 1 : Davidson done 3 : Davidson done + 8 : Davidson done + 4 : Davidson done ---------- davidson.00000013 -* Broadcast time 13.68234610557556 +* Broadcast time 29.18301892280579 -.. >>>>> [ RES MEM : 33.784336 GB ] [ VIRT MEM : 44.694412 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 59382.173047 s ] [ CPU TIME: 3802255.883040 s ] <<<<< .. +.. >>>>> [ RES MEM : 64.389843 GB ] [ VIRT MEM : 75.420387 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 251162.844965 s ] [ CPU TIME: ************** s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 4572338 -* Number of unique alpha determinants 4612009 - 5 : Davidson done - 6 : Davidson done - 7 : Davidson done - 4 : Davidson done - 1 : Davidson done - 3 : Davidson done +* Number of unique beta determinants 6702388 +* Number of unique alpha determinants 6814359 8 : Davidson done + 4 : Davidson done + 6 : Davidson done + 5 : Davidson done + 3 : Davidson done + 7 : Davidson done + 1 : Davidson done 0 : Davidson done 2 : Davidson done ---------- davidson.00000014 -* Broadcast time 14.51096892356873 +* Broadcast time 32.60969400405884 -.. >>>>> [ RES MEM : 33.778416 GB ] [ VIRT MEM : 44.688934 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 66616.502208 s ] [ CPU TIME: 4273597.782886 s ] <<<<< .. +.. >>>>> [ RES MEM : 64.390110 GB ] [ VIRT MEM : 75.420387 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 281954.764770 s ] [ CPU TIME: ************** s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 4572338 -* Number of unique alpha determinants 4612009 +* Number of unique beta determinants 6702388 +* Number of unique alpha determinants 6814359 + 4 : Davidson done + 3 : Davidson done + 6 : Davidson done + 1 : Davidson done + 2 : Davidson done 8 : Davidson done 0 : Davidson done - 4 : Davidson done - 6 : Davidson done - 3 : Davidson done - 2 : Davidson done 5 : Davidson done - 1 : Davidson done 7 : Davidson done ---------- davidson.00000015 -* Broadcast time 13.84220695495605 +* Broadcast time 27.41700100898743 -.. >>>>> [ RES MEM : 33.751114 GB ] [ VIRT MEM : 44.661430 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 73784.818021 s ] [ CPU TIME: 4744934.241967 s ] <<<<< .. +.. >>>>> [ RES MEM : 64.317829 GB ] [ VIRT MEM : 75.347698 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 312806.631793 s ] [ CPU TIME: ************** s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 4572338 -* Number of unique alpha determinants 4612009 +* Number of unique beta determinants 6702388 +* Number of unique alpha determinants 6814359 0 : Davidson done - 7 : Davidson done - 5 : Davidson done - 8 : Davidson done - 1 : Davidson done - 3 : Davidson done 2 : Davidson done 6 : Davidson done + 1 : Davidson done + 5 : Davidson done + 7 : Davidson done + 8 : Davidson done + 3 : Davidson done 4 : Davidson done ---------- davidson.00000016 -* Broadcast time 14.70761919021606 +* Broadcast time 33.62463402748108 -.. >>>>> [ RES MEM : 33.751045 GB ] [ VIRT MEM : 44.661430 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 80946.114522 s ] [ CPU TIME: 5215686.508126 s ] <<<<< .. +.. >>>>> [ RES MEM : 64.045620 GB ] [ VIRT MEM : 75.075333 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 343374.081812 s ] [ CPU TIME: ************** s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 4572338 -* Number of unique alpha determinants 4612009 - 3 : Davidson done +* Number of unique beta determinants 6702388 +* Number of unique alpha determinants 6814359 + 0 : Davidson done + 2 : Davidson done 7 : Davidson done + 8 : Davidson done + 3 : Davidson done 4 : Davidson done 1 : Davidson done - 2 : Davidson done - 0 : Davidson done - 8 : Davidson done - 6 : Davidson done 5 : Davidson done + 6 : Davidson done ---------- davidson.00000017 -* Broadcast time 14.62246704101562 +* Broadcast time 27.56709289550781 -.. >>>>> [ RES MEM : 33.751156 GB ] [ VIRT MEM : 44.661430 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 88196.007857 s ] [ CPU TIME: 5683404.464789 s ] <<<<< .. +.. >>>>> [ RES MEM : 64.045620 GB ] [ VIRT MEM : 75.075333 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373988.405314 s ] [ CPU TIME: ************** s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 4572338 -* Number of unique alpha determinants 4612009 - 2 : Davidson done - 7 : Davidson done +* Number of unique beta determinants 6702388 +* Number of unique alpha determinants 6814359 + 8 : Davidson done + 0 : Davidson done 4 : Davidson done + 3 : Davidson done + 7 : Davidson done + 5 : Davidson done + 2 : Davidson done + 1 : Davidson done + 6 : Davidson done + ---------- + davidson.00000018 +* Broadcast time 27.63976001739502 + +.. >>>>> [ RES MEM : 64.046051 GB ] [ VIRT MEM : 75.075333 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 404804.957446 s ] [ CPU TIME: ************** s ] <<<<< .. + + Read n_states_diag +* Number of unique beta determinants 6702388 +* Number of unique alpha determinants 6814359 + 4 : Davidson done + 2 : Davidson done + 1 : Davidson done + 7 : Davidson done + 0 : Davidson done + 5 : Davidson done + 8 : Davidson done 6 : Davidson done 3 : Davidson done - 8 : Davidson done - 1 : Davidson done - 5 : Davidson done - 0 : Davidson done - ---------- - pt2.00000018 - Using pt2-matching weight in selection - # PT2 weight 1.000000 - # Total weight 1.000000 - Using pt2-matching weight in selection - # PT2 weight 1.000000 - # Total weight 1.000000 - Using pt2-matching weight in selection - # PT2 weight 1.000000 - # Total weight 1.000000 - Using pt2-matching weight in selection - # PT2 weight 1.000000 - # Total weight 1.000000 - Using pt2-matching weight in selection - # PT2 weight 1.000000 - # Total weight 1.000000 - Using pt2-matching weight in selection - # PT2 weight 1.000000 - # Total weight 1.000000 - Using pt2-matching weight in selection - # PT2 weight 1.000000 - # Total weight 1.000000 - Using pt2-matching weight in selection - # PT2 weight 1.000000 - # Total weight 1.000000 - Using pt2-matching weight in selection - # PT2 weight 1.000000 - # Total weight 1.000000 - -.. >>>>> [ RES MEM : 36.094547 GB ] [ VIRT MEM : 47.004692 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 96356.116502 s ] [ CPU TIME: 6152000.113168 s ] <<<<< .. - -* Number of generators 83629162 - -.. >>>>> [ RES MEM : 36.094547 GB ] [ VIRT MEM : 47.004692 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 96356.320824 s ] [ CPU TIME: 6152000.289787 s ] <<<<< .. - -* Number of selectors 83629162 -* Broadcast time 28.80620002746582 - -.. >>>>> [ RES MEM : 36.094616 GB ] [ VIRT MEM : 47.004692 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 96369.771348 s ] [ CPU TIME: 6152455.282163 s ] <<<<< .. - -* Number of generators 83629162 -* Number of comb teeth 100 -* pt2_n_tasks_max 638 - N_det 83664815 - N_det_generators 83629162 - N_det_selectors 83629162 - pt2_e0_denominator -390.421844962665 - pt2_stoch_istate 1 - state_average_weight 1.00000000000000 - Number of threads 72 - Running PT2 - -.. >>>>> [ RES MEM : 41.698856 GB ] [ VIRT MEM : 52.610161 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 96382.185437 s ] [ CPU TIME: 6152469.803796 s ] <<<<< .. - - Read n_states_diag -* Number of unique beta determinants 4572338 -* Number of unique alpha determinants 4612009 - -.. >>>>> [ RES MEM : 48.095493 GB ] [ VIRT MEM : 53.330532 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 96651.268137 s ] [ CPU TIME: 6171701.275179 s ] <<<<< .. - -* Number of selectors 83629162 - 8 : PT2 done - ------- - 1 : PT2 done - ------- - 2 : PT2 done - ------- - 0 : PT2 done - ------- - 3 : PT2 done - ------- - 4 : PT2 done - ------- - 6 : PT2 done - ------- - 7 : PT2 done - ------- - 5 : PT2 done - ------- ---------- davidson.00000019 -* Broadcast time 28.92955183982849 +* Broadcast time 28.12791109085083 -.. >>>>> [ RES MEM : 47.267643 GB ] [ VIRT MEM : 51.713020 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 103819.001514 s ] [ CPU TIME: 6513087.208984 s ] <<<<< .. +.. >>>>> [ RES MEM : 64.045395 GB ] [ VIRT MEM : 75.075333 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 435563.824099 s ] [ CPU TIME: ************** s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 6747536 -* Number of unique alpha determinants 6868850 +* Number of unique beta determinants 6702388 +* Number of unique alpha determinants 6814359 + 5 : Davidson done 7 : Davidson done - 1 : Davidson done - 2 : Davidson done 0 : Davidson done + 1 : Davidson done + 3 : Davidson done 8 : Davidson done 4 : Davidson done - 3 : Davidson done - 5 : Davidson done + 2 : Davidson done 6 : Davidson done ---------- davidson.00000020 -* Broadcast time 28.20003414154053 +* Broadcast time 29.57620191574097 -.. >>>>> [ RES MEM : 64.417580 GB ] [ VIRT MEM : 75.468910 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 133967.319824 s ] [ CPU TIME: 8548630.143981 s ] <<<<< .. +.. >>>>> [ RES MEM : 64.045612 GB ] [ VIRT MEM : 75.075333 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 466225.964669 s ] [ CPU TIME: ************** s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 6747536 -* Number of unique alpha determinants 6868850 +* Number of unique beta determinants 6702388 +* Number of unique alpha determinants 6814359 + 0 : Davidson done 5 : Davidson done 4 : Davidson done - 7 : Davidson done 1 : Davidson done 6 : Davidson done 2 : Davidson done + 7 : Davidson done 8 : Davidson done - 0 : Davidson done 3 : Davidson done ---------- davidson.00000021 -* Broadcast time 26.88339209556580 +* Broadcast time 31.56579613685608 -.. >>>>> [ RES MEM : 64.435837 GB ] [ VIRT MEM : 75.502666 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 164397.473980 s ] [ CPU TIME: ************** s ] <<<<< .. +.. >>>>> [ RES MEM : 64.044971 GB ] [ VIRT MEM : 75.075333 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 497003.892535 s ] [ CPU TIME: ************** s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 6747536 -* Number of unique alpha determinants 6868850 - 1 : Davidson done - 5 : Davidson done - 2 : Davidson done +* Number of unique beta determinants 6702388 +* Number of unique alpha determinants 6814359 + 6 : Davidson done 8 : Davidson done 3 : Davidson done - 4 : Davidson done + 5 : Davidson done 7 : Davidson done + 1 : Davidson done 0 : Davidson done - 6 : Davidson done + 2 : Davidson done + 4 : Davidson done ---------- davidson.00000022 -* Broadcast time 26.30948805809021 +* Broadcast time 30.65503811836243 -.. >>>>> [ RES MEM : 64.431217 GB ] [ VIRT MEM : 75.499599 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 194898.243278 s ] [ CPU TIME: ************** s ] <<<<< .. +.. >>>>> [ RES MEM : 64.045670 GB ] [ VIRT MEM : 75.075333 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 527881.048133 s ] [ CPU TIME: ************** s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 6747536 -* Number of unique alpha determinants 6868850 - 5 : Davidson done - 8 : Davidson done - 1 : Davidson done - 6 : Davidson done - 4 : Davidson done - 2 : Davidson done - 7 : Davidson done +* Number of unique beta determinants 6702388 +* Number of unique alpha determinants 6814359 0 : Davidson done 3 : Davidson done + 8 : Davidson done + 4 : Davidson done + 2 : Davidson done + 5 : Davidson done + 1 : Davidson done + 6 : Davidson done + 7 : Davidson done ---------- davidson.00000023 -* Broadcast time 29.21908617019653 +* Broadcast time 32.35763192176819 -.. >>>>> [ RES MEM : 64.433872 GB ] [ VIRT MEM : 75.499599 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 225336.581699 s ] [ CPU TIME: ************** s ] <<<<< .. +.. >>>>> [ RES MEM : 64.045956 GB ] [ VIRT MEM : 75.076328 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 558769.664139 s ] [ CPU TIME: ************** s ] <<<<< .. Read n_states_diag -* Number of unique beta determinants 6747536 -* Number of unique alpha determinants 6868850 - 4 : Davidson done - 8 : Davidson done - 7 : Davidson done - 0 : Davidson done - 3 : Davidson done - 5 : Davidson done - 6 : Davidson done - 1 : Davidson done - 2 : Davidson done - ---------- - davidson.00000024 -* Broadcast time 26.68139410018921 - -.. >>>>> [ RES MEM : 64.433414 GB ] [ VIRT MEM : 75.499599 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 255866.844441 s ] [ CPU TIME: ************** s ] <<<<< .. - - Read n_states_diag -* Number of unique beta determinants 6747536 -* Number of unique alpha determinants 6868850 - 8 : Davidson done - 3 : Davidson done - 4 : Davidson done - 1 : Davidson done - 7 : Davidson done - 2 : Davidson done - 5 : Davidson done - 6 : Davidson done - 0 : Davidson done - ---------- - davidson.00000025 -* Broadcast time 26.41703605651855 - -.. >>>>> [ RES MEM : 64.433296 GB ] [ VIRT MEM : 75.499599 GB ] <<<<< .. -.. >>>>> [ WALL TIME: 286280.534186 s ] [ CPU TIME: ************** s ] <<<<< .. - - Read n_states_diag -* Number of unique beta determinants 6747536 -* Number of unique alpha determinants 6868850 +* Number of unique beta determinants 6702388 +* Number of unique alpha determinants 6814359 diff --git a/furan/cc-pvdz/furan.restart2.nofci.out b/furan/cc-pvdz/furan.restart2.nofci.out index 2ceea08..ae1fb47 100644 --- a/furan/cc-pvdz/furan.restart2.nofci.out +++ b/furan/cc-pvdz/furan.restart2.nofci.out @@ -790,3 +790,6 @@ Iter Energy S^2 Residual 3 -229.3277053511 0.008545 0.539E-04 1 -229.3277053511 0.008545 0.539E-04 2 -229.3278095199 0.008639 0.177E-04 + 3 -229.3278470438 0.008803 0.812E-06 + 1 -229.3278470438 0.008803 0.812E-06 + 2 -229.3278520095 0.008846 0.255E-06 diff --git a/furan/cc-pvdz/run_restart.sh b/furan/cc-pvdz/run_restart.sh index 61bfc63..e28dd4f 100644 --- a/furan/cc-pvdz/run_restart.sh +++ b/furan/cc-pvdz/run_restart.sh @@ -8,10 +8,10 @@ source ~/tmpdir/qp2/quantum_package.rc set -e -cp -r ${INPUT}.localized ${INPUT}.restart +#cp -r ${INPUT}.localized ${INPUT}.restart qp set_file ${INPUT}.restart qp set determinants n_states 1 qp set determinants read_wf True qp set determinants s2_eig False -qp set determinants n_det_max 1e8 -qp srun fci > ${INPUT}.restart.nofci.out +qp set determinants n_det_max 2e8 +qp srun fci > ${INPUT}.restart3.nofci.out