From a1c4df8d82b49385d1a554d34e1044c884dc8ee1 Mon Sep 17 00:00:00 2001 From: Pierre-Francois Loos Date: Wed, 28 Oct 2020 15:21:47 +0100 Subject: [PATCH 1/5] Manuscript --- Manuscript/Ec.bib | 1076 +++++++++++++++++++++++++++++++++++++++++++++ Manuscript/Ec.tex | 73 +++ 2 files changed, 1149 insertions(+) create mode 100644 Manuscript/Ec.bib create mode 100644 Manuscript/Ec.tex diff --git a/Manuscript/Ec.bib b/Manuscript/Ec.bib new file mode 100644 index 0000000..68d6c0e --- /dev/null +++ b/Manuscript/Ec.bib @@ -0,0 +1,1076 @@ +%% This BibTeX bibliography file was created using BibDesk. +%% http://bibdesk.sourceforge.net/ + +%% Created for Pierre-Francois Loos at 2020-10-26 13:09:05 +0100 + + +%% Saved with string encoding Unicode (UTF-8) + + + +@misc{Xu_2020, + Archiveprefix = {arXiv}, + Author = {Enhua Xu and Motoyuki Uejima and Seiichiro L. Ten-no}, + Date-Added = {2020-10-10 13:54:02 +0200}, + Date-Modified = {2020-10-10 13:54:09 +0200}, + Eprint = {2010.01850}, + Primaryclass = {physics.chem-ph}, + Title = {Towards near-exact solutions of molecular electronic structure: Full coupled-cluster reduction with a second-order perturbative correction}, + Year = {2020}} + +@inbook{Caffarel_2016b, + Author = {Caffarel, Michel and Applencourt, Thomas and Giner, Emmanuel and Scemama, Anthony}, + Booktitle = {Recent Progress in Quantum Monte Carlo}, + Chapter = {2}, + Date-Added = {2020-10-10 13:52:37 +0200}, + Date-Modified = {2020-10-10 13:53:07 +0200}, + Doi = {10.1021/bk-2016-1234.ch002}, + Pages = {15-46}, + Title = {Using CIPSI Nodes in Diffusion Monte Carlo}, + Bdsk-Url-1 = {https://pubs.acs.org/doi/abs/10.1021/bk-2016-1234.ch002}, + Bdsk-Url-2 = {https://doi.org/10.1021/bk-2016-1234.ch002}} + +@article{BenAmor_2011, + Author = {Ben Amor,Nadia and Bessac,Fabienne and Hoyau,Sophie and Maynau,Daniel}, + Date-Added = {2020-10-09 21:28:40 +0200}, + Date-Modified = {2020-10-09 21:29:52 +0200}, + Doi = {10.1063/1.3600351}, + Journal = {J. Chem. Phys.}, + Pages = {014101}, + Title = {Direct selected multireference configuration interaction calculations for large systems using localized orbitals}, + Volume = {135}, + Year = {2011}, + Bdsk-Url-1 = {https://doi.org/10.1063/1.3600351}} + +@article{Suaud_2017, + Author = {Suaud, Nicolas and Malrieu, Jean-Paul}, + Doi = {10.1080/00268976.2017.1303207}, + Issn = {0026-8976}, + Journal = {Mol. Phys.}, + Month = {Nov}, + Number = {21-22}, + Pages = {2684--2695}, + Publisher = {Taylor {\&} Francis}, + Title = {{Natural molecular orbitals: limits of a Lowdin's conjecture}}, + Volume = {115}, + Year = {2017}, + Bdsk-Url-1 = {https://doi.org/10.1080/00268976.2017.1303207}} + +@article{Angeli_2009, + Author = {Angeli, Celestino}, + Doi = {10.1002/jcc.21155}, + Issn = {0192-8651}, + Journal = {J. Comput. Chem.}, + Month = {Jun}, + Number = {8}, + Pages = {1319--1333}, + Publisher = {John Wiley {\&} Sons, Ltd}, + Title = {{On the nature of the π {$\rightarrow$} π{$\ast$} ionic excited states: The V state of ethene as a prototype}}, + Volume = {30}, + Year = {2009}, + Bdsk-Url-1 = {https://doi.org/10.1002/jcc.21155}} + +@article{Angeli_2003, + Author = {Angeli, Celestino and Calzado, Carmen J. and Cimiraglia, Renzo and Evangelisti, Stefano and Guih\'ery, Nathalie and Leininger, Thierry and Malrieu, Jean-Paul and Maynau, Daniel and Ruiz, Jos\'e Vicente Pitarch and Sparta, Manuel}, + Doi = {10.1080/0026897031000082149}, + Issn = {0026-8976}, + Journal = {Mol. Phys.}, + Month = {May}, + Number = {9}, + Pages = {1389--1398}, + Publisher = {Taylor {\&} Francis}, + Title = {{The use of local orbitals in multireference calculations}}, + Volume = {101}, + Year = {2003}, + Bdsk-Url-1 = {https://doi.org/10.1080/0026897031000082149}} + +@article{Deustua_2017, + Author = {Deustua, J. Emiliano and Shen, Jun and Piecuch, Piotr}, + Date-Added = {2020-10-09 12:21:32 +0200}, + Date-Modified = {2020-10-09 12:21:59 +0200}, + Doi = {10.1103/PhysRevLett.119.223003}, + Journal = {Phys. Rev. Lett.}, + Pages = {223003}, + Title = {Converging High-Level Coupled-Cluster Energetics by Monte Carlo Sampling and Moment Expansions}, + Volume = {119}, + Year = {2017}, + Bdsk-Url-1 = {https://link.aps.org/doi/10.1103/PhysRevLett.119.223003}, + Bdsk-Url-2 = {https://doi.org/10.1103/PhysRevLett.119.223003}} + +@article{Zhang_2020, + Author = {Zhang, Ning and Liu, Wenjian and Hoffmann, Mark R.}, + Date-Added = {2020-10-09 12:06:01 +0200}, + Date-Modified = {2020-10-09 12:06:54 +0200}, + Doi = {10.1021/acs.jctc.9b01200}, + Journal = {J. Chem. Theory Comput.}, + Number = {4}, + Pages = {2296-2316}, + Title = {Iterative Configuration Interaction with Selection}, + Volume = {16}, + Year = {2020}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.9b01200}} + +@article{Lei_2017, + Author = {Yibo Lei and Wenjian Liu and Mark R. Hoffmann}, + Date-Added = {2020-10-09 12:04:45 +0200}, + Date-Modified = {2020-10-09 12:07:10 +0200}, + Doi = {10.1080/00268976.2017.1308029}, + Journal = {Mol. Phys.}, + Number = {21-22}, + Pages = {2696-2707}, + Title = {Further development of SDSPT2 for strongly correlated electrons}, + Volume = {115}, + Year = {2017}, + Bdsk-Url-1 = {https://doi.org/10.1080/00268976.2017.1308029}} + +@article{Liu_2014, + Author = {Liu, W. and Hoffmann, M.R.}, + Date-Added = {2020-10-09 12:02:24 +0200}, + Date-Modified = {2020-10-09 12:07:31 +0200}, + Doi = {10.1007/s00214-014-1481-x}, + Journal = {Theor. Chem. Acc.}, + Pages = {1481}, + Title = {SDS: the static--dynamic--static framework for strongly correlated electrons}, + Volume = {133}, + Year = {2014}, + Bdsk-Url-1 = {https://doi.org/10.1007/s00214-014-1481-x}} + +@article{Chan_2011, + Abstract = { The density matrix renormalization group is a method that is useful for describing molecules that have strongly correlated electrons. Here we provide a pedagogical overview of the basic challenges of strong correlation, how the density matrix renormalization group works, a survey of its existing applications to molecular problems, and some thoughts on the future of the method. }, + Author = {Chan, Garnet Kin-Lic and Sharma, Sandeep}, + Date-Added = {2020-10-09 11:59:58 +0200}, + Date-Modified = {2020-10-09 21:37:30 +0200}, + Doi = {10.1146/annurev-physchem-032210-103338}, + Journal = {Annu. Rev. Phys. Chem.}, + Pages = {465-481}, + Title = {The Density Matrix Renormalization Group in Quantum Chemistry}, + Volume = {62}, + Year = {2011}, + Bdsk-Url-1 = {https://doi.org/10.1146/annurev-physchem-032210-103338}} + +@article{White_1993, + Author = {White, S. R.}, + Date-Added = {2020-10-09 11:57:24 +0200}, + Date-Modified = {2020-10-09 11:58:16 +0200}, + Doi = {10.1103/PhysRevB.48.10345}, + Journal = {Phys. Rev. B}, + Pages = {10345}, + Title = {Density-matrix algorithms for quantum renormalization groups}, + Volume = {48}, + Year = {1993}, + Bdsk-Url-1 = {https://doi.org/10.1103/PhysRevLett.69.2863}} + +@article{Eriksen_2019b, + Author = {J. J. Eriksen and J. Gauss}, + Date-Added = {2020-08-25 18:14:27 +0200}, + Date-Modified = {2020-08-25 18:15:20 +0200}, + Doi = {10.1021/acs.jpclett.9b02968}, + Journal = {J. Phys. Chem. Lett.}, + Pages = {7910--7915}, + Title = {Generalized Many-Body Expanded Full Configuration Interaction Theory}, + Volume = {27}, + Year = {2019}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jpclett.9b02968}} + +@article{Eriksen_2017, + Author = {J. J. Eriksen and F. Lipparini and J. Gauss}, + Date-Added = {2020-08-25 18:12:46 +0200}, + Date-Modified = {2020-08-25 18:13:55 +0200}, + Doi = {10.1021/acs.jpclett.7b02075}, + Journal = {J. Phys. Chem. Lett.}, + Pages = {4633--4639}, + Title = {Virtual Orbital Many-Body Expansions: A Possible Route towards the Full Configuration Interaction Limit}, + Volume = {8}, + Year = {2017}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jpclett.7b02075}} + +@article{Sauer_2009, + Author = {Sauer, Stephan P. A. and Schreiber, Marko and Silva-Junior, Mario R. and Thiel, Walter}, + Date-Added = {2020-08-24 16:15:18 +0200}, + Date-Modified = {2020-08-24 16:20:35 +0200}, + Doi = {10.1021/ct800256j}, + Journal = {J. Chem. Theory Comput.}, + Number = {3}, + Pages = {555--564}, + Title = {Benchmarks for Electronically Excited States: A Comparison of Noniterative and Iterative Triples Corrections in Linear Response Coupled Cluster Methods: CCSDR(3) versus CC3}, + Volume = {5}, + Year = {2009}, + Bdsk-Url-1 = {https://doi.org/10.1021/ct800256j}} + +@article{Schreiber_2008, + Author = {Schreiber, M. and Silva-Junior, M. R. and Sauer, S. P. A. and Thiel, W.}, + Date-Added = {2020-08-24 16:15:18 +0200}, + Date-Modified = {2020-08-24 16:21:02 +0200}, + Doi = {10.1063/1.2889385}, + Journal = {J. Chem. Phys.}, + Pages = {134110}, + Title = {Benchmarks for Electronically Excited States: CASPT2, CC2, CCSD and CC3}, + Volume = 128, + Year = 2008, + Bdsk-Url-1 = {https://doi.org/10.1063/1.2889385}} + +@article{Silva-Junior_2010a, + Author = {Silva-Junior, M. R. and Schreiber, M. and Sauer, S. P. A. and Thiel, W.}, + Date-Added = {2020-08-24 16:15:18 +0200}, + Date-Modified = {2020-08-24 16:19:10 +0200}, + Doi = {10.1063/1.2973541}, + Journal = {J. Chem. Phys.}, + Pages = {104103}, + Title = {Benchmarks for Electronically Excited States: Time-Dependent Density Functional Theory and Density Functional Theory Based Multireference Configuration Interaction}, + Volume = 129, + Year = 2008, + Bdsk-Url-1 = {https://doi.org/10.1063/1.2973541}} + +@article{Silva-Junior_2010b, + Author = {Silva-Junior, M. R. and Sauer, S. P. A. and Schreiber, M. and Thiel, W.}, + Date-Added = {2020-08-24 16:15:18 +0200}, + Date-Modified = {2020-08-24 16:19:37 +0200}, + Doi = {10.1080/00268970903549047}, + Journal = {Mol. Phys.}, + Pages = {453--465}, + Title = {Basis Set Effects on Coupled Cluster Benchmarks of Electronically Excited States: CC3, CCSDR(3) and CC2}, + Volume = 108, + Year = 2010, + Bdsk-Url-1 = {https://doi.org/10.1080/00268970903549047}} + +@article{Silva-Junior_2010c, + Author = {Silva-Junior, M. R. and Schreiber, M. and Sauer, S. P. A. and Thiel, W.}, + Date-Added = {2020-08-24 16:15:18 +0200}, + Date-Modified = {2020-08-24 16:20:03 +0200}, + Doi = {10.1063/1.3499598}, + Journal = {J. Chem. Phys.}, + Pages = {174318}, + Title = {Benchmarks of Electronically Excited States: Basis Set Effecs on {{CASPT2}} Results}, + Volume = 133, + Year = 2010, + Bdsk-Url-1 = {https://doi.org/10.1063/1.3499598}} + +@article{Boys_1960, + Author = {J. M. Foster and S. F. Boys}, + Date-Added = {2020-08-22 17:56:32 +0200}, + Date-Modified = {2020-08-22 17:57:16 +0200}, + Doi = {10.1103/RevModPhys.32.300}, + Journal = {Rev. Mod. 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Theory Comput.}, + Month = {Dec}, + Number = {12}, + Pages = {5286--5296}, + Publisher = {American Chemical Society (ACS)}, + Title = {Spin Density Distribution in Open-Shell Transition Metal Systems: A Comparative Post-Hartree--Fock, Density Functional Theory, and Quantum Monte Carlo Study of the CuCl$_2$ Molecule}, + Url = {http://dx.doi.org/10.1021/ct5004252}, + Volume = {10}, + Year = {2014}, + Bdsk-Url-1 = {http://dx.doi.org/10.1021/ct5004252}} + +@article{Garniron_2017, + Author = {Yann Garniron and Anthony Scemama and Pierre-Fran{\c{c}}ois Loos and Michel Caffarel}, + Date-Added = {2020-08-18 22:12:52 +0200}, + Date-Modified = {2020-08-18 22:12:54 +0200}, + Doi = {10.1063/1.4992127}, + Journal = {J. Chem. Phys.}, + Month = {jul}, + Number = {3}, + Pages = {034101}, + Publisher = {{AIP} Publishing}, + Title = {Hybrid stochastic-deterministic calculation of the second-order perturbative contribution of multireference perturbation theory}, + Url = {https://doi.org/10.1063%2F1.4992127}, + Volume = {147}, + Year = 2017, + Bdsk-Url-1 = {https://doi.org/10.1063%2F1.4992127}, + Bdsk-Url-2 = {https://doi.org/10.1063/1.4992127}} + +@article{Dash_2019, + Author = {Dash, Monika and Feldt, Jonas and Moroni, Saverio and Scemama, Anthony and Filippi, Claudia}, + Date-Added = {2020-08-18 22:10:14 +0200}, + Date-Modified = {2020-08-18 22:10:14 +0200}, + Doi = {10.1021/acs.jctc.9b00476}, + Issn = {1549-9618}, + Journal = {J. Chem. Theory Comput.}, + Month = {Sep}, + Number = {9}, + Pages = {4896--4906}, + Publisher = {American Chemical Society}, + Title = {{Excited States with Selected Configuration Interaction-Quantum Monte Carlo: Chemically Accurate Excitation Energies and Geometries}}, + Volume = {15}, + Year = {2019}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.9b00476}} + +@article{Dash_2018, + Author = {Dash, Monika and Moroni, Saverio and Scemama, Anthony and Filippi, Claudia}, + Date-Added = {2020-08-18 22:10:14 +0200}, + Date-Modified = {2020-08-18 22:10:14 +0200}, + Doi = {10.1021/acs.jctc.8b00393}, + Issn = {1549-9618}, + Journal = {J. Chem. Theory Comput.}, + Month = {Aug}, + Number = {8}, + Pages = {4176--4182}, + Publisher = {American Chemical Society}, + Title = {{Perturbatively Selected Configuration-Interaction Wave Functions for Efficient Geometry Optimization in Quantum Monte Carlo}}, + Volume = {14}, + Year = {2018}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.8b00393}} + +@article{Kucharski_1992, + Author = {Kucharski, S. A. and Bartlett, R. J.}, + Date-Added = {2020-08-18 21:48:06 +0200}, + Date-Modified = {2020-08-19 17:14:16 +0200}, + Doi = {10.1063/1.463930}, + Journal = {J. Chem. Phys.}, + Pages = {4282}, + Title = {The Coupled-Cluster Single, Double, Triple, and Quadruple Excitation Method}, + Volume = {97}, + Year = {1992}, + Bdsk-Url-1 = {https://doi.org/10.1063/1.463930}} + +@article{Oliphant_1991, + Author = {Oliphant, N. and Adamowicz, L.}, + Date-Added = {2020-08-18 21:47:03 +0200}, + Date-Modified = {2020-08-19 17:13:34 +0200}, + Doi = {10.1063/1.461534}, + Journal = {J. Chem. 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Phys.}, + Pages = {151101}, + Title = {Communication: Approaching Ex- act Quantum Chemistry by Cluster Analysis of Full Configuration Interaction Quan- tum Monte Carlo Wave Functions}, + Volume = {149}, + Year = {2018}, + Bdsk-Url-1 = {https://doi.org/10.1063/1.5055769}} + +@misc{Tubman_2018, + Archiveprefix = {arXiv}, + Author = {Norm M. Tubman and Daniel S. Levine and Diptarka Hait and Martin Head-Gordon and K. Birgitta Whaley}, + Eprint = {1808.02049}, + Primaryclass = {cond-mat.str-el}, + Title = {An efficient deterministic perturbation theory for selected configuration interaction methods}, + Year = {2018}} + +@article{Tubman_2020, + Author = {Tubman, N. M. and Freeman, C. D. and Levine, D. S. and Hait, D. and Head-Gordon, M. and Whaley, K. B.}, + Date-Added = {2020-08-18 21:15:49 +0200}, + Date-Modified = {2020-08-19 17:15:03 +0200}, + Doi = {10.1021/acs.jctc.8b00536}, + Journal = {J. Chem. Theory Comput.}, + Pages = {2139}, + Title = {Modern Approaches to Exact Diagonalization and Selected Configuration Interaction with the Adaptive Sampling CI Method}, + Volume = {16}, + Year = {2020}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.8b00536}} + +@article{Tubman_2016, + Author = {Tubman, Norm M. and Lee, Joonho and Takeshita, Tyler Y. and {Head-Gordon}, Martin and Whaley, K. Birgitta}, + Date-Added = {2020-08-18 21:12:46 +0200}, + Date-Modified = {2020-08-20 10:17:19 +0200}, + Doi = {10.1063/1.4955109}, + File = {/Users/loos/Zotero/storage/VDKR3CTF/Tubman16.pdf}, + Issn = {0021-9606, 1089-7690}, + Journal = {J. Chem. Phys.}, + Language = {en}, + Month = jul, + Number = {4}, + Pages = {044112}, + Title = {A Deterministic Alternative to the Full Configuration Interaction Quantum {{Monte Carlo}} Method}, + Volume = {145}, + Year = {2016}, + Bdsk-Url-1 = {https://doi.org/10.1063/1.4955109}} + +@article{Lee_2020, + Author = {Joonho Lee and Fionn D. Malone and David R. 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Weakly Correlated Regime}, + Volume = {14}, + Year = {2018}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.8b00680}} + +@article{Eriksen_2020, + Author = {Janus J. Eriksen and Tyler A. Anderson and J. Emiliano Deustua and Khaldoon Ghanem and Diptarka Hait and Mark R. Hoffmann and Seunghoon Lee and Daniel S. Levine and Ilias Magoulas and Jun Shen and Norman M. Tubman and K. Birgitta Whaley and Enhua Xu and Yuan Yao and Ning Zhang and Ali Alavi and Garnet Kin-Lic Chan and Martin Head-Gordon and Wenjian Liu and Piotr Piecuch and Sandeep Sharma and Seiichiro L. Ten-no and C. J. Umrigar and J{\"u}rgen Gauss}, + Date-Modified = {2020-10-09 09:34:57 +0200}, + Doi = {10.1021/acs.jpclett.0c02621}, + Journal = {J. Phys. Chem. 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Phys.}, + Month = {Mar}, + Number = {12}, + Pages = {124114}, + Publisher = {AIP Publishing}, + Title = {Adaptive multiconfigurational wave functions}, + Url = {http://dx.doi.org/10.1063/1.4869192}, + Volume = {140}, + Year = {2014}, + Bdsk-Url-1 = {http://dx.doi.org/10.1063/1.4869192}} + +@article{Schriber_2016, + Author = {Schriber, Jeffrey B. and Evangelista, Francesco A.}, + Date-Added = {2020-08-02 18:18:29 +0200}, + Date-Modified = {2020-08-02 18:18:29 +0200}, + Doi = {10.1063/1.4948308}, + File = {Full Text PDF:/home/scemama/Dropbox/Zotero/storage/XR99ZTDH/Schriber and Evangelista - 2016 - Communication An adaptive configuration interacti.pdf:application/pdf;Snapshot:/home/scemama/Dropbox/Zotero/storage/6KITP3BL/1.html:text/html}, + Issn = {0021-9606}, + Journal = {J. Chem. Phys.}, + Month = apr, + Number = {16}, + Pages = {161106}, + Shorttitle = {Communication}, + Title = {Communication: {An} adaptive configuration interaction approach for strongly correlated electrons with tunable accuracy}, + Url = {http://aip.scitation.org/doi/abs/10.1063/1.4948308}, + Urldate = {2017-11-17}, + Volume = {144}, + Year = {2016}, + Bdsk-Url-1 = {http://aip.scitation.org/doi/abs/10.1063/1.4948308}, + Bdsk-Url-2 = {http://dx.doi.org/10.1063/1.4948308}} + +@article{Schriber_2017, + Author = {Schriber, Jeffrey B. and Evangelista, Francesco A.}, + Date-Added = {2020-08-02 18:18:29 +0200}, + Date-Modified = {2020-08-02 18:18:29 +0200}, + Doi = {10.1021/acs.jctc.7b00725}, + Journal = {J. Chem. Theory Comput.}, + Month = {Oct}, + Publisher = {American Chemical Society}, + Title = {{Adaptive Configuration Interaction for Computing Challenging Electronic Excited States with Tunable Accuracy}}, + Year = {2017}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.7b00725}} + +@article{Evangelisti_1983, + Author = {Stefano Evangelisti and Jean-Pierre Daudey and Jean-Paul Malrieu}, + Date-Added = {2020-08-02 18:18:19 +0200}, + Date-Modified = {2020-08-17 08:49:23 +0200}, + Doi = {10.1016/0301-0104(83)85011-3}, + Journal = {Chem. Phys.}, + Month = {feb}, + Number = {1}, + Pages = {91--102}, + Publisher = {Elsevier {BV}}, + Title = {Convergence of an improved {CIPSI} algorithm}, + Url = {https://doi.org/10.1016%2F0301-0104%2883%2985011-3}, + Volume = {75}, + Year = 1983, + Bdsk-Url-1 = {https://doi.org/10.1016%2F0301-0104%2883%2985011-3}, + Bdsk-Url-2 = {https://doi.org/10.1016/0301-0104(83)85011-3}} + +@article{Booth_2009, + Author = {George H. Booth and Alex J. W. 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Phys.}, + Month = {jan}, + Number = {4}, + Pages = {041103}, + Publisher = {{AIP} Publishing}, + Title = {Communications: Survival of the fittest: Accelerating convergence in full configuration-interaction quantum Monte Carlo}, + Url = {https://doi.org/10.1063%2F1.3302277}, + Volume = {132}, + Year = 2010, + Bdsk-Url-1 = {https://doi.org/10.1063%2F1.3302277}, + Bdsk-Url-2 = {https://doi.org/10.1063/1.3302277}} + +@article{Garniron_2018, + Author = {Y. Garniron and A. Scemama and E. Giner and M. Caffarel and P. F. Loos}, + Date-Added = {2020-08-02 17:40:11 +0200}, + Date-Modified = {2020-08-17 08:48:49 +0200}, + Doi = {10.1063/1.5044503}, + Journal = {J. Chem. Phys.}, + Pages = {064103}, + Title = {Selected Configuration Interaction Dressed by Perturbation}, + Volume = {149}, + Year = {2018}, + Bdsk-Url-1 = {https://doi.org/10.1063/1.5044503}} + +@article{Loos_2018a, + Author = {P. F. Loos and A. Scemama and A. Blondel and Y. Garniron and M. Caffarel and D. Jacquemin}, + Date-Added = {2020-08-02 17:39:54 +0200}, + Date-Modified = {2020-08-02 17:39:54 +0200}, + Doi = {10.1021/acs.jctc.8b00406}, + Journal = {J. Chem. Theory Comput.}, + Pages = {4360}, + Title = {A Mountaineering Strategy to Excited States: Highly-Accurate Reference Energies and Benchmarks}, + Volume = {14}, + Year = {2018}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.8b00406}} + +@article{Loos_2019, + Author = {Loos, Pierre-Fran{\c c}ois and Boggio-Pasqua, Martial and Scemama, Anthony and Caffarel, Michel and Jacquemin, Denis}, + Date-Added = {2020-08-02 17:39:50 +0200}, + Date-Modified = {2020-08-02 17:39:50 +0200}, + Doi = {10.1021/acs.jctc.8b01205}, + Journal = {J. Chem. Theory Comput.}, + Number = {3}, + Pages = {1939--1956}, + Title = {Reference Energies for Double Excitations}, + Volume = {15}, + Year = {2019}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.8b01205}} + +@article{Loos_2020a, + Author = {P. F. Loos and A. Scemama and D. Jacquemin}, + Date-Added = {2020-08-02 17:37:34 +0200}, + Date-Modified = {2020-08-19 17:13:00 +0200}, + Doi = {10.1021/acs.jpclett.0c00014}, + Journal = {J. Phys. Chem. Lett.}, + Pages = {2374--2383}, + Title = {The Quest for Highly-Accurate Excitation Energies: a Computational Perspective}, + Volume = {11}, + Year = {2020}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jpclett.0c00014}} + +@article{Loos_2020b, + Author = {P. F. Loos and F. Lipparini and M. Boggio-Pasqua and A. Scemama and D. Jacquemin}, + Date-Added = {2020-08-02 17:37:29 +0200}, + Date-Modified = {2020-08-02 17:37:29 +0200}, + Doi = {10.1021/acs.jctc.9b01216}, + Journal = {J. Chem. Theory Comput.}, + Pages = {1711}, + Title = {A Mountaineering Strategy to Excited States: Highly-Accurate Energies and Benchmarks for Medium Size Molecules,}, + Volume = {16}, + Year = {2020}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.9b01216}} + +@article{Loos_2020c, + Author = {P. F. Loos and A. Scemama and M. Boggio-Pasqua and D. Jacquemin}, + Date-Added = {2020-08-02 17:37:29 +0200}, + Date-Modified = {2020-08-02 17:37:29 +0200}, + Doi = {10.1021/acs.jctc.0c00227}, + Journal = {J. Chem. Theory Comput.}, + Pages = {3720--3736}, + Title = {A Mountaineering Strategy to Excited States: Highly-Accurate Energies and Benchmarks for Exotic Molecules and Radicals}, + Volume = {16}, + Year = {2020}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.9b01216}} + +@article{Chien_2018, + Author = {Chien, Alan D. and Holmes, Adam A. and Otten, Matthew and Umrigar, C. J. and Sharma, Sandeep and Zimmerman, Paul M.}, + Date-Added = {2020-08-02 17:36:33 +0200}, + Date-Modified = {2020-10-09 13:24:02 +0200}, + Doi = {10.1021/acs.jpca.8b01554}, + Journal = {J. Phys. Chem. 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W. and Alavi, Ali}, + Date-Added = {2020-08-02 17:35:58 +0200}, + Date-Modified = {2020-08-02 17:35:58 +0200}, + Doi = {10.1063/1.3624383}, + Issn = {0021-9606, 1089-7690}, + Journal = {J. Chem. Phys.}, + Month = aug, + Number = {8}, + Pages = {084104}, + Shorttitle = {Breaking the Carbon Dimer}, + Title = {Breaking the Carbon Dimer: {{The}} Challenges of Multiple Bond Dissociation with Full Configuration Interaction Quantum {{Monte Carlo}} Methods}, + Volume = {135}, + Year = {2011}, + Bdsk-Url-1 = {https://doi.org/10.1063/1.3624383}} + +@article{Sharma_2017, + Author = {Sharma, Sandeep and Holmes, Adam A. and Jeanmairet, Guillaume and Alavi, Ali and Umrigar, C. J.}, + Date-Added = {2020-08-02 17:35:54 +0200}, + Date-Modified = {2020-08-02 17:35:54 +0200}, + Doi = {10.1021/acs.jctc.6b01028}, + Issn = {1549-9626}, + Journal = {J. Chem. Theory Comput.}, + Month = {Mar}, + Number = {4}, + Pages = {1595--1604}, + Publisher = {American Chemical Society (ACS)}, + Title = {Semistochastic Heat-Bath Configuration Interaction Method: Selected Configuration Interaction with Semistochastic Perturbation Theory}, + Url = {http://dx.doi.org/10.1021/acs.jctc.6b01028}, + Volume = {13}, + Year = {2017}, + Bdsk-Url-1 = {http://dx.doi.org/10.1021/acs.jctc.6b01028}} + +@article{Garniron_2019, + Author = {Garniron, Yann and Applencourt, Thomas and Gasperich, Kevin and Benali, Anouar and Fert{\'e}, Anthony and Paquier, Julien and Pradines, Barth{\'e}l{\'e}my and Assaraf, Roland and Reinhardt, Peter and Toulouse, Julien and Barbaresco, Pierrette and Renon, Nicolas and David, Gr{\'e}goire and Malrieu, Jean-Paul and V{\'e}ril, Micka{\"e}l and Caffarel, Michel and Loos, Pierre-Fran{\c c}ois and Giner, Emmanuel and Scemama, Anthony}, + Doi = {10.1021/acs.jctc.9b00176}, + Issn = {1549-9618}, + Journal = {J. Chem. 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Chem.}, + Pages = {938--951}, + Title = {{Quantum Monte Carlo for large chemical systems: Implementing efficient strategies for petascale platforms and beyond}}, + Volume = {34}, + Year = {2013}, + Bdsk-Url-1 = {https://doi.org/10.1002/jcc.23216}} + +@article{Caffarel_2016a, + Author = {Caffarel, Michel and Applencourt, Thomas and Giner, Emmanuel and Scemama, Anthony}, + Date-Modified = {2020-08-18 20:50:28 +0200}, + Doi = {10.1063/1.4947093}, + Issn = {0021-9606}, + Journal = {J. Chem. Phys.}, + Month = {Apr}, + Number = {15}, + Pages = {151103}, + Publisher = {American Institute of Physics}, + Title = {{Communication: Toward an improved control of the fixed-node error in quantum Monte Carlo: The case of the water molecule}}, + Volume = {144}, + Year = {2016}, + Bdsk-Url-1 = {https://doi.org/10.1063/1.4947093}} + +@article{Holmes_2017, + Author = {Holmes, Adam A. and Umrigar, C. J. and Sharma, Sandeep}, + Doi = {10.1063/1.4998614}, + Issn = {0021-9606}, + Journal = {J. Chem. 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Phys.}, + Month = {Jul}, + Number = {3}, + Pages = {034108}, + Publisher = {American Institute of Physics}, + Title = {{Excitation energies from diffusion Monte Carlo using selected configuration interaction nodes}}, + Volume = {149}, + Year = {2018}, + Bdsk-Url-1 = {https://doi.org/10.1063/1.5041327}} + +@article{Giner_2015, + Author = {Giner, Emmanuel and Scemama, Anthony and Caffarel, Michel}, + Doi = {10.1063/1.4905528}, + Issn = {0021-9606}, + Journal = {J. Chem. Phys.}, + Month = {Jan}, + Number = {4}, + Pages = {044115}, + Publisher = {American Institute of Physics}, + Title = {{Fixed-node diffusion Monte Carlo potential energy curve of the fluorine molecule F2 using selected configuration interaction trial wavefunctions}}, + Volume = {142}, + Year = {2015}, + Bdsk-Url-1 = {https://doi.org/10.1063/1.4905528}} + +@article{Huron_1973, + Author = {Huron, B. and Malrieu, J. P. and Rancurel, P.}, + Doi = {10.1063/1.1679199}, + Issn = {0021-9606}, + Journal = {J. Chem. Phys.}, + Month = {Jun}, + Number = {12}, + Pages = {5745--5759}, + Publisher = {American Institute of Physics}, + Title = {{Iterative perturbation calculations of ground and excited state energies from multiconfigurational zeroth{-}order wavefunctions}}, + Volume = {58}, + Year = {1973}, + Bdsk-Url-1 = {https://doi.org/10.1063/1.1679199}} + +@article{Holmes_2016, + Author = {Holmes, Adam A. and Changlani, Hitesh J. and Umrigar, C. J.}, + Doi = {10.1021/acs.jctc.5b01170}, + Issn = {1549-9618}, + Journal = {J. Chem. Theory Comput.}, + Month = {Apr}, + Number = {4}, + Pages = {1561--1571}, + Publisher = {American Chemical Society}, + Title = {{Efficient Heat-Bath Sampling in Fock Space}}, + Volume = {12}, + Year = {2016}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.5b01170}} + +@article{Bender_1969, + Author = {Bender, Charles F. and Davidson, Ernest R.}, + Doi = {10.1103/PhysRev.183.23}, + Issn = {1536-6065}, + Journal = {Phys. Rev.}, + Month = {Jul}, + Number = {1}, + Pages = {23--30}, + Publisher = {American Physical Society}, + Title = {{Studies in Configuration Interaction: The First-Row Diatomic Hydrides}}, + Volume = {183}, + Year = {1969}, + Bdsk-Url-1 = {https://doi.org/10.1103/PhysRev.183.23}} + +@article{Buenker_1974, + Author = {Buenker, Robert J. and Peyerimhoff, Sigrid D.}, + Doi = {10.1007/BF02394557}, + Issn = {1432-2234}, + Journal = {Theor. Chim. Acta}, + Month = {Aug}, + Number = {1}, + Pages = {33--58}, + Publisher = {Springer-Verlag}, + Title = {{Individualized configuration selection in CI calculations with subsequent energy extrapolation}}, + Volume = {35}, + Year = {1974}, + Bdsk-Url-1 = {https://doi.org/10.1007/BF02394557}} + +@article{Liu_2016, + Author = {Liu, Wenjian and Hoffmann, Mark R.}, + Doi = {10.1021/acs.jctc.5b01099}, + Issn = {1549-9618}, + Journal = {J. Chem. Theory Comput.}, + Month = {Mar}, + Number = {3}, + Pages = {1169--1178}, + Publisher = {American Chemical Society}, + Title = {{iCI: Iterative CI toward full CI}}, + Volume = {12}, + Year = {2016}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.5b01099}} + +@misc{Scemama_2015, + Author = {Scemama, Anthony and Giner, Emmanuel and Applencourt, Thomas and Caffarel, Michel}, + Doi = {10.13140/RG.2.1.3187.9766}, + Howpublished = {Pacifichem, Advances in Quantum Monte Carlo}, + Month = {Dec}, + Title = {{QMC using very large configuration interaction-type expansions}}, + Year = {2015}, + Bdsk-Url-1 = {https://doi.org/10.13140/RG.2.1.3187.9766}} + +@misc{Applencourt_2018, + Archiveprefix = {arXiv}, + Author = {Thomas Applencourt and Kevin Gasperich and Anthony Scemama}, + Eprint = {1812.06902}, + Primaryclass = {physics.chem-ph}, + Title = {Spin adaptation with determinant-based selected configuration interaction}, + Year = {2018}} diff --git a/Manuscript/Ec.tex b/Manuscript/Ec.tex new file mode 100644 index 0000000..f4f66af --- /dev/null +++ b/Manuscript/Ec.tex @@ -0,0 +1,73 @@ +\documentclass[aps,prb,reprint,noshowkeys,superscriptaddress]{revtex4-1} +\usepackage{graphicx,dcolumn,bm,xcolor,microtype,multirow,amscd,amsmath,amssymb,amsfonts,physics,wrapfig,txfonts} +\usepackage[version=4]{mhchem} + +\newcommand{\ie}{\textit{i.e.}} +\newcommand{\eg}{\textit{e.g.}} +\newcommand{\alert}[1]{\textcolor{black}{#1}} +\usepackage[normalem]{ulem} +\newcommand{\titou}[1]{\textcolor{red}{#1}} +\newcommand{\trashPFL}[1]{\textcolor{red}{\sout{#1}}} +\newcommand{\PFL}[1]{\titou{(\underline{\bf PFL}: #1)}} +\newcommand{\toto}[1]{\textcolor{green}{#1}} +\newcommand{\trashAS}[1]{\textcolor{green}{\sout{#1}}} +\newcommand{\AS}[1]{\toto{(\underline{\bf AS}: #1)}} + +\newcommand{\mc}{\multicolumn} +\newcommand{\fnm}{\footnotemark} +\newcommand{\fnt}{\footnotetext} +\newcommand{\tabc}[1]{\multicolumn{1}{c}{#1}} +\newcommand{\QP}{\textsc{quantum package}} + +\usepackage[ + colorlinks=true, + citecolor=blue, + breaklinks=true + ]{hyperref} +\urlstyle{same} + +\begin{document} + +\newcommand{\LCPQ}{Laboratoire de Chimie et Physique Quantiques (UMR 5626), Universit\'e de Toulouse, CNRS, UPS, France} +\newcommand{\CEISAM}{Universit\'e de Nantes, CNRS, CEISAM UMR 6230, F-44000 Nantes, France} + +\title{Reference correlation energies in finite Hilbert spaces: five- and six-membered rings} + +\author{Micka\"el V\'eril} +\affiliation{\LCPQ} +\author{Yann Damour} +\affiliation{\LCPQ} +\author{Anthony Scemama} +\affiliation{\LCPQ} +\author{Denis Jacquemin} +\affiliation{\CEISAM} +\author{Pierre-Fran\c{c}ois Loos} +\email{loos@irsamc.ups-tlse.fr} +\affiliation{\LCPQ} + +% Abstract +\begin{abstract} +\end{abstract} + +% Title +\maketitle + +\section{Introduction} + +\section{Computational details} + +\section{Results and discussion} + +\section{Conclusion} + +\begin{acknowledgements} +This work was performed using HPC resources from GENCI-TGCC (2020-gen1738) and from CALMIP (Toulouse) under allocation 2020-18005. +PFL and AS have received funding from the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme (Grant agreement No.~863481). +\end{acknowledgements} + +\section*{Data availability statement} +The data that support the findings of this study are openly available in Zenodo at \href{http://doi.org/XX.XXXX/zenodo.XXXXXXX}{http://doi.org/XX.XXXX/zenodo.XXXXXXX}. + +\bibliography{Ec} + +\end{document} From 2ca637dfc5bb6c581a2ed4a7e433117926efc5be Mon Sep 17 00:00:00 2001 From: Pierre-Francois Loos Date: Mon, 2 Nov 2020 20:39:39 +0100 Subject: [PATCH 2/5] data Denis --- CC_cc-pvdz_5mem.txt | 146 ++++ furan/cc-pvdz/CC/fura-gs-cc3.out | 985 +++++++++++++++++++++++++ furan/cc-pvdz/CC/fura-gs-cc4.out | 1001 ++++++++++++++++++++++++++ furan/cc-pvdz/CC/fura-gs-ccsd.out | 1029 +++++++++++++++++++++++++++ furan/cc-pvdz/CC/fura-gs-ccsdt.out | 1011 ++++++++++++++++++++++++++ furan/cc-pvdz/CC/fura-gs-ccsdtq.out | 1028 ++++++++++++++++++++++++++ furan/cc-pvdz/FromDenis.txt | 26 - 7 files changed, 5200 insertions(+), 26 deletions(-) create mode 100644 CC_cc-pvdz_5mem.txt create mode 100644 furan/cc-pvdz/CC/fura-gs-cc3.out create mode 100644 furan/cc-pvdz/CC/fura-gs-cc4.out create mode 100644 furan/cc-pvdz/CC/fura-gs-ccsd.out create mode 100644 furan/cc-pvdz/CC/fura-gs-ccsdt.out create mode 100644 furan/cc-pvdz/CC/fura-gs-ccsdtq.out delete mode 100644 furan/cc-pvdz/FromDenis.txt diff --git a/CC_cc-pvdz_5mem.txt b/CC_cc-pvdz_5mem.txt new file mode 100644 index 0000000..83e9171 --- /dev/null +++ b/CC_cc-pvdz_5mem.txt @@ -0,0 +1,146 @@ +=============== +Cyclopentadiene +=============== + +C 0.00000000 0.00000000 -2.33113051 +C 0.00000000 2.22209092 -0.56871188 +C 0.00000000 -2.22209092 -0.56871188 +C 0.00000000 1.38514451 1.83772922 +C 0.00000000 -1.38514451 1.83772922 +H 1.66130504 0.00000000 -3.56414299 +H -1.66130504 0.00000000 -3.56414299 +H 0.00000000 4.16550405 -1.18116624 +H 0.00000000 -4.16550405 -1.18116624 +H 0.00000000 2.54514584 3.51352303 +H 0.00000000 -2.54514584 3.51352303 + +cc-pVDZ 100 BF + +Cfour +HF -192.808319784581 +MP2 -193.471694583002 -0.663374798421 +CCSD -193.515557363805186 -0.707237579224683 +CC3 -193.544894006853781 -0.736574222273275 +CCSDT -193.544566492999309 -0.736246708418799 +CC4 -193.546686469127337 -0.738366684546823 +CCSDTQ + +===== +Furan +===== + +C 0.00000000 2.06365826 -0.60051250 +C 0.00000000 -2.06365826 -0.60051250 +C 0.00000000 1.35348578 1.86336416 +C 0.00000000 -1.35348578 1.86336416 +O 0.00000000 0.00000000 -2.13945332 +H 0.00000000 3.86337287 -1.53765695 +H 0.00000000 -3.86337287 -1.53765695 +H 0.00000000 2.59168789 3.47168051 +H 0.00000000 -2.59168789 3.47168051 + +cc-pVDZ 90 BF + +Cfour +HF -228.643312572484575 +MP2 -229.350762946309 -0.707450373824 +CCSD -229.378285257894248 -0.734972685409664 +CC3 -229.409042621239877 -0.765730048755297 +CCSDT -229.407644692870491 -0.764332120385917 +CC4 -229.410178829371802 -0.766866256888079 +CCSDTQ -229.409966781261375 -0.76665420877679 + +Dalton +HF -228.643312572485 +MP2 -229.3507629658025451 +CC2 -229.360495928343 +CCSD -229.3782852538 +CC3 -229.4090426487 + +MRCC +HF -228.6433125723933699 +MP2 -229.350762954683 +CCSD -229.37828519649 -0.734972624097 +CC3 -229.409042619076 +CCSDT -229.407644699645 +CC4 -229.410178825868 + +CISD -229.260645347830 +CISDT -229.27741998 + +========= +Imidazole +========= + +C 0.41662795 2.06006259 0.00000000 +C -1.52618386 -1.62343163 0.00000000 +C 1.04160471 -1.93007427 0.00000000 +N -1.90345764 0.94914956 0.00000000 +N 2.24215443 0.38083431 0.00000000 +H 0.65501634 4.07748278 0.00000000 +H -3.57500545 1.84103166 0.00000000 +H -3.06363894 -2.94559167 0.00000000 +H 2.08673940 -3.67001102 0.00000000 + +cc-pVDZ 90 BF + +Cfour +HF -224.835356714467 +MP2 -225.555786629729 -0.720429915262 +CCSD -225.579555600773460 -0.744198886306645 +CC3 -225.611468227039040 -0.776111512572204 +CCSDT -225.609907888416501 -0.774551173949665 +CC4 -225.612560996345906 -0.777204281879068 +CCSDTQ + +======= +Pyrrole +======= + +C 0.00000000 2.11924634 0.62676569 +C 0.00000000 -2.11924634 0.62676569 +C 0.00000000 1.34568862 -1.85506908 +C 0.00000000 -1.34568862 -1.85506908 +N 0.00000000 0.00000000 2.10934391 +H 0.00000000 0.00000000 4.00257355 +H 0.00000000 3.97648410 1.44830201 +H 0.00000000 -3.97648410 1.44830201 +H 0.00000000 2.56726559 -3.47837232 +H 0.00000000 -2.56726559 -3.47837232 + +cc-pVDZ 95 BF + +Cfour +HF -208.828614693633 +MP2 -209.524336644342 -0.695721950709 +CCSD -209.554327546276966 -0.725712852643528 +CC3 -209.584885457786328 -0.756270764152895 +CCSDT -209.583798415096226 -0.755183721462796 +CC4 -209.586191075800997 -0.757576382167585 +CCSDTQ + +========= +Thiophene +========= + +C 0.00000000 2.33342542 -0.09858421 +C 0.00000000 -2.33342542 -0.09858421 +C 0.00000000 1.34371718 -2.48297725 +C 0.00000000 -1.34371718 -2.48297725 +S 0.00000000 0.00000000 2.17250692 +H 0.00000000 4.29028016 0.44577296 +H 0.00000000 -4.29028016 0.44577296 +H 0.00000000 2.48760051 -4.16768392 +H 0.00000000 -2.48760051 -4.16768392 + +cc-pVDZ 94 BF + +Cfour +HF -551.321002444800 +MP2 -551.982490121638 -0.661487676839 +CCSD -552.015457778804375 -0.694455334004781 +CC3 -552.047270750728444 -0.726268305928940 +CCSDT -552.046137469176301 -0.725135024376793 +CC4 -552.048664989321765 -0.727662544525096 +CCSDTQ + diff --git a/furan/cc-pvdz/CC/fura-gs-cc3.out b/furan/cc-pvdz/CC/fura-gs-cc3.out new file mode 100644 index 0000000..e0daf0c --- /dev/null +++ b/furan/cc-pvdz/CC/fura-gs-cc3.out @@ -0,0 +1,985 @@ + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xjoda + + + ************************************************************************* + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + ************************************************************************* + + **************************************************************** + * CFOUR Coupled-Cluster techniques for Computational Chemistry * + **************************************************************** + + + Department of Chemistry Institut fuer Physikalische Chemie + University of Florida Universitaet Mainz + Gainesville, FL 32611, USA D-55099 Mainz, Germany + + Department of Chemistry Fakultaet fuer Chemie und Biowiss. + Johns Hopkins University Karlsruher Institut fuer Technologie + Baltimore, MD 21218, USA D-76131 Karlsruhe, Germany + + Department of Chemistry Department of Physical Chemistry + Southern Methodist University Eotvos Lorand University + Dallas, TX 75275, USA H-1053 Budapest, Hungary + + + Version 2.1 + + nazare075.cluster + Thu Oct 15 11:17:22 CEST 2020 + integer*8 version is running + +******************************************************************************** +* Input from ZMAT file * +******************************************************************************** +Ketene -GS +C 0.00000000 2.06365826 -0.60051250 +C 0.00000000 -2.06365826 -0.60051250 +C 0.00000000 1.35348578 1.86336416 +C 0.00000000 -1.35348578 1.86336416 +O 0.00000000 0.00000000 -2.13945332 +H 0.00000000 3.86337287 -1.53765695 +H 0.00000000 -3.86337287 -1.53765695 +H 0.00000000 2.59168789 3.47168051 +H 0.00000000 -2.59168789 3.47168051 + +*CFOUR(COORD=CARTESIAN,UNITS=BOHR + MEMORY=100,MEM_UNIT=GB,CC_PROG=NCC + FROZEN_CORE=1 + CALC=CC3,BASIS=PVDZ + SCF_CONV=9,CC_CONV=7,ESTATE_MAXCYC=80) + +******************************************************************************** + ------------------------------------------------------------------- + CFOUR Control Parameters + ------------------------------------------------------------------- + External Internal Value Units + Name Name + ------------------------------------------------------------------- + ABCDTYPE IABCDT STANDARD [ 0] *** + ANHARMONIC IANHAR OFF [ 0] *** + ANH_ALGORIT IANALG STANDARD [ 0] *** + ANH_DERIVAT IANDER SECOND [ 1] *** + ANH_MODE ANHMOD VIBRATION [ 0] *** + ANH_STEPSIZ ICUBST 50000 x 10-6 + ANH_SYMMETR IANHSM ABELIAN [ 0] *** + AO_LADDERS IAOLAD SINGLEPASS [ 1] *** + AV_SCF IAVSCF OFF [ 0] *** + BASIS IBASIS PVDZ [ 13] *** + BOTHVECTORS BOTHVC OFF [ 0] *** + BOX_POTENT IPIAB OFF [ 0] *** + BREIT IBREIT OFF [ 0] *** + BRUCK_CONV IBRTOL 10D- 4 *** + BRUECKNER IBRKNR OFF [ 0] *** + BUFFERSIZE IBUFFS 4096 *** + CACHE_RECS ICHREC 10 *** + CALCLEVEL ICLLVL CC3 [ 32] *** + CCORBOPT ICCORB OFF [ 0] x 0.01 + CC_CONV ICCCNV 10D- 7 *** + CC_EXPORDER ICCEOR 5 *** + CC_EXTRAPOL ICCEXT DIIS [ 1] *** + CC_GUESS ICCGES MP2 [ 0] *** + CC_MAXCYC ICCCYC 100 cycles + CC_PROGRAM ICCPRO NCC [ 5] *** + CHARGE ICHRGE 0 *** + CHOLESKY ICHOLE OFF [ 0] *** + CIS_CONV ICISTL 5 *** + COMM_SIZE IPSIZE *** *** + CONSTANT ICONST OLD [ 1] *** + CONTINUUM ICONTU NONE [ 0] *** + CONTRACTION ICNTYP GENERAL [ 1] *** + COORDINATES ICOORD CARTESIAN [ 1] *** + CPHF_CONVER ICPHFT 10D- 16 *** + CPHF_MAXCYC ICPHFC 64 cycles + CUBIC ICUBIC OFF [ 0] *** + CURVILINEAR ICURVY OFF [ 0] *** + DBOC IDBOC OFF [ 0] *** + DCT IDCT OFF [ 0] *** + DERIV_LEV IDRLVL ZERO [ 0] *** + DEVMEM_SIZE IDVMEM ********* MByte + DIAG_MRCC IEOMST 10D- 0 *** + DIFF_TYPE IDIFTY RELAXED [ 0] *** + DIRECT IDIRCT OFF [ 0] *** + DROPMO IDRPMO NONE + ECP IECP OFF [ 0] *** + EIGENVECTOR IVEC 1 *** + EL_ANHARM IELANH OFF [ 0] *** + EOMFOLLOW IEOMSR ENERGY [ 0] *** + EOMIP IEOMIP OFF [ 0] *** + EOMLEVEL HBARFM SAME [ 0] *** + EOM_MRCC IMRCCE NEW [ 1] *** + EOM_NONIT EOMNON OFF [ 0] *** + EOM_NSING IEOMSI 10D- 0 *** + EOM_NSTATES IMRCCD DAVIDSON [ 0] *** + EOM_NTRIP IEOMTR 10D- 0 *** + EOM_ORDER IEXORD ENERGY [ 0] *** + EOM_PROPSTA IEOMST 0 *** + ESTATE_CONV IEXTOL 10D- 5 *** + ESTATE_DIAG IEXDIG ITERATIVE [ 0] *** + ESTATE_LOCK IESLOC ON [ 1] *** + ESTATE_MAXC IEXMXC 80 *** + ESTATE_PROP IEXPRP OFF [ 0] *** + EVAL_HESS IRECAL 0 # of cyc. + EXCITATION IEXCIT 0 *** + EXCITE IEXCIT NONE [ 0] *** + EXTERN_POT IEXPOT OFF [ 0] *** + FCGRADNEW IFCGNW OFF [ 0] *** + FC_FIELD IFINFC 0 x 10-6 + FD_CALTYPE IFDCAL GRADONLY [ 0] *** + FD_PROJECT IFDPRJ OFF [ 1] *** + FD_STEPSIZE IDISFD 0 10-4 bohr + FD_USEGROUP IFDGRP FULL [ 0] *** + FILE_RECSIZ IFLREC 4096 words + FINITE_PERT IFIPER 0 x 10-6 + FIXGEOM IFIXGM OFF [ 0] *** + FOCK IFOCK AO [ 1] *** + FREQ_ALGORI IVIALG STANDARD [ 0] *** + FROZEN_CORE IFROCO ON [ 1] *** + GAMMA_ABCD IGABCD STORE [ 0] *** + GAMMA_ABCI IGABCI STORE [ 0] *** + GENBAS_1 IGNBS1 0 *** + GENBAS_2 IGNBS2 0 *** + GENBAS_3 IGNBS3 0 *** + GENBAS_4 IGNBS4 0 *** + GEO_CONV ICONTL 5 H/bohr + GEO_MAXCYC IOPTCY 50 *** + GEO_MAXSTEP IMXSTP 300 millibohr + GEO_METHOD INR SINGLE_POINT[ 5] *** + GIAO IGIAO OFF [ 1] *** + GIMIC IGIMIC OFF [ 0] *** + GRID IGRID OFF [ 0] *** + GRID_ALGO IGALGO SERIAL [ 0] *** + GUESS IGUESS MOREAD [ 0] *** + HBAR IHBAR OFF [ 0] *** + HESS_TYPE IHESTP SCF [ 0] *** + HF2_FILE IHF2Fl USE [ 1] *** + HFSTABILITY ISTABL OFF [ 0] *** + INCORE INCORE OFF [ 0] *** + INPUT_MRCC IMRCC ON [ 1] *** + INTEGRALS INTTYP VMOL [ 1] *** + JODA_PRINT IJPRNT 0 *** + KEYWORD_OUT IDMPKW NO [ 0] *** + LINDEP_TOL ILINDP 8 *** + LINEQ_CONV IZTACN 10D- 7 cycles + LINEQ_EXPOR ILMAXD 5 *** + LINEQ_MAXCY ILMAXC 100 *** + LINEQ_TYPE ILTYPE DIIS [ 1] *** + LOCK_ORBOCC ILOCOC OFF [ 0] *** + MEMORY_SIZE IMEMSZ ********* words + MEM_UNIT IMEMU GB [ 3] *** + MRCC IMRCCC OFF [ 0] *** + MULTIPLICTY IMULTP 1 *** + NACOUPLING IVCOUP OFF [ 0] *** + NEGEVAL IDIE ABORT [ 0] *** + NEWNORM INEWNO OFF [ 0] *** + NON-HF INONHF OFF [ 0] *** + NTOP_TAMP ITOPT2 15 *** + NUC_MODEL INUCMO POINT [ 0] *** + OCCUPATION IOCCU ESTIMATED BY SCF + OPEN-SHELL IOPEN SPIN-ORBITAL[ 0] *** + OPTVIB IOPTVB OFF [ 0] *** + ORBITALS IORBTP STANDARD [ 0] *** + PARALLEL IPARAL ON [ 1] *** + PARA_INT IPINTS ON [ 1] *** + PARA_PRINT IPPRIN 0 *** + PERT_ORB IPTORB STANDARD [ 0] *** + POINTS IGRDFD 0 *** + PRINT IPRNT 0 *** + PROPS IPROPS OFF [ 0] *** + PROP_INTEGR IINTYP INTERNAL [ 0] *** + PSI IPSI OFF [ 0] *** + QC_ALG IQCALG FLM [ 0] *** + QC_LINALG IQCLIN TRIDIAG [ 2] *** + QC_MAXCYC IQCMAX 10D-100 cycles + QC_MAXSCFCY IQCMSC 10D- 15 cycles + QC_RTRUST IQCRTR 10D- 0 x 10-3 + QC_SKIPSCF IQCSKI OFF [ 0] *** + QC_START IQCSTA 10D- 1 *** + QRHFGUESS IQGUES OFF [ 0] *** + QUARTIC IQUART OFF [ 0] *** + RAMAN_INT IRAMIN OFF [ 0] *** + RAMAN_ORB IRAMRE UNRELAXED [ 0] *** + RDO IRDOFM OFF [ 0] *** + REDUCE_REPR REDREP Ir [ 0] *** + REFERENCE IREFNC RHF [ 0] *** + RELATIVIST IRELAT OFF [ 0] *** + RELAX_DENS IRDENS OFF [ 0] *** + RESET_FLAGS IRESET OFF [ 0] *** + RESTART_CC ICCRES OFF [ 0] *** + ROT_EVEC ROTVEC 0 *** + SAVE_INTS ISVINT OFF [ 0] *** + SCALE_ON ISTCRT 0 *** + SCF_CONV ISCFCV 10D- 9 *** + SCF_DAMPING IDAMP 0 x 10-3 + SCF_EXPORDE IRPPOR 6 *** + SCF_EXPSTAR IRPPLS 8 *** + SCF_EXTRAPO IRPP ON [ 1] *** + SCF_MAXCYC ISCFCY 150 cycles + SCF_NOSTOP ISCFST OFF [ 0] *** + SCF_PRINT ISCFPR 0 *** + SCF_PROG ISCFPR SCF [ 0] *** + SD_FIELD IFINSD 0 x 10-6 + SOPERT IPERSO OFF [ 0] *** + SPHERICAL IDFGHI ON [ 1] *** + SPINORBIT ISOCAL OFF [ 0] *** + SPINROTATIO ISRCON OFF [ 0] *** + SPIN_FLIP ISPFLP OFF [ 0] *** + SPIN_ORBIT ISPORB OFF [ 0] *** + SPIN_SCAL ISCSMP OFF [ 0] *** + STEEPSCALE ISTPSC 1000 x 10-3 + SUBGROUP ISUBGP DEFAULT [ 0] *** + SUBGRPAXIS ISBXYZ X [ 0] *** + SYMMETRY ISYM ON [ 0] *** + SYM_CHECK ISYMCK OVERRIDE [ 1] *** + T3_EXTRAPOL IT3EXT ON [ 1] *** + T4_EXTRAPOL IT4EXP OFF [ 0] *** + TAMP_SUM IEVERY 5 *** + TESTSUITE ITESTS OFF [ 0] *** + THERMOCH ITHERM OFF [ 0] *** + TOL_CHOLESK ITOLCH 10D- 4 *** + TRANGRAD IRESRM OFF [ 0] *** + TRANS_INV ITRAIN USE [ 0] *** + TREAT_PERT ITREAT SIMULTANEOUS[ 0] *** + TRIP_ALGORI ITRALG NORMAL [ 0] *** + UIJ_THRESHO IUIJTH 1 *** + UNITS IUNITS BOHR [ 1] *** + UNOS IUNOS OFF [ 0] *** + UPDATE_HESS IHUPDT ON [ 1] *** + VIBPHASE ISETPH STANDARD [ 0] *** + VIBRATION IVIB NO [ 0] *** + VIB_ALGORIT IGEALG STANDARD [ 0] *** + VNATORB IVNORB OFF [ 0] *** + VTRAN IVTRAN FULL/PARTIAL[ 0] *** + XFIELD IXEFLD 0 x 10-6 + XFORM_TOL IXFTOL 10D- 11 *** + YFIELD IYEFLD 0 x 10-6 + ZFIELD IZEFLD 0 x 10-6 + ZSCALE_EXP IZEXPS OFF [ 0] *** + ------------------------------------------------------------------- + @GETXYZ-I, 9 atoms read from ZMAT. + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 +******************************************************************************** + The full molecular point group is C2v . + The largest Abelian subgroup of the full molecular point group is C2v . + The computational point group is C2v . +******************************************************************************** + + + ---------------------------------------------------------------- + Coordinates used in calculation (QCOMP) + ---------------------------------------------------------------- + Z-matrix Atomic Coordinates (in bohr) + Symbol Number X Y Z + ---------------------------------------------------------------- + C 6 0.00000000 -2.06365826 0.60031230 + C 6 0.00000000 2.06365826 0.60031230 + C 6 0.00000000 -1.35348578 -1.86356436 + C 6 0.00000000 1.35348578 -1.86356436 + O 8 0.00000000 0.00000000 2.13925312 + H 1 0.00000000 -3.86337287 1.53745675 + H 1 0.00000000 3.86337287 1.53745675 + H 1 0.00000000 -2.59168789 -3.47188071 + H 1 0.00000000 2.59168789 -3.47188071 + ---------------------------------------------------------------- + + Interatomic distance matrix (Angstroms) + + C C C C O + [ 1] [ 2] [ 3] [ 4] [ 5] + C [ 1] 0.00000 + C [ 2] 2.18408 0.00000 + C [ 3] 1.35691 2.22931 0.00000 + C [ 4] 2.22931 1.35691 1.43247 0.00000 + O [ 5] 1.36226 1.36226 2.23601 2.23601 0.00000 + H [ 6] 1.07375 3.17541 2.23677 3.29549 2.06906 + H [ 7] 3.17541 1.07375 3.29549 2.23677 2.06906 + H [ 8] 2.17295 3.27299 1.07409 2.25451 3.27071 + H [ 9] 3.27299 2.17295 2.25451 1.07409 3.27071 + + H H H H + [ 6] [ 7] [ 8] [ 9] + H [ 6] 0.00000 + H [ 7] 4.08882 0.00000 + H [ 8] 2.73491 4.32378 0.00000 + H [ 9] 4.32378 2.73491 2.74292 0.00000 + rotcon2 + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 + There are 5 frozen-core orbitals. + There are 90 basis functions. + @GEOPT-W, Archive file not created for single-point calculation. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.12/ 1.28 seconds. +--executable xjoda finished with status 0 in 1.76 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol + SERIAL VERSION OF MOLECULE STARTED +******************************************************************************** + INPUT FROM MOL FILE +******************************************************************************** +INTGRL 1 0 1 0 0 0 0 0 0 + *** CFOUR Program System (Release V0.1) *** +Ketene -GS + 5 2 X Y 0.10E-08 0 0 + 9999.00 3.00 + 6.00000000 1 3 1 1 1 +C #1 0.000000000000000 -2.063658260000000 0.600312302999175 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 6.00000000 1 3 1 1 1 +C #2 0.000000000000000 -1.353485780000000 -1.863564357000825 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 8.00000000 1 3 1 1 1 +O #3 0.000000000000000 0.000000000000000 2.139253122999175 + 9 3 + 11720.0000000000 7.100000000000000E-004 -1.600000000000000E-004 + 0.000000000000000E+000 + 1759.00000000000 5.470000000000000E-003 -1.263000000000000E-003 + 0.000000000000000E+000 + 400.800000000000 2.783700000000000E-002 -6.267000000000000E-003 + 0.000000000000000E+000 + 113.700000000000 0.104800000000000 -2.571600000000000E-002 + 0.000000000000000E+000 + 37.0300000000000 0.283062000000000 -7.092400000000000E-002 + 0.000000000000000E+000 + 13.2700000000000 0.448719000000000 -0.165411000000000 + 0.000000000000000E+000 + 5.02500000000000 0.270952000000000 -0.116955000000000 + 0.000000000000000E+000 + 1.01300000000000 1.545800000000000E-002 0.557368000000000 + 0.000000000000000E+000 + 0.302300000000000 -2.585000000000000E-003 0.572759000000000 + 1.00000000000000 + 4 2 + 17.7000000000000 4.301800000000000E-002 0.000000000000000E+000 + 3.85400000000000 0.228913000000000 0.000000000000000E+000 + 1.04600000000000 0.508728000000000 0.000000000000000E+000 + 0.275300000000000 0.460531000000000 1.00000000000000 + 1 1 + 1.18500000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #4 0.000000000000000 -3.863372870000000 1.537456752999175 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #5 0.000000000000000 -2.591687890000000 -3.471880707000825 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 +FINISH + +******************************************************************************** + ONE- AND TWO-ELECTRON INTEGRALS OVER SYMMETRY-ADAPTED AOS ARE CALCULATED. + + SPHERICAL HARMONICS ARE USED. + + INTEGRALS LESS THAN 0.10E-13 ARE NEGLECTED. + + NUCLEAR REPULSION ENERGY : 161.1082297788 A.U. + @MOLECU-I, ONE ELECTRON INTEGRALS (CPU/WALL): 0.02/ 0.03 SECONDS. + @TWOEL-I, 325108 INTEGRALS OF SYMMETRY TYPE I I I I + @TWOEL-I, 908743 INTEGRALS OF SYMMETRY TYPE I J I J + @TWOEL-I, 490042 INTEGRALS OF SYMMETRY TYPE I I J J + @TWOEL-I, 460725 INTEGRALS OF SYMMETRY TYPE I J K L + @TWOEL-I, TOTAL NUMBER OF 2-E INTEGRALS 2184618. + @MOLECU-I, TWO ELECTRON INTEGRALS (CPU/WALL): 1.44/ 1.44 SECONDS. + @CHECKOUT-I, Total execution time (CPU/WALL): 1.47/ 1.49 seconds. + +Running with 20 threads/proc + +--executable xvmol finished with status 0 in 1.98 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol2ja + @GETMEM-I, Allocated 95367 MB of main memory. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.06/ 0.02 seconds. +--executable xvmol2ja finished with status 0 in 0.50 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvscf + There are 90 functions in the AO basis. + + There are 4 irreducible representations. + + Irrep # of functions + 1 35 + 2 13 + 3 31 + 4 11 + + + Parameters for SCF calculation: + SCF reference function: RHF + Maximum number of iterations: 150 + Full symmetry point group: C2v + Computational point group: C2v + Initial density matrix: MOREAD + SCF convergence tolerance: 10**(- 9) + DIIS convergence acceleration: ON + Latest start for DIIS: 8 + DIIS order: 6 + + Memory information: 341888 words required. + Fock matrices are constructed from AO integral file. + @GETMEM-I, Allocated 2 MB of main memory. + Initialization and symmetry analysis required 0.001 seconds. + + @INITGES-I, Occupancies from core Hamiltonian: + + Alpha population by irrep: 9 2 6 1 + Beta population by irrep: 9 2 6 1 + + + total no. of electrons in initial guess : 0.000000000000000E+000 + -------------------------------------------------------------------- + Iteration Total Energy Largest Density Difference + -------------------------------------------------------------------- + 0 161.108229778788910 0.0000000000D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 1 -196.263249175407992 0.1098182460D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 2 -179.889864626336106 0.1675780025D+02 + current occupation vector + 9 1 7 1 + 9 1 7 1 + 3 -180.580457259652945 0.1772125138D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 4 -162.771013663095033 0.1566999730D+02 + current occupation vector + 8 2 7 1 + 8 2 7 1 + 5 -169.943224465301597 0.1454729382D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 6 -160.269967975315780 0.1454634919D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 7 -168.828658617537684 0.1395077743D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 8 -160.232275948463297 0.1395068492D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 9 -209.746508446745025 0.5520995458D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 10 -228.180230304181549 0.2015536648D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 11 -228.454713327495682 0.6531384936D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 12 -228.600329261507483 0.3196758217D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 13 -228.637509917234041 0.7498321731D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 14 -228.642938164599826 0.5250342791D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 15 -228.643241982659248 0.9795506231D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 16 -228.643308522550143 0.3593200395D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 17 -228.643312517846056 0.1473098013D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 18 -228.643312570337258 0.1244041229D-03 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 19 -228.643312572356052 0.2423484470D-04 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 20 -228.643312572476049 0.5414751593D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 21 -228.643312572485769 0.2003507219D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 22 -228.643312572485598 0.8833300562D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 23 -228.643312572484461 0.3139636784D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 24 -228.643312572486110 0.4136764657D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 25 -228.643312572485542 0.9839839787D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 26 -228.643312572486622 0.1838835018D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 27 -228.643312572484007 0.3228508794D-08 + current occupation vector + 9 2 6 1 + 9 2 6 1 + + SCF has converged. + + Density matrix saved to file den.dat + total electron number: 36.0000000000000 + E(SCF)= -228.643312572484575 0.7981584282D-09 + + Eigenvector printing suppressed. + + @PUTMOS-I, Writing converged MOs to NEWMOS. + @PUTMOS-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTMOS-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTMOS-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTMOS-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + @PUTFOCK-I, Writing converged Fock matrix to NEWFOCK. + @PUTFOCK-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTFOCK-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + + + + ORBITAL EIGENVALUES (ALPHA) (1H = 27.2113834 eV) + + MO # E(hartree) E(eV) FULLSYM COMPSYM + ---- -------------------- -------------------- ------- --------- + 1 1 -20.6219765861 -561.1525113512 A1 A1 (1) + 2 49 -11.2892088103 -307.1949892207 B2 B2 (3) + 3 2 -11.2891634657 -307.1937553315 A1 A1 (1) + 4 3 -11.2328159068 -305.6604603025 A1 A1 (1) + 5 50 -11.2318729764 -305.6348018622 B2 B2 (3) + 6 4 -1.4574476329 -39.6591663239 A1 A1 (1) + 7 5 -1.0834872588 -29.4831872086 A1 A1 (1) + 8 51 -1.0036038078 -27.3094479952 B2 B2 (3) + 9 52 -0.8050606676 -21.9068144851 B2 B2 (3) + 10 6 -0.7793049296 -21.2059652251 A1 A1 (1) + 11 7 -0.7372159421 -20.0606656495 A1 A1 (1) + 12 36 -0.6283416633 -17.0980459063 B1 B1 (2) + 13 53 -0.6064452640 -16.5022145907 B2 B2 (3) + 14 54 -0.5741889664 -15.6244761082 B2 B2 (3) + 15 8 -0.5622006055 -15.2982562239 A1 A1 (1) + 16 9 -0.5366322238 -14.6025051862 A1 A1 (1) + 17 37 -0.3944127682 -10.7325170532 B1 B1 (2) + 18 80 -0.3173264428 -8.6348914980 A2 A2 (4) + +++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ + 19 38 0.1616454919 4.3985974562 B1 B1 (2) + 20 10 0.2028007990 5.5184902966 A1 A1 (1) + 21 55 0.2259953076 6.1496449623 B2 B2 (3) + 22 11 0.2331452351 6.3442043789 A1 A1 (1) + 23 81 0.2346526075 6.3852220682 A2 A2 (4) + 24 56 0.2409072580 6.5554197617 B2 B2 (3) + 25 12 0.3379830583 9.1969865830 A1 A1 (1) + 26 57 0.3670668300 9.9883962435 B2 B2 (3) + 27 13 0.4400792390 11.9751648999 A1 A1 (1) + 28 58 0.5035354267 13.7018955503 B2 B2 (3) + 29 14 0.5796551077 15.7732173745 A1 A1 (1) + 30 59 0.6027649445 16.4020680057 B2 B2 (3) + 31 39 0.6720867908 18.2884113425 B1 B1 (2) + 32 15 0.6949257331 18.9098905590 A1 A1 (1) + 33 60 0.7033703399 19.1396799905 B2 B2 (3) + 34 82 0.7176012567 19.5269229246 A2 A2 (4) + 35 61 0.7543801794 20.5277282917 B2 B2 (3) + 36 40 0.7622869649 20.7428828633 B1 B1 (2) + 37 16 0.7651070466 20.8196211868 A1 A1 (1) + 38 17 0.7917408050 21.5443625978 A1 A1 (1) + 39 83 0.8438632537 22.9626865338 A2 A2 (4) + 40 62 0.8844205187 24.0663058221 B2 B2 (3) + 41 18 0.9187910190 25.0015746820 A1 A1 (1) + 42 19 0.9547555380 25.9802189979 A1 A1 (1) + 43 63 0.9634112815 26.2157537519 B2 B2 (3) + 44 64 1.0592164869 28.8227459274 B2 B2 (3) + 45 41 1.0743328454 29.2340829566 B1 B1 (2) + 46 20 1.1352329173 30.8912581602 A1 A1 (1) + 47 65 1.1904894416 32.3948646279 B2 B2 (3) + 48 21 1.1908922750 32.4058262839 A1 A1 (1) + 49 42 1.2129419174 33.0058275576 B1 B1 (2) + 50 66 1.2581407748 34.2357509943 B2 B2 (3) + 51 84 1.2921641151 35.1615731515 A2 A2 (4) + 52 22 1.2994001068 35.3584744953 A1 A1 (1) + 53 43 1.3116428673 35.6916169462 B1 B1 (2) + 54 85 1.3649569984 37.1423682072 A2 A2 (4) + 55 44 1.5283489789 41.5884900335 B1 B1 (2) + 56 23 1.5439841774 42.0139454134 A1 A1 (1) + 57 67 1.5691624192 42.6990802047 B2 B2 (3) + 58 68 1.5969806595 43.4560530082 B2 B2 (3) + 59 24 1.7377154792 47.2856421455 A1 A1 (1) + 60 69 1.7438095776 47.4514709939 B2 B2 (3) + 61 86 1.7443895833 47.4672537511 A2 A2 (4) + 62 25 1.7729617500 48.2447419337 A1 A1 (1) + 63 45 1.8384391578 50.0264727818 B1 B1 (2) + 64 26 1.8727560698 50.9602834298 A1 A1 (1) + 65 46 1.9574193824 53.2640892885 B1 B1 (2) + 66 70 1.9863618073 54.0516527104 B2 B2 (3) + 67 71 2.0036624844 54.5224280672 B2 B2 (3) + 68 87 2.0489211710 55.7539795407 A2 A2 (4) + 69 27 2.0703324397 56.3366097828 A1 A1 (1) + 70 88 2.1357719213 58.1173086059 A2 A2 (4) + 71 28 2.1641427105 58.8893170284 A1 A1 (1) + 72 72 2.1880643996 59.5402592802 B2 B2 (3) + 73 47 2.1914898441 59.6334703659 B1 B1 (2) + 74 29 2.2271655184 60.6042548161 A1 A1 (1) + 75 73 2.2977715809 62.5255434529 B2 B2 (3) + 76 30 2.3793504210 64.7454165492 A1 A1 (1) + 77 89 2.5107047412 68.3197493175 A2 A2 (4) + 78 74 2.5407172731 69.1364318293 B2 B2 (3) + 79 75 2.6586433664 72.3453639681 B2 B2 (3) + 80 31 2.6718877167 72.7057610618 A1 A1 (1) + 81 32 2.8267951805 76.9210074510 A1 A1 (1) + 82 76 2.9419209269 80.0537382753 B2 B2 (3) + 83 77 2.9853767071 81.2362301695 B2 B2 (3) + 84 33 3.0013526923 81.6709588287 A1 A1 (1) + 85 48 3.2421725037 88.2239990462 B1 B1 (2) + 86 90 3.2857682253 89.4102989431 A2 A2 (4) + 87 34 3.4838249547 94.7996965407 A1 A1 (1) + 88 78 3.6959298762 100.5713648809 B2 B2 (3) + 89 79 3.7700022467 102.5869765541 B2 B2 (3) + 90 35 3.8341979240 104.3338297409 A1 A1 (1) + + + VSCF finished. + + @CHECKOUT-I, Total execution time (CPU/WALL): 4.37/ 0.93 seconds. +--executable xvscf finished with status 0 in 1.40 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvtran + @GETMEM-I, Allocated 95367 MB of main memory. + Full RHF integral transformation + The following 5 MOs will be dropped: + 1 2 3 12 13 + There are 85 active molecular orbitals. + Transformation of IIII integrals : + 1 pass through the AO integral file was required. + 325108 AO integrals were read. + 240883 MO integrals were written to HF2. + Transformation of IIJJ integrals : + 1 pass through the AO integral file was required. + 490042 AO integrals were read. + 386877 MO integrals were written to HF2. + Transformation of IJIJ integrals : + 1 pass through the AO integral file was required. + 908743 AO integrals were read. + 712509 MO integrals were written to HF2. + Transformation of IJKL integrals : + 1 pass through the AO integral file was required. + 460725 AO integrals were read. + 398112 MO integrals were written to HF2. + Summary of active molecular orbitals: +------------------------------------------------------------------------ + + Index Eigenvalue Symmetry Index Eigenvalue Symmetry +------------------------------------------------------------------------ + 1 -1.4574476 1 44 1.2129419 2 + 2 -1.0834873 1 45 1.3116429 2 + 3 -0.7793049 1 46 1.5283490 2 + 4 -0.7372159 1 47 1.8384392 2 + 5 -0.5622006 1 48 1.9574194 2 + 6 -0.5366322 1 49 2.1914898 2 + 7 -0.6283417 2 50 3.2421725 2 + 8 -0.3944128 2 51 0.2259953 3 + 9 -1.0036038 3 52 0.2409073 3 + 10 -0.8050607 3 53 0.3670668 3 + 11 -0.6064453 3 54 0.5035354 3 + 12 -0.5741890 3 55 0.6027649 3 + 13 -0.3173264 4 56 0.7033703 3 + 14 0.2028008 1 57 0.7543802 3 + 15 0.2331452 1 58 0.8844205 3 + 16 0.3379831 1 59 0.9634113 3 + 17 0.4400792 1 60 1.0592165 3 + 18 0.5796551 1 61 1.1904894 3 + 19 0.6949257 1 62 1.2581408 3 + 20 0.7651070 1 63 1.5691624 3 + 21 0.7917408 1 64 1.5969807 3 + 22 0.9187910 1 65 1.7438096 3 + 23 0.9547555 1 66 1.9863618 3 + 24 1.1352329 1 67 2.0036625 3 + 25 1.1908923 1 68 2.1880644 3 + 26 1.2994001 1 69 2.2977716 3 + 27 1.5439842 1 70 2.5407173 3 + 28 1.7377155 1 71 2.6586434 3 + 29 1.7729618 1 72 2.9419209 3 + 30 1.8727561 1 73 2.9853767 3 + 31 2.0703324 1 74 3.6959299 3 + 32 2.1641427 1 75 3.7700022 3 + 33 2.2271655 1 76 0.2346526 4 + 34 2.3793504 1 77 0.7176013 4 + 35 2.6718877 1 78 0.8438633 4 + 36 2.8267952 1 79 1.2921641 4 + 37 3.0013527 1 80 1.3649570 4 + 38 3.4838250 1 81 1.7443896 4 + 39 3.8341979 1 82 2.0489212 4 + 40 0.1616455 2 83 2.1357719 4 + 41 0.6720868 2 84 2.5107047 4 + 42 0.7622870 2 85 3.2857682 4 + 43 1.0743328 2 +------------------------------------------------------------------------ + -1.45744763288719 -1.08348725881441 -0.779304929609897 + -0.737215942115339 -0.562200605497301 -0.536632223783724 + -0.628341663300699 -0.394412768193209 -1.00360380778026 + -0.805060667553655 -0.606445264032669 -0.574188966380078 + -0.317326442801090 0.202800799044599 0.233145235052782 + 0.337983058334004 0.440079239041159 0.579655107669000 + 0.694925733138531 0.765107046589679 0.791740804983910 + 0.918791018982032 0.954755538003189 1.13523291727329 + 1.19089227502871 1.29940010677049 1.54398417735024 + 1.73771547923282 1.77296175003401 1.87275606979175 + 2.07033243972521 2.16414271052282 2.22716551838589 + 2.37935042101669 2.67188771673553 2.82679518054224 + 3.00135269229820 3.48382495469438 3.83419792398046 + 0.161645491943529 0.672086790797680 0.762286964920328 + 1.07433284544462 1.21294191744913 1.31164286730943 + 1.52834897888630 1.83843915784915 1.95741938237798 + 2.19148984413109 3.24217250366571 0.225995307622873 + 0.240907258015995 0.367066829963131 0.503535426659975 + 0.602764944529835 0.703370339875812 0.754380179426906 + 0.884420518732559 0.963411281466499 1.05921648685572 + 1.19048944155892 1.25814077480321 1.56916241916196 + 1.59698065950503 1.74380957764511 1.98636180732934 + 2.00366248439902 2.18806439955680 2.29777158087759 + 2.54071727310046 2.65864336644143 2.94192092693438 + 2.98537670707142 3.69592987620463 3.77000224671010 + 0.234652607487977 0.717601256707210 0.843863253708071 + 1.29216411509331 1.36495699837027 1.74438958333340 + 2.04892117101004 2.13577192131677 2.51070474122043 + 3.28576822533544 + @CHECKOUT-I, Total execution time (CPU/WALL): 6.89/ 0.47 seconds. +--executable xvtran finished with status 0 in 0.93 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xintprc + @GETMEM-I, Allocated 95367 MB of main memory. + @GMOIAA-I, Processing MO integrals for spin case AA. + @GMOIAA-I, Generation of integral list completed. + TYPE NUMBER + ---- -------- + PPPP 894479 + PPPH 640524 + PPHH 115497 + PHPH 63721 + PHHH 22938 + HHHH 1222 + + TOTAL 1738381 + + @FORMT2-I, Second-order MP correlation energies: + ------------------------------------------------ + E(SCF) = -228.643312572485 a.u. + E2(AA) = -0.093684343380 a.u. + E2(AB) = -0.520081687065 a.u. + E2(TOT) = -0.707450373824 a.u. + Total MP2 energy = -229.350762946309 a.u. + ------------------------------------------------ + Largest T2 amplitudes for spin case AB: + _ _ _ _ _ _ + i j a b i j a b i j a b +----------------------------------------------------------------------------- +[ 13 13 40 40]-0.06710 [ 8 8 40 40]-0.05436 [ 13 13 76 76]-0.05241 +[ 13 8 76 40]-0.04215 [ 8 13 40 76]-0.04215 [ 8 8 76 76]-0.03737 +[ 7 7 40 40]-0.03140 [ 13 7 40 76]-0.02053 [ 7 13 76 40]-0.02053 +[ 13 13 77 77]-0.01960 [ 13 13 40 42]-0.01810 [ 13 13 42 40]-0.01810 +[ 7 7 45 45]-0.01664 [ 13 13 41 41]-0.01633 [ 13 13 78 76]-0.01595 +----------------------------------------------------------------------------- + Norm of T2AB vector ( 230058 symmetry allowed elements): 0.4218925855. +----------------------------------------------------------------------------- + @CHECKOUT-I, Total execution time (CPU/WALL): 4.49/ 0.35 seconds. +--executable xintprc finished with status 0 in 0.82 seconds (walltime). + calling xncc + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xncc + @GETMEM-I, Allocated 7 MB of main memory. + +Running with 20 threads/proc + +Using DIIS to accelerate the convergence of T1 and T2 +Using immediate high-order contributions +Performing 3 CCSD sub-iterations +Damping factor for T3: 0.000000 +Damping factor for T4: 0.000000 + +Transposes are coarse-threaded + +Memory limit: 93.132 GiB +Minimum memory requirement: 19.231 MiB +Compromise memory amount: 55.151 MiB +Optimal memory requirement: 437.270 MiB + +List Location Size Cached Hunks Est. Disk I/O +----------------- ---------- ----------- ------ ----- ------------- + + T_DIIS 70:0 8.787 MiB Yes - 158.166 MiB + Z_DIIS 70:1 8.787 MiB Yes - 263.610 MiB + 18 1.755 MiB Yes - 274.921 MiB + 233 52.803 MiB Yes - 3.867 GiB + 30 9.615 MiB Yes - 4.648 GiB + 16 1.755 MiB Yes - 1.109 GiB + 25 1.755 MiB Yes - 236.952 MiB + 21 1.755 MiB No - 0 B + 10 329.156 KiB Yes - 236.260 MiB + 13 60.633 KiB Yes - 4.441 MiB + F(EA) 92:0 11.891 KiB Yes - 4.180 MiB + F(EM) 93:0 2.250 KiB Yes - 641.250 KiB + F(MI) 91:0 456 B Yes - 187.031 KiB + Q(AI) 190:2 2.250 KiB Yes - 371.250 KiB + Q(Ab,Ij) 50 1.755 MiB Yes - 974.138 MiB + T(AI) 90:0 2.250 KiB Yes - 2.375 MiB + T(Ab,Ij) 46 1.755 MiB Yes - 1.623 GiB + W(Mn,Ij) 53 60.633 KiB Yes - 7.105 MiB + W~(Ab,Ej) 130 9.615 MiB Yes - 4.731 GiB + W~(EM,bj) 56 1.755 MiB Yes - 526.561 MiB + W~(Em,Bj) 58 1.755 MiB Yes - 526.561 MiB + W~(Ij,Mb) 110 329.156 KiB Yes - 106.076 MiB + W~~(Ab,Ej) 169 9.615 MiB No - 0 B + W~~(EM,bj) 76 1.755 MiB Yes - 105.312 MiB + W~~(Em,Bj) 78 1.755 MiB Yes - 105.312 MiB + W~~(Ij,Mb) 165 329.156 KiB No - 0 B + Z(AI) 90:2 2.250 KiB Yes - 1.022 MiB + Z(Ab,Ij) 63 1.755 MiB Yes - 816.170 MiB + T(abc,ijk) - 319.713 MiB No 1 0 B + Z(abc,ijk) - 319.713 MiB No 1 0 B + +Simulation and memory analysis took 0.218 seconds + +MP2 correlation energy: -0.707450373824291 + +Non-iterative calculation of MP2 took 0.297 cpu seconds and 0.017 walltime seconds at 0.749 Gflops/sec + +Total MP2 energy: -229.350762946308862 + +Beginning iterative solution of CC3 equations: + +It. Correlation Energy T1 Residual T2 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------- + 1 -0.764614021207282 5.85438e-03 1.35155e-02 36.566 1.844 + 2 -0.765656065903802 1.47321e-03 2.82614e-03 33.172 1.662 + 3 -0.765739967778334 3.65464e-04 6.09720e-04 32.510 1.629 + 4 -0.765735001866212 9.77413e-05 1.29558e-04 32.852 1.645 + 5 -0.765730995032383 2.29869e-05 2.68772e-05 32.871 1.646 + + A I A I A I +-------------------------- -------------------------- -------------------------- + 19 17 -0.0296954266991 31 17 0.0114114231087 25 15 0.0075106982204 + 19 12 0.0284808798547 36 17 -0.0108678874992 21 14 -0.0074596432522 + 34 18 0.0224725250737 25 16 -0.0102794471483 45 17 0.0074433819912 + 23 18 0.0176490672721 27 16 -0.0094125348255 26 13 0.0069096616154 + 51 18 0.0134527465790 53 17 0.0077124218397 49 17 0.0065786944159 + + A B I J A B I J +------------------------------------ ------------------------------------ + 19 19 18 18 -0.1045675283017 23 19 12 18 -0.0298037366898 + 23 23 18 18 -0.0616675121997 19 36 18 18 -0.0267815174391 + 19 19 17 17 -0.0598637352962 36 19 18 18 -0.0267815174391 + 23 19 18 17 -0.0592798131708 19 23 12 18 -0.0218110842890 + 19 23 17 18 -0.0592798131708 23 19 18 12 -0.0218110842890 + 23 23 17 17 -0.0585654670093 39 23 17 17 -0.0204007938238 + 19 19 12 12 -0.0377911957482 23 39 17 17 -0.0204007938238 + 19 23 18 12 -0.0298037366898 + +It. Correlation Energy T1 Residual T2 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------- + 6 -0.765730202116214 3.59012e-06 5.40250e-06 31.730 1.589 + 7 -0.765730083477215 6.51759e-07 1.13410e-06 32.999 1.653 + 8 -0.765730055650190 1.62428e-07 2.53819e-07 31.647 1.585 + 9 -0.765730048755297 3.70380e-08 5.75273e-08 32.029 1.605 + +CC3 iterations converged in 9 cycles and 14.862 seconds (1.651 s/it.) at 17.026 Gflops/sec + +Total CC3 energy: -229.409042621239877 + + @CHECKOUT-I, Total execution time (CPU/WALL): 298.95/ 15.26 seconds. +--executable xncc finished with status 0 in 15.83 seconds (walltime). + The final electronic energy is -229.409042621239877 a.u. + This computation required 23.80 seconds (walltime). diff --git a/furan/cc-pvdz/CC/fura-gs-cc4.out b/furan/cc-pvdz/CC/fura-gs-cc4.out new file mode 100644 index 0000000..495e58d --- /dev/null +++ b/furan/cc-pvdz/CC/fura-gs-cc4.out @@ -0,0 +1,1001 @@ + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xjoda + + + ************************************************************************* + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + ************************************************************************* + + **************************************************************** + * CFOUR Coupled-Cluster techniques for Computational Chemistry * + **************************************************************** + + + Department of Chemistry Institut fuer Physikalische Chemie + University of Florida Universitaet Mainz + Gainesville, FL 32611, USA D-55099 Mainz, Germany + + Department of Chemistry Fakultaet fuer Chemie und Biowiss. + Johns Hopkins University Karlsruher Institut fuer Technologie + Baltimore, MD 21218, USA D-76131 Karlsruhe, Germany + + Department of Chemistry Department of Physical Chemistry + Southern Methodist University Eotvos Lorand University + Dallas, TX 75275, USA H-1053 Budapest, Hungary + + + Version 2.1 + + cribbar020 + Thu Oct 15 19:11:56 CEST 2020 + integer*8 version is running + +******************************************************************************** +* Input from ZMAT file * +******************************************************************************** +Ketene -GS +C 0.00000000 2.06365826 -0.60051250 +C 0.00000000 -2.06365826 -0.60051250 +C 0.00000000 1.35348578 1.86336416 +C 0.00000000 -1.35348578 1.86336416 +O 0.00000000 0.00000000 -2.13945332 +H 0.00000000 3.86337287 -1.53765695 +H 0.00000000 -3.86337287 -1.53765695 +H 0.00000000 2.59168789 3.47168051 +H 0.00000000 -2.59168789 3.47168051 + +*CFOUR(COORD=CARTESIAN,UNITS=BOHR + MEMORY=180,MEM_UNIT=GB,CC_PROG=NCC + FROZEN_CORE=1 + CALC=CC4,BASIS=PVDZ + SCF_CONV=9,CC_CONV=7,ESTATE_MAXCYC=80) + +******************************************************************************** + ------------------------------------------------------------------- + CFOUR Control Parameters + ------------------------------------------------------------------- + External Internal Value Units + Name Name + ------------------------------------------------------------------- + ABCDTYPE IABCDT STANDARD [ 0] *** + ANHARMONIC IANHAR OFF [ 0] *** + ANH_ALGORIT IANALG STANDARD [ 0] *** + ANH_DERIVAT IANDER SECOND [ 1] *** + ANH_MODE ANHMOD VIBRATION [ 0] *** + ANH_STEPSIZ ICUBST 50000 x 10-6 + ANH_SYMMETR IANHSM ABELIAN [ 0] *** + AO_LADDERS IAOLAD SINGLEPASS [ 1] *** + AV_SCF IAVSCF OFF [ 0] *** + BASIS IBASIS PVDZ [ 13] *** + BOTHVECTORS BOTHVC OFF [ 0] *** + BOX_POTENT IPIAB OFF [ 0] *** + BREIT IBREIT OFF [ 0] *** + BRUCK_CONV IBRTOL 10D- 4 *** + BRUECKNER IBRKNR OFF [ 0] *** + BUFFERSIZE IBUFFS 4096 *** + CACHE_RECS ICHREC 10 *** + CALCLEVEL ICLLVL CC4 [ 52] *** + CCORBOPT ICCORB OFF [ 0] x 0.01 + CC_CONV ICCCNV 10D- 7 *** + CC_EXPORDER ICCEOR 5 *** + CC_EXTRAPOL ICCEXT DIIS [ 1] *** + CC_GUESS ICCGES MP2 [ 0] *** + CC_MAXCYC ICCCYC 100 cycles + CC_PROGRAM ICCPRO NCC [ 5] *** + CHARGE ICHRGE 0 *** + CHOLESKY ICHOLE OFF [ 0] *** + CIS_CONV ICISTL 5 *** + COMM_SIZE IPSIZE *** *** + CONSTANT ICONST OLD [ 1] *** + CONTINUUM ICONTU NONE [ 0] *** + CONTRACTION ICNTYP GENERAL [ 1] *** + COORDINATES ICOORD CARTESIAN [ 1] *** + CPHF_CONVER ICPHFT 10D- 16 *** + CPHF_MAXCYC ICPHFC 64 cycles + CUBIC ICUBIC OFF [ 0] *** + CURVILINEAR ICURVY OFF [ 0] *** + DBOC IDBOC OFF [ 0] *** + DCT IDCT OFF [ 0] *** + DERIV_LEV IDRLVL ZERO [ 0] *** + DEVMEM_SIZE IDVMEM ********* MByte + DIAG_MRCC IEOMST 10D- 0 *** + DIFF_TYPE IDIFTY RELAXED [ 0] *** + DIRECT IDIRCT OFF [ 0] *** + DROPMO IDRPMO NONE + ECP IECP OFF [ 0] *** + EIGENVECTOR IVEC 1 *** + EL_ANHARM IELANH OFF [ 0] *** + EOMFOLLOW IEOMSR ENERGY [ 0] *** + EOMIP IEOMIP OFF [ 0] *** + EOMLEVEL HBARFM SAME [ 0] *** + EOM_MRCC IMRCCE NEW [ 1] *** + EOM_NONIT EOMNON OFF [ 0] *** + EOM_NSING IEOMSI 10D- 0 *** + EOM_NSTATES IMRCCD DAVIDSON [ 0] *** + EOM_NTRIP IEOMTR 10D- 0 *** + EOM_ORDER IEXORD ENERGY [ 0] *** + EOM_PROPSTA IEOMST 0 *** + ESTATE_CONV IEXTOL 10D- 5 *** + ESTATE_DIAG IEXDIG ITERATIVE [ 0] *** + ESTATE_LOCK IESLOC ON [ 1] *** + ESTATE_MAXC IEXMXC 80 *** + ESTATE_PROP IEXPRP OFF [ 0] *** + EVAL_HESS IRECAL 0 # of cyc. + EXCITATION IEXCIT 0 *** + EXCITE IEXCIT NONE [ 0] *** + EXTERN_POT IEXPOT OFF [ 0] *** + FCGRADNEW IFCGNW OFF [ 0] *** + FC_FIELD IFINFC 0 x 10-6 + FD_CALTYPE IFDCAL GRADONLY [ 0] *** + FD_PROJECT IFDPRJ OFF [ 1] *** + FD_STEPSIZE IDISFD 0 10-4 bohr + FD_USEGROUP IFDGRP FULL [ 0] *** + FILE_RECSIZ IFLREC 4096 words + FINITE_PERT IFIPER 0 x 10-6 + FIXGEOM IFIXGM OFF [ 0] *** + FOCK IFOCK AO [ 1] *** + FREQ_ALGORI IVIALG STANDARD [ 0] *** + FROZEN_CORE IFROCO ON [ 1] *** + GAMMA_ABCD IGABCD STORE [ 0] *** + GAMMA_ABCI IGABCI STORE [ 0] *** + GENBAS_1 IGNBS1 0 *** + GENBAS_2 IGNBS2 0 *** + GENBAS_3 IGNBS3 0 *** + GENBAS_4 IGNBS4 0 *** + GEO_CONV ICONTL 5 H/bohr + GEO_MAXCYC IOPTCY 50 *** + GEO_MAXSTEP IMXSTP 300 millibohr + GEO_METHOD INR SINGLE_POINT[ 5] *** + GIAO IGIAO OFF [ 1] *** + GIMIC IGIMIC OFF [ 0] *** + GRID IGRID OFF [ 0] *** + GRID_ALGO IGALGO SERIAL [ 0] *** + GUESS IGUESS MOREAD [ 0] *** + HBAR IHBAR OFF [ 0] *** + HESS_TYPE IHESTP SCF [ 0] *** + HF2_FILE IHF2Fl USE [ 1] *** + HFSTABILITY ISTABL OFF [ 0] *** + INCORE INCORE OFF [ 0] *** + INPUT_MRCC IMRCC ON [ 1] *** + INTEGRALS INTTYP VMOL [ 1] *** + JODA_PRINT IJPRNT 0 *** + KEYWORD_OUT IDMPKW NO [ 0] *** + LINDEP_TOL ILINDP 8 *** + LINEQ_CONV IZTACN 10D- 7 cycles + LINEQ_EXPOR ILMAXD 5 *** + LINEQ_MAXCY ILMAXC 100 *** + LINEQ_TYPE ILTYPE DIIS [ 1] *** + LOCK_ORBOCC ILOCOC OFF [ 0] *** + MEMORY_SIZE IMEMSZ ********* words + MEM_UNIT IMEMU GB [ 3] *** + MRCC IMRCCC OFF [ 0] *** + MULTIPLICTY IMULTP 1 *** + NACOUPLING IVCOUP OFF [ 0] *** + NEGEVAL IDIE ABORT [ 0] *** + NEWNORM INEWNO OFF [ 0] *** + NON-HF INONHF OFF [ 0] *** + NTOP_TAMP ITOPT2 15 *** + NUC_MODEL INUCMO POINT [ 0] *** + OCCUPATION IOCCU ESTIMATED BY SCF + OPEN-SHELL IOPEN SPIN-ORBITAL[ 0] *** + OPTVIB IOPTVB OFF [ 0] *** + ORBITALS IORBTP STANDARD [ 0] *** + PARALLEL IPARAL ON [ 1] *** + PARA_INT IPINTS ON [ 1] *** + PARA_PRINT IPPRIN 0 *** + PERT_ORB IPTORB STANDARD [ 0] *** + POINTS IGRDFD 0 *** + PRINT IPRNT 0 *** + PROPS IPROPS OFF [ 0] *** + PROP_INTEGR IINTYP INTERNAL [ 0] *** + PSI IPSI OFF [ 0] *** + QC_ALG IQCALG FLM [ 0] *** + QC_LINALG IQCLIN TRIDIAG [ 2] *** + QC_MAXCYC IQCMAX 10D-100 cycles + QC_MAXSCFCY IQCMSC 10D- 15 cycles + QC_RTRUST IQCRTR 10D- 0 x 10-3 + QC_SKIPSCF IQCSKI OFF [ 0] *** + QC_START IQCSTA 10D- 1 *** + QRHFGUESS IQGUES OFF [ 0] *** + QUARTIC IQUART OFF [ 0] *** + RAMAN_INT IRAMIN OFF [ 0] *** + RAMAN_ORB IRAMRE UNRELAXED [ 0] *** + RDO IRDOFM OFF [ 0] *** + REDUCE_REPR REDREP Ir [ 0] *** + REFERENCE IREFNC RHF [ 0] *** + RELATIVIST IRELAT OFF [ 0] *** + RELAX_DENS IRDENS OFF [ 0] *** + RESET_FLAGS IRESET OFF [ 0] *** + RESTART_CC ICCRES OFF [ 0] *** + ROT_EVEC ROTVEC 0 *** + SAVE_INTS ISVINT OFF [ 0] *** + SCALE_ON ISTCRT 0 *** + SCF_CONV ISCFCV 10D- 9 *** + SCF_DAMPING IDAMP 0 x 10-3 + SCF_EXPORDE IRPPOR 6 *** + SCF_EXPSTAR IRPPLS 8 *** + SCF_EXTRAPO IRPP ON [ 1] *** + SCF_MAXCYC ISCFCY 150 cycles + SCF_NOSTOP ISCFST OFF [ 0] *** + SCF_PRINT ISCFPR 0 *** + SCF_PROG ISCFPR SCF [ 0] *** + SD_FIELD IFINSD 0 x 10-6 + SOPERT IPERSO OFF [ 0] *** + SPHERICAL IDFGHI ON [ 1] *** + SPINORBIT ISOCAL OFF [ 0] *** + SPINROTATIO ISRCON OFF [ 0] *** + SPIN_FLIP ISPFLP OFF [ 0] *** + SPIN_ORBIT ISPORB OFF [ 0] *** + SPIN_SCAL ISCSMP OFF [ 0] *** + STEEPSCALE ISTPSC 1000 x 10-3 + SUBGROUP ISUBGP DEFAULT [ 0] *** + SUBGRPAXIS ISBXYZ X [ 0] *** + SYMMETRY ISYM ON [ 0] *** + SYM_CHECK ISYMCK OVERRIDE [ 1] *** + T3_EXTRAPOL IT3EXT ON [ 1] *** + T4_EXTRAPOL IT4EXP OFF [ 0] *** + TAMP_SUM IEVERY 5 *** + TESTSUITE ITESTS OFF [ 0] *** + THERMOCH ITHERM OFF [ 0] *** + TOL_CHOLESK ITOLCH 10D- 4 *** + TRANGRAD IRESRM OFF [ 0] *** + TRANS_INV ITRAIN USE [ 0] *** + TREAT_PERT ITREAT SIMULTANEOUS[ 0] *** + TRIP_ALGORI ITRALG NORMAL [ 0] *** + UIJ_THRESHO IUIJTH 1 *** + UNITS IUNITS BOHR [ 1] *** + UNOS IUNOS OFF [ 0] *** + UPDATE_HESS IHUPDT ON [ 1] *** + VIBPHASE ISETPH STANDARD [ 0] *** + VIBRATION IVIB NO [ 0] *** + VIB_ALGORIT IGEALG STANDARD [ 0] *** + VNATORB IVNORB OFF [ 0] *** + VTRAN IVTRAN FULL/PARTIAL[ 0] *** + XFIELD IXEFLD 0 x 10-6 + XFORM_TOL IXFTOL 10D- 11 *** + YFIELD IYEFLD 0 x 10-6 + ZFIELD IZEFLD 0 x 10-6 + ZSCALE_EXP IZEXPS OFF [ 0] *** + ------------------------------------------------------------------- + @GETXYZ-I, 9 atoms read from ZMAT. + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 +******************************************************************************** + The full molecular point group is C2v . + The largest Abelian subgroup of the full molecular point group is C2v . + The computational point group is C2v . +******************************************************************************** + + + ---------------------------------------------------------------- + Coordinates used in calculation (QCOMP) + ---------------------------------------------------------------- + Z-matrix Atomic Coordinates (in bohr) + Symbol Number X Y Z + ---------------------------------------------------------------- + C 6 0.00000000 -2.06365826 0.60031230 + C 6 0.00000000 2.06365826 0.60031230 + C 6 0.00000000 -1.35348578 -1.86356436 + C 6 0.00000000 1.35348578 -1.86356436 + O 8 0.00000000 0.00000000 2.13925312 + H 1 0.00000000 -3.86337287 1.53745675 + H 1 0.00000000 3.86337287 1.53745675 + H 1 0.00000000 -2.59168789 -3.47188071 + H 1 0.00000000 2.59168789 -3.47188071 + ---------------------------------------------------------------- + + Interatomic distance matrix (Angstroms) + + C C C C O + [ 1] [ 2] [ 3] [ 4] [ 5] + C [ 1] 0.00000 + C [ 2] 2.18408 0.00000 + C [ 3] 1.35691 2.22931 0.00000 + C [ 4] 2.22931 1.35691 1.43247 0.00000 + O [ 5] 1.36226 1.36226 2.23601 2.23601 0.00000 + H [ 6] 1.07375 3.17541 2.23677 3.29549 2.06906 + H [ 7] 3.17541 1.07375 3.29549 2.23677 2.06906 + H [ 8] 2.17295 3.27299 1.07409 2.25451 3.27071 + H [ 9] 3.27299 2.17295 2.25451 1.07409 3.27071 + + H H H H + [ 6] [ 7] [ 8] [ 9] + H [ 6] 0.00000 + H [ 7] 4.08882 0.00000 + H [ 8] 2.73491 4.32378 0.00000 + H [ 9] 4.32378 2.73491 2.74292 0.00000 + rotcon2 + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 + There are 5 frozen-core orbitals. + There are 90 basis functions. + @GEOPT-W, Archive file not created for single-point calculation. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.20/ 1.91 seconds. +--executable xjoda finished with status 0 in 2.45 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol + SERIAL VERSION OF MOLECULE STARTED +******************************************************************************** + INPUT FROM MOL FILE +******************************************************************************** +INTGRL 1 0 1 0 0 0 0 0 0 + *** CFOUR Program System (Release V0.1) *** +Ketene -GS + 5 2 X Y 0.10E-08 0 0 + 9999.00 3.00 + 6.00000000 1 3 1 1 1 +C #1 0.000000000000000 -2.063658260000000 0.600312302999175 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 6.00000000 1 3 1 1 1 +C #2 0.000000000000000 -1.353485780000000 -1.863564357000825 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 8.00000000 1 3 1 1 1 +O #3 0.000000000000000 0.000000000000000 2.139253122999175 + 9 3 + 11720.0000000000 7.100000000000000E-004 -1.600000000000000E-004 + 0.000000000000000E+000 + 1759.00000000000 5.470000000000000E-003 -1.263000000000000E-003 + 0.000000000000000E+000 + 400.800000000000 2.783700000000000E-002 -6.267000000000000E-003 + 0.000000000000000E+000 + 113.700000000000 0.104800000000000 -2.571600000000000E-002 + 0.000000000000000E+000 + 37.0300000000000 0.283062000000000 -7.092400000000000E-002 + 0.000000000000000E+000 + 13.2700000000000 0.448719000000000 -0.165411000000000 + 0.000000000000000E+000 + 5.02500000000000 0.270952000000000 -0.116955000000000 + 0.000000000000000E+000 + 1.01300000000000 1.545800000000000E-002 0.557368000000000 + 0.000000000000000E+000 + 0.302300000000000 -2.585000000000000E-003 0.572759000000000 + 1.00000000000000 + 4 2 + 17.7000000000000 4.301800000000000E-002 0.000000000000000E+000 + 3.85400000000000 0.228913000000000 0.000000000000000E+000 + 1.04600000000000 0.508728000000000 0.000000000000000E+000 + 0.275300000000000 0.460531000000000 1.00000000000000 + 1 1 + 1.18500000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #4 0.000000000000000 -3.863372870000000 1.537456752999175 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #5 0.000000000000000 -2.591687890000000 -3.471880707000825 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 +FINISH + +******************************************************************************** + ONE- AND TWO-ELECTRON INTEGRALS OVER SYMMETRY-ADAPTED AOS ARE CALCULATED. + + SPHERICAL HARMONICS ARE USED. + + INTEGRALS LESS THAN 0.10E-13 ARE NEGLECTED. + + NUCLEAR REPULSION ENERGY : 161.1082297788 A.U. + @MOLECU-I, ONE ELECTRON INTEGRALS (CPU/WALL): 0.05/ 0.09 SECONDS. + @TWOEL-I, 325108 INTEGRALS OF SYMMETRY TYPE I I I I + @TWOEL-I, 908743 INTEGRALS OF SYMMETRY TYPE I J I J + @TWOEL-I, 490042 INTEGRALS OF SYMMETRY TYPE I I J J + @TWOEL-I, 460725 INTEGRALS OF SYMMETRY TYPE I J K L + @TWOEL-I, TOTAL NUMBER OF 2-E INTEGRALS 2184618. + @MOLECU-I, TWO ELECTRON INTEGRALS (CPU/WALL): 2.19/ 2.20 SECONDS. + @CHECKOUT-I, Total execution time (CPU/WALL): 2.27/ 2.32 seconds. + +Running with 20 threads/proc + +--executable xvmol finished with status 0 in 3.08 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol2ja + @GETMEM-I, Allocated 171661 MB of main memory. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.52/ 0.25 seconds. +--executable xvmol2ja finished with status 0 in 1.35 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvscf + There are 90 functions in the AO basis. + + There are 4 irreducible representations. + + Irrep # of functions + 1 35 + 2 13 + 3 31 + 4 11 + + + Parameters for SCF calculation: + SCF reference function: RHF + Maximum number of iterations: 150 + Full symmetry point group: C2v + Computational point group: C2v + Initial density matrix: MOREAD + SCF convergence tolerance: 10**(- 9) + DIIS convergence acceleration: ON + Latest start for DIIS: 8 + DIIS order: 6 + + Memory information: 341888 words required. + Fock matrices are constructed from AO integral file. + @GETMEM-I, Allocated 2 MB of main memory. + Initialization and symmetry analysis required 0.004 seconds. + + @INITGES-I, Occupancies from core Hamiltonian: + + Alpha population by irrep: 9 2 6 1 + Beta population by irrep: 9 2 6 1 + + + total no. of electrons in initial guess : 0.000000000000000E+000 + -------------------------------------------------------------------- + Iteration Total Energy Largest Density Difference + -------------------------------------------------------------------- + 0 161.108229778788910 0.0000000000D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 1 -196.263249175406742 0.1098182460D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 2 -179.889864626346110 0.1675780025D+02 + current occupation vector + 9 1 7 1 + 9 1 7 1 + 3 -180.580457259655276 0.1772125138D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 4 -162.771013663102423 0.1566999730D+02 + current occupation vector + 8 2 7 1 + 8 2 7 1 + 5 -169.943224465304610 0.1454729382D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 6 -160.269967975319304 0.1454634919D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 7 -168.828658617539219 0.1395077743D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 8 -160.232275948462728 0.1395068492D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 9 -209.746508446751051 0.5520995458D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 10 -228.180230304178195 0.2015536648D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 11 -228.454713327495170 0.6531384936D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 12 -228.600329261509017 0.3196758217D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 13 -228.637509917233530 0.7498321731D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 14 -228.642938164598405 0.5250342791D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 15 -228.643241982659077 0.9795506231D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 16 -228.643308522549574 0.3593200395D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 17 -228.643312517845317 0.1473098013D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 18 -228.643312570337088 0.1244041229D-03 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 19 -228.643312572355882 0.2423484434D-04 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 20 -228.643312572475082 0.5414752037D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 21 -228.643312572483552 0.2003508847D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 22 -228.643312572485314 0.8833300431D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 23 -228.643312572485655 0.3139638252D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 24 -228.643312572485598 0.4136765797D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 25 -228.643312572485883 0.9839837678D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 26 -228.643312572484120 0.1838787145D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 27 -228.643312572485030 0.3228645795D-08 + current occupation vector + 9 2 6 1 + 9 2 6 1 + + SCF has converged. + + Density matrix saved to file den.dat + total electron number: 36.0000000000001 + E(SCF)= -228.643312572483723 0.7983149697D-09 + + Eigenvector printing suppressed. + + @PUTMOS-I, Writing converged MOs to NEWMOS. + @PUTMOS-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTMOS-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTMOS-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTMOS-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + @PUTFOCK-I, Writing converged Fock matrix to NEWFOCK. + @PUTFOCK-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTFOCK-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + + + + ORBITAL EIGENVALUES (ALPHA) (1H = 27.2113834 eV) + + MO # E(hartree) E(eV) FULLSYM COMPSYM + ---- -------------------- -------------------- ------- --------- + 1 1 -20.6219765861 -561.1525113512 A1 A1 (1) + 2 49 -11.2892088103 -307.1949892207 B2 B2 (3) + 3 2 -11.2891634657 -307.1937553315 A1 A1 (1) + 4 3 -11.2328159068 -305.6604603025 A1 A1 (1) + 5 50 -11.2318729764 -305.6348018622 B2 B2 (3) + 6 4 -1.4574476329 -39.6591663239 A1 A1 (1) + 7 5 -1.0834872588 -29.4831872086 A1 A1 (1) + 8 51 -1.0036038078 -27.3094479952 B2 B2 (3) + 9 52 -0.8050606676 -21.9068144851 B2 B2 (3) + 10 6 -0.7793049296 -21.2059652251 A1 A1 (1) + 11 7 -0.7372159421 -20.0606656495 A1 A1 (1) + 12 36 -0.6283416633 -17.0980459063 B1 B1 (2) + 13 53 -0.6064452640 -16.5022145907 B2 B2 (3) + 14 54 -0.5741889664 -15.6244761082 B2 B2 (3) + 15 8 -0.5622006055 -15.2982562239 A1 A1 (1) + 16 9 -0.5366322238 -14.6025051862 A1 A1 (1) + 17 37 -0.3944127682 -10.7325170532 B1 B1 (2) + 18 80 -0.3173264428 -8.6348914980 A2 A2 (4) + +++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ + 19 38 0.1616454919 4.3985974562 B1 B1 (2) + 20 10 0.2028007990 5.5184902966 A1 A1 (1) + 21 55 0.2259953076 6.1496449623 B2 B2 (3) + 22 11 0.2331452351 6.3442043789 A1 A1 (1) + 23 81 0.2346526075 6.3852220682 A2 A2 (4) + 24 56 0.2409072580 6.5554197617 B2 B2 (3) + 25 12 0.3379830583 9.1969865830 A1 A1 (1) + 26 57 0.3670668300 9.9883962435 B2 B2 (3) + 27 13 0.4400792390 11.9751648999 A1 A1 (1) + 28 58 0.5035354267 13.7018955503 B2 B2 (3) + 29 14 0.5796551077 15.7732173745 A1 A1 (1) + 30 59 0.6027649445 16.4020680057 B2 B2 (3) + 31 39 0.6720867908 18.2884113425 B1 B1 (2) + 32 15 0.6949257331 18.9098905590 A1 A1 (1) + 33 60 0.7033703399 19.1396799906 B2 B2 (3) + 34 82 0.7176012567 19.5269229246 A2 A2 (4) + 35 61 0.7543801794 20.5277282918 B2 B2 (3) + 36 40 0.7622869649 20.7428828633 B1 B1 (2) + 37 16 0.7651070466 20.8196211868 A1 A1 (1) + 38 17 0.7917408050 21.5443625978 A1 A1 (1) + 39 83 0.8438632537 22.9626865338 A2 A2 (4) + 40 62 0.8844205187 24.0663058221 B2 B2 (3) + 41 18 0.9187910190 25.0015746820 A1 A1 (1) + 42 19 0.9547555380 25.9802189979 A1 A1 (1) + 43 63 0.9634112815 26.2157537519 B2 B2 (3) + 44 64 1.0592164869 28.8227459274 B2 B2 (3) + 45 41 1.0743328454 29.2340829566 B1 B1 (2) + 46 20 1.1352329173 30.8912581603 A1 A1 (1) + 47 65 1.1904894416 32.3948646279 B2 B2 (3) + 48 21 1.1908922750 32.4058262839 A1 A1 (1) + 49 42 1.2129419174 33.0058275576 B1 B1 (2) + 50 66 1.2581407748 34.2357509944 B2 B2 (3) + 51 84 1.2921641151 35.1615731515 A2 A2 (4) + 52 22 1.2994001068 35.3584744953 A1 A1 (1) + 53 43 1.3116428673 35.6916169462 B1 B1 (2) + 54 85 1.3649569984 37.1423682072 A2 A2 (4) + 55 44 1.5283489789 41.5884900335 B1 B1 (2) + 56 23 1.5439841773 42.0139454134 A1 A1 (1) + 57 67 1.5691624192 42.6990802047 B2 B2 (3) + 58 68 1.5969806595 43.4560530082 B2 B2 (3) + 59 24 1.7377154792 47.2856421455 A1 A1 (1) + 60 69 1.7438095776 47.4514709939 B2 B2 (3) + 61 86 1.7443895833 47.4672537511 A2 A2 (4) + 62 25 1.7729617500 48.2447419337 A1 A1 (1) + 63 45 1.8384391578 50.0264727818 B1 B1 (2) + 64 26 1.8727560698 50.9602834298 A1 A1 (1) + 65 46 1.9574193824 53.2640892885 B1 B1 (2) + 66 70 1.9863618073 54.0516527104 B2 B2 (3) + 67 71 2.0036624844 54.5224280672 B2 B2 (3) + 68 87 2.0489211710 55.7539795407 A2 A2 (4) + 69 27 2.0703324397 56.3366097828 A1 A1 (1) + 70 88 2.1357719213 58.1173086059 A2 A2 (4) + 71 28 2.1641427105 58.8893170283 A1 A1 (1) + 72 72 2.1880643996 59.5402592802 B2 B2 (3) + 73 47 2.1914898441 59.6334703659 B1 B1 (2) + 74 29 2.2271655184 60.6042548161 A1 A1 (1) + 75 73 2.2977715809 62.5255434529 B2 B2 (3) + 76 30 2.3793504210 64.7454165492 A1 A1 (1) + 77 89 2.5107047412 68.3197493175 A2 A2 (4) + 78 74 2.5407172731 69.1364318293 B2 B2 (3) + 79 75 2.6586433664 72.3453639681 B2 B2 (3) + 80 31 2.6718877167 72.7057610618 A1 A1 (1) + 81 32 2.8267951805 76.9210074510 A1 A1 (1) + 82 76 2.9419209269 80.0537382753 B2 B2 (3) + 83 77 2.9853767071 81.2362301696 B2 B2 (3) + 84 33 3.0013526923 81.6709588287 A1 A1 (1) + 85 48 3.2421725037 88.2239990462 B1 B1 (2) + 86 90 3.2857682253 89.4102989431 A2 A2 (4) + 87 34 3.4838249547 94.7996965407 A1 A1 (1) + 88 78 3.6959298762 100.5713648809 B2 B2 (3) + 89 79 3.7700022467 102.5869765541 B2 B2 (3) + 90 35 3.8341979240 104.3338297409 A1 A1 (1) + + + VSCF finished. + + @CHECKOUT-I, Total execution time (CPU/WALL): 4.51/ 1.05 seconds. +--executable xvscf finished with status 0 in 1.59 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvtran + @GETMEM-I, Allocated 171661 MB of main memory. + Full RHF integral transformation + The following 5 MOs will be dropped: + 1 2 3 12 13 + There are 85 active molecular orbitals. + Transformation of IIII integrals : + 1 pass through the AO integral file was required. + 325108 AO integrals were read. + 240883 MO integrals were written to HF2. + Transformation of IIJJ integrals : + 1 pass through the AO integral file was required. + 490042 AO integrals were read. + 386877 MO integrals were written to HF2. + Transformation of IJIJ integrals : + 1 pass through the AO integral file was required. + 908743 AO integrals were read. + 712509 MO integrals were written to HF2. + Transformation of IJKL integrals : + 1 pass through the AO integral file was required. + 460725 AO integrals were read. + 398112 MO integrals were written to HF2. + Summary of active molecular orbitals: +------------------------------------------------------------------------ + + Index Eigenvalue Symmetry Index Eigenvalue Symmetry +------------------------------------------------------------------------ + 1 -1.4574476 1 44 1.2129419 2 + 2 -1.0834873 1 45 1.3116429 2 + 3 -0.7793049 1 46 1.5283490 2 + 4 -0.7372159 1 47 1.8384392 2 + 5 -0.5622006 1 48 1.9574194 2 + 6 -0.5366322 1 49 2.1914898 2 + 7 -0.6283417 2 50 3.2421725 2 + 8 -0.3944128 2 51 0.2259953 3 + 9 -1.0036038 3 52 0.2409073 3 + 10 -0.8050607 3 53 0.3670668 3 + 11 -0.6064453 3 54 0.5035354 3 + 12 -0.5741890 3 55 0.6027649 3 + 13 -0.3173264 4 56 0.7033703 3 + 14 0.2028008 1 57 0.7543802 3 + 15 0.2331452 1 58 0.8844205 3 + 16 0.3379831 1 59 0.9634113 3 + 17 0.4400792 1 60 1.0592165 3 + 18 0.5796551 1 61 1.1904894 3 + 19 0.6949257 1 62 1.2581408 3 + 20 0.7651070 1 63 1.5691624 3 + 21 0.7917408 1 64 1.5969807 3 + 22 0.9187910 1 65 1.7438096 3 + 23 0.9547555 1 66 1.9863618 3 + 24 1.1352329 1 67 2.0036625 3 + 25 1.1908923 1 68 2.1880644 3 + 26 1.2994001 1 69 2.2977716 3 + 27 1.5439842 1 70 2.5407173 3 + 28 1.7377155 1 71 2.6586434 3 + 29 1.7729618 1 72 2.9419209 3 + 30 1.8727561 1 73 2.9853767 3 + 31 2.0703324 1 74 3.6959299 3 + 32 2.1641427 1 75 3.7700022 3 + 33 2.2271655 1 76 0.2346526 4 + 34 2.3793504 1 77 0.7176013 4 + 35 2.6718877 1 78 0.8438633 4 + 36 2.8267952 1 79 1.2921641 4 + 37 3.0013527 1 80 1.3649570 4 + 38 3.4838250 1 81 1.7443896 4 + 39 3.8341979 1 82 2.0489212 4 + 40 0.1616455 2 83 2.1357719 4 + 41 0.6720868 2 84 2.5107047 4 + 42 0.7622870 2 85 3.2857682 4 + 43 1.0743328 2 +------------------------------------------------------------------------ + -1.45744763288719 -1.08348725881446 -0.779304929609906 + -0.737215942115345 -0.562200605497247 -0.536632223783709 + -0.628341663300678 -0.394412768193199 -1.00360380778027 + -0.805060667553656 -0.606445264032674 -0.574188966380062 + -0.317326442801082 0.202800799044621 0.233145235052796 + 0.337983058333910 0.440079239040636 0.579655107668687 + 0.694925733138532 0.765107046589604 0.791740804983874 + 0.918791018981417 0.954755538002272 1.13523291727429 + 1.19089227502855 1.29940010677045 1.54398417734964 + 1.73771547923301 1.77296175003384 1.87275606979142 + 2.07033243972491 2.16414271052241 2.22716551838582 + 2.37935042101672 2.67188771673541 2.82679518054206 + 3.00135269229792 3.48382495469385 3.83419792398027 + 0.161645491943538 0.672086790797538 0.762286964920225 + 1.07433284544460 1.21294191744910 1.31164286730924 + 1.52834897888623 1.83843915784912 1.95741938237799 + 2.19148984413106 3.24217250366569 0.225995307622885 + 0.240907258016188 0.367066829963072 0.503535426660154 + 0.602764944530587 0.703370339876010 0.754380179427082 + 0.884420518732847 0.963411281466860 1.05921648685456 + 1.19048944155904 1.25814077480351 1.56916241916270 + 1.59698065950514 1.74380957764519 1.98636180732945 + 2.00366248439906 2.18806439955611 2.29777158087798 + 2.54071727310058 2.65864336644201 2.94192092693410 + 2.98537670707155 3.69592987620534 3.77000224671027 + 0.234652607488001 0.717601256707188 0.843863253708062 + 1.29216411509330 1.36495699837025 1.74438958333342 + 2.04892117101006 2.13577192131675 2.51070474122047 + 3.28576822533551 + @CHECKOUT-I, Total execution time (CPU/WALL): 7.14/ 0.54 seconds. +--executable xvtran finished with status 0 in 1.07 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xintprc + @GETMEM-I, Allocated 171661 MB of main memory. + @GMOIAA-I, Processing MO integrals for spin case AA. + @GMOIAA-I, Generation of integral list completed. + TYPE NUMBER + ---- -------- + PPPP 894479 + PPPH 640524 + PPHH 115497 + PHPH 63721 + PHHH 22938 + HHHH 1222 + + TOTAL 1738381 + + @FORMT2-I, Second-order MP correlation energies: + ------------------------------------------------ + E(SCF) = -228.643312572484 a.u. + E2(AA) = -0.093684343380 a.u. + E2(AB) = -0.520081687065 a.u. + E2(TOT) = -0.707450373824 a.u. + Total MP2 energy = -229.350762946308 a.u. + ------------------------------------------------ + Largest T2 amplitudes for spin case AB: + _ _ _ _ _ _ + i j a b i j a b i j a b +----------------------------------------------------------------------------- +[ 13 13 40 40]-0.06710 [ 8 8 40 40]-0.05436 [ 13 13 76 76]-0.05241 +[ 13 8 76 40]-0.04215 [ 8 13 40 76]-0.04215 [ 8 8 76 76]-0.03737 +[ 7 7 40 40]-0.03140 [ 13 7 40 76]-0.02053 [ 7 13 76 40]-0.02053 +[ 13 13 77 77]-0.01960 [ 13 13 42 40]-0.01810 [ 13 13 40 42]-0.01810 +[ 7 7 45 45]-0.01664 [ 13 13 41 41]-0.01633 [ 13 13 78 76]-0.01595 +----------------------------------------------------------------------------- + Norm of T2AB vector ( 230058 symmetry allowed elements): 0.4218925855. +----------------------------------------------------------------------------- + @CHECKOUT-I, Total execution time (CPU/WALL): 3.53/ 0.56 seconds. +--executable xintprc finished with status 0 in 1.14 seconds (walltime). + calling xncc + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xncc + @GETMEM-I, Allocated 7 MB of main memory. + +Running with 20 threads/proc + +Using DIIS to accelerate the convergence of T1 and T2 +Using DIIS to accelerate the convergence of T3 +Using immediate high-order contributions +Performing 2 CCSDT sub-iterations +Damping factor for T3: 0.000000 +Damping factor for T4: 0.000000 + +Transposes are coarse-threaded + +Memory limit: 167.638 GiB +Minimum memory requirement: 109.028 MiB +Compromise memory amount: 8.961 GiB +Optimal memory requirement: 92.002 GiB + +List Location Size Cached Hunks Est. Disk I/O +----------------- ---------- ----------- ------ ----- ------------- + + T_DIIS 70:0 8.787 MiB Yes - 158.166 MiB + Z_DIIS 70:1 8.787 MiB Yes - 263.610 MiB + 18 1.755 MiB Yes - 318.085 MiB + 233 52.803 MiB Yes - 154.696 GiB + 30 9.615 MiB Yes - 12.536 GiB + 16 1.755 MiB Yes - 2.780 GiB + 25 1.755 MiB Yes - 289.609 MiB + 21 1.755 MiB No - 0 B + 10 329.156 KiB Yes - 530.379 MiB + 13 60.633 KiB Yes - 4.441 MiB + F(EA) 92:0 11.891 KiB Yes - 4.703 MiB + F(EM) 93:0 2.250 KiB Yes - 945.000 KiB + F(MI) 91:0 456 B Yes - 240.469 KiB + Q(AI) 190:2 2.250 KiB Yes - 810.000 KiB + Q(Ab,Ij) 50 1.755 MiB Yes - 2.623 GiB + QQ(Ab,Ij) 3 1.755 MiB Yes - 421.249 MiB + T(AI) 90:0 2.250 KiB Yes - 3.232 MiB + T(Ab,Ij) 46 1.755 MiB Yes - 3.243 GiB + W(Mn,Ij) 53 60.633 KiB Yes - 26.645 MiB + W~(Ab,Ej) 130 9.615 MiB Yes - 16.446 GiB + W~(EM,bj) 56 1.755 MiB Yes - 1.568 GiB + W~(Em,Bj) 58 1.755 MiB Yes - 1.877 GiB + W~(Ij,Mb) 110 329.156 KiB Yes - 351.979 MiB + W~~(Ab,Ej) 169 9.615 MiB Yes - 5.916 GiB + W~~(EM,bj) 76 1.755 MiB Yes - 789.841 MiB + W~~(Em,Bj) 78 1.755 MiB Yes - 789.841 MiB + W~~(Ij,Mb) 165 329.156 KiB Yes - 202.508 MiB + Z(AI) 90:2 2.250 KiB Yes - 810.000 KiB + Z(Ab,Ij) 63 1.755 MiB Yes - 631.873 MiB + Q(abc,ijk) Q3FILE 319.713 MiB Yes 1 18.733 GiB + T(abc,ijk) T3FILE 319.713 MiB Yes 1 56.200 GiB + T(abcd,ijkl) - 83.022 GiB No 1 0 B + T3_1 T3_1 319.713 MiB Yes 1 9.367 GiB + T3_2 T3_2 319.713 MiB Yes 1 4.683 GiB + T3_3 T3_3 319.713 MiB Yes 1 4.683 GiB + T3_4 T3_4 319.713 MiB Yes 1 4.683 GiB + T3_5 T3_5 319.713 MiB Yes 1 4.683 GiB + W(abc,ije) WABCIJE 4.602 GiB Yes 1 138.057 GiB + W(abm,ijk) WABMIJK 154.671 MiB Yes 1 4.531 GiB + Z(abc,ijk) Z3FILE 319.713 MiB Yes 1 51.516 GiB + Z(abcd,ijkl) - 83.022 GiB No 1 0 B + Z3_1 Z3_1 319.713 MiB Yes 1 9.367 GiB + Z3_2 Z3_2 319.713 MiB Yes 1 9.367 GiB + Z3_3 Z3_3 319.713 MiB Yes 1 9.367 GiB + Z3_4 Z3_4 319.713 MiB Yes 1 9.367 GiB + Z3_5 Z3_5 319.713 MiB Yes 1 9.367 GiB + +Simulation and memory analysis took 16.656 seconds + +MP2 correlation energy: -0.707450373824315 + +Non-iterative calculation of MP2 took 0.188 cpu seconds and 0.010 walltime seconds at 1.349 Gflops/sec + +Total MP2 energy: -229.350762946308038 + +Beginning iterative solution of CC4 equations: + +It. Correlation Energy T1 Residual T2 Residual T3 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------------------- + 1 -0.763375159102744 3.28785e-03 6.98171e-03 4.80884e-04 22621.529 1196.376 + 2 -0.766433762900516 5.88798e-04 1.62319e-03 1.10295e-04 23062.492 1229.456 + 3 -0.766857072881060 1.23168e-04 2.49712e-04 3.48802e-05 23807.750 1282.923 + 4 -0.766869333160990 1.85847e-05 1.98072e-05 1.06542e-05 24460.077 1332.728 + 5 -0.766866389167529 1.49279e-06 1.58229e-06 2.17366e-06 25199.102 1390.896 + + A I A I A I +-------------------------- -------------------------- -------------------------- + 19 17 -0.0297256743386 31 17 0.0116307205787 25 15 0.0075767455010 + 19 12 0.0286586556753 36 17 -0.0107385016684 21 14 -0.0074621820902 + 34 18 0.0227581299395 25 16 -0.0100970812397 45 17 0.0074604919856 + 23 18 0.0168465032737 27 16 -0.0093740175532 26 13 0.0071607167867 + 51 18 0.0135429419447 53 17 0.0076606092376 49 17 0.0066118894725 + + A B I J A B I J +------------------------------------ ------------------------------------ + 19 19 18 18 -0.1082304819777 23 19 12 18 -0.0301860542543 + 23 23 18 18 -0.0621899371619 36 19 18 18 -0.0274304417538 + 23 19 18 17 -0.0611568155877 19 36 18 18 -0.0274304417538 + 19 23 17 18 -0.0611568155877 19 23 12 18 -0.0229486425034 + 19 19 17 17 -0.0594078338407 23 19 18 12 -0.0229486425034 + 23 23 17 17 -0.0589677787849 19 23 18 17 -0.0213253760558 + 19 19 12 12 -0.0367239396211 23 19 17 18 -0.0213253760558 + 19 23 18 12 -0.0301860542543 + +It. Correlation Energy T1 Residual T2 Residual T3 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------------------- + 6 -0.766866336061061 5.68331e-07 3.26099e-07 3.59252e-07 25462.752 1419.642 + 7 -0.766866267531340 1.02660e-07 3.63553e-08 4.61834e-08 25861.423 1441.941 + 8 -0.766866256888079 1.71035e-08 5.77081e-09 4.83505e-09 26140.130 1463.487 + +CC4 iterations converged in 8 cycles and 10757.452 seconds (1344.682 s/it.) at 11.883 Gflops/sec + +Total CC4 energy: -229.410178829371802 + + @CHECKOUT-I, Total execution time (CPU/WALL): 196656.36/ 10778.59 seconds. +--executable xncc finished with status 0 in 10780.64 seconds (walltime). + The final electronic energy is -229.410178829371802 a.u. + This computation required 10792.12 seconds (walltime). diff --git a/furan/cc-pvdz/CC/fura-gs-ccsd.out b/furan/cc-pvdz/CC/fura-gs-ccsd.out new file mode 100644 index 0000000..5ebcd4f --- /dev/null +++ b/furan/cc-pvdz/CC/fura-gs-ccsd.out @@ -0,0 +1,1029 @@ + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xjoda + + + ************************************************************************* + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + ************************************************************************* + + **************************************************************** + * CFOUR Coupled-Cluster techniques for Computational Chemistry * + **************************************************************** + + + Department of Chemistry Institut fuer Physikalische Chemie + University of Florida Universitaet Mainz + Gainesville, FL 32611, USA D-55099 Mainz, Germany + + Department of Chemistry Fakultaet fuer Chemie und Biowiss. + Johns Hopkins University Karlsruher Institut fuer Technologie + Baltimore, MD 21218, USA D-76131 Karlsruhe, Germany + + Department of Chemistry Department of Physical Chemistry + Southern Methodist University Eotvos Lorand University + Dallas, TX 75275, USA H-1053 Budapest, Hungary + + + Version 2.1 + + nazare074.cluster + Thu Oct 15 11:17:07 CEST 2020 + integer*8 version is running + +******************************************************************************** +* Input from ZMAT file * +******************************************************************************** +Ketene -GS +C 0.00000000 2.06365826 -0.60051250 +C 0.00000000 -2.06365826 -0.60051250 +C 0.00000000 1.35348578 1.86336416 +C 0.00000000 -1.35348578 1.86336416 +O 0.00000000 0.00000000 -2.13945332 +H 0.00000000 3.86337287 -1.53765695 +H 0.00000000 -3.86337287 -1.53765695 +H 0.00000000 2.59168789 3.47168051 +H 0.00000000 -2.59168789 3.47168051 + +*CFOUR(COORD=CARTESIAN,UNITS=BOHR + MEMORY=100,MEM_UNIT=GB,CC_PROG=NCC + FROZEN_CORE=1 + CALC=CCSD,BASIS=PVDZ + SCF_CONV=9,CC_CONV=7,ESTATE_MAXCYC=80) + +******************************************************************************** + ------------------------------------------------------------------- + CFOUR Control Parameters + ------------------------------------------------------------------- + External Internal Value Units + Name Name + ------------------------------------------------------------------- + ABCDTYPE IABCDT STANDARD [ 0] *** + ANHARMONIC IANHAR OFF [ 0] *** + ANH_ALGORIT IANALG STANDARD [ 0] *** + ANH_DERIVAT IANDER SECOND [ 1] *** + ANH_MODE ANHMOD VIBRATION [ 0] *** + ANH_STEPSIZ ICUBST 50000 x 10-6 + ANH_SYMMETR IANHSM ABELIAN [ 0] *** + AO_LADDERS IAOLAD SINGLEPASS [ 1] *** + AV_SCF IAVSCF OFF [ 0] *** + BASIS IBASIS PVDZ [ 13] *** + BOTHVECTORS BOTHVC OFF [ 0] *** + BOX_POTENT IPIAB OFF [ 0] *** + BREIT IBREIT OFF [ 0] *** + BRUCK_CONV IBRTOL 10D- 4 *** + BRUECKNER IBRKNR OFF [ 0] *** + BUFFERSIZE IBUFFS 4096 *** + CACHE_RECS ICHREC 10 *** + CALCLEVEL ICLLVL CCSD [ 10] *** + CCORBOPT ICCORB OFF [ 0] x 0.01 + CC_CONV ICCCNV 10D- 7 *** + CC_EXPORDER ICCEOR 5 *** + CC_EXTRAPOL ICCEXT DIIS [ 1] *** + CC_GUESS ICCGES MP2 [ 0] *** + CC_MAXCYC ICCCYC 100 cycles + CC_PROGRAM ICCPRO NCC [ 5] *** + CHARGE ICHRGE 0 *** + CHOLESKY ICHOLE OFF [ 0] *** + CIS_CONV ICISTL 5 *** + COMM_SIZE IPSIZE *** *** + CONSTANT ICONST OLD [ 1] *** + CONTINUUM ICONTU NONE [ 0] *** + CONTRACTION ICNTYP GENERAL [ 1] *** + COORDINATES ICOORD CARTESIAN [ 1] *** + CPHF_CONVER ICPHFT 10D- 16 *** + CPHF_MAXCYC ICPHFC 64 cycles + CUBIC ICUBIC OFF [ 0] *** + CURVILINEAR ICURVY OFF [ 0] *** + DBOC IDBOC OFF [ 0] *** + DCT IDCT OFF [ 0] *** + DERIV_LEV IDRLVL ZERO [ 0] *** + DEVMEM_SIZE IDVMEM ********* MByte + DIAG_MRCC IEOMST 10D- 0 *** + DIFF_TYPE IDIFTY RELAXED [ 0] *** + DIRECT IDIRCT OFF [ 0] *** + DROPMO IDRPMO NONE + ECP IECP OFF [ 0] *** + EIGENVECTOR IVEC 1 *** + EL_ANHARM IELANH OFF [ 0] *** + EOMFOLLOW IEOMSR ENERGY [ 0] *** + EOMIP IEOMIP OFF [ 0] *** + EOMLEVEL HBARFM SAME [ 0] *** + EOM_MRCC IMRCCE NEW [ 1] *** + EOM_NONIT EOMNON OFF [ 0] *** + EOM_NSING IEOMSI 10D- 0 *** + EOM_NSTATES IMRCCD DAVIDSON [ 0] *** + EOM_NTRIP IEOMTR 10D- 0 *** + EOM_ORDER IEXORD ENERGY [ 0] *** + EOM_PROPSTA IEOMST 0 *** + ESTATE_CONV IEXTOL 10D- 5 *** + ESTATE_DIAG IEXDIG ITERATIVE [ 0] *** + ESTATE_LOCK IESLOC ON [ 1] *** + ESTATE_MAXC IEXMXC 80 *** + ESTATE_PROP IEXPRP OFF [ 0] *** + EVAL_HESS IRECAL 0 # of cyc. + EXCITATION IEXCIT 0 *** + EXCITE IEXCIT NONE [ 0] *** + EXTERN_POT IEXPOT OFF [ 0] *** + FCGRADNEW IFCGNW OFF [ 0] *** + FC_FIELD IFINFC 0 x 10-6 + FD_CALTYPE IFDCAL GRADONLY [ 0] *** + FD_PROJECT IFDPRJ OFF [ 1] *** + FD_STEPSIZE IDISFD 0 10-4 bohr + FD_USEGROUP IFDGRP FULL [ 0] *** + FILE_RECSIZ IFLREC 4096 words + FINITE_PERT IFIPER 0 x 10-6 + FIXGEOM IFIXGM OFF [ 0] *** + FOCK IFOCK AO [ 1] *** + FREQ_ALGORI IVIALG STANDARD [ 0] *** + FROZEN_CORE IFROCO ON [ 1] *** + GAMMA_ABCD IGABCD STORE [ 0] *** + GAMMA_ABCI IGABCI STORE [ 0] *** + GENBAS_1 IGNBS1 0 *** + GENBAS_2 IGNBS2 0 *** + GENBAS_3 IGNBS3 0 *** + GENBAS_4 IGNBS4 0 *** + GEO_CONV ICONTL 5 H/bohr + GEO_MAXCYC IOPTCY 50 *** + GEO_MAXSTEP IMXSTP 300 millibohr + GEO_METHOD INR SINGLE_POINT[ 5] *** + GIAO IGIAO OFF [ 1] *** + GIMIC IGIMIC OFF [ 0] *** + GRID IGRID OFF [ 0] *** + GRID_ALGO IGALGO SERIAL [ 0] *** + GUESS IGUESS MOREAD [ 0] *** + HBAR IHBAR OFF [ 0] *** + HESS_TYPE IHESTP SCF [ 0] *** + HF2_FILE IHF2Fl USE [ 1] *** + HFSTABILITY ISTABL OFF [ 0] *** + INCORE INCORE OFF [ 0] *** + INPUT_MRCC IMRCC ON [ 1] *** + INTEGRALS INTTYP VMOL [ 1] *** + JODA_PRINT IJPRNT 0 *** + KEYWORD_OUT IDMPKW NO [ 0] *** + LINDEP_TOL ILINDP 8 *** + LINEQ_CONV IZTACN 10D- 7 cycles + LINEQ_EXPOR ILMAXD 5 *** + LINEQ_MAXCY ILMAXC 100 *** + LINEQ_TYPE ILTYPE DIIS [ 1] *** + LOCK_ORBOCC ILOCOC OFF [ 0] *** + MEMORY_SIZE IMEMSZ ********* words + MEM_UNIT IMEMU GB [ 3] *** + MRCC IMRCCC OFF [ 0] *** + MULTIPLICTY IMULTP 1 *** + NACOUPLING IVCOUP OFF [ 0] *** + NEGEVAL IDIE ABORT [ 0] *** + NEWNORM INEWNO OFF [ 0] *** + NON-HF INONHF OFF [ 0] *** + NTOP_TAMP ITOPT2 15 *** + NUC_MODEL INUCMO POINT [ 0] *** + OCCUPATION IOCCU ESTIMATED BY SCF + OPEN-SHELL IOPEN SPIN-ORBITAL[ 0] *** + OPTVIB IOPTVB OFF [ 0] *** + ORBITALS IORBTP STANDARD [ 0] *** + PARALLEL IPARAL ON [ 1] *** + PARA_INT IPINTS ON [ 1] *** + PARA_PRINT IPPRIN 0 *** + PERT_ORB IPTORB STANDARD [ 0] *** + POINTS IGRDFD 0 *** + PRINT IPRNT 0 *** + PROPS IPROPS OFF [ 0] *** + PROP_INTEGR IINTYP INTERNAL [ 0] *** + PSI IPSI OFF [ 0] *** + QC_ALG IQCALG FLM [ 0] *** + QC_LINALG IQCLIN TRIDIAG [ 2] *** + QC_MAXCYC IQCMAX 10D-100 cycles + QC_MAXSCFCY IQCMSC 10D- 15 cycles + QC_RTRUST IQCRTR 10D- 0 x 10-3 + QC_SKIPSCF IQCSKI OFF [ 0] *** + QC_START IQCSTA 10D- 1 *** + QRHFGUESS IQGUES OFF [ 0] *** + QUARTIC IQUART OFF [ 0] *** + RAMAN_INT IRAMIN OFF [ 0] *** + RAMAN_ORB IRAMRE UNRELAXED [ 0] *** + RDO IRDOFM OFF [ 0] *** + REDUCE_REPR REDREP Ir [ 0] *** + REFERENCE IREFNC RHF [ 0] *** + RELATIVIST IRELAT OFF [ 0] *** + RELAX_DENS IRDENS OFF [ 0] *** + RESET_FLAGS IRESET OFF [ 0] *** + RESTART_CC ICCRES OFF [ 0] *** + ROT_EVEC ROTVEC 0 *** + SAVE_INTS ISVINT OFF [ 0] *** + SCALE_ON ISTCRT 0 *** + SCF_CONV ISCFCV 10D- 9 *** + SCF_DAMPING IDAMP 0 x 10-3 + SCF_EXPORDE IRPPOR 6 *** + SCF_EXPSTAR IRPPLS 8 *** + SCF_EXTRAPO IRPP ON [ 1] *** + SCF_MAXCYC ISCFCY 150 cycles + SCF_NOSTOP ISCFST OFF [ 0] *** + SCF_PRINT ISCFPR 0 *** + SCF_PROG ISCFPR SCF [ 0] *** + SD_FIELD IFINSD 0 x 10-6 + SOPERT IPERSO OFF [ 0] *** + SPHERICAL IDFGHI ON [ 1] *** + SPINORBIT ISOCAL OFF [ 0] *** + SPINROTATIO ISRCON OFF [ 0] *** + SPIN_FLIP ISPFLP OFF [ 0] *** + SPIN_ORBIT ISPORB OFF [ 0] *** + SPIN_SCAL ISCSMP OFF [ 0] *** + STEEPSCALE ISTPSC 1000 x 10-3 + SUBGROUP ISUBGP DEFAULT [ 0] *** + SUBGRPAXIS ISBXYZ X [ 0] *** + SYMMETRY ISYM ON [ 0] *** + SYM_CHECK ISYMCK OVERRIDE [ 1] *** + T3_EXTRAPOL IT3EXT OFF [ 0] *** + T4_EXTRAPOL IT4EXP OFF [ 0] *** + TAMP_SUM IEVERY 5 *** + TESTSUITE ITESTS OFF [ 0] *** + THERMOCH ITHERM OFF [ 0] *** + TOL_CHOLESK ITOLCH 10D- 4 *** + TRANGRAD IRESRM OFF [ 0] *** + TRANS_INV ITRAIN USE [ 0] *** + TREAT_PERT ITREAT SIMULTANEOUS[ 0] *** + TRIP_ALGORI ITRALG NORMAL [ 0] *** + UIJ_THRESHO IUIJTH 1 *** + UNITS IUNITS BOHR [ 1] *** + UNOS IUNOS OFF [ 0] *** + UPDATE_HESS IHUPDT ON [ 1] *** + VIBPHASE ISETPH STANDARD [ 0] *** + VIBRATION IVIB NO [ 0] *** + VIB_ALGORIT IGEALG STANDARD [ 0] *** + VNATORB IVNORB OFF [ 0] *** + VTRAN IVTRAN FULL/PARTIAL[ 0] *** + XFIELD IXEFLD 0 x 10-6 + XFORM_TOL IXFTOL 10D- 11 *** + YFIELD IYEFLD 0 x 10-6 + ZFIELD IZEFLD 0 x 10-6 + ZSCALE_EXP IZEXPS OFF [ 0] *** + ------------------------------------------------------------------- + @GETXYZ-I, 9 atoms read from ZMAT. + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 +******************************************************************************** + The full molecular point group is C2v . + The largest Abelian subgroup of the full molecular point group is C2v . + The computational point group is C2v . +******************************************************************************** + + + ---------------------------------------------------------------- + Coordinates used in calculation (QCOMP) + ---------------------------------------------------------------- + Z-matrix Atomic Coordinates (in bohr) + Symbol Number X Y Z + ---------------------------------------------------------------- + C 6 0.00000000 -2.06365826 0.60031230 + C 6 0.00000000 2.06365826 0.60031230 + C 6 0.00000000 -1.35348578 -1.86356436 + C 6 0.00000000 1.35348578 -1.86356436 + O 8 0.00000000 0.00000000 2.13925312 + H 1 0.00000000 -3.86337287 1.53745675 + H 1 0.00000000 3.86337287 1.53745675 + H 1 0.00000000 -2.59168789 -3.47188071 + H 1 0.00000000 2.59168789 -3.47188071 + ---------------------------------------------------------------- + + Interatomic distance matrix (Angstroms) + + C C C C O + [ 1] [ 2] [ 3] [ 4] [ 5] + C [ 1] 0.00000 + C [ 2] 2.18408 0.00000 + C [ 3] 1.35691 2.22931 0.00000 + C [ 4] 2.22931 1.35691 1.43247 0.00000 + O [ 5] 1.36226 1.36226 2.23601 2.23601 0.00000 + H [ 6] 1.07375 3.17541 2.23677 3.29549 2.06906 + H [ 7] 3.17541 1.07375 3.29549 2.23677 2.06906 + H [ 8] 2.17295 3.27299 1.07409 2.25451 3.27071 + H [ 9] 3.27299 2.17295 2.25451 1.07409 3.27071 + + H H H H + [ 6] [ 7] [ 8] [ 9] + H [ 6] 0.00000 + H [ 7] 4.08882 0.00000 + H [ 8] 2.73491 4.32378 0.00000 + H [ 9] 4.32378 2.73491 2.74292 0.00000 + rotcon2 + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 + There are 5 frozen-core orbitals. + There are 90 basis functions. + @GEOPT-W, Archive file not created for single-point calculation. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.12/ 2.00 seconds. +--executable xjoda finished with status 0 in 2.56 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol + SERIAL VERSION OF MOLECULE STARTED +******************************************************************************** + INPUT FROM MOL FILE +******************************************************************************** +INTGRL 1 0 1 0 0 0 0 0 0 + *** CFOUR Program System (Release V0.1) *** +Ketene -GS + 5 2 X Y 0.10E-08 0 0 + 9999.00 3.00 + 6.00000000 1 3 1 1 1 +C #1 0.000000000000000 -2.063658260000000 0.600312302999175 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 6.00000000 1 3 1 1 1 +C #2 0.000000000000000 -1.353485780000000 -1.863564357000825 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 8.00000000 1 3 1 1 1 +O #3 0.000000000000000 0.000000000000000 2.139253122999175 + 9 3 + 11720.0000000000 7.100000000000000E-004 -1.600000000000000E-004 + 0.000000000000000E+000 + 1759.00000000000 5.470000000000000E-003 -1.263000000000000E-003 + 0.000000000000000E+000 + 400.800000000000 2.783700000000000E-002 -6.267000000000000E-003 + 0.000000000000000E+000 + 113.700000000000 0.104800000000000 -2.571600000000000E-002 + 0.000000000000000E+000 + 37.0300000000000 0.283062000000000 -7.092400000000000E-002 + 0.000000000000000E+000 + 13.2700000000000 0.448719000000000 -0.165411000000000 + 0.000000000000000E+000 + 5.02500000000000 0.270952000000000 -0.116955000000000 + 0.000000000000000E+000 + 1.01300000000000 1.545800000000000E-002 0.557368000000000 + 0.000000000000000E+000 + 0.302300000000000 -2.585000000000000E-003 0.572759000000000 + 1.00000000000000 + 4 2 + 17.7000000000000 4.301800000000000E-002 0.000000000000000E+000 + 3.85400000000000 0.228913000000000 0.000000000000000E+000 + 1.04600000000000 0.508728000000000 0.000000000000000E+000 + 0.275300000000000 0.460531000000000 1.00000000000000 + 1 1 + 1.18500000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #4 0.000000000000000 -3.863372870000000 1.537456752999175 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #5 0.000000000000000 -2.591687890000000 -3.471880707000825 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 +FINISH + +******************************************************************************** + ONE- AND TWO-ELECTRON INTEGRALS OVER SYMMETRY-ADAPTED AOS ARE CALCULATED. + + SPHERICAL HARMONICS ARE USED. + + INTEGRALS LESS THAN 0.10E-13 ARE NEGLECTED. + + NUCLEAR REPULSION ENERGY : 161.1082297788 A.U. + @MOLECU-I, ONE ELECTRON INTEGRALS (CPU/WALL): 0.02/ 0.05 SECONDS. + @TWOEL-I, 325108 INTEGRALS OF SYMMETRY TYPE I I I I + @TWOEL-I, 908743 INTEGRALS OF SYMMETRY TYPE I J I J + @TWOEL-I, 490042 INTEGRALS OF SYMMETRY TYPE I I J J + @TWOEL-I, 460725 INTEGRALS OF SYMMETRY TYPE I J K L + @TWOEL-I, TOTAL NUMBER OF 2-E INTEGRALS 2184618. + @MOLECU-I, TWO ELECTRON INTEGRALS (CPU/WALL): 1.42/ 1.43 SECONDS. + @CHECKOUT-I, Total execution time (CPU/WALL): 1.45/ 1.49 seconds. + +Running with 20 threads/proc + +--executable xvmol finished with status 0 in 2.18 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol2ja + @GETMEM-I, Allocated 95367 MB of main memory. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.28/ 0.05 seconds. +--executable xvmol2ja finished with status 0 in 0.56 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvscf + There are 90 functions in the AO basis. + + There are 4 irreducible representations. + + Irrep # of functions + 1 35 + 2 13 + 3 31 + 4 11 + + + Parameters for SCF calculation: + SCF reference function: RHF + Maximum number of iterations: 150 + Full symmetry point group: C2v + Computational point group: C2v + Initial density matrix: MOREAD + SCF convergence tolerance: 10**(- 9) + DIIS convergence acceleration: ON + Latest start for DIIS: 8 + DIIS order: 6 + + Memory information: 341888 words required. + Fock matrices are constructed from AO integral file. + @GETMEM-I, Allocated 2 MB of main memory. + Initialization and symmetry analysis required 0.001 seconds. + + @INITGES-I, Occupancies from core Hamiltonian: + + Alpha population by irrep: 9 2 6 1 + Beta population by irrep: 9 2 6 1 + + + total no. of electrons in initial guess : 0.000000000000000E+000 + -------------------------------------------------------------------- + Iteration Total Energy Largest Density Difference + -------------------------------------------------------------------- + 0 161.108229778788910 0.0000000000D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 1 -196.263249175407992 0.1098182460D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 2 -179.889864626336106 0.1675780025D+02 + current occupation vector + 9 1 7 1 + 9 1 7 1 + 3 -180.580457259652945 0.1772125138D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 4 -162.771013663095033 0.1566999730D+02 + current occupation vector + 8 2 7 1 + 8 2 7 1 + 5 -169.943224465301597 0.1454729382D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 6 -160.269967975315780 0.1454634919D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 7 -168.828658617537684 0.1395077743D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 8 -160.232275948463297 0.1395068492D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 9 -209.746508446745025 0.5520995458D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 10 -228.180230304181549 0.2015536648D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 11 -228.454713327495682 0.6531384936D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 12 -228.600329261507483 0.3196758217D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 13 -228.637509917234041 0.7498321731D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 14 -228.642938164599826 0.5250342791D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 15 -228.643241982659248 0.9795506231D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 16 -228.643308522550143 0.3593200395D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 17 -228.643312517846056 0.1473098013D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 18 -228.643312570337258 0.1244041229D-03 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 19 -228.643312572356052 0.2423484470D-04 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 20 -228.643312572476049 0.5414751593D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 21 -228.643312572485769 0.2003507219D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 22 -228.643312572485598 0.8833300562D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 23 -228.643312572484461 0.3139636784D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 24 -228.643312572486110 0.4136764657D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 25 -228.643312572485542 0.9839839787D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 26 -228.643312572486622 0.1838835018D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 27 -228.643312572484007 0.3228508794D-08 + current occupation vector + 9 2 6 1 + 9 2 6 1 + + SCF has converged. + + Density matrix saved to file den.dat + total electron number: 36.0000000000000 + E(SCF)= -228.643312572484575 0.7981584282D-09 + + Eigenvector printing suppressed. + + @PUTMOS-I, Writing converged MOs to NEWMOS. + @PUTMOS-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTMOS-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTMOS-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTMOS-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + @PUTFOCK-I, Writing converged Fock matrix to NEWFOCK. + @PUTFOCK-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTFOCK-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + + + + ORBITAL EIGENVALUES (ALPHA) (1H = 27.2113834 eV) + + MO # E(hartree) E(eV) FULLSYM COMPSYM + ---- -------------------- -------------------- ------- --------- + 1 1 -20.6219765861 -561.1525113512 A1 A1 (1) + 2 49 -11.2892088103 -307.1949892207 B2 B2 (3) + 3 2 -11.2891634657 -307.1937553315 A1 A1 (1) + 4 3 -11.2328159068 -305.6604603025 A1 A1 (1) + 5 50 -11.2318729764 -305.6348018622 B2 B2 (3) + 6 4 -1.4574476329 -39.6591663239 A1 A1 (1) + 7 5 -1.0834872588 -29.4831872086 A1 A1 (1) + 8 51 -1.0036038078 -27.3094479952 B2 B2 (3) + 9 52 -0.8050606676 -21.9068144851 B2 B2 (3) + 10 6 -0.7793049296 -21.2059652251 A1 A1 (1) + 11 7 -0.7372159421 -20.0606656495 A1 A1 (1) + 12 36 -0.6283416633 -17.0980459063 B1 B1 (2) + 13 53 -0.6064452640 -16.5022145907 B2 B2 (3) + 14 54 -0.5741889664 -15.6244761082 B2 B2 (3) + 15 8 -0.5622006055 -15.2982562239 A1 A1 (1) + 16 9 -0.5366322238 -14.6025051862 A1 A1 (1) + 17 37 -0.3944127682 -10.7325170532 B1 B1 (2) + 18 80 -0.3173264428 -8.6348914980 A2 A2 (4) + +++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ + 19 38 0.1616454919 4.3985974562 B1 B1 (2) + 20 10 0.2028007990 5.5184902966 A1 A1 (1) + 21 55 0.2259953076 6.1496449623 B2 B2 (3) + 22 11 0.2331452351 6.3442043789 A1 A1 (1) + 23 81 0.2346526075 6.3852220682 A2 A2 (4) + 24 56 0.2409072580 6.5554197617 B2 B2 (3) + 25 12 0.3379830583 9.1969865830 A1 A1 (1) + 26 57 0.3670668300 9.9883962435 B2 B2 (3) + 27 13 0.4400792390 11.9751648999 A1 A1 (1) + 28 58 0.5035354267 13.7018955503 B2 B2 (3) + 29 14 0.5796551077 15.7732173745 A1 A1 (1) + 30 59 0.6027649445 16.4020680057 B2 B2 (3) + 31 39 0.6720867908 18.2884113425 B1 B1 (2) + 32 15 0.6949257331 18.9098905590 A1 A1 (1) + 33 60 0.7033703399 19.1396799905 B2 B2 (3) + 34 82 0.7176012567 19.5269229246 A2 A2 (4) + 35 61 0.7543801794 20.5277282917 B2 B2 (3) + 36 40 0.7622869649 20.7428828633 B1 B1 (2) + 37 16 0.7651070466 20.8196211868 A1 A1 (1) + 38 17 0.7917408050 21.5443625978 A1 A1 (1) + 39 83 0.8438632537 22.9626865338 A2 A2 (4) + 40 62 0.8844205187 24.0663058221 B2 B2 (3) + 41 18 0.9187910190 25.0015746820 A1 A1 (1) + 42 19 0.9547555380 25.9802189979 A1 A1 (1) + 43 63 0.9634112815 26.2157537519 B2 B2 (3) + 44 64 1.0592164869 28.8227459274 B2 B2 (3) + 45 41 1.0743328454 29.2340829566 B1 B1 (2) + 46 20 1.1352329173 30.8912581602 A1 A1 (1) + 47 65 1.1904894416 32.3948646279 B2 B2 (3) + 48 21 1.1908922750 32.4058262839 A1 A1 (1) + 49 42 1.2129419174 33.0058275576 B1 B1 (2) + 50 66 1.2581407748 34.2357509943 B2 B2 (3) + 51 84 1.2921641151 35.1615731515 A2 A2 (4) + 52 22 1.2994001068 35.3584744953 A1 A1 (1) + 53 43 1.3116428673 35.6916169462 B1 B1 (2) + 54 85 1.3649569984 37.1423682072 A2 A2 (4) + 55 44 1.5283489789 41.5884900335 B1 B1 (2) + 56 23 1.5439841774 42.0139454134 A1 A1 (1) + 57 67 1.5691624192 42.6990802047 B2 B2 (3) + 58 68 1.5969806595 43.4560530082 B2 B2 (3) + 59 24 1.7377154792 47.2856421455 A1 A1 (1) + 60 69 1.7438095776 47.4514709939 B2 B2 (3) + 61 86 1.7443895833 47.4672537511 A2 A2 (4) + 62 25 1.7729617500 48.2447419337 A1 A1 (1) + 63 45 1.8384391578 50.0264727818 B1 B1 (2) + 64 26 1.8727560698 50.9602834298 A1 A1 (1) + 65 46 1.9574193824 53.2640892885 B1 B1 (2) + 66 70 1.9863618073 54.0516527104 B2 B2 (3) + 67 71 2.0036624844 54.5224280672 B2 B2 (3) + 68 87 2.0489211710 55.7539795407 A2 A2 (4) + 69 27 2.0703324397 56.3366097828 A1 A1 (1) + 70 88 2.1357719213 58.1173086059 A2 A2 (4) + 71 28 2.1641427105 58.8893170284 A1 A1 (1) + 72 72 2.1880643996 59.5402592802 B2 B2 (3) + 73 47 2.1914898441 59.6334703659 B1 B1 (2) + 74 29 2.2271655184 60.6042548161 A1 A1 (1) + 75 73 2.2977715809 62.5255434529 B2 B2 (3) + 76 30 2.3793504210 64.7454165492 A1 A1 (1) + 77 89 2.5107047412 68.3197493175 A2 A2 (4) + 78 74 2.5407172731 69.1364318293 B2 B2 (3) + 79 75 2.6586433664 72.3453639681 B2 B2 (3) + 80 31 2.6718877167 72.7057610618 A1 A1 (1) + 81 32 2.8267951805 76.9210074510 A1 A1 (1) + 82 76 2.9419209269 80.0537382753 B2 B2 (3) + 83 77 2.9853767071 81.2362301695 B2 B2 (3) + 84 33 3.0013526923 81.6709588287 A1 A1 (1) + 85 48 3.2421725037 88.2239990462 B1 B1 (2) + 86 90 3.2857682253 89.4102989431 A2 A2 (4) + 87 34 3.4838249547 94.7996965407 A1 A1 (1) + 88 78 3.6959298762 100.5713648809 B2 B2 (3) + 89 79 3.7700022467 102.5869765541 B2 B2 (3) + 90 35 3.8341979240 104.3338297409 A1 A1 (1) + + + VSCF finished. + + @CHECKOUT-I, Total execution time (CPU/WALL): 3.94/ 0.86 seconds. +--executable xvscf finished with status 0 in 1.37 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvtran + @GETMEM-I, Allocated 95367 MB of main memory. + Full RHF integral transformation + The following 5 MOs will be dropped: + 1 2 3 12 13 + There are 85 active molecular orbitals. + Transformation of IIII integrals : + 1 pass through the AO integral file was required. + 325108 AO integrals were read. + 240883 MO integrals were written to HF2. + Transformation of IIJJ integrals : + 1 pass through the AO integral file was required. + 490042 AO integrals were read. + 386877 MO integrals were written to HF2. + Transformation of IJIJ integrals : + 1 pass through the AO integral file was required. + 908743 AO integrals were read. + 712509 MO integrals were written to HF2. + Transformation of IJKL integrals : + 1 pass through the AO integral file was required. + 460725 AO integrals were read. + 398112 MO integrals were written to HF2. + Summary of active molecular orbitals: +------------------------------------------------------------------------ + + Index Eigenvalue Symmetry Index Eigenvalue Symmetry +------------------------------------------------------------------------ + 1 -1.4574476 1 44 1.2129419 2 + 2 -1.0834873 1 45 1.3116429 2 + 3 -0.7793049 1 46 1.5283490 2 + 4 -0.7372159 1 47 1.8384392 2 + 5 -0.5622006 1 48 1.9574194 2 + 6 -0.5366322 1 49 2.1914898 2 + 7 -0.6283417 2 50 3.2421725 2 + 8 -0.3944128 2 51 0.2259953 3 + 9 -1.0036038 3 52 0.2409073 3 + 10 -0.8050607 3 53 0.3670668 3 + 11 -0.6064453 3 54 0.5035354 3 + 12 -0.5741890 3 55 0.6027649 3 + 13 -0.3173264 4 56 0.7033703 3 + 14 0.2028008 1 57 0.7543802 3 + 15 0.2331452 1 58 0.8844205 3 + 16 0.3379831 1 59 0.9634113 3 + 17 0.4400792 1 60 1.0592165 3 + 18 0.5796551 1 61 1.1904894 3 + 19 0.6949257 1 62 1.2581408 3 + 20 0.7651070 1 63 1.5691624 3 + 21 0.7917408 1 64 1.5969807 3 + 22 0.9187910 1 65 1.7438096 3 + 23 0.9547555 1 66 1.9863618 3 + 24 1.1352329 1 67 2.0036625 3 + 25 1.1908923 1 68 2.1880644 3 + 26 1.2994001 1 69 2.2977716 3 + 27 1.5439842 1 70 2.5407173 3 + 28 1.7377155 1 71 2.6586434 3 + 29 1.7729618 1 72 2.9419209 3 + 30 1.8727561 1 73 2.9853767 3 + 31 2.0703324 1 74 3.6959299 3 + 32 2.1641427 1 75 3.7700022 3 + 33 2.2271655 1 76 0.2346526 4 + 34 2.3793504 1 77 0.7176013 4 + 35 2.6718877 1 78 0.8438633 4 + 36 2.8267952 1 79 1.2921641 4 + 37 3.0013527 1 80 1.3649570 4 + 38 3.4838250 1 81 1.7443896 4 + 39 3.8341979 1 82 2.0489212 4 + 40 0.1616455 2 83 2.1357719 4 + 41 0.6720868 2 84 2.5107047 4 + 42 0.7622870 2 85 3.2857682 4 + 43 1.0743328 2 +------------------------------------------------------------------------ + -1.45744763288719 -1.08348725881441 -0.779304929609897 + -0.737215942115339 -0.562200605497301 -0.536632223783724 + -0.628341663300699 -0.394412768193209 -1.00360380778026 + -0.805060667553655 -0.606445264032669 -0.574188966380078 + -0.317326442801090 0.202800799044599 0.233145235052782 + 0.337983058334004 0.440079239041159 0.579655107669000 + 0.694925733138531 0.765107046589679 0.791740804983910 + 0.918791018982032 0.954755538003189 1.13523291727329 + 1.19089227502871 1.29940010677049 1.54398417735024 + 1.73771547923282 1.77296175003401 1.87275606979175 + 2.07033243972521 2.16414271052282 2.22716551838589 + 2.37935042101669 2.67188771673553 2.82679518054224 + 3.00135269229820 3.48382495469438 3.83419792398046 + 0.161645491943529 0.672086790797680 0.762286964920328 + 1.07433284544462 1.21294191744913 1.31164286730943 + 1.52834897888630 1.83843915784915 1.95741938237798 + 2.19148984413109 3.24217250366571 0.225995307622873 + 0.240907258015995 0.367066829963131 0.503535426659975 + 0.602764944529835 0.703370339875812 0.754380179426906 + 0.884420518732559 0.963411281466499 1.05921648685572 + 1.19048944155892 1.25814077480321 1.56916241916196 + 1.59698065950503 1.74380957764511 1.98636180732934 + 2.00366248439902 2.18806439955680 2.29777158087759 + 2.54071727310046 2.65864336644143 2.94192092693438 + 2.98537670707142 3.69592987620463 3.77000224671010 + 0.234652607487977 0.717601256707210 0.843863253708071 + 1.29216411509331 1.36495699837027 1.74438958333340 + 2.04892117101004 2.13577192131677 2.51070474122043 + 3.28576822533544 + @CHECKOUT-I, Total execution time (CPU/WALL): 6.97/ 0.46 seconds. +--executable xvtran finished with status 0 in 0.95 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xintprc + @GETMEM-I, Allocated 95367 MB of main memory. + Processing integrals for CCSD calculation. + @GMOIAA-I, Processing MO integrals for spin case AA. + @GMOIAA-I, Generation of integral list completed. + TYPE NUMBER + ---- -------- + PPPP 894479 + PPPH 640524 + PPHH 115497 + PHPH 63721 + PHHH 22938 + HHHH 1222 + + TOTAL 1738381 + + @FORMT2-I, Second-order MP correlation energies: + ------------------------------------------------ + E(SCF) = -228.643312572485 a.u. + E2(AA) = -0.093684343380 a.u. + E2(AB) = -0.520081687065 a.u. + E2(TOT) = -0.707450373824 a.u. + Total MP2 energy = -229.350762946309 a.u. + ------------------------------------------------ + Largest T2 amplitudes for spin case AB: + _ _ _ _ _ _ + i j a b i j a b i j a b +----------------------------------------------------------------------------- +[ 13 13 40 40]-0.06710 [ 8 8 40 40]-0.05436 [ 13 13 76 76]-0.05241 +[ 13 8 76 40]-0.04215 [ 8 13 40 76]-0.04215 [ 8 8 76 76]-0.03737 +[ 7 7 40 40]-0.03140 [ 13 7 40 76]-0.02053 [ 7 13 76 40]-0.02053 +[ 13 13 77 77]-0.01960 [ 13 13 40 42]-0.01810 [ 13 13 42 40]-0.01810 +[ 7 7 45 45]-0.01664 [ 13 13 41 41]-0.01633 [ 13 13 78 76]-0.01595 +----------------------------------------------------------------------------- + Norm of T2AB vector ( 230058 symmetry allowed elements): 0.4218925855. +----------------------------------------------------------------------------- + @CHECKOUT-I, Total execution time (CPU/WALL): 3.91/ 0.33 seconds. +--executable xintprc finished with status 0 in 0.84 seconds (walltime). + calling xncc + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xncc + @GETMEM-I, Allocated 7 MB of main memory. + +Running with 20 threads/proc + +Using DIIS to accelerate the convergence of T1 and T2 +Using immediate high-order contributions +Damping factor for T3: 0.000000 +Damping factor for T4: 0.000000 + +Transposes are coarse-threaded + +Memory limit: 93.132 GiB +Minimum memory requirement: 12.286 MiB +Compromise memory amount: 49.883 MiB +Optimal memory requirement: 112.301 MiB + +List Location Size Cached Hunks Est. Disk I/O +----------------- ---------- ----------- ------ ----- ------------- + + T_DIIS 70:0 8.787 MiB Yes - 158.166 MiB + Z_DIIS 70:1 8.787 MiB Yes - 263.610 MiB + 18 1.755 MiB Yes - 62.148 MiB + 233 52.803 MiB Yes - 792.042 MiB + 30 9.615 MiB Yes - 721.156 MiB + 16 1.755 MiB Yes - 240.463 MiB + 25 1.755 MiB Yes - 52.656 MiB + 21 1.755 MiB No - 0 B + 10 329.156 KiB Yes - 43.395 MiB + 13 60.633 KiB Yes - 909.492 KiB + F(EA) 92:0 11.891 KiB Yes - 1.045 MiB + F(EM) 93:0 2.250 KiB Yes - 135.000 KiB + F(MI) 91:0 456 B Yes - 46.758 KiB + T(AI) 90:0 2.250 KiB Yes - 609.750 KiB + T(Ab,Ij) 46 1.755 MiB Yes - 398.431 MiB + W(Mn,Ij) 53 60.633 KiB Yes - 1.776 MiB + W~(EM,bj) 56 1.755 MiB Yes - 131.640 MiB + W~(Em,Bj) 58 1.755 MiB Yes - 131.640 MiB + W~(Ij,Mb) 110 329.156 KiB Yes - 14.465 MiB + W~~(EM,bj) 76 1.755 MiB No - 0 B + W~~(Em,Bj) 78 1.755 MiB No - 0 B + Z(AI) 90:2 2.250 KiB Yes - 337.500 KiB + Z(Ab,Ij) 63 1.755 MiB Yes - 263.280 MiB + +Simulation and memory analysis took 0.077 seconds + +MP2 correlation energy: -0.707450373824291 + +Non-iterative calculation of MP2 took 0.394 cpu seconds and 0.030 walltime seconds at 0.427 Gflops/sec + +Total MP2 energy: -229.350762946308862 + +Beginning iterative solution of CCSD equations: + +It. Correlation Energy T1 Residual T2 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------- + 1 -0.710330365665595 2.59892e-02 9.89691e-03 7.860 0.765 + 2 -0.731384640061197 3.61814e-03 9.03347e-03 1.571 0.079 + 3 -0.731956756689663 6.18099e-03 3.24648e-03 1.506 0.075 + 4 -0.734581315377452 9.23994e-04 1.13972e-03 1.531 0.077 + 5 -0.734932040699374 9.96826e-04 5.56474e-04 1.481 0.074 + + A I A I A I +-------------------------- -------------------------- -------------------------- + 19 12 0.0309648177093 31 17 0.0123907907787 45 17 0.0075254680442 + 19 17 -0.0302138663118 36 17 -0.0102686992189 53 17 0.0073321925679 + 34 18 0.0234076768743 25 16 -0.0097331201041 25 15 0.0071343499057 + 51 18 0.0134092938229 27 16 -0.0091252892083 37 16 0.0067244244367 + 23 18 0.0132355667898 26 13 0.0080302966500 31 12 0.0066813522839 + + A B I J A B I J +------------------------------------ ------------------------------------ + 19 19 18 18 -0.0864840489887 23 19 12 18 -0.0263855510649 + 23 23 18 18 -0.0533861721483 19 36 18 18 -0.0238163966628 + 23 19 18 17 -0.0521565004034 36 19 18 18 -0.0238163966628 + 19 23 17 18 -0.0521565004034 23 19 18 12 -0.0208474757928 + 23 23 17 17 -0.0498991564072 19 23 12 18 -0.0208474757928 + 19 19 17 17 -0.0484235042025 19 23 18 17 -0.0189398489144 + 19 19 12 12 -0.0312865996647 23 19 17 18 -0.0189398489144 + 19 23 18 12 -0.0263855510649 + +It. Correlation Energy T1 Residual T2 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------- + 6 -0.734968831698199 2.86084e-04 1.13465e-04 1.517 0.076 + 7 -0.734971740268961 1.62289e-04 6.06563e-05 1.578 0.079 + 8 -0.734969631752116 6.77257e-05 1.63091e-05 2.199 0.111 + 9 -0.734969815111073 1.32823e-05 5.58533e-06 1.493 0.075 + 10 -0.734971505312760 8.66008e-06 1.03652e-06 1.442 0.072 + + A I A I A I +-------------------------- -------------------------- -------------------------- + 19 12 0.0311108208578 31 17 0.0123104770427 45 17 0.0075336426648 + 19 17 -0.0310751115583 36 17 -0.0104046451078 53 17 0.0073074748217 + 34 18 0.0233782910697 25 16 -0.0097813817793 25 15 0.0071704017575 + 23 18 0.0138958024463 27 16 -0.0090967931430 37 16 0.0067229138479 + 51 18 0.0133887374494 26 13 0.0079464506357 31 12 0.0066841833155 + + A B I J A B I J +------------------------------------ ------------------------------------ + 19 19 18 18 -0.0867689223810 23 19 12 18 -0.0263411202363 + 23 23 18 18 -0.0530761221864 19 36 18 18 -0.0238731069787 + 23 19 18 17 -0.0521126076824 36 19 18 18 -0.0238731069787 + 19 23 17 18 -0.0521126076824 19 23 12 18 -0.0208285247603 + 23 23 17 17 -0.0501399729337 23 19 18 12 -0.0208285247603 + 19 19 17 17 -0.0481872128411 19 23 18 17 -0.0187589163318 + 19 19 12 12 -0.0313367424144 23 19 17 18 -0.0187589163318 + 19 23 18 12 -0.0263411202363 + +It. Correlation Energy T1 Residual T2 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------- + 11 -0.734972180262170 1.72072e-06 5.59276e-07 1.560 0.078 + 12 -0.734972480248231 8.38584e-07 4.94736e-07 1.539 0.077 + 13 -0.734972635940772 2.99058e-07 2.02218e-07 1.434 0.072 + 14 -0.734972678637797 1.78596e-07 8.39001e-08 1.504 0.075 + 15 -0.734972684411973 1.00482e-07 3.34986e-08 1.495 0.075 + + A I A I A I +-------------------------- -------------------------- -------------------------- + 19 12 0.0311117997502 31 17 0.0123110161388 45 17 0.0075336096766 + 19 17 -0.0310775780577 36 17 -0.0104053838287 53 17 0.0073075977232 + 34 18 0.0233793496166 25 16 -0.0097818792076 25 15 0.0071712368041 + 23 18 0.0138989328941 27 16 -0.0090973444397 37 16 0.0067231287655 + 51 18 0.0133887634099 26 13 0.0079470196131 31 12 0.0066844421404 + + A B I J A B I J +------------------------------------ ------------------------------------ + 19 19 18 18 -0.0867703174851 23 19 12 18 -0.0263416496904 + 23 23 18 18 -0.0530767767631 19 36 18 18 -0.0238735919485 + 23 19 18 17 -0.0521127109067 36 19 18 18 -0.0238735919485 + 19 23 17 18 -0.0521127109067 19 23 12 18 -0.0208288165624 + 23 23 17 17 -0.0501411836645 23 19 18 12 -0.0208288165624 + 19 19 17 17 -0.0481870678656 19 23 18 17 -0.0187589863188 + 19 19 12 12 -0.0313378020825 23 19 17 18 -0.0187589863188 + 19 23 18 12 -0.0263416496904 + +It. Correlation Energy T1 Residual T2 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------- + 16 -0.734972685409664 2.76339e-08 1.19149e-08 1.551 0.078 + +CCSD iterations converged in 16 cycles and 1.948 seconds (0.122 s/it.) at 13.622 Gflops/sec + +Total CCSD energy: -229.378285257894248 + + @CHECKOUT-I, Total execution time (CPU/WALL): 33.76/ 2.39 seconds. +--executable xncc finished with status 0 in 5.50 seconds (walltime). + The final electronic energy is -229.378285257894248 a.u. + This computation required 14.58 seconds (walltime). diff --git a/furan/cc-pvdz/CC/fura-gs-ccsdt.out b/furan/cc-pvdz/CC/fura-gs-ccsdt.out new file mode 100644 index 0000000..e6fbb8f --- /dev/null +++ b/furan/cc-pvdz/CC/fura-gs-ccsdt.out @@ -0,0 +1,1011 @@ + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xjoda + + + ************************************************************************* + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + ************************************************************************* + + **************************************************************** + * CFOUR Coupled-Cluster techniques for Computational Chemistry * + **************************************************************** + + + Department of Chemistry Institut fuer Physikalische Chemie + University of Florida Universitaet Mainz + Gainesville, FL 32611, USA D-55099 Mainz, Germany + + Department of Chemistry Fakultaet fuer Chemie und Biowiss. + Johns Hopkins University Karlsruher Institut fuer Technologie + Baltimore, MD 21218, USA D-76131 Karlsruhe, Germany + + Department of Chemistry Department of Physical Chemistry + Southern Methodist University Eotvos Lorand University + Dallas, TX 75275, USA H-1053 Budapest, Hungary + + + Version 2.1 + + nazare074.cluster + Thu Oct 15 11:17:32 CEST 2020 + integer*8 version is running + +******************************************************************************** +* Input from ZMAT file * +******************************************************************************** +Ketene -GS +C 0.00000000 2.06365826 -0.60051250 +C 0.00000000 -2.06365826 -0.60051250 +C 0.00000000 1.35348578 1.86336416 +C 0.00000000 -1.35348578 1.86336416 +O 0.00000000 0.00000000 -2.13945332 +H 0.00000000 3.86337287 -1.53765695 +H 0.00000000 -3.86337287 -1.53765695 +H 0.00000000 2.59168789 3.47168051 +H 0.00000000 -2.59168789 3.47168051 + +*CFOUR(COORD=CARTESIAN,UNITS=BOHR + MEMORY=100,MEM_UNIT=GB,CC_PROG=NCC + FROZEN_CORE=1 + CALC=CCSDT,BASIS=PVDZ + SCF_CONV=9,CC_CONV=7,ESTATE_MAXCYC=80) + +******************************************************************************** + ------------------------------------------------------------------- + CFOUR Control Parameters + ------------------------------------------------------------------- + External Internal Value Units + Name Name + ------------------------------------------------------------------- + ABCDTYPE IABCDT STANDARD [ 0] *** + ANHARMONIC IANHAR OFF [ 0] *** + ANH_ALGORIT IANALG STANDARD [ 0] *** + ANH_DERIVAT IANDER SECOND [ 1] *** + ANH_MODE ANHMOD VIBRATION [ 0] *** + ANH_STEPSIZ ICUBST 50000 x 10-6 + ANH_SYMMETR IANHSM ABELIAN [ 0] *** + AO_LADDERS IAOLAD SINGLEPASS [ 1] *** + AV_SCF IAVSCF OFF [ 0] *** + BASIS IBASIS PVDZ [ 13] *** + BOTHVECTORS BOTHVC OFF [ 0] *** + BOX_POTENT IPIAB OFF [ 0] *** + BREIT IBREIT OFF [ 0] *** + BRUCK_CONV IBRTOL 10D- 4 *** + BRUECKNER IBRKNR OFF [ 0] *** + BUFFERSIZE IBUFFS 4096 *** + CACHE_RECS ICHREC 10 *** + CALCLEVEL ICLLVL CCSDT [ 18] *** + CCORBOPT ICCORB OFF [ 0] x 0.01 + CC_CONV ICCCNV 10D- 7 *** + CC_EXPORDER ICCEOR 5 *** + CC_EXTRAPOL ICCEXT DIIS [ 1] *** + CC_GUESS ICCGES MP2 [ 0] *** + CC_MAXCYC ICCCYC 100 cycles + CC_PROGRAM ICCPRO NCC [ 5] *** + CHARGE ICHRGE 0 *** + CHOLESKY ICHOLE OFF [ 0] *** + CIS_CONV ICISTL 5 *** + COMM_SIZE IPSIZE *** *** + CONSTANT ICONST OLD [ 1] *** + CONTINUUM ICONTU NONE [ 0] *** + CONTRACTION ICNTYP GENERAL [ 1] *** + COORDINATES ICOORD CARTESIAN [ 1] *** + CPHF_CONVER ICPHFT 10D- 16 *** + CPHF_MAXCYC ICPHFC 64 cycles + CUBIC ICUBIC OFF [ 0] *** + CURVILINEAR ICURVY OFF [ 0] *** + DBOC IDBOC OFF [ 0] *** + DCT IDCT OFF [ 0] *** + DERIV_LEV IDRLVL ZERO [ 0] *** + DEVMEM_SIZE IDVMEM ********* MByte + DIAG_MRCC IEOMST 10D- 0 *** + DIFF_TYPE IDIFTY RELAXED [ 0] *** + DIRECT IDIRCT OFF [ 0] *** + DROPMO IDRPMO NONE + ECP IECP OFF [ 0] *** + EIGENVECTOR IVEC 1 *** + EL_ANHARM IELANH OFF [ 0] *** + EOMFOLLOW IEOMSR ENERGY [ 0] *** + EOMIP IEOMIP OFF [ 0] *** + EOMLEVEL HBARFM SAME [ 0] *** + EOM_MRCC IMRCCE NEW [ 1] *** + EOM_NONIT EOMNON OFF [ 0] *** + EOM_NSING IEOMSI 10D- 0 *** + EOM_NSTATES IMRCCD DAVIDSON [ 0] *** + EOM_NTRIP IEOMTR 10D- 0 *** + EOM_ORDER IEXORD ENERGY [ 0] *** + EOM_PROPSTA IEOMST 0 *** + ESTATE_CONV IEXTOL 10D- 5 *** + ESTATE_DIAG IEXDIG ITERATIVE [ 0] *** + ESTATE_LOCK IESLOC ON [ 1] *** + ESTATE_MAXC IEXMXC 80 *** + ESTATE_PROP IEXPRP OFF [ 0] *** + EVAL_HESS IRECAL 0 # of cyc. + EXCITATION IEXCIT 0 *** + EXCITE IEXCIT NONE [ 0] *** + EXTERN_POT IEXPOT OFF [ 0] *** + FCGRADNEW IFCGNW OFF [ 0] *** + FC_FIELD IFINFC 0 x 10-6 + FD_CALTYPE IFDCAL GRADONLY [ 0] *** + FD_PROJECT IFDPRJ OFF [ 1] *** + FD_STEPSIZE IDISFD 0 10-4 bohr + FD_USEGROUP IFDGRP FULL [ 0] *** + FILE_RECSIZ IFLREC 4096 words + FINITE_PERT IFIPER 0 x 10-6 + FIXGEOM IFIXGM OFF [ 0] *** + FOCK IFOCK AO [ 1] *** + FREQ_ALGORI IVIALG STANDARD [ 0] *** + FROZEN_CORE IFROCO ON [ 1] *** + GAMMA_ABCD IGABCD STORE [ 0] *** + GAMMA_ABCI IGABCI STORE [ 0] *** + GENBAS_1 IGNBS1 0 *** + GENBAS_2 IGNBS2 0 *** + GENBAS_3 IGNBS3 0 *** + GENBAS_4 IGNBS4 0 *** + GEO_CONV ICONTL 5 H/bohr + GEO_MAXCYC IOPTCY 50 *** + GEO_MAXSTEP IMXSTP 300 millibohr + GEO_METHOD INR SINGLE_POINT[ 5] *** + GIAO IGIAO OFF [ 1] *** + GIMIC IGIMIC OFF [ 0] *** + GRID IGRID OFF [ 0] *** + GRID_ALGO IGALGO SERIAL [ 0] *** + GUESS IGUESS MOREAD [ 0] *** + HBAR IHBAR OFF [ 0] *** + HESS_TYPE IHESTP SCF [ 0] *** + HF2_FILE IHF2Fl USE [ 1] *** + HFSTABILITY ISTABL OFF [ 0] *** + INCORE INCORE OFF [ 0] *** + INPUT_MRCC IMRCC ON [ 1] *** + INTEGRALS INTTYP VMOL [ 1] *** + JODA_PRINT IJPRNT 0 *** + KEYWORD_OUT IDMPKW NO [ 0] *** + LINDEP_TOL ILINDP 8 *** + LINEQ_CONV IZTACN 10D- 7 cycles + LINEQ_EXPOR ILMAXD 5 *** + LINEQ_MAXCY ILMAXC 100 *** + LINEQ_TYPE ILTYPE DIIS [ 1] *** + LOCK_ORBOCC ILOCOC OFF [ 0] *** + MEMORY_SIZE IMEMSZ ********* words + MEM_UNIT IMEMU GB [ 3] *** + MRCC IMRCCC OFF [ 0] *** + MULTIPLICTY IMULTP 1 *** + NACOUPLING IVCOUP OFF [ 0] *** + NEGEVAL IDIE ABORT [ 0] *** + NEWNORM INEWNO OFF [ 0] *** + NON-HF INONHF OFF [ 0] *** + NTOP_TAMP ITOPT2 15 *** + NUC_MODEL INUCMO POINT [ 0] *** + OCCUPATION IOCCU ESTIMATED BY SCF + OPEN-SHELL IOPEN SPIN-ORBITAL[ 0] *** + OPTVIB IOPTVB OFF [ 0] *** + ORBITALS IORBTP STANDARD [ 0] *** + PARALLEL IPARAL ON [ 1] *** + PARA_INT IPINTS ON [ 1] *** + PARA_PRINT IPPRIN 0 *** + PERT_ORB IPTORB STANDARD [ 0] *** + POINTS IGRDFD 0 *** + PRINT IPRNT 0 *** + PROPS IPROPS OFF [ 0] *** + PROP_INTEGR IINTYP INTERNAL [ 0] *** + PSI IPSI OFF [ 0] *** + QC_ALG IQCALG FLM [ 0] *** + QC_LINALG IQCLIN TRIDIAG [ 2] *** + QC_MAXCYC IQCMAX 10D-100 cycles + QC_MAXSCFCY IQCMSC 10D- 15 cycles + QC_RTRUST IQCRTR 10D- 0 x 10-3 + QC_SKIPSCF IQCSKI OFF [ 0] *** + QC_START IQCSTA 10D- 1 *** + QRHFGUESS IQGUES OFF [ 0] *** + QUARTIC IQUART OFF [ 0] *** + RAMAN_INT IRAMIN OFF [ 0] *** + RAMAN_ORB IRAMRE UNRELAXED [ 0] *** + RDO IRDOFM OFF [ 0] *** + REDUCE_REPR REDREP Ir [ 0] *** + REFERENCE IREFNC RHF [ 0] *** + RELATIVIST IRELAT OFF [ 0] *** + RELAX_DENS IRDENS OFF [ 0] *** + RESET_FLAGS IRESET OFF [ 0] *** + RESTART_CC ICCRES OFF [ 0] *** + ROT_EVEC ROTVEC 0 *** + SAVE_INTS ISVINT OFF [ 0] *** + SCALE_ON ISTCRT 0 *** + SCF_CONV ISCFCV 10D- 9 *** + SCF_DAMPING IDAMP 0 x 10-3 + SCF_EXPORDE IRPPOR 6 *** + SCF_EXPSTAR IRPPLS 8 *** + SCF_EXTRAPO IRPP ON [ 1] *** + SCF_MAXCYC ISCFCY 150 cycles + SCF_NOSTOP ISCFST OFF [ 0] *** + SCF_PRINT ISCFPR 0 *** + SCF_PROG ISCFPR SCF [ 0] *** + SD_FIELD IFINSD 0 x 10-6 + SOPERT IPERSO OFF [ 0] *** + SPHERICAL IDFGHI ON [ 1] *** + SPINORBIT ISOCAL OFF [ 0] *** + SPINROTATIO ISRCON OFF [ 0] *** + SPIN_FLIP ISPFLP OFF [ 0] *** + SPIN_ORBIT ISPORB OFF [ 0] *** + SPIN_SCAL ISCSMP OFF [ 0] *** + STEEPSCALE ISTPSC 1000 x 10-3 + SUBGROUP ISUBGP DEFAULT [ 0] *** + SUBGRPAXIS ISBXYZ X [ 0] *** + SYMMETRY ISYM ON [ 0] *** + SYM_CHECK ISYMCK OVERRIDE [ 1] *** + T3_EXTRAPOL IT3EXT OFF [ 0] *** + T4_EXTRAPOL IT4EXP OFF [ 0] *** + TAMP_SUM IEVERY 5 *** + TESTSUITE ITESTS OFF [ 0] *** + THERMOCH ITHERM OFF [ 0] *** + TOL_CHOLESK ITOLCH 10D- 4 *** + TRANGRAD IRESRM OFF [ 0] *** + TRANS_INV ITRAIN USE [ 0] *** + TREAT_PERT ITREAT SIMULTANEOUS[ 0] *** + TRIP_ALGORI ITRALG NORMAL [ 0] *** + UIJ_THRESHO IUIJTH 1 *** + UNITS IUNITS BOHR [ 1] *** + UNOS IUNOS OFF [ 0] *** + UPDATE_HESS IHUPDT ON [ 1] *** + VIBPHASE ISETPH STANDARD [ 0] *** + VIBRATION IVIB NO [ 0] *** + VIB_ALGORIT IGEALG STANDARD [ 0] *** + VNATORB IVNORB OFF [ 0] *** + VTRAN IVTRAN FULL/PARTIAL[ 0] *** + XFIELD IXEFLD 0 x 10-6 + XFORM_TOL IXFTOL 10D- 11 *** + YFIELD IYEFLD 0 x 10-6 + ZFIELD IZEFLD 0 x 10-6 + ZSCALE_EXP IZEXPS OFF [ 0] *** + ------------------------------------------------------------------- + @GETXYZ-I, 9 atoms read from ZMAT. + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 +******************************************************************************** + The full molecular point group is C2v . + The largest Abelian subgroup of the full molecular point group is C2v . + The computational point group is C2v . +******************************************************************************** + + + ---------------------------------------------------------------- + Coordinates used in calculation (QCOMP) + ---------------------------------------------------------------- + Z-matrix Atomic Coordinates (in bohr) + Symbol Number X Y Z + ---------------------------------------------------------------- + C 6 0.00000000 -2.06365826 0.60031230 + C 6 0.00000000 2.06365826 0.60031230 + C 6 0.00000000 -1.35348578 -1.86356436 + C 6 0.00000000 1.35348578 -1.86356436 + O 8 0.00000000 0.00000000 2.13925312 + H 1 0.00000000 -3.86337287 1.53745675 + H 1 0.00000000 3.86337287 1.53745675 + H 1 0.00000000 -2.59168789 -3.47188071 + H 1 0.00000000 2.59168789 -3.47188071 + ---------------------------------------------------------------- + + Interatomic distance matrix (Angstroms) + + C C C C O + [ 1] [ 2] [ 3] [ 4] [ 5] + C [ 1] 0.00000 + C [ 2] 2.18408 0.00000 + C [ 3] 1.35691 2.22931 0.00000 + C [ 4] 2.22931 1.35691 1.43247 0.00000 + O [ 5] 1.36226 1.36226 2.23601 2.23601 0.00000 + H [ 6] 1.07375 3.17541 2.23677 3.29549 2.06906 + H [ 7] 3.17541 1.07375 3.29549 2.23677 2.06906 + H [ 8] 2.17295 3.27299 1.07409 2.25451 3.27071 + H [ 9] 3.27299 2.17295 2.25451 1.07409 3.27071 + + H H H H + [ 6] [ 7] [ 8] [ 9] + H [ 6] 0.00000 + H [ 7] 4.08882 0.00000 + H [ 8] 2.73491 4.32378 0.00000 + H [ 9] 4.32378 2.73491 2.74292 0.00000 + rotcon2 + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 + There are 5 frozen-core orbitals. + There are 90 basis functions. + @GEOPT-W, Archive file not created for single-point calculation. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.12/ 1.31 seconds. +--executable xjoda finished with status 0 in 1.79 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol + SERIAL VERSION OF MOLECULE STARTED +******************************************************************************** + INPUT FROM MOL FILE +******************************************************************************** +INTGRL 1 0 1 0 0 0 0 0 0 + *** CFOUR Program System (Release V0.1) *** +Ketene -GS + 5 2 X Y 0.10E-08 0 0 + 9999.00 3.00 + 6.00000000 1 3 1 1 1 +C #1 0.000000000000000 -2.063658260000000 0.600312302999175 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 6.00000000 1 3 1 1 1 +C #2 0.000000000000000 -1.353485780000000 -1.863564357000825 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 8.00000000 1 3 1 1 1 +O #3 0.000000000000000 0.000000000000000 2.139253122999175 + 9 3 + 11720.0000000000 7.100000000000000E-004 -1.600000000000000E-004 + 0.000000000000000E+000 + 1759.00000000000 5.470000000000000E-003 -1.263000000000000E-003 + 0.000000000000000E+000 + 400.800000000000 2.783700000000000E-002 -6.267000000000000E-003 + 0.000000000000000E+000 + 113.700000000000 0.104800000000000 -2.571600000000000E-002 + 0.000000000000000E+000 + 37.0300000000000 0.283062000000000 -7.092400000000000E-002 + 0.000000000000000E+000 + 13.2700000000000 0.448719000000000 -0.165411000000000 + 0.000000000000000E+000 + 5.02500000000000 0.270952000000000 -0.116955000000000 + 0.000000000000000E+000 + 1.01300000000000 1.545800000000000E-002 0.557368000000000 + 0.000000000000000E+000 + 0.302300000000000 -2.585000000000000E-003 0.572759000000000 + 1.00000000000000 + 4 2 + 17.7000000000000 4.301800000000000E-002 0.000000000000000E+000 + 3.85400000000000 0.228913000000000 0.000000000000000E+000 + 1.04600000000000 0.508728000000000 0.000000000000000E+000 + 0.275300000000000 0.460531000000000 1.00000000000000 + 1 1 + 1.18500000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #4 0.000000000000000 -3.863372870000000 1.537456752999175 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #5 0.000000000000000 -2.591687890000000 -3.471880707000825 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 +FINISH + +******************************************************************************** + ONE- AND TWO-ELECTRON INTEGRALS OVER SYMMETRY-ADAPTED AOS ARE CALCULATED. + + SPHERICAL HARMONICS ARE USED. + + INTEGRALS LESS THAN 0.10E-13 ARE NEGLECTED. + + NUCLEAR REPULSION ENERGY : 161.1082297788 A.U. + @MOLECU-I, ONE ELECTRON INTEGRALS (CPU/WALL): 0.02/ 0.03 SECONDS. + @TWOEL-I, 325108 INTEGRALS OF SYMMETRY TYPE I I I I + @TWOEL-I, 908743 INTEGRALS OF SYMMETRY TYPE I J I J + @TWOEL-I, 490042 INTEGRALS OF SYMMETRY TYPE I I J J + @TWOEL-I, 460725 INTEGRALS OF SYMMETRY TYPE I J K L + @TWOEL-I, TOTAL NUMBER OF 2-E INTEGRALS 2184618. + @MOLECU-I, TWO ELECTRON INTEGRALS (CPU/WALL): 1.41/ 1.41 SECONDS. + @CHECKOUT-I, Total execution time (CPU/WALL): 1.44/ 1.46 seconds. + +Running with 20 threads/proc + +--executable xvmol finished with status 0 in 1.93 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol2ja + @GETMEM-I, Allocated 95367 MB of main memory. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.22/ 0.04 seconds. +--executable xvmol2ja finished with status 0 in 0.51 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvscf + There are 90 functions in the AO basis. + + There are 4 irreducible representations. + + Irrep # of functions + 1 35 + 2 13 + 3 31 + 4 11 + + + Parameters for SCF calculation: + SCF reference function: RHF + Maximum number of iterations: 150 + Full symmetry point group: C2v + Computational point group: C2v + Initial density matrix: MOREAD + SCF convergence tolerance: 10**(- 9) + DIIS convergence acceleration: ON + Latest start for DIIS: 8 + DIIS order: 6 + + Memory information: 341888 words required. + Fock matrices are constructed from AO integral file. + @GETMEM-I, Allocated 2 MB of main memory. + Initialization and symmetry analysis required 0.001 seconds. + + @INITGES-I, Occupancies from core Hamiltonian: + + Alpha population by irrep: 9 2 6 1 + Beta population by irrep: 9 2 6 1 + + + total no. of electrons in initial guess : 0.000000000000000E+000 + -------------------------------------------------------------------- + Iteration Total Energy Largest Density Difference + -------------------------------------------------------------------- + 0 161.108229778788910 0.0000000000D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 1 -196.263249175407992 0.1098182460D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 2 -179.889864626336106 0.1675780025D+02 + current occupation vector + 9 1 7 1 + 9 1 7 1 + 3 -180.580457259652945 0.1772125138D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 4 -162.771013663095033 0.1566999730D+02 + current occupation vector + 8 2 7 1 + 8 2 7 1 + 5 -169.943224465301597 0.1454729382D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 6 -160.269967975315780 0.1454634919D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 7 -168.828658617537684 0.1395077743D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 8 -160.232275948463297 0.1395068492D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 9 -209.746508446745025 0.5520995458D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 10 -228.180230304181549 0.2015536648D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 11 -228.454713327495682 0.6531384936D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 12 -228.600329261507483 0.3196758217D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 13 -228.637509917234041 0.7498321731D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 14 -228.642938164599826 0.5250342791D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 15 -228.643241982659248 0.9795506231D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 16 -228.643308522550143 0.3593200395D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 17 -228.643312517846056 0.1473098013D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 18 -228.643312570337258 0.1244041229D-03 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 19 -228.643312572356052 0.2423484470D-04 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 20 -228.643312572476049 0.5414751593D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 21 -228.643312572485769 0.2003507219D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 22 -228.643312572485598 0.8833300562D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 23 -228.643312572484461 0.3139636784D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 24 -228.643312572486110 0.4136764657D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 25 -228.643312572485542 0.9839839787D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 26 -228.643312572486622 0.1838835018D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 27 -228.643312572484007 0.3228508794D-08 + current occupation vector + 9 2 6 1 + 9 2 6 1 + + SCF has converged. + + Density matrix saved to file den.dat + total electron number: 36.0000000000000 + E(SCF)= -228.643312572484575 0.7981584282D-09 + + Eigenvector printing suppressed. + + @PUTMOS-I, Writing converged MOs to NEWMOS. + @PUTMOS-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTMOS-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTMOS-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTMOS-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + @PUTFOCK-I, Writing converged Fock matrix to NEWFOCK. + @PUTFOCK-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTFOCK-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + + + + ORBITAL EIGENVALUES (ALPHA) (1H = 27.2113834 eV) + + MO # E(hartree) E(eV) FULLSYM COMPSYM + ---- -------------------- -------------------- ------- --------- + 1 1 -20.6219765861 -561.1525113512 A1 A1 (1) + 2 49 -11.2892088103 -307.1949892207 B2 B2 (3) + 3 2 -11.2891634657 -307.1937553315 A1 A1 (1) + 4 3 -11.2328159068 -305.6604603025 A1 A1 (1) + 5 50 -11.2318729764 -305.6348018622 B2 B2 (3) + 6 4 -1.4574476329 -39.6591663239 A1 A1 (1) + 7 5 -1.0834872588 -29.4831872086 A1 A1 (1) + 8 51 -1.0036038078 -27.3094479952 B2 B2 (3) + 9 52 -0.8050606676 -21.9068144851 B2 B2 (3) + 10 6 -0.7793049296 -21.2059652251 A1 A1 (1) + 11 7 -0.7372159421 -20.0606656495 A1 A1 (1) + 12 36 -0.6283416633 -17.0980459063 B1 B1 (2) + 13 53 -0.6064452640 -16.5022145907 B2 B2 (3) + 14 54 -0.5741889664 -15.6244761082 B2 B2 (3) + 15 8 -0.5622006055 -15.2982562239 A1 A1 (1) + 16 9 -0.5366322238 -14.6025051862 A1 A1 (1) + 17 37 -0.3944127682 -10.7325170532 B1 B1 (2) + 18 80 -0.3173264428 -8.6348914980 A2 A2 (4) + +++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ + 19 38 0.1616454919 4.3985974562 B1 B1 (2) + 20 10 0.2028007990 5.5184902966 A1 A1 (1) + 21 55 0.2259953076 6.1496449623 B2 B2 (3) + 22 11 0.2331452351 6.3442043789 A1 A1 (1) + 23 81 0.2346526075 6.3852220682 A2 A2 (4) + 24 56 0.2409072580 6.5554197617 B2 B2 (3) + 25 12 0.3379830583 9.1969865830 A1 A1 (1) + 26 57 0.3670668300 9.9883962435 B2 B2 (3) + 27 13 0.4400792390 11.9751648999 A1 A1 (1) + 28 58 0.5035354267 13.7018955503 B2 B2 (3) + 29 14 0.5796551077 15.7732173745 A1 A1 (1) + 30 59 0.6027649445 16.4020680057 B2 B2 (3) + 31 39 0.6720867908 18.2884113425 B1 B1 (2) + 32 15 0.6949257331 18.9098905590 A1 A1 (1) + 33 60 0.7033703399 19.1396799905 B2 B2 (3) + 34 82 0.7176012567 19.5269229246 A2 A2 (4) + 35 61 0.7543801794 20.5277282917 B2 B2 (3) + 36 40 0.7622869649 20.7428828633 B1 B1 (2) + 37 16 0.7651070466 20.8196211868 A1 A1 (1) + 38 17 0.7917408050 21.5443625978 A1 A1 (1) + 39 83 0.8438632537 22.9626865338 A2 A2 (4) + 40 62 0.8844205187 24.0663058221 B2 B2 (3) + 41 18 0.9187910190 25.0015746820 A1 A1 (1) + 42 19 0.9547555380 25.9802189979 A1 A1 (1) + 43 63 0.9634112815 26.2157537519 B2 B2 (3) + 44 64 1.0592164869 28.8227459274 B2 B2 (3) + 45 41 1.0743328454 29.2340829566 B1 B1 (2) + 46 20 1.1352329173 30.8912581602 A1 A1 (1) + 47 65 1.1904894416 32.3948646279 B2 B2 (3) + 48 21 1.1908922750 32.4058262839 A1 A1 (1) + 49 42 1.2129419174 33.0058275576 B1 B1 (2) + 50 66 1.2581407748 34.2357509943 B2 B2 (3) + 51 84 1.2921641151 35.1615731515 A2 A2 (4) + 52 22 1.2994001068 35.3584744953 A1 A1 (1) + 53 43 1.3116428673 35.6916169462 B1 B1 (2) + 54 85 1.3649569984 37.1423682072 A2 A2 (4) + 55 44 1.5283489789 41.5884900335 B1 B1 (2) + 56 23 1.5439841774 42.0139454134 A1 A1 (1) + 57 67 1.5691624192 42.6990802047 B2 B2 (3) + 58 68 1.5969806595 43.4560530082 B2 B2 (3) + 59 24 1.7377154792 47.2856421455 A1 A1 (1) + 60 69 1.7438095776 47.4514709939 B2 B2 (3) + 61 86 1.7443895833 47.4672537511 A2 A2 (4) + 62 25 1.7729617500 48.2447419337 A1 A1 (1) + 63 45 1.8384391578 50.0264727818 B1 B1 (2) + 64 26 1.8727560698 50.9602834298 A1 A1 (1) + 65 46 1.9574193824 53.2640892885 B1 B1 (2) + 66 70 1.9863618073 54.0516527104 B2 B2 (3) + 67 71 2.0036624844 54.5224280672 B2 B2 (3) + 68 87 2.0489211710 55.7539795407 A2 A2 (4) + 69 27 2.0703324397 56.3366097828 A1 A1 (1) + 70 88 2.1357719213 58.1173086059 A2 A2 (4) + 71 28 2.1641427105 58.8893170284 A1 A1 (1) + 72 72 2.1880643996 59.5402592802 B2 B2 (3) + 73 47 2.1914898441 59.6334703659 B1 B1 (2) + 74 29 2.2271655184 60.6042548161 A1 A1 (1) + 75 73 2.2977715809 62.5255434529 B2 B2 (3) + 76 30 2.3793504210 64.7454165492 A1 A1 (1) + 77 89 2.5107047412 68.3197493175 A2 A2 (4) + 78 74 2.5407172731 69.1364318293 B2 B2 (3) + 79 75 2.6586433664 72.3453639681 B2 B2 (3) + 80 31 2.6718877167 72.7057610618 A1 A1 (1) + 81 32 2.8267951805 76.9210074510 A1 A1 (1) + 82 76 2.9419209269 80.0537382753 B2 B2 (3) + 83 77 2.9853767071 81.2362301695 B2 B2 (3) + 84 33 3.0013526923 81.6709588287 A1 A1 (1) + 85 48 3.2421725037 88.2239990462 B1 B1 (2) + 86 90 3.2857682253 89.4102989431 A2 A2 (4) + 87 34 3.4838249547 94.7996965407 A1 A1 (1) + 88 78 3.6959298762 100.5713648809 B2 B2 (3) + 89 79 3.7700022467 102.5869765541 B2 B2 (3) + 90 35 3.8341979240 104.3338297409 A1 A1 (1) + + + VSCF finished. + + @CHECKOUT-I, Total execution time (CPU/WALL): 4.67/ 0.87 seconds. +--executable xvscf finished with status 0 in 1.34 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvtran + @GETMEM-I, Allocated 95367 MB of main memory. + Full RHF integral transformation + The following 5 MOs will be dropped: + 1 2 3 12 13 + There are 85 active molecular orbitals. + Transformation of IIII integrals : + 1 pass through the AO integral file was required. + 325108 AO integrals were read. + 240883 MO integrals were written to HF2. + Transformation of IIJJ integrals : + 1 pass through the AO integral file was required. + 490042 AO integrals were read. + 386877 MO integrals were written to HF2. + Transformation of IJIJ integrals : + 1 pass through the AO integral file was required. + 908743 AO integrals were read. + 712509 MO integrals were written to HF2. + Transformation of IJKL integrals : + 1 pass through the AO integral file was required. + 460725 AO integrals were read. + 398112 MO integrals were written to HF2. + Summary of active molecular orbitals: +------------------------------------------------------------------------ + + Index Eigenvalue Symmetry Index Eigenvalue Symmetry +------------------------------------------------------------------------ + 1 -1.4574476 1 44 1.2129419 2 + 2 -1.0834873 1 45 1.3116429 2 + 3 -0.7793049 1 46 1.5283490 2 + 4 -0.7372159 1 47 1.8384392 2 + 5 -0.5622006 1 48 1.9574194 2 + 6 -0.5366322 1 49 2.1914898 2 + 7 -0.6283417 2 50 3.2421725 2 + 8 -0.3944128 2 51 0.2259953 3 + 9 -1.0036038 3 52 0.2409073 3 + 10 -0.8050607 3 53 0.3670668 3 + 11 -0.6064453 3 54 0.5035354 3 + 12 -0.5741890 3 55 0.6027649 3 + 13 -0.3173264 4 56 0.7033703 3 + 14 0.2028008 1 57 0.7543802 3 + 15 0.2331452 1 58 0.8844205 3 + 16 0.3379831 1 59 0.9634113 3 + 17 0.4400792 1 60 1.0592165 3 + 18 0.5796551 1 61 1.1904894 3 + 19 0.6949257 1 62 1.2581408 3 + 20 0.7651070 1 63 1.5691624 3 + 21 0.7917408 1 64 1.5969807 3 + 22 0.9187910 1 65 1.7438096 3 + 23 0.9547555 1 66 1.9863618 3 + 24 1.1352329 1 67 2.0036625 3 + 25 1.1908923 1 68 2.1880644 3 + 26 1.2994001 1 69 2.2977716 3 + 27 1.5439842 1 70 2.5407173 3 + 28 1.7377155 1 71 2.6586434 3 + 29 1.7729618 1 72 2.9419209 3 + 30 1.8727561 1 73 2.9853767 3 + 31 2.0703324 1 74 3.6959299 3 + 32 2.1641427 1 75 3.7700022 3 + 33 2.2271655 1 76 0.2346526 4 + 34 2.3793504 1 77 0.7176013 4 + 35 2.6718877 1 78 0.8438633 4 + 36 2.8267952 1 79 1.2921641 4 + 37 3.0013527 1 80 1.3649570 4 + 38 3.4838250 1 81 1.7443896 4 + 39 3.8341979 1 82 2.0489212 4 + 40 0.1616455 2 83 2.1357719 4 + 41 0.6720868 2 84 2.5107047 4 + 42 0.7622870 2 85 3.2857682 4 + 43 1.0743328 2 +------------------------------------------------------------------------ + -1.45744763288719 -1.08348725881441 -0.779304929609897 + -0.737215942115339 -0.562200605497301 -0.536632223783724 + -0.628341663300699 -0.394412768193209 -1.00360380778026 + -0.805060667553655 -0.606445264032669 -0.574188966380078 + -0.317326442801090 0.202800799044599 0.233145235052782 + 0.337983058334004 0.440079239041159 0.579655107669000 + 0.694925733138531 0.765107046589679 0.791740804983910 + 0.918791018982032 0.954755538003189 1.13523291727329 + 1.19089227502871 1.29940010677049 1.54398417735024 + 1.73771547923282 1.77296175003401 1.87275606979175 + 2.07033243972521 2.16414271052282 2.22716551838589 + 2.37935042101669 2.67188771673553 2.82679518054224 + 3.00135269229820 3.48382495469438 3.83419792398046 + 0.161645491943529 0.672086790797680 0.762286964920328 + 1.07433284544462 1.21294191744913 1.31164286730943 + 1.52834897888630 1.83843915784915 1.95741938237798 + 2.19148984413109 3.24217250366571 0.225995307622873 + 0.240907258015995 0.367066829963131 0.503535426659975 + 0.602764944529835 0.703370339875812 0.754380179426906 + 0.884420518732559 0.963411281466499 1.05921648685572 + 1.19048944155892 1.25814077480321 1.56916241916196 + 1.59698065950503 1.74380957764511 1.98636180732934 + 2.00366248439902 2.18806439955680 2.29777158087759 + 2.54071727310046 2.65864336644143 2.94192092693438 + 2.98537670707142 3.69592987620463 3.77000224671010 + 0.234652607487977 0.717601256707210 0.843863253708071 + 1.29216411509331 1.36495699837027 1.74438958333340 + 2.04892117101004 2.13577192131677 2.51070474122043 + 3.28576822533544 + @CHECKOUT-I, Total execution time (CPU/WALL): 6.92/ 0.47 seconds. +--executable xvtran finished with status 0 in 0.95 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xintprc + @GETMEM-I, Allocated 95367 MB of main memory. + @GMOIAA-I, Processing MO integrals for spin case AA. + @GMOIAA-I, Generation of integral list completed. + TYPE NUMBER + ---- -------- + PPPP 894479 + PPPH 640524 + PPHH 115497 + PHPH 63721 + PHHH 22938 + HHHH 1222 + + TOTAL 1738381 + + @FORMT2-I, Second-order MP correlation energies: + ------------------------------------------------ + E(SCF) = -228.643312572485 a.u. + E2(AA) = -0.093684343380 a.u. + E2(AB) = -0.520081687065 a.u. + E2(TOT) = -0.707450373824 a.u. + Total MP2 energy = -229.350762946309 a.u. + ------------------------------------------------ + Largest T2 amplitudes for spin case AB: + _ _ _ _ _ _ + i j a b i j a b i j a b +----------------------------------------------------------------------------- +[ 13 13 40 40]-0.06710 [ 8 8 40 40]-0.05436 [ 13 13 76 76]-0.05241 +[ 13 8 76 40]-0.04215 [ 8 13 40 76]-0.04215 [ 8 8 76 76]-0.03737 +[ 7 7 40 40]-0.03140 [ 13 7 40 76]-0.02053 [ 7 13 76 40]-0.02053 +[ 13 13 77 77]-0.01960 [ 13 13 40 42]-0.01810 [ 13 13 42 40]-0.01810 +[ 7 7 45 45]-0.01664 [ 13 13 41 41]-0.01633 [ 13 13 78 76]-0.01595 +----------------------------------------------------------------------------- + Norm of T2AB vector ( 230058 symmetry allowed elements): 0.4218925855. +----------------------------------------------------------------------------- + @CHECKOUT-I, Total execution time (CPU/WALL): 4.17/ 0.34 seconds. +--executable xintprc finished with status 0 in 0.81 seconds (walltime). + calling xncc + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xncc + @GETMEM-I, Allocated 7 MB of main memory. + +Running with 20 threads/proc + +Using DIIS to accelerate the convergence of T1 and T2 +Using immediate high-order contributions +Performing 3 CCSD sub-iterations +Damping factor for T3: 0.000000 +Damping factor for T4: 0.000000 + +Transposes are coarse-threaded + +Memory limit: 93.132 GiB +Minimum memory requirement: 68.171 MiB +Compromise memory amount: 715.873 MiB +Optimal memory requirement: 822.194 MiB + +List Location Size Cached Hunks Est. Disk I/O +----------------- ---------- ----------- ------ ----- ------------- + + T_DIIS 70:0 8.787 MiB Yes - 158.166 MiB + Z_DIIS 70:1 8.787 MiB Yes - 263.610 MiB + 18 1.755 MiB Yes - 274.921 MiB + 233 52.803 MiB Yes - 51.050 GiB + 30 9.615 MiB Yes - 4.789 GiB + 16 1.755 MiB Yes - 1.418 GiB + 25 1.755 MiB Yes - 236.952 MiB + 21 1.755 MiB No - 0 B + 10 329.156 KiB Yes - 221.795 MiB + 13 60.633 KiB Yes - 3.553 MiB + F(EA) 92:0 11.891 KiB Yes - 4.703 MiB + F(EM) 93:0 2.250 KiB Yes - 675.000 KiB + F(MI) 91:0 456 B Yes - 220.430 KiB + Q(AI) 190:2 2.250 KiB Yes - 405.000 KiB + Q(Ab,Ij) 50 1.755 MiB Yes - 947.810 MiB + T(AI) 90:0 2.250 KiB Yes - 2.375 MiB + T(Ab,Ij) 46 1.755 MiB Yes - 1.777 GiB + W(Mn,Ij) 53 60.633 KiB Yes - 13.323 MiB + W~(Ab,Ej) 130 9.615 MiB Yes - 4.731 GiB + W~(EM,bj) 56 1.755 MiB Yes - 895.154 MiB + W~(Em,Bj) 58 1.755 MiB Yes - 1000.466 MiB + W~(Ij,Mb) 110 329.156 KiB Yes - 96.432 MiB + W~~(Ab,Ej) 169 9.615 MiB Yes - 1.972 GiB + W~~(EM,bj) 76 1.755 MiB Yes - 210.624 MiB + W~~(Em,Bj) 78 1.755 MiB Yes - 210.624 MiB + W~~(Ij,Mb) 165 329.156 KiB Yes - 67.503 MiB + Z(AI) 90:2 2.250 KiB Yes - 1.022 MiB + Z(Ab,Ij) 63 1.755 MiB Yes - 816.170 MiB + T(abc,ijk) T3FILE 319.713 MiB Yes 1 14.050 GiB + Z(abc,ijk) Z3FILE 319.713 MiB Yes 1 14.050 GiB + +Simulation and memory analysis took 2.716 seconds + +MP2 correlation energy: -0.707450373824291 + +Non-iterative calculation of MP2 took 0.089 cpu seconds and 0.005 walltime seconds at 2.822 Gflops/sec + +Total MP2 energy: -229.350762946308862 + +Beginning iterative solution of CCSDT equations: + +It. Correlation Energy T1 Residual T2 Residual T3 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------------------- + 1 -0.761396515712305 5.32054e-03 1.23577e-02 1.50483e-03 53.963 2.710 + 2 -0.763231024720669 2.84291e-04 3.16802e-03 3.06462e-04 166.297 8.330 + 3 -0.764056715235343 1.05657e-04 1.02652e-03 1.27851e-04 163.458 8.187 + 4 -0.764248713424053 3.36063e-05 3.40254e-04 4.52491e-05 164.833 8.283 + 5 -0.764306507492691 1.62126e-05 1.18592e-04 1.81390e-05 163.320 8.185 + + A I A I A I +-------------------------- -------------------------- -------------------------- + 19 17 -0.0307453101979 31 17 0.0115710690035 25 15 0.0075575670022 + 19 12 0.0293730023218 36 17 -0.0108277579830 45 17 0.0074421235645 + 34 18 0.0227360659951 25 16 -0.0102013312375 21 14 -0.0074114904981 + 23 18 0.0165996131329 27 16 -0.0094471179841 26 13 0.0073879709639 + 51 18 0.0134857543681 53 17 0.0076112997694 22 15 -0.0065998291459 + + A B I J A B I J +------------------------------------ ------------------------------------ + 19 19 18 18 -0.1056877817077 23 19 12 18 -0.0299063054292 + 23 23 18 18 -0.0613044001293 36 19 18 18 -0.0270360007383 + 23 19 18 17 -0.0600669509361 19 36 18 18 -0.0270360007383 + 19 23 17 18 -0.0600669509361 19 23 12 18 -0.0226926616609 + 23 23 17 17 -0.0584561253098 23 19 18 12 -0.0226926616609 + 19 19 17 17 -0.0581621873054 19 23 18 17 -0.0210584541816 + 19 19 12 12 -0.0365934941924 23 19 17 18 -0.0210584541816 + 19 23 18 12 -0.0299063054292 + +It. Correlation Energy T1 Residual T2 Residual T3 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------------------- + 6 -0.764323026538578 2.97452e-06 4.25856e-05 7.83436e-06 166.103 8.332 + 7 -0.764328936237041 8.45049e-07 1.62347e-05 3.23184e-06 159.637 7.999 + 8 -0.764330915253402 1.60750e-07 6.38053e-06 1.39119e-06 159.569 7.993 + 9 -0.764331685282940 2.12600e-07 2.57485e-06 6.67873e-07 163.674 8.212 + 10 -0.764331953390088 1.28096e-07 1.04816e-06 3.40245e-07 162.688 8.156 + + A I A I A I +-------------------------- -------------------------- -------------------------- + 19 17 -0.0307388727895 31 17 0.0115720951522 25 15 0.0075568588653 + 19 12 0.0293753428594 36 17 -0.0108267095141 45 17 0.0074419669160 + 34 18 0.0227371511283 25 16 -0.0102032251498 21 14 -0.0074128063418 + 23 18 0.0165928414765 27 16 -0.0094482705029 26 13 0.0073892431894 + 51 18 0.0134864557533 53 17 0.0076116631443 22 15 -0.0066014240484 + + A B I J A B I J +------------------------------------ ------------------------------------ + 19 19 18 18 -0.1056999392535 23 19 12 18 -0.0299060870498 + 23 23 18 18 -0.0613032053597 19 36 18 18 -0.0270381793830 + 23 19 18 17 -0.0600698688184 36 19 18 18 -0.0270381793830 + 19 23 17 18 -0.0600698688184 19 23 12 18 -0.0226924465502 + 23 23 17 17 -0.0584525648842 23 19 18 12 -0.0226924465502 + 19 19 17 17 -0.0581591939789 19 23 18 17 -0.0210606563251 + 19 19 12 12 -0.0365923448057 23 19 17 18 -0.0210606563251 + 19 23 18 12 -0.0299060870498 + +It. Correlation Energy T1 Residual T2 Residual T3 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------------------- + 11 -0.764332062876228 7.13166e-08 4.33795e-07 1.70597e-07 159.364 7.982 + 12 -0.764332102477517 2.66336e-08 1.81180e-07 8.46321e-08 160.219 8.025 + 13 -0.764332120385917 1.06750e-08 7.76879e-08 4.18403e-08 162.393 8.137 + +CCSDT iterations converged in 13 cycles and 100.538 seconds (7.734 s/it.) at 67.271 Gflops/sec + +Total CCSDT energy: -229.407644692870491 + + @CHECKOUT-I, Total execution time (CPU/WALL): 2012.07/ 103.43 seconds. +--executable xncc finished with status 0 in 104.02 seconds (walltime). + The final electronic energy is -229.407644692870491 a.u. + This computation required 111.95 seconds (walltime). diff --git a/furan/cc-pvdz/CC/fura-gs-ccsdtq.out b/furan/cc-pvdz/CC/fura-gs-ccsdtq.out new file mode 100644 index 0000000..f4ce106 --- /dev/null +++ b/furan/cc-pvdz/CC/fura-gs-ccsdtq.out @@ -0,0 +1,1028 @@ + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xjoda + + + ************************************************************************* + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + ************************************************************************* + + **************************************************************** + * CFOUR Coupled-Cluster techniques for Computational Chemistry * + **************************************************************** + + + Department of Chemistry Institut fuer Physikalische Chemie + University of Florida Universitaet Mainz + Gainesville, FL 32611, USA D-55099 Mainz, Germany + + Department of Chemistry Fakultaet fuer Chemie und Biowiss. + Johns Hopkins University Karlsruher Institut fuer Technologie + Baltimore, MD 21218, USA D-76131 Karlsruhe, Germany + + Department of Chemistry Department of Physical Chemistry + Southern Methodist University Eotvos Lorand University + Dallas, TX 75275, USA H-1053 Budapest, Hungary + + + Version 2.1 + + nazare115 + Thu Oct 15 14:34:58 CEST 2020 + integer*8 version is running + +******************************************************************************** +* Input from ZMAT file * +******************************************************************************** +Ketene -GS +C 0.00000000 2.06365826 -0.60051250 +C 0.00000000 -2.06365826 -0.60051250 +C 0.00000000 1.35348578 1.86336416 +C 0.00000000 -1.35348578 1.86336416 +O 0.00000000 0.00000000 -2.13945332 +H 0.00000000 3.86337287 -1.53765695 +H 0.00000000 -3.86337287 -1.53765695 +H 0.00000000 2.59168789 3.47168051 +H 0.00000000 -2.59168789 3.47168051 + +*CFOUR(COORD=CARTESIAN,UNITS=BOHR + MEMORY=100,MEM_UNIT=GB,CC_PROG=NCC + FROZEN_CORE=1 + CALC=CCSDTQ,BASIS=PVDZ + SCF_CONV=9,CC_CONV=7,ESTATE_MAXCYC=80) + +******************************************************************************** + ------------------------------------------------------------------- + CFOUR Control Parameters + ------------------------------------------------------------------- + External Internal Value Units + Name Name + ------------------------------------------------------------------- + ABCDTYPE IABCDT STANDARD [ 0] *** + ANHARMONIC IANHAR OFF [ 0] *** + ANH_ALGORIT IANALG STANDARD [ 0] *** + ANH_DERIVAT IANDER SECOND [ 1] *** + ANH_MODE ANHMOD VIBRATION [ 0] *** + ANH_STEPSIZ ICUBST 50000 x 10-6 + ANH_SYMMETR IANHSM ABELIAN [ 0] *** + AO_LADDERS IAOLAD SINGLEPASS [ 1] *** + AV_SCF IAVSCF OFF [ 0] *** + BASIS IBASIS PVDZ [ 13] *** + BOTHVECTORS BOTHVC OFF [ 0] *** + BOX_POTENT IPIAB OFF [ 0] *** + BREIT IBREIT OFF [ 0] *** + BRUCK_CONV IBRTOL 10D- 4 *** + BRUECKNER IBRKNR OFF [ 0] *** + BUFFERSIZE IBUFFS 4096 *** + CACHE_RECS ICHREC 10 *** + CALCLEVEL ICLLVL CCSDTQ [ 46] *** + CCORBOPT ICCORB OFF [ 0] x 0.01 + CC_CONV ICCCNV 10D- 7 *** + CC_EXPORDER ICCEOR 5 *** + CC_EXTRAPOL ICCEXT DIIS [ 1] *** + CC_GUESS ICCGES MP2 [ 0] *** + CC_MAXCYC ICCCYC 100 cycles + CC_PROGRAM ICCPRO NCC [ 5] *** + CHARGE ICHRGE 0 *** + CHOLESKY ICHOLE OFF [ 0] *** + CIS_CONV ICISTL 5 *** + COMM_SIZE IPSIZE *** *** + CONSTANT ICONST OLD [ 1] *** + CONTINUUM ICONTU NONE [ 0] *** + CONTRACTION ICNTYP GENERAL [ 1] *** + COORDINATES ICOORD CARTESIAN [ 1] *** + CPHF_CONVER ICPHFT 10D- 16 *** + CPHF_MAXCYC ICPHFC 64 cycles + CUBIC ICUBIC OFF [ 0] *** + CURVILINEAR ICURVY OFF [ 0] *** + DBOC IDBOC OFF [ 0] *** + DCT IDCT OFF [ 0] *** + DERIV_LEV IDRLVL ZERO [ 0] *** + DEVMEM_SIZE IDVMEM ********* MByte + DIAG_MRCC IEOMST 10D- 0 *** + DIFF_TYPE IDIFTY RELAXED [ 0] *** + DIRECT IDIRCT OFF [ 0] *** + DROPMO IDRPMO NONE + ECP IECP OFF [ 0] *** + EIGENVECTOR IVEC 1 *** + EL_ANHARM IELANH OFF [ 0] *** + EOMFOLLOW IEOMSR ENERGY [ 0] *** + EOMIP IEOMIP OFF [ 0] *** + EOMLEVEL HBARFM SAME [ 0] *** + EOM_MRCC IMRCCE NEW [ 1] *** + EOM_NONIT EOMNON OFF [ 0] *** + EOM_NSING IEOMSI 10D- 0 *** + EOM_NSTATES IMRCCD DAVIDSON [ 0] *** + EOM_NTRIP IEOMTR 10D- 0 *** + EOM_ORDER IEXORD ENERGY [ 0] *** + EOM_PROPSTA IEOMST 0 *** + ESTATE_CONV IEXTOL 10D- 5 *** + ESTATE_DIAG IEXDIG ITERATIVE [ 0] *** + ESTATE_LOCK IESLOC ON [ 1] *** + ESTATE_MAXC IEXMXC 80 *** + ESTATE_PROP IEXPRP OFF [ 0] *** + EVAL_HESS IRECAL 0 # of cyc. + EXCITATION IEXCIT 0 *** + EXCITE IEXCIT NONE [ 0] *** + EXTERN_POT IEXPOT OFF [ 0] *** + FCGRADNEW IFCGNW OFF [ 0] *** + FC_FIELD IFINFC 0 x 10-6 + FD_CALTYPE IFDCAL GRADONLY [ 0] *** + FD_PROJECT IFDPRJ OFF [ 1] *** + FD_STEPSIZE IDISFD 0 10-4 bohr + FD_USEGROUP IFDGRP FULL [ 0] *** + FILE_RECSIZ IFLREC 4096 words + FINITE_PERT IFIPER 0 x 10-6 + FIXGEOM IFIXGM OFF [ 0] *** + FOCK IFOCK AO [ 1] *** + FREQ_ALGORI IVIALG STANDARD [ 0] *** + FROZEN_CORE IFROCO ON [ 1] *** + GAMMA_ABCD IGABCD STORE [ 0] *** + GAMMA_ABCI IGABCI STORE [ 0] *** + GENBAS_1 IGNBS1 0 *** + GENBAS_2 IGNBS2 0 *** + GENBAS_3 IGNBS3 0 *** + GENBAS_4 IGNBS4 0 *** + GEO_CONV ICONTL 5 H/bohr + GEO_MAXCYC IOPTCY 50 *** + GEO_MAXSTEP IMXSTP 300 millibohr + GEO_METHOD INR SINGLE_POINT[ 5] *** + GIAO IGIAO OFF [ 1] *** + GIMIC IGIMIC OFF [ 0] *** + GRID IGRID OFF [ 0] *** + GRID_ALGO IGALGO SERIAL [ 0] *** + GUESS IGUESS MOREAD [ 0] *** + HBAR IHBAR OFF [ 0] *** + HESS_TYPE IHESTP SCF [ 0] *** + HF2_FILE IHF2Fl USE [ 1] *** + HFSTABILITY ISTABL OFF [ 0] *** + INCORE INCORE OFF [ 0] *** + INPUT_MRCC IMRCC ON [ 1] *** + INTEGRALS INTTYP VMOL [ 1] *** + JODA_PRINT IJPRNT 0 *** + KEYWORD_OUT IDMPKW NO [ 0] *** + LINDEP_TOL ILINDP 8 *** + LINEQ_CONV IZTACN 10D- 7 cycles + LINEQ_EXPOR ILMAXD 5 *** + LINEQ_MAXCY ILMAXC 100 *** + LINEQ_TYPE ILTYPE DIIS [ 1] *** + LOCK_ORBOCC ILOCOC OFF [ 0] *** + MEMORY_SIZE IMEMSZ ********* words + MEM_UNIT IMEMU GB [ 3] *** + MRCC IMRCCC OFF [ 0] *** + MULTIPLICTY IMULTP 1 *** + NACOUPLING IVCOUP OFF [ 0] *** + NEGEVAL IDIE ABORT [ 0] *** + NEWNORM INEWNO OFF [ 0] *** + NON-HF INONHF OFF [ 0] *** + NTOP_TAMP ITOPT2 15 *** + NUC_MODEL INUCMO POINT [ 0] *** + OCCUPATION IOCCU ESTIMATED BY SCF + OPEN-SHELL IOPEN SPIN-ORBITAL[ 0] *** + OPTVIB IOPTVB OFF [ 0] *** + ORBITALS IORBTP STANDARD [ 0] *** + PARALLEL IPARAL ON [ 1] *** + PARA_INT IPINTS ON [ 1] *** + PARA_PRINT IPPRIN 0 *** + PERT_ORB IPTORB STANDARD [ 0] *** + POINTS IGRDFD 0 *** + PRINT IPRNT 0 *** + PROPS IPROPS OFF [ 0] *** + PROP_INTEGR IINTYP INTERNAL [ 0] *** + PSI IPSI OFF [ 0] *** + QC_ALG IQCALG FLM [ 0] *** + QC_LINALG IQCLIN TRIDIAG [ 2] *** + QC_MAXCYC IQCMAX 10D-100 cycles + QC_MAXSCFCY IQCMSC 10D- 15 cycles + QC_RTRUST IQCRTR 10D- 0 x 10-3 + QC_SKIPSCF IQCSKI OFF [ 0] *** + QC_START IQCSTA 10D- 1 *** + QRHFGUESS IQGUES OFF [ 0] *** + QUARTIC IQUART OFF [ 0] *** + RAMAN_INT IRAMIN OFF [ 0] *** + RAMAN_ORB IRAMRE UNRELAXED [ 0] *** + RDO IRDOFM OFF [ 0] *** + REDUCE_REPR REDREP Ir [ 0] *** + REFERENCE IREFNC RHF [ 0] *** + RELATIVIST IRELAT OFF [ 0] *** + RELAX_DENS IRDENS OFF [ 0] *** + RESET_FLAGS IRESET OFF [ 0] *** + RESTART_CC ICCRES OFF [ 0] *** + ROT_EVEC ROTVEC 0 *** + SAVE_INTS ISVINT OFF [ 0] *** + SCALE_ON ISTCRT 0 *** + SCF_CONV ISCFCV 10D- 9 *** + SCF_DAMPING IDAMP 0 x 10-3 + SCF_EXPORDE IRPPOR 6 *** + SCF_EXPSTAR IRPPLS 8 *** + SCF_EXTRAPO IRPP ON [ 1] *** + SCF_MAXCYC ISCFCY 150 cycles + SCF_NOSTOP ISCFST OFF [ 0] *** + SCF_PRINT ISCFPR 0 *** + SCF_PROG ISCFPR SCF [ 0] *** + SD_FIELD IFINSD 0 x 10-6 + SOPERT IPERSO OFF [ 0] *** + SPHERICAL IDFGHI ON [ 1] *** + SPINORBIT ISOCAL OFF [ 0] *** + SPINROTATIO ISRCON OFF [ 0] *** + SPIN_FLIP ISPFLP OFF [ 0] *** + SPIN_ORBIT ISPORB OFF [ 0] *** + SPIN_SCAL ISCSMP OFF [ 0] *** + STEEPSCALE ISTPSC 1000 x 10-3 + SUBGROUP ISUBGP DEFAULT [ 0] *** + SUBGRPAXIS ISBXYZ X [ 0] *** + SYMMETRY ISYM ON [ 0] *** + SYM_CHECK ISYMCK OVERRIDE [ 1] *** + T3_EXTRAPOL IT3EXT ON [ 1] *** + T4_EXTRAPOL IT4EXP OFF [ 0] *** + TAMP_SUM IEVERY 5 *** + TESTSUITE ITESTS OFF [ 0] *** + THERMOCH ITHERM OFF [ 0] *** + TOL_CHOLESK ITOLCH 10D- 4 *** + TRANGRAD IRESRM OFF [ 0] *** + TRANS_INV ITRAIN USE [ 0] *** + TREAT_PERT ITREAT SIMULTANEOUS[ 0] *** + TRIP_ALGORI ITRALG NORMAL [ 0] *** + UIJ_THRESHO IUIJTH 1 *** + UNITS IUNITS BOHR [ 1] *** + UNOS IUNOS OFF [ 0] *** + UPDATE_HESS IHUPDT ON [ 1] *** + VIBPHASE ISETPH STANDARD [ 0] *** + VIBRATION IVIB NO [ 0] *** + VIB_ALGORIT IGEALG STANDARD [ 0] *** + VNATORB IVNORB OFF [ 0] *** + VTRAN IVTRAN FULL/PARTIAL[ 0] *** + XFIELD IXEFLD 0 x 10-6 + XFORM_TOL IXFTOL 10D- 11 *** + YFIELD IYEFLD 0 x 10-6 + ZFIELD IZEFLD 0 x 10-6 + ZSCALE_EXP IZEXPS OFF [ 0] *** + ------------------------------------------------------------------- + @GETXYZ-I, 9 atoms read from ZMAT. + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 +******************************************************************************** + The full molecular point group is C2v . + The largest Abelian subgroup of the full molecular point group is C2v . + The computational point group is C2v . +******************************************************************************** + + + ---------------------------------------------------------------- + Coordinates used in calculation (QCOMP) + ---------------------------------------------------------------- + Z-matrix Atomic Coordinates (in bohr) + Symbol Number X Y Z + ---------------------------------------------------------------- + C 6 0.00000000 -2.06365826 0.60031230 + C 6 0.00000000 2.06365826 0.60031230 + C 6 0.00000000 -1.35348578 -1.86356436 + C 6 0.00000000 1.35348578 -1.86356436 + O 8 0.00000000 0.00000000 2.13925312 + H 1 0.00000000 -3.86337287 1.53745675 + H 1 0.00000000 3.86337287 1.53745675 + H 1 0.00000000 -2.59168789 -3.47188071 + H 1 0.00000000 2.59168789 -3.47188071 + ---------------------------------------------------------------- + + Interatomic distance matrix (Angstroms) + + C C C C O + [ 1] [ 2] [ 3] [ 4] [ 5] + C [ 1] 0.00000 + C [ 2] 2.18408 0.00000 + C [ 3] 1.35691 2.22931 0.00000 + C [ 4] 2.22931 1.35691 1.43247 0.00000 + O [ 5] 1.36226 1.36226 2.23601 2.23601 0.00000 + H [ 6] 1.07375 3.17541 2.23677 3.29549 2.06906 + H [ 7] 3.17541 1.07375 3.29549 2.23677 2.06906 + H [ 8] 2.17295 3.27299 1.07409 2.25451 3.27071 + H [ 9] 3.27299 2.17295 2.25451 1.07409 3.27071 + + H H H H + [ 6] [ 7] [ 8] [ 9] + H [ 6] 0.00000 + H [ 7] 4.08882 0.00000 + H [ 8] 2.73491 4.32378 0.00000 + H [ 9] 4.32378 2.73491 2.74292 0.00000 + rotcon2 + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 + There are 5 frozen-core orbitals. + There are 90 basis functions. + @GEOPT-W, Archive file not created for single-point calculation. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.27/ 2.12 seconds. +--executable xjoda finished with status 0 in 2.65 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol + SERIAL VERSION OF MOLECULE STARTED +******************************************************************************** + INPUT FROM MOL FILE +******************************************************************************** +INTGRL 1 0 1 0 0 0 0 0 0 + *** CFOUR Program System (Release V0.1) *** +Ketene -GS + 5 2 X Y 0.10E-08 0 0 + 9999.00 3.00 + 6.00000000 1 3 1 1 1 +C #1 0.000000000000000 -2.063658260000000 0.600312302999175 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 6.00000000 1 3 1 1 1 +C #2 0.000000000000000 -1.353485780000000 -1.863564357000825 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 8.00000000 1 3 1 1 1 +O #3 0.000000000000000 0.000000000000000 2.139253122999175 + 9 3 + 11720.0000000000 7.100000000000000E-004 -1.600000000000000E-004 + 0.000000000000000E+000 + 1759.00000000000 5.470000000000000E-003 -1.263000000000000E-003 + 0.000000000000000E+000 + 400.800000000000 2.783700000000000E-002 -6.267000000000000E-003 + 0.000000000000000E+000 + 113.700000000000 0.104800000000000 -2.571600000000000E-002 + 0.000000000000000E+000 + 37.0300000000000 0.283062000000000 -7.092400000000000E-002 + 0.000000000000000E+000 + 13.2700000000000 0.448719000000000 -0.165411000000000 + 0.000000000000000E+000 + 5.02500000000000 0.270952000000000 -0.116955000000000 + 0.000000000000000E+000 + 1.01300000000000 1.545800000000000E-002 0.557368000000000 + 0.000000000000000E+000 + 0.302300000000000 -2.585000000000000E-003 0.572759000000000 + 1.00000000000000 + 4 2 + 17.7000000000000 4.301800000000000E-002 0.000000000000000E+000 + 3.85400000000000 0.228913000000000 0.000000000000000E+000 + 1.04600000000000 0.508728000000000 0.000000000000000E+000 + 0.275300000000000 0.460531000000000 1.00000000000000 + 1 1 + 1.18500000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #4 0.000000000000000 -3.863372870000000 1.537456752999175 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #5 0.000000000000000 -2.591687890000000 -3.471880707000825 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 +FINISH + +******************************************************************************** + ONE- AND TWO-ELECTRON INTEGRALS OVER SYMMETRY-ADAPTED AOS ARE CALCULATED. + + SPHERICAL HARMONICS ARE USED. + + INTEGRALS LESS THAN 0.10E-13 ARE NEGLECTED. + + NUCLEAR REPULSION ENERGY : 161.1082297788 A.U. + @MOLECU-I, ONE ELECTRON INTEGRALS (CPU/WALL): 0.05/ 0.08 SECONDS. + @TWOEL-I, 325108 INTEGRALS OF SYMMETRY TYPE I I I I + @TWOEL-I, 908743 INTEGRALS OF SYMMETRY TYPE I J I J + @TWOEL-I, 490042 INTEGRALS OF SYMMETRY TYPE I I J J + @TWOEL-I, 460725 INTEGRALS OF SYMMETRY TYPE I J K L + @TWOEL-I, TOTAL NUMBER OF 2-E INTEGRALS 2184618. + @MOLECU-I, TWO ELECTRON INTEGRALS (CPU/WALL): 2.31/ 2.32 SECONDS. + @CHECKOUT-I, Total execution time (CPU/WALL): 2.37/ 2.46 seconds. + +Running with 20 threads/proc + +--executable xvmol finished with status 0 in 3.01 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol2ja + @GETMEM-I, Allocated 95367 MB of main memory. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.31/ 0.06 seconds. +--executable xvmol2ja finished with status 0 in 0.57 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvscf + There are 90 functions in the AO basis. + + There are 4 irreducible representations. + + Irrep # of functions + 1 35 + 2 13 + 3 31 + 4 11 + + + Parameters for SCF calculation: + SCF reference function: RHF + Maximum number of iterations: 150 + Full symmetry point group: C2v + Computational point group: C2v + Initial density matrix: MOREAD + SCF convergence tolerance: 10**(- 9) + DIIS convergence acceleration: ON + Latest start for DIIS: 8 + DIIS order: 6 + + Memory information: 341888 words required. + Fock matrices are constructed from AO integral file. + @GETMEM-I, Allocated 2 MB of main memory. + Initialization and symmetry analysis required 0.002 seconds. + + @INITGES-I, Occupancies from core Hamiltonian: + + Alpha population by irrep: 9 2 6 1 + Beta population by irrep: 9 2 6 1 + + + total no. of electrons in initial guess : 0.000000000000000E+000 + -------------------------------------------------------------------- + Iteration Total Energy Largest Density Difference + -------------------------------------------------------------------- + 0 161.108229778788910 0.0000000000D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 1 -196.263249175407992 0.1098182460D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 2 -179.889864626336106 0.1675780025D+02 + current occupation vector + 9 1 7 1 + 9 1 7 1 + 3 -180.580457259652945 0.1772125138D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 4 -162.771013663095033 0.1566999730D+02 + current occupation vector + 8 2 7 1 + 8 2 7 1 + 5 -169.943224465301597 0.1454729382D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 6 -160.269967975315780 0.1454634919D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 7 -168.828658617537684 0.1395077743D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 8 -160.232275948463297 0.1395068492D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 9 -209.746508446745025 0.5520995458D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 10 -228.180230304181549 0.2015536648D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 11 -228.454713327495682 0.6531384936D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 12 -228.600329261507483 0.3196758217D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 13 -228.637509917234041 0.7498321731D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 14 -228.642938164599826 0.5250342791D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 15 -228.643241982659248 0.9795506231D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 16 -228.643308522550143 0.3593200395D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 17 -228.643312517846056 0.1473098013D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 18 -228.643312570337258 0.1244041229D-03 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 19 -228.643312572356052 0.2423484470D-04 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 20 -228.643312572476049 0.5414751593D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 21 -228.643312572485769 0.2003507219D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 22 -228.643312572485598 0.8833300562D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 23 -228.643312572484461 0.3139636784D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 24 -228.643312572486110 0.4136764657D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 25 -228.643312572485542 0.9839839787D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 26 -228.643312572486622 0.1838835018D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 27 -228.643312572484007 0.3228508794D-08 + current occupation vector + 9 2 6 1 + 9 2 6 1 + + SCF has converged. + + Density matrix saved to file den.dat + total electron number: 36.0000000000000 + E(SCF)= -228.643312572484575 0.7981584282D-09 + + Eigenvector printing suppressed. + + @PUTMOS-I, Writing converged MOs to NEWMOS. + @PUTMOS-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTMOS-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTMOS-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTMOS-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + @PUTFOCK-I, Writing converged Fock matrix to NEWFOCK. + @PUTFOCK-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTFOCK-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + + + + ORBITAL EIGENVALUES (ALPHA) (1H = 27.2113834 eV) + + MO # E(hartree) E(eV) FULLSYM COMPSYM + ---- -------------------- -------------------- ------- --------- + 1 1 -20.6219765861 -561.1525113512 A1 A1 (1) + 2 49 -11.2892088103 -307.1949892207 B2 B2 (3) + 3 2 -11.2891634657 -307.1937553315 A1 A1 (1) + 4 3 -11.2328159068 -305.6604603025 A1 A1 (1) + 5 50 -11.2318729764 -305.6348018622 B2 B2 (3) + 6 4 -1.4574476329 -39.6591663239 A1 A1 (1) + 7 5 -1.0834872588 -29.4831872086 A1 A1 (1) + 8 51 -1.0036038078 -27.3094479952 B2 B2 (3) + 9 52 -0.8050606676 -21.9068144851 B2 B2 (3) + 10 6 -0.7793049296 -21.2059652251 A1 A1 (1) + 11 7 -0.7372159421 -20.0606656495 A1 A1 (1) + 12 36 -0.6283416633 -17.0980459063 B1 B1 (2) + 13 53 -0.6064452640 -16.5022145907 B2 B2 (3) + 14 54 -0.5741889664 -15.6244761082 B2 B2 (3) + 15 8 -0.5622006055 -15.2982562239 A1 A1 (1) + 16 9 -0.5366322238 -14.6025051862 A1 A1 (1) + 17 37 -0.3944127682 -10.7325170532 B1 B1 (2) + 18 80 -0.3173264428 -8.6348914980 A2 A2 (4) + +++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ + 19 38 0.1616454919 4.3985974562 B1 B1 (2) + 20 10 0.2028007990 5.5184902966 A1 A1 (1) + 21 55 0.2259953076 6.1496449623 B2 B2 (3) + 22 11 0.2331452351 6.3442043789 A1 A1 (1) + 23 81 0.2346526075 6.3852220682 A2 A2 (4) + 24 56 0.2409072580 6.5554197617 B2 B2 (3) + 25 12 0.3379830583 9.1969865830 A1 A1 (1) + 26 57 0.3670668300 9.9883962435 B2 B2 (3) + 27 13 0.4400792390 11.9751648999 A1 A1 (1) + 28 58 0.5035354267 13.7018955503 B2 B2 (3) + 29 14 0.5796551077 15.7732173745 A1 A1 (1) + 30 59 0.6027649445 16.4020680057 B2 B2 (3) + 31 39 0.6720867908 18.2884113425 B1 B1 (2) + 32 15 0.6949257331 18.9098905590 A1 A1 (1) + 33 60 0.7033703399 19.1396799905 B2 B2 (3) + 34 82 0.7176012567 19.5269229246 A2 A2 (4) + 35 61 0.7543801794 20.5277282917 B2 B2 (3) + 36 40 0.7622869649 20.7428828633 B1 B1 (2) + 37 16 0.7651070466 20.8196211868 A1 A1 (1) + 38 17 0.7917408050 21.5443625978 A1 A1 (1) + 39 83 0.8438632537 22.9626865338 A2 A2 (4) + 40 62 0.8844205187 24.0663058221 B2 B2 (3) + 41 18 0.9187910190 25.0015746820 A1 A1 (1) + 42 19 0.9547555380 25.9802189979 A1 A1 (1) + 43 63 0.9634112815 26.2157537519 B2 B2 (3) + 44 64 1.0592164869 28.8227459274 B2 B2 (3) + 45 41 1.0743328454 29.2340829566 B1 B1 (2) + 46 20 1.1352329173 30.8912581602 A1 A1 (1) + 47 65 1.1904894416 32.3948646279 B2 B2 (3) + 48 21 1.1908922750 32.4058262839 A1 A1 (1) + 49 42 1.2129419174 33.0058275576 B1 B1 (2) + 50 66 1.2581407748 34.2357509943 B2 B2 (3) + 51 84 1.2921641151 35.1615731515 A2 A2 (4) + 52 22 1.2994001068 35.3584744953 A1 A1 (1) + 53 43 1.3116428673 35.6916169462 B1 B1 (2) + 54 85 1.3649569984 37.1423682072 A2 A2 (4) + 55 44 1.5283489789 41.5884900335 B1 B1 (2) + 56 23 1.5439841774 42.0139454134 A1 A1 (1) + 57 67 1.5691624192 42.6990802047 B2 B2 (3) + 58 68 1.5969806595 43.4560530082 B2 B2 (3) + 59 24 1.7377154792 47.2856421455 A1 A1 (1) + 60 69 1.7438095776 47.4514709939 B2 B2 (3) + 61 86 1.7443895833 47.4672537511 A2 A2 (4) + 62 25 1.7729617500 48.2447419337 A1 A1 (1) + 63 45 1.8384391578 50.0264727818 B1 B1 (2) + 64 26 1.8727560698 50.9602834298 A1 A1 (1) + 65 46 1.9574193824 53.2640892885 B1 B1 (2) + 66 70 1.9863618073 54.0516527104 B2 B2 (3) + 67 71 2.0036624844 54.5224280672 B2 B2 (3) + 68 87 2.0489211710 55.7539795407 A2 A2 (4) + 69 27 2.0703324397 56.3366097828 A1 A1 (1) + 70 88 2.1357719213 58.1173086059 A2 A2 (4) + 71 28 2.1641427105 58.8893170284 A1 A1 (1) + 72 72 2.1880643996 59.5402592802 B2 B2 (3) + 73 47 2.1914898441 59.6334703659 B1 B1 (2) + 74 29 2.2271655184 60.6042548161 A1 A1 (1) + 75 73 2.2977715809 62.5255434529 B2 B2 (3) + 76 30 2.3793504210 64.7454165492 A1 A1 (1) + 77 89 2.5107047412 68.3197493175 A2 A2 (4) + 78 74 2.5407172731 69.1364318293 B2 B2 (3) + 79 75 2.6586433664 72.3453639681 B2 B2 (3) + 80 31 2.6718877167 72.7057610618 A1 A1 (1) + 81 32 2.8267951805 76.9210074510 A1 A1 (1) + 82 76 2.9419209269 80.0537382753 B2 B2 (3) + 83 77 2.9853767071 81.2362301695 B2 B2 (3) + 84 33 3.0013526923 81.6709588287 A1 A1 (1) + 85 48 3.2421725037 88.2239990462 B1 B1 (2) + 86 90 3.2857682253 89.4102989431 A2 A2 (4) + 87 34 3.4838249547 94.7996965407 A1 A1 (1) + 88 78 3.6959298762 100.5713648809 B2 B2 (3) + 89 79 3.7700022467 102.5869765541 B2 B2 (3) + 90 35 3.8341979240 104.3338297409 A1 A1 (1) + + + VSCF finished. + + @CHECKOUT-I, Total execution time (CPU/WALL): 5.39/ 1.56 seconds. +--executable xvscf finished with status 0 in 2.15 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvtran + @GETMEM-I, Allocated 95367 MB of main memory. + Full RHF integral transformation + The following 5 MOs will be dropped: + 1 2 3 12 13 + There are 85 active molecular orbitals. + Transformation of IIII integrals : + 1 pass through the AO integral file was required. + 325108 AO integrals were read. + 240883 MO integrals were written to HF2. + Transformation of IIJJ integrals : + 1 pass through the AO integral file was required. + 490042 AO integrals were read. + 386877 MO integrals were written to HF2. + Transformation of IJIJ integrals : + 1 pass through the AO integral file was required. + 908743 AO integrals were read. + 712509 MO integrals were written to HF2. + Transformation of IJKL integrals : + 1 pass through the AO integral file was required. + 460725 AO integrals were read. + 398112 MO integrals were written to HF2. + Summary of active molecular orbitals: +------------------------------------------------------------------------ + + Index Eigenvalue Symmetry Index Eigenvalue Symmetry +------------------------------------------------------------------------ + 1 -1.4574476 1 44 1.2129419 2 + 2 -1.0834873 1 45 1.3116429 2 + 3 -0.7793049 1 46 1.5283490 2 + 4 -0.7372159 1 47 1.8384392 2 + 5 -0.5622006 1 48 1.9574194 2 + 6 -0.5366322 1 49 2.1914898 2 + 7 -0.6283417 2 50 3.2421725 2 + 8 -0.3944128 2 51 0.2259953 3 + 9 -1.0036038 3 52 0.2409073 3 + 10 -0.8050607 3 53 0.3670668 3 + 11 -0.6064453 3 54 0.5035354 3 + 12 -0.5741890 3 55 0.6027649 3 + 13 -0.3173264 4 56 0.7033703 3 + 14 0.2028008 1 57 0.7543802 3 + 15 0.2331452 1 58 0.8844205 3 + 16 0.3379831 1 59 0.9634113 3 + 17 0.4400792 1 60 1.0592165 3 + 18 0.5796551 1 61 1.1904894 3 + 19 0.6949257 1 62 1.2581408 3 + 20 0.7651070 1 63 1.5691624 3 + 21 0.7917408 1 64 1.5969807 3 + 22 0.9187910 1 65 1.7438096 3 + 23 0.9547555 1 66 1.9863618 3 + 24 1.1352329 1 67 2.0036625 3 + 25 1.1908923 1 68 2.1880644 3 + 26 1.2994001 1 69 2.2977716 3 + 27 1.5439842 1 70 2.5407173 3 + 28 1.7377155 1 71 2.6586434 3 + 29 1.7729618 1 72 2.9419209 3 + 30 1.8727561 1 73 2.9853767 3 + 31 2.0703324 1 74 3.6959299 3 + 32 2.1641427 1 75 3.7700022 3 + 33 2.2271655 1 76 0.2346526 4 + 34 2.3793504 1 77 0.7176013 4 + 35 2.6718877 1 78 0.8438633 4 + 36 2.8267952 1 79 1.2921641 4 + 37 3.0013527 1 80 1.3649570 4 + 38 3.4838250 1 81 1.7443896 4 + 39 3.8341979 1 82 2.0489212 4 + 40 0.1616455 2 83 2.1357719 4 + 41 0.6720868 2 84 2.5107047 4 + 42 0.7622870 2 85 3.2857682 4 + 43 1.0743328 2 +------------------------------------------------------------------------ + -1.45744763288719 -1.08348725881441 -0.779304929609897 + -0.737215942115339 -0.562200605497301 -0.536632223783724 + -0.628341663300699 -0.394412768193209 -1.00360380778026 + -0.805060667553655 -0.606445264032669 -0.574188966380078 + -0.317326442801090 0.202800799044599 0.233145235052782 + 0.337983058334004 0.440079239041159 0.579655107669000 + 0.694925733138531 0.765107046589679 0.791740804983910 + 0.918791018982032 0.954755538003189 1.13523291727329 + 1.19089227502871 1.29940010677049 1.54398417735024 + 1.73771547923282 1.77296175003401 1.87275606979175 + 2.07033243972521 2.16414271052282 2.22716551838589 + 2.37935042101669 2.67188771673553 2.82679518054224 + 3.00135269229820 3.48382495469438 3.83419792398046 + 0.161645491943529 0.672086790797680 0.762286964920328 + 1.07433284544462 1.21294191744913 1.31164286730943 + 1.52834897888630 1.83843915784915 1.95741938237798 + 2.19148984413109 3.24217250366571 0.225995307622873 + 0.240907258015995 0.367066829963131 0.503535426659975 + 0.602764944529835 0.703370339875812 0.754380179426906 + 0.884420518732559 0.963411281466499 1.05921648685572 + 1.19048944155892 1.25814077480321 1.56916241916196 + 1.59698065950503 1.74380957764511 1.98636180732934 + 2.00366248439902 2.18806439955680 2.29777158087759 + 2.54071727310046 2.65864336644143 2.94192092693438 + 2.98537670707142 3.69592987620463 3.77000224671010 + 0.234652607487977 0.717601256707210 0.843863253708071 + 1.29216411509331 1.36495699837027 1.74438958333340 + 2.04892117101004 2.13577192131677 2.51070474122043 + 3.28576822533544 + @CHECKOUT-I, Total execution time (CPU/WALL): 11.75/ 1.06 seconds. +--executable xvtran finished with status 0 in 2.07 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xintprc + @GETMEM-I, Allocated 95367 MB of main memory. + @GMOIAA-I, Processing MO integrals for spin case AA. + @GMOIAA-I, Generation of integral list completed. + TYPE NUMBER + ---- -------- + PPPP 894479 + PPPH 640524 + PPHH 115497 + PHPH 63721 + PHHH 22938 + HHHH 1222 + + TOTAL 1738381 + + @FORMT2-I, Second-order MP correlation energies: + ------------------------------------------------ + E(SCF) = -228.643312572485 a.u. + E2(AA) = -0.093684343380 a.u. + E2(AB) = -0.520081687065 a.u. + E2(TOT) = -0.707450373824 a.u. + Total MP2 energy = -229.350762946309 a.u. + ------------------------------------------------ + Largest T2 amplitudes for spin case AB: + _ _ _ _ _ _ + i j a b i j a b i j a b +----------------------------------------------------------------------------- +[ 13 13 40 40]-0.06710 [ 8 8 40 40]-0.05436 [ 13 13 76 76]-0.05241 +[ 13 8 76 40]-0.04215 [ 8 13 40 76]-0.04215 [ 8 8 76 76]-0.03737 +[ 7 7 40 40]-0.03140 [ 13 7 40 76]-0.02053 [ 7 13 76 40]-0.02053 +[ 13 13 77 77]-0.01960 [ 13 13 40 42]-0.01810 [ 13 13 42 40]-0.01810 +[ 7 7 45 45]-0.01664 [ 13 13 41 41]-0.01633 [ 13 13 78 76]-0.01595 +----------------------------------------------------------------------------- + Norm of T2AB vector ( 230058 symmetry allowed elements): 0.4218925855. +----------------------------------------------------------------------------- + @CHECKOUT-I, Total execution time (CPU/WALL): 5.13/ 0.65 seconds. +--executable xintprc finished with status 0 in 1.19 seconds (walltime). + calling xncc + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xncc + @GETMEM-I, Allocated 7 MB of main memory. + +Running with 20 threads/proc + +Using DIIS to accelerate the convergence of T1 and T2 +Using DIIS to accelerate the convergence of T3 +Using immediate high-order contributions +Performing 2 CCSDT sub-iterations +Damping factor for T3: 0.000000 +Damping factor for T4: 0.000000 + +Transposes are coarse-threaded + +Memory limit: 93.132 GiB +Minimum memory requirement: 10.986 GiB +Compromise memory amount: 177.337 GiB +Optimal memory requirement: 343.473 GiB + +List Location Size Cached Hunks Est. Disk I/O +----------------- ---------- ----------- ------ ----- ------------- + + T_DIIS 70:0 8.787 MiB Yes - 158.166 MiB + Z_DIIS 70:1 8.787 MiB Yes - 263.610 MiB + 18 1.755 MiB Yes - 265.429 MiB + 233 52.803 MiB Yes - 150.055 GiB + 30 9.615 MiB Yes - 10.986 GiB + 16 1.755 MiB Yes - 3.243 GiB + 25 1.755 MiB Yes - 236.952 MiB + 21 1.755 MiB No - 0 B + 10 329.156 KiB Yes - 472.519 MiB + 13 60.633 KiB Yes - 2.665 MiB + F(EA) 92:0 11.891 KiB Yes - 5.400 MiB + F(EM) 93:0 2.250 KiB Yes - 978.750 KiB + F(MI) 91:0 456 B Yes - 307.266 KiB + Q(AI) 190:2 2.250 KiB Yes - 810.000 KiB + Q(Ab,Ij) 50 1.755 MiB Yes - 2.623 GiB + QQ(Ab,Ij) 3 1.755 MiB Yes - 447.577 MiB + T(AI) 90:0 2.250 KiB Yes - 2.474 MiB + T(Ab,Ij) 46 1.755 MiB Yes - 3.397 GiB + W(Mn,Ij) 53 60.633 KiB Yes - 44.988 MiB + W~(Ab,Ej) 130 9.615 MiB Yes - 16.165 GiB + W~(EM,bj) 56 1.755 MiB Yes - 1.928 GiB + W~(Em,Bj) 58 1.755 MiB Yes - 2.700 GiB + W~(Ij,Mb) 110 329.156 KiB Yes - 332.692 MiB + W~~(Ab,Ej) 169 9.615 MiB Yes - 5.916 GiB + W~~(EM,bj) 76 1.755 MiB Yes - 631.873 MiB + W~~(Em,Bj) 78 1.755 MiB Yes - 631.873 MiB + W~~(Ij,Mb) 165 329.156 KiB Yes - 202.508 MiB + Z(AI) 90:2 2.250 KiB Yes - 810.000 KiB + Z(Ab,Ij) 63 1.755 MiB Yes - 631.873 MiB + Q(abc,ijk) Q3FILE 319.713 MiB Yes 1 18.733 GiB + T(abc,ijk) T3FILE 319.713 MiB Yes 1 65.566 GiB + T(abcd,ijkl) T4FILE 83.022 GiB No 4 3735.986 GiB + T3_1 T3_1 319.713 MiB Yes 1 9.367 GiB + T3_2 T3_2 319.713 MiB Yes 1 4.683 GiB + T3_3 T3_3 319.713 MiB Yes 1 4.683 GiB + T3_4 T3_4 319.713 MiB Yes 1 4.683 GiB + T3_5 T3_5 319.713 MiB Yes 1 4.683 GiB + W(abc,ije) WABCIJE 4.602 GiB Yes 1 276.115 GiB + W(abf,ijn) WABFIJN 853.370 MiB Yes 1 25.001 GiB + W(abf,inj) WABFINJ 1.545 GiB Yes 1 46.340 GiB + W(abm,ijk) WABMIJK 154.671 MiB Yes 1 9.063 GiB + W(mnd,jkl) WMNDJKL 28.065 MiB Yes 1 841.961 MiB + Z(abc,ijk) Z3FILE 319.713 MiB Yes 1 51.516 GiB + Z(abcd,ijkl) Z4FILE 83.022 GiB No 4 3735.986 GiB + Z3_1 Z3_1 319.713 MiB Yes 1 9.367 GiB + Z3_2 Z3_2 319.713 MiB Yes 1 9.367 GiB + Z3_3 Z3_3 319.713 MiB Yes 1 9.367 GiB + Z3_4 Z3_4 319.713 MiB Yes 1 9.367 GiB + Z3_5 Z3_5 319.713 MiB Yes 1 9.367 GiB + +Simulation and memory analysis took 246.367 seconds + +MP2 correlation energy: -0.707450373824291 + +Non-iterative calculation of MP2 took 0.327 cpu seconds and 0.017 walltime seconds at 0.777 Gflops/sec + +Total MP2 energy: -229.350762946308862 + +Beginning iterative solution of CCSDTQ equations: + +It. Correlation Energy T1 Residual T2 Residual T3 Residual T4 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------------------------------- + 1 -0.759137461775374 3.25613e-03 5.40842e-03 4.76332e-04 5.97398e-05 27293.020 5029.234 + 2 -0.765974884486305 7.18487e-04 2.77254e-03 7.09656e-05 1.22459e-04 244203.600 58948.004 + 3 -0.766487440625816 1.32975e-04 3.64550e-04 2.75956e-05 2.73513e-05 262494.763 41030.113 + 4 -0.766627050849718 3.32152e-05 1.33722e-04 1.03871e-05 1.53179e-05 268604.178 30213.125 + 5 -0.766644673851899 3.56368e-06 2.00731e-05 3.03661e-06 6.19820e-06 271772.975 22180.286 + + A I A I A I +-------------------------- -------------------------- -------------------------- + 19 17 -0.0299554171441 31 17 0.0116102497247 25 15 0.0075950397181 + 19 12 0.0287554436410 36 17 -0.0107605660048 21 14 -0.0074637602681 + 34 18 0.0227430138950 25 16 -0.0100926773043 45 17 0.0074527866712 + 23 18 0.0168081937403 27 16 -0.0094000341572 26 13 0.0072107996075 + 51 18 0.0135307664993 53 17 0.0076536679500 49 17 0.0065989280229 + + A B I J A B I J +------------------------------------ ------------------------------------ + 19 19 18 18 -0.1081697782235 23 19 12 18 -0.0301925687631 + 23 23 18 18 -0.0621082291040 36 19 18 18 -0.0274088510026 + 23 19 18 17 -0.0611153224610 19 36 18 18 -0.0274088510026 + 19 23 17 18 -0.0611153224610 19 23 12 18 -0.0229450277327 + 19 19 17 17 -0.0592567104918 23 19 18 12 -0.0229450277327 + 23 23 17 17 -0.0589716241287 19 23 18 17 -0.0213510875554 + 19 19 12 12 -0.0366992415363 23 19 17 18 -0.0213510875554 + 19 23 18 12 -0.0301925687631 + +It. Correlation Energy T1 Residual T2 Residual T3 Residual T4 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------------------------------- + 6 -0.766651521413942 1.58611e-06 7.29587e-06 1.11425e-06 3.07594e-06 276200.302 24018.124 + 7 -0.766653320142007 7.58206e-07 1.91374e-06 4.46696e-07 1.59012e-06 273767.645 22420.691 + 8 -0.766653963270390 2.39970e-07 4.88721e-07 1.78961e-07 8.04424e-07 274249.527 22247.423 + 9 -0.766654139150392 2.96953e-08 2.15357e-07 7.63380e-08 3.99978e-07 273563.775 22352.628 + 10 -0.766654208776797 1.60751e-08 6.46856e-08 3.45466e-08 1.98535e-07 271852.489 22006.045 + + A I A I A I +-------------------------- -------------------------- -------------------------- + 19 17 -0.0299484258823 31 17 0.0116110540428 25 15 0.0075947066740 + 19 12 0.0287525658366 36 17 -0.0107596967714 21 14 -0.0074645148725 + 34 18 0.0227447438009 25 16 -0.0100927354553 45 17 0.0074527511924 + 23 18 0.0168032993414 27 16 -0.0094003045394 26 13 0.0072119170024 + 51 18 0.0135313355816 53 17 0.0076540487120 49 17 0.0065991592359 + + A B I J A B I J +------------------------------------ ------------------------------------ + 19 19 18 18 -0.1081862316258 23 19 12 18 -0.0301945407259 + 23 23 18 18 -0.0621145852950 19 36 18 18 -0.0274134330092 + 23 19 18 17 -0.0611190783348 36 19 18 18 -0.0274134330092 + 19 23 17 18 -0.0611190783348 19 23 12 18 -0.0229470254900 + 19 19 17 17 -0.0592601149358 23 19 18 12 -0.0229470254900 + 23 23 17 17 -0.0589717799103 19 23 18 17 -0.0213536946113 + 19 19 12 12 -0.0366979941182 23 19 17 18 -0.0213536946113 + 19 23 18 12 -0.0301945407259 + +It. Correlation Energy T1 Residual T2 Residual T3 Residual T4 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------------------------------- + +CCSDTQ iterations converged in 10 cycles and 270445.905 seconds (27044.591 s/it.) at 13.022 Gflops/sec + +Total CCSDTQ energy: -229.409966781261375 + + @CHECKOUT-I, Total execution time (CPU/WALL): 2444295.19/ 270694.34 seconds. +--executable xncc finished with status 0 in 270699.30 seconds (walltime). + The final electronic energy is -229.409966781261375 a.u. + This computation required 270712.42 seconds (walltime). diff --git a/furan/cc-pvdz/FromDenis.txt b/furan/cc-pvdz/FromDenis.txt deleted file mode 100644 index 990050e..0000000 --- a/furan/cc-pvdz/FromDenis.txt +++ /dev/null @@ -1,26 +0,0 @@ -Cfour -HF -228.643312572484575 -MP2 -229.350762946309 -0.707450373824 -CCSD -229.378285257894248 -0.734972685409664 -CC3 -229.409042621239877 -0.765730048755297 -CCSDT -229.407644692870491 -0.764332120385917 -CC4 -229.410178829371802 -0.766866256888079 -CCSDTQ -229.409966781261375 -0.76665420877679 - -Dalton -HF -228.643312572485 -MP2 -229.3507629658025451 -0.7074503933 -CC2 -229.360495928343 -0.7171833559 -CCSD -229.3782852538 -0.7349726813 -CC3 -229.4090426487 -0.7657300762 - -MRCC -HF -228.6433125723933699 -MP2 -229.350762954683 -0.7074503823 -CCSD -229.37828519649 -0.734972624097 -CC3 -229.409042619076 -0.7657300467 -CCSDT -229.407644699645 -0.7643321273 -CC4 -229.410178825868 -0.7668662535 - -CISD -229.260645347830 -0.6173327754 -CISDT -229.27741998 -0.6341074076 From ce030db9b3475547cb3a5ab374631b380c62b164 Mon Sep 17 00:00:00 2001 From: 2487 Date: Mon, 2 Nov 2020 20:40:47 +0100 Subject: [PATCH 3/5] update t2 olympe --- benzene/cc-pvdz/benzene.nofci.out | 225 + benzene/cc-pvdz/slurm-485510.out | 17551 ++++++++++++ benzene/cc-pvtz/slurm-486690.out | 42884 ++++++++++++++++++++++++++++ furan/cc-pvtz/furan.fci.out | 122 + furan/cc-pvtz/slurm-485509.out | 34405 ++++++++++++++++++++++ 5 files changed, 95187 insertions(+) diff --git a/benzene/cc-pvdz/benzene.nofci.out b/benzene/cc-pvdz/benzene.nofci.out index 6e5be13..fb0a3b0 100644 --- a/benzene/cc-pvdz/benzene.nofci.out +++ b/benzene/cc-pvdz/benzene.nofci.out @@ -4350,3 +4350,228 @@ Iter Energy S^2 Residual 7 -217.4173118941 0.003264 0.294E-08 8 -217.4173119155 0.003264 0.102E-08 9 -217.4173119231 0.003264 0.414E-09 + 10 -217.4173119262 0.003264 0.169E-09 + 11 -217.4173119274 0.003264 0.673E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 67.879211 GB ] [ VIRT MEM : 84.512684 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 233086.397569 s ] [ CPU TIME: ************** s ] <<<<< .. + + +.. >>>>> [ RES MEM : 25.178658 GB ] [ VIRT MEM : 36.200653 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 233090.634623 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Energy of state 1 -217.4173119274494 +* S^2 of state 1 0.3263588373208825E-02 +* Saved determinants 41833507 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 23.443043 GB ] [ VIRT MEM : 28.219784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 233551.672890 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 41656018 + +.. >>>>> [ RES MEM : 23.443043 GB ] [ VIRT MEM : 28.219784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 233551.763394 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 41656018 +* Number of comb teeth 100 +* pt2_n_tasks_max 870 +* PT2 Energy denominator -217.4173119274494 + +.. >>>>> [ RES MEM : 30.671066 GB ] [ VIRT MEM : 35.457417 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 233584.703959 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 41656018 + +.. >>>>> [ RES MEM : 30.671066 GB ] [ VIRT MEM : 35.457417 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 233584.790267 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 41656018 +* Number of comb teeth 100 +* pt2_n_tasks_max 870 +* Number of tasks 42476564 +* Number of fragmented tasks 11464 +* Number of threads for PT2 72 +* Memory (Gb) 45.20599612168968 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -217.4853677195 0.190E-02 0.6199641937 0.0078838122 3112.8668 + 4 -217.4857937358 0.136E-02 0.6255605610 0.0079273664 3917.4754 + 5 -217.4857142827 0.965E-03 0.6257625479 0.0079157589 4816.8483 + 6 -217.4857151595 0.777E-03 0.6256725196 0.0079189905 5619.1574 + 7 -217.4856149736 0.659E-03 0.6254676511 0.0079010186 6447.8476 + 8 -217.4853215097 0.674E-03 0.6231730188 0.0078671977 7216.2379 + 9 -217.4853424356 0.592E-03 0.6227642412 0.0078783833 7946.2287 + 10 -217.4855940989 0.616E-03 0.6256126525 0.0079008158 8322.0344 + 11 -217.4856544044 0.559E-03 0.6266220966 0.0079055986 8439.0258 + 12 -217.4857253608 0.515E-03 0.6270309359 0.0079141060 9086.5732 + 13 -217.4855402436 0.467E-03 0.6252914247 0.0078959279 9277.8165 + 14 -217.4856695794 0.452E-03 0.6259554818 0.0079138427 9912.5005 + 15 -217.4857545984 0.429E-03 0.6264597257 0.0079262202 10473.1468 + 16 -217.4857352832 0.401E-03 0.6259721834 0.0079278076 10554.5837 + 17 -217.4858998754 0.412E-03 0.6272506409 0.0079477265 10677.8507 + 18 -217.4860038247 0.386E-03 0.6279569904 0.0079629746 11162.4349 + 19 -217.4859594149 0.368E-03 0.6277111598 0.0079567004 11916.1570 + 20 -217.4860073535 0.352E-03 0.6277802630 0.0079664461 12638.4535 + 21 -217.4860263942 0.337E-03 0.6280530368 0.0079674826 12851.8051 + 22 -217.4859950596 0.323E-03 0.6278783110 0.0079622949 12871.0417 + 23 -217.4859920018 0.308E-03 0.6276646625 0.0079643553 13308.8848 + 24 -217.4860311730 0.293E-03 0.6276517040 0.0079735625 13326.4013 + 25 -217.4860385852 0.281E-03 0.6279123613 0.0079725625 13520.5458 + 26 -217.4860619847 0.270E-03 0.6282559865 0.0079738510 13766.9926 + 27 -217.4860797327 0.261E-03 0.6280261470 0.0079797634 14264.4677 + 28 -217.4861230650 0.255E-03 0.6282079006 0.0079854096 14893.4933 + 29 -217.4861172806 0.250E-03 0.6285179596 0.0079800810 15458.3672 + 30 -217.4861645634 0.247E-03 0.6288451800 0.0079854745 15980.5263 + 31 -217.4861596355 0.238E-03 0.6291639882 0.0079812387 16117.9330 + 32 -217.4862116026 0.237E-03 0.6294913198 0.0079881911 16668.0734 + 33 -217.4861727079 0.221E-03 0.6289246789 0.0079861503 17186.6894 + 34 -217.4861918328 0.215E-03 0.6289820809 0.0079906505 17500.3978 + 35 -217.4861963005 0.206E-03 0.6288421266 0.0079928570 17698.9660 + 36 -217.4861548460 0.205E-03 0.6282982365 0.0079893099 17861.7051 + 37 -217.4861222017 0.197E-03 0.6278326709 0.0079877337 18156.3658 + 38 -217.4861148790 0.192E-03 0.6276550067 0.0079880273 18274.8281 + 39 -217.4860840693 0.190E-03 0.6272629112 0.0079853815 18548.6954 + 41 -217.4860961099 0.178E-03 0.6275603745 0.0079851179 18907.6068 + 42 -217.4860713068 0.176E-03 0.6272703663 0.0079829703 19396.8258 + 43 -217.4860701695 0.171E-03 0.6271709526 0.0079842717 19896.7045 + 44 -217.4860749680 0.166E-03 0.6271927971 0.0079851348 20134.6820 + 45 -217.4860846271 0.163E-03 0.6271650428 0.0079876160 20293.5771 + 46 -217.4860815853 0.164E-03 0.6272235998 0.0079865076 20329.9210 + 47 -217.4860275422 0.169E-03 0.6266902223 0.0079810071 20655.7678 + 48 -217.4860243537 0.165E-03 0.6266710475 0.0079802356 20851.3353 + 49 -217.4860612129 0.160E-03 0.6270204113 0.0079842445 21077.6269 + 51 -217.4860360789 0.153E-03 0.6265309226 0.0079843167 21261.7714 + 52 -217.4860221672 0.150E-03 0.6264827709 0.0079825357 21410.8838 + 53 -217.4859745181 0.155E-03 0.6258940106 0.0079789101 21609.3920 + 54 -217.4859712751 0.152E-03 0.6258871404 0.0079785157 21627.6486 + 55 -217.4859784029 0.149E-03 0.6259548560 0.0079793434 21803.9127 + 56 -217.4859419461 0.151E-03 0.6255707314 0.0079756663 22000.2279 + 58 -217.4859230561 0.145E-03 0.6253199274 0.0079743981 22128.0450 + 59 -217.4859113769 0.143E-03 0.6250867909 0.0079742842 22229.7618 + 60 -217.4859206177 0.141E-03 0.6250968861 0.0079758297 22390.6734 + 62 -217.4859413879 0.140E-03 0.6254401179 0.0079770151 22765.9383 + 64 -217.4860130540 0.150E-03 0.6261362522 0.0079846985 22947.0083 + 65 -217.4859823334 0.151E-03 0.6258379992 0.0079814648 22978.7929 + 67 -217.4860086565 0.148E-03 0.6261941342 0.0079830535 23252.7413 + 68 -217.4859872762 0.141E-03 0.6261385027 0.0079786842 23263.3748 + 69 -217.4860051823 0.140E-03 0.6263526453 0.0079801390 23341.3858 + 70 -217.4860064260 0.138E-03 0.6262895771 0.0079806480 23454.1088 + 71 -217.4859978852 0.137E-03 0.6263235859 0.0079789906 23623.1433 + 72 -217.4860104015 0.135E-03 0.6265107669 0.0079794393 23734.0249 + 73 -217.4860176036 0.134E-03 0.6264982167 0.0079806447 23769.0858 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 31.089817 GB ] [ VIRT MEM : 36.379189 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 257512.893219 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 41656018 + +.. >>>>> [ RES MEM : 31.089817 GB ] [ VIRT MEM : 36.379189 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 257512.979578 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 41656018 +* Number of comb teeth 100 +* pt2_n_tasks_max 870 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8995334189716244 + +Summary at N_det = 41833507 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -217.41731193 +# PT2 -0.06870568 0.00013352 +# rPT2 -0.06816170 0.00013246 +# +# E+PT2 -217.48601760 0.00013352 +# E+rPT2 -217.48547363 0.00013246 +# ============ ============================= + + N_det = 41833507 + N_states = 1 + + * State 1 + < S^2 > = 3.263588373208825E-003 + E = -217.417311927449 + Variance = 0.626498216653461 + PT norm = 8.933445389600192E-002 + PT2 = -6.870567618562975E-002 + rPT2 = -6.816170186411555E-002 + E+PT2 = -217.486017603635 +/- 1.335168201144385E-004 + E+rPT2 = -217.485473629314 +/- 1.324597062678874E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 385.277019406018 + Ven = -1315.56057531265 + Vee = 439.444093821300 + Vecp = 0.000000000000000E+000 + T = 273.422150157887 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0705 -217.47903206 + -0.0718 -217.48482525 + -0.0729 -217.48458358 + -0.0738 -217.48428220 + -0.0750 -217.48242926 + -0.0762 -217.48332595 + -0.0786 -217.48490434 + =========== =================== + +* Number of unique beta determinants 6068482 +* Number of unique alpha determinants 6141416 + +.. >>>>> [ RES MEM : 46.204697 GB ] [ VIRT MEM : 61.476562 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 307197.609280 s ] [ CPU TIME: ************** s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 83171337 +* Number of threads for diagonalization 72 +* Memory(Gb) 122.2481629587710 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -217.4165381630 0.003590 0.636E-03 + 2 -217.4205580256 0.003842 0.571E-04 + 3 -217.4207438425 0.003906 0.103E-04 + 4 -217.4207737816 0.003917 0.127E-05 + 5 -217.4207787948 0.003912 0.184E-06 + 6 -217.4207798851 0.003908 0.461E-07 + 7 -217.4207801708 0.003907 0.154E-07 + 8 -217.4207802631 0.003906 0.531E-08 + 9 -217.4207802964 0.003907 0.180E-08 diff --git a/benzene/cc-pvdz/slurm-485510.out b/benzene/cc-pvdz/slurm-485510.out index 50be94f..33aecf3 100644 --- a/benzene/cc-pvdz/slurm-485510.out +++ b/benzene/cc-pvdz/slurm-485510.out @@ -17086,3 +17086,17554 @@ 4.78 % in 3078 seconds 4.87 % in 3219 seconds 4.97 % in 3357 seconds + 5.06 % in 3497 seconds + 5.16 % in 3636 seconds + 5.25 % in 3664 seconds + 5.35 % in 3678 seconds + 5.54 % in 3711 seconds + 5.64 % in 3745 seconds + 5.73 % in 3768 seconds + 5.92 % in 3778 seconds + 6.02 % in 3810 seconds + 6.11 % in 3840 seconds + 6.21 % in 3856 seconds + 6.30 % in 3869 seconds + 6.40 % in 3886 seconds + 6.49 % in 3898 seconds + 6.59 % in 3918 seconds + 6.69 % in 3941 seconds + 6.78 % in 3964 seconds + 6.88 % in 3987 seconds + 6.97 % in 4013 seconds + 7.07 % in 4039 seconds + 7.16 % in 4055 seconds + 7.45 % in 4094 seconds + 7.55 % in 4126 seconds + 7.64 % in 4136 seconds + 7.83 % in 4150 seconds + 7.93 % in 4183 seconds + 8.02 % in 4217 seconds + 8.12 % in 4233 seconds + 8.21 % in 4248 seconds + 8.31 % in 4263 seconds + 8.40 % in 4285 seconds + 8.50 % in 4297 seconds + 8.60 % in 4315 seconds + 8.69 % in 4332 seconds + 8.79 % in 4362 seconds + 8.88 % in 4386 seconds + 8.98 % in 4411 seconds + 9.07 % in 4437 seconds + 9.17 % in 4454 seconds + 9.36 % in 4466 seconds + 9.65 % in 4492 seconds + 9.84 % in 4517 seconds + 9.93 % in 4536 seconds +10.12 % in 4567 seconds +10.22 % in 4584 seconds +10.32 % in 4599 seconds +10.41 % in 4615 seconds +10.51 % in 4637 seconds +10.60 % in 4657 seconds +10.70 % in 4679 seconds +10.79 % in 4701 seconds +10.89 % in 4725 seconds +10.98 % in 4747 seconds +11.27 % in 4758 seconds +11.56 % in 4775 seconds +11.75 % in 4797 seconds +11.84 % in 4817 seconds +11.94 % in 4833 seconds +12.03 % in 4850 seconds +12.13 % in 4869 seconds +12.23 % in 4882 seconds +12.32 % in 4907 seconds +12.42 % in 4925 seconds +12.51 % in 4947 seconds +12.61 % in 4971 seconds +12.70 % in 4994 seconds +12.80 % in 5018 seconds +12.89 % in 5030 seconds +13.18 % in 5040 seconds +13.56 % in 5052 seconds +13.66 % in 5063 seconds +13.75 % in 5073 seconds +13.85 % in 5098 seconds +13.94 % in 5108 seconds +14.04 % in 5133 seconds +14.14 % in 5146 seconds +14.23 % in 5165 seconds +14.33 % in 5187 seconds +14.42 % in 5208 seconds +14.52 % in 5225 seconds +14.61 % in 5246 seconds +14.71 % in 5268 seconds +14.80 % in 5292 seconds +14.90 % in 5315 seconds +15.00 % in 5329 seconds +15.28 % in 5339 seconds +15.66 % in 5352 seconds +15.95 % in 5367 seconds +16.14 % in 5392 seconds +16.24 % in 5419 seconds +16.33 % in 5434 seconds +16.43 % in 5449 seconds +16.52 % in 5469 seconds +16.62 % in 5484 seconds +16.71 % in 5508 seconds +16.81 % in 5533 seconds +16.91 % in 5555 seconds +17.00 % in 5575 seconds +17.29 % in 5585 seconds +17.67 % in 5598 seconds +17.96 % in 5608 seconds +18.05 % in 5618 seconds +18.15 % in 5632 seconds +18.34 % in 5661 seconds +18.43 % in 5687 seconds +18.53 % in 5704 seconds +18.62 % in 5720 seconds +18.72 % in 5737 seconds +18.82 % in 5763 seconds +18.91 % in 5783 seconds +19.01 % in 5805 seconds +19.10 % in 5829 seconds +19.39 % in 5840 seconds +19.68 % in 5850 seconds +19.96 % in 5860 seconds +20.25 % in 5871 seconds +20.34 % in 5890 seconds +20.44 % in 5902 seconds +20.53 % in 5918 seconds +20.63 % in 5931 seconds +20.73 % in 5946 seconds +20.82 % in 5966 seconds +20.92 % in 5984 seconds +21.01 % in 6003 seconds +21.11 % in 6026 seconds +21.20 % in 6049 seconds +21.30 % in 6064 seconds +21.68 % in 6076 seconds +21.97 % in 6086 seconds +22.25 % in 6097 seconds +22.45 % in 6110 seconds +22.64 % in 6141 seconds +22.73 % in 6155 seconds +22.83 % in 6174 seconds +22.92 % in 6189 seconds +23.02 % in 6206 seconds +23.11 % in 6227 seconds +23.21 % in 6246 seconds +23.30 % in 6268 seconds +23.40 % in 6290 seconds +23.50 % in 6314 seconds +23.78 % in 6324 seconds +24.07 % in 6334 seconds +24.36 % in 6344 seconds +24.64 % in 6355 seconds +24.93 % in 6376 seconds +25.02 % in 6396 seconds +25.12 % in 6410 seconds +25.21 % in 6426 seconds +25.31 % in 6446 seconds +25.41 % in 6462 seconds +25.50 % in 6487 seconds +25.60 % in 6506 seconds +25.69 % in 6528 seconds +25.79 % in 6551 seconds +25.88 % in 6564 seconds +26.17 % in 6575 seconds +26.55 % in 6588 seconds +26.84 % in 6599 seconds +27.13 % in 6609 seconds +27.32 % in 6622 seconds +27.51 % in 6654 seconds +27.60 % in 6666 seconds +27.70 % in 6684 seconds +27.79 % in 6699 seconds +27.89 % in 6715 seconds +27.98 % in 6737 seconds +28.08 % in 6758 seconds +28.18 % in 6781 seconds +28.27 % in 6802 seconds +28.46 % in 6813 seconds +28.75 % in 6823 seconds +29.04 % in 6834 seconds +29.32 % in 6845 seconds +29.61 % in 6856 seconds +29.89 % in 6867 seconds +29.99 % in 6883 seconds +30.09 % in 6898 seconds +30.18 % in 6916 seconds +30.28 % in 6933 seconds +30.37 % in 6952 seconds +30.47 % in 6967 seconds +30.56 % in 6987 seconds +30.66 % in 7009 seconds +30.75 % in 7029 seconds +30.85 % in 7054 seconds +30.95 % in 7071 seconds +31.23 % in 7082 seconds +31.61 % in 7095 seconds +31.90 % in 7105 seconds +32.19 % in 7116 seconds +32.47 % in 7128 seconds +32.66 % in 7151 seconds +32.76 % in 7165 seconds +32.86 % in 7178 seconds +32.95 % in 7191 seconds +33.05 % in 7211 seconds +33.14 % in 7231 seconds +33.24 % in 7252 seconds +33.33 % in 7275 seconds +33.43 % in 7297 seconds +33.52 % in 7307 seconds +33.81 % in 7317 seconds +34.19 % in 7329 seconds +34.48 % in 7339 seconds +34.77 % in 7351 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seconds +13.59 % in 257077 seconds +13.59 % in 257089 seconds +13.59 % in 257110 seconds + + unset COMMAND ++ qp run save_natorb ++ case $1 in ++ which qp_run ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' benzene +++ qp_run save_natorb benzene ++ unset COMMAND ++ qp set determinants n_det_max 1e8 ++ case $1 in ++ ezfio set determinants n_det_max 1e8 ++ case $1 in ++ shift ++ _ezfio_set determinants n_det_max 1e8 ++ _require_ezfio_file ++ [[ -z benzene ]] ++ [[ ! -d benzene ]] ++ _require_first_argument determinants n_det_max 1e8 ++ [[ -z determinants ]] ++ return 0 ++ _require_second_argument determinants n_det_max 1e8 ++ [[ -z n_det_max ]] ++ [[ -z 1e8 ]] ++ echo 1e8 ++ _ezfio_py set determinants n_det_max ++ python2 /tmpdir/loos/qp2/external/ezfio/Python/ezfio.py set determinants n_det_max ++ return 0 ++ qp run fci ++ case $1 in ++ which qp_run ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' benzene +++ qp_run fci benzene + 0.00 % in 4 seconds +22.57 % in 14 seconds +33.67 % in 24 seconds +39.76 % in 34 seconds +47.49 % in 44 seconds +54.81 % in 54 seconds +61.70 % in 64 seconds +68.33 % in 74 seconds +74.31 % in 84 seconds +80.20 % in 94 seconds +85.96 % in 104 seconds +90.73 % in 114 seconds +96.61 % in 124 seconds + 50.00 % in 23 seconds + 16.67 % in 11 seconds + 9.09 % in 11 seconds + 4.76 % in 12 seconds + 2.44 % in 13 seconds + 1.23 % in 20 seconds +88.89 % in 32 seconds + 0.62 % in 20 seconds +44.10 % in 31 seconds +44.72 % in 41 seconds +89.44 % in 53 seconds + 0.31 % in 20 seconds +22.12 % in 40 seconds +44.55 % in 61 seconds +66.98 % in 82 seconds +89.41 % in 96 seconds + 0.16 % in 20 seconds +11.08 % in 43 seconds +22.15 % in 57 seconds +26.37 % in 67 seconds +33.39 % in 78 seconds +35.73 % in 88 seconds +44.62 % in 100 seconds +50.55 % in 110 seconds +55.85 % in 122 seconds +63.18 % in 132 seconds +67.08 % in 142 seconds +73.48 % in 152 seconds +78.32 % in 163 seconds +85.18 % in 173 seconds +89.70 % in 187 seconds + 0.08 % in 18 seconds + 4.76 % in 28 seconds + 5.54 % in 41 seconds + 9.60 % in 51 seconds +11.16 % in 61 seconds +14.21 % in 71 seconds +16.78 % in 81 seconds +19.05 % in 91 seconds +21.78 % in 101 seconds +25.76 % in 111 seconds + 0.04 % in 18 seconds + 2.15 % in 28 seconds + 2.81 % in 39 seconds + 4.76 % in 49 seconds + 5.43 % in 59 seconds + 6.05 % in 69 seconds + 8.12 % in 79 seconds + 8.28 % in 90 seconds +10.66 % in 100 seconds +10.93 % in 110 seconds +13.12 % in 122 seconds +13.59 % in 132 seconds +15.70 % in 142 seconds +16.13 % in 152 seconds +18.04 % in 162 seconds +18.78 % in 173 seconds +20.81 % in 183 seconds + 0.02 % in 19 seconds + 0.80 % in 29 seconds + 1.29 % in 39 seconds + 1.64 % in 49 seconds + 2.44 % in 59 seconds + 3.07 % in 70 seconds + 3.26 % in 80 seconds + 4.39 % in 90 seconds + 4.69 % in 100 seconds + 4.80 % in 110 seconds + 6.09 % in 121 seconds + 6.25 % in 135 seconds + 7.40 % in 145 seconds + 7.65 % in 155 seconds + 8.14 % in 165 seconds + 9.04 % in 175 seconds + 9.28 % in 188 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99 seconds +23.53 % in 110 seconds +29.41 % in 122 seconds +35.29 % in 133 seconds +41.18 % in 144 seconds +47.06 % in 155 seconds +52.94 % in 165 seconds +58.82 % in 175 seconds +64.71 % in 187 seconds +70.59 % in 198 seconds +76.47 % in 210 seconds +82.35 % in 224 seconds +88.24 % in 237 seconds +94.12 % in 250 seconds + 2.94 % in 9 seconds + 5.88 % in 24 seconds +11.76 % in 41 seconds +14.71 % in 60 seconds +17.65 % in 80 seconds +20.59 % in 101 seconds +23.53 % in 111 seconds +29.41 % in 124 seconds +35.29 % in 135 seconds +41.18 % in 146 seconds +47.06 % in 156 seconds +52.94 % in 166 seconds +58.82 % in 176 seconds +64.71 % in 187 seconds +70.59 % in 199 seconds +76.47 % in 210 seconds +82.35 % in 224 seconds +88.24 % in 238 seconds +94.12 % in 250 seconds + 2.94 % in 8 seconds + 5.88 % in 25 seconds +11.76 % in 40 seconds +14.71 % in 60 seconds +17.65 % in 80 seconds +20.59 % in 101 seconds +23.53 % in 111 seconds +29.41 % in 124 seconds +35.29 % in 135 seconds +41.18 % in 145 seconds +47.06 % in 156 seconds +52.94 % in 166 seconds +58.82 % in 176 seconds +64.71 % in 187 seconds +70.59 % in 199 seconds +76.47 % in 211 seconds +82.35 % in 225 seconds +88.24 % in 238 seconds +94.12 % in 251 seconds + 2.94 % in 9 seconds + 5.88 % in 24 seconds +11.76 % in 39 seconds +14.71 % in 58 seconds +17.65 % in 78 seconds +20.59 % in 99 seconds +23.53 % in 109 seconds +29.41 % in 122 seconds +35.29 % in 134 seconds +41.18 % in 144 seconds +47.06 % in 154 seconds +52.94 % in 164 seconds +58.82 % in 175 seconds +64.71 % in 186 seconds +70.59 % in 199 seconds +76.47 % in 211 seconds +82.35 % in 225 seconds +88.24 % in 239 seconds +94.12 % in 251 seconds + 2.94 % in 10 seconds + 5.88 % in 26 seconds +11.76 % in 40 seconds +14.71 % in 60 seconds +17.65 % in 81 seconds +20.59 % in 100 seconds +23.53 % in 110 seconds +29.41 % in 122 seconds +35.29 % in 133 seconds +41.18 % in 143 seconds +47.06 % in 154 seconds +52.94 % in 165 seconds +58.82 % in 175 seconds +64.71 % in 186 seconds +70.59 % in 198 seconds +76.47 % in 210 seconds +82.35 % in 223 seconds +88.24 % in 238 seconds +94.12 % in 251 seconds + 2.94 % in 9 seconds + 5.88 % in 24 seconds +11.76 % in 39 seconds +14.71 % in 59 seconds +17.65 % in 78 seconds +20.59 % in 100 seconds +23.53 % in 110 seconds +29.41 % in 123 seconds +35.29 % in 134 seconds +41.18 % in 145 seconds +47.06 % in 155 seconds +52.94 % in 166 seconds +58.82 % in 176 seconds +64.71 % in 187 seconds +70.59 % in 199 seconds +76.47 % in 211 seconds +82.35 % in 225 seconds +88.24 % in 238 seconds +94.12 % in 251 seconds + 2.94 % in 9 seconds + 5.88 % in 24 seconds +11.76 % in 39 seconds +14.71 % in 59 seconds +17.65 % in 79 seconds +20.59 % in 99 seconds +23.53 % in 110 seconds +29.41 % in 122 seconds +35.29 % in 134 seconds +41.18 % in 145 seconds +47.06 % in 155 seconds +52.94 % in 165 seconds +58.82 % in 176 seconds +64.71 % in 187 seconds +70.59 % in 199 seconds +76.47 % in 210 seconds +82.35 % in 225 seconds +88.24 % in 239 seconds +94.12 % in 251 seconds + 2.94 % in 8 seconds + 5.88 % in 24 seconds +11.76 % in 39 seconds +14.71 % in 59 seconds +17.65 % in 79 seconds diff --git a/furan/cc-pvtz/furan.fci.out b/furan/cc-pvtz/furan.fci.out index 413e802..0061ab5 100644 --- a/furan/cc-pvtz/furan.fci.out +++ b/furan/cc-pvtz/furan.fci.out @@ -4018,3 +4018,125 @@ Iter Energy S^2 Residual 89 -229.5932737492 0.344E-03 1.0723408636 0.0202533844 57863.6245 91 -229.5932937164 0.337E-03 1.0723997899 0.0202572053 58401.4889 92 -229.5933275137 0.335E-03 1.0725988471 0.0202622625 59550.8759 + 94 -229.5932895963 0.329E-03 1.0717614467 0.0202627483 60592.6484 + 97 -229.5932543155 0.320E-03 1.0718276440 0.0202573025 62587.6969 + 104 -229.5930974387 0.304E-03 1.0701064023 0.0202441570 64162.5389 + 105 -229.5930624264 0.303E-03 1.0696836286 0.0202414126 64557.2191 + 109 -229.5929911112 0.295E-03 1.0688737807 0.0202331719 64848.9272 + 110 -229.5930015554 0.292E-03 1.0688095471 0.0202364751 65603.0269 + 111 -229.5930574564 0.295E-03 1.0694200502 0.0202428055 65868.3633 + 112 -229.5930889602 0.294E-03 1.0695838234 0.0202471578 66053.0479 + 113 -229.5931001754 0.292E-03 1.0697781424 0.0202466421 68121.0142 + 116 -229.5932131172 0.294E-03 1.0709311550 0.0202600762 68304.5601 + 118 -229.5931165916 0.297E-03 1.0699880192 0.0202472013 68343.3189 + 119 -229.5930881971 0.296E-03 1.0694929140 0.0202461471 68641.1378 + 120 -229.5931123087 0.287E-03 1.0699371651 0.0202428183 69276.1715 + 121 -229.5931099457 0.285E-03 1.0699824386 0.0202409578 69359.0295 + 122 -229.5930172246 0.297E-03 1.0691103838 0.0202285153 71194.5244 + 123 -229.5931324959 0.317E-03 1.0703331612 0.0202410801 72807.1707 + 128 -229.5931714881 0.311E-03 1.0710402816 0.0202449912 73229.7515 + 129 -229.5932061182 0.311E-03 1.0714690147 0.0202466378 73435.0964 + 130 -229.5931883496 0.309E-03 1.0711911884 0.0202445849 73589.2588 + 131 -229.5932040221 0.307E-03 1.0712044389 0.0202475357 74160.5929 + 132 -229.5931936221 0.305E-03 1.0711364955 0.0202459136 74215.7865 + 133 -229.5931862724 0.303E-03 1.0709808179 0.0202460811 74442.4799 + 134 -229.5931482062 0.303E-03 1.0704543318 0.0202430361 74998.6902 + 135 -229.5931248430 0.301E-03 1.0703481852 0.0202386779 75191.2029 + 136 -229.5931644007 0.302E-03 1.0706194330 0.0202450850 75808.4738 + 137 -229.5931401817 0.300E-03 1.0702364077 0.0202440874 76316.6385 + 138 -229.5932089606 0.302E-03 1.0710654783 0.0202511508 77304.9392 + 141 -229.5931825412 0.296E-03 1.0708327084 0.0202494728 77780.0351 + 142 -229.5931992059 0.294E-03 1.0708084628 0.0202538914 78194.0608 + 143 -229.5931841614 0.293E-03 1.0705573815 0.0202539811 79237.5683 + 145 -229.5931640136 0.289E-03 1.0702751475 0.0202512933 79254.0473 + 146 -229.5931739727 0.288E-03 1.0705762962 0.0202504750 79714.4618 + 147 -229.5931462074 0.287E-03 1.0702481090 0.0202472199 80142.3050 + 148 -229.5931716526 0.286E-03 1.0704851787 0.0202498872 80637.5013 + 149 -229.5931739785 0.284E-03 1.0705459320 0.0202492323 81190.4288 + 151 -229.5931597274 0.281E-03 1.0703870609 0.0202472561 83121.2068 + 154 -229.5931090938 0.277E-03 1.0697289010 0.0202445576 83390.8408 + 155 -229.5930988231 0.275E-03 1.0695045039 0.0202453331 84030.8974 + 156 -229.5930808189 0.271E-03 1.0693595424 0.0202440996 84356.1901 + 157 -229.5930886523 0.269E-03 1.0693447066 0.0202459658 84662.0666 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 23.536201 GB ] [ VIRT MEM : 27.610054 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 281339.682630 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 10485644 + +.. >>>>> [ RES MEM : 23.536201 GB ] [ VIRT MEM : 27.610054 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 281339.705640 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 10485644 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +Summary at N_det = 10485760 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.45768991 +# PT2 -0.13539874 0.00026900 +# rPT2 -0.13271186 0.00026366 +# +# E+PT2 -229.59308865 0.00026900 +# E+rPT2 -229.59040177 0.00026366 +# ============ ============================= + + N_det = 10485760 + N_states = 1 + + * State 1 + < S^2 > = 3.885695262140281E-003 + E = -229.457689910376 + Variance = 1.06934470661111 + PT norm = 0.142288319185474 + PT2 = -0.135398741913064 + rPT2 = -0.132711862094937 + E+PT2 = -229.593088652289 +/- 2.690014497441929E-004 + E+rPT2 = -229.590401772471 +/- 2.636633309688461E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.365817979737 + Vee = 238.637505330097 + Vecp = 0.000000000000000E+000 + T = 229.162392960475 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1358 -229.59952563 + -0.1384 -229.63518667 + -0.1430 -229.63894032 + -0.1658 -229.61615717 + -0.2102 -229.61275472 + -0.2699 -229.61273101 + -0.3355 -229.61436759 + =========== =================== + +Wall time: 78:10:38 + diff --git a/furan/cc-pvtz/slurm-485509.out b/furan/cc-pvtz/slurm-485509.out index 5cbf057..d5efa61 100644 --- a/furan/cc-pvtz/slurm-485509.out +++ b/furan/cc-pvtz/slurm-485509.out @@ -21374,3 +21374,34408 @@ 6.74 % in 60294 seconds 6.74 % in 60306 seconds 6.74 % in 60320 seconds + 6.74 % in 60339 seconds + 6.74 % in 60352 seconds + 6.74 % in 60364 seconds + 6.74 % in 60375 seconds + 6.74 % in 60389 seconds + 6.74 % in 60402 seconds + 6.74 % in 60413 seconds + 6.74 % in 60423 seconds + 6.75 % in 60433 seconds + 6.75 % in 60443 seconds + 6.75 % in 60454 seconds + 6.75 % in 60465 seconds + 6.75 % in 60475 seconds + 6.75 % in 60485 seconds + 6.75 % in 60495 seconds + 6.75 % in 60505 seconds + 6.75 % in 60515 seconds + 6.75 % in 60525 seconds + 6.76 % in 60536 seconds + 6.76 % in 60546 seconds + 6.76 % in 60558 seconds + 6.76 % in 60568 seconds + 6.76 % in 60582 seconds + 6.76 % in 60592 seconds + 6.76 % in 60602 seconds + 6.76 % in 60612 seconds + 6.76 % in 60622 seconds + 6.76 % in 60636 seconds + 6.76 % in 60646 seconds + 6.76 % in 60657 seconds + 6.76 % in 60667 seconds + 6.76 % in 60677 seconds + 6.76 % in 60688 seconds + 6.77 % in 60698 seconds + 6.77 % in 60709 seconds + 6.77 % in 60720 seconds + 6.77 % in 60730 seconds + 6.77 % in 60740 seconds + 6.77 % in 60750 seconds + 6.77 % in 60760 seconds + 6.77 % in 60773 seconds + 6.77 % in 60783 seconds + 6.77 % in 60793 seconds + 6.77 % in 60803 seconds + 6.77 % in 60813 seconds + 6.78 % in 60824 seconds + 6.78 % in 60835 seconds + 6.78 % in 60846 seconds + 6.78 % in 60856 seconds + 6.78 % in 60867 seconds + 6.78 % in 60877 seconds + 6.78 % in 60887 seconds + 6.78 % in 60899 seconds + 6.79 % in 60909 seconds + 6.79 % in 60919 seconds + 6.79 % in 60929 seconds + 6.79 % in 60939 seconds + 6.79 % in 60949 seconds + 6.79 % in 60959 seconds + 6.80 % in 60969 seconds + 6.80 % in 60979 seconds + 6.80 % in 60989 seconds + 6.80 % in 60999 seconds + 6.80 % in 61009 seconds + 6.81 % in 61019 seconds + 6.81 % in 61029 seconds + 6.81 % in 61039 seconds + 6.81 % in 61050 seconds + 6.81 % in 61061 seconds + 6.81 % in 61079 seconds + 6.81 % in 61093 seconds + 6.81 % in 61111 seconds + 6.81 % in 61123 seconds + 6.81 % in 61133 seconds + 6.81 % in 61144 seconds + 6.81 % in 61159 seconds + 6.81 % in 61169 seconds + 6.81 % in 61179 seconds + 6.81 % in 61189 seconds + 6.81 % in 61199 seconds + 6.81 % in 61209 seconds + 6.81 % in 61219 seconds + 6.81 % in 61230 seconds + 6.81 % in 61240 seconds + 6.81 % in 61251 seconds + 6.82 % in 61261 seconds + 6.82 % in 61271 seconds + 6.82 % in 61281 seconds + 6.82 % in 61291 seconds + 6.82 % in 61301 seconds + 6.82 % in 61312 seconds + 6.82 % in 61323 seconds + 6.82 % in 61333 seconds + 6.83 % in 61343 seconds + 6.83 % in 61354 seconds + 6.83 % in 61364 seconds + 6.83 % in 61376 seconds + 6.83 % in 61386 seconds + 6.83 % in 61405 seconds + 6.83 % in 61417 seconds + 6.83 % in 61428 seconds + 6.83 % in 61438 seconds + 6.83 % in 61449 seconds + 6.83 % in 61459 seconds + 6.83 % in 61469 seconds + 6.83 % in 61480 seconds + 6.83 % in 61492 seconds + 6.83 % in 61502 seconds + 6.83 % in 61512 seconds + 6.83 % in 61522 seconds + 6.84 % in 61533 seconds + 6.84 % in 61543 seconds + 6.84 % in 61553 seconds + 6.84 % in 61566 seconds + 6.84 % in 61578 seconds + 6.84 % in 61590 seconds + 6.84 % in 61600 seconds + 6.84 % in 61610 seconds + 6.84 % in 61620 seconds + 6.84 % in 61630 seconds + 6.84 % in 61641 seconds + 6.85 % in 61651 seconds + 6.85 % in 61661 seconds + 6.85 % in 61671 seconds + 6.85 % in 61682 seconds + 6.85 % in 61694 seconds + 6.85 % in 61704 seconds + 6.85 % in 61715 seconds + 6.85 % in 61725 seconds + 6.86 % in 61735 seconds + 6.86 % in 61745 seconds + 6.86 % in 61755 seconds + 6.86 % in 61765 seconds + 6.86 % in 61775 seconds + 6.86 % in 61785 seconds + 6.87 % in 61795 seconds + 6.87 % in 61805 seconds + 6.87 % in 61816 seconds + 6.87 % in 61826 seconds + 6.87 % in 61837 seconds + 6.88 % in 61848 seconds + 6.88 % in 61858 seconds + 6.88 % in 61868 seconds + 6.88 % in 61878 seconds + 6.88 % in 61889 seconds + 6.88 % in 61899 seconds + 6.89 % in 61909 seconds + 6.89 % in 61920 seconds + 6.89 % in 61932 seconds + 6.89 % in 61945 seconds + 6.90 % in 61955 seconds + 6.90 % in 61965 seconds + 6.90 % in 61975 seconds + 6.90 % in 61985 seconds + 6.90 % in 61995 seconds + 6.91 % in 62005 seconds + 6.91 % in 62015 seconds + 6.91 % in 62025 seconds + 6.91 % in 62035 seconds + 6.91 % in 62045 seconds + 6.91 % in 62070 seconds + 6.92 % in 62102 seconds + 6.92 % in 62128 seconds + 6.92 % in 62138 seconds + 6.92 % in 62149 seconds + 6.92 % in 62160 seconds + 6.92 % in 62171 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9.21 % in 84050 seconds + 9.21 % in 84060 seconds + 9.21 % in 84070 seconds + 9.21 % in 84080 seconds + 9.21 % in 84090 seconds + 9.22 % in 84100 seconds + 9.22 % in 84110 seconds + 9.22 % in 84120 seconds + 9.22 % in 84131 seconds + 9.22 % in 84142 seconds + 9.23 % in 84152 seconds + 9.23 % in 84162 seconds + 9.23 % in 84172 seconds + 9.23 % in 84183 seconds + 9.23 % in 84193 seconds + 9.24 % in 84203 seconds + 9.24 % in 84213 seconds + 9.24 % in 84225 seconds + 9.24 % in 84237 seconds + 9.24 % in 84249 seconds + 9.24 % in 84261 seconds + 9.24 % in 84271 seconds + 9.24 % in 84282 seconds + 9.24 % in 84293 seconds + 9.24 % in 84308 seconds + 9.24 % in 84320 seconds + 9.24 % in 84335 seconds + 9.24 % in 84346 seconds + 9.24 % in 84356 seconds + 9.24 % in 84366 seconds + 9.24 % in 84376 seconds + 9.25 % in 84388 seconds + 9.25 % in 84430 seconds + 9.25 % in 84447 seconds + 9.25 % in 84459 seconds + 9.25 % in 84478 seconds + 9.25 % in 84490 seconds + 9.25 % in 84508 seconds + 9.25 % in 84520 seconds + 9.25 % in 84533 seconds + 9.25 % in 84543 seconds + 9.25 % in 84570 seconds + 9.25 % in 84687 seconds + 9.25 % in 84699 seconds + + unset COMMAND ++ qp run save_natorb ++ case $1 in ++ which qp_run ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' furan +++ qp_run save_natorb furan ++ unset COMMAND ++ qp set determinants n_det_max 1e8 ++ case $1 in ++ ezfio set determinants n_det_max 1e8 ++ case $1 in ++ shift ++ _ezfio_set determinants n_det_max 1e8 ++ _require_ezfio_file ++ [[ -z furan ]] ++ [[ ! -d furan ]] ++ _require_first_argument determinants n_det_max 1e8 ++ [[ -z determinants ]] ++ return 0 ++ _require_second_argument determinants n_det_max 1e8 ++ [[ -z n_det_max ]] ++ [[ -z 1e8 ]] ++ echo 1e8 ++ _ezfio_py set determinants n_det_max ++ python2 /tmpdir/loos/qp2/external/ezfio/Python/ezfio.py set determinants n_det_max ++ return 0 ++ qp run fci ++ case $1 in ++ which qp_run ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' furan +++ qp_run fci furan + 0.00 % in 1 seconds +40.86 % in 11 seconds +65.59 % in 21 seconds +87.43 % in 31 seconds + 50.00 % in 7 seconds + 16.67 % in 3 seconds + 9.09 % in 4 seconds + 4.76 % in 4 seconds + 2.44 % in 4 seconds + 1.23 % in 5 seconds + 0.62 % in 5 seconds +91.30 % in 15 seconds + 0.31 % in 6 seconds +43.61 % in 16 seconds +82.55 % in 26 seconds + 0.16 % in 4 seconds +16.07 % in 14 seconds +33.70 % in 24 seconds +53.35 % in 34 seconds +73.17 % in 44 seconds +93.92 % in 54 seconds + 0.08 % in 6 seconds +10.07 % in 16 seconds +17.02 % in 26 seconds +26.78 % in 36 seconds + 0.04 % in 5 seconds + 3.01 % in 15 seconds + 7.85 % in 25 seconds +11.44 % in 35 seconds +15.03 % in 45 seconds +20.19 % in 55 seconds +23.70 % in 65 seconds + 0.02 % in 6 seconds + 1.27 % in 16 seconds + 2.89 % in 26 seconds + 4.76 % in 36 seconds + 6.56 % in 46 seconds + 8.38 % in 56 seconds +10.23 % in 66 seconds +12.24 % in 76 seconds +14.53 % in 86 seconds +16.44 % in 96 seconds +18.75 % in 106 seconds +20.87 % in 116 seconds +22.28 % in 126 seconds + 0.01 % in 7 seconds + 0.70 % in 17 seconds + 1.68 % in 27 seconds + 2.44 % in 37 seconds + 3.51 % in 47 seconds + 4.38 % in 57 seconds + 5.33 % in 67 seconds + 6.18 % in 77 seconds + 7.20 % in 87 seconds + 8.10 % in 97 seconds + 9.18 % in 107 seconds +10.13 % in 117 seconds +10.99 % in 127 seconds +11.28 % in 137 seconds + 0.00 % in 6 seconds + 0.33 % in 16 seconds + 0.80 % in 26 seconds + 1.05 % in 36 seconds + 1.56 % in 46 seconds + 2.01 % in 56 seconds + 2.41 % in 66 seconds + 2.79 % in 76 seconds + 3.35 % in 86 seconds + 3.74 % in 96 seconds + 4.13 % in 106 seconds + 4.59 % in 116 seconds + 5.07 % in 126 seconds + 5.48 % in 136 seconds + 5.92 % in 146 seconds + 6.43 % in 156 seconds + 6.86 % in 167 seconds + 7.32 % in 177 seconds + 7.70 % in 187 seconds + 8.06 % in 197 seconds + 8.59 % in 207 seconds + 9.03 % in 217 seconds + 9.29 % in 227 seconds + 9.37 % in 240 seconds + 9.40 % in 250 seconds + 0.00 % in 3 seconds + 0.12 % in 13 seconds + 0.36 % in 23 seconds + 0.45 % in 33 seconds + 0.66 % in 43 seconds + 0.89 % in 54 seconds + 1.00 % in 64 seconds + 1.36 % in 74 seconds + 1.53 % in 84 seconds + 1.74 % in 94 seconds + 2.02 % in 104 seconds + 2.18 % in 114 seconds + 2.43 % in 124 seconds + 2.71 % in 134 seconds + 2.89 % in 144 seconds + 3.08 % in 154 seconds + 3.36 % in 164 seconds + 3.58 % in 174 seconds + 3.82 % in 184 seconds + 4.07 % in 194 seconds + 4.28 % in 205 seconds + 4.57 % in 215 seconds + 4.84 % in 227 seconds + 5.04 % in 237 seconds + 5.29 % in 247 seconds + 5.54 % in 258 seconds + 5.73 % in 268 seconds + 0.00 % in 4 seconds + 0.06 % in 15 seconds + 0.17 % in 25 seconds + 0.29 % in 35 seconds + 0.35 % in 45 seconds + 0.40 % in 55 seconds + 0.54 % in 66 seconds + 0.67 % in 76 seconds + 0.76 % in 87 seconds + 0.89 % in 97 seconds + 1.04 % in 107 seconds + 1.14 % in 117 seconds + 1.24 % in 127 seconds + 1.37 % in 137 seconds + 1.49 % in 147 seconds + 1.56 % in 157 seconds + 1.71 % in 167 seconds + 1.87 % in 178 seconds + 1.96 % in 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7.17 % in 619 seconds + 7.19 % in 648 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 16.67 % in 0 seconds + 16.67 % in 1 seconds + 16.67 % in 0 seconds + 16.67 % in 1 seconds + 16.67 % in 0 seconds + 16.67 % in 1 seconds + 0.00 % in 5 seconds + 0.03 % in 15 seconds + 0.07 % in 25 seconds + 0.09 % in 35 seconds + 0.16 % in 45 seconds + 0.21 % in 55 seconds + 0.27 % in 65 seconds + 0.32 % in 75 seconds + 0.33 % in 85 seconds + 0.40 % in 95 seconds + 0.45 % in 105 seconds + 0.51 % in 116 seconds + 0.56 % in 126 seconds + 0.64 % in 137 seconds + 0.68 % in 147 seconds + 0.75 % in 158 seconds + 0.85 % in 168 seconds + 0.88 % in 178 seconds + 0.94 % in 189 seconds + 0.98 % in 199 seconds + 1.05 % in 209 seconds + 1.11 % in 219 seconds + 1.17 % in 229 seconds + 1.25 % in 239 seconds + 1.32 % in 249 seconds + 1.38 % in 259 seconds + 1.46 % in 269 seconds + 1.52 % in 279 seconds + 1.58 % in 289 seconds + 1.66 % in 299 seconds + 1.71 % in 310 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in 739 seconds + 4.64 % in 749 seconds + 4.70 % in 760 seconds + 4.78 % in 770 seconds + 4.84 % in 781 seconds + 4.89 % in 791 seconds + 4.98 % in 801 seconds + 5.08 % in 811 seconds + 5.13 % in 821 seconds + 5.17 % in 831 seconds + 5.25 % in 841 seconds + 5.32 % in 852 seconds + 5.38 % in 862 seconds + 5.46 % in 872 seconds + 5.52 % in 882 seconds + 5.60 % in 892 seconds + 5.63 % in 902 seconds + 5.69 % in 912 seconds + 5.77 % in 922 seconds + 5.82 % in 932 seconds + 5.90 % in 942 seconds + 5.95 % in 952 seconds + 6.03 % in 962 seconds + 6.10 % in 972 seconds + 6.18 % in 982 seconds + 6.22 % in 992 seconds + 6.29 % in 1002 seconds + 6.37 % in 1012 seconds + 6.43 % in 1022 seconds + 6.49 % in 1033 seconds + 6.53 % in 1043 seconds + 6.61 % in 1053 seconds + 6.66 % in 1063 seconds + 6.72 % in 1073 seconds + 6.78 % in 1083 seconds + 6.84 % in 1093 seconds + 6.94 % in 1103 seconds + 7.00 % in 1113 seconds + 7.05 % in 1123 seconds + 7.09 % in 1133 seconds + 7.15 % in 1144 seconds + 7.22 % 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16453 seconds +40.38 % in 16464 seconds +40.57 % in 16475 seconds +40.76 % in 16485 seconds +40.95 % in 16495 seconds +41.14 % in 16506 seconds +41.33 % in 16516 seconds +41.52 % in 16527 seconds +41.71 % in 16539 seconds +41.81 % in 16552 seconds +41.90 % in 16602 seconds +42.00 % in 16655 seconds +42.10 % in 16705 seconds +42.19 % in 16755 seconds +42.29 % in 16816 seconds +42.38 % in 16848 seconds +42.57 % in 16865 seconds +42.76 % in 16877 seconds +42.95 % in 16888 seconds +43.14 % in 16899 seconds +43.33 % in 16910 seconds +43.52 % in 16920 seconds +43.71 % in 16932 seconds +43.90 % in 16945 seconds +44.10 % in 16957 seconds +44.29 % in 16996 seconds From 4e38eaeed2b69092b6852ac5bad5afa1d8683b36 Mon Sep 17 00:00:00 2001 From: 2487 Date: Tue, 3 Nov 2020 09:25:08 +0100 Subject: [PATCH 4/5] update t2 --- benzene/cc-pvdz/benzene.nofci.out | 1 + benzene/cc-pvdz/slurm-485510.out | 1333 +++++++++ benzene/cc-pvtz/slurm-486690.out | 3915 ++++++++++++++++++++++++ furan/cc-pvtz/furan.natorb.out | 369 +++ furan/cc-pvtz/furan.nofci.out | 4568 +++++++++++++++++++++++++++++ furan/cc-pvtz/slurm-485509.out | 1202 ++++++++ 6 files changed, 11388 insertions(+) create mode 100644 furan/cc-pvtz/furan.natorb.out create mode 100644 furan/cc-pvtz/furan.nofci.out diff --git a/benzene/cc-pvdz/benzene.nofci.out b/benzene/cc-pvdz/benzene.nofci.out index fb0a3b0..241164a 100644 --- a/benzene/cc-pvdz/benzene.nofci.out +++ b/benzene/cc-pvdz/benzene.nofci.out @@ -4575,3 +4575,4 @@ Iter Energy S^2 Residual 7 -217.4207801708 0.003907 0.154E-07 8 -217.4207802631 0.003906 0.531E-08 9 -217.4207802964 0.003907 0.180E-08 + 10 -217.4207803092 0.003907 0.703E-09 diff --git a/benzene/cc-pvdz/slurm-485510.out b/benzene/cc-pvdz/slurm-485510.out index 33aecf3..e59f535 100644 --- a/benzene/cc-pvdz/slurm-485510.out +++ b/benzene/cc-pvdz/slurm-485510.out @@ -34637,3 +34637,1336 @@ 14.13 % in 20631 seconds 14.18 % in 20684 seconds 14.22 % in 20728 seconds +14.27 % in 20770 seconds 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15654 seconds + 4.07 % in 15664 seconds + 4.08 % in 15674 seconds + 4.08 % in 15687 seconds + 4.09 % in 15698 seconds + 4.09 % in 15708 seconds + 4.10 % in 15718 seconds + 4.10 % in 15728 seconds + 4.11 % in 15738 seconds + 4.12 % in 15748 seconds + 4.12 % in 15759 seconds + 4.13 % in 15769 seconds + 4.13 % in 15779 seconds + 4.14 % in 15789 seconds + 4.15 % in 15799 seconds + 4.16 % in 15809 seconds + 4.16 % in 15819 seconds + 4.17 % in 15830 seconds + 4.17 % in 15840 seconds + 4.17 % in 15850 seconds diff --git a/furan/cc-pvtz/furan.natorb.out b/furan/cc-pvtz/furan.natorb.out new file mode 100644 index 0000000..f48e595 --- /dev/null +++ b/furan/cc-pvtz/furan.natorb.out @@ -0,0 +1,369 @@ +Date: 27/10/2020 16:29:59 +=============== +Quantum Package +=============== + +Git Commit: Fixed NaN bug in DIIS +Git Date : Wed Sep 2 18:48:45 2020 +0200 +Git SHA1 : e2e500dad8e43be46add568575fc215d515b6a24 +EZFIO Dir : furan + + +Task server running : tcp://172.28.1.65:41279 +.. >>>>> [ IO READ: n_states ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017426 GB ] [ VIRT MEM : 0.201935 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.050090 s ] [ CPU TIME: 0.031848 s ] <<<<< .. + +.. >>>>> [ IO READ: read_wf ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017426 GB ] [ VIRT MEM : 0.201935 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.065347 s ] [ CPU TIME: 0.032562 s ] <<<<< .. + +.. >>>>> [ IO READ: elec_beta_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017426 GB ] [ VIRT MEM : 0.201935 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.078774 s ] [ CPU TIME: 0.033794 s ] <<<<< .. + +* mo_num 206 +.. >>>>> [ IO READ: elec_alpha_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017624 GB ] [ VIRT MEM : 0.201935 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.081733 s ] [ CPU TIME: 0.034785 s ] <<<<< .. + + Read mo_occ +.. >>>>> [ IO READ: mo_class ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019432 GB ] [ VIRT MEM : 4.921257 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.154746 s ] [ CPU TIME: 2.436147 s ] <<<<< .. + +* Number of virtual MOs 0 + Virtual MOs: + +.. >>>>> [ IO READ: ao_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019432 GB ] [ VIRT MEM : 4.921257 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.186175 s ] [ CPU TIME: 4.407021 s ] <<<<< .. + + Read mo_coef + * mo_label Canonical +* Number of determinants 10485760 +* Dimension of the psi arrays 10485760 +* N_int 4 + Read psi_det +* Number of unique beta determinants 1152932 +* Number of unique alpha determinants 1052165 + Read psi_coef 10485760 1 +.. >>>>> [ IO READ: weight_one_e_dm ] <<<<< .. + +.. >>>>> [ RES MEM : 3.827347 GB ] [ VIRT MEM : 8.821079 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 264.899781 s ] [ CPU TIME: 8670.624614 s ] <<<<< .. + +* Number of active MOs 201 +* Number of core MOs 5 +* Number of inactive MOs 0 + Core MOs: + 1 2 3 4 5 + Active MOs: + 6 7 8 9 10 11 + 12 13 14 15 16 17 + 18 19 20 21 22 23 + 24 25 26 27 28 29 + 30 31 32 33 34 35 + 36 37 38 39 40 41 + 42 43 44 45 46 47 + 48 49 50 51 52 53 + 54 55 56 57 58 59 + 60 61 62 63 64 65 + 66 67 68 69 70 71 + 72 73 74 75 76 77 + 78 79 80 81 82 83 + 84 85 86 87 88 89 + 90 91 92 93 94 95 + 96 97 98 99 100 101 + 102 103 104 105 106 107 + 108 109 110 111 112 113 + 114 115 116 117 118 119 + 120 121 122 123 124 125 + 126 127 128 129 130 131 + 132 133 134 135 136 137 + 138 139 140 141 142 143 + 144 145 146 147 148 149 + 150 151 152 153 154 155 + 156 157 158 159 160 161 + 162 163 164 165 166 167 + 168 169 170 171 172 173 + 174 175 176 177 178 179 + 180 181 182 183 184 185 + 186 187 188 189 190 191 + 192 193 194 195 196 197 + 198 199 200 201 202 203 + 204 205 206 + Core, Inactive and Active MOs: + 1 2 3 4 5 6 + 7 8 9 10 11 12 + 13 14 15 16 17 18 + 19 20 21 22 23 24 + 25 26 27 28 29 30 + 31 32 33 34 35 36 + 37 38 39 40 41 42 + 43 44 45 46 47 48 + 49 50 51 52 53 54 + 55 56 57 58 59 60 + 61 62 63 64 65 66 + 67 68 69 70 71 72 + 73 74 75 76 77 78 + 79 80 81 82 83 84 + 85 86 87 88 89 90 + 91 92 93 94 95 96 + 97 98 99 100 101 102 + 103 104 105 106 107 108 + 109 110 111 112 113 114 + 115 116 117 118 119 120 + 121 122 123 124 125 126 + 127 128 129 130 131 132 + 133 134 135 136 137 138 + 139 140 141 142 143 144 + 145 146 147 148 149 150 + 151 152 153 154 155 156 + 157 158 159 160 161 162 + 163 164 165 166 167 168 + 169 170 171 172 173 174 + 175 176 177 178 179 180 + 181 182 183 184 185 186 + 187 188 189 190 191 192 + 193 194 195 196 197 198 + 199 200 201 202 203 204 + 205 206 + +.. >>>>> [ RES MEM : 3.827652 GB ] [ VIRT MEM : 8.821079 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 264.920861 s ] [ CPU TIME: 8672.120888 s ] <<<<< .. + +MOs are now **Natural** + +Eigenvalues +----------- + +======== ================ ================ + MO Eigenvalue Cumulative +======== ================ ================ + 1 2.0000000000 2.0000000000 + 2 2.0000000000 4.0000000000 + 3 2.0000000000 6.0000000000 + 4 2.0000000000 8.0000000000 + 5 2.0000000000 10.0000000000 + 6 1.9881093714 11.9881093714 + 7 1.9850993704 13.9732087418 + 8 1.9835069109 15.9567156527 + 9 1.9797901650 17.9365058177 + 10 1.9796062349 19.9161120526 + 11 1.9786801155 21.8947921680 + 12 1.9747772950 23.8695694630 + 13 1.9745448275 25.8441142905 + 14 1.9735545614 27.8176688519 + 15 1.9713025120 29.7889713639 + 16 1.9706361662 31.7596075301 + 17 1.9594889560 33.7190964861 + 18 1.9444039067 35.6635003928 + 19 0.0479886536 35.7114890464 + 20 0.0276451029 35.7391341493 + 21 0.0196879617 35.7588221110 + 22 0.0185365919 35.7773587029 + 23 0.0140560795 35.7914147824 + 24 0.0131988032 35.8046135855 + 25 0.0118043868 35.8164179723 + 26 0.0114340053 35.8278519776 + 27 0.0104142692 35.8382662468 + 28 0.0095880509 35.8478542978 + 29 0.0084560263 35.8563103240 + 30 0.0082166703 35.8645269943 + 31 0.0075032098 35.8720302042 + 32 0.0064029766 35.8784331808 + 33 0.0057386479 35.8841718287 + 34 0.0056880888 35.8898599175 + 35 0.0056879492 35.8955478667 + 36 0.0054038414 35.9009517081 + 37 0.0053839264 35.9063356345 + 38 0.0052523947 35.9115880292 + 39 0.0049784075 35.9165664368 + 40 0.0048668583 35.9214332950 + 41 0.0045995085 35.9260328036 + 42 0.0043696700 35.9304024736 + 43 0.0037670838 35.9341695574 + 44 0.0035574673 35.9377270247 + 45 0.0031934855 35.9409205102 + 46 0.0028691321 35.9437896423 + 47 0.0026282936 35.9464179359 + 48 0.0024774462 35.9488953820 + 49 0.0024695569 35.9513649390 + 50 0.0023981362 35.9537630752 + 51 0.0021877971 35.9559508723 + 52 0.0021610631 35.9581119354 + 53 0.0018729651 35.9599849005 + 54 0.0018286444 35.9618135450 + 55 0.0017139438 35.9635274888 + 56 0.0014560588 35.9649835475 + 57 0.0013254656 35.9663090132 + 58 0.0012890392 35.9675980524 + 59 0.0012873269 35.9688853793 + 60 0.0011226789 35.9700080581 + 61 0.0011011542 35.9711092123 + 62 0.0010803438 35.9721895562 + 63 0.0010470413 35.9732365974 + 64 0.0009992721 35.9742358696 + 65 0.0009834747 35.9752193442 + 66 0.0009724616 35.9761918059 + 67 0.0009224900 35.9771142958 + 68 0.0008763677 35.9779906636 + 69 0.0007996581 35.9787903216 + 70 0.0007216672 35.9795119888 + 71 0.0006813152 35.9801933040 + 72 0.0006621076 35.9808554116 + 73 0.0006451966 35.9815006082 + 74 0.0005639960 35.9820646042 + 75 0.0005474465 35.9826120507 + 76 0.0005315088 35.9831435594 + 77 0.0005285737 35.9836721332 + 78 0.0005094481 35.9841815813 + 79 0.0005042781 35.9846858594 + 80 0.0004703166 35.9851561760 + 81 0.0004338478 35.9855900238 + 82 0.0004190848 35.9860091085 + 83 0.0004096964 35.9864188050 + 84 0.0004013001 35.9868201050 + 85 0.0003727981 35.9871929031 + 86 0.0003727961 35.9875656991 + 87 0.0003489820 35.9879146812 + 88 0.0003401766 35.9882548578 + 89 0.0003388421 35.9885936999 + 90 0.0003360155 35.9889297154 + 91 0.0003299120 35.9892596274 + 92 0.0003263634 35.9895859908 + 93 0.0003127846 35.9898987754 + 94 0.0003071382 35.9902059136 + 95 0.0003048517 35.9905107653 + 96 0.0002917660 35.9908025313 + 97 0.0002915579 35.9910940891 + 98 0.0002899037 35.9913839928 + 99 0.0002759210 35.9916599138 + 100 0.0002741472 35.9919340610 + 101 0.0002689332 35.9922029942 + 102 0.0002624715 35.9924654657 + 103 0.0002484800 35.9927139457 + 104 0.0002275804 35.9929415261 + 105 0.0002209952 35.9931625213 + 106 0.0002112727 35.9933737940 + 107 0.0002092353 35.9935830293 + 108 0.0002052705 35.9937882999 + 109 0.0001923053 35.9939806051 + 110 0.0001889207 35.9941695259 + 111 0.0001885978 35.9943581237 + 112 0.0001881830 35.9945463067 + 113 0.0001783550 35.9947246617 + 114 0.0001750368 35.9948996984 + 115 0.0001719309 35.9950716294 + 116 0.0001665082 35.9952381376 + 117 0.0001655235 35.9954036611 + 118 0.0001642167 35.9955678778 + 119 0.0001565662 35.9957244440 + 120 0.0001503911 35.9958748351 + 121 0.0001499119 35.9960247470 + 122 0.0001430900 35.9961678370 + 123 0.0001335052 35.9963013422 + 124 0.0001310143 35.9964323565 + 125 0.0001306707 35.9965630272 + 126 0.0001298396 35.9966928668 + 127 0.0001282995 35.9968211663 + 128 0.0001200133 35.9969411796 + 129 0.0001085329 35.9970497125 + 130 0.0001084295 35.9971581420 + 131 0.0001051972 35.9972633392 + 132 0.0000988734 35.9973622126 + 133 0.0000972014 35.9974594140 + 134 0.0000937738 35.9975531878 + 135 0.0000854249 35.9976386128 + 136 0.0000818294 35.9977204422 + 137 0.0000781751 35.9977986173 + 138 0.0000773244 35.9978759417 + 139 0.0000745053 35.9979504470 + 140 0.0000742639 35.9980247109 + 141 0.0000675879 35.9980922988 + 142 0.0000651503 35.9981574490 + 143 0.0000626635 35.9982201125 + 144 0.0000607231 35.9982808356 + 145 0.0000601848 35.9983410204 + 146 0.0000574133 35.9983984336 + 147 0.0000572633 35.9984556969 + 148 0.0000561256 35.9985118225 + 149 0.0000532261 35.9985650487 + 150 0.0000523152 35.9986173638 + 151 0.0000517666 35.9986691305 + 152 0.0000508821 35.9987200126 + 153 0.0000477483 35.9987677608 + 154 0.0000475467 35.9988153076 + 155 0.0000440180 35.9988593255 + 156 0.0000439169 35.9989032424 + 157 0.0000438124 35.9989470548 + 158 0.0000402577 35.9989873125 + 159 0.0000381267 35.9990254392 + 160 0.0000377450 35.9990631842 + 161 0.0000370760 35.9991002601 + 162 0.0000370295 35.9991372896 + 163 0.0000359092 35.9991731988 + 164 0.0000358067 35.9992090055 + 165 0.0000351280 35.9992441335 + 166 0.0000346583 35.9992787918 + 167 0.0000341951 35.9993129869 + 168 0.0000331527 35.9993461396 + 169 0.0000331300 35.9993792696 + 170 0.0000326214 35.9994118910 + 171 0.0000312586 35.9994431496 + 172 0.0000308896 35.9994740391 + 173 0.0000288430 35.9995028821 + 174 0.0000277974 35.9995306795 + 175 0.0000272993 35.9995579789 + 176 0.0000271911 35.9995851700 + 177 0.0000255205 35.9996106905 + 178 0.0000246076 35.9996352981 + 179 0.0000244977 35.9996597957 + 180 0.0000233289 35.9996831246 + 181 0.0000219873 35.9997051119 + 182 0.0000214427 35.9997265546 + 183 0.0000200285 35.9997465831 + 184 0.0000199680 35.9997665511 + 185 0.0000188956 35.9997854467 + 186 0.0000176171 35.9998030638 + 187 0.0000169105 35.9998199743 + 188 0.0000155612 35.9998355355 + 189 0.0000149994 35.9998505349 + 190 0.0000147668 35.9998653017 + 191 0.0000137114 35.9998790131 + 192 0.0000121805 35.9998911936 + 193 0.0000120527 35.9999032462 + 194 0.0000120278 35.9999152740 + 195 0.0000111637 35.9999264377 + 196 0.0000111035 35.9999375412 + 197 0.0000088774 35.9999464185 + 198 0.0000086580 35.9999550766 + 199 0.0000083560 35.9999634326 + 200 0.0000083430 35.9999717755 + 201 0.0000075515 35.9999793270 + 202 0.0000063448 35.9999856717 + 203 0.0000039911 35.9999896628 + 204 0.0000038722 35.9999935350 + 205 0.0000036403 35.9999971753 + 206 0.0000028247 36.0000000000 +======== ================ ================ + + +.. >>>>> [ RES MEM : 3.833748 GB ] [ VIRT MEM : 8.927223 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 264.974530 s ] [ CPU TIME: 8675.916461 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_md5 ] <<<<< .. + +.. >>>>> [ RES MEM : 3.833748 GB ] [ VIRT MEM : 8.927223 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 264.975583 s ] [ CPU TIME: 8675.991119 s ] <<<<< .. + +* Saved determinants 1 +Wall time: 0:04:30 + diff --git a/furan/cc-pvtz/furan.nofci.out b/furan/cc-pvtz/furan.nofci.out new file mode 100644 index 0000000..654e343 --- /dev/null +++ b/furan/cc-pvtz/furan.nofci.out @@ -0,0 +1,4568 @@ +Date: 27/10/2020 16:34:29 +=============== +Quantum Package +=============== + +Git Commit: Fixed NaN bug in DIIS +Git Date : Wed Sep 2 18:48:45 2020 +0200 +Git SHA1 : e2e500dad8e43be46add568575fc215d515b6a24 +EZFIO Dir : furan + + +Task server running : tcp://172.28.1.65:41279 +* mo_num 206 +.. >>>>> [ IO READ: mo_class ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019283 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.000990 s ] [ CPU TIME: 0.147188 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_two_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019283 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.003004 s ] [ CPU TIME: 0.266390 s ] <<<<< .. + +* N_int 4 + MO map initialized: 227303181 +.. >>>>> [ IO READ: io_ao_two_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.020992 GB ] [ VIRT MEM : 4.927048 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.025873 s ] [ CPU TIME: 1.615725 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.020992 GB ] [ VIRT MEM : 4.927048 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.050580 s ] [ CPU TIME: 3.070842 s ] <<<<< .. + + AO map initialized : 384490315 +.. >>>>> [ IO READ: ao_power ] <<<<< .. + +.. >>>>> [ RES MEM : 0.024220 GB ] [ VIRT MEM : 4.928890 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.067173 s ] [ CPU TIME: 4.038930 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_prim_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.024269 GB ] [ VIRT MEM : 4.928890 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.070877 s ] [ CPU TIME: 4.263010 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_expo ] <<<<< .. + +.. >>>>> [ RES MEM : 0.024315 GB ] [ VIRT MEM : 4.928890 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.077272 s ] [ CPU TIME: 4.586903 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_coef ] <<<<< .. + +.. >>>>> [ RES MEM : 0.024403 GB ] [ VIRT MEM : 4.928890 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.082930 s ] [ CPU TIME: 4.878062 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_nucl ] <<<<< .. + +.. >>>>> [ RES MEM : 0.024635 GB ] [ VIRT MEM : 4.928890 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.087280 s ] [ CPU TIME: 5.147585 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_integrals_threshold ] <<<<< .. + +.. >>>>> [ RES MEM : 0.024635 GB ] [ VIRT MEM : 4.928890 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.088613 s ] [ CPU TIME: 5.233334 s ] <<<<< .. + + Providing the AO integrals +.. >>>>> [ IO READ: nucl_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.026108 GB ] [ VIRT MEM : 5.134129 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.215183 s ] [ CPU TIME: 12.785062 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_label ] <<<<< .. + +.. >>>>> [ RES MEM : 0.026260 GB ] [ VIRT MEM : 5.134129 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.218910 s ] [ CPU TIME: 13.024423 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_charge ] <<<<< .. + +.. >>>>> [ RES MEM : 0.026291 GB ] [ VIRT MEM : 5.134129 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.236160 s ] [ CPU TIME: 14.126668 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.026302 GB ] [ VIRT MEM : 5.134129 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.239227 s ] [ CPU TIME: 14.323670 s ] <<<<< .. + + +Nuclear Coordinates (Angstroms) +=============================== + +================ ============ ============ ============ ============ + Atom Charge X Y Z +================ ============ ============ ============ ============ +C 6.000000 0.000000 1.092041 -0.317778 +C 6.000000 0.000000 -1.092041 -0.317778 +C 6.000000 0.000000 0.716234 0.986050 +C 6.000000 0.000000 -0.716234 0.986050 +O 8.000000 0.000000 0.000000 -1.132150 +H 1.000000 0.000000 2.044409 -0.813693 +H 1.000000 0.000000 -2.044409 -0.813693 +H 1.000000 0.000000 1.371462 1.837134 +H 1.000000 0.000000 -1.371462 1.837134 +================ ============ ============ ============ ============ + + Sorting the map + AO integrals provided: + Size of AO map : 2246.25938415527 MB + Number of AO integrals : 188930778 + cpu time : 2327.00046000000 s + wall time : 38.3217859268188 s ( x 60.7226517168003 ) + + AO -> MO integrals transformation + --------------------------------- + + Read mo_coef +.. >>>>> [ IO READ: mo_integrals_threshold ] <<<<< .. + +.. >>>>> [ RES MEM : 1.974586 GB ] [ VIRT MEM : 7.502449 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 38.508648 s ] [ CPU TIME: 2333.664590 s ] <<<<< .. + + Buffers : 364.4832 MB / core + 29.36170 % in 29.7232389450073 s 3048.31726837158 MB + 42.97872 % in 41.6294198036194 s 3179.16926193237 MB + 67.65958 % in 55.9997758865356 s 3135.88913726807 MB + 88.93617 % in 68.6770470142365 s 3158.65235137939 MB + Molecular integrals provided: + Size of MO map 3166.79978179932 MB + Number of MO integrals: 162965666 + cpu time : 5289.13246300000 s + wall time : 85.0493991374969 s ( x 62.1889456790778 ) +.. >>>>> [ IO READ: n_states ] <<<<< .. + +.. >>>>> [ RES MEM : 6.649330 GB ] [ VIRT MEM : 12.218460 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.500003 s ] [ CPU TIME: 7624.181316 s ] <<<<< .. + + * mo_label Natural +.. >>>>> [ IO READ: read_wf ] <<<<< .. + +.. >>>>> [ RES MEM : 6.649330 GB ] [ VIRT MEM : 12.218460 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.501934 s ] [ CPU TIME: 7624.317861 s ] <<<<< .. + +* Number of determinants 1 +* Dimension of the psi arrays 100000 + Read psi_coef 1 1 +.. >>>>> [ IO READ: elec_beta_num ] <<<<< .. + +.. >>>>> [ RES MEM : 6.649517 GB ] [ VIRT MEM : 12.218460 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.520616 s ] [ CPU TIME: 7625.639404 s ] <<<<< .. + +.. >>>>> [ IO READ: elec_alpha_num ] <<<<< .. + +.. >>>>> [ RES MEM : 6.649517 GB ] [ VIRT MEM : 12.218460 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.521457 s ] [ CPU TIME: 7625.698989 s ] <<<<< .. + + Read psi_det +.. >>>>> [ IO READ: do_pt2 ] <<<<< .. + +.. >>>>> [ RES MEM : 6.655521 GB ] [ VIRT MEM : 12.224430 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.560949 s ] [ CPU TIME: 7628.494297 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 6.655594 GB ] [ VIRT MEM : 12.224430 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.595045 s ] [ CPU TIME: 7630.880158 s ] <<<<< .. + +.. >>>>> [ IO READ: selection_factor ] <<<<< .. + +.. >>>>> [ RES MEM : 6.655594 GB ] [ VIRT MEM : 12.224430 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.595892 s ] [ CPU TIME: 7630.940041 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_max ] <<<<< .. + +.. >>>>> [ RES MEM : 6.655594 GB ] [ VIRT MEM : 12.230400 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.596994 s ] [ CPU TIME: 7631.017754 s ] <<<<< .. + +.. >>>>> [ IO READ: s2_eig ] <<<<< .. + +.. >>>>> [ RES MEM : 6.671875 GB ] [ VIRT MEM : 12.253860 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.600301 s ] [ CPU TIME: 7631.242825 s ] <<<<< .. + +.. >>>>> [ IO READ: variance_max ] <<<<< .. + +.. >>>>> [ RES MEM : 6.671875 GB ] [ VIRT MEM : 12.253860 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.601093 s ] [ CPU TIME: 7631.298683 s ] <<<<< .. + +.. >>>>> [ IO READ: distributed_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 6.671875 GB ] [ VIRT MEM : 12.253860 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.616163 s ] [ CPU TIME: 7632.351556 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_max_full ] <<<<< .. + +.. >>>>> [ RES MEM : 6.671875 GB ] [ VIRT MEM : 12.253860 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.616965 s ] [ CPU TIME: 7632.408033 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_integrals_e_n ] <<<<< .. + +.. >>>>> [ RES MEM : 8.674786 GB ] [ VIRT MEM : 14.259727 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.840304 s ] [ CPU TIME: 7705.129443 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_integrals_e_n ] <<<<< .. + +.. >>>>> [ RES MEM : 8.674786 GB ] [ VIRT MEM : 14.259727 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.849535 s ] [ CPU TIME: 7705.130438 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_integrals_kinetic ] <<<<< .. + +.. >>>>> [ RES MEM : 8.676453 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.885519 s ] [ CPU TIME: 7706.819276 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_integrals_kinetic ] <<<<< .. + +.. >>>>> [ RES MEM : 8.676453 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.886416 s ] [ CPU TIME: 7706.881848 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_one_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 8.676453 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.899636 s ] [ CPU TIME: 7707.804852 s ] <<<<< .. + + Providing the one-electron integrals +.. >>>>> [ IO READ: do_pseudo ] <<<<< .. + +.. >>>>> [ RES MEM : 8.676628 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.914394 s ] [ CPU TIME: 7708.834606 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_relative_error ] <<<<< .. + +.. >>>>> [ RES MEM : 8.676628 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.977457 s ] [ CPU TIME: 7713.264356 s ] <<<<< .. + +.. >>>>> [ IO READ: correlation_energy_ratio_max ] <<<<< .. + +.. >>>>> [ RES MEM : 8.676628 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.978571 s ] [ CPU TIME: 7713.343080 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.676628 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.979392 s ] [ CPU TIME: 7713.400597 s ] <<<<< .. + + Read n_states_diag +.. >>>>> [ IO READ: io_nuclear_repulsion ] <<<<< .. + +.. >>>>> [ RES MEM : 8.676628 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.980680 s ] [ CPU TIME: 7713.491308 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.676628 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.981039 s ] [ CPU TIME: 7713.516963 s ] <<<<< .. + +* Nuclear repulsion energy 161.1082297787890 +.. >>>>> [ IO READ: weight_one_e_dm ] <<<<< .. + +.. >>>>> [ RES MEM : 8.676628 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.981929 s ] [ CPU TIME: 7713.579412 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_max ] <<<<< .. + +.. >>>>> [ RES MEM : 8.684780 GB ] [ VIRT MEM : 14.331917 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.992241 s ] [ CPU TIME: 7714.307147 s ] <<<<< .. + +.. >>>>> [ IO READ: threshold_generators ] <<<<< .. + +.. >>>>> [ RES MEM : 8.684780 GB ] [ VIRT MEM : 14.331917 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.993024 s ] [ CPU TIME: 7714.362393 s ] <<<<< .. + +* Target maximum memory (GB) 170 +.. >>>>> [ IO READ: threshold_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 8.684780 GB ] [ VIRT MEM : 14.331917 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.994531 s ] [ CPU TIME: 7714.468204 s ] <<<<< .. + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.685020 GB ] [ VIRT MEM : 14.331917 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.996702 s ] [ CPU TIME: 7714.613266 s ] <<<<< .. + +* Energy of state 1 -228.7049349645350 +* S^2 of state 1 0.000000000000000 +* Saved determinants 1 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 1 +* Number of unique alpha determinants 1 +.. >>>>> [ IO READ: weight_selection ] <<<<< .. + +.. >>>>> [ RES MEM : 8.685093 GB ] [ VIRT MEM : 14.344120 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 129.091014 s ] [ CPU TIME: 7721.258095 s ] <<<<< .. + + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +.. >>>>> [ IO READ: pseudo_sym ] <<<<< .. + +.. >>>>> [ RES MEM : 8.685093 GB ] [ VIRT MEM : 14.344120 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 129.091946 s ] [ CPU TIME: 7721.324092 s ] <<<<< .. + +.. >>>>> [ IO READ: h0_type ] <<<<< .. + +.. >>>>> [ RES MEM : 8.685093 GB ] [ VIRT MEM : 14.350090 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 129.094159 s ] [ CPU TIME: 7721.480881 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.685093 GB ] [ VIRT MEM : 14.350090 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 129.094628 s ] [ CPU TIME: 7721.514054 s ] <<<<< .. + +* Number of generators 1 + +.. >>>>> [ RES MEM : 8.685093 GB ] [ VIRT MEM : 14.350090 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 129.095017 s ] [ CPU TIME: 7721.542034 s ] <<<<< .. + +* Number of selectors 1 +* Number of comb teeth 1 +* Number of core MOs 5 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.7049349645350 +* Estimated memory/thread (Gb) 0.2384185791015625E-06 +* Number of virtual MOs 0 +* Number of active MOs 201 + Active MOs: + 6 7 8 9 10 11 + 12 13 14 15 16 17 + 18 19 20 21 22 23 + 24 25 26 27 28 29 + 30 31 32 33 34 35 + 36 37 38 39 40 41 + 42 43 44 45 46 47 + 48 49 50 51 52 53 + 54 55 56 57 58 59 + 60 61 62 63 64 65 + 66 67 68 69 70 71 + 72 73 74 75 76 77 + 78 79 80 81 82 83 + 84 85 86 87 88 89 + 90 91 92 93 94 95 + 96 97 98 99 100 101 + 102 103 104 105 106 107 + 108 109 110 111 112 113 + 114 115 116 117 118 119 + 120 121 122 123 124 125 + 126 127 128 129 130 131 + 132 133 134 135 136 137 + 138 139 140 141 142 143 + 144 145 146 147 148 149 + 150 151 152 153 154 155 + 156 157 158 159 160 161 + 162 163 164 165 166 167 + 168 169 170 171 172 173 + 174 175 176 177 178 179 + 180 181 182 183 184 185 + 186 187 188 189 190 191 + 192 193 194 195 196 197 + 198 199 200 201 202 203 + 204 205 206 +* Number of inactive MOs 0 +.. >>>>> [ IO READ: pert_2rdm ] <<<<< .. + +.. >>>>> [ RES MEM : 8.686672 GB ] [ VIRT MEM : 14.366783 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 129.140552 s ] [ CPU TIME: 7724.064437 s ] <<<<< .. + +.. >>>>> [ IO READ: pruning ] <<<<< .. + +.. >>>>> [ RES MEM : 8.686913 GB ] [ VIRT MEM : 14.366783 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 136.949785 s ] [ CPU TIME: 7744.234028 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.687389 GB ] [ VIRT MEM : 14.366783 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 136.955979 s ] [ CPU TIME: 7744.653888 s ] <<<<< .. + +* Number of generators 1 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Saved determinants 5 +* Number of unique beta determinants 5 +* Number of unique alpha determinants 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.687397 GB ] [ VIRT MEM : 14.366791 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 136.999704 s ] [ CPU TIME: 7747.704436 s ] <<<<< .. + +* Number of selectors 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio -0.2642772445189763E-02 + +Summary at N_det = 5 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.70493496 +# PT2 -1.18969291 0.00000000 +# rPT2 -0.79729600 0.00000000 +# +# E+PT2 -229.89462787 0.00000000 +# E+rPT2 -229.50223096 0.00000000 +# ============ ============================= + + N_det = 5 + N_states = 1 + + * State 1 + < S^2 > = 0.000000000000000E+000 + E = -228.704934964535 + Variance = 3.94097846340409 + PT norm = 0.701540906201389 + PT2 = -1.18969290887493 + rPT2 = -0.797295996039776 + E+PT2 = -229.894627873410 +/- 0.000000000000000E+000 + E+rPT2 = -229.502230960575 +/- 0.000000000000000E+000 + + ----- +.. >>>>> [ IO READ: io_mo_integrals_pseudo ] <<<<< .. + +.. >>>>> [ RES MEM : 8.687397 GB ] [ VIRT MEM : 14.366791 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 137.001901 s ] [ CPU TIME: 7747.859772 s ] <<<<< .. + + Energy components + ================= + + Vnn : Nucleus-Nucleus potential energy + Ven : Electron-Nucleus potential energy + Vee : Electron-Electron potential energy + Vecp : Potential energy of the pseudo-potentials + T : Electronic kinetic energy + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.266764137126 + Vee = 239.783845933426 + Vecp = 0.000000000000000E+000 + T = 228.669753460375 + + +.. >>>>> [ IO READ: energy_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 8.687626 GB ] [ VIRT MEM : 14.366791 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 137.044655 s ] [ CPU TIME: 7750.856642 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 8.687626 GB ] [ VIRT MEM : 14.366791 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 137.048461 s ] [ CPU TIME: 7751.115046 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 8.687626 GB ] [ VIRT MEM : 14.366791 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 137.052075 s ] [ CPU TIME: 7751.360495 s ] <<<<< .. + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.687862 GB ] [ VIRT MEM : 14.366791 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 137.077452 s ] [ CPU TIME: 7753.119452 s ] <<<<< .. + +* Energy of state 1 -228.7334168477461 +* S^2 of state 1 0.000000000000000 +* Saved determinants 5 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 5 +* Number of unique alpha determinants 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.688026 GB ] [ VIRT MEM : 14.366791 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 137.128542 s ] [ CPU TIME: 7756.697230 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 8.688026 GB ] [ VIRT MEM : 14.366791 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 137.128933 s ] [ CPU TIME: 7756.725497 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.7334168477461 + +.. >>>>> [ RES MEM : 8.694569 GB ] [ VIRT MEM : 14.372761 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 137.137135 s ] [ CPU TIME: 7757.305915 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 8.694569 GB ] [ VIRT MEM : 14.372761 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 137.137542 s ] [ CPU TIME: 7757.334763 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 5 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2289864551275968E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.7389426786 0.137 3.9185897182 0.3428888926 3.6880 + 4 -229.8531848587 0.00 3.8677674678 0.4266462800 3.6882 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.700115 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 140.854202 s ] [ CPU TIME: 7789.993807 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 8.700115 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 140.854610 s ] [ CPU TIME: 7790.022761 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.3251713951989021E-01 + +Summary at N_det = 5 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.73341685 +# PT2 -1.11976801 0.00000000 +# rPT2 -0.78489534 0.00000000 +# +# E+PT2 -229.85318486 0.00000000 +# E+rPT2 -229.51831218 0.00000000 +# ============ ============================= + + N_det = 5 + N_states = 1 + + * State 1 + < S^2 > = 0.000000000000000E+000 + E = -228.733416847746 + Variance = 3.86776746783035 + PT norm = 0.653181659227952 + PT2 = -1.11976801092552 + rPT2 = -0.784895335768418 + E+PT2 = -229.853184858672 +/- 0.000000000000000E+000 + E+rPT2 = -229.518312183514 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.355547232896 + Vee = 239.780961698066 + Vecp = 0.000000000000000E+000 + T = 228.732938908296 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7973 -230.53616741 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.700314 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 140.910040 s ] [ CPU TIME: 7793.792304 s ] <<<<< .. + +* Energy of state 1 -228.7551465252178 +* S^2 of state 1 0.3654049137933620E-01 +* Saved determinants 10 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 7 +* Number of unique alpha determinants 7 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.700489 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 140.961003 s ] [ CPU TIME: 7797.251202 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 8.700489 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 140.961404 s ] [ CPU TIME: 7797.279130 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.7551465252178 + +.. >>>>> [ RES MEM : 8.700489 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 140.965231 s ] [ CPU TIME: 7797.546515 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 8.700489 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 140.965614 s ] [ CPU TIME: 7797.573206 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 10 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2299601100385189E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.7081478119 0.139 3.7988965697 0.3078027421 3.8759 + 9 -229.8212555312 0.00 3.8106125223 0.3789987718 3.8761 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.701031 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 144.858387 s ] [ CPU TIME: 7849.260798 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 8.701031 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 144.858780 s ] [ CPU TIME: 7849.288353 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.5858407150153518E-01 + +Summary at N_det = 10 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.75514653 +# PT2 -1.06610901 0.00000000 +# rPT2 -0.77310367 0.00000000 +# +# E+PT2 -229.82125553 0.00000000 +# E+rPT2 -229.52825019 0.00000000 +# ============ ============================= + + N_det = 10 + N_states = 1 + + * State 1 + < S^2 > = 3.654049137933620E-002 + E = -228.755146525218 + Variance = 3.81061252232975 + PT norm = 0.615628761319305 + PT2 = -1.06610900594115 + rPT2 = -0.773103666058929 + E+PT2 = -229.821255531159 +/- 0.000000000000000E+000 + E+rPT2 = -229.528250191277 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.420597310419 + Vee = 239.774235426831 + Vecp = 0.000000000000000E+000 + T = 228.782985579581 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7849 -230.17982121 + -0.7973 -230.36214419 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.701069 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 144.908654 s ] [ CPU TIME: 7852.650318 s ] <<<<< .. + +* Energy of state 1 -228.7736826900622 +* S^2 of state 1 0.4205370227240829E-01 +* Saved determinants 20 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 12 +* Number of unique alpha determinants 12 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.701164 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 144.963436 s ] [ CPU TIME: 7856.437046 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 8.701164 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 144.963829 s ] [ CPU TIME: 7856.465512 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.7736826900622 + +.. >>>>> [ RES MEM : 8.701164 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 144.967625 s ] [ CPU TIME: 7856.733690 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 8.701164 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 144.968006 s ] [ CPU TIME: 7856.761118 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 20 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2319074198603630E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6525722592 0.172 3.7529883329 0.2695714590 4.0944 + 19 -229.7965632430 0.00 3.7456665981 0.3506854415 4.0947 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.701164 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 149.084246 s ] [ CPU TIME: 7947.277738 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 8.701164 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 149.084601 s ] [ CPU TIME: 7947.302017 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8088613009620557E-01 + +Summary at N_det = 20 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.77368269 +# PT2 -1.02288055 0.00000000 +# rPT2 -0.75730479 0.00000000 +# +# E+PT2 -229.79656324 0.00000000 +# E+rPT2 -229.53098748 0.00000000 +# ============ ============================= + + N_det = 20 + N_states = 1 + + * State 1 + < S^2 > = 4.205370227240829E-002 + E = -228.773682690062 + Variance = 3.74566659814474 + PT norm = 0.592186998762511 + PT2 = -1.02288055292685 + rPT2 = -0.757304788736266 + E+PT2 = -229.796563242989 +/- 0.000000000000000E+000 + E+rPT2 = -229.530987478798 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.421127489723 + Vee = 239.740306346793 + Vecp = 0.000000000000000E+000 + T = 228.798908674079 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7731 -229.66219686 + -0.7849 -229.86824684 + -0.7973 -230.07519775 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.701817 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 149.134738 s ] [ CPU TIME: 7950.626254 s ] <<<<< .. + +* Energy of state 1 -228.7927824063258 +* S^2 of state 1 0.5913828857592524E-01 +* Saved determinants 40 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 18 +* Number of unique alpha determinants 17 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.701866 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 149.185734 s ] [ CPU TIME: 7954.061950 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 8.701866 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 149.186121 s ] [ CPU TIME: 7954.089039 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.7927824063258 + +.. >>>>> [ RES MEM : 8.701866 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 149.189998 s ] [ CPU TIME: 7954.355122 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 8.701866 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 149.190387 s ] [ CPU TIME: 7954.381864 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 40 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2358020395040512E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6077982944 0.195 3.6544755139 0.2418223596 5.0587 + 38 -229.7742753722 0.00 3.6819034980 0.3248351004 5.0592 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.702389 GB ] [ VIRT MEM : 14.378151 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 154.271251 s ] [ CPU TIME: 8144.748258 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 8.702389 GB ] [ VIRT MEM : 14.378151 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 154.271577 s ] [ CPU TIME: 8144.768515 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1037348380696177 + +Summary at N_det = 40 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.79278241 +# PT2 -0.98149297 0.00000000 +# rPT2 -0.74084161 0.00000000 +# +# E+PT2 -229.77427537 0.00000000 +# E+rPT2 -229.53362401 0.00000000 +# ============ ============================= + + N_det = 40 + N_states = 1 + + * State 1 + < S^2 > = 5.913828857592524E-002 + E = -228.792782406326 + Variance = 3.68190349799974 + PT norm = 0.569943067678712 + PT2 = -0.981492965866232 + rPT2 = -0.740841607814877 + E+PT2 = -229.774275372192 +/- 0.000000000000000E+000 + E+rPT2 = -229.533624014141 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.428361346522 + Vee = 239.710738572231 + Vecp = 0.000000000000000E+000 + T = 228.816610589176 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7573 -229.65226786 + -0.7731 -229.65702562 + -0.7849 -229.77101328 + -0.7973 -229.92267122 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.703808 GB ] [ VIRT MEM : 14.380062 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 154.332868 s ] [ CPU TIME: 8148.520835 s ] <<<<< .. + +* Energy of state 1 -228.8198994088955 +* S^2 of state 1 0.3711488752774673E-01 +* Saved determinants 80 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 30 +* Number of unique alpha determinants 31 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.704056 GB ] [ VIRT MEM : 14.380230 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 154.388492 s ] [ CPU TIME: 8152.036237 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 8.704056 GB ] [ VIRT MEM : 14.380230 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 154.388897 s ] [ CPU TIME: 8152.062903 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.8198994088955 + +.. >>>>> [ RES MEM : 8.704056 GB ] [ VIRT MEM : 14.380230 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 154.393065 s ] [ CPU TIME: 8152.332489 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 8.704056 GB ] [ VIRT MEM : 14.380230 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 154.393480 s ] [ CPU TIME: 8152.359478 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 80 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2435912787914276E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.5983808388 0.174 3.5267046553 0.2225645364 7.2476 + 70 -229.7321291818 0.998E-02 3.5834457820 0.2862226551 8.7435 + 76 -229.7506493354 0.00 3.5963323488 0.2954526872 9.5784 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.711388 GB ] [ VIRT MEM : 14.386070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 163.997939 s ] [ CPU TIME: 8634.465060 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 8.711388 GB ] [ VIRT MEM : 14.386070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 163.998322 s ] [ CPU TIME: 8634.489573 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1357606445556215 + +Summary at N_det = 80 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.81989941 +# PT2 -0.93074993 0.00000000 +# rPT2 -0.71847466 0.00000000 +# +# E+PT2 -229.75064934 0.00000000 +# E+rPT2 -229.53837407 0.00000000 +# ============ ============================= + + N_det = 80 + N_states = 1 + + * State 1 + < S^2 > = 3.711488752774673E-002 + E = -228.819899408895 + Variance = 3.59633234876446 + PT norm = 0.543555597158984 + PT2 = -0.930749926553985 + rPT2 = -0.718474658124072 + E+PT2 = -229.750649335449 +/- 0.000000000000000E+000 + E+rPT2 = -229.538374067020 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.442892146420 + Vee = 239.670732844008 + Vecp = 0.000000000000000E+000 + T = 228.844030114728 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7408 -229.69095601 + -0.7573 -229.67583103 + -0.7731 -229.67036298 + -0.7849 -229.73113300 + -0.7973 -229.83194627 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.711582 GB ] [ VIRT MEM : 14.386070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 164.060992 s ] [ CPU TIME: 8638.560178 s ] <<<<< .. + +* Energy of state 1 -228.8544512377611 +* S^2 of state 1 0.1378582764711756E-01 +* Saved determinants 160 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 58 +* Number of unique alpha determinants 59 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.711880 GB ] [ VIRT MEM : 14.386070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 164.118059 s ] [ CPU TIME: 8642.426540 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 8.711880 GB ] [ VIRT MEM : 14.386070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 164.118466 s ] [ CPU TIME: 8642.455545 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.8544512377611 + +.. >>>>> [ RES MEM : 8.711880 GB ] [ VIRT MEM : 14.386070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 164.122481 s ] [ CPU TIME: 8642.739362 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 8.711880 GB ] [ VIRT MEM : 14.386070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 164.122867 s ] [ CPU TIME: 8642.767171 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 160 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2591697573661804E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.5704696984 0.171 3.3482625731 0.1960795147 9.2269 + 68 -229.7014795843 0.147E-01 3.4546067237 0.2523826110 11.3750 + 86 -229.7087804774 0.122E-01 3.4592812923 0.2560375293 12.4524 + 135 -229.7139998493 0.795E-02 3.4464978084 0.2596789241 13.6625 + 140 -229.7141646952 0.767E-02 3.4448977426 0.2598776185 15.1347 + 154 -229.7246415824 0.00 3.4848692229 0.2626194565 15.5890 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.712040 GB ] [ VIRT MEM : 14.386070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 179.737808 s ] [ CPU TIME: 9587.041928 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 8.712040 GB ] [ VIRT MEM : 14.386070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 179.738194 s ] [ CPU TIME: 9587.067300 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1762050322733896 + +Summary at N_det = 160 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.85445124 +# PT2 -0.87019034 0.00000000 +# rPT2 -0.68919447 0.00000000 +# +# E+PT2 -229.72464158 0.00000000 +# E+rPT2 -229.54364571 0.00000000 +# ============ ============================= + + N_det = 160 + N_states = 1 + + * State 1 + < S^2 > = 1.378582764711756E-002 + E = -228.854451237761 + Variance = 3.48486922290769 + PT norm = 0.512464102690972 + PT2 = -0.870190344655737 + rPT2 = -0.689194468011462 + E+PT2 = -229.724641582417 +/- 0.000000000000000E+000 + E+rPT2 = -229.543645705773 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.460271693621 + Vee = 239.622985428415 + Vecp = 0.000000000000000E+000 + T = 228.874605248656 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7185 -229.66772906 + -0.7408 -229.67701047 + -0.7573 -229.67374002 + -0.7731 -229.67132525 + -0.7849 -229.70626351 + -0.7973 -229.77205506 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.721512 GB ] [ VIRT MEM : 14.389980 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 179.854960 s ] [ CPU TIME: 9594.957566 s ] <<<<< .. + +* Energy of state 1 -228.8917428312415 +* S^2 of state 1 0.2187330368180108E-01 +* Saved determinants 320 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 118 +* Number of unique alpha determinants 118 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.721546 GB ] [ VIRT MEM : 14.389980 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 179.919084 s ] [ CPU TIME: 9599.126817 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 8.721546 GB ] [ VIRT MEM : 14.389980 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 179.919492 s ] [ CPU TIME: 9599.155612 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.8917428312415 + +.. >>>>> [ RES MEM : 8.721546 GB ] [ VIRT MEM : 14.389980 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 179.923806 s ] [ CPU TIME: 9599.456694 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 8.721546 GB ] [ VIRT MEM : 14.389980 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 179.924193 s ] [ CPU TIME: 9599.484262 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 320 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2903267145156860E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.5406764364 0.172 3.2473032491 0.1697923259 12.7296 + 108 -229.6812473579 0.759E-02 3.2875892291 0.2280439997 13.7645 + 133 -229.6851207629 0.661E-02 3.2932417927 0.2295987057 15.3045 + 139 -229.6853041472 0.633E-02 3.2910432760 0.2298240036 16.6705 + 147 -229.6867366660 0.611E-02 3.2986051401 0.2300223813 18.1377 + 169 -229.6913409281 0.616E-02 3.3097807933 0.2317185024 19.3713 + 195 -229.6932690524 0.636E-02 3.3187368443 0.2320884291 20.4262 + 211 -229.6955961127 0.627E-02 3.3390480092 0.2319763609 22.5798 + 225 -229.6933995532 0.616E-02 3.3295634962 0.2314071294 23.6975 + 250 -229.6939863566 0.563E-02 3.3266110809 0.2318934034 24.7315 + 268 -229.6974592444 0.577E-02 3.3383284165 0.2329983865 25.8996 + 284 -229.6974075713 0.563E-02 3.3428020139 0.2326796857 27.1077 + 296 -229.6972800177 0.594E-02 3.3505439553 0.2321389436 28.1312 + 313 -229.7020442680 0.00 3.3597879993 0.2339962183 28.8795 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.721584 GB ] [ VIRT MEM : 14.390209 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 208.827129 s ] [ CPU TIME: 11513.176691 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 8.721584 GB ] [ VIRT MEM : 14.390209 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 208.827531 s ] [ CPU TIME: 11513.202721 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.2195344894941106 + +Summary at N_det = 320 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.89174283 +# PT2 -0.81030144 0.00000000 +# rPT2 -0.65664823 0.00000000 +# +# E+PT2 -229.70204427 0.00000000 +# E+rPT2 -229.54839106 0.00000000 +# ============ ============================= + + N_det = 320 + N_states = 1 + + * State 1 + < S^2 > = 2.187330368180108E-002 + E = -228.891742831241 + Variance = 3.35978799925428 + PT norm = 0.483731556015154 + PT2 = -0.810301436743569 + rPT2 = -0.656648233387477 + E+PT2 = -229.702044267985 +/- 0.000000000000000E+000 + E+rPT2 = -229.548391064629 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.456954939699 + Vee = 239.558203371858 + Vecp = 0.000000000000000E+000 + T = 228.898778957811 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6892 -229.64413275 + -0.7185 -229.65474920 + -0.7408 -229.66356146 + -0.7573 -229.66465504 + -0.7731 -229.66489329 + -0.7849 -229.68766700 + -0.7973 -229.73258531 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.730675 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 209.097148 s ] [ CPU TIME: 11531.758234 s ] <<<<< .. + +* Energy of state 1 -228.9367488820007 +* S^2 of state 1 0.2741316602258568E-01 +* Saved determinants 640 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 201 +* Number of unique alpha determinants 200 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.730675 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 209.165280 s ] [ CPU TIME: 11535.862464 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 8.730675 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 209.165634 s ] [ CPU TIME: 11535.887393 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.9367488820007 + +.. >>>>> [ RES MEM : 8.730675 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 209.169601 s ] [ CPU TIME: 11536.163956 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 8.730675 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 209.169938 s ] [ CPU TIME: 11536.187978 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 640 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.3526406288146973E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.5208856587 0.158 2.9345579369 0.1477880275 19.3281 + 150 -229.6570423772 0.856E-02 3.1147341148 0.1987341886 20.4058 + 180 -229.6649232380 0.845E-02 3.1377342597 0.2013492749 21.5600 + 201 -229.6661762861 0.781E-02 3.1519334900 0.2012059845 22.8121 + 209 -229.6659304225 0.753E-02 3.1561318443 0.2007771019 23.9849 + 211 -229.6658561499 0.746E-02 3.1550919400 0.2007988776 26.3981 + 258 -229.6675986608 0.684E-02 3.1603182017 0.2012825530 28.1446 + 276 -229.6737191378 0.773E-02 3.1929988637 0.2024783829 29.1884 + 283 -229.6733326667 0.754E-02 3.1893732860 0.2024931262 30.2608 + 290 -229.6744101531 0.749E-02 3.1943161141 0.2027128381 31.7651 + 301 -229.6756152173 0.816E-02 3.2078195482 0.2025635691 32.9641 + 318 -229.6758883860 0.782E-02 3.2050215112 0.2028460148 35.4696 + 354 -229.6769552198 0.726E-02 3.2093938445 0.2031106087 36.7281 + 375 -229.6744691188 0.696E-02 3.2008256155 0.2024005822 38.7289 + 400 -229.6767069924 0.683E-02 3.2135536248 0.2027584595 40.2398 + 418 -229.6773119704 0.667E-02 3.2171259102 0.2028827872 41.2860 + 424 -229.6770400274 0.658E-02 3.2147102880 0.2028854992 42.4636 + 436 -229.6773166144 0.644E-02 3.2136877499 0.2030624355 44.0071 + 461 -229.6764020678 0.610E-02 3.2084072717 0.2029228037 45.2213 + 486 -229.6792638608 0.616E-02 3.2206577774 0.2036152354 46.6660 + 496 -229.6788370624 0.604E-02 3.2171449581 0.2036043321 47.7890 + 510 -229.6804660609 0.606E-02 3.2228378001 0.2041015821 49.2758 + 536 -229.6792984682 0.586E-02 3.2212654846 0.2036054368 50.4067 + 551 -229.6801993344 0.579E-02 3.2227644832 0.2039761861 51.6440 + 563 -229.6807688188 0.575E-02 3.2228898460 0.2042714403 52.8078 + 583 -229.6807300695 0.562E-02 3.2262812414 0.2040437840 53.8984 + 608 -229.6804657469 0.543E-02 3.2215238262 0.2041958174 55.0177 + 626 -229.6794400142 0.00 3.2102461442 0.2043229295 55.8758 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.732224 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.069032 s ] [ CPU TIME: 15405.599642 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 8.732224 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.069414 s ] [ CPU TIME: 15405.622881 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.2713993072087593 + +Summary at N_det = 640 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.93674888 +# PT2 -0.74269113 0.00000000 +# rPT2 -0.61668770 0.00000000 +# +# E+PT2 -229.67944001 0.00000000 +# E+rPT2 -229.55343658 0.00000000 +# ============ ============================= + + N_det = 640 + N_states = 1 + + * State 1 + < S^2 > = 2.741316602258568E-002 + E = -228.936748882001 + Variance = 3.21024614424007 + PT norm = 0.452020939228012 + PT2 = -0.742691132166853 + rPT2 = -0.616687695612374 + E+PT2 = -229.679440014168 +/- 0.000000000000000E+000 + E+rPT2 = -229.553436577613 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.444077485274 + Vee = 239.475791357614 + Vecp = 0.000000000000000E+000 + T = 228.923307466871 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6566 -229.63130104 + -0.6892 -229.63661232 + -0.7185 -229.64444803 + -0.7408 -229.65186555 + -0.7573 -229.65456859 + -0.7731 -229.65620525 + -0.7849 -229.67195054 + =========== =================== + +* Number of unique alpha determinants 347 +* Number of unique beta determinants 347 +.. >>>>> [ IO READ: davidson_sze_max ] <<<<< .. + +.. >>>>> [ RES MEM : 8.732746 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.135443 s ] [ CPU TIME: 15409.805586 s ] <<<<< .. + +.. >>>>> [ IO READ: state_following ] <<<<< .. + +.. >>>>> [ RES MEM : 8.732746 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.136551 s ] [ CPU TIME: 15409.879884 s ] <<<<< .. + +.. >>>>> [ IO READ: only_expected_s2 ] <<<<< .. + +.. >>>>> [ RES MEM : 8.732746 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.137798 s ] [ CPU TIME: 15409.963146 s ] <<<<< .. + +.. >>>>> [ IO READ: disk_based_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 8.732746 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.138606 s ] [ CPU TIME: 15410.017048 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.732746 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.138969 s ] [ CPU TIME: 15410.041552 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 1280 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.3220573067665100E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9374783859 0.027589 0.199E-01 + 2 -228.9862919229 0.033155 0.156E-02 + 3 -228.9869046385 0.032075 0.581E-04 + 4 -228.9869751923 0.032231 0.944E-06 + 5 -228.9869770710 0.032227 0.188E-07 + 6 -228.9869771071 0.032221 0.357E-09 + 7 -228.9869771078 0.032221 0.615E-11 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 8.733212 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.236169 s ] [ CPU TIME: 15416.701853 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.733212 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.236586 s ] [ CPU TIME: 15416.731238 s ] <<<<< .. + +* Energy of state 1 -228.9869771078373 +* S^2 of state 1 0.3222128543233175E-01 +* Saved determinants 1280 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.733372 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.328887 s ] [ CPU TIME: 15421.832138 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 8.733372 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.329273 s ] [ CPU TIME: 15421.859441 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 59 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.9869771078373 + +.. >>>>> [ RES MEM : 8.730354 GB ] [ VIRT MEM : 14.393272 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.340311 s ] [ CPU TIME: 15422.627153 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 8.730354 GB ] [ VIRT MEM : 14.393272 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.340703 s ] [ CPU TIME: 15422.654671 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 59 +* pt2_n_tasks_max 1 +* Number of tasks 1280 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.4772857427597046E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6564720946 0.630E-03 3.0335283311 0.1740067076 32.2217 + 4 -229.6569721265 0.702E-03 3.0363458456 0.1741043070 33.2528 + 5 -229.6568223054 0.552E-03 3.0352326794 0.1740877534 36.9138 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.731403 GB ] [ VIRT MEM : 14.393272 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 303.924058 s ] [ CPU TIME: 17985.912249 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 8.731403 GB ] [ VIRT MEM : 14.393272 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 303.924453 s ] [ CPU TIME: 17985.936294 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 59 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.3291620006571093 + +Summary at N_det = 1280 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.98697711 +# PT2 -0.66984520 0.00055242 +# rPT2 -0.57052396 0.00047051 +# +# E+PT2 -229.65682231 0.00055242 +# E+rPT2 -229.55750107 0.00047051 +# ============ ============================= + + N_det = 1280 + N_states = 1 + + * State 1 + < S^2 > = 3.222128543233175E-002 + E = -228.986977107837 + Variance = 3.03523267944884 + PT norm = 0.417238245320142 + PT2 = -0.669845197569430 + rPT2 = -0.570523962671194 + E+PT2 = -229.656822305407 +/- 5.524248246837784E-004 + E+rPT2 = -229.557501070508 +/- 4.705140847469635E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.437642992751 + Vee = 239.394044843884 + Vecp = 0.000000000000000E+000 + T = 228.948391262241 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6167 -229.60773294 + -0.6566 -229.61784248 + -0.6892 -229.62466903 + -0.7185 -229.63202542 + -0.7408 -229.63882912 + -0.7573 -229.64238537 + -0.7731 -229.64490741 + =========== =================== + +* Number of unique alpha determinants 591 +* Number of unique beta determinants 590 + +.. >>>>> [ RES MEM : 8.731815 GB ] [ VIRT MEM : 14.393272 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 304.029062 s ] [ CPU TIME: 17992.579035 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 2560 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.5900710821151733E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9870035588 0.032190 0.214E-01 + 2 -229.0430875634 0.038630 0.167E-02 + 3 -229.0438566802 0.037511 0.677E-04 + 4 -229.0439447783 0.037864 0.130E-05 + 5 -229.0439474876 0.037878 0.369E-07 + 6 -229.0439475624 0.037876 0.786E-09 + 7 -229.0439475642 0.037876 0.167E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 8.733974 GB ] [ VIRT MEM : 14.395584 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 304.077438 s ] [ CPU TIME: 17995.926636 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.733974 GB ] [ VIRT MEM : 14.395584 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 304.077840 s ] [ CPU TIME: 17995.955897 s ] <<<<< .. + +* Energy of state 1 -229.0439475641669 +* S^2 of state 1 0.3787616457599306E-01 +* Saved determinants 2560 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.733456 GB ] [ VIRT MEM : 14.394428 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 304.209321 s ] [ CPU TIME: 18002.433513 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 8.733456 GB ] [ VIRT MEM : 14.394428 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 304.209720 s ] [ CPU TIME: 18002.461638 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 77 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -229.0439475641669 + +.. >>>>> [ RES MEM : 8.733456 GB ] [ VIRT MEM : 14.394428 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 304.219021 s ] [ CPU TIME: 18003.109163 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 8.733456 GB ] [ VIRT MEM : 14.394428 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 304.219413 s ] [ CPU TIME: 18003.136383 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 77 +* pt2_n_tasks_max 1 +* Number of tasks 2560 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.7265467643737793E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6393713591 0.159E-02 2.8496874008 0.1448302284 57.5848 + 7 -229.6391540590 0.471E-03 2.8484071847 0.1447917195 61.9746 + 8 -229.6393472275 0.441E-03 2.8502363640 0.1448037532 68.6799 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.735867 GB ] [ VIRT MEM : 14.393288 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373.195011 s ] [ CPU TIME: 22679.308732 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 8.735867 GB ] [ VIRT MEM : 14.393288 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373.195406 s ] [ CPU TIME: 22679.333326 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 77 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.3931284829640186 + +Summary at N_det = 2560 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.04394756 +# PT2 -0.59539966 0.00044114 +# rPT2 -0.52008885 0.00038534 +# +# E+PT2 -229.63934723 0.00044114 +# E+rPT2 -229.56403641 0.00038534 +# ============ ============================= + + N_det = 2560 + N_states = 1 + + * State 1 + < S^2 > = 3.787616457599306E-002 + E = -229.043947564167 + Variance = 2.85023636404320 + PT norm = 0.380530883321600 + PT2 = -0.595399663310130 + rPT2 = -0.520088846377259 + E+PT2 = -229.639347227477 +/- 4.411359506152892E-004 + E+rPT2 = -229.564036410544 +/- 3.853376173837985E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.437754533912 + Vee = 239.307829426061 + Vecp = 0.000000000000000E+000 + T = 228.977747764896 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.5705 -229.63142909 + -0.6167 -229.62094603 + -0.6566 -229.62198927 + -0.6892 -229.62493253 + -0.7185 -229.62939552 + -0.7408 -229.63416065 + -0.7573 -229.63706383 + =========== =================== + +* Number of unique alpha determinants 1024 +* Number of unique beta determinants 1025 + +.. >>>>> [ RES MEM : 8.736507 GB ] [ VIRT MEM : 14.393288 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373.262301 s ] [ CPU TIME: 22683.596820 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5120 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.1104352623224258E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.0440175216 0.037847 0.223E-01 + 2 -229.1073693041 0.035922 0.157E-02 + 3 -229.1082554690 0.034496 0.798E-04 + 4 -229.1083612184 0.034732 0.175E-05 + 5 -229.1083646631 0.034734 0.724E-07 + 6 -229.1083647955 0.034725 0.228E-08 + 7 -229.1083648002 0.034726 0.559E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 8.742447 GB ] [ VIRT MEM : 14.399044 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373.327126 s ] [ CPU TIME: 22688.137404 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.741386 GB ] [ VIRT MEM : 14.396744 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373.327750 s ] [ CPU TIME: 22688.182733 s ] <<<<< .. + +* Energy of state 1 -229.1083648001895 +* S^2 of state 1 0.3472550438209854E-01 +* Saved determinants 5120 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.741402 GB ] [ VIRT MEM : 14.399498 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373.541743 s ] [ CPU TIME: 22697.624094 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 8.741402 GB ] [ VIRT MEM : 14.399498 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373.542144 s ] [ CPU TIME: 22697.652904 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 93 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -229.1083648001895 + +.. >>>>> [ RES MEM : 8.742027 GB ] [ VIRT MEM : 14.399498 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373.550585 s ] [ CPU TIME: 22698.249649 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 8.742027 GB ] [ VIRT MEM : 14.399498 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373.550978 s ] [ CPU TIME: 22698.277711 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 93 +* pt2_n_tasks_max 1 +* Number of tasks 5120 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1225062847137451 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6262129720 0.995E-03 2.6394536289 0.1166586191 115.5414 + 14 -229.6260775952 0.240E-03 2.6369478667 0.1166741900 118.1759 + 15 -229.6259907455 0.231E-03 2.6363810598 0.1166632010 122.5737 + 16 -229.6260908120 0.234E-03 2.6370885341 0.1166785682 126.2910 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.841839 GB ] [ VIRT MEM : 14.491184 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 499.880724 s ] [ CPU TIME: 31744.334770 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 8.841839 GB ] [ VIRT MEM : 14.491184 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 499.881153 s ] [ CPU TIME: 31744.365800 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 93 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.4639855741856925 + +Summary at N_det = 5120 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.10836480 +# PT2 -0.51772601 0.00023413 +# rPT2 -0.46363029 0.00020966 +# +# E+PT2 -229.62609081 0.00023413 +# E+rPT2 -229.57199509 0.00020966 +# ============ ============================= + + N_det = 5120 + N_states = 1 + + * State 1 + < S^2 > = 3.472550438209854E-002 + E = -229.108364800189 + Variance = 2.63708853409067 + PT norm = 0.341582447216161 + PT2 = -0.517726011815542 + rPT2 = -0.463630293029323 + E+PT2 = -229.626090812005 +/- 2.341272390196389E-004 + E+rPT2 = -229.571995093219 +/- 2.096639495708702E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.432837508192 + Vee = 239.207357164710 + Vecp = 0.000000000000000E+000 + T = 229.008885764504 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.5201 -229.63735076 + -0.5705 -229.63481413 + -0.6167 -229.62827552 + -0.6566 -229.62704642 + -0.6892 -229.62788960 + -0.7185 -229.63029654 + -0.7408 -229.63335504 + =========== =================== + +* Number of unique alpha determinants 1781 +* Number of unique beta determinants 1781 + +.. >>>>> [ RES MEM : 8.843113 GB ] [ VIRT MEM : 14.491184 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 499.956749 s ] [ CPU TIME: 31749.669417 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 10240 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.2087812870740891E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.1083818717 0.034725 0.214E-01 + 2 -229.1755362730 0.030965 0.128E-02 + 3 -229.1764961676 0.029818 0.101E-03 + 4 -229.1766212632 0.030020 0.314E-05 + 5 -229.1766265759 0.030021 0.197E-06 + 6 -229.1766269387 0.030013 0.786E-08 + 7 -229.1766269553 0.030012 0.343E-09 + 8 -229.1766269561 0.030012 0.130E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 8.854446 GB ] [ VIRT MEM : 14.500362 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 500.117516 s ] [ CPU TIME: 31761.149568 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.851715 GB ] [ VIRT MEM : 14.495773 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 500.118348 s ] [ CPU TIME: 31761.210067 s ] <<<<< .. + +* Energy of state 1 -229.1766269560631 +* S^2 of state 1 0.3001189343387325E-01 +* Saved determinants 10240 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.849567 GB ] [ VIRT MEM : 14.493057 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 500.658054 s ] [ CPU TIME: 31788.161164 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 8.849567 GB ] [ VIRT MEM : 14.493057 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 500.658491 s ] [ CPU TIME: 31788.192845 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 100 +* pt2_n_tasks_max 2 +* PT2 Energy denominator -229.1766269560631 + +.. >>>>> [ RES MEM : 8.846939 GB ] [ VIRT MEM : 14.491184 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 500.667552 s ] [ CPU TIME: 31788.843105 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 8.846939 GB ] [ VIRT MEM : 14.491184 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 500.667967 s ] [ CPU TIME: 31788.873331 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 100 +* pt2_n_tasks_max 2 +* Number of tasks 10587 +* Number of fragmented tasks 347 +* Number of threads for PT2 72 +* Memory (Gb) 0.2222455322742462 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6160969682 0.589E-03 2.3917537467 0.0913316999 114.5550 + 8 -229.6167346429 0.428E-03 2.3978425055 0.0913925861 117.2712 + 9 -229.6169520736 0.500E-03 2.4010570758 0.0913738602 128.6165 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 9.004078 GB ] [ VIRT MEM : 14.630657 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 637.175640 s ] [ CPU TIME: 41576.139410 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 9.004078 GB ] [ VIRT MEM : 14.630657 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 637.176058 s ] [ CPU TIME: 41576.169850 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 100 +* pt2_n_tasks_max 2 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.5378735521753327 + +Summary at N_det = 10240 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.17662696 +# PT2 -0.44032512 0.00050039 +# rPT2 -0.40345947 0.00045849 +# +# E+PT2 -229.61695207 0.00050039 +# E+rPT2 -229.58008642 0.00045849 +# ============ ============================= + + N_det = 10240 + N_states = 1 + + * State 1 + < S^2 > = 3.001189343387325E-002 + E = -229.176626956063 + Variance = 2.40105707583223 + PT norm = 0.302281094738255 + PT2 = -0.440325117499553 + rPT2 = -0.403459468421090 + E+PT2 = -229.616952073563 +/- 5.003873397270396E-004 + E+rPT2 = -229.580086424484 +/- 4.584930590318179E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.437096445811 + Vee = 239.106680040198 + Vecp = 0.000000000000000E+000 + T = 229.045559670761 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4636 -229.63434070 + -0.5201 -229.63565585 + -0.5705 -229.63487757 + -0.6167 -229.63108486 + -0.6566 -229.62976838 + -0.6892 -229.62989128 + -0.7185 -229.63124391 + =========== =================== + +* Number of unique alpha determinants 3119 +* Number of unique beta determinants 3120 + +.. >>>>> [ RES MEM : 9.006138 GB ] [ VIRT MEM : 14.630657 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 637.299785 s ] [ CPU TIME: 41584.881017 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 20480 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.3985065594315529E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.1766591886 0.030018 0.188E-01 + 2 -229.2429815360 0.024300 0.999E-03 + 3 -229.2439254286 0.023455 0.108E-03 + 4 -229.2440586083 0.023589 0.261E-05 + 5 -229.2440643470 0.023584 0.163E-06 + 6 -229.2440646722 0.023576 0.886E-08 + 7 -229.2440646912 0.023575 0.553E-09 + 8 -229.2440646923 0.023575 0.248E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 9.025131 GB ] [ VIRT MEM : 14.653809 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 637.750825 s ] [ CPU TIME: 41617.252835 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 9.016979 GB ] [ VIRT MEM : 14.639938 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 637.752467 s ] [ CPU TIME: 41617.371180 s ] <<<<< .. + +* Energy of state 1 -229.2440646923496 +* S^2 of state 1 0.2357490408333245E-01 +* Saved determinants 20480 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 9.011219 GB ] [ VIRT MEM : 14.630657 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 638.300291 s ] [ CPU TIME: 41639.059363 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 9.011219 GB ] [ VIRT MEM : 14.630657 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 638.300757 s ] [ CPU TIME: 41639.092878 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 +* PT2 Energy denominator -229.2440646923496 + +.. >>>>> [ RES MEM : 9.015141 GB ] [ VIRT MEM : 14.635563 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 638.314719 s ] [ CPU TIME: 41640.095265 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 9.015141 GB ] [ VIRT MEM : 14.635563 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 638.315150 s ] [ CPU TIME: 41640.126800 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 +* Number of tasks 21194 +* Number of fragmented tasks 357 +* Number of threads for PT2 72 +* Memory (Gb) 0.4216868340969085 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6131213840 0.193E-02 2.1554665964 0.0704138138 151.1675 + 8 -229.6115867244 0.899E-03 2.1434888620 0.0702553710 160.1223 + 9 -229.6109307597 0.974E-03 2.1390692895 0.0701505218 170.9463 + 12 -229.6107326778 0.742E-03 2.1358472377 0.0701761602 188.7403 + 13 -229.6109604051 0.718E-03 2.1378631559 0.0701963891 203.7714 + 14 -229.6114482173 0.739E-03 2.1413400265 0.0702666930 224.2328 + 18 -229.6113858779 0.657E-03 2.1408027760 0.0702572998 240.4788 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 9.195686 GB ] [ VIRT MEM : 14.757458 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 890.000099 s ] [ CPU TIME: 59695.973475 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 9.195686 GB ] [ VIRT MEM : 14.757458 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 890.000553 s ] [ CPU TIME: 59696.006154 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.6100953612375624 + +Summary at N_det = 20480 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.24406469 +# PT2 -0.36732119 0.00065703 +# rPT2 -0.34320830 0.00061390 +# +# E+PT2 -229.61138588 0.00065703 +# E+rPT2 -229.58727299 0.00061390 +# ============ ============================= + + N_det = 20480 + N_states = 1 + + * State 1 + < S^2 > = 2.357490408333245E-002 + E = -229.244064692350 + Variance = 2.14080277599700 + PT norm = 0.265060936014814 + PT2 = -0.367321185556197 + rPT2 = -0.343208297317363 + E+PT2 = -229.611385877906 +/- 6.570336498838788E-004 + E+rPT2 = -229.587272989667 +/- 6.139025167181903E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.452138513771 + Vee = 239.014888427914 + Vecp = 0.000000000000000E+000 + T = 229.084955614719 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4035 -229.62820977 + -0.4636 -229.63096752 + -0.5201 -229.63278682 + -0.5705 -229.63304739 + -0.6167 -229.63103323 + -0.6566 -229.63017675 + -0.6892 -229.63020774 + =========== =================== + +* Number of unique alpha determinants 5649 +* Number of unique beta determinants 5648 + +.. >>>>> [ RES MEM : 9.200565 GB ] [ VIRT MEM : 14.757458 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 890.236960 s ] [ CPU TIME: 59712.882292 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 40960 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.7719568163156509E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.2440682405 0.023578 0.153E-01 + 2 -229.3054354334 0.017176 0.708E-03 + 3 -229.3063725709 0.016637 0.119E-03 + 4 -229.3065073870 0.016764 0.285E-05 + 5 -229.3065145194 0.016766 0.197E-06 + 6 -229.3065149412 0.016761 0.112E-07 + 7 -229.3065149674 0.016760 0.616E-09 + 8 -229.3065149690 0.016760 0.403E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 9.235298 GB ] [ VIRT MEM : 14.805088 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 891.593348 s ] [ CPU TIME: 59810.299475 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 9.218910 GB ] [ VIRT MEM : 14.777248 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 891.596142 s ] [ CPU TIME: 59810.500861 s ] <<<<< .. + +* Energy of state 1 -229.3065149689926 +* S^2 of state 1 0.1676042243388065E-01 +* Saved determinants 40960 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 9.206879 GB ] [ VIRT MEM : 14.759480 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 892.480894 s ] [ CPU TIME: 59844.429654 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 9.206879 GB ] [ VIRT MEM : 14.759480 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 892.481395 s ] [ CPU TIME: 59844.465230 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 +* PT2 Energy denominator -229.3065149689926 + +.. >>>>> [ RES MEM : 9.217926 GB ] [ VIRT MEM : 14.769268 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 892.504195 s ] [ CPU TIME: 59846.102713 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 9.217926 GB ] [ VIRT MEM : 14.769268 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 892.504689 s ] [ CPU TIME: 59846.138569 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 +* Number of tasks 51065 +* Number of fragmented tasks 8806 +* Number of threads for PT2 72 +* Memory (Gb) 0.8205694377422332 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6100014080 0.178E-02 1.8927198160 0.0536594103 182.2602 + 8 -229.6096286435 0.798E-03 1.8906961610 0.0535531964 205.1941 + 9 -229.6095356856 0.609E-03 1.8904582340 0.0535381553 231.7744 + 11 -229.6096176234 0.465E-03 1.8911954955 0.0535574981 237.7181 + 12 -229.6098550945 0.489E-03 1.8936782402 0.0535733111 257.4569 + 13 -229.6097263083 0.467E-03 1.8923729131 0.0535618591 261.9601 + 14 -229.6096894292 0.434E-03 1.8914620394 0.0535759993 272.6980 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 9.910763 GB ] [ VIRT MEM : 15.374176 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1165.463570 s ] [ CPU TIME: 79423.777918 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 9.910763 GB ] [ VIRT MEM : 15.374176 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1165.464050 s ] [ CPU TIME: 79423.812422 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.6756696686749257 + +Summary at N_det = 40960 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.30651497 +# PT2 -0.30317446 0.00043368 +# rPT2 -0.28775756 0.00041163 +# +# E+PT2 -229.60968943 0.00043368 +# E+rPT2 -229.59427253 0.00041163 +# ============ ============================= + + N_det = 40960 + N_states = 1 + + * State 1 + < S^2 > = 1.676042243388065E-002 + E = -229.306514968993 + Variance = 1.89146203941882 + PT norm = 0.231464898590599 + PT2 = -0.303174460220198 + rPT2 = -0.287757561322117 + E+PT2 = -229.609689429213 +/- 4.336828866924833E-004 + E+rPT2 = -229.594272530315 +/- 4.116294287161430E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.493982457798 + Vee = 238.955486460545 + Vecp = 0.000000000000000E+000 + T = 229.123751249471 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3432 -229.63059614 + -0.4035 -229.62947076 + -0.4636 -229.63056764 + -0.5201 -229.63178593 + -0.5705 -229.63215953 + -0.6167 -229.63094616 + -0.6566 -229.63036157 + =========== =================== + +* Number of unique alpha determinants 10331 +* Number of unique beta determinants 10328 + +.. >>>>> [ RES MEM : 9.920082 GB ] [ VIRT MEM : 15.374176 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1166.095965 s ] [ CPU TIME: 79469.131563 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 81920 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.1503715664148331 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.3065155889 0.016759 0.114E-01 + 2 -229.3583880172 0.011299 0.454E-03 + 3 -229.3593035074 0.011025 0.102E-03 + 4 -229.3594082290 0.011115 0.356E-05 + 5 -229.3594169631 0.011113 0.230E-06 + 6 -229.3594175356 0.011110 0.154E-07 + 7 -229.3594175753 0.011110 0.923E-09 + 8 -229.3594175781 0.011110 0.638E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 9.984844 GB ] [ VIRT MEM : 15.480579 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1170.670337 s ] [ CPU TIME: 79797.665709 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 9.951870 GB ] [ VIRT MEM : 15.424908 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1170.675108 s ] [ CPU TIME: 79798.009056 s ] <<<<< .. + +* Energy of state 1 -229.3594175780977 +* S^2 of state 1 0.1111040911605222E-01 +* Saved determinants 81920 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 9.921829 GB ] [ VIRT MEM : 15.389664 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1172.224672 s ] [ CPU TIME: 79849.596189 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 9.921829 GB ] [ VIRT MEM : 15.389664 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1172.225267 s ] [ CPU TIME: 79849.639316 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 +* PT2 Energy denominator -229.3594175780977 + +.. >>>>> [ RES MEM : 9.942085 GB ] [ VIRT MEM : 15.410179 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1172.264531 s ] [ CPU TIME: 79852.458507 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 9.942085 GB ] [ VIRT MEM : 15.410179 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1172.265099 s ] [ CPU TIME: 79852.499895 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 +* Number of tasks 109702 +* Number of fragmented tasks 12385 +* Number of threads for PT2 72 +* Memory (Gb) 1.618334645032883 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6080377951 0.110E-02 1.6317582379 0.0413888028 213.7246 + 5 -229.6076599346 0.754E-03 1.6304894192 0.0412983972 223.9781 + 6 -229.6079923977 0.760E-03 1.6317451585 0.0413771437 233.0131 + 7 -229.6085075094 0.830E-03 1.6360626180 0.0414428490 265.3876 + 8 -229.6092605054 0.106E-02 1.6419104852 0.0415550265 318.9040 + 10 -229.6091259917 0.892E-03 1.6417687456 0.0415313963 337.6071 + 11 -229.6094250280 0.830E-03 1.6432432824 0.0415804545 340.1976 + 12 -229.6096536058 0.791E-03 1.6452881859 0.0416080213 355.1833 + 13 -229.6093134113 0.805E-03 1.6426054793 0.0415587251 369.4010 + 14 -229.6092383199 0.748E-03 1.6419783321 0.0415518801 383.3541 + 15 -229.6091337407 0.734E-03 1.6410730953 0.0415437875 423.9914 + 17 -229.6087497652 0.705E-03 1.6396618144 0.0414626236 446.8681 + 18 -229.6088081345 0.666E-03 1.6401367276 0.0414739518 461.2656 + 19 -229.6088256844 0.630E-03 1.6406038595 0.0414680542 476.7795 + 20 -229.6089394409 0.635E-03 1.6412856511 0.0414895480 513.7852 + 23 -229.6090339272 0.533E-03 1.6428030426 0.0414889705 531.0943 + 24 -229.6089430629 0.519E-03 1.6421304992 0.0414743620 540.2881 + 25 -229.6088598743 0.504E-03 1.6419863824 0.0414530282 543.4761 + 26 -229.6089928604 0.465E-03 1.6428406561 0.0414747069 563.9853 + 27 -229.6090340911 0.449E-03 1.6434585985 0.0414699402 589.7493 + 28 -229.6091320412 0.444E-03 1.6447013195 0.0414754359 613.0111 + 29 -229.6091724997 0.413E-03 1.6448480644 0.0414842026 623.4240 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 10.599472 GB ] [ VIRT MEM : 15.892624 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1820.225675 s ] [ CPU TIME: 126343.006592 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 10.599472 GB ] [ VIRT MEM : 15.892624 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1820.226259 s ] [ CPU TIME: 126343.049271 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7312149711461546 + +Summary at N_det = 81920 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.35941758 +# PT2 -0.24975492 0.00041264 +# rPT2 -0.23980673 0.00039621 +# +# E+PT2 -229.60917250 0.00041264 +# E+rPT2 -229.59922431 0.00039621 +# ============ ============================= + + N_det = 81920 + N_states = 1 + + * State 1 + < S^2 > = 1.111040911605222E-002 + E = -229.359417578098 + Variance = 1.64484806442808 + PT norm = 0.203676710985907 + PT2 = -0.249754921572942 + rPT2 = -0.239806730577301 + E+PT2 = -229.609172499671 +/- 4.126428795964624E-004 + E+rPT2 = -229.599224308675 +/- 3.962065661361961E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.528486795056 + Vee = 238.891624404543 + Vecp = 0.000000000000000E+000 + T = 229.169215033625 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2878 -229.62398863 + -0.3432 -229.62721838 + -0.4035 -229.62782294 + -0.4636 -229.62898937 + -0.5201 -229.63015670 + -0.5705 -229.63069849 + -0.6167 -229.63003171 + =========== =================== + +* Number of unique beta determinants 19431 +* Number of unique alpha determinants 19435 + +.. >>>>> [ RES MEM : 10.592014 GB ] [ VIRT MEM : 15.880005 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1822.806548 s ] [ CPU TIME: 126528.124090 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 163840 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.2956763058900833 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.3594189755 0.011110 0.787E-02 + 2 -229.3999943895 0.007157 0.319E-03 + 3 -229.4008732284 0.007043 0.697E-04 + 4 -229.4009543405 0.007104 0.479E-05 + 5 -229.4009646441 0.007116 0.413E-06 + 6 -229.4009656455 0.007119 0.328E-07 + 7 -229.4009657443 0.007122 0.317E-08 + 8 -229.4009657538 0.007123 0.288E-09 + 9 -229.4009657548 0.007123 0.289E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 10.791767 GB ] [ VIRT MEM : 16.096462 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1844.782984 s ] [ CPU TIME: 128098.753306 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 10.718586 GB ] [ VIRT MEM : 15.985615 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1844.793444 s ] [ CPU TIME: 128099.505246 s ] <<<<< .. + +* Energy of state 1 -229.4009657547833 +* S^2 of state 1 0.7123027130826926E-02 +* Saved determinants 163840 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 10.617191 GB ] [ VIRT MEM : 15.881107 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1847.658963 s ] [ CPU TIME: 128171.073938 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 10.617191 GB ] [ VIRT MEM : 15.881107 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1847.659776 s ] [ CPU TIME: 128171.132758 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 +* PT2 Energy denominator -229.4009657547833 + +.. >>>>> [ RES MEM : 10.645077 GB ] [ VIRT MEM : 15.909214 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1847.733773 s ] [ CPU TIME: 128176.446505 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 10.645077 GB ] [ VIRT MEM : 15.909214 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1847.734563 s ] [ CPU TIME: 128176.503721 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 +* Number of tasks 218978 +* Number of fragmented tasks 15970 +* Number of threads for PT2 72 +* Memory (Gb) 3.213865059614181 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6097705887 0.151E-02 1.4247375209 0.0333067448 255.8303 + 4 -229.6092252579 0.134E-02 1.4221773530 0.0332183329 344.9863 + 5 -229.6098734451 0.132E-02 1.4305414204 0.0332576286 359.6133 + 6 -229.6098357748 0.113E-02 1.4278875591 0.0333239769 428.7863 + 7 -229.6101316552 0.961E-03 1.4336361057 0.0332814637 442.3086 + 8 -229.6097046108 0.938E-03 1.4297780674 0.0332371587 523.1803 + 10 -229.6087105796 0.110E-02 1.4216282120 0.0331174412 524.2577 + 11 -229.6087274905 0.993E-03 1.4225281783 0.0330982933 555.0366 + 12 -229.6089670961 0.875E-03 1.4253635184 0.0331264712 595.6733 + 14 -229.6091269600 0.828E-03 1.4262531603 0.0331555368 625.5403 + 15 -229.6090786750 0.771E-03 1.4246762793 0.0331791638 665.5333 + 16 -229.6087664631 0.781E-03 1.4222298164 0.0331371629 669.7853 + 17 -229.6090550290 0.789E-03 1.4254317306 0.0331642151 681.8963 + 18 -229.6090595510 0.743E-03 1.4255772106 0.0331624014 712.5833 + 19 -229.6090647961 0.672E-03 1.4249606331 0.0331786162 776.9893 + 22 -229.6094567345 0.643E-03 1.4292338205 0.0332009872 805.2975 + 24 -229.6093990433 0.574E-03 1.4298710309 0.0331743013 834.7057 + 25 -229.6094199989 0.551E-03 1.4301775881 0.0331710471 844.9741 + 26 -229.6093515388 0.533E-03 1.4296451923 0.0331631079 916.2763 + 28 -229.6094008891 0.560E-03 1.4297163034 0.0331790809 930.6723 + 29 -229.6095237843 0.554E-03 1.4306440666 0.0332000911 989.4300 + 30 -229.6095394076 0.528E-03 1.4311176026 0.0331932710 1010.3513 + 32 -229.6092330566 0.539E-03 1.4282535813 0.0331584855 1018.6815 + 33 -229.6091063365 0.527E-03 1.4272095163 0.0331451135 1098.3633 + 34 -229.6090302052 0.516E-03 1.4267725587 0.0331325790 1134.1885 + 38 -229.6088641762 0.470E-03 1.4248786479 0.0331205994 1143.5443 + 39 -229.6089376122 0.463E-03 1.4249942398 0.0331407083 1153.3397 + 40 -229.6089519416 0.452E-03 1.4248224969 0.0331474587 1154.6824 + 41 -229.6090337614 0.448E-03 1.4257412804 0.0331541443 1243.8356 + 43 -229.6089276277 0.440E-03 1.4247550683 0.0331435719 1269.1863 + 44 -229.6089304432 0.430E-03 1.4246837259 0.0331464454 1292.7323 + 46 -229.6089922070 0.411E-03 1.4253367815 0.0331492217 1313.5073 + 47 -229.6089945447 0.403E-03 1.4254218304 0.0331471359 1330.2431 + 50 -229.6091158903 0.376E-03 1.4267019708 0.0331552356 1393.5766 + 52 -229.6090703515 0.365E-03 1.4258836275 0.0331586020 1405.7410 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 12.405186 GB ] [ VIRT MEM : 17.115452 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3254.150035 s ] [ CPU TIME: 229087.614157 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 12.405186 GB ] [ VIRT MEM : 17.115452 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3254.150840 s ] [ CPU TIME: 229087.671465 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7750326598781910 + +Summary at N_det = 163840 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.40096575 +# PT2 -0.20810460 0.00036474 +# rPT2 -0.20142561 0.00035303 +# +# E+PT2 -229.60907035 0.00036474 +# E+rPT2 -229.60239136 0.00035303 +# ============ ============================= + + N_det = 163840 + N_states = 1 + + * State 1 + < S^2 > = 7.123027130826926E-003 + E = -229.400965754783 + Variance = 1.42588362747232 + PT norm = 0.182095035613465 + PT2 = -0.208104596717451 + rPT2 = -0.201425605241628 + E+PT2 = -229.609070351501 +/- 3.647363842768916E-004 + E+rPT2 = -229.602391360025 +/- 3.530303900800627E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.558017179929 + Vee = 238.840042883609 + Vecp = 0.000000000000000E+000 + T = 229.208778762747 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2398 -229.61901217 + -0.2878 -229.62157293 + -0.3432 -229.62448484 + -0.4035 -229.62573230 + -0.4636 -229.62705421 + -0.5201 -229.62826752 + -0.5705 -229.62895217 + =========== =================== + +* Number of unique beta determinants 38063 +* Number of unique alpha determinants 38143 + +.. >>>>> [ RES MEM : 12.210995 GB ] [ VIRT MEM : 16.916683 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3265.176980 s ] [ CPU TIME: 229879.221114 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 327680 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.5882993042469025 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.4009663010 0.007123 0.510E-02 + 2 -229.4302037001 0.004862 0.232E-03 + 3 -229.4310075339 0.004815 0.353E-04 + 4 -229.4310760743 0.004846 0.604E-05 + 5 -229.4310864971 0.004858 0.990E-06 + 6 -229.4310883547 0.004861 0.934E-07 + 7 -229.4310886552 0.004864 0.104E-07 + 8 -229.4310886885 0.004865 0.957E-09 + 9 -229.4310886918 0.004865 0.100E-09 + 10 -229.4310886921 0.004865 0.117E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 12.568295 GB ] [ VIRT MEM : 17.334187 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3374.289258 s ] [ CPU TIME: 237660.887682 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 12.260757 GB ] [ VIRT MEM : 16.966499 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3374.341244 s ] [ CPU TIME: 237664.621235 s ] <<<<< .. + +* Energy of state 1 -229.4310886920963 +* S^2 of state 1 0.4864913266398860E-02 +* Saved determinants 327680 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 12.220970 GB ] [ VIRT MEM : 16.923744 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3379.889716 s ] [ CPU TIME: 237772.639648 s ] <<<<< .. + +* Number of generators 327680 + +.. >>>>> [ RES MEM : 12.220970 GB ] [ VIRT MEM : 16.923744 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3379.890907 s ] [ CPU TIME: 237772.725570 s ] <<<<< .. + +* Number of selectors 327680 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 +* PT2 Energy denominator -229.4310886920963 + +.. >>>>> [ RES MEM : 12.296017 GB ] [ VIRT MEM : 17.002361 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3380.064820 s ] [ CPU TIME: 237785.214612 s ] <<<<< .. + +* Number of generators 327680 + +.. >>>>> [ RES MEM : 12.296017 GB ] [ VIRT MEM : 17.002361 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3380.066001 s ] [ CPU TIME: 237785.299933 s ] <<<<< .. + +* Number of selectors 327680 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 +* Number of tasks 419716 +* Number of fragmented tasks 18900 +* Number of threads for PT2 72 +* Memory (Gb) 6.404925888776779 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6114402368 0.552E-03 1.2829329460 0.0278152573 555.3151 + 4 -229.6112575692 0.421E-03 1.2797200631 0.0278015021 595.7963 + 5 -229.6100060839 0.142E-02 1.2664262532 0.0277091804 796.0210 + 7 -229.6092669388 0.173E-02 1.2577883797 0.0276447951 817.6554 + 10 -229.6089003014 0.145E-02 1.2520237823 0.0276361323 843.1943 + 11 -229.6090694378 0.132E-02 1.2528921909 0.0276642271 876.4943 + 12 -229.6089520526 0.121E-02 1.2504853004 0.0276808656 929.9839 + 13 -229.6089184195 0.111E-02 1.2513378929 0.0276549556 1076.3123 + 14 -229.6089378247 0.103E-02 1.2507140913 0.0276745977 1101.5872 + 15 -229.6088899199 0.942E-03 1.2505318022 0.0276579070 1133.5763 + 18 -229.6089406690 0.790E-03 1.2496670003 0.0276823538 1198.6263 + 19 -229.6090752038 0.741E-03 1.2500000951 0.0277253813 1219.7958 + 20 -229.6090370821 0.704E-03 1.2505278587 0.0277015039 1274.5556 + 22 -229.6087732856 0.631E-03 1.2485111505 0.0276662513 1355.2244 + 24 -229.6089616281 0.603E-03 1.2500837097 0.0276923533 1370.7101 + 27 -229.6090389457 0.560E-03 1.2508377274 0.0276969191 1629.7343 + 32 -229.6093472641 0.516E-03 1.2535436856 0.0277352146 1759.0822 + 34 -229.6095772718 0.494E-03 1.2552510818 0.0277668604 1800.7363 + 35 -229.6096005417 0.456E-03 1.2550480710 0.0277794361 1862.1163 + 38 -229.6095489557 0.430E-03 1.2544023529 0.0277766624 1882.9766 + 40 -229.6097001801 0.425E-03 1.2553803501 0.0277984403 1905.9013 + 41 -229.6096282710 0.421E-03 1.2547045306 0.0277896031 2000.6013 + 42 -229.6095503820 0.418E-03 1.2540829525 0.0277773270 2350.4643 + 58 -229.6097450523 0.354E-03 1.2549832310 0.0278153229 2411.0188 + 59 -229.6097563084 0.335E-03 1.2550748521 0.0278168903 2412.4279 + 60 -229.6097058306 0.333E-03 1.2545779921 0.0278111095 2635.5358 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.117435 GB ] [ VIRT MEM : 20.085648 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6017.097546 s ] [ CPU TIME: 426978.134414 s ] <<<<< .. + +* Number of generators 327680 + +.. >>>>> [ RES MEM : 16.117435 GB ] [ VIRT MEM : 20.085648 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6017.098623 s ] [ CPU TIME: 426978.212679 s ] <<<<< .. + +* Number of selectors 327680 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8064285078652442 + +Summary at N_det = 327680 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.43108869 +# PT2 -0.17863240 0.00030530 +# rPT2 -0.17379825 0.00029704 +# +# E+PT2 -229.60972109 0.00030530 +# E+rPT2 -229.60488695 0.00029704 +# ============ ============================= + + N_det = 327680 + N_states = 1 + + * State 1 + < S^2 > = 4.864913266398860E-003 + E = -229.431088692096 + Variance = 1.25458980470710 + PT norm = 0.166777419430299 + PT2 = -0.178632401538825 + rPT2 = -0.173798253919141 + E+PT2 = -229.609721093635 +/- 3.053021754182815E-004 + E+rPT2 = -229.604886946015 +/- 2.970400921015452E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.571547279040 + Vee = 238.792122945946 + Vecp = 0.000000000000000E+000 + T = 229.240105862208 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2014 -229.62058619 + -0.2398 -229.61971268 + -0.2878 -229.62106288 + -0.3432 -229.62327124 + -0.4035 -229.62451322 + -0.4636 -229.62577325 + -0.5201 -229.62692675 + =========== =================== + +* Number of unique beta determinants 76905 +* Number of unique alpha determinants 77253 + +.. >>>>> [ RES MEM : 16.000683 GB ] [ VIRT MEM : 19.957195 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6063.136271 s ] [ CPU TIME: 430235.576604 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 655360 +* Number of threads for diagonalization 72 +* Memory(Gb) 1.180367104709148 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.4310888038 0.004865 0.310E-02 + 2 -229.4497946502 0.003718 0.177E-03 + 3 -229.4504565467 0.003738 0.218E-04 + 4 -229.4505321131 0.003767 0.644E-05 + 5 -229.4505474498 0.003781 0.126E-05 + 6 -229.4505509796 0.003794 0.355E-06 + 7 -229.4505518063 0.003803 0.359E-07 + 8 -229.4505519337 0.003804 0.502E-08 + 9 -229.4505519515 0.003803 0.703E-09 + 10 -229.4505519540 0.003803 0.105E-09 + 11 -229.4505519544 0.003803 0.164E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 16.751488 GB ] [ VIRT MEM : 20.800976 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6557.816018 s ] [ CPU TIME: 465360.586625 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 16.107079 GB ] [ VIRT MEM : 20.067078 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6557.902720 s ] [ CPU TIME: 465366.534586 s ] <<<<< .. + +* Energy of state 1 -229.4505519544271 +* S^2 of state 1 0.3803143713824979E-02 +* Saved determinants 655360 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 15.953159 GB ] [ VIRT MEM : 19.907383 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6568.740707 s ] [ CPU TIME: 465545.295012 s ] <<<<< .. + +* Number of generators 655358 + +.. >>>>> [ RES MEM : 15.953159 GB ] [ VIRT MEM : 19.907383 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6568.742629 s ] [ CPU TIME: 465545.429550 s ] <<<<< .. + +* Number of selectors 655358 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 +* PT2 Energy denominator -229.4505519544271 + +.. >>>>> [ RES MEM : 16.109344 GB ] [ VIRT MEM : 20.064621 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6569.130034 s ] [ CPU TIME: 465572.796451 s ] <<<<< .. + +* Number of generators 655358 + +.. >>>>> [ RES MEM : 16.109344 GB ] [ VIRT MEM : 20.064621 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6569.131908 s ] [ CPU TIME: 465572.931652 s ] <<<<< .. + +* Number of selectors 655358 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 +* Number of tasks 838114 +* Number of fragmented tasks 21062 +* Number of threads for PT2 72 +* Memory (Gb) 12.78708426900208 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6119901782 0.293E-02 1.1580618764 0.0246618515 939.7118 + 4 -229.6116269586 0.202E-02 1.1525521804 0.0246457317 943.5957 + 5 -229.6101950044 0.225E-02 1.1402471281 0.0244828662 1059.1195 + 6 -229.6095763608 0.189E-02 1.1338372390 0.0244430163 1225.0148 + 7 -229.6102547050 0.173E-02 1.1377033215 0.0245713148 1487.3877 + 8 -229.6097174491 0.151E-02 1.1335904971 0.0245020162 1613.3186 + 12 -229.6110001649 0.129E-02 1.1432658137 0.0246882563 1910.5682 + 17 -229.6111391901 0.103E-02 1.1433119809 0.0247136072 2001.7237 + 18 -229.6110760280 0.976E-03 1.1433776884 0.0247015973 2062.0038 + 19 -229.6108098824 0.925E-03 1.1403622466 0.0246886208 2131.8518 + 20 -229.6107482658 0.879E-03 1.1397416386 0.0246794707 2156.5737 + 22 -229.6107750212 0.830E-03 1.1401512688 0.0246741964 2186.0228 + 23 -229.6104267787 0.867E-03 1.1372697399 0.0246260811 2244.4297 + 24 -229.6105807189 0.844E-03 1.1377475160 0.0246605870 2371.7247 + 25 -229.6105441432 0.801E-03 1.1379892750 0.0246401990 2410.9756 + 26 -229.6106938063 0.784E-03 1.1394217150 0.0246558344 2467.1477 + 27 -229.6107206151 0.755E-03 1.1391384626 0.0246650071 2573.2847 + 28 -229.6107264604 0.727E-03 1.1393898471 0.0246602761 2655.4637 + 29 -229.6108998815 0.723E-03 1.1409300130 0.0246807707 2708.3357 + 30 -229.6109557200 0.673E-03 1.1411458524 0.0246903452 2796.3317 + 32 -229.6109488180 0.624E-03 1.1409988068 0.0246910998 2972.4158 + 34 -229.6106498809 0.623E-03 1.1387146238 0.0246477843 3117.4826 + 35 -229.6107487125 0.613E-03 1.1396708870 0.0246593327 3158.1808 + 37 -229.6106830819 0.573E-03 1.1388944841 0.0246557986 3203.5807 + 38 -229.6108862350 0.594E-03 1.1408896830 0.0246754193 3327.2099 + 41 -229.6107663675 0.561E-03 1.1396948961 0.0246618922 3517.5767 + 43 -229.6107259759 0.541E-03 1.1394703567 0.0246524882 3539.8028 + 45 -229.6107501672 0.518E-03 1.1399762857 0.0246497645 3616.2998 + 46 -229.6106621735 0.518E-03 1.1387698191 0.0246506477 3677.7404 + 47 -229.6106558539 0.507E-03 1.1387101683 0.0246502677 3872.2360 + 49 -229.6107327120 0.505E-03 1.1390289911 0.0246664238 3884.6092 + 52 -229.6106625255 0.452E-03 1.1387480292 0.0246548404 4202.0406 + 59 -229.6104599560 0.397E-03 1.1364909752 0.0246430387 4217.2337 + 61 -229.6105381253 0.388E-03 1.1370698934 0.0246531322 4280.8188 + 63 -229.6104258215 0.359E-03 1.1363411503 0.0246374198 4374.2419 + 65 -229.6103857219 0.349E-03 1.1363136544 0.0246279773 4413.7738 + 68 -229.6103622867 0.335E-03 1.1360107008 0.0246258417 4444.8768 + 69 -229.6104047608 0.333E-03 1.1364784189 0.0246299375 4602.1168 + 70 -229.6104572702 0.332E-03 1.1370917876 0.0246335964 4634.3750 + 71 -229.6105647859 0.332E-03 1.1379875800 0.0246474783 4733.8008 + 74 -229.6105692839 0.333E-03 1.1381532245 0.0246460205 4891.8048 + 80 -229.6106362320 0.314E-03 1.1394500581 0.0246444047 4960.6328 + 81 -229.6106175195 0.310E-03 1.1393675986 0.0246406354 4963.9067 + 84 -229.6106894060 0.306E-03 1.1399707937 0.0246483692 5008.1451 + 85 -229.6106351281 0.308E-03 1.1394884164 0.0246419379 5106.6588 + 86 -229.6106769508 0.307E-03 1.1399102242 0.0246467606 5305.0927 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 17.751541 GB ] [ VIRT MEM : 21.027313 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11877.131645 s ] [ CPU TIME: 846364.537516 s ] <<<<< .. + +* Number of generators 655358 + +.. >>>>> [ RES MEM : 17.751541 GB ] [ VIRT MEM : 21.027313 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11877.133525 s ] [ CPU TIME: 846364.672884 s ] <<<<< .. + +* Number of selectors 655358 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8263221792243254 + +Summary at N_det = 655360 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.45055195 +# PT2 -0.16012500 0.00030686 +# rPT2 -0.15627336 0.00029948 +# +# E+PT2 -229.61067695 0.00030686 +# E+rPT2 -229.60682532 0.00029948 +# ============ ============================= + + N_det = 655360 + N_states = 1 + + * State 1 + < S^2 > = 3.803143713824979E-003 + E = -229.450551954427 + Variance = 1.13991022418847 + PT norm = 0.156992867866944 + PT2 = -0.160124996390994 + rPT2 = -0.156273364201445 + E+PT2 = -229.610676950818 +/- 3.068595022743165E-004 + E+rPT2 = -229.606825318628 +/- 2.994783315435292E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.579847673765 + Vee = 238.759558490200 + Vecp = 0.000000000000000E+000 + T = 229.261507450349 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1738 -229.62411022 + -0.2014 -229.62197375 + -0.2398 -229.62069661 + -0.2878 -229.62132851 + -0.3432 -229.62296220 + -0.4035 -229.62402522 + -0.4636 -229.62513840 + =========== =================== + +* Number of unique beta determinants 155927 +* Number of unique alpha determinants 156351 + +.. >>>>> [ RES MEM : 18.023392 GB ] [ VIRT MEM : 21.332363 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12038.536969 s ] [ CPU TIME: 857593.024506 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 1310720 +* Number of threads for diagonalization 72 +* Memory(Gb) 2.368038445711136 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.4505519801 0.003803 0.200E-02 + 2 -229.4619102891 0.004225 0.157E-03 + 3 -229.4623560556 0.004411 0.321E-04 + 4 -229.4624239445 0.004542 0.852E-05 + 5 -229.4624410121 0.004611 0.124E-05 + 6 -229.4624446422 0.004665 0.224E-06 + 7 -229.4624454387 0.004699 0.410E-07 + 8 -229.4624455841 0.004709 0.751E-08 + 9 -229.4624456109 0.004710 0.112E-08 + 10 -229.4624456153 0.004709 0.182E-09 + 11 -229.4624456160 0.004709 0.304E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 19.401897 GB ] [ VIRT MEM : 22.886803 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13816.875737 s ] [ CPU TIME: 980687.069607 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 18.113033 GB ] [ VIRT MEM : 21.420483 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13817.022842 s ] [ CPU TIME: 980692.985622 s ] <<<<< .. + +* Energy of state 1 -229.4624456159761 +* S^2 of state 1 0.4708649202323860E-02 +* Saved determinants 1310720 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 17.882206 GB ] [ VIRT MEM : 21.183155 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13838.776984 s ] [ CPU TIME: 981018.142729 s ] <<<<< .. + +* Number of generators 1310681 + +.. >>>>> [ RES MEM : 17.882206 GB ] [ VIRT MEM : 21.183155 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13838.780286 s ] [ CPU TIME: 981018.376973 s ] <<<<< .. + +* Number of selectors 1310681 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 +* PT2 Energy denominator -229.4624456159761 + +.. >>>>> [ RES MEM : 18.271793 GB ] [ VIRT MEM : 21.574783 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13839.685716 s ] [ CPU TIME: 981072.688667 s ] <<<<< .. + +* Number of generators 1310681 + +.. >>>>> [ RES MEM : 18.271793 GB ] [ VIRT MEM : 21.574783 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13839.688991 s ] [ CPU TIME: 981072.924346 s ] <<<<< .. + +* Number of selectors 1310681 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 +* Number of tasks 1608853 +* Number of fragmented tasks 22412 +* Number of threads for PT2 72 +* Memory (Gb) 25.55140013571829 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6084577828 0.263E-02 1.0572907039 0.0221133714 1571.0882 + 4 -229.6079971229 0.171E-02 1.0567013346 0.0219839473 1864.2443 + 5 -229.6090965798 0.172E-02 1.0646580080 0.0221560647 1999.8263 + 6 -229.6093941327 0.145E-02 1.0661872241 0.0222138313 2256.9782 + 7 -229.6108422152 0.194E-02 1.0735000161 0.0224743071 2454.8795 + 8 -229.6105591532 0.167E-02 1.0693361866 0.0224691663 2809.0783 + 9 -229.6107884639 0.142E-02 1.0681905294 0.0225668661 2867.2313 + 12 -229.6107992356 0.107E-02 1.0659755304 0.0226006820 3176.2423 + 15 -229.6109281696 0.102E-02 1.0685574611 0.0225912050 3480.3313 + 18 -229.6114660808 0.931E-03 1.0712165847 0.0226888202 3606.7693 + 19 -229.6113961575 0.877E-03 1.0702699943 0.0226925863 3618.3392 + 20 -229.6114536213 0.834E-03 1.0704954599 0.0227082380 3833.6573 + 22 -229.6114166257 0.774E-03 1.0701651123 0.0227087514 3898.2214 + 23 -229.6112761859 0.752E-03 1.0691392443 0.0226856157 3965.3630 + 24 -229.6110516760 0.755E-03 1.0679049619 0.0226450182 4552.8442 + 27 -229.6110079991 0.701E-03 1.0677084341 0.0226420535 4677.9392 + 28 -229.6108683335 0.688E-03 1.0667587413 0.0226244589 5055.3013 + 32 -229.6109878947 0.695E-03 1.0676826708 0.0226311290 5106.6084 + 33 -229.6110307906 0.675E-03 1.0680607041 0.0226347078 5275.6093 + 34 -229.6111451486 0.665E-03 1.0690981006 0.0226449334 5442.5343 + 36 -229.6110071622 0.635E-03 1.0683854254 0.0226195289 5607.4395 + 37 -229.6111151743 0.619E-03 1.0694566130 0.0226280049 5650.3564 + 39 -229.6111999118 0.593E-03 1.0704855156 0.0226396427 5721.1843 + 41 -229.6112693822 0.568E-03 1.0704707621 0.0226591581 5977.4453 + 42 -229.6113304786 0.558E-03 1.0704003975 0.0226799382 6128.7901 + 43 -229.6114566612 0.559E-03 1.0710684205 0.0227005287 6301.5450 + 45 -229.6114802376 0.535E-03 1.0714737618 0.0227026357 6469.9334 + 47 -229.6114835389 0.514E-03 1.0716055439 0.0226997590 6524.9003 + 49 -229.6115275594 0.504E-03 1.0725781200 0.0226947178 6530.2266 + 50 -229.6113843233 0.490E-03 1.0715725600 0.0226724102 6863.8457 + 54 -229.6114262482 0.463E-03 1.0716826305 0.0226787279 7446.0953 + 61 -229.6110204907 0.451E-03 1.0687339365 0.0226209098 7693.9233 + 67 -229.6110920182 0.464E-03 1.0686754091 0.0226399252 7853.1562 + 69 -229.6111085490 0.452E-03 1.0686822507 0.0226430605 7864.4673 + 71 -229.6111723307 0.440E-03 1.0690778943 0.0226555469 8102.3843 + 72 -229.6111753666 0.434E-03 1.0692881980 0.0226544053 8163.5043 + 74 -229.6111818307 0.422E-03 1.0694501061 0.0226541221 8298.1422 + 77 -229.6111581231 0.409E-03 1.0697881571 0.0226435651 8417.0474 + 79 -229.6110968412 0.401E-03 1.0695760448 0.0226307445 8587.0924 + 80 -229.6110964686 0.396E-03 1.0695883969 0.0226308044 8681.5683 + 82 -229.6111245842 0.387E-03 1.0697309632 0.0226365643 8717.7202 + 84 -229.6112033093 0.383E-03 1.0703280715 0.0226475358 8758.3693 + 85 -229.6112048673 0.379E-03 1.0704193284 0.0226472643 8861.8333 + 86 -229.6112234162 0.375E-03 1.0703740074 0.0226533173 8877.1123 + 87 -229.6113055267 0.387E-03 1.0714169345 0.0226568781 9047.4163 + 88 -229.6113061043 0.382E-03 1.0714022451 0.0226573187 9173.6793 + 90 -229.6112774241 0.377E-03 1.0711839029 0.0226540971 9267.0643 + 91 -229.6112371156 0.375E-03 1.0709406918 0.0226475880 9352.8235 + 92 -229.6112421927 0.371E-03 1.0709515738 0.0226483816 9375.4403 + 93 -229.6113025897 0.364E-03 1.0714926385 0.0226533341 9387.6093 + 94 -229.6112574371 0.363E-03 1.0712160814 0.0226457112 9791.5874 + 103 -229.6112575386 0.335E-03 1.0718288702 0.0226349321 9861.5103 + 104 -229.6112370497 0.332E-03 1.0716597482 0.0226326137 10047.0390 + 106 -229.6111501642 0.332E-03 1.0709657183 0.0226214773 10079.8472 + 107 -229.6111419493 0.329E-03 1.0708349542 0.0226208571 10357.7141 + 109 -229.6111043121 0.333E-03 1.0706048797 0.0226144880 10426.4980 + 110 -229.6110776645 0.331E-03 1.0704567031 0.0226099109 11150.9493 + 126 -229.6114025731 0.296E-03 1.0730594855 0.0226516464 11205.4513 + 127 -229.6114358486 0.295E-03 1.0734004312 0.0226557205 11286.6160 + 128 -229.6114190328 0.293E-03 1.0732261387 0.0226537250 11373.6522 + 131 -229.6114362363 0.292E-03 1.0732059995 0.0226584628 11520.4390 + 132 -229.6114763769 0.293E-03 1.0735541084 0.0226637329 11527.1990 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 19.850719 GB ] [ VIRT MEM : 22.895908 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 25372.990012 s ] [ CPU TIME: 1808309.423705 s ] <<<<< .. + +* Number of generators 1310681 + +.. >>>>> [ RES MEM : 19.850719 GB ] [ VIRT MEM : 22.895908 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 25372.993264 s ] [ CPU TIME: 1808309.657678 s ] <<<<< .. + +* Number of selectors 1310681 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8383112162487515 + +Summary at N_det = 1310720 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.46244562 +# PT2 -0.14900074 0.00029234 +# rPT2 -0.14569909 0.00028586 +# +# E+PT2 -229.61144636 0.00029234 +# E+rPT2 -229.60814471 0.00028586 +# ============ ============================= + + N_det = 1310720 + N_states = 1 + + * State 1 + < S^2 > = 4.708649202323860E-003 + E = -229.462445615976 + Variance = 1.07323469697373 + PT norm = 0.150534809244305 + PT2 = -0.149000740818207 + rPT2 = -0.145699093182045 + E+PT2 = -229.611446356794 +/- 2.923385885803041E-004 + E+rPT2 = -229.608144709158 +/- 2.858607750832375E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.578037487112 + Vee = 238.732546860200 + Vecp = 0.000000000000000E+000 + T = 229.274815232147 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1563 -229.62632412 + -0.1738 -229.62492042 + -0.2014 -229.62291147 + -0.2398 -229.62149363 + -0.2878 -229.62173167 + -0.3432 -229.62298211 + -0.4035 -229.62387540 + =========== =================== + +* Number of unique beta determinants 299317 +* Number of unique alpha determinants 299381 + +.. >>>>> [ RES MEM : 20.268238 GB ] [ VIRT MEM : 23.789764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 25807.219614 s ] [ CPU TIME: 1837333.143364 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 2621440 +* Number of threads for diagonalization 72 +* Memory(Gb) 4.682307057082653 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.4624456222 0.004709 0.145E-02 + 2 -229.4701494566 0.005795 0.156E-03 + 3 -229.4704346696 0.006016 0.307E-04 + 4 -229.4704981678 0.006179 0.652E-05 + 5 -229.4705179726 0.006311 0.111E-05 + 6 -229.4705222682 0.006363 0.242E-06 + 7 -229.4705230938 0.006378 0.433E-07 + 8 -229.4705232537 0.006376 0.848E-08 + 9 -229.4705232853 0.006372 0.177E-08 + 10 -229.4705232919 0.006370 0.331E-09 + 11 -229.4705232931 0.006370 0.620E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 22.161758 GB ] [ VIRT MEM : 25.931465 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30624.168691 s ] [ CPU TIME: 2159431.345178 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 19.583828 GB ] [ VIRT MEM : 23.000301 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30624.529608 s ] [ CPU TIME: 2159437.988961 s ] <<<<< .. + +* Energy of state 1 -229.4705232931297 +* S^2 of state 1 0.6369550710436214E-02 +* Saved determinants 2621440 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 18.673920 GB ] [ VIRT MEM : 21.855942 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30668.311539 s ] [ CPU TIME: 2160039.725777 s ] <<<<< .. + +* Number of generators 2621240 + +.. >>>>> [ RES MEM : 18.673920 GB ] [ VIRT MEM : 21.855942 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30668.317985 s ] [ CPU TIME: 2160040.182614 s ] <<<<< .. + +* Number of selectors 2621240 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 +* PT2 Energy denominator -229.4705232931297 + +.. >>>>> [ RES MEM : 19.404621 GB ] [ VIRT MEM : 22.587887 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30670.323279 s ] [ CPU TIME: 2160134.406468 s ] <<<<< .. + +* Number of generators 2621240 + +.. >>>>> [ RES MEM : 19.404621 GB ] [ VIRT MEM : 22.587887 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30670.329581 s ] [ CPU TIME: 2160134.859635 s ] <<<<< .. + +* Number of selectors 2621240 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 +* Number of tasks 3120527 +* Number of fragmented tasks 23307 +* Number of threads for PT2 72 +* Memory (Gb) 51.07999273687601 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6139487878 0.328E-02 1.0586154583 0.0213358623 3108.8605 + 5 -229.6143216158 0.153E-02 1.0597855660 0.0214227141 3460.6671 + 7 -229.6145102934 0.117E-02 1.0598149299 0.0214322925 4351.6564 + 11 -229.6135680648 0.108E-02 1.0514582759 0.0213159069 5299.7414 + 14 -229.6134761304 0.832E-03 1.0478499105 0.0213574408 5347.2614 + 15 -229.6135665660 0.765E-03 1.0475981321 0.0213802904 5527.2545 + 18 -229.6134536554 0.765E-03 1.0468786249 0.0213642789 6133.8723 + 19 -229.6132765620 0.745E-03 1.0455032748 0.0213384301 6947.3583 + 26 -229.6126500686 0.683E-03 1.0393973030 0.0212757702 6982.0904 + 27 -229.6126307341 0.658E-03 1.0388155534 0.0212775091 7510.3894 + 28 -229.6127722696 0.649E-03 1.0404088981 0.0212929477 7767.9436 + 29 -229.6126241555 0.644E-03 1.0390630620 0.0212762513 8328.5884 + 32 -229.6124565560 0.583E-03 1.0381026102 0.0212491588 9029.6651 + 33 -229.6123987473 0.567E-03 1.0374859281 0.0212451035 9107.6124 + 36 -229.6122605467 0.528E-03 1.0361433356 0.0212336605 10209.3193 + 45 -229.6121566266 0.489E-03 1.0327099496 0.0212592652 10391.7094 + 47 -229.6123315205 0.474E-03 1.0344152196 0.0212808490 11287.4245 + 49 -229.6122689009 0.471E-03 1.0336639270 0.0212768079 11569.8674 + 54 -229.6121468741 0.445E-03 1.0328729059 0.0212533833 11771.8481 + 55 -229.6121558193 0.437E-03 1.0330031112 0.0212542149 11960.7529 + 56 -229.6122210374 0.434E-03 1.0338998216 0.0212581217 11968.7380 + 58 -229.6122972887 0.439E-03 1.0340017076 0.0212762269 11979.8302 + 59 -229.6122569167 0.434E-03 1.0334737058 0.0212736320 12136.8304 + 62 -229.6121774008 0.416E-03 1.0325187132 0.0212686141 12332.2084 + 63 -229.6122085815 0.410E-03 1.0328318743 0.0212717492 12576.8644 + 64 -229.6121664173 0.406E-03 1.0324694811 0.0212674533 12797.5684 + 68 -229.6120999287 0.389E-03 1.0321158565 0.0212543430 12825.7174 + 69 -229.6121340938 0.385E-03 1.0324233151 0.0212585740 13021.0178 + 70 -229.6122601130 0.376E-03 1.0331555553 0.0212822163 13435.2165 + 72 -229.6124145505 0.382E-03 1.0341455420 0.0213088516 13842.1026 + 79 -229.6122307461 0.351E-03 1.0332218835 0.0212765908 14039.1493 + 80 -229.6122340572 0.346E-03 1.0333343569 0.0212753579 14180.9481 + 82 -229.6121412873 0.348E-03 1.0325015520 0.0212647669 14214.0163 + 83 -229.6121208556 0.345E-03 1.0322694084 0.0212638479 14403.6024 + 85 -229.6121299052 0.337E-03 1.0323117516 0.0212654920 14648.4454 + 86 -229.6120960234 0.334E-03 1.0320302003 0.0212608254 14745.6344 + 87 -229.6121241495 0.326E-03 1.0325690143 0.0212574722 14789.8324 + 88 -229.6121707728 0.325E-03 1.0328762087 0.0212652278 15106.6674 + 90 -229.6121572331 0.322E-03 1.0327015134 0.0212640317 16817.7186 + 112 -229.6120864045 0.283E-03 1.0324324448 0.0212491272 17070.7385 + 113 -229.6120717020 0.281E-03 1.0324921700 0.0212441376 17247.0354 + 114 -229.6120480339 0.279E-03 1.0324039525 0.0212398177 17304.7794 + 116 -229.6119337330 0.273E-03 1.0316681093 0.0212215076 17404.9705 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 26.084831 GB ] [ VIRT MEM : 29.272808 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 48087.022111 s ] [ CPU TIME: 3409181.883750 s ] <<<<< .. + +* Number of generators 2621240 + +.. >>>>> [ RES MEM : 26.084831 GB ] [ VIRT MEM : 29.272808 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 48087.028416 s ] [ CPU TIME: 3409182.330238 s ] <<<<< .. + +* Number of selectors 2621240 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8464841803168530 + +Summary at N_det = 2621440 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.47052329 +# PT2 -0.14140176 0.00026853 +# rPT2 -0.13846367 0.00026295 +# +# E+PT2 -229.61192505 0.00026853 +# E+rPT2 -229.60898696 0.00026295 +# ============ ============================= + + N_det = 2621440 + N_states = 1 + + * State 1 + < S^2 > = 6.369550710436214E-003 + E = -229.470523293130 + Variance = 1.03165284684030 + PT norm = 0.145668126336215 + PT2 = -0.141401755509312 + rPT2 = -0.138463666850099 + E+PT2 = -229.611925048639 +/- 2.685281020905417E-004 + E+rPT2 = -229.608986959980 +/- 2.629485435582564E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.579133384351 + Vee = 238.714123156264 + Vecp = 0.000000000000000E+000 + T = 229.286257156168 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1457 -229.62510503 + -0.1563 -229.62584149 + -0.1738 -229.62508051 + -0.2014 -229.62338426 + -0.2398 -229.62199690 + -0.2878 -229.62203687 + -0.3432 -229.62304759 + =========== =================== + +* Number of unique beta determinants 541830 +* Number of unique alpha determinants 541542 + +.. >>>>> [ RES MEM : 17.773308 GB ] [ VIRT MEM : 21.632961 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 49210.583872 s ] [ CPU TIME: 3483923.042887 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5242880 +* Number of threads for diagonalization 72 +* Memory(Gb) 9.135221090167761 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.4705232960 0.006370 0.121E-02 + 2 -229.4767720598 0.007375 0.132E-03 + 3 -229.4770037062 0.007566 0.220E-04 + 4 -229.4770506663 0.007698 0.488E-05 + 5 -229.4770651306 0.007783 0.136E-05 + 6 -229.4770700217 0.007845 0.319E-06 + 7 -229.4770713429 0.007877 0.809E-07 + 8 -229.4770716324 0.007882 0.172E-07 + 9 -229.4770716972 0.007882 0.391E-08 + 10 -229.4770717119 0.007879 0.834E-09 + 11 -229.4770717151 0.007878 0.165E-09 + 12 -229.4770717157 0.007877 0.359E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 23.073372 GB ] [ VIRT MEM : 27.405235 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 62572.021682 s ] [ CPU TIME: 4373591.051588 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 17.526527 GB ] [ VIRT MEM : 21.387642 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 62572.806334 s ] [ CPU TIME: 4373597.890700 s ] <<<<< .. + +* Energy of state 1 -229.4770717157417 +* S^2 of state 1 0.7876592596751296E-02 +* Saved determinants 5242880 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.225677 GB ] [ VIRT MEM : 19.328300 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 62659.674308 s ] [ CPU TIME: 4374719.631089 s ] <<<<< .. + +* Number of generators 5241744 + +.. >>>>> [ RES MEM : 16.225677 GB ] [ VIRT MEM : 19.328300 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 62659.686459 s ] [ CPU TIME: 4374720.504283 s ] <<<<< .. + +* Number of selectors 5241744 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 +* PT2 Energy denominator -229.4770717157417 + +.. >>>>> [ RES MEM : 17.834713 GB ] [ VIRT MEM : 20.940140 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 62664.136971 s ] [ CPU TIME: 4374897.812287 s ] <<<<< .. + +* Number of generators 5241744 + +.. >>>>> [ RES MEM : 17.834713 GB ] [ VIRT MEM : 20.940140 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 62664.148633 s ] [ CPU TIME: 4374897.823863 s ] <<<<< .. + +* Number of selectors 5241744 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 +* Number of tasks 6045846 +* Number of fragmented tasks 23991 +* Number of threads for PT2 72 +* Memory (Gb) 102.1371613103151 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6144332478 0.256E-02 1.0112649908 0.0204335495 4004.5034 + 4 -229.6146174120 0.168E-02 1.0111984476 0.0204708980 4735.3847 + 5 -229.6137334679 0.155E-02 1.0050983490 0.0203254475 5230.3329 + 6 -229.6142540367 0.135E-02 1.0103240286 0.0203794078 5823.8848 + 7 -229.6136805419 0.136E-02 1.0071648692 0.0202625405 6727.7838 + 8 -229.6139385789 0.120E-02 1.0086947332 0.0202971576 6731.8130 + 9 -229.6136212538 0.112E-02 1.0060174198 0.0202559115 7272.5238 + 10 -229.6138605736 0.104E-02 1.0090483766 0.0202703639 7277.5345 + 11 -229.6137229613 0.986E-03 1.0079387272 0.0202442921 7829.1089 + 12 -229.6139043939 0.917E-03 1.0083793246 0.0202876429 8082.2079 + 13 -229.6138185753 0.846E-03 1.0082869884 0.0202649275 8186.8759 + 14 -229.6134260258 0.870E-03 1.0061282417 0.0202008639 9068.9638 + 15 -229.6134764396 0.810E-03 1.0072467235 0.0201990225 9653.3400 + 18 -229.6131215035 0.715E-03 1.0044440823 0.0201493265 10052.3049 + 19 -229.6130095618 0.718E-03 1.0037841576 0.0201286638 10821.3048 + 20 -229.6129178199 0.687E-03 1.0032108034 0.0201131394 11079.5019 + 22 -229.6131091073 0.638E-03 1.0054460706 0.0201274857 11315.7958 + 24 -229.6128680618 0.612E-03 1.0037797971 0.0200925139 12052.9378 + 27 -229.6131688364 0.624E-03 1.0065898211 0.0201319080 12609.4129 + 28 -229.6132381903 0.605E-03 1.0070299915 0.0201427446 13138.0019 + 29 -229.6134272481 0.614E-03 1.0090015747 0.0201608847 13228.3489 + 30 -229.6133369746 0.600E-03 1.0079113397 0.0201574350 13429.6568 + 31 -229.6134230463 0.587E-03 1.0087680406 0.0201660605 13491.5940 + 32 -229.6136256710 0.596E-03 1.0103636925 0.0201913169 14675.6730 + 34 -229.6139544068 0.602E-03 1.0118568915 0.0202575837 14843.8828 + 36 -229.6137479881 0.600E-03 1.0097168584 0.0202402308 14913.8769 + 37 -229.6137692839 0.584E-03 1.0099659636 0.0202432197 15230.3357 + 39 -229.6137725533 0.571E-03 1.0096150124 0.0202509168 15436.4080 + 40 -229.6137600681 0.557E-03 1.0095834881 0.0202486947 16006.7938 + 41 -229.6137223957 0.544E-03 1.0090970924 0.0202463472 16131.7061 + 42 -229.6136965054 0.532E-03 1.0087720367 0.0202450406 16493.7838 + 43 -229.6135855267 0.531E-03 1.0075715059 0.0202361800 16879.7439 + 45 -229.6134073797 0.521E-03 1.0057161980 0.0202213210 17025.5444 + 47 -229.6134794184 0.509E-03 1.0065516748 0.0202298171 17545.1058 + 48 -229.6134885164 0.493E-03 1.0068062858 0.0202266829 17671.1088 + 49 -229.6135361292 0.485E-03 1.0072233667 0.0202345194 17947.2669 + 50 -229.6135047227 0.476E-03 1.0069770382 0.0202304065 18155.8440 + 51 -229.6134743433 0.468E-03 1.0067895128 0.0202259070 18393.4922 + 52 -229.6135231600 0.466E-03 1.0069853735 0.0202385509 18530.7848 + 53 -229.6136184212 0.467E-03 1.0074306676 0.0202561392 18782.7448 + 54 -229.6135833762 0.460E-03 1.0070192067 0.0202534788 18906.0379 + 55 -229.6134894807 0.461E-03 1.0061559918 0.0202419795 18923.6439 + 56 -229.6135299036 0.455E-03 1.0062195218 0.0202526192 19348.4908 + 57 -229.6134312537 0.457E-03 1.0055165080 0.0202385848 19510.4808 + 59 -229.6132366946 0.446E-03 1.0040239108 0.0202139656 20383.7988 + 61 -229.6132244539 0.449E-03 1.0038243972 0.0202125059 20821.7419 + 69 -229.6130737596 0.421E-03 1.0021660019 0.0202039504 21295.7279 + 70 -229.6131528835 0.422E-03 1.0029144766 0.0202122118 21494.6826 + 71 -229.6131607736 0.416E-03 1.0031516352 0.0202102940 21547.9738 + 72 -229.6131735011 0.410E-03 1.0032150238 0.0202123076 21794.7340 + 74 -229.6131506729 0.399E-03 1.0028400302 0.0202114126 21795.7749 + 75 -229.6131650253 0.394E-03 1.0030418325 0.0202116267 21880.9199 + 76 -229.6131936288 0.390E-03 1.0032831065 0.0202152853 22214.5568 + 77 -229.6131765908 0.385E-03 1.0032212959 0.0202118702 22355.0143 + 78 -229.6131782452 0.380E-03 1.0030682317 0.0202144498 22606.0361 + 79 -229.6132525321 0.383E-03 1.0037732212 0.0202210230 23240.1691 + 83 -229.6133107642 0.375E-03 1.0045017779 0.0202257374 23541.9718 + 86 -229.6132948660 0.368E-03 1.0043210610 0.0202232879 23993.4330 + 87 -229.6133240845 0.365E-03 1.0045622157 0.0202266212 24018.7769 + 88 -229.6133159934 0.360E-03 1.0044422055 0.0202260110 24415.6008 + 91 -229.6133010028 0.356E-03 1.0042228854 0.0202253683 24772.9919 + 93 -229.6133642727 0.353E-03 1.0047486998 0.0202333746 24827.4959 + 94 -229.6133286297 0.344E-03 1.0046517501 0.0202251632 25054.3339 + 95 -229.6133131194 0.341E-03 1.0046062761 0.0202221906 25882.7279 + 101 -229.6133387617 0.343E-03 1.0050806607 0.0202203051 26095.2650 + 103 -229.6133417336 0.337E-03 1.0053601180 0.0202183084 26117.8030 + 104 -229.6133034361 0.336E-03 1.0051459810 0.0202112998 26277.2820 + 105 -229.6133189221 0.332E-03 1.0052768092 0.0202139411 26523.3851 + 106 -229.6133225037 0.329E-03 1.0052045001 0.0202156272 26676.4860 + 107 -229.6133143944 0.326E-03 1.0051389235 0.0202144554 26970.7309 + 108 -229.6132907671 0.324E-03 1.0049455727 0.0202107712 27396.5922 + 112 -229.6132433559 0.316E-03 1.0046021410 0.0202040749 27568.1528 + 114 -229.6131660224 0.318E-03 1.0039037708 0.0201946316 27715.1291 + 115 -229.6132587200 0.319E-03 1.0048508606 0.0202031742 27780.8598 + 118 -229.6131721222 0.321E-03 1.0040130643 0.0201948517 27914.2409 + 119 -229.6131264803 0.321E-03 1.0036086944 0.0201891127 27957.5149 + 120 -229.6131374818 0.319E-03 1.0037514918 0.0201893160 28138.3832 + 121 -229.6131127450 0.317E-03 1.0036154366 0.0201846980 28279.5914 + 123 -229.6130850954 0.314E-03 1.0033502512 0.0201818757 28407.2548 + 124 -229.6130331331 0.315E-03 1.0028564907 0.0201766651 28661.3188 + 125 -229.6130368536 0.313E-03 1.0028684018 0.0201773590 28984.7161 + 126 -229.6129894760 0.314E-03 1.0024242432 0.0201721963 29115.6358 + 127 -229.6129534039 0.314E-03 1.0021109269 0.0201670536 29195.2899 + 128 -229.6130079396 0.321E-03 1.0023311723 0.0201781967 29460.3269 + 131 -229.6129845529 0.315E-03 1.0022329584 0.0201725136 29733.5309 + 134 -229.6129643982 0.309E-03 1.0020793526 0.0201702419 30036.4719 + 136 -229.6129346555 0.306E-03 1.0020038833 0.0201631443 30371.7813 + 137 -229.6129427158 0.304E-03 1.0020629385 0.0201641130 30539.3850 + 139 -229.6129040976 0.298E-03 1.0018787552 0.0201561362 30736.0132 + 140 -229.6129166270 0.297E-03 1.0019107769 0.0201590946 30847.6260 + 142 -229.6128740205 0.294E-03 1.0015301685 0.0201536767 30985.5009 + 143 -229.6129013202 0.293E-03 1.0018022512 0.0201567472 31171.8190 + 144 -229.6129336621 0.293E-03 1.0020436266 0.0201616903 31351.0893 + 146 -229.6129468390 0.289E-03 1.0021224226 0.0201637228 31505.8402 + 147 -229.6129169088 0.289E-03 1.0019350718 0.0201588843 31689.5820 + 149 -229.6129294992 0.287E-03 1.0021191099 0.0201590102 31931.7102 + 150 -229.6128988345 0.288E-03 1.0019536656 0.0201538627 31941.8469 + 151 -229.6128450010 0.291E-03 1.0015307569 0.0201464814 32074.0831 + 152 -229.6128303245 0.289E-03 1.0013453604 0.0201455852 32327.8938 + 153 -229.6128187505 0.288E-03 1.0012889724 0.0201435163 32662.0329 + 154 -229.6128281374 0.286E-03 1.0014143465 0.0201444042 32682.9869 + 155 -229.6128217556 0.284E-03 1.0013743055 0.0201432589 33125.0010 + 159 -229.6128029707 0.284E-03 1.0012594919 0.0201393571 33580.8581 + 161 -229.6128138723 0.283E-03 1.0012948903 0.0201419672 33645.8571 + 163 -229.6128114881 0.279E-03 1.0012154195 0.0201422178 33976.6980 + 165 -229.6128578747 0.272E-03 1.0014714752 0.0201515622 34096.4599 + 167 -229.6128483982 0.269E-03 1.0014802800 0.0201489096 34330.9779 + 168 -229.6128439978 0.267E-03 1.0014827572 0.0201480236 34351.5991 + 169 -229.6128458593 0.266E-03 1.0015763478 0.0201470331 34405.0308 + 170 -229.6128294845 0.265E-03 1.0015033804 0.0201439390 34691.1204 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 26.149158 GB ] [ VIRT MEM : 29.338898 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 97378.145689 s ] [ CPU TIME: 6862768.920253 s ] <<<<< .. + +* Number of generators 5241744 + +.. >>>>> [ RES MEM : 26.149158 GB ] [ VIRT MEM : 29.338898 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 97378.156808 s ] [ CPU TIME: 6862768.931292 s ] <<<<< .. + +* Number of selectors 5241744 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8526461531918800 + +Summary at N_det = 5242880 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.47707172 +# PT2 -0.13575777 0.00026458 +# rPT2 -0.13307707 0.00025936 +# +# E+PT2 -229.61282948 0.00026458 +# E+rPT2 -229.61014879 0.00025936 +# ============ ============================= + + N_det = 5242880 + N_states = 1 + + * State 1 + < S^2 > = 7.876592596751296E-003 + E = -229.477071715742 + Variance = 1.00150338043737 + PT norm = 0.141929345231953 + PT2 = -0.135757768741394 + rPT2 = -0.133077072309441 + E+PT2 = -229.612829484483 +/- 2.645818671384988E-004 + E+rPT2 = -229.610148788051 +/- 2.593573877309982E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.583183708959 + Vee = 238.699603206414 + Vecp = 0.000000000000000E+000 + T = 229.298279008014 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1385 -229.63885202 + -0.1457 -229.63084858 + -0.1563 -229.62837441 + -0.1738 -229.62649403 + -0.2014 -229.62440377 + -0.2398 -229.62279157 + -0.2878 -229.62257821 + =========== =================== + +* Number of unique beta determinants 923712 +* Number of unique alpha determinants 878270 + +.. >>>>> [ RES MEM : 28.342758 GB ] [ VIRT MEM : 33.274990 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 100142.026073 s ] [ CPU TIME: 7049687.152403 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 10485760 +* Number of threads for diagonalization 72 +* Memory(Gb) 17.62619972601533 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.4770717178 0.007877 0.108E-02 + 2 -229.4827667604 0.009135 0.978E-04 + 3 -229.4829419561 0.009260 0.144E-04 + 4 -229.4829689421 0.009338 0.130E-05 + 5 -229.4829731367 0.009371 0.187E-06 + 6 -229.4829739243 0.009388 0.341E-07 + 7 -229.4829740796 0.009397 0.828E-08 + 8 -229.4829741133 0.009402 0.201E-08 + 9 -229.4829741217 0.009405 0.419E-09 + 10 -229.4829741236 0.009407 0.929E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 39.166859 GB ] [ VIRT MEM : 45.979141 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 127526.451671 s ] [ CPU TIME: 8903282.312074 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 29.010700 GB ] [ VIRT MEM : 33.945923 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 127527.680208 s ] [ CPU TIME: 8903288.921146 s ] <<<<< .. + +* Energy of state 1 -229.4829741236329 +* S^2 of state 1 0.9406969096859598E-02 +* Saved determinants 10485760 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 27.110012 GB ] [ VIRT MEM : 30.445778 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 127698.328141 s ] [ CPU TIME: 8905380.798026 s ] <<<<< .. + +* Number of generators 10482954 + +.. >>>>> [ RES MEM : 27.110012 GB ] [ VIRT MEM : 30.445778 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 127698.351705 s ] [ CPU TIME: 8905382.490948 s ] <<<<< .. + +* Number of selectors 10482954 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -229.4829741236329 + +.. >>>>> [ RES MEM : 30.156700 GB ] [ VIRT MEM : 33.492668 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 127707.508505 s ] [ CPU TIME: 8905720.978722 s ] <<<<< .. + +* Number of generators 10482954 + +.. >>>>> [ RES MEM : 30.156700 GB ] [ VIRT MEM : 33.492668 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 127707.531090 s ] [ CPU TIME: 8905721.001194 s ] <<<<< .. + +* Number of selectors 10482954 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 11436716 +* Number of fragmented tasks 24364 +* Number of threads for PT2 49 +* Memory (Gb) 139.5341278969497 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6144391798 0.844E-03 0.9787131395 0.0193322729 6101.6803 + 4 -229.6135777212 0.129E-02 0.9726131851 0.0192062470 7241.0559 + 5 -229.6136951987 0.983E-03 0.9750629472 0.0192022919 8399.5306 + 6 -229.6131582090 0.987E-03 0.9736877252 0.0190965879 9270.0211 + 7 -229.6121894127 0.131E-02 0.9646813009 0.0189854447 10249.8985 + 8 -229.6121649851 0.103E-02 0.9620102247 0.0190265702 11204.9838 + 9 -229.6124281042 0.907E-03 0.9666626791 0.0190311535 12258.6354 + 10 -229.6126466838 0.841E-03 0.9681570395 0.0190456624 12369.8117 + 11 -229.6129691723 0.827E-03 0.9706385448 0.0190875125 12907.0856 + 12 -229.6127737819 0.769E-03 0.9683482268 0.0190727543 13736.1338 + 13 -229.6131520144 0.804E-03 0.9698209271 0.0191625725 14158.4003 + 14 -229.6131692743 0.744E-03 0.9701238009 0.0191558858 15066.3744 + 15 -229.6130173514 0.708E-03 0.9693743672 0.0191203232 15531.8316 + 16 -229.6133396559 0.735E-03 0.9730612770 0.0191526745 16555.2750 + 18 -229.6129453343 0.723E-03 0.9683520194 0.0191254482 16703.7241 + 19 -229.6129221984 0.683E-03 0.9686632450 0.0191097041 17576.2609 + 20 -229.6130095145 0.654E-03 0.9690573869 0.0191249989 18647.3206 + 22 -229.6137386379 0.738E-03 0.9751502195 0.0192171989 19126.8286 + 23 -229.6137878658 0.706E-03 0.9762428043 0.0192109653 19324.7752 + 24 -229.6136465748 0.691E-03 0.9748316990 0.0191934521 19793.0985 + 25 -229.6134358379 0.691E-03 0.9732117247 0.0191658905 20130.4440 + 26 -229.6135258413 0.669E-03 0.9741143887 0.0191767580 20454.4521 + 27 -229.6135010926 0.644E-03 0.9731882992 0.0191866499 21220.0415 + 28 -229.6134555800 0.622E-03 0.9722165837 0.0191909956 21664.0679 + 29 -229.6135356834 0.606E-03 0.9727250042 0.0191988737 22553.7885 + 30 -229.6136335398 0.595E-03 0.9737128036 0.0192108473 23385.4470 + 31 -229.6134041477 0.620E-03 0.9719855176 0.0191782376 23524.3041 + 32 -229.6134050731 0.600E-03 0.9720671092 0.0191737815 24349.3846 + 33 -229.6135293420 0.595E-03 0.9734515156 0.0191840041 24879.9654 + 34 -229.6134990869 0.578E-03 0.9735470109 0.0191740105 25254.9783 + 35 -229.6135768938 0.566E-03 0.9744089645 0.0191778634 25885.5804 + 36 -229.6135597118 0.551E-03 0.9738773500 0.0191798926 26175.8436 + 37 -229.6133638749 0.568E-03 0.9720862540 0.0191568122 26294.0027 + 38 -229.6134060427 0.554E-03 0.9725746518 0.0191598659 26897.3233 + 39 -229.6131875095 0.583E-03 0.9706929349 0.0191324123 27151.5172 + 40 -229.6131128440 0.573E-03 0.9703909793 0.0191160249 27504.4909 + 41 -229.6130090384 0.576E-03 0.9699388922 0.0190958708 27903.2704 + 42 -229.6128464333 0.585E-03 0.9684697652 0.0190754591 28552.5284 + 43 -229.6129119023 0.575E-03 0.9690871022 0.0190820574 29042.6477 + 44 -229.6130463272 0.578E-03 0.9701364641 0.0190991268 29118.0685 + 45 -229.6129896108 0.568E-03 0.9699130712 0.0190901146 29757.8794 + 47 -229.6128605356 0.551E-03 0.9691774549 0.0190690369 30517.9170 + 48 -229.6128686729 0.539E-03 0.9692307618 0.0190722573 30706.2743 + 49 -229.6128203133 0.526E-03 0.9692440628 0.0190586686 31013.5611 + 50 -229.6127593057 0.519E-03 0.9686551524 0.0190517524 31677.0957 + 51 -229.6127383346 0.509E-03 0.9684256094 0.0190487340 32010.4978 + 52 -229.6127838891 0.501E-03 0.9684667752 0.0190594875 32397.0597 + 54 -229.6129478858 0.490E-03 0.9699584424 0.0190815657 32771.3028 + 55 -229.6130511526 0.492E-03 0.9709554434 0.0190932425 33396.4181 + 56 -229.6130732856 0.484E-03 0.9714370840 0.0190918491 34132.6078 + 59 -229.6128778920 0.486E-03 0.9696415482 0.0190675036 34181.1597 + 61 -229.6129446000 0.469E-03 0.9696487228 0.0190865745 34591.0713 + 62 -229.6130257566 0.468E-03 0.9703568939 0.0190946454 34858.3463 + 63 -229.6131889302 0.489E-03 0.9718622878 0.0191126359 35141.6935 + 64 -229.6132764126 0.489E-03 0.9724144171 0.0191259677 35583.2204 + 67 -229.6131924730 0.471E-03 0.9721473913 0.0191071115 35936.9390 + 68 -229.6131591340 0.466E-03 0.9719033916 0.0191019125 36028.6823 + 69 -229.6132411808 0.466E-03 0.9726120284 0.0191104986 36576.3632 + 70 -229.6132084913 0.460E-03 0.9722042364 0.0191091571 37384.9310 + 72 -229.6132135060 0.448E-03 0.9721078124 0.0191148234 37682.3852 + 74 -229.6131514805 0.440E-03 0.9716332649 0.0191066364 37864.8722 + 76 -229.6132172547 0.430E-03 0.9721547598 0.0191141680 38387.7300 + 77 -229.6132618092 0.426E-03 0.9724114472 0.0191226198 38661.9247 + 78 -229.6132858264 0.421E-03 0.9724488138 0.0191281385 38942.0469 + 79 -229.6132785556 0.416E-03 0.9725868550 0.0191245543 39748.7875 + 80 -229.6132438551 0.412E-03 0.9724924341 0.0191181068 39816.7351 + 82 -229.6132900588 0.407E-03 0.9727033095 0.0191267770 40107.5797 + 83 -229.6132782753 0.403E-03 0.9724974736 0.0191267247 41100.3979 + 86 -229.6132325613 0.391E-03 0.9716748994 0.0191274768 41115.7787 + 87 -229.6131452880 0.396E-03 0.9709321720 0.0191166845 41458.5052 + 88 -229.6131706983 0.393E-03 0.9709525585 0.0191227299 41866.5838 + 90 -229.6132667938 0.390E-03 0.9716585268 0.0191350553 42618.0050 + 93 -229.6133400652 0.380E-03 0.9722049613 0.0191455249 42883.3989 + 94 -229.6133387392 0.376E-03 0.9722304463 0.0191447796 43915.4051 + 98 -229.6133972474 0.364E-03 0.9728078006 0.0191505633 44463.5701 + 102 -229.6132991972 0.358E-03 0.9722286405 0.0191338211 44698.9532 + 103 -229.6133167966 0.355E-03 0.9723721376 0.0191360331 45138.8842 + 104 -229.6133308231 0.352E-03 0.9724803012 0.0191375994 45328.3981 + 105 -229.6133631417 0.350E-03 0.9726207573 0.0191446243 45610.4170 + 106 -229.6133373195 0.345E-03 0.9724360024 0.0191403647 46453.4768 + 111 -229.6133100169 0.333E-03 0.9722381049 0.0191358078 46920.8144 + 112 -229.6133058835 0.330E-03 0.9723461884 0.0191330660 47781.5955 + 116 -229.6133932892 0.324E-03 0.9730558886 0.0191444382 48462.9197 + 117 -229.6132888819 0.319E-03 0.9723735995 0.0191280102 48666.4636 + 121 -229.6133303852 0.311E-03 0.9727505640 0.0191328565 48932.8285 + 123 -229.6133091349 0.306E-03 0.9725886397 0.0191303121 49340.8260 + 124 -229.6132886244 0.304E-03 0.9723687706 0.0191285393 49670.2463 + 125 -229.6132971629 0.302E-03 0.9723357871 0.0191310801 50094.3285 + 126 -229.6133128083 0.300E-03 0.9724976566 0.0191324659 50229.9812 + 127 -229.6133159626 0.297E-03 0.9724777767 0.0191338858 50419.3933 + 128 -229.6133322603 0.295E-03 0.9725889477 0.0191356711 50910.3080 + 131 -229.6132846181 0.292E-03 0.9722248631 0.0191287314 51125.7135 + 132 -229.6132757401 0.290E-03 0.9721606063 0.0191271503 51253.7931 + 134 -229.6133264331 0.289E-03 0.9725594334 0.0191338426 51603.0324 + 135 -229.6133336142 0.287E-03 0.9727271897 0.0191332569 51946.6846 + 137 -229.6133038026 0.285E-03 0.9721993433 0.0191342483 52376.3875 + 138 -229.6132707761 0.282E-03 0.9720655802 0.0191280222 52411.4742 + 139 -229.6132958099 0.281E-03 0.9722128929 0.0191318877 52637.1352 + 140 -229.6133160516 0.280E-03 0.9724004010 0.0191346272 52797.9720 + 141 -229.6133070679 0.278E-03 0.9723367778 0.0191335483 53154.7858 + 142 -229.6133332229 0.278E-03 0.9726086339 0.0191362188 53251.0619 + 143 -229.6133357505 0.276E-03 0.9726270515 0.0191366596 53537.2299 + 144 -229.6133260417 0.274E-03 0.9724901910 0.0191365630 53690.1971 + 146 -229.6133191913 0.270E-03 0.9724470044 0.0191347499 53892.7879 + 147 -229.6133247472 0.268E-03 0.9725480999 0.0191338791 54155.3873 + 148 -229.6134178603 0.263E-03 0.9730544338 0.0191496474 54438.1966 + 149 -229.6134081667 0.261E-03 0.9729583438 0.0191484766 54746.3902 + 150 -229.6134180437 0.260E-03 0.9730301331 0.0191498280 55198.2216 + 151 -229.6134121021 0.258E-03 0.9730756620 0.0191475268 55226.3989 + 152 -229.6134100860 0.257E-03 0.9731174118 0.0191463486 55271.8537 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 28.520943 GB ] [ VIRT MEM : 32.099110 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 183024.497452 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 10482954 + +.. >>>>> [ RES MEM : 28.520943 GB ] [ VIRT MEM : 32.099110 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 183024.519320 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 10482954 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8584110745943684 + +Summary at N_det = 10485760 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.48297412 +# PT2 -0.13043596 0.00025655 +# rPT2 -0.12798551 0.00025173 +# +# E+PT2 -229.61341009 0.00025655 +# E+rPT2 -229.61095963 0.00025173 +# ============ ============================= + + N_det = 10485760 + N_states = 1 + + * State 1 + < S^2 > = 9.406969096859598E-003 + E = -229.482974123633 + Variance = 0.973117411809485 + PT norm = 0.138370331219028 + PT2 = -0.130435962342354 + rPT2 = -0.127985507210461 + E+PT2 = -229.613410085975 +/- 2.565493450210496E-004 + E+rPT2 = -229.610959630843 +/- 2.517296415604310E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.583985730929 + Vee = 238.684700660727 + Vecp = 0.000000000000000E+000 + T = 229.308081167780 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1331 -229.63134160 + -0.1385 -229.63513930 + -0.1457 -229.63174064 + -0.1563 -229.62949771 + -0.1738 -229.62744185 + -0.2014 -229.62521572 + -0.2398 -229.62347030 + =========== =================== + +* Number of unique beta determinants 1520205 +* Number of unique alpha determinants 1457882 + +.. >>>>> [ RES MEM : 33.749149 GB ] [ VIRT MEM : 40.417747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 191175.964539 s ] [ CPU TIME: ************** s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 20971520 +* Number of threads for diagonalization 72 +* Memory(Gb) 33.93455018848181 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.4829741246 0.009407 0.104E-02 + 2 -229.4886274318 0.010511 0.986E-04 + 3 -229.4888211424 0.010622 0.159E-04 + 4 -229.4888509359 0.010694 0.147E-05 + 5 -229.4888555281 0.010716 0.190E-06 + 6 -229.4888563518 0.010719 0.376E-07 + 7 -229.4888565103 0.010720 0.912E-08 + 8 -229.4888565469 0.010719 0.249E-08 + 9 -229.4888565573 0.010719 0.692E-09 + 10 -229.4888565601 0.010718 0.161E-09 + 11 -229.4888565608 0.010718 0.389E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 54.843021 GB ] [ VIRT MEM : 64.319141 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 280766.489202 s ] [ CPU TIME: ************** s ] <<<<< .. + + +.. >>>>> [ RES MEM : 33.436924 GB ] [ VIRT MEM : 40.097931 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 280769.069475 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Energy of state 1 -229.4888565608188 +* S^2 of state 1 0.1071836052757673E-01 +* Saved determinants 20971520 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 31.890965 GB ] [ VIRT MEM : 35.430775 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 281115.239840 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 20963892 + +.. >>>>> [ RES MEM : 31.890965 GB ] [ VIRT MEM : 35.430775 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 281115.287262 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 20963892 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -229.4888565608188 + +.. >>>>> [ RES MEM : 37.866425 GB ] [ VIRT MEM : 41.407341 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 281135.956875 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 20963892 + +.. >>>>> [ RES MEM : 37.866425 GB ] [ VIRT MEM : 41.407341 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 281136.002157 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 20963892 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 21919928 +* Number of fragmented tasks 24612 +* Number of threads for PT2 41 +* Memory (Gb) 129.3389113129675 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6144944884 0.197E-02 0.9440851329 0.0183206787 9365.9918 + 4 -229.6156618021 0.194E-02 0.9547432525 0.0184177774 11300.9996 + 5 -229.6160151276 0.161E-02 0.9562931782 0.0184963937 12873.7761 + 6 -229.6155961524 0.131E-02 0.9516414475 0.0184627074 14706.8090 + 7 -229.6152316506 0.119E-02 0.9481235019 0.0184184614 15960.6873 + 8 -229.6151488381 0.103E-02 0.9477915373 0.0184025299 19126.7634 + 10 -229.6152542563 0.910E-03 0.9480436286 0.0184428807 19407.6555 + 11 -229.6147479442 0.939E-03 0.9436733296 0.0183841164 20126.4334 + 12 -229.6152157759 0.980E-03 0.9476710751 0.0184428546 21253.8465 + 13 -229.6146821650 0.105E-02 0.9445606954 0.0183509289 21847.0903 + 14 -229.6146282896 0.974E-03 0.9442866113 0.0183431434 23073.3948 + 15 -229.6143349550 0.941E-03 0.9422287718 0.0182946372 24270.4888 + 16 -229.6144464197 0.886E-03 0.9429084554 0.0183156747 24738.7645 + 17 -229.6142617998 0.852E-03 0.9414537604 0.0182910072 24884.8173 + 18 -229.6145367576 0.850E-03 0.9429252072 0.0183431206 26355.3667 + 19 -229.6147012168 0.830E-03 0.9445931051 0.0183613419 27388.6822 + 20 -229.6144809166 0.818E-03 0.9428070114 0.0183354337 28415.4804 + 21 -229.6144447648 0.778E-03 0.9418945906 0.0183415987 28759.6207 + 22 -229.6145831152 0.751E-03 0.9430429258 0.0183560977 29464.7976 + 23 -229.6149056399 0.788E-03 0.9455121418 0.0183977998 30185.3493 + 24 -229.6146538102 0.763E-03 0.9434418346 0.0183717291 30995.2822 + 25 -229.6147478282 0.737E-03 0.9442700281 0.0183873497 31751.8456 + 26 -229.6147129102 0.709E-03 0.9445141383 0.0183732445 31997.4328 + 27 -229.6147902840 0.702E-03 0.9447196999 0.0183919833 32998.8034 + 28 -229.6145259554 0.727E-03 0.9425996763 0.0183562641 34209.4263 + 29 -229.6143778494 0.717E-03 0.9414323403 0.0183350976 36685.2971 + 31 -229.6143817699 0.685E-03 0.9422992534 0.0183225555 37318.1791 + 32 -229.6144871304 0.672E-03 0.9428513458 0.0183407361 38214.3907 + 33 -229.6143864286 0.648E-03 0.9419903952 0.0183268393 38856.4056 + 34 -229.6143206142 0.632E-03 0.9419477551 0.0183111512 40283.6364 + 35 -229.6141382345 0.631E-03 0.9404654182 0.0182910589 40828.8361 + 36 -229.6140314078 0.623E-03 0.9397444844 0.0182765255 41544.7545 + 37 -229.6141350781 0.614E-03 0.9405438780 0.0182896841 41986.5584 + 38 -229.6142788701 0.615E-03 0.9418515867 0.0183052363 42422.3552 + 39 -229.6140753525 0.627E-03 0.9404137687 0.0182731363 43019.0444 + 40 -229.6141932533 0.622E-03 0.9407511149 0.0182987340 43661.1566 + 41 -229.6141077079 0.613E-03 0.9405422649 0.0182793169 44824.1478 + 42 -229.6140631951 0.599E-03 0.9404453902 0.0182694938 45458.0411 + 43 -229.6140769822 0.585E-03 0.9404419876 0.0182731372 46774.5837 + 44 -229.6141791129 0.581E-03 0.9410280364 0.0182886927 46992.7705 + 45 -229.6141594804 0.576E-03 0.9409402411 0.0182830423 47583.9490 + 46 -229.6140941544 0.567E-03 0.9409665659 0.0182664705 47705.0653 + 47 -229.6140073407 0.562E-03 0.9401879349 0.0182583377 48746.7797 + 48 -229.6140469097 0.563E-03 0.9405301616 0.0182628095 49434.0493 + 49 -229.6140020890 0.553E-03 0.9400302252 0.0182598077 49999.9292 + 50 -229.6139571072 0.544E-03 0.9397808940 0.0182526851 50718.4082 + 51 -229.6138874569 0.538E-03 0.9391213471 0.0182449044 51150.1996 + 52 -229.6139709063 0.527E-03 0.9403583914 0.0182480170 51802.4029 + 53 -229.6140340924 0.521E-03 0.9408688459 0.0182547640 52116.5896 + 54 -229.6140712366 0.512E-03 0.9411023504 0.0182633169 52918.3548 + 55 -229.6141640776 0.511E-03 0.9420867356 0.0182716908 53246.1517 + 56 -229.6141178097 0.504E-03 0.9417695809 0.0182649031 53790.4127 + 57 -229.6141490852 0.496E-03 0.9418998113 0.0182702667 54167.9739 + 58 -229.6140536878 0.483E-03 0.9410330679 0.0182591513 54312.8986 + 59 -229.6140006822 0.477E-03 0.9405837687 0.0182508441 55143.2159 + 61 -229.6139292931 0.481E-03 0.9402271799 0.0182381042 55458.5422 + 62 -229.6138102238 0.488E-03 0.9391619643 0.0182235264 55984.6173 + 63 -229.6137652962 0.482E-03 0.9385222955 0.0182209249 56482.5121 + 64 -229.6138156227 0.477E-03 0.9388451252 0.0182294989 57254.5470 + 67 -229.6139564921 0.472E-03 0.9397107092 0.0182532103 57403.2340 + 68 -229.6140538877 0.475E-03 0.9404237116 0.0182680831 57692.1178 + 69 -229.6139139218 0.489E-03 0.9391226545 0.0182527509 58360.8915 + 70 -229.6138847326 0.483E-03 0.9389364361 0.0182480526 59489.3351 + 72 -229.6138676615 0.478E-03 0.9387924258 0.0182483175 60562.6912 + 74 -229.6140081938 0.485E-03 0.9400517158 0.0182635168 60651.9059 + 76 -229.6139881001 0.473E-03 0.9400911231 0.0182589308 61127.6011 + 77 -229.6139867317 0.467E-03 0.9397904833 0.0182639395 61733.3668 + 78 -229.6140034982 0.461E-03 0.9399943510 0.0182648941 62182.2216 + 79 -229.6140034096 0.455E-03 0.9399551370 0.0182653234 63051.6508 + 81 -229.6138207009 0.465E-03 0.9384492973 0.0182418491 63283.1561 + 82 -229.6137985286 0.453E-03 0.9382146150 0.0182412256 64018.1919 + 83 -229.6138725097 0.454E-03 0.9389443811 0.0182494271 64872.7612 + 85 -229.6139077001 0.448E-03 0.9389912842 0.0182584843 65345.8438 + 86 -229.6139408565 0.444E-03 0.9392521089 0.0182628699 65562.2127 + 87 -229.6140126951 0.445E-03 0.9398395828 0.0182721929 66274.1488 + 88 -229.6139210237 0.449E-03 0.9391610953 0.0182587064 66726.4742 + 89 -229.6138461302 0.450E-03 0.9387236039 0.0182460384 66816.8126 + 90 -229.6138085515 0.447E-03 0.9385325325 0.0182402863 67886.7404 + 91 -229.6137087163 0.440E-03 0.9376974549 0.0182283022 67965.0547 + 92 -229.6137269986 0.436E-03 0.9377729274 0.0182318665 68064.9158 + 93 -229.6137347081 0.431E-03 0.9379240192 0.0182317785 68557.1806 + 94 -229.6137567389 0.427E-03 0.9381437093 0.0182338499 69506.4615 + 97 -229.6137927501 0.419E-03 0.9385992858 0.0182343999 69984.5342 + 98 -229.6137863855 0.415E-03 0.9385785218 0.0182341107 70712.1869 + 100 -229.6138197929 0.410E-03 0.9388730810 0.0182369389 71016.1155 + 102 -229.6137188628 0.408E-03 0.9381214744 0.0182224473 71127.9240 + 103 -229.6136040267 0.406E-03 0.9373028191 0.0182066819 71768.5028 + 104 -229.6136162963 0.402E-03 0.9374523176 0.0182072771 72386.2258 + 105 -229.6135625611 0.402E-03 0.9371096891 0.0181986451 72814.8899 + 106 -229.6135820504 0.399E-03 0.9372676773 0.0182003855 73675.7325 + 110 -229.6136179793 0.391E-03 0.9375643877 0.0182033532 73902.7713 + 111 -229.6136762135 0.392E-03 0.9379781185 0.0182118839 74538.9082 + 112 -229.6137123283 0.390E-03 0.9382419829 0.0182168001 76173.2231 + 115 -229.6137453704 0.373E-03 0.9384835959 0.0182216529 76257.5887 + 118 -229.6137945597 0.367E-03 0.9389466420 0.0182270752 76585.7914 + 119 -229.6137971587 0.364E-03 0.9389825211 0.0182269135 76881.7892 + 120 -229.6138032339 0.361E-03 0.9390871795 0.0182271387 77330.0687 + 121 -229.6137985668 0.358E-03 0.9390794828 0.0182260413 77473.4494 + 122 -229.6137748621 0.356E-03 0.9389943050 0.0182207078 77933.6568 + 123 -229.6137818191 0.353E-03 0.9390995374 0.0182199232 78509.2885 + 124 -229.6138051949 0.351E-03 0.9393240379 0.0182225703 79420.0197 + 125 -229.6138013618 0.345E-03 0.9393779585 0.0182202778 79673.6235 + 126 -229.6138109092 0.343E-03 0.9395407813 0.0182203817 80068.3500 + 127 -229.6137922170 0.340E-03 0.9393385805 0.0182183793 80277.7222 + 128 -229.6138560523 0.344E-03 0.9397764377 0.0182275134 80799.1958 + 129 -229.6138826047 0.342E-03 0.9398748868 0.0182331643 80821.5229 + 131 -229.6138770706 0.337E-03 0.9397627623 0.0182328951 81374.4391 + 132 -229.6138946009 0.335E-03 0.9398215411 0.0182360868 81625.4896 + 133 -229.6138516702 0.335E-03 0.9393592557 0.0182315752 81654.7157 + 134 -229.6138491343 0.333E-03 0.9394203263 0.0182293808 82141.1823 + 135 -229.6138143155 0.332E-03 0.9391473909 0.0182247125 82419.1221 + 136 -229.6138265435 0.325E-03 0.9393903744 0.0182232344 82686.4856 + 137 -229.6137972379 0.324E-03 0.9393098388 0.0182171853 83096.5102 + 138 -229.6137873720 0.322E-03 0.9391746616 0.0182165065 85713.3191 + 146 -229.6137697996 0.307E-03 0.9392618889 0.0182099537 86045.1984 + 147 -229.6137834831 0.306E-03 0.9394759369 0.0182100420 86328.1504 + 148 -229.6138314654 0.309E-03 0.9399390064 0.0182153014 86630.8330 + 149 -229.6138230586 0.307E-03 0.9399050021 0.0182135083 86931.4991 + 150 -229.6138615263 0.307E-03 0.9404455628 0.0182155507 87163.6069 + 151 -229.6138520466 0.305E-03 0.9404200528 0.0182135027 87486.3491 + 152 -229.6138620632 0.303E-03 0.9405202984 0.0182149329 88061.6324 + 153 -229.6138943315 0.303E-03 0.9408142163 0.0182183025 88299.0764 + 154 -229.6138601382 0.303E-03 0.9406087737 0.0182127370 89007.6099 + 155 -229.6138689247 0.301E-03 0.9407862264 0.0182127544 89200.7391 + 156 -229.6138747272 0.299E-03 0.9407650271 0.0182141612 89618.4645 + 157 -229.6138636117 0.298E-03 0.9406763953 0.0182125838 89855.0353 + 158 -229.6138915247 0.297E-03 0.9408826302 0.0182163211 90051.5464 + 159 -229.6139236235 0.297E-03 0.9411147831 0.0182211357 90373.3256 + 160 -229.6139634125 0.298E-03 0.9414100677 0.0182267938 90885.6498 + 161 -229.6139220381 0.291E-03 0.9411289048 0.0182205516 90983.9564 + 162 -229.6139105834 0.290E-03 0.9410098808 0.0182194596 91404.0051 + 163 -229.6139307987 0.289E-03 0.9412059739 0.0182212146 91909.9981 + 165 -229.6139007728 0.286E-03 0.9410574257 0.0182158344 92249.4721 + 167 -229.6138608510 0.284E-03 0.9407334435 0.0182103191 92620.3020 + 168 -229.6138204737 0.285E-03 0.9404508946 0.0182044602 92885.9692 + 169 -229.6138574418 0.286E-03 0.9406747748 0.0182105454 93479.8741 + 170 -229.6138633469 0.284E-03 0.9406677485 0.0182122289 94079.5141 + 171 -229.6139044963 0.286E-03 0.9410077554 0.0182175305 94259.9507 + 172 -229.6139089875 0.284E-03 0.9409702099 0.0182188157 94596.9924 + 173 -229.6138507446 0.281E-03 0.9404789223 0.0182116215 95026.0175 + 174 -229.6138464164 0.279E-03 0.9404871041 0.0182101559 95246.5916 + 175 -229.6138634510 0.278E-03 0.9405920470 0.0182127178 95691.1998 + 176 -229.6138453748 0.277E-03 0.9404430259 0.0182100877 96064.0352 + 177 -229.6138087101 0.278E-03 0.9401445889 0.0182054854 96382.7213 + 180 -229.6138115077 0.274E-03 0.9400885149 0.0182071864 96520.4809 + 181 -229.6138165241 0.273E-03 0.9401301421 0.0182077967 97447.6762 + 182 -229.6137898470 0.272E-03 0.9397988507 0.0182060832 97590.5833 + 184 -229.6137846306 0.270E-03 0.9396420413 0.0182066083 97603.6914 + 185 -229.6138601228 0.266E-03 0.9403821582 0.0182128985 97986.7299 + 186 -229.6138720348 0.265E-03 0.9405023730 0.0182139854 98576.7978 + 188 -229.6138849066 0.262E-03 0.9405227253 0.0182171887 98783.9548 + 189 -229.6138637389 0.262E-03 0.9403543193 0.0182144581 99155.7883 + 190 -229.6138576211 0.261E-03 0.9402791355 0.0182139909 99562.6330 + 191 -229.6138574165 0.259E-03 0.9402528991 0.0182146711 99769.7882 + 192 -229.6138312967 0.259E-03 0.9400500282 0.0182112614 ********** + 193 -229.6138183709 0.258E-03 0.9399983759 0.0182087836 ********** + 194 -229.6138177289 0.257E-03 0.9399813089 0.0182091604 ********** + 195 -229.6138181575 0.256E-03 0.9401045231 0.0182074162 ********** + 197 -229.6138065961 0.254E-03 0.9399744536 0.0182064623 ********** + 198 -229.6137780422 0.250E-03 0.9398082742 0.0182020509 ********** + 201 -229.6137208985 0.249E-03 0.9393280913 0.0181944097 ********** + 202 -229.6137254333 0.247E-03 0.9393773009 0.0181948205 ********** +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 38.885296 GB ] [ VIRT MEM : 42.980614 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 383750.661164 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 20963892 + +.. >>>>> [ RES MEM : 38.885296 GB ] [ VIRT MEM : 42.980614 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 383750.704618 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 20963892 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8644076766822755 + +Summary at N_det = 20971520 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.48885656 +# PT2 -0.12486887 0.00024739 +# rPT2 -0.12263751 0.00024297 +# +# E+PT2 -229.61372543 0.00024739 +# E+rPT2 -229.61149407 0.00024297 +# ============ ============================= + + N_det = 20971520 + N_states = 1 + + * State 1 + < S^2 > = 1.071836052757673E-002 + E = -229.488856560819 + Variance = 0.939377300888757 + PT norm = 0.134888177788547 + PT2 = -0.124868872452553 + rPT2 = -0.122637505060536 + E+PT2 = -229.613725433271 +/- 2.473906706299786E-004 + E+rPT2 = -229.611494065879 +/- 2.429698773234429E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.586697188150 + Vee = 238.670832942964 + Vecp = 0.000000000000000E+000 + T = 229.318777905577 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1280 -229.62374944 + -0.1331 -229.62731809 + -0.1385 -229.63109295 + -0.1457 -229.63036611 + -0.1563 -229.62921826 + -0.1738 -229.62764366 + -0.2014 -229.62561799 + =========== =================== + +* Number of unique beta determinants 2252423 +* Number of unique alpha determinants 2179859 + +.. >>>>> [ RES MEM : 50.924034 GB ] [ VIRT MEM : 59.591255 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 410390.238657 s ] [ CPU TIME: ************** s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 41943040 +* Number of threads for diagonalization 72 +* Memory(Gb) 64.69572049379349 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.4888565610 0.010718 0.157E-02 + 2 -229.4975778320 0.012004 0.200E-03 + 3 -229.4979009221 0.012135 0.295E-04 + 4 -229.4979574323 0.012242 0.247E-05 + 5 -229.4979662427 0.012266 0.464E-06 + 6 -229.4979678977 0.012259 0.863E-07 diff --git a/furan/cc-pvtz/slurm-485509.out b/furan/cc-pvtz/slurm-485509.out index d5efa61..fb94bb5 100644 --- a/furan/cc-pvtz/slurm-485509.out +++ b/furan/cc-pvtz/slurm-485509.out @@ -55779,3 +55779,1205 @@ 43.90 % in 16945 seconds 44.10 % in 16957 seconds 44.29 % in 16996 seconds +44.38 % in 17043 seconds +44.48 % in 17094 seconds +44.57 % in 17148 seconds +44.67 % in 17205 seconds +44.76 % in 17249 seconds +44.86 % in 17260 seconds +45.05 % in 17275 seconds +45.24 % in 17287 seconds +45.43 % in 17298 seconds +45.62 % in 17309 seconds +45.81 % in 17321 seconds +46.00 % in 17333 seconds +46.19 % in 17344 seconds +46.38 % in 17355 seconds +46.57 % in 17369 seconds +46.67 % in 17414 seconds +46.76 % in 17459 seconds +46.86 % in 17508 seconds +46.95 % in 17570 seconds +47.05 % in 17620 seconds +47.14 % in 17670 seconds +47.24 % in 17681 seconds +47.43 % in 17696 seconds +47.62 % in 17708 seconds +47.81 % in 17720 seconds +48.00 % in 17731 seconds +48.19 % in 17742 seconds +48.38 % in 17753 seconds +48.57 % in 17765 seconds +48.76 % in 17776 seconds +48.95 % in 17789 seconds +49.14 % in 17802 seconds +49.24 % in 17814 seconds +49.33 % in 17860 seconds +49.43 % in 17908 seconds +49.52 % in 17962 seconds +49.62 % in 18012 seconds +49.71 % in 18067 seconds +49.81 % in 18116 seconds +49.90 % in 18127 seconds +50.10 % in 18143 seconds +50.29 % in 18154 seconds +50.48 % in 18165 seconds +50.67 % in 18177 seconds +50.86 % in 18187 seconds +51.05 % in 18198 seconds +51.24 % in 18210 seconds +51.43 % in 18220 seconds +51.62 % in 18232 seconds +51.81 % in 18244 seconds +52.00 % in 18258 seconds +52.10 % in 18303 seconds +52.19 % in 18344 seconds +52.29 % in 18393 seconds +52.38 % in 18439 seconds +52.48 % in 18500 seconds +52.57 % in 18545 seconds +52.67 % in 18557 seconds +52.86 % in 18572 seconds +53.05 % in 18584 seconds +53.24 % in 18595 seconds +53.43 % in 18606 seconds +53.62 % in 18616 seconds +53.81 % in 18627 seconds +54.00 % in 18640 seconds +54.19 % in 18652 seconds +54.38 % in 18664 seconds +54.57 % in 18677 seconds +54.67 % in 18711 seconds +54.76 % in 18751 seconds +54.86 % in 18797 seconds +54.95 % in 18851 seconds +55.05 % in 18900 seconds +55.14 % in 18951 seconds +55.24 % in 18981 seconds +55.43 % in 18998 seconds +55.62 % in 19010 seconds +55.81 % in 19022 seconds +56.00 % in 19033 seconds +56.19 % in 19043 seconds +56.38 % in 19054 seconds +56.57 % in 19066 seconds +56.76 % in 19076 seconds +56.95 % in 19088 seconds +57.14 % in 19100 seconds +57.33 % in 19114 seconds +57.52 % in 19125 seconds +57.62 % in 19167 seconds +57.71 % in 19211 seconds +57.81 % in 19262 seconds +57.90 % in 19312 seconds +58.00 % in 19364 seconds +58.10 % in 19420 seconds +58.19 % in 19432 seconds +58.38 % in 19446 seconds +58.57 % in 19458 seconds +58.76 % in 19470 seconds +58.95 % in 19480 seconds +59.14 % in 19491 seconds +59.33 % in 19502 seconds +59.52 % in 19513 seconds +59.71 % in 19526 seconds +59.90 % in 19539 seconds +60.10 % in 19552 seconds +60.29 % in 19568 seconds +60.38 % in 19620 seconds +60.48 % in 19669 seconds +60.57 % in 19718 seconds +60.67 % in 19777 seconds +60.76 % in 19824 seconds +60.86 % in 19835 seconds +61.05 % in 19848 seconds +61.24 % in 19861 seconds +61.43 % in 19871 seconds +61.62 % in 19882 seconds +61.81 % in 19894 seconds +62.00 % in 19904 seconds +62.19 % in 19916 seconds +62.38 % in 19926 seconds +62.57 % in 19940 seconds +62.76 % in 19951 seconds +62.95 % in 20004 seconds +63.05 % in 20051 seconds +63.14 % in 20098 seconds +63.24 % in 20146 seconds +63.33 % in 20211 seconds +63.43 % in 20237 seconds +63.62 % in 20254 seconds +63.81 % in 20266 seconds +64.00 % in 20277 seconds +64.19 % in 20288 seconds +64.38 % in 20299 seconds +64.57 % in 20310 seconds +64.76 % in 20322 seconds +64.95 % in 20334 seconds +65.14 % in 20346 seconds +65.33 % in 20358 seconds +65.52 % in 20371 seconds +65.62 % in 20412 seconds +65.71 % in 20462 seconds +65.81 % in 20524 seconds +65.90 % in 20582 seconds +66.00 % in 20625 seconds +66.10 % in 20635 seconds +66.29 % in 20650 seconds +66.48 % in 20662 seconds +66.67 % in 20672 seconds +66.86 % in 20683 seconds +67.05 % in 20695 seconds +67.24 % in 20706 seconds +67.43 % in 20719 seconds +67.62 % in 20731 seconds +67.81 % in 20745 seconds +68.00 % in 20786 seconds +68.10 % in 20832 seconds +68.19 % in 20882 seconds +68.29 % in 20941 seconds +68.38 % in 21004 seconds +68.48 % in 21024 seconds +68.67 % in 21038 seconds +68.86 % in 21050 seconds +69.05 % in 21062 seconds +69.24 % in 21074 seconds +69.43 % in 21085 seconds +69.62 % in 21096 seconds +69.81 % in 21107 seconds +70.00 % in 21121 seconds +70.19 % in 21133 seconds +70.38 % in 21146 seconds +70.57 % in 21160 seconds +70.67 % in 21178 seconds +70.76 % in 21229 seconds +70.86 % in 21287 seconds +70.95 % in 21359 seconds +71.05 % in 21417 seconds 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22382 seconds +77.24 % in 22397 seconds +77.43 % in 22409 seconds +77.62 % in 22420 seconds +77.81 % in 22431 seconds +78.00 % in 22442 seconds +78.19 % in 22455 seconds +78.38 % in 22467 seconds +78.57 % in 22481 seconds +78.67 % in 22516 seconds +78.76 % in 22567 seconds +78.86 % in 22620 seconds +78.95 % in 22673 seconds +79.05 % in 22684 seconds +79.24 % in 22697 seconds +79.43 % in 22708 seconds +79.62 % in 22719 seconds +79.81 % in 22731 seconds +80.00 % in 22743 seconds +80.19 % in 22755 seconds +80.38 % in 22769 seconds +80.48 % in 22795 seconds +80.57 % in 22847 seconds +80.67 % in 22910 seconds +80.76 % in 22962 seconds +80.86 % in 22972 seconds +81.05 % in 22985 seconds +81.24 % in 22997 seconds +81.43 % in 23008 seconds +81.62 % in 23019 seconds +81.81 % in 23030 seconds +82.00 % in 23043 seconds +82.19 % in 23056 seconds +82.38 % in 23101 seconds +82.48 % in 23162 seconds +82.57 % in 23214 seconds +82.67 % in 23252 seconds +82.86 % in 23266 seconds +83.05 % in 23278 seconds +83.24 % in 23289 seconds +83.43 % in 23301 seconds +83.62 % in 23313 seconds +83.81 % in 23326 seconds +84.00 % in 23341 seconds +84.10 % in 23393 seconds +84.19 % in 23451 seconds +84.29 % in 23509 seconds +84.38 % in 23538 seconds +84.57 % in 23552 seconds +84.76 % in 23563 seconds +84.95 % in 23574 seconds +85.14 % in 23586 seconds +85.33 % in 23598 seconds +85.52 % in 23610 seconds +85.71 % in 23624 seconds +85.81 % in 23639 seconds +85.90 % in 23691 seconds +86.00 % in 23745 seconds +86.10 % in 23793 seconds +86.19 % in 23803 seconds +86.38 % in 23816 seconds +86.57 % in 23827 seconds +86.76 % in 23839 seconds +86.95 % in 23852 seconds +87.14 % in 23864 seconds +87.33 % in 23879 seconds +87.43 % in 23945 seconds +87.52 % in 24016 seconds +87.62 % in 24060 seconds +87.71 % in 24070 seconds +87.90 % in 24082 seconds +88.10 % in 24094 seconds +88.29 % in 24105 seconds +88.48 % in 24119 seconds +88.67 % in 24133 seconds +88.86 % in 24166 seconds +88.95 % in 24227 seconds 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in 364 seconds + 0.67 % in 426 seconds + 0.76 % in 483 seconds + 0.86 % in 540 seconds + 0.95 % in 599 seconds + 1.05 % in 659 seconds + 1.14 % in 716 seconds + 1.24 % in 781 seconds + 1.33 % in 829 seconds + 1.43 % in 885 seconds + 1.52 % in 941 seconds + 1.62 % in 1001 seconds + 1.71 % in 1061 seconds + 1.81 % in 1126 seconds + 1.90 % in 1190 seconds + 2.00 % in 1257 seconds + 2.10 % in 1317 seconds + 2.19 % in 1377 seconds + 2.29 % in 1437 seconds + 2.38 % in 1491 seconds + 2.48 % in 1550 seconds + 2.57 % in 1697 seconds + 2.67 % in 1948 seconds + 2.76 % in 2190 seconds + 2.86 % in 2435 seconds + 2.95 % in 2680 seconds + 3.05 % in 2922 seconds + 3.14 % in 3168 seconds + 3.24 % in 3418 seconds + 3.33 % in 3661 seconds + 3.43 % in 3895 seconds + 3.52 % in 4131 seconds + 3.62 % in 4373 seconds + 3.71 % in 4610 seconds + 3.81 % in 4844 seconds + 3.90 % in 5096 seconds + 4.00 % in 5348 seconds + 4.10 % in 5586 seconds + 4.19 % in 5834 seconds + 4.29 % in 6080 seconds + 4.38 % in 6322 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9383 seconds +10.38 % in 9439 seconds +10.48 % in 9488 seconds +10.57 % in 9500 seconds +10.76 % in 9518 seconds +10.95 % in 9534 seconds +11.14 % in 9550 seconds +11.33 % in 9587 seconds +11.43 % in 9620 seconds +11.52 % in 9659 seconds +11.62 % in 9711 seconds +11.71 % in 9750 seconds +11.81 % in 9799 seconds +11.90 % in 9825 seconds +12.00 % in 9886 seconds +12.10 % in 9947 seconds +12.19 % in 9989 seconds +12.29 % in 10040 seconds +12.38 % in 10095 seconds +12.48 % in 10148 seconds From 90e6cb05bba3c7566f4d568cb9122a6e3e45396b Mon Sep 17 00:00:00 2001 From: Pierre-Francois Loos Date: Tue, 3 Nov 2020 09:39:14 +0100 Subject: [PATCH 5/5] update Denis --- CC_cc-pvdz.txt | 327 ++++++++++++++++++++++++++++++++++++++++++++ CC_cc-pvdz_5mem.txt | 146 -------------------- 2 files changed, 327 insertions(+), 146 deletions(-) create mode 100644 CC_cc-pvdz.txt delete mode 100644 CC_cc-pvdz_5mem.txt diff --git a/CC_cc-pvdz.txt b/CC_cc-pvdz.txt new file mode 100644 index 0000000..0a1a974 --- /dev/null +++ b/CC_cc-pvdz.txt @@ -0,0 +1,327 @@ +=============== +Cyclopentadiene +=============== + +C 0.00000000 0.00000000 -2.33113051 +C 0.00000000 2.22209092 -0.56871188 +C 0.00000000 -2.22209092 -0.56871188 +C 0.00000000 1.38514451 1.83772922 +C 0.00000000 -1.38514451 1.83772922 +H 1.66130504 0.00000000 -3.56414299 +H -1.66130504 0.00000000 -3.56414299 +H 0.00000000 4.16550405 -1.18116624 +H 0.00000000 -4.16550405 -1.18116624 +H 0.00000000 2.54514584 3.51352303 +H 0.00000000 -2.54514584 3.51352303 + +cc-pVDZ 100 BF + +Cfour +HF -192.808319784581 +MP2 -193.471694583002 -0.663374798421 +CCSD -193.515557363805186 -0.707237579224683 +CC3 -193.544894006853781 -0.736574222273275 +CCSDT -193.544566492999309 -0.736246708418799 +CC4 -193.546686469127337 -0.738366684546823 +CCSDTQ + +===== +Furan +===== + +C 0.00000000 2.06365826 -0.60051250 +C 0.00000000 -2.06365826 -0.60051250 +C 0.00000000 1.35348578 1.86336416 +C 0.00000000 -1.35348578 1.86336416 +O 0.00000000 0.00000000 -2.13945332 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