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+ +C 0.00000000 -2.11414732 -1.22060353 +C 0.00000000 0.00000000 2.44120705 +C 0.00000000 2.11414732 -1.22060353 +N 0.00000000 -2.24624733 1.29687150 +N 0.00000000 2.24624733 1.29687150 +N 0.00000000 0.00000000 -2.59374300 +H 0.00000000 3.88296710 -2.24183210 +H 0.00000000 -3.88296710 -2.24183210 +H 0.00000000 0.00000000 4.48366420 + +cc-pVDZ 99 BF + +Cfour +HF -278.717319389695 +MP2 -279.567838672171 -0.850519282476 +CCSD -279.591139307707863 -0.873819918012385 +CC3 -279.632903200419094 -0.915583810723581 +CCSDT -279.630035882850507 -0.912716493155011 +CC4 +CCSDTQ + diff --git a/Manuscript/Ec.bib b/Manuscript/Ec.bib new file mode 100644 index 0000000..68d6c0e --- /dev/null +++ b/Manuscript/Ec.bib @@ -0,0 +1,1076 @@ +%% This BibTeX bibliography file was created using BibDesk. +%% http://bibdesk.sourceforge.net/ + +%% Created for Pierre-Francois Loos at 2020-10-26 13:09:05 +0100 + + +%% Saved with string encoding Unicode (UTF-8) + + + +@misc{Xu_2020, + Archiveprefix = {arXiv}, + Author = {Enhua Xu and Motoyuki Uejima and Seiichiro L. Ten-no}, + Date-Added = {2020-10-10 13:54:02 +0200}, + Date-Modified = {2020-10-10 13:54:09 +0200}, + Eprint = {2010.01850}, + Primaryclass = {physics.chem-ph}, + Title = {Towards near-exact solutions of molecular electronic structure: Full coupled-cluster reduction with a second-order perturbative correction}, + Year = {2020}} + +@inbook{Caffarel_2016b, + Author = {Caffarel, Michel and Applencourt, Thomas and Giner, Emmanuel and Scemama, Anthony}, + Booktitle = {Recent Progress in Quantum Monte Carlo}, + Chapter = {2}, + Date-Added = {2020-10-10 13:52:37 +0200}, + Date-Modified = {2020-10-10 13:53:07 +0200}, + Doi = {10.1021/bk-2016-1234.ch002}, + Pages = {15-46}, + Title = {Using CIPSI Nodes in Diffusion Monte Carlo}, + Bdsk-Url-1 = {https://pubs.acs.org/doi/abs/10.1021/bk-2016-1234.ch002}, + Bdsk-Url-2 = {https://doi.org/10.1021/bk-2016-1234.ch002}} + +@article{BenAmor_2011, + Author = {Ben Amor,Nadia and Bessac,Fabienne and Hoyau,Sophie and Maynau,Daniel}, + Date-Added = {2020-10-09 21:28:40 +0200}, + Date-Modified = {2020-10-09 21:29:52 +0200}, + Doi = {10.1063/1.3600351}, + Journal = {J. Chem. Phys.}, + Pages = {014101}, + Title = {Direct selected multireference configuration interaction calculations for large systems using localized orbitals}, + Volume = {135}, + Year = {2011}, + Bdsk-Url-1 = {https://doi.org/10.1063/1.3600351}} + +@article{Suaud_2017, + Author = {Suaud, Nicolas and Malrieu, Jean-Paul}, + Doi = {10.1080/00268976.2017.1303207}, + Issn = {0026-8976}, + Journal = {Mol. Phys.}, + Month = {Nov}, + Number = {21-22}, + Pages = {2684--2695}, + Publisher = {Taylor {\&} Francis}, + Title = {{Natural molecular orbitals: limits of a Lowdin's conjecture}}, + Volume = {115}, + Year = {2017}, + Bdsk-Url-1 = {https://doi.org/10.1080/00268976.2017.1303207}} + +@article{Angeli_2009, + Author = {Angeli, Celestino}, + Doi = {10.1002/jcc.21155}, + Issn = {0192-8651}, + Journal = {J. Comput. Chem.}, + Month = {Jun}, + Number = {8}, + Pages = {1319--1333}, + Publisher = {John Wiley {\&} Sons, Ltd}, + Title = {{On the nature of the π {$\rightarrow$} π{$\ast$} ionic excited states: The V state of ethene as a prototype}}, + Volume = {30}, + Year = {2009}, + Bdsk-Url-1 = {https://doi.org/10.1002/jcc.21155}} + +@article{Angeli_2003, + Author = {Angeli, Celestino and Calzado, Carmen J. and Cimiraglia, Renzo and Evangelisti, Stefano and Guih\'ery, Nathalie and Leininger, Thierry and Malrieu, Jean-Paul and Maynau, Daniel and Ruiz, Jos\'e Vicente Pitarch and Sparta, Manuel}, + Doi = {10.1080/0026897031000082149}, + Issn = {0026-8976}, + Journal = {Mol. Phys.}, + Month = {May}, + Number = {9}, + Pages = {1389--1398}, + Publisher = {Taylor {\&} Francis}, + Title = {{The use of local orbitals in multireference calculations}}, + Volume = {101}, + Year = {2003}, + Bdsk-Url-1 = {https://doi.org/10.1080/0026897031000082149}} + +@article{Deustua_2017, + Author = {Deustua, J. Emiliano and Shen, Jun and Piecuch, Piotr}, + Date-Added = {2020-10-09 12:21:32 +0200}, + Date-Modified = {2020-10-09 12:21:59 +0200}, + Doi = {10.1103/PhysRevLett.119.223003}, + Journal = {Phys. Rev. Lett.}, + Pages = {223003}, + Title = {Converging High-Level Coupled-Cluster Energetics by Monte Carlo Sampling and Moment Expansions}, + Volume = {119}, + Year = {2017}, + Bdsk-Url-1 = {https://link.aps.org/doi/10.1103/PhysRevLett.119.223003}, + Bdsk-Url-2 = {https://doi.org/10.1103/PhysRevLett.119.223003}} + +@article{Zhang_2020, + Author = {Zhang, Ning and Liu, Wenjian and Hoffmann, Mark R.}, + Date-Added = {2020-10-09 12:06:01 +0200}, + Date-Modified = {2020-10-09 12:06:54 +0200}, + Doi = {10.1021/acs.jctc.9b01200}, + Journal = {J. Chem. Theory Comput.}, + Number = {4}, + Pages = {2296-2316}, + Title = {Iterative Configuration Interaction with Selection}, + Volume = {16}, + Year = {2020}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.9b01200}} + +@article{Lei_2017, + Author = {Yibo Lei and Wenjian Liu and Mark R. Hoffmann}, + Date-Added = {2020-10-09 12:04:45 +0200}, + Date-Modified = {2020-10-09 12:07:10 +0200}, + Doi = {10.1080/00268976.2017.1308029}, + Journal = {Mol. Phys.}, + Number = {21-22}, + Pages = {2696-2707}, + Title = {Further development of SDSPT2 for strongly correlated electrons}, + Volume = {115}, + Year = {2017}, + Bdsk-Url-1 = {https://doi.org/10.1080/00268976.2017.1308029}} + +@article{Liu_2014, + Author = {Liu, W. and Hoffmann, M.R.}, + Date-Added = {2020-10-09 12:02:24 +0200}, + Date-Modified = {2020-10-09 12:07:31 +0200}, + Doi = {10.1007/s00214-014-1481-x}, + Journal = {Theor. Chem. Acc.}, + Pages = {1481}, + Title = {SDS: the static--dynamic--static framework for strongly correlated electrons}, + Volume = {133}, + Year = {2014}, + Bdsk-Url-1 = {https://doi.org/10.1007/s00214-014-1481-x}} + +@article{Chan_2011, + Abstract = { The density matrix renormalization group is a method that is useful for describing molecules that have strongly correlated electrons. Here we provide a pedagogical overview of the basic challenges of strong correlation, how the density matrix renormalization group works, a survey of its existing applications to molecular problems, and some thoughts on the future of the method. }, + Author = {Chan, Garnet Kin-Lic and Sharma, Sandeep}, + Date-Added = {2020-10-09 11:59:58 +0200}, + Date-Modified = {2020-10-09 21:37:30 +0200}, + Doi = {10.1146/annurev-physchem-032210-103338}, + Journal = {Annu. Rev. Phys. Chem.}, + Pages = {465-481}, + Title = {The Density Matrix Renormalization Group in Quantum Chemistry}, + Volume = {62}, + Year = {2011}, + Bdsk-Url-1 = {https://doi.org/10.1146/annurev-physchem-032210-103338}} + +@article{White_1993, + Author = {White, S. R.}, + Date-Added = {2020-10-09 11:57:24 +0200}, + Date-Modified = {2020-10-09 11:58:16 +0200}, + Doi = {10.1103/PhysRevB.48.10345}, + Journal = {Phys. Rev. B}, + Pages = {10345}, + Title = {Density-matrix algorithms for quantum renormalization groups}, + Volume = {48}, + Year = {1993}, + Bdsk-Url-1 = {https://doi.org/10.1103/PhysRevLett.69.2863}} + +@article{Eriksen_2019b, + Author = {J. J. Eriksen and J. Gauss}, + Date-Added = {2020-08-25 18:14:27 +0200}, + Date-Modified = {2020-08-25 18:15:20 +0200}, + Doi = {10.1021/acs.jpclett.9b02968}, + Journal = {J. Phys. Chem. Lett.}, + Pages = {7910--7915}, + Title = {Generalized Many-Body Expanded Full Configuration Interaction Theory}, + Volume = {27}, + Year = {2019}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jpclett.9b02968}} + +@article{Eriksen_2017, + Author = {J. J. Eriksen and F. Lipparini and J. Gauss}, + Date-Added = {2020-08-25 18:12:46 +0200}, + Date-Modified = {2020-08-25 18:13:55 +0200}, + Doi = {10.1021/acs.jpclett.7b02075}, + Journal = {J. Phys. Chem. Lett.}, + Pages = {4633--4639}, + Title = {Virtual Orbital Many-Body Expansions: A Possible Route towards the Full Configuration Interaction Limit}, + Volume = {8}, + Year = {2017}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jpclett.7b02075}} + +@article{Sauer_2009, + Author = {Sauer, Stephan P. A. and Schreiber, Marko and Silva-Junior, Mario R. and Thiel, Walter}, + Date-Added = {2020-08-24 16:15:18 +0200}, + Date-Modified = {2020-08-24 16:20:35 +0200}, + Doi = {10.1021/ct800256j}, + Journal = {J. Chem. Theory Comput.}, + Number = {3}, + Pages = {555--564}, + Title = {Benchmarks for Electronically Excited States: A Comparison of Noniterative and Iterative Triples Corrections in Linear Response Coupled Cluster Methods: CCSDR(3) versus CC3}, + Volume = {5}, + Year = {2009}, + Bdsk-Url-1 = {https://doi.org/10.1021/ct800256j}} + +@article{Schreiber_2008, + Author = {Schreiber, M. and Silva-Junior, M. R. and Sauer, S. P. A. and Thiel, W.}, + Date-Added = {2020-08-24 16:15:18 +0200}, + Date-Modified = {2020-08-24 16:21:02 +0200}, + Doi = {10.1063/1.2889385}, + Journal = {J. Chem. Phys.}, + Pages = {134110}, + Title = {Benchmarks for Electronically Excited States: CASPT2, CC2, CCSD and CC3}, + Volume = 128, + Year = 2008, + Bdsk-Url-1 = {https://doi.org/10.1063/1.2889385}} + +@article{Silva-Junior_2010a, + Author = {Silva-Junior, M. R. and Schreiber, M. and Sauer, S. P. A. and Thiel, W.}, + Date-Added = {2020-08-24 16:15:18 +0200}, + Date-Modified = {2020-08-24 16:19:10 +0200}, + Doi = {10.1063/1.2973541}, + Journal = {J. Chem. Phys.}, + Pages = {104103}, + Title = {Benchmarks for Electronically Excited States: Time-Dependent Density Functional Theory and Density Functional Theory Based Multireference Configuration Interaction}, + Volume = 129, + Year = 2008, + Bdsk-Url-1 = {https://doi.org/10.1063/1.2973541}} + +@article{Silva-Junior_2010b, + Author = {Silva-Junior, M. R. and Sauer, S. P. A. and Schreiber, M. and Thiel, W.}, + Date-Added = {2020-08-24 16:15:18 +0200}, + Date-Modified = {2020-08-24 16:19:37 +0200}, + Doi = {10.1080/00268970903549047}, + Journal = {Mol. Phys.}, + Pages = {453--465}, + Title = {Basis Set Effects on Coupled Cluster Benchmarks of Electronically Excited States: CC3, CCSDR(3) and CC2}, + Volume = 108, + Year = 2010, + Bdsk-Url-1 = {https://doi.org/10.1080/00268970903549047}} + +@article{Silva-Junior_2010c, + Author = {Silva-Junior, M. R. and Schreiber, M. and Sauer, S. P. A. and Thiel, W.}, + Date-Added = {2020-08-24 16:15:18 +0200}, + Date-Modified = {2020-08-24 16:20:03 +0200}, + Doi = {10.1063/1.3499598}, + Journal = {J. Chem. Phys.}, + Pages = {174318}, + Title = {Benchmarks of Electronically Excited States: Basis Set Effecs on {{CASPT2}} Results}, + Volume = 133, + Year = 2010, + Bdsk-Url-1 = {https://doi.org/10.1063/1.3499598}} + +@article{Boys_1960, + Author = {J. M. Foster and S. F. Boys}, + Date-Added = {2020-08-22 17:56:32 +0200}, + Date-Modified = {2020-08-22 17:57:16 +0200}, + Doi = {10.1103/RevModPhys.32.300}, + Journal = {Rev. Mod. 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Jacquemin}, + Date-Added = {2020-08-02 17:39:54 +0200}, + Date-Modified = {2020-08-02 17:39:54 +0200}, + Doi = {10.1021/acs.jctc.8b00406}, + Journal = {J. Chem. Theory Comput.}, + Pages = {4360}, + Title = {A Mountaineering Strategy to Excited States: Highly-Accurate Reference Energies and Benchmarks}, + Volume = {14}, + Year = {2018}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.8b00406}} + +@article{Loos_2019, + Author = {Loos, Pierre-Fran{\c c}ois and Boggio-Pasqua, Martial and Scemama, Anthony and Caffarel, Michel and Jacquemin, Denis}, + Date-Added = {2020-08-02 17:39:50 +0200}, + Date-Modified = {2020-08-02 17:39:50 +0200}, + Doi = {10.1021/acs.jctc.8b01205}, + Journal = {J. Chem. Theory Comput.}, + Number = {3}, + Pages = {1939--1956}, + Title = {Reference Energies for Double Excitations}, + Volume = {15}, + Year = {2019}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.8b01205}} + +@article{Loos_2020a, + Author = {P. F. Loos and A. Scemama and D. 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Theory Comput.}, + Month = {Jun}, + Number = {6}, + Pages = {3591--3609}, + Publisher = {American Chemical Society}, + Title = {{Quantum Package 2.0: An Open-Source Determinant-Driven Suite of Programs}}, + Volume = {15}, + Year = {2019}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.9b00176}} + +@article{Scemama_2013, + Author = {Scemama, Anthony and Caffarel, Michel and Oseret, Emmanuel and Jalby, William}, + Date-Modified = {2020-08-16 13:53:13 +0200}, + Doi = {10.1002/jcc.23216}, + Journal = {J. Comput. Chem.}, + Pages = {938--951}, + Title = {{Quantum Monte Carlo for large chemical systems: Implementing efficient strategies for petascale platforms and beyond}}, + Volume = {34}, + Year = {2013}, + Bdsk-Url-1 = {https://doi.org/10.1002/jcc.23216}} + +@article{Caffarel_2016a, + Author = {Caffarel, Michel and Applencourt, Thomas and Giner, Emmanuel and Scemama, Anthony}, + Date-Modified = {2020-08-18 20:50:28 +0200}, + Doi = {10.1063/1.4947093}, + Issn = {0021-9606}, + Journal = {J. Chem. Phys.}, + Month = {Apr}, + Number = {15}, + Pages = {151103}, + Publisher = {American Institute of Physics}, + Title = {{Communication: Toward an improved control of the fixed-node error in quantum Monte Carlo: The case of the water molecule}}, + Volume = {144}, + Year = {2016}, + Bdsk-Url-1 = {https://doi.org/10.1063/1.4947093}} + +@article{Holmes_2017, + Author = {Holmes, Adam A. and Umrigar, C. J. and Sharma, Sandeep}, + Doi = {10.1063/1.4998614}, + Issn = {0021-9606}, + Journal = {J. Chem. Phys.}, + Month = {Oct}, + Number = {16}, + Pages = {164111}, + Publisher = {American Institute of Physics}, + Title = {{Excited states using semistochastic heat-bath configuration interaction}}, + Volume = {147}, + Year = {2017}, + Bdsk-Url-1 = {https://doi.org/10.1063/1.4998614}} + +@article{Scemama_2018, + Author = {Scemama, Anthony and Garniron, Yann and Caffarel, Michel and Loos, Pierre-Fran{\c c}ois}, + Doi = {10.1021/acs.jctc.7b01250}, + Issn = {1549-9618}, + Journal = {J. Chem. Theory Comput.}, + Month = {Mar}, + Number = {3}, + Pages = {1395--1402}, + Publisher = {American Chemical Society}, + Title = {{Deterministic Construction of Nodal Surfaces within Quantum Monte Carlo: The Case of FeS}}, + Volume = {14}, + Year = {2018}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.7b01250}} + +@article{Scemama_2018b, + Author = {Scemama, Anthony and Benali, Anouar and Jacquemin, Denis and Caffarel, Michel and Loos, Pierre-Fran{\c c}ois}, + Doi = {10.1063/1.5041327}, + Issn = {0021-9606}, + Journal = {J. Chem. Phys.}, + Month = {Jul}, + Number = {3}, + Pages = {034108}, + Publisher = {American Institute of Physics}, + Title = {{Excitation energies from diffusion Monte Carlo using selected configuration interaction nodes}}, + Volume = {149}, + Year = {2018}, + Bdsk-Url-1 = {https://doi.org/10.1063/1.5041327}} + +@article{Giner_2015, + Author = {Giner, Emmanuel and Scemama, Anthony and Caffarel, Michel}, + Doi = {10.1063/1.4905528}, + Issn = {0021-9606}, + Journal = {J. Chem. Phys.}, + Month = {Jan}, + Number = {4}, + Pages = {044115}, + Publisher = {American Institute of Physics}, + Title = {{Fixed-node diffusion Monte Carlo potential energy curve of the fluorine molecule F2 using selected configuration interaction trial wavefunctions}}, + Volume = {142}, + Year = {2015}, + Bdsk-Url-1 = {https://doi.org/10.1063/1.4905528}} + +@article{Huron_1973, + Author = {Huron, B. and Malrieu, J. P. and Rancurel, P.}, + Doi = {10.1063/1.1679199}, + Issn = {0021-9606}, + Journal = {J. Chem. Phys.}, + Month = {Jun}, + Number = {12}, + Pages = {5745--5759}, + Publisher = {American Institute of Physics}, + Title = {{Iterative perturbation calculations of ground and excited state energies from multiconfigurational zeroth{-}order wavefunctions}}, + Volume = {58}, + Year = {1973}, + Bdsk-Url-1 = {https://doi.org/10.1063/1.1679199}} + +@article{Holmes_2016, + Author = {Holmes, Adam A. and Changlani, Hitesh J. and Umrigar, C. J.}, + Doi = {10.1021/acs.jctc.5b01170}, + Issn = {1549-9618}, + Journal = {J. Chem. Theory Comput.}, + Month = {Apr}, + Number = {4}, + Pages = {1561--1571}, + Publisher = {American Chemical Society}, + Title = {{Efficient Heat-Bath Sampling in Fock Space}}, + Volume = {12}, + Year = {2016}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.5b01170}} + +@article{Bender_1969, + Author = {Bender, Charles F. and Davidson, Ernest R.}, + Doi = {10.1103/PhysRev.183.23}, + Issn = {1536-6065}, + Journal = {Phys. Rev.}, + Month = {Jul}, + Number = {1}, + Pages = {23--30}, + Publisher = {American Physical Society}, + Title = {{Studies in Configuration Interaction: The First-Row Diatomic Hydrides}}, + Volume = {183}, + Year = {1969}, + Bdsk-Url-1 = {https://doi.org/10.1103/PhysRev.183.23}} + +@article{Buenker_1974, + Author = {Buenker, Robert J. and Peyerimhoff, Sigrid D.}, + Doi = {10.1007/BF02394557}, + Issn = {1432-2234}, + Journal = {Theor. Chim. Acta}, + Month = {Aug}, + Number = {1}, + Pages = {33--58}, + Publisher = {Springer-Verlag}, + Title = {{Individualized configuration selection in CI calculations with subsequent energy extrapolation}}, + Volume = {35}, + Year = {1974}, + Bdsk-Url-1 = {https://doi.org/10.1007/BF02394557}} + +@article{Liu_2016, + Author = {Liu, Wenjian and Hoffmann, Mark R.}, + Doi = {10.1021/acs.jctc.5b01099}, + Issn = {1549-9618}, + Journal = {J. Chem. Theory Comput.}, + Month = {Mar}, + Number = {3}, + Pages = {1169--1178}, + Publisher = {American Chemical Society}, + Title = {{iCI: Iterative CI toward full CI}}, + Volume = {12}, + Year = {2016}, + Bdsk-Url-1 = {https://doi.org/10.1021/acs.jctc.5b01099}} + +@misc{Scemama_2015, + Author = {Scemama, Anthony and Giner, Emmanuel and Applencourt, Thomas and Caffarel, Michel}, + Doi = {10.13140/RG.2.1.3187.9766}, + Howpublished = {Pacifichem, Advances in Quantum Monte Carlo}, + Month = {Dec}, + Title = {{QMC using very large configuration interaction-type expansions}}, + Year = {2015}, + Bdsk-Url-1 = {https://doi.org/10.13140/RG.2.1.3187.9766}} + +@misc{Applencourt_2018, + Archiveprefix = {arXiv}, + Author = {Thomas Applencourt and Kevin Gasperich and Anthony Scemama}, + Eprint = {1812.06902}, + Primaryclass = {physics.chem-ph}, + Title = {Spin adaptation with determinant-based selected configuration interaction}, + Year = {2018}} diff --git a/Manuscript/Ec.tex b/Manuscript/Ec.tex new file mode 100644 index 0000000..f4f66af --- /dev/null +++ b/Manuscript/Ec.tex @@ -0,0 +1,73 @@ +\documentclass[aps,prb,reprint,noshowkeys,superscriptaddress]{revtex4-1} +\usepackage{graphicx,dcolumn,bm,xcolor,microtype,multirow,amscd,amsmath,amssymb,amsfonts,physics,wrapfig,txfonts} +\usepackage[version=4]{mhchem} + +\newcommand{\ie}{\textit{i.e.}} +\newcommand{\eg}{\textit{e.g.}} +\newcommand{\alert}[1]{\textcolor{black}{#1}} +\usepackage[normalem]{ulem} +\newcommand{\titou}[1]{\textcolor{red}{#1}} +\newcommand{\trashPFL}[1]{\textcolor{red}{\sout{#1}}} +\newcommand{\PFL}[1]{\titou{(\underline{\bf PFL}: #1)}} +\newcommand{\toto}[1]{\textcolor{green}{#1}} +\newcommand{\trashAS}[1]{\textcolor{green}{\sout{#1}}} +\newcommand{\AS}[1]{\toto{(\underline{\bf AS}: #1)}} + +\newcommand{\mc}{\multicolumn} +\newcommand{\fnm}{\footnotemark} +\newcommand{\fnt}{\footnotetext} +\newcommand{\tabc}[1]{\multicolumn{1}{c}{#1}} +\newcommand{\QP}{\textsc{quantum package}} + +\usepackage[ + colorlinks=true, + citecolor=blue, + breaklinks=true + ]{hyperref} +\urlstyle{same} + +\begin{document} + +\newcommand{\LCPQ}{Laboratoire de Chimie et Physique Quantiques (UMR 5626), Universit\'e de Toulouse, CNRS, UPS, France} +\newcommand{\CEISAM}{Universit\'e de Nantes, CNRS, CEISAM UMR 6230, F-44000 Nantes, France} + +\title{Reference correlation energies in finite Hilbert spaces: five- and six-membered rings} + +\author{Micka\"el V\'eril} +\affiliation{\LCPQ} +\author{Yann Damour} +\affiliation{\LCPQ} +\author{Anthony Scemama} +\affiliation{\LCPQ} +\author{Denis Jacquemin} +\affiliation{\CEISAM} +\author{Pierre-Fran\c{c}ois Loos} +\email{loos@irsamc.ups-tlse.fr} +\affiliation{\LCPQ} + +% Abstract +\begin{abstract} +\end{abstract} + +% Title +\maketitle + +\section{Introduction} + +\section{Computational details} + +\section{Results and discussion} + +\section{Conclusion} + +\begin{acknowledgements} +This work was performed using HPC resources from GENCI-TGCC (2020-gen1738) and from CALMIP (Toulouse) under allocation 2020-18005. +PFL and AS have received funding from the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme (Grant agreement No.~863481). +\end{acknowledgements} + +\section*{Data availability statement} +The data that support the findings of this study are openly available in Zenodo at \href{http://doi.org/XX.XXXX/zenodo.XXXXXXX}{http://doi.org/XX.XXXX/zenodo.XXXXXXX}. + +\bibliography{Ec} + +\end{document} diff --git a/benzene/cc-pvdz/benzene.nofci.out b/benzene/cc-pvdz/benzene.nofci.out index 6e5be13..241164a 100644 --- a/benzene/cc-pvdz/benzene.nofci.out +++ b/benzene/cc-pvdz/benzene.nofci.out @@ -4350,3 +4350,229 @@ Iter Energy S^2 Residual 7 -217.4173118941 0.003264 0.294E-08 8 -217.4173119155 0.003264 0.102E-08 9 -217.4173119231 0.003264 0.414E-09 + 10 -217.4173119262 0.003264 0.169E-09 + 11 -217.4173119274 0.003264 0.673E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 67.879211 GB ] [ VIRT MEM : 84.512684 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 233086.397569 s ] [ CPU TIME: ************** s ] <<<<< .. + + +.. >>>>> [ RES MEM : 25.178658 GB ] [ VIRT MEM : 36.200653 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 233090.634623 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Energy of state 1 -217.4173119274494 +* S^2 of state 1 0.3263588373208825E-02 +* Saved determinants 41833507 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 23.443043 GB ] [ VIRT MEM : 28.219784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 233551.672890 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 41656018 + +.. >>>>> [ RES MEM : 23.443043 GB ] [ VIRT MEM : 28.219784 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 233551.763394 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 41656018 +* Number of comb teeth 100 +* pt2_n_tasks_max 870 +* PT2 Energy denominator -217.4173119274494 + +.. >>>>> [ RES MEM : 30.671066 GB ] [ VIRT MEM : 35.457417 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 233584.703959 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 41656018 + +.. >>>>> [ RES MEM : 30.671066 GB ] [ VIRT MEM : 35.457417 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 233584.790267 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 41656018 +* Number of comb teeth 100 +* pt2_n_tasks_max 870 +* Number of tasks 42476564 +* Number of fragmented tasks 11464 +* Number of threads for PT2 72 +* Memory (Gb) 45.20599612168968 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -217.4853677195 0.190E-02 0.6199641937 0.0078838122 3112.8668 + 4 -217.4857937358 0.136E-02 0.6255605610 0.0079273664 3917.4754 + 5 -217.4857142827 0.965E-03 0.6257625479 0.0079157589 4816.8483 + 6 -217.4857151595 0.777E-03 0.6256725196 0.0079189905 5619.1574 + 7 -217.4856149736 0.659E-03 0.6254676511 0.0079010186 6447.8476 + 8 -217.4853215097 0.674E-03 0.6231730188 0.0078671977 7216.2379 + 9 -217.4853424356 0.592E-03 0.6227642412 0.0078783833 7946.2287 + 10 -217.4855940989 0.616E-03 0.6256126525 0.0079008158 8322.0344 + 11 -217.4856544044 0.559E-03 0.6266220966 0.0079055986 8439.0258 + 12 -217.4857253608 0.515E-03 0.6270309359 0.0079141060 9086.5732 + 13 -217.4855402436 0.467E-03 0.6252914247 0.0078959279 9277.8165 + 14 -217.4856695794 0.452E-03 0.6259554818 0.0079138427 9912.5005 + 15 -217.4857545984 0.429E-03 0.6264597257 0.0079262202 10473.1468 + 16 -217.4857352832 0.401E-03 0.6259721834 0.0079278076 10554.5837 + 17 -217.4858998754 0.412E-03 0.6272506409 0.0079477265 10677.8507 + 18 -217.4860038247 0.386E-03 0.6279569904 0.0079629746 11162.4349 + 19 -217.4859594149 0.368E-03 0.6277111598 0.0079567004 11916.1570 + 20 -217.4860073535 0.352E-03 0.6277802630 0.0079664461 12638.4535 + 21 -217.4860263942 0.337E-03 0.6280530368 0.0079674826 12851.8051 + 22 -217.4859950596 0.323E-03 0.6278783110 0.0079622949 12871.0417 + 23 -217.4859920018 0.308E-03 0.6276646625 0.0079643553 13308.8848 + 24 -217.4860311730 0.293E-03 0.6276517040 0.0079735625 13326.4013 + 25 -217.4860385852 0.281E-03 0.6279123613 0.0079725625 13520.5458 + 26 -217.4860619847 0.270E-03 0.6282559865 0.0079738510 13766.9926 + 27 -217.4860797327 0.261E-03 0.6280261470 0.0079797634 14264.4677 + 28 -217.4861230650 0.255E-03 0.6282079006 0.0079854096 14893.4933 + 29 -217.4861172806 0.250E-03 0.6285179596 0.0079800810 15458.3672 + 30 -217.4861645634 0.247E-03 0.6288451800 0.0079854745 15980.5263 + 31 -217.4861596355 0.238E-03 0.6291639882 0.0079812387 16117.9330 + 32 -217.4862116026 0.237E-03 0.6294913198 0.0079881911 16668.0734 + 33 -217.4861727079 0.221E-03 0.6289246789 0.0079861503 17186.6894 + 34 -217.4861918328 0.215E-03 0.6289820809 0.0079906505 17500.3978 + 35 -217.4861963005 0.206E-03 0.6288421266 0.0079928570 17698.9660 + 36 -217.4861548460 0.205E-03 0.6282982365 0.0079893099 17861.7051 + 37 -217.4861222017 0.197E-03 0.6278326709 0.0079877337 18156.3658 + 38 -217.4861148790 0.192E-03 0.6276550067 0.0079880273 18274.8281 + 39 -217.4860840693 0.190E-03 0.6272629112 0.0079853815 18548.6954 + 41 -217.4860961099 0.178E-03 0.6275603745 0.0079851179 18907.6068 + 42 -217.4860713068 0.176E-03 0.6272703663 0.0079829703 19396.8258 + 43 -217.4860701695 0.171E-03 0.6271709526 0.0079842717 19896.7045 + 44 -217.4860749680 0.166E-03 0.6271927971 0.0079851348 20134.6820 + 45 -217.4860846271 0.163E-03 0.6271650428 0.0079876160 20293.5771 + 46 -217.4860815853 0.164E-03 0.6272235998 0.0079865076 20329.9210 + 47 -217.4860275422 0.169E-03 0.6266902223 0.0079810071 20655.7678 + 48 -217.4860243537 0.165E-03 0.6266710475 0.0079802356 20851.3353 + 49 -217.4860612129 0.160E-03 0.6270204113 0.0079842445 21077.6269 + 51 -217.4860360789 0.153E-03 0.6265309226 0.0079843167 21261.7714 + 52 -217.4860221672 0.150E-03 0.6264827709 0.0079825357 21410.8838 + 53 -217.4859745181 0.155E-03 0.6258940106 0.0079789101 21609.3920 + 54 -217.4859712751 0.152E-03 0.6258871404 0.0079785157 21627.6486 + 55 -217.4859784029 0.149E-03 0.6259548560 0.0079793434 21803.9127 + 56 -217.4859419461 0.151E-03 0.6255707314 0.0079756663 22000.2279 + 58 -217.4859230561 0.145E-03 0.6253199274 0.0079743981 22128.0450 + 59 -217.4859113769 0.143E-03 0.6250867909 0.0079742842 22229.7618 + 60 -217.4859206177 0.141E-03 0.6250968861 0.0079758297 22390.6734 + 62 -217.4859413879 0.140E-03 0.6254401179 0.0079770151 22765.9383 + 64 -217.4860130540 0.150E-03 0.6261362522 0.0079846985 22947.0083 + 65 -217.4859823334 0.151E-03 0.6258379992 0.0079814648 22978.7929 + 67 -217.4860086565 0.148E-03 0.6261941342 0.0079830535 23252.7413 + 68 -217.4859872762 0.141E-03 0.6261385027 0.0079786842 23263.3748 + 69 -217.4860051823 0.140E-03 0.6263526453 0.0079801390 23341.3858 + 70 -217.4860064260 0.138E-03 0.6262895771 0.0079806480 23454.1088 + 71 -217.4859978852 0.137E-03 0.6263235859 0.0079789906 23623.1433 + 72 -217.4860104015 0.135E-03 0.6265107669 0.0079794393 23734.0249 + 73 -217.4860176036 0.134E-03 0.6264982167 0.0079806447 23769.0858 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 31.089817 GB ] [ VIRT MEM : 36.379189 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 257512.893219 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 41656018 + +.. >>>>> [ RES MEM : 31.089817 GB ] [ VIRT MEM : 36.379189 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 257512.979578 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 41656018 +* Number of comb teeth 100 +* pt2_n_tasks_max 870 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8995334189716244 + +Summary at N_det = 41833507 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -217.41731193 +# PT2 -0.06870568 0.00013352 +# rPT2 -0.06816170 0.00013246 +# +# E+PT2 -217.48601760 0.00013352 +# E+rPT2 -217.48547363 0.00013246 +# ============ ============================= + + N_det = 41833507 + N_states = 1 + + * State 1 + < S^2 > = 3.263588373208825E-003 + E = -217.417311927449 + Variance = 0.626498216653461 + PT norm = 8.933445389600192E-002 + PT2 = -6.870567618562975E-002 + rPT2 = -6.816170186411555E-002 + E+PT2 = -217.486017603635 +/- 1.335168201144385E-004 + E+rPT2 = -217.485473629314 +/- 1.324597062678874E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 385.277019406018 + Ven = -1315.56057531265 + Vee = 439.444093821300 + Vecp = 0.000000000000000E+000 + T = 273.422150157887 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.0705 -217.47903206 + -0.0718 -217.48482525 + -0.0729 -217.48458358 + -0.0738 -217.48428220 + -0.0750 -217.48242926 + -0.0762 -217.48332595 + -0.0786 -217.48490434 + =========== =================== + +* Number of unique beta determinants 6068482 +* Number of unique alpha determinants 6141416 + +.. >>>>> [ RES MEM : 46.204697 GB ] [ VIRT MEM : 61.476562 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 307197.609280 s ] [ CPU TIME: ************** s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 83171337 +* Number of threads for diagonalization 72 +* Memory(Gb) 122.2481629587710 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -217.4165381630 0.003590 0.636E-03 + 2 -217.4205580256 0.003842 0.571E-04 + 3 -217.4207438425 0.003906 0.103E-04 + 4 -217.4207737816 0.003917 0.127E-05 + 5 -217.4207787948 0.003912 0.184E-06 + 6 -217.4207798851 0.003908 0.461E-07 + 7 -217.4207801708 0.003907 0.154E-07 + 8 -217.4207802631 0.003906 0.531E-08 + 9 -217.4207802964 0.003907 0.180E-08 + 10 -217.4207803092 0.003907 0.703E-09 diff --git a/benzene/cc-pvdz/slurm-485510.out b/benzene/cc-pvdz/slurm-485510.out index 50be94f..e59f535 100644 --- a/benzene/cc-pvdz/slurm-485510.out +++ b/benzene/cc-pvdz/slurm-485510.out @@ -17086,3 +17086,18887 @@ 4.78 % in 3078 seconds 4.87 % in 3219 seconds 4.97 % in 3357 seconds + 5.06 % in 3497 seconds + 5.16 % in 3636 seconds + 5.25 % in 3664 seconds + 5.35 % in 3678 seconds + 5.54 % in 3711 seconds + 5.64 % in 3745 seconds + 5.73 % in 3768 seconds + 5.92 % in 3778 seconds + 6.02 % in 3810 seconds + 6.11 % in 3840 seconds + 6.21 % in 3856 seconds + 6.30 % in 3869 seconds + 6.40 % in 3886 seconds + 6.49 % in 3898 seconds + 6.59 % in 3918 seconds + 6.69 % in 3941 seconds + 6.78 % in 3964 seconds + 6.88 % in 3987 seconds + 6.97 % in 4013 seconds + 7.07 % in 4039 seconds + 7.16 % in 4055 seconds + 7.45 % in 4094 seconds + 7.55 % in 4126 seconds + 7.64 % in 4136 seconds + 7.83 % in 4150 seconds + 7.93 % in 4183 seconds + 8.02 % in 4217 seconds + 8.12 % in 4233 seconds + 8.21 % in 4248 seconds + 8.31 % in 4263 seconds + 8.40 % in 4285 seconds + 8.50 % in 4297 seconds + 8.60 % in 4315 seconds + 8.69 % in 4332 seconds + 8.79 % in 4362 seconds + 8.88 % in 4386 seconds + 8.98 % in 4411 seconds + 9.07 % in 4437 seconds + 9.17 % in 4454 seconds + 9.36 % in 4466 seconds + 9.65 % in 4492 seconds + 9.84 % in 4517 seconds + 9.93 % in 4536 seconds +10.12 % in 4567 seconds +10.22 % in 4584 seconds +10.32 % in 4599 seconds +10.41 % in 4615 seconds +10.51 % in 4637 seconds +10.60 % in 4657 seconds +10.70 % in 4679 seconds +10.79 % in 4701 seconds +10.89 % in 4725 seconds +10.98 % in 4747 seconds +11.27 % in 4758 seconds +11.56 % in 4775 seconds +11.75 % in 4797 seconds +11.84 % in 4817 seconds +11.94 % in 4833 seconds +12.03 % in 4850 seconds +12.13 % in 4869 seconds +12.23 % in 4882 seconds +12.32 % in 4907 seconds +12.42 % in 4925 seconds +12.51 % in 4947 seconds +12.61 % in 4971 seconds +12.70 % in 4994 seconds +12.80 % in 5018 seconds +12.89 % in 5030 seconds +13.18 % in 5040 seconds +13.56 % in 5052 seconds +13.66 % in 5063 seconds +13.75 % in 5073 seconds +13.85 % in 5098 seconds +13.94 % in 5108 seconds +14.04 % in 5133 seconds +14.14 % in 5146 seconds +14.23 % in 5165 seconds +14.33 % in 5187 seconds +14.42 % in 5208 seconds +14.52 % in 5225 seconds +14.61 % in 5246 seconds +14.71 % in 5268 seconds +14.80 % in 5292 seconds +14.90 % in 5315 seconds 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+27.79 % in 6699 seconds +27.89 % in 6715 seconds +27.98 % in 6737 seconds +28.08 % in 6758 seconds +28.18 % in 6781 seconds +28.27 % in 6802 seconds +28.46 % in 6813 seconds +28.75 % in 6823 seconds +29.04 % in 6834 seconds +29.32 % in 6845 seconds +29.61 % in 6856 seconds +29.89 % in 6867 seconds +29.99 % in 6883 seconds +30.09 % in 6898 seconds +30.18 % in 6916 seconds +30.28 % in 6933 seconds +30.37 % in 6952 seconds +30.47 % in 6967 seconds +30.56 % in 6987 seconds +30.66 % in 7009 seconds +30.75 % in 7029 seconds +30.85 % in 7054 seconds +30.95 % in 7071 seconds +31.23 % in 7082 seconds +31.61 % in 7095 seconds +31.90 % in 7105 seconds +32.19 % in 7116 seconds +32.47 % in 7128 seconds +32.66 % in 7151 seconds +32.76 % in 7165 seconds +32.86 % in 7178 seconds +32.95 % in 7191 seconds +33.05 % in 7211 seconds +33.14 % in 7231 seconds +33.24 % in 7252 seconds +33.33 % in 7275 seconds +33.43 % in 7297 seconds +33.52 % in 7307 seconds +33.81 % in 7317 seconds +34.19 % in 7329 seconds 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256770 seconds +13.56 % in 256781 seconds +13.56 % in 256792 seconds +13.56 % in 256802 seconds +13.56 % in 256812 seconds +13.56 % in 256822 seconds +13.56 % in 256833 seconds +13.56 % in 256843 seconds +13.56 % in 256853 seconds +13.57 % in 256863 seconds +13.57 % in 256873 seconds +13.57 % in 256883 seconds +13.57 % in 256893 seconds +13.57 % in 256903 seconds +13.57 % in 256913 seconds +13.57 % in 256923 seconds +13.57 % in 256933 seconds +13.57 % in 256943 seconds +13.58 % in 256956 seconds +13.58 % in 256966 seconds +13.58 % in 256976 seconds +13.58 % in 256987 seconds +13.58 % in 257004 seconds +13.58 % in 257014 seconds +13.58 % in 257024 seconds +13.58 % in 257067 seconds +13.59 % in 257077 seconds +13.59 % in 257089 seconds +13.59 % in 257110 seconds + + unset COMMAND ++ qp run save_natorb ++ case $1 in ++ which qp_run ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' benzene +++ qp_run save_natorb benzene ++ unset COMMAND ++ qp set determinants n_det_max 1e8 ++ case $1 in ++ ezfio set determinants n_det_max 1e8 ++ case $1 in ++ shift ++ _ezfio_set determinants n_det_max 1e8 ++ _require_ezfio_file ++ [[ -z benzene ]] ++ [[ ! -d benzene ]] ++ _require_first_argument determinants n_det_max 1e8 ++ [[ -z determinants ]] ++ return 0 ++ _require_second_argument determinants n_det_max 1e8 ++ [[ -z n_det_max ]] ++ [[ -z 1e8 ]] ++ echo 1e8 ++ _ezfio_py set determinants n_det_max ++ python2 /tmpdir/loos/qp2/external/ezfio/Python/ezfio.py set determinants n_det_max ++ return 0 ++ qp run fci ++ case $1 in ++ which qp_run ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' benzene +++ qp_run fci benzene + 0.00 % in 4 seconds +22.57 % in 14 seconds +33.67 % in 24 seconds +39.76 % in 34 seconds +47.49 % in 44 seconds +54.81 % in 54 seconds +61.70 % in 64 seconds +68.33 % in 74 seconds +74.31 % in 84 seconds +80.20 % in 94 seconds +85.96 % in 104 seconds +90.73 % in 114 seconds +96.61 % in 124 seconds + 50.00 % in 23 seconds + 16.67 % in 11 seconds + 9.09 % in 11 seconds + 4.76 % in 12 seconds + 2.44 % in 13 seconds + 1.23 % in 20 seconds +88.89 % in 32 seconds + 0.62 % in 20 seconds +44.10 % in 31 seconds +44.72 % in 41 seconds +89.44 % in 53 seconds + 0.31 % in 20 seconds +22.12 % in 40 seconds +44.55 % in 61 seconds +66.98 % in 82 seconds +89.41 % in 96 seconds + 0.16 % in 20 seconds +11.08 % in 43 seconds +22.15 % in 57 seconds +26.37 % in 67 seconds +33.39 % in 78 seconds +35.73 % in 88 seconds +44.62 % in 100 seconds +50.55 % in 110 seconds +55.85 % in 122 seconds +63.18 % in 132 seconds +67.08 % in 142 seconds +73.48 % in 152 seconds +78.32 % in 163 seconds +85.18 % in 173 seconds +89.70 % in 187 seconds + 0.08 % in 18 seconds + 4.76 % in 28 seconds + 5.54 % in 41 seconds + 9.60 % in 51 seconds +11.16 % in 61 seconds +14.21 % in 71 seconds +16.78 % in 81 seconds +19.05 % in 91 seconds +21.78 % in 101 seconds +25.76 % in 111 seconds + 0.04 % in 18 seconds + 2.15 % in 28 seconds + 2.81 % in 39 seconds + 4.76 % in 49 seconds + 5.43 % in 59 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seconds + 0.67 % in 172 seconds + 0.71 % in 182 seconds + 0.78 % in 192 seconds + 0.83 % in 202 seconds + 0.89 % in 212 seconds + 0.93 % in 222 seconds + 0.95 % in 232 seconds + 0.99 % in 242 seconds + 1.01 % in 252 seconds + 1.05 % in 262 seconds + 1.09 % in 272 seconds + 1.16 % in 282 seconds + 1.23 % in 292 seconds + 1.29 % in 302 seconds + 1.33 % in 313 seconds + 1.35 % in 323 seconds + 1.37 % in 334 seconds + 1.41 % in 344 seconds + 1.45 % in 354 seconds + 1.51 % in 364 seconds + 1.58 % in 374 seconds + 1.65 % in 387 seconds + 1.69 % in 397 seconds + 1.71 % in 407 seconds + 1.74 % in 417 seconds + 1.77 % in 427 seconds + 1.81 % in 437 seconds + 1.88 % in 447 seconds + 1.93 % in 457 seconds + 2.00 % in 467 seconds + 2.04 % in 477 seconds + 2.06 % in 487 seconds + 2.09 % in 498 seconds + 2.13 % in 508 seconds + 2.18 % in 518 seconds + 2.24 % in 528 seconds + 2.30 % in 538 seconds + 2.34 % in 548 seconds + 2.37 % in 558 seconds + 2.40 % in 568 seconds + 2.43 % in 578 seconds + 2.48 % in 588 seconds + 2.54 % in 598 seconds + 2.62 % in 608 seconds + 2.68 % in 618 seconds + 2.71 % in 628 seconds + 2.75 % in 638 seconds + 2.79 % in 649 seconds + 2.84 % in 660 seconds + 2.90 % in 670 seconds + 2.96 % in 680 seconds + 3.02 % in 690 seconds + 3.06 % in 700 seconds + 3.09 % in 710 seconds + 3.11 % in 720 seconds + 3.15 % in 730 seconds + 3.20 % in 740 seconds + 3.23 % in 751 seconds + 3.25 % in 761 seconds + 3.27 % in 774 seconds + 3.27 % in 785 seconds + 3.28 % in 887 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 16.67 % in 2 seconds + 16.67 % in 2 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 16.67 % in 2 seconds + 16.67 % in 2 seconds + 16.67 % in 2 seconds + 0.00 % in 8 seconds + 0.02 % in 18 seconds + 0.03 % in 28 seconds + 0.06 % in 38 seconds + 0.08 % in 48 seconds + 0.11 % in 58 seconds + 0.14 % in 68 seconds + 0.17 % in 79 seconds + 0.21 % in 91 seconds + 0.23 % in 102 seconds + 0.24 % in 113 seconds + 0.24 % in 123 seconds + 0.25 % in 134 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in 571 seconds + 1.19 % in 581 seconds + 1.22 % in 591 seconds + 1.26 % in 601 seconds + 1.28 % in 611 seconds + 1.31 % in 621 seconds + 1.36 % in 631 seconds + 1.38 % in 641 seconds + 1.40 % in 651 seconds + 1.43 % in 664 seconds + 1.45 % in 674 seconds + 1.48 % in 684 seconds + 1.49 % in 694 seconds + 1.53 % in 704 seconds + 1.57 % in 714 seconds + 1.61 % in 724 seconds + 1.65 % in 734 seconds + 1.68 % in 744 seconds + 1.69 % in 754 seconds + 1.71 % in 764 seconds + 1.73 % in 775 seconds + 1.77 % in 785 seconds + 1.80 % in 795 seconds + 1.83 % in 805 seconds + 1.87 % in 815 seconds + 1.90 % in 825 seconds + 1.94 % in 835 seconds + 1.97 % in 845 seconds + 1.98 % in 855 seconds + 1.99 % in 865 seconds + 2.01 % in 875 seconds + 2.03 % in 885 seconds + 2.05 % in 895 seconds + 2.10 % in 905 seconds + 2.14 % in 915 seconds + 2.19 % in 925 seconds + 2.24 % in 936 seconds + 2.26 % in 946 seconds + 2.27 % in 956 seconds + 2.29 % in 966 seconds + 2.30 % in 976 seconds + 2.32 % in 986 seconds + 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in 13 seconds + 10.00 % in 1 seconds +40.00 % in 12 seconds + 10.00 % in 2 seconds +40.00 % in 12 seconds + 10.00 % in 2 seconds +40.00 % in 12 seconds + 10.00 % in 2 seconds +40.00 % in 13 seconds + 10.00 % in 2 seconds +40.00 % in 13 seconds + 10.00 % in 2 seconds +40.00 % in 13 seconds + 10.00 % in 2 seconds +40.00 % in 12 seconds + 10.00 % in 2 seconds +40.00 % in 13 seconds + 0.00 % in 8 seconds + 0.01 % in 18 seconds + 0.01 % in 28 seconds + 0.02 % in 38 seconds + 0.03 % in 48 seconds + 0.03 % in 58 seconds + 0.04 % in 68 seconds + 0.06 % in 79 seconds + 0.07 % in 89 seconds + 0.07 % in 99 seconds + 0.09 % in 110 seconds + 0.11 % in 121 seconds + 0.13 % in 133 seconds + 0.14 % in 143 seconds + 0.15 % in 153 seconds + 0.17 % in 163 seconds + 0.18 % in 173 seconds + 0.19 % in 183 seconds + 0.21 % in 194 seconds + 0.22 % in 205 seconds + 0.23 % in 217 seconds + 0.24 % in 236 seconds + 0.25 % in 249 seconds + 0.25 % in 260 seconds + 0.25 % in 271 seconds + 0.26 % in 282 seconds + 0.27 % in 292 seconds + 0.27 % in 303 seconds + 0.28 % in 313 seconds + 0.29 % in 325 seconds + 0.30 % in 335 seconds + 0.30 % in 346 seconds + 0.31 % in 356 seconds + 0.32 % in 366 seconds + 0.33 % in 376 seconds + 0.34 % in 386 seconds + 0.36 % in 397 seconds + 0.37 % in 407 seconds + 0.38 % in 417 seconds + 0.40 % in 429 seconds + 0.40 % in 440 seconds + 0.42 % in 451 seconds + 0.43 % in 461 seconds + 0.46 % in 471 seconds + 0.47 % in 481 seconds + 0.48 % in 491 seconds + 0.49 % in 501 seconds + 0.51 % in 516 seconds + 0.51 % in 526 seconds + 0.51 % in 537 seconds + 0.51 % in 549 seconds + 0.52 % in 559 seconds + 0.52 % in 577 seconds + 0.52 % in 587 seconds + 0.52 % in 598 seconds + 0.53 % in 608 seconds + 0.55 % in 618 seconds + 0.55 % in 628 seconds + 0.56 % in 638 seconds + 0.57 % in 648 seconds + 0.58 % in 658 seconds + 0.60 % in 668 seconds + 0.61 % in 678 seconds + 0.63 % in 688 seconds + 0.66 % in 698 seconds + 0.67 % in 708 seconds + 0.70 % in 718 seconds + 0.72 % in 728 seconds + 0.74 % in 738 seconds + 0.77 % in 748 seconds + 0.78 % in 758 seconds + 0.79 % in 768 seconds + 0.80 % in 778 seconds + 0.80 % in 789 seconds + 0.82 % in 799 seconds + 0.83 % in 809 seconds + 0.86 % in 819 seconds + 0.87 % in 829 seconds + 0.89 % in 839 seconds + 0.91 % in 849 seconds + 0.95 % in 859 seconds + 0.98 % in 869 seconds + 0.99 % in 879 seconds + 1.01 % in 891 seconds + 1.01 % in 903 seconds + 1.03 % in 914 seconds + 1.03 % in 924 seconds + 1.05 % in 934 seconds + 1.06 % in 944 seconds + 1.07 % in 954 seconds + 1.08 % in 964 seconds + 1.10 % in 974 seconds + 1.11 % in 984 seconds + 1.13 % in 994 seconds + 1.14 % in 1004 seconds + 1.17 % in 1015 seconds + 1.19 % in 1025 seconds + 1.22 % in 1035 seconds + 1.24 % in 1046 seconds + 1.26 % in 1056 seconds + 1.27 % in 1066 seconds + 1.28 % in 1076 seconds + 1.29 % in 1086 seconds + 1.30 % in 1096 seconds + 1.31 % in 1107 seconds + 1.32 % in 1117 seconds + 1.33 % in 1127 seconds + 1.35 % in 1137 seconds + 1.37 % in 1147 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seconds + 3.27 % in 2391 seconds + 3.27 % in 2402 seconds + 3.28 % in 2413 seconds + 3.29 % in 2423 seconds + 3.30 % in 2433 seconds + 3.31 % in 2443 seconds + 3.33 % in 2453 seconds + 3.34 % in 2463 seconds + 3.35 % in 2473 seconds + 3.36 % in 2483 seconds + 3.37 % in 2494 seconds + 3.37 % in 2504 seconds + 3.38 % in 2514 seconds + 3.39 % in 2524 seconds + 3.41 % in 2534 seconds + 3.43 % in 2544 seconds + 3.45 % in 2554 seconds + 3.46 % in 2564 seconds + 3.48 % in 2574 seconds + 3.51 % in 2584 seconds + 3.53 % in 2594 seconds + 3.56 % in 2604 seconds + 3.57 % in 2615 seconds + 3.57 % in 2625 seconds + 3.58 % in 2635 seconds + 3.59 % in 2645 seconds + 3.60 % in 2655 seconds + 3.61 % in 2665 seconds + 3.62 % in 2675 seconds + 3.64 % in 2685 seconds + 3.65 % in 2695 seconds + 3.67 % in 2705 seconds + 3.70 % in 2715 seconds + 3.72 % in 2725 seconds + 3.74 % in 2735 seconds + 3.77 % in 2745 seconds + 3.78 % in 2755 seconds + 3.80 % in 2765 seconds + 3.81 % in 2777 seconds + 3.82 % in 2787 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seconds +72.22 % in 69 seconds +88.89 % in 79 seconds + 5.56 % in 5 seconds +11.11 % in 15 seconds +16.67 % in 25 seconds +22.22 % in 35 seconds +38.89 % in 46 seconds +55.56 % in 57 seconds +72.22 % in 70 seconds +88.89 % in 80 seconds + 5.56 % in 5 seconds +16.67 % in 25 seconds +27.78 % in 38 seconds +44.44 % in 49 seconds +61.11 % in 60 seconds +77.78 % in 72 seconds + 5.56 % in 4 seconds +16.67 % in 26 seconds +27.78 % in 39 seconds +44.44 % in 50 seconds +61.11 % in 61 seconds +77.78 % in 73 seconds + 5.56 % in 4 seconds +16.67 % in 24 seconds +22.22 % in 34 seconds +38.89 % in 45 seconds +55.56 % in 56 seconds +72.22 % in 69 seconds +88.89 % in 79 seconds + 5.56 % in 4 seconds +16.67 % in 24 seconds +22.22 % in 34 seconds +38.89 % in 45 seconds +55.56 % in 56 seconds +72.22 % in 68 seconds +88.89 % in 78 seconds + 5.56 % in 4 seconds +16.67 % in 25 seconds +27.78 % in 38 seconds +44.44 % in 49 seconds +61.11 % in 60 seconds +77.78 % in 72 seconds + 5.56 % in 5 seconds +16.67 % in 25 seconds +27.78 % in 35 seconds +38.89 % in 46 seconds +55.56 % in 56 seconds +72.22 % in 69 seconds +88.89 % in 79 seconds + 5.56 % in 5 seconds +16.67 % in 25 seconds +22.22 % in 35 seconds +38.89 % in 46 seconds +55.56 % in 57 seconds +72.22 % in 69 seconds +88.89 % in 80 seconds + 5.56 % in 5 seconds +16.67 % in 25 seconds +22.22 % in 35 seconds +38.89 % in 46 seconds +55.56 % in 56 seconds +72.22 % in 69 seconds +88.89 % in 79 seconds + 5.56 % in 5 seconds +16.67 % in 26 seconds +22.22 % in 36 seconds +38.89 % in 47 seconds +55.56 % in 58 seconds +72.22 % in 70 seconds +88.89 % in 80 seconds + 0.00 % in 22 seconds + 0.00 % in 35 seconds + 0.00 % in 48 seconds + 0.00 % in 58 seconds + 0.00 % in 68 seconds + 0.00 % in 80 seconds + 0.00 % in 94 seconds + 0.00 % in 113 seconds + 0.00 % in 125 seconds + 0.00 % in 137 seconds + 0.00 % in 148 seconds + 0.01 % in 161 seconds + 0.01 % in 172 seconds + 0.01 % in 182 seconds + 0.01 % in 203 seconds + 0.01 % in 225 seconds + 0.01 % in 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seconds + 4.09 % in 15698 seconds + 4.09 % in 15708 seconds + 4.10 % in 15718 seconds + 4.10 % in 15728 seconds + 4.11 % in 15738 seconds + 4.12 % in 15748 seconds + 4.12 % in 15759 seconds + 4.13 % in 15769 seconds + 4.13 % in 15779 seconds + 4.14 % in 15789 seconds + 4.15 % in 15799 seconds + 4.16 % in 15809 seconds + 4.16 % in 15819 seconds + 4.17 % in 15830 seconds + 4.17 % in 15840 seconds + 4.17 % in 15850 seconds diff --git a/furan/cc-pvdz/CC/fura-gs-cc3.out b/furan/cc-pvdz/CC/fura-gs-cc3.out new file mode 100644 index 0000000..e0daf0c --- /dev/null +++ b/furan/cc-pvdz/CC/fura-gs-cc3.out @@ -0,0 +1,985 @@ + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xjoda + + + ************************************************************************* + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + ************************************************************************* + + **************************************************************** + * CFOUR Coupled-Cluster techniques for Computational Chemistry * + **************************************************************** + + + Department of Chemistry Institut fuer Physikalische Chemie + University of Florida Universitaet Mainz + Gainesville, FL 32611, USA D-55099 Mainz, Germany + + Department of Chemistry Fakultaet fuer Chemie und Biowiss. + Johns Hopkins University Karlsruher Institut fuer Technologie + Baltimore, MD 21218, USA D-76131 Karlsruhe, Germany + + Department of Chemistry Department of Physical Chemistry + Southern Methodist University Eotvos Lorand University + Dallas, TX 75275, USA H-1053 Budapest, Hungary + + + Version 2.1 + + nazare075.cluster + Thu Oct 15 11:17:22 CEST 2020 + integer*8 version is running + +******************************************************************************** +* Input from ZMAT file * +******************************************************************************** +Ketene -GS +C 0.00000000 2.06365826 -0.60051250 +C 0.00000000 -2.06365826 -0.60051250 +C 0.00000000 1.35348578 1.86336416 +C 0.00000000 -1.35348578 1.86336416 +O 0.00000000 0.00000000 -2.13945332 +H 0.00000000 3.86337287 -1.53765695 +H 0.00000000 -3.86337287 -1.53765695 +H 0.00000000 2.59168789 3.47168051 +H 0.00000000 -2.59168789 3.47168051 + +*CFOUR(COORD=CARTESIAN,UNITS=BOHR + MEMORY=100,MEM_UNIT=GB,CC_PROG=NCC + FROZEN_CORE=1 + CALC=CC3,BASIS=PVDZ + SCF_CONV=9,CC_CONV=7,ESTATE_MAXCYC=80) + +******************************************************************************** + ------------------------------------------------------------------- + CFOUR Control Parameters + ------------------------------------------------------------------- + External Internal Value Units + Name Name + ------------------------------------------------------------------- + ABCDTYPE IABCDT STANDARD [ 0] *** + ANHARMONIC IANHAR OFF [ 0] *** + ANH_ALGORIT IANALG STANDARD [ 0] *** + ANH_DERIVAT IANDER SECOND [ 1] *** + ANH_MODE ANHMOD VIBRATION [ 0] *** + ANH_STEPSIZ ICUBST 50000 x 10-6 + ANH_SYMMETR IANHSM ABELIAN [ 0] *** + AO_LADDERS IAOLAD SINGLEPASS [ 1] *** + AV_SCF IAVSCF OFF [ 0] *** + BASIS IBASIS PVDZ [ 13] *** + BOTHVECTORS BOTHVC OFF [ 0] *** + BOX_POTENT IPIAB OFF [ 0] *** + BREIT IBREIT OFF [ 0] *** + BRUCK_CONV IBRTOL 10D- 4 *** + BRUECKNER IBRKNR OFF [ 0] *** + BUFFERSIZE IBUFFS 4096 *** + CACHE_RECS ICHREC 10 *** + CALCLEVEL ICLLVL CC3 [ 32] *** + CCORBOPT ICCORB OFF [ 0] x 0.01 + CC_CONV ICCCNV 10D- 7 *** + CC_EXPORDER ICCEOR 5 *** + CC_EXTRAPOL ICCEXT DIIS [ 1] *** + CC_GUESS ICCGES MP2 [ 0] *** + CC_MAXCYC ICCCYC 100 cycles + CC_PROGRAM ICCPRO NCC [ 5] *** + CHARGE ICHRGE 0 *** + CHOLESKY ICHOLE OFF [ 0] *** + CIS_CONV ICISTL 5 *** + COMM_SIZE IPSIZE *** *** + CONSTANT ICONST OLD [ 1] *** + CONTINUUM ICONTU NONE [ 0] *** + CONTRACTION ICNTYP GENERAL [ 1] *** + COORDINATES ICOORD CARTESIAN [ 1] *** + CPHF_CONVER ICPHFT 10D- 16 *** + CPHF_MAXCYC ICPHFC 64 cycles + CUBIC ICUBIC OFF [ 0] *** + CURVILINEAR ICURVY OFF [ 0] *** + DBOC IDBOC OFF [ 0] *** + DCT IDCT OFF [ 0] *** + DERIV_LEV IDRLVL ZERO [ 0] *** + DEVMEM_SIZE IDVMEM ********* MByte + DIAG_MRCC IEOMST 10D- 0 *** + DIFF_TYPE IDIFTY RELAXED [ 0] *** + DIRECT IDIRCT OFF [ 0] *** + DROPMO IDRPMO NONE + ECP IECP OFF [ 0] *** + EIGENVECTOR IVEC 1 *** + EL_ANHARM IELANH OFF [ 0] *** + EOMFOLLOW IEOMSR ENERGY [ 0] *** + EOMIP IEOMIP OFF [ 0] *** + EOMLEVEL HBARFM SAME [ 0] *** + EOM_MRCC IMRCCE NEW [ 1] *** + EOM_NONIT EOMNON OFF [ 0] *** + EOM_NSING IEOMSI 10D- 0 *** + EOM_NSTATES IMRCCD DAVIDSON [ 0] *** + EOM_NTRIP IEOMTR 10D- 0 *** + EOM_ORDER IEXORD ENERGY [ 0] *** + EOM_PROPSTA IEOMST 0 *** + ESTATE_CONV IEXTOL 10D- 5 *** + ESTATE_DIAG IEXDIG ITERATIVE [ 0] *** + ESTATE_LOCK IESLOC ON [ 1] *** + ESTATE_MAXC IEXMXC 80 *** + ESTATE_PROP IEXPRP OFF [ 0] *** + EVAL_HESS IRECAL 0 # of cyc. + EXCITATION IEXCIT 0 *** + EXCITE IEXCIT NONE [ 0] *** + EXTERN_POT IEXPOT OFF [ 0] *** + FCGRADNEW IFCGNW OFF [ 0] *** + FC_FIELD IFINFC 0 x 10-6 + FD_CALTYPE IFDCAL GRADONLY [ 0] *** + FD_PROJECT IFDPRJ OFF [ 1] *** + FD_STEPSIZE IDISFD 0 10-4 bohr + FD_USEGROUP IFDGRP FULL [ 0] *** + FILE_RECSIZ IFLREC 4096 words + FINITE_PERT IFIPER 0 x 10-6 + FIXGEOM IFIXGM OFF [ 0] *** + FOCK IFOCK AO [ 1] *** + FREQ_ALGORI IVIALG STANDARD [ 0] *** + FROZEN_CORE IFROCO ON [ 1] *** + GAMMA_ABCD IGABCD STORE [ 0] *** + GAMMA_ABCI IGABCI STORE [ 0] *** + GENBAS_1 IGNBS1 0 *** + GENBAS_2 IGNBS2 0 *** + GENBAS_3 IGNBS3 0 *** + GENBAS_4 IGNBS4 0 *** + GEO_CONV ICONTL 5 H/bohr + GEO_MAXCYC IOPTCY 50 *** + GEO_MAXSTEP IMXSTP 300 millibohr + GEO_METHOD INR SINGLE_POINT[ 5] *** + GIAO IGIAO OFF [ 1] *** + GIMIC IGIMIC OFF [ 0] *** + GRID IGRID OFF [ 0] *** + GRID_ALGO IGALGO SERIAL [ 0] *** + GUESS IGUESS MOREAD [ 0] *** + HBAR IHBAR OFF [ 0] *** + HESS_TYPE IHESTP SCF [ 0] *** + HF2_FILE IHF2Fl USE [ 1] *** + HFSTABILITY ISTABL OFF [ 0] *** + INCORE INCORE OFF [ 0] *** + INPUT_MRCC IMRCC ON [ 1] *** + INTEGRALS INTTYP VMOL [ 1] *** + JODA_PRINT IJPRNT 0 *** + KEYWORD_OUT IDMPKW NO [ 0] *** + LINDEP_TOL ILINDP 8 *** + LINEQ_CONV IZTACN 10D- 7 cycles + LINEQ_EXPOR ILMAXD 5 *** + LINEQ_MAXCY ILMAXC 100 *** + LINEQ_TYPE ILTYPE DIIS [ 1] *** + LOCK_ORBOCC ILOCOC OFF [ 0] *** + MEMORY_SIZE IMEMSZ ********* words + MEM_UNIT IMEMU GB [ 3] *** + MRCC IMRCCC OFF [ 0] *** + MULTIPLICTY IMULTP 1 *** + NACOUPLING IVCOUP OFF [ 0] *** + NEGEVAL IDIE ABORT [ 0] *** + NEWNORM INEWNO OFF [ 0] *** + NON-HF INONHF OFF [ 0] *** + NTOP_TAMP ITOPT2 15 *** + NUC_MODEL INUCMO POINT [ 0] *** + OCCUPATION IOCCU ESTIMATED BY SCF + OPEN-SHELL IOPEN SPIN-ORBITAL[ 0] *** + OPTVIB IOPTVB OFF [ 0] *** + ORBITALS IORBTP STANDARD [ 0] *** + PARALLEL IPARAL ON [ 1] *** + PARA_INT IPINTS ON [ 1] *** + PARA_PRINT IPPRIN 0 *** + PERT_ORB IPTORB STANDARD [ 0] *** + POINTS IGRDFD 0 *** + PRINT IPRNT 0 *** + PROPS IPROPS OFF [ 0] *** + PROP_INTEGR IINTYP INTERNAL [ 0] *** + PSI IPSI OFF [ 0] *** + QC_ALG IQCALG FLM [ 0] *** + QC_LINALG IQCLIN TRIDIAG [ 2] *** + QC_MAXCYC IQCMAX 10D-100 cycles + QC_MAXSCFCY IQCMSC 10D- 15 cycles + QC_RTRUST IQCRTR 10D- 0 x 10-3 + QC_SKIPSCF IQCSKI OFF [ 0] *** + QC_START IQCSTA 10D- 1 *** + QRHFGUESS IQGUES OFF [ 0] *** + QUARTIC IQUART OFF [ 0] *** + RAMAN_INT IRAMIN OFF [ 0] *** + RAMAN_ORB IRAMRE UNRELAXED [ 0] *** + RDO IRDOFM OFF [ 0] *** + REDUCE_REPR REDREP Ir [ 0] *** + REFERENCE IREFNC RHF [ 0] *** + RELATIVIST IRELAT OFF [ 0] *** + RELAX_DENS IRDENS OFF [ 0] *** + RESET_FLAGS IRESET OFF [ 0] *** + RESTART_CC ICCRES OFF [ 0] *** + ROT_EVEC ROTVEC 0 *** + SAVE_INTS ISVINT OFF [ 0] *** + SCALE_ON ISTCRT 0 *** + SCF_CONV ISCFCV 10D- 9 *** + SCF_DAMPING IDAMP 0 x 10-3 + SCF_EXPORDE IRPPOR 6 *** + SCF_EXPSTAR IRPPLS 8 *** + SCF_EXTRAPO IRPP ON [ 1] *** + SCF_MAXCYC ISCFCY 150 cycles + SCF_NOSTOP ISCFST OFF [ 0] *** + SCF_PRINT ISCFPR 0 *** + SCF_PROG ISCFPR SCF [ 0] *** + SD_FIELD IFINSD 0 x 10-6 + SOPERT IPERSO OFF [ 0] *** + SPHERICAL IDFGHI ON [ 1] *** + SPINORBIT ISOCAL OFF [ 0] *** + SPINROTATIO ISRCON OFF [ 0] *** + SPIN_FLIP ISPFLP OFF [ 0] *** + SPIN_ORBIT ISPORB OFF [ 0] *** + SPIN_SCAL ISCSMP OFF [ 0] *** + STEEPSCALE ISTPSC 1000 x 10-3 + SUBGROUP ISUBGP DEFAULT [ 0] *** + SUBGRPAXIS ISBXYZ X [ 0] *** + SYMMETRY ISYM ON [ 0] *** + SYM_CHECK ISYMCK OVERRIDE [ 1] *** + T3_EXTRAPOL IT3EXT ON [ 1] *** + T4_EXTRAPOL IT4EXP OFF [ 0] *** + TAMP_SUM IEVERY 5 *** + TESTSUITE ITESTS OFF [ 0] *** + THERMOCH ITHERM OFF [ 0] *** + TOL_CHOLESK ITOLCH 10D- 4 *** + TRANGRAD IRESRM OFF [ 0] *** + TRANS_INV ITRAIN USE [ 0] *** + TREAT_PERT ITREAT SIMULTANEOUS[ 0] *** + TRIP_ALGORI ITRALG NORMAL [ 0] *** + UIJ_THRESHO IUIJTH 1 *** + UNITS IUNITS BOHR [ 1] *** + UNOS IUNOS OFF [ 0] *** + UPDATE_HESS IHUPDT ON [ 1] *** + VIBPHASE ISETPH STANDARD [ 0] *** + VIBRATION IVIB NO [ 0] *** + VIB_ALGORIT IGEALG STANDARD [ 0] *** + VNATORB IVNORB OFF [ 0] *** + VTRAN IVTRAN FULL/PARTIAL[ 0] *** + XFIELD IXEFLD 0 x 10-6 + XFORM_TOL IXFTOL 10D- 11 *** + YFIELD IYEFLD 0 x 10-6 + ZFIELD IZEFLD 0 x 10-6 + ZSCALE_EXP IZEXPS OFF [ 0] *** + ------------------------------------------------------------------- + @GETXYZ-I, 9 atoms read from ZMAT. + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 +******************************************************************************** + The full molecular point group is C2v . + The largest Abelian subgroup of the full molecular point group is C2v . + The computational point group is C2v . +******************************************************************************** + + + ---------------------------------------------------------------- + Coordinates used in calculation (QCOMP) + ---------------------------------------------------------------- + Z-matrix Atomic Coordinates (in bohr) + Symbol Number X Y Z + ---------------------------------------------------------------- + C 6 0.00000000 -2.06365826 0.60031230 + C 6 0.00000000 2.06365826 0.60031230 + C 6 0.00000000 -1.35348578 -1.86356436 + C 6 0.00000000 1.35348578 -1.86356436 + O 8 0.00000000 0.00000000 2.13925312 + H 1 0.00000000 -3.86337287 1.53745675 + H 1 0.00000000 3.86337287 1.53745675 + H 1 0.00000000 -2.59168789 -3.47188071 + H 1 0.00000000 2.59168789 -3.47188071 + ---------------------------------------------------------------- + + Interatomic distance matrix (Angstroms) + + C C C C O + [ 1] [ 2] [ 3] [ 4] [ 5] + C [ 1] 0.00000 + C [ 2] 2.18408 0.00000 + C [ 3] 1.35691 2.22931 0.00000 + C [ 4] 2.22931 1.35691 1.43247 0.00000 + O [ 5] 1.36226 1.36226 2.23601 2.23601 0.00000 + H [ 6] 1.07375 3.17541 2.23677 3.29549 2.06906 + H [ 7] 3.17541 1.07375 3.29549 2.23677 2.06906 + H [ 8] 2.17295 3.27299 1.07409 2.25451 3.27071 + H [ 9] 3.27299 2.17295 2.25451 1.07409 3.27071 + + H H H H + [ 6] [ 7] [ 8] [ 9] + H [ 6] 0.00000 + H [ 7] 4.08882 0.00000 + H [ 8] 2.73491 4.32378 0.00000 + H [ 9] 4.32378 2.73491 2.74292 0.00000 + rotcon2 + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 + There are 5 frozen-core orbitals. + There are 90 basis functions. + @GEOPT-W, Archive file not created for single-point calculation. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.12/ 1.28 seconds. +--executable xjoda finished with status 0 in 1.76 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol + SERIAL VERSION OF MOLECULE STARTED +******************************************************************************** + INPUT FROM MOL FILE +******************************************************************************** +INTGRL 1 0 1 0 0 0 0 0 0 + *** CFOUR Program System (Release V0.1) *** +Ketene -GS + 5 2 X Y 0.10E-08 0 0 + 9999.00 3.00 + 6.00000000 1 3 1 1 1 +C #1 0.000000000000000 -2.063658260000000 0.600312302999175 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 6.00000000 1 3 1 1 1 +C #2 0.000000000000000 -1.353485780000000 -1.863564357000825 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 8.00000000 1 3 1 1 1 +O #3 0.000000000000000 0.000000000000000 2.139253122999175 + 9 3 + 11720.0000000000 7.100000000000000E-004 -1.600000000000000E-004 + 0.000000000000000E+000 + 1759.00000000000 5.470000000000000E-003 -1.263000000000000E-003 + 0.000000000000000E+000 + 400.800000000000 2.783700000000000E-002 -6.267000000000000E-003 + 0.000000000000000E+000 + 113.700000000000 0.104800000000000 -2.571600000000000E-002 + 0.000000000000000E+000 + 37.0300000000000 0.283062000000000 -7.092400000000000E-002 + 0.000000000000000E+000 + 13.2700000000000 0.448719000000000 -0.165411000000000 + 0.000000000000000E+000 + 5.02500000000000 0.270952000000000 -0.116955000000000 + 0.000000000000000E+000 + 1.01300000000000 1.545800000000000E-002 0.557368000000000 + 0.000000000000000E+000 + 0.302300000000000 -2.585000000000000E-003 0.572759000000000 + 1.00000000000000 + 4 2 + 17.7000000000000 4.301800000000000E-002 0.000000000000000E+000 + 3.85400000000000 0.228913000000000 0.000000000000000E+000 + 1.04600000000000 0.508728000000000 0.000000000000000E+000 + 0.275300000000000 0.460531000000000 1.00000000000000 + 1 1 + 1.18500000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #4 0.000000000000000 -3.863372870000000 1.537456752999175 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #5 0.000000000000000 -2.591687890000000 -3.471880707000825 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 +FINISH + +******************************************************************************** + ONE- AND TWO-ELECTRON INTEGRALS OVER SYMMETRY-ADAPTED AOS ARE CALCULATED. + + SPHERICAL HARMONICS ARE USED. + + INTEGRALS LESS THAN 0.10E-13 ARE NEGLECTED. + + NUCLEAR REPULSION ENERGY : 161.1082297788 A.U. + @MOLECU-I, ONE ELECTRON INTEGRALS (CPU/WALL): 0.02/ 0.03 SECONDS. + @TWOEL-I, 325108 INTEGRALS OF SYMMETRY TYPE I I I I + @TWOEL-I, 908743 INTEGRALS OF SYMMETRY TYPE I J I J + @TWOEL-I, 490042 INTEGRALS OF SYMMETRY TYPE I I J J + @TWOEL-I, 460725 INTEGRALS OF SYMMETRY TYPE I J K L + @TWOEL-I, TOTAL NUMBER OF 2-E INTEGRALS 2184618. + @MOLECU-I, TWO ELECTRON INTEGRALS (CPU/WALL): 1.44/ 1.44 SECONDS. + @CHECKOUT-I, Total execution time (CPU/WALL): 1.47/ 1.49 seconds. + +Running with 20 threads/proc + +--executable xvmol finished with status 0 in 1.98 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol2ja + @GETMEM-I, Allocated 95367 MB of main memory. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.06/ 0.02 seconds. +--executable xvmol2ja finished with status 0 in 0.50 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvscf + There are 90 functions in the AO basis. + + There are 4 irreducible representations. + + Irrep # of functions + 1 35 + 2 13 + 3 31 + 4 11 + + + Parameters for SCF calculation: + SCF reference function: RHF + Maximum number of iterations: 150 + Full symmetry point group: C2v + Computational point group: C2v + Initial density matrix: MOREAD + SCF convergence tolerance: 10**(- 9) + DIIS convergence acceleration: ON + Latest start for DIIS: 8 + DIIS order: 6 + + Memory information: 341888 words required. + Fock matrices are constructed from AO integral file. + @GETMEM-I, Allocated 2 MB of main memory. + Initialization and symmetry analysis required 0.001 seconds. + + @INITGES-I, Occupancies from core Hamiltonian: + + Alpha population by irrep: 9 2 6 1 + Beta population by irrep: 9 2 6 1 + + + total no. of electrons in initial guess : 0.000000000000000E+000 + -------------------------------------------------------------------- + Iteration Total Energy Largest Density Difference + -------------------------------------------------------------------- + 0 161.108229778788910 0.0000000000D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 1 -196.263249175407992 0.1098182460D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 2 -179.889864626336106 0.1675780025D+02 + current occupation vector + 9 1 7 1 + 9 1 7 1 + 3 -180.580457259652945 0.1772125138D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 4 -162.771013663095033 0.1566999730D+02 + current occupation vector + 8 2 7 1 + 8 2 7 1 + 5 -169.943224465301597 0.1454729382D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 6 -160.269967975315780 0.1454634919D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 7 -168.828658617537684 0.1395077743D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 8 -160.232275948463297 0.1395068492D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 9 -209.746508446745025 0.5520995458D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 10 -228.180230304181549 0.2015536648D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 11 -228.454713327495682 0.6531384936D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 12 -228.600329261507483 0.3196758217D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 13 -228.637509917234041 0.7498321731D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 14 -228.642938164599826 0.5250342791D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 15 -228.643241982659248 0.9795506231D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 16 -228.643308522550143 0.3593200395D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 17 -228.643312517846056 0.1473098013D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 18 -228.643312570337258 0.1244041229D-03 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 19 -228.643312572356052 0.2423484470D-04 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 20 -228.643312572476049 0.5414751593D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 21 -228.643312572485769 0.2003507219D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 22 -228.643312572485598 0.8833300562D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 23 -228.643312572484461 0.3139636784D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 24 -228.643312572486110 0.4136764657D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 25 -228.643312572485542 0.9839839787D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 26 -228.643312572486622 0.1838835018D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 27 -228.643312572484007 0.3228508794D-08 + current occupation vector + 9 2 6 1 + 9 2 6 1 + + SCF has converged. + + Density matrix saved to file den.dat + total electron number: 36.0000000000000 + E(SCF)= -228.643312572484575 0.7981584282D-09 + + Eigenvector printing suppressed. + + @PUTMOS-I, Writing converged MOs to NEWMOS. + @PUTMOS-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTMOS-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTMOS-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTMOS-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + @PUTFOCK-I, Writing converged Fock matrix to NEWFOCK. + @PUTFOCK-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTFOCK-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + + + + ORBITAL EIGENVALUES (ALPHA) (1H = 27.2113834 eV) + + MO # E(hartree) E(eV) FULLSYM COMPSYM + ---- -------------------- -------------------- ------- --------- + 1 1 -20.6219765861 -561.1525113512 A1 A1 (1) + 2 49 -11.2892088103 -307.1949892207 B2 B2 (3) + 3 2 -11.2891634657 -307.1937553315 A1 A1 (1) + 4 3 -11.2328159068 -305.6604603025 A1 A1 (1) + 5 50 -11.2318729764 -305.6348018622 B2 B2 (3) + 6 4 -1.4574476329 -39.6591663239 A1 A1 (1) + 7 5 -1.0834872588 -29.4831872086 A1 A1 (1) + 8 51 -1.0036038078 -27.3094479952 B2 B2 (3) + 9 52 -0.8050606676 -21.9068144851 B2 B2 (3) + 10 6 -0.7793049296 -21.2059652251 A1 A1 (1) + 11 7 -0.7372159421 -20.0606656495 A1 A1 (1) + 12 36 -0.6283416633 -17.0980459063 B1 B1 (2) + 13 53 -0.6064452640 -16.5022145907 B2 B2 (3) + 14 54 -0.5741889664 -15.6244761082 B2 B2 (3) + 15 8 -0.5622006055 -15.2982562239 A1 A1 (1) + 16 9 -0.5366322238 -14.6025051862 A1 A1 (1) + 17 37 -0.3944127682 -10.7325170532 B1 B1 (2) + 18 80 -0.3173264428 -8.6348914980 A2 A2 (4) + +++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ + 19 38 0.1616454919 4.3985974562 B1 B1 (2) + 20 10 0.2028007990 5.5184902966 A1 A1 (1) + 21 55 0.2259953076 6.1496449623 B2 B2 (3) + 22 11 0.2331452351 6.3442043789 A1 A1 (1) + 23 81 0.2346526075 6.3852220682 A2 A2 (4) + 24 56 0.2409072580 6.5554197617 B2 B2 (3) + 25 12 0.3379830583 9.1969865830 A1 A1 (1) + 26 57 0.3670668300 9.9883962435 B2 B2 (3) + 27 13 0.4400792390 11.9751648999 A1 A1 (1) + 28 58 0.5035354267 13.7018955503 B2 B2 (3) + 29 14 0.5796551077 15.7732173745 A1 A1 (1) + 30 59 0.6027649445 16.4020680057 B2 B2 (3) + 31 39 0.6720867908 18.2884113425 B1 B1 (2) + 32 15 0.6949257331 18.9098905590 A1 A1 (1) + 33 60 0.7033703399 19.1396799905 B2 B2 (3) + 34 82 0.7176012567 19.5269229246 A2 A2 (4) + 35 61 0.7543801794 20.5277282917 B2 B2 (3) + 36 40 0.7622869649 20.7428828633 B1 B1 (2) + 37 16 0.7651070466 20.8196211868 A1 A1 (1) + 38 17 0.7917408050 21.5443625978 A1 A1 (1) + 39 83 0.8438632537 22.9626865338 A2 A2 (4) + 40 62 0.8844205187 24.0663058221 B2 B2 (3) + 41 18 0.9187910190 25.0015746820 A1 A1 (1) + 42 19 0.9547555380 25.9802189979 A1 A1 (1) + 43 63 0.9634112815 26.2157537519 B2 B2 (3) + 44 64 1.0592164869 28.8227459274 B2 B2 (3) + 45 41 1.0743328454 29.2340829566 B1 B1 (2) + 46 20 1.1352329173 30.8912581602 A1 A1 (1) + 47 65 1.1904894416 32.3948646279 B2 B2 (3) + 48 21 1.1908922750 32.4058262839 A1 A1 (1) + 49 42 1.2129419174 33.0058275576 B1 B1 (2) + 50 66 1.2581407748 34.2357509943 B2 B2 (3) + 51 84 1.2921641151 35.1615731515 A2 A2 (4) + 52 22 1.2994001068 35.3584744953 A1 A1 (1) + 53 43 1.3116428673 35.6916169462 B1 B1 (2) + 54 85 1.3649569984 37.1423682072 A2 A2 (4) + 55 44 1.5283489789 41.5884900335 B1 B1 (2) + 56 23 1.5439841774 42.0139454134 A1 A1 (1) + 57 67 1.5691624192 42.6990802047 B2 B2 (3) + 58 68 1.5969806595 43.4560530082 B2 B2 (3) + 59 24 1.7377154792 47.2856421455 A1 A1 (1) + 60 69 1.7438095776 47.4514709939 B2 B2 (3) + 61 86 1.7443895833 47.4672537511 A2 A2 (4) + 62 25 1.7729617500 48.2447419337 A1 A1 (1) + 63 45 1.8384391578 50.0264727818 B1 B1 (2) + 64 26 1.8727560698 50.9602834298 A1 A1 (1) + 65 46 1.9574193824 53.2640892885 B1 B1 (2) + 66 70 1.9863618073 54.0516527104 B2 B2 (3) + 67 71 2.0036624844 54.5224280672 B2 B2 (3) + 68 87 2.0489211710 55.7539795407 A2 A2 (4) + 69 27 2.0703324397 56.3366097828 A1 A1 (1) + 70 88 2.1357719213 58.1173086059 A2 A2 (4) + 71 28 2.1641427105 58.8893170284 A1 A1 (1) + 72 72 2.1880643996 59.5402592802 B2 B2 (3) + 73 47 2.1914898441 59.6334703659 B1 B1 (2) + 74 29 2.2271655184 60.6042548161 A1 A1 (1) + 75 73 2.2977715809 62.5255434529 B2 B2 (3) + 76 30 2.3793504210 64.7454165492 A1 A1 (1) + 77 89 2.5107047412 68.3197493175 A2 A2 (4) + 78 74 2.5407172731 69.1364318293 B2 B2 (3) + 79 75 2.6586433664 72.3453639681 B2 B2 (3) + 80 31 2.6718877167 72.7057610618 A1 A1 (1) + 81 32 2.8267951805 76.9210074510 A1 A1 (1) + 82 76 2.9419209269 80.0537382753 B2 B2 (3) + 83 77 2.9853767071 81.2362301695 B2 B2 (3) + 84 33 3.0013526923 81.6709588287 A1 A1 (1) + 85 48 3.2421725037 88.2239990462 B1 B1 (2) + 86 90 3.2857682253 89.4102989431 A2 A2 (4) + 87 34 3.4838249547 94.7996965407 A1 A1 (1) + 88 78 3.6959298762 100.5713648809 B2 B2 (3) + 89 79 3.7700022467 102.5869765541 B2 B2 (3) + 90 35 3.8341979240 104.3338297409 A1 A1 (1) + + + VSCF finished. + + @CHECKOUT-I, Total execution time (CPU/WALL): 4.37/ 0.93 seconds. +--executable xvscf finished with status 0 in 1.40 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvtran + @GETMEM-I, Allocated 95367 MB of main memory. + Full RHF integral transformation + The following 5 MOs will be dropped: + 1 2 3 12 13 + There are 85 active molecular orbitals. + Transformation of IIII integrals : + 1 pass through the AO integral file was required. + 325108 AO integrals were read. + 240883 MO integrals were written to HF2. + Transformation of IIJJ integrals : + 1 pass through the AO integral file was required. + 490042 AO integrals were read. + 386877 MO integrals were written to HF2. + Transformation of IJIJ integrals : + 1 pass through the AO integral file was required. + 908743 AO integrals were read. + 712509 MO integrals were written to HF2. + Transformation of IJKL integrals : + 1 pass through the AO integral file was required. + 460725 AO integrals were read. + 398112 MO integrals were written to HF2. + Summary of active molecular orbitals: +------------------------------------------------------------------------ + + Index Eigenvalue Symmetry Index Eigenvalue Symmetry +------------------------------------------------------------------------ + 1 -1.4574476 1 44 1.2129419 2 + 2 -1.0834873 1 45 1.3116429 2 + 3 -0.7793049 1 46 1.5283490 2 + 4 -0.7372159 1 47 1.8384392 2 + 5 -0.5622006 1 48 1.9574194 2 + 6 -0.5366322 1 49 2.1914898 2 + 7 -0.6283417 2 50 3.2421725 2 + 8 -0.3944128 2 51 0.2259953 3 + 9 -1.0036038 3 52 0.2409073 3 + 10 -0.8050607 3 53 0.3670668 3 + 11 -0.6064453 3 54 0.5035354 3 + 12 -0.5741890 3 55 0.6027649 3 + 13 -0.3173264 4 56 0.7033703 3 + 14 0.2028008 1 57 0.7543802 3 + 15 0.2331452 1 58 0.8844205 3 + 16 0.3379831 1 59 0.9634113 3 + 17 0.4400792 1 60 1.0592165 3 + 18 0.5796551 1 61 1.1904894 3 + 19 0.6949257 1 62 1.2581408 3 + 20 0.7651070 1 63 1.5691624 3 + 21 0.7917408 1 64 1.5969807 3 + 22 0.9187910 1 65 1.7438096 3 + 23 0.9547555 1 66 1.9863618 3 + 24 1.1352329 1 67 2.0036625 3 + 25 1.1908923 1 68 2.1880644 3 + 26 1.2994001 1 69 2.2977716 3 + 27 1.5439842 1 70 2.5407173 3 + 28 1.7377155 1 71 2.6586434 3 + 29 1.7729618 1 72 2.9419209 3 + 30 1.8727561 1 73 2.9853767 3 + 31 2.0703324 1 74 3.6959299 3 + 32 2.1641427 1 75 3.7700022 3 + 33 2.2271655 1 76 0.2346526 4 + 34 2.3793504 1 77 0.7176013 4 + 35 2.6718877 1 78 0.8438633 4 + 36 2.8267952 1 79 1.2921641 4 + 37 3.0013527 1 80 1.3649570 4 + 38 3.4838250 1 81 1.7443896 4 + 39 3.8341979 1 82 2.0489212 4 + 40 0.1616455 2 83 2.1357719 4 + 41 0.6720868 2 84 2.5107047 4 + 42 0.7622870 2 85 3.2857682 4 + 43 1.0743328 2 +------------------------------------------------------------------------ + -1.45744763288719 -1.08348725881441 -0.779304929609897 + -0.737215942115339 -0.562200605497301 -0.536632223783724 + -0.628341663300699 -0.394412768193209 -1.00360380778026 + -0.805060667553655 -0.606445264032669 -0.574188966380078 + -0.317326442801090 0.202800799044599 0.233145235052782 + 0.337983058334004 0.440079239041159 0.579655107669000 + 0.694925733138531 0.765107046589679 0.791740804983910 + 0.918791018982032 0.954755538003189 1.13523291727329 + 1.19089227502871 1.29940010677049 1.54398417735024 + 1.73771547923282 1.77296175003401 1.87275606979175 + 2.07033243972521 2.16414271052282 2.22716551838589 + 2.37935042101669 2.67188771673553 2.82679518054224 + 3.00135269229820 3.48382495469438 3.83419792398046 + 0.161645491943529 0.672086790797680 0.762286964920328 + 1.07433284544462 1.21294191744913 1.31164286730943 + 1.52834897888630 1.83843915784915 1.95741938237798 + 2.19148984413109 3.24217250366571 0.225995307622873 + 0.240907258015995 0.367066829963131 0.503535426659975 + 0.602764944529835 0.703370339875812 0.754380179426906 + 0.884420518732559 0.963411281466499 1.05921648685572 + 1.19048944155892 1.25814077480321 1.56916241916196 + 1.59698065950503 1.74380957764511 1.98636180732934 + 2.00366248439902 2.18806439955680 2.29777158087759 + 2.54071727310046 2.65864336644143 2.94192092693438 + 2.98537670707142 3.69592987620463 3.77000224671010 + 0.234652607487977 0.717601256707210 0.843863253708071 + 1.29216411509331 1.36495699837027 1.74438958333340 + 2.04892117101004 2.13577192131677 2.51070474122043 + 3.28576822533544 + @CHECKOUT-I, Total execution time (CPU/WALL): 6.89/ 0.47 seconds. +--executable xvtran finished with status 0 in 0.93 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xintprc + @GETMEM-I, Allocated 95367 MB of main memory. + @GMOIAA-I, Processing MO integrals for spin case AA. + @GMOIAA-I, Generation of integral list completed. + TYPE NUMBER + ---- -------- + PPPP 894479 + PPPH 640524 + PPHH 115497 + PHPH 63721 + PHHH 22938 + HHHH 1222 + + TOTAL 1738381 + + @FORMT2-I, Second-order MP correlation energies: + ------------------------------------------------ + E(SCF) = -228.643312572485 a.u. + E2(AA) = -0.093684343380 a.u. + E2(AB) = -0.520081687065 a.u. + E2(TOT) = -0.707450373824 a.u. + Total MP2 energy = -229.350762946309 a.u. + ------------------------------------------------ + Largest T2 amplitudes for spin case AB: + _ _ _ _ _ _ + i j a b i j a b i j a b +----------------------------------------------------------------------------- +[ 13 13 40 40]-0.06710 [ 8 8 40 40]-0.05436 [ 13 13 76 76]-0.05241 +[ 13 8 76 40]-0.04215 [ 8 13 40 76]-0.04215 [ 8 8 76 76]-0.03737 +[ 7 7 40 40]-0.03140 [ 13 7 40 76]-0.02053 [ 7 13 76 40]-0.02053 +[ 13 13 77 77]-0.01960 [ 13 13 40 42]-0.01810 [ 13 13 42 40]-0.01810 +[ 7 7 45 45]-0.01664 [ 13 13 41 41]-0.01633 [ 13 13 78 76]-0.01595 +----------------------------------------------------------------------------- + Norm of T2AB vector ( 230058 symmetry allowed elements): 0.4218925855. +----------------------------------------------------------------------------- + @CHECKOUT-I, Total execution time (CPU/WALL): 4.49/ 0.35 seconds. +--executable xintprc finished with status 0 in 0.82 seconds (walltime). + calling xncc + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xncc + @GETMEM-I, Allocated 7 MB of main memory. + +Running with 20 threads/proc + +Using DIIS to accelerate the convergence of T1 and T2 +Using immediate high-order contributions +Performing 3 CCSD sub-iterations +Damping factor for T3: 0.000000 +Damping factor for T4: 0.000000 + +Transposes are coarse-threaded + +Memory limit: 93.132 GiB +Minimum memory requirement: 19.231 MiB +Compromise memory amount: 55.151 MiB +Optimal memory requirement: 437.270 MiB + +List Location Size Cached Hunks Est. Disk I/O +----------------- ---------- ----------- ------ ----- ------------- + + T_DIIS 70:0 8.787 MiB Yes - 158.166 MiB + Z_DIIS 70:1 8.787 MiB Yes - 263.610 MiB + 18 1.755 MiB Yes - 274.921 MiB + 233 52.803 MiB Yes - 3.867 GiB + 30 9.615 MiB Yes - 4.648 GiB + 16 1.755 MiB Yes - 1.109 GiB + 25 1.755 MiB Yes - 236.952 MiB + 21 1.755 MiB No - 0 B + 10 329.156 KiB Yes - 236.260 MiB + 13 60.633 KiB Yes - 4.441 MiB + F(EA) 92:0 11.891 KiB Yes - 4.180 MiB + F(EM) 93:0 2.250 KiB Yes - 641.250 KiB + F(MI) 91:0 456 B Yes - 187.031 KiB + Q(AI) 190:2 2.250 KiB Yes - 371.250 KiB + Q(Ab,Ij) 50 1.755 MiB Yes - 974.138 MiB + T(AI) 90:0 2.250 KiB Yes - 2.375 MiB + T(Ab,Ij) 46 1.755 MiB Yes - 1.623 GiB + W(Mn,Ij) 53 60.633 KiB Yes - 7.105 MiB + W~(Ab,Ej) 130 9.615 MiB Yes - 4.731 GiB + W~(EM,bj) 56 1.755 MiB Yes - 526.561 MiB + W~(Em,Bj) 58 1.755 MiB Yes - 526.561 MiB + W~(Ij,Mb) 110 329.156 KiB Yes - 106.076 MiB + W~~(Ab,Ej) 169 9.615 MiB No - 0 B + W~~(EM,bj) 76 1.755 MiB Yes - 105.312 MiB + W~~(Em,Bj) 78 1.755 MiB Yes - 105.312 MiB + W~~(Ij,Mb) 165 329.156 KiB No - 0 B + Z(AI) 90:2 2.250 KiB Yes - 1.022 MiB + Z(Ab,Ij) 63 1.755 MiB Yes - 816.170 MiB + T(abc,ijk) - 319.713 MiB No 1 0 B + Z(abc,ijk) - 319.713 MiB No 1 0 B + +Simulation and memory analysis took 0.218 seconds + +MP2 correlation energy: -0.707450373824291 + +Non-iterative calculation of MP2 took 0.297 cpu seconds and 0.017 walltime seconds at 0.749 Gflops/sec + +Total MP2 energy: -229.350762946308862 + +Beginning iterative solution of CC3 equations: + +It. Correlation Energy T1 Residual T2 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------- + 1 -0.764614021207282 5.85438e-03 1.35155e-02 36.566 1.844 + 2 -0.765656065903802 1.47321e-03 2.82614e-03 33.172 1.662 + 3 -0.765739967778334 3.65464e-04 6.09720e-04 32.510 1.629 + 4 -0.765735001866212 9.77413e-05 1.29558e-04 32.852 1.645 + 5 -0.765730995032383 2.29869e-05 2.68772e-05 32.871 1.646 + + A I A I A I +-------------------------- -------------------------- -------------------------- + 19 17 -0.0296954266991 31 17 0.0114114231087 25 15 0.0075106982204 + 19 12 0.0284808798547 36 17 -0.0108678874992 21 14 -0.0074596432522 + 34 18 0.0224725250737 25 16 -0.0102794471483 45 17 0.0074433819912 + 23 18 0.0176490672721 27 16 -0.0094125348255 26 13 0.0069096616154 + 51 18 0.0134527465790 53 17 0.0077124218397 49 17 0.0065786944159 + + A B I J A B I J +------------------------------------ ------------------------------------ + 19 19 18 18 -0.1045675283017 23 19 12 18 -0.0298037366898 + 23 23 18 18 -0.0616675121997 19 36 18 18 -0.0267815174391 + 19 19 17 17 -0.0598637352962 36 19 18 18 -0.0267815174391 + 23 19 18 17 -0.0592798131708 19 23 12 18 -0.0218110842890 + 19 23 17 18 -0.0592798131708 23 19 18 12 -0.0218110842890 + 23 23 17 17 -0.0585654670093 39 23 17 17 -0.0204007938238 + 19 19 12 12 -0.0377911957482 23 39 17 17 -0.0204007938238 + 19 23 18 12 -0.0298037366898 + +It. Correlation Energy T1 Residual T2 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------- + 6 -0.765730202116214 3.59012e-06 5.40250e-06 31.730 1.589 + 7 -0.765730083477215 6.51759e-07 1.13410e-06 32.999 1.653 + 8 -0.765730055650190 1.62428e-07 2.53819e-07 31.647 1.585 + 9 -0.765730048755297 3.70380e-08 5.75273e-08 32.029 1.605 + +CC3 iterations converged in 9 cycles and 14.862 seconds (1.651 s/it.) at 17.026 Gflops/sec + +Total CC3 energy: -229.409042621239877 + + @CHECKOUT-I, Total execution time (CPU/WALL): 298.95/ 15.26 seconds. +--executable xncc finished with status 0 in 15.83 seconds (walltime). + The final electronic energy is -229.409042621239877 a.u. + This computation required 23.80 seconds (walltime). diff --git a/furan/cc-pvdz/CC/fura-gs-cc4.out b/furan/cc-pvdz/CC/fura-gs-cc4.out new file mode 100644 index 0000000..495e58d --- /dev/null +++ b/furan/cc-pvdz/CC/fura-gs-cc4.out @@ -0,0 +1,1001 @@ + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xjoda + + + ************************************************************************* + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + ************************************************************************* + + **************************************************************** + * CFOUR Coupled-Cluster techniques for Computational Chemistry * + **************************************************************** + + + Department of Chemistry Institut fuer Physikalische Chemie + University of Florida Universitaet Mainz + Gainesville, FL 32611, USA D-55099 Mainz, Germany + + Department of Chemistry Fakultaet fuer Chemie und Biowiss. + Johns Hopkins University Karlsruher Institut fuer Technologie + Baltimore, MD 21218, USA D-76131 Karlsruhe, Germany + + Department of Chemistry Department of Physical Chemistry + Southern Methodist University Eotvos Lorand University + Dallas, TX 75275, USA H-1053 Budapest, Hungary + + + Version 2.1 + + cribbar020 + Thu Oct 15 19:11:56 CEST 2020 + integer*8 version is running + +******************************************************************************** +* Input from ZMAT file * +******************************************************************************** +Ketene -GS +C 0.00000000 2.06365826 -0.60051250 +C 0.00000000 -2.06365826 -0.60051250 +C 0.00000000 1.35348578 1.86336416 +C 0.00000000 -1.35348578 1.86336416 +O 0.00000000 0.00000000 -2.13945332 +H 0.00000000 3.86337287 -1.53765695 +H 0.00000000 -3.86337287 -1.53765695 +H 0.00000000 2.59168789 3.47168051 +H 0.00000000 -2.59168789 3.47168051 + +*CFOUR(COORD=CARTESIAN,UNITS=BOHR + MEMORY=180,MEM_UNIT=GB,CC_PROG=NCC + FROZEN_CORE=1 + CALC=CC4,BASIS=PVDZ + SCF_CONV=9,CC_CONV=7,ESTATE_MAXCYC=80) + +******************************************************************************** + ------------------------------------------------------------------- + CFOUR Control Parameters + ------------------------------------------------------------------- + External Internal Value Units + Name Name + ------------------------------------------------------------------- + ABCDTYPE IABCDT STANDARD [ 0] *** + ANHARMONIC IANHAR OFF [ 0] *** + ANH_ALGORIT IANALG STANDARD [ 0] *** + ANH_DERIVAT IANDER SECOND [ 1] *** + ANH_MODE ANHMOD VIBRATION [ 0] *** + ANH_STEPSIZ ICUBST 50000 x 10-6 + ANH_SYMMETR IANHSM ABELIAN [ 0] *** + AO_LADDERS IAOLAD SINGLEPASS [ 1] *** + AV_SCF IAVSCF OFF [ 0] *** + BASIS IBASIS PVDZ [ 13] *** + BOTHVECTORS BOTHVC OFF [ 0] *** + BOX_POTENT IPIAB OFF [ 0] *** + BREIT IBREIT OFF [ 0] *** + BRUCK_CONV IBRTOL 10D- 4 *** + BRUECKNER IBRKNR OFF [ 0] *** + BUFFERSIZE IBUFFS 4096 *** + CACHE_RECS ICHREC 10 *** + CALCLEVEL ICLLVL CC4 [ 52] *** + CCORBOPT ICCORB OFF [ 0] x 0.01 + CC_CONV ICCCNV 10D- 7 *** + CC_EXPORDER ICCEOR 5 *** + CC_EXTRAPOL ICCEXT DIIS [ 1] *** + CC_GUESS ICCGES MP2 [ 0] *** + CC_MAXCYC ICCCYC 100 cycles + CC_PROGRAM ICCPRO NCC [ 5] *** + CHARGE ICHRGE 0 *** + CHOLESKY ICHOLE OFF [ 0] *** + CIS_CONV ICISTL 5 *** + COMM_SIZE IPSIZE *** *** + CONSTANT ICONST OLD [ 1] *** + CONTINUUM ICONTU NONE [ 0] *** + CONTRACTION ICNTYP GENERAL [ 1] *** + COORDINATES ICOORD CARTESIAN [ 1] *** + CPHF_CONVER ICPHFT 10D- 16 *** + CPHF_MAXCYC ICPHFC 64 cycles + CUBIC ICUBIC OFF [ 0] *** + CURVILINEAR ICURVY OFF [ 0] *** + DBOC IDBOC OFF [ 0] *** + DCT IDCT OFF [ 0] *** + DERIV_LEV IDRLVL ZERO [ 0] *** + DEVMEM_SIZE IDVMEM ********* MByte + DIAG_MRCC IEOMST 10D- 0 *** + DIFF_TYPE IDIFTY RELAXED [ 0] *** + DIRECT IDIRCT OFF [ 0] *** + DROPMO IDRPMO NONE + ECP IECP OFF [ 0] *** + EIGENVECTOR IVEC 1 *** + EL_ANHARM IELANH OFF [ 0] *** + EOMFOLLOW IEOMSR ENERGY [ 0] *** + EOMIP IEOMIP OFF [ 0] *** + EOMLEVEL HBARFM SAME [ 0] *** + EOM_MRCC IMRCCE NEW [ 1] *** + EOM_NONIT EOMNON OFF [ 0] *** + EOM_NSING IEOMSI 10D- 0 *** + EOM_NSTATES IMRCCD DAVIDSON [ 0] *** + EOM_NTRIP IEOMTR 10D- 0 *** + EOM_ORDER IEXORD ENERGY [ 0] *** + EOM_PROPSTA IEOMST 0 *** + ESTATE_CONV IEXTOL 10D- 5 *** + ESTATE_DIAG IEXDIG ITERATIVE [ 0] *** + ESTATE_LOCK IESLOC ON [ 1] *** + ESTATE_MAXC IEXMXC 80 *** + ESTATE_PROP IEXPRP OFF [ 0] *** + EVAL_HESS IRECAL 0 # of cyc. + EXCITATION IEXCIT 0 *** + EXCITE IEXCIT NONE [ 0] *** + EXTERN_POT IEXPOT OFF [ 0] *** + FCGRADNEW IFCGNW OFF [ 0] *** + FC_FIELD IFINFC 0 x 10-6 + FD_CALTYPE IFDCAL GRADONLY [ 0] *** + FD_PROJECT IFDPRJ OFF [ 1] *** + FD_STEPSIZE IDISFD 0 10-4 bohr + FD_USEGROUP IFDGRP FULL [ 0] *** + FILE_RECSIZ IFLREC 4096 words + FINITE_PERT IFIPER 0 x 10-6 + FIXGEOM IFIXGM OFF [ 0] *** + FOCK IFOCK AO [ 1] *** + FREQ_ALGORI IVIALG STANDARD [ 0] *** + FROZEN_CORE IFROCO ON [ 1] *** + GAMMA_ABCD IGABCD STORE [ 0] *** + GAMMA_ABCI IGABCI STORE [ 0] *** + GENBAS_1 IGNBS1 0 *** + GENBAS_2 IGNBS2 0 *** + GENBAS_3 IGNBS3 0 *** + GENBAS_4 IGNBS4 0 *** + GEO_CONV ICONTL 5 H/bohr + GEO_MAXCYC IOPTCY 50 *** + GEO_MAXSTEP IMXSTP 300 millibohr + GEO_METHOD INR SINGLE_POINT[ 5] *** + GIAO IGIAO OFF [ 1] *** + GIMIC IGIMIC OFF [ 0] *** + GRID IGRID OFF [ 0] *** + GRID_ALGO IGALGO SERIAL [ 0] *** + GUESS IGUESS MOREAD [ 0] *** + HBAR IHBAR OFF [ 0] *** + HESS_TYPE IHESTP SCF [ 0] *** + HF2_FILE IHF2Fl USE [ 1] *** + HFSTABILITY ISTABL OFF [ 0] *** + INCORE INCORE OFF [ 0] *** + INPUT_MRCC IMRCC ON [ 1] *** + INTEGRALS INTTYP VMOL [ 1] *** + JODA_PRINT IJPRNT 0 *** + KEYWORD_OUT IDMPKW NO [ 0] *** + LINDEP_TOL ILINDP 8 *** + LINEQ_CONV IZTACN 10D- 7 cycles + LINEQ_EXPOR ILMAXD 5 *** + LINEQ_MAXCY ILMAXC 100 *** + LINEQ_TYPE ILTYPE DIIS [ 1] *** + LOCK_ORBOCC ILOCOC OFF [ 0] *** + MEMORY_SIZE IMEMSZ ********* words + MEM_UNIT IMEMU GB [ 3] *** + MRCC IMRCCC OFF [ 0] *** + MULTIPLICTY IMULTP 1 *** + NACOUPLING IVCOUP OFF [ 0] *** + NEGEVAL IDIE ABORT [ 0] *** + NEWNORM INEWNO OFF [ 0] *** + NON-HF INONHF OFF [ 0] *** + NTOP_TAMP ITOPT2 15 *** + NUC_MODEL INUCMO POINT [ 0] *** + OCCUPATION IOCCU ESTIMATED BY SCF + OPEN-SHELL IOPEN SPIN-ORBITAL[ 0] *** + OPTVIB IOPTVB OFF [ 0] *** + ORBITALS IORBTP STANDARD [ 0] *** + PARALLEL IPARAL ON [ 1] *** + PARA_INT IPINTS ON [ 1] *** + PARA_PRINT IPPRIN 0 *** + PERT_ORB IPTORB STANDARD [ 0] *** + POINTS IGRDFD 0 *** + PRINT IPRNT 0 *** + PROPS IPROPS OFF [ 0] *** + PROP_INTEGR IINTYP INTERNAL [ 0] *** + PSI IPSI OFF [ 0] *** + QC_ALG IQCALG FLM [ 0] *** + QC_LINALG IQCLIN TRIDIAG [ 2] *** + QC_MAXCYC IQCMAX 10D-100 cycles + QC_MAXSCFCY IQCMSC 10D- 15 cycles + QC_RTRUST IQCRTR 10D- 0 x 10-3 + QC_SKIPSCF IQCSKI OFF [ 0] *** + QC_START IQCSTA 10D- 1 *** + QRHFGUESS IQGUES OFF [ 0] *** + QUARTIC IQUART OFF [ 0] *** + RAMAN_INT IRAMIN OFF [ 0] *** + RAMAN_ORB IRAMRE UNRELAXED [ 0] *** + RDO IRDOFM OFF [ 0] *** + REDUCE_REPR REDREP Ir [ 0] *** + REFERENCE IREFNC RHF [ 0] *** + RELATIVIST IRELAT OFF [ 0] *** + RELAX_DENS IRDENS OFF [ 0] *** + RESET_FLAGS IRESET OFF [ 0] *** + RESTART_CC ICCRES OFF [ 0] *** + ROT_EVEC ROTVEC 0 *** + SAVE_INTS ISVINT OFF [ 0] *** + SCALE_ON ISTCRT 0 *** + SCF_CONV ISCFCV 10D- 9 *** + SCF_DAMPING IDAMP 0 x 10-3 + SCF_EXPORDE IRPPOR 6 *** + SCF_EXPSTAR IRPPLS 8 *** + SCF_EXTRAPO IRPP ON [ 1] *** + SCF_MAXCYC ISCFCY 150 cycles + SCF_NOSTOP ISCFST OFF [ 0] *** + SCF_PRINT ISCFPR 0 *** + SCF_PROG ISCFPR SCF [ 0] *** + SD_FIELD IFINSD 0 x 10-6 + SOPERT IPERSO OFF [ 0] *** + SPHERICAL IDFGHI ON [ 1] *** + SPINORBIT ISOCAL OFF [ 0] *** + SPINROTATIO ISRCON OFF [ 0] *** + SPIN_FLIP ISPFLP OFF [ 0] *** + SPIN_ORBIT ISPORB OFF [ 0] *** + SPIN_SCAL ISCSMP OFF [ 0] *** + STEEPSCALE ISTPSC 1000 x 10-3 + SUBGROUP ISUBGP DEFAULT [ 0] *** + SUBGRPAXIS ISBXYZ X [ 0] *** + SYMMETRY ISYM ON [ 0] *** + SYM_CHECK ISYMCK OVERRIDE [ 1] *** + T3_EXTRAPOL IT3EXT ON [ 1] *** + T4_EXTRAPOL IT4EXP OFF [ 0] *** + TAMP_SUM IEVERY 5 *** + TESTSUITE ITESTS OFF [ 0] *** + THERMOCH ITHERM OFF [ 0] *** + TOL_CHOLESK ITOLCH 10D- 4 *** + TRANGRAD IRESRM OFF [ 0] *** + TRANS_INV ITRAIN USE [ 0] *** + TREAT_PERT ITREAT SIMULTANEOUS[ 0] *** + TRIP_ALGORI ITRALG NORMAL [ 0] *** + UIJ_THRESHO IUIJTH 1 *** + UNITS IUNITS BOHR [ 1] *** + UNOS IUNOS OFF [ 0] *** + UPDATE_HESS IHUPDT ON [ 1] *** + VIBPHASE ISETPH STANDARD [ 0] *** + VIBRATION IVIB NO [ 0] *** + VIB_ALGORIT IGEALG STANDARD [ 0] *** + VNATORB IVNORB OFF [ 0] *** + VTRAN IVTRAN FULL/PARTIAL[ 0] *** + XFIELD IXEFLD 0 x 10-6 + XFORM_TOL IXFTOL 10D- 11 *** + YFIELD IYEFLD 0 x 10-6 + ZFIELD IZEFLD 0 x 10-6 + ZSCALE_EXP IZEXPS OFF [ 0] *** + ------------------------------------------------------------------- + @GETXYZ-I, 9 atoms read from ZMAT. + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 +******************************************************************************** + The full molecular point group is C2v . + The largest Abelian subgroup of the full molecular point group is C2v . + The computational point group is C2v . +******************************************************************************** + + + ---------------------------------------------------------------- + Coordinates used in calculation (QCOMP) + ---------------------------------------------------------------- + Z-matrix Atomic Coordinates (in bohr) + Symbol Number X Y Z + ---------------------------------------------------------------- + C 6 0.00000000 -2.06365826 0.60031230 + C 6 0.00000000 2.06365826 0.60031230 + C 6 0.00000000 -1.35348578 -1.86356436 + C 6 0.00000000 1.35348578 -1.86356436 + O 8 0.00000000 0.00000000 2.13925312 + H 1 0.00000000 -3.86337287 1.53745675 + H 1 0.00000000 3.86337287 1.53745675 + H 1 0.00000000 -2.59168789 -3.47188071 + H 1 0.00000000 2.59168789 -3.47188071 + ---------------------------------------------------------------- + + Interatomic distance matrix (Angstroms) + + C C C C O + [ 1] [ 2] [ 3] [ 4] [ 5] + C [ 1] 0.00000 + C [ 2] 2.18408 0.00000 + C [ 3] 1.35691 2.22931 0.00000 + C [ 4] 2.22931 1.35691 1.43247 0.00000 + O [ 5] 1.36226 1.36226 2.23601 2.23601 0.00000 + H [ 6] 1.07375 3.17541 2.23677 3.29549 2.06906 + H [ 7] 3.17541 1.07375 3.29549 2.23677 2.06906 + H [ 8] 2.17295 3.27299 1.07409 2.25451 3.27071 + H [ 9] 3.27299 2.17295 2.25451 1.07409 3.27071 + + H H H H + [ 6] [ 7] [ 8] [ 9] + H [ 6] 0.00000 + H [ 7] 4.08882 0.00000 + H [ 8] 2.73491 4.32378 0.00000 + H [ 9] 4.32378 2.73491 2.74292 0.00000 + rotcon2 + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 + There are 5 frozen-core orbitals. + There are 90 basis functions. + @GEOPT-W, Archive file not created for single-point calculation. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.20/ 1.91 seconds. +--executable xjoda finished with status 0 in 2.45 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol + SERIAL VERSION OF MOLECULE STARTED +******************************************************************************** + INPUT FROM MOL FILE +******************************************************************************** +INTGRL 1 0 1 0 0 0 0 0 0 + *** CFOUR Program System (Release V0.1) *** +Ketene -GS + 5 2 X Y 0.10E-08 0 0 + 9999.00 3.00 + 6.00000000 1 3 1 1 1 +C #1 0.000000000000000 -2.063658260000000 0.600312302999175 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 6.00000000 1 3 1 1 1 +C #2 0.000000000000000 -1.353485780000000 -1.863564357000825 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 8.00000000 1 3 1 1 1 +O #3 0.000000000000000 0.000000000000000 2.139253122999175 + 9 3 + 11720.0000000000 7.100000000000000E-004 -1.600000000000000E-004 + 0.000000000000000E+000 + 1759.00000000000 5.470000000000000E-003 -1.263000000000000E-003 + 0.000000000000000E+000 + 400.800000000000 2.783700000000000E-002 -6.267000000000000E-003 + 0.000000000000000E+000 + 113.700000000000 0.104800000000000 -2.571600000000000E-002 + 0.000000000000000E+000 + 37.0300000000000 0.283062000000000 -7.092400000000000E-002 + 0.000000000000000E+000 + 13.2700000000000 0.448719000000000 -0.165411000000000 + 0.000000000000000E+000 + 5.02500000000000 0.270952000000000 -0.116955000000000 + 0.000000000000000E+000 + 1.01300000000000 1.545800000000000E-002 0.557368000000000 + 0.000000000000000E+000 + 0.302300000000000 -2.585000000000000E-003 0.572759000000000 + 1.00000000000000 + 4 2 + 17.7000000000000 4.301800000000000E-002 0.000000000000000E+000 + 3.85400000000000 0.228913000000000 0.000000000000000E+000 + 1.04600000000000 0.508728000000000 0.000000000000000E+000 + 0.275300000000000 0.460531000000000 1.00000000000000 + 1 1 + 1.18500000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #4 0.000000000000000 -3.863372870000000 1.537456752999175 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #5 0.000000000000000 -2.591687890000000 -3.471880707000825 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 +FINISH + +******************************************************************************** + ONE- AND TWO-ELECTRON INTEGRALS OVER SYMMETRY-ADAPTED AOS ARE CALCULATED. + + SPHERICAL HARMONICS ARE USED. + + INTEGRALS LESS THAN 0.10E-13 ARE NEGLECTED. + + NUCLEAR REPULSION ENERGY : 161.1082297788 A.U. + @MOLECU-I, ONE ELECTRON INTEGRALS (CPU/WALL): 0.05/ 0.09 SECONDS. + @TWOEL-I, 325108 INTEGRALS OF SYMMETRY TYPE I I I I + @TWOEL-I, 908743 INTEGRALS OF SYMMETRY TYPE I J I J + @TWOEL-I, 490042 INTEGRALS OF SYMMETRY TYPE I I J J + @TWOEL-I, 460725 INTEGRALS OF SYMMETRY TYPE I J K L + @TWOEL-I, TOTAL NUMBER OF 2-E INTEGRALS 2184618. + @MOLECU-I, TWO ELECTRON INTEGRALS (CPU/WALL): 2.19/ 2.20 SECONDS. + @CHECKOUT-I, Total execution time (CPU/WALL): 2.27/ 2.32 seconds. + +Running with 20 threads/proc + +--executable xvmol finished with status 0 in 3.08 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol2ja + @GETMEM-I, Allocated 171661 MB of main memory. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.52/ 0.25 seconds. +--executable xvmol2ja finished with status 0 in 1.35 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvscf + There are 90 functions in the AO basis. + + There are 4 irreducible representations. + + Irrep # of functions + 1 35 + 2 13 + 3 31 + 4 11 + + + Parameters for SCF calculation: + SCF reference function: RHF + Maximum number of iterations: 150 + Full symmetry point group: C2v + Computational point group: C2v + Initial density matrix: MOREAD + SCF convergence tolerance: 10**(- 9) + DIIS convergence acceleration: ON + Latest start for DIIS: 8 + DIIS order: 6 + + Memory information: 341888 words required. + Fock matrices are constructed from AO integral file. + @GETMEM-I, Allocated 2 MB of main memory. + Initialization and symmetry analysis required 0.004 seconds. + + @INITGES-I, Occupancies from core Hamiltonian: + + Alpha population by irrep: 9 2 6 1 + Beta population by irrep: 9 2 6 1 + + + total no. of electrons in initial guess : 0.000000000000000E+000 + -------------------------------------------------------------------- + Iteration Total Energy Largest Density Difference + -------------------------------------------------------------------- + 0 161.108229778788910 0.0000000000D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 1 -196.263249175406742 0.1098182460D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 2 -179.889864626346110 0.1675780025D+02 + current occupation vector + 9 1 7 1 + 9 1 7 1 + 3 -180.580457259655276 0.1772125138D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 4 -162.771013663102423 0.1566999730D+02 + current occupation vector + 8 2 7 1 + 8 2 7 1 + 5 -169.943224465304610 0.1454729382D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 6 -160.269967975319304 0.1454634919D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 7 -168.828658617539219 0.1395077743D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 8 -160.232275948462728 0.1395068492D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 9 -209.746508446751051 0.5520995458D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 10 -228.180230304178195 0.2015536648D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 11 -228.454713327495170 0.6531384936D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 12 -228.600329261509017 0.3196758217D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 13 -228.637509917233530 0.7498321731D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 14 -228.642938164598405 0.5250342791D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 15 -228.643241982659077 0.9795506231D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 16 -228.643308522549574 0.3593200395D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 17 -228.643312517845317 0.1473098013D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 18 -228.643312570337088 0.1244041229D-03 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 19 -228.643312572355882 0.2423484434D-04 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 20 -228.643312572475082 0.5414752037D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 21 -228.643312572483552 0.2003508847D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 22 -228.643312572485314 0.8833300431D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 23 -228.643312572485655 0.3139638252D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 24 -228.643312572485598 0.4136765797D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 25 -228.643312572485883 0.9839837678D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 26 -228.643312572484120 0.1838787145D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 27 -228.643312572485030 0.3228645795D-08 + current occupation vector + 9 2 6 1 + 9 2 6 1 + + SCF has converged. + + Density matrix saved to file den.dat + total electron number: 36.0000000000001 + E(SCF)= -228.643312572483723 0.7983149697D-09 + + Eigenvector printing suppressed. + + @PUTMOS-I, Writing converged MOs to NEWMOS. + @PUTMOS-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTMOS-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTMOS-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTMOS-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + @PUTFOCK-I, Writing converged Fock matrix to NEWFOCK. + @PUTFOCK-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTFOCK-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + + + + ORBITAL EIGENVALUES (ALPHA) (1H = 27.2113834 eV) + + MO # E(hartree) E(eV) FULLSYM COMPSYM + ---- -------------------- -------------------- ------- --------- + 1 1 -20.6219765861 -561.1525113512 A1 A1 (1) + 2 49 -11.2892088103 -307.1949892207 B2 B2 (3) + 3 2 -11.2891634657 -307.1937553315 A1 A1 (1) + 4 3 -11.2328159068 -305.6604603025 A1 A1 (1) + 5 50 -11.2318729764 -305.6348018622 B2 B2 (3) + 6 4 -1.4574476329 -39.6591663239 A1 A1 (1) + 7 5 -1.0834872588 -29.4831872086 A1 A1 (1) + 8 51 -1.0036038078 -27.3094479952 B2 B2 (3) + 9 52 -0.8050606676 -21.9068144851 B2 B2 (3) + 10 6 -0.7793049296 -21.2059652251 A1 A1 (1) + 11 7 -0.7372159421 -20.0606656495 A1 A1 (1) + 12 36 -0.6283416633 -17.0980459063 B1 B1 (2) + 13 53 -0.6064452640 -16.5022145907 B2 B2 (3) + 14 54 -0.5741889664 -15.6244761082 B2 B2 (3) + 15 8 -0.5622006055 -15.2982562239 A1 A1 (1) + 16 9 -0.5366322238 -14.6025051862 A1 A1 (1) + 17 37 -0.3944127682 -10.7325170532 B1 B1 (2) + 18 80 -0.3173264428 -8.6348914980 A2 A2 (4) + +++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ + 19 38 0.1616454919 4.3985974562 B1 B1 (2) + 20 10 0.2028007990 5.5184902966 A1 A1 (1) + 21 55 0.2259953076 6.1496449623 B2 B2 (3) + 22 11 0.2331452351 6.3442043789 A1 A1 (1) + 23 81 0.2346526075 6.3852220682 A2 A2 (4) + 24 56 0.2409072580 6.5554197617 B2 B2 (3) + 25 12 0.3379830583 9.1969865830 A1 A1 (1) + 26 57 0.3670668300 9.9883962435 B2 B2 (3) + 27 13 0.4400792390 11.9751648999 A1 A1 (1) + 28 58 0.5035354267 13.7018955503 B2 B2 (3) + 29 14 0.5796551077 15.7732173745 A1 A1 (1) + 30 59 0.6027649445 16.4020680057 B2 B2 (3) + 31 39 0.6720867908 18.2884113425 B1 B1 (2) + 32 15 0.6949257331 18.9098905590 A1 A1 (1) + 33 60 0.7033703399 19.1396799906 B2 B2 (3) + 34 82 0.7176012567 19.5269229246 A2 A2 (4) + 35 61 0.7543801794 20.5277282918 B2 B2 (3) + 36 40 0.7622869649 20.7428828633 B1 B1 (2) + 37 16 0.7651070466 20.8196211868 A1 A1 (1) + 38 17 0.7917408050 21.5443625978 A1 A1 (1) + 39 83 0.8438632537 22.9626865338 A2 A2 (4) + 40 62 0.8844205187 24.0663058221 B2 B2 (3) + 41 18 0.9187910190 25.0015746820 A1 A1 (1) + 42 19 0.9547555380 25.9802189979 A1 A1 (1) + 43 63 0.9634112815 26.2157537519 B2 B2 (3) + 44 64 1.0592164869 28.8227459274 B2 B2 (3) + 45 41 1.0743328454 29.2340829566 B1 B1 (2) + 46 20 1.1352329173 30.8912581603 A1 A1 (1) + 47 65 1.1904894416 32.3948646279 B2 B2 (3) + 48 21 1.1908922750 32.4058262839 A1 A1 (1) + 49 42 1.2129419174 33.0058275576 B1 B1 (2) + 50 66 1.2581407748 34.2357509944 B2 B2 (3) + 51 84 1.2921641151 35.1615731515 A2 A2 (4) + 52 22 1.2994001068 35.3584744953 A1 A1 (1) + 53 43 1.3116428673 35.6916169462 B1 B1 (2) + 54 85 1.3649569984 37.1423682072 A2 A2 (4) + 55 44 1.5283489789 41.5884900335 B1 B1 (2) + 56 23 1.5439841773 42.0139454134 A1 A1 (1) + 57 67 1.5691624192 42.6990802047 B2 B2 (3) + 58 68 1.5969806595 43.4560530082 B2 B2 (3) + 59 24 1.7377154792 47.2856421455 A1 A1 (1) + 60 69 1.7438095776 47.4514709939 B2 B2 (3) + 61 86 1.7443895833 47.4672537511 A2 A2 (4) + 62 25 1.7729617500 48.2447419337 A1 A1 (1) + 63 45 1.8384391578 50.0264727818 B1 B1 (2) + 64 26 1.8727560698 50.9602834298 A1 A1 (1) + 65 46 1.9574193824 53.2640892885 B1 B1 (2) + 66 70 1.9863618073 54.0516527104 B2 B2 (3) + 67 71 2.0036624844 54.5224280672 B2 B2 (3) + 68 87 2.0489211710 55.7539795407 A2 A2 (4) + 69 27 2.0703324397 56.3366097828 A1 A1 (1) + 70 88 2.1357719213 58.1173086059 A2 A2 (4) + 71 28 2.1641427105 58.8893170283 A1 A1 (1) + 72 72 2.1880643996 59.5402592802 B2 B2 (3) + 73 47 2.1914898441 59.6334703659 B1 B1 (2) + 74 29 2.2271655184 60.6042548161 A1 A1 (1) + 75 73 2.2977715809 62.5255434529 B2 B2 (3) + 76 30 2.3793504210 64.7454165492 A1 A1 (1) + 77 89 2.5107047412 68.3197493175 A2 A2 (4) + 78 74 2.5407172731 69.1364318293 B2 B2 (3) + 79 75 2.6586433664 72.3453639681 B2 B2 (3) + 80 31 2.6718877167 72.7057610618 A1 A1 (1) + 81 32 2.8267951805 76.9210074510 A1 A1 (1) + 82 76 2.9419209269 80.0537382753 B2 B2 (3) + 83 77 2.9853767071 81.2362301696 B2 B2 (3) + 84 33 3.0013526923 81.6709588287 A1 A1 (1) + 85 48 3.2421725037 88.2239990462 B1 B1 (2) + 86 90 3.2857682253 89.4102989431 A2 A2 (4) + 87 34 3.4838249547 94.7996965407 A1 A1 (1) + 88 78 3.6959298762 100.5713648809 B2 B2 (3) + 89 79 3.7700022467 102.5869765541 B2 B2 (3) + 90 35 3.8341979240 104.3338297409 A1 A1 (1) + + + VSCF finished. + + @CHECKOUT-I, Total execution time (CPU/WALL): 4.51/ 1.05 seconds. +--executable xvscf finished with status 0 in 1.59 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvtran + @GETMEM-I, Allocated 171661 MB of main memory. + Full RHF integral transformation + The following 5 MOs will be dropped: + 1 2 3 12 13 + There are 85 active molecular orbitals. + Transformation of IIII integrals : + 1 pass through the AO integral file was required. + 325108 AO integrals were read. + 240883 MO integrals were written to HF2. + Transformation of IIJJ integrals : + 1 pass through the AO integral file was required. + 490042 AO integrals were read. + 386877 MO integrals were written to HF2. + Transformation of IJIJ integrals : + 1 pass through the AO integral file was required. + 908743 AO integrals were read. + 712509 MO integrals were written to HF2. + Transformation of IJKL integrals : + 1 pass through the AO integral file was required. + 460725 AO integrals were read. + 398112 MO integrals were written to HF2. + Summary of active molecular orbitals: +------------------------------------------------------------------------ + + Index Eigenvalue Symmetry Index Eigenvalue Symmetry +------------------------------------------------------------------------ + 1 -1.4574476 1 44 1.2129419 2 + 2 -1.0834873 1 45 1.3116429 2 + 3 -0.7793049 1 46 1.5283490 2 + 4 -0.7372159 1 47 1.8384392 2 + 5 -0.5622006 1 48 1.9574194 2 + 6 -0.5366322 1 49 2.1914898 2 + 7 -0.6283417 2 50 3.2421725 2 + 8 -0.3944128 2 51 0.2259953 3 + 9 -1.0036038 3 52 0.2409073 3 + 10 -0.8050607 3 53 0.3670668 3 + 11 -0.6064453 3 54 0.5035354 3 + 12 -0.5741890 3 55 0.6027649 3 + 13 -0.3173264 4 56 0.7033703 3 + 14 0.2028008 1 57 0.7543802 3 + 15 0.2331452 1 58 0.8844205 3 + 16 0.3379831 1 59 0.9634113 3 + 17 0.4400792 1 60 1.0592165 3 + 18 0.5796551 1 61 1.1904894 3 + 19 0.6949257 1 62 1.2581408 3 + 20 0.7651070 1 63 1.5691624 3 + 21 0.7917408 1 64 1.5969807 3 + 22 0.9187910 1 65 1.7438096 3 + 23 0.9547555 1 66 1.9863618 3 + 24 1.1352329 1 67 2.0036625 3 + 25 1.1908923 1 68 2.1880644 3 + 26 1.2994001 1 69 2.2977716 3 + 27 1.5439842 1 70 2.5407173 3 + 28 1.7377155 1 71 2.6586434 3 + 29 1.7729618 1 72 2.9419209 3 + 30 1.8727561 1 73 2.9853767 3 + 31 2.0703324 1 74 3.6959299 3 + 32 2.1641427 1 75 3.7700022 3 + 33 2.2271655 1 76 0.2346526 4 + 34 2.3793504 1 77 0.7176013 4 + 35 2.6718877 1 78 0.8438633 4 + 36 2.8267952 1 79 1.2921641 4 + 37 3.0013527 1 80 1.3649570 4 + 38 3.4838250 1 81 1.7443896 4 + 39 3.8341979 1 82 2.0489212 4 + 40 0.1616455 2 83 2.1357719 4 + 41 0.6720868 2 84 2.5107047 4 + 42 0.7622870 2 85 3.2857682 4 + 43 1.0743328 2 +------------------------------------------------------------------------ + -1.45744763288719 -1.08348725881446 -0.779304929609906 + -0.737215942115345 -0.562200605497247 -0.536632223783709 + -0.628341663300678 -0.394412768193199 -1.00360380778027 + -0.805060667553656 -0.606445264032674 -0.574188966380062 + -0.317326442801082 0.202800799044621 0.233145235052796 + 0.337983058333910 0.440079239040636 0.579655107668687 + 0.694925733138532 0.765107046589604 0.791740804983874 + 0.918791018981417 0.954755538002272 1.13523291727429 + 1.19089227502855 1.29940010677045 1.54398417734964 + 1.73771547923301 1.77296175003384 1.87275606979142 + 2.07033243972491 2.16414271052241 2.22716551838582 + 2.37935042101672 2.67188771673541 2.82679518054206 + 3.00135269229792 3.48382495469385 3.83419792398027 + 0.161645491943538 0.672086790797538 0.762286964920225 + 1.07433284544460 1.21294191744910 1.31164286730924 + 1.52834897888623 1.83843915784912 1.95741938237799 + 2.19148984413106 3.24217250366569 0.225995307622885 + 0.240907258016188 0.367066829963072 0.503535426660154 + 0.602764944530587 0.703370339876010 0.754380179427082 + 0.884420518732847 0.963411281466860 1.05921648685456 + 1.19048944155904 1.25814077480351 1.56916241916270 + 1.59698065950514 1.74380957764519 1.98636180732945 + 2.00366248439906 2.18806439955611 2.29777158087798 + 2.54071727310058 2.65864336644201 2.94192092693410 + 2.98537670707155 3.69592987620534 3.77000224671027 + 0.234652607488001 0.717601256707188 0.843863253708062 + 1.29216411509330 1.36495699837025 1.74438958333342 + 2.04892117101006 2.13577192131675 2.51070474122047 + 3.28576822533551 + @CHECKOUT-I, Total execution time (CPU/WALL): 7.14/ 0.54 seconds. +--executable xvtran finished with status 0 in 1.07 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xintprc + @GETMEM-I, Allocated 171661 MB of main memory. + @GMOIAA-I, Processing MO integrals for spin case AA. + @GMOIAA-I, Generation of integral list completed. + TYPE NUMBER + ---- -------- + PPPP 894479 + PPPH 640524 + PPHH 115497 + PHPH 63721 + PHHH 22938 + HHHH 1222 + + TOTAL 1738381 + + @FORMT2-I, Second-order MP correlation energies: + ------------------------------------------------ + E(SCF) = -228.643312572484 a.u. + E2(AA) = -0.093684343380 a.u. + E2(AB) = -0.520081687065 a.u. + E2(TOT) = -0.707450373824 a.u. + Total MP2 energy = -229.350762946308 a.u. + ------------------------------------------------ + Largest T2 amplitudes for spin case AB: + _ _ _ _ _ _ + i j a b i j a b i j a b +----------------------------------------------------------------------------- +[ 13 13 40 40]-0.06710 [ 8 8 40 40]-0.05436 [ 13 13 76 76]-0.05241 +[ 13 8 76 40]-0.04215 [ 8 13 40 76]-0.04215 [ 8 8 76 76]-0.03737 +[ 7 7 40 40]-0.03140 [ 13 7 40 76]-0.02053 [ 7 13 76 40]-0.02053 +[ 13 13 77 77]-0.01960 [ 13 13 42 40]-0.01810 [ 13 13 40 42]-0.01810 +[ 7 7 45 45]-0.01664 [ 13 13 41 41]-0.01633 [ 13 13 78 76]-0.01595 +----------------------------------------------------------------------------- + Norm of T2AB vector ( 230058 symmetry allowed elements): 0.4218925855. +----------------------------------------------------------------------------- + @CHECKOUT-I, Total execution time (CPU/WALL): 3.53/ 0.56 seconds. +--executable xintprc finished with status 0 in 1.14 seconds (walltime). + calling xncc + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xncc + @GETMEM-I, Allocated 7 MB of main memory. + +Running with 20 threads/proc + +Using DIIS to accelerate the convergence of T1 and T2 +Using DIIS to accelerate the convergence of T3 +Using immediate high-order contributions +Performing 2 CCSDT sub-iterations +Damping factor for T3: 0.000000 +Damping factor for T4: 0.000000 + +Transposes are coarse-threaded + +Memory limit: 167.638 GiB +Minimum memory requirement: 109.028 MiB +Compromise memory amount: 8.961 GiB +Optimal memory requirement: 92.002 GiB + +List Location Size Cached Hunks Est. Disk I/O +----------------- ---------- ----------- ------ ----- ------------- + + T_DIIS 70:0 8.787 MiB Yes - 158.166 MiB + Z_DIIS 70:1 8.787 MiB Yes - 263.610 MiB + 18 1.755 MiB Yes - 318.085 MiB + 233 52.803 MiB Yes - 154.696 GiB + 30 9.615 MiB Yes - 12.536 GiB + 16 1.755 MiB Yes - 2.780 GiB + 25 1.755 MiB Yes - 289.609 MiB + 21 1.755 MiB No - 0 B + 10 329.156 KiB Yes - 530.379 MiB + 13 60.633 KiB Yes - 4.441 MiB + F(EA) 92:0 11.891 KiB Yes - 4.703 MiB + F(EM) 93:0 2.250 KiB Yes - 945.000 KiB + F(MI) 91:0 456 B Yes - 240.469 KiB + Q(AI) 190:2 2.250 KiB Yes - 810.000 KiB + Q(Ab,Ij) 50 1.755 MiB Yes - 2.623 GiB + QQ(Ab,Ij) 3 1.755 MiB Yes - 421.249 MiB + T(AI) 90:0 2.250 KiB Yes - 3.232 MiB + T(Ab,Ij) 46 1.755 MiB Yes - 3.243 GiB + W(Mn,Ij) 53 60.633 KiB Yes - 26.645 MiB + W~(Ab,Ej) 130 9.615 MiB Yes - 16.446 GiB + W~(EM,bj) 56 1.755 MiB Yes - 1.568 GiB + W~(Em,Bj) 58 1.755 MiB Yes - 1.877 GiB + W~(Ij,Mb) 110 329.156 KiB Yes - 351.979 MiB + W~~(Ab,Ej) 169 9.615 MiB Yes - 5.916 GiB + W~~(EM,bj) 76 1.755 MiB Yes - 789.841 MiB + W~~(Em,Bj) 78 1.755 MiB Yes - 789.841 MiB + W~~(Ij,Mb) 165 329.156 KiB Yes - 202.508 MiB + Z(AI) 90:2 2.250 KiB Yes - 810.000 KiB + Z(Ab,Ij) 63 1.755 MiB Yes - 631.873 MiB + Q(abc,ijk) Q3FILE 319.713 MiB Yes 1 18.733 GiB + T(abc,ijk) T3FILE 319.713 MiB Yes 1 56.200 GiB + T(abcd,ijkl) - 83.022 GiB No 1 0 B + T3_1 T3_1 319.713 MiB Yes 1 9.367 GiB + T3_2 T3_2 319.713 MiB Yes 1 4.683 GiB + T3_3 T3_3 319.713 MiB Yes 1 4.683 GiB + T3_4 T3_4 319.713 MiB Yes 1 4.683 GiB + T3_5 T3_5 319.713 MiB Yes 1 4.683 GiB + W(abc,ije) WABCIJE 4.602 GiB Yes 1 138.057 GiB + W(abm,ijk) WABMIJK 154.671 MiB Yes 1 4.531 GiB + Z(abc,ijk) Z3FILE 319.713 MiB Yes 1 51.516 GiB + Z(abcd,ijkl) - 83.022 GiB No 1 0 B + Z3_1 Z3_1 319.713 MiB Yes 1 9.367 GiB + Z3_2 Z3_2 319.713 MiB Yes 1 9.367 GiB + Z3_3 Z3_3 319.713 MiB Yes 1 9.367 GiB + Z3_4 Z3_4 319.713 MiB Yes 1 9.367 GiB + Z3_5 Z3_5 319.713 MiB Yes 1 9.367 GiB + +Simulation and memory analysis took 16.656 seconds + +MP2 correlation energy: -0.707450373824315 + +Non-iterative calculation of MP2 took 0.188 cpu seconds and 0.010 walltime seconds at 1.349 Gflops/sec + +Total MP2 energy: -229.350762946308038 + +Beginning iterative solution of CC4 equations: + +It. Correlation Energy T1 Residual T2 Residual T3 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------------------- + 1 -0.763375159102744 3.28785e-03 6.98171e-03 4.80884e-04 22621.529 1196.376 + 2 -0.766433762900516 5.88798e-04 1.62319e-03 1.10295e-04 23062.492 1229.456 + 3 -0.766857072881060 1.23168e-04 2.49712e-04 3.48802e-05 23807.750 1282.923 + 4 -0.766869333160990 1.85847e-05 1.98072e-05 1.06542e-05 24460.077 1332.728 + 5 -0.766866389167529 1.49279e-06 1.58229e-06 2.17366e-06 25199.102 1390.896 + + A I A I A I +-------------------------- -------------------------- -------------------------- + 19 17 -0.0297256743386 31 17 0.0116307205787 25 15 0.0075767455010 + 19 12 0.0286586556753 36 17 -0.0107385016684 21 14 -0.0074621820902 + 34 18 0.0227581299395 25 16 -0.0100970812397 45 17 0.0074604919856 + 23 18 0.0168465032737 27 16 -0.0093740175532 26 13 0.0071607167867 + 51 18 0.0135429419447 53 17 0.0076606092376 49 17 0.0066118894725 + + A B I J A B I J +------------------------------------ ------------------------------------ + 19 19 18 18 -0.1082304819777 23 19 12 18 -0.0301860542543 + 23 23 18 18 -0.0621899371619 36 19 18 18 -0.0274304417538 + 23 19 18 17 -0.0611568155877 19 36 18 18 -0.0274304417538 + 19 23 17 18 -0.0611568155877 19 23 12 18 -0.0229486425034 + 19 19 17 17 -0.0594078338407 23 19 18 12 -0.0229486425034 + 23 23 17 17 -0.0589677787849 19 23 18 17 -0.0213253760558 + 19 19 12 12 -0.0367239396211 23 19 17 18 -0.0213253760558 + 19 23 18 12 -0.0301860542543 + +It. Correlation Energy T1 Residual T2 Residual T3 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------------------- + 6 -0.766866336061061 5.68331e-07 3.26099e-07 3.59252e-07 25462.752 1419.642 + 7 -0.766866267531340 1.02660e-07 3.63553e-08 4.61834e-08 25861.423 1441.941 + 8 -0.766866256888079 1.71035e-08 5.77081e-09 4.83505e-09 26140.130 1463.487 + +CC4 iterations converged in 8 cycles and 10757.452 seconds (1344.682 s/it.) at 11.883 Gflops/sec + +Total CC4 energy: -229.410178829371802 + + @CHECKOUT-I, Total execution time (CPU/WALL): 196656.36/ 10778.59 seconds. +--executable xncc finished with status 0 in 10780.64 seconds (walltime). + The final electronic energy is -229.410178829371802 a.u. + This computation required 10792.12 seconds (walltime). diff --git a/furan/cc-pvdz/CC/fura-gs-ccsd.out b/furan/cc-pvdz/CC/fura-gs-ccsd.out new file mode 100644 index 0000000..5ebcd4f --- /dev/null +++ b/furan/cc-pvdz/CC/fura-gs-ccsd.out @@ -0,0 +1,1029 @@ + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xjoda + + + ************************************************************************* + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + ************************************************************************* + + **************************************************************** + * CFOUR Coupled-Cluster techniques for Computational Chemistry * + **************************************************************** + + + Department of Chemistry Institut fuer Physikalische Chemie + University of Florida Universitaet Mainz + Gainesville, FL 32611, USA D-55099 Mainz, Germany + + Department of Chemistry Fakultaet fuer Chemie und Biowiss. + Johns Hopkins University Karlsruher Institut fuer Technologie + Baltimore, MD 21218, USA D-76131 Karlsruhe, Germany + + Department of Chemistry Department of Physical Chemistry + Southern Methodist University Eotvos Lorand University + Dallas, TX 75275, USA H-1053 Budapest, Hungary + + + Version 2.1 + + nazare074.cluster + Thu Oct 15 11:17:07 CEST 2020 + integer*8 version is running + +******************************************************************************** +* Input from ZMAT file * +******************************************************************************** +Ketene -GS +C 0.00000000 2.06365826 -0.60051250 +C 0.00000000 -2.06365826 -0.60051250 +C 0.00000000 1.35348578 1.86336416 +C 0.00000000 -1.35348578 1.86336416 +O 0.00000000 0.00000000 -2.13945332 +H 0.00000000 3.86337287 -1.53765695 +H 0.00000000 -3.86337287 -1.53765695 +H 0.00000000 2.59168789 3.47168051 +H 0.00000000 -2.59168789 3.47168051 + +*CFOUR(COORD=CARTESIAN,UNITS=BOHR + MEMORY=100,MEM_UNIT=GB,CC_PROG=NCC + FROZEN_CORE=1 + CALC=CCSD,BASIS=PVDZ + SCF_CONV=9,CC_CONV=7,ESTATE_MAXCYC=80) + +******************************************************************************** + ------------------------------------------------------------------- + CFOUR Control Parameters + ------------------------------------------------------------------- + External Internal Value Units + Name Name + ------------------------------------------------------------------- + ABCDTYPE IABCDT STANDARD [ 0] *** + ANHARMONIC IANHAR OFF [ 0] *** + ANH_ALGORIT IANALG STANDARD [ 0] *** + ANH_DERIVAT IANDER SECOND [ 1] *** + ANH_MODE ANHMOD VIBRATION [ 0] *** + ANH_STEPSIZ ICUBST 50000 x 10-6 + ANH_SYMMETR IANHSM ABELIAN [ 0] *** + AO_LADDERS IAOLAD SINGLEPASS [ 1] *** + AV_SCF IAVSCF OFF [ 0] *** + BASIS IBASIS PVDZ [ 13] *** + BOTHVECTORS BOTHVC OFF [ 0] *** + BOX_POTENT IPIAB OFF [ 0] *** + BREIT IBREIT OFF [ 0] *** + BRUCK_CONV IBRTOL 10D- 4 *** + BRUECKNER IBRKNR OFF [ 0] *** + BUFFERSIZE IBUFFS 4096 *** + CACHE_RECS ICHREC 10 *** + CALCLEVEL ICLLVL CCSD [ 10] *** + CCORBOPT ICCORB OFF [ 0] x 0.01 + CC_CONV ICCCNV 10D- 7 *** + CC_EXPORDER ICCEOR 5 *** + CC_EXTRAPOL ICCEXT DIIS [ 1] *** + CC_GUESS ICCGES MP2 [ 0] *** + CC_MAXCYC ICCCYC 100 cycles + CC_PROGRAM ICCPRO NCC [ 5] *** + CHARGE ICHRGE 0 *** + CHOLESKY ICHOLE OFF [ 0] *** + CIS_CONV ICISTL 5 *** + COMM_SIZE IPSIZE *** *** + CONSTANT ICONST OLD [ 1] *** + CONTINUUM ICONTU NONE [ 0] *** + CONTRACTION ICNTYP GENERAL [ 1] *** + COORDINATES ICOORD CARTESIAN [ 1] *** + CPHF_CONVER ICPHFT 10D- 16 *** + CPHF_MAXCYC ICPHFC 64 cycles + CUBIC ICUBIC OFF [ 0] *** + CURVILINEAR ICURVY OFF [ 0] *** + DBOC IDBOC OFF [ 0] *** + DCT IDCT OFF [ 0] *** + DERIV_LEV IDRLVL ZERO [ 0] *** + DEVMEM_SIZE IDVMEM ********* MByte + DIAG_MRCC IEOMST 10D- 0 *** + DIFF_TYPE IDIFTY RELAXED [ 0] *** + DIRECT IDIRCT OFF [ 0] *** + DROPMO IDRPMO NONE + ECP IECP OFF [ 0] *** + EIGENVECTOR IVEC 1 *** + EL_ANHARM IELANH OFF [ 0] *** + EOMFOLLOW IEOMSR ENERGY [ 0] *** + EOMIP IEOMIP OFF [ 0] *** + EOMLEVEL HBARFM SAME [ 0] *** + EOM_MRCC IMRCCE NEW [ 1] *** + EOM_NONIT EOMNON OFF [ 0] *** + EOM_NSING IEOMSI 10D- 0 *** + EOM_NSTATES IMRCCD DAVIDSON [ 0] *** + EOM_NTRIP IEOMTR 10D- 0 *** + EOM_ORDER IEXORD ENERGY [ 0] *** + EOM_PROPSTA IEOMST 0 *** + ESTATE_CONV IEXTOL 10D- 5 *** + ESTATE_DIAG IEXDIG ITERATIVE [ 0] *** + ESTATE_LOCK IESLOC ON [ 1] *** + ESTATE_MAXC IEXMXC 80 *** + ESTATE_PROP IEXPRP OFF [ 0] *** + EVAL_HESS IRECAL 0 # of cyc. + EXCITATION IEXCIT 0 *** + EXCITE IEXCIT NONE [ 0] *** + EXTERN_POT IEXPOT OFF [ 0] *** + FCGRADNEW IFCGNW OFF [ 0] *** + FC_FIELD IFINFC 0 x 10-6 + FD_CALTYPE IFDCAL GRADONLY [ 0] *** + FD_PROJECT IFDPRJ OFF [ 1] *** + FD_STEPSIZE IDISFD 0 10-4 bohr + FD_USEGROUP IFDGRP FULL [ 0] *** + FILE_RECSIZ IFLREC 4096 words + FINITE_PERT IFIPER 0 x 10-6 + FIXGEOM IFIXGM OFF [ 0] *** + FOCK IFOCK AO [ 1] *** + FREQ_ALGORI IVIALG STANDARD [ 0] *** + FROZEN_CORE IFROCO ON [ 1] *** + GAMMA_ABCD IGABCD STORE [ 0] *** + GAMMA_ABCI IGABCI STORE [ 0] *** + GENBAS_1 IGNBS1 0 *** + GENBAS_2 IGNBS2 0 *** + GENBAS_3 IGNBS3 0 *** + GENBAS_4 IGNBS4 0 *** + GEO_CONV ICONTL 5 H/bohr + GEO_MAXCYC IOPTCY 50 *** + GEO_MAXSTEP IMXSTP 300 millibohr + GEO_METHOD INR SINGLE_POINT[ 5] *** + GIAO IGIAO OFF [ 1] *** + GIMIC IGIMIC OFF [ 0] *** + GRID IGRID OFF [ 0] *** + GRID_ALGO IGALGO SERIAL [ 0] *** + GUESS IGUESS MOREAD [ 0] *** + HBAR IHBAR OFF [ 0] *** + HESS_TYPE IHESTP SCF [ 0] *** + HF2_FILE IHF2Fl USE [ 1] *** + HFSTABILITY ISTABL OFF [ 0] *** + INCORE INCORE OFF [ 0] *** + INPUT_MRCC IMRCC ON [ 1] *** + INTEGRALS INTTYP VMOL [ 1] *** + JODA_PRINT IJPRNT 0 *** + KEYWORD_OUT IDMPKW NO [ 0] *** + LINDEP_TOL ILINDP 8 *** + LINEQ_CONV IZTACN 10D- 7 cycles + LINEQ_EXPOR ILMAXD 5 *** + LINEQ_MAXCY ILMAXC 100 *** + LINEQ_TYPE ILTYPE DIIS [ 1] *** + LOCK_ORBOCC ILOCOC OFF [ 0] *** + MEMORY_SIZE IMEMSZ ********* words + MEM_UNIT IMEMU GB [ 3] *** + MRCC IMRCCC OFF [ 0] *** + MULTIPLICTY IMULTP 1 *** + NACOUPLING IVCOUP OFF [ 0] *** + NEGEVAL IDIE ABORT [ 0] *** + NEWNORM INEWNO OFF [ 0] *** + NON-HF INONHF OFF [ 0] *** + NTOP_TAMP ITOPT2 15 *** + NUC_MODEL INUCMO POINT [ 0] *** + OCCUPATION IOCCU ESTIMATED BY SCF + OPEN-SHELL IOPEN SPIN-ORBITAL[ 0] *** + OPTVIB IOPTVB OFF [ 0] *** + ORBITALS IORBTP STANDARD [ 0] *** + PARALLEL IPARAL ON [ 1] *** + PARA_INT IPINTS ON [ 1] *** + PARA_PRINT IPPRIN 0 *** + PERT_ORB IPTORB STANDARD [ 0] *** + POINTS IGRDFD 0 *** + PRINT IPRNT 0 *** + PROPS IPROPS OFF [ 0] *** + PROP_INTEGR IINTYP INTERNAL [ 0] *** + PSI IPSI OFF [ 0] *** + QC_ALG IQCALG FLM [ 0] *** + QC_LINALG IQCLIN TRIDIAG [ 2] *** + QC_MAXCYC IQCMAX 10D-100 cycles + QC_MAXSCFCY IQCMSC 10D- 15 cycles + QC_RTRUST IQCRTR 10D- 0 x 10-3 + QC_SKIPSCF IQCSKI OFF [ 0] *** + QC_START IQCSTA 10D- 1 *** + QRHFGUESS IQGUES OFF [ 0] *** + QUARTIC IQUART OFF [ 0] *** + RAMAN_INT IRAMIN OFF [ 0] *** + RAMAN_ORB IRAMRE UNRELAXED [ 0] *** + RDO IRDOFM OFF [ 0] *** + REDUCE_REPR REDREP Ir [ 0] *** + REFERENCE IREFNC RHF [ 0] *** + RELATIVIST IRELAT OFF [ 0] *** + RELAX_DENS IRDENS OFF [ 0] *** + RESET_FLAGS IRESET OFF [ 0] *** + RESTART_CC ICCRES OFF [ 0] *** + ROT_EVEC ROTVEC 0 *** + SAVE_INTS ISVINT OFF [ 0] *** + SCALE_ON ISTCRT 0 *** + SCF_CONV ISCFCV 10D- 9 *** + SCF_DAMPING IDAMP 0 x 10-3 + SCF_EXPORDE IRPPOR 6 *** + SCF_EXPSTAR IRPPLS 8 *** + SCF_EXTRAPO IRPP ON [ 1] *** + SCF_MAXCYC ISCFCY 150 cycles + SCF_NOSTOP ISCFST OFF [ 0] *** + SCF_PRINT ISCFPR 0 *** + SCF_PROG ISCFPR SCF [ 0] *** + SD_FIELD IFINSD 0 x 10-6 + SOPERT IPERSO OFF [ 0] *** + SPHERICAL IDFGHI ON [ 1] *** + SPINORBIT ISOCAL OFF [ 0] *** + SPINROTATIO ISRCON OFF [ 0] *** + SPIN_FLIP ISPFLP OFF [ 0] *** + SPIN_ORBIT ISPORB OFF [ 0] *** + SPIN_SCAL ISCSMP OFF [ 0] *** + STEEPSCALE ISTPSC 1000 x 10-3 + SUBGROUP ISUBGP DEFAULT [ 0] *** + SUBGRPAXIS ISBXYZ X [ 0] *** + SYMMETRY ISYM ON [ 0] *** + SYM_CHECK ISYMCK OVERRIDE [ 1] *** + T3_EXTRAPOL IT3EXT OFF [ 0] *** + T4_EXTRAPOL IT4EXP OFF [ 0] *** + TAMP_SUM IEVERY 5 *** + TESTSUITE ITESTS OFF [ 0] *** + THERMOCH ITHERM OFF [ 0] *** + TOL_CHOLESK ITOLCH 10D- 4 *** + TRANGRAD IRESRM OFF [ 0] *** + TRANS_INV ITRAIN USE [ 0] *** + TREAT_PERT ITREAT SIMULTANEOUS[ 0] *** + TRIP_ALGORI ITRALG NORMAL [ 0] *** + UIJ_THRESHO IUIJTH 1 *** + UNITS IUNITS BOHR [ 1] *** + UNOS IUNOS OFF [ 0] *** + UPDATE_HESS IHUPDT ON [ 1] *** + VIBPHASE ISETPH STANDARD [ 0] *** + VIBRATION IVIB NO [ 0] *** + VIB_ALGORIT IGEALG STANDARD [ 0] *** + VNATORB IVNORB OFF [ 0] *** + VTRAN IVTRAN FULL/PARTIAL[ 0] *** + XFIELD IXEFLD 0 x 10-6 + XFORM_TOL IXFTOL 10D- 11 *** + YFIELD IYEFLD 0 x 10-6 + ZFIELD IZEFLD 0 x 10-6 + ZSCALE_EXP IZEXPS OFF [ 0] *** + ------------------------------------------------------------------- + @GETXYZ-I, 9 atoms read from ZMAT. + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 +******************************************************************************** + The full molecular point group is C2v . + The largest Abelian subgroup of the full molecular point group is C2v . + The computational point group is C2v . +******************************************************************************** + + + ---------------------------------------------------------------- + Coordinates used in calculation (QCOMP) + ---------------------------------------------------------------- + Z-matrix Atomic Coordinates (in bohr) + Symbol Number X Y Z + ---------------------------------------------------------------- + C 6 0.00000000 -2.06365826 0.60031230 + C 6 0.00000000 2.06365826 0.60031230 + C 6 0.00000000 -1.35348578 -1.86356436 + C 6 0.00000000 1.35348578 -1.86356436 + O 8 0.00000000 0.00000000 2.13925312 + H 1 0.00000000 -3.86337287 1.53745675 + H 1 0.00000000 3.86337287 1.53745675 + H 1 0.00000000 -2.59168789 -3.47188071 + H 1 0.00000000 2.59168789 -3.47188071 + ---------------------------------------------------------------- + + Interatomic distance matrix (Angstroms) + + C C C C O + [ 1] [ 2] [ 3] [ 4] [ 5] + C [ 1] 0.00000 + C [ 2] 2.18408 0.00000 + C [ 3] 1.35691 2.22931 0.00000 + C [ 4] 2.22931 1.35691 1.43247 0.00000 + O [ 5] 1.36226 1.36226 2.23601 2.23601 0.00000 + H [ 6] 1.07375 3.17541 2.23677 3.29549 2.06906 + H [ 7] 3.17541 1.07375 3.29549 2.23677 2.06906 + H [ 8] 2.17295 3.27299 1.07409 2.25451 3.27071 + H [ 9] 3.27299 2.17295 2.25451 1.07409 3.27071 + + H H H H + [ 6] [ 7] [ 8] [ 9] + H [ 6] 0.00000 + H [ 7] 4.08882 0.00000 + H [ 8] 2.73491 4.32378 0.00000 + H [ 9] 4.32378 2.73491 2.74292 0.00000 + rotcon2 + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 + There are 5 frozen-core orbitals. + There are 90 basis functions. + @GEOPT-W, Archive file not created for single-point calculation. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.12/ 2.00 seconds. +--executable xjoda finished with status 0 in 2.56 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol + SERIAL VERSION OF MOLECULE STARTED +******************************************************************************** + INPUT FROM MOL FILE +******************************************************************************** +INTGRL 1 0 1 0 0 0 0 0 0 + *** CFOUR Program System (Release V0.1) *** +Ketene -GS + 5 2 X Y 0.10E-08 0 0 + 9999.00 3.00 + 6.00000000 1 3 1 1 1 +C #1 0.000000000000000 -2.063658260000000 0.600312302999175 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 6.00000000 1 3 1 1 1 +C #2 0.000000000000000 -1.353485780000000 -1.863564357000825 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 8.00000000 1 3 1 1 1 +O #3 0.000000000000000 0.000000000000000 2.139253122999175 + 9 3 + 11720.0000000000 7.100000000000000E-004 -1.600000000000000E-004 + 0.000000000000000E+000 + 1759.00000000000 5.470000000000000E-003 -1.263000000000000E-003 + 0.000000000000000E+000 + 400.800000000000 2.783700000000000E-002 -6.267000000000000E-003 + 0.000000000000000E+000 + 113.700000000000 0.104800000000000 -2.571600000000000E-002 + 0.000000000000000E+000 + 37.0300000000000 0.283062000000000 -7.092400000000000E-002 + 0.000000000000000E+000 + 13.2700000000000 0.448719000000000 -0.165411000000000 + 0.000000000000000E+000 + 5.02500000000000 0.270952000000000 -0.116955000000000 + 0.000000000000000E+000 + 1.01300000000000 1.545800000000000E-002 0.557368000000000 + 0.000000000000000E+000 + 0.302300000000000 -2.585000000000000E-003 0.572759000000000 + 1.00000000000000 + 4 2 + 17.7000000000000 4.301800000000000E-002 0.000000000000000E+000 + 3.85400000000000 0.228913000000000 0.000000000000000E+000 + 1.04600000000000 0.508728000000000 0.000000000000000E+000 + 0.275300000000000 0.460531000000000 1.00000000000000 + 1 1 + 1.18500000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #4 0.000000000000000 -3.863372870000000 1.537456752999175 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #5 0.000000000000000 -2.591687890000000 -3.471880707000825 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 +FINISH + +******************************************************************************** + ONE- AND TWO-ELECTRON INTEGRALS OVER SYMMETRY-ADAPTED AOS ARE CALCULATED. + + SPHERICAL HARMONICS ARE USED. + + INTEGRALS LESS THAN 0.10E-13 ARE NEGLECTED. + + NUCLEAR REPULSION ENERGY : 161.1082297788 A.U. + @MOLECU-I, ONE ELECTRON INTEGRALS (CPU/WALL): 0.02/ 0.05 SECONDS. + @TWOEL-I, 325108 INTEGRALS OF SYMMETRY TYPE I I I I + @TWOEL-I, 908743 INTEGRALS OF SYMMETRY TYPE I J I J + @TWOEL-I, 490042 INTEGRALS OF SYMMETRY TYPE I I J J + @TWOEL-I, 460725 INTEGRALS OF SYMMETRY TYPE I J K L + @TWOEL-I, TOTAL NUMBER OF 2-E INTEGRALS 2184618. + @MOLECU-I, TWO ELECTRON INTEGRALS (CPU/WALL): 1.42/ 1.43 SECONDS. + @CHECKOUT-I, Total execution time (CPU/WALL): 1.45/ 1.49 seconds. + +Running with 20 threads/proc + +--executable xvmol finished with status 0 in 2.18 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol2ja + @GETMEM-I, Allocated 95367 MB of main memory. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.28/ 0.05 seconds. +--executable xvmol2ja finished with status 0 in 0.56 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvscf + There are 90 functions in the AO basis. + + There are 4 irreducible representations. + + Irrep # of functions + 1 35 + 2 13 + 3 31 + 4 11 + + + Parameters for SCF calculation: + SCF reference function: RHF + Maximum number of iterations: 150 + Full symmetry point group: C2v + Computational point group: C2v + Initial density matrix: MOREAD + SCF convergence tolerance: 10**(- 9) + DIIS convergence acceleration: ON + Latest start for DIIS: 8 + DIIS order: 6 + + Memory information: 341888 words required. + Fock matrices are constructed from AO integral file. + @GETMEM-I, Allocated 2 MB of main memory. + Initialization and symmetry analysis required 0.001 seconds. + + @INITGES-I, Occupancies from core Hamiltonian: + + Alpha population by irrep: 9 2 6 1 + Beta population by irrep: 9 2 6 1 + + + total no. of electrons in initial guess : 0.000000000000000E+000 + -------------------------------------------------------------------- + Iteration Total Energy Largest Density Difference + -------------------------------------------------------------------- + 0 161.108229778788910 0.0000000000D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 1 -196.263249175407992 0.1098182460D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 2 -179.889864626336106 0.1675780025D+02 + current occupation vector + 9 1 7 1 + 9 1 7 1 + 3 -180.580457259652945 0.1772125138D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 4 -162.771013663095033 0.1566999730D+02 + current occupation vector + 8 2 7 1 + 8 2 7 1 + 5 -169.943224465301597 0.1454729382D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 6 -160.269967975315780 0.1454634919D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 7 -168.828658617537684 0.1395077743D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 8 -160.232275948463297 0.1395068492D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 9 -209.746508446745025 0.5520995458D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 10 -228.180230304181549 0.2015536648D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 11 -228.454713327495682 0.6531384936D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 12 -228.600329261507483 0.3196758217D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 13 -228.637509917234041 0.7498321731D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 14 -228.642938164599826 0.5250342791D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 15 -228.643241982659248 0.9795506231D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 16 -228.643308522550143 0.3593200395D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 17 -228.643312517846056 0.1473098013D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 18 -228.643312570337258 0.1244041229D-03 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 19 -228.643312572356052 0.2423484470D-04 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 20 -228.643312572476049 0.5414751593D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 21 -228.643312572485769 0.2003507219D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 22 -228.643312572485598 0.8833300562D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 23 -228.643312572484461 0.3139636784D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 24 -228.643312572486110 0.4136764657D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 25 -228.643312572485542 0.9839839787D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 26 -228.643312572486622 0.1838835018D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 27 -228.643312572484007 0.3228508794D-08 + current occupation vector + 9 2 6 1 + 9 2 6 1 + + SCF has converged. + + Density matrix saved to file den.dat + total electron number: 36.0000000000000 + E(SCF)= -228.643312572484575 0.7981584282D-09 + + Eigenvector printing suppressed. + + @PUTMOS-I, Writing converged MOs to NEWMOS. + @PUTMOS-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTMOS-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTMOS-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTMOS-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + @PUTFOCK-I, Writing converged Fock matrix to NEWFOCK. + @PUTFOCK-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTFOCK-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + + + + ORBITAL EIGENVALUES (ALPHA) (1H = 27.2113834 eV) + + MO # E(hartree) E(eV) FULLSYM COMPSYM + ---- -------------------- -------------------- ------- --------- + 1 1 -20.6219765861 -561.1525113512 A1 A1 (1) + 2 49 -11.2892088103 -307.1949892207 B2 B2 (3) + 3 2 -11.2891634657 -307.1937553315 A1 A1 (1) + 4 3 -11.2328159068 -305.6604603025 A1 A1 (1) + 5 50 -11.2318729764 -305.6348018622 B2 B2 (3) + 6 4 -1.4574476329 -39.6591663239 A1 A1 (1) + 7 5 -1.0834872588 -29.4831872086 A1 A1 (1) + 8 51 -1.0036038078 -27.3094479952 B2 B2 (3) + 9 52 -0.8050606676 -21.9068144851 B2 B2 (3) + 10 6 -0.7793049296 -21.2059652251 A1 A1 (1) + 11 7 -0.7372159421 -20.0606656495 A1 A1 (1) + 12 36 -0.6283416633 -17.0980459063 B1 B1 (2) + 13 53 -0.6064452640 -16.5022145907 B2 B2 (3) + 14 54 -0.5741889664 -15.6244761082 B2 B2 (3) + 15 8 -0.5622006055 -15.2982562239 A1 A1 (1) + 16 9 -0.5366322238 -14.6025051862 A1 A1 (1) + 17 37 -0.3944127682 -10.7325170532 B1 B1 (2) + 18 80 -0.3173264428 -8.6348914980 A2 A2 (4) + +++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ + 19 38 0.1616454919 4.3985974562 B1 B1 (2) + 20 10 0.2028007990 5.5184902966 A1 A1 (1) + 21 55 0.2259953076 6.1496449623 B2 B2 (3) + 22 11 0.2331452351 6.3442043789 A1 A1 (1) + 23 81 0.2346526075 6.3852220682 A2 A2 (4) + 24 56 0.2409072580 6.5554197617 B2 B2 (3) + 25 12 0.3379830583 9.1969865830 A1 A1 (1) + 26 57 0.3670668300 9.9883962435 B2 B2 (3) + 27 13 0.4400792390 11.9751648999 A1 A1 (1) + 28 58 0.5035354267 13.7018955503 B2 B2 (3) + 29 14 0.5796551077 15.7732173745 A1 A1 (1) + 30 59 0.6027649445 16.4020680057 B2 B2 (3) + 31 39 0.6720867908 18.2884113425 B1 B1 (2) + 32 15 0.6949257331 18.9098905590 A1 A1 (1) + 33 60 0.7033703399 19.1396799905 B2 B2 (3) + 34 82 0.7176012567 19.5269229246 A2 A2 (4) + 35 61 0.7543801794 20.5277282917 B2 B2 (3) + 36 40 0.7622869649 20.7428828633 B1 B1 (2) + 37 16 0.7651070466 20.8196211868 A1 A1 (1) + 38 17 0.7917408050 21.5443625978 A1 A1 (1) + 39 83 0.8438632537 22.9626865338 A2 A2 (4) + 40 62 0.8844205187 24.0663058221 B2 B2 (3) + 41 18 0.9187910190 25.0015746820 A1 A1 (1) + 42 19 0.9547555380 25.9802189979 A1 A1 (1) + 43 63 0.9634112815 26.2157537519 B2 B2 (3) + 44 64 1.0592164869 28.8227459274 B2 B2 (3) + 45 41 1.0743328454 29.2340829566 B1 B1 (2) + 46 20 1.1352329173 30.8912581602 A1 A1 (1) + 47 65 1.1904894416 32.3948646279 B2 B2 (3) + 48 21 1.1908922750 32.4058262839 A1 A1 (1) + 49 42 1.2129419174 33.0058275576 B1 B1 (2) + 50 66 1.2581407748 34.2357509943 B2 B2 (3) + 51 84 1.2921641151 35.1615731515 A2 A2 (4) + 52 22 1.2994001068 35.3584744953 A1 A1 (1) + 53 43 1.3116428673 35.6916169462 B1 B1 (2) + 54 85 1.3649569984 37.1423682072 A2 A2 (4) + 55 44 1.5283489789 41.5884900335 B1 B1 (2) + 56 23 1.5439841774 42.0139454134 A1 A1 (1) + 57 67 1.5691624192 42.6990802047 B2 B2 (3) + 58 68 1.5969806595 43.4560530082 B2 B2 (3) + 59 24 1.7377154792 47.2856421455 A1 A1 (1) + 60 69 1.7438095776 47.4514709939 B2 B2 (3) + 61 86 1.7443895833 47.4672537511 A2 A2 (4) + 62 25 1.7729617500 48.2447419337 A1 A1 (1) + 63 45 1.8384391578 50.0264727818 B1 B1 (2) + 64 26 1.8727560698 50.9602834298 A1 A1 (1) + 65 46 1.9574193824 53.2640892885 B1 B1 (2) + 66 70 1.9863618073 54.0516527104 B2 B2 (3) + 67 71 2.0036624844 54.5224280672 B2 B2 (3) + 68 87 2.0489211710 55.7539795407 A2 A2 (4) + 69 27 2.0703324397 56.3366097828 A1 A1 (1) + 70 88 2.1357719213 58.1173086059 A2 A2 (4) + 71 28 2.1641427105 58.8893170284 A1 A1 (1) + 72 72 2.1880643996 59.5402592802 B2 B2 (3) + 73 47 2.1914898441 59.6334703659 B1 B1 (2) + 74 29 2.2271655184 60.6042548161 A1 A1 (1) + 75 73 2.2977715809 62.5255434529 B2 B2 (3) + 76 30 2.3793504210 64.7454165492 A1 A1 (1) + 77 89 2.5107047412 68.3197493175 A2 A2 (4) + 78 74 2.5407172731 69.1364318293 B2 B2 (3) + 79 75 2.6586433664 72.3453639681 B2 B2 (3) + 80 31 2.6718877167 72.7057610618 A1 A1 (1) + 81 32 2.8267951805 76.9210074510 A1 A1 (1) + 82 76 2.9419209269 80.0537382753 B2 B2 (3) + 83 77 2.9853767071 81.2362301695 B2 B2 (3) + 84 33 3.0013526923 81.6709588287 A1 A1 (1) + 85 48 3.2421725037 88.2239990462 B1 B1 (2) + 86 90 3.2857682253 89.4102989431 A2 A2 (4) + 87 34 3.4838249547 94.7996965407 A1 A1 (1) + 88 78 3.6959298762 100.5713648809 B2 B2 (3) + 89 79 3.7700022467 102.5869765541 B2 B2 (3) + 90 35 3.8341979240 104.3338297409 A1 A1 (1) + + + VSCF finished. + + @CHECKOUT-I, Total execution time (CPU/WALL): 3.94/ 0.86 seconds. +--executable xvscf finished with status 0 in 1.37 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvtran + @GETMEM-I, Allocated 95367 MB of main memory. + Full RHF integral transformation + The following 5 MOs will be dropped: + 1 2 3 12 13 + There are 85 active molecular orbitals. + Transformation of IIII integrals : + 1 pass through the AO integral file was required. + 325108 AO integrals were read. + 240883 MO integrals were written to HF2. + Transformation of IIJJ integrals : + 1 pass through the AO integral file was required. + 490042 AO integrals were read. + 386877 MO integrals were written to HF2. + Transformation of IJIJ integrals : + 1 pass through the AO integral file was required. + 908743 AO integrals were read. + 712509 MO integrals were written to HF2. + Transformation of IJKL integrals : + 1 pass through the AO integral file was required. + 460725 AO integrals were read. + 398112 MO integrals were written to HF2. + Summary of active molecular orbitals: +------------------------------------------------------------------------ + + Index Eigenvalue Symmetry Index Eigenvalue Symmetry +------------------------------------------------------------------------ + 1 -1.4574476 1 44 1.2129419 2 + 2 -1.0834873 1 45 1.3116429 2 + 3 -0.7793049 1 46 1.5283490 2 + 4 -0.7372159 1 47 1.8384392 2 + 5 -0.5622006 1 48 1.9574194 2 + 6 -0.5366322 1 49 2.1914898 2 + 7 -0.6283417 2 50 3.2421725 2 + 8 -0.3944128 2 51 0.2259953 3 + 9 -1.0036038 3 52 0.2409073 3 + 10 -0.8050607 3 53 0.3670668 3 + 11 -0.6064453 3 54 0.5035354 3 + 12 -0.5741890 3 55 0.6027649 3 + 13 -0.3173264 4 56 0.7033703 3 + 14 0.2028008 1 57 0.7543802 3 + 15 0.2331452 1 58 0.8844205 3 + 16 0.3379831 1 59 0.9634113 3 + 17 0.4400792 1 60 1.0592165 3 + 18 0.5796551 1 61 1.1904894 3 + 19 0.6949257 1 62 1.2581408 3 + 20 0.7651070 1 63 1.5691624 3 + 21 0.7917408 1 64 1.5969807 3 + 22 0.9187910 1 65 1.7438096 3 + 23 0.9547555 1 66 1.9863618 3 + 24 1.1352329 1 67 2.0036625 3 + 25 1.1908923 1 68 2.1880644 3 + 26 1.2994001 1 69 2.2977716 3 + 27 1.5439842 1 70 2.5407173 3 + 28 1.7377155 1 71 2.6586434 3 + 29 1.7729618 1 72 2.9419209 3 + 30 1.8727561 1 73 2.9853767 3 + 31 2.0703324 1 74 3.6959299 3 + 32 2.1641427 1 75 3.7700022 3 + 33 2.2271655 1 76 0.2346526 4 + 34 2.3793504 1 77 0.7176013 4 + 35 2.6718877 1 78 0.8438633 4 + 36 2.8267952 1 79 1.2921641 4 + 37 3.0013527 1 80 1.3649570 4 + 38 3.4838250 1 81 1.7443896 4 + 39 3.8341979 1 82 2.0489212 4 + 40 0.1616455 2 83 2.1357719 4 + 41 0.6720868 2 84 2.5107047 4 + 42 0.7622870 2 85 3.2857682 4 + 43 1.0743328 2 +------------------------------------------------------------------------ + -1.45744763288719 -1.08348725881441 -0.779304929609897 + -0.737215942115339 -0.562200605497301 -0.536632223783724 + -0.628341663300699 -0.394412768193209 -1.00360380778026 + -0.805060667553655 -0.606445264032669 -0.574188966380078 + -0.317326442801090 0.202800799044599 0.233145235052782 + 0.337983058334004 0.440079239041159 0.579655107669000 + 0.694925733138531 0.765107046589679 0.791740804983910 + 0.918791018982032 0.954755538003189 1.13523291727329 + 1.19089227502871 1.29940010677049 1.54398417735024 + 1.73771547923282 1.77296175003401 1.87275606979175 + 2.07033243972521 2.16414271052282 2.22716551838589 + 2.37935042101669 2.67188771673553 2.82679518054224 + 3.00135269229820 3.48382495469438 3.83419792398046 + 0.161645491943529 0.672086790797680 0.762286964920328 + 1.07433284544462 1.21294191744913 1.31164286730943 + 1.52834897888630 1.83843915784915 1.95741938237798 + 2.19148984413109 3.24217250366571 0.225995307622873 + 0.240907258015995 0.367066829963131 0.503535426659975 + 0.602764944529835 0.703370339875812 0.754380179426906 + 0.884420518732559 0.963411281466499 1.05921648685572 + 1.19048944155892 1.25814077480321 1.56916241916196 + 1.59698065950503 1.74380957764511 1.98636180732934 + 2.00366248439902 2.18806439955680 2.29777158087759 + 2.54071727310046 2.65864336644143 2.94192092693438 + 2.98537670707142 3.69592987620463 3.77000224671010 + 0.234652607487977 0.717601256707210 0.843863253708071 + 1.29216411509331 1.36495699837027 1.74438958333340 + 2.04892117101004 2.13577192131677 2.51070474122043 + 3.28576822533544 + @CHECKOUT-I, Total execution time (CPU/WALL): 6.97/ 0.46 seconds. +--executable xvtran finished with status 0 in 0.95 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xintprc + @GETMEM-I, Allocated 95367 MB of main memory. + Processing integrals for CCSD calculation. + @GMOIAA-I, Processing MO integrals for spin case AA. + @GMOIAA-I, Generation of integral list completed. + TYPE NUMBER + ---- -------- + PPPP 894479 + PPPH 640524 + PPHH 115497 + PHPH 63721 + PHHH 22938 + HHHH 1222 + + TOTAL 1738381 + + @FORMT2-I, Second-order MP correlation energies: + ------------------------------------------------ + E(SCF) = -228.643312572485 a.u. + E2(AA) = -0.093684343380 a.u. + E2(AB) = -0.520081687065 a.u. + E2(TOT) = -0.707450373824 a.u. + Total MP2 energy = -229.350762946309 a.u. + ------------------------------------------------ + Largest T2 amplitudes for spin case AB: + _ _ _ _ _ _ + i j a b i j a b i j a b +----------------------------------------------------------------------------- +[ 13 13 40 40]-0.06710 [ 8 8 40 40]-0.05436 [ 13 13 76 76]-0.05241 +[ 13 8 76 40]-0.04215 [ 8 13 40 76]-0.04215 [ 8 8 76 76]-0.03737 +[ 7 7 40 40]-0.03140 [ 13 7 40 76]-0.02053 [ 7 13 76 40]-0.02053 +[ 13 13 77 77]-0.01960 [ 13 13 40 42]-0.01810 [ 13 13 42 40]-0.01810 +[ 7 7 45 45]-0.01664 [ 13 13 41 41]-0.01633 [ 13 13 78 76]-0.01595 +----------------------------------------------------------------------------- + Norm of T2AB vector ( 230058 symmetry allowed elements): 0.4218925855. +----------------------------------------------------------------------------- + @CHECKOUT-I, Total execution time (CPU/WALL): 3.91/ 0.33 seconds. +--executable xintprc finished with status 0 in 0.84 seconds (walltime). + calling xncc + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xncc + @GETMEM-I, Allocated 7 MB of main memory. + +Running with 20 threads/proc + +Using DIIS to accelerate the convergence of T1 and T2 +Using immediate high-order contributions +Damping factor for T3: 0.000000 +Damping factor for T4: 0.000000 + +Transposes are coarse-threaded + +Memory limit: 93.132 GiB +Minimum memory requirement: 12.286 MiB +Compromise memory amount: 49.883 MiB +Optimal memory requirement: 112.301 MiB + +List Location Size Cached Hunks Est. Disk I/O +----------------- ---------- ----------- ------ ----- ------------- + + T_DIIS 70:0 8.787 MiB Yes - 158.166 MiB + Z_DIIS 70:1 8.787 MiB Yes - 263.610 MiB + 18 1.755 MiB Yes - 62.148 MiB + 233 52.803 MiB Yes - 792.042 MiB + 30 9.615 MiB Yes - 721.156 MiB + 16 1.755 MiB Yes - 240.463 MiB + 25 1.755 MiB Yes - 52.656 MiB + 21 1.755 MiB No - 0 B + 10 329.156 KiB Yes - 43.395 MiB + 13 60.633 KiB Yes - 909.492 KiB + F(EA) 92:0 11.891 KiB Yes - 1.045 MiB + F(EM) 93:0 2.250 KiB Yes - 135.000 KiB + F(MI) 91:0 456 B Yes - 46.758 KiB + T(AI) 90:0 2.250 KiB Yes - 609.750 KiB + T(Ab,Ij) 46 1.755 MiB Yes - 398.431 MiB + W(Mn,Ij) 53 60.633 KiB Yes - 1.776 MiB + W~(EM,bj) 56 1.755 MiB Yes - 131.640 MiB + W~(Em,Bj) 58 1.755 MiB Yes - 131.640 MiB + W~(Ij,Mb) 110 329.156 KiB Yes - 14.465 MiB + W~~(EM,bj) 76 1.755 MiB No - 0 B + W~~(Em,Bj) 78 1.755 MiB No - 0 B + Z(AI) 90:2 2.250 KiB Yes - 337.500 KiB + Z(Ab,Ij) 63 1.755 MiB Yes - 263.280 MiB + +Simulation and memory analysis took 0.077 seconds + +MP2 correlation energy: -0.707450373824291 + +Non-iterative calculation of MP2 took 0.394 cpu seconds and 0.030 walltime seconds at 0.427 Gflops/sec + +Total MP2 energy: -229.350762946308862 + +Beginning iterative solution of CCSD equations: + +It. Correlation Energy T1 Residual T2 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------- + 1 -0.710330365665595 2.59892e-02 9.89691e-03 7.860 0.765 + 2 -0.731384640061197 3.61814e-03 9.03347e-03 1.571 0.079 + 3 -0.731956756689663 6.18099e-03 3.24648e-03 1.506 0.075 + 4 -0.734581315377452 9.23994e-04 1.13972e-03 1.531 0.077 + 5 -0.734932040699374 9.96826e-04 5.56474e-04 1.481 0.074 + + A I A I A I +-------------------------- -------------------------- -------------------------- + 19 12 0.0309648177093 31 17 0.0123907907787 45 17 0.0075254680442 + 19 17 -0.0302138663118 36 17 -0.0102686992189 53 17 0.0073321925679 + 34 18 0.0234076768743 25 16 -0.0097331201041 25 15 0.0071343499057 + 51 18 0.0134092938229 27 16 -0.0091252892083 37 16 0.0067244244367 + 23 18 0.0132355667898 26 13 0.0080302966500 31 12 0.0066813522839 + + A B I J A B I J +------------------------------------ ------------------------------------ + 19 19 18 18 -0.0864840489887 23 19 12 18 -0.0263855510649 + 23 23 18 18 -0.0533861721483 19 36 18 18 -0.0238163966628 + 23 19 18 17 -0.0521565004034 36 19 18 18 -0.0238163966628 + 19 23 17 18 -0.0521565004034 23 19 18 12 -0.0208474757928 + 23 23 17 17 -0.0498991564072 19 23 12 18 -0.0208474757928 + 19 19 17 17 -0.0484235042025 19 23 18 17 -0.0189398489144 + 19 19 12 12 -0.0312865996647 23 19 17 18 -0.0189398489144 + 19 23 18 12 -0.0263855510649 + +It. Correlation Energy T1 Residual T2 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------- + 6 -0.734968831698199 2.86084e-04 1.13465e-04 1.517 0.076 + 7 -0.734971740268961 1.62289e-04 6.06563e-05 1.578 0.079 + 8 -0.734969631752116 6.77257e-05 1.63091e-05 2.199 0.111 + 9 -0.734969815111073 1.32823e-05 5.58533e-06 1.493 0.075 + 10 -0.734971505312760 8.66008e-06 1.03652e-06 1.442 0.072 + + A I A I A I +-------------------------- -------------------------- -------------------------- + 19 12 0.0311108208578 31 17 0.0123104770427 45 17 0.0075336426648 + 19 17 -0.0310751115583 36 17 -0.0104046451078 53 17 0.0073074748217 + 34 18 0.0233782910697 25 16 -0.0097813817793 25 15 0.0071704017575 + 23 18 0.0138958024463 27 16 -0.0090967931430 37 16 0.0067229138479 + 51 18 0.0133887374494 26 13 0.0079464506357 31 12 0.0066841833155 + + A B I J A B I J +------------------------------------ ------------------------------------ + 19 19 18 18 -0.0867689223810 23 19 12 18 -0.0263411202363 + 23 23 18 18 -0.0530761221864 19 36 18 18 -0.0238731069787 + 23 19 18 17 -0.0521126076824 36 19 18 18 -0.0238731069787 + 19 23 17 18 -0.0521126076824 19 23 12 18 -0.0208285247603 + 23 23 17 17 -0.0501399729337 23 19 18 12 -0.0208285247603 + 19 19 17 17 -0.0481872128411 19 23 18 17 -0.0187589163318 + 19 19 12 12 -0.0313367424144 23 19 17 18 -0.0187589163318 + 19 23 18 12 -0.0263411202363 + +It. Correlation Energy T1 Residual T2 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------- + 11 -0.734972180262170 1.72072e-06 5.59276e-07 1.560 0.078 + 12 -0.734972480248231 8.38584e-07 4.94736e-07 1.539 0.077 + 13 -0.734972635940772 2.99058e-07 2.02218e-07 1.434 0.072 + 14 -0.734972678637797 1.78596e-07 8.39001e-08 1.504 0.075 + 15 -0.734972684411973 1.00482e-07 3.34986e-08 1.495 0.075 + + A I A I A I +-------------------------- -------------------------- -------------------------- + 19 12 0.0311117997502 31 17 0.0123110161388 45 17 0.0075336096766 + 19 17 -0.0310775780577 36 17 -0.0104053838287 53 17 0.0073075977232 + 34 18 0.0233793496166 25 16 -0.0097818792076 25 15 0.0071712368041 + 23 18 0.0138989328941 27 16 -0.0090973444397 37 16 0.0067231287655 + 51 18 0.0133887634099 26 13 0.0079470196131 31 12 0.0066844421404 + + A B I J A B I J +------------------------------------ ------------------------------------ + 19 19 18 18 -0.0867703174851 23 19 12 18 -0.0263416496904 + 23 23 18 18 -0.0530767767631 19 36 18 18 -0.0238735919485 + 23 19 18 17 -0.0521127109067 36 19 18 18 -0.0238735919485 + 19 23 17 18 -0.0521127109067 19 23 12 18 -0.0208288165624 + 23 23 17 17 -0.0501411836645 23 19 18 12 -0.0208288165624 + 19 19 17 17 -0.0481870678656 19 23 18 17 -0.0187589863188 + 19 19 12 12 -0.0313378020825 23 19 17 18 -0.0187589863188 + 19 23 18 12 -0.0263416496904 + +It. Correlation Energy T1 Residual T2 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------- + 16 -0.734972685409664 2.76339e-08 1.19149e-08 1.551 0.078 + +CCSD iterations converged in 16 cycles and 1.948 seconds (0.122 s/it.) at 13.622 Gflops/sec + +Total CCSD energy: -229.378285257894248 + + @CHECKOUT-I, Total execution time (CPU/WALL): 33.76/ 2.39 seconds. +--executable xncc finished with status 0 in 5.50 seconds (walltime). + The final electronic energy is -229.378285257894248 a.u. + This computation required 14.58 seconds (walltime). diff --git a/furan/cc-pvdz/CC/fura-gs-ccsdt.out b/furan/cc-pvdz/CC/fura-gs-ccsdt.out new file mode 100644 index 0000000..e6fbb8f --- /dev/null +++ b/furan/cc-pvdz/CC/fura-gs-ccsdt.out @@ -0,0 +1,1011 @@ + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xjoda + + + ************************************************************************* + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + ************************************************************************* + + **************************************************************** + * CFOUR Coupled-Cluster techniques for Computational Chemistry * + **************************************************************** + + + Department of Chemistry Institut fuer Physikalische Chemie + University of Florida Universitaet Mainz + Gainesville, FL 32611, USA D-55099 Mainz, Germany + + Department of Chemistry Fakultaet fuer Chemie und Biowiss. + Johns Hopkins University Karlsruher Institut fuer Technologie + Baltimore, MD 21218, USA D-76131 Karlsruhe, Germany + + Department of Chemistry Department of Physical Chemistry + Southern Methodist University Eotvos Lorand University + Dallas, TX 75275, USA H-1053 Budapest, Hungary + + + Version 2.1 + + nazare074.cluster + Thu Oct 15 11:17:32 CEST 2020 + integer*8 version is running + +******************************************************************************** +* Input from ZMAT file * +******************************************************************************** +Ketene -GS +C 0.00000000 2.06365826 -0.60051250 +C 0.00000000 -2.06365826 -0.60051250 +C 0.00000000 1.35348578 1.86336416 +C 0.00000000 -1.35348578 1.86336416 +O 0.00000000 0.00000000 -2.13945332 +H 0.00000000 3.86337287 -1.53765695 +H 0.00000000 -3.86337287 -1.53765695 +H 0.00000000 2.59168789 3.47168051 +H 0.00000000 -2.59168789 3.47168051 + +*CFOUR(COORD=CARTESIAN,UNITS=BOHR + MEMORY=100,MEM_UNIT=GB,CC_PROG=NCC + FROZEN_CORE=1 + CALC=CCSDT,BASIS=PVDZ + SCF_CONV=9,CC_CONV=7,ESTATE_MAXCYC=80) + +******************************************************************************** + ------------------------------------------------------------------- + CFOUR Control Parameters + ------------------------------------------------------------------- + External Internal Value Units + Name Name + ------------------------------------------------------------------- + ABCDTYPE IABCDT STANDARD [ 0] *** + ANHARMONIC IANHAR OFF [ 0] *** + ANH_ALGORIT IANALG STANDARD [ 0] *** + ANH_DERIVAT IANDER SECOND [ 1] *** + ANH_MODE ANHMOD VIBRATION [ 0] *** + ANH_STEPSIZ ICUBST 50000 x 10-6 + ANH_SYMMETR IANHSM ABELIAN [ 0] *** + AO_LADDERS IAOLAD SINGLEPASS [ 1] *** + AV_SCF IAVSCF OFF [ 0] *** + BASIS IBASIS PVDZ [ 13] *** + BOTHVECTORS BOTHVC OFF [ 0] *** + BOX_POTENT IPIAB OFF [ 0] *** + BREIT IBREIT OFF [ 0] *** + BRUCK_CONV IBRTOL 10D- 4 *** + BRUECKNER IBRKNR OFF [ 0] *** + BUFFERSIZE IBUFFS 4096 *** + CACHE_RECS ICHREC 10 *** + CALCLEVEL ICLLVL CCSDT [ 18] *** + CCORBOPT ICCORB OFF [ 0] x 0.01 + CC_CONV ICCCNV 10D- 7 *** + CC_EXPORDER ICCEOR 5 *** + CC_EXTRAPOL ICCEXT DIIS [ 1] *** + CC_GUESS ICCGES MP2 [ 0] *** + CC_MAXCYC ICCCYC 100 cycles + CC_PROGRAM ICCPRO NCC [ 5] *** + CHARGE ICHRGE 0 *** + CHOLESKY ICHOLE OFF [ 0] *** + CIS_CONV ICISTL 5 *** + COMM_SIZE IPSIZE *** *** + CONSTANT ICONST OLD [ 1] *** + CONTINUUM ICONTU NONE [ 0] *** + CONTRACTION ICNTYP GENERAL [ 1] *** + COORDINATES ICOORD CARTESIAN [ 1] *** + CPHF_CONVER ICPHFT 10D- 16 *** + CPHF_MAXCYC ICPHFC 64 cycles + CUBIC ICUBIC OFF [ 0] *** + CURVILINEAR ICURVY OFF [ 0] *** + DBOC IDBOC OFF [ 0] *** + DCT IDCT OFF [ 0] *** + DERIV_LEV IDRLVL ZERO [ 0] *** + DEVMEM_SIZE IDVMEM ********* MByte + DIAG_MRCC IEOMST 10D- 0 *** + DIFF_TYPE IDIFTY RELAXED [ 0] *** + DIRECT IDIRCT OFF [ 0] *** + DROPMO IDRPMO NONE + ECP IECP OFF [ 0] *** + EIGENVECTOR IVEC 1 *** + EL_ANHARM IELANH OFF [ 0] *** + EOMFOLLOW IEOMSR ENERGY [ 0] *** + EOMIP IEOMIP OFF [ 0] *** + EOMLEVEL HBARFM SAME [ 0] *** + EOM_MRCC IMRCCE NEW [ 1] *** + EOM_NONIT EOMNON OFF [ 0] *** + EOM_NSING IEOMSI 10D- 0 *** + EOM_NSTATES IMRCCD DAVIDSON [ 0] *** + EOM_NTRIP IEOMTR 10D- 0 *** + EOM_ORDER IEXORD ENERGY [ 0] *** + EOM_PROPSTA IEOMST 0 *** + ESTATE_CONV IEXTOL 10D- 5 *** + ESTATE_DIAG IEXDIG ITERATIVE [ 0] *** + ESTATE_LOCK IESLOC ON [ 1] *** + ESTATE_MAXC IEXMXC 80 *** + ESTATE_PROP IEXPRP OFF [ 0] *** + EVAL_HESS IRECAL 0 # of cyc. + EXCITATION IEXCIT 0 *** + EXCITE IEXCIT NONE [ 0] *** + EXTERN_POT IEXPOT OFF [ 0] *** + FCGRADNEW IFCGNW OFF [ 0] *** + FC_FIELD IFINFC 0 x 10-6 + FD_CALTYPE IFDCAL GRADONLY [ 0] *** + FD_PROJECT IFDPRJ OFF [ 1] *** + FD_STEPSIZE IDISFD 0 10-4 bohr + FD_USEGROUP IFDGRP FULL [ 0] *** + FILE_RECSIZ IFLREC 4096 words + FINITE_PERT IFIPER 0 x 10-6 + FIXGEOM IFIXGM OFF [ 0] *** + FOCK IFOCK AO [ 1] *** + FREQ_ALGORI IVIALG STANDARD [ 0] *** + FROZEN_CORE IFROCO ON [ 1] *** + GAMMA_ABCD IGABCD STORE [ 0] *** + GAMMA_ABCI IGABCI STORE [ 0] *** + GENBAS_1 IGNBS1 0 *** + GENBAS_2 IGNBS2 0 *** + GENBAS_3 IGNBS3 0 *** + GENBAS_4 IGNBS4 0 *** + GEO_CONV ICONTL 5 H/bohr + GEO_MAXCYC IOPTCY 50 *** + GEO_MAXSTEP IMXSTP 300 millibohr + GEO_METHOD INR SINGLE_POINT[ 5] *** + GIAO IGIAO OFF [ 1] *** + GIMIC IGIMIC OFF [ 0] *** + GRID IGRID OFF [ 0] *** + GRID_ALGO IGALGO SERIAL [ 0] *** + GUESS IGUESS MOREAD [ 0] *** + HBAR IHBAR OFF [ 0] *** + HESS_TYPE IHESTP SCF [ 0] *** + HF2_FILE IHF2Fl USE [ 1] *** + HFSTABILITY ISTABL OFF [ 0] *** + INCORE INCORE OFF [ 0] *** + INPUT_MRCC IMRCC ON [ 1] *** + INTEGRALS INTTYP VMOL [ 1] *** + JODA_PRINT IJPRNT 0 *** + KEYWORD_OUT IDMPKW NO [ 0] *** + LINDEP_TOL ILINDP 8 *** + LINEQ_CONV IZTACN 10D- 7 cycles + LINEQ_EXPOR ILMAXD 5 *** + LINEQ_MAXCY ILMAXC 100 *** + LINEQ_TYPE ILTYPE DIIS [ 1] *** + LOCK_ORBOCC ILOCOC OFF [ 0] *** + MEMORY_SIZE IMEMSZ ********* words + MEM_UNIT IMEMU GB [ 3] *** + MRCC IMRCCC OFF [ 0] *** + MULTIPLICTY IMULTP 1 *** + NACOUPLING IVCOUP OFF [ 0] *** + NEGEVAL IDIE ABORT [ 0] *** + NEWNORM INEWNO OFF [ 0] *** + NON-HF INONHF OFF [ 0] *** + NTOP_TAMP ITOPT2 15 *** + NUC_MODEL INUCMO POINT [ 0] *** + OCCUPATION IOCCU ESTIMATED BY SCF + OPEN-SHELL IOPEN SPIN-ORBITAL[ 0] *** + OPTVIB IOPTVB OFF [ 0] *** + ORBITALS IORBTP STANDARD [ 0] *** + PARALLEL IPARAL ON [ 1] *** + PARA_INT IPINTS ON [ 1] *** + PARA_PRINT IPPRIN 0 *** + PERT_ORB IPTORB STANDARD [ 0] *** + POINTS IGRDFD 0 *** + PRINT IPRNT 0 *** + PROPS IPROPS OFF [ 0] *** + PROP_INTEGR IINTYP INTERNAL [ 0] *** + PSI IPSI OFF [ 0] *** + QC_ALG IQCALG FLM [ 0] *** + QC_LINALG IQCLIN TRIDIAG [ 2] *** + QC_MAXCYC IQCMAX 10D-100 cycles + QC_MAXSCFCY IQCMSC 10D- 15 cycles + QC_RTRUST IQCRTR 10D- 0 x 10-3 + QC_SKIPSCF IQCSKI OFF [ 0] *** + QC_START IQCSTA 10D- 1 *** + QRHFGUESS IQGUES OFF [ 0] *** + QUARTIC IQUART OFF [ 0] *** + RAMAN_INT IRAMIN OFF [ 0] *** + RAMAN_ORB IRAMRE UNRELAXED [ 0] *** + RDO IRDOFM OFF [ 0] *** + REDUCE_REPR REDREP Ir [ 0] *** + REFERENCE IREFNC RHF [ 0] *** + RELATIVIST IRELAT OFF [ 0] *** + RELAX_DENS IRDENS OFF [ 0] *** + RESET_FLAGS IRESET OFF [ 0] *** + RESTART_CC ICCRES OFF [ 0] *** + ROT_EVEC ROTVEC 0 *** + SAVE_INTS ISVINT OFF [ 0] *** + SCALE_ON ISTCRT 0 *** + SCF_CONV ISCFCV 10D- 9 *** + SCF_DAMPING IDAMP 0 x 10-3 + SCF_EXPORDE IRPPOR 6 *** + SCF_EXPSTAR IRPPLS 8 *** + SCF_EXTRAPO IRPP ON [ 1] *** + SCF_MAXCYC ISCFCY 150 cycles + SCF_NOSTOP ISCFST OFF [ 0] *** + SCF_PRINT ISCFPR 0 *** + SCF_PROG ISCFPR SCF [ 0] *** + SD_FIELD IFINSD 0 x 10-6 + SOPERT IPERSO OFF [ 0] *** + SPHERICAL IDFGHI ON [ 1] *** + SPINORBIT ISOCAL OFF [ 0] *** + SPINROTATIO ISRCON OFF [ 0] *** + SPIN_FLIP ISPFLP OFF [ 0] *** + SPIN_ORBIT ISPORB OFF [ 0] *** + SPIN_SCAL ISCSMP OFF [ 0] *** + STEEPSCALE ISTPSC 1000 x 10-3 + SUBGROUP ISUBGP DEFAULT [ 0] *** + SUBGRPAXIS ISBXYZ X [ 0] *** + SYMMETRY ISYM ON [ 0] *** + SYM_CHECK ISYMCK OVERRIDE [ 1] *** + T3_EXTRAPOL IT3EXT OFF [ 0] *** + T4_EXTRAPOL IT4EXP OFF [ 0] *** + TAMP_SUM IEVERY 5 *** + TESTSUITE ITESTS OFF [ 0] *** + THERMOCH ITHERM OFF [ 0] *** + TOL_CHOLESK ITOLCH 10D- 4 *** + TRANGRAD IRESRM OFF [ 0] *** + TRANS_INV ITRAIN USE [ 0] *** + TREAT_PERT ITREAT SIMULTANEOUS[ 0] *** + TRIP_ALGORI ITRALG NORMAL [ 0] *** + UIJ_THRESHO IUIJTH 1 *** + UNITS IUNITS BOHR [ 1] *** + UNOS IUNOS OFF [ 0] *** + UPDATE_HESS IHUPDT ON [ 1] *** + VIBPHASE ISETPH STANDARD [ 0] *** + VIBRATION IVIB NO [ 0] *** + VIB_ALGORIT IGEALG STANDARD [ 0] *** + VNATORB IVNORB OFF [ 0] *** + VTRAN IVTRAN FULL/PARTIAL[ 0] *** + XFIELD IXEFLD 0 x 10-6 + XFORM_TOL IXFTOL 10D- 11 *** + YFIELD IYEFLD 0 x 10-6 + ZFIELD IZEFLD 0 x 10-6 + ZSCALE_EXP IZEXPS OFF [ 0] *** + ------------------------------------------------------------------- + @GETXYZ-I, 9 atoms read from ZMAT. + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 +******************************************************************************** + The full molecular point group is C2v . + The largest Abelian subgroup of the full molecular point group is C2v . + The computational point group is C2v . +******************************************************************************** + + + ---------------------------------------------------------------- + Coordinates used in calculation (QCOMP) + ---------------------------------------------------------------- + Z-matrix Atomic Coordinates (in bohr) + Symbol Number X Y Z + ---------------------------------------------------------------- + C 6 0.00000000 -2.06365826 0.60031230 + C 6 0.00000000 2.06365826 0.60031230 + C 6 0.00000000 -1.35348578 -1.86356436 + C 6 0.00000000 1.35348578 -1.86356436 + O 8 0.00000000 0.00000000 2.13925312 + H 1 0.00000000 -3.86337287 1.53745675 + H 1 0.00000000 3.86337287 1.53745675 + H 1 0.00000000 -2.59168789 -3.47188071 + H 1 0.00000000 2.59168789 -3.47188071 + ---------------------------------------------------------------- + + Interatomic distance matrix (Angstroms) + + C C C C O + [ 1] [ 2] [ 3] [ 4] [ 5] + C [ 1] 0.00000 + C [ 2] 2.18408 0.00000 + C [ 3] 1.35691 2.22931 0.00000 + C [ 4] 2.22931 1.35691 1.43247 0.00000 + O [ 5] 1.36226 1.36226 2.23601 2.23601 0.00000 + H [ 6] 1.07375 3.17541 2.23677 3.29549 2.06906 + H [ 7] 3.17541 1.07375 3.29549 2.23677 2.06906 + H [ 8] 2.17295 3.27299 1.07409 2.25451 3.27071 + H [ 9] 3.27299 2.17295 2.25451 1.07409 3.27071 + + H H H H + [ 6] [ 7] [ 8] [ 9] + H [ 6] 0.00000 + H [ 7] 4.08882 0.00000 + H [ 8] 2.73491 4.32378 0.00000 + H [ 9] 4.32378 2.73491 2.74292 0.00000 + rotcon2 + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 + There are 5 frozen-core orbitals. + There are 90 basis functions. + @GEOPT-W, Archive file not created for single-point calculation. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.12/ 1.31 seconds. +--executable xjoda finished with status 0 in 1.79 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol + SERIAL VERSION OF MOLECULE STARTED +******************************************************************************** + INPUT FROM MOL FILE +******************************************************************************** +INTGRL 1 0 1 0 0 0 0 0 0 + *** CFOUR Program System (Release V0.1) *** +Ketene -GS + 5 2 X Y 0.10E-08 0 0 + 9999.00 3.00 + 6.00000000 1 3 1 1 1 +C #1 0.000000000000000 -2.063658260000000 0.600312302999175 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 6.00000000 1 3 1 1 1 +C #2 0.000000000000000 -1.353485780000000 -1.863564357000825 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 8.00000000 1 3 1 1 1 +O #3 0.000000000000000 0.000000000000000 2.139253122999175 + 9 3 + 11720.0000000000 7.100000000000000E-004 -1.600000000000000E-004 + 0.000000000000000E+000 + 1759.00000000000 5.470000000000000E-003 -1.263000000000000E-003 + 0.000000000000000E+000 + 400.800000000000 2.783700000000000E-002 -6.267000000000000E-003 + 0.000000000000000E+000 + 113.700000000000 0.104800000000000 -2.571600000000000E-002 + 0.000000000000000E+000 + 37.0300000000000 0.283062000000000 -7.092400000000000E-002 + 0.000000000000000E+000 + 13.2700000000000 0.448719000000000 -0.165411000000000 + 0.000000000000000E+000 + 5.02500000000000 0.270952000000000 -0.116955000000000 + 0.000000000000000E+000 + 1.01300000000000 1.545800000000000E-002 0.557368000000000 + 0.000000000000000E+000 + 0.302300000000000 -2.585000000000000E-003 0.572759000000000 + 1.00000000000000 + 4 2 + 17.7000000000000 4.301800000000000E-002 0.000000000000000E+000 + 3.85400000000000 0.228913000000000 0.000000000000000E+000 + 1.04600000000000 0.508728000000000 0.000000000000000E+000 + 0.275300000000000 0.460531000000000 1.00000000000000 + 1 1 + 1.18500000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #4 0.000000000000000 -3.863372870000000 1.537456752999175 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #5 0.000000000000000 -2.591687890000000 -3.471880707000825 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 +FINISH + +******************************************************************************** + ONE- AND TWO-ELECTRON INTEGRALS OVER SYMMETRY-ADAPTED AOS ARE CALCULATED. + + SPHERICAL HARMONICS ARE USED. + + INTEGRALS LESS THAN 0.10E-13 ARE NEGLECTED. + + NUCLEAR REPULSION ENERGY : 161.1082297788 A.U. + @MOLECU-I, ONE ELECTRON INTEGRALS (CPU/WALL): 0.02/ 0.03 SECONDS. + @TWOEL-I, 325108 INTEGRALS OF SYMMETRY TYPE I I I I + @TWOEL-I, 908743 INTEGRALS OF SYMMETRY TYPE I J I J + @TWOEL-I, 490042 INTEGRALS OF SYMMETRY TYPE I I J J + @TWOEL-I, 460725 INTEGRALS OF SYMMETRY TYPE I J K L + @TWOEL-I, TOTAL NUMBER OF 2-E INTEGRALS 2184618. + @MOLECU-I, TWO ELECTRON INTEGRALS (CPU/WALL): 1.41/ 1.41 SECONDS. + @CHECKOUT-I, Total execution time (CPU/WALL): 1.44/ 1.46 seconds. + +Running with 20 threads/proc + +--executable xvmol finished with status 0 in 1.93 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol2ja + @GETMEM-I, Allocated 95367 MB of main memory. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.22/ 0.04 seconds. +--executable xvmol2ja finished with status 0 in 0.51 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvscf + There are 90 functions in the AO basis. + + There are 4 irreducible representations. + + Irrep # of functions + 1 35 + 2 13 + 3 31 + 4 11 + + + Parameters for SCF calculation: + SCF reference function: RHF + Maximum number of iterations: 150 + Full symmetry point group: C2v + Computational point group: C2v + Initial density matrix: MOREAD + SCF convergence tolerance: 10**(- 9) + DIIS convergence acceleration: ON + Latest start for DIIS: 8 + DIIS order: 6 + + Memory information: 341888 words required. + Fock matrices are constructed from AO integral file. + @GETMEM-I, Allocated 2 MB of main memory. + Initialization and symmetry analysis required 0.001 seconds. + + @INITGES-I, Occupancies from core Hamiltonian: + + Alpha population by irrep: 9 2 6 1 + Beta population by irrep: 9 2 6 1 + + + total no. of electrons in initial guess : 0.000000000000000E+000 + -------------------------------------------------------------------- + Iteration Total Energy Largest Density Difference + -------------------------------------------------------------------- + 0 161.108229778788910 0.0000000000D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 1 -196.263249175407992 0.1098182460D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 2 -179.889864626336106 0.1675780025D+02 + current occupation vector + 9 1 7 1 + 9 1 7 1 + 3 -180.580457259652945 0.1772125138D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 4 -162.771013663095033 0.1566999730D+02 + current occupation vector + 8 2 7 1 + 8 2 7 1 + 5 -169.943224465301597 0.1454729382D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 6 -160.269967975315780 0.1454634919D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 7 -168.828658617537684 0.1395077743D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 8 -160.232275948463297 0.1395068492D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 9 -209.746508446745025 0.5520995458D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 10 -228.180230304181549 0.2015536648D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 11 -228.454713327495682 0.6531384936D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 12 -228.600329261507483 0.3196758217D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 13 -228.637509917234041 0.7498321731D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 14 -228.642938164599826 0.5250342791D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 15 -228.643241982659248 0.9795506231D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 16 -228.643308522550143 0.3593200395D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 17 -228.643312517846056 0.1473098013D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 18 -228.643312570337258 0.1244041229D-03 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 19 -228.643312572356052 0.2423484470D-04 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 20 -228.643312572476049 0.5414751593D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 21 -228.643312572485769 0.2003507219D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 22 -228.643312572485598 0.8833300562D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 23 -228.643312572484461 0.3139636784D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 24 -228.643312572486110 0.4136764657D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 25 -228.643312572485542 0.9839839787D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 26 -228.643312572486622 0.1838835018D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 27 -228.643312572484007 0.3228508794D-08 + current occupation vector + 9 2 6 1 + 9 2 6 1 + + SCF has converged. + + Density matrix saved to file den.dat + total electron number: 36.0000000000000 + E(SCF)= -228.643312572484575 0.7981584282D-09 + + Eigenvector printing suppressed. + + @PUTMOS-I, Writing converged MOs to NEWMOS. + @PUTMOS-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTMOS-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTMOS-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTMOS-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + @PUTFOCK-I, Writing converged Fock matrix to NEWFOCK. + @PUTFOCK-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTFOCK-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + + + + ORBITAL EIGENVALUES (ALPHA) (1H = 27.2113834 eV) + + MO # E(hartree) E(eV) FULLSYM COMPSYM + ---- -------------------- -------------------- ------- --------- + 1 1 -20.6219765861 -561.1525113512 A1 A1 (1) + 2 49 -11.2892088103 -307.1949892207 B2 B2 (3) + 3 2 -11.2891634657 -307.1937553315 A1 A1 (1) + 4 3 -11.2328159068 -305.6604603025 A1 A1 (1) + 5 50 -11.2318729764 -305.6348018622 B2 B2 (3) + 6 4 -1.4574476329 -39.6591663239 A1 A1 (1) + 7 5 -1.0834872588 -29.4831872086 A1 A1 (1) + 8 51 -1.0036038078 -27.3094479952 B2 B2 (3) + 9 52 -0.8050606676 -21.9068144851 B2 B2 (3) + 10 6 -0.7793049296 -21.2059652251 A1 A1 (1) + 11 7 -0.7372159421 -20.0606656495 A1 A1 (1) + 12 36 -0.6283416633 -17.0980459063 B1 B1 (2) + 13 53 -0.6064452640 -16.5022145907 B2 B2 (3) + 14 54 -0.5741889664 -15.6244761082 B2 B2 (3) + 15 8 -0.5622006055 -15.2982562239 A1 A1 (1) + 16 9 -0.5366322238 -14.6025051862 A1 A1 (1) + 17 37 -0.3944127682 -10.7325170532 B1 B1 (2) + 18 80 -0.3173264428 -8.6348914980 A2 A2 (4) + +++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ + 19 38 0.1616454919 4.3985974562 B1 B1 (2) + 20 10 0.2028007990 5.5184902966 A1 A1 (1) + 21 55 0.2259953076 6.1496449623 B2 B2 (3) + 22 11 0.2331452351 6.3442043789 A1 A1 (1) + 23 81 0.2346526075 6.3852220682 A2 A2 (4) + 24 56 0.2409072580 6.5554197617 B2 B2 (3) + 25 12 0.3379830583 9.1969865830 A1 A1 (1) + 26 57 0.3670668300 9.9883962435 B2 B2 (3) + 27 13 0.4400792390 11.9751648999 A1 A1 (1) + 28 58 0.5035354267 13.7018955503 B2 B2 (3) + 29 14 0.5796551077 15.7732173745 A1 A1 (1) + 30 59 0.6027649445 16.4020680057 B2 B2 (3) + 31 39 0.6720867908 18.2884113425 B1 B1 (2) + 32 15 0.6949257331 18.9098905590 A1 A1 (1) + 33 60 0.7033703399 19.1396799905 B2 B2 (3) + 34 82 0.7176012567 19.5269229246 A2 A2 (4) + 35 61 0.7543801794 20.5277282917 B2 B2 (3) + 36 40 0.7622869649 20.7428828633 B1 B1 (2) + 37 16 0.7651070466 20.8196211868 A1 A1 (1) + 38 17 0.7917408050 21.5443625978 A1 A1 (1) + 39 83 0.8438632537 22.9626865338 A2 A2 (4) + 40 62 0.8844205187 24.0663058221 B2 B2 (3) + 41 18 0.9187910190 25.0015746820 A1 A1 (1) + 42 19 0.9547555380 25.9802189979 A1 A1 (1) + 43 63 0.9634112815 26.2157537519 B2 B2 (3) + 44 64 1.0592164869 28.8227459274 B2 B2 (3) + 45 41 1.0743328454 29.2340829566 B1 B1 (2) + 46 20 1.1352329173 30.8912581602 A1 A1 (1) + 47 65 1.1904894416 32.3948646279 B2 B2 (3) + 48 21 1.1908922750 32.4058262839 A1 A1 (1) + 49 42 1.2129419174 33.0058275576 B1 B1 (2) + 50 66 1.2581407748 34.2357509943 B2 B2 (3) + 51 84 1.2921641151 35.1615731515 A2 A2 (4) + 52 22 1.2994001068 35.3584744953 A1 A1 (1) + 53 43 1.3116428673 35.6916169462 B1 B1 (2) + 54 85 1.3649569984 37.1423682072 A2 A2 (4) + 55 44 1.5283489789 41.5884900335 B1 B1 (2) + 56 23 1.5439841774 42.0139454134 A1 A1 (1) + 57 67 1.5691624192 42.6990802047 B2 B2 (3) + 58 68 1.5969806595 43.4560530082 B2 B2 (3) + 59 24 1.7377154792 47.2856421455 A1 A1 (1) + 60 69 1.7438095776 47.4514709939 B2 B2 (3) + 61 86 1.7443895833 47.4672537511 A2 A2 (4) + 62 25 1.7729617500 48.2447419337 A1 A1 (1) + 63 45 1.8384391578 50.0264727818 B1 B1 (2) + 64 26 1.8727560698 50.9602834298 A1 A1 (1) + 65 46 1.9574193824 53.2640892885 B1 B1 (2) + 66 70 1.9863618073 54.0516527104 B2 B2 (3) + 67 71 2.0036624844 54.5224280672 B2 B2 (3) + 68 87 2.0489211710 55.7539795407 A2 A2 (4) + 69 27 2.0703324397 56.3366097828 A1 A1 (1) + 70 88 2.1357719213 58.1173086059 A2 A2 (4) + 71 28 2.1641427105 58.8893170284 A1 A1 (1) + 72 72 2.1880643996 59.5402592802 B2 B2 (3) + 73 47 2.1914898441 59.6334703659 B1 B1 (2) + 74 29 2.2271655184 60.6042548161 A1 A1 (1) + 75 73 2.2977715809 62.5255434529 B2 B2 (3) + 76 30 2.3793504210 64.7454165492 A1 A1 (1) + 77 89 2.5107047412 68.3197493175 A2 A2 (4) + 78 74 2.5407172731 69.1364318293 B2 B2 (3) + 79 75 2.6586433664 72.3453639681 B2 B2 (3) + 80 31 2.6718877167 72.7057610618 A1 A1 (1) + 81 32 2.8267951805 76.9210074510 A1 A1 (1) + 82 76 2.9419209269 80.0537382753 B2 B2 (3) + 83 77 2.9853767071 81.2362301695 B2 B2 (3) + 84 33 3.0013526923 81.6709588287 A1 A1 (1) + 85 48 3.2421725037 88.2239990462 B1 B1 (2) + 86 90 3.2857682253 89.4102989431 A2 A2 (4) + 87 34 3.4838249547 94.7996965407 A1 A1 (1) + 88 78 3.6959298762 100.5713648809 B2 B2 (3) + 89 79 3.7700022467 102.5869765541 B2 B2 (3) + 90 35 3.8341979240 104.3338297409 A1 A1 (1) + + + VSCF finished. + + @CHECKOUT-I, Total execution time (CPU/WALL): 4.67/ 0.87 seconds. +--executable xvscf finished with status 0 in 1.34 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvtran + @GETMEM-I, Allocated 95367 MB of main memory. + Full RHF integral transformation + The following 5 MOs will be dropped: + 1 2 3 12 13 + There are 85 active molecular orbitals. + Transformation of IIII integrals : + 1 pass through the AO integral file was required. + 325108 AO integrals were read. + 240883 MO integrals were written to HF2. + Transformation of IIJJ integrals : + 1 pass through the AO integral file was required. + 490042 AO integrals were read. + 386877 MO integrals were written to HF2. + Transformation of IJIJ integrals : + 1 pass through the AO integral file was required. + 908743 AO integrals were read. + 712509 MO integrals were written to HF2. + Transformation of IJKL integrals : + 1 pass through the AO integral file was required. + 460725 AO integrals were read. + 398112 MO integrals were written to HF2. + Summary of active molecular orbitals: +------------------------------------------------------------------------ + + Index Eigenvalue Symmetry Index Eigenvalue Symmetry +------------------------------------------------------------------------ + 1 -1.4574476 1 44 1.2129419 2 + 2 -1.0834873 1 45 1.3116429 2 + 3 -0.7793049 1 46 1.5283490 2 + 4 -0.7372159 1 47 1.8384392 2 + 5 -0.5622006 1 48 1.9574194 2 + 6 -0.5366322 1 49 2.1914898 2 + 7 -0.6283417 2 50 3.2421725 2 + 8 -0.3944128 2 51 0.2259953 3 + 9 -1.0036038 3 52 0.2409073 3 + 10 -0.8050607 3 53 0.3670668 3 + 11 -0.6064453 3 54 0.5035354 3 + 12 -0.5741890 3 55 0.6027649 3 + 13 -0.3173264 4 56 0.7033703 3 + 14 0.2028008 1 57 0.7543802 3 + 15 0.2331452 1 58 0.8844205 3 + 16 0.3379831 1 59 0.9634113 3 + 17 0.4400792 1 60 1.0592165 3 + 18 0.5796551 1 61 1.1904894 3 + 19 0.6949257 1 62 1.2581408 3 + 20 0.7651070 1 63 1.5691624 3 + 21 0.7917408 1 64 1.5969807 3 + 22 0.9187910 1 65 1.7438096 3 + 23 0.9547555 1 66 1.9863618 3 + 24 1.1352329 1 67 2.0036625 3 + 25 1.1908923 1 68 2.1880644 3 + 26 1.2994001 1 69 2.2977716 3 + 27 1.5439842 1 70 2.5407173 3 + 28 1.7377155 1 71 2.6586434 3 + 29 1.7729618 1 72 2.9419209 3 + 30 1.8727561 1 73 2.9853767 3 + 31 2.0703324 1 74 3.6959299 3 + 32 2.1641427 1 75 3.7700022 3 + 33 2.2271655 1 76 0.2346526 4 + 34 2.3793504 1 77 0.7176013 4 + 35 2.6718877 1 78 0.8438633 4 + 36 2.8267952 1 79 1.2921641 4 + 37 3.0013527 1 80 1.3649570 4 + 38 3.4838250 1 81 1.7443896 4 + 39 3.8341979 1 82 2.0489212 4 + 40 0.1616455 2 83 2.1357719 4 + 41 0.6720868 2 84 2.5107047 4 + 42 0.7622870 2 85 3.2857682 4 + 43 1.0743328 2 +------------------------------------------------------------------------ + -1.45744763288719 -1.08348725881441 -0.779304929609897 + -0.737215942115339 -0.562200605497301 -0.536632223783724 + -0.628341663300699 -0.394412768193209 -1.00360380778026 + -0.805060667553655 -0.606445264032669 -0.574188966380078 + -0.317326442801090 0.202800799044599 0.233145235052782 + 0.337983058334004 0.440079239041159 0.579655107669000 + 0.694925733138531 0.765107046589679 0.791740804983910 + 0.918791018982032 0.954755538003189 1.13523291727329 + 1.19089227502871 1.29940010677049 1.54398417735024 + 1.73771547923282 1.77296175003401 1.87275606979175 + 2.07033243972521 2.16414271052282 2.22716551838589 + 2.37935042101669 2.67188771673553 2.82679518054224 + 3.00135269229820 3.48382495469438 3.83419792398046 + 0.161645491943529 0.672086790797680 0.762286964920328 + 1.07433284544462 1.21294191744913 1.31164286730943 + 1.52834897888630 1.83843915784915 1.95741938237798 + 2.19148984413109 3.24217250366571 0.225995307622873 + 0.240907258015995 0.367066829963131 0.503535426659975 + 0.602764944529835 0.703370339875812 0.754380179426906 + 0.884420518732559 0.963411281466499 1.05921648685572 + 1.19048944155892 1.25814077480321 1.56916241916196 + 1.59698065950503 1.74380957764511 1.98636180732934 + 2.00366248439902 2.18806439955680 2.29777158087759 + 2.54071727310046 2.65864336644143 2.94192092693438 + 2.98537670707142 3.69592987620463 3.77000224671010 + 0.234652607487977 0.717601256707210 0.843863253708071 + 1.29216411509331 1.36495699837027 1.74438958333340 + 2.04892117101004 2.13577192131677 2.51070474122043 + 3.28576822533544 + @CHECKOUT-I, Total execution time (CPU/WALL): 6.92/ 0.47 seconds. +--executable xvtran finished with status 0 in 0.95 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xintprc + @GETMEM-I, Allocated 95367 MB of main memory. + @GMOIAA-I, Processing MO integrals for spin case AA. + @GMOIAA-I, Generation of integral list completed. + TYPE NUMBER + ---- -------- + PPPP 894479 + PPPH 640524 + PPHH 115497 + PHPH 63721 + PHHH 22938 + HHHH 1222 + + TOTAL 1738381 + + @FORMT2-I, Second-order MP correlation energies: + ------------------------------------------------ + E(SCF) = -228.643312572485 a.u. + E2(AA) = -0.093684343380 a.u. + E2(AB) = -0.520081687065 a.u. + E2(TOT) = -0.707450373824 a.u. + Total MP2 energy = -229.350762946309 a.u. + ------------------------------------------------ + Largest T2 amplitudes for spin case AB: + _ _ _ _ _ _ + i j a b i j a b i j a b +----------------------------------------------------------------------------- +[ 13 13 40 40]-0.06710 [ 8 8 40 40]-0.05436 [ 13 13 76 76]-0.05241 +[ 13 8 76 40]-0.04215 [ 8 13 40 76]-0.04215 [ 8 8 76 76]-0.03737 +[ 7 7 40 40]-0.03140 [ 13 7 40 76]-0.02053 [ 7 13 76 40]-0.02053 +[ 13 13 77 77]-0.01960 [ 13 13 40 42]-0.01810 [ 13 13 42 40]-0.01810 +[ 7 7 45 45]-0.01664 [ 13 13 41 41]-0.01633 [ 13 13 78 76]-0.01595 +----------------------------------------------------------------------------- + Norm of T2AB vector ( 230058 symmetry allowed elements): 0.4218925855. +----------------------------------------------------------------------------- + @CHECKOUT-I, Total execution time (CPU/WALL): 4.17/ 0.34 seconds. +--executable xintprc finished with status 0 in 0.81 seconds (walltime). + calling xncc + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xncc + @GETMEM-I, Allocated 7 MB of main memory. + +Running with 20 threads/proc + +Using DIIS to accelerate the convergence of T1 and T2 +Using immediate high-order contributions +Performing 3 CCSD sub-iterations +Damping factor for T3: 0.000000 +Damping factor for T4: 0.000000 + +Transposes are coarse-threaded + +Memory limit: 93.132 GiB +Minimum memory requirement: 68.171 MiB +Compromise memory amount: 715.873 MiB +Optimal memory requirement: 822.194 MiB + +List Location Size Cached Hunks Est. Disk I/O +----------------- ---------- ----------- ------ ----- ------------- + + T_DIIS 70:0 8.787 MiB Yes - 158.166 MiB + Z_DIIS 70:1 8.787 MiB Yes - 263.610 MiB + 18 1.755 MiB Yes - 274.921 MiB + 233 52.803 MiB Yes - 51.050 GiB + 30 9.615 MiB Yes - 4.789 GiB + 16 1.755 MiB Yes - 1.418 GiB + 25 1.755 MiB Yes - 236.952 MiB + 21 1.755 MiB No - 0 B + 10 329.156 KiB Yes - 221.795 MiB + 13 60.633 KiB Yes - 3.553 MiB + F(EA) 92:0 11.891 KiB Yes - 4.703 MiB + F(EM) 93:0 2.250 KiB Yes - 675.000 KiB + F(MI) 91:0 456 B Yes - 220.430 KiB + Q(AI) 190:2 2.250 KiB Yes - 405.000 KiB + Q(Ab,Ij) 50 1.755 MiB Yes - 947.810 MiB + T(AI) 90:0 2.250 KiB Yes - 2.375 MiB + T(Ab,Ij) 46 1.755 MiB Yes - 1.777 GiB + W(Mn,Ij) 53 60.633 KiB Yes - 13.323 MiB + W~(Ab,Ej) 130 9.615 MiB Yes - 4.731 GiB + W~(EM,bj) 56 1.755 MiB Yes - 895.154 MiB + W~(Em,Bj) 58 1.755 MiB Yes - 1000.466 MiB + W~(Ij,Mb) 110 329.156 KiB Yes - 96.432 MiB + W~~(Ab,Ej) 169 9.615 MiB Yes - 1.972 GiB + W~~(EM,bj) 76 1.755 MiB Yes - 210.624 MiB + W~~(Em,Bj) 78 1.755 MiB Yes - 210.624 MiB + W~~(Ij,Mb) 165 329.156 KiB Yes - 67.503 MiB + Z(AI) 90:2 2.250 KiB Yes - 1.022 MiB + Z(Ab,Ij) 63 1.755 MiB Yes - 816.170 MiB + T(abc,ijk) T3FILE 319.713 MiB Yes 1 14.050 GiB + Z(abc,ijk) Z3FILE 319.713 MiB Yes 1 14.050 GiB + +Simulation and memory analysis took 2.716 seconds + +MP2 correlation energy: -0.707450373824291 + +Non-iterative calculation of MP2 took 0.089 cpu seconds and 0.005 walltime seconds at 2.822 Gflops/sec + +Total MP2 energy: -229.350762946308862 + +Beginning iterative solution of CCSDT equations: + +It. Correlation Energy T1 Residual T2 Residual T3 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------------------- + 1 -0.761396515712305 5.32054e-03 1.23577e-02 1.50483e-03 53.963 2.710 + 2 -0.763231024720669 2.84291e-04 3.16802e-03 3.06462e-04 166.297 8.330 + 3 -0.764056715235343 1.05657e-04 1.02652e-03 1.27851e-04 163.458 8.187 + 4 -0.764248713424053 3.36063e-05 3.40254e-04 4.52491e-05 164.833 8.283 + 5 -0.764306507492691 1.62126e-05 1.18592e-04 1.81390e-05 163.320 8.185 + + A I A I A I +-------------------------- -------------------------- -------------------------- + 19 17 -0.0307453101979 31 17 0.0115710690035 25 15 0.0075575670022 + 19 12 0.0293730023218 36 17 -0.0108277579830 45 17 0.0074421235645 + 34 18 0.0227360659951 25 16 -0.0102013312375 21 14 -0.0074114904981 + 23 18 0.0165996131329 27 16 -0.0094471179841 26 13 0.0073879709639 + 51 18 0.0134857543681 53 17 0.0076112997694 22 15 -0.0065998291459 + + A B I J A B I J +------------------------------------ ------------------------------------ + 19 19 18 18 -0.1056877817077 23 19 12 18 -0.0299063054292 + 23 23 18 18 -0.0613044001293 36 19 18 18 -0.0270360007383 + 23 19 18 17 -0.0600669509361 19 36 18 18 -0.0270360007383 + 19 23 17 18 -0.0600669509361 19 23 12 18 -0.0226926616609 + 23 23 17 17 -0.0584561253098 23 19 18 12 -0.0226926616609 + 19 19 17 17 -0.0581621873054 19 23 18 17 -0.0210584541816 + 19 19 12 12 -0.0365934941924 23 19 17 18 -0.0210584541816 + 19 23 18 12 -0.0299063054292 + +It. Correlation Energy T1 Residual T2 Residual T3 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------------------- + 6 -0.764323026538578 2.97452e-06 4.25856e-05 7.83436e-06 166.103 8.332 + 7 -0.764328936237041 8.45049e-07 1.62347e-05 3.23184e-06 159.637 7.999 + 8 -0.764330915253402 1.60750e-07 6.38053e-06 1.39119e-06 159.569 7.993 + 9 -0.764331685282940 2.12600e-07 2.57485e-06 6.67873e-07 163.674 8.212 + 10 -0.764331953390088 1.28096e-07 1.04816e-06 3.40245e-07 162.688 8.156 + + A I A I A I +-------------------------- -------------------------- -------------------------- + 19 17 -0.0307388727895 31 17 0.0115720951522 25 15 0.0075568588653 + 19 12 0.0293753428594 36 17 -0.0108267095141 45 17 0.0074419669160 + 34 18 0.0227371511283 25 16 -0.0102032251498 21 14 -0.0074128063418 + 23 18 0.0165928414765 27 16 -0.0094482705029 26 13 0.0073892431894 + 51 18 0.0134864557533 53 17 0.0076116631443 22 15 -0.0066014240484 + + A B I J A B I J +------------------------------------ ------------------------------------ + 19 19 18 18 -0.1056999392535 23 19 12 18 -0.0299060870498 + 23 23 18 18 -0.0613032053597 19 36 18 18 -0.0270381793830 + 23 19 18 17 -0.0600698688184 36 19 18 18 -0.0270381793830 + 19 23 17 18 -0.0600698688184 19 23 12 18 -0.0226924465502 + 23 23 17 17 -0.0584525648842 23 19 18 12 -0.0226924465502 + 19 19 17 17 -0.0581591939789 19 23 18 17 -0.0210606563251 + 19 19 12 12 -0.0365923448057 23 19 17 18 -0.0210606563251 + 19 23 18 12 -0.0299060870498 + +It. Correlation Energy T1 Residual T2 Residual T3 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------------------- + 11 -0.764332062876228 7.13166e-08 4.33795e-07 1.70597e-07 159.364 7.982 + 12 -0.764332102477517 2.66336e-08 1.81180e-07 8.46321e-08 160.219 8.025 + 13 -0.764332120385917 1.06750e-08 7.76879e-08 4.18403e-08 162.393 8.137 + +CCSDT iterations converged in 13 cycles and 100.538 seconds (7.734 s/it.) at 67.271 Gflops/sec + +Total CCSDT energy: -229.407644692870491 + + @CHECKOUT-I, Total execution time (CPU/WALL): 2012.07/ 103.43 seconds. +--executable xncc finished with status 0 in 104.02 seconds (walltime). + The final electronic energy is -229.407644692870491 a.u. + This computation required 111.95 seconds (walltime). diff --git a/furan/cc-pvdz/CC/fura-gs-ccsdtq.out b/furan/cc-pvdz/CC/fura-gs-ccsdtq.out new file mode 100644 index 0000000..f4ce106 --- /dev/null +++ b/furan/cc-pvdz/CC/fura-gs-ccsdtq.out @@ -0,0 +1,1028 @@ + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xjoda + + + ************************************************************************* + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCC CCC ||| CCC CCC >>> + <<< CCCCCC CCCCCC ||| CCCCCC CCCCCC >>> + ************************************************************************* + + **************************************************************** + * CFOUR Coupled-Cluster techniques for Computational Chemistry * + **************************************************************** + + + Department of Chemistry Institut fuer Physikalische Chemie + University of Florida Universitaet Mainz + Gainesville, FL 32611, USA D-55099 Mainz, Germany + + Department of Chemistry Fakultaet fuer Chemie und Biowiss. + Johns Hopkins University Karlsruher Institut fuer Technologie + Baltimore, MD 21218, USA D-76131 Karlsruhe, Germany + + Department of Chemistry Department of Physical Chemistry + Southern Methodist University Eotvos Lorand University + Dallas, TX 75275, USA H-1053 Budapest, Hungary + + + Version 2.1 + + nazare115 + Thu Oct 15 14:34:58 CEST 2020 + integer*8 version is running + +******************************************************************************** +* Input from ZMAT file * +******************************************************************************** +Ketene -GS +C 0.00000000 2.06365826 -0.60051250 +C 0.00000000 -2.06365826 -0.60051250 +C 0.00000000 1.35348578 1.86336416 +C 0.00000000 -1.35348578 1.86336416 +O 0.00000000 0.00000000 -2.13945332 +H 0.00000000 3.86337287 -1.53765695 +H 0.00000000 -3.86337287 -1.53765695 +H 0.00000000 2.59168789 3.47168051 +H 0.00000000 -2.59168789 3.47168051 + +*CFOUR(COORD=CARTESIAN,UNITS=BOHR + MEMORY=100,MEM_UNIT=GB,CC_PROG=NCC + FROZEN_CORE=1 + CALC=CCSDTQ,BASIS=PVDZ + SCF_CONV=9,CC_CONV=7,ESTATE_MAXCYC=80) + +******************************************************************************** + ------------------------------------------------------------------- + CFOUR Control Parameters + ------------------------------------------------------------------- + External Internal Value Units + Name Name + ------------------------------------------------------------------- + ABCDTYPE IABCDT STANDARD [ 0] *** + ANHARMONIC IANHAR OFF [ 0] *** + ANH_ALGORIT IANALG STANDARD [ 0] *** + ANH_DERIVAT IANDER SECOND [ 1] *** + ANH_MODE ANHMOD VIBRATION [ 0] *** + ANH_STEPSIZ ICUBST 50000 x 10-6 + ANH_SYMMETR IANHSM ABELIAN [ 0] *** + AO_LADDERS IAOLAD SINGLEPASS [ 1] *** + AV_SCF IAVSCF OFF [ 0] *** + BASIS IBASIS PVDZ [ 13] *** + BOTHVECTORS BOTHVC OFF [ 0] *** + BOX_POTENT IPIAB OFF [ 0] *** + BREIT IBREIT OFF [ 0] *** + BRUCK_CONV IBRTOL 10D- 4 *** + BRUECKNER IBRKNR OFF [ 0] *** + BUFFERSIZE IBUFFS 4096 *** + CACHE_RECS ICHREC 10 *** + CALCLEVEL ICLLVL CCSDTQ [ 46] *** + CCORBOPT ICCORB OFF [ 0] x 0.01 + CC_CONV ICCCNV 10D- 7 *** + CC_EXPORDER ICCEOR 5 *** + CC_EXTRAPOL ICCEXT DIIS [ 1] *** + CC_GUESS ICCGES MP2 [ 0] *** + CC_MAXCYC ICCCYC 100 cycles + CC_PROGRAM ICCPRO NCC [ 5] *** + CHARGE ICHRGE 0 *** + CHOLESKY ICHOLE OFF [ 0] *** + CIS_CONV ICISTL 5 *** + COMM_SIZE IPSIZE *** *** + CONSTANT ICONST OLD [ 1] *** + CONTINUUM ICONTU NONE [ 0] *** + CONTRACTION ICNTYP GENERAL [ 1] *** + COORDINATES ICOORD CARTESIAN [ 1] *** + CPHF_CONVER ICPHFT 10D- 16 *** + CPHF_MAXCYC ICPHFC 64 cycles + CUBIC ICUBIC OFF [ 0] *** + CURVILINEAR ICURVY OFF [ 0] *** + DBOC IDBOC OFF [ 0] *** + DCT IDCT OFF [ 0] *** + DERIV_LEV IDRLVL ZERO [ 0] *** + DEVMEM_SIZE IDVMEM ********* MByte + DIAG_MRCC IEOMST 10D- 0 *** + DIFF_TYPE IDIFTY RELAXED [ 0] *** + DIRECT IDIRCT OFF [ 0] *** + DROPMO IDRPMO NONE + ECP IECP OFF [ 0] *** + EIGENVECTOR IVEC 1 *** + EL_ANHARM IELANH OFF [ 0] *** + EOMFOLLOW IEOMSR ENERGY [ 0] *** + EOMIP IEOMIP OFF [ 0] *** + EOMLEVEL HBARFM SAME [ 0] *** + EOM_MRCC IMRCCE NEW [ 1] *** + EOM_NONIT EOMNON OFF [ 0] *** + EOM_NSING IEOMSI 10D- 0 *** + EOM_NSTATES IMRCCD DAVIDSON [ 0] *** + EOM_NTRIP IEOMTR 10D- 0 *** + EOM_ORDER IEXORD ENERGY [ 0] *** + EOM_PROPSTA IEOMST 0 *** + ESTATE_CONV IEXTOL 10D- 5 *** + ESTATE_DIAG IEXDIG ITERATIVE [ 0] *** + ESTATE_LOCK IESLOC ON [ 1] *** + ESTATE_MAXC IEXMXC 80 *** + ESTATE_PROP IEXPRP OFF [ 0] *** + EVAL_HESS IRECAL 0 # of cyc. + EXCITATION IEXCIT 0 *** + EXCITE IEXCIT NONE [ 0] *** + EXTERN_POT IEXPOT OFF [ 0] *** + FCGRADNEW IFCGNW OFF [ 0] *** + FC_FIELD IFINFC 0 x 10-6 + FD_CALTYPE IFDCAL GRADONLY [ 0] *** + FD_PROJECT IFDPRJ OFF [ 1] *** + FD_STEPSIZE IDISFD 0 10-4 bohr + FD_USEGROUP IFDGRP FULL [ 0] *** + FILE_RECSIZ IFLREC 4096 words + FINITE_PERT IFIPER 0 x 10-6 + FIXGEOM IFIXGM OFF [ 0] *** + FOCK IFOCK AO [ 1] *** + FREQ_ALGORI IVIALG STANDARD [ 0] *** + FROZEN_CORE IFROCO ON [ 1] *** + GAMMA_ABCD IGABCD STORE [ 0] *** + GAMMA_ABCI IGABCI STORE [ 0] *** + GENBAS_1 IGNBS1 0 *** + GENBAS_2 IGNBS2 0 *** + GENBAS_3 IGNBS3 0 *** + GENBAS_4 IGNBS4 0 *** + GEO_CONV ICONTL 5 H/bohr + GEO_MAXCYC IOPTCY 50 *** + GEO_MAXSTEP IMXSTP 300 millibohr + GEO_METHOD INR SINGLE_POINT[ 5] *** + GIAO IGIAO OFF [ 1] *** + GIMIC IGIMIC OFF [ 0] *** + GRID IGRID OFF [ 0] *** + GRID_ALGO IGALGO SERIAL [ 0] *** + GUESS IGUESS MOREAD [ 0] *** + HBAR IHBAR OFF [ 0] *** + HESS_TYPE IHESTP SCF [ 0] *** + HF2_FILE IHF2Fl USE [ 1] *** + HFSTABILITY ISTABL OFF [ 0] *** + INCORE INCORE OFF [ 0] *** + INPUT_MRCC IMRCC ON [ 1] *** + INTEGRALS INTTYP VMOL [ 1] *** + JODA_PRINT IJPRNT 0 *** + KEYWORD_OUT IDMPKW NO [ 0] *** + LINDEP_TOL ILINDP 8 *** + LINEQ_CONV IZTACN 10D- 7 cycles + LINEQ_EXPOR ILMAXD 5 *** + LINEQ_MAXCY ILMAXC 100 *** + LINEQ_TYPE ILTYPE DIIS [ 1] *** + LOCK_ORBOCC ILOCOC OFF [ 0] *** + MEMORY_SIZE IMEMSZ ********* words + MEM_UNIT IMEMU GB [ 3] *** + MRCC IMRCCC OFF [ 0] *** + MULTIPLICTY IMULTP 1 *** + NACOUPLING IVCOUP OFF [ 0] *** + NEGEVAL IDIE ABORT [ 0] *** + NEWNORM INEWNO OFF [ 0] *** + NON-HF INONHF OFF [ 0] *** + NTOP_TAMP ITOPT2 15 *** + NUC_MODEL INUCMO POINT [ 0] *** + OCCUPATION IOCCU ESTIMATED BY SCF + OPEN-SHELL IOPEN SPIN-ORBITAL[ 0] *** + OPTVIB IOPTVB OFF [ 0] *** + ORBITALS IORBTP STANDARD [ 0] *** + PARALLEL IPARAL ON [ 1] *** + PARA_INT IPINTS ON [ 1] *** + PARA_PRINT IPPRIN 0 *** + PERT_ORB IPTORB STANDARD [ 0] *** + POINTS IGRDFD 0 *** + PRINT IPRNT 0 *** + PROPS IPROPS OFF [ 0] *** + PROP_INTEGR IINTYP INTERNAL [ 0] *** + PSI IPSI OFF [ 0] *** + QC_ALG IQCALG FLM [ 0] *** + QC_LINALG IQCLIN TRIDIAG [ 2] *** + QC_MAXCYC IQCMAX 10D-100 cycles + QC_MAXSCFCY IQCMSC 10D- 15 cycles + QC_RTRUST IQCRTR 10D- 0 x 10-3 + QC_SKIPSCF IQCSKI OFF [ 0] *** + QC_START IQCSTA 10D- 1 *** + QRHFGUESS IQGUES OFF [ 0] *** + QUARTIC IQUART OFF [ 0] *** + RAMAN_INT IRAMIN OFF [ 0] *** + RAMAN_ORB IRAMRE UNRELAXED [ 0] *** + RDO IRDOFM OFF [ 0] *** + REDUCE_REPR REDREP Ir [ 0] *** + REFERENCE IREFNC RHF [ 0] *** + RELATIVIST IRELAT OFF [ 0] *** + RELAX_DENS IRDENS OFF [ 0] *** + RESET_FLAGS IRESET OFF [ 0] *** + RESTART_CC ICCRES OFF [ 0] *** + ROT_EVEC ROTVEC 0 *** + SAVE_INTS ISVINT OFF [ 0] *** + SCALE_ON ISTCRT 0 *** + SCF_CONV ISCFCV 10D- 9 *** + SCF_DAMPING IDAMP 0 x 10-3 + SCF_EXPORDE IRPPOR 6 *** + SCF_EXPSTAR IRPPLS 8 *** + SCF_EXTRAPO IRPP ON [ 1] *** + SCF_MAXCYC ISCFCY 150 cycles + SCF_NOSTOP ISCFST OFF [ 0] *** + SCF_PRINT ISCFPR 0 *** + SCF_PROG ISCFPR SCF [ 0] *** + SD_FIELD IFINSD 0 x 10-6 + SOPERT IPERSO OFF [ 0] *** + SPHERICAL IDFGHI ON [ 1] *** + SPINORBIT ISOCAL OFF [ 0] *** + SPINROTATIO ISRCON OFF [ 0] *** + SPIN_FLIP ISPFLP OFF [ 0] *** + SPIN_ORBIT ISPORB OFF [ 0] *** + SPIN_SCAL ISCSMP OFF [ 0] *** + STEEPSCALE ISTPSC 1000 x 10-3 + SUBGROUP ISUBGP DEFAULT [ 0] *** + SUBGRPAXIS ISBXYZ X [ 0] *** + SYMMETRY ISYM ON [ 0] *** + SYM_CHECK ISYMCK OVERRIDE [ 1] *** + T3_EXTRAPOL IT3EXT ON [ 1] *** + T4_EXTRAPOL IT4EXP OFF [ 0] *** + TAMP_SUM IEVERY 5 *** + TESTSUITE ITESTS OFF [ 0] *** + THERMOCH ITHERM OFF [ 0] *** + TOL_CHOLESK ITOLCH 10D- 4 *** + TRANGRAD IRESRM OFF [ 0] *** + TRANS_INV ITRAIN USE [ 0] *** + TREAT_PERT ITREAT SIMULTANEOUS[ 0] *** + TRIP_ALGORI ITRALG NORMAL [ 0] *** + UIJ_THRESHO IUIJTH 1 *** + UNITS IUNITS BOHR [ 1] *** + UNOS IUNOS OFF [ 0] *** + UPDATE_HESS IHUPDT ON [ 1] *** + VIBPHASE ISETPH STANDARD [ 0] *** + VIBRATION IVIB NO [ 0] *** + VIB_ALGORIT IGEALG STANDARD [ 0] *** + VNATORB IVNORB OFF [ 0] *** + VTRAN IVTRAN FULL/PARTIAL[ 0] *** + XFIELD IXEFLD 0 x 10-6 + XFORM_TOL IXFTOL 10D- 11 *** + YFIELD IYEFLD 0 x 10-6 + ZFIELD IZEFLD 0 x 10-6 + ZSCALE_EXP IZEXPS OFF [ 0] *** + ------------------------------------------------------------------- + @GETXYZ-I, 9 atoms read from ZMAT. + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 +******************************************************************************** + The full molecular point group is C2v . + The largest Abelian subgroup of the full molecular point group is C2v . + The computational point group is C2v . +******************************************************************************** + + + ---------------------------------------------------------------- + Coordinates used in calculation (QCOMP) + ---------------------------------------------------------------- + Z-matrix Atomic Coordinates (in bohr) + Symbol Number X Y Z + ---------------------------------------------------------------- + C 6 0.00000000 -2.06365826 0.60031230 + C 6 0.00000000 2.06365826 0.60031230 + C 6 0.00000000 -1.35348578 -1.86356436 + C 6 0.00000000 1.35348578 -1.86356436 + O 8 0.00000000 0.00000000 2.13925312 + H 1 0.00000000 -3.86337287 1.53745675 + H 1 0.00000000 3.86337287 1.53745675 + H 1 0.00000000 -2.59168789 -3.47188071 + H 1 0.00000000 2.59168789 -3.47188071 + ---------------------------------------------------------------- + + Interatomic distance matrix (Angstroms) + + C C C C O + [ 1] [ 2] [ 3] [ 4] [ 5] + C [ 1] 0.00000 + C [ 2] 2.18408 0.00000 + C [ 3] 1.35691 2.22931 0.00000 + C [ 4] 2.22931 1.35691 1.43247 0.00000 + O [ 5] 1.36226 1.36226 2.23601 2.23601 0.00000 + H [ 6] 1.07375 3.17541 2.23677 3.29549 2.06906 + H [ 7] 3.17541 1.07375 3.29549 2.23677 2.06906 + H [ 8] 2.17295 3.27299 1.07409 2.25451 3.27071 + H [ 9] 3.27299 2.17295 2.25451 1.07409 3.27071 + + H H H H + [ 6] [ 7] [ 8] [ 9] + H [ 6] 0.00000 + H [ 7] 4.08882 0.00000 + H [ 8] 2.73491 4.32378 0.00000 + H [ 9] 4.32378 2.73491 2.74292 0.00000 + rotcon2 + Rotational constants (in cm-1): + 0.1567470279 0.3098953647 0.3171773090 + Rotational constants (in MHz): + 4699.1583347524 9290.4306132155 9508.7378403410 + There are 5 frozen-core orbitals. + There are 90 basis functions. + @GEOPT-W, Archive file not created for single-point calculation. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.27/ 2.12 seconds. +--executable xjoda finished with status 0 in 2.65 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol + SERIAL VERSION OF MOLECULE STARTED +******************************************************************************** + INPUT FROM MOL FILE +******************************************************************************** +INTGRL 1 0 1 0 0 0 0 0 0 + *** CFOUR Program System (Release V0.1) *** +Ketene -GS + 5 2 X Y 0.10E-08 0 0 + 9999.00 3.00 + 6.00000000 1 3 1 1 1 +C #1 0.000000000000000 -2.063658260000000 0.600312302999175 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 6.00000000 1 3 1 1 1 +C #2 0.000000000000000 -1.353485780000000 -1.863564357000825 + 9 3 + 6665.00000000000 6.920000000000000E-004 -1.460000000000000E-004 + 0.000000000000000E+000 + 1000.00000000000 5.329000000000000E-003 -1.154000000000000E-003 + 0.000000000000000E+000 + 228.000000000000 2.707700000000000E-002 -5.725000000000000E-003 + 0.000000000000000E+000 + 64.7100000000000 0.101718000000000 -2.331200000000000E-002 + 0.000000000000000E+000 + 21.0600000000000 0.274740000000000 -6.395500000000000E-002 + 0.000000000000000E+000 + 7.49500000000000 0.448564000000000 -0.149981000000000 + 0.000000000000000E+000 + 2.79700000000000 0.285074000000000 -0.127262000000000 + 0.000000000000000E+000 + 0.521500000000000 1.520400000000000E-002 0.544529000000000 + 0.000000000000000E+000 + 0.159600000000000 -3.191000000000000E-003 0.580496000000000 + 1.00000000000000 + 4 2 + 9.43900000000000 3.810900000000000E-002 0.000000000000000E+000 + 2.00200000000000 0.209480000000000 0.000000000000000E+000 + 0.545600000000000 0.508557000000000 0.000000000000000E+000 + 0.151700000000000 0.468842000000000 1.00000000000000 + 1 1 + 0.550000000000000 1.00000000000000 + 8.00000000 1 3 1 1 1 +O #3 0.000000000000000 0.000000000000000 2.139253122999175 + 9 3 + 11720.0000000000 7.100000000000000E-004 -1.600000000000000E-004 + 0.000000000000000E+000 + 1759.00000000000 5.470000000000000E-003 -1.263000000000000E-003 + 0.000000000000000E+000 + 400.800000000000 2.783700000000000E-002 -6.267000000000000E-003 + 0.000000000000000E+000 + 113.700000000000 0.104800000000000 -2.571600000000000E-002 + 0.000000000000000E+000 + 37.0300000000000 0.283062000000000 -7.092400000000000E-002 + 0.000000000000000E+000 + 13.2700000000000 0.448719000000000 -0.165411000000000 + 0.000000000000000E+000 + 5.02500000000000 0.270952000000000 -0.116955000000000 + 0.000000000000000E+000 + 1.01300000000000 1.545800000000000E-002 0.557368000000000 + 0.000000000000000E+000 + 0.302300000000000 -2.585000000000000E-003 0.572759000000000 + 1.00000000000000 + 4 2 + 17.7000000000000 4.301800000000000E-002 0.000000000000000E+000 + 3.85400000000000 0.228913000000000 0.000000000000000E+000 + 1.04600000000000 0.508728000000000 0.000000000000000E+000 + 0.275300000000000 0.460531000000000 1.00000000000000 + 1 1 + 1.18500000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #4 0.000000000000000 -3.863372870000000 1.537456752999175 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 + 1.00000000 1 2 1 1 +H #5 0.000000000000000 -2.591687890000000 -3.471880707000825 + 4 2 + 13.0100000000000 1.968500000000000E-002 0.000000000000000E+000 + 1.96200000000000 0.137977000000000 0.000000000000000E+000 + 0.444600000000000 0.478148000000000 0.000000000000000E+000 + 0.122000000000000 0.501240000000000 1.00000000000000 + 1 1 + 0.727000000000000 1.00000000000000 +FINISH + +******************************************************************************** + ONE- AND TWO-ELECTRON INTEGRALS OVER SYMMETRY-ADAPTED AOS ARE CALCULATED. + + SPHERICAL HARMONICS ARE USED. + + INTEGRALS LESS THAN 0.10E-13 ARE NEGLECTED. + + NUCLEAR REPULSION ENERGY : 161.1082297788 A.U. + @MOLECU-I, ONE ELECTRON INTEGRALS (CPU/WALL): 0.05/ 0.08 SECONDS. + @TWOEL-I, 325108 INTEGRALS OF SYMMETRY TYPE I I I I + @TWOEL-I, 908743 INTEGRALS OF SYMMETRY TYPE I J I J + @TWOEL-I, 490042 INTEGRALS OF SYMMETRY TYPE I I J J + @TWOEL-I, 460725 INTEGRALS OF SYMMETRY TYPE I J K L + @TWOEL-I, TOTAL NUMBER OF 2-E INTEGRALS 2184618. + @MOLECU-I, TWO ELECTRON INTEGRALS (CPU/WALL): 2.31/ 2.32 SECONDS. + @CHECKOUT-I, Total execution time (CPU/WALL): 2.37/ 2.46 seconds. + +Running with 20 threads/proc + +--executable xvmol finished with status 0 in 3.01 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvmol2ja + @GETMEM-I, Allocated 95367 MB of main memory. + @CHECKOUT-I, Total execution time (CPU/WALL): 0.31/ 0.06 seconds. +--executable xvmol2ja finished with status 0 in 0.57 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvscf + There are 90 functions in the AO basis. + + There are 4 irreducible representations. + + Irrep # of functions + 1 35 + 2 13 + 3 31 + 4 11 + + + Parameters for SCF calculation: + SCF reference function: RHF + Maximum number of iterations: 150 + Full symmetry point group: C2v + Computational point group: C2v + Initial density matrix: MOREAD + SCF convergence tolerance: 10**(- 9) + DIIS convergence acceleration: ON + Latest start for DIIS: 8 + DIIS order: 6 + + Memory information: 341888 words required. + Fock matrices are constructed from AO integral file. + @GETMEM-I, Allocated 2 MB of main memory. + Initialization and symmetry analysis required 0.002 seconds. + + @INITGES-I, Occupancies from core Hamiltonian: + + Alpha population by irrep: 9 2 6 1 + Beta population by irrep: 9 2 6 1 + + + total no. of electrons in initial guess : 0.000000000000000E+000 + -------------------------------------------------------------------- + Iteration Total Energy Largest Density Difference + -------------------------------------------------------------------- + 0 161.108229778788910 0.0000000000D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 1 -196.263249175407992 0.1098182460D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 2 -179.889864626336106 0.1675780025D+02 + current occupation vector + 9 1 7 1 + 9 1 7 1 + 3 -180.580457259652945 0.1772125138D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 4 -162.771013663095033 0.1566999730D+02 + current occupation vector + 8 2 7 1 + 8 2 7 1 + 5 -169.943224465301597 0.1454729382D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 6 -160.269967975315780 0.1454634919D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 7 -168.828658617537684 0.1395077743D+02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 8 -160.232275948463297 0.1395068492D+02 + current occupation vector + 8 3 6 1 + 8 3 6 1 + 9 -209.746508446745025 0.5520995458D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 10 -228.180230304181549 0.2015536648D+01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 11 -228.454713327495682 0.6531384936D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 12 -228.600329261507483 0.3196758217D+00 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 13 -228.637509917234041 0.7498321731D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 14 -228.642938164599826 0.5250342791D-01 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 15 -228.643241982659248 0.9795506231D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 16 -228.643308522550143 0.3593200395D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 17 -228.643312517846056 0.1473098013D-02 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 18 -228.643312570337258 0.1244041229D-03 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 19 -228.643312572356052 0.2423484470D-04 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 20 -228.643312572476049 0.5414751593D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 21 -228.643312572485769 0.2003507219D-05 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 22 -228.643312572485598 0.8833300562D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 23 -228.643312572484461 0.3139636784D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 24 -228.643312572486110 0.4136764657D-06 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 25 -228.643312572485542 0.9839839787D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 26 -228.643312572486622 0.1838835018D-07 + current occupation vector + 9 2 6 1 + 9 2 6 1 + 27 -228.643312572484007 0.3228508794D-08 + current occupation vector + 9 2 6 1 + 9 2 6 1 + + SCF has converged. + + Density matrix saved to file den.dat + total electron number: 36.0000000000000 + E(SCF)= -228.643312572484575 0.7981584282D-09 + + Eigenvector printing suppressed. + + @PUTMOS-I, Writing converged MOs to NEWMOS. + @PUTMOS-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTMOS-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTMOS-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTMOS-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + @PUTFOCK-I, Writing converged Fock matrix to NEWFOCK. + @PUTFOCK-I, Symmetry 1 Full Blocks 8 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 2 Full Blocks 3 Partial Blocksize 1 + @PUTFOCK-I, Symmetry 3 Full Blocks 7 Partial Blocksize 3 + @PUTFOCK-I, Symmetry 4 Full Blocks 2 Partial Blocksize 3 + + + + ORBITAL EIGENVALUES (ALPHA) (1H = 27.2113834 eV) + + MO # E(hartree) E(eV) FULLSYM COMPSYM + ---- -------------------- -------------------- ------- --------- + 1 1 -20.6219765861 -561.1525113512 A1 A1 (1) + 2 49 -11.2892088103 -307.1949892207 B2 B2 (3) + 3 2 -11.2891634657 -307.1937553315 A1 A1 (1) + 4 3 -11.2328159068 -305.6604603025 A1 A1 (1) + 5 50 -11.2318729764 -305.6348018622 B2 B2 (3) + 6 4 -1.4574476329 -39.6591663239 A1 A1 (1) + 7 5 -1.0834872588 -29.4831872086 A1 A1 (1) + 8 51 -1.0036038078 -27.3094479952 B2 B2 (3) + 9 52 -0.8050606676 -21.9068144851 B2 B2 (3) + 10 6 -0.7793049296 -21.2059652251 A1 A1 (1) + 11 7 -0.7372159421 -20.0606656495 A1 A1 (1) + 12 36 -0.6283416633 -17.0980459063 B1 B1 (2) + 13 53 -0.6064452640 -16.5022145907 B2 B2 (3) + 14 54 -0.5741889664 -15.6244761082 B2 B2 (3) + 15 8 -0.5622006055 -15.2982562239 A1 A1 (1) + 16 9 -0.5366322238 -14.6025051862 A1 A1 (1) + 17 37 -0.3944127682 -10.7325170532 B1 B1 (2) + 18 80 -0.3173264428 -8.6348914980 A2 A2 (4) + +++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++ + 19 38 0.1616454919 4.3985974562 B1 B1 (2) + 20 10 0.2028007990 5.5184902966 A1 A1 (1) + 21 55 0.2259953076 6.1496449623 B2 B2 (3) + 22 11 0.2331452351 6.3442043789 A1 A1 (1) + 23 81 0.2346526075 6.3852220682 A2 A2 (4) + 24 56 0.2409072580 6.5554197617 B2 B2 (3) + 25 12 0.3379830583 9.1969865830 A1 A1 (1) + 26 57 0.3670668300 9.9883962435 B2 B2 (3) + 27 13 0.4400792390 11.9751648999 A1 A1 (1) + 28 58 0.5035354267 13.7018955503 B2 B2 (3) + 29 14 0.5796551077 15.7732173745 A1 A1 (1) + 30 59 0.6027649445 16.4020680057 B2 B2 (3) + 31 39 0.6720867908 18.2884113425 B1 B1 (2) + 32 15 0.6949257331 18.9098905590 A1 A1 (1) + 33 60 0.7033703399 19.1396799905 B2 B2 (3) + 34 82 0.7176012567 19.5269229246 A2 A2 (4) + 35 61 0.7543801794 20.5277282917 B2 B2 (3) + 36 40 0.7622869649 20.7428828633 B1 B1 (2) + 37 16 0.7651070466 20.8196211868 A1 A1 (1) + 38 17 0.7917408050 21.5443625978 A1 A1 (1) + 39 83 0.8438632537 22.9626865338 A2 A2 (4) + 40 62 0.8844205187 24.0663058221 B2 B2 (3) + 41 18 0.9187910190 25.0015746820 A1 A1 (1) + 42 19 0.9547555380 25.9802189979 A1 A1 (1) + 43 63 0.9634112815 26.2157537519 B2 B2 (3) + 44 64 1.0592164869 28.8227459274 B2 B2 (3) + 45 41 1.0743328454 29.2340829566 B1 B1 (2) + 46 20 1.1352329173 30.8912581602 A1 A1 (1) + 47 65 1.1904894416 32.3948646279 B2 B2 (3) + 48 21 1.1908922750 32.4058262839 A1 A1 (1) + 49 42 1.2129419174 33.0058275576 B1 B1 (2) + 50 66 1.2581407748 34.2357509943 B2 B2 (3) + 51 84 1.2921641151 35.1615731515 A2 A2 (4) + 52 22 1.2994001068 35.3584744953 A1 A1 (1) + 53 43 1.3116428673 35.6916169462 B1 B1 (2) + 54 85 1.3649569984 37.1423682072 A2 A2 (4) + 55 44 1.5283489789 41.5884900335 B1 B1 (2) + 56 23 1.5439841774 42.0139454134 A1 A1 (1) + 57 67 1.5691624192 42.6990802047 B2 B2 (3) + 58 68 1.5969806595 43.4560530082 B2 B2 (3) + 59 24 1.7377154792 47.2856421455 A1 A1 (1) + 60 69 1.7438095776 47.4514709939 B2 B2 (3) + 61 86 1.7443895833 47.4672537511 A2 A2 (4) + 62 25 1.7729617500 48.2447419337 A1 A1 (1) + 63 45 1.8384391578 50.0264727818 B1 B1 (2) + 64 26 1.8727560698 50.9602834298 A1 A1 (1) + 65 46 1.9574193824 53.2640892885 B1 B1 (2) + 66 70 1.9863618073 54.0516527104 B2 B2 (3) + 67 71 2.0036624844 54.5224280672 B2 B2 (3) + 68 87 2.0489211710 55.7539795407 A2 A2 (4) + 69 27 2.0703324397 56.3366097828 A1 A1 (1) + 70 88 2.1357719213 58.1173086059 A2 A2 (4) + 71 28 2.1641427105 58.8893170284 A1 A1 (1) + 72 72 2.1880643996 59.5402592802 B2 B2 (3) + 73 47 2.1914898441 59.6334703659 B1 B1 (2) + 74 29 2.2271655184 60.6042548161 A1 A1 (1) + 75 73 2.2977715809 62.5255434529 B2 B2 (3) + 76 30 2.3793504210 64.7454165492 A1 A1 (1) + 77 89 2.5107047412 68.3197493175 A2 A2 (4) + 78 74 2.5407172731 69.1364318293 B2 B2 (3) + 79 75 2.6586433664 72.3453639681 B2 B2 (3) + 80 31 2.6718877167 72.7057610618 A1 A1 (1) + 81 32 2.8267951805 76.9210074510 A1 A1 (1) + 82 76 2.9419209269 80.0537382753 B2 B2 (3) + 83 77 2.9853767071 81.2362301695 B2 B2 (3) + 84 33 3.0013526923 81.6709588287 A1 A1 (1) + 85 48 3.2421725037 88.2239990462 B1 B1 (2) + 86 90 3.2857682253 89.4102989431 A2 A2 (4) + 87 34 3.4838249547 94.7996965407 A1 A1 (1) + 88 78 3.6959298762 100.5713648809 B2 B2 (3) + 89 79 3.7700022467 102.5869765541 B2 B2 (3) + 90 35 3.8341979240 104.3338297409 A1 A1 (1) + + + VSCF finished. + + @CHECKOUT-I, Total execution time (CPU/WALL): 5.39/ 1.56 seconds. +--executable xvscf finished with status 0 in 2.15 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xvtran + @GETMEM-I, Allocated 95367 MB of main memory. + Full RHF integral transformation + The following 5 MOs will be dropped: + 1 2 3 12 13 + There are 85 active molecular orbitals. + Transformation of IIII integrals : + 1 pass through the AO integral file was required. + 325108 AO integrals were read. + 240883 MO integrals were written to HF2. + Transformation of IIJJ integrals : + 1 pass through the AO integral file was required. + 490042 AO integrals were read. + 386877 MO integrals were written to HF2. + Transformation of IJIJ integrals : + 1 pass through the AO integral file was required. + 908743 AO integrals were read. + 712509 MO integrals were written to HF2. + Transformation of IJKL integrals : + 1 pass through the AO integral file was required. + 460725 AO integrals were read. + 398112 MO integrals were written to HF2. + Summary of active molecular orbitals: +------------------------------------------------------------------------ + + Index Eigenvalue Symmetry Index Eigenvalue Symmetry +------------------------------------------------------------------------ + 1 -1.4574476 1 44 1.2129419 2 + 2 -1.0834873 1 45 1.3116429 2 + 3 -0.7793049 1 46 1.5283490 2 + 4 -0.7372159 1 47 1.8384392 2 + 5 -0.5622006 1 48 1.9574194 2 + 6 -0.5366322 1 49 2.1914898 2 + 7 -0.6283417 2 50 3.2421725 2 + 8 -0.3944128 2 51 0.2259953 3 + 9 -1.0036038 3 52 0.2409073 3 + 10 -0.8050607 3 53 0.3670668 3 + 11 -0.6064453 3 54 0.5035354 3 + 12 -0.5741890 3 55 0.6027649 3 + 13 -0.3173264 4 56 0.7033703 3 + 14 0.2028008 1 57 0.7543802 3 + 15 0.2331452 1 58 0.8844205 3 + 16 0.3379831 1 59 0.9634113 3 + 17 0.4400792 1 60 1.0592165 3 + 18 0.5796551 1 61 1.1904894 3 + 19 0.6949257 1 62 1.2581408 3 + 20 0.7651070 1 63 1.5691624 3 + 21 0.7917408 1 64 1.5969807 3 + 22 0.9187910 1 65 1.7438096 3 + 23 0.9547555 1 66 1.9863618 3 + 24 1.1352329 1 67 2.0036625 3 + 25 1.1908923 1 68 2.1880644 3 + 26 1.2994001 1 69 2.2977716 3 + 27 1.5439842 1 70 2.5407173 3 + 28 1.7377155 1 71 2.6586434 3 + 29 1.7729618 1 72 2.9419209 3 + 30 1.8727561 1 73 2.9853767 3 + 31 2.0703324 1 74 3.6959299 3 + 32 2.1641427 1 75 3.7700022 3 + 33 2.2271655 1 76 0.2346526 4 + 34 2.3793504 1 77 0.7176013 4 + 35 2.6718877 1 78 0.8438633 4 + 36 2.8267952 1 79 1.2921641 4 + 37 3.0013527 1 80 1.3649570 4 + 38 3.4838250 1 81 1.7443896 4 + 39 3.8341979 1 82 2.0489212 4 + 40 0.1616455 2 83 2.1357719 4 + 41 0.6720868 2 84 2.5107047 4 + 42 0.7622870 2 85 3.2857682 4 + 43 1.0743328 2 +------------------------------------------------------------------------ + -1.45744763288719 -1.08348725881441 -0.779304929609897 + -0.737215942115339 -0.562200605497301 -0.536632223783724 + -0.628341663300699 -0.394412768193209 -1.00360380778026 + -0.805060667553655 -0.606445264032669 -0.574188966380078 + -0.317326442801090 0.202800799044599 0.233145235052782 + 0.337983058334004 0.440079239041159 0.579655107669000 + 0.694925733138531 0.765107046589679 0.791740804983910 + 0.918791018982032 0.954755538003189 1.13523291727329 + 1.19089227502871 1.29940010677049 1.54398417735024 + 1.73771547923282 1.77296175003401 1.87275606979175 + 2.07033243972521 2.16414271052282 2.22716551838589 + 2.37935042101669 2.67188771673553 2.82679518054224 + 3.00135269229820 3.48382495469438 3.83419792398046 + 0.161645491943529 0.672086790797680 0.762286964920328 + 1.07433284544462 1.21294191744913 1.31164286730943 + 1.52834897888630 1.83843915784915 1.95741938237798 + 2.19148984413109 3.24217250366571 0.225995307622873 + 0.240907258015995 0.367066829963131 0.503535426659975 + 0.602764944529835 0.703370339875812 0.754380179426906 + 0.884420518732559 0.963411281466499 1.05921648685572 + 1.19048944155892 1.25814077480321 1.56916241916196 + 1.59698065950503 1.74380957764511 1.98636180732934 + 2.00366248439902 2.18806439955680 2.29777158087759 + 2.54071727310046 2.65864336644143 2.94192092693438 + 2.98537670707142 3.69592987620463 3.77000224671010 + 0.234652607487977 0.717601256707210 0.843863253708071 + 1.29216411509331 1.36495699837027 1.74438958333340 + 2.04892117101004 2.13577192131677 2.51070474122043 + 3.28576822533544 + @CHECKOUT-I, Total execution time (CPU/WALL): 11.75/ 1.06 seconds. +--executable xvtran finished with status 0 in 2.07 seconds (walltime). + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xintprc + @GETMEM-I, Allocated 95367 MB of main memory. + @GMOIAA-I, Processing MO integrals for spin case AA. + @GMOIAA-I, Generation of integral list completed. + TYPE NUMBER + ---- -------- + PPPP 894479 + PPPH 640524 + PPHH 115497 + PHPH 63721 + PHHH 22938 + HHHH 1222 + + TOTAL 1738381 + + @FORMT2-I, Second-order MP correlation energies: + ------------------------------------------------ + E(SCF) = -228.643312572485 a.u. + E2(AA) = -0.093684343380 a.u. + E2(AB) = -0.520081687065 a.u. + E2(TOT) = -0.707450373824 a.u. + Total MP2 energy = -229.350762946309 a.u. + ------------------------------------------------ + Largest T2 amplitudes for spin case AB: + _ _ _ _ _ _ + i j a b i j a b i j a b +----------------------------------------------------------------------------- +[ 13 13 40 40]-0.06710 [ 8 8 40 40]-0.05436 [ 13 13 76 76]-0.05241 +[ 13 8 76 40]-0.04215 [ 8 13 40 76]-0.04215 [ 8 8 76 76]-0.03737 +[ 7 7 40 40]-0.03140 [ 13 7 40 76]-0.02053 [ 7 13 76 40]-0.02053 +[ 13 13 77 77]-0.01960 [ 13 13 40 42]-0.01810 [ 13 13 42 40]-0.01810 +[ 7 7 45 45]-0.01664 [ 13 13 41 41]-0.01633 [ 13 13 78 76]-0.01595 +----------------------------------------------------------------------------- + Norm of T2AB vector ( 230058 symmetry allowed elements): 0.4218925855. +----------------------------------------------------------------------------- + @CHECKOUT-I, Total execution time (CPU/WALL): 5.13/ 0.65 seconds. +--executable xintprc finished with status 0 in 1.19 seconds (walltime). + calling xncc + --invoking executable-- +/home/CEISAM/blondel-a/soft/cfour2.1/cfour2.1-serial-mkl/bin/xncc + @GETMEM-I, Allocated 7 MB of main memory. + +Running with 20 threads/proc + +Using DIIS to accelerate the convergence of T1 and T2 +Using DIIS to accelerate the convergence of T3 +Using immediate high-order contributions +Performing 2 CCSDT sub-iterations +Damping factor for T3: 0.000000 +Damping factor for T4: 0.000000 + +Transposes are coarse-threaded + +Memory limit: 93.132 GiB +Minimum memory requirement: 10.986 GiB +Compromise memory amount: 177.337 GiB +Optimal memory requirement: 343.473 GiB + +List Location Size Cached Hunks Est. Disk I/O +----------------- ---------- ----------- ------ ----- ------------- + + T_DIIS 70:0 8.787 MiB Yes - 158.166 MiB + Z_DIIS 70:1 8.787 MiB Yes - 263.610 MiB + 18 1.755 MiB Yes - 265.429 MiB + 233 52.803 MiB Yes - 150.055 GiB + 30 9.615 MiB Yes - 10.986 GiB + 16 1.755 MiB Yes - 3.243 GiB + 25 1.755 MiB Yes - 236.952 MiB + 21 1.755 MiB No - 0 B + 10 329.156 KiB Yes - 472.519 MiB + 13 60.633 KiB Yes - 2.665 MiB + F(EA) 92:0 11.891 KiB Yes - 5.400 MiB + F(EM) 93:0 2.250 KiB Yes - 978.750 KiB + F(MI) 91:0 456 B Yes - 307.266 KiB + Q(AI) 190:2 2.250 KiB Yes - 810.000 KiB + Q(Ab,Ij) 50 1.755 MiB Yes - 2.623 GiB + QQ(Ab,Ij) 3 1.755 MiB Yes - 447.577 MiB + T(AI) 90:0 2.250 KiB Yes - 2.474 MiB + T(Ab,Ij) 46 1.755 MiB Yes - 3.397 GiB + W(Mn,Ij) 53 60.633 KiB Yes - 44.988 MiB + W~(Ab,Ej) 130 9.615 MiB Yes - 16.165 GiB + W~(EM,bj) 56 1.755 MiB Yes - 1.928 GiB + W~(Em,Bj) 58 1.755 MiB Yes - 2.700 GiB + W~(Ij,Mb) 110 329.156 KiB Yes - 332.692 MiB + W~~(Ab,Ej) 169 9.615 MiB Yes - 5.916 GiB + W~~(EM,bj) 76 1.755 MiB Yes - 631.873 MiB + W~~(Em,Bj) 78 1.755 MiB Yes - 631.873 MiB + W~~(Ij,Mb) 165 329.156 KiB Yes - 202.508 MiB + Z(AI) 90:2 2.250 KiB Yes - 810.000 KiB + Z(Ab,Ij) 63 1.755 MiB Yes - 631.873 MiB + Q(abc,ijk) Q3FILE 319.713 MiB Yes 1 18.733 GiB + T(abc,ijk) T3FILE 319.713 MiB Yes 1 65.566 GiB + T(abcd,ijkl) T4FILE 83.022 GiB No 4 3735.986 GiB + T3_1 T3_1 319.713 MiB Yes 1 9.367 GiB + T3_2 T3_2 319.713 MiB Yes 1 4.683 GiB + T3_3 T3_3 319.713 MiB Yes 1 4.683 GiB + T3_4 T3_4 319.713 MiB Yes 1 4.683 GiB + T3_5 T3_5 319.713 MiB Yes 1 4.683 GiB + W(abc,ije) WABCIJE 4.602 GiB Yes 1 276.115 GiB + W(abf,ijn) WABFIJN 853.370 MiB Yes 1 25.001 GiB + W(abf,inj) WABFINJ 1.545 GiB Yes 1 46.340 GiB + W(abm,ijk) WABMIJK 154.671 MiB Yes 1 9.063 GiB + W(mnd,jkl) WMNDJKL 28.065 MiB Yes 1 841.961 MiB + Z(abc,ijk) Z3FILE 319.713 MiB Yes 1 51.516 GiB + Z(abcd,ijkl) Z4FILE 83.022 GiB No 4 3735.986 GiB + Z3_1 Z3_1 319.713 MiB Yes 1 9.367 GiB + Z3_2 Z3_2 319.713 MiB Yes 1 9.367 GiB + Z3_3 Z3_3 319.713 MiB Yes 1 9.367 GiB + Z3_4 Z3_4 319.713 MiB Yes 1 9.367 GiB + Z3_5 Z3_5 319.713 MiB Yes 1 9.367 GiB + +Simulation and memory analysis took 246.367 seconds + +MP2 correlation energy: -0.707450373824291 + +Non-iterative calculation of MP2 took 0.327 cpu seconds and 0.017 walltime seconds at 0.777 Gflops/sec + +Total MP2 energy: -229.350762946308862 + +Beginning iterative solution of CCSDTQ equations: + +It. Correlation Energy T1 Residual T2 Residual T3 Residual T4 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------------------------------- + 1 -0.759137461775374 3.25613e-03 5.40842e-03 4.76332e-04 5.97398e-05 27293.020 5029.234 + 2 -0.765974884486305 7.18487e-04 2.77254e-03 7.09656e-05 1.22459e-04 244203.600 58948.004 + 3 -0.766487440625816 1.32975e-04 3.64550e-04 2.75956e-05 2.73513e-05 262494.763 41030.113 + 4 -0.766627050849718 3.32152e-05 1.33722e-04 1.03871e-05 1.53179e-05 268604.178 30213.125 + 5 -0.766644673851899 3.56368e-06 2.00731e-05 3.03661e-06 6.19820e-06 271772.975 22180.286 + + A I A I A I +-------------------------- -------------------------- -------------------------- + 19 17 -0.0299554171441 31 17 0.0116102497247 25 15 0.0075950397181 + 19 12 0.0287554436410 36 17 -0.0107605660048 21 14 -0.0074637602681 + 34 18 0.0227430138950 25 16 -0.0100926773043 45 17 0.0074527866712 + 23 18 0.0168081937403 27 16 -0.0094000341572 26 13 0.0072107996075 + 51 18 0.0135307664993 53 17 0.0076536679500 49 17 0.0065989280229 + + A B I J A B I J +------------------------------------ ------------------------------------ + 19 19 18 18 -0.1081697782235 23 19 12 18 -0.0301925687631 + 23 23 18 18 -0.0621082291040 36 19 18 18 -0.0274088510026 + 23 19 18 17 -0.0611153224610 19 36 18 18 -0.0274088510026 + 19 23 17 18 -0.0611153224610 19 23 12 18 -0.0229450277327 + 19 19 17 17 -0.0592567104918 23 19 18 12 -0.0229450277327 + 23 23 17 17 -0.0589716241287 19 23 18 17 -0.0213510875554 + 19 19 12 12 -0.0366992415363 23 19 17 18 -0.0213510875554 + 19 23 18 12 -0.0301925687631 + +It. Correlation Energy T1 Residual T2 Residual T3 Residual T4 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------------------------------- + 6 -0.766651521413942 1.58611e-06 7.29587e-06 1.11425e-06 3.07594e-06 276200.302 24018.124 + 7 -0.766653320142007 7.58206e-07 1.91374e-06 4.46696e-07 1.59012e-06 273767.645 22420.691 + 8 -0.766653963270390 2.39970e-07 4.88721e-07 1.78961e-07 8.04424e-07 274249.527 22247.423 + 9 -0.766654139150392 2.96953e-08 2.15357e-07 7.63380e-08 3.99978e-07 273563.775 22352.628 + 10 -0.766654208776797 1.60751e-08 6.46856e-08 3.45466e-08 1.98535e-07 271852.489 22006.045 + + A I A I A I +-------------------------- -------------------------- -------------------------- + 19 17 -0.0299484258823 31 17 0.0116110540428 25 15 0.0075947066740 + 19 12 0.0287525658366 36 17 -0.0107596967714 21 14 -0.0074645148725 + 34 18 0.0227447438009 25 16 -0.0100927354553 45 17 0.0074527511924 + 23 18 0.0168032993414 27 16 -0.0094003045394 26 13 0.0072119170024 + 51 18 0.0135313355816 53 17 0.0076540487120 49 17 0.0065991592359 + + A B I J A B I J +------------------------------------ ------------------------------------ + 19 19 18 18 -0.1081862316258 23 19 12 18 -0.0301945407259 + 23 23 18 18 -0.0621145852950 19 36 18 18 -0.0274134330092 + 23 19 18 17 -0.0611190783348 36 19 18 18 -0.0274134330092 + 19 23 17 18 -0.0611190783348 19 23 12 18 -0.0229470254900 + 19 19 17 17 -0.0592601149358 23 19 18 12 -0.0229470254900 + 23 23 17 17 -0.0589717799103 19 23 18 17 -0.0213536946113 + 19 19 12 12 -0.0366979941182 23 19 17 18 -0.0213536946113 + 19 23 18 12 -0.0301945407259 + +It. Correlation Energy T1 Residual T2 Residual T3 Residual T4 Residual CPU Time (s) Walltime (s) +------------------------------------------------------------------------------------------------- + +CCSDTQ iterations converged in 10 cycles and 270445.905 seconds (27044.591 s/it.) at 13.022 Gflops/sec + +Total CCSDTQ energy: -229.409966781261375 + + @CHECKOUT-I, Total execution time (CPU/WALL): 2444295.19/ 270694.34 seconds. +--executable xncc finished with status 0 in 270699.30 seconds (walltime). + The final electronic energy is -229.409966781261375 a.u. + This computation required 270712.42 seconds (walltime). diff --git a/furan/cc-pvdz/FromDenis.txt b/furan/cc-pvdz/FromDenis.txt deleted file mode 100644 index 990050e..0000000 --- a/furan/cc-pvdz/FromDenis.txt +++ /dev/null @@ -1,26 +0,0 @@ -Cfour -HF -228.643312572484575 -MP2 -229.350762946309 -0.707450373824 -CCSD -229.378285257894248 -0.734972685409664 -CC3 -229.409042621239877 -0.765730048755297 -CCSDT -229.407644692870491 -0.764332120385917 -CC4 -229.410178829371802 -0.766866256888079 -CCSDTQ -229.409966781261375 -0.76665420877679 - -Dalton -HF -228.643312572485 -MP2 -229.3507629658025451 -0.7074503933 -CC2 -229.360495928343 -0.7171833559 -CCSD -229.3782852538 -0.7349726813 -CC3 -229.4090426487 -0.7657300762 - -MRCC -HF -228.6433125723933699 -MP2 -229.350762954683 -0.7074503823 -CCSD -229.37828519649 -0.734972624097 -CC3 -229.409042619076 -0.7657300467 -CCSDT -229.407644699645 -0.7643321273 -CC4 -229.410178825868 -0.7668662535 - -CISD -229.260645347830 -0.6173327754 -CISDT -229.27741998 -0.6341074076 diff --git a/furan/cc-pvtz/furan.fci.out b/furan/cc-pvtz/furan.fci.out index 413e802..0061ab5 100644 --- a/furan/cc-pvtz/furan.fci.out +++ b/furan/cc-pvtz/furan.fci.out @@ -4018,3 +4018,125 @@ Iter Energy S^2 Residual 89 -229.5932737492 0.344E-03 1.0723408636 0.0202533844 57863.6245 91 -229.5932937164 0.337E-03 1.0723997899 0.0202572053 58401.4889 92 -229.5933275137 0.335E-03 1.0725988471 0.0202622625 59550.8759 + 94 -229.5932895963 0.329E-03 1.0717614467 0.0202627483 60592.6484 + 97 -229.5932543155 0.320E-03 1.0718276440 0.0202573025 62587.6969 + 104 -229.5930974387 0.304E-03 1.0701064023 0.0202441570 64162.5389 + 105 -229.5930624264 0.303E-03 1.0696836286 0.0202414126 64557.2191 + 109 -229.5929911112 0.295E-03 1.0688737807 0.0202331719 64848.9272 + 110 -229.5930015554 0.292E-03 1.0688095471 0.0202364751 65603.0269 + 111 -229.5930574564 0.295E-03 1.0694200502 0.0202428055 65868.3633 + 112 -229.5930889602 0.294E-03 1.0695838234 0.0202471578 66053.0479 + 113 -229.5931001754 0.292E-03 1.0697781424 0.0202466421 68121.0142 + 116 -229.5932131172 0.294E-03 1.0709311550 0.0202600762 68304.5601 + 118 -229.5931165916 0.297E-03 1.0699880192 0.0202472013 68343.3189 + 119 -229.5930881971 0.296E-03 1.0694929140 0.0202461471 68641.1378 + 120 -229.5931123087 0.287E-03 1.0699371651 0.0202428183 69276.1715 + 121 -229.5931099457 0.285E-03 1.0699824386 0.0202409578 69359.0295 + 122 -229.5930172246 0.297E-03 1.0691103838 0.0202285153 71194.5244 + 123 -229.5931324959 0.317E-03 1.0703331612 0.0202410801 72807.1707 + 128 -229.5931714881 0.311E-03 1.0710402816 0.0202449912 73229.7515 + 129 -229.5932061182 0.311E-03 1.0714690147 0.0202466378 73435.0964 + 130 -229.5931883496 0.309E-03 1.0711911884 0.0202445849 73589.2588 + 131 -229.5932040221 0.307E-03 1.0712044389 0.0202475357 74160.5929 + 132 -229.5931936221 0.305E-03 1.0711364955 0.0202459136 74215.7865 + 133 -229.5931862724 0.303E-03 1.0709808179 0.0202460811 74442.4799 + 134 -229.5931482062 0.303E-03 1.0704543318 0.0202430361 74998.6902 + 135 -229.5931248430 0.301E-03 1.0703481852 0.0202386779 75191.2029 + 136 -229.5931644007 0.302E-03 1.0706194330 0.0202450850 75808.4738 + 137 -229.5931401817 0.300E-03 1.0702364077 0.0202440874 76316.6385 + 138 -229.5932089606 0.302E-03 1.0710654783 0.0202511508 77304.9392 + 141 -229.5931825412 0.296E-03 1.0708327084 0.0202494728 77780.0351 + 142 -229.5931992059 0.294E-03 1.0708084628 0.0202538914 78194.0608 + 143 -229.5931841614 0.293E-03 1.0705573815 0.0202539811 79237.5683 + 145 -229.5931640136 0.289E-03 1.0702751475 0.0202512933 79254.0473 + 146 -229.5931739727 0.288E-03 1.0705762962 0.0202504750 79714.4618 + 147 -229.5931462074 0.287E-03 1.0702481090 0.0202472199 80142.3050 + 148 -229.5931716526 0.286E-03 1.0704851787 0.0202498872 80637.5013 + 149 -229.5931739785 0.284E-03 1.0705459320 0.0202492323 81190.4288 + 151 -229.5931597274 0.281E-03 1.0703870609 0.0202472561 83121.2068 + 154 -229.5931090938 0.277E-03 1.0697289010 0.0202445576 83390.8408 + 155 -229.5930988231 0.275E-03 1.0695045039 0.0202453331 84030.8974 + 156 -229.5930808189 0.271E-03 1.0693595424 0.0202440996 84356.1901 + 157 -229.5930886523 0.269E-03 1.0693447066 0.0202459658 84662.0666 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 23.536201 GB ] [ VIRT MEM : 27.610054 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 281339.682630 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 10485644 + +.. >>>>> [ RES MEM : 23.536201 GB ] [ VIRT MEM : 27.610054 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 281339.705640 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 10485644 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +Summary at N_det = 10485760 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.45768991 +# PT2 -0.13539874 0.00026900 +# rPT2 -0.13271186 0.00026366 +# +# E+PT2 -229.59308865 0.00026900 +# E+rPT2 -229.59040177 0.00026366 +# ============ ============================= + + N_det = 10485760 + N_states = 1 + + * State 1 + < S^2 > = 3.885695262140281E-003 + E = -229.457689910376 + Variance = 1.06934470661111 + PT norm = 0.142288319185474 + PT2 = -0.135398741913064 + rPT2 = -0.132711862094937 + E+PT2 = -229.593088652289 +/- 2.690014497441929E-004 + E+rPT2 = -229.590401772471 +/- 2.636633309688461E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.365817979737 + Vee = 238.637505330097 + Vecp = 0.000000000000000E+000 + T = 229.162392960475 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1358 -229.59952563 + -0.1384 -229.63518667 + -0.1430 -229.63894032 + -0.1658 -229.61615717 + -0.2102 -229.61275472 + -0.2699 -229.61273101 + -0.3355 -229.61436759 + =========== =================== + +Wall time: 78:10:38 + diff --git a/furan/cc-pvtz/furan.natorb.out b/furan/cc-pvtz/furan.natorb.out new file mode 100644 index 0000000..f48e595 --- /dev/null +++ b/furan/cc-pvtz/furan.natorb.out @@ -0,0 +1,369 @@ +Date: 27/10/2020 16:29:59 +=============== +Quantum Package +=============== + +Git Commit: Fixed NaN bug in DIIS +Git Date : Wed Sep 2 18:48:45 2020 +0200 +Git SHA1 : e2e500dad8e43be46add568575fc215d515b6a24 +EZFIO Dir : furan + + +Task server running : tcp://172.28.1.65:41279 +.. >>>>> [ IO READ: n_states ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017426 GB ] [ VIRT MEM : 0.201935 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.050090 s ] [ CPU TIME: 0.031848 s ] <<<<< .. + +.. >>>>> [ IO READ: read_wf ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017426 GB ] [ VIRT MEM : 0.201935 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.065347 s ] [ CPU TIME: 0.032562 s ] <<<<< .. + +.. >>>>> [ IO READ: elec_beta_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017426 GB ] [ VIRT MEM : 0.201935 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.078774 s ] [ CPU TIME: 0.033794 s ] <<<<< .. + +* mo_num 206 +.. >>>>> [ IO READ: elec_alpha_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.017624 GB ] [ VIRT MEM : 0.201935 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.081733 s ] [ CPU TIME: 0.034785 s ] <<<<< .. + + Read mo_occ +.. >>>>> [ IO READ: mo_class ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019432 GB ] [ VIRT MEM : 4.921257 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.154746 s ] [ CPU TIME: 2.436147 s ] <<<<< .. + +* Number of virtual MOs 0 + Virtual MOs: + +.. >>>>> [ IO READ: ao_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019432 GB ] [ VIRT MEM : 4.921257 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.186175 s ] [ CPU TIME: 4.407021 s ] <<<<< .. + + Read mo_coef + * mo_label Canonical +* Number of determinants 10485760 +* Dimension of the psi arrays 10485760 +* N_int 4 + Read psi_det +* Number of unique beta determinants 1152932 +* Number of unique alpha determinants 1052165 + Read psi_coef 10485760 1 +.. >>>>> [ IO READ: weight_one_e_dm ] <<<<< .. + +.. >>>>> [ RES MEM : 3.827347 GB ] [ VIRT MEM : 8.821079 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 264.899781 s ] [ CPU TIME: 8670.624614 s ] <<<<< .. + +* Number of active MOs 201 +* Number of core MOs 5 +* Number of inactive MOs 0 + Core MOs: + 1 2 3 4 5 + Active MOs: + 6 7 8 9 10 11 + 12 13 14 15 16 17 + 18 19 20 21 22 23 + 24 25 26 27 28 29 + 30 31 32 33 34 35 + 36 37 38 39 40 41 + 42 43 44 45 46 47 + 48 49 50 51 52 53 + 54 55 56 57 58 59 + 60 61 62 63 64 65 + 66 67 68 69 70 71 + 72 73 74 75 76 77 + 78 79 80 81 82 83 + 84 85 86 87 88 89 + 90 91 92 93 94 95 + 96 97 98 99 100 101 + 102 103 104 105 106 107 + 108 109 110 111 112 113 + 114 115 116 117 118 119 + 120 121 122 123 124 125 + 126 127 128 129 130 131 + 132 133 134 135 136 137 + 138 139 140 141 142 143 + 144 145 146 147 148 149 + 150 151 152 153 154 155 + 156 157 158 159 160 161 + 162 163 164 165 166 167 + 168 169 170 171 172 173 + 174 175 176 177 178 179 + 180 181 182 183 184 185 + 186 187 188 189 190 191 + 192 193 194 195 196 197 + 198 199 200 201 202 203 + 204 205 206 + Core, Inactive and Active MOs: + 1 2 3 4 5 6 + 7 8 9 10 11 12 + 13 14 15 16 17 18 + 19 20 21 22 23 24 + 25 26 27 28 29 30 + 31 32 33 34 35 36 + 37 38 39 40 41 42 + 43 44 45 46 47 48 + 49 50 51 52 53 54 + 55 56 57 58 59 60 + 61 62 63 64 65 66 + 67 68 69 70 71 72 + 73 74 75 76 77 78 + 79 80 81 82 83 84 + 85 86 87 88 89 90 + 91 92 93 94 95 96 + 97 98 99 100 101 102 + 103 104 105 106 107 108 + 109 110 111 112 113 114 + 115 116 117 118 119 120 + 121 122 123 124 125 126 + 127 128 129 130 131 132 + 133 134 135 136 137 138 + 139 140 141 142 143 144 + 145 146 147 148 149 150 + 151 152 153 154 155 156 + 157 158 159 160 161 162 + 163 164 165 166 167 168 + 169 170 171 172 173 174 + 175 176 177 178 179 180 + 181 182 183 184 185 186 + 187 188 189 190 191 192 + 193 194 195 196 197 198 + 199 200 201 202 203 204 + 205 206 + +.. >>>>> [ RES MEM : 3.827652 GB ] [ VIRT MEM : 8.821079 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 264.920861 s ] [ CPU TIME: 8672.120888 s ] <<<<< .. + +MOs are now **Natural** + +Eigenvalues +----------- + +======== ================ ================ + MO Eigenvalue Cumulative +======== ================ ================ + 1 2.0000000000 2.0000000000 + 2 2.0000000000 4.0000000000 + 3 2.0000000000 6.0000000000 + 4 2.0000000000 8.0000000000 + 5 2.0000000000 10.0000000000 + 6 1.9881093714 11.9881093714 + 7 1.9850993704 13.9732087418 + 8 1.9835069109 15.9567156527 + 9 1.9797901650 17.9365058177 + 10 1.9796062349 19.9161120526 + 11 1.9786801155 21.8947921680 + 12 1.9747772950 23.8695694630 + 13 1.9745448275 25.8441142905 + 14 1.9735545614 27.8176688519 + 15 1.9713025120 29.7889713639 + 16 1.9706361662 31.7596075301 + 17 1.9594889560 33.7190964861 + 18 1.9444039067 35.6635003928 + 19 0.0479886536 35.7114890464 + 20 0.0276451029 35.7391341493 + 21 0.0196879617 35.7588221110 + 22 0.0185365919 35.7773587029 + 23 0.0140560795 35.7914147824 + 24 0.0131988032 35.8046135855 + 25 0.0118043868 35.8164179723 + 26 0.0114340053 35.8278519776 + 27 0.0104142692 35.8382662468 + 28 0.0095880509 35.8478542978 + 29 0.0084560263 35.8563103240 + 30 0.0082166703 35.8645269943 + 31 0.0075032098 35.8720302042 + 32 0.0064029766 35.8784331808 + 33 0.0057386479 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35.9742358696 + 65 0.0009834747 35.9752193442 + 66 0.0009724616 35.9761918059 + 67 0.0009224900 35.9771142958 + 68 0.0008763677 35.9779906636 + 69 0.0007996581 35.9787903216 + 70 0.0007216672 35.9795119888 + 71 0.0006813152 35.9801933040 + 72 0.0006621076 35.9808554116 + 73 0.0006451966 35.9815006082 + 74 0.0005639960 35.9820646042 + 75 0.0005474465 35.9826120507 + 76 0.0005315088 35.9831435594 + 77 0.0005285737 35.9836721332 + 78 0.0005094481 35.9841815813 + 79 0.0005042781 35.9846858594 + 80 0.0004703166 35.9851561760 + 81 0.0004338478 35.9855900238 + 82 0.0004190848 35.9860091085 + 83 0.0004096964 35.9864188050 + 84 0.0004013001 35.9868201050 + 85 0.0003727981 35.9871929031 + 86 0.0003727961 35.9875656991 + 87 0.0003489820 35.9879146812 + 88 0.0003401766 35.9882548578 + 89 0.0003388421 35.9885936999 + 90 0.0003360155 35.9889297154 + 91 0.0003299120 35.9892596274 + 92 0.0003263634 35.9895859908 + 93 0.0003127846 35.9898987754 + 94 0.0003071382 35.9902059136 + 95 0.0003048517 35.9905107653 + 96 0.0002917660 35.9908025313 + 97 0.0002915579 35.9910940891 + 98 0.0002899037 35.9913839928 + 99 0.0002759210 35.9916599138 + 100 0.0002741472 35.9919340610 + 101 0.0002689332 35.9922029942 + 102 0.0002624715 35.9924654657 + 103 0.0002484800 35.9927139457 + 104 0.0002275804 35.9929415261 + 105 0.0002209952 35.9931625213 + 106 0.0002112727 35.9933737940 + 107 0.0002092353 35.9935830293 + 108 0.0002052705 35.9937882999 + 109 0.0001923053 35.9939806051 + 110 0.0001889207 35.9941695259 + 111 0.0001885978 35.9943581237 + 112 0.0001881830 35.9945463067 + 113 0.0001783550 35.9947246617 + 114 0.0001750368 35.9948996984 + 115 0.0001719309 35.9950716294 + 116 0.0001665082 35.9952381376 + 117 0.0001655235 35.9954036611 + 118 0.0001642167 35.9955678778 + 119 0.0001565662 35.9957244440 + 120 0.0001503911 35.9958748351 + 121 0.0001499119 35.9960247470 + 122 0.0001430900 35.9961678370 + 123 0.0001335052 35.9963013422 + 124 0.0001310143 35.9964323565 + 125 0.0001306707 35.9965630272 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0.0000439169 35.9989032424 + 157 0.0000438124 35.9989470548 + 158 0.0000402577 35.9989873125 + 159 0.0000381267 35.9990254392 + 160 0.0000377450 35.9990631842 + 161 0.0000370760 35.9991002601 + 162 0.0000370295 35.9991372896 + 163 0.0000359092 35.9991731988 + 164 0.0000358067 35.9992090055 + 165 0.0000351280 35.9992441335 + 166 0.0000346583 35.9992787918 + 167 0.0000341951 35.9993129869 + 168 0.0000331527 35.9993461396 + 169 0.0000331300 35.9993792696 + 170 0.0000326214 35.9994118910 + 171 0.0000312586 35.9994431496 + 172 0.0000308896 35.9994740391 + 173 0.0000288430 35.9995028821 + 174 0.0000277974 35.9995306795 + 175 0.0000272993 35.9995579789 + 176 0.0000271911 35.9995851700 + 177 0.0000255205 35.9996106905 + 178 0.0000246076 35.9996352981 + 179 0.0000244977 35.9996597957 + 180 0.0000233289 35.9996831246 + 181 0.0000219873 35.9997051119 + 182 0.0000214427 35.9997265546 + 183 0.0000200285 35.9997465831 + 184 0.0000199680 35.9997665511 + 185 0.0000188956 35.9997854467 + 186 0.0000176171 35.9998030638 + 187 0.0000169105 35.9998199743 + 188 0.0000155612 35.9998355355 + 189 0.0000149994 35.9998505349 + 190 0.0000147668 35.9998653017 + 191 0.0000137114 35.9998790131 + 192 0.0000121805 35.9998911936 + 193 0.0000120527 35.9999032462 + 194 0.0000120278 35.9999152740 + 195 0.0000111637 35.9999264377 + 196 0.0000111035 35.9999375412 + 197 0.0000088774 35.9999464185 + 198 0.0000086580 35.9999550766 + 199 0.0000083560 35.9999634326 + 200 0.0000083430 35.9999717755 + 201 0.0000075515 35.9999793270 + 202 0.0000063448 35.9999856717 + 203 0.0000039911 35.9999896628 + 204 0.0000038722 35.9999935350 + 205 0.0000036403 35.9999971753 + 206 0.0000028247 36.0000000000 +======== ================ ================ + + +.. >>>>> [ RES MEM : 3.833748 GB ] [ VIRT MEM : 8.927223 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 264.974530 s ] [ CPU TIME: 8675.916461 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_md5 ] <<<<< .. + +.. >>>>> [ RES MEM : 3.833748 GB ] [ VIRT MEM : 8.927223 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 264.975583 s ] [ CPU TIME: 8675.991119 s ] <<<<< .. + +* Saved determinants 1 +Wall time: 0:04:30 + diff --git a/furan/cc-pvtz/furan.nofci.out b/furan/cc-pvtz/furan.nofci.out new file mode 100644 index 0000000..654e343 --- /dev/null +++ b/furan/cc-pvtz/furan.nofci.out @@ -0,0 +1,4568 @@ +Date: 27/10/2020 16:34:29 +=============== +Quantum Package +=============== + +Git Commit: Fixed NaN bug in DIIS +Git Date : Wed Sep 2 18:48:45 2020 +0200 +Git SHA1 : e2e500dad8e43be46add568575fc215d515b6a24 +EZFIO Dir : furan + + +Task server running : tcp://172.28.1.65:41279 +* mo_num 206 +.. >>>>> [ IO READ: mo_class ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019283 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.000990 s ] [ CPU TIME: 0.147188 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_two_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.019283 GB ] [ VIRT MEM : 4.922047 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.003004 s ] [ CPU TIME: 0.266390 s ] <<<<< .. + +* N_int 4 + MO map initialized: 227303181 +.. >>>>> [ IO READ: io_ao_two_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 0.020992 GB ] [ VIRT MEM : 4.927048 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.025873 s ] [ CPU TIME: 1.615725 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.020992 GB ] [ VIRT MEM : 4.927048 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.050580 s ] [ CPU TIME: 3.070842 s ] <<<<< .. + + AO map initialized : 384490315 +.. >>>>> [ IO READ: ao_power ] <<<<< .. + +.. >>>>> [ RES MEM : 0.024220 GB ] [ VIRT MEM : 4.928890 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.067173 s ] [ CPU TIME: 4.038930 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_prim_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.024269 GB ] [ VIRT MEM : 4.928890 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.070877 s ] [ CPU TIME: 4.263010 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_expo ] <<<<< .. + +.. >>>>> [ RES MEM : 0.024315 GB ] [ VIRT MEM : 4.928890 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.077272 s ] [ CPU TIME: 4.586903 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_coef ] <<<<< .. + +.. >>>>> [ RES MEM : 0.024403 GB ] [ VIRT MEM : 4.928890 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.082930 s ] [ CPU TIME: 4.878062 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_nucl ] <<<<< .. + +.. >>>>> [ RES MEM : 0.024635 GB ] [ VIRT MEM : 4.928890 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.087280 s ] [ CPU TIME: 5.147585 s ] <<<<< .. + +.. >>>>> [ IO READ: ao_integrals_threshold ] <<<<< .. + +.. >>>>> [ RES MEM : 0.024635 GB ] [ VIRT MEM : 4.928890 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.088613 s ] [ CPU TIME: 5.233334 s ] <<<<< .. + + Providing the AO integrals +.. >>>>> [ IO READ: nucl_num ] <<<<< .. + +.. >>>>> [ RES MEM : 0.026108 GB ] [ VIRT MEM : 5.134129 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.215183 s ] [ CPU TIME: 12.785062 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_label ] <<<<< .. + +.. >>>>> [ RES MEM : 0.026260 GB ] [ VIRT MEM : 5.134129 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.218910 s ] [ CPU TIME: 13.024423 s ] <<<<< .. + +.. >>>>> [ IO READ: nucl_charge ] <<<<< .. + +.. >>>>> [ RES MEM : 0.026291 GB ] [ VIRT MEM : 5.134129 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.236160 s ] [ CPU TIME: 14.126668 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 0.026302 GB ] [ VIRT MEM : 5.134129 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 0.239227 s ] [ CPU TIME: 14.323670 s ] <<<<< .. + + +Nuclear Coordinates (Angstroms) +=============================== + +================ ============ ============ ============ ============ + Atom Charge X Y Z +================ ============ ============ ============ ============ +C 6.000000 0.000000 1.092041 -0.317778 +C 6.000000 0.000000 -1.092041 -0.317778 +C 6.000000 0.000000 0.716234 0.986050 +C 6.000000 0.000000 -0.716234 0.986050 +O 8.000000 0.000000 0.000000 -1.132150 +H 1.000000 0.000000 2.044409 -0.813693 +H 1.000000 0.000000 -2.044409 -0.813693 +H 1.000000 0.000000 1.371462 1.837134 +H 1.000000 0.000000 -1.371462 1.837134 +================ ============ ============ ============ ============ + + Sorting the map + AO integrals provided: + Size of AO map : 2246.25938415527 MB + Number of AO integrals : 188930778 + cpu time : 2327.00046000000 s + wall time : 38.3217859268188 s ( x 60.7226517168003 ) + + AO -> MO integrals transformation + --------------------------------- + + Read mo_coef +.. >>>>> [ IO READ: mo_integrals_threshold ] <<<<< .. + +.. >>>>> [ RES MEM : 1.974586 GB ] [ VIRT MEM : 7.502449 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 38.508648 s ] [ CPU TIME: 2333.664590 s ] <<<<< .. + + Buffers : 364.4832 MB / core + 29.36170 % in 29.7232389450073 s 3048.31726837158 MB + 42.97872 % in 41.6294198036194 s 3179.16926193237 MB + 67.65958 % in 55.9997758865356 s 3135.88913726807 MB + 88.93617 % in 68.6770470142365 s 3158.65235137939 MB + Molecular integrals provided: + Size of MO map 3166.79978179932 MB + Number of MO integrals: 162965666 + cpu time : 5289.13246300000 s + wall time : 85.0493991374969 s ( x 62.1889456790778 ) +.. >>>>> [ IO READ: n_states ] <<<<< .. + +.. >>>>> [ RES MEM : 6.649330 GB ] [ VIRT MEM : 12.218460 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.500003 s ] [ CPU TIME: 7624.181316 s ] <<<<< .. + + * mo_label Natural +.. >>>>> [ IO READ: read_wf ] <<<<< .. + +.. >>>>> [ RES MEM : 6.649330 GB ] [ VIRT MEM : 12.218460 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.501934 s ] [ CPU TIME: 7624.317861 s ] <<<<< .. + +* Number of determinants 1 +* Dimension of the psi arrays 100000 + Read psi_coef 1 1 +.. >>>>> [ IO READ: elec_beta_num ] <<<<< .. + +.. >>>>> [ RES MEM : 6.649517 GB ] [ VIRT MEM : 12.218460 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.520616 s ] [ CPU TIME: 7625.639404 s ] <<<<< .. + +.. >>>>> [ IO READ: elec_alpha_num ] <<<<< .. + +.. >>>>> [ RES MEM : 6.649517 GB ] [ VIRT MEM : 12.218460 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.521457 s ] [ CPU TIME: 7625.698989 s ] <<<<< .. + + Read psi_det +.. >>>>> [ IO READ: do_pt2 ] <<<<< .. + +.. >>>>> [ RES MEM : 6.655521 GB ] [ VIRT MEM : 12.224430 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.560949 s ] [ CPU TIME: 7628.494297 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 6.655594 GB ] [ VIRT MEM : 12.224430 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.595045 s ] [ CPU TIME: 7630.880158 s ] <<<<< .. + +.. >>>>> [ IO READ: selection_factor ] <<<<< .. + +.. >>>>> [ RES MEM : 6.655594 GB ] [ VIRT MEM : 12.224430 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.595892 s ] [ CPU TIME: 7630.940041 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_max ] <<<<< .. + +.. >>>>> [ RES MEM : 6.655594 GB ] [ VIRT MEM : 12.230400 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.596994 s ] [ CPU TIME: 7631.017754 s ] <<<<< .. + +.. >>>>> [ IO READ: s2_eig ] <<<<< .. + +.. >>>>> [ RES MEM : 6.671875 GB ] [ VIRT MEM : 12.253860 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.600301 s ] [ CPU TIME: 7631.242825 s ] <<<<< .. + +.. >>>>> [ IO READ: variance_max ] <<<<< .. + +.. >>>>> [ RES MEM : 6.671875 GB ] [ VIRT MEM : 12.253860 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.601093 s ] [ CPU TIME: 7631.298683 s ] <<<<< .. + +.. >>>>> [ IO READ: distributed_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 6.671875 GB ] [ VIRT MEM : 12.253860 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.616163 s ] [ CPU TIME: 7632.351556 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_max_full ] <<<<< .. + +.. >>>>> [ RES MEM : 6.671875 GB ] [ VIRT MEM : 12.253860 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 123.616965 s ] [ CPU TIME: 7632.408033 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_integrals_e_n ] <<<<< .. + +.. >>>>> [ RES MEM : 8.674786 GB ] [ VIRT MEM : 14.259727 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.840304 s ] [ CPU TIME: 7705.129443 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_integrals_e_n ] <<<<< .. + +.. >>>>> [ RES MEM : 8.674786 GB ] [ VIRT MEM : 14.259727 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.849535 s ] [ CPU TIME: 7705.130438 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_integrals_kinetic ] <<<<< .. + +.. >>>>> [ RES MEM : 8.676453 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.885519 s ] [ CPU TIME: 7706.819276 s ] <<<<< .. + +.. >>>>> [ IO READ: io_ao_integrals_kinetic ] <<<<< .. + +.. >>>>> [ RES MEM : 8.676453 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.886416 s ] [ CPU TIME: 7706.881848 s ] <<<<< .. + +.. >>>>> [ IO READ: io_mo_one_e_integrals ] <<<<< .. + +.. >>>>> [ RES MEM : 8.676453 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.899636 s ] [ CPU TIME: 7707.804852 s ] <<<<< .. + + Providing the one-electron integrals +.. >>>>> [ IO READ: do_pseudo ] <<<<< .. + +.. >>>>> [ RES MEM : 8.676628 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.914394 s ] [ CPU TIME: 7708.834606 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_relative_error ] <<<<< .. + +.. >>>>> [ RES MEM : 8.676628 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.977457 s ] [ CPU TIME: 7713.264356 s ] <<<<< .. + +.. >>>>> [ IO READ: correlation_energy_ratio_max ] <<<<< .. + +.. >>>>> [ RES MEM : 8.676628 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.978571 s ] [ CPU TIME: 7713.343080 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.676628 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.979392 s ] [ CPU TIME: 7713.400597 s ] <<<<< .. + + Read n_states_diag +.. >>>>> [ IO READ: io_nuclear_repulsion ] <<<<< .. + +.. >>>>> [ RES MEM : 8.676628 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.980680 s ] [ CPU TIME: 7713.491308 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.676628 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.981039 s ] [ CPU TIME: 7713.516963 s ] <<<<< .. + +* Nuclear repulsion energy 161.1082297787890 +.. >>>>> [ IO READ: weight_one_e_dm ] <<<<< .. + +.. >>>>> [ RES MEM : 8.676628 GB ] [ VIRT MEM : 14.325947 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.981929 s ] [ CPU TIME: 7713.579412 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_max ] <<<<< .. + +.. >>>>> [ RES MEM : 8.684780 GB ] [ VIRT MEM : 14.331917 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.992241 s ] [ CPU TIME: 7714.307147 s ] <<<<< .. + +.. >>>>> [ IO READ: threshold_generators ] <<<<< .. + +.. >>>>> [ RES MEM : 8.684780 GB ] [ VIRT MEM : 14.331917 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.993024 s ] [ CPU TIME: 7714.362393 s ] <<<<< .. + +* Target maximum memory (GB) 170 +.. >>>>> [ IO READ: threshold_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 8.684780 GB ] [ VIRT MEM : 14.331917 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.994531 s ] [ CPU TIME: 7714.468204 s ] <<<<< .. + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.685020 GB ] [ VIRT MEM : 14.331917 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 128.996702 s ] [ CPU TIME: 7714.613266 s ] <<<<< .. + +* Energy of state 1 -228.7049349645350 +* S^2 of state 1 0.000000000000000 +* Saved determinants 1 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 1 +* Number of unique alpha determinants 1 +.. >>>>> [ IO READ: weight_selection ] <<<<< .. + +.. >>>>> [ RES MEM : 8.685093 GB ] [ VIRT MEM : 14.344120 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 129.091014 s ] [ CPU TIME: 7721.258095 s ] <<<<< .. + + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +.. >>>>> [ IO READ: pseudo_sym ] <<<<< .. + +.. >>>>> [ RES MEM : 8.685093 GB ] [ VIRT MEM : 14.344120 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 129.091946 s ] [ CPU TIME: 7721.324092 s ] <<<<< .. + +.. >>>>> [ IO READ: h0_type ] <<<<< .. + +.. >>>>> [ RES MEM : 8.685093 GB ] [ VIRT MEM : 14.350090 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 129.094159 s ] [ CPU TIME: 7721.480881 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.685093 GB ] [ VIRT MEM : 14.350090 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 129.094628 s ] [ CPU TIME: 7721.514054 s ] <<<<< .. + +* Number of generators 1 + +.. >>>>> [ RES MEM : 8.685093 GB ] [ VIRT MEM : 14.350090 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 129.095017 s ] [ CPU TIME: 7721.542034 s ] <<<<< .. + +* Number of selectors 1 +* Number of comb teeth 1 +* Number of core MOs 5 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.7049349645350 +* Estimated memory/thread (Gb) 0.2384185791015625E-06 +* Number of virtual MOs 0 +* Number of active MOs 201 + Active MOs: + 6 7 8 9 10 11 + 12 13 14 15 16 17 + 18 19 20 21 22 23 + 24 25 26 27 28 29 + 30 31 32 33 34 35 + 36 37 38 39 40 41 + 42 43 44 45 46 47 + 48 49 50 51 52 53 + 54 55 56 57 58 59 + 60 61 62 63 64 65 + 66 67 68 69 70 71 + 72 73 74 75 76 77 + 78 79 80 81 82 83 + 84 85 86 87 88 89 + 90 91 92 93 94 95 + 96 97 98 99 100 101 + 102 103 104 105 106 107 + 108 109 110 111 112 113 + 114 115 116 117 118 119 + 120 121 122 123 124 125 + 126 127 128 129 130 131 + 132 133 134 135 136 137 + 138 139 140 141 142 143 + 144 145 146 147 148 149 + 150 151 152 153 154 155 + 156 157 158 159 160 161 + 162 163 164 165 166 167 + 168 169 170 171 172 173 + 174 175 176 177 178 179 + 180 181 182 183 184 185 + 186 187 188 189 190 191 + 192 193 194 195 196 197 + 198 199 200 201 202 203 + 204 205 206 +* Number of inactive MOs 0 +.. >>>>> [ IO READ: pert_2rdm ] <<<<< .. + +.. >>>>> [ RES MEM : 8.686672 GB ] [ VIRT MEM : 14.366783 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 129.140552 s ] [ CPU TIME: 7724.064437 s ] <<<<< .. + +.. >>>>> [ IO READ: pruning ] <<<<< .. + +.. >>>>> [ RES MEM : 8.686913 GB ] [ VIRT MEM : 14.366783 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 136.949785 s ] [ CPU TIME: 7744.234028 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.687389 GB ] [ VIRT MEM : 14.366783 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 136.955979 s ] [ CPU TIME: 7744.653888 s ] <<<<< .. + +* Number of generators 1 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Saved determinants 5 +* Number of unique beta determinants 5 +* Number of unique alpha determinants 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.687397 GB ] [ VIRT MEM : 14.366791 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 136.999704 s ] [ CPU TIME: 7747.704436 s ] <<<<< .. + +* Number of selectors 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio -0.2642772445189763E-02 + +Summary at N_det = 5 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.70493496 +# PT2 -1.18969291 0.00000000 +# rPT2 -0.79729600 0.00000000 +# +# E+PT2 -229.89462787 0.00000000 +# E+rPT2 -229.50223096 0.00000000 +# ============ ============================= + + N_det = 5 + N_states = 1 + + * State 1 + < S^2 > = 0.000000000000000E+000 + E = -228.704934964535 + Variance = 3.94097846340409 + PT norm = 0.701540906201389 + PT2 = -1.18969290887493 + rPT2 = -0.797295996039776 + E+PT2 = -229.894627873410 +/- 0.000000000000000E+000 + E+rPT2 = -229.502230960575 +/- 0.000000000000000E+000 + + ----- +.. >>>>> [ IO READ: io_mo_integrals_pseudo ] <<<<< .. + +.. >>>>> [ RES MEM : 8.687397 GB ] [ VIRT MEM : 14.366791 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 137.001901 s ] [ CPU TIME: 7747.859772 s ] <<<<< .. + + Energy components + ================= + + Vnn : Nucleus-Nucleus potential energy + Ven : Electron-Nucleus potential energy + Vee : Electron-Electron potential energy + Vecp : Potential energy of the pseudo-potentials + T : Electronic kinetic energy + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.266764137126 + Vee = 239.783845933426 + Vecp = 0.000000000000000E+000 + T = 228.669753460375 + + +.. >>>>> [ IO READ: energy_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 8.687626 GB ] [ VIRT MEM : 14.366791 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 137.044655 s ] [ CPU TIME: 7750.856642 s ] <<<<< .. + +.. >>>>> [ IO READ: pt2_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 8.687626 GB ] [ VIRT MEM : 14.366791 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 137.048461 s ] [ CPU TIME: 7751.115046 s ] <<<<< .. + +.. >>>>> [ IO READ: n_det_iterations ] <<<<< .. + +.. >>>>> [ RES MEM : 8.687626 GB ] [ VIRT MEM : 14.366791 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 137.052075 s ] [ CPU TIME: 7751.360495 s ] <<<<< .. + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.687862 GB ] [ VIRT MEM : 14.366791 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 137.077452 s ] [ CPU TIME: 7753.119452 s ] <<<<< .. + +* Energy of state 1 -228.7334168477461 +* S^2 of state 1 0.000000000000000 +* Saved determinants 5 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 5 +* Number of unique alpha determinants 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.688026 GB ] [ VIRT MEM : 14.366791 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 137.128542 s ] [ CPU TIME: 7756.697230 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 8.688026 GB ] [ VIRT MEM : 14.366791 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 137.128933 s ] [ CPU TIME: 7756.725497 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.7334168477461 + +.. >>>>> [ RES MEM : 8.694569 GB ] [ VIRT MEM : 14.372761 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 137.137135 s ] [ CPU TIME: 7757.305915 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 8.694569 GB ] [ VIRT MEM : 14.372761 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 137.137542 s ] [ CPU TIME: 7757.334763 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 5 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2289864551275968E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.7389426786 0.137 3.9185897182 0.3428888926 3.6880 + 4 -229.8531848587 0.00 3.8677674678 0.4266462800 3.6882 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.700115 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 140.854202 s ] [ CPU TIME: 7789.993807 s ] <<<<< .. + +* Number of generators 5 + +.. >>>>> [ RES MEM : 8.700115 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 140.854610 s ] [ CPU TIME: 7790.022761 s ] <<<<< .. + +* Number of selectors 5 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.3251713951989021E-01 + +Summary at N_det = 5 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.73341685 +# PT2 -1.11976801 0.00000000 +# rPT2 -0.78489534 0.00000000 +# +# E+PT2 -229.85318486 0.00000000 +# E+rPT2 -229.51831218 0.00000000 +# ============ ============================= + + N_det = 5 + N_states = 1 + + * State 1 + < S^2 > = 0.000000000000000E+000 + E = -228.733416847746 + Variance = 3.86776746783035 + PT norm = 0.653181659227952 + PT2 = -1.11976801092552 + rPT2 = -0.784895335768418 + E+PT2 = -229.853184858672 +/- 0.000000000000000E+000 + E+rPT2 = -229.518312183514 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.355547232896 + Vee = 239.780961698066 + Vecp = 0.000000000000000E+000 + T = 228.732938908296 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7973 -230.53616741 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.700314 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 140.910040 s ] [ CPU TIME: 7793.792304 s ] <<<<< .. + +* Energy of state 1 -228.7551465252178 +* S^2 of state 1 0.3654049137933620E-01 +* Saved determinants 10 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 7 +* Number of unique alpha determinants 7 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.700489 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 140.961003 s ] [ CPU TIME: 7797.251202 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 8.700489 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 140.961404 s ] [ CPU TIME: 7797.279130 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.7551465252178 + +.. >>>>> [ RES MEM : 8.700489 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 140.965231 s ] [ CPU TIME: 7797.546515 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 8.700489 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 140.965614 s ] [ CPU TIME: 7797.573206 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 10 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2299601100385189E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.7081478119 0.139 3.7988965697 0.3078027421 3.8759 + 9 -229.8212555312 0.00 3.8106125223 0.3789987718 3.8761 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.701031 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 144.858387 s ] [ CPU TIME: 7849.260798 s ] <<<<< .. + +* Number of generators 10 + +.. >>>>> [ RES MEM : 8.701031 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 144.858780 s ] [ CPU TIME: 7849.288353 s ] <<<<< .. + +* Number of selectors 10 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.5858407150153518E-01 + +Summary at N_det = 10 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.75514653 +# PT2 -1.06610901 0.00000000 +# rPT2 -0.77310367 0.00000000 +# +# E+PT2 -229.82125553 0.00000000 +# E+rPT2 -229.52825019 0.00000000 +# ============ ============================= + + N_det = 10 + N_states = 1 + + * State 1 + < S^2 > = 3.654049137933620E-002 + E = -228.755146525218 + Variance = 3.81061252232975 + PT norm = 0.615628761319305 + PT2 = -1.06610900594115 + rPT2 = -0.773103666058929 + E+PT2 = -229.821255531159 +/- 0.000000000000000E+000 + E+rPT2 = -229.528250191277 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.420597310419 + Vee = 239.774235426831 + Vecp = 0.000000000000000E+000 + T = 228.782985579581 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7849 -230.17982121 + -0.7973 -230.36214419 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.701069 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 144.908654 s ] [ CPU TIME: 7852.650318 s ] <<<<< .. + +* Energy of state 1 -228.7736826900622 +* S^2 of state 1 0.4205370227240829E-01 +* Saved determinants 20 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 12 +* Number of unique alpha determinants 12 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.701164 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 144.963436 s ] [ CPU TIME: 7856.437046 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 8.701164 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 144.963829 s ] [ CPU TIME: 7856.465512 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.7736826900622 + +.. >>>>> [ RES MEM : 8.701164 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 144.967625 s ] [ CPU TIME: 7856.733690 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 8.701164 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 144.968006 s ] [ CPU TIME: 7856.761118 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 20 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2319074198603630E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6525722592 0.172 3.7529883329 0.2695714590 4.0944 + 19 -229.7965632430 0.00 3.7456665981 0.3506854415 4.0947 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.701164 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 149.084246 s ] [ CPU TIME: 7947.277738 s ] <<<<< .. + +* Number of generators 20 + +.. >>>>> [ RES MEM : 8.701164 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 149.084601 s ] [ CPU TIME: 7947.302017 s ] <<<<< .. + +* Number of selectors 20 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8088613009620557E-01 + +Summary at N_det = 20 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.77368269 +# PT2 -1.02288055 0.00000000 +# rPT2 -0.75730479 0.00000000 +# +# E+PT2 -229.79656324 0.00000000 +# E+rPT2 -229.53098748 0.00000000 +# ============ ============================= + + N_det = 20 + N_states = 1 + + * State 1 + < S^2 > = 4.205370227240829E-002 + E = -228.773682690062 + Variance = 3.74566659814474 + PT norm = 0.592186998762511 + PT2 = -1.02288055292685 + rPT2 = -0.757304788736266 + E+PT2 = -229.796563242989 +/- 0.000000000000000E+000 + E+rPT2 = -229.530987478798 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.421127489723 + Vee = 239.740306346793 + Vecp = 0.000000000000000E+000 + T = 228.798908674079 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7731 -229.66219686 + -0.7849 -229.86824684 + -0.7973 -230.07519775 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.701817 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 149.134738 s ] [ CPU TIME: 7950.626254 s ] <<<<< .. + +* Energy of state 1 -228.7927824063258 +* S^2 of state 1 0.5913828857592524E-01 +* Saved determinants 40 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 18 +* Number of unique alpha determinants 17 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.701866 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 149.185734 s ] [ CPU TIME: 7954.061950 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 8.701866 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 149.186121 s ] [ CPU TIME: 7954.089039 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.7927824063258 + +.. >>>>> [ RES MEM : 8.701866 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 149.189998 s ] [ CPU TIME: 7954.355122 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 8.701866 GB ] [ VIRT MEM : 14.378010 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 149.190387 s ] [ CPU TIME: 7954.381864 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 40 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2358020395040512E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6077982944 0.195 3.6544755139 0.2418223596 5.0587 + 38 -229.7742753722 0.00 3.6819034980 0.3248351004 5.0592 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.702389 GB ] [ VIRT MEM : 14.378151 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 154.271251 s ] [ CPU TIME: 8144.748258 s ] <<<<< .. + +* Number of generators 40 + +.. >>>>> [ RES MEM : 8.702389 GB ] [ VIRT MEM : 14.378151 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 154.271577 s ] [ CPU TIME: 8144.768515 s ] <<<<< .. + +* Number of selectors 40 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1037348380696177 + +Summary at N_det = 40 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.79278241 +# PT2 -0.98149297 0.00000000 +# rPT2 -0.74084161 0.00000000 +# +# E+PT2 -229.77427537 0.00000000 +# E+rPT2 -229.53362401 0.00000000 +# ============ ============================= + + N_det = 40 + N_states = 1 + + * State 1 + < S^2 > = 5.913828857592524E-002 + E = -228.792782406326 + Variance = 3.68190349799974 + PT norm = 0.569943067678712 + PT2 = -0.981492965866232 + rPT2 = -0.740841607814877 + E+PT2 = -229.774275372192 +/- 0.000000000000000E+000 + E+rPT2 = -229.533624014141 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.428361346522 + Vee = 239.710738572231 + Vecp = 0.000000000000000E+000 + T = 228.816610589176 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7573 -229.65226786 + -0.7731 -229.65702562 + -0.7849 -229.77101328 + -0.7973 -229.92267122 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.703808 GB ] [ VIRT MEM : 14.380062 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 154.332868 s ] [ CPU TIME: 8148.520835 s ] <<<<< .. + +* Energy of state 1 -228.8198994088955 +* S^2 of state 1 0.3711488752774673E-01 +* Saved determinants 80 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 30 +* Number of unique alpha determinants 31 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.704056 GB ] [ VIRT MEM : 14.380230 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 154.388492 s ] [ CPU TIME: 8152.036237 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 8.704056 GB ] [ VIRT MEM : 14.380230 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 154.388897 s ] [ CPU TIME: 8152.062903 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.8198994088955 + +.. >>>>> [ RES MEM : 8.704056 GB ] [ VIRT MEM : 14.380230 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 154.393065 s ] [ CPU TIME: 8152.332489 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 8.704056 GB ] [ VIRT MEM : 14.380230 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 154.393480 s ] [ CPU TIME: 8152.359478 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 80 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2435912787914276E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.5983808388 0.174 3.5267046553 0.2225645364 7.2476 + 70 -229.7321291818 0.998E-02 3.5834457820 0.2862226551 8.7435 + 76 -229.7506493354 0.00 3.5963323488 0.2954526872 9.5784 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.711388 GB ] [ VIRT MEM : 14.386070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 163.997939 s ] [ CPU TIME: 8634.465060 s ] <<<<< .. + +* Number of generators 80 + +.. >>>>> [ RES MEM : 8.711388 GB ] [ VIRT MEM : 14.386070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 163.998322 s ] [ CPU TIME: 8634.489573 s ] <<<<< .. + +* Number of selectors 80 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1357606445556215 + +Summary at N_det = 80 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.81989941 +# PT2 -0.93074993 0.00000000 +# rPT2 -0.71847466 0.00000000 +# +# E+PT2 -229.75064934 0.00000000 +# E+rPT2 -229.53837407 0.00000000 +# ============ ============================= + + N_det = 80 + N_states = 1 + + * State 1 + < S^2 > = 3.711488752774673E-002 + E = -228.819899408895 + Variance = 3.59633234876446 + PT norm = 0.543555597158984 + PT2 = -0.930749926553985 + rPT2 = -0.718474658124072 + E+PT2 = -229.750649335449 +/- 0.000000000000000E+000 + E+rPT2 = -229.538374067020 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.442892146420 + Vee = 239.670732844008 + Vecp = 0.000000000000000E+000 + T = 228.844030114728 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7408 -229.69095601 + -0.7573 -229.67583103 + -0.7731 -229.67036298 + -0.7849 -229.73113300 + -0.7973 -229.83194627 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.711582 GB ] [ VIRT MEM : 14.386070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 164.060992 s ] [ CPU TIME: 8638.560178 s ] <<<<< .. + +* Energy of state 1 -228.8544512377611 +* S^2 of state 1 0.1378582764711756E-01 +* Saved determinants 160 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 58 +* Number of unique alpha determinants 59 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.711880 GB ] [ VIRT MEM : 14.386070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 164.118059 s ] [ CPU TIME: 8642.426540 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 8.711880 GB ] [ VIRT MEM : 14.386070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 164.118466 s ] [ CPU TIME: 8642.455545 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.8544512377611 + +.. >>>>> [ RES MEM : 8.711880 GB ] [ VIRT MEM : 14.386070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 164.122481 s ] [ CPU TIME: 8642.739362 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 8.711880 GB ] [ VIRT MEM : 14.386070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 164.122867 s ] [ CPU TIME: 8642.767171 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 160 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2591697573661804E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.5704696984 0.171 3.3482625731 0.1960795147 9.2269 + 68 -229.7014795843 0.147E-01 3.4546067237 0.2523826110 11.3750 + 86 -229.7087804774 0.122E-01 3.4592812923 0.2560375293 12.4524 + 135 -229.7139998493 0.795E-02 3.4464978084 0.2596789241 13.6625 + 140 -229.7141646952 0.767E-02 3.4448977426 0.2598776185 15.1347 + 154 -229.7246415824 0.00 3.4848692229 0.2626194565 15.5890 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.712040 GB ] [ VIRT MEM : 14.386070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 179.737808 s ] [ CPU TIME: 9587.041928 s ] <<<<< .. + +* Number of generators 160 + +.. >>>>> [ RES MEM : 8.712040 GB ] [ VIRT MEM : 14.386070 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 179.738194 s ] [ CPU TIME: 9587.067300 s ] <<<<< .. + +* Number of selectors 160 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.1762050322733896 + +Summary at N_det = 160 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.85445124 +# PT2 -0.87019034 0.00000000 +# rPT2 -0.68919447 0.00000000 +# +# E+PT2 -229.72464158 0.00000000 +# E+rPT2 -229.54364571 0.00000000 +# ============ ============================= + + N_det = 160 + N_states = 1 + + * State 1 + < S^2 > = 1.378582764711756E-002 + E = -228.854451237761 + Variance = 3.48486922290769 + PT norm = 0.512464102690972 + PT2 = -0.870190344655737 + rPT2 = -0.689194468011462 + E+PT2 = -229.724641582417 +/- 0.000000000000000E+000 + E+rPT2 = -229.543645705773 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.460271693621 + Vee = 239.622985428415 + Vecp = 0.000000000000000E+000 + T = 228.874605248656 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.7185 -229.66772906 + -0.7408 -229.67701047 + -0.7573 -229.67374002 + -0.7731 -229.67132525 + -0.7849 -229.70626351 + -0.7973 -229.77205506 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.721512 GB ] [ VIRT MEM : 14.389980 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 179.854960 s ] [ CPU TIME: 9594.957566 s ] <<<<< .. + +* Energy of state 1 -228.8917428312415 +* S^2 of state 1 0.2187330368180108E-01 +* Saved determinants 320 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 118 +* Number of unique alpha determinants 118 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.721546 GB ] [ VIRT MEM : 14.389980 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 179.919084 s ] [ CPU TIME: 9599.126817 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 8.721546 GB ] [ VIRT MEM : 14.389980 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 179.919492 s ] [ CPU TIME: 9599.155612 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.8917428312415 + +.. >>>>> [ RES MEM : 8.721546 GB ] [ VIRT MEM : 14.389980 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 179.923806 s ] [ CPU TIME: 9599.456694 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 8.721546 GB ] [ VIRT MEM : 14.389980 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 179.924193 s ] [ CPU TIME: 9599.484262 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 320 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.2903267145156860E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.5406764364 0.172 3.2473032491 0.1697923259 12.7296 + 108 -229.6812473579 0.759E-02 3.2875892291 0.2280439997 13.7645 + 133 -229.6851207629 0.661E-02 3.2932417927 0.2295987057 15.3045 + 139 -229.6853041472 0.633E-02 3.2910432760 0.2298240036 16.6705 + 147 -229.6867366660 0.611E-02 3.2986051401 0.2300223813 18.1377 + 169 -229.6913409281 0.616E-02 3.3097807933 0.2317185024 19.3713 + 195 -229.6932690524 0.636E-02 3.3187368443 0.2320884291 20.4262 + 211 -229.6955961127 0.627E-02 3.3390480092 0.2319763609 22.5798 + 225 -229.6933995532 0.616E-02 3.3295634962 0.2314071294 23.6975 + 250 -229.6939863566 0.563E-02 3.3266110809 0.2318934034 24.7315 + 268 -229.6974592444 0.577E-02 3.3383284165 0.2329983865 25.8996 + 284 -229.6974075713 0.563E-02 3.3428020139 0.2326796857 27.1077 + 296 -229.6972800177 0.594E-02 3.3505439553 0.2321389436 28.1312 + 313 -229.7020442680 0.00 3.3597879993 0.2339962183 28.8795 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.721584 GB ] [ VIRT MEM : 14.390209 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 208.827129 s ] [ CPU TIME: 11513.176691 s ] <<<<< .. + +* Number of generators 320 + +.. >>>>> [ RES MEM : 8.721584 GB ] [ VIRT MEM : 14.390209 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 208.827531 s ] [ CPU TIME: 11513.202721 s ] <<<<< .. + +* Number of selectors 320 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.2195344894941106 + +Summary at N_det = 320 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.89174283 +# PT2 -0.81030144 0.00000000 +# rPT2 -0.65664823 0.00000000 +# +# E+PT2 -229.70204427 0.00000000 +# E+rPT2 -229.54839106 0.00000000 +# ============ ============================= + + N_det = 320 + N_states = 1 + + * State 1 + < S^2 > = 2.187330368180108E-002 + E = -228.891742831241 + Variance = 3.35978799925428 + PT norm = 0.483731556015154 + PT2 = -0.810301436743569 + rPT2 = -0.656648233387477 + E+PT2 = -229.702044267985 +/- 0.000000000000000E+000 + E+rPT2 = -229.548391064629 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.456954939699 + Vee = 239.558203371858 + Vecp = 0.000000000000000E+000 + T = 228.898778957811 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6892 -229.64413275 + -0.7185 -229.65474920 + -0.7408 -229.66356146 + -0.7573 -229.66465504 + -0.7731 -229.66489329 + -0.7849 -229.68766700 + -0.7973 -229.73258531 + =========== =================== + + Diagonalization of H using Lapack + +.. >>>>> [ RES MEM : 8.730675 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 209.097148 s ] [ CPU TIME: 11531.758234 s ] <<<<< .. + +* Energy of state 1 -228.9367488820007 +* S^2 of state 1 0.2741316602258568E-01 +* Saved determinants 640 +-------------------------------------------------------------------------------- +* Number of unique beta determinants 201 +* Number of unique alpha determinants 200 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.730675 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 209.165280 s ] [ CPU TIME: 11535.862464 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 8.730675 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 209.165634 s ] [ CPU TIME: 11535.887393 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.9367488820007 + +.. >>>>> [ RES MEM : 8.730675 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 209.169601 s ] [ CPU TIME: 11536.163956 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 8.730675 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 209.169938 s ] [ CPU TIME: 11536.187978 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 +* Number of tasks 640 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.3526406288146973E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.5208856587 0.158 2.9345579369 0.1477880275 19.3281 + 150 -229.6570423772 0.856E-02 3.1147341148 0.1987341886 20.4058 + 180 -229.6649232380 0.845E-02 3.1377342597 0.2013492749 21.5600 + 201 -229.6661762861 0.781E-02 3.1519334900 0.2012059845 22.8121 + 209 -229.6659304225 0.753E-02 3.1561318443 0.2007771019 23.9849 + 211 -229.6658561499 0.746E-02 3.1550919400 0.2007988776 26.3981 + 258 -229.6675986608 0.684E-02 3.1603182017 0.2012825530 28.1446 + 276 -229.6737191378 0.773E-02 3.1929988637 0.2024783829 29.1884 + 283 -229.6733326667 0.754E-02 3.1893732860 0.2024931262 30.2608 + 290 -229.6744101531 0.749E-02 3.1943161141 0.2027128381 31.7651 + 301 -229.6756152173 0.816E-02 3.2078195482 0.2025635691 32.9641 + 318 -229.6758883860 0.782E-02 3.2050215112 0.2028460148 35.4696 + 354 -229.6769552198 0.726E-02 3.2093938445 0.2031106087 36.7281 + 375 -229.6744691188 0.696E-02 3.2008256155 0.2024005822 38.7289 + 400 -229.6767069924 0.683E-02 3.2135536248 0.2027584595 40.2398 + 418 -229.6773119704 0.667E-02 3.2171259102 0.2028827872 41.2860 + 424 -229.6770400274 0.658E-02 3.2147102880 0.2028854992 42.4636 + 436 -229.6773166144 0.644E-02 3.2136877499 0.2030624355 44.0071 + 461 -229.6764020678 0.610E-02 3.2084072717 0.2029228037 45.2213 + 486 -229.6792638608 0.616E-02 3.2206577774 0.2036152354 46.6660 + 496 -229.6788370624 0.604E-02 3.2171449581 0.2036043321 47.7890 + 510 -229.6804660609 0.606E-02 3.2228378001 0.2041015821 49.2758 + 536 -229.6792984682 0.586E-02 3.2212654846 0.2036054368 50.4067 + 551 -229.6801993344 0.579E-02 3.2227644832 0.2039761861 51.6440 + 563 -229.6807688188 0.575E-02 3.2228898460 0.2042714403 52.8078 + 583 -229.6807300695 0.562E-02 3.2262812414 0.2040437840 53.8984 + 608 -229.6804657469 0.543E-02 3.2215238262 0.2041958174 55.0177 + 626 -229.6794400142 0.00 3.2102461442 0.2043229295 55.8758 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.732224 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.069032 s ] [ CPU TIME: 15405.599642 s ] <<<<< .. + +* Number of generators 640 + +.. >>>>> [ RES MEM : 8.732224 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.069414 s ] [ CPU TIME: 15405.622881 s ] <<<<< .. + +* Number of selectors 640 +* Number of comb teeth 1 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.2713993072087593 + +Summary at N_det = 640 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.93674888 +# PT2 -0.74269113 0.00000000 +# rPT2 -0.61668770 0.00000000 +# +# E+PT2 -229.67944001 0.00000000 +# E+rPT2 -229.55343658 0.00000000 +# ============ ============================= + + N_det = 640 + N_states = 1 + + * State 1 + < S^2 > = 2.741316602258568E-002 + E = -228.936748882001 + Variance = 3.21024614424007 + PT norm = 0.452020939228012 + PT2 = -0.742691132166853 + rPT2 = -0.616687695612374 + E+PT2 = -229.679440014168 +/- 0.000000000000000E+000 + E+rPT2 = -229.553436577613 +/- 0.000000000000000E+000 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.444077485274 + Vee = 239.475791357614 + Vecp = 0.000000000000000E+000 + T = 228.923307466871 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6566 -229.63130104 + -0.6892 -229.63661232 + -0.7185 -229.64444803 + -0.7408 -229.65186555 + -0.7573 -229.65456859 + -0.7731 -229.65620525 + -0.7849 -229.67195054 + =========== =================== + +* Number of unique alpha determinants 347 +* Number of unique beta determinants 347 +.. >>>>> [ IO READ: davidson_sze_max ] <<<<< .. + +.. >>>>> [ RES MEM : 8.732746 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.135443 s ] [ CPU TIME: 15409.805586 s ] <<<<< .. + +.. >>>>> [ IO READ: state_following ] <<<<< .. + +.. >>>>> [ RES MEM : 8.732746 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.136551 s ] [ CPU TIME: 15409.879884 s ] <<<<< .. + +.. >>>>> [ IO READ: only_expected_s2 ] <<<<< .. + +.. >>>>> [ RES MEM : 8.732746 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.137798 s ] [ CPU TIME: 15409.963146 s ] <<<<< .. + +.. >>>>> [ IO READ: disk_based_davidson ] <<<<< .. + +.. >>>>> [ RES MEM : 8.732746 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.138606 s ] [ CPU TIME: 15410.017048 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.732746 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.138969 s ] [ CPU TIME: 15410.041552 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 1280 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.3220573067665100E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9374783859 0.027589 0.199E-01 + 2 -228.9862919229 0.033155 0.156E-02 + 3 -228.9869046385 0.032075 0.581E-04 + 4 -228.9869751923 0.032231 0.944E-06 + 5 -228.9869770710 0.032227 0.188E-07 + 6 -228.9869771071 0.032221 0.357E-09 + 7 -228.9869771078 0.032221 0.615E-11 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 8.733212 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.236169 s ] [ CPU TIME: 15416.701853 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.733212 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.236586 s ] [ CPU TIME: 15416.731238 s ] <<<<< .. + +* Energy of state 1 -228.9869771078373 +* S^2 of state 1 0.3222128543233175E-01 +* Saved determinants 1280 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.733372 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.328887 s ] [ CPU TIME: 15421.832138 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 8.733372 GB ] [ VIRT MEM : 14.396336 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.329273 s ] [ CPU TIME: 15421.859441 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 59 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -228.9869771078373 + +.. >>>>> [ RES MEM : 8.730354 GB ] [ VIRT MEM : 14.393272 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.340311 s ] [ CPU TIME: 15422.627153 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 8.730354 GB ] [ VIRT MEM : 14.393272 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 265.340703 s ] [ CPU TIME: 15422.654671 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 59 +* pt2_n_tasks_max 1 +* Number of tasks 1280 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.4772857427597046E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6564720946 0.630E-03 3.0335283311 0.1740067076 32.2217 + 4 -229.6569721265 0.702E-03 3.0363458456 0.1741043070 33.2528 + 5 -229.6568223054 0.552E-03 3.0352326794 0.1740877534 36.9138 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.731403 GB ] [ VIRT MEM : 14.393272 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 303.924058 s ] [ CPU TIME: 17985.912249 s ] <<<<< .. + +* Number of generators 1280 + +.. >>>>> [ RES MEM : 8.731403 GB ] [ VIRT MEM : 14.393272 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 303.924453 s ] [ CPU TIME: 17985.936294 s ] <<<<< .. + +* Number of selectors 1280 +* Number of comb teeth 59 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.3291620006571093 + +Summary at N_det = 1280 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -228.98697711 +# PT2 -0.66984520 0.00055242 +# rPT2 -0.57052396 0.00047051 +# +# E+PT2 -229.65682231 0.00055242 +# E+rPT2 -229.55750107 0.00047051 +# ============ ============================= + + N_det = 1280 + N_states = 1 + + * State 1 + < S^2 > = 3.222128543233175E-002 + E = -228.986977107837 + Variance = 3.03523267944884 + PT norm = 0.417238245320142 + PT2 = -0.669845197569430 + rPT2 = -0.570523962671194 + E+PT2 = -229.656822305407 +/- 5.524248246837784E-004 + E+rPT2 = -229.557501070508 +/- 4.705140847469635E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.437642992751 + Vee = 239.394044843884 + Vecp = 0.000000000000000E+000 + T = 228.948391262241 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.6167 -229.60773294 + -0.6566 -229.61784248 + -0.6892 -229.62466903 + -0.7185 -229.63202542 + -0.7408 -229.63882912 + -0.7573 -229.64238537 + -0.7731 -229.64490741 + =========== =================== + +* Number of unique alpha determinants 591 +* Number of unique beta determinants 590 + +.. >>>>> [ RES MEM : 8.731815 GB ] [ VIRT MEM : 14.393272 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 304.029062 s ] [ CPU TIME: 17992.579035 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 2560 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.5900710821151733E-02 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -228.9870035588 0.032190 0.214E-01 + 2 -229.0430875634 0.038630 0.167E-02 + 3 -229.0438566802 0.037511 0.677E-04 + 4 -229.0439447783 0.037864 0.130E-05 + 5 -229.0439474876 0.037878 0.369E-07 + 6 -229.0439475624 0.037876 0.786E-09 + 7 -229.0439475642 0.037876 0.167E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 8.733974 GB ] [ VIRT MEM : 14.395584 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 304.077438 s ] [ CPU TIME: 17995.926636 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.733974 GB ] [ VIRT MEM : 14.395584 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 304.077840 s ] [ CPU TIME: 17995.955897 s ] <<<<< .. + +* Energy of state 1 -229.0439475641669 +* S^2 of state 1 0.3787616457599306E-01 +* Saved determinants 2560 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.733456 GB ] [ VIRT MEM : 14.394428 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 304.209321 s ] [ CPU TIME: 18002.433513 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 8.733456 GB ] [ VIRT MEM : 14.394428 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 304.209720 s ] [ CPU TIME: 18002.461638 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 77 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -229.0439475641669 + +.. >>>>> [ RES MEM : 8.733456 GB ] [ VIRT MEM : 14.394428 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 304.219021 s ] [ CPU TIME: 18003.109163 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 8.733456 GB ] [ VIRT MEM : 14.394428 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 304.219413 s ] [ CPU TIME: 18003.136383 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 77 +* pt2_n_tasks_max 1 +* Number of tasks 2560 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.7265467643737793E-01 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6393713591 0.159E-02 2.8496874008 0.1448302284 57.5848 + 7 -229.6391540590 0.471E-03 2.8484071847 0.1447917195 61.9746 + 8 -229.6393472275 0.441E-03 2.8502363640 0.1448037532 68.6799 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.735867 GB ] [ VIRT MEM : 14.393288 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373.195011 s ] [ CPU TIME: 22679.308732 s ] <<<<< .. + +* Number of generators 2560 + +.. >>>>> [ RES MEM : 8.735867 GB ] [ VIRT MEM : 14.393288 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373.195406 s ] [ CPU TIME: 22679.333326 s ] <<<<< .. + +* Number of selectors 2560 +* Number of comb teeth 77 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.3931284829640186 + +Summary at N_det = 2560 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.04394756 +# PT2 -0.59539966 0.00044114 +# rPT2 -0.52008885 0.00038534 +# +# E+PT2 -229.63934723 0.00044114 +# E+rPT2 -229.56403641 0.00038534 +# ============ ============================= + + N_det = 2560 + N_states = 1 + + * State 1 + < S^2 > = 3.787616457599306E-002 + E = -229.043947564167 + Variance = 2.85023636404320 + PT norm = 0.380530883321600 + PT2 = -0.595399663310130 + rPT2 = -0.520088846377259 + E+PT2 = -229.639347227477 +/- 4.411359506152892E-004 + E+rPT2 = -229.564036410544 +/- 3.853376173837985E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.437754533912 + Vee = 239.307829426061 + Vecp = 0.000000000000000E+000 + T = 228.977747764896 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.5705 -229.63142909 + -0.6167 -229.62094603 + -0.6566 -229.62198927 + -0.6892 -229.62493253 + -0.7185 -229.62939552 + -0.7408 -229.63416065 + -0.7573 -229.63706383 + =========== =================== + +* Number of unique alpha determinants 1024 +* Number of unique beta determinants 1025 + +.. >>>>> [ RES MEM : 8.736507 GB ] [ VIRT MEM : 14.393288 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373.262301 s ] [ CPU TIME: 22683.596820 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5120 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.1104352623224258E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.0440175216 0.037847 0.223E-01 + 2 -229.1073693041 0.035922 0.157E-02 + 3 -229.1082554690 0.034496 0.798E-04 + 4 -229.1083612184 0.034732 0.175E-05 + 5 -229.1083646631 0.034734 0.724E-07 + 6 -229.1083647955 0.034725 0.228E-08 + 7 -229.1083648002 0.034726 0.559E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 8.742447 GB ] [ VIRT MEM : 14.399044 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373.327126 s ] [ CPU TIME: 22688.137404 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.741386 GB ] [ VIRT MEM : 14.396744 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373.327750 s ] [ CPU TIME: 22688.182733 s ] <<<<< .. + +* Energy of state 1 -229.1083648001895 +* S^2 of state 1 0.3472550438209854E-01 +* Saved determinants 5120 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.741402 GB ] [ VIRT MEM : 14.399498 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373.541743 s ] [ CPU TIME: 22697.624094 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 8.741402 GB ] [ VIRT MEM : 14.399498 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373.542144 s ] [ CPU TIME: 22697.652904 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 93 +* pt2_n_tasks_max 1 +* PT2 Energy denominator -229.1083648001895 + +.. >>>>> [ RES MEM : 8.742027 GB ] [ VIRT MEM : 14.399498 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373.550585 s ] [ CPU TIME: 22698.249649 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 8.742027 GB ] [ VIRT MEM : 14.399498 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 373.550978 s ] [ CPU TIME: 22698.277711 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 93 +* pt2_n_tasks_max 1 +* Number of tasks 5120 +* Number of fragmented tasks 0 +* Number of threads for PT2 72 +* Memory (Gb) 0.1225062847137451 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6262129720 0.995E-03 2.6394536289 0.1166586191 115.5414 + 14 -229.6260775952 0.240E-03 2.6369478667 0.1166741900 118.1759 + 15 -229.6259907455 0.231E-03 2.6363810598 0.1166632010 122.5737 + 16 -229.6260908120 0.234E-03 2.6370885341 0.1166785682 126.2910 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.841839 GB ] [ VIRT MEM : 14.491184 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 499.880724 s ] [ CPU TIME: 31744.334770 s ] <<<<< .. + +* Number of generators 5120 + +.. >>>>> [ RES MEM : 8.841839 GB ] [ VIRT MEM : 14.491184 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 499.881153 s ] [ CPU TIME: 31744.365800 s ] <<<<< .. + +* Number of selectors 5120 +* Number of comb teeth 93 +* pt2_n_tasks_max 1 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.4639855741856925 + +Summary at N_det = 5120 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.10836480 +# PT2 -0.51772601 0.00023413 +# rPT2 -0.46363029 0.00020966 +# +# E+PT2 -229.62609081 0.00023413 +# E+rPT2 -229.57199509 0.00020966 +# ============ ============================= + + N_det = 5120 + N_states = 1 + + * State 1 + < S^2 > = 3.472550438209854E-002 + E = -229.108364800189 + Variance = 2.63708853409067 + PT norm = 0.341582447216161 + PT2 = -0.517726011815542 + rPT2 = -0.463630293029323 + E+PT2 = -229.626090812005 +/- 2.341272390196389E-004 + E+rPT2 = -229.571995093219 +/- 2.096639495708702E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.432837508192 + Vee = 239.207357164710 + Vecp = 0.000000000000000E+000 + T = 229.008885764504 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.5201 -229.63735076 + -0.5705 -229.63481413 + -0.6167 -229.62827552 + -0.6566 -229.62704642 + -0.6892 -229.62788960 + -0.7185 -229.63029654 + -0.7408 -229.63335504 + =========== =================== + +* Number of unique alpha determinants 1781 +* Number of unique beta determinants 1781 + +.. >>>>> [ RES MEM : 8.843113 GB ] [ VIRT MEM : 14.491184 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 499.956749 s ] [ CPU TIME: 31749.669417 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 10240 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.2087812870740891E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.1083818717 0.034725 0.214E-01 + 2 -229.1755362730 0.030965 0.128E-02 + 3 -229.1764961676 0.029818 0.101E-03 + 4 -229.1766212632 0.030020 0.314E-05 + 5 -229.1766265759 0.030021 0.197E-06 + 6 -229.1766269387 0.030013 0.786E-08 + 7 -229.1766269553 0.030012 0.343E-09 + 8 -229.1766269561 0.030012 0.130E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 8.854446 GB ] [ VIRT MEM : 14.500362 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 500.117516 s ] [ CPU TIME: 31761.149568 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 8.851715 GB ] [ VIRT MEM : 14.495773 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 500.118348 s ] [ CPU TIME: 31761.210067 s ] <<<<< .. + +* Energy of state 1 -229.1766269560631 +* S^2 of state 1 0.3001189343387325E-01 +* Saved determinants 10240 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 8.849567 GB ] [ VIRT MEM : 14.493057 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 500.658054 s ] [ CPU TIME: 31788.161164 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 8.849567 GB ] [ VIRT MEM : 14.493057 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 500.658491 s ] [ CPU TIME: 31788.192845 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 100 +* pt2_n_tasks_max 2 +* PT2 Energy denominator -229.1766269560631 + +.. >>>>> [ RES MEM : 8.846939 GB ] [ VIRT MEM : 14.491184 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 500.667552 s ] [ CPU TIME: 31788.843105 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 8.846939 GB ] [ VIRT MEM : 14.491184 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 500.667967 s ] [ CPU TIME: 31788.873331 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 100 +* pt2_n_tasks_max 2 +* Number of tasks 10587 +* Number of fragmented tasks 347 +* Number of threads for PT2 72 +* Memory (Gb) 0.2222455322742462 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6160969682 0.589E-03 2.3917537467 0.0913316999 114.5550 + 8 -229.6167346429 0.428E-03 2.3978425055 0.0913925861 117.2712 + 9 -229.6169520736 0.500E-03 2.4010570758 0.0913738602 128.6165 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 9.004078 GB ] [ VIRT MEM : 14.630657 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 637.175640 s ] [ CPU TIME: 41576.139410 s ] <<<<< .. + +* Number of generators 10240 + +.. >>>>> [ RES MEM : 9.004078 GB ] [ VIRT MEM : 14.630657 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 637.176058 s ] [ CPU TIME: 41576.169850 s ] <<<<< .. + +* Number of selectors 10240 +* Number of comb teeth 100 +* pt2_n_tasks_max 2 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.5378735521753327 + +Summary at N_det = 10240 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.17662696 +# PT2 -0.44032512 0.00050039 +# rPT2 -0.40345947 0.00045849 +# +# E+PT2 -229.61695207 0.00050039 +# E+rPT2 -229.58008642 0.00045849 +# ============ ============================= + + N_det = 10240 + N_states = 1 + + * State 1 + < S^2 > = 3.001189343387325E-002 + E = -229.176626956063 + Variance = 2.40105707583223 + PT norm = 0.302281094738255 + PT2 = -0.440325117499553 + rPT2 = -0.403459468421090 + E+PT2 = -229.616952073563 +/- 5.003873397270396E-004 + E+rPT2 = -229.580086424484 +/- 4.584930590318179E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.437096445811 + Vee = 239.106680040198 + Vecp = 0.000000000000000E+000 + T = 229.045559670761 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4636 -229.63434070 + -0.5201 -229.63565585 + -0.5705 -229.63487757 + -0.6167 -229.63108486 + -0.6566 -229.62976838 + -0.6892 -229.62989128 + -0.7185 -229.63124391 + =========== =================== + +* Number of unique alpha determinants 3119 +* Number of unique beta determinants 3120 + +.. >>>>> [ RES MEM : 9.006138 GB ] [ VIRT MEM : 14.630657 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 637.299785 s ] [ CPU TIME: 41584.881017 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 20480 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.3985065594315529E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.1766591886 0.030018 0.188E-01 + 2 -229.2429815360 0.024300 0.999E-03 + 3 -229.2439254286 0.023455 0.108E-03 + 4 -229.2440586083 0.023589 0.261E-05 + 5 -229.2440643470 0.023584 0.163E-06 + 6 -229.2440646722 0.023576 0.886E-08 + 7 -229.2440646912 0.023575 0.553E-09 + 8 -229.2440646923 0.023575 0.248E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 9.025131 GB ] [ VIRT MEM : 14.653809 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 637.750825 s ] [ CPU TIME: 41617.252835 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 9.016979 GB ] [ VIRT MEM : 14.639938 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 637.752467 s ] [ CPU TIME: 41617.371180 s ] <<<<< .. + +* Energy of state 1 -229.2440646923496 +* S^2 of state 1 0.2357490408333245E-01 +* Saved determinants 20480 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 9.011219 GB ] [ VIRT MEM : 14.630657 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 638.300291 s ] [ CPU TIME: 41639.059363 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 9.011219 GB ] [ VIRT MEM : 14.630657 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 638.300757 s ] [ CPU TIME: 41639.092878 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 +* PT2 Energy denominator -229.2440646923496 + +.. >>>>> [ RES MEM : 9.015141 GB ] [ VIRT MEM : 14.635563 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 638.314719 s ] [ CPU TIME: 41640.095265 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 9.015141 GB ] [ VIRT MEM : 14.635563 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 638.315150 s ] [ CPU TIME: 41640.126800 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 +* Number of tasks 21194 +* Number of fragmented tasks 357 +* Number of threads for PT2 72 +* Memory (Gb) 0.4216868340969085 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6131213840 0.193E-02 2.1554665964 0.0704138138 151.1675 + 8 -229.6115867244 0.899E-03 2.1434888620 0.0702553710 160.1223 + 9 -229.6109307597 0.974E-03 2.1390692895 0.0701505218 170.9463 + 12 -229.6107326778 0.742E-03 2.1358472377 0.0701761602 188.7403 + 13 -229.6109604051 0.718E-03 2.1378631559 0.0701963891 203.7714 + 14 -229.6114482173 0.739E-03 2.1413400265 0.0702666930 224.2328 + 18 -229.6113858779 0.657E-03 2.1408027760 0.0702572998 240.4788 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 9.195686 GB ] [ VIRT MEM : 14.757458 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 890.000099 s ] [ CPU TIME: 59695.973475 s ] <<<<< .. + +* Number of generators 20480 + +.. >>>>> [ RES MEM : 9.195686 GB ] [ VIRT MEM : 14.757458 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 890.000553 s ] [ CPU TIME: 59696.006154 s ] <<<<< .. + +* Number of selectors 20480 +* Number of comb teeth 100 +* pt2_n_tasks_max 3 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.6100953612375624 + +Summary at N_det = 20480 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.24406469 +# PT2 -0.36732119 0.00065703 +# rPT2 -0.34320830 0.00061390 +# +# E+PT2 -229.61138588 0.00065703 +# E+rPT2 -229.58727299 0.00061390 +# ============ ============================= + + N_det = 20480 + N_states = 1 + + * State 1 + < S^2 > = 2.357490408333245E-002 + E = -229.244064692350 + Variance = 2.14080277599700 + PT norm = 0.265060936014814 + PT2 = -0.367321185556197 + rPT2 = -0.343208297317363 + E+PT2 = -229.611385877906 +/- 6.570336498838788E-004 + E+rPT2 = -229.587272989667 +/- 6.139025167181903E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.452138513771 + Vee = 239.014888427914 + Vecp = 0.000000000000000E+000 + T = 229.084955614719 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.4035 -229.62820977 + -0.4636 -229.63096752 + -0.5201 -229.63278682 + -0.5705 -229.63304739 + -0.6167 -229.63103323 + -0.6566 -229.63017675 + -0.6892 -229.63020774 + =========== =================== + +* Number of unique alpha determinants 5649 +* Number of unique beta determinants 5648 + +.. >>>>> [ RES MEM : 9.200565 GB ] [ VIRT MEM : 14.757458 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 890.236960 s ] [ CPU TIME: 59712.882292 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 40960 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.7719568163156509E-01 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.2440682405 0.023578 0.153E-01 + 2 -229.3054354334 0.017176 0.708E-03 + 3 -229.3063725709 0.016637 0.119E-03 + 4 -229.3065073870 0.016764 0.285E-05 + 5 -229.3065145194 0.016766 0.197E-06 + 6 -229.3065149412 0.016761 0.112E-07 + 7 -229.3065149674 0.016760 0.616E-09 + 8 -229.3065149690 0.016760 0.403E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 9.235298 GB ] [ VIRT MEM : 14.805088 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 891.593348 s ] [ CPU TIME: 59810.299475 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 9.218910 GB ] [ VIRT MEM : 14.777248 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 891.596142 s ] [ CPU TIME: 59810.500861 s ] <<<<< .. + +* Energy of state 1 -229.3065149689926 +* S^2 of state 1 0.1676042243388065E-01 +* Saved determinants 40960 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 9.206879 GB ] [ VIRT MEM : 14.759480 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 892.480894 s ] [ CPU TIME: 59844.429654 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 9.206879 GB ] [ VIRT MEM : 14.759480 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 892.481395 s ] [ CPU TIME: 59844.465230 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 +* PT2 Energy denominator -229.3065149689926 + +.. >>>>> [ RES MEM : 9.217926 GB ] [ VIRT MEM : 14.769268 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 892.504195 s ] [ CPU TIME: 59846.102713 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 9.217926 GB ] [ VIRT MEM : 14.769268 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 892.504689 s ] [ CPU TIME: 59846.138569 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 +* Number of tasks 51065 +* Number of fragmented tasks 8806 +* Number of threads for PT2 72 +* Memory (Gb) 0.8205694377422332 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6100014080 0.178E-02 1.8927198160 0.0536594103 182.2602 + 8 -229.6096286435 0.798E-03 1.8906961610 0.0535531964 205.1941 + 9 -229.6095356856 0.609E-03 1.8904582340 0.0535381553 231.7744 + 11 -229.6096176234 0.465E-03 1.8911954955 0.0535574981 237.7181 + 12 -229.6098550945 0.489E-03 1.8936782402 0.0535733111 257.4569 + 13 -229.6097263083 0.467E-03 1.8923729131 0.0535618591 261.9601 + 14 -229.6096894292 0.434E-03 1.8914620394 0.0535759993 272.6980 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 9.910763 GB ] [ VIRT MEM : 15.374176 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1165.463570 s ] [ CPU TIME: 79423.777918 s ] <<<<< .. + +* Number of generators 40960 + +.. >>>>> [ RES MEM : 9.910763 GB ] [ VIRT MEM : 15.374176 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1165.464050 s ] [ CPU TIME: 79423.812422 s ] <<<<< .. + +* Number of selectors 40960 +* Number of comb teeth 100 +* pt2_n_tasks_max 5 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.6756696686749257 + +Summary at N_det = 40960 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.30651497 +# PT2 -0.30317446 0.00043368 +# rPT2 -0.28775756 0.00041163 +# +# E+PT2 -229.60968943 0.00043368 +# E+rPT2 -229.59427253 0.00041163 +# ============ ============================= + + N_det = 40960 + N_states = 1 + + * State 1 + < S^2 > = 1.676042243388065E-002 + E = -229.306514968993 + Variance = 1.89146203941882 + PT norm = 0.231464898590599 + PT2 = -0.303174460220198 + rPT2 = -0.287757561322117 + E+PT2 = -229.609689429213 +/- 4.336828866924833E-004 + E+rPT2 = -229.594272530315 +/- 4.116294287161430E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.493982457798 + Vee = 238.955486460545 + Vecp = 0.000000000000000E+000 + T = 229.123751249471 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.3432 -229.63059614 + -0.4035 -229.62947076 + -0.4636 -229.63056764 + -0.5201 -229.63178593 + -0.5705 -229.63215953 + -0.6167 -229.63094616 + -0.6566 -229.63036157 + =========== =================== + +* Number of unique alpha determinants 10331 +* Number of unique beta determinants 10328 + +.. >>>>> [ RES MEM : 9.920082 GB ] [ VIRT MEM : 15.374176 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1166.095965 s ] [ CPU TIME: 79469.131563 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 81920 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.1503715664148331 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.3065155889 0.016759 0.114E-01 + 2 -229.3583880172 0.011299 0.454E-03 + 3 -229.3593035074 0.011025 0.102E-03 + 4 -229.3594082290 0.011115 0.356E-05 + 5 -229.3594169631 0.011113 0.230E-06 + 6 -229.3594175356 0.011110 0.154E-07 + 7 -229.3594175753 0.011110 0.923E-09 + 8 -229.3594175781 0.011110 0.638E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 9.984844 GB ] [ VIRT MEM : 15.480579 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1170.670337 s ] [ CPU TIME: 79797.665709 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 9.951870 GB ] [ VIRT MEM : 15.424908 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1170.675108 s ] [ CPU TIME: 79798.009056 s ] <<<<< .. + +* Energy of state 1 -229.3594175780977 +* S^2 of state 1 0.1111040911605222E-01 +* Saved determinants 81920 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 9.921829 GB ] [ VIRT MEM : 15.389664 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1172.224672 s ] [ CPU TIME: 79849.596189 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 9.921829 GB ] [ VIRT MEM : 15.389664 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1172.225267 s ] [ CPU TIME: 79849.639316 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 +* PT2 Energy denominator -229.3594175780977 + +.. >>>>> [ RES MEM : 9.942085 GB ] [ VIRT MEM : 15.410179 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1172.264531 s ] [ CPU TIME: 79852.458507 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 9.942085 GB ] [ VIRT MEM : 15.410179 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1172.265099 s ] [ CPU TIME: 79852.499895 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 +* Number of tasks 109702 +* Number of fragmented tasks 12385 +* Number of threads for PT2 72 +* Memory (Gb) 1.618334645032883 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6080377951 0.110E-02 1.6317582379 0.0413888028 213.7246 + 5 -229.6076599346 0.754E-03 1.6304894192 0.0412983972 223.9781 + 6 -229.6079923977 0.760E-03 1.6317451585 0.0413771437 233.0131 + 7 -229.6085075094 0.830E-03 1.6360626180 0.0414428490 265.3876 + 8 -229.6092605054 0.106E-02 1.6419104852 0.0415550265 318.9040 + 10 -229.6091259917 0.892E-03 1.6417687456 0.0415313963 337.6071 + 11 -229.6094250280 0.830E-03 1.6432432824 0.0415804545 340.1976 + 12 -229.6096536058 0.791E-03 1.6452881859 0.0416080213 355.1833 + 13 -229.6093134113 0.805E-03 1.6426054793 0.0415587251 369.4010 + 14 -229.6092383199 0.748E-03 1.6419783321 0.0415518801 383.3541 + 15 -229.6091337407 0.734E-03 1.6410730953 0.0415437875 423.9914 + 17 -229.6087497652 0.705E-03 1.6396618144 0.0414626236 446.8681 + 18 -229.6088081345 0.666E-03 1.6401367276 0.0414739518 461.2656 + 19 -229.6088256844 0.630E-03 1.6406038595 0.0414680542 476.7795 + 20 -229.6089394409 0.635E-03 1.6412856511 0.0414895480 513.7852 + 23 -229.6090339272 0.533E-03 1.6428030426 0.0414889705 531.0943 + 24 -229.6089430629 0.519E-03 1.6421304992 0.0414743620 540.2881 + 25 -229.6088598743 0.504E-03 1.6419863824 0.0414530282 543.4761 + 26 -229.6089928604 0.465E-03 1.6428406561 0.0414747069 563.9853 + 27 -229.6090340911 0.449E-03 1.6434585985 0.0414699402 589.7493 + 28 -229.6091320412 0.444E-03 1.6447013195 0.0414754359 613.0111 + 29 -229.6091724997 0.413E-03 1.6448480644 0.0414842026 623.4240 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 10.599472 GB ] [ VIRT MEM : 15.892624 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1820.225675 s ] [ CPU TIME: 126343.006592 s ] <<<<< .. + +* Number of generators 81920 + +.. >>>>> [ RES MEM : 10.599472 GB ] [ VIRT MEM : 15.892624 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1820.226259 s ] [ CPU TIME: 126343.049271 s ] <<<<< .. + +* Number of selectors 81920 +* Number of comb teeth 100 +* pt2_n_tasks_max 9 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7312149711461546 + +Summary at N_det = 81920 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.35941758 +# PT2 -0.24975492 0.00041264 +# rPT2 -0.23980673 0.00039621 +# +# E+PT2 -229.60917250 0.00041264 +# E+rPT2 -229.59922431 0.00039621 +# ============ ============================= + + N_det = 81920 + N_states = 1 + + * State 1 + < S^2 > = 1.111040911605222E-002 + E = -229.359417578098 + Variance = 1.64484806442808 + PT norm = 0.203676710985907 + PT2 = -0.249754921572942 + rPT2 = -0.239806730577301 + E+PT2 = -229.609172499671 +/- 4.126428795964624E-004 + E+rPT2 = -229.599224308675 +/- 3.962065661361961E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.528486795056 + Vee = 238.891624404543 + Vecp = 0.000000000000000E+000 + T = 229.169215033625 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2878 -229.62398863 + -0.3432 -229.62721838 + -0.4035 -229.62782294 + -0.4636 -229.62898937 + -0.5201 -229.63015670 + -0.5705 -229.63069849 + -0.6167 -229.63003171 + =========== =================== + +* Number of unique beta determinants 19431 +* Number of unique alpha determinants 19435 + +.. >>>>> [ RES MEM : 10.592014 GB ] [ VIRT MEM : 15.880005 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1822.806548 s ] [ CPU TIME: 126528.124090 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 163840 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.2956763058900833 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.3594189755 0.011110 0.787E-02 + 2 -229.3999943895 0.007157 0.319E-03 + 3 -229.4008732284 0.007043 0.697E-04 + 4 -229.4009543405 0.007104 0.479E-05 + 5 -229.4009646441 0.007116 0.413E-06 + 6 -229.4009656455 0.007119 0.328E-07 + 7 -229.4009657443 0.007122 0.317E-08 + 8 -229.4009657538 0.007123 0.288E-09 + 9 -229.4009657548 0.007123 0.289E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 10.791767 GB ] [ VIRT MEM : 16.096462 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1844.782984 s ] [ CPU TIME: 128098.753306 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 10.718586 GB ] [ VIRT MEM : 15.985615 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1844.793444 s ] [ CPU TIME: 128099.505246 s ] <<<<< .. + +* Energy of state 1 -229.4009657547833 +* S^2 of state 1 0.7123027130826926E-02 +* Saved determinants 163840 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 10.617191 GB ] [ VIRT MEM : 15.881107 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1847.658963 s ] [ CPU TIME: 128171.073938 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 10.617191 GB ] [ VIRT MEM : 15.881107 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1847.659776 s ] [ CPU TIME: 128171.132758 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 +* PT2 Energy denominator -229.4009657547833 + +.. >>>>> [ RES MEM : 10.645077 GB ] [ VIRT MEM : 15.909214 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1847.733773 s ] [ CPU TIME: 128176.446505 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 10.645077 GB ] [ VIRT MEM : 15.909214 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 1847.734563 s ] [ CPU TIME: 128176.503721 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 +* Number of tasks 218978 +* Number of fragmented tasks 15970 +* Number of threads for PT2 72 +* Memory (Gb) 3.213865059614181 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6097705887 0.151E-02 1.4247375209 0.0333067448 255.8303 + 4 -229.6092252579 0.134E-02 1.4221773530 0.0332183329 344.9863 + 5 -229.6098734451 0.132E-02 1.4305414204 0.0332576286 359.6133 + 6 -229.6098357748 0.113E-02 1.4278875591 0.0333239769 428.7863 + 7 -229.6101316552 0.961E-03 1.4336361057 0.0332814637 442.3086 + 8 -229.6097046108 0.938E-03 1.4297780674 0.0332371587 523.1803 + 10 -229.6087105796 0.110E-02 1.4216282120 0.0331174412 524.2577 + 11 -229.6087274905 0.993E-03 1.4225281783 0.0330982933 555.0366 + 12 -229.6089670961 0.875E-03 1.4253635184 0.0331264712 595.6733 + 14 -229.6091269600 0.828E-03 1.4262531603 0.0331555368 625.5403 + 15 -229.6090786750 0.771E-03 1.4246762793 0.0331791638 665.5333 + 16 -229.6087664631 0.781E-03 1.4222298164 0.0331371629 669.7853 + 17 -229.6090550290 0.789E-03 1.4254317306 0.0331642151 681.8963 + 18 -229.6090595510 0.743E-03 1.4255772106 0.0331624014 712.5833 + 19 -229.6090647961 0.672E-03 1.4249606331 0.0331786162 776.9893 + 22 -229.6094567345 0.643E-03 1.4292338205 0.0332009872 805.2975 + 24 -229.6093990433 0.574E-03 1.4298710309 0.0331743013 834.7057 + 25 -229.6094199989 0.551E-03 1.4301775881 0.0331710471 844.9741 + 26 -229.6093515388 0.533E-03 1.4296451923 0.0331631079 916.2763 + 28 -229.6094008891 0.560E-03 1.4297163034 0.0331790809 930.6723 + 29 -229.6095237843 0.554E-03 1.4306440666 0.0332000911 989.4300 + 30 -229.6095394076 0.528E-03 1.4311176026 0.0331932710 1010.3513 + 32 -229.6092330566 0.539E-03 1.4282535813 0.0331584855 1018.6815 + 33 -229.6091063365 0.527E-03 1.4272095163 0.0331451135 1098.3633 + 34 -229.6090302052 0.516E-03 1.4267725587 0.0331325790 1134.1885 + 38 -229.6088641762 0.470E-03 1.4248786479 0.0331205994 1143.5443 + 39 -229.6089376122 0.463E-03 1.4249942398 0.0331407083 1153.3397 + 40 -229.6089519416 0.452E-03 1.4248224969 0.0331474587 1154.6824 + 41 -229.6090337614 0.448E-03 1.4257412804 0.0331541443 1243.8356 + 43 -229.6089276277 0.440E-03 1.4247550683 0.0331435719 1269.1863 + 44 -229.6089304432 0.430E-03 1.4246837259 0.0331464454 1292.7323 + 46 -229.6089922070 0.411E-03 1.4253367815 0.0331492217 1313.5073 + 47 -229.6089945447 0.403E-03 1.4254218304 0.0331471359 1330.2431 + 50 -229.6091158903 0.376E-03 1.4267019708 0.0331552356 1393.5766 + 52 -229.6090703515 0.365E-03 1.4258836275 0.0331586020 1405.7410 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 12.405186 GB ] [ VIRT MEM : 17.115452 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3254.150035 s ] [ CPU TIME: 229087.614157 s ] <<<<< .. + +* Number of generators 163840 + +.. >>>>> [ RES MEM : 12.405186 GB ] [ VIRT MEM : 17.115452 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3254.150840 s ] [ CPU TIME: 229087.671465 s ] <<<<< .. + +* Number of selectors 163840 +* Number of comb teeth 100 +* pt2_n_tasks_max 17 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.7750326598781910 + +Summary at N_det = 163840 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.40096575 +# PT2 -0.20810460 0.00036474 +# rPT2 -0.20142561 0.00035303 +# +# E+PT2 -229.60907035 0.00036474 +# E+rPT2 -229.60239136 0.00035303 +# ============ ============================= + + N_det = 163840 + N_states = 1 + + * State 1 + < S^2 > = 7.123027130826926E-003 + E = -229.400965754783 + Variance = 1.42588362747232 + PT norm = 0.182095035613465 + PT2 = -0.208104596717451 + rPT2 = -0.201425605241628 + E+PT2 = -229.609070351501 +/- 3.647363842768916E-004 + E+rPT2 = -229.602391360025 +/- 3.530303900800627E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.558017179929 + Vee = 238.840042883609 + Vecp = 0.000000000000000E+000 + T = 229.208778762747 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2398 -229.61901217 + -0.2878 -229.62157293 + -0.3432 -229.62448484 + -0.4035 -229.62573230 + -0.4636 -229.62705421 + -0.5201 -229.62826752 + -0.5705 -229.62895217 + =========== =================== + +* Number of unique beta determinants 38063 +* Number of unique alpha determinants 38143 + +.. >>>>> [ RES MEM : 12.210995 GB ] [ VIRT MEM : 16.916683 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3265.176980 s ] [ CPU TIME: 229879.221114 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 327680 +* Number of threads for diagonalization 72 +* Memory(Gb) 0.5882993042469025 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.4009663010 0.007123 0.510E-02 + 2 -229.4302037001 0.004862 0.232E-03 + 3 -229.4310075339 0.004815 0.353E-04 + 4 -229.4310760743 0.004846 0.604E-05 + 5 -229.4310864971 0.004858 0.990E-06 + 6 -229.4310883547 0.004861 0.934E-07 + 7 -229.4310886552 0.004864 0.104E-07 + 8 -229.4310886885 0.004865 0.957E-09 + 9 -229.4310886918 0.004865 0.100E-09 + 10 -229.4310886921 0.004865 0.117E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 12.568295 GB ] [ VIRT MEM : 17.334187 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3374.289258 s ] [ CPU TIME: 237660.887682 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 12.260757 GB ] [ VIRT MEM : 16.966499 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3374.341244 s ] [ CPU TIME: 237664.621235 s ] <<<<< .. + +* Energy of state 1 -229.4310886920963 +* S^2 of state 1 0.4864913266398860E-02 +* Saved determinants 327680 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 12.220970 GB ] [ VIRT MEM : 16.923744 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3379.889716 s ] [ CPU TIME: 237772.639648 s ] <<<<< .. + +* Number of generators 327680 + +.. >>>>> [ RES MEM : 12.220970 GB ] [ VIRT MEM : 16.923744 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3379.890907 s ] [ CPU TIME: 237772.725570 s ] <<<<< .. + +* Number of selectors 327680 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 +* PT2 Energy denominator -229.4310886920963 + +.. >>>>> [ RES MEM : 12.296017 GB ] [ VIRT MEM : 17.002361 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3380.064820 s ] [ CPU TIME: 237785.214612 s ] <<<<< .. + +* Number of generators 327680 + +.. >>>>> [ RES MEM : 12.296017 GB ] [ VIRT MEM : 17.002361 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 3380.066001 s ] [ CPU TIME: 237785.299933 s ] <<<<< .. + +* Number of selectors 327680 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 +* Number of tasks 419716 +* Number of fragmented tasks 18900 +* Number of threads for PT2 72 +* Memory (Gb) 6.404925888776779 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6114402368 0.552E-03 1.2829329460 0.0278152573 555.3151 + 4 -229.6112575692 0.421E-03 1.2797200631 0.0278015021 595.7963 + 5 -229.6100060839 0.142E-02 1.2664262532 0.0277091804 796.0210 + 7 -229.6092669388 0.173E-02 1.2577883797 0.0276447951 817.6554 + 10 -229.6089003014 0.145E-02 1.2520237823 0.0276361323 843.1943 + 11 -229.6090694378 0.132E-02 1.2528921909 0.0276642271 876.4943 + 12 -229.6089520526 0.121E-02 1.2504853004 0.0276808656 929.9839 + 13 -229.6089184195 0.111E-02 1.2513378929 0.0276549556 1076.3123 + 14 -229.6089378247 0.103E-02 1.2507140913 0.0276745977 1101.5872 + 15 -229.6088899199 0.942E-03 1.2505318022 0.0276579070 1133.5763 + 18 -229.6089406690 0.790E-03 1.2496670003 0.0276823538 1198.6263 + 19 -229.6090752038 0.741E-03 1.2500000951 0.0277253813 1219.7958 + 20 -229.6090370821 0.704E-03 1.2505278587 0.0277015039 1274.5556 + 22 -229.6087732856 0.631E-03 1.2485111505 0.0276662513 1355.2244 + 24 -229.6089616281 0.603E-03 1.2500837097 0.0276923533 1370.7101 + 27 -229.6090389457 0.560E-03 1.2508377274 0.0276969191 1629.7343 + 32 -229.6093472641 0.516E-03 1.2535436856 0.0277352146 1759.0822 + 34 -229.6095772718 0.494E-03 1.2552510818 0.0277668604 1800.7363 + 35 -229.6096005417 0.456E-03 1.2550480710 0.0277794361 1862.1163 + 38 -229.6095489557 0.430E-03 1.2544023529 0.0277766624 1882.9766 + 40 -229.6097001801 0.425E-03 1.2553803501 0.0277984403 1905.9013 + 41 -229.6096282710 0.421E-03 1.2547045306 0.0277896031 2000.6013 + 42 -229.6095503820 0.418E-03 1.2540829525 0.0277773270 2350.4643 + 58 -229.6097450523 0.354E-03 1.2549832310 0.0278153229 2411.0188 + 59 -229.6097563084 0.335E-03 1.2550748521 0.0278168903 2412.4279 + 60 -229.6097058306 0.333E-03 1.2545779921 0.0278111095 2635.5358 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.117435 GB ] [ VIRT MEM : 20.085648 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6017.097546 s ] [ CPU TIME: 426978.134414 s ] <<<<< .. + +* Number of generators 327680 + +.. >>>>> [ RES MEM : 16.117435 GB ] [ VIRT MEM : 20.085648 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6017.098623 s ] [ CPU TIME: 426978.212679 s ] <<<<< .. + +* Number of selectors 327680 +* Number of comb teeth 100 +* pt2_n_tasks_max 33 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8064285078652442 + +Summary at N_det = 327680 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.43108869 +# PT2 -0.17863240 0.00030530 +# rPT2 -0.17379825 0.00029704 +# +# E+PT2 -229.60972109 0.00030530 +# E+rPT2 -229.60488695 0.00029704 +# ============ ============================= + + N_det = 327680 + N_states = 1 + + * State 1 + < S^2 > = 4.864913266398860E-003 + E = -229.431088692096 + Variance = 1.25458980470710 + PT norm = 0.166777419430299 + PT2 = -0.178632401538825 + rPT2 = -0.173798253919141 + E+PT2 = -229.609721093635 +/- 3.053021754182815E-004 + E+rPT2 = -229.604886946015 +/- 2.970400921015452E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.571547279040 + Vee = 238.792122945946 + Vecp = 0.000000000000000E+000 + T = 229.240105862208 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.2014 -229.62058619 + -0.2398 -229.61971268 + -0.2878 -229.62106288 + -0.3432 -229.62327124 + -0.4035 -229.62451322 + -0.4636 -229.62577325 + -0.5201 -229.62692675 + =========== =================== + +* Number of unique beta determinants 76905 +* Number of unique alpha determinants 77253 + +.. >>>>> [ RES MEM : 16.000683 GB ] [ VIRT MEM : 19.957195 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6063.136271 s ] [ CPU TIME: 430235.576604 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 655360 +* Number of threads for diagonalization 72 +* Memory(Gb) 1.180367104709148 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.4310888038 0.004865 0.310E-02 + 2 -229.4497946502 0.003718 0.177E-03 + 3 -229.4504565467 0.003738 0.218E-04 + 4 -229.4505321131 0.003767 0.644E-05 + 5 -229.4505474498 0.003781 0.126E-05 + 6 -229.4505509796 0.003794 0.355E-06 + 7 -229.4505518063 0.003803 0.359E-07 + 8 -229.4505519337 0.003804 0.502E-08 + 9 -229.4505519515 0.003803 0.703E-09 + 10 -229.4505519540 0.003803 0.105E-09 + 11 -229.4505519544 0.003803 0.164E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 16.751488 GB ] [ VIRT MEM : 20.800976 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6557.816018 s ] [ CPU TIME: 465360.586625 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 16.107079 GB ] [ VIRT MEM : 20.067078 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6557.902720 s ] [ CPU TIME: 465366.534586 s ] <<<<< .. + +* Energy of state 1 -229.4505519544271 +* S^2 of state 1 0.3803143713824979E-02 +* Saved determinants 655360 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 15.953159 GB ] [ VIRT MEM : 19.907383 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6568.740707 s ] [ CPU TIME: 465545.295012 s ] <<<<< .. + +* Number of generators 655358 + +.. >>>>> [ RES MEM : 15.953159 GB ] [ VIRT MEM : 19.907383 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6568.742629 s ] [ CPU TIME: 465545.429550 s ] <<<<< .. + +* Number of selectors 655358 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 +* PT2 Energy denominator -229.4505519544271 + +.. >>>>> [ RES MEM : 16.109344 GB ] [ VIRT MEM : 20.064621 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6569.130034 s ] [ CPU TIME: 465572.796451 s ] <<<<< .. + +* Number of generators 655358 + +.. >>>>> [ RES MEM : 16.109344 GB ] [ VIRT MEM : 20.064621 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 6569.131908 s ] [ CPU TIME: 465572.931652 s ] <<<<< .. + +* Number of selectors 655358 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 +* Number of tasks 838114 +* Number of fragmented tasks 21062 +* Number of threads for PT2 72 +* Memory (Gb) 12.78708426900208 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6119901782 0.293E-02 1.1580618764 0.0246618515 939.7118 + 4 -229.6116269586 0.202E-02 1.1525521804 0.0246457317 943.5957 + 5 -229.6101950044 0.225E-02 1.1402471281 0.0244828662 1059.1195 + 6 -229.6095763608 0.189E-02 1.1338372390 0.0244430163 1225.0148 + 7 -229.6102547050 0.173E-02 1.1377033215 0.0245713148 1487.3877 + 8 -229.6097174491 0.151E-02 1.1335904971 0.0245020162 1613.3186 + 12 -229.6110001649 0.129E-02 1.1432658137 0.0246882563 1910.5682 + 17 -229.6111391901 0.103E-02 1.1433119809 0.0247136072 2001.7237 + 18 -229.6110760280 0.976E-03 1.1433776884 0.0247015973 2062.0038 + 19 -229.6108098824 0.925E-03 1.1403622466 0.0246886208 2131.8518 + 20 -229.6107482658 0.879E-03 1.1397416386 0.0246794707 2156.5737 + 22 -229.6107750212 0.830E-03 1.1401512688 0.0246741964 2186.0228 + 23 -229.6104267787 0.867E-03 1.1372697399 0.0246260811 2244.4297 + 24 -229.6105807189 0.844E-03 1.1377475160 0.0246605870 2371.7247 + 25 -229.6105441432 0.801E-03 1.1379892750 0.0246401990 2410.9756 + 26 -229.6106938063 0.784E-03 1.1394217150 0.0246558344 2467.1477 + 27 -229.6107206151 0.755E-03 1.1391384626 0.0246650071 2573.2847 + 28 -229.6107264604 0.727E-03 1.1393898471 0.0246602761 2655.4637 + 29 -229.6108998815 0.723E-03 1.1409300130 0.0246807707 2708.3357 + 30 -229.6109557200 0.673E-03 1.1411458524 0.0246903452 2796.3317 + 32 -229.6109488180 0.624E-03 1.1409988068 0.0246910998 2972.4158 + 34 -229.6106498809 0.623E-03 1.1387146238 0.0246477843 3117.4826 + 35 -229.6107487125 0.613E-03 1.1396708870 0.0246593327 3158.1808 + 37 -229.6106830819 0.573E-03 1.1388944841 0.0246557986 3203.5807 + 38 -229.6108862350 0.594E-03 1.1408896830 0.0246754193 3327.2099 + 41 -229.6107663675 0.561E-03 1.1396948961 0.0246618922 3517.5767 + 43 -229.6107259759 0.541E-03 1.1394703567 0.0246524882 3539.8028 + 45 -229.6107501672 0.518E-03 1.1399762857 0.0246497645 3616.2998 + 46 -229.6106621735 0.518E-03 1.1387698191 0.0246506477 3677.7404 + 47 -229.6106558539 0.507E-03 1.1387101683 0.0246502677 3872.2360 + 49 -229.6107327120 0.505E-03 1.1390289911 0.0246664238 3884.6092 + 52 -229.6106625255 0.452E-03 1.1387480292 0.0246548404 4202.0406 + 59 -229.6104599560 0.397E-03 1.1364909752 0.0246430387 4217.2337 + 61 -229.6105381253 0.388E-03 1.1370698934 0.0246531322 4280.8188 + 63 -229.6104258215 0.359E-03 1.1363411503 0.0246374198 4374.2419 + 65 -229.6103857219 0.349E-03 1.1363136544 0.0246279773 4413.7738 + 68 -229.6103622867 0.335E-03 1.1360107008 0.0246258417 4444.8768 + 69 -229.6104047608 0.333E-03 1.1364784189 0.0246299375 4602.1168 + 70 -229.6104572702 0.332E-03 1.1370917876 0.0246335964 4634.3750 + 71 -229.6105647859 0.332E-03 1.1379875800 0.0246474783 4733.8008 + 74 -229.6105692839 0.333E-03 1.1381532245 0.0246460205 4891.8048 + 80 -229.6106362320 0.314E-03 1.1394500581 0.0246444047 4960.6328 + 81 -229.6106175195 0.310E-03 1.1393675986 0.0246406354 4963.9067 + 84 -229.6106894060 0.306E-03 1.1399707937 0.0246483692 5008.1451 + 85 -229.6106351281 0.308E-03 1.1394884164 0.0246419379 5106.6588 + 86 -229.6106769508 0.307E-03 1.1399102242 0.0246467606 5305.0927 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 17.751541 GB ] [ VIRT MEM : 21.027313 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11877.131645 s ] [ CPU TIME: 846364.537516 s ] <<<<< .. + +* Number of generators 655358 + +.. >>>>> [ RES MEM : 17.751541 GB ] [ VIRT MEM : 21.027313 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 11877.133525 s ] [ CPU TIME: 846364.672884 s ] <<<<< .. + +* Number of selectors 655358 +* Number of comb teeth 100 +* pt2_n_tasks_max 66 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8263221792243254 + +Summary at N_det = 655360 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.45055195 +# PT2 -0.16012500 0.00030686 +# rPT2 -0.15627336 0.00029948 +# +# E+PT2 -229.61067695 0.00030686 +# E+rPT2 -229.60682532 0.00029948 +# ============ ============================= + + N_det = 655360 + N_states = 1 + + * State 1 + < S^2 > = 3.803143713824979E-003 + E = -229.450551954427 + Variance = 1.13991022418847 + PT norm = 0.156992867866944 + PT2 = -0.160124996390994 + rPT2 = -0.156273364201445 + E+PT2 = -229.610676950818 +/- 3.068595022743165E-004 + E+rPT2 = -229.606825318628 +/- 2.994783315435292E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.579847673765 + Vee = 238.759558490200 + Vecp = 0.000000000000000E+000 + T = 229.261507450349 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1738 -229.62411022 + -0.2014 -229.62197375 + -0.2398 -229.62069661 + -0.2878 -229.62132851 + -0.3432 -229.62296220 + -0.4035 -229.62402522 + -0.4636 -229.62513840 + =========== =================== + +* Number of unique beta determinants 155927 +* Number of unique alpha determinants 156351 + +.. >>>>> [ RES MEM : 18.023392 GB ] [ VIRT MEM : 21.332363 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 12038.536969 s ] [ CPU TIME: 857593.024506 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 1310720 +* Number of threads for diagonalization 72 +* Memory(Gb) 2.368038445711136 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.4505519801 0.003803 0.200E-02 + 2 -229.4619102891 0.004225 0.157E-03 + 3 -229.4623560556 0.004411 0.321E-04 + 4 -229.4624239445 0.004542 0.852E-05 + 5 -229.4624410121 0.004611 0.124E-05 + 6 -229.4624446422 0.004665 0.224E-06 + 7 -229.4624454387 0.004699 0.410E-07 + 8 -229.4624455841 0.004709 0.751E-08 + 9 -229.4624456109 0.004710 0.112E-08 + 10 -229.4624456153 0.004709 0.182E-09 + 11 -229.4624456160 0.004709 0.304E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 19.401897 GB ] [ VIRT MEM : 22.886803 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13816.875737 s ] [ CPU TIME: 980687.069607 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 18.113033 GB ] [ VIRT MEM : 21.420483 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13817.022842 s ] [ CPU TIME: 980692.985622 s ] <<<<< .. + +* Energy of state 1 -229.4624456159761 +* S^2 of state 1 0.4708649202323860E-02 +* Saved determinants 1310720 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 17.882206 GB ] [ VIRT MEM : 21.183155 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13838.776984 s ] [ CPU TIME: 981018.142729 s ] <<<<< .. + +* Number of generators 1310681 + +.. >>>>> [ RES MEM : 17.882206 GB ] [ VIRT MEM : 21.183155 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13838.780286 s ] [ CPU TIME: 981018.376973 s ] <<<<< .. + +* Number of selectors 1310681 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 +* PT2 Energy denominator -229.4624456159761 + +.. >>>>> [ RES MEM : 18.271793 GB ] [ VIRT MEM : 21.574783 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13839.685716 s ] [ CPU TIME: 981072.688667 s ] <<<<< .. + +* Number of generators 1310681 + +.. >>>>> [ RES MEM : 18.271793 GB ] [ VIRT MEM : 21.574783 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 13839.688991 s ] [ CPU TIME: 981072.924346 s ] <<<<< .. + +* Number of selectors 1310681 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 +* Number of tasks 1608853 +* Number of fragmented tasks 22412 +* Number of threads for PT2 72 +* Memory (Gb) 25.55140013571829 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6084577828 0.263E-02 1.0572907039 0.0221133714 1571.0882 + 4 -229.6079971229 0.171E-02 1.0567013346 0.0219839473 1864.2443 + 5 -229.6090965798 0.172E-02 1.0646580080 0.0221560647 1999.8263 + 6 -229.6093941327 0.145E-02 1.0661872241 0.0222138313 2256.9782 + 7 -229.6108422152 0.194E-02 1.0735000161 0.0224743071 2454.8795 + 8 -229.6105591532 0.167E-02 1.0693361866 0.0224691663 2809.0783 + 9 -229.6107884639 0.142E-02 1.0681905294 0.0225668661 2867.2313 + 12 -229.6107992356 0.107E-02 1.0659755304 0.0226006820 3176.2423 + 15 -229.6109281696 0.102E-02 1.0685574611 0.0225912050 3480.3313 + 18 -229.6114660808 0.931E-03 1.0712165847 0.0226888202 3606.7693 + 19 -229.6113961575 0.877E-03 1.0702699943 0.0226925863 3618.3392 + 20 -229.6114536213 0.834E-03 1.0704954599 0.0227082380 3833.6573 + 22 -229.6114166257 0.774E-03 1.0701651123 0.0227087514 3898.2214 + 23 -229.6112761859 0.752E-03 1.0691392443 0.0226856157 3965.3630 + 24 -229.6110516760 0.755E-03 1.0679049619 0.0226450182 4552.8442 + 27 -229.6110079991 0.701E-03 1.0677084341 0.0226420535 4677.9392 + 28 -229.6108683335 0.688E-03 1.0667587413 0.0226244589 5055.3013 + 32 -229.6109878947 0.695E-03 1.0676826708 0.0226311290 5106.6084 + 33 -229.6110307906 0.675E-03 1.0680607041 0.0226347078 5275.6093 + 34 -229.6111451486 0.665E-03 1.0690981006 0.0226449334 5442.5343 + 36 -229.6110071622 0.635E-03 1.0683854254 0.0226195289 5607.4395 + 37 -229.6111151743 0.619E-03 1.0694566130 0.0226280049 5650.3564 + 39 -229.6111999118 0.593E-03 1.0704855156 0.0226396427 5721.1843 + 41 -229.6112693822 0.568E-03 1.0704707621 0.0226591581 5977.4453 + 42 -229.6113304786 0.558E-03 1.0704003975 0.0226799382 6128.7901 + 43 -229.6114566612 0.559E-03 1.0710684205 0.0227005287 6301.5450 + 45 -229.6114802376 0.535E-03 1.0714737618 0.0227026357 6469.9334 + 47 -229.6114835389 0.514E-03 1.0716055439 0.0226997590 6524.9003 + 49 -229.6115275594 0.504E-03 1.0725781200 0.0226947178 6530.2266 + 50 -229.6113843233 0.490E-03 1.0715725600 0.0226724102 6863.8457 + 54 -229.6114262482 0.463E-03 1.0716826305 0.0226787279 7446.0953 + 61 -229.6110204907 0.451E-03 1.0687339365 0.0226209098 7693.9233 + 67 -229.6110920182 0.464E-03 1.0686754091 0.0226399252 7853.1562 + 69 -229.6111085490 0.452E-03 1.0686822507 0.0226430605 7864.4673 + 71 -229.6111723307 0.440E-03 1.0690778943 0.0226555469 8102.3843 + 72 -229.6111753666 0.434E-03 1.0692881980 0.0226544053 8163.5043 + 74 -229.6111818307 0.422E-03 1.0694501061 0.0226541221 8298.1422 + 77 -229.6111581231 0.409E-03 1.0697881571 0.0226435651 8417.0474 + 79 -229.6110968412 0.401E-03 1.0695760448 0.0226307445 8587.0924 + 80 -229.6110964686 0.396E-03 1.0695883969 0.0226308044 8681.5683 + 82 -229.6111245842 0.387E-03 1.0697309632 0.0226365643 8717.7202 + 84 -229.6112033093 0.383E-03 1.0703280715 0.0226475358 8758.3693 + 85 -229.6112048673 0.379E-03 1.0704193284 0.0226472643 8861.8333 + 86 -229.6112234162 0.375E-03 1.0703740074 0.0226533173 8877.1123 + 87 -229.6113055267 0.387E-03 1.0714169345 0.0226568781 9047.4163 + 88 -229.6113061043 0.382E-03 1.0714022451 0.0226573187 9173.6793 + 90 -229.6112774241 0.377E-03 1.0711839029 0.0226540971 9267.0643 + 91 -229.6112371156 0.375E-03 1.0709406918 0.0226475880 9352.8235 + 92 -229.6112421927 0.371E-03 1.0709515738 0.0226483816 9375.4403 + 93 -229.6113025897 0.364E-03 1.0714926385 0.0226533341 9387.6093 + 94 -229.6112574371 0.363E-03 1.0712160814 0.0226457112 9791.5874 + 103 -229.6112575386 0.335E-03 1.0718288702 0.0226349321 9861.5103 + 104 -229.6112370497 0.332E-03 1.0716597482 0.0226326137 10047.0390 + 106 -229.6111501642 0.332E-03 1.0709657183 0.0226214773 10079.8472 + 107 -229.6111419493 0.329E-03 1.0708349542 0.0226208571 10357.7141 + 109 -229.6111043121 0.333E-03 1.0706048797 0.0226144880 10426.4980 + 110 -229.6110776645 0.331E-03 1.0704567031 0.0226099109 11150.9493 + 126 -229.6114025731 0.296E-03 1.0730594855 0.0226516464 11205.4513 + 127 -229.6114358486 0.295E-03 1.0734004312 0.0226557205 11286.6160 + 128 -229.6114190328 0.293E-03 1.0732261387 0.0226537250 11373.6522 + 131 -229.6114362363 0.292E-03 1.0732059995 0.0226584628 11520.4390 + 132 -229.6114763769 0.293E-03 1.0735541084 0.0226637329 11527.1990 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 19.850719 GB ] [ VIRT MEM : 22.895908 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 25372.990012 s ] [ CPU TIME: 1808309.423705 s ] <<<<< .. + +* Number of generators 1310681 + +.. >>>>> [ RES MEM : 19.850719 GB ] [ VIRT MEM : 22.895908 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 25372.993264 s ] [ CPU TIME: 1808309.657678 s ] <<<<< .. + +* Number of selectors 1310681 +* Number of comb teeth 100 +* pt2_n_tasks_max 132 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8383112162487515 + +Summary at N_det = 1310720 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.46244562 +# PT2 -0.14900074 0.00029234 +# rPT2 -0.14569909 0.00028586 +# +# E+PT2 -229.61144636 0.00029234 +# E+rPT2 -229.60814471 0.00028586 +# ============ ============================= + + N_det = 1310720 + N_states = 1 + + * State 1 + < S^2 > = 4.708649202323860E-003 + E = -229.462445615976 + Variance = 1.07323469697373 + PT norm = 0.150534809244305 + PT2 = -0.149000740818207 + rPT2 = -0.145699093182045 + E+PT2 = -229.611446356794 +/- 2.923385885803041E-004 + E+rPT2 = -229.608144709158 +/- 2.858607750832375E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.578037487112 + Vee = 238.732546860200 + Vecp = 0.000000000000000E+000 + T = 229.274815232147 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1563 -229.62632412 + -0.1738 -229.62492042 + -0.2014 -229.62291147 + -0.2398 -229.62149363 + -0.2878 -229.62173167 + -0.3432 -229.62298211 + -0.4035 -229.62387540 + =========== =================== + +* Number of unique beta determinants 299317 +* Number of unique alpha determinants 299381 + +.. >>>>> [ RES MEM : 20.268238 GB ] [ VIRT MEM : 23.789764 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 25807.219614 s ] [ CPU TIME: 1837333.143364 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 2621440 +* Number of threads for diagonalization 72 +* Memory(Gb) 4.682307057082653 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.4624456222 0.004709 0.145E-02 + 2 -229.4701494566 0.005795 0.156E-03 + 3 -229.4704346696 0.006016 0.307E-04 + 4 -229.4704981678 0.006179 0.652E-05 + 5 -229.4705179726 0.006311 0.111E-05 + 6 -229.4705222682 0.006363 0.242E-06 + 7 -229.4705230938 0.006378 0.433E-07 + 8 -229.4705232537 0.006376 0.848E-08 + 9 -229.4705232853 0.006372 0.177E-08 + 10 -229.4705232919 0.006370 0.331E-09 + 11 -229.4705232931 0.006370 0.620E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 22.161758 GB ] [ VIRT MEM : 25.931465 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30624.168691 s ] [ CPU TIME: 2159431.345178 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 19.583828 GB ] [ VIRT MEM : 23.000301 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30624.529608 s ] [ CPU TIME: 2159437.988961 s ] <<<<< .. + +* Energy of state 1 -229.4705232931297 +* S^2 of state 1 0.6369550710436214E-02 +* Saved determinants 2621440 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 18.673920 GB ] [ VIRT MEM : 21.855942 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30668.311539 s ] [ CPU TIME: 2160039.725777 s ] <<<<< .. + +* Number of generators 2621240 + +.. >>>>> [ RES MEM : 18.673920 GB ] [ VIRT MEM : 21.855942 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30668.317985 s ] [ CPU TIME: 2160040.182614 s ] <<<<< .. + +* Number of selectors 2621240 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 +* PT2 Energy denominator -229.4705232931297 + +.. >>>>> [ RES MEM : 19.404621 GB ] [ VIRT MEM : 22.587887 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30670.323279 s ] [ CPU TIME: 2160134.406468 s ] <<<<< .. + +* Number of generators 2621240 + +.. >>>>> [ RES MEM : 19.404621 GB ] [ VIRT MEM : 22.587887 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 30670.329581 s ] [ CPU TIME: 2160134.859635 s ] <<<<< .. + +* Number of selectors 2621240 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 +* Number of tasks 3120527 +* Number of fragmented tasks 23307 +* Number of threads for PT2 72 +* Memory (Gb) 51.07999273687601 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6139487878 0.328E-02 1.0586154583 0.0213358623 3108.8605 + 5 -229.6143216158 0.153E-02 1.0597855660 0.0214227141 3460.6671 + 7 -229.6145102934 0.117E-02 1.0598149299 0.0214322925 4351.6564 + 11 -229.6135680648 0.108E-02 1.0514582759 0.0213159069 5299.7414 + 14 -229.6134761304 0.832E-03 1.0478499105 0.0213574408 5347.2614 + 15 -229.6135665660 0.765E-03 1.0475981321 0.0213802904 5527.2545 + 18 -229.6134536554 0.765E-03 1.0468786249 0.0213642789 6133.8723 + 19 -229.6132765620 0.745E-03 1.0455032748 0.0213384301 6947.3583 + 26 -229.6126500686 0.683E-03 1.0393973030 0.0212757702 6982.0904 + 27 -229.6126307341 0.658E-03 1.0388155534 0.0212775091 7510.3894 + 28 -229.6127722696 0.649E-03 1.0404088981 0.0212929477 7767.9436 + 29 -229.6126241555 0.644E-03 1.0390630620 0.0212762513 8328.5884 + 32 -229.6124565560 0.583E-03 1.0381026102 0.0212491588 9029.6651 + 33 -229.6123987473 0.567E-03 1.0374859281 0.0212451035 9107.6124 + 36 -229.6122605467 0.528E-03 1.0361433356 0.0212336605 10209.3193 + 45 -229.6121566266 0.489E-03 1.0327099496 0.0212592652 10391.7094 + 47 -229.6123315205 0.474E-03 1.0344152196 0.0212808490 11287.4245 + 49 -229.6122689009 0.471E-03 1.0336639270 0.0212768079 11569.8674 + 54 -229.6121468741 0.445E-03 1.0328729059 0.0212533833 11771.8481 + 55 -229.6121558193 0.437E-03 1.0330031112 0.0212542149 11960.7529 + 56 -229.6122210374 0.434E-03 1.0338998216 0.0212581217 11968.7380 + 58 -229.6122972887 0.439E-03 1.0340017076 0.0212762269 11979.8302 + 59 -229.6122569167 0.434E-03 1.0334737058 0.0212736320 12136.8304 + 62 -229.6121774008 0.416E-03 1.0325187132 0.0212686141 12332.2084 + 63 -229.6122085815 0.410E-03 1.0328318743 0.0212717492 12576.8644 + 64 -229.6121664173 0.406E-03 1.0324694811 0.0212674533 12797.5684 + 68 -229.6120999287 0.389E-03 1.0321158565 0.0212543430 12825.7174 + 69 -229.6121340938 0.385E-03 1.0324233151 0.0212585740 13021.0178 + 70 -229.6122601130 0.376E-03 1.0331555553 0.0212822163 13435.2165 + 72 -229.6124145505 0.382E-03 1.0341455420 0.0213088516 13842.1026 + 79 -229.6122307461 0.351E-03 1.0332218835 0.0212765908 14039.1493 + 80 -229.6122340572 0.346E-03 1.0333343569 0.0212753579 14180.9481 + 82 -229.6121412873 0.348E-03 1.0325015520 0.0212647669 14214.0163 + 83 -229.6121208556 0.345E-03 1.0322694084 0.0212638479 14403.6024 + 85 -229.6121299052 0.337E-03 1.0323117516 0.0212654920 14648.4454 + 86 -229.6120960234 0.334E-03 1.0320302003 0.0212608254 14745.6344 + 87 -229.6121241495 0.326E-03 1.0325690143 0.0212574722 14789.8324 + 88 -229.6121707728 0.325E-03 1.0328762087 0.0212652278 15106.6674 + 90 -229.6121572331 0.322E-03 1.0327015134 0.0212640317 16817.7186 + 112 -229.6120864045 0.283E-03 1.0324324448 0.0212491272 17070.7385 + 113 -229.6120717020 0.281E-03 1.0324921700 0.0212441376 17247.0354 + 114 -229.6120480339 0.279E-03 1.0324039525 0.0212398177 17304.7794 + 116 -229.6119337330 0.273E-03 1.0316681093 0.0212215076 17404.9705 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 26.084831 GB ] [ VIRT MEM : 29.272808 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 48087.022111 s ] [ CPU TIME: 3409181.883750 s ] <<<<< .. + +* Number of generators 2621240 + +.. >>>>> [ RES MEM : 26.084831 GB ] [ VIRT MEM : 29.272808 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 48087.028416 s ] [ CPU TIME: 3409182.330238 s ] <<<<< .. + +* Number of selectors 2621240 +* Number of comb teeth 100 +* pt2_n_tasks_max 263 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8464841803168530 + +Summary at N_det = 2621440 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.47052329 +# PT2 -0.14140176 0.00026853 +# rPT2 -0.13846367 0.00026295 +# +# E+PT2 -229.61192505 0.00026853 +# E+rPT2 -229.60898696 0.00026295 +# ============ ============================= + + N_det = 2621440 + N_states = 1 + + * State 1 + < S^2 > = 6.369550710436214E-003 + E = -229.470523293130 + Variance = 1.03165284684030 + PT norm = 0.145668126336215 + PT2 = -0.141401755509312 + rPT2 = -0.138463666850099 + E+PT2 = -229.611925048639 +/- 2.685281020905417E-004 + E+rPT2 = -229.608986959980 +/- 2.629485435582564E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.579133384351 + Vee = 238.714123156264 + Vecp = 0.000000000000000E+000 + T = 229.286257156168 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1457 -229.62510503 + -0.1563 -229.62584149 + -0.1738 -229.62508051 + -0.2014 -229.62338426 + -0.2398 -229.62199690 + -0.2878 -229.62203687 + -0.3432 -229.62304759 + =========== =================== + +* Number of unique beta determinants 541830 +* Number of unique alpha determinants 541542 + +.. >>>>> [ RES MEM : 17.773308 GB ] [ VIRT MEM : 21.632961 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 49210.583872 s ] [ CPU TIME: 3483923.042887 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 5242880 +* Number of threads for diagonalization 72 +* Memory(Gb) 9.135221090167761 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.4705232960 0.006370 0.121E-02 + 2 -229.4767720598 0.007375 0.132E-03 + 3 -229.4770037062 0.007566 0.220E-04 + 4 -229.4770506663 0.007698 0.488E-05 + 5 -229.4770651306 0.007783 0.136E-05 + 6 -229.4770700217 0.007845 0.319E-06 + 7 -229.4770713429 0.007877 0.809E-07 + 8 -229.4770716324 0.007882 0.172E-07 + 9 -229.4770716972 0.007882 0.391E-08 + 10 -229.4770717119 0.007879 0.834E-09 + 11 -229.4770717151 0.007878 0.165E-09 + 12 -229.4770717157 0.007877 0.359E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 23.073372 GB ] [ VIRT MEM : 27.405235 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 62572.021682 s ] [ CPU TIME: 4373591.051588 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 17.526527 GB ] [ VIRT MEM : 21.387642 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 62572.806334 s ] [ CPU TIME: 4373597.890700 s ] <<<<< .. + +* Energy of state 1 -229.4770717157417 +* S^2 of state 1 0.7876592596751296E-02 +* Saved determinants 5242880 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 16.225677 GB ] [ VIRT MEM : 19.328300 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 62659.674308 s ] [ CPU TIME: 4374719.631089 s ] <<<<< .. + +* Number of generators 5241744 + +.. >>>>> [ RES MEM : 16.225677 GB ] [ VIRT MEM : 19.328300 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 62659.686459 s ] [ CPU TIME: 4374720.504283 s ] <<<<< .. + +* Number of selectors 5241744 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 +* PT2 Energy denominator -229.4770717157417 + +.. >>>>> [ RES MEM : 17.834713 GB ] [ VIRT MEM : 20.940140 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 62664.136971 s ] [ CPU TIME: 4374897.812287 s ] <<<<< .. + +* Number of generators 5241744 + +.. >>>>> [ RES MEM : 17.834713 GB ] [ VIRT MEM : 20.940140 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 62664.148633 s ] [ CPU TIME: 4374897.823863 s ] <<<<< .. + +* Number of selectors 5241744 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 +* Number of tasks 6045846 +* Number of fragmented tasks 23991 +* Number of threads for PT2 72 +* Memory (Gb) 102.1371613103151 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6144332478 0.256E-02 1.0112649908 0.0204335495 4004.5034 + 4 -229.6146174120 0.168E-02 1.0111984476 0.0204708980 4735.3847 + 5 -229.6137334679 0.155E-02 1.0050983490 0.0203254475 5230.3329 + 6 -229.6142540367 0.135E-02 1.0103240286 0.0203794078 5823.8848 + 7 -229.6136805419 0.136E-02 1.0071648692 0.0202625405 6727.7838 + 8 -229.6139385789 0.120E-02 1.0086947332 0.0202971576 6731.8130 + 9 -229.6136212538 0.112E-02 1.0060174198 0.0202559115 7272.5238 + 10 -229.6138605736 0.104E-02 1.0090483766 0.0202703639 7277.5345 + 11 -229.6137229613 0.986E-03 1.0079387272 0.0202442921 7829.1089 + 12 -229.6139043939 0.917E-03 1.0083793246 0.0202876429 8082.2079 + 13 -229.6138185753 0.846E-03 1.0082869884 0.0202649275 8186.8759 + 14 -229.6134260258 0.870E-03 1.0061282417 0.0202008639 9068.9638 + 15 -229.6134764396 0.810E-03 1.0072467235 0.0201990225 9653.3400 + 18 -229.6131215035 0.715E-03 1.0044440823 0.0201493265 10052.3049 + 19 -229.6130095618 0.718E-03 1.0037841576 0.0201286638 10821.3048 + 20 -229.6129178199 0.687E-03 1.0032108034 0.0201131394 11079.5019 + 22 -229.6131091073 0.638E-03 1.0054460706 0.0201274857 11315.7958 + 24 -229.6128680618 0.612E-03 1.0037797971 0.0200925139 12052.9378 + 27 -229.6131688364 0.624E-03 1.0065898211 0.0201319080 12609.4129 + 28 -229.6132381903 0.605E-03 1.0070299915 0.0201427446 13138.0019 + 29 -229.6134272481 0.614E-03 1.0090015747 0.0201608847 13228.3489 + 30 -229.6133369746 0.600E-03 1.0079113397 0.0201574350 13429.6568 + 31 -229.6134230463 0.587E-03 1.0087680406 0.0201660605 13491.5940 + 32 -229.6136256710 0.596E-03 1.0103636925 0.0201913169 14675.6730 + 34 -229.6139544068 0.602E-03 1.0118568915 0.0202575837 14843.8828 + 36 -229.6137479881 0.600E-03 1.0097168584 0.0202402308 14913.8769 + 37 -229.6137692839 0.584E-03 1.0099659636 0.0202432197 15230.3357 + 39 -229.6137725533 0.571E-03 1.0096150124 0.0202509168 15436.4080 + 40 -229.6137600681 0.557E-03 1.0095834881 0.0202486947 16006.7938 + 41 -229.6137223957 0.544E-03 1.0090970924 0.0202463472 16131.7061 + 42 -229.6136965054 0.532E-03 1.0087720367 0.0202450406 16493.7838 + 43 -229.6135855267 0.531E-03 1.0075715059 0.0202361800 16879.7439 + 45 -229.6134073797 0.521E-03 1.0057161980 0.0202213210 17025.5444 + 47 -229.6134794184 0.509E-03 1.0065516748 0.0202298171 17545.1058 + 48 -229.6134885164 0.493E-03 1.0068062858 0.0202266829 17671.1088 + 49 -229.6135361292 0.485E-03 1.0072233667 0.0202345194 17947.2669 + 50 -229.6135047227 0.476E-03 1.0069770382 0.0202304065 18155.8440 + 51 -229.6134743433 0.468E-03 1.0067895128 0.0202259070 18393.4922 + 52 -229.6135231600 0.466E-03 1.0069853735 0.0202385509 18530.7848 + 53 -229.6136184212 0.467E-03 1.0074306676 0.0202561392 18782.7448 + 54 -229.6135833762 0.460E-03 1.0070192067 0.0202534788 18906.0379 + 55 -229.6134894807 0.461E-03 1.0061559918 0.0202419795 18923.6439 + 56 -229.6135299036 0.455E-03 1.0062195218 0.0202526192 19348.4908 + 57 -229.6134312537 0.457E-03 1.0055165080 0.0202385848 19510.4808 + 59 -229.6132366946 0.446E-03 1.0040239108 0.0202139656 20383.7988 + 61 -229.6132244539 0.449E-03 1.0038243972 0.0202125059 20821.7419 + 69 -229.6130737596 0.421E-03 1.0021660019 0.0202039504 21295.7279 + 70 -229.6131528835 0.422E-03 1.0029144766 0.0202122118 21494.6826 + 71 -229.6131607736 0.416E-03 1.0031516352 0.0202102940 21547.9738 + 72 -229.6131735011 0.410E-03 1.0032150238 0.0202123076 21794.7340 + 74 -229.6131506729 0.399E-03 1.0028400302 0.0202114126 21795.7749 + 75 -229.6131650253 0.394E-03 1.0030418325 0.0202116267 21880.9199 + 76 -229.6131936288 0.390E-03 1.0032831065 0.0202152853 22214.5568 + 77 -229.6131765908 0.385E-03 1.0032212959 0.0202118702 22355.0143 + 78 -229.6131782452 0.380E-03 1.0030682317 0.0202144498 22606.0361 + 79 -229.6132525321 0.383E-03 1.0037732212 0.0202210230 23240.1691 + 83 -229.6133107642 0.375E-03 1.0045017779 0.0202257374 23541.9718 + 86 -229.6132948660 0.368E-03 1.0043210610 0.0202232879 23993.4330 + 87 -229.6133240845 0.365E-03 1.0045622157 0.0202266212 24018.7769 + 88 -229.6133159934 0.360E-03 1.0044422055 0.0202260110 24415.6008 + 91 -229.6133010028 0.356E-03 1.0042228854 0.0202253683 24772.9919 + 93 -229.6133642727 0.353E-03 1.0047486998 0.0202333746 24827.4959 + 94 -229.6133286297 0.344E-03 1.0046517501 0.0202251632 25054.3339 + 95 -229.6133131194 0.341E-03 1.0046062761 0.0202221906 25882.7279 + 101 -229.6133387617 0.343E-03 1.0050806607 0.0202203051 26095.2650 + 103 -229.6133417336 0.337E-03 1.0053601180 0.0202183084 26117.8030 + 104 -229.6133034361 0.336E-03 1.0051459810 0.0202112998 26277.2820 + 105 -229.6133189221 0.332E-03 1.0052768092 0.0202139411 26523.3851 + 106 -229.6133225037 0.329E-03 1.0052045001 0.0202156272 26676.4860 + 107 -229.6133143944 0.326E-03 1.0051389235 0.0202144554 26970.7309 + 108 -229.6132907671 0.324E-03 1.0049455727 0.0202107712 27396.5922 + 112 -229.6132433559 0.316E-03 1.0046021410 0.0202040749 27568.1528 + 114 -229.6131660224 0.318E-03 1.0039037708 0.0201946316 27715.1291 + 115 -229.6132587200 0.319E-03 1.0048508606 0.0202031742 27780.8598 + 118 -229.6131721222 0.321E-03 1.0040130643 0.0201948517 27914.2409 + 119 -229.6131264803 0.321E-03 1.0036086944 0.0201891127 27957.5149 + 120 -229.6131374818 0.319E-03 1.0037514918 0.0201893160 28138.3832 + 121 -229.6131127450 0.317E-03 1.0036154366 0.0201846980 28279.5914 + 123 -229.6130850954 0.314E-03 1.0033502512 0.0201818757 28407.2548 + 124 -229.6130331331 0.315E-03 1.0028564907 0.0201766651 28661.3188 + 125 -229.6130368536 0.313E-03 1.0028684018 0.0201773590 28984.7161 + 126 -229.6129894760 0.314E-03 1.0024242432 0.0201721963 29115.6358 + 127 -229.6129534039 0.314E-03 1.0021109269 0.0201670536 29195.2899 + 128 -229.6130079396 0.321E-03 1.0023311723 0.0201781967 29460.3269 + 131 -229.6129845529 0.315E-03 1.0022329584 0.0201725136 29733.5309 + 134 -229.6129643982 0.309E-03 1.0020793526 0.0201702419 30036.4719 + 136 -229.6129346555 0.306E-03 1.0020038833 0.0201631443 30371.7813 + 137 -229.6129427158 0.304E-03 1.0020629385 0.0201641130 30539.3850 + 139 -229.6129040976 0.298E-03 1.0018787552 0.0201561362 30736.0132 + 140 -229.6129166270 0.297E-03 1.0019107769 0.0201590946 30847.6260 + 142 -229.6128740205 0.294E-03 1.0015301685 0.0201536767 30985.5009 + 143 -229.6129013202 0.293E-03 1.0018022512 0.0201567472 31171.8190 + 144 -229.6129336621 0.293E-03 1.0020436266 0.0201616903 31351.0893 + 146 -229.6129468390 0.289E-03 1.0021224226 0.0201637228 31505.8402 + 147 -229.6129169088 0.289E-03 1.0019350718 0.0201588843 31689.5820 + 149 -229.6129294992 0.287E-03 1.0021191099 0.0201590102 31931.7102 + 150 -229.6128988345 0.288E-03 1.0019536656 0.0201538627 31941.8469 + 151 -229.6128450010 0.291E-03 1.0015307569 0.0201464814 32074.0831 + 152 -229.6128303245 0.289E-03 1.0013453604 0.0201455852 32327.8938 + 153 -229.6128187505 0.288E-03 1.0012889724 0.0201435163 32662.0329 + 154 -229.6128281374 0.286E-03 1.0014143465 0.0201444042 32682.9869 + 155 -229.6128217556 0.284E-03 1.0013743055 0.0201432589 33125.0010 + 159 -229.6128029707 0.284E-03 1.0012594919 0.0201393571 33580.8581 + 161 -229.6128138723 0.283E-03 1.0012948903 0.0201419672 33645.8571 + 163 -229.6128114881 0.279E-03 1.0012154195 0.0201422178 33976.6980 + 165 -229.6128578747 0.272E-03 1.0014714752 0.0201515622 34096.4599 + 167 -229.6128483982 0.269E-03 1.0014802800 0.0201489096 34330.9779 + 168 -229.6128439978 0.267E-03 1.0014827572 0.0201480236 34351.5991 + 169 -229.6128458593 0.266E-03 1.0015763478 0.0201470331 34405.0308 + 170 -229.6128294845 0.265E-03 1.0015033804 0.0201439390 34691.1204 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 26.149158 GB ] [ VIRT MEM : 29.338898 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 97378.145689 s ] [ CPU TIME: 6862768.920253 s ] <<<<< .. + +* Number of generators 5241744 + +.. >>>>> [ RES MEM : 26.149158 GB ] [ VIRT MEM : 29.338898 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 97378.156808 s ] [ CPU TIME: 6862768.931292 s ] <<<<< .. + +* Number of selectors 5241744 +* Number of comb teeth 100 +* pt2_n_tasks_max 525 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8526461531918800 + +Summary at N_det = 5242880 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.47707172 +# PT2 -0.13575777 0.00026458 +# rPT2 -0.13307707 0.00025936 +# +# E+PT2 -229.61282948 0.00026458 +# E+rPT2 -229.61014879 0.00025936 +# ============ ============================= + + N_det = 5242880 + N_states = 1 + + * State 1 + < S^2 > = 7.876592596751296E-003 + E = -229.477071715742 + Variance = 1.00150338043737 + PT norm = 0.141929345231953 + PT2 = -0.135757768741394 + rPT2 = -0.133077072309441 + E+PT2 = -229.612829484483 +/- 2.645818671384988E-004 + E+rPT2 = -229.610148788051 +/- 2.593573877309982E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.583183708959 + Vee = 238.699603206414 + Vecp = 0.000000000000000E+000 + T = 229.298279008014 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1385 -229.63885202 + -0.1457 -229.63084858 + -0.1563 -229.62837441 + -0.1738 -229.62649403 + -0.2014 -229.62440377 + -0.2398 -229.62279157 + -0.2878 -229.62257821 + =========== =================== + +* Number of unique beta determinants 923712 +* Number of unique alpha determinants 878270 + +.. >>>>> [ RES MEM : 28.342758 GB ] [ VIRT MEM : 33.274990 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 100142.026073 s ] [ CPU TIME: 7049687.152403 s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 10485760 +* Number of threads for diagonalization 72 +* Memory(Gb) 17.62619972601533 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.4770717178 0.007877 0.108E-02 + 2 -229.4827667604 0.009135 0.978E-04 + 3 -229.4829419561 0.009260 0.144E-04 + 4 -229.4829689421 0.009338 0.130E-05 + 5 -229.4829731367 0.009371 0.187E-06 + 6 -229.4829739243 0.009388 0.341E-07 + 7 -229.4829740796 0.009397 0.828E-08 + 8 -229.4829741133 0.009402 0.201E-08 + 9 -229.4829741217 0.009405 0.419E-09 + 10 -229.4829741236 0.009407 0.929E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 39.166859 GB ] [ VIRT MEM : 45.979141 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 127526.451671 s ] [ CPU TIME: 8903282.312074 s ] <<<<< .. + + +.. >>>>> [ RES MEM : 29.010700 GB ] [ VIRT MEM : 33.945923 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 127527.680208 s ] [ CPU TIME: 8903288.921146 s ] <<<<< .. + +* Energy of state 1 -229.4829741236329 +* S^2 of state 1 0.9406969096859598E-02 +* Saved determinants 10485760 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 27.110012 GB ] [ VIRT MEM : 30.445778 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 127698.328141 s ] [ CPU TIME: 8905380.798026 s ] <<<<< .. + +* Number of generators 10482954 + +.. >>>>> [ RES MEM : 27.110012 GB ] [ VIRT MEM : 30.445778 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 127698.351705 s ] [ CPU TIME: 8905382.490948 s ] <<<<< .. + +* Number of selectors 10482954 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -229.4829741236329 + +.. >>>>> [ RES MEM : 30.156700 GB ] [ VIRT MEM : 33.492668 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 127707.508505 s ] [ CPU TIME: 8905720.978722 s ] <<<<< .. + +* Number of generators 10482954 + +.. >>>>> [ RES MEM : 30.156700 GB ] [ VIRT MEM : 33.492668 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 127707.531090 s ] [ CPU TIME: 8905721.001194 s ] <<<<< .. + +* Number of selectors 10482954 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 11436716 +* Number of fragmented tasks 24364 +* Number of threads for PT2 49 +* Memory (Gb) 139.5341278969497 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6144391798 0.844E-03 0.9787131395 0.0193322729 6101.6803 + 4 -229.6135777212 0.129E-02 0.9726131851 0.0192062470 7241.0559 + 5 -229.6136951987 0.983E-03 0.9750629472 0.0192022919 8399.5306 + 6 -229.6131582090 0.987E-03 0.9736877252 0.0190965879 9270.0211 + 7 -229.6121894127 0.131E-02 0.9646813009 0.0189854447 10249.8985 + 8 -229.6121649851 0.103E-02 0.9620102247 0.0190265702 11204.9838 + 9 -229.6124281042 0.907E-03 0.9666626791 0.0190311535 12258.6354 + 10 -229.6126466838 0.841E-03 0.9681570395 0.0190456624 12369.8117 + 11 -229.6129691723 0.827E-03 0.9706385448 0.0190875125 12907.0856 + 12 -229.6127737819 0.769E-03 0.9683482268 0.0190727543 13736.1338 + 13 -229.6131520144 0.804E-03 0.9698209271 0.0191625725 14158.4003 + 14 -229.6131692743 0.744E-03 0.9701238009 0.0191558858 15066.3744 + 15 -229.6130173514 0.708E-03 0.9693743672 0.0191203232 15531.8316 + 16 -229.6133396559 0.735E-03 0.9730612770 0.0191526745 16555.2750 + 18 -229.6129453343 0.723E-03 0.9683520194 0.0191254482 16703.7241 + 19 -229.6129221984 0.683E-03 0.9686632450 0.0191097041 17576.2609 + 20 -229.6130095145 0.654E-03 0.9690573869 0.0191249989 18647.3206 + 22 -229.6137386379 0.738E-03 0.9751502195 0.0192171989 19126.8286 + 23 -229.6137878658 0.706E-03 0.9762428043 0.0192109653 19324.7752 + 24 -229.6136465748 0.691E-03 0.9748316990 0.0191934521 19793.0985 + 25 -229.6134358379 0.691E-03 0.9732117247 0.0191658905 20130.4440 + 26 -229.6135258413 0.669E-03 0.9741143887 0.0191767580 20454.4521 + 27 -229.6135010926 0.644E-03 0.9731882992 0.0191866499 21220.0415 + 28 -229.6134555800 0.622E-03 0.9722165837 0.0191909956 21664.0679 + 29 -229.6135356834 0.606E-03 0.9727250042 0.0191988737 22553.7885 + 30 -229.6136335398 0.595E-03 0.9737128036 0.0192108473 23385.4470 + 31 -229.6134041477 0.620E-03 0.9719855176 0.0191782376 23524.3041 + 32 -229.6134050731 0.600E-03 0.9720671092 0.0191737815 24349.3846 + 33 -229.6135293420 0.595E-03 0.9734515156 0.0191840041 24879.9654 + 34 -229.6134990869 0.578E-03 0.9735470109 0.0191740105 25254.9783 + 35 -229.6135768938 0.566E-03 0.9744089645 0.0191778634 25885.5804 + 36 -229.6135597118 0.551E-03 0.9738773500 0.0191798926 26175.8436 + 37 -229.6133638749 0.568E-03 0.9720862540 0.0191568122 26294.0027 + 38 -229.6134060427 0.554E-03 0.9725746518 0.0191598659 26897.3233 + 39 -229.6131875095 0.583E-03 0.9706929349 0.0191324123 27151.5172 + 40 -229.6131128440 0.573E-03 0.9703909793 0.0191160249 27504.4909 + 41 -229.6130090384 0.576E-03 0.9699388922 0.0190958708 27903.2704 + 42 -229.6128464333 0.585E-03 0.9684697652 0.0190754591 28552.5284 + 43 -229.6129119023 0.575E-03 0.9690871022 0.0190820574 29042.6477 + 44 -229.6130463272 0.578E-03 0.9701364641 0.0190991268 29118.0685 + 45 -229.6129896108 0.568E-03 0.9699130712 0.0190901146 29757.8794 + 47 -229.6128605356 0.551E-03 0.9691774549 0.0190690369 30517.9170 + 48 -229.6128686729 0.539E-03 0.9692307618 0.0190722573 30706.2743 + 49 -229.6128203133 0.526E-03 0.9692440628 0.0190586686 31013.5611 + 50 -229.6127593057 0.519E-03 0.9686551524 0.0190517524 31677.0957 + 51 -229.6127383346 0.509E-03 0.9684256094 0.0190487340 32010.4978 + 52 -229.6127838891 0.501E-03 0.9684667752 0.0190594875 32397.0597 + 54 -229.6129478858 0.490E-03 0.9699584424 0.0190815657 32771.3028 + 55 -229.6130511526 0.492E-03 0.9709554434 0.0190932425 33396.4181 + 56 -229.6130732856 0.484E-03 0.9714370840 0.0190918491 34132.6078 + 59 -229.6128778920 0.486E-03 0.9696415482 0.0190675036 34181.1597 + 61 -229.6129446000 0.469E-03 0.9696487228 0.0190865745 34591.0713 + 62 -229.6130257566 0.468E-03 0.9703568939 0.0190946454 34858.3463 + 63 -229.6131889302 0.489E-03 0.9718622878 0.0191126359 35141.6935 + 64 -229.6132764126 0.489E-03 0.9724144171 0.0191259677 35583.2204 + 67 -229.6131924730 0.471E-03 0.9721473913 0.0191071115 35936.9390 + 68 -229.6131591340 0.466E-03 0.9719033916 0.0191019125 36028.6823 + 69 -229.6132411808 0.466E-03 0.9726120284 0.0191104986 36576.3632 + 70 -229.6132084913 0.460E-03 0.9722042364 0.0191091571 37384.9310 + 72 -229.6132135060 0.448E-03 0.9721078124 0.0191148234 37682.3852 + 74 -229.6131514805 0.440E-03 0.9716332649 0.0191066364 37864.8722 + 76 -229.6132172547 0.430E-03 0.9721547598 0.0191141680 38387.7300 + 77 -229.6132618092 0.426E-03 0.9724114472 0.0191226198 38661.9247 + 78 -229.6132858264 0.421E-03 0.9724488138 0.0191281385 38942.0469 + 79 -229.6132785556 0.416E-03 0.9725868550 0.0191245543 39748.7875 + 80 -229.6132438551 0.412E-03 0.9724924341 0.0191181068 39816.7351 + 82 -229.6132900588 0.407E-03 0.9727033095 0.0191267770 40107.5797 + 83 -229.6132782753 0.403E-03 0.9724974736 0.0191267247 41100.3979 + 86 -229.6132325613 0.391E-03 0.9716748994 0.0191274768 41115.7787 + 87 -229.6131452880 0.396E-03 0.9709321720 0.0191166845 41458.5052 + 88 -229.6131706983 0.393E-03 0.9709525585 0.0191227299 41866.5838 + 90 -229.6132667938 0.390E-03 0.9716585268 0.0191350553 42618.0050 + 93 -229.6133400652 0.380E-03 0.9722049613 0.0191455249 42883.3989 + 94 -229.6133387392 0.376E-03 0.9722304463 0.0191447796 43915.4051 + 98 -229.6133972474 0.364E-03 0.9728078006 0.0191505633 44463.5701 + 102 -229.6132991972 0.358E-03 0.9722286405 0.0191338211 44698.9532 + 103 -229.6133167966 0.355E-03 0.9723721376 0.0191360331 45138.8842 + 104 -229.6133308231 0.352E-03 0.9724803012 0.0191375994 45328.3981 + 105 -229.6133631417 0.350E-03 0.9726207573 0.0191446243 45610.4170 + 106 -229.6133373195 0.345E-03 0.9724360024 0.0191403647 46453.4768 + 111 -229.6133100169 0.333E-03 0.9722381049 0.0191358078 46920.8144 + 112 -229.6133058835 0.330E-03 0.9723461884 0.0191330660 47781.5955 + 116 -229.6133932892 0.324E-03 0.9730558886 0.0191444382 48462.9197 + 117 -229.6132888819 0.319E-03 0.9723735995 0.0191280102 48666.4636 + 121 -229.6133303852 0.311E-03 0.9727505640 0.0191328565 48932.8285 + 123 -229.6133091349 0.306E-03 0.9725886397 0.0191303121 49340.8260 + 124 -229.6132886244 0.304E-03 0.9723687706 0.0191285393 49670.2463 + 125 -229.6132971629 0.302E-03 0.9723357871 0.0191310801 50094.3285 + 126 -229.6133128083 0.300E-03 0.9724976566 0.0191324659 50229.9812 + 127 -229.6133159626 0.297E-03 0.9724777767 0.0191338858 50419.3933 + 128 -229.6133322603 0.295E-03 0.9725889477 0.0191356711 50910.3080 + 131 -229.6132846181 0.292E-03 0.9722248631 0.0191287314 51125.7135 + 132 -229.6132757401 0.290E-03 0.9721606063 0.0191271503 51253.7931 + 134 -229.6133264331 0.289E-03 0.9725594334 0.0191338426 51603.0324 + 135 -229.6133336142 0.287E-03 0.9727271897 0.0191332569 51946.6846 + 137 -229.6133038026 0.285E-03 0.9721993433 0.0191342483 52376.3875 + 138 -229.6132707761 0.282E-03 0.9720655802 0.0191280222 52411.4742 + 139 -229.6132958099 0.281E-03 0.9722128929 0.0191318877 52637.1352 + 140 -229.6133160516 0.280E-03 0.9724004010 0.0191346272 52797.9720 + 141 -229.6133070679 0.278E-03 0.9723367778 0.0191335483 53154.7858 + 142 -229.6133332229 0.278E-03 0.9726086339 0.0191362188 53251.0619 + 143 -229.6133357505 0.276E-03 0.9726270515 0.0191366596 53537.2299 + 144 -229.6133260417 0.274E-03 0.9724901910 0.0191365630 53690.1971 + 146 -229.6133191913 0.270E-03 0.9724470044 0.0191347499 53892.7879 + 147 -229.6133247472 0.268E-03 0.9725480999 0.0191338791 54155.3873 + 148 -229.6134178603 0.263E-03 0.9730544338 0.0191496474 54438.1966 + 149 -229.6134081667 0.261E-03 0.9729583438 0.0191484766 54746.3902 + 150 -229.6134180437 0.260E-03 0.9730301331 0.0191498280 55198.2216 + 151 -229.6134121021 0.258E-03 0.9730756620 0.0191475268 55226.3989 + 152 -229.6134100860 0.257E-03 0.9731174118 0.0191463486 55271.8537 +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 28.520943 GB ] [ VIRT MEM : 32.099110 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 183024.497452 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 10482954 + +.. >>>>> [ RES MEM : 28.520943 GB ] [ VIRT MEM : 32.099110 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 183024.519320 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 10482954 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8584110745943684 + +Summary at N_det = 10485760 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.48297412 +# PT2 -0.13043596 0.00025655 +# rPT2 -0.12798551 0.00025173 +# +# E+PT2 -229.61341009 0.00025655 +# E+rPT2 -229.61095963 0.00025173 +# ============ ============================= + + N_det = 10485760 + N_states = 1 + + * State 1 + < S^2 > = 9.406969096859598E-003 + E = -229.482974123633 + Variance = 0.973117411809485 + PT norm = 0.138370331219028 + PT2 = -0.130435962342354 + rPT2 = -0.127985507210461 + E+PT2 = -229.613410085975 +/- 2.565493450210496E-004 + E+rPT2 = -229.610959630843 +/- 2.517296415604310E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.583985730929 + Vee = 238.684700660727 + Vecp = 0.000000000000000E+000 + T = 229.308081167780 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1331 -229.63134160 + -0.1385 -229.63513930 + -0.1457 -229.63174064 + -0.1563 -229.62949771 + -0.1738 -229.62744185 + -0.2014 -229.62521572 + -0.2398 -229.62347030 + =========== =================== + +* Number of unique beta determinants 1520205 +* Number of unique alpha determinants 1457882 + +.. >>>>> [ RES MEM : 33.749149 GB ] [ VIRT MEM : 40.417747 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 191175.964539 s ] [ CPU TIME: ************** s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 20971520 +* Number of threads for diagonalization 72 +* Memory(Gb) 33.93455018848181 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.4829741246 0.009407 0.104E-02 + 2 -229.4886274318 0.010511 0.986E-04 + 3 -229.4888211424 0.010622 0.159E-04 + 4 -229.4888509359 0.010694 0.147E-05 + 5 -229.4888555281 0.010716 0.190E-06 + 6 -229.4888563518 0.010719 0.376E-07 + 7 -229.4888565103 0.010720 0.912E-08 + 8 -229.4888565469 0.010719 0.249E-08 + 9 -229.4888565573 0.010719 0.692E-09 + 10 -229.4888565601 0.010718 0.161E-09 + 11 -229.4888565608 0.010718 0.389E-10 +====== ================ =========== =========== + + +.. >>>>> [ RES MEM : 54.843021 GB ] [ VIRT MEM : 64.319141 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 280766.489202 s ] [ CPU TIME: ************** s ] <<<<< .. + + +.. >>>>> [ RES MEM : 33.436924 GB ] [ VIRT MEM : 40.097931 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 280769.069475 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Energy of state 1 -229.4888565608188 +* S^2 of state 1 0.1071836052757673E-01 +* Saved determinants 20971520 +-------------------------------------------------------------------------------- + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 31.890965 GB ] [ VIRT MEM : 35.430775 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 281115.239840 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 20963892 + +.. >>>>> [ RES MEM : 31.890965 GB ] [ VIRT MEM : 35.430775 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 281115.287262 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 20963892 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* PT2 Energy denominator -229.4888565608188 + +.. >>>>> [ RES MEM : 37.866425 GB ] [ VIRT MEM : 41.407341 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 281135.956875 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 20963892 + +.. >>>>> [ RES MEM : 37.866425 GB ] [ VIRT MEM : 41.407341 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 281136.002157 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 20963892 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 +* Number of tasks 21919928 +* Number of fragmented tasks 24612 +* Number of threads for PT2 41 +* Memory (Gb) 129.3389113129675 +========== ================= =========== =============== =============== ================= + Samples Energy Stat. Err Variance Norm Seconds +========== ================= =========== =============== =============== ================= + 3 -229.6144944884 0.197E-02 0.9440851329 0.0183206787 9365.9918 + 4 -229.6156618021 0.194E-02 0.9547432525 0.0184177774 11300.9996 + 5 -229.6160151276 0.161E-02 0.9562931782 0.0184963937 12873.7761 + 6 -229.6155961524 0.131E-02 0.9516414475 0.0184627074 14706.8090 + 7 -229.6152316506 0.119E-02 0.9481235019 0.0184184614 15960.6873 + 8 -229.6151488381 0.103E-02 0.9477915373 0.0184025299 19126.7634 + 10 -229.6152542563 0.910E-03 0.9480436286 0.0184428807 19407.6555 + 11 -229.6147479442 0.939E-03 0.9436733296 0.0183841164 20126.4334 + 12 -229.6152157759 0.980E-03 0.9476710751 0.0184428546 21253.8465 + 13 -229.6146821650 0.105E-02 0.9445606954 0.0183509289 21847.0903 + 14 -229.6146282896 0.974E-03 0.9442866113 0.0183431434 23073.3948 + 15 -229.6143349550 0.941E-03 0.9422287718 0.0182946372 24270.4888 + 16 -229.6144464197 0.886E-03 0.9429084554 0.0183156747 24738.7645 + 17 -229.6142617998 0.852E-03 0.9414537604 0.0182910072 24884.8173 + 18 -229.6145367576 0.850E-03 0.9429252072 0.0183431206 26355.3667 + 19 -229.6147012168 0.830E-03 0.9445931051 0.0183613419 27388.6822 + 20 -229.6144809166 0.818E-03 0.9428070114 0.0183354337 28415.4804 + 21 -229.6144447648 0.778E-03 0.9418945906 0.0183415987 28759.6207 + 22 -229.6145831152 0.751E-03 0.9430429258 0.0183560977 29464.7976 + 23 -229.6149056399 0.788E-03 0.9455121418 0.0183977998 30185.3493 + 24 -229.6146538102 0.763E-03 0.9434418346 0.0183717291 30995.2822 + 25 -229.6147478282 0.737E-03 0.9442700281 0.0183873497 31751.8456 + 26 -229.6147129102 0.709E-03 0.9445141383 0.0183732445 31997.4328 + 27 -229.6147902840 0.702E-03 0.9447196999 0.0183919833 32998.8034 + 28 -229.6145259554 0.727E-03 0.9425996763 0.0183562641 34209.4263 + 29 -229.6143778494 0.717E-03 0.9414323403 0.0183350976 36685.2971 + 31 -229.6143817699 0.685E-03 0.9422992534 0.0183225555 37318.1791 + 32 -229.6144871304 0.672E-03 0.9428513458 0.0183407361 38214.3907 + 33 -229.6143864286 0.648E-03 0.9419903952 0.0183268393 38856.4056 + 34 -229.6143206142 0.632E-03 0.9419477551 0.0183111512 40283.6364 + 35 -229.6141382345 0.631E-03 0.9404654182 0.0182910589 40828.8361 + 36 -229.6140314078 0.623E-03 0.9397444844 0.0182765255 41544.7545 + 37 -229.6141350781 0.614E-03 0.9405438780 0.0182896841 41986.5584 + 38 -229.6142788701 0.615E-03 0.9418515867 0.0183052363 42422.3552 + 39 -229.6140753525 0.627E-03 0.9404137687 0.0182731363 43019.0444 + 40 -229.6141932533 0.622E-03 0.9407511149 0.0182987340 43661.1566 + 41 -229.6141077079 0.613E-03 0.9405422649 0.0182793169 44824.1478 + 42 -229.6140631951 0.599E-03 0.9404453902 0.0182694938 45458.0411 + 43 -229.6140769822 0.585E-03 0.9404419876 0.0182731372 46774.5837 + 44 -229.6141791129 0.581E-03 0.9410280364 0.0182886927 46992.7705 + 45 -229.6141594804 0.576E-03 0.9409402411 0.0182830423 47583.9490 + 46 -229.6140941544 0.567E-03 0.9409665659 0.0182664705 47705.0653 + 47 -229.6140073407 0.562E-03 0.9401879349 0.0182583377 48746.7797 + 48 -229.6140469097 0.563E-03 0.9405301616 0.0182628095 49434.0493 + 49 -229.6140020890 0.553E-03 0.9400302252 0.0182598077 49999.9292 + 50 -229.6139571072 0.544E-03 0.9397808940 0.0182526851 50718.4082 + 51 -229.6138874569 0.538E-03 0.9391213471 0.0182449044 51150.1996 + 52 -229.6139709063 0.527E-03 0.9403583914 0.0182480170 51802.4029 + 53 -229.6140340924 0.521E-03 0.9408688459 0.0182547640 52116.5896 + 54 -229.6140712366 0.512E-03 0.9411023504 0.0182633169 52918.3548 + 55 -229.6141640776 0.511E-03 0.9420867356 0.0182716908 53246.1517 + 56 -229.6141178097 0.504E-03 0.9417695809 0.0182649031 53790.4127 + 57 -229.6141490852 0.496E-03 0.9418998113 0.0182702667 54167.9739 + 58 -229.6140536878 0.483E-03 0.9410330679 0.0182591513 54312.8986 + 59 -229.6140006822 0.477E-03 0.9405837687 0.0182508441 55143.2159 + 61 -229.6139292931 0.481E-03 0.9402271799 0.0182381042 55458.5422 + 62 -229.6138102238 0.488E-03 0.9391619643 0.0182235264 55984.6173 + 63 -229.6137652962 0.482E-03 0.9385222955 0.0182209249 56482.5121 + 64 -229.6138156227 0.477E-03 0.9388451252 0.0182294989 57254.5470 + 67 -229.6139564921 0.472E-03 0.9397107092 0.0182532103 57403.2340 + 68 -229.6140538877 0.475E-03 0.9404237116 0.0182680831 57692.1178 + 69 -229.6139139218 0.489E-03 0.9391226545 0.0182527509 58360.8915 + 70 -229.6138847326 0.483E-03 0.9389364361 0.0182480526 59489.3351 + 72 -229.6138676615 0.478E-03 0.9387924258 0.0182483175 60562.6912 + 74 -229.6140081938 0.485E-03 0.9400517158 0.0182635168 60651.9059 + 76 -229.6139881001 0.473E-03 0.9400911231 0.0182589308 61127.6011 + 77 -229.6139867317 0.467E-03 0.9397904833 0.0182639395 61733.3668 + 78 -229.6140034982 0.461E-03 0.9399943510 0.0182648941 62182.2216 + 79 -229.6140034096 0.455E-03 0.9399551370 0.0182653234 63051.6508 + 81 -229.6138207009 0.465E-03 0.9384492973 0.0182418491 63283.1561 + 82 -229.6137985286 0.453E-03 0.9382146150 0.0182412256 64018.1919 + 83 -229.6138725097 0.454E-03 0.9389443811 0.0182494271 64872.7612 + 85 -229.6139077001 0.448E-03 0.9389912842 0.0182584843 65345.8438 + 86 -229.6139408565 0.444E-03 0.9392521089 0.0182628699 65562.2127 + 87 -229.6140126951 0.445E-03 0.9398395828 0.0182721929 66274.1488 + 88 -229.6139210237 0.449E-03 0.9391610953 0.0182587064 66726.4742 + 89 -229.6138461302 0.450E-03 0.9387236039 0.0182460384 66816.8126 + 90 -229.6138085515 0.447E-03 0.9385325325 0.0182402863 67886.7404 + 91 -229.6137087163 0.440E-03 0.9376974549 0.0182283022 67965.0547 + 92 -229.6137269986 0.436E-03 0.9377729274 0.0182318665 68064.9158 + 93 -229.6137347081 0.431E-03 0.9379240192 0.0182317785 68557.1806 + 94 -229.6137567389 0.427E-03 0.9381437093 0.0182338499 69506.4615 + 97 -229.6137927501 0.419E-03 0.9385992858 0.0182343999 69984.5342 + 98 -229.6137863855 0.415E-03 0.9385785218 0.0182341107 70712.1869 + 100 -229.6138197929 0.410E-03 0.9388730810 0.0182369389 71016.1155 + 102 -229.6137188628 0.408E-03 0.9381214744 0.0182224473 71127.9240 + 103 -229.6136040267 0.406E-03 0.9373028191 0.0182066819 71768.5028 + 104 -229.6136162963 0.402E-03 0.9374523176 0.0182072771 72386.2258 + 105 -229.6135625611 0.402E-03 0.9371096891 0.0181986451 72814.8899 + 106 -229.6135820504 0.399E-03 0.9372676773 0.0182003855 73675.7325 + 110 -229.6136179793 0.391E-03 0.9375643877 0.0182033532 73902.7713 + 111 -229.6136762135 0.392E-03 0.9379781185 0.0182118839 74538.9082 + 112 -229.6137123283 0.390E-03 0.9382419829 0.0182168001 76173.2231 + 115 -229.6137453704 0.373E-03 0.9384835959 0.0182216529 76257.5887 + 118 -229.6137945597 0.367E-03 0.9389466420 0.0182270752 76585.7914 + 119 -229.6137971587 0.364E-03 0.9389825211 0.0182269135 76881.7892 + 120 -229.6138032339 0.361E-03 0.9390871795 0.0182271387 77330.0687 + 121 -229.6137985668 0.358E-03 0.9390794828 0.0182260413 77473.4494 + 122 -229.6137748621 0.356E-03 0.9389943050 0.0182207078 77933.6568 + 123 -229.6137818191 0.353E-03 0.9390995374 0.0182199232 78509.2885 + 124 -229.6138051949 0.351E-03 0.9393240379 0.0182225703 79420.0197 + 125 -229.6138013618 0.345E-03 0.9393779585 0.0182202778 79673.6235 + 126 -229.6138109092 0.343E-03 0.9395407813 0.0182203817 80068.3500 + 127 -229.6137922170 0.340E-03 0.9393385805 0.0182183793 80277.7222 + 128 -229.6138560523 0.344E-03 0.9397764377 0.0182275134 80799.1958 + 129 -229.6138826047 0.342E-03 0.9398748868 0.0182331643 80821.5229 + 131 -229.6138770706 0.337E-03 0.9397627623 0.0182328951 81374.4391 + 132 -229.6138946009 0.335E-03 0.9398215411 0.0182360868 81625.4896 + 133 -229.6138516702 0.335E-03 0.9393592557 0.0182315752 81654.7157 + 134 -229.6138491343 0.333E-03 0.9394203263 0.0182293808 82141.1823 + 135 -229.6138143155 0.332E-03 0.9391473909 0.0182247125 82419.1221 + 136 -229.6138265435 0.325E-03 0.9393903744 0.0182232344 82686.4856 + 137 -229.6137972379 0.324E-03 0.9393098388 0.0182171853 83096.5102 + 138 -229.6137873720 0.322E-03 0.9391746616 0.0182165065 85713.3191 + 146 -229.6137697996 0.307E-03 0.9392618889 0.0182099537 86045.1984 + 147 -229.6137834831 0.306E-03 0.9394759369 0.0182100420 86328.1504 + 148 -229.6138314654 0.309E-03 0.9399390064 0.0182153014 86630.8330 + 149 -229.6138230586 0.307E-03 0.9399050021 0.0182135083 86931.4991 + 150 -229.6138615263 0.307E-03 0.9404455628 0.0182155507 87163.6069 + 151 -229.6138520466 0.305E-03 0.9404200528 0.0182135027 87486.3491 + 152 -229.6138620632 0.303E-03 0.9405202984 0.0182149329 88061.6324 + 153 -229.6138943315 0.303E-03 0.9408142163 0.0182183025 88299.0764 + 154 -229.6138601382 0.303E-03 0.9406087737 0.0182127370 89007.6099 + 155 -229.6138689247 0.301E-03 0.9407862264 0.0182127544 89200.7391 + 156 -229.6138747272 0.299E-03 0.9407650271 0.0182141612 89618.4645 + 157 -229.6138636117 0.298E-03 0.9406763953 0.0182125838 89855.0353 + 158 -229.6138915247 0.297E-03 0.9408826302 0.0182163211 90051.5464 + 159 -229.6139236235 0.297E-03 0.9411147831 0.0182211357 90373.3256 + 160 -229.6139634125 0.298E-03 0.9414100677 0.0182267938 90885.6498 + 161 -229.6139220381 0.291E-03 0.9411289048 0.0182205516 90983.9564 + 162 -229.6139105834 0.290E-03 0.9410098808 0.0182194596 91404.0051 + 163 -229.6139307987 0.289E-03 0.9412059739 0.0182212146 91909.9981 + 165 -229.6139007728 0.286E-03 0.9410574257 0.0182158344 92249.4721 + 167 -229.6138608510 0.284E-03 0.9407334435 0.0182103191 92620.3020 + 168 -229.6138204737 0.285E-03 0.9404508946 0.0182044602 92885.9692 + 169 -229.6138574418 0.286E-03 0.9406747748 0.0182105454 93479.8741 + 170 -229.6138633469 0.284E-03 0.9406677485 0.0182122289 94079.5141 + 171 -229.6139044963 0.286E-03 0.9410077554 0.0182175305 94259.9507 + 172 -229.6139089875 0.284E-03 0.9409702099 0.0182188157 94596.9924 + 173 -229.6138507446 0.281E-03 0.9404789223 0.0182116215 95026.0175 + 174 -229.6138464164 0.279E-03 0.9404871041 0.0182101559 95246.5916 + 175 -229.6138634510 0.278E-03 0.9405920470 0.0182127178 95691.1998 + 176 -229.6138453748 0.277E-03 0.9404430259 0.0182100877 96064.0352 + 177 -229.6138087101 0.278E-03 0.9401445889 0.0182054854 96382.7213 + 180 -229.6138115077 0.274E-03 0.9400885149 0.0182071864 96520.4809 + 181 -229.6138165241 0.273E-03 0.9401301421 0.0182077967 97447.6762 + 182 -229.6137898470 0.272E-03 0.9397988507 0.0182060832 97590.5833 + 184 -229.6137846306 0.270E-03 0.9396420413 0.0182066083 97603.6914 + 185 -229.6138601228 0.266E-03 0.9403821582 0.0182128985 97986.7299 + 186 -229.6138720348 0.265E-03 0.9405023730 0.0182139854 98576.7978 + 188 -229.6138849066 0.262E-03 0.9405227253 0.0182171887 98783.9548 + 189 -229.6138637389 0.262E-03 0.9403543193 0.0182144581 99155.7883 + 190 -229.6138576211 0.261E-03 0.9402791355 0.0182139909 99562.6330 + 191 -229.6138574165 0.259E-03 0.9402528991 0.0182146711 99769.7882 + 192 -229.6138312967 0.259E-03 0.9400500282 0.0182112614 ********** + 193 -229.6138183709 0.258E-03 0.9399983759 0.0182087836 ********** + 194 -229.6138177289 0.257E-03 0.9399813089 0.0182091604 ********** + 195 -229.6138181575 0.256E-03 0.9401045231 0.0182074162 ********** + 197 -229.6138065961 0.254E-03 0.9399744536 0.0182064623 ********** + 198 -229.6137780422 0.250E-03 0.9398082742 0.0182020509 ********** + 201 -229.6137208985 0.249E-03 0.9393280913 0.0181944097 ********** + 202 -229.6137254333 0.247E-03 0.9393773009 0.0181948205 ********** +========== ================= =========== =============== =============== ================= + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 + +.. >>>>> [ RES MEM : 38.885296 GB ] [ VIRT MEM : 42.980614 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 383750.661164 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of generators 20963892 + +.. >>>>> [ RES MEM : 38.885296 GB ] [ VIRT MEM : 42.980614 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 383750.704618 s ] [ CPU TIME: ************** s ] <<<<< .. + +* Number of selectors 20963892 +* Number of comb teeth 100 +* pt2_n_tasks_max 638 + Using pt2-matching weight in selection + # PT2 weight 1.000000 + # Total weight 1.000000 +* Correlation ratio 0.8644076766822755 + +Summary at N_det = 20971520 +----------------------------------- + +# ============ ============================= + State 1 +# ============ ============================= +# E -229.48885656 +# PT2 -0.12486887 0.00024739 +# rPT2 -0.12263751 0.00024297 +# +# E+PT2 -229.61372543 0.00024739 +# E+rPT2 -229.61149407 0.00024297 +# ============ ============================= + + N_det = 20971520 + N_states = 1 + + * State 1 + < S^2 > = 1.071836052757673E-002 + E = -229.488856560819 + Variance = 0.939377300888757 + PT norm = 0.134888177788547 + PT2 = -0.124868872452553 + rPT2 = -0.122637505060536 + E+PT2 = -229.613725433271 +/- 2.473906706299786E-004 + E+rPT2 = -229.611494065879 +/- 2.429698773234429E-004 + + ----- + Energy components + ================= + + State 1 + --------- + + Vnn = 161.108229778789 + Ven = -858.586697188150 + Vee = 238.670832942964 + Vecp = 0.000000000000000E+000 + T = 229.318777905577 + + + +Extrapolated energies +------------------------ + + + State 1 + + =========== =================== + minimum PT2 Extrapolated energy + =========== =================== + -0.1280 -229.62374944 + -0.1331 -229.62731809 + -0.1385 -229.63109295 + -0.1457 -229.63036611 + -0.1563 -229.62921826 + -0.1738 -229.62764366 + -0.2014 -229.62561799 + =========== =================== + +* Number of unique beta determinants 2252423 +* Number of unique alpha determinants 2179859 + +.. >>>>> [ RES MEM : 50.924034 GB ] [ VIRT MEM : 59.591255 GB ] <<<<< .. +.. >>>>> [ WALL TIME: 410390.238657 s ] [ CPU TIME: ************** s ] <<<<< .. + + +Davidson Diagonalization +------------------------ + +* Number of states 1 +* Number of states in diagonalization 4 +* Number of determinants 41943040 +* Number of threads for diagonalization 72 +* Memory(Gb) 64.69572049379349 + +===== ================ =========== =========== +Iter Energy S^2 Residual +===== ================ =========== =========== + 1 -229.4888565610 0.010718 0.157E-02 + 2 -229.4975778320 0.012004 0.200E-03 + 3 -229.4979009221 0.012135 0.295E-04 + 4 -229.4979574323 0.012242 0.247E-05 + 5 -229.4979662427 0.012266 0.464E-06 + 6 -229.4979678977 0.012259 0.863E-07 diff --git a/furan/cc-pvtz/slurm-485509.out b/furan/cc-pvtz/slurm-485509.out index 5cbf057..fb94bb5 100644 --- a/furan/cc-pvtz/slurm-485509.out +++ b/furan/cc-pvtz/slurm-485509.out @@ -21374,3 +21374,35610 @@ 6.74 % in 60294 seconds 6.74 % in 60306 seconds 6.74 % in 60320 seconds + 6.74 % in 60339 seconds + 6.74 % in 60352 seconds + 6.74 % in 60364 seconds + 6.74 % in 60375 seconds + 6.74 % in 60389 seconds + 6.74 % in 60402 seconds + 6.74 % in 60413 seconds + 6.74 % in 60423 seconds + 6.75 % in 60433 seconds + 6.75 % in 60443 seconds + 6.75 % in 60454 seconds + 6.75 % in 60465 seconds + 6.75 % in 60475 seconds + 6.75 % in 60485 seconds + 6.75 % in 60495 seconds + 6.75 % in 60505 seconds + 6.75 % in 60515 seconds + 6.75 % in 60525 seconds + 6.76 % in 60536 seconds + 6.76 % in 60546 seconds + 6.76 % in 60558 seconds + 6.76 % in 60568 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9.19 % in 83726 seconds + 9.19 % in 83736 seconds + 9.19 % in 83747 seconds + 9.19 % in 83757 seconds + 9.19 % in 83767 seconds + 9.19 % in 83777 seconds + 9.19 % in 83787 seconds + 9.19 % in 83797 seconds + 9.19 % in 83809 seconds + 9.19 % in 83819 seconds + 9.19 % in 83833 seconds + 9.19 % in 83843 seconds + 9.19 % in 83856 seconds + 9.20 % in 83867 seconds + 9.20 % in 83879 seconds + 9.20 % in 83889 seconds + 9.20 % in 83900 seconds + 9.20 % in 83910 seconds + 9.20 % in 83921 seconds + 9.20 % in 83931 seconds + 9.20 % in 83942 seconds + 9.20 % in 83952 seconds + 9.20 % in 83963 seconds + 9.20 % in 83973 seconds + 9.20 % in 83985 seconds + 9.20 % in 83999 seconds + 9.21 % in 84009 seconds + 9.21 % in 84019 seconds + 9.21 % in 84029 seconds + 9.21 % in 84040 seconds + 9.21 % in 84050 seconds + 9.21 % in 84060 seconds + 9.21 % in 84070 seconds + 9.21 % in 84080 seconds + 9.21 % in 84090 seconds + 9.22 % in 84100 seconds + 9.22 % in 84110 seconds + 9.22 % in 84120 seconds + 9.22 % in 84131 seconds + 9.22 % in 84142 seconds + 9.23 % in 84152 seconds + 9.23 % in 84162 seconds + 9.23 % in 84172 seconds + 9.23 % in 84183 seconds + 9.23 % in 84193 seconds + 9.24 % in 84203 seconds + 9.24 % in 84213 seconds + 9.24 % in 84225 seconds + 9.24 % in 84237 seconds + 9.24 % in 84249 seconds + 9.24 % in 84261 seconds + 9.24 % in 84271 seconds + 9.24 % in 84282 seconds + 9.24 % in 84293 seconds + 9.24 % in 84308 seconds + 9.24 % in 84320 seconds + 9.24 % in 84335 seconds + 9.24 % in 84346 seconds + 9.24 % in 84356 seconds + 9.24 % in 84366 seconds + 9.24 % in 84376 seconds + 9.25 % in 84388 seconds + 9.25 % in 84430 seconds + 9.25 % in 84447 seconds + 9.25 % in 84459 seconds + 9.25 % in 84478 seconds + 9.25 % in 84490 seconds + 9.25 % in 84508 seconds + 9.25 % in 84520 seconds + 9.25 % in 84533 seconds + 9.25 % in 84543 seconds + 9.25 % in 84570 seconds + 9.25 % in 84687 seconds + 9.25 % in 84699 seconds + + unset COMMAND ++ qp run save_natorb ++ case $1 in ++ which qp_run ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' furan +++ qp_run save_natorb furan ++ unset COMMAND ++ qp set determinants n_det_max 1e8 ++ case $1 in ++ ezfio set determinants n_det_max 1e8 ++ case $1 in ++ shift ++ _ezfio_set determinants n_det_max 1e8 ++ _require_ezfio_file ++ [[ -z furan ]] ++ [[ ! -d furan ]] ++ _require_first_argument determinants n_det_max 1e8 ++ [[ -z determinants ]] ++ return 0 ++ _require_second_argument determinants n_det_max 1e8 ++ [[ -z n_det_max ]] ++ [[ -z 1e8 ]] ++ echo 1e8 ++ _ezfio_py set determinants n_det_max ++ python2 /tmpdir/loos/qp2/external/ezfio/Python/ezfio.py set determinants n_det_max ++ return 0 ++ qp run fci ++ case $1 in ++ which qp_run ++ [[ 0 -eq 0 ]] ++ COMMAND='qp_$@' ++ eval 'qp_$@' furan +++ qp_run fci furan + 0.00 % in 1 seconds +40.86 % in 11 seconds +65.59 % in 21 seconds +87.43 % in 31 seconds + 50.00 % in 7 seconds + 16.67 % in 3 seconds + 9.09 % in 4 seconds + 4.76 % in 4 seconds + 2.44 % in 4 seconds + 1.23 % in 5 seconds + 0.62 % in 5 seconds +91.30 % in 15 seconds + 0.31 % in 6 seconds +43.61 % in 16 seconds +82.55 % in 26 seconds + 0.16 % in 4 seconds +16.07 % in 14 seconds +33.70 % in 24 seconds +53.35 % in 34 seconds +73.17 % in 44 seconds +93.92 % in 54 seconds + 0.08 % in 6 seconds +10.07 % in 16 seconds +17.02 % in 26 seconds +26.78 % in 36 seconds + 0.04 % in 5 seconds + 3.01 % in 15 seconds + 7.85 % in 25 seconds +11.44 % in 35 seconds +15.03 % in 45 seconds +20.19 % in 55 seconds +23.70 % in 65 seconds + 0.02 % in 6 seconds + 1.27 % in 16 seconds + 2.89 % in 26 seconds + 4.76 % in 36 seconds + 6.56 % in 46 seconds + 8.38 % in 56 seconds +10.23 % in 66 seconds +12.24 % in 76 seconds +14.53 % in 86 seconds +16.44 % in 96 seconds +18.75 % in 106 seconds +20.87 % in 116 seconds +22.28 % in 126 seconds + 0.01 % in 7 seconds + 0.70 % in 17 seconds + 1.68 % in 27 seconds + 2.44 % in 37 seconds + 3.51 % in 47 seconds + 4.38 % in 57 seconds + 5.33 % in 67 seconds + 6.18 % in 77 seconds + 7.20 % in 87 seconds + 8.10 % in 97 seconds + 9.18 % in 107 seconds +10.13 % in 117 seconds +10.99 % in 127 seconds +11.28 % in 137 seconds + 0.00 % in 6 seconds + 0.33 % in 16 seconds + 0.80 % in 26 seconds + 1.05 % in 36 seconds + 1.56 % in 46 seconds + 2.01 % in 56 seconds + 2.41 % in 66 seconds + 2.79 % in 76 seconds + 3.35 % in 86 seconds + 3.74 % in 96 seconds + 4.13 % in 106 seconds + 4.59 % in 116 seconds + 5.07 % in 126 seconds + 5.48 % in 136 seconds + 5.92 % in 146 seconds + 6.43 % in 156 seconds + 6.86 % in 167 seconds + 7.32 % in 177 seconds + 7.70 % in 187 seconds + 8.06 % in 197 seconds + 8.59 % in 207 seconds + 9.03 % in 217 seconds + 9.29 % in 227 seconds + 9.37 % in 240 seconds + 9.40 % in 250 seconds + 0.00 % in 3 seconds + 0.12 % in 13 seconds + 0.36 % in 23 seconds + 0.45 % in 33 seconds + 0.66 % in 43 seconds + 0.89 % in 54 seconds + 1.00 % in 64 seconds + 1.36 % in 74 seconds + 1.53 % in 84 seconds + 1.74 % in 94 seconds + 2.02 % in 104 seconds + 2.18 % in 114 seconds + 2.43 % in 124 seconds + 2.71 % in 134 seconds + 2.89 % in 144 seconds + 3.08 % in 154 seconds + 3.36 % in 164 seconds + 3.58 % in 174 seconds + 3.82 % in 184 seconds + 4.07 % in 194 seconds + 4.28 % in 205 seconds + 4.57 % in 215 seconds + 4.84 % in 227 seconds + 5.04 % in 237 seconds + 5.29 % in 247 seconds + 5.54 % in 258 seconds + 5.73 % in 268 seconds + 0.00 % in 4 seconds + 0.06 % in 15 seconds + 0.17 % in 25 seconds + 0.29 % in 35 seconds + 0.35 % in 45 seconds + 0.40 % in 55 seconds + 0.54 % in 66 seconds + 0.67 % in 76 seconds + 0.76 % in 87 seconds + 0.89 % in 97 seconds + 1.04 % in 107 seconds + 1.14 % in 117 seconds + 1.24 % in 127 seconds + 1.37 % in 137 seconds + 1.49 % in 147 seconds + 1.56 % in 157 seconds + 1.71 % in 167 seconds + 1.87 % in 178 seconds + 1.96 % in 188 seconds + 2.08 % in 198 seconds + 2.24 % in 208 seconds + 2.33 % in 218 seconds + 2.46 % in 228 seconds + 2.60 % in 238 seconds + 2.72 % in 249 seconds + 2.89 % in 259 seconds + 3.03 % in 269 seconds + 3.13 % in 279 seconds + 3.23 % in 289 seconds + 3.43 % in 299 seconds + 3.53 % in 309 seconds + 3.59 % in 319 seconds + 3.76 % in 329 seconds + 3.89 % in 339 seconds + 3.99 % in 349 seconds + 4.14 % in 359 seconds + 4.24 % in 369 seconds + 4.41 % in 379 seconds + 4.54 % in 389 seconds + 4.65 % in 400 seconds + 4.78 % in 410 seconds + 4.92 % in 420 seconds + 5.06 % in 430 seconds + 5.19 % in 440 seconds + 5.30 % in 450 seconds + 5.40 % in 460 seconds + 5.50 % in 470 seconds + 5.66 % in 480 seconds + 5.75 % in 490 seconds + 5.91 % in 500 seconds + 6.03 % in 510 seconds + 6.15 % in 521 seconds + 6.32 % in 531 seconds + 6.43 % in 541 seconds + 6.58 % in 551 seconds + 6.66 % in 562 seconds + 6.80 % in 573 seconds + 6.97 % in 584 seconds + 7.09 % in 595 seconds + 7.13 % in 606 seconds + 7.17 % in 619 seconds + 7.19 % in 648 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 16.67 % in 1 seconds + 16.67 % in 0 seconds + 16.67 % in 1 seconds + 16.67 % in 0 seconds + 16.67 % in 1 seconds + 16.67 % in 0 seconds + 16.67 % in 1 seconds + 0.00 % in 5 seconds + 0.03 % in 15 seconds + 0.07 % in 25 seconds + 0.09 % in 35 seconds + 0.16 % in 45 seconds + 0.21 % in 55 seconds + 0.27 % in 65 seconds + 0.32 % in 75 seconds + 0.33 % in 85 seconds + 0.40 % in 95 seconds + 0.45 % in 105 seconds + 0.51 % in 116 seconds + 0.56 % in 126 seconds + 0.64 % in 137 seconds + 0.68 % in 147 seconds + 0.75 % in 158 seconds + 0.85 % in 168 seconds + 0.88 % in 178 seconds + 0.94 % in 189 seconds + 0.98 % in 199 seconds + 1.05 % in 209 seconds + 1.11 % in 219 seconds + 1.17 % in 229 seconds + 1.25 % in 239 seconds + 1.32 % in 249 seconds + 1.38 % in 259 seconds + 1.46 % in 269 seconds + 1.52 % in 279 seconds + 1.58 % in 289 seconds + 1.66 % in 299 seconds + 1.71 % in 310 seconds + 1.80 % in 320 seconds + 1.87 % in 330 seconds + 1.93 % in 340 seconds + 2.01 % in 351 seconds + 2.10 % in 361 seconds + 2.14 % in 371 seconds + 2.21 % in 381 seconds + 2.32 % in 391 seconds + 2.39 % in 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