diff --git a/data_AS/benzene_no.dat b/data_AS/benzene_no.dat
index 73cbb7a..74a3b8a 100644
--- a/data_AS/benzene_no.dat
+++ b/data_AS/benzene_no.dat
@@ -23,3 +23,4 @@
   10485760   -231.4529267946  -0.1034069718   0.0002056718  -0.1015824747   0.0002020429
   20971520   -231.4645290852  -0.0942474663   0.0001880281  -0.0927652325   0.0001850710
   41943040   -231.4768202820  -0.0842614465   0.0001668731  -0.0831039064   0.0001645807
+  83886080   -231.4895438170  -0.0746164115   0.0003622034  -0.0737313072   0.0035790692
diff --git a/data_AS/pyridine_no.dat b/data_AS/pyridine_no.dat
index a10834e..5eb8eb8 100644
--- a/data_AS/pyridine_no.dat
+++ b/data_AS/pyridine_no.dat
@@ -23,3 +23,4 @@
   10485760   -247.4637428655  -0.1057773192   0.0002104625  -0.1039205954   0.0002067683
   20971520   -247.4753699775  -0.0967407932   0.0001933432  -0.0952218594   0.0001903075
   41943040   -247.4876731985  -0.0865878863   0.0001719015  -0.0853982537   0.0001695398
+  83886080   -247.5004308830  -0.0770957245   0.0003815831  -0.0761773500   0.0003770376