CBD/CBD_CIPSI/autoisomerization/D2h/AVTZ/CBD_D2h_CASPT2.natorb.out
2021-04-14 11:41:05 +02:00

463 lines
22 KiB
Plaintext

Date: 10/03/2021 00:53:28
===============
Quantum Package
===============
Git Commit: Fix space in size for EZFIO.cfg
Git Date : Fri Oct 16 14:24:01 2020 +0200
Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b
EZFIO Dir : CBD_D2h_CASPT2
Task server running : tcp://172.28.0.48:41279
.. >>>>> [ IO READ: n_states ] <<<<< ..
.. >>>>> [ RES MEM : 0.017437 GB ] [ VIRT MEM : 0.201981 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.016310 s ] [ CPU TIME: 0.030806 s ] <<<<< ..
.. >>>>> [ IO READ: read_wf ] <<<<< ..
.. >>>>> [ RES MEM : 0.017437 GB ] [ VIRT MEM : 0.201981 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.023607 s ] [ CPU TIME: 0.031233 s ] <<<<< ..
.. >>>>> [ IO READ: elec_beta_num ] <<<<< ..
.. >>>>> [ RES MEM : 0.017437 GB ] [ VIRT MEM : 0.201981 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.034510 s ] [ CPU TIME: 0.032119 s ] <<<<< ..
* mo_num 276
.. >>>>> [ IO READ: elec_alpha_num ] <<<<< ..
.. >>>>> [ RES MEM : 0.017639 GB ] [ VIRT MEM : 0.201981 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.046551 s ] [ CPU TIME: 0.033175 s ] <<<<< ..
Read mo_occ
.. >>>>> [ IO READ: mo_class ] <<<<< ..
.. >>>>> [ RES MEM : 0.019478 GB ] [ VIRT MEM : 4.925480 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.160020 s ] [ CPU TIME: 5.918013 s ] <<<<< ..
* Number of virtual MOs 0
Virtual MOs:
.. >>>>> [ IO READ: ao_num ] <<<<< ..
.. >>>>> [ RES MEM : 0.019478 GB ] [ VIRT MEM : 4.925480 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.196291 s ] [ CPU TIME: 8.258749 s ] <<<<< ..
Read mo_coef
* mo_label Canonical
* Number of determinants 11483185
* Dimension of the psi arrays 11483185
* N_int 5
Read psi_det
* Number of unique beta determinants 1185954
* Number of unique alpha determinants 1185954
Read psi_coef 11483185 1
.. >>>>> [ IO READ: weight_one_e_dm ] <<<<< ..
.. >>>>> [ RES MEM : 5.073685 GB ] [ VIRT MEM : 10.079739 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 337.614371 s ] [ CPU TIME: 10419.164575 s ] <<<<< ..
* Number of active MOs 272
* Number of core MOs 4
* Number of inactive MOs 0
Core MOs:
1 2 3 4
Active MOs:
5 6 7 8 9 10
11 12 13 14 15 16
17 18 19 20 21 22
23 24 25 26 27 28
29 30 31 32 33 34
35 36 37 38 39 40
41 42 43 44 45 46
47 48 49 50 51 52
53 54 55 56 57 58
59 60 61 62 63 64
65 66 67 68 69 70
71 72 73 74 75 76
77 78 79 80 81 82
83 84 85 86 87 88
89 90 91 92 93 94
95 96 97 98 99 100
101 102 103 104 105 106
107 108 109 110 111 112
113 114 115 116 117 118
119 120 121 122 123 124
125 126 127 128 129 130
131 132 133 134 135 136
137 138 139 140 141 142
143 144 145 146 147 148
149 150 151 152 153 154
155 156 157 158 159 160
161 162 163 164 165 166
167 168 169 170 171 172
173 174 175 176 177 178
179 180 181 182 183 184
185 186 187 188 189 190
191 192 193 194 195 196
197 198 199 200 201 202
203 204 205 206 207 208
209 210 211 212 213 214
215 216 217 218 219 220
221 222 223 224 225 226
227 228 229 230 231 232
233 234 235 236 237 238
239 240 241 242 243 244
245 246 247 248 249 250
251 252 253 254 255 256
257 258 259 260 261 262
263 264 265 266 267 268
269 270 271 272 273 274
275 276
Core, Inactive and Active MOs:
1 2 3 4 5 6
7 8 9 10 11 12
13 14 15 16 17 18
19 20 21 22 23 24
25 26 27 28 29 30
31 32 33 34 35 36
37 38 39 40 41 42
43 44 45 46 47 48
49 50 51 52 53 54
55 56 57 58 59 60
61 62 63 64 65 66
67 68 69 70 71 72
73 74 75 76 77 78
79 80 81 82 83 84
85 86 87 88 89 90
91 92 93 94 95 96
97 98 99 100 101 102
103 104 105 106 107 108
109 110 111 112 113 114
115 116 117 118 119 120
121 122 123 124 125 126
127 128 129 130 131 132
133 134 135 136 137 138
139 140 141 142 143 144
145 146 147 148 149 150
151 152 153 154 155 156
157 158 159 160 161 162
163 164 165 166 167 168
169 170 171 172 173 174
175 176 177 178 179 180
181 182 183 184 185 186
187 188 189 190 191 192
193 194 195 196 197 198
199 200 201 202 203 204
205 206 207 208 209 210
211 212 213 214 215 216
217 218 219 220 221 222
223 224 225 226 227 228
229 230 231 232 233 234
235 236 237 238 239 240
241 242 243 244 245 246
247 248 249 250 251 252
253 254 255 256 257 258
259 260 261 262 263 264
265 266 267 268 269 270
271 272 273 274 275 276
.. >>>>> [ RES MEM : 5.074223 GB ] [ VIRT MEM : 10.079739 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 337.630808 s ] [ CPU TIME: 10420.330550 s ] <<<<< ..
MOs are now **Natural**
Eigenvalues
-----------
======== ================ ================
MO Eigenvalue Cumulative
======== ================ ================
1 2.0000000000 2.0000000000
2 2.0000000000 4.0000000000
3 2.0000000000 6.0000000000
4 2.0000000000 8.0000000000
5 1.9837367709 9.9837367709
6 1.9805108914 11.9642476623
7 1.9783634591 13.9426111214
8 1.9762092535 15.9188203749
9 1.9744717880 17.8932921629
10 1.9701492889 19.8634414519
11 1.9644538108 21.8278952627
12 1.9638866427 23.7917819054
13 1.9435162289 25.7352981343
14 1.9171121426 27.6524102769
15 0.0646816548 27.7170919318
16 0.0430653597 27.7601572915
17 0.0222552403 27.7824125318
18 0.0175815584 27.7999940902
19 0.0163055988 27.8162996890
20 0.0144917820 27.8307914710
21 0.0141262837 27.8449177547
22 0.0120340995 27.8569518543
23 0.0114916430 27.8684434973
24 0.0087336317 27.8771771290
25 0.0075185472 27.8846956762
26 0.0074091295 27.8921048057
27 0.0069414454 27.8990462511
28 0.0069079743 27.9059542254
29 0.0065403635 27.9124945890
30 0.0064028864 27.9188974754
31 0.0058501493 27.9247476247
32 0.0043642431 27.9291118678
33 0.0042127844 27.9333246522
34 0.0037601443 27.9370847965
35 0.0034202264 27.9405050230
36 0.0032871818 27.9437922048
37 0.0029714657 27.9467636705
38 0.0027310950 27.9494947655
39 0.0026640918 27.9521588573
40 0.0025384187 27.9546972760
41 0.0025190077 27.9572162837
42 0.0021563940 27.9593726777
43 0.0019952282 27.9613679059
44 0.0019554085 27.9633233145
45 0.0019236568 27.9652469712
46 0.0016599942 27.9669069654
47 0.0014767410 27.9683837064
48 0.0013705365 27.9697542429
49 0.0012799791 27.9710342220
50 0.0012070682 27.9722412902
51 0.0011168937 27.9733581839
52 0.0010958363 27.9744540202
53 0.0010761072 27.9755301274
54 0.0009853682 27.9765154956
55 0.0009571867 27.9774726823
56 0.0009182607 27.9783909430
57 0.0008332843 27.9792242273
58 0.0007997769 27.9800240042
59 0.0007417340 27.9807657382
60 0.0006413069 27.9814070451
61 0.0006378323 27.9820448774
62 0.0005760817 27.9826209590
63 0.0005716144 27.9831925734
64 0.0005655450 27.9837581184
65 0.0005401926 27.9842983110
66 0.0005395524 27.9848378634
67 0.0005145053 27.9853523687
68 0.0004488684 27.9858012370
69 0.0004434233 27.9862446603
70 0.0004394581 27.9866841184
71 0.0003980357 27.9870821542
72 0.0003740941 27.9874562482
73 0.0003706612 27.9878269095
74 0.0003662506 27.9881931601
75 0.0003521164 27.9885452766
76 0.0003449131 27.9888901897
77 0.0003434556 27.9892336453
78 0.0003340218 27.9895676671
79 0.0003055051 27.9898731721
80 0.0002984952 27.9901716673
81 0.0002918777 27.9904635450
82 0.0002832942 27.9907468393
83 0.0002546827 27.9910015220
84 0.0002404775 27.9912419995
85 0.0002392019 27.9914812014
86 0.0002311001 27.9917123015
87 0.0002291802 27.9919414816
88 0.0002285034 27.9921699850
89 0.0002247445 27.9923947295
90 0.0002199243 27.9926146538
91 0.0002144965 27.9928291503
92 0.0002130396 27.9930421899
93 0.0002065349 27.9932487249
94 0.0002062833 27.9934550081
95 0.0001887538 27.9936437620
96 0.0001852915 27.9938290535
97 0.0001757767 27.9940048302
98 0.0001742579 27.9941790881
99 0.0001720336 27.9943511217
100 0.0001528927 27.9945040143
101 0.0001335543 27.9946375686
102 0.0001331856 27.9947707542
103 0.0001330034 27.9949037577
104 0.0001265800 27.9950303376
105 0.0001242647 27.9951546023
106 0.0001167840 27.9952713863
107 0.0001126323 27.9953840186
108 0.0001073677 27.9954913863
109 0.0001039275 27.9955953138
110 0.0000976253 27.9956929391
111 0.0000964582 27.9957893973
112 0.0000944588 27.9958838561
113 0.0000893213 27.9959731774
114 0.0000880794 27.9960612568
115 0.0000852807 27.9961465376
116 0.0000807211 27.9962272586
117 0.0000804611 27.9963077197
118 0.0000765270 27.9963842467
119 0.0000762551 27.9964605018
120 0.0000757165 27.9965362184
121 0.0000739369 27.9966101553
122 0.0000726447 27.9966828000
123 0.0000726361 27.9967554361
124 0.0000682957 27.9968237319
125 0.0000681377 27.9968918696
126 0.0000652178 27.9969570873
127 0.0000622385 27.9970193258
128 0.0000583877 27.9970777135
129 0.0000581307 27.9971358442
130 0.0000580415 27.9971938857
131 0.0000558763 27.9972497620
132 0.0000553733 27.9973051353
133 0.0000553293 27.9973604646
134 0.0000552049 27.9974156695
135 0.0000544327 27.9974701022
136 0.0000540983 27.9975242005
137 0.0000505652 27.9975747658
138 0.0000504018 27.9976251675
139 0.0000493175 27.9976744850
140 0.0000482936 27.9977227787
141 0.0000480449 27.9977708235
142 0.0000457586 27.9978165821
143 0.0000446573 27.9978612394
144 0.0000437082 27.9979049476
145 0.0000435431 27.9979484907
146 0.0000425991 27.9979910898
147 0.0000401033 27.9980311931
148 0.0000400781 27.9980712713
149 0.0000394555 27.9981107268
150 0.0000394164 27.9981501432
151 0.0000389886 27.9981891318
152 0.0000389743 27.9982281061
153 0.0000385473 27.9982666534
154 0.0000377078 27.9983043612
155 0.0000365803 27.9983409414
156 0.0000364741 27.9983774155
157 0.0000363134 27.9984137289
158 0.0000343721 27.9984481010
159 0.0000341834 27.9984822844
160 0.0000338682 27.9985161525
161 0.0000332943 27.9985494468
162 0.0000315351 27.9985809819
163 0.0000314129 27.9986123948
164 0.0000302344 27.9986426292
165 0.0000283974 27.9986710266
166 0.0000283314 27.9986993580
167 0.0000283221 27.9987276802
168 0.0000269693 27.9987546495
169 0.0000265204 27.9987811698
170 0.0000264564 27.9988076263
171 0.0000261487 27.9988337750
172 0.0000254946 27.9988592696
173 0.0000250599 27.9988843295
174 0.0000247195 27.9989090490
175 0.0000237342 27.9989327832
176 0.0000235812 27.9989563644
177 0.0000230497 27.9989794142
178 0.0000230090 27.9990024231
179 0.0000228945 27.9990253176
180 0.0000226458 27.9990479634
181 0.0000226232 27.9990705867
182 0.0000223440 27.9990929306
183 0.0000212926 27.9991142233
184 0.0000207604 27.9991349837
185 0.0000196082 27.9991545918
186 0.0000190869 27.9991736787
187 0.0000188972 27.9991925759
188 0.0000186604 27.9992112363
189 0.0000186081 27.9992298444
190 0.0000178804 27.9992477248
191 0.0000176813 27.9992654061
192 0.0000170608 27.9992824669
193 0.0000169689 27.9992994358
194 0.0000165529 27.9993159886
195 0.0000164249 27.9993324135
196 0.0000160616 27.9993484751
197 0.0000158226 27.9993642977
198 0.0000154040 27.9993797016
199 0.0000150787 27.9993947803
200 0.0000147517 27.9994095320
201 0.0000137833 27.9994233153
202 0.0000137454 27.9994370607
203 0.0000136832 27.9994507439
204 0.0000133924 27.9994641363
205 0.0000130924 27.9994772286
206 0.0000129340 27.9994901626
207 0.0000128428 27.9995030054
208 0.0000126622 27.9995156677
209 0.0000125901 27.9995282578
210 0.0000125035 27.9995407613
211 0.0000119499 27.9995527112
212 0.0000114747 27.9995641858
213 0.0000114448 27.9995756306
214 0.0000113840 27.9995870146
215 0.0000113520 27.9995983667
216 0.0000112897 27.9996096563
217 0.0000112049 27.9996208612
218 0.0000107879 27.9996316491
219 0.0000107826 27.9996424317
220 0.0000105932 27.9996530249
221 0.0000104745 27.9996634994
222 0.0000104734 27.9996739728
223 0.0000101213 27.9996840941
224 0.0000099503 27.9996940444
225 0.0000099380 27.9997039824
226 0.0000098383 27.9997138207
227 0.0000097868 27.9997236075
228 0.0000095319 27.9997331394
229 0.0000094839 27.9997426232
230 0.0000092039 27.9997518271
231 0.0000091312 27.9997609584
232 0.0000090801 27.9997700385
233 0.0000088982 27.9997789367
234 0.0000088930 27.9997878297
235 0.0000086090 27.9997964387
236 0.0000084998 27.9998049385
237 0.0000083824 27.9998133209
238 0.0000080534 27.9998213743
239 0.0000080158 27.9998293900
240 0.0000077906 27.9998371806
241 0.0000074744 27.9998446551
242 0.0000074604 27.9998521154
243 0.0000072046 27.9998593201
244 0.0000070803 27.9998664003
245 0.0000069607 27.9998733611
246 0.0000068958 27.9998802569
247 0.0000068662 27.9998871231
248 0.0000067491 27.9998938721
249 0.0000064530 27.9999003252
250 0.0000064107 27.9999067359
251 0.0000060119 27.9999127477
252 0.0000055809 27.9999183287
253 0.0000055300 27.9999238587
254 0.0000053510 27.9999292097
255 0.0000050523 27.9999342620
256 0.0000050318 27.9999392938
257 0.0000049886 27.9999442824
258 0.0000048740 27.9999491564
259 0.0000047391 27.9999538955
260 0.0000043245 27.9999582200
261 0.0000038581 27.9999620781
262 0.0000037512 27.9999658293
263 0.0000037424 27.9999695717
264 0.0000035014 27.9999730731
265 0.0000032966 27.9999763697
266 0.0000028503 27.9999792200
267 0.0000027301 27.9999819501
268 0.0000027182 27.9999846683
269 0.0000025742 27.9999872425
270 0.0000023919 27.9999896344
271 0.0000020307 27.9999916652
272 0.0000018990 27.9999935642
273 0.0000017405 27.9999953046
274 0.0000016672 27.9999969718
275 0.0000016234 27.9999985952
276 0.0000014048 28.0000000000
======== ================ ================
.. >>>>> [ RES MEM : 5.088566 GB ] [ VIRT MEM : 10.193748 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 337.673534 s ] [ CPU TIME: 10423.368554 s ] <<<<< ..
.. >>>>> [ IO READ: ao_md5 ] <<<<< ..
.. >>>>> [ RES MEM : 5.088566 GB ] [ VIRT MEM : 10.193748 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 337.674415 s ] [ CPU TIME: 10423.431915 s ] <<<<< ..
* Saved determinants 1
Wall time: 0:05:44