CBD/CBD_CIPSI/autoisomerization/D4h/AVTZ/CBD_D4h_CASPT2.natorb.out
2021-04-14 11:41:05 +02:00

463 lines
22 KiB
Plaintext

Date: 12/03/2021 18:54:25
===============
Quantum Package
===============
Git Commit: Fix space in size for EZFIO.cfg
Git Date : Fri Oct 16 14:24:01 2020 +0200
Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b
EZFIO Dir : CBD_D4h_CASPT2
Task server running : tcp://172.28.1.62:41279
.. >>>>> [ IO READ: n_states ] <<<<< ..
.. >>>>> [ RES MEM : 0.017441 GB ] [ VIRT MEM : 0.201981 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.017745 s ] [ CPU TIME: 0.031808 s ] <<<<< ..
.. >>>>> [ IO READ: read_wf ] <<<<< ..
.. >>>>> [ RES MEM : 0.017441 GB ] [ VIRT MEM : 0.201981 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.032121 s ] [ CPU TIME: 0.032378 s ] <<<<< ..
.. >>>>> [ IO READ: elec_beta_num ] <<<<< ..
.. >>>>> [ RES MEM : 0.017441 GB ] [ VIRT MEM : 0.201981 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.042347 s ] [ CPU TIME: 0.033408 s ] <<<<< ..
* mo_num 276
.. >>>>> [ IO READ: elec_alpha_num ] <<<<< ..
.. >>>>> [ RES MEM : 0.017643 GB ] [ VIRT MEM : 0.201981 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.051783 s ] [ CPU TIME: 0.034433 s ] <<<<< ..
Read mo_occ
.. >>>>> [ IO READ: mo_class ] <<<<< ..
.. >>>>> [ RES MEM : 0.019493 GB ] [ VIRT MEM : 4.925480 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.170273 s ] [ CPU TIME: 2.912326 s ] <<<<< ..
* Number of virtual MOs 0
Virtual MOs:
.. >>>>> [ IO READ: ao_num ] <<<<< ..
.. >>>>> [ RES MEM : 0.019493 GB ] [ VIRT MEM : 4.925480 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.199988 s ] [ CPU TIME: 4.677467 s ] <<<<< ..
Read mo_coef
* mo_label Canonical
* Number of determinants 16701832
* Dimension of the psi arrays 16701832
* N_int 5
Read psi_det
* Number of unique beta determinants 1629263
* Number of unique alpha determinants 1629263
Read psi_coef 16701832 1
.. >>>>> [ IO READ: weight_one_e_dm ] <<<<< ..
.. >>>>> [ RES MEM : 7.343430 GB ] [ VIRT MEM : 12.333160 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 561.532499 s ] [ CPU TIME: 18051.459439 s ] <<<<< ..
* Number of active MOs 272
* Number of core MOs 4
* Number of inactive MOs 0
Core MOs:
1 2 3 4
Active MOs:
5 6 7 8 9 10
11 12 13 14 15 16
17 18 19 20 21 22
23 24 25 26 27 28
29 30 31 32 33 34
35 36 37 38 39 40
41 42 43 44 45 46
47 48 49 50 51 52
53 54 55 56 57 58
59 60 61 62 63 64
65 66 67 68 69 70
71 72 73 74 75 76
77 78 79 80 81 82
83 84 85 86 87 88
89 90 91 92 93 94
95 96 97 98 99 100
101 102 103 104 105 106
107 108 109 110 111 112
113 114 115 116 117 118
119 120 121 122 123 124
125 126 127 128 129 130
131 132 133 134 135 136
137 138 139 140 141 142
143 144 145 146 147 148
149 150 151 152 153 154
155 156 157 158 159 160
161 162 163 164 165 166
167 168 169 170 171 172
173 174 175 176 177 178
179 180 181 182 183 184
185 186 187 188 189 190
191 192 193 194 195 196
197 198 199 200 201 202
203 204 205 206 207 208
209 210 211 212 213 214
215 216 217 218 219 220
221 222 223 224 225 226
227 228 229 230 231 232
233 234 235 236 237 238
239 240 241 242 243 244
245 246 247 248 249 250
251 252 253 254 255 256
257 258 259 260 261 262
263 264 265 266 267 268
269 270 271 272 273 274
275 276
Core, Inactive and Active MOs:
1 2 3 4 5 6
7 8 9 10 11 12
13 14 15 16 17 18
19 20 21 22 23 24
25 26 27 28 29 30
31 32 33 34 35 36
37 38 39 40 41 42
43 44 45 46 47 48
49 50 51 52 53 54
55 56 57 58 59 60
61 62 63 64 65 66
67 68 69 70 71 72
73 74 75 76 77 78
79 80 81 82 83 84
85 86 87 88 89 90
91 92 93 94 95 96
97 98 99 100 101 102
103 104 105 106 107 108
109 110 111 112 113 114
115 116 117 118 119 120
121 122 123 124 125 126
127 128 129 130 131 132
133 134 135 136 137 138
139 140 141 142 143 144
145 146 147 148 149 150
151 152 153 154 155 156
157 158 159 160 161 162
163 164 165 166 167 168
169 170 171 172 173 174
175 176 177 178 179 180
181 182 183 184 185 186
187 188 189 190 191 192
193 194 195 196 197 198
199 200 201 202 203 204
205 206 207 208 209 210
211 212 213 214 215 216
217 218 219 220 221 222
223 224 225 226 227 228
229 230 231 232 233 234
235 236 237 238 239 240
241 242 243 244 245 246
247 248 249 250 251 252
253 254 255 256 257 258
259 260 261 262 263 264
265 266 267 268 269 270
271 272 273 274 275 276
.. >>>>> [ RES MEM : 7.344055 GB ] [ VIRT MEM : 12.333160 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 561.551843 s ] [ CPU TIME: 18052.831349 s ] <<<<< ..
MOs are now **Natural**
Eigenvalues
-----------
======== ================ ================
MO Eigenvalue Cumulative
======== ================ ================
1 2.0000000000 2.0000000000
2 2.0000000000 4.0000000000
3 2.0000000000 6.0000000000
4 2.0000000000 8.0000000000
5 1.9835751062 9.9835751062
6 1.9795933745 11.9631684807
7 1.9778166890 13.9409851698
8 1.9754212611 15.9164064309
9 1.9735338939 17.8899403248
10 1.9667326970 19.8566730219
11 1.9662575279 21.8229305497
12 1.9636424722 23.7865730220
13 1.9395560847 25.7261291067
14 1.9342119646 27.6603410712
15 0.0489788117 27.7093198829
16 0.0419833836 27.7513032665
17 0.0210269541 27.7723302206
18 0.0175613420 27.7898915626
19 0.0165293116 27.8064208742
20 0.0161682740 27.8225891481
21 0.0143961758 27.8369853240
22 0.0123702550 27.8493555789
23 0.0118748620 27.8612304409
24 0.0097118925 27.8709423334
25 0.0090745097 27.8800168431
26 0.0076840490 27.8877008921
27 0.0073945793 27.8950954714
28 0.0073318823 27.9024273537
29 0.0071047336 27.9095320873
30 0.0068169881 27.9163490754
31 0.0061357857 27.9224848611
32 0.0049567253 27.9274415864
33 0.0044416218 27.9318832082
34 0.0042366255 27.9361198337
35 0.0038628889 27.9399827226
36 0.0031706821 27.9431534048
37 0.0029590213 27.9461124261
38 0.0029488422 27.9490612683
39 0.0025652491 27.9516265174
40 0.0025115089 27.9541380263
41 0.0023226499 27.9564606762
42 0.0022603597 27.9587210358
43 0.0020727508 27.9607937867
44 0.0019918112 27.9627855979
45 0.0016058039 27.9643914018
46 0.0015506198 27.9659420215
47 0.0015128626 27.9674548841
48 0.0014234166 27.9688783007
49 0.0013649925 27.9702432932
50 0.0012522451 27.9714955383
51 0.0011307449 27.9726262832
52 0.0010834025 27.9737096857
53 0.0010376616 27.9747473473
54 0.0010090203 27.9757563676
55 0.0009789990 27.9767353666
56 0.0009418967 27.9776772633
57 0.0008815704 27.9785588336
58 0.0008522911 27.9794111248
59 0.0007361815 27.9801473063
60 0.0006430197 27.9807903259
61 0.0006335942 27.9814239202
62 0.0006275862 27.9820515063
63 0.0006184016 27.9826699079
64 0.0006171626 27.9832870705
65 0.0006084286 27.9838954991
66 0.0005683661 27.9844638652
67 0.0005629360 27.9850268012
68 0.0005584844 27.9855852855
69 0.0004488848 27.9860341704
70 0.0004419920 27.9864761623
71 0.0004103956 27.9868865579
72 0.0003899166 27.9872764745
73 0.0003761335 27.9876526081
74 0.0003690626 27.9880216706
75 0.0003486016 27.9883702722
76 0.0003412265 27.9887114987
77 0.0003367933 27.9890482920
78 0.0003217244 27.9893700164
79 0.0003135280 27.9896835445
80 0.0003038686 27.9899874130
81 0.0003036389 27.9902910519
82 0.0002643404 27.9905553923
83 0.0002421760 27.9907975683
84 0.0002411865 27.9910387548
85 0.0002400782 27.9912788330
86 0.0002345421 27.9915133751
87 0.0002341602 27.9917475353
88 0.0002305203 27.9919780556
89 0.0002293426 27.9922073983
90 0.0002253575 27.9924327558
91 0.0002207894 27.9926535452
92 0.0002133960 27.9928669412
93 0.0002035215 27.9930704627
94 0.0002025261 27.9932729888
95 0.0001982685 27.9934712573
96 0.0001839859 27.9936552432
97 0.0001819348 27.9938371780
98 0.0001798853 27.9940170633
99 0.0001774579 27.9941945212
100 0.0001538683 27.9943483895
101 0.0001432157 27.9944916052
102 0.0001394626 27.9946310678
103 0.0001374386 27.9947685064
104 0.0001362870 27.9949047934
105 0.0001234790 27.9950282723
106 0.0001162881 27.9951445604
107 0.0001083855 27.9952529459
108 0.0001047468 27.9953576927
109 0.0000995308 27.9954572235
110 0.0000961378 27.9955533613
111 0.0000930729 27.9956464343
112 0.0000928452 27.9957392795
113 0.0000919261 27.9958312056
114 0.0000895678 27.9959207734
115 0.0000894449 27.9960102183
116 0.0000839942 27.9960942125
117 0.0000836007 27.9961778132
118 0.0000800982 27.9962579114
119 0.0000777172 27.9963356286
120 0.0000762812 27.9964119098
121 0.0000737839 27.9964856937
122 0.0000732848 27.9965589785
123 0.0000726000 27.9966315786
124 0.0000693888 27.9967009674
125 0.0000686509 27.9967696182
126 0.0000685995 27.9968382177
127 0.0000669992 27.9969052169
128 0.0000664889 27.9969717058
129 0.0000620210 27.9970337268
130 0.0000617212 27.9970954480
131 0.0000609423 27.9971563903
132 0.0000602719 27.9972166622
133 0.0000584297 27.9972750919
134 0.0000579771 27.9973330689
135 0.0000567089 27.9973897779
136 0.0000554372 27.9974452150
137 0.0000537886 27.9974990036
138 0.0000529788 27.9975519823
139 0.0000515517 27.9976035340
140 0.0000495841 27.9976531182
141 0.0000484628 27.9977015810
142 0.0000483173 27.9977498983
143 0.0000451861 27.9977950844
144 0.0000450644 27.9978401489
145 0.0000437474 27.9978838963
146 0.0000437426 27.9979276388
147 0.0000434408 27.9979710796
148 0.0000427923 27.9980138719
149 0.0000413824 27.9980552543
150 0.0000407075 27.9980959618
151 0.0000395448 27.9981355066
152 0.0000388802 27.9981743868
153 0.0000374691 27.9982118559
154 0.0000371693 27.9982490252
155 0.0000367500 27.9982857752
156 0.0000361141 27.9983218893
157 0.0000354741 27.9983573634
158 0.0000353901 27.9983927535
159 0.0000350638 27.9984278173
160 0.0000332907 27.9984611080
161 0.0000331715 27.9984942796
162 0.0000331588 27.9985274384
163 0.0000331201 27.9985605585
164 0.0000313234 27.9985918819
165 0.0000307913 27.9986226731
166 0.0000295047 27.9986521778
167 0.0000283689 27.9986805468
168 0.0000280251 27.9987085719
169 0.0000270096 27.9987355815
170 0.0000269346 27.9987625161
171 0.0000267646 27.9987892807
172 0.0000264948 27.9988157756
173 0.0000254276 27.9988412032
174 0.0000251601 27.9988663632
175 0.0000247347 27.9988910979
176 0.0000243122 27.9989154101
177 0.0000239987 27.9989394088
178 0.0000239398 27.9989633487
179 0.0000238581 27.9989872067
180 0.0000233262 27.9990105329
181 0.0000228027 27.9990333356
182 0.0000226468 27.9990559824
183 0.0000215116 27.9990774940
184 0.0000209046 27.9990983986
185 0.0000208963 27.9991192948
186 0.0000202331 27.9991395280
187 0.0000200820 27.9991596100
188 0.0000200294 27.9991796394
189 0.0000197694 27.9991994088
190 0.0000197253 27.9992191341
191 0.0000191937 27.9992383278
192 0.0000191625 27.9992574903
193 0.0000191095 27.9992765998
194 0.0000185972 27.9992951970
195 0.0000173004 27.9993124974
196 0.0000171101 27.9993296074
197 0.0000170854 27.9993466928
198 0.0000166445 27.9993633373
199 0.0000163192 27.9993796565
200 0.0000156133 27.9993952698
201 0.0000147890 27.9994100588
202 0.0000146327 27.9994246915
203 0.0000143460 27.9994390376
204 0.0000141920 27.9994532295
205 0.0000139649 27.9994671944
206 0.0000139085 27.9994811029
207 0.0000136080 27.9994947109
208 0.0000135221 27.9995082330
209 0.0000132218 27.9995214547
210 0.0000130334 27.9995344881
211 0.0000130069 27.9995474950
212 0.0000127242 27.9995602192
213 0.0000126645 27.9995728836
214 0.0000121853 27.9995850690
215 0.0000120231 27.9995970920
216 0.0000118467 27.9996089387
217 0.0000117924 27.9996207312
218 0.0000113083 27.9996320394
219 0.0000110877 27.9996431271
220 0.0000107940 27.9996539212
221 0.0000103949 27.9996643161
222 0.0000102618 27.9996745778
223 0.0000100738 27.9996846516
224 0.0000099911 27.9996946426
225 0.0000098908 27.9997045334
226 0.0000098444 27.9997143778
227 0.0000096842 27.9997240620
228 0.0000093899 27.9997334520
229 0.0000092187 27.9997426707
230 0.0000091439 27.9997518146
231 0.0000090280 27.9997608426
232 0.0000089562 27.9997697988
233 0.0000089488 27.9997787476
234 0.0000086983 27.9997874459
235 0.0000085903 27.9997960362
236 0.0000085295 27.9998045657
237 0.0000084733 27.9998130390
238 0.0000084472 27.9998214862
239 0.0000081337 27.9998296199
240 0.0000080280 27.9998376480
241 0.0000077368 27.9998453848
242 0.0000072405 27.9998526253
243 0.0000071066 27.9998597319
244 0.0000070957 27.9998668276
245 0.0000069490 27.9998737766
246 0.0000067283 27.9998805049
247 0.0000065872 27.9998870921
248 0.0000065383 27.9998936305
249 0.0000065018 27.9999001322
250 0.0000063160 27.9999064483
251 0.0000061262 27.9999125744
252 0.0000059061 27.9999184805
253 0.0000053614 27.9999238419
254 0.0000053230 27.9999291649
255 0.0000050103 27.9999341752
256 0.0000048492 27.9999390243
257 0.0000047828 27.9999438072
258 0.0000047820 27.9999485892
259 0.0000043772 27.9999529664
260 0.0000043587 27.9999573251
261 0.0000041102 27.9999614352
262 0.0000040632 27.9999654984
263 0.0000039513 27.9999694497
264 0.0000037355 27.9999731852
265 0.0000032674 27.9999764526
266 0.0000027602 27.9999792128
267 0.0000026280 27.9999818408
268 0.0000025234 27.9999843641
269 0.0000025219 27.9999868860
270 0.0000022084 27.9999890944
271 0.0000021551 27.9999912495
272 0.0000018815 27.9999931310
273 0.0000018762 27.9999950072
274 0.0000017883 27.9999967955
275 0.0000016736 27.9999984691
276 0.0000015309 28.0000000000
======== ================ ================
.. >>>>> [ RES MEM : 7.352962 GB ] [ VIRT MEM : 12.451080 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 561.598754 s ] [ CPU TIME: 18056.146825 s ] <<<<< ..
.. >>>>> [ IO READ: ao_md5 ] <<<<< ..
.. >>>>> [ RES MEM : 7.352962 GB ] [ VIRT MEM : 12.451080 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 561.599621 s ] [ CPU TIME: 18056.209194 s ] <<<<< ..
* Saved determinants 1
Wall time: 0:09:28