CBD/CBD_CIPSI/D4h/Pop/triplet_only/CBD_D4h.scf.out
2021-04-14 11:41:05 +02:00

316 lines
12 KiB
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Date: 25/02/2021 16:05:24
===============
Quantum Package
===============
Git Commit: Fix space in size for EZFIO.cfg
Git Date : Fri Oct 16 14:24:01 2020 +0200
Git SHA1 : fd990ec9ca7a51ee7a8ff855ee6e3a6929b0dc7b
EZFIO Dir : CBD_D4h
Task server running : tcp://172.28.0.238:41279
.. >>>>> [ IO READ: ao_num ] <<<<< ..
.. >>>>> [ RES MEM : 0.017384 GB ] [ VIRT MEM : 0.201401 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.000939 s ] [ CPU TIME: 0.064915 s ] <<<<< ..
* mo_num 80
Read mo_coef
.. >>>>> [ IO READ: io_ao_integrals_overlap ] <<<<< ..
.. >>>>> [ RES MEM : 0.019409 GB ] [ VIRT MEM : 4.920952 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.039916 s ] [ CPU TIME: 1.235646 s ] <<<<< ..
.. >>>>> [ IO READ: ao_prim_num ] <<<<< ..
.. >>>>> [ RES MEM : 0.019878 GB ] [ VIRT MEM : 4.920952 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.044242 s ] [ CPU TIME: 1.505239 s ] <<<<< ..
.. >>>>> [ IO READ: ao_expo ] <<<<< ..
.. >>>>> [ RES MEM : 0.019905 GB ] [ VIRT MEM : 4.920952 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.047421 s ] [ CPU TIME: 1.695659 s ] <<<<< ..
.. >>>>> [ IO READ: ao_coef ] <<<<< ..
.. >>>>> [ RES MEM : 0.019924 GB ] [ VIRT MEM : 4.920952 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.050545 s ] [ CPU TIME: 1.887355 s ] <<<<< ..
.. >>>>> [ IO READ: ao_power ] <<<<< ..
.. >>>>> [ RES MEM : 0.019924 GB ] [ VIRT MEM : 4.920952 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.053163 s ] [ CPU TIME: 2.052495 s ] <<<<< ..
.. >>>>> [ IO READ: ao_nucl ] <<<<< ..
.. >>>>> [ RES MEM : 0.020100 GB ] [ VIRT MEM : 4.920952 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.056672 s ] [ CPU TIME: 2.282735 s ] <<<<< ..
.. >>>>> [ IO READ: nucl_num ] <<<<< ..
.. >>>>> [ RES MEM : 0.020100 GB ] [ VIRT MEM : 4.920952 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.072106 s ] [ CPU TIME: 3.314800 s ] <<<<< ..
.. >>>>> [ IO READ: nucl_label ] <<<<< ..
.. >>>>> [ RES MEM : 0.020130 GB ] [ VIRT MEM : 4.920952 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.074518 s ] [ CPU TIME: 3.476677 s ] <<<<< ..
.. >>>>> [ IO READ: nucl_charge ] <<<<< ..
.. >>>>> [ RES MEM : 0.020134 GB ] [ VIRT MEM : 4.920952 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.076822 s ] [ CPU TIME: 3.630397 s ] <<<<< ..
.. >>>>> [ RES MEM : 0.020134 GB ] [ VIRT MEM : 4.920952 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.078879 s ] [ CPU TIME: 3.768865 s ] <<<<< ..
Nuclear Coordinates (Angstroms)
===============================
================ ============ ============ ============ ============
Atom Charge X Y Z
================ ============ ============ ============ ============
C 6.000000 0.000000 1.017702 0.000000
C 6.000000 1.017702 0.000000 0.000000
C 6.000000 -1.017702 0.000000 0.000000
C 6.000000 0.000000 -1.017702 0.000000
H 1.000000 0.000000 2.092429 0.000000
H 1.000000 2.092429 0.000000 0.000000
H 1.000000 0.000000 -2.092429 0.000000
H 1.000000 -2.092429 0.000000 0.000000
================ ============ ============ ============ ============
* mo_label Natural
.. >>>>> [ IO READ: io_ao_one_e_integrals ] <<<<< ..
.. >>>>> [ RES MEM : 0.022678 GB ] [ VIRT MEM : 5.007198 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.158474 s ] [ CPU TIME: 9.179314 s ] <<<<< ..
.. >>>>> [ IO READ: do_pseudo ] <<<<< ..
.. >>>>> [ RES MEM : 0.022678 GB ] [ VIRT MEM : 5.007198 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.169606 s ] [ CPU TIME: 9.935112 s ] <<<<< ..
.. >>>>> [ IO READ: io_ao_integrals_kinetic ] <<<<< ..
.. >>>>> [ RES MEM : 0.022678 GB ] [ VIRT MEM : 5.007198 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.170248 s ] [ CPU TIME: 9.979255 s ] <<<<< ..
.. >>>>> [ IO READ: io_ao_integrals_e_n ] <<<<< ..
.. >>>>> [ RES MEM : 0.022678 GB ] [ VIRT MEM : 5.007198 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.172525 s ] [ CPU TIME: 10.135651 s ] <<<<< ..
.. >>>>> [ IO READ: io_nuclear_repulsion ] <<<<< ..
.. >>>>> [ RES MEM : 0.022678 GB ] [ VIRT MEM : 5.007198 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.176240 s ] [ CPU TIME: 10.385679 s ] <<<<< ..
.. >>>>> [ RES MEM : 0.022678 GB ] [ VIRT MEM : 5.007198 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.176512 s ] [ CPU TIME: 10.405180 s ] <<<<< ..
* Nuclear repulsion energy 99.44981960704467
.. >>>>> [ IO READ: elec_beta_num ] <<<<< ..
.. >>>>> [ RES MEM : 0.022881 GB ] [ VIRT MEM : 5.007198 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.187953 s ] [ CPU TIME: 11.192637 s ] <<<<< ..
.. >>>>> [ IO READ: elec_alpha_num ] <<<<< ..
.. >>>>> [ RES MEM : 0.022881 GB ] [ VIRT MEM : 5.007198 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.188691 s ] [ CPU TIME: 11.244368 s ] <<<<< ..
.. >>>>> [ IO READ: do_direct_integrals ] <<<<< ..
.. >>>>> [ RES MEM : 0.022881 GB ] [ VIRT MEM : 5.007198 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.190547 s ] [ CPU TIME: 11.372245 s ] <<<<< ..
AO map initialized : 6374235
.. >>>>> [ IO READ: io_ao_two_e_integrals ] <<<<< ..
.. >>>>> [ RES MEM : 0.023125 GB ] [ VIRT MEM : 5.011105 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.191603 s ] [ CPU TIME: 11.445548 s ] <<<<< ..
.. >>>>> [ IO READ: ao_integrals_threshold ] <<<<< ..
.. >>>>> [ RES MEM : 0.023125 GB ] [ VIRT MEM : 5.011105 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 0.192311 s ] [ CPU TIME: 11.494932 s ] <<<<< ..
Providing the AO integrals
Sorting the map
AO integrals provided:
Size of AO map : 36.3832054138184 MB
Number of AO integrals : 3212443
cpu time : 86.0342200000000 s
wall time : 1.54498600959778 s ( x 55.6860835409106 )
.. >>>>> [ IO READ: max_dim_diis ] <<<<< ..
.. >>>>> [ RES MEM : 0.091820 GB ] [ VIRT MEM : 5.276005 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 1.767702 s ] [ CPU TIME: 99.668395 s ] <<<<< ..
Read mo_occ
.. >>>>> [ IO READ: ao_md5 ] <<<<< ..
.. >>>>> [ RES MEM : 0.091846 GB ] [ VIRT MEM : 5.276005 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 1.770949 s ] [ CPU TIME: 99.892898 s ] <<<<< ..
.. >>>>> [ IO READ: level_shift ] <<<<< ..
.. >>>>> [ RES MEM : 0.091846 GB ] [ VIRT MEM : 5.276005 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 1.771561 s ] [ CPU TIME: 99.937118 s ] <<<<< ..
.. >>>>> [ IO READ: frozen_orb_scf ] <<<<< ..
.. >>>>> [ RES MEM : 0.091846 GB ] [ VIRT MEM : 5.276005 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 1.772170 s ] [ CPU TIME: 99.980431 s ] <<<<< ..
.. >>>>> [ IO READ: scf_algorithm ] <<<<< ..
.. >>>>> [ RES MEM : 0.097435 GB ] [ VIRT MEM : 5.378857 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 1.775964 s ] [ CPU TIME: 100.237037 s ] <<<<< ..
.. >>>>> [ IO READ: n_it_scf_max ] <<<<< ..
.. >>>>> [ RES MEM : 0.098595 GB ] [ VIRT MEM : 5.378857 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 1.777692 s ] [ CPU TIME: 100.360144 s ] <<<<< ..
.. >>>>> [ IO READ: thresh_scf ] <<<<< ..
.. >>>>> [ RES MEM : 0.098595 GB ] [ VIRT MEM : 5.378857 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 1.778352 s ] [ CPU TIME: 100.408066 s ] <<<<< ..
.. >>>>> [ IO READ: threshold_diis ] <<<<< ..
.. >>>>> [ RES MEM : 0.098595 GB ] [ VIRT MEM : 5.378857 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 1.778963 s ] [ CPU TIME: 100.451728 s ] <<<<< ..
.. >>>>> [ RES MEM : 0.098595 GB ] [ VIRT MEM : 5.382767 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 1.779317 s ] [ CPU TIME: 100.477543 s ] <<<<< ..
Energy of the guess = -153.647873093872
==== ================ ================ ================ ================
N Energy Energy diff DIIS error Level shift
==== ================ ================ ================ ================
1 -153.6499490677 -0.0020759739 0.0083301022 0.0000000000 1
.. >>>>> [ IO READ: mo_class ] <<<<< ..
.. >>>>> [ RES MEM : 0.098888 GB ] [ VIRT MEM : 5.382767 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 1.798414 s ] [ CPU TIME: 101.838545 s ] <<<<< ..
2 -153.6501250892 -0.0001760214 0.0046995755 0.0000000000 2
3 -153.6501570142 -0.0000319250 0.0008331270 0.0000000000 3
4 -153.6501584677 -0.0000014535 0.0002488797 0.0000000000 4
5 -153.6501585878 -0.0000001201 0.0000357243 0.0000000000 5
6 -153.6501585903 -0.0000000025 0.0000038059 0.0000000000 6
7 -153.6501585903 -0.0000000000 0.0000002933 0.0000000000 7
==== ================ ================ ================ ================
.. >>>>> [ RES MEM : 0.107208 GB ] [ VIRT MEM : 5.382950 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 4.391746 s ] [ CPU TIME: 203.839172 s ] <<<<< ..
MOs are now **Canonical**
Eigenvalues
-----------
======== ================
1 -11.2566123802
2 -11.2557682892
3 -11.2557680634
4 -11.2547329821
5 -1.2191040323
6 -0.9221923797
7 -0.9221923580
8 -0.7311366525
9 -0.7187798235
10 -0.6435757358
11 -0.5680437295
12 -0.5313276934
13 -0.5313276765
14 -0.0903937022
15 -0.0903935745
16 0.0856147554
17 0.0856147579
18 0.0894359681
19 0.1033702050
20 0.1416719721
21 0.1419054967
22 0.1712316439
23 0.1712316449
24 0.1789742408
25 0.1830108036
26 0.1830108063
27 0.1891362992
28 0.2202343516
29 0.2616526208
30 0.2616526229
31 0.2951326436
32 0.3561360665
33 0.4131412439
34 0.4131412525
35 0.4207599023
36 0.4422943413
37 0.4655564577
38 0.4655564627
39 0.5400830522
40 0.7953523433
41 0.8508015236
42 0.8912224724
43 0.9740308501
44 0.9740308678
45 0.9748970428
46 0.9977163017
47 0.9977163713
48 1.0541127882
49 1.0633525658
50 1.1003609127
51 1.1506973492
52 1.1506973853
53 1.1704434488
54 1.2498303550
55 1.2763852261
56 1.2763852430
57 1.5069496245
58 1.5096630260
59 1.5096630373
60 1.6213317706
61 1.6556561504
62 1.8666950504
63 1.8666950573
64 1.9123797681
65 1.9185927067
66 2.1725998241
67 2.3272918058
68 2.3272918260
69 2.3445890047
70 2.5388430277
71 2.5388430355
72 2.6785650791
73 2.7675377796
74 2.7675378052
75 2.7815721482
76 3.0126364624
77 3.0126364626
78 3.0303935049
79 3.2981664343
80 3.4262387604
======== ================
.. >>>>> [ RES MEM : 0.107578 GB ] [ VIRT MEM : 5.557274 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 4.395492 s ] [ CPU TIME: 204.090282 s ] <<<<< ..
* SCF energy -153.6501585903380
.. >>>>> [ RES MEM : 0.107670 GB ] [ VIRT MEM : 5.557274 GB ] <<<<< ..
.. >>>>> [ WALL TIME: 4.480034 s ] [ CPU TIME: 209.616407 s ] <<<<< ..
Wall time: 0:00:07