430 lines
18 KiB
Plaintext
430 lines
18 KiB
Plaintext
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Running Job 1 of 1 h2_1.55.inp
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qchem h2_1.55.inp_46398.0 /mnt/beegfs/tmpdir/qchem46398/ 0
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/share/apps/common/q-chem/5.2.1/exe/qcprog.exe_s h2_1.55.inp_46398.0 /mnt/beegfs/tmpdir/qchem46398/
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Welcome to Q-Chem
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A Quantum Leap Into The Future Of Chemistry
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Q-Chem 5.2, Q-Chem, Inc., Pleasanton, CA (2019)
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Yihan Shao, Zhengting Gan, E. Epifanovsky, A. T. B. Gilbert, M. Wormit,
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J. Kussmann, A. W. Lange, A. Behn, Jia Deng, Xintian Feng, D. Ghosh,
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M. Goldey, P. R. Horn, L. D. Jacobson, I. Kaliman, T. Kus, A. Landau,
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Jie Liu, E. I. Proynov, R. M. Richard, R. P. Steele, E. J. Sundstrom,
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H. L. Woodcock III, P. M. Zimmerman, D. Zuev, B. Albrecht, E. Alguire,
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S. A. Baeppler, D. Barton, Z. Benda, Y. A. Bernard, E. J. Berquist,
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K. B. Bravaya, H. Burton, D. Casanova, Chun-Min Chang, Yunqing Chen,
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A. Chien, K. D. Closser, M. P. Coons, S. Coriani, S. Dasgupta,
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A. L. Dempwolff, M. Diedenhofen, Hainam Do, R. G. Edgar, Po-Tung Fang,
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S. Faraji, S. Fatehi, Qingguo Feng, K. D. Fenk, J. Fosso-Tande,
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J. Gayvert, Qinghui Ge, A. Ghysels, G. Gidofalvi, J. Gomes,
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J. Gonthier, A. Gunina, D. Hait, M. W. D. Hanson-Heine,
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P. H. P. Harbach, A. W. Hauser, M. F. Herbst, J. E. Herr,
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E. G. Hohenstein, Z. C. Holden, Kerwin Hui, B. C. Huynh, T.-C. Jagau,
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Hyunjun Ji, B. Kaduk, K. Khistyaev, Jaehoon Kim, P. Klunzinger, K. Koh,
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D. Kosenkov, L. Koulias, T. Kowalczyk, C. M. Krauter, A. Kunitsa,
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Ka Un Lao, A. Laurent, K. V. Lawler, Joonho Lee, D. Lefrancois,
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S. Lehtola, D. S. Levine, Yi-Pei Li, You-Sheng Lin, Fenglai Liu,
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E. Livshits, A. Luenser, P. Manohar, E. Mansoor, S. F. Manzer,
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Shan-Ping Mao, Yuezhi Mao, N. Mardirossian, A. V. Marenich,
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T. Markovich, L. A. Martinez-Martinez, S. A. Maurer, N. J. Mayhall,
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S. C. McKenzie, J.-M. Mewes, P. Morgante, A. F. Morrison,
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J. W. Mullinax, K. Nanda, T. S. Nguyen-Beck, R. Olivares-Amaya,
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J. A. Parkhill, Zheng Pei, T. M. Perrine, F. Plasser, P. Pokhilko,
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S. Prager, A. Prociuk, E. Ramos, D. R. Rehn, F. Rob, M. Scheurer,
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M. Schneider, N. Sergueev, S. M. Sharada, S. Sharma, D. W. Small,
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T. Stauch, T. Stein, Yu-Chuan Su, A. J. W. Thom, A. Tkatchenko,
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T. Tsuchimochi, N. M. Tubman, L. Vogt, M. L. Vidal, O. Vydrov,
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M. A. Watson, J. Wenzel, M. de Wergifosse, T. A. Wesolowski, A. White,
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J. Witte, A. Yamada, Jun Yang, K. Yao, S. Yeganeh, S. R. Yost,
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Zhi-Qiang You, A. Zech, Igor Ying Zhang, Xing Zhang, Yan Zhao,
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Ying Zhu, B. R. Brooks, G. K. L. Chan, C. J. Cramer, M. S. Gordon,
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W. J. Hehre, A. Klamt, M. W. Schmidt, C. D. Sherrill, D. G. Truhlar,
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A. Aspuru-Guzik, R. Baer, A. T. Bell, N. A. Besley, Jeng-Da Chai,
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A. E. DePrince, III, R. A. DiStasio Jr., A. Dreuw, B. D. Dunietz,
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T. R. Furlani, Chao-Ping Hsu, Yousung Jung, Jing Kong, D. S. Lambrecht,
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WanZhen Liang, C. Ochsenfeld, V. A. Rassolov, L. V. Slipchenko,
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J. E. Subotnik, T. Van Voorhis, J. M. Herbert, A. I. Krylov,
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P. M. W. Gill, M. Head-Gordon
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Contributors to earlier versions of Q-Chem not listed above:
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R. D. Adamson, B. Austin, J. Baker, G. J. O. Beran, K. Brandhorst,
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S. T. Brown, E. F. C. Byrd, A. K. Chakraborty, C.-L. Cheng,
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Siu Hung Chien, D. M. Chipman, D. L. Crittenden, H. Dachsel,
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R. J. Doerksen, A. D. Dutoi, L. Fusti-Molnar, W. A. Goddard III,
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A. Golubeva-Zadorozhnaya, S. R. Gwaltney, G. Hawkins, A. Heyden,
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S. Hirata, G. Kedziora, F. J. Keil, C. Kelley, Jihan Kim, R. A. King,
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R. Z. Khaliullin, P. P. Korambath, W. Kurlancheek, A. M. Lee, M. S. Lee,
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S. V. Levchenko, Ching Yeh Lin, D. Liotard, R. C. Lochan, I. Lotan,
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P. E. Maslen, N. Nair, D. P. O'Neill, D. Neuhauser, E. Neuscamman,
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C. M. Oana, R. Olson, B. Peters, R. Peverati, P. A. Pieniazek,
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Y. M. Rhee, J. Ritchie, M. A. Rohrdanz, E. Rosta, N. J. Russ,
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H. F. Schaefer III, N. E. Schultz, N. Shenvi, A. C. Simmonett, A. Sodt,
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D. Stuck, K. S. Thanthiriwatte, V. Vanovschi, Tao Wang, A. Warshel,
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C. F. Williams, Q. Wu, X. Xu, W. Zhang
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Please cite Q-Chem as follows:
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Y. Shao et al., Mol. Phys. 113, 184-215 (2015)
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DOI: 10.1080/00268976.2014.952696
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Q-Chem 5.2.1 for Intel X86 EM64T Linux
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Parts of Q-Chem use Armadillo 8.300.2 (Tropical Shenanigans).
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http://arma.sourceforge.net/
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Q-Chem begins on Fri Jan 22 16:42:54 2021
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Host:
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0
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Scratch files written to /mnt/beegfs/tmpdir/qchem46398//
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Jul1719 |scratch|qcdevops|jenkins|workspace|build_RNUM 6358
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Processing $rem in /share/apps/common/q-chem/5.2.1/config/preferences:
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MEM_TOTAL 5000
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NAlpha2: 4
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NElect 2
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Mult 3
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Checking the input file for inconsistencies... ...done.
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--------------------------------------------------------------
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User input:
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--------------------------------------------------------------
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$comment
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SF-CIS
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$end
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$molecule
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0 3
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H 0 0 0
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H 0 0 1.55
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$end
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$rem
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JOBTYPE = sp
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METHOD = HF
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BASIS = CC-PVQZ
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PURECART = 2222
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SCF_CONVERGENCE = 9
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THRESH = 12
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MAX_SCF_CYCLES = 100
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MAX_CIS_CYCLES = 100
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SPIN_FLIP = TRUE
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UNRESTRICTED = TRUE
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CIS_N_ROOTS = 20
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RPA = FALSE
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$end
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--------------------------------------------------------------
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----------------------------------------------------------------
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Standard Nuclear Orientation (Angstroms)
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I Atom X Y Z
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----------------------------------------------------------------
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1 H 0.0000000000 0.0000000000 -0.7750000000
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2 H 0.0000000000 0.0000000000 0.7750000000
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----------------------------------------------------------------
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Molecular Point Group D*h NOp =***
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Largest Abelian Subgroup D2h NOp = 1
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Nuclear Repulsion Energy = 0.34140465 hartrees
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There are 2 alpha and 0 beta electrons
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Q-Chem warning in module forms1/BasisType.C, line 1983:
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You are not using the predefined 5D/6D in this basis set.
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Requested basis set is cc-pVQZ
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There are 20 shells and 70 basis functions
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Total QAlloc Memory Limit 5000 MB
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Mega-Array Size 188 MB
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MEM_STATIC part 192 MB
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Distance Matrix (Angstroms)
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H ( 1)
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H ( 2) 1.550000
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A cutoff of 1.0D-12 yielded 210 shell pairs
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There are 2653 function pairs
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Smallest overlap matrix eigenvalue = 9.89E-04
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Scale SEOQF with 1.000000e+00/1.000000e+00/1.000000e+00
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Standard Electronic Orientation quadrupole field applied
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Nucleus-field energy = -0.0000000013 hartrees
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Guess from superposition of atomic densities
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Warning: Energy on first SCF cycle will be non-variational
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SAD guess density has 0.090382 electrons
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-----------------------------------------------------------------------
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General SCF calculation program by
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Eric Jon Sundstrom, Paul Horn, Yuezhi Mao, Dmitri Zuev, Alec White,
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David Stuck, Shaama M.S., Shane Yost, Joonho Lee, David Small,
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Daniel Levine, Susi Lehtola, Hugh Burton, Evgeny Epifanovsky,
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Bang C. Huynh
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-----------------------------------------------------------------------
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Hartree-Fock
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A unrestricted SCF calculation will be
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performed using DIIS
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SCF converges when DIIS error is below 1.0e-09
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---------------------------------------
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Cycle Energy DIIS error
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---------------------------------------
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1 0.2682351247 9.27e-04
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2 20.6086464823 1.77e-01
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3 20.5158526002 1.76e-01
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4 20.5107252137 1.76e-01
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5 20.5097206306 1.76e-01
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6 20.5092836322 1.76e-01
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7 20.4886615474 1.76e-01
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8 20.4604500653 1.76e-01
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9 20.4794861959 1.76e-01
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10 20.4090690118 1.76e-01
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11 20.4479366905 1.76e-01
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12 20.4488661711 1.76e-01
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13 20.4736371459 1.76e-01
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14 20.3703309186 1.75e-01
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15 20.3711419034 1.75e-01
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16 20.3649756871 1.75e-01
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17 -0.8536759631 5.32e-03
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18 -0.9587076374 1.08e-03
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19 -0.9665946982 2.21e-04
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20 -0.9669722687 1.33e-05
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21 -0.9669737651 3.21e-06
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22 -0.9669738499 2.49e-07
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23 -0.9669738502 4.81e-08
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24 -0.9669738503 1.25e-08
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25 -0.9669738503 1.15e-09
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26 -0.9669738503 1.32e-10 Convergence criterion met
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---------------------------------------
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SCF time: CPU 2.35s wall 3.00s
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<S^2> = 2.000000000
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SCF energy in the final basis set = -0.9669738503
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Total energy in the final basis set = -0.9669738503
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Spin-flip UCIS calculation will be performed
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CIS energy converged when residual is below 10e- 6
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---------------------------------------------------
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Iter Rts Conv Rts Left Ttl Dev Max Dev
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---------------------------------------------------
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1 0 20 0.115285 0.008535
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2 0 20 0.017407 0.008895
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3 0 20 0.000635 0.000231
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4 15 5 0.000011 0.000002
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5 20 0 0.000002 0.000000 Roots Converged
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---------------------------------------------------
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---------------------------------------------------
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SF-CIS Excitation Energies
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(The first "excited" state might be the ground state)
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---------------------------------------------------
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Excited state 1: excitation energy (eV) = -2.2046
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Total energy for state 1: -1.04799202 au
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<S**2> : 0.0064
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S( 1) --> S( 2) amplitude = 0.2491 alpha
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S( 1) --> V( 2) amplitude = 0.2156 alpha
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S( 2) --> S( 1) amplitude = 0.8898 alpha
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S( 2) --> V( 1) amplitude = 0.2966 alpha
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Excited state 2: excitation energy (eV) = -0.0000
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Total energy for state 2: -0.96697385 au
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<S**2> : 2.0000
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S( 1) --> S( 1) amplitude = 0.6514 alpha
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S( 1) --> V( 1) amplitude = 0.2607 alpha
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S( 2) --> S( 2) amplitude = 0.5817 alpha
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S( 2) --> V( 2) amplitude = 0.3913 alpha
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Excited state 3: excitation energy (eV) = 7.5282
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Total energy for state 3: -0.69031790 au
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<S**2> : 0.1681
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S( 1) --> S( 1) amplitude = -0.6223 alpha
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S( 1) --> V( 1) amplitude = -0.2092 alpha
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S( 2) --> S( 2) amplitude = 0.7381 alpha
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Excited state 4: excitation energy (eV) = 9.8624
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Total energy for state 4: -0.60453877 au
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<S**2> : 0.6234
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S( 1) --> S( 2) amplitude = 0.4640 alpha
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S( 1) --> V( 2) amplitude = 0.3591 alpha
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S( 2) --> S( 1) amplitude = -0.4532 alpha
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S( 2) --> V( 1) amplitude = 0.6469 alpha
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Excited state 5: excitation energy (eV) = 11.1799
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Total energy for state 5: -0.55611884 au
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<S**2> : 0.5087
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S( 1) --> S( 2) amplitude = 0.7111 alpha
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S( 2) --> V( 1) amplitude = -0.6377 alpha
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S( 2) --> V( 5) amplitude = -0.2573 alpha
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Excited state 6: excitation energy (eV) = 12.3701
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Total energy for state 6: -0.51238244 au
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<S**2> : 0.9077
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S( 1) --> S( 1) amplitude = -0.3686 alpha
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S( 1) --> V( 1) amplitude = 0.3093 alpha
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S( 2) --> S( 2) amplitude = -0.3026 alpha
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S( 2) --> V( 2) amplitude = 0.8067 alpha
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Excited state 7: excitation energy (eV) = 13.3045
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Total energy for state 7: -0.47804257 au
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<S**2> : 1.0000
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S( 1) --> V( 7) amplitude = -0.1990 alpha
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S( 2) --> V( 4) amplitude = 0.9774 alpha
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Excited state 8: excitation energy (eV) = 13.3045
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Total energy for state 8: -0.47804257 au
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<S**2> : 1.0000
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S( 1) --> V( 6) amplitude = -0.1990 alpha
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S( 2) --> V( 3) amplitude = 0.9774 alpha
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Excited state 9: excitation energy (eV) = 16.8113
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Total energy for state 9: -0.34917132 au
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<S**2> : 1.0000
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S( 1) --> V( 4) amplitude = 0.7510 alpha
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S( 2) --> V( 7) amplitude = -0.6539 alpha
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Excited state 10: excitation energy (eV) = 16.8113
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Total energy for state 10: -0.34917132 au
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<S**2> : 1.0000
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S( 1) --> V( 3) amplitude = 0.7510 alpha
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S( 2) --> V( 6) amplitude = -0.6539 alpha
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Excited state 11: excitation energy (eV) = 17.0827
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Total energy for state 11: -0.33919781 au
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<S**2> : 0.9758
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S( 1) --> S( 1) amplitude = -0.2253 alpha
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S( 1) --> V( 1) amplitude = 0.8645 alpha
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S( 2) --> V( 2) amplitude = -0.3947 alpha
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Excited state 12: excitation energy (eV) = 17.9896
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Total energy for state 12: -0.30586766 au
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<S**2> : 0.9564
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S( 1) --> S( 2) amplitude = 0.3577 alpha
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S( 1) --> V( 2) amplitude = -0.1842 alpha
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S( 2) --> V( 5) amplitude = 0.9022 alpha
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Excited state 13: excitation energy (eV) = 19.1602
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Total energy for state 13: -0.26284873 au
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<S**2> : 0.9190
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S( 1) --> S( 2) amplitude = -0.2974 alpha
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S( 1) --> V( 2) amplitude = 0.8525 alpha
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S( 2) --> V( 1) amplitude = -0.2727 alpha
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S( 2) --> V( 5) amplitude = 0.2771 alpha
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Excited state 14: excitation energy (eV) = 21.6997
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Total energy for state 14: -0.16952383 au
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<S**2> : 1.0000
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S( 1) --> V( 4) amplitude = 0.6557 alpha
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S( 2) --> V( 7) amplitude = 0.7528 alpha
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Excited state 15: excitation energy (eV) = 21.6997
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Total energy for state 15: -0.16952383 au
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<S**2> : 1.0000
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S( 1) --> V( 3) amplitude = 0.6557 alpha
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S( 2) --> V( 6) amplitude = 0.7528 alpha
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Excited state 16: excitation energy (eV) = 22.8404
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Total energy for state 16: -0.12760280 au
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<S**2> : 0.9607
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S( 1) --> V( 1) amplitude = -0.1552 alpha
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S( 1) --> V( 5) amplitude = 0.8808 alpha
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S( 2) --> V( 8) amplitude = -0.4194 alpha
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Excited state 17: excitation energy (eV) = 25.7340
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Total energy for state 17: -0.02126587 au
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<S**2> : 1.0000
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S( 1) --> V( 7) amplitude = 0.9754 alpha
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S( 2) --> V( 4) amplitude = 0.2028 alpha
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Excited state 18: excitation energy (eV) = 25.7340
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Total energy for state 18: -0.02126587 au
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<S**2> : 1.0000
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S( 1) --> V( 6) amplitude = 0.9754 alpha
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S( 2) --> V( 3) amplitude = 0.2028 alpha
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Excited state 19: excitation energy (eV) = 28.5414
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Total energy for state 19: 0.08190338 au
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<S**2> : 0.9988
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S( 1) --> V( 5) amplitude = 0.4076 alpha
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S( 2) --> V( 8) amplitude = 0.8841 alpha
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Excited state 20: excitation energy (eV) = 32.0350
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Total energy for state 20: 0.21029192 au
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<S**2> : 0.9949
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S( 1) --> V( 2) amplitude = -0.1854 alpha
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S( 1) --> V( 8) amplitude = -0.4159 alpha
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S( 1) --> V( 10) amplitude = 0.2854 alpha
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S( 2) --> V( 9) amplitude = 0.8316 alpha
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---------------------------------------------------
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SETman timing summary (seconds)
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CPU time 1.20s
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System time 0.00s
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Wall time 1.54s
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--------------------------------------------------------------
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Orbital Energies (a.u.)
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--------------------------------------------------------------
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Alpha MOs
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-- Occupied --
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-0.6124 -0.3968
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-- Virtual --
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0.2227 0.2670 0.3968 0.3968 0.5338 0.6074 0.6074 0.9051
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1.1192 1.1762 1.6068 1.7175 1.7175 1.9029 1.9029 1.9230
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1.9230 1.9516 1.9516 2.1787 2.1787 2.2255 2.4794 2.6535
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2.6535 3.0245 3.0739 3.5765 4.3841 4.3841 4.5056 4.5056
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4.5777 4.8085 5.6956 5.6956 5.8483 5.8725 5.8725 6.0282
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6.0282 6.0697 6.0697 6.2443 6.2443 6.8286 6.8286 7.8209
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8.0686 8.0686 8.1437 8.1437 8.1943 8.1943 8.5670 8.5670
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8.7027 9.2193 9.5799 9.6996 9.6996 9.7316 9.7316 9.8802
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9.9091 10.1510 22.6021 23.4490
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--------------------------------------------------------------
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Ground-State Mulliken Net Atomic Charges
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Atom Charge (a.u.) Spin (a.u.)
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--------------------------------------------------------
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1 H 0.000000 1.000000
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2 H -0.000000 1.000000
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--------------------------------------------------------
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Sum of atomic charges = -0.000000
|
|
Sum of spin charges = 2.000000
|
|
|
|
-----------------------------------------------------------------
|
|
Cartesian Multipole Moments
|
|
-----------------------------------------------------------------
|
|
Charge (ESU x 10^10)
|
|
-0.0000
|
|
Dipole Moment (Debye)
|
|
X 0.0000 Y -0.0000 Z -0.0000
|
|
Tot 0.0000
|
|
Quadrupole Moments (Debye-Ang)
|
|
XX -2.5301 XY 0.0000 YY -2.5301
|
|
XZ 0.0000 YZ 0.0000 ZZ -3.7022
|
|
Octopole Moments (Debye-Ang^2)
|
|
XXX -0.0000 XXY 0.0000 XYY -0.0000
|
|
YYY 0.0000 XXZ -0.0000 XYZ 0.0000
|
|
YYZ -0.0000 XZZ -0.0000 YZZ -0.0000
|
|
ZZZ -0.0000
|
|
Hexadecapole Moments (Debye-Ang^3)
|
|
XXXX -2.9897 XXXY 0.0000 XXYY -0.9966
|
|
XYYY 0.0000 YYYY -2.9897 XXXZ 0.0000
|
|
XXYZ 0.0000 XYYZ 0.0000 YYYZ 0.0000
|
|
XXZZ -3.1262 XYZZ -0.0000 YYZZ -3.1262
|
|
XZZZ 0.0000 YZZZ 0.0000 ZZZZ -16.6734
|
|
-----------------------------------------------------------------
|
|
Archival summary:
|
|
1\1\lcpq-curie.ups-tlse.fr\SP\HF\BasisUnspecified\2(3)\emonino\FriJan2216:42:582021FriJan2216:42:582021\0\\#,HF,BasisUnspecified,\\0,3\H\H,1,1.55\\HF=-0.96697385\\@
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Total job time: 4.21s(wall), 3.65s(cpu)
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Fri Jan 22 16:42:58 2021
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*************************************************************
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* *
|
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* Thank you very much for using Q-Chem. Have a nice day. *
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* *
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*************************************************************
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