430 lines
18 KiB
Plaintext
430 lines
18 KiB
Plaintext
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Running Job 1 of 1 h2_1.50.inp
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qchem h2_1.50.inp_46325.0 /mnt/beegfs/tmpdir/qchem46325/ 0
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/share/apps/common/q-chem/5.2.1/exe/qcprog.exe_s h2_1.50.inp_46325.0 /mnt/beegfs/tmpdir/qchem46325/
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Welcome to Q-Chem
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A Quantum Leap Into The Future Of Chemistry
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Q-Chem 5.2, Q-Chem, Inc., Pleasanton, CA (2019)
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Yihan Shao, Zhengting Gan, E. Epifanovsky, A. T. B. Gilbert, M. Wormit,
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J. Kussmann, A. W. Lange, A. Behn, Jia Deng, Xintian Feng, D. Ghosh,
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M. Goldey, P. R. Horn, L. D. Jacobson, I. Kaliman, T. Kus, A. Landau,
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Jie Liu, E. I. Proynov, R. M. Richard, R. P. Steele, E. J. Sundstrom,
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H. L. Woodcock III, P. M. Zimmerman, D. Zuev, B. Albrecht, E. Alguire,
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S. A. Baeppler, D. Barton, Z. Benda, Y. A. Bernard, E. J. Berquist,
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K. B. Bravaya, H. Burton, D. Casanova, Chun-Min Chang, Yunqing Chen,
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A. Chien, K. D. Closser, M. P. Coons, S. Coriani, S. Dasgupta,
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A. L. Dempwolff, M. Diedenhofen, Hainam Do, R. G. Edgar, Po-Tung Fang,
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S. Faraji, S. Fatehi, Qingguo Feng, K. D. Fenk, J. Fosso-Tande,
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J. Gayvert, Qinghui Ge, A. Ghysels, G. Gidofalvi, J. Gomes,
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J. Gonthier, A. Gunina, D. Hait, M. W. D. Hanson-Heine,
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P. H. P. Harbach, A. W. Hauser, M. F. Herbst, J. E. Herr,
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E. G. Hohenstein, Z. C. Holden, Kerwin Hui, B. C. Huynh, T.-C. Jagau,
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Hyunjun Ji, B. Kaduk, K. Khistyaev, Jaehoon Kim, P. Klunzinger, K. Koh,
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D. Kosenkov, L. Koulias, T. Kowalczyk, C. M. Krauter, A. Kunitsa,
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Ka Un Lao, A. Laurent, K. V. Lawler, Joonho Lee, D. Lefrancois,
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S. Lehtola, D. S. Levine, Yi-Pei Li, You-Sheng Lin, Fenglai Liu,
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E. Livshits, A. Luenser, P. Manohar, E. Mansoor, S. F. Manzer,
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Shan-Ping Mao, Yuezhi Mao, N. Mardirossian, A. V. Marenich,
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T. Markovich, L. A. Martinez-Martinez, S. A. Maurer, N. J. Mayhall,
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S. C. McKenzie, J.-M. Mewes, P. Morgante, A. F. Morrison,
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J. W. Mullinax, K. Nanda, T. S. Nguyen-Beck, R. Olivares-Amaya,
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J. A. Parkhill, Zheng Pei, T. M. Perrine, F. Plasser, P. Pokhilko,
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S. Prager, A. Prociuk, E. Ramos, D. R. Rehn, F. Rob, M. Scheurer,
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M. Schneider, N. Sergueev, S. M. Sharada, S. Sharma, D. W. Small,
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T. Stauch, T. Stein, Yu-Chuan Su, A. J. W. Thom, A. Tkatchenko,
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T. Tsuchimochi, N. M. Tubman, L. Vogt, M. L. Vidal, O. Vydrov,
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M. A. Watson, J. Wenzel, M. de Wergifosse, T. A. Wesolowski, A. White,
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J. Witte, A. Yamada, Jun Yang, K. Yao, S. Yeganeh, S. R. Yost,
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Zhi-Qiang You, A. Zech, Igor Ying Zhang, Xing Zhang, Yan Zhao,
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Ying Zhu, B. R. Brooks, G. K. L. Chan, C. J. Cramer, M. S. Gordon,
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W. J. Hehre, A. Klamt, M. W. Schmidt, C. D. Sherrill, D. G. Truhlar,
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A. Aspuru-Guzik, R. Baer, A. T. Bell, N. A. Besley, Jeng-Da Chai,
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A. E. DePrince, III, R. A. DiStasio Jr., A. Dreuw, B. D. Dunietz,
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T. R. Furlani, Chao-Ping Hsu, Yousung Jung, Jing Kong, D. S. Lambrecht,
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WanZhen Liang, C. Ochsenfeld, V. A. Rassolov, L. V. Slipchenko,
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J. E. Subotnik, T. Van Voorhis, J. M. Herbert, A. I. Krylov,
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P. M. W. Gill, M. Head-Gordon
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Contributors to earlier versions of Q-Chem not listed above:
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R. D. Adamson, B. Austin, J. Baker, G. J. O. Beran, K. Brandhorst,
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S. T. Brown, E. F. C. Byrd, A. K. Chakraborty, C.-L. Cheng,
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Siu Hung Chien, D. M. Chipman, D. L. Crittenden, H. Dachsel,
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R. J. Doerksen, A. D. Dutoi, L. Fusti-Molnar, W. A. Goddard III,
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A. Golubeva-Zadorozhnaya, S. R. Gwaltney, G. Hawkins, A. Heyden,
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S. Hirata, G. Kedziora, F. J. Keil, C. Kelley, Jihan Kim, R. A. King,
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R. Z. Khaliullin, P. P. Korambath, W. Kurlancheek, A. M. Lee, M. S. Lee,
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S. V. Levchenko, Ching Yeh Lin, D. Liotard, R. C. Lochan, I. Lotan,
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P. E. Maslen, N. Nair, D. P. O'Neill, D. Neuhauser, E. Neuscamman,
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C. M. Oana, R. Olson, B. Peters, R. Peverati, P. A. Pieniazek,
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Y. M. Rhee, J. Ritchie, M. A. Rohrdanz, E. Rosta, N. J. Russ,
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H. F. Schaefer III, N. E. Schultz, N. Shenvi, A. C. Simmonett, A. Sodt,
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D. Stuck, K. S. Thanthiriwatte, V. Vanovschi, Tao Wang, A. Warshel,
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C. F. Williams, Q. Wu, X. Xu, W. Zhang
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Please cite Q-Chem as follows:
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Y. Shao et al., Mol. Phys. 113, 184-215 (2015)
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DOI: 10.1080/00268976.2014.952696
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Q-Chem 5.2.1 for Intel X86 EM64T Linux
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Parts of Q-Chem use Armadillo 8.300.2 (Tropical Shenanigans).
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http://arma.sourceforge.net/
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Q-Chem begins on Fri Jan 22 16:42:50 2021
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Host:
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0
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Scratch files written to /mnt/beegfs/tmpdir/qchem46325//
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Jul1719 |scratch|qcdevops|jenkins|workspace|build_RNUM 6358
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Processing $rem in /share/apps/common/q-chem/5.2.1/config/preferences:
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MEM_TOTAL 5000
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NAlpha2: 4
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NElect 2
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Mult 3
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Checking the input file for inconsistencies... ...done.
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--------------------------------------------------------------
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User input:
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--------------------------------------------------------------
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$comment
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SF-CIS
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$end
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$molecule
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0 3
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H 0 0 0
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H 0 0 1.50
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$end
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$rem
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JOBTYPE = sp
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METHOD = HF
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BASIS = CC-PVQZ
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PURECART = 2222
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SCF_CONVERGENCE = 9
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THRESH = 12
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MAX_SCF_CYCLES = 100
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MAX_CIS_CYCLES = 100
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SPIN_FLIP = TRUE
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UNRESTRICTED = TRUE
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CIS_N_ROOTS = 20
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RPA = FALSE
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$end
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--------------------------------------------------------------
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----------------------------------------------------------------
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Standard Nuclear Orientation (Angstroms)
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I Atom X Y Z
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----------------------------------------------------------------
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1 H 0.0000000000 0.0000000000 -0.7500000000
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2 H 0.0000000000 0.0000000000 0.7500000000
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----------------------------------------------------------------
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Molecular Point Group D*h NOp =***
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Largest Abelian Subgroup D2h NOp = 1
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Nuclear Repulsion Energy = 0.35278481 hartrees
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There are 2 alpha and 0 beta electrons
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Q-Chem warning in module forms1/BasisType.C, line 1983:
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You are not using the predefined 5D/6D in this basis set.
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Requested basis set is cc-pVQZ
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There are 20 shells and 70 basis functions
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Total QAlloc Memory Limit 5000 MB
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Mega-Array Size 188 MB
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MEM_STATIC part 192 MB
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Distance Matrix (Angstroms)
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H ( 1)
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H ( 2) 1.500000
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A cutoff of 1.0D-12 yielded 210 shell pairs
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There are 2653 function pairs
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Smallest overlap matrix eigenvalue = 9.05E-04
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Scale SEOQF with 1.000000e+00/1.000000e+00/1.000000e+00
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Standard Electronic Orientation quadrupole field applied
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Nucleus-field energy = -0.0000000012 hartrees
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Guess from superposition of atomic densities
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Warning: Energy on first SCF cycle will be non-variational
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SAD guess density has 0.090382 electrons
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-----------------------------------------------------------------------
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General SCF calculation program by
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Eric Jon Sundstrom, Paul Horn, Yuezhi Mao, Dmitri Zuev, Alec White,
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David Stuck, Shaama M.S., Shane Yost, Joonho Lee, David Small,
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Daniel Levine, Susi Lehtola, Hugh Burton, Evgeny Epifanovsky,
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Bang C. Huynh
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-----------------------------------------------------------------------
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Hartree-Fock
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A unrestricted SCF calculation will be
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performed using DIIS
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SCF converges when DIIS error is below 1.0e-09
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---------------------------------------
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Cycle Energy DIIS error
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---------------------------------------
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1 0.2786287653 9.37e-04
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2 16.1043720902 1.26e-01
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3 16.0909701336 1.27e-01
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4 16.0909179931 1.27e-01
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5 16.0900718701 1.27e-01
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6 16.1003689780 1.27e-01
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7 16.1073592066 1.27e-01
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8 16.1389984614 1.27e-01
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9 16.1283046214 1.27e-01
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10 16.1024832043 1.26e-01
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11 16.1226116443 1.27e-01
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12 16.3077123426 1.29e-01
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13 16.4452319642 1.31e-01
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14 16.1457465558 1.27e-01
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15 16.0954439380 1.27e-01
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16 16.0794083476 1.27e-01
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17 -0.7446246894 4.49e-03
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18 -0.9375695607 1.58e-03
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19 -0.9620743985 2.42e-04
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20 -0.9626030281 3.14e-05
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21 -0.9626108441 8.11e-06
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22 -0.9626115479 1.67e-06
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23 -0.9626115766 1.24e-07
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24 -0.9626115767 8.61e-09
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25 -0.9626115767 1.12e-09
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26 -0.9626115767 1.86e-10 Convergence criterion met
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---------------------------------------
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SCF time: CPU 2.34s wall 2.00s
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<S^2> = 2.000000000
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SCF energy in the final basis set = -0.9626115767
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Total energy in the final basis set = -0.9626115767
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Spin-flip UCIS calculation will be performed
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CIS energy converged when residual is below 10e- 6
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---------------------------------------------------
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Iter Rts Conv Rts Left Ttl Dev Max Dev
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---------------------------------------------------
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1 0 20 0.118382 0.008569
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2 0 20 0.010004 0.001503
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3 1 19 0.000449 0.000056
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4 16 4 0.000010 0.000002
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5 20 0 0.000004 0.000001 Roots Converged
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---------------------------------------------------
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---------------------------------------------------
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SF-CIS Excitation Energies
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(The first "excited" state might be the ground state)
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---------------------------------------------------
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Excited state 1: excitation energy (eV) = -2.4667
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Total energy for state 1: -1.05326017 au
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<S**2> : 0.0069
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S( 1) --> S( 2) amplitude = 0.2325 alpha
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S( 1) --> V( 2) amplitude = 0.2078 alpha
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S( 2) --> S( 1) amplitude = 0.8971 alpha
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S( 2) --> V( 1) amplitude = -0.2945 alpha
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Excited state 2: excitation energy (eV) = -0.0000
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Total energy for state 2: -0.96261158 au
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<S**2> : 2.0000
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S( 1) --> S( 1) amplitude = 0.6523 alpha
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S( 1) --> V( 1) amplitude = -0.2591 alpha
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S( 2) --> S( 2) amplitude = 0.5796 alpha
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S( 2) --> V( 2) amplitude = 0.3942 alpha
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Excited state 3: excitation energy (eV) = 7.3764
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Total energy for state 3: -0.69153391 au
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<S**2> : 0.1706
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S( 1) --> S( 1) amplitude = -0.6174 alpha
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S( 1) --> V( 1) amplitude = 0.2150 alpha
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S( 2) --> S( 2) amplitude = 0.7413 alpha
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Excited state 4: excitation energy (eV) = 9.7955
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Total energy for state 4: -0.60263195 au
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<S**2> : 0.7566
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S( 1) --> S( 2) amplitude = -0.3502 alpha
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S( 1) --> V( 2) amplitude = -0.3274 alpha
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S( 2) --> S( 1) amplitude = 0.4307 alpha
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S( 2) --> V( 1) amplitude = 0.7478 alpha
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Excited state 5: excitation energy (eV) = 11.1964
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Total energy for state 5: -0.55115080 au
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<S**2> : 0.3737
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S( 1) --> S( 2) amplitude = 0.7719 alpha
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S( 1) --> V( 2) amplitude = 0.2073 alpha
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S( 2) --> V( 1) amplitude = 0.5252 alpha
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S( 2) --> V( 5) amplitude = 0.2752 alpha
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Excited state 6: excitation energy (eV) = 12.3190
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Total energy for state 6: -0.50989674 au
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<S**2> : 0.8983
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S( 1) --> S( 1) amplitude = -0.3680 alpha
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S( 1) --> V( 1) amplitude = -0.2831 alpha
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S( 2) --> S( 2) amplitude = -0.3018 alpha
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S( 2) --> V( 2) amplitude = 0.8173 alpha
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Excited state 7: excitation energy (eV) = 13.0669
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Total energy for state 7: -0.48241051 au
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<S**2> : 1.0000
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S( 1) --> V( 7) amplitude = 0.1865 alpha
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S( 2) --> V( 4) amplitude = 0.9799 alpha
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Excited state 8: excitation energy (eV) = 13.0669
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Total energy for state 8: -0.48241051 au
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<S**2> : 1.0000
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S( 1) --> V( 6) amplitude = -0.1865 alpha
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S( 2) --> V( 3) amplitude = 0.9799 alpha
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Excited state 9: excitation energy (eV) = 16.8790
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Total energy for state 9: -0.34231999 au
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<S**2> : 1.0000
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S( 1) --> V( 4) amplitude = 0.7403 alpha
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S( 2) --> V( 7) amplitude = 0.6659 alpha
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Excited state 10: excitation energy (eV) = 16.8790
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Total energy for state 10: -0.34231999 au
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<S**2> : 1.0000
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S( 1) --> V( 3) amplitude = 0.7403 alpha
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S( 2) --> V( 6) amplitude = -0.6659 alpha
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Excited state 11: excitation energy (eV) = 17.1164
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Total energy for state 11: -0.33359723 au
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<S**2> : 0.9792
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S( 1) --> S( 1) amplitude = 0.2367 alpha
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S( 1) --> V( 1) amplitude = 0.8727 alpha
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S( 2) --> V( 2) amplitude = 0.3717 alpha
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Excited state 12: excitation energy (eV) = 18.0613
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Total energy for state 12: -0.29887163 au
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<S**2> : 0.9499
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S( 1) --> S( 2) amplitude = -0.3520 alpha
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S( 2) --> V( 5) amplitude = 0.9114 alpha
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Excited state 13: excitation energy (eV) = 19.3453
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Total energy for state 13: -0.25168551 au
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<S**2> : 0.9266
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S( 1) --> S( 2) amplitude = -0.3211 alpha
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S( 1) --> V( 2) amplitude = 0.8589 alpha
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S( 2) --> V( 1) amplitude = 0.2558 alpha
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S( 2) --> V( 5) amplitude = -0.2442 alpha
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Excited state 14: excitation energy (eV) = 21.6469
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Total energy for state 14: -0.16710224 au
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<S**2> : 1.0000
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S( 1) --> V( 4) amplitude = -0.6675 alpha
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S( 2) --> V( 7) amplitude = 0.7422 alpha
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Excited state 15: excitation energy (eV) = 21.6469
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Total energy for state 15: -0.16710224 au
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<S**2> : 1.0000
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S( 1) --> V( 3) amplitude = 0.6675 alpha
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S( 2) --> V( 6) amplitude = 0.7422 alpha
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Excited state 16: excitation energy (eV) = 23.2357
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Total energy for state 16: -0.10871497 au
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<S**2> : 0.9638
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S( 1) --> V( 1) amplitude = -0.1516 alpha
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S( 1) --> V( 5) amplitude = 0.8722 alpha
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S( 2) --> V( 8) amplitude = 0.4406 alpha
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Excited state 17: excitation energy (eV) = 26.0244
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Total energy for state 17: -0.00623347 au
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<S**2> : 1.0000
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S( 1) --> V( 7) amplitude = 0.9778 alpha
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S( 2) --> V( 4) amplitude = -0.1903 alpha
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Excited state 18: excitation energy (eV) = 26.0244
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Total energy for state 18: -0.00623346 au
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<S**2> : 1.0000
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S( 1) --> V( 6) amplitude = 0.9778 alpha
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S( 2) --> V( 3) amplitude = 0.1903 alpha
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Excited state 19: excitation energy (eV) = 28.6399
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Total energy for state 19: 0.08988706 au
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<S**2> : 0.9988
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S( 1) --> V( 5) amplitude = -0.4293 alpha
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S( 2) --> V( 8) amplitude = 0.8736 alpha
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Excited state 20: excitation energy (eV) = 31.9095
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Total energy for state 20: 0.21004069 au
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<S**2> : 0.9946
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S( 1) --> V( 2) amplitude = 0.1783 alpha
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S( 1) --> V( 8) amplitude = 0.3189 alpha
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S( 1) --> V( 10) amplitude = -0.2808 alpha
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S( 2) --> V( 9) amplitude = 0.8770 alpha
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---------------------------------------------------
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SETman timing summary (seconds)
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CPU time 1.19s
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System time 0.00s
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Wall time 1.55s
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--------------------------------------------------------------
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Orbital Energies (a.u.)
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--------------------------------------------------------------
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Alpha MOs
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-- Occupied --
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-0.6210 -0.3894
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-- Virtual --
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0.2203 0.2685 0.3952 0.3952 0.5429 0.6130 0.6130 0.9150
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1.1158 1.1763 1.6171 1.7061 1.7061 1.9116 1.9116 1.9388
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1.9388 1.9415 1.9415 2.1923 2.1923 2.2529 2.5314 2.6962
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2.6962 3.0277 3.0748 3.6548 4.3900 4.3900 4.5063 4.5063
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4.5309 4.8395 5.6616 5.6616 5.8298 5.8298 5.9060 6.0186
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6.0186 6.0755 6.0755 6.2973 6.2973 6.9891 6.9891 8.0439
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8.0664 8.0664 8.1727 8.1727 8.2004 8.2004 8.5865 8.5865
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8.8053 9.2045 9.5640 9.6914 9.6914 9.7357 9.7357 9.8744
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9.8938 10.2600 22.5602 23.5398
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--------------------------------------------------------------
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Ground-State Mulliken Net Atomic Charges
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Atom Charge (a.u.) Spin (a.u.)
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--------------------------------------------------------
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1 H 0.000000 1.000000
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2 H -0.000000 1.000000
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--------------------------------------------------------
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Sum of atomic charges = -0.000000
|
|
Sum of spin charges = 2.000000
|
|
|
|
-----------------------------------------------------------------
|
|
Cartesian Multipole Moments
|
|
-----------------------------------------------------------------
|
|
Charge (ESU x 10^10)
|
|
-0.0000
|
|
Dipole Moment (Debye)
|
|
X 0.0000 Y 0.0000 Z 0.0000
|
|
Tot 0.0000
|
|
Quadrupole Moments (Debye-Ang)
|
|
XX -2.5246 XY -0.0000 YY -2.5246
|
|
XZ 0.0000 YZ -0.0000 ZZ -3.7835
|
|
Octopole Moments (Debye-Ang^2)
|
|
XXX 0.0000 XXY 0.0000 XYY 0.0000
|
|
YYY 0.0000 XXZ -0.0000 XYZ -0.0000
|
|
YYZ -0.0000 XZZ 0.0000 YZZ 0.0000
|
|
ZZZ -0.0000
|
|
Hexadecapole Moments (Debye-Ang^3)
|
|
XXXX -2.9827 XXXY -0.0000 XXYY -0.9942
|
|
XYYY -0.0000 YYYY -2.9827 XXXZ 0.0000
|
|
XXYZ -0.0000 XYYZ 0.0000 YYYZ -0.0000
|
|
XXZZ -3.0698 XYZZ -0.0000 YYZZ -3.0698
|
|
XZZZ 0.0000 YZZZ -0.0000 ZZZZ -16.3484
|
|
-----------------------------------------------------------------
|
|
Archival summary:
|
|
1\1\lcpq-curie.ups-tlse.fr\SP\HF\BasisUnspecified\2(3)\emonino\FriJan2216:42:542021FriJan2216:42:542021\0\\#,HF,BasisUnspecified,\\0,3\H\H,1,1.5\\HF=-0.962611577\\@
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Total job time: 4.23s(wall), 3.65s(cpu)
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|
Fri Jan 22 16:42:54 2021
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|
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*************************************************************
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* *
|
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* Thank you very much for using Q-Chem. Have a nice day. *
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* *
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*************************************************************
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