sfBSE/output/H2/CIS/h2_cis_quack_5.out
2021-01-19 14:22:38 +01:00

2584 lines
185 KiB
Plaintext

210 significant shell pairs computed in 0.000099 seconds
0
Computed Electron repulsion integrals Integrals in parallel in 3.719550 seconds
******************************************************************************************
* QuAcK QuAcK QuAcK *
* __ __ __ __ __ __ __ __ __ *
* <(o )___ <(o )___ <(o )___ <(o )___ <(o )___ <(o )___ <(o )___ <(o )___ <(o )___ *
* ( ._> / ( ._> / ( ._> / ( ._> / ( ._> / ( ._> / ( ._> / ( ._> / ( ._> / *
*|--------------------------------------------------------------------------------------|*
******************************************************************************************
----------------------
Number of atoms 2
----------------------
----------------------
Number of spin-up electron 1
Number of spin-down electron 1
Total number of electron 2
----------------------
----------------------
Number of core electron 0
Number of Rydberg electron 0
----------------------
------------------
Molecular geometry
------------------
Atom n. 1
Z = 1.0000000000
Atom coordinates: 0.0000000000 0.0000000000 0.0000000000
Atom n. 2
Z = 1.0000000000
Atom coordinates: 0.0000000000 0.0000000000 1.3228082878
------------------
Nuclear repulsion energy = 0.7559674438
------------------
Gaussian basis set
------------------
Atom n. 1
number of shells 10
------------------
s-type shell with K = 6
Exponents Contraction
82.6400000000 0.0020060000
12.4100000000 0.0153430000
2.8240000000 0.0755790000
0.7977000000 0.2568750000
0.2581000000 0.4973680000
0.0898900000 0.2961330000
s-type shell with K = 1
Exponents Contraction
0.7977000000 1.0000000000
s-type shell with K = 1
Exponents Contraction
0.2581000000 1.0000000000
s-type shell with K = 1
Exponents Contraction
0.0898900000 1.0000000000
p-type shell with K = 1
Exponents Contraction
2.2920000000 1.0000000000
p-type shell with K = 1
Exponents Contraction
0.8380000000 1.0000000000
p-type shell with K = 1
Exponents Contraction
0.2920000000 1.0000000000
d-type shell with K = 1
Exponents Contraction
2.0620000000 1.0000000000
d-type shell with K = 1
Exponents Contraction
0.6620000000 1.0000000000
f-type shell with K = 1
Exponents Contraction
1.3970000000 1.0000000000
------------------
Atom n. 2
number of shells 10
------------------
s-type shell with K = 6
Exponents Contraction
82.6400000000 0.0020060000
12.4100000000 0.0153430000
2.8240000000 0.0755790000
0.7977000000 0.2568750000
0.2581000000 0.4973680000
0.0898900000 0.2961330000
s-type shell with K = 1
Exponents Contraction
0.7977000000 1.0000000000
s-type shell with K = 1
Exponents Contraction
0.2581000000 1.0000000000
s-type shell with K = 1
Exponents Contraction
0.0898900000 1.0000000000
p-type shell with K = 1
Exponents Contraction
2.2920000000 1.0000000000
p-type shell with K = 1
Exponents Contraction
0.8380000000 1.0000000000
p-type shell with K = 1
Exponents Contraction
0.2920000000 1.0000000000
d-type shell with K = 1
Exponents Contraction
2.0620000000 1.0000000000
d-type shell with K = 1
Exponents Contraction
0.6620000000 1.0000000000
f-type shell with K = 1
Exponents Contraction
1.3970000000 1.0000000000
------------------
Number of shells 20
------------------
------------------
Number of basis functions 70
------------------
Scaling integrals by 1.0000000000000000
Total CPU time for reading integrals = 1.228 seconds
Lowdin orthogonalization
************************************************
* Unrestricted Hartree-Fock calculation *
************************************************
----------------------------------------------------------
| # | E(UHF) | Ex(UHF) | Conv |
----------------------------------------------------------
| 1 | -1.0656139944 | -0.7989802601 | 1.000000 |
| 2 | -1.1279274911 | -0.6966225610 | 0.029422 |
| 3 | -1.1312114660 | -0.6783170483 | 0.012815 |
| 4 | -1.1319892033 | -0.6746678808 | 0.008159 |
| 5 | -1.1323273566 | -0.6738131697 | 0.005683 |
| 6 | -1.1324863466 | -0.6735717480 | 0.003936 |
| 7 | -1.1325618099 | -0.6734905518 | 0.002720 |
| 8 | -1.1325976824 | -0.6734592837 | 0.001877 |
| 9 | -1.1326147409 | -0.6734461029 | 0.001295 |
| 10 | -1.1326228538 | -0.6734402363 | 0.000893 |
| 11 | -1.1326267124 | -0.6734375439 | 0.000616 |
| 12 | -1.1326285477 | -0.6734362875 | 0.000425 |
| 13 | -1.1326294206 | -0.6734356959 | 0.000293 |
| 14 | -1.1326298358 | -0.6734354160 | 0.000202 |
| 15 | -1.1326300332 | -0.6734352833 | 0.000139 |
| 16 | -1.1326301272 | -0.6734352202 | 0.000096 |
| 17 | -1.1326301718 | -0.6734351903 | 0.000066 |
| 18 | -1.1326301931 | -0.6734351760 | 0.000046 |
| 19 | -1.1326302032 | -0.6734351692 | 0.000032 |
| 20 | -1.1326302080 | -0.6734351660 | 0.000022 |
| 21 | -1.1326302103 | -0.6734351645 | 0.000015 |
| 22 | -1.1326302114 | -0.6734351638 | 0.000010 |
| 23 | -1.1326302119 | -0.6734351634 | 0.000007 |
| 24 | -1.1326302121 | -0.6734351632 | 0.000005 |
| 25 | -1.1326302123 | -0.6734351632 | 0.000003 |
| 26 | -1.1326302123 | -0.6734351631 | 0.000002 |
| 27 | -1.1326302123 | -0.6734351631 | 0.000002 |
| 28 | -1.1326302124 | -0.6734351631 | 0.000001 |
| 29 | -1.1326302124 | -0.6734351631 | 0.000001 |
| 30 | -1.1326302124 | -0.6734351631 | 0.000001 |
| 31 | -1.1326302124 | -0.6734351631 | 0.000000 |
| 32 | -1.1326302124 | -0.6734351631 | 0.000000 |
| 33 | -1.1326302124 | -0.6734351631 | 0.000000 |
| 34 | -1.1326302124 | -0.6734351631 | 0.000000 |
| 35 | -1.1326302124 | -0.6734351631 | 0.000000 |
----------------------------------------------------------
-------------------------------------------------
Summary
-------------------------------------------------
One-electron energy: -2.5620328193 au
One-electron a energy: -1.2810164096 au
One-electron b energy: -1.2810164096 au
Kinetic energy: 1.1697929966 au
Kinetic a energy: 0.5848964983 au
Kinetic b energy: 0.5848964983 au
Potential energy: -3.7318258158 au
Potential a energy: -1.8659129079 au
Potential b energy: -1.8659129079 au
-------------------------------------------------
Two-electron energy: 0.6734351631 au
Two-electron aa energy: 0.0000000000 au
Two-electron ab energy: 0.6734351631 au
Two-electron bb energy: -0.0000000000 au
Hartree energy: 1.3468703262 au
Hartree aa energy: 0.3367175815 au
Hartree ab energy: 0.6734351631 au
Hartree bb energy: 0.3367175815 au
Exchange energy: -0.6734351631 au
Exchange a energy: -0.3367175815 au
Exchange b energy: -0.3367175815 au
-------------------------------------------------
Electronic energy: -1.8885976562 au
Nuclear repulsion: 0.7559674438 au
UHF energy: -1.1326302124 au
-------------------------------------------------
UHF HOMO a energy: -16.533128 eV
UHF LUMO a energy: 4.032662 eV
UHF HOMOa-LUMOa gap: 20.565790 eV
-------------------------------------------------
UHF HOMO b energy: -16.533128 eV
UHF LUMO b energy: 4.032662 eV
UHF HOMOb-LUMOb gap : 20.565790 eV
-------------------------------------------------
S (exact) : 1.000000
S : 1.000000
<S**2> (exact) : 0.000000
<S**2> : 0.000000
-------------------------------------------------
Dipole moment (Debye)
X Y Z Tot.
0.000000 -0.000000 -0.000000 0.000000
-------------------------------------------------
-----------------------------------------
UHF spin-up orbital coefficients
-----------------------------------------
1 2 3 4 5
1 0.86327484 0.37233490 0.00802623 0.00000000 0.00000000
2 -0.04106335 0.69778715 -0.14262818 0.00000000 0.00000000
3 -0.16942385 -0.71167365 1.50133408 0.00000000 0.00000000
4 -0.16603621 2.99891061 -1.10905979 0.00000000 0.00000000
5 0.00000000 0.00000000 0.00000000 0.07727578 0.46696384
6 0.00000000 0.00000000 0.00000000 -0.46696384 0.07727578
7 0.00573888 -0.06970244 -0.04551177 0.00000000 0.00000000
8 0.00000000 0.00000000 0.00000000 -0.27582746 -1.66677635
9 0.00000000 0.00000000 0.00000000 1.66677635 -0.27582746
10 0.01217163 0.54939319 0.22448410 0.00000000 0.00000000
11 0.00000000 0.00000000 0.00000000 0.13488985 0.81511541
12 0.00000000 0.00000000 0.00000000 -0.81511541 0.13488985
13 0.01595108 0.18777981 -0.09594275 0.00000000 0.00000000
14 0.00092387 0.00393249 -0.01278552 0.00000000 0.00000000
15 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
16 0.00000000 0.00000000 0.00000000 -0.00018260 -0.00110344
17 0.00092387 0.00393249 -0.01278552 0.00000000 0.00000000
18 0.00000000 0.00000000 0.00000000 0.00110344 -0.00018260
19 0.00294645 0.02890565 -0.02146622 0.00000000 0.00000000
20 0.00022702 0.13387671 -0.18803347 0.00000000 0.00000000
21 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
22 0.00000000 0.00000000 0.00000000 0.00105400 0.00636914
23 0.00022702 0.13387671 -0.18803347 0.00000000 0.00000000
24 0.00000000 0.00000000 0.00000000 -0.00636914 0.00105400
25 0.00112784 0.31465620 -0.22413902 0.00000000 0.00000000
26 0.00000000 0.00000000 0.00000000 0.11340691 0.68529784
27 0.00000000 0.00000000 0.00000000 -0.30647451 0.05071711
28 -0.00012836 -0.04643768 -0.03362137 0.00000000 0.00000000
29 0.00000000 0.00000000 0.00000000 0.05071711 0.30647451
30 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
31 0.00000000 0.00000000 0.00000000 0.05032264 0.30409075
32 0.00000000 0.00000000 0.00000000 -0.68529784 0.11340691
33 -0.00012836 -0.04643768 -0.03362137 0.00000000 0.00000000
34 0.00000000 0.00000000 0.00000000 -0.30409075 0.05032264
35 -0.00026859 -0.07976558 -0.11676989 0.00000000 0.00000000
36 0.86327537 -0.37233458 0.00802620 0.00000000 0.00000000
37 -0.04106325 -0.69778714 -0.14262870 0.00000000 0.00000000
38 -0.16942357 0.71167296 1.50133476 0.00000000 0.00000000
39 -0.16603607 -2.99891014 -1.10906183 0.00000000 0.00000000
40 0.00000000 0.00000000 0.00000000 0.07727580 0.46696391
41 0.00000000 0.00000000 0.00000000 -0.46696391 0.07727580
42 -0.00573887 -0.06970248 0.04551172 0.00000000 0.00000000
43 0.00000000 0.00000000 0.00000000 -0.27582749 -1.66677657
44 0.00000000 0.00000000 0.00000000 1.66677657 -0.27582749
45 -0.01217166 0.54939332 -0.22448368 0.00000000 0.00000000
46 0.00000000 0.00000000 0.00000000 0.13488990 0.81511574
47 0.00000000 0.00000000 0.00000000 -0.81511574 0.13488990
48 -0.01595108 0.18777967 0.09594292 0.00000000 0.00000000
49 0.00092387 -0.00393248 -0.01278552 0.00000000 0.00000000
50 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
51 0.00000000 0.00000000 0.00000000 0.00018260 0.00110343
52 0.00092387 -0.00393248 -0.01278552 0.00000000 0.00000000
53 0.00000000 0.00000000 0.00000000 -0.00110343 0.00018260
54 0.00294645 -0.02890564 -0.02146625 0.00000000 0.00000000
55 0.00022702 -0.13387664 -0.18803358 0.00000000 0.00000000
56 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
57 0.00000000 0.00000000 0.00000000 -0.00105401 -0.00636917
58 0.00022702 -0.13387664 -0.18803358 0.00000000 0.00000000
59 0.00000000 0.00000000 0.00000000 0.00636917 -0.00105401
60 0.00112785 -0.31465610 -0.22413927 0.00000000 0.00000000
61 0.00000000 0.00000000 0.00000000 0.11340693 0.68529794
62 0.00000000 0.00000000 0.00000000 -0.30647455 0.05071712
63 0.00012837 -0.04643771 0.03362133 0.00000000 0.00000000
64 0.00000000 0.00000000 0.00000000 0.05071712 0.30647455
65 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
66 0.00000000 0.00000000 0.00000000 0.05032264 0.30409080
67 0.00000000 0.00000000 0.00000000 -0.68529794 0.11340693
68 0.00012837 -0.04643771 0.03362133 0.00000000 0.00000000
69 0.00000000 0.00000000 0.00000000 -0.30409080 0.05032264
70 0.00026860 -0.07976565 0.11676983 0.00000000 0.00000000
6 7 8 9 10
1 0.04267692 0.19752414 0.00000000 0.00000000 -1.74093893
2 -2.05112196 -0.13451536 0.00000000 0.00000000 -0.81678957
3 1.93711645 -1.30903078 0.00000000 0.00000000 4.05048597
4 -3.28314106 0.47679718 0.00000000 0.00000000 -0.27662711
5 0.00000000 0.00000000 -0.02256295 0.63930252 0.00000000
6 0.00000000 0.00000000 0.63930252 0.02256295 0.00000000
7 0.14070537 0.50408364 0.00000000 0.00000000 0.07239856
8 0.00000000 0.00000000 0.07689199 -2.17867133 0.00000000
9 0.00000000 0.00000000 -2.17867133 -0.07689199 0.00000000
10 -1.44534352 -1.97098417 0.00000000 0.00000000 -0.23813219
11 0.00000000 0.00000000 -0.08180261 2.31780973 0.00000000
12 0.00000000 0.00000000 2.31780973 0.08180261 0.00000000
13 -0.89683158 1.82705808 0.00000000 0.00000000 0.52976439
14 -0.00740617 0.01349229 0.00000000 0.00000000 -0.02855371
15 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
16 0.00000000 0.00000000 -0.00060314 0.01708953 0.00000000
17 -0.00740617 0.01349229 0.00000000 0.00000000 -0.02855371
18 0.00000000 0.00000000 0.01708953 0.00060314 0.00000000
19 -0.08069425 0.00984926 0.00000000 0.00000000 -0.06791878
20 -0.38136368 0.03123018 0.00000000 0.00000000 -0.70687666
21 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
22 0.00000000 0.00000000 -0.00905635 0.25660413 0.00000000
23 -0.38136368 0.03123018 0.00000000 0.00000000 -0.70687666
24 0.00000000 0.00000000 0.25660413 0.00905635 0.00000000
25 -0.90433985 0.36156833 0.00000000 0.00000000 -0.67297234
26 0.00000000 0.00000000 -0.03165783 0.89699855 0.00000000
27 0.00000000 0.00000000 0.40114995 0.01415781 0.00000000
28 0.10590810 0.32994417 0.00000000 0.00000000 0.04786597
29 0.00000000 0.00000000 -0.01415781 0.40114995 0.00000000
30 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
31 0.00000000 0.00000000 -0.01657931 0.46976113 0.00000000
32 0.00000000 0.00000000 0.89699855 0.03165783 0.00000000
33 0.10590810 0.32994417 0.00000000 0.00000000 0.04786597
34 0.00000000 0.00000000 0.46976113 0.01657931 0.00000000
35 0.16628949 0.86364449 0.00000000 0.00000000 0.01753505
36 -0.04267676 0.19752420 0.00000000 0.00000000 -1.74093944
37 2.05112178 -0.13451536 0.00000000 0.00000000 -0.81679175
38 -1.93711582 -1.30902928 0.00000000 0.00000000 4.05048374
39 3.28314077 0.47679694 0.00000000 0.00000000 -0.27662790
40 0.00000000 0.00000000 0.02256294 -0.63930239 0.00000000
41 0.00000000 0.00000000 -0.63930239 -0.02256294 0.00000000
42 0.14070534 -0.50408365 0.00000000 0.00000000 -0.07239869
43 0.00000000 0.00000000 -0.07689197 2.17867086 0.00000000
44 0.00000000 0.00000000 2.17867086 0.07689197 0.00000000
45 -1.44534346 1.97098417 0.00000000 0.00000000 0.23813363
46 0.00000000 0.00000000 0.08180260 -2.31780955 0.00000000
47 0.00000000 0.00000000 -2.31780955 -0.08180260 0.00000000
48 -0.89683179 -1.82705853 0.00000000 0.00000000 -0.52976252
49 0.00740617 0.01349228 0.00000000 0.00000000 -0.02855371
50 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
51 0.00000000 0.00000000 -0.00060314 0.01708953 0.00000000
52 0.00740617 0.01349228 0.00000000 0.00000000 -0.02855371
53 0.00000000 0.00000000 0.01708953 0.00060314 0.00000000
54 0.08069424 0.00984925 0.00000000 0.00000000 -0.06791885
55 0.38136357 0.03123014 0.00000000 0.00000000 -0.70687694
56 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
57 0.00000000 0.00000000 -0.00905635 0.25660412 0.00000000
58 0.38136357 0.03123014 0.00000000 0.00000000 -0.70687694
59 0.00000000 0.00000000 0.25660412 0.00905635 0.00000000
60 0.90433975 0.36156831 0.00000000 0.00000000 -0.67297325
61 0.00000000 0.00000000 0.03165782 -0.89699836 0.00000000
62 0.00000000 0.00000000 -0.40114986 -0.01415781 0.00000000
63 0.10590809 -0.32994417 0.00000000 0.00000000 -0.04786607
64 0.00000000 0.00000000 0.01415781 -0.40114986 0.00000000
65 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
66 0.00000000 0.00000000 0.01657931 -0.46976105 0.00000000
67 0.00000000 0.00000000 -0.89699836 -0.03165782 0.00000000
68 0.10590809 -0.32994417 0.00000000 0.00000000 -0.04786607
69 0.00000000 0.00000000 -0.46976105 -0.01657931 0.00000000
70 0.16628947 -0.86364450 0.00000000 0.00000000 -0.01753518
11 12 13 14 15
1 -0.01624009 -1.90815067 0.00000000 0.00000000 0.00000000
2 5.66564707 -5.01345292 0.00000000 0.00000000 0.00000000
3 29.11837830 6.52999718 0.00000000 0.00000000 0.00000000
4 0.06101027 -1.96164523 0.00000000 0.00000000 0.00000000
5 0.00000000 0.00000000 0.00653544 -1.39666119 0.00000000
6 0.00000000 0.00000000 -1.39666119 -0.00653544 0.00000000
7 -0.24760760 0.35698230 0.00000000 0.00000000 0.00000000
8 0.00000000 0.00000000 -0.02468396 5.27510494 0.00000000
9 0.00000000 0.00000000 5.27510494 0.02468396 0.00000000
10 4.00301058 -3.21446752 0.00000000 0.00000000 0.00000000
11 0.00000000 0.00000000 0.00441457 -0.94341978 0.00000000
12 0.00000000 0.00000000 -0.94341978 -0.00441457 0.00000000
13 12.02867658 -0.36725430 0.00000000 0.00000000 0.00000000
14 -0.01929529 -0.01593509 0.00000000 0.00000000 0.08277363
15 0.00000000 0.00000000 0.00000000 0.00000000 0.00011755
16 0.00000000 0.00000000 -0.00003539 0.00756367 0.00000000
17 -0.01929529 -0.01593509 0.00000000 0.00000000 -0.08277363
18 0.00000000 0.00000000 0.00756367 0.00003539 0.00000000
19 0.19794163 -0.16516333 0.00000000 0.00000000 0.00000000
20 0.10220817 -1.02953408 0.00000000 0.00000000 -0.53452502
21 0.00000000 0.00000000 0.00000000 0.00000000 -0.00075910
22 0.00000000 0.00000000 0.00005086 -0.01086815 0.00000000
23 0.10220817 -1.02953408 0.00000000 0.00000000 0.53452502
24 0.00000000 0.00000000 -0.01086815 -0.00005086 0.00000000
25 2.36842907 -2.15334110 0.00000000 0.00000000 0.00000000
26 0.00000000 0.00000000 0.00979881 -2.09406228 0.00000000
27 0.00000000 0.00000000 -0.93649312 -0.00438216 0.00000000
28 -0.25032806 0.23658127 0.00000000 0.00000000 0.01900492
29 0.00000000 0.00000000 0.00438216 -0.93649312 0.00000000
30 0.00000000 0.00000000 0.00000000 0.00000000 0.00002699
31 0.00000000 0.00000000 0.00436133 -0.93204060 0.00000000
32 0.00000000 0.00000000 -2.09406228 -0.00979881 0.00000000
33 -0.25032806 0.23658127 0.00000000 0.00000000 -0.01900492
34 0.00000000 0.00000000 -0.93204060 -0.00436133 0.00000000
35 -0.21368708 0.39537521 0.00000000 0.00000000 0.00000000
36 0.01624038 1.90815006 0.00000000 0.00000000 0.00000000
37 -5.66564699 5.01345271 0.00000000 0.00000000 0.00000000
38 -29.11837896 -6.52999608 0.00000000 0.00000000 0.00000000
39 -0.06101022 1.96164524 0.00000000 0.00000000 0.00000000
40 0.00000000 0.00000000 0.00653544 -1.39666136 0.00000000
41 0.00000000 0.00000000 -1.39666136 -0.00653544 0.00000000
42 -0.24760761 0.35698225 0.00000000 0.00000000 0.00000000
43 0.00000000 0.00000000 -0.02468396 5.27510558 0.00000000
44 0.00000000 0.00000000 5.27510558 0.02468396 0.00000000
45 4.00301065 -3.21446728 0.00000000 0.00000000 0.00000000
46 0.00000000 0.00000000 0.00441457 -0.94342012 0.00000000
47 0.00000000 0.00000000 -0.94342012 -0.00441457 0.00000000
48 12.02867654 -0.36725451 0.00000000 0.00000000 0.00000000
49 0.01929530 0.01593508 0.00000000 0.00000000 0.08277364
50 0.00000000 0.00000000 0.00000000 0.00000000 0.00011755
51 0.00000000 0.00000000 0.00003539 -0.00756367 0.00000000
52 0.01929530 0.01593508 0.00000000 0.00000000 -0.08277364
53 0.00000000 0.00000000 -0.00756367 -0.00003539 0.00000000
54 -0.19794162 0.16516331 0.00000000 0.00000000 0.00000000
55 -0.10220807 1.02953386 0.00000000 0.00000000 -0.53452509
56 0.00000000 0.00000000 0.00000000 0.00000000 -0.00075910
57 0.00000000 0.00000000 -0.00005086 0.01086826 0.00000000
58 -0.10220807 1.02953386 0.00000000 0.00000000 0.53452509
59 0.00000000 0.00000000 0.01086826 0.00005086 0.00000000
60 -2.36842893 2.15334093 0.00000000 0.00000000 0.00000000
61 0.00000000 0.00000000 0.00979881 -2.09406253 0.00000000
62 0.00000000 0.00000000 -0.93649323 -0.00438216 0.00000000
63 -0.25032807 0.23658123 0.00000000 0.00000000 -0.01900492
64 0.00000000 0.00000000 0.00438216 -0.93649323 0.00000000
65 0.00000000 0.00000000 0.00000000 0.00000000 -0.00002699
66 0.00000000 0.00000000 0.00436133 -0.93204074 0.00000000
67 0.00000000 0.00000000 -2.09406253 -0.00979881 0.00000000
68 -0.25032807 0.23658123 0.00000000 0.00000000 0.01900492
69 0.00000000 0.00000000 -0.93204074 -0.00436133 0.00000000
70 -0.21368712 0.39537514 0.00000000 0.00000000 0.00000000
16 17 18 19 20
1 0.00000000 0.04985525 0.00000000 0.00000000 0.00000000
2 0.00000000 -0.54297374 0.00000000 0.00000000 0.00000000
3 0.00000000 -1.50318266 0.00000000 0.00000000 0.00000000
4 0.00000000 0.38283704 0.00000000 0.00000000 0.00000000
5 0.00000000 0.00000000 -0.12139841 1.29312757 0.25669383
6 0.00000000 0.00000000 1.29312757 0.12139841 0.06593879
7 0.00000000 0.99273275 0.00000000 0.00000000 0.00000000
8 0.00000000 0.00000000 0.38853919 -4.13869281 -1.20672620
9 0.00000000 0.00000000 -4.13869281 -0.38853919 -0.30998044
10 0.00000000 -4.26211619 0.00000000 0.00000000 0.00000000
11 0.00000000 0.00000000 -0.21565170 2.29710715 0.20678416
12 0.00000000 0.00000000 2.29710715 0.21565170 0.05311813
13 0.00000000 1.80162813 0.00000000 0.00000000 0.00000000
14 -0.00010180 0.04165619 0.00000000 0.00000000 0.00000000
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54 0.00000001 -3.90878488 -1.75911070 3.09637150 -3.79433011
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57 -1.31226447 -0.00000000 0.00000000 0.00000000 0.00000000
58 0.00000001 -5.19395370 3.65490765 3.04152189 -2.97981593
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60 0.00000004 -22.03301746 8.49152181 1.73989352 0.75707903
61 -0.13646386 -0.00000000 0.00000000 0.00000000 0.00000000
62 0.05244026 0.00000000 0.00000000 0.00000000 0.00000000
63 0.00000003 -12.96116503 6.90447213 -0.31868637 1.31878648
64 -0.06102849 -0.00000000 0.00000000 0.00000000 0.00000000
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67 0.11725999 0.00000000 0.00000000 0.00000000 0.00000000
68 0.00000003 -12.96116503 6.90447213 -0.31868637 1.31878648
69 -1.15512032 -0.00000000 0.00000000 0.00000000 0.00000000
70 0.00000005 -25.04677534 15.90142563 0.87404201 3.00819982
-----------------------------------------
UHF spin-down orbital coefficients
-----------------------------------------
1 2 3 4 5
1 -0.86327537 0.37233458 0.00802620 0.00000000 0.00000000
2 0.04106325 0.69778714 -0.14262870 0.00000000 0.00000000
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17 -0.00092387 0.00393248 -0.01278552 0.00000000 0.00000000
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19 -0.00294645 0.02890564 -0.02146625 0.00000000 0.00000000
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16 17 18 19 20
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36 0.00000001 -2.66393737 4.37012330 60.39209287 -60.93064276
37 0.00000012 -60.31054942 14.77252088 -27.03398297 40.55371986
38 0.00000001 -7.01246486 -7.43409654 -33.79792641 43.84975821
39 0.00000000 -0.35107957 -0.58107162 -17.39240006 16.67805027
40 0.53164918 0.00000000 0.00000000 0.00000000 0.00000000
41 -0.35759600 -0.00000000 0.00000000 0.00000000 0.00000000
42 0.00000003 -17.08505255 12.51859257 -0.66687960 2.68223947
43 1.85250257 0.00000000 0.00000000 0.00000000 0.00000000
44 -1.24602375 -0.00000000 0.00000000 0.00000000 0.00000000
45 -0.00000019 97.08998041 -43.75736597 0.74003415 -14.45336965
46 0.53660404 0.00000000 0.00000000 0.00000000 0.00000000
47 -0.36092872 -0.00000000 0.00000000 0.00000000 0.00000000
48 -0.00000001 6.76736358 0.48824731 0.51637976 -3.63209016
49 -0.00000000 0.36423290 0.70702008 3.72561192 -3.74584765
50 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
51 -1.66467331 -0.00000000 0.00000000 0.00000000 0.00000000
52 -0.00000000 0.36423290 0.70702008 3.72561192 -3.74584765
53 1.11968670 0.00000000 0.00000000 0.00000000 0.00000000
54 0.00000001 -3.90878489 -1.75911071 3.09637134 -3.79433023
55 0.00000001 -5.19395370 3.65490765 3.04152177 -2.97981606
56 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
57 -1.43563945 -0.00000000 0.00000000 0.00000000 0.00000000
58 0.00000001 -5.19395370 3.65490765 3.04152177 -2.97981606
59 0.96563475 0.00000000 0.00000000 0.00000000 0.00000000
60 0.00000004 -22.03301747 8.49152181 1.73989355 0.75707896
61 -0.14929376 -0.00000000 0.00000000 0.00000000 0.00000000
62 0.04490805 0.00000000 0.00000000 0.00000000 0.00000000
63 0.00000002 -12.96116503 6.90447213 -0.31868632 1.31878650
64 -0.06676620 -0.00000000 0.00000000 0.00000000 0.00000000
65 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
66 1.47068285 0.00000000 0.00000000 0.00000000 0.00000000
67 0.10041744 0.00000000 0.00000000 0.00000000 0.00000000
68 0.00000002 -12.96116503 6.90447213 -0.31868632 1.31878650
69 -0.98920552 -0.00000000 0.00000000 0.00000000 0.00000000
70 0.00000005 -25.04677534 15.90142563 0.87404213 3.00819978
---------------------------------------
UHF spin-up orbital energies
---------------------------------------
1
1 -0.60758125
2 0.14819760
3 0.20758938
4 0.46278682
5 0.46278682
6 0.50343499
7 0.75471898
8 0.77085714
9 0.77085714
10 1.04165639
11 1.06999743
12 1.36572231
13 1.70225100
14 1.70225100
15 1.94955745
16 1.94955745
17 2.07096672
18 2.20314219
19 2.20314219
20 2.55708634
21 2.55708634
22 2.56687633
23 2.56687633
24 2.65031013
25 2.91249267
26 3.29399535
27 3.32115952
28 3.32115952
29 3.45469352
30 4.23553916
31 4.23553916
32 4.55197907
33 4.98216809
34 4.98216809
35 5.13907392
36 5.70176510
37 5.70176510
38 6.34796525
39 6.34796525
40 6.81188906
41 6.81188906
42 7.28106270
43 7.28106270
44 7.41102610
45 7.52313132
46 7.52313132
47 7.68877352
48 7.87124063
49 7.87124063
50 7.97505489
51 7.97505489
52 8.33960909
53 8.33960909
54 8.84018960
55 9.46474110
56 9.48731852
57 9.48731852
58 9.76964348
59 9.85120631
60 9.85120631
61 9.91248321
62 9.91248321
63 10.18955009
64 12.84517856
65 13.23026954
66 13.23026954
67 13.23166855
68 16.86864502
69 26.31051881
70 26.72365176
---------------------------------------
UHF spin-down orbital energies
---------------------------------------
1
1 -0.60758125
2 0.14819760
3 0.20758938
4 0.46278682
5 0.46278682
6 0.50343499
7 0.75471898
8 0.77085714
9 0.77085714
10 1.04165639
11 1.06999743
12 1.36572231
13 1.70225100
14 1.70225100
15 1.94955745
16 1.94955745
17 2.07096672
18 2.20314219
19 2.20314219
20 2.55708634
21 2.55708634
22 2.56687633
23 2.56687633
24 2.65031013
25 2.91249267
26 3.29399535
27 3.32115952
28 3.32115952
29 3.45469352
30 4.23553916
31 4.23553916
32 4.55197907
33 4.98216809
34 4.98216809
35 5.13907392
36 5.70176510
37 5.70176510
38 6.34796525
39 6.34796525
40 6.81188906
41 6.81188906
42 7.28106270
43 7.28106270
44 7.41102610
45 7.52313132
46 7.52313132
47 7.68877352
48 7.87124063
49 7.87124063
50 7.97505489
51 7.97505489
52 8.33960909
53 8.33960909
54 8.84018960
55 9.46474110
56 9.48731852
57 9.48731852
58 9.76964348
59 9.85120631
60 9.85120631
61 9.91248321
62 9.91248321
63 10.18955009
64 12.84517856
65 13.23026954
66 13.23026954
67 13.23166855
68 16.86864502
69 26.31051881
70 26.72365176
Total CPU time for UHF = 3.053 seconds
AO to MO transformation... Please be patient
Total CPU time for AO to MO transformation = 15.346 seconds
************************************************
| Configuration Interaction Singles |
************************************************
-------------------------------------------------------------
UCIS calculation: spin-conserved manifold
-------------------------------------------------------------
| State | Excitation energy (au) | Excitation energy (eV) |
-------------------------------------------------------------
| 1 | 0.391504 | 10.653380 |
| 2 | 0.496543 | 13.511618 |
| 3 | 0.505136 | 13.745456 |
| 4 | 0.584000 | 15.891444 |
| 5 | 0.618260 | 16.823707 |
| 6 | 0.618260 | 16.823707 |
| 7 | 0.712153 | 19.378671 |
| 8 | 0.741616 | 20.180399 |
| 9 | 0.741616 | 20.180399 |
| 10 | 0.835845 | 22.744505 |
| 11 | 0.979844 | 26.662906 |
| 12 | 0.999546 | 27.199024 |
| 13 | 0.999546 | 27.199024 |
| 14 | 1.029755 | 28.021050 |
| 15 | 1.033184 | 28.114375 |
| 16 | 1.033184 | 28.114375 |
| 17 | 1.200464 | 32.666282 |
| 18 | 1.313383 | 35.738974 |
| 19 | 1.338849 | 36.431938 |
| 20 | 1.352919 | 36.814800 |
-------------------------------------------------------------
---------------------------------------------------------------
Transition dipole moment (au)
---------------------------------------------------------------
# X Y Z dip. str. osc. str.
---------------------------------------------------------------
1 -0.000000 -0.000000 -0.000000 0.000000 0.000000
2 -0.000000 -0.000000 -0.000004 0.000000 0.000000
3 0.000000 0.000000 1.173742 1.377671 0.463941
4 0.000000 -0.000000 -0.000000 0.000000 0.000000
5 0.000000 -0.000000 -0.000000 0.000000 0.000000
6 0.000000 0.000000 -0.000000 0.000000 0.000000
7 0.000000 -0.000000 -0.000000 0.000000 0.000000
8 0.472645 -1.074813 -0.000000 1.378617 0.681603
9 1.074813 0.472645 -0.000000 1.378617 0.681603
10 -0.000000 0.000000 -0.719908 0.518268 0.288794
11 -0.000000 -0.000000 0.000000 0.000000 0.000000
12 0.000000 -0.000000 -0.000000 0.000000 0.000000
13 0.000000 0.000000 0.000000 0.000000 0.000000
14 -0.000000 0.000000 0.000000 0.000000 0.000000
15 -0.000000 0.000000 -0.000000 0.000000 0.000000
16 0.000000 0.000000 -0.000000 0.000000 0.000000
17 0.000000 0.000000 0.000000 0.000000 0.000000
18 -0.000000 0.000000 -0.000000 0.000000 0.000000
19 0.000000 0.000000 0.000000 0.000000 0.000000
20 -0.000000 0.000000 0.003820 0.000015 0.000013
---------------------------------------------------------------
-------------------------------------------------------------
Excitation n. 1: 10.653380 eV f = 0.0000 <S**2> = 2.0000
-------------------------------------------------------------
1A -> 2A = -0.634622
1A -> 6A = -0.304220
1B -> 2B = -0.634622
1B -> 6B = -0.304220
-------------------------------------------------------------
Excitation n. 2: 13.511618 eV f = 0.0000 <S**2> = 2.0000
-------------------------------------------------------------
1A -> 3A = 0.695854
1A -> 10A = -0.102776
1B -> 3B = 0.695854
1B -> 10B = -0.102776
-------------------------------------------------------------
Excitation n. 3: 13.745456 eV f = 0.4639 <S**2> = 0.0000
-------------------------------------------------------------
1A -> 2A = -0.702979
1B -> 2B = 0.702979
-------------------------------------------------------------
Excitation n. 4: 15.891444 eV f = 0.0000 <S**2> = 0.0000
-------------------------------------------------------------
1A -> 3A = 0.706729
1B -> 3B = -0.706729
-------------------------------------------------------------
Excitation n. 5: 16.823707 eV f = 0.0000 <S**2> = 2.0000
-------------------------------------------------------------
1A -> 4A = -0.694728
1A -> 5A = -0.108888
1B -> 4B = 0.701675
-------------------------------------------------------------
Excitation n. 6: 16.823707 eV f = 0.0000 <S**2> = 2.0000
-------------------------------------------------------------
1A -> 4A = 0.108888
1A -> 5A = -0.694728
1B -> 5B = -0.701675
-------------------------------------------------------------
Excitation n. 7: 19.378671 eV f = 0.0000 <S**2> = 2.0000
-------------------------------------------------------------
1A -> 2A = 0.311724
1A -> 6A = -0.623136
1A -> 12A = 0.116035
1B -> 2B = 0.311724
1B -> 6B = -0.623136
1B -> 12B = 0.116035
-------------------------------------------------------------
Excitation n. 8: 20.180399 eV f = 0.6816 <S**2> = 0.0000
-------------------------------------------------------------
1A -> 4A = 0.684927
1A -> 5A = 0.175106
1B -> 4B = 0.706664
-------------------------------------------------------------
Excitation n. 9: 20.180399 eV f = 0.6816 <S**2> = 0.0000
-------------------------------------------------------------
1A -> 4A = -0.175106
1A -> 5A = 0.684927
1B -> 5B = -0.706664
-------------------------------------------------------------
Excitation n. 10: 22.744505 eV f = 0.2888 <S**2> = 0.0000
-------------------------------------------------------------
1A -> 6A = 0.702492
1B -> 6B = -0.702492
-------------------------------------------------------------
Excitation n. 11: 26.662906 eV f = 0.0000 <S**2> = 2.0000
-------------------------------------------------------------
1A -> 7A = -0.701040
1B -> 7B = 0.701040
-------------------------------------------------------------
Excitation n. 12: 27.199024 eV f = 0.0000 <S**2> = 2.0000
-------------------------------------------------------------
1A -> 8A = 0.698517
1A -> 9A = -0.100053
1B -> 8B = 0.702357
-------------------------------------------------------------
Excitation n. 13: 27.199024 eV f = 0.0000 <S**2> = 2.0000
-------------------------------------------------------------
1A -> 8A = -0.100053
1A -> 9A = -0.698517
1B -> 9B = -0.702357
-------------------------------------------------------------
Excitation n. 14: 28.021050 eV f = 0.0000 <S**2> = 0.0000
-------------------------------------------------------------
1A -> 7A = -0.702959
1B -> 7B = -0.702959
-------------------------------------------------------------
Excitation n. 15: 28.114375 eV f = 0.0000 <S**2> = 0.0000
-------------------------------------------------------------
1A -> 8A = -0.706171
1B -> 8B = 0.706534
-------------------------------------------------------------
Excitation n. 16: 28.114375 eV f = 0.0000 <S**2> = 0.0000
-------------------------------------------------------------
1A -> 9A = -0.706171
1B -> 9B = 0.706534
-------------------------------------------------------------
Excitation n. 17: 32.666282 eV f = 0.0000 <S**2> = 2.0000
-------------------------------------------------------------
1A -> 3A = -0.103268
1A -> 10A = -0.697158
1B -> 3B = -0.103268
1B -> 10B = -0.697158
-------------------------------------------------------------
Excitation n. 18: 35.738974 eV f = 0.0000 <S**2> = 0.0000
-------------------------------------------------------------
1A -> 10A = -0.703035
1B -> 10B = 0.703035
-------------------------------------------------------------
Excitation n. 19: 36.431938 eV f = 0.0000 <S**2> = 2.0000
-------------------------------------------------------------
1A -> 11A = 0.703847
1B -> 11B = -0.703847
-------------------------------------------------------------
Excitation n. 20: 36.814800 eV f = 0.0000 <S**2> = 0.0000
-------------------------------------------------------------
1A -> 11A = -0.706561
1B -> 11B = -0.706561
Thomas-Reiche-Kuhn sum rule = 2.115954
Total CPU time for CIS = 0.007 seconds
Total CPU time for QuAcK = 19.635 seconds