374 lines
16 KiB
Plaintext
374 lines
16 KiB
Plaintext
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Running Job 1 of 1 h2_0,65.inp
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qchem h2_0,65.inp_14581.0 /mnt/beegfs/tmpdir/qchem14581/ 0
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/share/apps/common/q-chem/5.2.1/exe/qcprog.exe_s h2_0,65.inp_14581.0 /mnt/beegfs/tmpdir/qchem14581/
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Welcome to Q-Chem
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A Quantum Leap Into The Future Of Chemistry
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Q-Chem 5.2, Q-Chem, Inc., Pleasanton, CA (2019)
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Yihan Shao, Zhengting Gan, E. Epifanovsky, A. T. B. Gilbert, M. Wormit,
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J. Kussmann, A. W. Lange, A. Behn, Jia Deng, Xintian Feng, D. Ghosh,
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M. Goldey, P. R. Horn, L. D. Jacobson, I. Kaliman, T. Kus, A. Landau,
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Jie Liu, E. I. Proynov, R. M. Richard, R. P. Steele, E. J. Sundstrom,
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H. L. Woodcock III, P. M. Zimmerman, D. Zuev, B. Albrecht, E. Alguire,
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S. A. Baeppler, D. Barton, Z. Benda, Y. A. Bernard, E. J. Berquist,
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K. B. Bravaya, H. Burton, D. Casanova, Chun-Min Chang, Yunqing Chen,
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A. Chien, K. D. Closser, M. P. Coons, S. Coriani, S. Dasgupta,
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A. L. Dempwolff, M. Diedenhofen, Hainam Do, R. G. Edgar, Po-Tung Fang,
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S. Faraji, S. Fatehi, Qingguo Feng, K. D. Fenk, J. Fosso-Tande,
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J. Gayvert, Qinghui Ge, A. Ghysels, G. Gidofalvi, J. Gomes,
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J. Gonthier, A. Gunina, D. Hait, M. W. D. Hanson-Heine,
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P. H. P. Harbach, A. W. Hauser, M. F. Herbst, J. E. Herr,
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E. G. Hohenstein, Z. C. Holden, Kerwin Hui, B. C. Huynh, T.-C. Jagau,
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Hyunjun Ji, B. Kaduk, K. Khistyaev, Jaehoon Kim, P. Klunzinger, K. Koh,
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D. Kosenkov, L. Koulias, T. Kowalczyk, C. M. Krauter, A. Kunitsa,
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Ka Un Lao, A. Laurent, K. V. Lawler, Joonho Lee, D. Lefrancois,
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S. Lehtola, D. S. Levine, Yi-Pei Li, You-Sheng Lin, Fenglai Liu,
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E. Livshits, A. Luenser, P. Manohar, E. Mansoor, S. F. Manzer,
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Shan-Ping Mao, Yuezhi Mao, N. Mardirossian, A. V. Marenich,
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T. Markovich, L. A. Martinez-Martinez, S. A. Maurer, N. J. Mayhall,
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S. C. McKenzie, J.-M. Mewes, P. Morgante, A. F. Morrison,
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J. W. Mullinax, K. Nanda, T. S. Nguyen-Beck, R. Olivares-Amaya,
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J. A. Parkhill, Zheng Pei, T. M. Perrine, F. Plasser, P. Pokhilko,
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S. Prager, A. Prociuk, E. Ramos, D. R. Rehn, F. Rob, M. Scheurer,
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M. Schneider, N. Sergueev, S. M. Sharada, S. Sharma, D. W. Small,
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T. Stauch, T. Stein, Yu-Chuan Su, A. J. W. Thom, A. Tkatchenko,
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T. Tsuchimochi, N. M. Tubman, L. Vogt, M. L. Vidal, O. Vydrov,
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M. A. Watson, J. Wenzel, M. de Wergifosse, T. A. Wesolowski, A. White,
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J. Witte, A. Yamada, Jun Yang, K. Yao, S. Yeganeh, S. R. Yost,
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Zhi-Qiang You, A. Zech, Igor Ying Zhang, Xing Zhang, Yan Zhao,
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Ying Zhu, B. R. Brooks, G. K. L. Chan, C. J. Cramer, M. S. Gordon,
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W. J. Hehre, A. Klamt, M. W. Schmidt, C. D. Sherrill, D. G. Truhlar,
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A. Aspuru-Guzik, R. Baer, A. T. Bell, N. A. Besley, Jeng-Da Chai,
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A. E. DePrince, III, R. A. DiStasio Jr., A. Dreuw, B. D. Dunietz,
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T. R. Furlani, Chao-Ping Hsu, Yousung Jung, Jing Kong, D. S. Lambrecht,
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WanZhen Liang, C. Ochsenfeld, V. A. Rassolov, L. V. Slipchenko,
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J. E. Subotnik, T. Van Voorhis, J. M. Herbert, A. I. Krylov,
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P. M. W. Gill, M. Head-Gordon
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Contributors to earlier versions of Q-Chem not listed above:
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R. D. Adamson, B. Austin, J. Baker, G. J. O. Beran, K. Brandhorst,
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S. T. Brown, E. F. C. Byrd, A. K. Chakraborty, C.-L. Cheng,
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Siu Hung Chien, D. M. Chipman, D. L. Crittenden, H. Dachsel,
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R. J. Doerksen, A. D. Dutoi, L. Fusti-Molnar, W. A. Goddard III,
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A. Golubeva-Zadorozhnaya, S. R. Gwaltney, G. Hawkins, A. Heyden,
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S. Hirata, G. Kedziora, F. J. Keil, C. Kelley, Jihan Kim, R. A. King,
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R. Z. Khaliullin, P. P. Korambath, W. Kurlancheek, A. M. Lee, M. S. Lee,
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S. V. Levchenko, Ching Yeh Lin, D. Liotard, R. C. Lochan, I. Lotan,
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P. E. Maslen, N. Nair, D. P. O'Neill, D. Neuhauser, E. Neuscamman,
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C. M. Oana, R. Olson, B. Peters, R. Peverati, P. A. Pieniazek,
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Y. M. Rhee, J. Ritchie, M. A. Rohrdanz, E. Rosta, N. J. Russ,
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H. F. Schaefer III, N. E. Schultz, N. Shenvi, A. C. Simmonett, A. Sodt,
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D. Stuck, K. S. Thanthiriwatte, V. Vanovschi, Tao Wang, A. Warshel,
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C. F. Williams, Q. Wu, X. Xu, W. Zhang
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Please cite Q-Chem as follows:
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Y. Shao et al., Mol. Phys. 113, 184-215 (2015)
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DOI: 10.1080/00268976.2014.952696
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Q-Chem 5.2.1 for Intel X86 EM64T Linux
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Parts of Q-Chem use Armadillo 8.300.2 (Tropical Shenanigans).
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http://arma.sourceforge.net/
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Q-Chem begins on Thu Dec 17 15:25:06 2020
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Host:
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0
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Scratch files written to /mnt/beegfs/tmpdir/qchem14581//
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Jul1719 |scratch|qcdevops|jenkins|workspace|build_RNUM 6358
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Processing $rem in /share/apps/common/q-chem/5.2.1/config/preferences:
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MEM_TOTAL 5000
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NAlpha2: 4
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NElect 2
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Mult 3
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Checking the input file for inconsistencies... ...done.
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--------------------------------------------------------------
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User input:
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--------------------------------------------------------------
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$comment
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SF-TDDFT
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$end
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$molecule
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0 3
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H 0 0 0
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H 0 0 0.65
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$end
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$rem
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JOBTYPE = sp
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METHOD = B3LYP
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BASIS = CC-PVQZ
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PURECART = 2222
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SCF_CONVERGENCE = 9
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THRESH = 12
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MAX_SCF_CYCLES = 100
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MAX_CIS_CYCLES = 100
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SPIN_FLIP = TRUE
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UNRESTRICTED = TRUE
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CIS_N_ROOTS = 16
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RPA = FALSE
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$end
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--------------------------------------------------------------
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----------------------------------------------------------------
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Standard Nuclear Orientation (Angstroms)
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I Atom X Y Z
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----------------------------------------------------------------
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1 H 0.0000000000 0.0000000000 -0.3250000000
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2 H 0.0000000000 0.0000000000 0.3250000000
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----------------------------------------------------------------
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Molecular Point Group D*h NOp =***
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Largest Abelian Subgroup D2h NOp = 1
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Nuclear Repulsion Energy = 0.81411879 hartrees
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There are 2 alpha and 0 beta electrons
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Q-Chem warning in module forms1/BasisType.C, line 1983:
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You are not using the predefined 5D/6D in this basis set.
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Requested basis set is cc-pVQZ
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There are 20 shells and 70 basis functions
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Total QAlloc Memory Limit 5000 MB
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Mega-Array Size 188 MB
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MEM_STATIC part 192 MB
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Distance Matrix (Angstroms)
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H ( 1)
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H ( 2) 0.650000
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A cutoff of 1.0D-12 yielded 210 shell pairs
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There are 2653 function pairs
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Smallest overlap matrix eigenvalue = 1.59E-05
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Scale SEOQF with 1.000000e+00/1.000000e+00/1.000000e+00
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Standard Electronic Orientation quadrupole field applied
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Nucleus-field energy = -0.0000000002 hartrees
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Guess from superposition of atomic densities
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Warning: Energy on first SCF cycle will be non-variational
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SAD guess density has 0.090382 electrons
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-----------------------------------------------------------------------
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General SCF calculation program by
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Eric Jon Sundstrom, Paul Horn, Yuezhi Mao, Dmitri Zuev, Alec White,
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David Stuck, Shaama M.S., Shane Yost, Joonho Lee, David Small,
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Daniel Levine, Susi Lehtola, Hugh Burton, Evgeny Epifanovsky,
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Bang C. Huynh
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-----------------------------------------------------------------------
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Exchange: 0.2000 Hartree-Fock + 0.0800 Slater + 0.7200 B88
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Correlation: 0.1900 VWN1RPA + 0.8100 LYP
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Using SG-1 standard quadrature grid
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A unrestricted SCF calculation will be
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performed using DIIS
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SCF converges when DIIS error is below 1.0e-09
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---------------------------------------
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Cycle Energy DIIS error
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---------------------------------------
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1 0.6842867615 1.06e-03
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2 3.0766188700 7.84e-02
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3 3.0712536007 7.84e-02
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4 3.0705701910 7.83e-02
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5 3.0677760540 7.83e-02
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6 3.0670720219 7.83e-02
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7 3.0669779245 7.83e-02
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8 3.0664636645 7.83e-02
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9 3.0618507626 7.83e-02
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10 3.0397661875 7.82e-02
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11 3.0328297578 7.81e-02
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12 3.0414798577 7.82e-02
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13 3.0078399471 7.79e-02
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14 3.0080868927 7.79e-02
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15 2.9378324662 7.74e-02
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16 2.1068665300 7.09e-02
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17 -0.5899609139 3.31e-03
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18 -0.7217428518 1.27e-03
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19 -0.7333472432 3.57e-04
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20 -0.7349362001 6.34e-05
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21 -0.7350324006 1.97e-05
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22 -0.7350411647 2.29e-06
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23 -0.7350412720 2.12e-07
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24 -0.7350412727 2.28e-08
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25 -0.7350412727 1.91e-09
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26 -0.7350412727 1.20e-10 Convergence criterion met
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---------------------------------------
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SCF time: CPU 3.57s wall 5.00s
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<S^2> = 2.000000000
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SCF energy in the final basis set = -0.7350412727
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Total energy in the final basis set = -0.7350412727
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Spin-flip DFT calculation will be performed
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CIS energy converged when residual is below 10e- 6
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---------------------------------------------------
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Iter Rts Conv Rts Left Ttl Dev Max Dev
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---------------------------------------------------
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1 0 16 0.018511 0.002253
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2 0 16 0.000360 0.000072
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3 15 1 0.000004 0.000001
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4 16 0 0.000002 0.000000 Roots Converged
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---------------------------------------------------
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---------------------------------------------------
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SF-DFT Excitation Energies
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(The first "excited" state might be the ground state)
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---------------------------------------------------
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Excited state 1: excitation energy (eV) = -4.4548
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Total energy for state 1: -0.89875175 au
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<S**2> : 0.0536
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S( 2) --> S( 1) amplitude = 0.9995 alpha
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Excited state 2: excitation energy (eV) = 5.4572
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Total energy for state 2: -0.53449342 au
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<S**2> : 1.0698
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S( 2) --> S( 2) amplitude = 0.9982 alpha
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Excited state 3: excitation energy (eV) = 6.6893
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Total energy for state 3: -0.48921402 au
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<S**2> : 0.9607
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S( 2) --> V( 1) amplitude = 0.9994 alpha
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Excited state 4: excitation energy (eV) = 11.3487
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Total energy for state 4: -0.31798575 au
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<S**2> : 1.0009
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S( 1) --> S( 1) amplitude = 0.9899 alpha
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Excited state 5: excitation energy (eV) = 12.0939
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Total energy for state 5: -0.29060038 au
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<S**2> : 1.0000
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S( 2) --> V( 3) amplitude = 0.9999 alpha
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Excited state 6: excitation energy (eV) = 12.0939
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Total energy for state 6: -0.29060038 au
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<S**2> : 1.0000
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S( 2) --> V( 2) amplitude = 0.9999 alpha
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Excited state 7: excitation energy (eV) = 14.8140
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Total energy for state 7: -0.19063809 au
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<S**2> : 0.9311
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S( 2) --> V( 4) amplitude = 0.9933 alpha
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Excited state 8: excitation energy (eV) = 21.0116
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Total energy for state 8: 0.03712113 au
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<S**2> : 1.0000
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S( 2) --> V( 6) amplitude = 0.9995 alpha
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Excited state 9: excitation energy (eV) = 21.0116
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Total energy for state 9: 0.03712113 au
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<S**2> : 1.0000
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S( 2) --> V( 5) amplitude = 0.9995 alpha
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Excited state 10: excitation energy (eV) = 21.1709
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Total energy for state 10: 0.04297502 au
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<S**2> : 0.9825
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S( 2) --> V( 7) amplitude = 0.9910 alpha
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Excited state 11: excitation energy (eV) = 22.7888
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Total energy for state 11: 0.10243032 au
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<S**2> : 0.1142
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S( 1) --> S( 2) amplitude = 0.9883 alpha
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Excited state 12: excitation energy (eV) = 23.7397
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Total energy for state 12: 0.13737528 au
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<S**2> : 1.0004
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S( 1) --> V( 1) amplitude = 0.9958 alpha
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Excited state 13: excitation energy (eV) = 27.2133
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Total energy for state 13: 0.26502925 au
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<S**2> : 0.9878
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S( 2) --> V( 8) amplitude = 0.9998 alpha
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Excited state 14: excitation energy (eV) = 28.8613
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Total energy for state 14: 0.32559326 au
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<S**2> : 1.0000
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S( 1) --> V( 3) amplitude = 0.9992 alpha
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Excited state 15: excitation energy (eV) = 28.8613
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Total energy for state 15: 0.32559326 au
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<S**2> : 1.0000
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S( 1) --> V( 2) amplitude = 0.9992 alpha
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Excited state 16: excitation energy (eV) = 29.4348
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Total energy for state 16: 0.34666794 au
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<S**2> : 1.0000
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S( 2) --> V( 9) amplitude = 0.9997 alpha
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---------------------------------------------------
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SETman timing summary (seconds)
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CPU time 0.76s
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System time 0.00s
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Wall time 1.59s
|
||
|
|
|
||
|
|
--------------------------------------------------------------
|
||
|
|
|
||
|
|
Orbital Energies (a.u.)
|
||
|
|
--------------------------------------------------------------
|
||
|
|
|
||
|
|
Alpha MOs
|
||
|
|
-- Occupied --
|
||
|
|
-0.7327 -0.0922
|
||
|
|
-- Virtual --
|
||
|
|
0.0561 0.2223 0.2223 0.2541 0.5313 0.5540 0.5540 0.7637
|
||
|
|
0.8848 1.0425 1.3369 1.3369 1.5823 1.5823 1.7363 1.8729
|
||
|
|
1.8729 2.2237 2.2237 2.2291 2.2291 2.3516 2.4634 2.8295
|
||
|
|
3.0536 3.0536 3.1085 3.7505 3.7505 4.1584 4.6593 4.6593
|
||
|
|
4.7584 5.1822 5.1822 5.9085 5.9085 6.3874 6.3874 6.8124
|
||
|
|
6.8238 6.8238 6.9002 6.9002 7.0671 7.2397 7.2397 7.3395
|
||
|
|
7.3397 7.9730 7.9730 8.1449 8.8362 9.2291 9.2296 9.2541
|
||
|
|
9.2541 9.2906 9.3276 9.3276 9.5954 12.4633 12.9438 13.0716
|
||
|
|
13.0716 16.5311 26.0672 27.5446
|
||
|
|
--------------------------------------------------------------
|
||
|
|
|
||
|
|
Ground-State Mulliken Net Atomic Charges
|
||
|
|
|
||
|
|
Atom Charge (a.u.) Spin (a.u.)
|
||
|
|
--------------------------------------------------------
|
||
|
|
1 H -0.000000 1.000000
|
||
|
|
2 H 0.000000 1.000000
|
||
|
|
--------------------------------------------------------
|
||
|
|
Sum of atomic charges = 0.000000
|
||
|
|
Sum of spin charges = 2.000000
|
||
|
|
|
||
|
|
-----------------------------------------------------------------
|
||
|
|
Cartesian Multipole Moments
|
||
|
|
-----------------------------------------------------------------
|
||
|
|
Charge (ESU x 10^10)
|
||
|
|
0.0000
|
||
|
|
Dipole Moment (Debye)
|
||
|
|
X -0.0000 Y 0.0000 Z 0.0000
|
||
|
|
Tot 0.0000
|
||
|
|
Quadrupole Moments (Debye-Ang)
|
||
|
|
XX -3.2209 XY 0.0000 YY -3.2209
|
||
|
|
XZ -0.0000 YZ -0.0000 ZZ -8.0131
|
||
|
|
Octopole Moments (Debye-Ang^2)
|
||
|
|
XXX -0.0000 XXY 0.0000 XYY -0.0000
|
||
|
|
YYY 0.0000 XXZ 0.0000 XYZ 0.0000
|
||
|
|
YYZ 0.0000 XZZ -0.0000 YZZ 0.0000
|
||
|
|
ZZZ 0.0000
|
||
|
|
Hexadecapole Moments (Debye-Ang^3)
|
||
|
|
XXXX -5.5706 XXXY 0.0000 XXYY -1.8569
|
||
|
|
XYYY 0.0000 YYYY -5.5706 XXXZ -0.0000
|
||
|
|
XXYZ -0.0000 XYYZ -0.0000 YYYZ -0.0000
|
||
|
|
XXZZ -5.5040 XYZZ 0.0000 YYZZ -5.5040
|
||
|
|
XZZZ -0.0000 YZZZ -0.0000 ZZZZ -28.2710
|
||
|
|
-----------------------------------------------------------------
|
||
|
|
Archival summary:
|
||
|
|
1\1\lcpq-curie.ups-tlse.fr\SP\ProcedureUnspecified\BasisUnspecified\2(3)\emonino\ThuDec1715:25:142020ThuDec1715:25:142020\0\\#,ProcedureUnspecified,BasisUnspecified,\\0,3\H\H,1,0.65\\\@
|
||
|
|
|
||
|
|
Total job time: 8.08s(wall), 4.44s(cpu)
|
||
|
|
Thu Dec 17 15:25:14 2020
|
||
|
|
|
||
|
|
*************************************************************
|
||
|
|
* *
|
||
|
|
* Thank you very much for using Q-Chem. Have a nice day. *
|
||
|
|
* *
|
||
|
|
*************************************************************
|
||
|
|
|
||
|
|
|