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8b22e38c9c
* fixed laplacian of aos * corrected the laplacians of aos * added dft_one_e * added new feature for new dft functionals * changed the configure to add new functionals * changed the configure * added dft_one_e/README.rst * added README.rst in new_functionals * added source/programmers_guide/new_ks.rst * Thesis Yann * Added gmp installation in configure * improved qp_e_conv_fci * Doc * Typos * Added variance_max * Fixed completion in qp_create * modif TODO * fixed DFT potential for n_states gt 1 * improved pot pbe * trying to improve sr PBE * fixed potential pbe * fixed the vxc smashed for pbe sr and normal * Comments in selection * bug fixed by peter * Fixed bug with zero beta electrons * Update README.rst * Update e_xc_new_func.irp.f * Update links.rst * Update quickstart.rst * Update quickstart.rst * updated cipsi * Fixed energies of non-expected s2 (#9) * Moved diag_algorithm in Davdison * Add print_ci_vector in tools (#11) * Fixed energies of non-expected s2 * Moved diag_algorithm in Davdison * Fixed travis * Added print_ci_vector * Documentation * Cleaned qp_set_mo_class.ml * Removed Core in taskserver * Merge develop-toto and manus (#12) * Fixed energies of non-expected s2 * Moved diag_algorithm in Davdison * Fixed travis * Added print_ci_vector * Documentation * Cleaned qp_set_mo_class.ml * Removed Core in taskserver * Frozen core for heavy atoms * Improved molden module * In sync with manus * Fixed some of the documentation errors * Develop toto (#13) * Fixed energies of non-expected s2 * Moved diag_algorithm in Davdison * Fixed travis * Added print_ci_vector * Documentation * Cleaned qp_set_mo_class.ml * Removed Core in taskserver * Frozen core for heavy atoms * Improved molden module * In sync with manus * Fixed some of the documentation errors * Develop manus (#14) * modified printing for rpt2 * Comment * Fixed plugins * Scripting for functionals * Documentation * Develop (#10) * fixed laplacian of aos * corrected the laplacians of aos * added dft_one_e * added new feature for new dft functionals * changed the configure to add new functionals * changed the configure * added dft_one_e/README.rst * added README.rst in new_functionals * added source/programmers_guide/new_ks.rst * Thesis Yann * Added gmp installation in configure * improved qp_e_conv_fci * Doc * Typos * Added variance_max * Fixed completion in qp_create * modif TODO * fixed DFT potential for n_states gt 1 * improved pot pbe * trying to improve sr PBE * fixed potential pbe * fixed the vxc smashed for pbe sr and normal * Comments in selection * bug fixed by peter * Fixed bug with zero beta electrons * Update README.rst * Update e_xc_new_func.irp.f * Update links.rst * Update quickstart.rst * Update quickstart.rst * updated cipsi * Fixed energies of non-expected s2 (#9) * Moved diag_algorithm in Davdison * some modifs * modified gfortran_debug.cfg * fixed automatization of functionals * modified e_xc_general.irp.f * minor modifs in ref_bitmask.irp.f * modifying functionals * rs_ks_scf and ks_scf compiles with the automatic handling of functionals * removed prints * fixed configure * fixed the new functionals * Merge toto * modified automatic functionals * Changed python into python2 * from_xyz suppressed * Cleaning repo * Update README.md * Update README.md * Contributors * Update GITHUB.md * bibtex
816 lines
15 KiB
ReStructuredText
816 lines
15 KiB
ReStructuredText
.. _module_mo_basis:
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.. program:: mo_basis
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.. default-role:: option
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========
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mo_basis
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========
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Molecular orbitals are expressed as
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.. math::
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\phi_k({\bf r}) = \sum_i C_{ik} \chi_k({\bf r})
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where :math:`\chi_k` are *normalized* atomic basis functions.
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The current set of |MOs| has a label `mo_label`.
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When the orbitals are modified, the label should also be updated to keep
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everything consistent.
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When saving the |MOs|, the :file:`mo_basis` directory of the |EZFIO| database
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is copied in the :file:`save` directory, named by the current `mo_label`. All
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this is done with the script named :file:`save_current_mos.sh` in the
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:file:`$QP_ROOT/scripts` directory.
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EZFIO parameters
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----------------
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.. option:: mo_num
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Total number of |MOs|
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.. option:: mo_coef
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Coefficient of the i-th |AO| on the j-th |MO|
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.. option:: mo_label
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Label characterizing the MOS (Local, Canonical, Natural, *etc*)
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.. option:: mo_occ
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|MO| occupation numbers
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.. option:: mo_class
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[ Core | Inactive | Active | Virtual | Deleted ], as defined by :ref:`qp_set_mo_class`
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.. option:: ao_md5
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MD5 checksum characterizing the |AO| basis set.
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Providers
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---------
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.. c:var:: mo_coef
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File : :file:`mo_basis/mos.irp.f`
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.. code:: fortran
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double precision, allocatable :: mo_coef (ao_num,mo_num)
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Molecular orbital coefficients on |AO| basis set
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mo_coef(i,j) = coefficient of the i-th |AO| on the jth mo
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mo_label : Label characterizing the MOS (local, canonical, natural, etc)
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Needs:
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.. hlist::
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:columns: 3
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* :c:data:`ao_num`
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* :c:data:`ao_ortho_canonical_coef`
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* :c:data:`ezfio_filename`
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* :c:data:`mo_num`
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* :c:data:`mpi_master`
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Needed by:
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.. hlist::
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:columns: 3
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* :c:data:`eigenvectors_fock_matrix_mo`
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* :c:data:`fock_matrix_mo_alpha`
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* :c:data:`fock_matrix_mo_beta`
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* :c:data:`fps_spf_matrix_mo`
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* :c:data:`mo_coef_in_ao_ortho_basis`
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* :c:data:`mo_coef_transp`
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* :c:data:`mo_dipole_x`
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* :c:data:`mo_integrals_n_e`
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* :c:data:`mo_integrals_n_e_per_atom`
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* :c:data:`mo_kinetic_integrals`
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* :c:data:`mo_overlap`
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* :c:data:`mo_pseudo_integrals`
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* :c:data:`mo_spread_x`
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* :c:data:`mo_two_e_int_erf_jj_from_ao`
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* :c:data:`mo_two_e_integral_jj_from_ao`
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* :c:data:`mo_two_e_integrals_erf_in_map`
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* :c:data:`mo_two_e_integrals_in_map`
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* :c:data:`mo_two_e_integrals_vv_from_ao`
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* :c:data:`one_e_dm_ao_alpha`
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* :c:data:`one_e_spin_density_ao`
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* :c:data:`psi_det`
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* :c:data:`s_mo_coef`
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* :c:data:`scf_density_matrix_ao_alpha`
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* :c:data:`scf_density_matrix_ao_beta`
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.. c:var:: mo_coef_begin_iteration
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File : :file:`mo_basis/track_orb.irp.f`
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.. code:: fortran
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double precision, allocatable :: mo_coef_begin_iteration (ao_num,mo_num)
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Void provider to store the coefficients of the |MO| basis at the beginning of the SCF iteration
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Usefull to track some orbitals
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Needs:
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.. hlist::
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:columns: 3
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* :c:data:`ao_num`
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* :c:data:`mo_num`
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.. c:var:: mo_coef_in_ao_ortho_basis
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File : :file:`mo_basis/mos.irp.f`
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.. code:: fortran
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double precision, allocatable :: mo_coef_in_ao_ortho_basis (ao_num,mo_num)
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|MO| coefficients in orthogonalized |AO| basis
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:math:`C^{-1}.C_{mo}`
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Needs:
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.. hlist::
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:columns: 3
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* :c:data:`ao_num`
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* :c:data:`ao_ortho_canonical_coef_inv`
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* :c:data:`mo_coef`
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* :c:data:`mo_num`
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.. c:var:: mo_coef_transp
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File : :file:`mo_basis/mos.irp.f`
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.. code:: fortran
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double precision, allocatable :: mo_coef_transp (mo_num,ao_num)
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|MO| coefficients on |AO| basis set
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Needs:
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.. hlist::
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:columns: 3
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* :c:data:`ao_num`
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* :c:data:`mo_coef`
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* :c:data:`mo_num`
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Needed by:
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.. hlist::
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:columns: 3
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* :c:data:`mo_two_e_int_erf_jj_from_ao`
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* :c:data:`mo_two_e_integral_jj_from_ao`
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* :c:data:`mo_two_e_integrals_erf_in_map`
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* :c:data:`mo_two_e_integrals_in_map`
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* :c:data:`mo_two_e_integrals_vv_from_ao`
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.. c:var:: mo_label
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File : :file:`mo_basis/mos.irp.f`
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.. code:: fortran
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character*(64) :: mo_label
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|MO| coefficients on |AO| basis set
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mo_coef(i,j) = coefficient of the i-th |AO| on the j-th |MO|
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mo_label : Label characterizing the |MOs| (local, canonical, natural, etc)
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Needs:
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.. hlist::
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:columns: 3
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* :c:data:`ezfio_filename`
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* :c:data:`mpi_master`
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Needed by:
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.. hlist::
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:columns: 3
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* :c:data:`n_det`
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* :c:data:`psi_coef`
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* :c:data:`psi_det`
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.. c:var:: mo_num
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File : :file:`mo_basis/mos.irp.f`
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.. code:: fortran
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integer :: mo_num
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Number of MOs
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Needs:
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.. hlist::
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:columns: 3
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* :c:data:`ao_ortho_canonical_coef`
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* :c:data:`ezfio_filename`
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* :c:data:`mpi_master`
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Needed by:
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.. hlist::
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:columns: 3
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* :c:data:`ao_ortho_canonical_nucl_elec_integrals`
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* :c:data:`ao_ortho_lowdin_nucl_elec_integrals`
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* :c:data:`big_array_coulomb_integrals`
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* :c:data:`core_fock_operator`
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* :c:data:`core_fock_operator_erf`
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* :c:data:`data_one_e_dm_alpha_mo`
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* :c:data:`data_one_e_dm_beta_mo`
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* :c:data:`eigenvectors_fock_matrix_mo`
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* :c:data:`fock_matrix_ao`
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* :c:data:`fock_matrix_mo`
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* :c:data:`fock_matrix_mo_alpha`
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* :c:data:`fock_matrix_mo_beta`
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* :c:data:`fock_operator_closed_shell_ref_bitmask`
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* :c:data:`fock_wee_closed_shell`
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* :c:data:`fps_spf_matrix_mo`
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* :c:data:`full_ijkl_bitmask`
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* :c:data:`int_erf_3_index`
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* :c:data:`list_core_inact_act`
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* :c:data:`list_inact`
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* :c:data:`mo_class`
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* :c:data:`mo_coef`
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* :c:data:`mo_coef_begin_iteration`
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* :c:data:`mo_coef_in_ao_ortho_basis`
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* :c:data:`mo_coef_transp`
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* :c:data:`mo_dipole_x`
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* :c:data:`mo_integrals_cache_min`
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* :c:data:`mo_integrals_erf_cache_min`
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* :c:data:`mo_integrals_erf_map`
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* :c:data:`mo_integrals_map`
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* :c:data:`mo_integrals_n_e`
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* :c:data:`mo_integrals_n_e_per_atom`
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* :c:data:`mo_kinetic_integrals`
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* :c:data:`mo_occ`
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* :c:data:`mo_one_e_integrals`
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* :c:data:`mo_overlap`
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* :c:data:`mo_pseudo_integrals`
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* :c:data:`mo_spread_x`
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* :c:data:`mo_two_e_int_erf_jj`
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* :c:data:`mo_two_e_int_erf_jj_from_ao`
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* :c:data:`mo_two_e_integral_jj_from_ao`
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* :c:data:`mo_two_e_integrals_erf_in_map`
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* :c:data:`mo_two_e_integrals_in_map`
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* :c:data:`mo_two_e_integrals_jj`
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* :c:data:`mo_two_e_integrals_vv_from_ao`
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* :c:data:`n_core_orb`
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* :c:data:`n_int`
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* :c:data:`one_e_dm_ao_alpha`
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* :c:data:`one_e_dm_dagger_mo_spin_index`
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* :c:data:`one_e_dm_mo`
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* :c:data:`one_e_dm_mo_alpha`
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* :c:data:`one_e_dm_mo_alpha_average`
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* :c:data:`one_e_dm_mo_diff`
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* :c:data:`one_e_dm_mo_spin_index`
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* :c:data:`one_e_spin_density_ao`
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* :c:data:`one_e_spin_density_mo`
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* :c:data:`psi_energy_h_core`
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* :c:data:`s_mo_coef`
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* :c:data:`singles_alpha_csc_idx`
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* :c:data:`singles_beta_csc_idx`
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.. c:var:: mo_occ
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File : :file:`mo_basis/mos.irp.f`
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.. code:: fortran
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double precision, allocatable :: mo_occ (mo_num)
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|MO| occupation numbers
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Needs:
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.. hlist::
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:columns: 3
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* :c:data:`elec_alpha_num`
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* :c:data:`elec_beta_num`
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* :c:data:`ezfio_filename`
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* :c:data:`mo_num`
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* :c:data:`mpi_master`
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Subroutines / functions
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-----------------------
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.. c:function:: ao_ortho_cano_to_ao:
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File : :file:`mo_basis/mos.irp.f`
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.. code:: fortran
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subroutine ao_ortho_cano_to_ao(A_ao,LDA_ao,A,LDA)
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Transform A from the |AO| basis to the orthogonal |AO| basis
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$C^{-1}.A_{ao}.C^{\dagger-1}$
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Needs:
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.. hlist::
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:columns: 3
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* :c:data:`ao_num`
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* :c:data:`ao_ortho_canonical_coef_inv`
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Calls:
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.. hlist::
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:columns: 3
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* :c:func:`dgemm`
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.. c:function:: ao_to_mo:
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File : :file:`mo_basis/mos.irp.f`
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.. code:: fortran
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subroutine ao_to_mo(A_ao,LDA_ao,A_mo,LDA_mo)
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Transform A from the |AO| basis to the |MO| basis
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$C^\dagger.A_{ao}.C$
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Needs:
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.. hlist::
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:columns: 3
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* :c:data:`ao_num`
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* :c:data:`mo_num`
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* :c:data:`mo_coef`
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Called by:
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.. hlist::
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:columns: 3
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* :c:data:`fock_matrix_mo_alpha`
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* :c:data:`fock_matrix_mo_beta`
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* :c:data:`fps_spf_matrix_mo`
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* :c:data:`mo_dipole_x`
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* :c:data:`mo_integrals_n_e`
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* :c:data:`mo_integrals_n_e_per_atom`
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* :c:data:`mo_kinetic_integrals`
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* :c:data:`mo_pseudo_integrals`
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* :c:data:`mo_spread_x`
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Calls:
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.. hlist::
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:columns: 3
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* :c:func:`dgemm`
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.. c:function:: give_all_mos_and_grad_and_lapl_at_r:
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File : :file:`mo_basis/mos_in_r.irp.f`
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.. code:: fortran
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subroutine give_all_mos_and_grad_and_lapl_at_r(r,mos_array,mos_grad_array,mos_lapl_array)
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Needs:
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.. hlist::
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:columns: 3
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* :c:data:`ao_num`
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* :c:data:`mo_num`
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* :c:data:`mo_coef`
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Calls:
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.. hlist::
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:columns: 3
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* :c:func:`give_all_aos_and_grad_and_lapl_at_r`
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.. c:function:: give_all_mos_and_grad_at_r:
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File : :file:`mo_basis/mos_in_r.irp.f`
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.. code:: fortran
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subroutine give_all_mos_and_grad_at_r(r,mos_array,mos_grad_array)
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Needs:
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.. hlist::
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:columns: 3
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* :c:data:`ao_num`
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* :c:data:`mo_num`
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* :c:data:`mo_coef`
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Calls:
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.. hlist::
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:columns: 3
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* :c:func:`give_all_aos_and_grad_at_r`
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.. c:function:: give_all_mos_at_r:
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File : :file:`mo_basis/mos_in_r.irp.f`
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.. code:: fortran
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subroutine give_all_mos_at_r(r,mos_array)
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Needs:
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.. hlist::
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:columns: 3
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* :c:data:`ao_num`
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* :c:data:`mo_num`
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* :c:data:`mo_coef_transp`
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Calls:
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.. hlist::
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:columns: 3
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* :c:func:`dgemv`
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* :c:func:`give_all_aos_at_r`
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.. c:function:: initialize_mo_coef_begin_iteration:
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File : :file:`mo_basis/track_orb.irp.f`
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.. code:: fortran
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subroutine initialize_mo_coef_begin_iteration
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Initialize :c:data:`mo_coef_begin_iteration` to the current :c:data:`mo_coef`
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Needs:
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.. hlist::
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:columns: 3
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* :c:data:`mo_coef_begin_iteration`
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* :c:data:`mo_coef`
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Called by:
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.. hlist::
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:columns: 3
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* :c:func:`damping_scf`
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* :c:func:`roothaan_hall_scf`
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.. c:function:: mix_mo_jk:
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File : :file:`mo_basis/mos.irp.f`
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.. code:: fortran
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subroutine mix_mo_jk(j,k)
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Rotates the j-th |MO| with the k-th |MO| to give two new |MOs| that are
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* $+ = \frac{1}{\sqrt{2}} ( | j\rangle + | k\rangle)$
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* $- = \frac{1}{\sqrt{2}} ( | j\rangle - | k\rangle)$
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by convention, the '+' |MO| is in the lowest index (min(j,k))
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by convention, the '-' |MO| is in the highest index (max(j,k))
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Needs:
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.. hlist::
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:columns: 3
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* :c:data:`ao_num`
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* :c:data:`mo_coef`
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.. c:function:: mo_as_eigvectors_of_mo_matrix:
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File : :file:`mo_basis/utils.irp.f`
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.. code:: fortran
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subroutine mo_as_eigvectors_of_mo_matrix(matrix,n,m,label,sign,output)
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Needs:
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.. hlist::
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:columns: 3
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* :c:data:`mo_label`
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* :c:data:`ao_num`
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* :c:data:`mo_num`
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* :c:data:`mo_coef`
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Called by:
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.. hlist::
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:columns: 3
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* :c:func:`create_guess`
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* :c:func:`damping_scf`
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* :c:func:`hcore_guess`
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* :c:func:`roothaan_hall_scf`
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Calls:
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.. hlist::
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:columns: 3
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* :c:func:`dgemm`
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* :c:func:`lapack_diag`
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* :c:func:`write_time`
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.. c:function:: mo_as_svd_vectors_of_mo_matrix:
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File : :file:`mo_basis/utils.irp.f`
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.. code:: fortran
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subroutine mo_as_svd_vectors_of_mo_matrix(matrix,lda,m,n,label)
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Needs:
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.. hlist::
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:columns: 3
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* :c:data:`mo_label`
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* :c:data:`ao_num`
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* :c:data:`mo_num`
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* :c:data:`mo_coef`
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Calls:
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.. hlist::
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:columns: 3
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* :c:func:`dgemm`
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* :c:func:`svd`
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* :c:func:`write_time`
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.. c:function:: mo_as_svd_vectors_of_mo_matrix_eig:
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File : :file:`mo_basis/utils.irp.f`
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.. code:: fortran
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subroutine mo_as_svd_vectors_of_mo_matrix_eig(matrix,lda,m,n,eig,label)
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Needs:
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.. hlist::
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:columns: 3
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* :c:data:`mo_label`
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* :c:data:`ao_num`
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* :c:data:`mo_num`
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* :c:data:`mo_coef`
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Called by:
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.. hlist::
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:columns: 3
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* :c:func:`set_natural_mos`
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Calls:
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.. hlist::
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:columns: 3
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* :c:func:`dgemm`
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* :c:func:`svd`
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* :c:func:`write_time`
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.. c:function:: reorder_core_orb:
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File : :file:`mo_basis/track_orb.irp.f`
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.. code:: fortran
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subroutine reorder_core_orb
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routines that takes the current :c:data:`mo_coef` and reorder the core orbitals (see :c:data:`list_core` and :c:data:`n_core_orb`) according to the overlap with :c:data:`mo_coef_begin_iteration`
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Needs:
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.. hlist::
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:columns: 3
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* :c:data:`mo_num`
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* :c:data:`mo_coef_begin_iteration`
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* :c:data:`mo_coef`
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* :c:data:`ao_overlap`
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* :c:data:`n_core_orb`
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* :c:data:`ao_num`
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* :c:data:`list_inact`
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Called by:
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.. hlist::
|
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:columns: 3
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* :c:func:`damping_scf`
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* :c:func:`roothaan_hall_scf`
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Calls:
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.. hlist::
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:columns: 3
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* :c:func:`dsort`
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.. c:function:: save_mos:
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File : :file:`mo_basis/utils.irp.f`
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.. code:: fortran
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subroutine save_mos
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Needs:
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|
.. hlist::
|
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:columns: 3
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* :c:data:`mo_occ`
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* :c:data:`ao_md5`
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* :c:data:`ezfio_filename`
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* :c:data:`mo_num`
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* :c:data:`mo_coef`
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* :c:data:`ao_num`
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* :c:data:`mo_label`
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|
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Called by:
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|
|
.. hlist::
|
|
:columns: 3
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|
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* :c:func:`damping_scf`
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* :c:func:`hcore_guess`
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* :c:func:`huckel_guess`
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* :c:func:`roothaan_hall_scf`
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* :c:func:`save_natural_mos`
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* :c:func:`save_ortho_mos`
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|
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Calls:
|
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|
|
.. hlist::
|
|
:columns: 3
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|
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* :c:func:`ezfio_set_mo_basis_ao_md5`
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* :c:func:`ezfio_set_mo_basis_mo_coef`
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* :c:func:`ezfio_set_mo_basis_mo_label`
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* :c:func:`ezfio_set_mo_basis_mo_num`
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* :c:func:`ezfio_set_mo_basis_mo_occ`
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* :c:func:`system`
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.. c:function:: save_mos_truncated:
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File : :file:`mo_basis/utils.irp.f`
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.. code:: fortran
|
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|
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subroutine save_mos_truncated(n)
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Needs:
|
|
|
|
.. hlist::
|
|
:columns: 3
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|
|
* :c:data:`mo_occ`
|
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* :c:data:`ao_md5`
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* :c:data:`ezfio_filename`
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* :c:data:`mo_coef`
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* :c:data:`ao_num`
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* :c:data:`mo_label`
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Calls:
|
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|
|
.. hlist::
|
|
:columns: 3
|
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|
|
* :c:func:`ezfio_set_mo_basis_ao_md5`
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* :c:func:`ezfio_set_mo_basis_mo_coef`
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* :c:func:`ezfio_set_mo_basis_mo_label`
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* :c:func:`ezfio_set_mo_basis_mo_num`
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* :c:func:`ezfio_set_mo_basis_mo_occ`
|
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* :c:func:`system`
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