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QuantumPackage/plugins/local/tc_scf/tcscf_energy_naive.irp.f

81 lines
1.8 KiB
Fortran

! ---
BEGIN_PROVIDER [double precision, tcscf_energy_3e_naive]
implicit none
integer :: i, j, k
integer :: neu, ned, D(elec_num)
integer :: ii, jj, kk
integer :: si, sj, sk
double precision :: I_ijk, I_jki, I_kij, I_jik, I_ikj, I_kji
double precision :: I_tot
PROVIDE mo_l_coef mo_r_coef
neu = elec_alpha_num
ned = elec_beta_num
if (neu > 0) D(1:neu) = [(2*i-1, i = 1, neu)]
if (ned > 0) D(neu+1:neu+ned) = [(2*i, i = 1, ned)]
!print*, "D = "
!do i = 1, elec_num
! ii = (D(i) - 1) / 2 + 1
! si = mod(D(i), 2)
! print*, i, D(i), ii, si
!enddo
tcscf_energy_3e_naive = 0.d0
do i = 1, elec_num - 2
ii = (D(i) - 1) / 2 + 1
si = mod(D(i), 2)
do j = i + 1, elec_num - 1
jj = (D(j) - 1) / 2 + 1
sj = mod(D(j), 2)
do k = j + 1, elec_num
kk = (D(k) - 1) / 2 + 1
sk = mod(D(k), 2)
call give_integrals_3_body_bi_ort(ii, jj, kk, ii, jj, kk, I_ijk)
I_tot = I_ijk
if(sj==si .and. sk==sj) then
call give_integrals_3_body_bi_ort(ii, jj, kk, jj, kk, ii, I_jki)
I_tot += I_jki
endif
if(sk==si .and. si==sj) then
call give_integrals_3_body_bi_ort(ii, jj, kk, kk, ii, jj, I_kij)
I_tot += I_kij
endif
if(sj==si) then
call give_integrals_3_body_bi_ort(ii, jj, kk, jj, ii, kk, I_jik)
I_tot -= I_jik
endif
if(sk==sj) then
call give_integrals_3_body_bi_ort(ii, jj, kk, ii, kk, jj, I_ikj)
I_tot -= I_ikj
endif
if(sk==si) then
call give_integrals_3_body_bi_ort(ii, jj, kk, kk, jj, ii, I_kji)
I_tot -= I_kji
endif
tcscf_energy_3e_naive += I_tot
enddo
enddo
enddo
tcscf_energy_3e_naive = -tcscf_energy_3e_naive
END_PROVIDER
! ---