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QuantumPackage/plugins/local/non_h_ints_mu/grad_squared.irp.f
2024-01-15 12:02:38 +01:00

126 lines
3.3 KiB
Fortran

! ---
BEGIN_PROVIDER [double precision, grad12_j12, (ao_num, ao_num, n_points_final_grid)]
implicit none
integer :: ipoint, i, j, m, igauss
double precision :: r(3), delta, coef
double precision :: tmp1
double precision :: time0, time1
double precision, external :: overlap_gauss_r12_ao
print*, ' providing grad12_j12 ...'
call wall_time(time0)
PROVIDE int2_grad1u2_grad2u2_env2
do ipoint = 1, n_points_final_grid
tmp1 = env_val(ipoint)
tmp1 = tmp1 * tmp1
do j = 1, ao_num
do i = 1, ao_num
grad12_j12(i,j,ipoint) = tmp1 * int2_grad1u2_grad2u2_env2(i,j,ipoint)
enddo
enddo
enddo
FREE int2_grad1u2_grad2u2_env2
call wall_time(time1)
print*, ' Wall time for grad12_j12 (min) = ', (time1 - time0) / 60.d0
END_PROVIDER
! ---
BEGIN_PROVIDER [double precision, u12sq_envsq, (ao_num, ao_num, n_points_final_grid)]
implicit none
integer :: ipoint, i, j
double precision :: tmp_x, tmp_y, tmp_z
double precision :: tmp1
double precision :: time0, time1
print*, ' providing u12sq_envsq ...'
call wall_time(time0)
! do not free here
PROVIDE int2_u2_env2
do ipoint = 1, n_points_final_grid
tmp_x = env_grad(1,ipoint)
tmp_y = env_grad(2,ipoint)
tmp_z = env_grad(3,ipoint)
tmp1 = -0.5d0 * (tmp_x * tmp_x + tmp_y * tmp_y + tmp_z * tmp_z)
do j = 1, ao_num
do i = 1, ao_num
u12sq_envsq(i,j,ipoint) = tmp1 * int2_u2_env2(i,j,ipoint)
enddo
enddo
enddo
call wall_time(time1)
print*, ' Wall time for u12sq_envsq (min) = ', (time1 - time0) / 60.d0
END_PROVIDER
! ---
BEGIN_PROVIDER [double precision, u12_grad1_u12_env_grad1_env, (ao_num, ao_num, n_points_final_grid)]
implicit none
integer :: ipoint, i, j, m, igauss
double precision :: x, y, z
double precision :: tmp_v, tmp_x, tmp_y, tmp_z
double precision :: tmp3, tmp4, tmp5, tmp6, tmp7, tmp8, tmp9
double precision :: time0, time1
double precision, external :: overlap_gauss_r12_ao
print*, ' providing u12_grad1_u12_env_grad1_env ...'
call wall_time(time0)
PROVIDE int2_u_grad1u_env2
PROVIDE int2_u_grad1u_x_env2
do ipoint = 1, n_points_final_grid
x = final_grid_points(1,ipoint)
y = final_grid_points(2,ipoint)
z = final_grid_points(3,ipoint)
tmp_v = env_val (ipoint)
tmp_x = env_grad(1,ipoint)
tmp_y = env_grad(2,ipoint)
tmp_z = env_grad(3,ipoint)
tmp3 = tmp_v * tmp_x
tmp4 = tmp_v * tmp_y
tmp5 = tmp_v * tmp_z
tmp6 = -x * tmp3
tmp7 = -y * tmp4
tmp8 = -z * tmp5
do j = 1, ao_num
do i = 1, ao_num
tmp9 = int2_u_grad1u_env2(i,j,ipoint)
u12_grad1_u12_env_grad1_env(i,j,ipoint) = tmp6 * tmp9 + tmp3 * int2_u_grad1u_x_env2(i,j,ipoint,1) &
+ tmp7 * tmp9 + tmp4 * int2_u_grad1u_x_env2(i,j,ipoint,2) &
+ tmp8 * tmp9 + tmp5 * int2_u_grad1u_x_env2(i,j,ipoint,3)
enddo
enddo
enddo
FREE int2_u_grad1u_env2
FREE int2_u_grad1u_x_env2
call wall_time(time1)
print*, ' Wall time for u12_grad1_u12_env_grad1_env (min) = ', (time1 - time0) / 60.d0
END_PROVIDER
! ---