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QuAcK/qcaml-tools/quack_integrals.ml

75 lines
2.7 KiB
OCaml

let quack_dir =
try Sys.getenv "QUACK_ROOT" with
Not_found -> "."
module Command_line = Qcaml.Common.Command_line
module Util = Qcaml.Common.Util
let () =
let open Command_line in
begin
set_header_doc (Sys.argv.(0) ^ " - QuAcK command");
set_description_doc "Computes the one- and two-electron integrals on the Gaussian atomic basis set.";
set_specs
[ { short='b' ; long="basis" ; opt=Mandatory;
arg=With_arg "<string>";
doc="Name of the file containing the basis set"; } ;
{ short='x' ; long="xyz" ; opt=Mandatory;
arg=With_arg "<string>";
doc="Name of the file containing the nuclear coordinates in xyz format"; } ;
{ short='u' ; long="range-separation" ; opt=Optional;
arg=With_arg "<float>";
doc="Range-separation parameter."; } ;
]
end;
let basis_file = Util.of_some @@ Command_line.get "basis" in
let nuclei_file = Util.of_some @@ Command_line.get "xyz" in
let range_separation =
match Command_line.get "range-separation" with
| None -> None
| Some mu -> Some (float_of_string mu)
in
let nuclei =
Qcaml.Particles.Nuclei.of_xyz_file nuclei_file
in
let operators =
match range_separation with
| None -> []
| Some mu -> [ Qcaml.Operators.Operator.of_range_separation mu ]
in
let ao_basis =
Qcaml.Ao.Basis.of_nuclei_and_basis_filename ~kind:`Gaussian
~operators ~cartesian:true ~nuclei basis_file
in
let overlap = Qcaml.Ao.Basis.overlap ao_basis in
let eN_ints = Qcaml.Ao.Basis.eN_ints ao_basis in
let kin_ints = Qcaml.Ao.Basis.kin_ints ao_basis in
let ee_ints = Qcaml.Ao.Basis.ee_ints ao_basis in
let multipole = Qcaml.Ao.Basis.multipole ao_basis in
let x_mat = Qcaml.Gaussian_integrals.Multipole.matrix_x multipole in
let y_mat = Qcaml.Gaussian_integrals.Multipole.matrix_y multipole in
let z_mat = Qcaml.Gaussian_integrals.Multipole.matrix_z multipole in
Qcaml.Gaussian_integrals.Overlap.to_file ~filename:(quack_dir ^ "/int/Ov.dat") overlap;
Qcaml.Gaussian_integrals.Electron_nucleus.to_file ~filename:(quack_dir ^ "/int/Nuc.dat") eN_ints;
Qcaml.Gaussian_integrals.Kinetic.to_file ~filename:(quack_dir ^ "/int/Kin.dat") kin_ints;
Qcaml.Gaussian_integrals.Eri.to_file ~filename:(quack_dir ^ "/int/ERI.dat") ee_ints;
Qcaml.Gaussian_integrals.Multipole.to_file ~filename:(quack_dir ^ "/int/x.dat") x_mat;
Qcaml.Gaussian_integrals.Multipole.to_file ~filename:(quack_dir ^ "/int/y.dat") y_mat;
Qcaml.Gaussian_integrals.Multipole.to_file ~filename:(quack_dir ^ "/int/z.dat") z_mat;
match range_separation with
| Some _mu ->
Qcaml.Gaussian_integrals.Eri_long_range.to_file ~filename:(quack_dir ^ "/int/ERI_lr.dat") (Qcaml.Ao.Basis.ee_lr_ints ao_basis)
| None -> ()