\newcommand{\Pop}{6-31+G(d)}
\newcommand{\AVDZ}{aug-cc-pVDZ}
\newcommand{\AVTZ}{aug-cc-pVTZ}
\newcommand{\AVQZ}{aug-cc-pVQZ}
\newcommand{\AVFZ}{aug-cc-pV5Z}
\newcommand{\Td}{\%T_1}
\begin{dfbOptions}
  \format{exoticcolumn}
  \initialState[\ce{CClF}]{^1A^\prime}
  \initialState[Formylfluoride]{^1A^\prime}
  \initialState[\ce{HCCl}]{^1A^\prime}
  \initialState[\ce{HCF}]{^1A^\prime}
  \initialState[\ce{HCP}]{^1\Sigma^+}
  \initialState[\ce{HPO}]{^1A^\prime}
  \initialState[\ce{HPS}]{^1A^\prime}
  \initialState[\ce{HSiF}]{^1A^\prime}
\end{dfbOptions}

\begin{tabular}
        &	&\multicolumn{3}{c}{\AVTZ}  & CBS & \multicolumn{4}{c}{\Pop} & \multicolumn{4}{c}{\AVDZ}  & \multicolumn{4}{c}{\AVTZ} \\
        &	& 	$f$ [CC3] &$\Td$ [TBE(FC)] & TBE(FC)	& TBE			&CC3	& CCSDT		& CCSDTQ 	& CCSDTQP 	& CC3	&  CCSDT		& CCSDTQ 	& FCI 			&CC3	& CCSDT 		& CCSDTQ & FCI \\
  Carbonylfluoride& $^1A_2$	&		&91.1&7.31$^a$	&7.31	&7.33	&7.30	&		&		&7.34	&7.31	&		&7.30$\pm$0.04	&7.31	&7.28	&		&7.32$\pm$0.05\\
        & $^3A_2$	&		&97.8&7.06$^b$	&7.07	&7.03	&7.00	&		&		&7.05	&7.02	&		&7.08$\pm$0.01	&7.03	&7.00	&		&7.04$\pm$0.10	\\
  \ce{CCl2}		& $^1B_1$	&0.002	&93.7&2.59$^b$	&2.57	&2.71	&2.70	&2.70	&		&2.69	&2.69	&		&2.68$\pm$0.02	&2.61	&2.60	&		& \\
        & $^1A_2$	&		&88.3&4.40$^b$	&4.41	&4.46	&4.44	&4.47	&		&4.40	&4.39	&		&4.46$\pm$0.01 	&4.35	&4.33	&	 	&\\
        & $^3B_1$	&		&98.6&1.22$^b$	&1.23	&1.10	&1.09	&1.11	&		&1.20	&1.19	&		&1.22$\pm$0.03 	&1.20	&1.19	&		&1.22$\pm$0.05	 \\
        & $^3A_2$	&		&96.1&4.31$^b$	&4.32	&4.41	&4.38	&4.42	&		&4.34	&4.31	&		&4.36$\pm$0.01 	&4.28	&4.26	&		&				 \\		
  
  \ce{CClF}		& $^1A^{\prime\prime}$		&0.007	&93.9&3.55$^b$	&3.54	&3.66	&3.66	&3.66	&		&3.63	&3.62	&		&3.62$\pm$0.01	&3.56	&3.55	&		&3.63$\pm$0.06	\\
  \ce{CF2}		& $^1B_1$	&0.034	&94.7&5.09		&5.07	&5.18	&5.18	&5.18	&		&5.12	&5.11	&5.11	&5.12$\pm$0.00	&5.07	&5.06	&		&5.09$\pm$0.01	\\			
        & $^3B_1$	&		&99.1&2.77		&2.78	&2.71	&2.70	&2.71	&		&2.71	&2.70	&2.71	&2.71$\pm$0.01	&2.76	&2.75	&		&2.77$\pm$0.01	\\
  Difluorodiazirine&$^1B_1$	&0.002	&93.1&3.74$^c$	&3.73$^d$&3.83	&3.83	&		&		&3.80	&3.80	&		&				&3.74	&3.74&&\\	
        &$^1A_2$		&		&91.4&7.00$^c$	&6.98$^d$&7.13	&7.11	&		&		&7.11	&7.08	&		&				&7.02	&7.00&&\\	
        &$^1B_2$		&0.026	&93.3&8.52$^c$	&8.54$^d$&8.51	&8.52	&		&		&8.45	&8.46	&		&				&8.50	&8.52&&\\	
        &$^3B_1$		&		&98.2&3.03$^e$	&3.03$^d$&3.09	&3.09	&		&		&3.06	&3.06	&		&				&3.03	&&&\\	
        &$^3B_2$		&		&98.9&5.44$^e$	&5.46$^d$&5.48	&5.48	&		&		&5.47	&5.46	&		&				&5.45	&&&\\	
        &$^3B_1$		&		&98.4&5.80$^e$	&5.81$^d$&5.86	&5.85	&		&		&5.83	&5.82	&		&				&5.81	&&&\\
  Formylfluoride	& $^1A^{\prime\prime}$		&0.001	&91.2&5.96$^b$	&5.97	&6.09	&6.06	&6.07	&		&6.03	&6.00	&		&6.00$\pm$0.03	&5.99	&5.96	&		&\\
        & $^3A^{\prime\prime}$		&		&97.9&5.73$^b$	&5.75	&5.72	&5.70	&5.71	&		&5.65	&5.62	&		&5.65$\pm$0.01	&5.62	&5.60	&		&\\
  \ce{HCCl}		& $^1A^{\prime\prime}$		&0.003	&94.5&1.98		&1.97	&2.05	&2.04	&2.05	&2.05	&2.02	&2.02	&2.02	&2.04$\pm$0.01	&1.97	&1.97	&		&1.98$\pm$0.00\\
  \ce{HCF}		&$^1A^{\prime\prime}$		&0.006	&95.4&2.49		&2.49	&2.58	&2.57	&2.58	&2.58	&2.53	&2.53	&2.53	&2.54$\pm$0.00	&2.49	&2.49	&		&2.49$\pm$0.02\\
  \ce{HCP}		& $^1\Sigma^-$	&		&94.9&4.84		&4.81	&5.19	&5.19	&5.18	&5.18	&5.06	&5.05	&5.04	&5.04$\pm$0.00	&4.85	&4.85	&4.84	&4.84$\pm$0.00\\
        & $^1\Delta$	&		&94.0&5.15		&5.10	&5.48	&5.48	&5.48	&5.48	&5.33	&5.33	&5.32	&5.32$\pm$0.00	&5.15	&5.15	&		&5.15$\pm$0.00\\
        & $^3\Sigma^+$&		&98.9&3.47		&3.49	&3.44	&3.45	&3.46	&3.46	&3.47	&3.47	&3.49	&3.49$\pm$0.00	&3.45	&3.45	&3.46	&3.47$\pm$0.00\\
        & $^3\Delta$	&		&98.8&4.22		&4.20	&4.40	&4.39	&4.39	&4.39	&4.35	&4.34	&4.34	&4.34$\pm$0.00	&4.22	&4.21	&4.21	&4.22$\pm$0.00\\
  \ce{HPO}		& $^1A^{\prime\prime}$		&0.003	&90.9&2.47		&2.49	&2.49	&2.47	&2.48	&2.48	&2.47	&2.45	&2.46	&2.46$\pm$0.00	&2.46	&2.46	&		&2.47$\pm$0.00\\
  \ce{HPS}		& $^1A^{\prime\prime}$		&0.001	&90.3&1.59		&1.61	&1.57	&1.55	&1.56	&1.56	&1.60	&1.59	&1.59	&1.60$\pm$0.00	&1.59	&1.58	&		&1.59$\pm$0.00\\
  \ce{HSiF}		& $^1A^{\prime\prime}$		&0.024	&93.1&3.05		&3.05	&3.09	&3.08	&3.08	&3.08	&3.08	&3.07	&3.07	&3.06$\pm$0.00	&3.07	&3.06	&		&3.05$\pm$0.00\\
  \ce{SiCl2}		&$^1B_1$		&0.031	&92.1&3.91$^b$	&3.93	&3.94	&3.94	&3.94	&		&3.93	&3.92	&		&3.95$\pm$0.02	&3.90	&3.88	&		&3.88$\pm$0.03\\
        &$^3B_1$		&		&98.7&2.48$^f$	&2.50	&2.39	&2.39	&2.40	&		&2.45	&2.44	&		&2.47$\pm$0.05	&2.48	&2.47	&		&2.49$\pm$0.04\\
  Silylidene		&$^1A_2$		&		&92.3&2.11		&2.12	&2.14	&2.11	&2.10	&2.10	&2.18	&2.15	&2.14	&2.14$\pm$0.00	&2.15	&2.13	&2.12	&2.11$\pm$0.01\\
        &$^1B_2$		&0.033	&88.0&3.78		&3.80	&3.88	&3.87	&3.88	&3.88	&3.81	&3.80	&3.80	&3.79$\pm$0.01	&3.78	&3.78	&3.78	&3.78$\pm$0.01\\
  \end{tabular}