\newcommand{\TDDFT}{TD-DFT}
\newcommand{\CASSCF}{CASSCF}
\newcommand{\CASPT}{CASPT2}
\newcommand{\ADC}[1]{ADC(#1)}
\newcommand{\CC}[1]{CC#1}
\newcommand{\CCSD}{CCSD}
\newcommand{\EOMCCSD}{EOM-CCSD}
\newcommand{\CCSDT}{CCSDT}
\newcommand{\CCSDTQ}{CCSDTQ}
\newcommand{\CCSDTQP}{CCSDTQP}
\newcommand{\CI}{CI}
\newcommand{\sCI}{sCI}
\newcommand{\exCI}{exFCI}
\newcommand{\FCI}{FCI}

% basis
\newcommand{\AVDZ}{aug-cc-pVDZ}
\newcommand{\AVTZ}{aug-cc-pVTZ}
\newcommand{\DAVTZ}{d-aug-cc-pVTZ}
\newcommand{\AVQZ}{aug-cc-pVQZ}
\newcommand{\DAVQZ}{d-aug-cc-pVQZ}
\newcommand{\TAVQZ}{t-aug-cc-pVQZ}
\newcommand{\AVPZ}{aug-cc-pV5Z}
\newcommand{\DAVPZ}{d-aug-cc-pV5Z}
\newcommand{\PopleDZ}{6-31+G(d)}

% greek shortcut
\newcommand{\pis}{\pi^\star}
\newcommand{\Ryd}{\mathrm{R}}

\begin{tabular}{llcccccc}
                        &		&	&		& TBE(FC)&  \multicolumn{3}{c}{Corrected TBE} \\
                        & State	 & $f$ & \%$T_1$ & 	AVTZ	& Method & Corr.	& Value \\
      Acetaldehyde	&$^1A''(\mathrm{V};n \rightarrow \pis)$					& 0.000	&91.3& 4.31		& {\exCI}/AVTZ & AVQZ		&4.31	\\
                        &$^3A''(\mathrm{V};n \rightarrow \pis)$					&		&97.9& 3.97$^a$ 	& {\exCI}/AVDZ & AVQZ		&3.98	\\
      Acetylene		&$^1\Sigma_u^- (\mathrm{V};\pi \rightarrow \pis)$ 			&		&96.5& 7.10		& {\exCI}/AVTZ & dAV5Z	 	&7.10 	\\
                        &$^1\Delta_u	(\mathrm{V};\pi \rightarrow \pis)$ 			&		&93.3& 7.44		&			&			&7.44 	\\	
                        &$^3\Sigma_u^+ (\mathrm{V};\pi \rightarrow \pis)$ 			&		&99.2& 5.53		&			&			&5.56 	\\	
                        &$^3\Delta_u	(\mathrm{V};\pi \rightarrow \pis)$ 			&		&99.0& 6.40		&			&			&6.40 	\\	
                        &$^3\Sigma_u^- (\mathrm{V};\pi \rightarrow \pis)$ 			&		&98.8& 7.08		&			&			&7.09 	\\	
                        &$^1A_u [\mathrm{F}]	(\mathrm{V};\pi \rightarrow \pis)$	&		&95.6& 3.64		&			&			&3.63 	\\	
                        &$^1A_2 [\mathrm{F}]	(\mathrm{V};\pi \rightarrow \pis)$	&		&95.5& 3.85		&			&			&3.85	\\	
      Ammonia		&$^1A_2 (\Ryd;n \rightarrow 3s)$ 						& 0.086	&93.5& 6.59		&{\exCI}/AVQZ & dAV5Z		&6.66 	\\
                        &$^1E (\Ryd;n \rightarrow 3p)$ 							& 0.006	&93.7& 8.16		&			&			&8.21	\\	
                        &$^1A_1 (\Ryd;n \rightarrow 3p)$ 						& 0.003	&94.0& 9.33		&			&			&8.65 	\\
                        &$^1A_2 (\Ryd;n \rightarrow 4s)$ 						& 0.008	&93.6& 9.96		&{\exCI}/AVTZ  & dAV5Z		&9.19 	\\
                        &$^3A_2 (\Ryd;n \rightarrow 3s)$ 						&		&98.2& 6.31		&{\exCI}/AVQZ & dAV5Z		&6.37	\\
      Carbon monoxyde	&$^1\Pi (\mathrm{V};n \rightarrow \pis)$ 				& 0.084	&93.1 & 8.49		& {\exCI}/AVQZ& dAV5Z		&8.48	\\
                        &$^1\Sigma^- (\mathrm{V};\pi \rightarrow \pis)$				&		&93.3 & 9.92		&			&			&9.98 	\\
                        &$^1\Delta (\mathrm{V};\pi \rightarrow \pis)$ 				&		&91.8 &10.06		&			&			&10.10 	\\
                        &$^1\Sigma^+ (\Ryd)$ 								& 0.003	&91.5 &10.95		&			&			&10.80 	\\
                        &$^1\Sigma^+ (\Ryd)$ 								& 0.200	&92.9 &11.52		&			&			&11.42 	\\
                        &$^1\Pi (\Ryd)$										& 0.053	&92.4 &11.72		&			&			&11.55 	\\
                        &$^3\Pi (\mathrm{V};n \rightarrow \pis)$ 					&		&98.7 & 6.28		&			&			&6.28 	\\
                        &$^3\Sigma^+ (\mathrm{V};\pi \rightarrow \pis)$			&		&98.7 & 8.45		&			&			&8.49 	\\
                        &$^3\Delta (\mathrm{V};\pi \rightarrow \pis)$ 				&		&98.4 & 9.27		&			&			&9.28 	\\
                        &$^3\Sigma^- (\mathrm{V};\pi \rightarrow \pis)$				&		&97.5 & 9.80		&			&			&9.77	\\
                        &$^3\Sigma^+ (\Ryd)$ 								&		&98.0 & 10.47		&  {\exCI}/AVTZ &dAV5Z		&10.37 	\\
      Cyclopropene	&$^1B_1 (\mathrm{V};\sigma \rightarrow \pis)$				& 0.001	&92.8 &6.68$^b$	& {\CCSDT}/AVTZ&AVQZ		& 6.68 	\\
                        &$^1B_2 (\mathrm{V};\pi \rightarrow \pis)$				& 0.071	&95.1 &6.79$^a$	& {\exCI}/AVDZ	    &AVQZ		& 6.78 	\\
                        &$^3B_2 (\mathrm{V};\pi \rightarrow \pis)$				&		&98.0 &4.38		& {\exCI}/AVTZ     &AVQZ 	& 4.38	 \\
                        &$^3B_1 (\mathrm{V};\sigma \rightarrow \pis)$				& 		&98.9 &6.45		& 			    &			& 6.45 	\\
      Diazomethane	&$^1A_2 (\mathrm{V};\pi \rightarrow \pis)$ 				&		&90.1 &3.14		&{\exCI}/AVTZ & dAVQZ		&3.13 	\\
                        &$^1B_1 (\Ryd;\pi \rightarrow 3s)$ 						& 0.002	&93.8 &5.54		&			&			&5.59 	\\
                        &$^1A_1 (\mathrm{V};\pi \rightarrow \pis)$				& 0.210	&91.4 &5.90		&			&			& 5.89	 \\
                        &$^3A_2 (\mathrm{V};\pi \rightarrow \pis)$ 				&		&97.7 &2.79$^a$	& {\exCI}/AVDZ & dAVQZ		&2.80	\\
                        &$^3A_1 (\mathrm{V};\pi \rightarrow \pis)$				&		&98.6 &4.05		& {\exCI}/AVTZ & dAVQZ		&4.05	\\
                        &$^3B_1 (\Ryd;\pi \rightarrow 3s)$ 						&		&98.0 &5.35		&			&			&5.40 	\\
                        &$^3A_1 (\Ryd;\pi \rightarrow 3p)$						&		&98.5 &6.82		&			&			&6.72 	\\
                        &$^1A'' [\mathrm{F}]	(\mathrm{V};\pi \rightarrow \pis)$		&		&87.4 &0.71		& 			 & 			& 0.70 	\\
      Dinitrogen		&$^1\Pi_g (\mathrm{V};n \rightarrow \pis)$ 				&		&92.6 &9.34		& {\exCI}/AVQZ&dAV5Z		&9.33	 \\
                        &$^1\Sigma_u^- (\mathrm{V};\pi \rightarrow \pis)$			&		&97.2 &9.88		&			&			&9.91	 \\
                        &$^1\Delta_u (\mathrm{V};\pi \rightarrow \pis)$ 				& 0.000	&95.9 &10.29		&			&			&10.31	 \\
                        &$^1\Sigma_g^+ (\Ryd)$ 								&		&92.2 &12.98		&			&			&12.30	 \\
                        &$^1\Pi_u (\Ryd)$ 									& 0.229	&82.9 &13.03		& {\exCI}/AVTZ&dAV5Z		&12.73	 \\
                        &$^1\Sigma_u^+ (\Ryd)$ 								& 0.296	&92.8 &13.09		&			&			&12.95	 \\
                        &$^1\Pi_u (\Ryd)$ 									& 0.000	&87.4 &13.46		&			&			&13.27	 \\
                        &$^3\Sigma_u^+ (\mathrm{V};\pi \rightarrow \pis)$			&		&99.3 &7.70		& {\exCI}/AVQZ&dAV5Z		&7.74	 \\
                        &$^3\Pi_g (\mathrm{V};n \rightarrow \pis)$ 				&		&98.4 &8.01		&			&			&8.03	 \\
                        &$^3\Delta_u (\mathrm{V};\pi \rightarrow \pis)$ 				&		&99.3 &8.87		&			&			&8.88	 \\
                        &$^3\Sigma_u^- (\mathrm{V};\pi \rightarrow \pis)$			&		&98.8 &9.66		&			&			&9.65	 \\
      Ethylene		&$^1B_{3u} (\Ryd;\pi \rightarrow 3s)$ 					& 0.078	&95.1 &7.40		&{\exCI}/AVTZ & dAV5Z		&7.44	 \\
                        &$^1B_{1u} (\mathrm{V};\pi \rightarrow \pis)$ 				& 0.346	&95.8 &7.91$^a$	&{\exCI}/AVDZ& dAV5Z		&7.89	\\
                        &$^1B_{1g} (\Ryd;\pi \rightarrow 3p)$ 					&		&95.3 &8.07		& {\exCI}/AVTZ& dAV5Z		&8.09	\\
                        &$^3B_{1u} (\mathrm{V};\pi \rightarrow \pis)$ 				&		&99.1 &4.54		& 			&			&4.54	\\
                        &$^3B_{3u} (\Ryd;\pi \rightarrow 3s)$ 					&		&98.5 &7.23$^a$	&{\exCI}/AVDZ& dAV5Z		&7.28	\\
                        &$^3B_{1g} (\Ryd;\pi \rightarrow 3p)$ 					&		&98.4 &7.98$^a$	&			&			&8.00	\\
      Formaldehyde	&$^1A_2 (\mathrm{V}; n \rightarrow \pis)$ 				&		&91.5 &3.98		&{\exCI}/AVTZ & dAV5Z		&3.97	\\
                        &$^1B_2 (\Ryd;n \rightarrow 3s)$ 						& 0.021	&91.7 &7.23		&			 &			&7.30	\\
                        &$^1B_2 (\Ryd;n \rightarrow 3p)$ 						& 0.037	&92.4 &8.13		&			&			&8.14	\\
                        &$^1A_1 (\Ryd;n \rightarrow 3p)$ 						& 0.052	&91.9 &8.23		&			&			&8.27	\\
                        &$^1A_2 (\Ryd;n \rightarrow 3p)$ 						&		&91.7 &8.67		&			&			&8.50	\\
                        &$^1B_1 (\mathrm{V};\sigma \rightarrow \pis)$				& 0.001	&90.8 &9.22		&			&			&9.21	\\
                        &$^1A_1 (\mathrm{V};\pi \rightarrow \pis)$				& 0.135	&90.4 &9.43		&			&			&9.26	\\
                        &$^3A_2 (\mathrm{V};n \rightarrow \pis)$ 					&		&98.1 &3.58		&			&			&3.58	\\
                        &$^3A_1 (\mathrm{V};\pi \rightarrow \pis)$				&		&99.0 &6.06		&			&			&6.07	\\
                        &$^3B_2 (\Ryd;n \rightarrow 3s)$ 						&		&97.1 &7.06		&			&			&7.14	\\
                        &$^3B_2 (\Ryd;n \rightarrow 3p)$ 						&		&97.4 &7.94		&			&			&7.96	\\
                        &$^3A_1 (\Ryd;n \rightarrow 3p)$ 						&		&97.2 &8.10		&			&			&8.15	\\
                        &$^3B_1 (\Ryd;n \rightarrow 3d)$ 						&		&97.9 &8.42		&			&			&8.42	\\
                        &$^1A'' [\mathrm{F}] (\mathrm{V};n \rightarrow \pis)$			&		&87.8 &2.80		&			&			&2.80	\\
      Formamide	&$^1A'' (\mathrm{V};n \rightarrow \pis)$					&0.000	&90.8 &5.65$^a$	&{\exCI}/AVDZ& AVQZ		&5.63	\\
                        &$^1A' (\Ryd;n \rightarrow 3s)$							&0.001	&88.6 &6.77$^a$	&			&			&6.81	\\
                        &$^1A' (\mathrm{V};\pi \rightarrow \pis)$					&0.251	&89.3 &7.63		&{\exCI}/AVTZ & AVQZ		&7.64	\\
                        &$^1A' (\Ryd;n \rightarrow 3p)$							&0.111	&89.6 &7.38$^b$	&{\CCSDT}/AVTZ& AVQZ		&7.41	\\
                        &$^3A'' (\mathrm{V};n \rightarrow \pis)$					&		&97.7 &5.38$^c$	&{\exCI}/AVDZ& AVQZ		&5.37	\\
                        &$^3A' (\mathrm{V};\pi \rightarrow \pis)$					&		&98.2 &5.81$^c$	&			&			&5.81	\\
      Hydrogen chloride	 & $^1\Pi (\mathrm{CT})$							&0.056	&94.3 &7.84		& {\exCI}/AVQZ &dAV5Z		&7.86	\\	
      Hydrogen sulfide &$^1A_2 (\Ryd;n \rightarrow 4p)$ 						&		&94.6 &6.18		& {\exCI}/AVQZ &dAV5Z		&6.10	\\
                        &$^1B_1 (\Ryd;n \rightarrow 4s)$ 						& 0.063	&94.3 &6.24		&  			&			&6.29	\\
                        &$^3A_2 (\Ryd;n \rightarrow 4p)$ 						&		&98.7 &5.81		&  			&			&5.74	\\
                        &$^3B_1 (\Ryd;n \rightarrow 4s)$ 						&		&98.4 &5.88		& 			&			&5.94	 \\
      Ketene		&$^1A_2 (\mathrm{V};\pi \rightarrow \pis)$ 				&		&91.0 &3.86		&{\exCI}/AVTZ & dAVQZ		&3.86	\\
                        &$^1B_1 (\Ryd;n \rightarrow 3s)$ 						& 0.035	&93.9 &6.01		&			&			&6.06	\\
                        &$^1A_2 (\Ryd;\pi \rightarrow 3p)$ 						&		&94.4 &7.18		&			&			&7.19	\\
                        &$^3A_2 (\mathrm{V};n \rightarrow \pis)$ 					&		&91.0 &3.77		&			&			&3.77	\\
                        &$^3A_1 (\mathrm{V};\pi \rightarrow \pis)$ 				&		&98.6 &5.61		&			&			&5.60	\\
                        &$^3B_1 (\Ryd;n \rightarrow 3s)$ 						&		&98.1 &5.79		&			&			&5.85	\\
                        &$^3A_2 (\Ryd;\pi \rightarrow 3p)$ 						&		&94.4 &7.12		&			&			&7.14	\\
                        &$^1A'' [\mathrm{F}] (\mathrm{V};\pi \rightarrow \pis)$		&		&87.9 &1.00		&			 & 			&1.00	\\
      Methanimine	&$^1A''(\mathrm{V}; n \rightarrow \pis)$ 					&0.003	&90.7 &5.23		&{\exCI}/AVTZ & dAVQZ		&5.21	\\
                        &$^3A'' (\mathrm{V}; n \rightarrow \pis)$					&		&98.1 &4.65		&			&			&4.64	\\	
      Nitrosomethane&$^1A'' (\mathrm{V};n \rightarrow \pis)$					& 0.000	&93.0 &1.96$^a$	& {\exCI}/AVDZ & AVQZ		&1.95	 \\
                        &$^1A' (\mathrm{V};n,n \rightarrow \pis,\pis)$				&0.000	&2.5	  &\emph{4.72}		& {\exCI}/AVTZ & AVQZ		& \emph{4.69}	\\
                        &$^1A' (\Ryd;n \rightarrow 3s/3p)$ 						&0.006	&90.8 &6.40$^a$	&{\exCI}/AVDZ	& AVQZ		&6.42 	\\
                        &$^3A'' (\mathrm{V};n \rightarrow \pis)$					&		&98.4 &1.16		&			&			&1.16 	\\
                        &$^3A' (\mathrm{V};\pi \rightarrow \pis)$					&		&98.9 &5.60		&			&			&5.61	\\
                        &$^1A'' [\mathrm{F}]	(\mathrm{V};n \rightarrow \pis)$			&		&92.7&1.67$^a$	&{\exCI}/AVDZ	& AVQZ		&1.66	\\
      Streptocyanine-C1&$^1B_2 (\mathrm{V};\pi \rightarrow \pis)$ 				& 0.347	&88.7&7.13$^a$	& {\exCI}/AVDZ & AVQZ		&7.12	\\
                        &	$^3B_2 (\mathrm{V};\pi \rightarrow \pis)$ 				& 		&98.3 &5.52		& {\exCI}/AVTZ & AVQZ		&5.52	 \\
      Thioformaldehyde&$^1A_2 (\mathrm{V};n \rightarrow \pis)$ 				&		&89.3 &2.22		&  {\exCI}/AVTZ & dAVQZ		&2.20	\\
                        &$^1B_2 (\Ryd;n \rightarrow 4s)$ 						& 0.012	&92.3 &5.96		&			&			&5.99	\\
                        &$^1A_1 (\mathrm{V};\pi \rightarrow \pis)$				& 0.178	&90.8 &6.38$^d$	&{\CCSDTQ}/AVDZ& dAVQZ	&6.34	\\
                        &$^3A_2 (\mathrm{V};n \rightarrow \pis)$ 					&		&97.7 &1.94		&{\exCI}/AVTZ & dAVQZ		&1.94	\\
                        &$^3A_1 (\mathrm{V};\pi \rightarrow \pis)$				&		&98.9 & 3.43		&			&			&3.44	\\
                        &$^3B_2 (\Ryd;n \rightarrow 4s)$ 						&		&97.6 &5.72$^a$	&{\exCI}/AVDZ& dAVQZ		&5.76	\\
                        &$^1A_2 [\mathrm{F}] (\mathrm{V};n \rightarrow \pis)$		&		&87.2 &1.95		&{\exCI}/AVTZ & dAVQZ		&1.94	\\
      Water		& $^1B_1 (\Ryd; n \rightarrow 3s)$ 						& 0.054	&93.4 &7.62		& {\exCI}/AVQZ&dAV5Z 		&7.70	 \\
                        & $^1A_2 (\Ryd; n \rightarrow 3p)$ 						& 		&93.6 &9.41		&			&			&9.47 	 \\	
                        & $^1A_1 (\Ryd; n \rightarrow 3s)$ 						& 0.100	&93.6 &9.99		&			&			&9.97	 \\	
                        & $^3B_1 (\Ryd; n \rightarrow 3s)$ 						& 		&98.1 &7.25		&			&			&7.33	 \\	
                        & $^3A_2 (\Ryd; n \rightarrow 3p)$ 						& 		&98.0 &9.24 		&			&			&9.30	 \\	
                        & $^3A_1 (\Ryd; n \rightarrow 3s)$ 						& 		&98.2 &9.54		&			&			&9.59	 \\	
       \end{tabular}