BSEdyn/Data/diacetylene_aVDZ.out

4085 lines
286 KiB
Plaintext

******************************************************************************************
* QuAcK QuAcK QuAcK *
* __ __ __ __ __ __ __ __ __ *
* <(o )___ <(o )___ <(o )___ <(o )___ <(o )___ <(o )___ <(o )___ <(o )___ <(o )___ *
* ( ._> / ( ._> / ( ._> / ( ._> / ( ._> / ( ._> / ( ._> / ( ._> / ( ._> / *
*|--------------------------------------------------------------------------------------|*
******************************************************************************************
----------------------
Number of atoms 6
----------------------
----------------------
Number of spin-up electron 13
Number of spin-down electron 13
Total number of electron 26
----------------------
----------------------
Number of core electron 0
Number of Rydberg electron 0
----------------------
------------------
Molecular geometry
------------------
Atom n. 1
Z = 6.0000000000
Atom coordinates: 0.0000000000 0.0000000000 1.2944770000
Atom n. 2
Z = 6.0000000000
Atom coordinates: 0.0000000000 0.0000000000 -1.2944770000
Atom n. 3
Z = 6.0000000000
Atom coordinates: 0.0000000000 0.0000000000 3.5844842900
Atom n. 4
Z = 6.0000000000
Atom coordinates: 0.0000000000 0.0000000000 -3.5844842900
Atom n. 5
Z = 1.0000000000
Atom coordinates: 0.0000000000 0.0000000000 5.5894300300
Atom n. 6
Z = 1.0000000000
Atom coordinates: 0.0000000000 0.0000000000 -5.5894300300
------------------
Nuclear repulsion energy = 77.0449436965
------------------
Gaussian basis set
------------------
Atom n. 1
number of shells 9
------------------
s-type shell with K = 8
Exponents Contraction
6665.0000000000 0.0006920000
1000.0000000000 0.0053290000
228.0000000000 0.0270770000
64.7100000000 0.1017180000
21.0600000000 0.2747400000
7.4950000000 0.4485640000
2.7970000000 0.2850740000
0.5215000000 0.0152040000
s-type shell with K = 8
Exponents Contraction
6665.0000000000 -0.0001460000
1000.0000000000 -0.0011540000
228.0000000000 -0.0057250000
64.7100000000 -0.0233120000
21.0600000000 -0.0639550000
7.4950000000 -0.1499810000
2.7970000000 -0.1272620000
0.5215000000 0.5445290000
s-type shell with K = 1
Exponents Contraction
0.1596000000 1.0000000000
s-type shell with K = 1
Exponents Contraction
0.0469000000 1.0000000000
p-type shell with K = 3
Exponents Contraction
9.4390000000 0.0381090000
2.0020000000 0.2094800000
0.5456000000 0.5085570000
p-type shell with K = 1
Exponents Contraction
0.1517000000 1.0000000000
p-type shell with K = 1
Exponents Contraction
0.0404100000 1.0000000000
d-type shell with K = 1
Exponents Contraction
0.5500000000 1.0000000000
d-type shell with K = 1
Exponents Contraction
0.1510000000 1.0000000000
------------------
Atom n. 2
number of shells 9
------------------
s-type shell with K = 8
Exponents Contraction
6665.0000000000 0.0006920000
1000.0000000000 0.0053290000
228.0000000000 0.0270770000
64.7100000000 0.1017180000
21.0600000000 0.2747400000
7.4950000000 0.4485640000
2.7970000000 0.2850740000
0.5215000000 0.0152040000
s-type shell with K = 8
Exponents Contraction
6665.0000000000 -0.0001460000
1000.0000000000 -0.0011540000
228.0000000000 -0.0057250000
64.7100000000 -0.0233120000
21.0600000000 -0.0639550000
7.4950000000 -0.1499810000
2.7970000000 -0.1272620000
0.5215000000 0.5445290000
s-type shell with K = 1
Exponents Contraction
0.1596000000 1.0000000000
s-type shell with K = 1
Exponents Contraction
0.0469000000 1.0000000000
p-type shell with K = 3
Exponents Contraction
9.4390000000 0.0381090000
2.0020000000 0.2094800000
0.5456000000 0.5085570000
p-type shell with K = 1
Exponents Contraction
0.1517000000 1.0000000000
p-type shell with K = 1
Exponents Contraction
0.0404100000 1.0000000000
d-type shell with K = 1
Exponents Contraction
0.5500000000 1.0000000000
d-type shell with K = 1
Exponents Contraction
0.1510000000 1.0000000000
------------------
Atom n. 3
number of shells 9
------------------
s-type shell with K = 8
Exponents Contraction
6665.0000000000 0.0006920000
1000.0000000000 0.0053290000
228.0000000000 0.0270770000
64.7100000000 0.1017180000
21.0600000000 0.2747400000
7.4950000000 0.4485640000
2.7970000000 0.2850740000
0.5215000000 0.0152040000
s-type shell with K = 8
Exponents Contraction
6665.0000000000 -0.0001460000
1000.0000000000 -0.0011540000
228.0000000000 -0.0057250000
64.7100000000 -0.0233120000
21.0600000000 -0.0639550000
7.4950000000 -0.1499810000
2.7970000000 -0.1272620000
0.5215000000 0.5445290000
s-type shell with K = 1
Exponents Contraction
0.1596000000 1.0000000000
s-type shell with K = 1
Exponents Contraction
0.0469000000 1.0000000000
p-type shell with K = 3
Exponents Contraction
9.4390000000 0.0381090000
2.0020000000 0.2094800000
0.5456000000 0.5085570000
p-type shell with K = 1
Exponents Contraction
0.1517000000 1.0000000000
p-type shell with K = 1
Exponents Contraction
0.0404100000 1.0000000000
d-type shell with K = 1
Exponents Contraction
0.5500000000 1.0000000000
d-type shell with K = 1
Exponents Contraction
0.1510000000 1.0000000000
------------------
Atom n. 4
number of shells 9
------------------
s-type shell with K = 8
Exponents Contraction
6665.0000000000 0.0006920000
1000.0000000000 0.0053290000
228.0000000000 0.0270770000
64.7100000000 0.1017180000
21.0600000000 0.2747400000
7.4950000000 0.4485640000
2.7970000000 0.2850740000
0.5215000000 0.0152040000
s-type shell with K = 8
Exponents Contraction
6665.0000000000 -0.0001460000
1000.0000000000 -0.0011540000
228.0000000000 -0.0057250000
64.7100000000 -0.0233120000
21.0600000000 -0.0639550000
7.4950000000 -0.1499810000
2.7970000000 -0.1272620000
0.5215000000 0.5445290000
s-type shell with K = 1
Exponents Contraction
0.1596000000 1.0000000000
s-type shell with K = 1
Exponents Contraction
0.0469000000 1.0000000000
p-type shell with K = 3
Exponents Contraction
9.4390000000 0.0381090000
2.0020000000 0.2094800000
0.5456000000 0.5085570000
p-type shell with K = 1
Exponents Contraction
0.1517000000 1.0000000000
p-type shell with K = 1
Exponents Contraction
0.0404100000 1.0000000000
d-type shell with K = 1
Exponents Contraction
0.5500000000 1.0000000000
d-type shell with K = 1
Exponents Contraction
0.1510000000 1.0000000000
------------------
Atom n. 5
number of shells 5
------------------
s-type shell with K = 3
Exponents Contraction
13.0100000000 0.0196850000
1.9620000000 0.1379770000
0.4446000000 0.4781480000
s-type shell with K = 1
Exponents Contraction
0.1220000000 1.0000000000
s-type shell with K = 1
Exponents Contraction
0.0297400000 1.0000000000
p-type shell with K = 1
Exponents Contraction
0.7270000000 1.0000000000
p-type shell with K = 1
Exponents Contraction
0.1410000000 1.0000000000
------------------
Atom n. 6
number of shells 5
------------------
s-type shell with K = 3
Exponents Contraction
13.0100000000 0.0196850000
1.9620000000 0.1379770000
0.4446000000 0.4781480000
s-type shell with K = 1
Exponents Contraction
0.1220000000 1.0000000000
s-type shell with K = 1
Exponents Contraction
0.0297400000 1.0000000000
p-type shell with K = 1
Exponents Contraction
0.7270000000 1.0000000000
p-type shell with K = 1
Exponents Contraction
0.1410000000 1.0000000000
------------------
Number of shells 46
------------------
------------------
Number of basis functions 118
------------------
Nuclear Coordinates (Angstrom)
------------------------------
-----------------------------------------------------------------------
Center Atomic Element Coordinates (Angstroms)
Number X Y Z
-----------------------------------------------------------------------
1 6 C 0.000000 0.000000 0.685008
2 6 C 0.000000 0.000000 -0.685008
3 6 C 0.000000 0.000000 1.896828
4 6 C 0.000000 0.000000 -1.896828
5 1 H 0.000000 0.000000 2.957799
6 1 H 0.000000 0.000000 -2.957799
-----------------------------------------------------------------------
Nuclear repulsion :
77.0449381146
Atomic Basis set
----------------
-----------------------------------------------------------------------
# Angular Coordinates (Bohr) Exponents Coefficients
Momentum X Y Z
-----------------------------------------------------------------------
1-4 S 0.0000 0.0000 1.2945 6.66500000e+03 6.92000000e-04
1.00000000e+03 5.32900000e-03
2.28000000e+02 2.70770000e-02
6.47100000e+01 1.01718000e-01
2.10600000e+01 2.74740000e-01
7.49500000e+00 4.48564000e-01
2.79700000e+00 2.85074000e-01
5.21500000e-01 1.52040000e-02
6.66500000e+03 -1.46000000e-04
1.00000000e+03 -1.15400000e-03
2.28000000e+02 -5.72500000e-03
6.47100000e+01 -2.33120000e-02
2.10600000e+01 -6.39550000e-02
7.49500000e+00 -1.49981000e-01
2.79700000e+00 -1.27262000e-01
5.21500000e-01 5.44529000e-01
1.59600000e-01 1.00000000e+00
4.69000000e-02 1.00000000e+00
-----------------------------------------------------------------------
5-13 P 0.0000 0.0000 1.2945 9.43900000e+00 3.81090000e-02
2.00200000e+00 2.09480000e-01
5.45600000e-01 5.08557000e-01
1.51700000e-01 1.00000000e+00
4.04100000e-02 1.00000000e+00
-----------------------------------------------------------------------
14-25 D 0.0000 0.0000 1.2945 5.50000000e-01 1.00000000e+00
1.51000000e-01 1.00000000e+00
-----------------------------------------------------------------------
26-29 S 0.0000 0.0000 -1.2945 6.66500000e+03 6.92000000e-04
1.00000000e+03 5.32900000e-03
2.28000000e+02 2.70770000e-02
6.47100000e+01 1.01718000e-01
2.10600000e+01 2.74740000e-01
7.49500000e+00 4.48564000e-01
2.79700000e+00 2.85074000e-01
5.21500000e-01 1.52040000e-02
6.66500000e+03 -1.46000000e-04
1.00000000e+03 -1.15400000e-03
2.28000000e+02 -5.72500000e-03
6.47100000e+01 -2.33120000e-02
2.10600000e+01 -6.39550000e-02
7.49500000e+00 -1.49981000e-01
2.79700000e+00 -1.27262000e-01
5.21500000e-01 5.44529000e-01
1.59600000e-01 1.00000000e+00
4.69000000e-02 1.00000000e+00
-----------------------------------------------------------------------
30-38 P 0.0000 0.0000 -1.2945 9.43900000e+00 3.81090000e-02
2.00200000e+00 2.09480000e-01
5.45600000e-01 5.08557000e-01
1.51700000e-01 1.00000000e+00
4.04100000e-02 1.00000000e+00
-----------------------------------------------------------------------
39-50 D 0.0000 0.0000 -1.2945 5.50000000e-01 1.00000000e+00
1.51000000e-01 1.00000000e+00
-----------------------------------------------------------------------
51-54 S 0.0000 0.0000 3.5845 6.66500000e+03 6.92000000e-04
1.00000000e+03 5.32900000e-03
2.28000000e+02 2.70770000e-02
6.47100000e+01 1.01718000e-01
2.10600000e+01 2.74740000e-01
7.49500000e+00 4.48564000e-01
2.79700000e+00 2.85074000e-01
5.21500000e-01 1.52040000e-02
6.66500000e+03 -1.46000000e-04
1.00000000e+03 -1.15400000e-03
2.28000000e+02 -5.72500000e-03
6.47100000e+01 -2.33120000e-02
2.10600000e+01 -6.39550000e-02
7.49500000e+00 -1.49981000e-01
2.79700000e+00 -1.27262000e-01
5.21500000e-01 5.44529000e-01
1.59600000e-01 1.00000000e+00
4.69000000e-02 1.00000000e+00
-----------------------------------------------------------------------
55-63 P 0.0000 0.0000 3.5845 9.43900000e+00 3.81090000e-02
2.00200000e+00 2.09480000e-01
5.45600000e-01 5.08557000e-01
1.51700000e-01 1.00000000e+00
4.04100000e-02 1.00000000e+00
-----------------------------------------------------------------------
64-75 D 0.0000 0.0000 3.5845 5.50000000e-01 1.00000000e+00
1.51000000e-01 1.00000000e+00
-----------------------------------------------------------------------
76-79 S 0.0000 0.0000 -3.5845 6.66500000e+03 6.92000000e-04
1.00000000e+03 5.32900000e-03
2.28000000e+02 2.70770000e-02
6.47100000e+01 1.01718000e-01
2.10600000e+01 2.74740000e-01
7.49500000e+00 4.48564000e-01
2.79700000e+00 2.85074000e-01
5.21500000e-01 1.52040000e-02
6.66500000e+03 -1.46000000e-04
1.00000000e+03 -1.15400000e-03
2.28000000e+02 -5.72500000e-03
6.47100000e+01 -2.33120000e-02
2.10600000e+01 -6.39550000e-02
7.49500000e+00 -1.49981000e-01
2.79700000e+00 -1.27262000e-01
5.21500000e-01 5.44529000e-01
1.59600000e-01 1.00000000e+00
4.69000000e-02 1.00000000e+00
-----------------------------------------------------------------------
80-88 P 0.0000 0.0000 -3.5845 9.43900000e+00 3.81090000e-02
2.00200000e+00 2.09480000e-01
5.45600000e-01 5.08557000e-01
1.51700000e-01 1.00000000e+00
4.04100000e-02 1.00000000e+00
-----------------------------------------------------------------------
89-100D 0.0000 0.0000 -3.5845 5.50000000e-01 1.00000000e+00
1.51000000e-01 1.00000000e+00
-----------------------------------------------------------------------
101-103S 0.0000 0.0000 5.5894 1.30100000e+01 1.96850000e-02
1.96200000e+00 1.37977000e-01
4.44600000e-01 4.78148000e-01
1.22000000e-01 1.00000000e+00
2.97400000e-02 1.00000000e+00
-----------------------------------------------------------------------
104-109P 0.0000 0.0000 5.5894 7.27000000e-01 1.00000000e+00
1.41000000e-01 1.00000000e+00
-----------------------------------------------------------------------
110-112S 0.0000 0.0000 -5.5894 1.30100000e+01 1.96850000e-02
1.96200000e+00 1.37977000e-01
4.44600000e-01 4.78148000e-01
1.22000000e-01 1.00000000e+00
2.97400000e-02 1.00000000e+00
-----------------------------------------------------------------------
113-118P 0.0000 0.0000 -5.5894 7.27000000e-01 1.00000000e+00
1.41000000e-01 1.00000000e+00
-----------------------------------------------------------------------
1052 significant shell pairs computed in 0.109263 seconds
1
2
3
4
7
10
13
19
25
26
27
28
29
32
35
38
44
50
51
52
53
54
57
60
63
69
75
76
77
78
79
82
85
88
94
100
101
102
103
106
109
110
111
112
115
Computed ERIs in 28.246431 seconds
Scaling integrals by 1.0000000000000000
Total CPU time for reading integrals = 9.903 seconds
Eigenvalue 1 is very small in Lowdin orthogonalization = 1.3508533088692473E-008
Eigenvalue 2 is very small in Lowdin orthogonalization = 8.4439218254170106E-008
************************************************
| Restricted Hartree-Fock calculation |
************************************************
----------------------------------------------------
| RHF calculation |
----------------------------------------------------
| # | HF energy | Conv | HL Gap |
----------------------------------------------------
| 1 | -114.1508046301 | 0.652762 | 0.007729 |
| 2 | -148.3238952958 | 1.237243 | 0.008382 |
| 3 | -138.4882154997 | 1.051508 | 0.025504 |
| 4 | -143.6912130002 | 1.002164 | 0.025425 |
| 5 | -142.2550947118 | 1.043884 | 0.025436 |
| 6 | -178.9387382702 | 1.042398 | 0.024540 |
| 7 | -139.7320285152 | 1.059584 | 0.306794 |
| 8 | -152.0336439207 | 0.199185 | 0.403289 |
| 9 | -152.2998684167 | 0.076014 | 0.417272 |
| 10 | -152.2190555538 | 0.043749 | 0.401924 |
| 11 | -152.4911791979 | 0.006028 | 0.401597 |
| 12 | -152.5202162580 | 0.001047 | 0.403989 |
| 13 | -152.5120926571 | 0.000509 | 0.404066 |
| 14 | -152.5128792547 | 0.000127 | 0.404031 |
| 15 | -152.5130719097 | 0.000046 | 0.404058 |
| 16 | -152.5129852889 | 0.000004 | 0.404062 |
| 17 | -152.5129740963 | 0.000003 | 0.404063 |
| 18 | -152.5129731304 | 0.000001 | 0.404063 |
| 19 | -152.5129730888 | 0.000000 | 0.404063 |
----------------------------------------------------
-----------------------------------------
Summary
-----------------------------------------
One-electron energy = -356.6361313607
Kinetic energy = 152.1845370925
Potential energy = -508.8206684532
-----------------------------------------
Two-electron energy = 127.0782145754
Coulomb energy = 148.3599946271
Exchange energy = -21.2817800518
-----------------------------------------
Electronic energy = -229.5579167853
Nuclear repulsion = 77.0449436965
Hartree-Fock energy = -152.5129730888
-----------------------------------------
HF HOMO energy (eV) = -10.072307
HF LUMO energy (eV) = 0.922808
HF HOMO-LUMO gap (eV) = 10.995115
-----------------------------------------
---------------------------------------
MO coefficients
---------------------------------------
1 2 3 4 5
1 -0.69576801 0.69312267 0.13166697 -0.15101734 0.02516601
2 -0.00775288 0.01068485 0.00216494 -0.00316672 -0.54982597
3 0.19090252 -1.08060928 -0.22812065 0.81304806 3.56611627
4 0.01568636 0.01109913 -0.00011319 -0.00877550 0.12406201
5 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
6 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
7 0.00130295 -0.00138767 -0.00033744 0.00024329 -0.00978806
8 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
9 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
10 0.11574269 0.18522682 -0.14023092 -0.17633650 2.35078759
11 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
12 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
13 0.00689654 0.00657401 -0.00067388 0.00901511 0.09453014
14 0.00150636 -0.00151258 -0.00025197 0.00017088 0.01164292
15 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
16 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
17 0.00150636 -0.00151258 -0.00025197 0.00017088 0.01164292
18 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
19 0.00077350 0.00133942 -0.00009699 0.00077180 -0.03859113
20 0.00263713 -0.02467339 -0.00472643 0.01899126 0.09075382
21 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
22 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
23 0.00263713 -0.02467339 -0.00472643 0.01899126 0.09075382
24 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
25 0.07990427 -0.29883823 -0.09930428 0.22725217 1.70360006
26 -0.69576760 -0.69312317 0.13158927 0.15108468 0.02516597
27 -0.00775289 -0.01068485 0.00216330 0.00316783 -0.54982631
28 0.19091297 1.08060696 -0.22769378 -0.81316686 3.56625720
29 0.01568619 -0.01109910 -0.00011795 0.00877545 0.12405908
30 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
31 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
32 -0.00130295 -0.00138767 0.00033732 0.00024346 0.00978814
33 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
34 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
35 -0.11573999 0.18522822 0.14032319 -0.17626341 -2.35075383
36 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
37 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
38 -0.00689653 0.00657402 0.00066928 0.00901547 -0.09452969
39 0.00150635 0.00151259 -0.00025188 -0.00017101 0.01164292
40 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
41 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
42 0.00150635 0.00151259 -0.00025188 -0.00017101 0.01164292
43 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
44 0.00077350 -0.00133942 -0.00009660 -0.00077185 -0.03859109
45 0.00263739 0.02467334 -0.00471645 -0.01899372 0.09075731
46 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
47 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
48 0.00263739 0.02467334 -0.00471645 -0.01899372 0.09075731
49 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
50 0.07990724 0.29883730 -0.09918497 -0.22730383 1.70363997
51 -0.13064101 0.14940216 -0.69653241 0.69225505 0.02259525
52 -0.00113309 0.00013791 -0.00850028 0.00821630 -0.33802984
53 -0.24559993 0.45718427 0.30228148 -0.31552437 -5.16360728
54 -0.01299833 -0.01840102 0.00172789 -0.01375701 -0.11562508
55 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
56 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
57 0.00044082 0.00044197 -0.00033137 0.00050489 0.14835123
58 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
59 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
60 0.10796203 -0.17342665 -0.12889054 0.11353033 2.13519115
61 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
62 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
63 0.00208323 0.00475164 0.00062577 0.00269200 -0.00021360
64 0.00048033 -0.00031538 0.00151620 -0.00138879 0.00444621
65 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
66 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
67 0.00048033 -0.00031538 0.00151620 -0.00138879 0.00444621
68 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
69 -0.00104265 0.00022253 0.00012861 -0.00035996 -0.01439042
70 -0.00537163 0.01220159 0.00570412 -0.00607655 -0.12524301
71 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
72 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
73 -0.00537163 0.01220159 0.00570412 -0.00607655 -0.12524301
74 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
75 -0.03092002 0.04690175 0.03665348 -0.02777272 -0.61149376
76 -0.13064079 -0.14940196 -0.69617760 -0.69261196 0.02259525
77 -0.00113309 -0.00013792 -0.00849607 -0.00822066 -0.33803008
78 -0.24560363 -0.45718132 0.30211557 0.31568178 -5.16365958
79 -0.01299823 0.01840100 0.00172101 0.01375789 -0.11562283
80 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
81 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
82 -0.00044082 0.00044197 0.00033111 0.00050506 -0.14835133
83 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
84 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
85 -0.10796328 -0.17342534 0.12883079 0.11359749 -2.13520920
86 0.00000000 0.00000000 0.00000000 0.00000000 0.00000000
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48 27.40821293 -11.38377796 79.41376493
49 0.00000000 0.00000000 0.00000000
50 342.20697872 -239.52512761 944.42952909
51 2.55428039 -2.32118635 -1.97291486
52 7.54254683 -6.76897940 -6.08577402
53 353.46111244 760.73408673 1411.26154627
54 -34.22244381 12.38335617 -23.94973266
55 0.00000000 0.00000000 0.00000000
56 0.00000000 0.00000000 0.00000000
57 -0.97285884 -0.04676274 0.78198821
58 -0.00000000 0.00000000 -0.00000000
59 -0.00000000 -0.00000000 -0.00000000
60 -108.72405186 -333.06819212 -529.20791858
61 0.00000000 0.00000000 0.00000000
62 0.00000000 0.00000000 0.00000000
63 8.08571304 -0.05713845 7.94783389
64 1.22958243 -1.09338677 -0.43819442
65 0.00000000 0.00000000 0.00000000
66 0.00000000 0.00000000 0.00000000
67 1.22958243 -1.09338677 -0.43819442
68 0.00000000 0.00000000 0.00000000
69 2.17569066 -2.38296518 -2.27360370
70 12.63497415 15.36577567 34.80632771
71 0.00000000 0.00000000 0.00000000
72 0.00000000 -0.00000000 0.00000000
73 12.63497415 15.36577567 34.80632771
74 0.00000000 0.00000000 0.00000000
75 26.20683557 97.69630999 141.54655096
76 -2.55428164 -2.32118411 1.97291561
77 -7.54255032 -6.76897259 6.08577636
78 -353.46092057 760.73448800 -1411.26203885
79 34.22246110 12.38332193 23.94973465
80 0.00000000 0.00000000 0.00000000
81 0.00000000 0.00000000 0.00000000
82 -0.97285892 0.04676415 0.78198809
83 0.00000000 -0.00000000 0.00000000
84 0.00000000 0.00000000 0.00000000
85 -108.72396629 333.06832347 -529.20813303
86 0.00000000 0.00000000 -0.00000000
87 0.00000000 0.00000000 0.00000000
88 8.08571494 0.05712989 7.94783533
89 -1.22958308 -1.09338604 0.43819467
90 0.00000000 0.00000000 0.00000000
91 0.00000000 0.00000000 0.00000000
92 -1.22958308 -1.09338604 0.43819467
93 0.00000000 0.00000000 0.00000000
94 -2.17569257 -2.38296274 2.27360402
95 -12.63497118 15.36578880 -34.80633869
96 0.00000000 0.00000000 0.00000000
97 0.00000000 -0.00000000 0.00000000
98 -12.63497118 15.36578880 -34.80633869
99 0.00000000 0.00000000 0.00000000
100 -26.20680945 97.69634250 -141.54661372
101 -1.04330030 1.66536766 1.88311500
102 -6.29116436 -4.59448602 -15.36054551
103 -3.78113478 -0.27365461 -2.71628677
104 0.00000000 0.00000000 0.00000000
105 0.00000000 0.00000000 0.00000000
106 0.58828771 -0.69195445 -0.58911569
107 0.00000000 0.00000000 -0.00000000
108 0.00000000 0.00000000 -0.00000000
109 2.35778835 -2.90377181 1.46480756
110 1.04330161 1.66536614 -1.88311530
111 6.29116139 -4.59449187 15.36054787
112 3.78113507 -0.27365811 2.71628713
113 0.00000000 0.00000000 0.00000000
114 0.00000000 0.00000000 0.00000000
115 0.58828830 0.69195372 -0.58911578
116 0.00000000 0.00000000 0.00000000
117 0.00000000 0.00000000 0.00000000
118 2.35778899 2.90376983 1.46480574
---------------------------------------
MO energies
---------------------------------------
1
1 -11.27986559
2 -11.27872326
3 -11.27022011
4 -11.27017377
5 -1.09550979
6 -1.02422799
7 -0.85427423
8 -0.73525995
9 -0.70657254
10 -0.49236147
11 -0.49236147
12 -0.37015046
13 -0.37015046
14 0.03391257
15 0.03481829
16 0.08043311
17 0.08043311
18 0.08716897
19 0.10938799
20 0.10938799
21 0.11612244
22 0.12935926
23 0.12935926
24 0.13296848
25 0.16162873
26 0.19736413
27 0.19736413
28 0.20283269
29 0.23695861
30 0.23695861
31 0.25641899
32 0.26969641
33 0.31384998
34 0.31803790
35 0.31803790
36 0.33928054
37 0.35325716
38 0.38543795
39 0.38543795
40 0.43881135
41 0.43881135
42 0.45955745
43 0.45955745
44 0.46524015
45 0.49386407
46 0.49386407
47 0.52019180
48 0.56464683
49 0.57532114
50 0.59591521
51 0.59591521
52 0.62749329
53 0.67779009
54 0.72153902
55 0.76754882
56 0.76754882
57 0.78981804
58 0.79252782
59 0.79252782
60 0.79711624
61 0.79711624
62 0.80838433
63 0.83363846
64 0.83363846
65 0.87756394
66 0.87756394
67 0.93988514
68 0.93988514
69 1.10281892
70 1.19348601
71 1.22081873
72 1.22081873
73 1.22260320
74 1.33018298
75 1.33018298
76 1.37898069
77 1.40779706
78 1.48955525
79 1.48955525
80 1.52717467
81 1.56354521
82 1.58166597
83 1.58166597
84 1.60623149
85 1.60623149
86 1.67330935
87 1.67330935
88 1.71954560
89 1.83240692
90 1.83240692
91 1.84638975
92 1.84638975
93 1.84853137
94 1.89063461
95 2.01288521
96 2.01288521
97 2.05523313
98 2.05523313
99 2.27065061
100 2.29137596
101 2.40880275
102 2.40880275
103 2.45138104
104 2.54382220
105 2.54382220
106 2.92181391
107 2.92782952
108 2.94576942
109 3.11693419
110 3.11693419
111 3.47626066
112 4.04679574
113 4.07761926
114 4.38518635
115 5.37821544
116 6.39194817
117 6.99769146
118 12.17247692
Total CPU time for RHF = 4.958 seconds
AO to MO transformation... Please be patient
Total CPU time for AO to MO transformation = 76.363 seconds
************************************************
| One-shot G0W0 calculation |
************************************************
*** Quasiparticle energies obtained by linearization ***
-------------------------------------------------------------------------------
One-shot G0W0 calculation
-------------------------------------------------------------------------------
| # | e_HF (eV) | Sigma_c (eV) | Z | e_QP (eV) |
-------------------------------------------------------------------------------
| 1 | -306.940777 | 11.307272 | 0.818891 | -297.681350 |
| 2 | -306.909693 | 11.305212 | 0.818863 | -297.652273 |
| 3 | -306.678310 | 11.425291 | 0.802526 | -297.509222 |
| 4 | -306.677049 | 11.423220 | 0.802739 | -297.507190 |
| 5 | -29.810340 | 4.254217 | 0.650060 | -27.044844 |
| 6 | -27.870663 | 3.525916 | 0.651508 | -25.573500 |
| 7 | -23.245986 | 2.245867 | 0.876768 | -21.276881 |
| 8 | -20.007442 | 1.430643 | 0.900379 | -18.719321 |
| 9 | -19.226818 | 1.406607 | 0.907253 | -17.950669 |
| 10 | -13.397838 | 0.512516 | 0.911646 | -12.930604 |
| 11 | -13.397838 | 0.512516 | 0.911646 | -12.930604 |
| 12 | -10.072307 | -0.126039 | 0.930591 | -10.189598 |
| 13 | -10.072307 | -0.126039 | 0.930591 | -10.189598 |
| 14 | 0.922808 | -0.100585 | 0.995561 | 0.822670 |
| 15 | 0.947454 | -0.145427 | 0.993944 | 0.802907 |
| 16 | 2.188696 | -0.616357 | 0.967556 | 1.592336 |
| 17 | 2.188696 | -0.616357 | 0.967556 | 1.592336 |
| 18 | 2.371988 | -0.236054 | 0.990762 | 2.138115 |
| 19 | 2.976599 | -0.210993 | 0.990545 | 2.767601 |
| 20 | 2.976599 | -0.210993 | 0.990545 | 2.767601 |
| 21 | 3.159852 | -0.177866 | 0.992653 | 2.983294 |
| 22 | 3.520045 | -0.560718 | 0.973505 | 2.974183 |
| 23 | 3.520045 | -0.560718 | 0.973505 | 2.974183 |
| 24 | 3.618257 | -0.272755 | 0.988470 | 3.348646 |
| 25 | 4.398142 | -0.343282 | 0.986110 | 4.059628 |
| 26 | 5.370551 | -0.510936 | 0.976608 | 4.871567 |
| 27 | 5.370551 | -0.510936 | 0.976608 | 4.871567 |
| 28 | 5.519359 | -0.221968 | 0.990585 | 5.299480 |
| 29 | 6.447972 | -0.235081 | 0.990820 | 6.215049 |
| 30 | 6.447972 | -0.235081 | 0.990820 | 6.215049 |
| 31 | 6.977516 | -0.508213 | 0.980384 | 6.479272 |
| 32 | 7.338813 | -0.560118 | 0.977430 | 6.791337 |
| 33 | 8.540293 | -0.713301 | 0.971674 | 7.847197 |
| 34 | 8.654252 | -1.428256 | 0.935415 | 7.318241 |
| 35 | 8.654252 | -1.428256 | 0.935415 | 7.318241 |
| 36 | 9.232294 | -0.559168 | 0.978283 | 8.685269 |
| 37 | 9.612617 | -0.957937 | 0.962221 | 8.690870 |
| 38 | 10.488301 | -0.697162 | 0.970680 | 9.811580 |
| 39 | 10.488301 | -0.697162 | 0.970680 | 9.811580 |
| 40 | 11.940665 | -0.699508 | 0.966829 | 11.264360 |
| 41 | 11.940665 | -0.699508 | 0.966829 | 11.264360 |
| 42 | 12.505195 | -0.722080 | 0.959809 | 11.812136 |
| 43 | 12.505195 | -0.722080 | 0.959809 | 11.812136 |
| 44 | 12.659829 | -1.912542 | 0.934236 | 10.873064 |
| 45 | 13.438726 | -1.388825 | 0.932390 | 12.143799 |
| 46 | 13.438726 | -1.388825 | 0.932390 | 12.143799 |
| 47 | 14.155140 | -0.872303 | 0.933734 | 13.340641 |
| 48 | 15.364823 | -0.861450 | 0.934470 | 14.559824 |
| 49 | 15.655286 | -1.095158 | 0.927424 | 14.639610 |
| 50 | 16.215679 | -0.919909 | 0.895087 | 15.392281 |
| 51 | 16.215679 | -0.919909 | 0.895087 | 15.392281 |
| 52 | 17.074962 | -1.190586 | 0.908832 | 15.992919 |
| 53 | 18.443608 | -0.738735 | 0.900915 | 17.778071 |
| 54 | 19.634077 | -1.282374 | 0.864951 | 18.524886 |
| 55 | 20.886067 | -1.421255 | 0.548653 | 20.106292 |
| 56 | 20.886067 | -1.421255 | 0.548653 | 20.106292 |
| 57 | 21.492044 | -1.867685 | 0.678150 | 20.225473 |
| 58 | 21.565780 | -0.892450 | 0.839286 | 20.816759 |
| 59 | 21.565780 | -0.892450 | 0.839286 | 20.816759 |
| 60 | 21.690638 | -2.230175 | 0.475306 | 20.630623 |
| 61 | 21.690638 | -2.230175 | 0.475306 | 20.630623 |
| 62 | 21.997258 | -1.031862 | 0.790002 | 21.182085 |
| 63 | 22.684458 | -2.039368 | 0.489708 | 21.685762 |
| 64 | 22.684458 | -2.039368 | 0.489708 | 21.685762 |
| 65 | 23.879731 | -2.371631 | 0.640537 | 22.360615 |
| 66 | 23.879731 | -2.371631 | 0.640537 | 22.360615 |
| 67 | 25.575577 | -2.915373 | 0.305477 | 24.684999 |
| 68 | 25.575577 | -2.915373 | 0.305477 | 24.684999 |
| 69 | 30.009231 | -3.683848 | 0.140087 | 29.493171 |
| 70 | 32.476409 | -2.751848 | 0.186349 | 31.963605 |
| 71 | 33.220170 | -2.269144 | 0.351492 | 32.422584 |
| 72 | 33.220170 | -2.269144 | 0.351492 | 32.422584 |
| 73 | 33.268728 | -1.772578 | 0.120864 | 33.054487 |
| 74 | 36.196122 | -1.750149 | 0.274455 | 35.715785 |
| 75 | 36.196122 | -1.750149 | 0.274455 | 35.715785 |
| 76 | 37.523976 | -3.202257 | 0.245011 | 36.739389 |
| 77 | 38.308109 | -2.411276 | 0.225053 | 37.765443 |
| 78 | 40.532863 | -1.948334 | 0.264388 | 40.017748 |
| 79 | 40.532863 | -1.948334 | 0.264388 | 40.017748 |
| 80 | 41.556539 | -2.360616 | 0.303257 | 40.840665 |
| 81 | 42.546232 | -1.615598 | 0.225132 | 42.182509 |
| 82 | 43.039323 | -2.700962 | 0.143627 | 42.651391 |
| 83 | 43.039323 | -2.700961 | 0.143627 | 42.651391 |
| 84 | 43.707785 | -2.049344 | 0.219113 | 43.258747 |
| 85 | 43.707785 | -2.049344 | 0.219113 | 43.258747 |
| 86 | 45.533067 | -2.470233 | 0.202717 | 45.032308 |
| 87 | 45.533067 | -2.470233 | 0.202717 | 45.032308 |
| 88 | 46.791219 | -3.668779 | 0.164741 | 46.186822 |
| 89 | 49.862332 | -2.739434 | 0.258695 | 49.153653 |
| 90 | 49.862332 | -2.739434 | 0.258695 | 49.153653 |
| 91 | 50.242824 | -2.181714 | 0.146171 | 49.923921 |
| 92 | 50.242824 | -2.181714 | 0.146171 | 49.923921 |
| 93 | 50.301101 | -2.466151 | 0.159137 | 49.908646 |
| 94 | 51.446788 | -3.004735 | 0.191380 | 50.871741 |
| 95 | 54.773396 | -2.866458 | 0.180511 | 54.255969 |
| 96 | 54.773396 | -2.866458 | 0.180511 | 54.255969 |
| 97 | 55.925742 | -4.234698 | 0.089607 | 55.546286 |
| 98 | 55.925742 | -4.234698 | 0.089607 | 55.546286 |
| 99 | 61.787550 | -2.415334 | 0.126911 | 61.481017 |
| 100 | 62.351516 | -3.484391 | 0.126210 | 61.911752 |
| 101 | 65.546862 | -2.751433 | 0.121781 | 65.211789 |
| 102 | 65.546862 | -2.751433 | 0.121781 | 65.211789 |
| 103 | 66.705476 | -2.247219 | 0.154959 | 66.357249 |
| 104 | 69.220928 | -2.504057 | 0.140952 | 68.867976 |
| 105 | 69.220928 | -2.504057 | 0.140952 | 68.867976 |
| 106 | 79.506606 | -2.715209 | 0.068652 | 79.320201 |
| 107 | 79.670299 | -1.884821 | 0.049379 | 79.577229 |
| 108 | 80.158469 | -2.732220 | 0.093960 | 79.901750 |
| 109 | 84.816100 | -5.170963 | 0.056094 | 84.526041 |
| 110 | 84.816100 | -5.170963 | 0.056094 | 84.526041 |
| 111 | 94.593871 | -2.689620 | 0.039804 | 94.486812 |
| 112 | 110.118921 | -4.385199 | 0.042729 | 109.931547 |
| 113 | 110.957672 | 0.661204 | 0.066899 | 111.001906 |
| 114 | 119.326999 | -0.660667 | 0.049196 | 119.294497 |
| 115 | 146.348696 | -1.206530 | 0.202506 | 146.104367 |
| 116 | 173.933769 | -0.898014 | 0.223588 | 173.732984 |
| 117 | 190.416884 | -3.800493 | 0.090870 | 190.071531 |
| 118 | 331.229968 | -1.135127 | 0.570771 | 330.582070 |
-------------------------------------------------------------------------------
G0W0 HOMO energy (eV): -10.189598
G0W0 LUMO energy (eV): 0.822670
G0W0 HOMO-LUMO gap (eV): 11.012268
-------------------------------------------------------------------------------
-------------------------------------------------------------------------------
Tr@RPA@G0W0 correlation energy (singlet) = -0.6217705819
Tr@RPA@G0W0 correlation energy (triplet) = 0.0000000000
Tr@RPA@G0W0 correlation energy = -0.6217705819
Tr@RPA@G0W0 total energy = -153.1347436707
-------------------------------------------------------------------------------
-------------------------------------------------------------
| BSE calculation: singlet manifold |
-------------------------------------------------------------
| State | Excitation energy (au) | Excitation energy (eV) |
-------------------------------------------------------------
| 1 | 0.206656 | 5.623400 |
| 2 | 0.215833 | 5.873106 |
| 3 | 0.215833 | 5.873106 |
| 4 | 0.272850 | 7.424632 |
| 5 | 0.272850 | 7.424632 |
| 6 | 0.288561 | 7.852134 |
| 7 | 0.292792 | 7.967289 |
| 8 | 0.292792 | 7.967289 |
| 9 | 0.292871 | 7.969435 |
| 10 | 0.305705 | 8.318657 |
| 11 | 0.305705 | 8.318657 |
| 12 | 0.312384 | 8.500396 |
| 13 | 0.312384 | 8.500396 |
| 14 | 0.314772 | 8.565391 |
| 15 | 0.314772 | 8.565391 |
| 16 | 0.316478 | 8.611798 |
| 17 | 0.340846 | 9.274887 |
| 18 | 0.341009 | 9.279327 |
| 19 | 0.341009 | 9.279327 |
| 20 | 0.344938 | 9.386228 |
| 21 | 0.349059 | 9.498371 |
| 22 | 0.349520 | 9.510914 |
| 23 | 0.349520 | 9.510914 |
| 24 | 0.373393 | 10.160530 |
| 25 | 0.373393 | 10.160530 |
| 26 | 0.380454 | 10.352683 |
| 27 | 0.380902 | 10.364876 |
| 28 | 0.380902 | 10.364876 |
| 29 | 0.385035 | 10.477338 |
| 30 | 0.385035 | 10.477338 |
| 31 | 0.396918 | 10.800696 |
| 32 | 0.396918 | 10.800696 |
-------------------------------------------------------------
--------------------------------
Excitation n. 1: 5.623400 eV
--------------------------------
12 -> 16 = -0.425345
12 -> 23 = 0.216180
12 -> 27 = -0.132963
13 -> 17 = -0.425345
13 -> 22 = -0.216180
13 -> 26 = 0.132963
--------------------------------
Excitation n. 2: 5.873106 eV
--------------------------------
12 -> 17 = -0.433098
12 -> 22 = -0.206149
12 -> 26 = 0.124334
13 -> 16 = -0.433098
13 -> 23 = 0.206149
13 -> 27 = -0.124334
--------------------------------
Excitation n. 3: 5.873106 eV
--------------------------------
12 -> 16 = 0.433098
12 -> 23 = -0.206149
12 -> 27 = 0.124334
13 -> 17 = -0.433098
13 -> 22 = -0.206149
13 -> 26 = 0.124334
--------------------------------
Excitation n. 4: 7.424632 eV
--------------------------------
12 -> 15 = 0.176984
12 -> 18 = 0.079131
13 -> 15 = -0.589497
13 -> 18 = -0.263568
13 -> 25 = -0.171443
--------------------------------
Excitation n. 5: 7.424632 eV
--------------------------------
12 -> 15 = -0.589497
12 -> 18 = -0.263568
12 -> 25 = -0.171443
13 -> 15 = -0.176984
13 -> 18 = -0.079131
--------------------------------
Excitation n. 6: 7.852134 eV
--------------------------------
12 -> 17 = 0.490115
12 -> 22 = -0.087286
13 -> 16 = -0.490115
13 -> 23 = -0.087286
--------------------------------
Excitation n. 7: 7.967289 eV
--------------------------------
10 -> 15 = -0.106415
13 -> 14 = 0.646558
13 -> 21 = 0.188844
13 -> 24 = -0.165771
--------------------------------
Excitation n. 8: 7.967289 eV
--------------------------------
11 -> 15 = 0.106415
12 -> 14 = -0.646558
12 -> 21 = -0.188844
12 -> 24 = 0.165771
--------------------------------
Excitation n. 9: 7.969435 eV
--------------------------------
10 -> 17 = 0.388437
10 -> 22 = 0.185969
10 -> 26 = -0.123590
11 -> 16 = 0.388437
11 -> 23 = -0.185969
11 -> 27 = 0.123590
12 -> 20 = -0.147948
12 -> 34 = 0.154249
13 -> 19 = 0.147948
13 -> 35 = 0.154249
--------------------------------
Excitation n. 10: 8.318657 eV
--------------------------------
10 -> 17 = -0.386196
10 -> 22 = -0.168395
10 -> 26 = 0.107412
11 -> 16 = 0.386196
11 -> 23 = -0.168395
11 -> 27 = 0.107412
12 -> 20 = -0.189752
12 -> 34 = 0.135971
13 -> 19 = -0.189752
13 -> 35 = -0.135971
---------------------------------------------------------------------------------------------------
First-order dynamical correction to static Bethe-Salpeter excitation energies
---------------------------------------------------------------------------------------------------
BSE neutral excitation must be lower than the GW gap = 11.012268 eV
---------------------------------------------------------------------------------------------------
# Static (eV) Dynamic (eV) Correction (eV) Renorm. (eV)
---------------------------------------------------------------------------------------------------
1 5.623400 5.347702 -0.275697 1.024693
2 5.873106 5.625903 -0.247204 1.024056
3 5.873106 5.625903 -0.247204 1.024056
4 7.424632 7.387513 -0.037119 1.004813
5 7.424632 7.387513 -0.037119 1.004813
6 7.852134 7.798349 -0.053785 1.010989
7 7.967289 7.941126 -0.026163 1.003223
8 7.967289 7.941126 -0.026163 1.003223
9 7.969435 7.593537 -0.375898 1.035767
10 8.318657 8.000224 -0.318433 1.033611
---------------------------------------------------------------------------------------------------
-------------------------------------------------------------
| BSE calculation: triplet manifold |
-------------------------------------------------------------
| State | Excitation energy (au) | Excitation energy (eV) |
-------------------------------------------------------------
| 1 | 0.204081 | 5.553314 |
| 2 | 0.217343 | 5.914214 |
| 3 | 0.217343 | 5.914214 |
| 4 | 0.229258 | 6.238432 |
| 5 | 0.274234 | 7.462284 |
| 6 | 0.274234 | 7.462284 |
| 7 | 0.293069 | 7.974821 |
| 8 | 0.293069 | 7.974821 |
| 9 | 0.302188 | 8.222961 |
| 10 | 0.312268 | 8.497250 |
| 11 | 0.313793 | 8.538735 |
| 12 | 0.313793 | 8.538735 |
| 13 | 0.317446 | 8.638147 |
| 14 | 0.317446 | 8.638147 |
| 15 | 0.317825 | 8.648463 |
| 16 | 0.317825 | 8.648463 |
| 17 | 0.323202 | 8.794787 |
| 18 | 0.330623 | 8.996716 |
| 19 | 0.335691 | 9.134628 |
| 20 | 0.339637 | 9.241983 |
| 21 | 0.339637 | 9.241983 |
| 22 | 0.343415 | 9.344792 |
| 23 | 0.349431 | 9.508504 |
| 24 | 0.349431 | 9.508504 |
| 25 | 0.375882 | 10.228266 |
| 26 | 0.375882 | 10.228266 |
| 27 | 0.378179 | 10.290781 |
| 28 | 0.378179 | 10.290781 |
| 29 | 0.388194 | 10.563284 |
| 30 | 0.388194 | 10.563284 |
| 31 | 0.393007 | 10.694254 |
| 32 | 0.393007 | 10.694254 |
-------------------------------------------------------------
--------------------------------
Excitation n. 1: 5.553314 eV
--------------------------------
12 -> 17 = 0.429086
12 -> 22 = 0.221001
12 -> 26 = -0.129309
13 -> 16 = -0.429086
13 -> 23 = 0.221001
13 -> 27 = -0.129309
--------------------------------
Excitation n. 2: 5.914214 eV
--------------------------------
12 -> 16 = 0.284520
12 -> 17 = -0.331645
12 -> 22 = -0.161481
12 -> 23 = -0.139316
12 -> 26 = 0.093370
12 -> 27 = 0.077731
13 -> 16 = -0.331645
13 -> 17 = -0.284520
13 -> 22 = -0.139316
13 -> 23 = 0.161481
13 -> 26 = 0.077731
13 -> 27 = -0.093370
--------------------------------
Excitation n. 3: 5.914214 eV
--------------------------------
12 -> 16 = -0.331645
12 -> 17 = -0.284520
12 -> 22 = -0.139316
12 -> 23 = 0.161481
12 -> 26 = 0.077731
12 -> 27 = -0.093370
13 -> 16 = -0.284520
13 -> 17 = 0.331645
13 -> 22 = 0.161481
13 -> 23 = 0.139316
13 -> 26 = -0.093370
13 -> 27 = -0.077731
--------------------------------
Excitation n. 4: 6.238432 eV
--------------------------------
12 -> 16 = 0.444328
12 -> 23 = -0.204190
12 -> 27 = 0.113741
13 -> 17 = 0.444328
13 -> 22 = 0.204190
13 -> 26 = -0.113741
--------------------------------
Excitation n. 5: 7.462284 eV
--------------------------------
13 -> 15 = 0.621443
13 -> 18 = 0.260375
13 -> 25 = 0.178016
--------------------------------
Excitation n. 6: 7.462284 eV
--------------------------------
12 -> 15 = -0.621443
12 -> 18 = -0.260375
12 -> 25 = -0.178016
--------------------------------
Excitation n. 7: 7.974821 eV
--------------------------------
13 -> 14 = -0.653950
13 -> 21 = -0.190908
13 -> 24 = 0.168776
--------------------------------
Excitation n. 8: 7.974821 eV
--------------------------------
12 -> 14 = 0.653950
12 -> 21 = 0.190908
12 -> 24 = -0.168776
--------------------------------
Excitation n. 9: 8.222961 eV
--------------------------------
10 -> 16 = 0.396361
10 -> 23 = -0.207650
10 -> 27 = 0.112939
11 -> 17 = -0.396361
11 -> 22 = -0.207650
11 -> 26 = 0.112939
12 -> 19 = -0.160539
12 -> 35 = -0.098307
13 -> 20 = -0.160539
13 -> 34 = 0.098307
--------------------------------
Excitation n. 10: 8.497250 eV
--------------------------------
12 -> 17 = -0.222903
12 -> 22 = 0.444921
13 -> 16 = 0.222903
13 -> 23 = 0.444921
---------------------------------------------------------------------------------------------------
First-order dynamical correction to static Bethe-Salpeter excitation energies
---------------------------------------------------------------------------------------------------
BSE neutral excitation must be lower than the GW gap = 11.012268 eV
---------------------------------------------------------------------------------------------------
# Static (eV) Dynamic (eV) Correction (eV) Renorm. (eV)
---------------------------------------------------------------------------------------------------
1 5.553314 5.055769 -0.497545 1.045908
2 5.914214 5.518889 -0.395325 1.042280
3 5.914214 5.518889 -0.395325 1.042280
4 6.238432 5.926391 -0.312040 1.039072
5 7.462284 7.401309 -0.060975 1.007907
6 7.462284 7.401309 -0.060975 1.007907
7 7.974821 7.949716 -0.025105 1.002622
8 7.974821 7.949716 -0.025105 1.002622
9 8.222961 7.504358 -0.718603 1.072508
10 8.497250 8.404514 -0.092736 1.012034
---------------------------------------------------------------------------------------------------
-------------------------------------------------------------------------------
Tr@BSE@G0W0 correlation energy (singlet) = -0.5202364310
Tr@BSE@G0W0 correlation energy (triplet) = -0.1105466142
Tr@BSE@G0W0 correlation energy = -0.6307830452
Tr@BSE@G0W0 total energy = -153.1437561340
-------------------------------------------------------------------------------
Total CPU time for G0W0 = 2533.416 seconds
Total CPU time for QuAcK = 2626.366 seconds