subroutine huckel_guess(nBas,nO,S,Hc,ERI,X,cp,F,Fp,e,c) ! Hickel guess of the molecular orbitals for HF calculation implicit none ! Input variables integer,intent(in) :: nBas integer,intent(in) :: nO double precision,intent(in) :: S(nBas,nBas) double precision,intent(in) :: Hc(nBas,nBas) double precision,intent(in) :: ERI(nBas,nBas,nBas,nBas) double precision,intent(in) :: X(nBas,nBas) double precision,intent(inout):: cp(nBas,nBas) double precision,intent(inout):: F(nBas,nBas) double precision,intent(inout):: Fp(nBas,nBas) double precision,intent(inout):: e(nBas) ! Local variables integer :: mu,nu double precision :: a ! Output variables double precision,intent(out) :: c(nBas,nBas) a = 1.75d0 F(:,:) = Hc(:,:) do mu=1,nBas do nu=mu+1,nBas F(mu,nu) = 0.5d0*a*S(mu,nu)*(Hc(mu,mu) + Hc(nu,nu)) F(nu,mu) = F(mu,nu) enddo enddo Fp(:,:) = matmul(transpose(X(:,:)),matmul(F(:,:),X(:,:))) cp(:,:) = Fp(:,:) call diagonalize_matrix(nBas,cp,e) c(:,:) = matmul(X(:,:),cp(:,:)) end subroutine