mirror of
https://github.com/pfloos/quack
synced 2024-11-06 22:24:03 +01:00
ppURPA
This commit is contained in:
parent
fcf46af600
commit
5d5824ce14
@ -13,9 +13,9 @@
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# G0F2* evGF2* qsGF2* G0F3 evGF3
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F F F F F
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# G0W0* evGW* qsGW* ufG0W0 ufGW
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F F F F F
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F F T F F
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# G0T0 evGT qsGT
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T F F
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F F F
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# MCMP2
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F
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# * unrestricted version available
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@ -11,8 +11,8 @@
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# GW/GT: maxSCF thresh DIIS n_diis lin eta COHSEX SOSEX TDA_W G0W GW0
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256 0.00001 T 15 T 0.00367493 F F F F F
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# ACFDT: AC Kx XBS
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F T F
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F F F
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# BSE: BSE dBSE dTDA evDyn
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T T T F
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F F F F
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# MCMP2: nMC nEq nWalk dt nPrint iSeed doDrift
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1000000 100000 10 0.3 10000 1234 T
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@ -1,4 +1,4 @@
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2
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H 0. 0. 0.
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H 0. 0. 0.5
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H 0. 0. 1.2
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116
src/LR/unrestricted_linear_response_B_pp.f90
Normal file
116
src/LR/unrestricted_linear_response_B_pp.f90
Normal file
@ -0,0 +1,116 @@
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subroutine unrestricted_linear_response_B_pp(ispin,nBas,nC,nO,nV,nR,nPaa,nPab,nPbb,nPt,nHaa, &
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nHab,nHbb,nHt,lambda,e,ERI_aaaa,ERI_aabb,ERI_bbbb,B_pp)
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! Compute linear response
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implicit none
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include 'parameters.h'
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! Input variables
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integer,intent(in) :: ispin
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integer,intent(in) :: nBas
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integer,intent(in) :: nC(nspin)
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integer,intent(in) :: nO(nspin)
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integer,intent(in) :: nV(nspin)
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integer,intent(in) :: nR(nspin)
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integer,intent(in) :: nPaa
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integer,intent(in) :: nPab
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integer,intent(in) :: nPbb
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integer,intent(in) :: nPt
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integer,intent(in) :: nHaa
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integer,intent(in) :: nHab
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integer,intent(in) :: nHbb
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integer,intent(in) :: nHt
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double precision,intent(in) :: lambda
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double precision,intent(in) :: e(nBas,nspin)
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double precision,intent(in) :: ERI_aaaa(nBas,nBas,nBas,nBas)
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double precision,intent(in) :: ERI_aabb(nBas,nBas,nBas,nBas)
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double precision,intent(in) :: ERI_bbbb(nBas,nBas,nBas,nBas)
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! Local variables
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double precision :: eF
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double precision,external :: Kronecker_delta
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integer :: i,j,a,b,c,d,ij,ab
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! Output variables
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double precision,intent(out) :: B_pp(nPt,nHt)
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eF = 0d0
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!-----------------------------------------------
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! Build B matrix for spin-conserving transitions
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!-----------------------------------------------
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if(ispin == 1) then
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! aaaa block
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ab = 0
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do a=nO(1)+1,nBas-nR(1)
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do b=nO(1)+1,nBas-nR(1)
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ab = ab + 1
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ij = 0
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do i=nC(1)+1,nO(1)
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do j=nC(1)+1,nO(1)
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ij = ij + 1
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B_pp(ab,ij) = lambda*(ERI_aaaa(a,b,i,j) - ERI_aaaa(a,b,j,i))
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end do
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end do
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end do
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end do
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! bbbb block
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ab = 0
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do a=nO(2)+1,nBas-nR(2)
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do b=nO(2)+1,nBas-nR(2)
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ab = ab + 1
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ij = 0
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do i=nC(2)+1,nO(2)
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do j=nC(2)+1,nO(2)
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ij = ij + 1
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B_pp(nPaa+nPab+ab,nHaa+nHab+ij) = lambda*(ERI_bbbb(a,b,i,j) - ERI_bbbb(a,b,j,i))
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end do
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end do
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end do
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end do
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end if
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!-----------------------------------------------
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! Build B matrix for spin-flip transitions
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!-----------------------------------------------
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if(ispin == 2) then
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B_pp(:,:) = 0d0
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! abab block
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ab = 0
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do a=nO(1)+1,nBas-nR(1)
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do b=nO(2)+1,nBas-nR(2)
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ab = ab + 1
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ij = 0
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do i=nC(1)+1,nO(1)
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do j=nC(2)+1,nO(2)
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ij = ij + 1
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B_pp(nPaa+ab,nHaa+ij) = lambda*ERI_aabb(a,b,i,j)
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end do
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end do
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end do
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end do
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end if
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end subroutine unrestricted_linear_response_B_pp
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115
src/LR/unrestricted_linear_response_C_pp.f90
Normal file
115
src/LR/unrestricted_linear_response_C_pp.f90
Normal file
@ -0,0 +1,115 @@
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subroutine unrestricted_linear_response_C_pp(ispin,nBas,nC,nO,nV,nR,nPaa,nPab,nPbb,nPt,lambda,&
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e,ERI_aaaa,ERI_aabb,ERI_bbbb,C_pp)
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! Compute linear response
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implicit none
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include 'parameters.h'
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! Input variables
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integer,intent(in) :: ispin
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integer,intent(in) :: nBas
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integer,intent(in) :: nC(nspin)
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integer,intent(in) :: nO(nspin)
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integer,intent(in) :: nV(nspin)
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integer,intent(in) :: nR(nspin)
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integer,intent(in) :: nPaa
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integer,intent(in) :: nPab
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integer,intent(in) :: nPbb
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integer,intent(in) :: nPt
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double precision,intent(in) :: lambda
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double precision,intent(in) :: e(nBas,nspin)
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double precision,intent(in) :: ERI_aaaa(nBas,nBas,nBas,nBas)
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double precision,intent(in) :: ERI_aabb(nBas,nBas,nBas,nBas)
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double precision,intent(in) :: ERI_bbbb(nBas,nBas,nBas,nBas)
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! Local variables
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double precision :: eF
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double precision,external :: Kronecker_delta
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integer :: i,j,a,b,c,d,ab,cd
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! Output variables
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double precision,intent(out) :: C_pp(nPt,nPt)
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eF = 0d0
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!-----------------------------------------------
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! Build C matrix for spin-conserving transitions
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!-----------------------------------------------
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if(ispin == 1) then
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! aaaa block
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ab = 0
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do a=nO(1)+1,nBas-nR(1)
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do b=nO(1)+1,nBas-nR(1)
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ab = ab + 1
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cd = 0
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do c=nO(1)+1,nBas-nR(1)
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do d=nO(1)+1,nBas-nR(1)
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cd = cd + 1
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C_pp(ab,cd) = (e(a,1) + e(b,1) - eF)*Kronecker_delta(a,c)*Kronecker_delta(b,d) &
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+ lambda*(ERI_aaaa(a,b,c,d) - ERI_aaaa(a,b,d,c))
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end do
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end do
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end do
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end do
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! bbbb block
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ab = 0
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do a=nO(2)+1,nBas-nR(2)
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do b=nO(2)+1,nBas-nR(2)
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ab = ab + 1
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cd = 0
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do c=nO(2)+1,nBas-nR(2)
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do d=nO(2)+1,nBas-nR(2)
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cd = cd + 1
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C_pp(nPaa+nPab+ab,nPaa+nPab+cd) = (e(a,2) + e(b,2) - eF)*Kronecker_delta(a,c) &
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*Kronecker_delta(b,d) + lambda*(ERI_bbbb(a,b,c,d) - ERI_bbbb(a,b,d,c))
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end do
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end do
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end do
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end do
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end if
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!-----------------------------------------------
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! Build C matrix for spin-flip transitions
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!-----------------------------------------------
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if(ispin == 2) then
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C_pp(:,:) = 0d0
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! abab block
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ab = 0
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do a=nO(1)+1,nBas-nR(1)
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do b=nO(2)+1,nBas-nR(2)
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ab = ab + 1
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cd = 0
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do c=nO(1)+1,nBas-nR(1)
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do d=nO(2)+1,nBas-nR(2)
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cd = cd + 1
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C_pp(nPaa+ab,nPaa+cd) = (e(a,1) + e(b,2))*Kronecker_delta(a,c) &
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*Kronecker_delta(b,c) + lambda*ERI_aabb(a,b,c,d)
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end do
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end do
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end do
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end do
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end if
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end subroutine unrestricted_linear_response_C_pp
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115
src/LR/unrestricted_linear_response_D_pp.f90
Normal file
115
src/LR/unrestricted_linear_response_D_pp.f90
Normal file
@ -0,0 +1,115 @@
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subroutine unrestricted_linear_response_D_pp(ispin,nBas,nC,nO,nV,nR,nHaa,nHab,nHbb,nHt,lambda,&
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e,ERI_aaaa,ERI_aabb,ERI_bbbb,D_pp)
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! Compute linear response
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implicit none
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include 'parameters.h'
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! Input variables
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integer,intent(in) :: ispin
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integer,intent(in) :: nBas
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integer,intent(in) :: nC(nspin)
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integer,intent(in) :: nO(nspin)
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integer,intent(in) :: nV(nspin)
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integer,intent(in) :: nR(nspin)
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integer,intent(in) :: nHaa
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integer,intent(in) :: nHab
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integer,intent(in) :: nHbb
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integer,intent(in) :: nHt
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double precision,intent(in) :: lambda
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double precision,intent(in) :: e(nBas,nspin)
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double precision,intent(in) :: ERI_aaaa(nBas,nBas,nBas,nBas)
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double precision,intent(in) :: ERI_aabb(nBas,nBas,nBas,nBas)
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double precision,intent(in) :: ERI_bbbb(nBas,nBas,nBas,nBas)
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! Local variables
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double precision :: eF
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double precision,external :: Kronecker_delta
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integer :: i,j,k,l,ij,kl
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! Output variables
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double precision,intent(out) :: D_pp(nHt,nHt)
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eF = 0d0
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!-----------------------------------------------
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! Build D matrix for spin-conserving transitions
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!-----------------------------------------------
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if(ispin == 1) then
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! aaaa block
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ij = 0
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do i=nC(1)+1,nO(1)
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do j=nC(1)+1,nO(1)
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ij = ij + 1
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kl = 0
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do k=nC(1)+1,nO(1)
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do l=nC(1)+1,nO(1)
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kl = kl + 1
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D_pp(ij,kl) = -(e(i,1) + e(j,1) - eF)*Kronecker_delta(i,k)*Kronecker_delta(j,l) &
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+ lambda*(ERI_aaaa(i,j,k,l) - ERI_aaaa(i,j,l,k))
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end do
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end do
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end do
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end do
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! bbbb block
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ij = 0
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do i=nC(2)+1,nO(2)
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do j=nC(2)+1,nO(2)
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ij = ij + 1
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kl = 0
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do k=nC(2)+1,nO(2)
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do l=nC(2)+1,nO(2)
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kl = kl + 1
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D_pp(nHaa+nHab+ij,nHaa+nHab+kl) = -(e(i,2) + e(j,2) - eF)*Kronecker_delta(i,k) &
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*Kronecker_delta(j,l) + lambda*(ERI_bbbb(i,j,k,l) - ERI_bbbb(i,j,l,k))
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end do
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end do
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end do
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end do
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end if
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!-----------------------------------------------
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! Build D matrix for spin-flip transitions
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!-----------------------------------------------
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if(ispin == 2) then
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D_pp(:,:) = 0d0
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! abab block
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ij = 0
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do i=nC(1)+1,nO(1)
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do j=nC(2)+1,nO(2)
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ij = ij + 1
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kl = 0
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do k=nC(1)+1,nO(1)
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do l=nC(2)+1,nO(2)
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kl = kl + 1
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D_pp(nHaa+ij,nHaa+kl) = -(e(i,1) + e(j,2))*Kronecker_delta(i,k)&
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*Kronecker_delta(j,l) +lambda*ERI_aabb(i,j,k,l)
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end do
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end do
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end do
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end do
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end if
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end subroutine unrestricted_linear_response_D_pp
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102
src/LR/unrestricted_linear_response_pp.f90
Normal file
102
src/LR/unrestricted_linear_response_pp.f90
Normal file
@ -0,0 +1,102 @@
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subroutine unrestricted_linear_response_pp(ispin,TDA,nBas,nC,nO,nV,nR,nPaa,nPab,nPbb,nPt, &
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nHaa,nHab,nHbb,nHt,nS_sc,lambda,e,ERI_aaaa,ERI_aabb,ERI_bbbb,Omega1,X1,Y1,Omega2,X2,Y2,&
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EcRPA)
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! Compute linear response for unrestricted formalism
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implicit none
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include 'parameters.h'
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! Input variables
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integer,intent(in) :: ispin
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logical,intent(in) :: TDA
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integer,intent(in) :: nBas
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integer,intent(in) :: nC(nspin)
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integer,intent(in) :: nO(nspin)
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integer,intent(in) :: nV(nspin)
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integer,intent(in) :: nR(nspin)
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integer,intent(in) :: nPaa
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integer,intent(in) :: nPab
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integer,intent(in) :: nPbb
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integer,intent(in) :: nPt
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integer,intent(in) :: nHaa
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integer,intent(in) :: nHab
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integer,intent(in) :: nHbb
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integer,intent(in) :: nHt
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integer,intent(in) :: nS_sc
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double precision,intent(in) :: lambda
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double precision,intent(in) :: e(nBas,nspin)
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double precision,intent(in) :: ERI_aaaa(nBas,nBas,nBas,nBas)
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double precision,intent(in) :: ERI_aabb(nBas,nBas,nBas,nBas)
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double precision,intent(in) :: ERI_bbbb(nBas,nBas,nBas,nBas)
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! Local variables
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double precision,external :: trace_matrix
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double precision :: EcRPA1
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double precision :: EcRPA2
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double precision,allocatable :: C(:,:)
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double precision,allocatable :: B(:,:)
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double precision,allocatable :: D(:,:)
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double precision,allocatable :: M(:,:)
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double precision,allocatable :: Z(:,:)
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double precision,allocatable :: Omega(:)
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! Output variables
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double precision,intent(out) :: Omega1(nPt)
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double precision,intent(out) :: X1(nPt,nPt)
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double precision,intent(out) :: Y1(nHt,nPt)
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double precision,intent(out) :: Omega2(nHt)
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double precision,intent(out) :: X2(nPt,nHt)
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double precision,intent(out) :: Y2(nHt,nHt)
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double precision,intent(out) :: EcRPA
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! Memory allocation
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allocate(C(nPt,nPt),B(nPt,nHt),D(nHt,nHt),M(nPt+nHt,nPt+nHt),Z(nPt+nHt,nPt+nHt),&
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Omega(nPt+nHt))
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! Build C, B and D matrices for the pp channel
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call unrestricted_linear_response_C_pp(ispin,nBas,nC,nO,nV,nR,nPaa,nPab,nPbb,nPt,lambda,&
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e,ERI_aaaa,ERI_aabb,ERI_bbbb,C)
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call unrestricted_linear_response_B_pp(ispin,nBas,nC,nO,nV,nR,nPaa,nPab,nPbb,nPt,nHaa,&
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nHab,nHbb,nHt,lambda,ERI_aaaa,ERI_aabb,ERI_bbbb,B)
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call unrestricted_linear_response_D_pp(ispin,nBas,nC,nO,nV,nR,nHaa,nHab,nHbb,nHt,lambda,&
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ERI_aaaa,ERI_aabb,ERI_bbbb,D)
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! Diagonal blocks
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M( 1:nPt , 1:nPt) = + C(1:nPt,1:nPt)
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M(nPt+1:nPt+nHt,nPt+1:nPt+nHt) = - D(1:nHt,1:nHt)
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! Off-diagonal blocks
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M( 1:nPt ,nPt+1:nHt+nPt) = - B(1:nPt,1:nHt)
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M(nPt+1:nHt+nPt, 1:nPt) = + transpose(B(1:nPt,1:nHt))
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! Diagonalize the p-h matrix
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if(nHt+nPt > 0) call diagonalize_general_matrix(nHt+nPt,M,Omega,Z)
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! Split the various quantities in p-p and h-h parts
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call sort_ppRPA(nHt,nPt,Omega(:),Z(:,:),Omega1(:),X1(:,:),Y1(:,:),Omega2(:),X2(:,:),&
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Y2(:,:))
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! end if Pourquoi ne faut-il pas de end if ici ?
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! Compute the RPA correlation energy
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||||
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EcRPA = 0.5d0*( sum(Omega1(:)) - sum(Omega2(:)) - trace_matrix(nPt,C(:,:)) - trace_matrix(nHt,D(:,:)) )
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EcRPA1 = +sum(Omega1(:)) - trace_matrix(nPt,C(:,:))
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||||
EcRPA2 = -sum(Omega2(:)) - trace_matrix(nHt,D(:,:))
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if(abs(EcRPA - EcRPA1) > 1d-6 .or. abs(EcRPA - EcRPA2) > 1d-6) &
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print*,'!!! Issue in pp-RPA linear reponse calculation RPA1 != RPA2 !!!'
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|
||||
end subroutine unrestricted_linear_response_pp
|
@ -27,14 +27,14 @@ subroutine ppURPA(TDA,doACFDT,spin_conserved,spin_flip,nBas,nC,nO,nV,nR,ENuc,EUH
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integer :: ispin
|
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integer :: nS
|
||||
integer :: nOOs,nOOt
|
||||
integer :: nVVs,nVVt
|
||||
double precision,allocatable :: Omega1s(:),Omega1t(:)
|
||||
double precision,allocatable :: X1s(:,:),X1t(:,:)
|
||||
double precision,allocatable :: Y1s(:,:),Y1t(:,:)
|
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double precision,allocatable :: Omega2s(:),Omega2t(:)
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||||
double precision,allocatable :: X2s(:,:),X2t(:,:)
|
||||
double precision,allocatable :: Y2s(:,:),Y2t(:,:)
|
||||
integer :: nPaa,nPbb,nPab,nPt
|
||||
integer :: nHaa,nHbb,nHab,nHt
|
||||
double precision,allocatable :: Omega1(:)
|
||||
double precision,allocatable :: X1(:,:)
|
||||
double precision,allocatable :: Y1(:,:)
|
||||
double precision,allocatable :: Omega2(:)
|
||||
double precision,allocatable :: X2(:,:)
|
||||
double precision,allocatable :: Y2(:,:)
|
||||
|
||||
double precision :: Ec_ppRPA(nspin)
|
||||
double precision :: EcAC(nspin)
|
||||
@ -54,18 +54,20 @@ subroutine ppURPA(TDA,doACFDT,spin_conserved,spin_flip,nBas,nC,nO,nV,nR,ENuc,EUH
|
||||
|
||||
! Useful quantities
|
||||
|
||||
! nS = nO*nV
|
||||
nPaa = nV(1)*(nV(1)-1)/2
|
||||
nPab = nV(1)*nV(2)
|
||||
nPbb = nV(2)*nV(2)
|
||||
nPt = nPaa + nPab + nPbb
|
||||
|
||||
! nOOs = nO*(nO+1)/2
|
||||
! nVVs = nV*(nV+1)/2
|
||||
|
||||
! nOOt = nO*(nO-1)/2
|
||||
! nVVt = nV*(nV-1)/2
|
||||
nHaa = nO(1)*(nO(1)-1)/2
|
||||
nHab = nO(1)*nO(2)
|
||||
nHbb = nO(2)*nO(2)
|
||||
nHt = nHaa + nHab + nHbb
|
||||
|
||||
! Memory allocation
|
||||
|
||||
! allocate(Omega1s(nVVs),X1s(nVVs,nVVs),Y1s(nOOs,nVVs), &
|
||||
! Omega2s(nOOs),X2s(nVVs,nOOs),Y2s(nOOs,nOOs))
|
||||
allocate(Omega1(nPt),X1(nPt,nPt),Y1(nHt,nPt), &
|
||||
Omega2(nHt),X2(nPt,nHt),Y2(nHt,nHt))
|
||||
|
||||
! allocate(Omega1t(nVVt),X1t(nVVt,nVVt),Y1t(nOOt,nVVt), &
|
||||
! Omega2t(nOOt),X2t(nVVt,nOOt),Y2t(nOOt,nOOt))
|
||||
|
Loading…
Reference in New Issue
Block a user