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QCaml/Basis/AOBasis.ml

131 lines
2.7 KiB
OCaml

open Lacaml.D
open Util
type t =
{
basis : Basis.t ;
overlap : Overlap.t lazy_t;
ortho : Orthonormalization.t lazy_t;
eN_ints : NucInt.t lazy_t;
kin_ints : KinInt.t lazy_t;
ee_ints : ERI.t lazy_t;
f12_ints : F12.t lazy_t;
cartesian : bool;
}
let basis t = t.basis
let overlap t = Lazy.force t.overlap
let ortho t = Lazy.force t.ortho
let eN_ints t = Lazy.force t.eN_ints
let kin_ints t = Lazy.force t.kin_ints
let ee_ints t = Lazy.force t.ee_ints
let f12_ints t = Lazy.force t.f12_ints
let cartesian t = t.cartesian
let make ~cartesian ~basis ?f12 nuclei =
let overlap = lazy (
Overlap.of_basis basis
) in
let ortho = lazy (
Orthonormalization.make ~cartesian ~basis (Lazy.force overlap)
) in
let eN_ints = lazy (
NucInt.of_basis_nuclei ~basis nuclei
) in
let kin_ints = lazy (
KinInt.of_basis basis
) in
let ee_ints = lazy (
ERI.of_basis basis
) in
let f12_ints = lazy (
F12.of_basis basis
) in
{ basis ; overlap ; ortho ; eN_ints ; kin_ints ; ee_ints ; f12_ints ;
cartesian ;
}
let test_case t =
let check_matrix title a r =
let a = Mat.to_array a in
Array.iteri (fun i x ->
let message =
Printf.sprintf "%s line %d" title i
in
Alcotest.(check (array (float 1.e-10))) message a.(i) x
) (Mat.to_array r)
in
let check_eri title a r =
let f { ERI.i_r1 ; j_r2 ; k_r1 ; l_r2 ; value } =
(i_r1, (j_r2, (k_r1, (l_r2, value))))
in
let a = ERI.to_list a |> List.map f
and r = ERI.to_list r |> List.map f
in
Alcotest.(check (list (pair int (pair int (pair int (pair int (float 1.e-12))))))) "ERI" a r
in
let test_overlap () =
let reference =
sym_matrix_of_file "test_files/ao_overlap.ref"
in
let overlap =
Lazy.force t.overlap |> Overlap.matrix
in
check_matrix "Overlap" overlap reference
in
let test_eN_ints () =
let reference =
sym_matrix_of_file "test_files/ao_nuc.ref"
in
let eN_ints =
Lazy.force t.eN_ints |> NucInt.matrix
in
check_matrix "eN_ints" eN_ints reference
in
let test_kin_ints () =
let reference =
sym_matrix_of_file "test_files/ao_kin.ref"
in
let kin_ints =
Lazy.force t.kin_ints |> KinInt.matrix
in
check_matrix "kin_ints" kin_ints reference
in
let test_ee_ints () =
let reference =
ERI.of_file "test_files/ao_eri.ref" ~sparsity:`Dense ~size:(Basis.size t.basis)
in
let ee_ints =
Lazy.force t.ee_ints
in
check_eri "ee_ints" ee_ints reference
in
[
"Overlap", `Quick, test_overlap;
"eN_ints", `Quick, test_eN_ints;
"kin_ints", `Quick, test_kin_ints;
"ee_ints", `Quick, test_ee_ints;
]